TW200922470A - Water-soluble concentrates of 3-(2-alkoxy-4-chloro-6-alkylphenyl)-substituted tetramates and their corresponding enoles - Google Patents

Abstract

The present invention relates to novel water-soluble concentrates of 3-(2-alkoxy-4-chloro-6-alkylphenyl)-substituted tetramates and enoles thereof, to processes for preparing these formulations and to their use as pesticides and/or herbicides.

Description

200922470 VI. INSTRUCTIONS OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to novel water-soluble concentrates of 3-(2-alkoxy-4-chloro-6-alkylphenyl)-substituted pyrrolidonic acid salts. (SL Formulations) and Enols thereof, 5 Methods of preparing these formulations and their use as herbicides. [Prior Art] The medical properties of 3-mercaptopyrrolidine-2,4-dione have been previously disclosed (S. Suzuki et al., Chem. Pharm. Bull 15: 1120 (1967)). Furthermore, 1〇 R. Schmierer and H. Mildenberger (Liebigs Ann. Chem. * 1985, 1095) have synthesized N-phenylpyrrolidine-2,4-dione. The biological activities of these compounds have not been described. A similarly constructed compound (3-arylpyrrolidine-2,4-dione) is disclosed in ΕΡ-Α-0 262 399 and GB-A-2 266 888, however it does not have herbicidal, insecticidal or 15 acaricidal action. A known compound having herbicidal, insecticidal or acaricidal action is an unsaturated bicyclic 3-arylpyrrolidin-2,4-dione derivative (EP-A-355, EP-A-' 415 211 and JP-A). -12-053 670) and saturated monocyclic 3-arylpyrrolidine-2,4-dione derivatives (EP-A-377 893 and EP-A-442-077). Other known are polycyclic 3-arylpyrrolidine-2,4-dione derivatives (EP-20 A-442 073) and 1H-arylpyrrolidinedione derivatives (EP-A-456 063, EP-A-521 334, EP-A-596 298, EP-A-613 884, EP-A-613 885, WO 94/01 997, WO 95/26 954, WO 95/20 572, ΕΡ-Α- 0 668 267, WO 96/25 395, WO 96/35 664, WO 97/01 535,

WO 97/02 243, WO 97/36 868, WO 97/43275, WO 3 200922470 98/05638, WO 98/06721, WO 98/25928, WO 99/24437,

WO 99/43649, WO 99/48869 and WO 99/55673, WO 01/17972, WO 01/23354, WO 01/74770, WO 03/013249,

WO 03/062244, WO 2004/007448, WO 2004/024 688, WO

5 04/065366, WO 04/080962, WO 04/111042, WO

05/044791, WO 05/044 796, WO 05/048710, WO 05/049596, WO 05/066125, WO 05/092897, WO 06/000355, WO 06/029799, WO 06/056 281, WO 06/056282 , WO 06/089633 and WO 07/048545). It is further known that the 1H-arylpyrrolidine-2,4-dione is substituted by the i ketal from WO 99/16748 and the substituted (helical) ketal is substituted for the N-alkoxy alkoxy aryl pyrrolidine. From JP-A-14 205 984 and Ito M. et al., Bioscience, Biotechnology and Biochemistry 67, 1230~1238 (2003). The substituted 3-(2-alkoxy-4,4-oxa-6-alkylphenyl)pyrrolidonic acid is known from w〇 15 2004/080962. However, the known compounds are particularly incapable of obtaining stable herbicidal activity and/or range of action and/or plant compatibility for crops. As a concentrated formulation of the active compound described below, only the EC formulation (emulsified concentrate) is disclosed in W〇〇4/〇8〇962. When used, it is diluted in water. Its 2〇 does not reveal aqueous formulations. The use of certain surfactants in insecticide and/or herbicidal compositions is disclosed in DE 35 13 889, US 6,184, 182 and US 5,389,598. However, the active compound is different from that described in the present invention. 4 200922470 SUMMARY OF THE INVENTION Concentrated compositions have been found which comprise a phase comprising at least one dissolved active compound of the formula (Ι-A) or (I-B)

(IA) (IB) 10 In the formula (Ι-A) or (IB): X represents a methoxy or ethoxy group, W represents a decyl group or an ethyl group, 15 Y represents chlorine, and m represents 1, 2 or 3 , η represents 1, 2 or 3, Α represents a CrQ alkyl group or a cyclopropyl group, B represents a fluorenyl group, and D represents a hydrogen; or A, B and a carbon atom to which they are bonded represent a saturated C5 to C6 cycloalkyl group, wherein one ring The member is optionally substituted by oxygen and is optionally substituted by a thiol, decyloxy or ethoxy group; 5 20 200922470 A and D together represent Q~(:4 alkylene, G represents metallurgy The equivalent ion of the ion, the soil of the soil, the equivalent ion of the equivalent ion or the equivalent ion of the transition metal or the others; the representative of the ion, wherein - two, three or all four hydrogen atoms are selectively hydrogen, Cl~ The c5_alkyl group, the Ci~C5_isofilament and the A々cycloalkyl group are substituted by the same or different groups of the group, which are respectively substituted by I t ^ nitrogen group, said single or multiple, or one or more Milk or sulfur atom, or other; η: or tertiary aliphatic or heteroaliphatic ammonium ion 'such as morpholine = morphine ion, mouth bite ion, mouth ratio is protonated in each case] 4 ^ _ a oyster ^ 1 _ a noisy and ring [2.2.2] octane (DABCO) =, 5 - two-rotating double ring [4 called ten - _7. olefin (DBU), or present him.) ΓίΐΓ Jing ion, For example, in each case, protonation, 15 20 疋 2, 5, methyl hydrazine, 2,6 dimethyl π ratio bite, 5-pyridylpyridinium, pyrrole, imidazole, hydrazine soil 1:3 - dimethyl sulphate sulphate sulphate ": its bismuth, dimethyl fine, represents sulfur ion, or other; represents IS magnesium cation; / or dilute suitable #纽使使(4) can play more quickly and: Further: crop compatibility and/or higher potency than the corresponding WP or sc formulation of the granular (4) active compound, for example, without water dilution. In the formulation according to the invention, even concentrated constituent active compounds , Wang Wang Hehe 6 200922470 Surprisingly, it has been found that any type of formulation can be used immediately after dilution with water due to the extremely high solubility of the active compound in water, and thus it would be expected to be different from the original formulation. The present invention therefore provides a composition comprising at least one solvent and at least one compound of the formula (Ι-A) or (IB) dissolved. Also provided is a process for the preparation of a water-soluble concentrate containing at least one compound of the formula (I-A) or (IB). Furthermore, the invention provides a composition comprising at least one compound of the formula (Ι-A) or (IB) for control Use of harmful vegetation. 10 15 Usually, all compounds of the above formula (Ι-A) or (IB) can be used in the composition of the present invention. It is preferred to use G to represent the equivalent of alkali metal ions and alkaline earth metal ions. A compound of the formula (VII) of an equivalent ion of an ion, aluminum or an equivalent ion of a transition metal. It is also preferred to use its G to represent an ammonium ion, one, two, three or all four hydrogen atoms thereof are selectively selected from hydrogen, Cl~C5_alkyl, Ci~C5_isoalkyl and C3~〇7-ring Substituted by the same or different groups of alkyl groups, which are respectively substituted by fluorine, 2, bromine, cyano, mono- or poly-substituted, or as a compound of formula (IB) with or without oxygen or sulfur. The best is to use the G: chain, nano, potassium, town, about, steel ^ zinc, Ming, ammonium, trimethyl sulfide or triethyl ionic ion formula: compound. σ is also optimally used for the expression of lithium, sodium and potassium by its G. The most preferred one is the formula (Ι_Β) compound which uses its G to represent lithium, sodium and potassium. 20 200922470 The most preferred is the use of compounds of formula (I-A). According to the present invention, the most preferred compound of the formula (Ι-A) listed in Table 1 contains a compound of its own. According to the present invention, the best compound of the formula (I-B) exemplified in Tables 2a and 2b contains a compound of its own. 200922470

Isomer 1 cis cis ) Melting point / °c or NMR data 1___ . Decomposition 3.67 ppm (s, 3H, Ar-O-CH3), 1.37 (s, 3 H, CH3 (C5)) — I. 1 m (S Cs v〇CN 2 -(CH2-)2-CH(OCH3HCH2)2- 1 1 -(CH2-)2-CH(OCH3)-(CH2)2- -(CH2-)2-0-(CH2)2 - K u < -(CH2)3- < u Q w ffi >H < ' « c2h5 !c2h5 i c2h5 c2h5 c2h5 c2h5 i X och3 i och3 〇c2h5 1 och3 1 ____J och3 OCH3 example number < C4 Cn < A.4 : 1 A.5 1 < 9 200922470

ο

1 Isomer 1 1 Melting point / ° C or NMR data * 3.93 (m, 1H, C (5) HN) S 6.92 and 6.97 (d, in each case 1H, Ar-H) ppm *3.95 (m, 1H, C(5)HN), 6.93 and 6.99 (d, in each case lH,Ar-H) *3.96 (m, 1H, C(5)HN), 6.93 and 6.99 (d, in each case 1H, Ar-H ε r—1 ο cd < -(CH2)3- -(CH2)r -(CH2)3- ft ΰ σ och3 och3 och3 c2h5 c2h5 c2h5 Example number s cd m CQ 10 200922470

