200920884 九、發明說明： 【發明所屬之技術領域】 本發明係有關一種機能性纖維、其製法及以該纖維製成之織 品，尤指一種採用機能性微粒、熱可塑彈性體(τρΕ)與聚烯類，經 二次混練’及炼融抽絲而製成纖維，並可以該纖維織製成織品， 而具有除臭’或抗菌、防霉，或可產生負離子或遠紅外線之功能， 及增進織品過濾效果及提升空氣品質。 【先前技術】 由於環境污染越來越嚴重’空氣中負離子數越來越少，再者， 一般人每天生活在室内環境中時間幾乎占了百分之八十，在有限 空間内，雜良好空氣品質實耻活之必要，而室_境中絲 人體接近_材例如空氣細、紗聰成，維護人體健康 的很重要原因。顧空氣過_來改善空氣品f，為目前已知最 經濟有效方式之-。含機能性微粒如可產生貞離子⑽織產品， 由於對於人體魏餘大伽，已受_織產f翻際間的重視 和關注。惟因目前傳統紡織技術尚未開發出較佳而可製出可有效 產生負離子的_，因而大雜仍然_貞離子產生器來產生^ 離子。細’負離子產生H會產生臭氧⑽，對人體有害，必需 低於0.12_以下，而且所產生負離子範圍僅在一米以内，且負離 子之時效性也有限。 因鑑於習用無-種具有較佳機能性的纖維及織物的製造技 術’本發明人等乃積極投入研發，且已研發多年，並不斷改良與 200920884 進多年前研發而有—定成果，才於_年提出第 一代的專利 申請’其技術如台灣中請第9312_號專利案，該案目前已獲准 專利）此外’在㈣多次麟驗與改良又有新研發技術產出，乃 申月美國專利11/彻，155號案。近來又有新的技術研發完成， 因而提出本案之申請。 目i S用也有抗菌除臭的織品或纖維技術，例如美國第 U84, 909號專利案’係為抗菌除臭纖維的技術，其主要是在纖維 内添力:銅。剩第6,54{)，號專利案，係為抗麟品的技術，其 主要疋以織ασ製成錄，而織^則包括有熱雛塑賴脂及抗菌 齊1美國第5, 690, 922號專利案’係為除臭纖維的技術，其纖維包 括四價的金屬_鹽和二價的金屬氫氧化物。然而，該等前案技 術均與本發明技術特徵不同。本發明乃本發明人多年研究及製造 經驗的研發成果’錄實驗刻確具實用功效，已#合專利要件， 爰提出專利之申請，以保障研發心血。 本發明係為改善現有環境汙染而針對改善室内空氣品質 IAQ(InderAir_ity)，轉健康，養生舒親境目的進而研 發改善現有纖轉構，崎展出—種長效型多機祕自淨濾網， 2機能性纖維能有效利用環境中風、光、水、熱等自然物理基礎 P a而藉由空氣流動及冷熱差、纖維震動摩擦、光觸媒催化等 原理而激發纖維中多功能機能性微粒本身壓電效應、熱電效應、 光電效應、催化效應、觸媒效應、緩釋效應以達到充分有效殺菌、 200920884 抗菌、防霉、防螨、負離子、遠紅外線、防火、抗靜電、抗電磁 波及排除異味、毛髮、TVOCs、PMx、CO、C〇2、曱醛（HCH0)、臭氧 0、氨氣（NH3)、乙醛（CKHO)、醋酸（CH£00H)等汙染物等符 合健康自動淨化空氣功效。 【發明内容】 目的’在於提供—種可製成具較佳機能性纖維 的方法。其方法特徵，係採用多功能機能性微粒、熱可塑彈性體 (TPE)與料類(poly〇lefme)以較佳的比例混煉及抽絲製成纖維， 藉由熱可塑彈性體的彈性作用’而使其機能性微粒得以發揮最佳 的效果。本發财法所製纖維含有5〜多雜機能性微粒 (如電氣石、奈米金屬粒子、光觸媒、酵素、微膠囊等微粒）， 以該纖維織製成網體，並組成機能性纖維，可使室内空氣品質 『IAQ』，藉由空氣流動及冷熱電、纖維震動摩擦等原理而激發多 功能機能性微粒本練電效應、_效應、催化效應、光電效應、 催化_、觸媒效應、緩釋效應、氣味中和以達到充分有效殺^、 抗菌、防霉、_、負離子、遠紅外線、防火、抗靜電、抗電磁 波及排除異味、毛髮、TTOs、PMxf汗染物等健康自動淨化空氣 功效。 «，明之弟-，，任於域一種可製成經濟效 產生負離子之纖维的方法。其方法特徵，係所採用 為次微米電氣石’藉由熱可塑彈性體的彈性作用，使纖二 200920884 的織品在U流動時產生較 有效率地產生負離子。 _ ’進而讓次微米電氣石得以 本發明之第三目的，在於提供 的方法。其方法特徵 了 之纖維 為酵素。 ’、斤知用的機能性微粒可為奈米銀，亦可 本發明之第四目的，在於描 ^ 财敎魅義芳香之纖 ㈣Γ ’細細㈣紐微粒為娜囊，且於 、Λ夕内匕覆有植物萃取精油，藉由熱可塑彈性體適當的阻擒精 油的釋放，故可達到使纖維芳香持久的目的。 述健康養生巾求，藉由空氣軸及冷熱電、纖維震動摩 擦等原理或統物響，崎多舰觀性錄纖雑產生各類 功效而形成長效射水洗機紐難養生自淨滤網。 【實施方式】 本發明主要是針對具有機紐之纖維做研發與試驗。其基本 特徵的技術，縣發__由包括有輯類(polyolefine)、熱可 塑彈性體⑽）、多功賴能性微粒為紐混練製成機能性纖維， 藉由空氣流動及冷熱電、纖維震動摩擦、陽光照射等原理，而強 化激發多功能機能性微粒本身壓電效應、熱電效應、光催化效應、 觸媒效應、緩釋效應等以達到充分有效殺菌、抗菌、防霉、防虫茜、 負離子、遠紅外線、防火、抗靜電、抗電磁波及排除異味、毛髮、 TVOCs、PMx等汙染物等健康自動淨化空氣功效。利用其纖維織成 200920884 慮材3D、、。構、蜂巢式等並能降低風阻、提高承载能力、提高過滤 效此去除化粉、塵埃，而達成長效型可水洗耐酸、驗等環境需 求及％保郎能等功效者。 為便於審查員了解本發明的可行性，鱗具體實施例詳細說明 如后。 A. 本發明的基本技術特徵 本么明主要疋針對具有機能性之纖維做研發與試驗。其基本 特徵的技術，縣發__由包財機級微粒、熱可塑彈性 體與聚烯騎舰製造域’躺使齡具有特殊的機能性，並 可供織造成織品等。其中’該織品可以是空氣過_，或鞋塾， 或帽子，或紗窗，或窗簾，或電視護目罩。 B. 關於本發明的纖維 本發明之_，主要為包括難性微粒(該機能性微粒可為次 微米電氣錄子’娜囊包物萃取精油，奈米絲子，或酵 素）、熱可娜㈣(TPE)與輯類(p〇iyGieflne)⑽σ聚丙烯或聚乙 烯）共混而成之纖維，藉由熱可塑彈性體的添加，而使本發明之纖 維具有較佳縛性與摩擦特性’進哺所添加的機能性微粒產生 較佳的效能。 本發明第-種具體實關，航性微粒採峰徑為丨微米至 100奈米之範圍内的電氣石，所製成之纖維線徑為G.Qlmm〜3mm。 其中’電氣石粒子含量佔整個纖維的HG%4量百分比的範圍 200920884 内，電氣石之遠紅外輻射率：〇. 948μη](3.48*1〇2w/m2)，粒徑分佈： D50(平均粒徑493咖），經實驗發現電氣石粒子佔整個纖維的3%重 里百分比的經濟效益最佳。藉以使過其纖維所織成的網體具有產 生負離子、遠紅外線、自淨、除臭、抗靜電、防電磁波等功效。 並可加入奈米竹炭、氧化鋅、氧化銅、氧化鐵、氧化矽、氧化鎢、 氧化錳、氧化鈷、氧化錄等一種或多種微粒自淨因子。 本發明第二種具體實施例，機能性微粒採用奈米銀粒子，藉 以產生抗菌、防霉功能，其所添加的奈米銀佔整個纖維的1 重量百分比。藉以使其纖維所織成的網體具有殺菌、抗菌、防霉、 防螨等健康功能。且可加入甲殼素、酵素或奈米貴金屬銅、辞、 金、翻、la、銳等一種或多種微粒殺菌、抗菌、防霉因子。 本發明製造機能性人造纖維的方法，主要是準備複數個第一 ♦稀類(polyolefine)碎片作為基材’其第一聚稀類佔整體重量之 %〜95%重量百分比，其可以是分子量為3,i5xl〇5g/m〇le的聚丙 烯，或是分子量為1.5〜2·5χ105g/mole的聚乙烯碎片（其中，本發 明以下各項試驗係以聚丙烯佔80%重量百分比為具體實施例做說 明）和佔整體重量之5%〜30%重量百分比的機能性微粒（本段以 次微米電氣石粒子為例做說明），及佔整體重量之丨〜仙％的熱可 塑彈性體(TPE或EPDM) ’以雙螺桿混練造粒而製成複數個母粒，再 取該複數個母粒及額外且相同於第一聚烯類的第二聚烯類，將該 200920884 複數_粒與該第二聚稀類混練而成—合成材料，使電氣石的最 終含1為佔該合成材料之H0%的重量百分比，再使該合成材料 經抽絲、冷卻、酸伸、加航型製錢^射，抽絲溫度為 靴〜獄的範圍内（本發明具體操作之實施例中抽絲溫度聚丙 蝉200°C舊C增溫’聚乙烯25(rc~3G(rc)，牵伸倍率3〜8倍（本 發明具體操作之實施例中牵伸倍率為6倍），熱延伸溫度13〇〜⑽ °C (本發明具體操作之實施例中係以⑽。c熱水延伸），加熱定型 溫度為70°C〜10(TC。 上述炼融抽絲是將該合成材料加熱溶融，溶融從喷絲孔擠出 進入空氣，在空氣中冷卻的同時，以一定速度捲曲，在該階段合 成材料熔體細化的同時凝固，即形成纖維，再進行熱拉伸，以提 高纖維的力學等性能。熔融抽絲工程，是將在聚合工序製得的具 有可紡性的聚合物在其熔點以上的溫度從噴絲板細孔擠出，冷卻 細化成絲狀固體，同時進行卷繞。 C·本發明機能性微粒的實施例 本發明為了能讓纖維產生負離子’其所採用的機能性微粒為 次微米電氣石粒子。本發明為了能產生抗菌及防霉效果，其所採 用的機能性微粒為奈米銀粒子，而如后面所示的試驗結果顯示本 發明亦具有較佳的抗菌及防霉效果。再者，本發明為了能產生其 他機能效果’在纖維中混練添加的機能性微粒為微膠囊(在本發明 實驗例中是含有微膠囊丨％重量百分比），且在微膠囊内包覆機能 11 200920884 性材料，其中該微膠囊的材料可為$殼素，而該機能性材料可為 植物萃取精油，藉以使本發明具有產生芳香的效果，而如后所示 的試驗結果顯示本發明具有使芳香持久的效果。此外，本發明所 採用的機能性微粒亦可為酵素，其對人體都有一定的幫助。 D.本發明之實驗例 本發明之實驗例，係以分子量為3. i5xl〇5g/m〇ie的聚丙稀做 為基材，先取聚丙烯佔20%重量百分比，與以下的材料：（1)機能 性微粒為防火材料且佔15%重量百分比，⑵機紐絲為次微米 電氣石佔1_量百分比’⑶魏性微粒為抗齡紐料且佔整 體重量之⑽。⑷機祕錄為除臭㈣（氣體絲)且佔⑽重量 百分比，（5)機能性微粒為抗靜電抗電磁波材料且佔重量百分 比；及⑹熱可娜性體(TP_35%重量百姐，將上述材料以雙 螺桿混練造粒崎賴數個母粒。再取織數_粒娜及額外的 聚丙稀6G%，再將雜與魏較丙烯錄成—合成材料，使該機 能性母粒的最終含量為健體重量之32%的重量百分比。再將該 合成材料經抽絲、冷卻、熱延伸、加熱定型製成纖維。其中，抽 絲溫度為24G°C範圍内，牽伸倍率5_6倍，熱延伸溫度丨⑽。c，加熱 定型溫度為85°C。 ^ 為了做具體的實驗，本發明再取上述的纖維紡織成織品，即 以複數條H向延伸的纖維及機條呈緯向延伸的纖維編織成織 品，其樣本尺寸為肌6mm * 2G3 2mm(4in * 8in)，經向纖維的 12 200920884 單位長度77佈數量為每射鄕，㈣向纖軸單位長度分佈數 量為每英吋34條。 a.本發明之機械性試驗 本發明上述樣本之各項機械性試驗結果如下。 (1)抗拉強度 表1 (kgf/cm2) 由實驗結果表1得知，隨著電氣石含量越多，其抗拉強度將逐 漸下降，但仍保有要求的強度，因而本發明所添加的電氣石粒子 佔整體重量的1〜5%為較佳。 (2)抗張強度: ^2(kgf/cm2) —· ;. 1 未添加織物 電氣石含量1 % 電氣石含量2% 電氣石含量3¾ 電氣石含量4% 電氣石含量5% 2 —一" __3 21.8¾¾ 23.725 23.728 19.174 22.765 21.129 21.345 22.349 22.706 20.609 22.086 20.308 26.816 24.627 21.764 22.047 91 01 117 4 一· _ —5 21.314 18.032 21.796 19.449 21.625 20.598 22.108 24.499 22.229 23.603 21.855 21 717 十巧fd _ 23.1698 22.012 21.9366 21.7586 21.5762 21.1652 由表2得知，本發明織品的抗張強度也隨著電氣石含量增加而 減少’在電氣石含量1%時經向抗張強度下降約5%，在電氣石含 量5%時經向抗張強度下降約8.6%，但仍然保持相當高的抗張強 度。因此電氣石添加1-5%之範圍内，並不影響抗張強度。 (3)水洗牢度試驗（測試時條件：濕度58%，溫度29。〇 : 13 200920884 表3 (I〇n/cc) 負離子添加量 測試刖 測試五次後平均値 备雜名减小骨西分卜卜 1% 265 263 99¾ 2% 350 343 98% 3% 383 365 95¾ 4% 435 416 96% 5¾ 489 461 94¾ 如表3 ’測試前後仍維持良好的堅牢度，負離子的產生量並 未因水洗而減少。 b.本發明負離子釋放分析 (1)負離子靜態釋放情能分析： 靜態模式負離子釋放性能分析’環境條件：濕度58%，溫度 28°0 表 4-l(Ion/cc) 電氣石添加暈 —層濾網 二層減網 三層麵 四層概網 五層濾網 1% 265 412 532 620 712 2% 350 523 652 734 825 3% 412 589 756 834 985 4% 465 652 852 935 1080 5% 489 712 867 973 1115 由表4-1分析可以得知電氣石添加量跟層數都為顯著影響因 子’但層數是其主要影響因子。次微米電氣石聚丙烯過濾材在一 層下其不同含量下負離子釋放265-489個Ion/cc。在含量1%次微 米電氣石聚丙烯過渡材離子釋放265-712個Ion/cc。兩者間相差了 223個I〇n/cc，在相同體積含有電氣石數下；層數的增加較有效於 添加率的增加在負離子釋放量上。 (2)負離子動態釋放情能分析： 動態模式負離子釋放性能分析，環境條件：濕度64%，溫度 29°C。 200920884 表 4-2 (%) 電氣石添加量 ------ m im 3層 4層 5層 1% ----- 2213 2732 2956 2% "------- 3012 3325 3456 η ------- J iii56 3919 3512 3759 3956 4% -----— 1956 3S19 3725 3856 4120 5% _-------- 3901 3921 4220 -—L— _ 由上表4-2中可看出在動態負離子釋放量上來說電氣石添加 量及過濾、層數都是重要因素’但職層數為主要重要因素。 b.本發明除臭及抗菌效能試驗 本發明纖維所編織成的織品的除臭及抗菌效能試驗，結果如 下。表4是分別以本發明織品，依JEM 1467測試法對於測量氨氣 (腸）及乙酸（CMO)之濃度，再測試醋g复（CH3C〇〇H)之濃度 的消除效旎而得之結果。由表4發現本發明織品具有較佳的除臭 效能。 表4 項目Item 起始濃度The beginning concentration 氨氣NH3 24.00PPM 乙醛CH3CH0 8.00PBI 醋酸 CH3C00H 0.20ΡΒΪ 30分鐘後濃度The concentration after 30minutes 4.00PPM 1.00PPM 0.04PPM the removing rate of multi pollution 各污染成分去除率 84.33% 87.50¾ 80.00¾ 總去除率Total Removing Rate 84.58¾ C.實驗例三 本發明纖維所編織成的織品的抗菌效能試驗結果如下。 表5 測試菌種 0 Initial Inoculation(CFU/ml) 0小時接菌量 Contaxt Time作用 1 小時（lhr later} Redruction抗菌效果(兔） 1 小時(lhr later〉 金黃色葡萄球菌 1.0 X 105 3.0 x 10* 94.8(%) 大腸桿菌 2.1 X 1〇5 1.6 x 10J 99.2(%) 肺炎桿菌 7.3 X 105 3.0 x 10* 95.8(%) 15 200920884200920884 IX. Description of the Invention: [Technical Field] The present invention relates to a functional fiber, a method for producing the same, and a fabric made of the fiber, in particular, a functional particle, a thermoplastic elastomer (τρΕ) and a polymer The olefins are made into fibers by secondary mixing and smelting and spinning, and the fibers can be woven into fabrics, and have the functions of deodorizing or antibacterial, anti-mildew, or generating negative ions or far infrared rays, and enhancing Fabric filtration and improved air quality. [Prior Art] Due to the increasing environmental pollution, 'the number of negative ions in the air is getting less and less. In addition, the average person lives in the indoor environment for almost 80% of the time. In a limited space, the good air quality is good. It is necessary to live a shame, and the human body in the room _ is close to the _ material such as air fine, yarn Congcheng, and it is an important reason to maintain human health. Taking air over _ to improve air quality f is the most cost-effective way to know. Including functional particles, such as ytterbium ion (10) woven products, due to the human body Wei Yu Dajia, has been the attention and attention of the _ weaving f. However, because the conventional textile technology has not been developed yet, it is possible to produce a _ which can effectively generate negative ions, and thus a large amount of _ 贞 ion generator is used to generate the ION. The fine 'negative ion' produces H (10), which is harmful to the human body, must be below 0.12_, and the negative ion range is only within one meter, and the time-dependent nature of the negative ion is also limited. The present inventors have actively invested in research and development, and have been researching and developing for many years, and have continuously improved and developed with 200920884 many years ago, and have achieved certain results, in view of the conventional technology of manufacturing fibers and fabrics with better functionality. _Year proposed the first generation of patent application 'its technology such as Taiwan's request for patent No. 9312_, the case has been granted patents. In addition, 'in (four) multiple inspections and improvements and new research and development technology output, is Shen U.S. Patent 11/T, 155. Recently, new technology research and development has been completed, and the application for this case has been filed. The fabric or fiber technology which also has antibacterial deodorization, for example, U.S. Patent No. U84,909, is a technique