Isomers 1 1 cis cis 1 1 *1.13 (m, 13⁄4 CH-cycPr), 6.95 and 7.00 (d, in each case 1H, Ar-H) *1.13 (m, 1H, CEr cycPr), 6.93 and 7.00 ( d, in each case 1H, Ar-H) ~ __ j **0.97 and 1.15 (in 1 each case 3H); 3.81 (me, 2H), 6.62 and 6.68 (in each case me, in each case 1H) ** 0.95 (t,3H),3_58 (s,3H), 6.64 and 6.68 (in each case me, in each case 1H) CO 00 ** 0.97 (t,3H),1.05 (s, 6H), 6.65 and 6.69 ( In each case me, in each case 1H) B 1—^ 1—H a Ο +cd z +C^ % +a % +〇3 zu ch3 -(ch2)2-ch(och3)-(ch2)2- -(ch2)2-ch(och3)-(ch2)2- -(CH2)2-0-(CH2)2- mu <d < lt X u Q a XK »' * Ό ΰ □ X Och3 och3 1 OC2H5 i och3 och3 och3 c2h5 c2h5 c2h5 c2h5 c2h5 c2h5 1 example number B.4 B.5 i cd 卜 PQ B.8 On PQ 11 200922470 Isomer cis cis 1 r Melting point / °c or NMR data **0.98 (t, 3H), 1.15 (t, 3H), 3.02, me, 1H), 6.61 and 6.67 (in each case me, in each case 1H) **0.94 (t, 3H), 1.15-1.43 ( m, 4H), 1.62 (m, 2H, 1.88 (me, 2H), 6.65 and 6.67 (in each case m e, in each case 1H) **0.99, (t, 3H, CH2-ch3) 1.05-1.13 (m, 2H, ch2-ch2-o> 1.87-1.95 (m, 2H, CH2-CH2-0) 3.59 ( s, 3H, OCH3) 6.64, 6.68 (2 d, 2H, Ar-H) **1.04 and 1.05 (in i each case s, in each case 3H), 6.64 and 6.68 (in each case me, in each case 1H 3 — H iH PQ -(ch2)2-ch(och3)-(ch2)2- 1 -(CH2)2-CH(OCH3)-(CH2)2- -(CH2)2-〇-(CH2) 2- ch3 γλ 〇Ω κ ΰ » σ X OC2H5 jii 1 och3 1 1 i och3 1 och3 1 c2H5 1 i c2H5 1 1 c2H5 c2h5 Example number B.10 _i 1 B.ll 1 1 _1 Ί B.12 1 B. 13 12 200922470 Isomer 1 cis cis! 1 Melting point / °c or NMR data **0,97 (t,3H),1_16 (t, 3H), 1.66 and 1.89 (in each case me, in each caase 2H), 6.63 and 6.68 (in each case me, in each case 1H) ** 0.96 (t, 3H), 3·15 (mc, 3H), 3.56 (mc, 3H), 4.10 (me, 1H); 6.65 And 6.69 (in caseeach case me, in 1 each case 1H) ____________ —. i 342 ' **0.97 (t, 3H), L05 ; (s,6H), 2.38-2.57 ; (m, 2H), 6.66 and 6.69 (in each case me, in each case 1H) ε t—1 β b —(CH2) 2-CH(OCH3HCH2)2- -(CH2)2-CH(OCH3HCH2)2-i-(CH2)2-o-(CH2)2-X u < ch3 Q ΰ ϋ u X OC2H5 och3 och3 _'_1 Och3 c2h5 1 1 i c2H5 c2h5 j c2h5 example number B.14 ! B.15 jj 1 i B.16 1 1 B.17 s>«飨eddvtt •ep-oSI/Ma^HS 00 inch)DiSM-H** 13 200922470

δ

>-

Isomers • Ϊ 2 (Λ melting point / ° c or NMR data L ^ . ... ** 0.98 and 1.16 (in each case t, in each case 3H), 3.82, me, 2H), 5.70-5.95 (s, br, 1H); 6.67 and 6.71 (in each case me, in each case 1H) mi ·〇fa d! 11^-〇1 ε CN <N 〇c3 -(CH2)2-CHOCH3-(CH2)2- 1 - (CH2)rCHOCHr(CH2)r 1 QEX ϋ I oc2h5 och3 X C2Hs Example No. 00 CQ On CQ 14 200922470 Isomer 1 i Melting point/°c or NMR data**0.98 (ts 3H), 1.11 (s, 6H) , 3.59 (s, 3H); 6.69 and 7.02 (in each case me, in each case 1H) ** 1.01 (t,3 H, CH?CH2), 1.10-1.17 (m, 2H, -CHr\ 1.95-2.07 (m, 2H, | 3.49-3.55 (m, 2H, OCHA 3.60 (s, 3HS OCHi), 3.88-3.90 I (m5 2H, OCH2), 6.69, '6.74 (2d„ 2H, Ar-H) L.. .... . **0.97 (t,3H), 3.58 (s,3H), 6.58 and 6.69 (in each case s, br, in each case 1H) 1 269-270 **3.60 ( s, 3H), 6.70 and 6.72 (in each case s, in each case 1H) ε CN CN e Ο 1 MgBr+ Λ SA Μ r^i X o -(CH2)2-0-(CH2)2- -(CH2 )2-CHOCH3-(CH2)2- -(CH2)2-CHOCH3-(CH2)r X uf»·» X 0 < m X CJ Ρ X Ffi X Ό 0 ΰ X och3 OCH3 1 OCH3' oc2h5 1 och3 c2h5 1 c2h5 c2h5 c2H3 C2H5 Example number B.20 B.21 B.22 B.23 . ! 1 ........1 ! 1 B. 24 ^ fffi :(0tNQ*ZHIAI ooe) iN-H[ i>«#Eaw :(9p-oswaN)Hs00 inch)ΉΡΊΜΉ-ί 15 200922470 In addition, it has been found (see examples A and B) by adding some kind of The surfactant enhances the activity of a composition comprising at least one compound of the formula (I-A) or (I_B). Suitable surfactants are, for example, the sulfates, sulfonates, phosphates and hypophosphites of hydrocarbons which optionally contain olefin oxide monomers. The melon salt, the 4 acid salt, the acid salt and the hypophosphite may be in the form of an acid or a salt. Preferably, the anionic surfactant of the following formula (II): orphan, RQ (Π) wherein Q represents -〇_s〇3M, -so3m, -op〇3hm or _p〇3hM; wherein Μ represents hydrogen or cation, Specifically, it refers to a metal cation such as an alkali metal ion or an alkaline earth metal ion, or an ammonium ion; R represents an unsubstituted or substituted CcC3 selectively linked via an oxyalkylene monomer. a hydrocarbyl group, or R represents an oxyalkylene monomer. The term "oxygenated olefin monomer" means a C2~C1G-alkylene oxide such as ethylene oxide 7, propylene oxide or butylene oxide, and the monomers in the surfactant may be the same or different and may be configured to be randomly mixed or block. Preferred is an R-based Cr^o-alkyl group (e.g., methyl, propyl, butyl) or a C6-CM-aryl group (e.g., phenyl, biphenyl, naphthyl), which is optionally 柘f Or a plurality of groups such as from a Cl~C2〇-alkyl group (eg, a straight or branched chain alkyl group such as a second butyl group or a dodecyl group) which may carry one or more earth groups such as C0 aryl groups a group (e.g., phenyl, biphenyl, naphthyl) and G~Qo-aryl (e.g., phenyl, biphenyl, naphthyl), which may optionally carry 16 200922470 one or more groups such as CcCht alkyl (e.g., decyl, ethyl, propyl, butyl); or 1 R is a WCHACOw group, w is an integer from 1 to 100 and octagonal to an olefinic monomer such as ^0) and 0) 2; 〇 is an ethylene oxide monomer, PO is a propylene oxide monomer, BO is a butylene oxide monomer, X is an integer from 〇 to 100, y is an integer from 〇 to 100, and z is from 〇 to 100 The integer, and the sum of x+y+z is at least! And the oxyalkylene monomer such as (E0)x(I>0)y(B0)z may be randomly mixed or block-configured; and 'R is Η, C〗 to Cw alkyl group (e.g., fluorenyl, ethyl) , propyl, butyl) or a C0-Cm-aryl group (eg phenyl, biphenyl, naphthyl) which may optionally carry one or more groups such as from Ci to C 2 〇-alkyl (eg Linear = branched chain CrQo-alkyl such as t-butyl or dodecyl) which may carry - or a plurality of groups such as C6~C2〇-aryl groups (eg phenyl, biphenyl, naphthyl) And C6~(:2〇-aryl (e.g., phenyl, biphenyl, naphthyl), which may optionally carry one or more groups such as Cr^Qo-alkyl (e.g., fluorenyl, ethyl, Propyldibutyl); or R2 4-0-S03M, _S03M, -〇-P〇3hM, H or -P〇3HM, preferably _p〇3HM, M is H or a cation, especially a metal cation For example, an alkali metal ion or an alkaline earth metal ion or an ammonium ion. The surfactant is preferably an alkyl aryl sulfonate such as a dodecyl sulfonate such as dodecylbenzene sulfonate alkaline earth metal such as dodecyl group Stupid sulfonate mother (eg Phemyisuiph〇 from Clariant) Nat® about 1 〇〇), alkyl aryl polyethylene glycol ether sulfate and alkyl aryl polyethylene glycol ether sulfonate, especially alkyl aryl polyethylene glycol ether sulfate, such as triphenyl Vinyl benzoquinone polydihydrofuran salt, correcting metal or ammonium or triethanolamine ^ 17 200922470 (eg from the Soprophore® series from Rhodia), daidyl ether sulfate and its salts (eg Genapol® from Clariant) LRO), alkyl sulphate and alkyl sulphate (such as the Hostapur® series from Clariant), polyalkylene glycol sulfate, especially metal salts (eg Rhodafac® from Rhodia), alkanes The aryl polyglycol ether sulfate, especially the metal salt type. Usually, the salt is preferably a metal salt such as an alkali metal or alkaline earth metal salt, or an ammonium or trialkylamine salt. Ether sulphates and their salts (for example from Genapol® LRO from Clariam). Other suitable surfactants are, for example, alkoxylated alkanols. The surfactant according to the invention is alkoxylated by formula (ΙΠ) Alkanol:

R2-〇-(-A〇)m-H

Of which: R2 AO

The bismuth and oxidized propylene groups or oxidized alkenyl groups represent a number from 2 to 20. The group of mixed surfactants of the group is the oxylated alcohol of formula (m_a):

R2-〇-(-EO)b_H (Ill-a) wherein: R2 represents a branched alkyl group having 8 to 15 carbon atoms, 18 200922470 E0 represents -CH2-CH2-〇-, and b represents from 4 to 18 Number of. Other suitable surfactants are cationic surfactants derived from the primary fatty alcohol amine. It can be described by the formula (IV) as: R3\^(ch2ch2〇)ph (iv)

(CH2CH2〇)qH wherein: R represents a straight or branched alkyl group having from 14 to 20 hindering atoms and a sum of p and q from 15 to 25. The above surfactants may be a mixture of various compounds within the scope of the formulae (II), (III) and (IV). Specifically, it is the average of m, b, p, and q. The most preferred surfactant is a compound of formula (II). Thus, the present invention also provides a composition comprising at least one surfactant selected from the group consisting of formula (II), (III) and (IV) in addition to at least one of the formula (Ι-A) or (I_B) dissolved compound. . Solvents suitable for use in the compositions of the present invention are all water-miscible solvents which are conventionally used in pesticide formulations and in which the active compounds of formula (Ι-A) and (17) are soluble at the concentration of use. Examples which may be mentioned are water; alcohols such as decyl alcohol, ethanol or isopropanol, 'ethers or polyethers such as 1,4-disulfide, tetrahydrofuran or dioxetane; acid amines such as formamide , acetamidine, dimethyl carbamide, dimethyl acetamide or Hallcomid® (50~60% τΥ, τΥ-dimethyl octanoate and 35%~45% condition #_ dimethyl a mixture of guanamine); sulfoxide/3⁄4 such as 19 2〇〇92247〇曱I hydrazine or sulpholane; and lactone/indoleamine such as i soil 15 than pyridinium and _butyrolactone . The best solvent is water. When the water-soluble concentrate of the present invention contains a compound of the formula (μΒ), the compound of the formula (I-B) is simultaneously produced during the preparation of the composition by reacting the compound of the formula (I_A) with a suitable base. This process produces a composition of a compound of the formula (I_B) which has low separation stability. Appropriate impurities are mainly provided as agricultural machines and inorganic bases. 10 15

Examples of tests are: (4) Metal oxynitrides, such as oxidized clocks, sodium hydroxide and potassium hydroxide, oxidized towns and hydroxides, hydrazine hydroxide, hydrazine or copper oxynitride' (b) metal oxides The substance 'is, for example, oxidized, sodium oxide and oxidized unloaded or alumina, (c) an amine of the general formula 3. Here, R1, ¥ and R3 may be the same or different and represent each hydrogen, Ci~CH^ group, c] decylalkyl group or C3~C7-cycloalkyl group, which are respectively fluorine, chlorine, bromine , Cyanodihydroxy is mono- or polysubstituted, or one or more oxygen or sulfur atoms are inserted. Specific examples are amines, decylamine, dimethylamine, triethylamine, ethylamine, diethylamine, triethylamine, isopropylamine, ethanolamine, diethanolamine, triethanolamine, 2-diethylethanolamine, diisopropylamine, and rings. Hexylamine, dicyclohexylamine, (d) mono-, di- or diamine, such as morpholine, thiomorpholine, piperidine, pyrrole bite, 1, diazabicyclo[2.2.2] octane Feed 1; 5_diazabicyclo 20 20 200922470 [4.3.0] eleven_7, (dBU), (e) diamine 'for example, bis(2-hydroxyethyl)- c8~C18-alkylamine , hexamethylenetetramine, condition #', #'-tetrakis(2-hydroxypropyl)ethylenediamine, 2-diethylamineethylamine, tetraethylethylenediamine, 5 IV Mercaptoethylenediamine, 2-(2-aminoethylamine)ethanol or lysine, (f) aromatic amine, for example, η ratio bite, 2-mercapto bite, 3-mercapto σ ratio Biting, 4-methylpyridine, 2,4-dimethylpyridine, 2,5-lutidine, 2,6-lutidine, 5-ethyl-2-methylpyridine, pyrrole, imidazole, Quinolin, 啥°morpholine, 1,2-dimethylimidazole, 1,3-dimercaptoimidazolium sulfonate 10, • (g) carbonate, such as potassium carbonate, potassium cesium carbonate, Sodium, sodium bicarbonate, magnesium carbonate, calcium carbonate, copper carbonate, zinc carbonate or lithium carbonate, (h) sulfites, such as sodium sulfite, potassium sulfite, lithium sulfite or zinc sulfite, 15 (phosphonium) phosphate Salts, for example, lithium phosphate, potassium phosphate, sodium phosphate, calcium phosphate and magnesium phosphate, lithium hydrogen phosphate, potassium hydrogen phosphate, sodium hydrogen phosphate, calcium hydrogen phosphate' and magnesium hydrogen phosphate or potassium dihydrogen phosphate and sodium dihydrogen phosphate, 0) calcined oxides, such as sodium neodymium and potassium sulphate or sodium ethoxide and potassium ethoxide, 20 (k) ammonium hydroxide, such as trimethyl ammonium hydroxide, triethyl ammonium hydroxide, hydrogen Dipropylammonium oxide or tributylammonium hydroxide, tetraammonium hydroxide, tetraethylammonium hydroxide, tetraethanolamine hydroxide or yttriumtriethylammonium hydroxide; (1) amidines And guanidines, which may be substituted in each instance 21 200922470 such as acetamidine, aminoguanidine, aminoguanidine or arginine, (m) basic formate, preferably acetic acid such as acetic acid Lithium, sodium acetate or potassium acetate, oxalates such as sodium oxalate or potassium oxalate; tartrates such as Sodium sulphate or potassium tartrate; and also includes succinates such as sodium citrate or acid detachment, (η) strong or weak base anion exchangers with hydroxide ions, such as AMBERLITE®, AMBERLYST® , commercially available from DUOLITE 8, EO WEX® or LEWATITE®. Basically, it is also possible to use, for example, a fixed base which removes the carrier material by filtration after preparing the concentrate of the present invention. Depending on the amount of the compound of the formula (Ι-A), it is possible to use 〇·ΐ to 1 〇〇 mole, generally 0.5 to 3 mole equivalents. The alkali auxiliary agent is preferably lithium hydroxide, sodium hydroxide, potassium hydroxide, magnesium hydroxide or calcium hydroxide, and also includes an amine, an alkylamine and a hydroxyoxyalkylamine. The formulations according to the invention further optionally contain antifoaming agents, antioxidants and/or colorants. Suitable antifoams are all materials commonly used in the use of agrochemical compositions. Preferred are polydidecyloxane, eucalyptus oil and magnesium stearate. Suitable antioxidants are all materials commonly used in the use of agrochemical compositions. Preferred is butylhydroxytoluene (2,6-di-t-butylmethylphenol, hydrazine). Suitable colorants are all materials commonly used in the use of agrochemical compositions. Examples which may be mentioned are titanium dioxide, carbon black, oxidized and blue 22 200922470 pigments ' and also include permanent red FRG. Formulated according to the invention containing only the active compound of formula (IA) or (IB) as a herbicidally active compound, the formula (I-A) or (the amount of active compound is usually from (U to 5Q% by weight, preferably It is from 2 to 5 % by weight ratio, more preferably from 1 to 25 % by weight, most preferably from 2 to 2 % by weight. In the formulation according to the invention, the surfactant The content (active shell, if appropriate to adjust the water content) is usually from 5 to the weight ratio and preferably from 1 to 30% by weight. In the ready-to-use formulation (spray), the surface The active agent is from 0.1 to 1 gram per liter, preferably from 〇 3 to 3 gram per liter. The application rate of the surfactant is usually from 2 〇 to i gram of activity. Ingredient/mu, preferably from 100 to 300 grams of active ingredient per acre. In addition to at least one compound of formula (I-A) or (IB), the composition of the invention may further comprise at least one herbicidally active compound, Preferably, it is selected from the group consisting of acetochlor, acifluorfen sodium, aclifen, alachlor, and sub Grass (alloxydim), ametryne, oxazolone, amidochlor, amidosulfuron, chlorpyridinic acid, anilofos, sulphate (asulam) , atrazine, azafenidin, azimsulfuron, beflubutamid, benazolin, benfuresate , benzylsulfuron, bentazone, bencarbazone, benzfendizone, benzobicyclon, 23 200922470 benzofenap, New Yanling (benzoylprop ethyl ester), bialaphos, bifenox, bispout s|(bispyribac), chlorfenapyr, > 8 months bromofenoxim, bromine 'bromoxynil, butachlor, fluoropropion. M. ally (but allyl butafenacil), butyroxydim, butarate, butaline (cafenstrole) , cycloxydim, carbetamide, carfentrazone ethyl ester, methoxy removal Chlomethoxyfen, chloramben, chloridazon, chlorimuron ethyl ester, chlornitrofen, chlorsulfuron, chlortoluron , ketoxime (ethyl cinidon), cinmethylin, ii | cinosulfuron, clefoxydim, clethodim, clodinafop (acetylene) Propyl clodinafop), domazone, clomeprop, dopyralid, fluprsulfuron 15 (flupyrsulfuron methyl ester), chlorsulfuron (cl〇ransulain) Methyl ester), cumyluron, cyanazine, cybutryne, cycloate, cyclosulfamuron, valerian, cycloxydim, cyhalofoprin Cyhalofop), 2,4-D, 2,4-DB, desmedipham, diallate, dicamba, 2,4-dip propionic acid (dichlorprop-P) ), grassy (diclofop oxime ester), diclofenac (diclosulam), acetochlor (diethatyl ethyl ester), grass ° than saliva (dif Enzoquat), diflufenican, diflufenzopyr, dime-furon, dimepiperate, dimethachlor, valerazine 24 200922470 (dimethametryn), Dimethenamid, dimexy- flam, dinitramine, diphenamid, diquat, dithiopyr, diuron, chlorpyrifos (dymron), epropodan, EPTC, esprocarb, ethalfluralin, ethametsulfuron oxime, ethofumesate, ethoxyfen, Ethylsulfuron, acebenbenid, fenoxaprop-p-ethyl, fentrazamide, flaprop isopropyl ester , isopropyl ester _l, methyl ester), flazasulfuron (flazasui_ 10 furon), diflustarx (florasulam), fine 0 than fluoxacillin (fluazif〇PP-butyl ester), isopropyl Grass flu (fluazolate), fluorine g with sulphate (flucarbazone sodium), flufenacet (flufenacet), oxazolidine Aumetsulam, flumiclorac acid, flumioxazin, flumipropyn, oxasulfuron, fluronium 15 (fluulmeturon) Fluorochloridone, fluoroglycofen ethyl ester, fiupoxam, flupropacil, flu azuridine (f]ur-pyrusuifuron vinegar, sodium), Carbofuran (flurenol butyl), flurid〇ne, fluoroacetic acid (butoxypropyl, fluorenyloxypyr), flurprimidol, humulone 20 (flurtam〇ne) ), fluthiaacet methyl, fluthiamide, f〇mesafen, foramsulfuron, giuf0Si_ nate ammonium ), L-solid herbicide (sodium, ammonium), Jia Phosphorus (glyphosate isopropylammonium ion), halosafen, halofose (haloxyfop ethoxylate), -P-A Vinegar), ring 25 200922470 hexazinone, ΗΟΚ-201, imazamethabenz methyl, imazamethapyr, σ米草 定定酸 (imazamox), 曱0糸σ sit niacin (imazapic), mouth rice 0 niacinpy (imazapyr), imi β 噎 噎 ( (imazaquin), p rice grass (imazethapyr), σ sit Mingshi Huanglong 5 (imazosulfuron), mothsulfuron (iodosulfuron, vinegar, sodium), ioxynil, isopropalin, iso-proturon, isouron ), isoxaben, isoxachlortole, isoxaf[ut〇ie), isoxapyrifop, lactofen , lenacil, linuron, MCPA, meperidine, mefenacet, mefenacet, mesosulfuron ), mesotrion, metamifop, metamitron, metazachlor, metabenzthiazuron, metobenzuron, A-metobromuron, metolachlor, metosulam, metaxu-ron, metribuzin, metsulfuron Ester), m〇iinate, monolinuron, napro aniUde, napropamide, neburon, nicosulfuron 2, norflurazon, orben_ carb, orthosulfamuron, oryZaiin 'oxadiargyl, oxadiazon, ring Oxygen σ sulfuron, σ oxazolone, oxyfhiorfen, paraquat, pelarg〇nic, 26 200922470 II Pendimethalin, pendralin, penoxsu-lam, pentoxazone, phenmedipham, picolinafen, oxazolin Pinoxaden), piperophos, pretilachlor, primate primasulfuron 5, profluazol, prometryn, propachlor, Propanil, propaquizafop, propisochlor, propoxycarbazone sodium , propyzamide, prosulfocarb, prosulfuron, pyronate (pyraflufen), pyrasulfotole, ίο Pyrazogyl, pyrazolate, pyr Pyrazolsulfuron (ethyl ester), pyrazoxyfen, pyribenzoxim, pyributicarb, pyridate, pyridatol, cyclic ester test Pyriftalide), Mouth grass i| (pyriminobac 曱酉), pyrimisul-fan,. Sulphuric acid i| (pyrithiobac sodium), pyroxasulfone, pyrothelium 15 amine (pyroxsulam), quinchlorac, chlorhexidine. Quinmerac, quinoclamine, quinoa (quizalofop-P-ethyl, -P-糠 vinegar), rimsulfuron, sethoxy-dim, grass Simazine, simetryn, sulco-trione, sulfentrazone, strontium. Sulmeturon 20 methyl, sulfosate, sulfosulfuron, tebutam, tebuthiuron, tembotrione, tepraloxydim , grass net (terbutryn),. Thenyl-chlor, thifluzamide, thiazopyr, thidiazimin, thifensulfuron, grass dan Thio- 27 200922470 bencarb), ti〇carbazii, toprame-zone, tralkoxydim, trillate, triasulfuron , tribenuron (tribenuron methyl ester), triclopy (triclopyr), trifluralin, trifluralin, trifloxysulfuron, triflusulfuron , tritosulfuron and a group of the following six compounds