for antibacterial deodorant fiber, which mainly adds force to the fiber: copper. The remaining patents No. 6, 54{), is a technology against lining products, which is mainly made of woven ασ, while woven ^ includes hot aging plastic lyophilized and antibacterial qi 1 US 5, 690 The '922 patent' is a technique for deodorizing fibers, and the fibers thereof include a tetravalent metal salt and a divalent metal hydroxide. However, these prior art techniques are different from the technical features of the present invention. The invention is the research and development result of the inventor's many years of research and manufacturing experience. The recording experiment has practical effects, and has been patented and patented to protect the research and development. The invention aims to improve the indoor air quality IAQ (InderAir_ity), to improve the indoor air quality, to improve the existing fiber structure, and to develop a long-lasting multi-machine secret self-cleaning filter. 2 Functional fibers can effectively utilize the natural physical basis P a of ambient wind, light, water, heat, etc., and stimulate the multi-functional functional particles themselves in the fiber by the principles of air flow, cold and heat difference, fiber vibration friction, photocatalytic catalysis. Effect, thermoelectric effect, photoelectric effect, catalytic effect, catalytic effect, sustained release effect to achieve full and effective sterilization, 200920884 antibacterial, anti-mildew, anti-mite, negative ion, far infrared, fire, anti-static, anti-electromagnetic wave and eliminate odor, hair , TVOCs, PMx, CO, C 〇 2, furfural (HCH0), ozone 0, ammonia (NH3), acetaldehyde (CKHO), acetic acid (CH £ 00H) and other pollutants in line with healthy automatic air purification. SUMMARY OF THE INVENTION The object is to provide a method for producing fibers having better functional properties. The method features a multi-functional functional particle, a thermoplastic elastomer (TPE) and a material (poly〇lefme) which are kneaded and drawn in a preferred ratio to form a fiber by the elastic action of the thermoplastic elastomer. 'Also make the functional particles to achieve the best results. The fiber produced by the present invention contains 5 to many functional particles (such as tourmaline, nano metal particles, photocatalyst, enzyme, microcapsules, etc.), and the fiber is woven into a mesh body and composed of functional fibers. The indoor air quality "IAQ" can be used to stimulate the multi-functional functional micro-practice effect, _effect, catalytic effect, photoelectric effect, catalysis, catalytic effect, etc. by the principles of air flow, cold and heat, fiber vibration friction and the like. Slow release effect, odor neutralization to achieve full effective killing, antibacterial, anti-mildew, _, negative ion, far infrared, fire, anti-static, anti-electromagnetic wave and eliminate odor, hair, TTOs, PMxf sweat stains, etc. . «, Ming's brother-,, is a method of making fibers that can produce economical negative ions. The method is characterized in that it is a sub-micron tourmaline' by the elastic action of the thermoplastic elastomer, so that the fabric of the fiber of 200920884 produces a more efficient generation of negative ions when U flows. _ 'In turn, the sub-micron tourmaline is the third object of the present invention, and the method is provided. The fiber characterized by the method is an enzyme. 'The functional particles used in the jinzhi can be nano silver, or the fourth purpose of the invention is to describe the scent of the scent of the scent of the scent of the scent of the scent of the scent of the scent of the scent of the scent of the scent. The inner raft is covered with plant extract essential oil, and the release of the essential oil by the thermoplastic elastomer can achieve the purpose of making the fiber fragrant lasting. In the case of healthy health towel, the principle of air shaft and cold and heat electricity, fiber vibration and friction, etc., and the sound effects of the singularity of the ship, the formation of long-acting water washing machine, the self-cleaning filter. [Embodiment] The present invention mainly aims at research and development and testing of fibers having a machine. The basic characteristics of the technology, the county __ consists of a series of (polyolefine), thermoplastic elastomer (10), multi-functional energy particles for the New Zealand mixed into functional fibers, by air flow and cold and heat, fiber Vibrating friction, sunlight and other principles, and strengthening the multi-functional functional particles