28 200922470 The composition according to the invention may also contain a herbicide protectant. Examples of such protectants are benoxacor, cloquintocet mexyl, benzalkon, herbicide, piperidin, ciprofloxacin, cyometrinil, dichloropropene Dichlormid, dicyclonon, dietholate, fenchlorazole, sputum, fenclorim, flurazole, fluxofenim, fluoxetine Furilazole), dibenzoic acid (iS0xaciifen), ethyl benzoxazole, mefenpyr, diethyl oxazide, mephenate, naphthalic anhydride, oxabetrinii. 10 15 2 0 The preferred protectants are diethyl zolyl ester and ethyl bisbenzoxazole. The composition of the present invention is preferably a herbicide containing the following active compounds: -A.3 and Jiashi 粦赛; • B.6 and Jia Can赛; -A.3 and solid grass; -B. 6 and solid killing Grass; -A.3 and L-solid grass; -B.6 and L-solid grass; -A.3 and Jingjin spirulina, -B.6 and fine stalks; Preferred compositions include those containing at least one of the formulas α-Α) or (Ι-Β), σ 唾 唾 禾 和 和 and diethyl sassafras vinegar, and also include at least one species A composition of the compound (Ι_Α) or (Ι_Β) compound ethyl benzoate. The mixture of the present invention and the formulation of the present invention contains at least 29 200922470 compounds of the formula (IA) or (Ι-B) and at least one other active compound and, where appropriate, a protective agent, in the total active compound content. The protective agent is usually from 0.2 to 50% by weight, preferably from 1 to 40% by weight, most preferably from 2 to 30% by weight. 5 When the herbicide-active compound is dissolved in a solvent of the formula (Ι-A) or (Ι-B)-active compound, all of its active compound can be dissolved in the phase. At this point, the concentrate of the present invention is a (e.g., aqueous) soluble concentrate. Accordingly, the composition of the present invention preferably comprises: - at least one dissolved active compound phase of the formula (Ι-A) or (Ι-B) and the selected εο 自由嘉, 杀草, and L-固草Other active compounds that make up the group; - other additives that are selectively taken from the group of antifoaming agents, antioxidants, and/or colorants; and - at least one solvent. 15 Therefore, the composition of the present invention more preferably contains: - at least one selected from the group consisting of A.2, A.3, B.4 and B.6, formula (Ι-A) or (Ι-B) a soluble active compound phase and other active compounds selected from the group consisting of chiaser, geranium and L-solid herb; 20 - selectively taken from antifoaming agents, antioxidants and/or colorants Other additives to the group; and - at least one solvent. Surprisingly, it has been found that if such a composition already contains the two concentrated forms of the compound, the composition is more active than the mixture of the same active 30 200922470 compound prepared by tank mixing in the same application rate. Due to the high water solubility of the active compound, it is not necessary to rely on the original formulation. 'If other herbicidal active 彳b compounds (for example, concentrate grass $) are insoluble in the solvent of formula (Ι-A) or (I-B), then the other active compound may be dissolved in another suitable solvent. The two phases are then mixed to form, for example, a formulation. Accordingly, the composition of the present invention contains: - at least one dissolved active compound phase of the formula (I-A) or (IB); • other phases containing saponin; - selectively taken from an antifoaming agent, Other additives to the group of antioxidants and/or colorants. Therefore, the composition of the present invention more preferably contains: - at least one formula (Ι-A) or (IB) dissolved activity composed of groups of free A.2, A.3, B.4 and B.6 Compound phase; other phases of refined, oxacillin and diethyl zodiazepine or carbazole and ethyl benzoxazole; - selective emulsifier, defoamer Other additives to the group of antioxidants and/or colorants. Suitable emulsifiers are all conventional nonionic, anionic, cationic and zwitterionic compounds which are generally used for the surface treatment of pesticide compositions. The halogenated substances include fatty acids, fatty acid esters, fatty alcohols, fatty amines, and sulphur Or a aryl group with ethylene oxide and / or propylene oxide and / or oxidized butyl sulphate - and also includes its sulfuric acid from the purpose of the reaction, the reaction product of the reaction and the reaction of ethylene oxide and propylene oxide The product, as well as the decyl sulfonate, hydrazine 31 10 15 2 0 200922470 sulfate, aryl sulphate, tetraalkylammonium halide, trialkyl aryl _ sulphur and sulphate. The emulsifier itself or a mixture thereof can be utilized. And preferably using a reaction product of medicinal sesame oil and ethylene oxide to a ratio of: 2 〇 to :: 6 〇 molar ratio, Q 〜C, an alcohol and ethylene oxide in a ratio of 丄·· 5 to i : 5 〇 molar ratio The reaction product of the product, fatty amine and ethylene oxide in i: 2 to oxime: molar ratio, reaction product of oxime phenol with 2 to 3 moles of styrene and 1 to 50 moles of ethylene oxide, C8~Ci2_ The reaction product of the alkyl group and the ethylene oxide in a ratio of 1.5 to 1.30 moles, the thioglycol, the q~c "- phenyl benzoate" (4), monoethanolammonium, diethanolammonium and trisodium. An example of an ionic emulsifier is the conventional trade name arsenic (10) τ 180 ('from the second tributyl phenol ethoxylate of Clariant), Aika_s 〇R36 (= acetoacetate ethoxy from Rhodia _) And the product of this heart TS54 ('from triphenylethyl (tetra) phenyl ethoxy vinegar from Clariant). The formulation of the present invention preferably uses these tristyryl phenyl redoxy oxime (Emulsogen TS540). An example of an agent is a commercial manufacturer of ag, Baykanol SL (= sulfonated phenyl ether) and also includes phosphorylated and/or triphenyl sulphide. Base: Dijon's products are Soprophor FLK and S〇pr〇ph〇r are still taken from Rhodia.) The composition of the invention has (4) effect against the extreme activity of the dicotyledonous harmful plant. Here, it is planted Pre-, pre-emergence or post-emergence use does not matter. By way of example, reference is made to the representative 32 200922470 mono- and dicotyledonous weeds which can be controlled by the compounds of the invention; however, this listing does not mean that it is limited to Certain species. In monocotyledonous weed species, the compound is effective for, for example, self-seeding cereals such as wheat, barley, rye, and triticale, and for example against Apera 5 spica venti, Avena species, Alopecurus species, Brachiaria species, Digitaria species, Lolium species, Echinochloa species, Panicum species, Phalaris species, Poa species, Setaria species; and also Bromus species such as Bromus catharticus, Bromus secalinus, Bromus erectus, Bromus tectorum and Bromus japonicus; and annual plant Cyperus 10 species and perennial Plants Agropyron, Cynodon, Imperata and

Sorghum' also includes the perennial Cyperus species. In the dicotyledonous weed plant species, its range of effects on annual plants can be extended to, for example, Abutilon species, Amaranthus species, Chenopo dium species, Chrysanthemuni species, Galium species, Ipomoea species, 15 Kochia species, Lamium species, Matricaria species. , Pharbitis species, Polygonum species, Sida species, Sinapis species, S〇lanum species, Stellaria species, Veronica species and Viola species; Xanthium species, papaver rh〇eas species, Centaurea species, and c〇nv〇 also including perennial weeds Wulus,

Cirsium, Rumex and Artemisia species. 10 When the composition of the present invention is applied to the surface of the soil before germination, the germination of the weed seeds can be completely prevented, or the growth can be stopped when the seeds are grown to the cotyledon stage and completely died after three to four weeks. If the composition is applied to the green part of the plant after germination, it can also be prevented from growing immediately after the treatment. The plant is still growing during the application, or completely died after ―(四) 33 200922470 and can be removed early and continuously. Competing weeds. The muscle of the blade The herbicidal composition of the present invention has a rapid and long-lasting herbicidal action. The active compound in the composition of the invention has an excellent anti-rinse effect. The use of the compound of the present invention can reduce the number of active compounds to be used by the county. J ^ 禹 application of the composition of the present invention is extremely harmful to the economically harmful mono- and dicotyledonous herbicides against herbicidal active compounds such as cyclamate, chlorpyrifos, oxaloquinone or imipenem herbicides. Herbicide activity. ', Lin Ben invention composition, although economically harmful, _ 雔 雔 丁 丁 又 又 又 又 又 又 又 又 又 又 但是 但是 但是 但是 但是 但是 但是 但是 但是 但是 但是 但是 但是 但是 但是 但是 但是 但是 但是 但是 但是 但是 但是 但是 但是 但是 但是 但是 但是 但是It has excellent growth regulating properties for this crop. It is involved in the regulation of the plant in a regulated manner. This can be used for plant components and for dry regulation of harvesting, for example by arousing dryness and growth retardation. In addition, its (iv) combination regulates and inhibits poor plant growth under the process towel. Inhibition of plant growth plays a major role in many mono- and dicotyledonous crops by reducing or completely avoiding lodging. η By virtue of its ability to weed and regulate plant growth, the compositions of the present invention can also be used to control harmful plants in known genetically modified or genetically modified crops. The transgenic plants typically have particular beneficial properties, e.g., against certain insecticides, which are indicative of certain pathogenic organisms such as certain insects or microorganisms such as fungi, bacteria or diseases other than Hf sinensis diseases or plants. Other special properties are, for example, the quantity, quality, storage stability, composition and specific ingredients of the harvest. Thus, for example, known harvests have transgenic plants that have increased coagulation or improved starch quality or have different fat compositions. Other special properties may be tolerance and resistance to non-biological sources such as heat, cold, drought and ultraviolet light. Compositions of the invention containing compounds of the formula (Ι-A) and (IB) are preferably used in economically important transgenic crops and ornamental plants such as alfalfa such as wheat, barley, rye, oats, millet, rice, cassava and Corn, or beets, cotton, soybeans, canola, potatoes, tomatoes, peas, and other plant crops. The composition of λ, a compound containing the formula (Ι-A) and (Ι-Β) is preferably used as a herbicide in a useful plant preparation which is resistant to or resistant to herbicide phytotoxicity by genetic engineering. Conventional methods of forming novel plants having improved properties compared to known plants include, for example, conventional breeding methods and the production of mutant strains. Alternatively, novel plants with improved properties can be produced by genetic engineering (see, for example, ΕΡ-Α- 0 221 044, ΕΡ-Α-0 131 624). For example, several examples thereof are: - genetic engineering to alter crops to improve starch synthesis of plants (eg, WO 92/11376 'WO 92/14827 'WO 91/19806); - against certain herbicides such as solid grass (eg, ΕΡ 0242236, 242 242246) or GM (WO 92/00377) or sulfonamide (ΕΡ 0257993, US 5013659) for genetically modified crops; - with a resistance to certain plant pests to produce sclerotin toxin (Bt toxin) Transgenic crops such as cotton (EP 0142924, EP 0193259); 35 200922470 - Transgenic crops with improved fatty acid composition (w〇91A3972); _ with novel ingredients or a second substance such as novel phytoalexins to increase disease resistance Genetically modified crops (Ep 309862, EP 0464461); 5 _ genetically modified plants with reduced photorespiration and high yield and high tolerance (EP 0305398); - production of medical music or cherish important proteins (molecules) Transgenic crops on farms; - genetically modified crops that can be distinguished by higher yields or better quality; • transgenic bases that can be distinguished by 10, for example, combinations of novel properties described above (gene stacking) Due to crops. Many molecular biotechnologies are known to produce novel transgenic plants with improved properties as described, for example, in I. Potrykus and G. Spangenberg (eds.), Plant Gene Transfer 'Springer Laboratory Handbook (1995), Springer Verlag Berlin, Heidelberg, or Christou, "Rit # of the side of the school 15 #" 1 (1996) 423 ~ 431). For such genetic engineering operations, nucleic acid molecules can be introduced into a plastid that can produce a mutation or sequence change by the recombinant DNA sequence. Standard methods can be used to remove partial sequences or to add natural or synthetic sequences by, for example, exchanging bases. Interlinking the DNA fragment can link adaptors 2 adaptors or linkers to the fragment, see for example

Sambrook et al. 1989, Molecular Selection, Laboratory Handbook, Second Edition, Cold Spring Harbor Laboratory, Cold Spring Harbor, New York; or Winnacker

[Gene and Clones], VCH Weinheim 2nd Edition, 1996. Plant cells with reduced gene product activity can be prepared by, for example, performing at least one suitable antisense-RNA, sense-RNA 36 200922470 to achieve a co-suppressive effect. 'Or by constructing at least one appropriate construction of a ribozyme that specifically cleaves the transcription of the above gene product. To achieve this goal, the complete coding sequence containing the gene product can be utilized, including any DNA molecule that may have flanking sequences or A DNA molecule containing only a portion of the coding sequence of the length required for the antisense effect in the cell. It is also possible to use a DNA sequence that is highly similar to the coding sequence of the gene product but is not identical. When present in a plant In the numerator, the synthetic protein may be located in any desired compartment of the plant cell. However, for localization in certain compartments, it is necessary to connect to the coding region, for example, in a DNA sequence that ensures localization in certain compartments. It is well known to those skilled in the art (see, for example, Braun et al., Wu Xi 11 (1992), 3219~3227; Wolter et al. ' /Voc. Shi ".Scf·US 85 (1988), 846~850; Sonnewald et al., corpse/train/J. 1 (1991), 95~106). The nucleic acid molecule can also be expressed in stolen goods. Within the organelles of the cells, the transgenic plants can be regenerated into whole plants by known techniques. The transgenic plants can in principle be plants of any desired variety, ie mono- and bi-co-leaf plants. A transgenic plant that overexpresses, suppresses, or inhibits a homologous (native) gene or gene sequence or by expressing a heterologous (foreign) gene or gene sequence. The compounds or compositions of the invention are preferably used to combat growth regulation Substance such as 2,4-D, rickety grass or anti-inhibition main plant fermentation ^ 200922470 = such as lactic acid synthase (ALS), EPSP synthase, glutamate synthetase (1) phantom or arginine pyruvate a herbicide of double oxidase (HPPD); or a herbicide from <"> from a group of continuous urea, chiasapon, chlorpyrifos or benzambeazole and similar active compounds; or against any of the above activities a transgenic crop of any combination of compounds. An example of a crop is, for example, corn or soybean having the trade name 〇ptimumTM gATTM (the resistance of AL S.). The compound or composition of the present invention is preferably used for combating 10 Transgenic crops of grass, L_solid herbicide or Jia Phosin or solid grass or L-solid herbicide and Jia Phosin. ^ When the active compound of the present invention is used in genetically modified crops, in addition to fighting harmful plants In addition to its effects, it can be observed in other crops, which are usually used for the problem of genetically modified crops, such as weeds that can be controlled 15 ^ improved or specifically widened the scope of action, can be used for application The amount of change, preferably, is compatible with the herbicide of the resistant transgenic crop, and can also affect the growth and yield of the transgenic crop. Thus, the compositions provided by the present invention can also be used to control harmful plants of genetically modified crops. 20 The invention also provides for the use of a composition for controlling harmful plants, preferably crops. The herbicidal composition of the present invention can also be used non-selectively to control harmful vegetation, for example, for cropping crops, roadsides, squares, shops or railways. 38 200922470 [Examples] Preparation Examples Preparation of Water-Dispersible Powders The active compound is mixed with an inert material. The powder is ground until an average particle size (d50) of 5 to 10 microns is reached. The following are typical compositions of the WP20 formulation. : A.3 20% by weight