themselves piezoelectric effect, thermoelectric effect, photocatalytic effect, catalytic effect, slow release effect, etc. to achieve full and effective sterilization, antibacterial, anti-mildew, anti-insect, Negative ions, far infrared rays, fireproofing, antistatic, anti-electromagnetic waves and the elimination of odor, hair, TVOCs, PMx and other pollutants and other healthy automatic air purification. Using its fiber woven into 200920884, considering 3D, and. Structure, honeycomb type, etc. can reduce wind resistance, improve load carrying capacity, improve filtration efficiency, remove powder and dust, and achieve long-acting water-washable acid resistance, environmental requirements such as inspection and % lang. To facilitate the examiner's understanding of the feasibility of the present invention, the specific embodiment of the scale is described in detail below. A. Basic technical features of the present invention It is mainly developed and tested for functional fibers. The basic characteristics of the technology, the county issued __ by the package of machine-scale particles, thermoplastic elastomer and polyene riding ship manufacturing domain lie to have a special degree of functionality, and can be woven into fabrics. Where the fabric can be air _, or shoe lasts, or hats, or screens, or curtains, or TV visors. B. Regarding the fiber of the present invention, the invention mainly includes difficult particles (the functional microparticles can be submicron electrical recordings, 'na bagging extract essential oil, nanospin, or enzyme), hot kina (4) Fibers blended with (TPE) and (p〇iyGieflne) (10) sigma polypropylene or polyethylene), the fibers of the present invention have better binding and friction characteristics by the addition of a thermoplastic elastomer. The addition of functional particles to the skin produces better performance. According to the first specific embodiment of the present invention, the aeronautical particles adopt a tourmaline having a peak diameter ranging from 丨micron to 100 nm, and the fiber diameter is G.Qlmm~3mm. Where 'the content of tourmaline particles accounts for the percentage of HG%4 of the whole fiber in 200920884, the far infrared radiance of tourmaline: 948. 948μη] (3.48*1〇2w/m2), particle size distribution: D50 (average grain Path 493 café), it has been found through experiments that tourmaline particles account for 3% of the total fiber yield of the best economic benefits. Therefore, the mesh body woven by the fiber has the effects of generating negative ions, far infrared rays, self-cleaning, deodorizing, antistatic, anti-electromagnetic waves and the like. One or more microparticle self-cleaning factors such as nano-charcoal, zinc oxide, copper oxide, iron oxide, cerium oxide, tungsten oxide, manganese oxide, cobalt oxide, and oxidation can be added. In a second embodiment of the present invention, the functional particles are made of nano silver particles to produce an antibacterial and antifungal function, and the added nano silver accounts for 1% by weight of the entire fiber. The mesh body woven by the fiber has the health functions of sterilization, antibacterial, anti-mildew, anti-mite and the like. And can add chitin, enzyme or nano precious metal copper, rhetoric, gold, turn, la, sharp and other micro-organisms, antibacterial, anti-mold factors. The method for producing functional rayon according to the present invention mainly comprises preparing a plurality of first ♦ polyolefine fragments as a substrate, wherein the first polycondensate accounts for % to 95% by weight of the total weight, which may be a molecular weight of 3, i5xl〇5g/m〇le of polypropylene, or a polyethylene fragment having a molecular weight of 1.5~2·5χ105g/mole (wherein the following test of the invention is based on 80% by weight of polypropylene as a specific example) Illustrative) and functional particles 5% to 30% by weight of the total weight (this section uses sub-micron tourmaline particles as an example), and the total weight of 热 ~ %% of the thermoplastic elastomer (TPE Or EPDM) 'making a plurality of master batches by twin-screw mixing and granulating, and taking the plurality of master batches and the second polyenes additionally and identical to the first polyolefins, the 200920884 plural number and the The second polythene is mixed into a synthetic material, so that the final content 1 of the tourmaline is the weight percentage of H0% of the synthetic material, and then the synthetic material is subjected to spinning, cooling, acid stretching, and navigation. ^ shot, spinning temperature for the boots ~ prison range (this In the