Sipernat® 22S 10% by weight

Baykanol® SL 10% by weight 10

Galoryl® MT 804 4% by weight

Kaolin W 54% by weight Preparation of Suspension Concentrate (SC Formulation) The active compound is stirred in an aqueous solution of a suitable surfactant. The dispersion was ground to a powder using a standard apparatus up to an average particle size of less than 5 microns. The following are typical compositions for the SC150 formulation: ' A.3 150 g/l 1,2-propanediol 52 g/l

Agnique® PG 8105 G 31 g / l 2 0 Arkopon® T 21 g / l

Acticide® MBS 2 g / l

Rhodopol® 23 2 g/L Water 773 g/L 39 200922470 Preparation of a Water-Soluble Tanning Liquid (SL Formulation) The SL formulation was prepared by stirring and dissolving the active compound in water. The solution contains up to 4 g/l of the active compound of the formula (Ι-A) in an amount of up to 1 g/l of the active compound of the formula (I-B). Further, in order to increase the biological activity, a water-soluble surfactant up to 300 g a.i./liter (a.i. = active ingredient) is selectively added. An aqueous solution of the Li, Na and K salts of the active compound can also be prepared by simultaneously stirring the active compound (Ι-A) and an equivalent molar amount of, for example, LiOH, NaOH or KOH or the corresponding carbonate, acetate or phosphate. 10 15 2 0 The following are typical compositions of SL formulations·· B-6 11 g/l

Genapol® LRO solution 764 g / liter (28% strength solution in water)

Rhodorsil® 481 3 g/l water 254 g/l In a similar manner, the B1〇 or B.14, B.18 or B.23 salts of this example of the invention may also be utilized. Preparation of a molybdenum mash containing a plurality of valerian active compounds In addition to at least one compound of the formula (I-A) or (i-b), the composition of the present invention may further comprise a herbicidally active compound or other active compound and a herbicide protectant. These composite preparations are prepared by mixing individual ingredients. It is also possible to use (Ι-A) in place of a mixture of (ι_Β) salts with, for example, sodium hydroxide, sodium carbonate, sodium ruthenium oxide, sodium acetate, sodium oxalate, sodium oxide or sodium phosphate. Alternatively, (IA) can also be used with, for example, potassium hydroxide or lithium hydroxide, potassium carbonate or carbonate 200922470 lithium, potassium ethoxide or lithium ethoxide, sodium bismuth oxide, potassium methoxide or lithium methoxide, potassium acetate or acetic acid , a mixture of potassium or oxalic acid clock, potassium oxide or oxidized clock, or a mixture of stone dance acid clock or acid clock. The EW formulation is prepared using a relatively high shear force sufficient to disperse the organic phase in the aqueous solution. A known device suitable for this purpose is, for example, a toothed colloid mill. The method can also be used to incorporate (Ι-A) or (IB) (or (Ι-A) in combination with the above exemplary auxiliaries) into commercially available products such as Puma Super, Ralon'Ricestar, Whip, Basta/Liberty. , within Rely'Finale or Ignite. The following are examples of such formulations: Exemplary mixture formulations) A.3 Guticide-ammonium Genapol® LRO slurry 1-decyloxy-2-propanol Rhodorsil® defoamer Duasyn Acid Blue AE 02 Water 0.25% (=2.8 g/L) 13.47% (=150 g/L) 58.62% 9.97% 0.25% 0.005% Add to 100% Exemplary mixture 2 (SL formulation) B.6 η ; Solid grass-ammonium Agnique® PG 8105 Tetrahydrofuranol 0.54% (=6.25 g/L) 24·50% (=280 g/L) 9.2% 6.2% 200922470

Break-Thru® S 200 0.6% SAG 1572 0.05% D&C Red 33 0.003%

Agnique® SLES 270 35.15% 5 water added to 100% exemplary mixture 3 (EW formulation) B.6 0.74% (=7·8 g/l) Diethylzolyl ester 7.12% (=75 g/l ) carbazole herbicide 6.55% (= 69 g / liter) Genapol® X-060 15.20% glycerin 9.98% Dispergator® V4133 sodium salt, 20% 9.48% Emulsogen® EL 400 1.00% Mergal® K9N 0.20% sodium hydroxide 0.01% water 14.81% Solvesso® 200 ND added to 100% ίο 15 2 0 In a similar manner, the above exemplary mixtures 2 and 3 may also utilize the corresponding bismuth B.10 or B.14, B in this example of the invention. .18 or B.23 salt. An exemplary mixture 4 Jia Phosin - Isopropylammonium 28.62% 42 200922470 (= 337 g / liter; equivalent to 250 g / liter of Jia Pho赛) B.6 0.29% (= 3.5 g / liter) Sodium hydroxide tablets 3.65% 10.77% added to 100%

Terwet 1250 5 Water Preparation Spray Solution Start using 300 liters/mu of water. The desired amount of the final formulation is then added. The spray liquid obtained in this way is homogenized by stirring. Or one of the ingredients, or "tank mix" of individual ingredients, for example, a mixture of solid herbicide, gamma chlorpyrifos or hydrazine, oxazinoxaline product and (Ι-A) or (IB) active compound can be continuously stirred into The spray liquid was prepared in the WP, SC, SL, EW or WG type. Biological test 15 Abbreviation used G of a.i./ha 1/ha

ALOMY APESV 20 AVEFA

BROER LOLMU SETLU SETVI = active substance / number of grams = l / therefore = Alopecurus myosuroides = Apera spica venti = Avena fatua = Bromus erectus = Lolium multiflorum = Setaria lutescens = Setaria viridis 43 200922470

ECHCG PHACA CYNDA TRZAS HORVS ZEAMD =Echinochloa crus galli =Phalaris canariensis =Cynodon dactylon =Triticum aestivum =Hordeum vulgare =Zea mays A method for determining the activity of a plant. Seeds are planted in a temperature-controlled chamber at a depth of 1 cm and cultured in a temperature # ίο room ( 12 hours of sunshine 'temperature during the day: 18 ° C, evening: 143⁄4) until the growth phase of BBCH 12 to BBCH 13. The plants were treated with a spray solution on an experimental crawler sprayer. The amount of water applied is 300 liters/mu. After treatment, the plants were returned to the temperature controlled chamber. In the outdoor test, the plants to be tested are planted in the field and grown to the desired stage. The spray liquid was applied as a spray bar after germination. At this time, the amount of water applied is 200 liters / 3⁄4 long. Each instance was evaluated for the temperature controlled chamber and field trials based on a scale from 〇 to 1〇〇% after the period: 0〇/〇 has no visual effect compared to untreated plants 2〇!〇〇% has killed all plant

Example A In a temperature controlled chamber test, the sc formulation of the active compound was prepared as described above and used at a dose of 10 g/mu after dilution. After 21 days of application, test 44 200922470 to combat the effects of weeds. The results in Table A clearly show that surfactants such as Genapol® LRO, Genapol® X150 and Genamin® T200NF according to the present invention have excellent activity enhancement.

5 Example B In this temperature control chamber test, sulphuric acid was added from the WP 20 formulation of the active compound A.3, 'prepared liquid,' at an application rate of 500 g/hr. Its effect against weeds was measured after 21 days of application. 5 The results of the flattening are shown in Table B, which clearly shows that the herbicides combined with humectants such as Genapol® LRO, Genapol® XI50 and Genamin® T200NF have excellent results. 45 200922470 J Average 〇〇 〇〇ΟΊ MD 〇〇ΟΊ ! I LOLMU g § BROER 〇tn o AVEFA m 00 〇APESV § in § o ALOMY moo φΐ fs Zhao d 佥o 200 g 200 g 200 g 200 g surfactant Genapol® LRO according to the invention Genapol® X150 according to the invention Genamin® T200NF according to the invention Soprophor® comparison 46 200922470 PQ<1 1 m 〇\ rH r'H SETLU 〇rH 〇〇〇\ r^i On LOLMU 00 00 m On Ό BROER 1______ 冢C\ <N AVEFA wo 00 in APESV 〇〇〇\ § ALOMY § (N o - amount of surfactant [g of ai/ha] 270 g 300 g 300 g 150 g surfactant Genapol® LR0 according to The present invention Genapol® XI50 According to the present invention, Genamin® T200NF according to the present invention Silwet® compares the green squatter ^ / ^ 005 and the genre ^ fat ^ * 趄昶 命 如 & 。 。 。 。 。 。 。 。 。 。 。 。 。 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 In the temperature control chamber test, a spray solution is prepared from the SC formulation of the active compound A.3 or the SL formulation corresponding to the sodium salt (B.6) by a method similar to the preparation example. In addition, 500 g/s of acid is used. Ammonium and 1 liter / gen of Genapol LPO 5 It was added to the spray. The effect against weeds was determined after 17 and 31 days of application. The results in Table C show that it works earlier and the SL formulation has a higher pharmacological effect compared to the SC formulation.

Ίο Example D. In this temperature controlled chamber test, the spray solution was prepared from a WP formulation of the active compound of the formula (Ι-A) or a SL formulation of the corresponding sodium salt of the formula (I-B) in a similar preparation example. Further, 500 g of ammonium sulfate and 1 liter of Genapol LPO solution were added to the spray liquid. 15 The efficacy was measured after 21 days of application. The results in Tables D1 to D3 show that the SL formulation has a faster and better efficacy than the WP formulation. 48 200922470 3<

LOLMU 31DAA i 〇17DAA o 〇\ APESV 31DAA o oo ON 17DAA § in 00 ALOMY 31DAA 17DAA Dose [g of ai/ha] ι/Ί in Formulation Example A.3 SC Example B.6 SL Alkali H<^ SE series = vva

Ia< Average (N oo 00 LOLMU tn 00 00 BROER ro 00 AVEFA σ\ APESV in oo ALOMY in Ό 00 oo dose [g of ai/ha] 20 g 20 g formulation* WP5 example B.4 of example A.2 SL5 00^ PS 02 u—ϋ ^ * 49 200922470 Average 〇\ LOLMU Q\ Q\ σί w ο r/, in G\ PQ AVEFA 00 〇\ 〇\ ο, APESV ό ALOMY m 〇\ dose [g of ai /ha] 10g 10g _ 2 荽<r> Χ/Ί ^7>inch<3 rO < CQ (Η

Average 04 Γ^· LOLMU 00 <N as pci mo rv^ s cn PQ AVEFA § ^Ti oo APESV ALOMY § § 7 =5 H -=r»· cd 敬 o yH o ,丨H _ 荽<7&gt C/j <7> -dv〇τΟ ffil < PQ 苳 (H 50 200922470 Example In this temperature-controlled room test, commercially available QT .u 8 is diluted with water. Liberty® (SL Formulation, Bayer CropScience) Or the spray solution is prepared according to the exemplary mixture [to the final concentration of the table. < The efficacy is determined 10 and 21 days after application. Table E1 shows the SL containing A.3 compared to the pure Liberty® product. The final formulation has a significantly better efficacy. Table E1 Formulation Concentration (g/L) Dose [g of ai/hal AV] EFA 10DAA 21DAA Liberty^ Solid Herbicide 150 135 60 50 SL Finishing Lithium® + A.3 (Exemplary mixture 1, acetochlor A.3 150 2.8 135 2.5 90 97 10 daa = days after application Example E2 This temperature control room test was prepared by diluting the formulation with water to the application amount in Table E2 The following spray solutions: "commercially available Liberty® (SL Formulation, Bayer CropScience) plus WP 2〇% of Α·3 active compound (Barrel mixing method).

- SL 51 containing 140 g/l of oxacillin and 1.4 g of the active compound of A.3 200922470 The final formulation was prepared similarly to the exemplary mixture 1. The efficacy was measured 24 days after administration. Table E2 shows that the SL final formulation is significantly better than the WP tank mix in controlling Avena fatua and self-seeding cereals. Table E2 Formulation Concentration (g/L) Dose [g of ai/ha] HORVS TRZAS AVEFA 24DAA 24DAA 24DAA Barrel Mixing Liberty® Solidicide Ammonium A.3 WP 20 150 20 125 1.25 30 35 25 SL Final Formulation (Similar to the exemplary mixture 1) acetochlor A.3 140 1.4 125 1.25 75 55 70 52 200922470 Example E3 In the field trial, the corresponding formulation (commercial Liberty® and exemplary mixture 2) was diluted with water to the table. The method of E3 describes the preparation of a spray liquid. The spray was sprayed onto AVEFA (oat grass), H〇RVs (barley) and 5 ZEAMD (corn). ZEAMD uses a variety of resistant grasses. Evaluation was performed on a scale of 0 to 100% 42 days after application: 〇% No visible effect compared to untreated plants 100% Killed all plants Table E3 Formulation concentration (g/L) Dose [g of ai/ha ] AVEFA HORVS ZEAMD 42DAA 42DAA 42DAA Liberty® Phytosalin 280 450 73 55 0 SL Final Formulation (Exemplary Mixture 2) Guticide Ammonium 280 450 95 85 93 B.6 6.25 10 DAA = days after application This result is clear It is shown that the B.6 Guticide SL formulation has a higher pharmacological effect than the SL formulation containing only the acesulfame. In addition, the use of Β·6 provides good control of resistant grass to kill grass. This has its benefits in controlling self-seeding corn. 53 200922470 E4 In-step field test towel, H prepared by the method of diluting the concentration of the compound to prepare the spray liquid: th4 - containing 154 g / liter of chlorfenapyr and 2.66 g / liter of B 6 activity The SL final formulation was prepared similar to the exemplary mixture. SL tank mix of commercially available SL 150 g/L of oxalic acid and B.6 active intervening SL formulation. σ 10 Spray the spray solution onto AVEFA (Oat Grass), ECHCG (Herb LOLMU, PHACA, and sage). ° Use 〇 to 33 days after application 100% scale for evaluation: 0〇/〇 has no visual effect compared to untreated plants 100% Killed all plants Table E4 shows that the final formulation has better efficacy in controlling weeds. 15 Table E4 Formulations Concentration dose AVEFA ECHCG LOLMU PHACA SETVI (g/L) [g of ai/hal 33DAA 33DAA 33DAA 33DAA 33DAA tank mix: Liberty® SL 150 acetochlor 150 400 87 50 90 93 50 B.6 compound SL 11.8 11.8 SL final formulation: solid killing grass 154.4 400 96 65 96 98 70 Β·6 compound 4.55 11.8 DAA= days after application 54 200922470

Example F In a temperature controlled chamber test, a commercially available formulation (EW formulation, by dilution to the desired concentration followed by the addition of the amount of the formula (Ι-A) or (IB) active compound (tank mix) Puma®, Bayer CropScience) prepared the spray. 5 The efficacy was evaluated after 33 days of application. As a result, it was found that the spray liquid containing A·3 had a significantly better effect than the spray liquid containing carbazole.

Table F Formulation dose [g of ai/ha] AVEFA BROER Puma® Asarum oxacillin 45 75 30 Puma®+A.3 carbazole herbicide 45 A.3 2 92 83 Puma® Fine ° and so on禾草灵 90 50 Puma®+A.3 carbazole oxacillin 90 A.3 4 94 55 200922470

Example G In a field trial, the spray liquor was prepared from a formulation of a commercial formulation (Roundup Ultra®, Monsanto) or exemplary mixture 4 by dilution with water to the desired concentration (Table G). 5 Evaluate its efficacy on a scale of 0 to 100% 21 days after application: 0% No visible effect compared to untreated plants 100% Killed all plants Table G results show A.3 compared to RoundUp ultra® The formulation is clearly highly effective. 10

Table G Formulation Concentration (g/L) Dosage [g of ai/ha] ALOMY LOLMU CYNDA 21DAA 21DAA 21DAA Roundup Ultra® Jia Phossai 750 75 50 60 Exemplary Mixture 4 Jia Scale Race 250 750 93 90 70 A.3 3.5 10.5 DAA=Number of days after application [Simple description of the diagram] [Explanation of main component symbols] None 56

Claims (1)