embodiment of the specific operation, the spinning temperature of polypropylene 200 ° C old C warming 'polyethylene 25 (rc ~ 3G (rc), draw ratio of 3 to 8 times (the draw ratio in the specific operation example of the present invention) 6 times), the heat extension temperature is 13 〇 ~ (10) ° C (in the specific operation example of the present invention, (10). c hot water extension), the heat setting temperature is 70 ° C ~ 10 (TC. The above smelting and spinning The synthetic material is heated and melted, and the melt is extruded from the spinning hole into the air, and is cooled in the air while being curled at a certain speed. At this stage, the melt of the synthetic material is refined while solidifying, that is, the fiber is formed, and then the heat is formed. Stretching to improve the mechanical properties of the fiber. The melt spinning process is to extrude the spinnable polymer from the spinneret at a temperature above the melting point of the polymer obtained in the polymerization process, and cool it into a wire. The solid is simultaneously wound. C. Examples of Functional Microparticles of the Invention The present invention is useful for producing negative ions in fibers. The functional microparticles used are submicron tourmaline particles. The present invention is capable of producing antibacterial and antifungal agents. Effect, the machine it uses The fine particles are nano silver particles, and the test results shown later show that the present invention also has a better antibacterial and antifungal effect. Furthermore, the present invention is capable of producing other functional effects in the function of mixing in the fiber. The microparticles are microcapsules (in the experimental example of the present invention, containing microcapsules 丨% by weight), and the microcapsules are coated with the functional material 11 200920884, wherein the microcapsule material may be $chitin, and the function is The material may be a plant extracting essential oil, whereby the present invention has an effect of producing aroma, and the test results shown later show that the present invention has an effect of imparting a long-lasting fragrance. Further, the functional microparticles used in the present invention may also be an enzyme. It has certain help to the human body. D. Experimental Example of the Invention The experimental example of the present invention is based on polypropylene having a molecular weight of 3. i5xl 〇 5g/m〇ie as a substrate, first taking 20% by weight of polypropylene, and the following materials: (1) Functional particles are fireproof materials and account for 15% by weight, (2) machine wires are sub-micron tourmaline accounts for 1% by volume '(3) Wei particles are resistant to ageing materials and account for the overall weight (10). (4) The secret is recorded as deodorant (4) (gas filament) and accounts for (10) weight percent, (5) functional particles are antistatic anti-electromagnetic materials and account for weight; and (6) thermonic body (TP_35% weight, sister, The above materials are granulated by twin-screw mixing and weaving several masterbatch. Then we take the weaving number _ granules and the extra polypropylene 6G%, and then record the propylene and propylene into a synthetic material to make the functional masterbatch The final content is 32% by weight of the weight of the body. The synthetic material is then subjected to spinning, cooling, heat extension, and heat setting to form a fiber, wherein the spinning temperature is in the range of 24 G ° C, and the drafting ratio is 5-6 times. , heat extension temperature 丨 (10). c, heat setting temperature is 85 ° C. ^ For specific experiments, the present invention takes the above-mentioned fiber woven into a fabric, that is, a plurality of H-extending fibers and a strip in the weft direction The stretched fiber is woven into a fabric with a sample size of 6mm * 2G3 2mm (4in * 8in), 12 of the warp fiber 200920884, a length of 77 cloth per shot, and (4) a distribution per unit length of the fiber axis per inch. 34. a. Mechanical test of the invention. The mechanical test results of the samples are as follows: (1) Tensile strength Table 1 (kgf/cm2) From the experimental results, Table 1 shows that as the tourmaline content increases, the tensile strength will gradually decrease, but still The required strength of the tourmaline particles is preferably 1 to 5% of the total weight of the present invention. (2) Tensile strength: ^2 (kgf/cm2) —· ;. 1 No added tourmaline Content 1 % Tourmaline content 2% Tourmaline content 33⁄4 Tourmaline content 4% Tourmaline content 5% 2 —1" __3 21.83⁄43⁄4 23.725 23.728 19.174 22.765 21.129 21.345 22.349 22.706 20.609 22.086 20.308 26.816 24.627 21.764 22.047 91 01 117 4 · _ —5 21.314 18.032 21.796 19.449 21.625 20.598 22.108 24.499 22.229 23.603 21.855 21 717 Decay fd _ 23.1698 22.012 21.9366 21.7586 21.5762 21.1652 It is known from Table 2 that the tensile strength of the fabric of the invention also decreases with increasing tourmaline content. When the tourmaline content is 1%, the tensile strength decreases by about 5%, and the tensile strength decreases by about 8.6% when the tourmaline content is 5%, but still maintains a relatively high tensile strength. Adding 1-5% of the range does not affect the tensile strength. (3) Washing fastness test (testing conditions: humidity 58%, temperature 29). 〇: 13 200920884 Table 3 (I〇n/cc) Negative ion addition test 刖 After five tests, the average 杂 杂 减小 减小 减小 1 1 1 1% 265 263 993⁄4 2% 350 343 98% 3% 383 365 953⁄4 4% 435 416 96% 53⁄4 489 461 943⁄4 As shown in Table 3 'The good fastness is maintained before and after the test, the amount of negative ions generated is not reduced by washing. b. Negative ion release analysis of the present invention (1) Negative ion static release performance analysis: Static mode negative ion release performance analysis 'Environmental conditions: humidity 58%, temperature 28° 0 Table 4-l (Ion/cc) Tourmaline add halo layer Filter two-layer reduction network three-layer four-layer network five-layer filter 1% 265 412 532 620 712 2% 350 523 652 734 825 3% 412 589 756 834 985 4% 465 652 852 935 1080 5% 489 712 867 973 1115 It can be seen from Table 4-1 that the amount of tourmaline added and the number of layers are both significant influence factors' but the number of layers is its main influence factor. The sub-micron tourmaline polypropylene filter material releases 265-489 Ion/cc of negative ions at different levels under one layer. In the content of 1% sub-micrometer tourmaline polypropylene transition material ion release 265-712 Ion / cc. There is a difference of 223 I〇n/cc between the two, which is the number of tourmaline in the same volume; the increase of the number of layers is more effective than the increase of the addition rate in the amount of negative ion release. (2) Negative ion dynamic release analysis: Dynamic mode negative ion release performance analysis, environmental conditions: humidity 64%, temperature 29 °C. 200920884 Table 4-2 (%) Tourmaline Addition ------ m im 3 Layer 4 Layer 5 Layer 1% ----- 2213 2732 2956 2% "------- 3012 3325 3456 η ------- J iii56 3919 3512 3759 3956 4% ----- 1956 3S19 3725 3856 4120 5% _-------- 3901 3921 4220 -—L— _ From Table 4 above In -2, it can be seen that the amount of tourmaline added, filtration and number of layers are important factors in the amount of dynamic anion release. However, the number of layers is the main important factor. b. Deodorization and antibacterial efficacy test of the present invention The deodorization and antibacterial efficacy test of the fabric woven by the fiber of the present invention is as follows. Table 4 shows the results of the elimination of the concentration of vinegar (CH3C〇〇H) by the fabric of the present invention according to the JEM 1467 test method for measuring the concentration of ammonia (intestine) and acetic acid (CMO). . From Table 4, it was found that the fabric of the present invention has a better deodorizing performance. Table 4 Item Starting concentration The beginning concentration Ammonia NH3 24.00PPM Acetaldehyde CH3CH0 8.00PBI Acetic acid CH3C00H 0.20ΡΒΪ After 30 minutes The concentration after 30 minutes 4.00PPM 1.00PPM 0.04PPM the removal rate of multi pollution The removal rate of each pollutant is 84.33 % 87.503⁄4 80.003⁄4 Total removal rate Total removal rate 84.583⁄4 C. Experimental Example 3 The antibacterial efficacy test results of the fabric woven by the inventive fiber are as follows. Table 5 Test species 0 Initial Inoculation (CFU/ml) 0 hour inoculation amount Contaxt Time 1 hour (lhr later) Redruction antibacterial effect (rabbit) 1 hour (lhr later> Staphylococcus aureus 1.0 X 105 3.0 x 10* 94.8 (%) Escherichia coli 2.1 X 1〇5 1.6 x 10J 99.2 (%) Klebsiella pneumoniae 7.3 X 105 3.0 x 10* 95.8 (%) 15 200920884
jjs Z 2911 黑麴菌 ATCC964?. JIS z 2911 青霉菌屬 ATCC9849Jjs Z 2911 Black bacillus ATCC964?. JIS z 2911 Penicillium ATCC9849
包抗菌率 表7 測試項目 Z 2911 球毛殼 ATCCfi川S JIS 2 291 1 抱漆菌 ATCC9095 H^T~G21-96 _霉葡 ATCC95S3 抗菌防霉環Package antibacterial rate Table 7 Test item Z 2911 Ball shell ATCCfi Chuan S JIS 2 291 1 Lactobacillus ATCC9095 H^T~G21-96 _ mold grape ATCC95S3 antibacterial mold ring
100(%) !00(«) 100(%) 100(¾) 大膜桿菌 =5得知以咖·侧驗法，及表6得知以服腕 100(¾) ==6嶋，酬綱_奈_子時，纖維具 有較佳的抗献防霉賴。由表7得知崎τα 147試驗法，本發 明添加有人轉素時’也具雜佳的抗菌效能。 d.本發明芳香持久效能試驗 本發明纖維所編織成的織品的芳香持久效能試驗。由表8的 結果顯示，本發經三则仍具有有效崎香效果，足證本發 明的製法及所製成的纖維，可以確保齡加微職中精油之芳香 的持久性。 ,8:添加含有精油之)¾¾囊的芳香持久測試 議項p 識結果(初始纖、 氣味官能評估 3,4 再測試) 4.0100 (%) !00 («) 100 (%) 100 (3⁄4) M. faecalis = 5 learned by the coffee side test, and Table 6 learned that the wrist 100 (3⁄4) == 6 嶋, reward When the yarn is used, the fiber has better resistance to mildew. It is known from Table 7 that the Sachine 147 test method has an excellent antibacterial effect when the present invention is added with a human. d. Aromatic Durability Test of the Invention The aromatic durability test of the fabric woven from the fibers of the present invention. From the results of Table 8, it is shown that the three hairs of the present invention still have an effective sacrificial effect, and that the method of the present invention and the fibers produced can ensure the durability of the fragrance of the essential oil in the age and the micro-employment. , 8: Adding an aromatic long-lasting test containing 3⁄4⁄4 capsules containing essential oils. Negotiation item p results (initial fiber, odor function evaluation 3, 4 retest) 4.0
再者，藉由GC-MS測試本發明網體纖維内含有天然精油成分 而得下表之結果。 M Z 由表9發現本發_雜有效含有天_油成分清淨能力。 200920884Further, the results of the following table were obtained by GC-MS testing of the natural essential oil component contained in the fiber of the present invention. M Z From Table 9, it was found that the present invention has an ability to clean the day-oil component. 200920884
e.本發明抗靜電效能試驗 依据AATCC 756-1995温度20°C湿度40%RH由下表发现本發 明纖維所織成的網體有良好有抗靜电效能能力。 试验项目 试验结果 电磁波遮蔽效果DB/分贝 300MHZ 0.2 电磁波遮蔽效果DB/分贝 1800MHZ 0.1 f.本發明防火效能試驗 依UL 94-97方法由下表發現本鞋墊有長久有防火能力VTM-0。 17 200920884 表15: 试验项目 试片一 试片二 试片三 试片四 试片五 VTM-0要求 试片厚度 2.95_ 2.82_ 2.84 刪 2.85» 每一试片余焰时间tl sec 0 0 0 0 0 S10秒 每一试片余焰时间t2sec 0 0 0 0 0 S10秒 每五片一组总余焰时间 (五片各个tl+t2的总和） 0 S50秒 每一试片第二次点火燃烧后的余焰加余烬的时 间t2+t3 0 0 0 0 0 S30秒 任一试片的余焰或余烬燃烧到夹具 否 否 否 否 否 否 棉花被燃烧颗粒或熔滴物点燃 否 否 否 否 否 否 g.主要實驗例測試結果總表 本發明主要實驗例測試結果總表及檢測單位一覽如表9。 表9: 功能 功效 方法/種類 時間 效果 檢測單位 奈米銀 段ft ASTTH 2149-01 金色葡萄球菌(AT0C#6538> 作用時間 —小時 94.8 SGS台灣檢驗科技 ASTH1 2149-01 大腸桿菌(AT0C#8739) 99.2 SGS台灣檢驗纖 _A-SBI 2149-01Z 肺炎桿菌(ATCC#4352) 95.8 SGS台灣檢驗_ 殺霉 JIS Z 2911 黑麴菌 ATCC9642 〇無生長 SGS台灣檢驗科技 「J IS Z 2911 青霉菌靥 ATCC9849 一 ... 0無生長 SGS台灣檢驗科技 JiS Z 2911 球毛殻 ATCC6205 ~ 〇無生長 SGS台灣檢驗j斗技 )IS Z 2911 袍漆菌 ATCC9095 〇無生長 SGS台灣檢驗Λ技 ASTM G21-96 ifS® ATCC9533 一 ~ δ無生長 SGS台灣檢驗科技 功能 功效 方法/種類 抗菌力％ 抑菌環mm 檢測單位 人工 酵素 抑菌 A · λ. T. C · C 147 -1998 金色葡萄球菌(ATCC#6538 > 100 % 10 mm SGS台灣檢驗科技 λ .A.T.C.C 147-1998 金色葡萄球菌(ATCC#6538) 100 % 13 mm ΕΡΑ美國環保署 _A.A.T.C.C 147-1998 大膜桿菌(ATCC#8739) 100 % Ί 4.5 mm 3〇3台灣檢驗科技 A—.A.T.C.C 147-1998 大腸桿菌(ATCC#8739) 100 % 1 mm ΕΡΑ美國環保署 A.A.T.C.C 147-1998 肺炎桿菌(ATGOM352) 100% 3.5咖 SGS台灣檢驗科技 A.A.T.C.C 147-1998 肺炎桿菌(ATCC#4352) 100% 6咖 ΕΡΑ美國環保署 防霉1 MTCC 30 ΡΑΡΤ 1Π 黑斑菌 ATCC6275 SGS台灣檢驗科技 負離子含 量 氧負離本1 4Ϊί*4Μ*4Μ負離子釋放量含量 1856(Ion/cc) ™ι妨麟合所 1956(Ion/cc) 1983(Ion/cc) 水洗實驗(水洗二十次） 維持98%以上 - 通紅外線 苜匕重 _遠紅外線放射率(50°C )置測3-15“m平均放射率 0.948 平均放射_ 工研院能資所 一 *··~· E.本發明的特點 1. 本發明纖維添加機能性微粒（如次微米電氣石粒子），其所製 成之漶網的機械強度，僅些微的減低，但無太大影響。 2. 本發明纖維添加機能性微粒（如次微米電氣石粒子），經水洗 18 200920884 牢度試驗，仍保有一定的功能。 3. 本發明添加熱可麵性體及次微米電氣石粒子，—方面在過遽 效能方面，因電氣石帶負電效果’在「靜電吸附原理」下而= 有效增加提升過濾效能，另方面因熱可塑舰體，㈣成之慮 材不僅具有較佳彈性、雜性，由於_子特殊功效4電性: 壓電性加迷水分解負離子⑽2-)下，彈性振動頻率高，摩擦力 較大’動態模式下便可大量釋放出負離子量，而能確實符合人 體健康的需求量⑽0_2000i〇n/cc)。經實驗發現，本剌在 4l^4m*4m的容積中負離子的釋放量含量約 1856〜1983(I〇n/cc) ’具有良好的釋放量。 4. 本發明添加包含有精油的微膠囊時，因同時添加有熱可塑彈性 體j由彈性體的作用可避免精油快速揮發，而可使精油以接 近疋置的方式釋出’避免浪肢增進耐久性。 5. 本發明於纖維中添加奈米銀粒子時，使得本發曰月的遽網具有一 定的抗菌效果。 6. 本發明於纖維中添加酵素時，經實驗證明本發明具冑良好的抑 菌及防霉效果。 7·而使用本發明纖維所製成之濾材，經實驗證明，室内空氣品質 得以有效提升如表9所示。 、 以上所述，僅為本發明之可行實施例，並非用以限定本發明 之專利範圍，凡舉依據下列巾請專利範圍所述之内容、特徵以及 19 200920884 其精神而為之其他變化的等效實施，皆應包含於本發明之專利範 圍内。 20e. Antistatic efficacy test of the present invention According to AATCC 756-1995 temperature 20 ° C humidity 40% RH, the mesh woven by the fiber of the present invention has good antistatic performance. Test items Test results Electromagnetic wave shielding effect DB/dB 300MHZ 0.2 Electromagnetic wave shielding effect DB/dB 1800MHZ 0.1 f. Fire resistance test of the invention According to the UL 94-97 method, the insole has long-term fireproofing ability VTM-0. 17 200920884 Table 15: Test items Test piece One test piece Two test piece Three test piece Four test piece Five VTM-0 required test piece thickness 2.95_ 2.82_ 2.84 Delete 2.85» Each test piece afterflame time tl sec 0 0 0 0 0 S10 seconds each test piece afterflame time t2sec 0 0 0 0 0 S10 seconds every five sets of total afterflame time (the sum of five pieces of each tl + t2) 0 S50 seconds after each test piece is ignited for the second time The time after the remaining flame plus tick t2+t3 0 0 0 0 0 S30 seconds The remaining flame or ember of any test piece is burned to the jig. No No No No No Cotton is ignited by burning particles or droplets No No No No No No g. Main Experimental Example Test Results Summary Table The main results of the main experimental examples of the present invention are summarized in Table 9. Table 9: Functional efficacy method/type time effect detection unit nano silver segment ft ASTTH 2149-01 Staphylococcus aureus (AT0C#6538> time-hour 94.8 SGS Taiwan inspection technology ASTH1 2149-01 Escherichia coli (AT0C#8739) 99.2 SGS Taiwan Inspection Fiber _A-SBI 2149-01Z Klebsiella pneumoniae (ATCC#4352) 95.8 SGS Taiwan Inspection _ Killing JIS Z 2911 Black sputum ATCC9642 〇 No growth SGS Taiwan Inspection Technology "J IS Z 2911 Penicillium 靥 ATCC9849 I. .. 0 no growth SGS Taiwan inspection technology JiS Z 2911 ball shell ATCC6205 ~ 〇 no growth SGS Taiwan test j fighting skills) IS Z 2911 robes bacteria ATCC9095 〇 no growth SGS Taiwan inspection technology ASTM G21-96 ifS® ATCC9533 ~ δ no growth SGS Taiwan test technology functional method / type antibacterial power % antibacterial ring mm detection unit artificial enzyme antibacterial A · λ. T. C · C 147 -1998 Staphylococcus aureus (ATCC#6538 > 100 % 10 Mm SGS Taiwan Inspection Technology λ .ATCC 147-1998 Staphylococcus aureus (ATCC #6538) 100 % 13 mm ΕΡΑ US Environmental Protection Agency _AATCC 147-1998 Large bacilli (ATCC #8739) 100 % Ί 4.5 mm 3 〇 3 units Inspection Technology A-.ATCC 147-1998 E. coli (ATCC#8739) 100 % 1 mm ΕΡΑ US Environmental Protection Agency AATCC 147-1998 Klebsiella pneumoniae (ATGOM352) 100% 3.5 Coffee SGS Taiwan Inspection Technology AATCC 147-1998 Pneumoniae (ATCC# 4352) 100% 6 Curry US EPA Mildew 1 MTCC 30 ΡΑΡΤ 1Π Black Spot ATC6275 SGS Taiwan Inspection Technology Negative Ion Content Oxygen Negative Isolation 1 4Ϊί*4Μ*4Μ Negative Ion Release Content 1856(Ion/cc) TMι Linhe Institute 1956 (Ion/cc) 1983 (Ion/cc) Washing experiment (washing 20 times) Maintaining 98% or more - Passing infrared ray weight _ Far infrared ray rate (50 °C) Setting 3-15"m The average emissivity is 0.948. The average radiation is _ _ _ _ _ _ E. Features of the present invention 1. The fiber of the present invention adds functional particles (such as sub-micron tourmaline particles), which are made of 漶The mechanical strength is only slightly reduced, but it does not have much impact. 2. The fiber-added functional particles (such as sub-micron tourmaline particles) of the present invention are subjected to water washing 18 200920884 for fastness test, and still retain a certain function. 3. The invention adds a thermal surface-receiving body and a sub-micron tourmaline particle, in terms of over-efficiency, because the negative effect of tourmaline is under the principle of "electrostatic adsorption" = effectively increasing the filtration efficiency, and Thermoplastic hull, (4) into the consideration of the material not only has better elasticity, hybridity, due to _ sub-special effect 4 electrical: piezoelectric and edema decomposition of negative ions (10) 2-), high elastic vibration frequency, large friction 'In dynamic mode, a large amount of negative ions can be released, and it can meet the demand for human health (10) 0_2000i〇n/cc). It has been found through experiments that the release amount of negative ions in the volume of 4l^4m*4m is about 1856~1983(I〇n/cc)' with good release. 4. When the microcapsules containing the essential oil are added in the invention, the thermoplastic elastomer is added at the same time, and the elastic body can avoid the rapid evaporation of the essential oil, and the essential oil can be released in a manner close to the squatting. Durability. 5. When the present invention adds nano silver particles to the fibers, the web of the present invention has a certain antibacterial effect. 6. When the present invention adds an enzyme to a fiber, it has been experimentally proved that the present invention has a good antibacterial and antifungal effect. 7. Using the filter material made of the fiber of the present invention, it has been experimentally proved that the indoor air quality is effectively improved as shown in Table 9. The above description is only a possible embodiment of the present invention, and is not intended to limit the scope of the patent of the present invention, and the contents and features described in the following patent claims, and other changes in the spirit of 19 200920884, etc. The implementation of the invention should be included in the scope of the patent of the present invention. 20