200922470 VII. Scope of application: 1. A composition comprising - a phase comprising at least one dissolved active compound of the formula (Ι-A) or (I-B) 10 15 2 0 (IA) (IB) In the formula (Ι-A) or (IB): X represents a decyloxy group or an ethoxy group, W represents a methyl group or an ethyl group, Y represents a gas, and m represents 1, 2 Or 3, η represents 1, 2 or 3, Α represents an alkyl group or a cyclopropyl group, Β represents a fluorenyl group, and D represents hydrogen; or Α, Β and its attached carbon atoms collectively represent a saturated C5~C6 cycloalkyl group, wherein a ring member is optionally substituted by oxygen and is optionally substituted with a thiol, decyloxy or ethoxy group; or 57 200922470 A and D together represent a C3 to C4-alkylene group, and G represents an alkali metal An equivalent ion of an ion or an alkaline earth metal, an equivalent ion of aluminum or an equivalent ion of a transition metal or the like; representing a money ion in which one, two, three or all four germanium atoms 5 are selectively derived from hydrogen, CfCs- The alkyl group, the CfCs-isoalkyl group and the C3~C7- ί sulphide group are substituted by the same or different groups in the group, which are respectively substituted by fluorine, chlorine, bromine, cyano group, hydroxyl group, or one or more Or a plurality of oxygen or sulfur atoms, or others; representing cyclic secondary or tertiary aliphatic or heteroaliphatic ammonium ions, such as 10 morphine ions Sulfur it. Forest ion, σ bottom 11 fixed ion, 11 specific rhodium ion, or in each case protonated 1,4-diazabicyclo [2.2.2] octane (DABCO) or 1,5-diazabicyclo ring [4_3.0] eleven-7-ene (DBU), or others; represents a heterocyclic ammonium cation, for example, in each case protonated pyridine, 2-mercaptopyridine, 3-mercaptopyridine, 4- Pyrithione, 2,4-dimercaptosium σ, 2, 2,5-dimethyl. Specific bite, 2,6-dimercapto 11 ratio bite, 5-ethyl-2-mercapto σ ratio bite, σ ratio ρ, σ m嗤, Ling Lin, 啥°若琳, 1,2-dimethyl Imidazole, 1,3-dimethylimidazolium ion decyl sulfate, or others; 20 represents a sparing ion, or others; represents a magnesium halide cation; - at least one solvent. 2. The composition of claim 1, further comprising at least one surfactant. 58 200922470 3. The composition of claim 2, comprising -50% by weight of the activated substance A of the formula (IV) and/or formula (4), from 5 to 50% by weight of surface active water. 4. The composition according to claim 2 or 3, wherein the agent is selected from the surfactant RQ (Π) 10 15 characterized by the surface active (II) wherein Q represents _〇_so3m, - So λ/Γ 八甘占u , , 〇 3M, -O-PO3HM or -P〇3HM ; /, Μ represents hydrogen or cation, especially: genus or alkaline earth metal ion, or | Substituted or methylated = base ' or r represents oxidized trans- </ RTI>; R2-〇-(-AO)mH (III) 2 0 where: : 〇 two, straight or branched alkyl groups; Or represents a mixture of oxidation: alkene and a butadiene group; and soil or oxybutene group 59 200922470 m represents a number from 2 to 20; and - a fatty alcohol amine of formula (IV): r3, n/(ch2ch2o) Ph I (IV) (0H2CH 2 O)qH 5 wherein: R 3 represents a straight or branched alkyl group having 14 to 20 carbon atoms, and the sum of p and q is from 15 to 25. 5. The composition of claim 3, comprising a surfactant of the formula (H) of claim 4 of claim 10. 6. The composition of any one of claims 1-5 to 5, comprising at least one compound selected from the group consisting of active compounds The group secret of any of the first to sixth patents of the patent range includes at least one active compound selected from the group consisting of fine (iv) grass herb, chia, W herbicide and chlorpyrifos. 8_If the patent application is in the third place? A composition according to any one of the preceding claims, comprising _ = a soluble active compound containing at least one formula (Ι-A) or (IB) and a group selected from the group consisting of chiaser, L-solid herbicide and chlorpyrifos The other active compound phase; 〃 'optionally other additives from the group of defoamers, antioxidants and/or colorants; and, at least one solvent. 9. A composition according to any one of the preceding claims, comprising - a phase comprising at least one dissolved active compound of the formula (Ι-A) or (IB), - comprising at least one other dissolved or particulate type active Other additives of the compound are suitably selected from the group consisting of emulsifiers &gt;month&gt; emulsifier and/or colorant groups. The herbicidal effective amount of the composition of any of items 1 to 9 of the patent scope is applied to the plant and/or its planting area. 11 ·: A table selected from the formula (11), (1 „) and (ΙV) of the scope of the patent application to enhance the activity of at least one of the first or second (I) activities as claimed in claim 1 The activity of the crop protection composition of the compound is 12. The scope of the invention is added to the use of at least 11 items, characterized by at least one surface active species such as the formula (IA) of the patent application scope (IA) 61 200922470 Or (IB) a concentrated formulation of the active compound. 13. As claimed in the scope of claim U, the special agent is added to at least one active compound containing at least one of the W or (IB) active compounds as claimed in the patent application. Ready-to-use formula. Formula (1, 8) 14. A preparation according to the scope of the patent application, containing the formula ^- = 2 (the composition of the compound Si such as GW formula (Ι-A) compound, appropriate The base and the composition of the composition are water-miscible solvent or water. One 10,000 component force σ = chelate, at least one compound selected from the group consisting of Jialuixai, chlorpyrifos and J: j and others The desired ingredients are dissolved in a water miscible solvent or water, and the amine is added to the solution at any time. 6. The composition of the patent application, which is in the form of a water-soluble concentrate, comprising - at least one selected from the group consisting of water, decyl alcohol, ethanol, isopropanol, hydrazine, 4-diazane, tetraruthenium σ Furan, dioxirane, Hallc〇mid® (mixture of 5〇~6〇〇/〇 dimethyloctylamine and 35%~45% Ml dimethyl decylamine), dimethyl sulfoxide, a solvent of the group consisting of cyclosulfone, V-decylpyrrolidinium and ^-butyrolactone; and - dissolved in the above solvent from 0.2 to 50% by weight of at least / of the formula (Ι-A) or IB) active compound; - from 5 to 50% by weight of at least one surfactant selected from the group consisting of (a) a surfactant of formula (II): 62 200922470 RQ (ii) m 3M, aP〇3HMlp〇zen仏 虱 虱 阳离子 阳离子 阳离子 阳离子 阳离子 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别Alcoholic alcohol: R 10 wherein R2_〇-(-A〇)m4i (III) 2 0 R ί is a linear or branched burnt with 4 to 2° carbon atoms °== ί: ethoxylation _ Group, gasification, butanization a mixture such as an emulsified propionyl group or oxygen m represents a number from 2 to 20'; σ, (c) a fatty alcohol amine of formula (IV): and r3\n/(ch2ch2〇)ph (CH2CH2〇)qH (IV) where: 63 200922470 R ^ Table with a straight or branched burn of 14 to 20 carbon atoms, and the sum of η such as bite and q is from 15 to 25. 5 A composition of claim 16 wherein the solvent is water. 8. The composition of claim I, wherein the composition comprises at least one compound selected from the group consisting of active compounds 15 , ch3 B.4 , C2Hs AH5 Α·6 Β·9 19·If the composition of the first application of the patent scope is a water-soluble concentrated type, 64 20 200922470 contains _ to > one selected from water, decyl alcohol, ethanol, isopropanol, 1,4- Dioxane, tetrazofuran, monomethoxyethane, Hallcomid® (50~60% out of dimethyl octylamine and 35%~45% 沁 曱 癸醯 癸醯 的) a solvent comprising a group consisting of a sulphate, a cyclodecane, a decyl pyrrolidone, and a butyrolactone; and _, at least one compound of the formula (I-Α) or (Ι-Β) dissolved in the above solvent ; 10 , the same as the wood; jw gluten in the above solvent consists of at least one active compound consisting of Jia Phosai, Guao Cao and Zhi Gu Cao; the total content of the tongue compound is from 〇.2 to 5 〇% by weight; - from 5 to 503⁄4 by weight of at least one surfactant selected from the group consisting of surfactants of formula (a): (II) RQ wherein Q represents -os〇3M, -s〇3M , 〇_p〇3HM or _p〇3HM; /, Μ represents hydrogen or cation, especially metal cation R such as metal ion or soil metal ion, or recorded ion. Represents selectivity via oxidized olefin monomer Alkoxylated alkanol of formula (III): 65 200922470 R2-0-(-A0)mH (III) wherein Z R2 represents 4 to 20 a linear or branched alkyl group of one carbon atom; AO represents an oxyethylene group, an oxypropylene group, an oxybutylene group or a mixture representing an ethylene oxide and a propylene oxide group or a oxidized butylene group; and m represents a number from 2 to 20; and (4) a fatty alcohol amine of formula (IV): 10 n/(ch2ch2o)ph (CH2CH2〇)qH (IV) wherein: 15 R3 represents a straight or branched alkyl group having 14 to 20 carbon atoms; and the sum of p and q is from 15 to 25. 20. The composition of claim 1, comprising 20 - at least one selected from the group consisting of water, decyl alcohol, ethanol, isopropanol, 1,4-dioxane, tetrahydrofuran, dimethoxyethane, Hallcomid® (50~60%#, #-dimercaptodecylamine and 35%~45% mixture of MiV-didecylguanamine), diterpenoid, sulfolane, decyl pyrrolidone and γ - a solvent of the group consisting of butyrolactone; and - at least one of the formula (Ι-A) or (IB) active compound 66 200922470 dissolved in the above solvent; may be mixed with the above-mentioned glutinous agent and formed into the presence of eucalyptus Other solvents of the separated phase of the herb; the total content of the herbicidal active compound of the formula (Ι-A) or (IB) and the carbazole herb is from 0.2 to 50% by weight; from 5 to 50% by weight At least one surfactant selected from the group consisting of (a) a surfactant of formula (II): (II) RQ 10 wherein QR 15 represents -os〇3M, s〇3M, 〇_P〇3HM or _p〇3 Boots in which money or cations are replaced, special metal cations such as alkali metal ions or alkaline earth metal ions, or ammonium ions; representing selective attachment via oxidized olefin monomers Substituted or substituted Cl~C3 "hydrocarbyl group, or R represents an oxidizing dilute hydrocarbon monomer; (b) alkoxylated alkanol (III) of formula (III) R2-〇-(-AO)mH wherein: R2 ^ a linear or branched ortho-sintered 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 4, 4, 4, 4, 4, 4, 4, 4, 6 20 200922470 A mixture of butadiene groups; and m represents a number from 2 to 20; and (c) a fatty alcohol amine of formula (IV): R3\ /(CH2CH2〇) H 5 V (IV) (CH2CH2〇) qH wherein: R3 represents a straight or branched alkyl group having 14 to 20 carbon atoms; and the sum of ίο p and q is from 15 to 25. 21. The composition of claim 1 comprising - at least one selected from the group consisting of water, decyl alcohol, ethanol, isopropanol, 1,4-dioxane, tetrahydrofuran, dimethoxyethane, Hallcomid® (50) ~60% dimercaptosylamine and 35%~45% dimercaptoamine mixture), 15 dioxins, ring-blocking, iV-mercapto-pyrrolidone and T-butane a solvent of the group of esters; and at least one active compound of the formula (Ι-A) or (Ι-Β) dissolved in the above solvent; - may be mixed with the above solvent and formed in the presence of carbazole and diethyl Other solvents such as 2(A) or (Ι-Β) and 哼 坐 基 草 草 草 或 或 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐 坐The total content of the herbicidal active compound of oxacillin and the protective agent is from 0.2 to 50% by weight; from 5 to 50% by weight of at least one surfactant selected from 68 200922470 (a) formula (II) Surfactant: RQ (II) 10 Q stands for -〇-s〇3M, -S〇3M, _〇_p〇3HM or leg; where M stands for hydrogen or cation, especially metal cations such as gold detectors Or test Metal ion, or R monomer-linked unsubstituted body c~-smoke base' or r represents oxidation bond (b) alkoxylated gas alcohol of formula (III): R2-0-(-AO)mH (III) where: 15 ί, 4 or 2G, linear or branched, A 〇 represents an oxyethylene group, an alkenyl group or a mixture representing an oxidized ethane group/oxidized butylated group And "propyl group or oxygen m represents a number from 2 to 20; and (c) fatty alcohol amine of formula (IV): R ^ N / (CH2CH20) pH (CH2CH20) qH 69 (IV) 20 200922470 R 3 represents a straight or branched alkyl group having 14 to 20 carbon atoms; and the sum of p and q is from 15 to 25. 5 22. The composition of claim 21, wherein the formula (Ι-A) or (IB) The solvent of the active compound is water. 70 200922470 IV. Designation of representative drawings: (1) The representative figure of the case is: (None). (2) A brief description of the symbol of the representative figure : Benefits &lt;, ", 5. If there is a chemical formula in this case, please reveal the chemical formula that best shows the characteristics of the invention: