TW200918709A - Anti-corrosive paper and treatment method thereof - Google Patents

Abstract

This invention discloses anti-corrosive paper and a treatment method thereof. The paper is treated by a preservative composition which comprises at least one silane-containing raw material and at least one hydrocarbon solvent containing molecules having at least five carbon atoms.

Description

200918709 IX. Description of the Invention [Technical Field to Which the Invention Is Applicable] It is mainly related to paper having a function of antiseptic property and, more particularly, to a method of treating such a paper. [Prior Art] 众所周知 It is well known that 'specific materials are vulnerable to damage caused by the natural environment ^ (10), especially water and insects (such as white sacrifice, special (four) (four) 四, and other annoying insects) = water will typically cause Many - materials, such as drywall) = bricks wide nrybricks) 'various wood products, variegated, have become faded and moldy. Often these materials are decaying and defeating: :: and: ^ = The damage to the material is usually restored in a large amount of two = - and inconvenient to restore the damaged part of the material. The agent manufacturer has sold a variety of possible preventions: =1 or "worm damage to the material, which has been applied to the sound. However, these treatment products are not completely satisfactory ^ (effectivene system, application of Jr, Bu 4th TM ^ ^ m period door, period of 1 ^, and provide protection / month aspect. Especially for paper materials. A preservative composition of paper material is desirable. It is desirable to provide a preservative composition that preserves the paper material against water 200918709 water intrusion and damage. The preservative composition should preserve the paper material effectively. It is resistant to insect erosion and damage, and is relatively inexpensive. It is relatively easy: application, in addition, has a relatively short processing time, and has a relatively long protection period. Therefore, in the present invention, it is first necessary to provide a Preservative composition as required and its handling of paper materials [Abstract] Accordingly, it is an object of the present invention to provide novel anticorrosion for various paper materials. Agent composition and method for the preservation thereof Another object of the present invention is to provide a novel preservative composition for protecting various materials of paper materials against water intrusion and/or pests. In order to achieve the aforementioned object, the present invention provides a method for providing A preservative composition of a paper material comprising at least one decane-containing material and at least one hydrocarbon solvent containing a molecule having at least 5 carbon atoms. Further, the present invention is a method for preserving a paper material, including the following Step: providing a hydrocarbon solvent having at least one decane-containing material and at least one hydrocarbon solvent having a molecule having at least 5 carbon atoms and contacting the material with the composition. One advantage of the present invention is that it is used for various paper materials A novel preservative composition is provided. Another advantage of the present invention is that the preservative composition retains a variety of different paper materials effective against water ingress and loss of 200918709. Yet another advantage of the present invention is that the paper material is preserved - T s '' preservative composition is effective against ant worm invasion and loss. Advantages of this invention 疋 the preservative The composition is relatively easy; the field g. is not expensive, phase, use, has a relatively short processing time, a relatively long protection period. 'One, other purposes, features and advantages of the present invention, detailed details By way of explanation, a complete understanding can be obtained. / 〇 [Embodiment] As shown in Fig. 1, the paper processing method of the anticorrosive function of the present invention first prepares a composition (1) containing hydrocarbons and a hydrocarbon. The composition (2), and the untreated paper (3) 'untreated paper (a)) are in a roll state; then, the untreated paper roll is pulled apart, and a mixed person is fed to (4) The medium mixing chamber (4) is filled and filled with the composition of the stone and the hydrocarbon composition. After a treatment period, the paper is pulled out from the mixing chamber (4) and then sent to an ammonia chamber ( 5) After processing, the paper drawn from the ammonia chamber is a paper that has been treated to have an antiseptic function. After mixing and processing the paper roll, hydrogen acid (6) or smoke (7) will be discharged, which can be recycled and reused, and the former can be used for other industrial purposes. The paper drawn from the above ammonia gas chamber is wound and packaged to become a treated paper having anticorrosive function. The present invention includes a composition which provides a paper material with an anti-corrosion function and a related method of treating paper for storage, protection, and handling of paper materials to provide protection against various differences.

Ο 200918709 Source damage, including, but not limited to, water and insects. According to an embodiment of the invention, the preservative composition comprises at least one decane-containing starting material and at least one solvent. The 5 hai preservative composition comprises at least one decane-containing material. Hydroxane is generally defined as a class of ruthenium-based feedstocks, analogs of alkanes, which are linear, saturated paraffin hydrocarbons of the formula SiNH2N+2, where N is equivalent to! Or a larger number of sharks. While other forms of decane-containing material are acceptable, the decane-containing material is preferably in the form of trichloromethyl decane (chemical formula: CH3Cl3Si).实施 Examples of the decane-containing raw material which is used in the practice of the present invention include, but are not limited to, (gas methyl) triclosan; [3-(heptafluoroisopropyl)propyl]trioxane; 1,6·二(三气矽基)hexilated; 3-bromopropyltrioxane; propylene bromobiguanide brothel; propylene-based three gas stone court; > skunk base gas dimethyl stone Xi sing; bromo thi decyl decane; gas (chloromethyl) dimethyl sulphur gas - isopropyl calcination; gas dimercaptoethyl oxime; gas dimercaptophenyl decane; Benzyl decane; 200918709 gas dimercapto decane; gas diphenyl decyl decane; gas triethyl decane; gas tridecyl decane; Dimethyl methyl ether-based calcination, diphenyldichlorodecane; D di-t-butylchlorodecane; ethyl trichloromethane; iodonium tridecyl pentane; pentyl trichloride crumb; phenyl trigas Decane; tris(3,3,3-trifluoropropyl)decane; tris(dichloroindenyl)decane; and, tri-vinyl vinyl decane. " The preservative composition contains at least one solvent. The solvent is in the form of a hydrocarbon. For example, hydrocarbons, which are liquid at room temperature, are acceptable. Examples of such hydrocarbons are hydrocarbons containing molecules having at least 5 carbon atoms including, but not limited to, pentane, hexane, and heptane. It should be understood that although a hydrocarbon solvent is used, other organic solvents such as tetrs hydrofuran (THF) may be used according to another embodiment of the invention in 200918709, the preservative composition comprising at least one a raw material for the pesticide, at least one raw material containing decane, and at least one solvent. While other forms of the boron-containing material are acceptable, the insecticide-containing material is preferably in the form of a boric anhydride (chemical formula B2〇3). By way of a non-limiting example, borax (chemical formula: Na2B407 · H20), and disodium octaborate tetrahydrate (chemical formula:

NaJsO!3 · H2〇) can also be used. Effective fungal resistance and fire resistance can be obtained using a boron loading of 0.1 weight percent based on the total reset of the target material. However, it is generally desirable to prevent paper material from being smashed with insect infestation (e.g., by ants or termites), a load of 1-2 weight percent boron. For more problematic insects, such as Taiwan's white fun (F〇m〇san termite) - a load of 7 weight percent boron is usually required. Accordingly, the present invention provides a paper material, and a method of treating a shell material, to use a raw material containing a pesticide such as boron at least about 0.1 to about 7 weight percent from u, 隹3丨, $ The level of the white knife rate is introduced into the paper material and sealed to prevent the ring culture, M. . . ^ Brother (such as rain) to wash it from the inside of the target material. It will be understood by the lamp rice that organic materials other than boron can be used. , 匕 3 has the preservative composition can be included in the sentence 』 includes other additives. Other ‘, π, 丄 additives such as paint 200918709 (paint) or dye (stain) can be used. The additive can be transported using a hydrocarbon solvent and a material containing the stone garden and penetrates the paper material to be processed. For example, colorant can be an additive to the preservative composition to treat and color the paper product. It should be understood that other types of organic 'additives can be used to process paper materials. [Method of Preserving Material and Material to be Stored] In order to use the preservative composition of the present invention to preserve various paper materials, the preservative composition is prepared. Next, the preservative composition is applied to the paper material to be preserved. For example, the preservative composition is applied topically to the paper material to be preserved. In accordance with the general teachings of the present invention, the preparation of an exemplary preservative composition is presented in Example I below:

Example I Approximately 50 ml of THF was added to a 250 ml Erlenmeyer flask. About 1.0 μηη of pecan anhydride (B2〇3) was added to the flask and stirred. The mixture was first turbid, but gradually cleared until it was stirred for 5 minutes. A small amount of B 2 〇 3 remains in the bottom of the flask. About 10 to 15 ml of tris-decyldecane was then slowly added to the solution. No clear evidence of an exothermic reaction was observed. The solution remained clear. In order to determine the effect of the exemplary preservative composition prepared in Example I, a comparative test was performed between the wounded and untreated portions of a treated portion of a plywood 200918709. The results of the comparison test are presented in Example II below:

Example II An eyedropper was used to store a few drops of the preservative composition prepared in Example I to a plywood. As the prepared dissolved d was added to the wood sample, there was no evidence of an exothermic reaction or a foul smell. HC1 was found. The composition spreads laterally across the surface of the panel, except that it passes vertically through the board. The water is poured into the treated area and it is effectively waterproof. The water is immediately absorbed by the untreated portion. A few drops are also deposited on the edge of the board to determine the solvent (ie, ΤΗ. effect on the glue. A screwdriver and a small shovel are used in an attempt to separate the splint. This effort is a failure. To further To determine the effect of the exemplary preservative composition prepared in Example I, a comparative test was performed between a treated portion of a heartwood and an untreated portion. The Q results of the comparative test are presented below. In Example III:

Example III A few drops of the preservative composition prepared in Example I were applied to a solid portion of a hardwood. The sample was allowed to stand for a few minutes before it was exposed to water. Until dry, no white residue was found on the surface of the sample. Water is removed on both sides of the sample, even if only one side is treated. In accordance with the general teachings of the present invention, the preparation of another exemplary preservative set 200918709 is presented in the following examples:

Example IV 20 ml of THF was added to a 1 〇〇 ml flask. About 1 gm of B2〇3 and 1 ml of trichlorodecyldecane were added to the tHF solvent. The total volume is approximately 22 ml. In order to determine the effect of the exemplary preservatives/components prepared in Example Iv, a comparative test was performed between a treated portion of a splint and an untreated portion. The results of the comparison test 〇 are presented in the following example v:

Example V A splint, 5/8 吋Χ 5 Torr X 3 1/2 Torr, was placed in a flask and partially immersed in the preservative composition prepared in Example Ιν. The flask was covered for approximately 5 minutes. After 5 minutes, the block was removed and allowed to air dry. The preservative composition remaining in the flask has been reduced in volume by up to 2-3 ml, or approximately 10%. There are no obvious white sinking objects on the splint table. The surface sample was removed from the treated and untreated portion of the splint to evaluate it under the microscope. There is a difference between the samples that can be observed. The treated splint ^ appears as if it had been coated with a glass or white cotton coating. There is a difference between heartwood and sapw〇〇d2. The cells of the untreated splint appear as voids, while those treated wood appear to be coated with glass. When the methanol droplets are added to the splint sample, the treated sample forms water droplets on the surface of the sample 13 200918709 and looks like a colloid. However, the effluent water is easily absorbed on the untreated splint. A portion of this splint (% σ X 1/2 leaves X 3/4) was placed in a 100 ml flask containing 1 〇 ml of water and covered with a view glass. The sample was allowed to stand undisturbed for 24 hours and then the splint was removed from the water. From the water of the leaching experiment; FTIR shows a wavelet peak at 800 cm-1. This peak is not strongly defined in the example of a decane reference peak. The treated splint showed no signs of decane on the surface after immersion in water for 24 hours. However, it does drain quickly on all sides. The cut surface is also drained' even though it has never been in direct contact with the preservative composition. It is from 丨/2吋 to 3 / 4吋 away from the preservative composition. There are a number of benefits associated with the use of a solvent such as THF over the application of pure methyltrichloromethane, including: (1) the cost is reduced by diluting the pure mercaptotrioxane solution (eg, with THF); no exotherm Evidence of the reaction was found; (3) no white residue remains on the surface of the treated material; (4) boron and sputum easily penetrate and spread over the target material and are transported in a single step; (5) Less or no drying time before use; (6) cycle treatment = completely reduced relative to the CCA step; (7) no splitting effect of the splint (delamination^ decomposition is found; (8) treated 'The material becomes waterproof; (9) the treated target material becomes insect-resistant (by virtue of the presence of boron); (10) the treated body becomes 200918709 refractory (by the strength of boron); 11} The treated target material is prohibited from washing. In order to determine the shed penetration and retention characteristics of the preservative composition of the present invention, an experiment was carried out as described in Example VI below:

Example VI 8 ml of THF was placed in a 2 liter Erlenmeyer flask. A magnetic stirring bar begins to be mixed at a low speed. 6.895 g (by weight of solvent 〇 7 percentage) b2 〇 3 was slowly added. The mixture was allowed to stir for 30 minutes. The solvent was clear, although some of the undissolved B2〇3 remained in the bottom of the flask. 200 ml of methyltrioxane was transferred to the stirred solution over a period of 10 minutes via a nitrogen pressured canula. Evidence that this system is fully functional and that there is no exothermic reaction was discovered. This resulted in a solution of decyl trioxane in an amount of about 20 volume percent. This solution was stirred for 1 minute and then the agitation was stopped. A small amount of undissolved 1〇3 residue remained at the bottom of the flask. An aliquot of 5 GG * liter (aliqUGt) was poured into two beakers of 1 liter each and covered with a large viewing glass. The first portion of a block has the dimensions of the i-cut leaf pair. One of the blocks: the two parts are W cubes. The wood pieces of each sample were placed separately into their respective solutions. - The smaller viewing glass is placed inside the beaker and the weight of the glass is viewed so that the wood sample is maintained at the end of 200918709. The sample is allowed to stand in solution for an hour. Some bubbles are generated throughout the process. After i hours of treatment, the blocks were removed from the solution and allowed to air dry overnight. The part of the wood seems to be smoking when it is dry. The smoke is believed to be qi and acid. It may be produced by hydrolysis of unreacted methyl trioxane which appears on the surface of the wood. The solution appeared cloudy after treatment and was slightly discolored. It may be too long to expose the wood to a composition of preservatives as described above for one hour. The treated wood has a smoky, direction (also known as HC1) due to the extra stone eve on the surface of the wood.

Li exposure to a preservative composition as described above for 5 to 10 minutes may be sufficient to achieve the above benefits. Further, the appearance of the material treated with the preservative composition as described above was gray or grayish white. This may be due to Shi Peng. A material which occurs 5 to 1 minute after the treatment of i with the preservative composition as described above. Ο: An alternative embodiment of the present invention, which contains the raw material "individual St material" before the infiltration of the raw material containing (4) or infiltration of the raw material independently of the 3rd stone. It is observed for use in 1% by weight. Or the higher processed 掣 的 曰 曰 曰 曰 曰 曰 ( ( ( 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 引入 引入 引入 引入, raw, and preferably under the influence of a pressurized treatment tube. Because TMF is commonly used in Shi Peng chemistry, although it was originally used by 16 200918709 as a solvent for boron-containing raw materials, Soluble in THF and repeated in a small amount in untreated wood products " to 2: widely used. Therefore, due to the type of solvent required: 100: poor: Jiadi is introduced into wood products before and after the raw materials containing decane.

In the case of - 4 hours of treatment with the raw material/water solution containing the collar, this should result in - which is the final concentration of 2 weight percent. It is intended that the higher (iv) charge concentration can be achieved by varying (column as increased) the boron concentration in the boron-containing treatment solution and by varying (e.g., increasing) the treatment period. What is to be followed is whether the wet, treated wood product (ie, the impregnated) can be subsequently treated with a raw material containing a sulphuric acid (eg, methyl sulphate for processing to produce a satisfactory result.

According to an alternative embodiment of the invention, in order to apply methyltrioxane to wet, boron-impregnated wood products, the performance and cost of the pentane solvent is observed to be superior to those of those of THF. By a non-limiting example, a preferred concentration of methyl trioxane with pentane, wherein the mercapto trioxane is present in a volume fraction of 丨 to ^, should be prepared on the immersion (four) wood product treatment j For example, thick wood products such as sleepers may require higher levels of bismuth-based triple IU sparks, while thinner wood products, such as planking for decks and decks, and gauges 200918709 (—31 lumber), may need lower = exist. However, at least - exposed (untreated:: = = 丄 surface is usually required to be included in the pre-existing wood structure.] Treated (e.g., boron impregnated) I: port: permeation characteristics, an experiment was carried out as described in Example VII below: , Example νπ D 2 to the volume fraction of methyl three gas bite/pental The solution was prepared and applied to a portion of the wood saturated with water. A second solution having a concentration of 3 vols of methyl trichloromethane/pentan was also prepared and tested. After the removal of the treatment officer, the two separated parts of the water-saturated wood were immediately sprayed. The wood block was previously treated with a pressurized aqueous solution containing boron as raw material for 2 hours. After the treatment, the wood did not appear immediately. The water Q is formed to form water drops. However, when the wood is dry, it shows evidence of complete drainage. After a drying time of 24 hours, the surface treated with i volume of the solution represents part of the water resistance. No surface A coating that can be observed. After a drying time of 24 hours, the 3 volume percent solution treated surface is completely water resistant. Until the wood is broken into half and an inner surface is exposed, the thickness of a human hair is decane. Permeation is evident. After removing the sample block from the rotten treatment tube, when the additional piece is 3 volumes of 200918709 percentage concentration of decyl trioxane/pentane solution for 3 minutes, 2 5 hours, Treated at intervals of 1 week, 2 weeks, and 4 weeks, better results can be obtained. This can mean that it is impossible to completely treat wet wood 'and local before applying methyl trioxane/pentane solution Drying of wood is necessary. When methyl trioxane is applied to treated wood, solvent*pentane appears to behave better than THF. The reactivity of mercaptotrioxane is reduced and not observable after treatment The number of limbs of hydrochloric acid (Ηα) gas f was found. This may be partly because Shi Xi-sing is present at a concentration of 3 volume percent or less. On the surface of the latex block, the thiol trioxane/pentane solution penetrates the lacquer layer and effectively seals the wood layer under the lacquer. When it is partially sprayed on a lacquered oil-based block On the surface, the methyltrioxane/pentane solution penetrates the lacquer layer and effectively seals the wood layer under the lacquer. 〇 In order to determine the selective methodology on a coated material having a coated surface The infiltration characteristics of Shi Xi-siu, an experiment was carried out as described in the following example:

Example VIII, a 3 volume percent decyl trioxane/pentane solution was prepared and introduced into a one gallon plastic pump sprayer. This solution is then sprayed locally onto the surface of the wood painted with latex and oil based paint. A single pass spraying results in decane 19 200918709 and under the painted surface. Extensive spraying seems to reduce the thickness of the latex paint = about 1 吋 penetration into the wood substrate is observed. The absence of a spray* will reduce the thickness or adhesion of the oil-based paint on the surface of the wood. The water-repellent penetration of the 1 part by volume of the f-based trichloro-I solution in the pentamidine is preferably 0.75 Å, and the water-repellent penetration of the 3-vol% solution of the decyl-trioxane in pentane is preferably 1.5 吋. ',', Ί In order to determine the infiltration characteristics of the selective method on the untreated paper material, an experiment was carried out as described in the following Example X:

Example IX 1 and 3 volume percent methyltrioxane/pentane solution Both were applied to fresh erythrotubes to determine the permeability of the solution. A quick one-way spray is applied to each piece of wood. The water-permeability penetration of a 1 volume percent solution of decyltrichloromethane in pentane is 〇.75 leaves. 3 volume percent of the sulfhydryl triclosan sulphur solution in the hospital, the waterproof penetration is 1 · 5 吋. The level of penetration is determined by cutting the worn portion from the block and then introducing a small bundle of water into the wood sample. The boundaries of treated and untreated wood can then be determined. Accordingly, it is preferred that the 1 and 3 volume percent mercaptotriclosan/pental is infiltrated with a stable one-pass application and the water of the protected wood is at least 0.75 Torr and at least about J < . Since the wood is usually in the size of a "wooden board", it is possible to spray and handle only one side of a wooden structure, such as a barrier.

A solution of Example X X to 5 volume percent of methyltrioxane/pentane was prepared and introduced into a hand-held garden mister. - 1 () volume percent of the methyl triphole to find / burn solution was also prepared and introduced into a different hand-held garden sprayer. The news '·' was coated with a polyurethane-filled insulator, and the paper used to coat the polyurethane-filled insulator was covered with a fine mist of a 5 volume percent solution. Different samples of newsprint, polyurethane-filled insulators coated with paper, and paper used to coat polyurethane-filled insulators were covered with a 1 vol. volume solution. Each sample was allowed to dry for 2 minutes. Next, water droplets were placed on each sample. For any sample, the entire surface is not 疋& Not enough preservative compositions can be positioned on the surface of the newsprint or paper to make them hydrophobic. A material similar to the 'insulating paper' was immediately trapped in a bag and fished when water was applied to the surface. In order to determine a more preferred method of applying the preservative composition of the present invention, another exemplary preservative composition according to the present invention is prepared as detailed in Example XI below: 21 200918709

Example XI was prepared as a 5 volume percent decyl trioxane/pentane solution and introduced into a hand-pump sprayer... a 1 G volume percent methyltrichloro find/sinter solution was also prepared. And was introduced - a different manual pump mist eliminator. The total volume of each solution is approximately one plus. In order to determine the effect of the preservative composition prepared in the actual XI on the processing of newsprint, an experiment was carried out as described in the following Example :: a 5 volume percent of the preparation prepared in Example XI The methyltrioxane/pentane solution was sprayed locally on the same as the newsprint. 2 The 10 volume percent thiol tris, decane/pentane solution prepared in Example XI was partially sprayed on a newsprint. ^ On the sample. The samples were allowed to dry for 20 minutes. The water was then placed on each sample. The two processed newsprint samples were each extremely hydrophobic: and water immediately formed water droplets. Water was also placed on a control sample of untreated newsprint' and the control sample was immediately wetted as a result. - Due to the presence of lignin in the paper, newsprint initially turned yellow when sprayed. (When exposed to -strong acid::: HC1 formed by the reaction of decane with paper, the wood in the paper will turn more colored. If there are enough primary, secondary, and tertiary amines in the paper, 22 200918709 paper will Keep yellow) Here, when the sample of the newsprint is dry, the yellow color fades over time, indicating that little or no amine is present on the surface of each sample. The treated samples of the newsprint also appeared white, indicating that an excess of mercaptotrioxane was present on each. Therefore, a more diluted 'solution may be used, such as a 2 to 3 volume percent sulfhydryl 'trioxane/pentane solution. In order to determine the effect of the preservative composition prepared in Example XI on the treatment of paper-coated polyurethane-filled insulators, an experiment was carried out as described in the following Examples:

Example XIII The 5 volume percent decyl trioxane/pentane solution prepared in Example XI was topically sprayed onto a sample of a polyurethane-filled insulator filled with paper. The 10 volume percent methyltrichloromethane/pentane solution prepared in the example of χι was sprayed on the paper in the form of paper coated with one of the insulators filled with polyamine g. One of the polyurethane-filled insulators coated with paper. • The sample was treated with pure methyltrioxane. Each sample was allowed to dry for 20 minutes. Water was then placed on each sample. Each of the treated samples of the insulator exhibited a strong hydrophobic shell. Water was also placed on a control sample of untreated paper coated with a polyurethane-filled insulator, and the control sample was immediately wetted as a result. 23 200918709 It was observed that neither methyltrioxane nor pentane decomposed the polyurethane bubbles of the sample. Again, the treated surface of the insulator sample appears white, indicating the presence of excess methyl trioxane. Therefore, a more diluted solution may be used, such as a volumetric solution of methyltrichlorodecane/pentane.

It is determined that 5 volume percent or 1 volume percent of methyltrioxane/pentane will not pass through the insulator sample. Therefore, both sides of the image sample should be treated to prevent water loss. Furthermore, it has been found that it is not feasible to use only one gallon of preservative solution to treat a paper-coated insulator that must be a minimum of 140 sheets because its surface area is higher than those of those wood products. In order to determine the effect of the preservative composition prepared in Example XI on the treated paper, which was coated with the paper coated with a polyurethane-filled insulator in the Example, an experiment was as follows The implementation described in Example XIV is carried out:

Example XIV The 5 volume percent methyldioxazole/pentane solution prepared in Example XI was topically sprayed on a paper coated with polyurethane for coating in Example XIII. Fill the insulation on the paper sample. The 10 volume percent methyltrioxane/pentane solution prepared in Example X was topically sprayed onto the coated epoxy-filled insulator coated in Example XIII. On the paper sample. Each sample was allowed to dry for 20 minutes 24 200918709 hours. Water is then placed on each sample. The treated surface of each sample exhibited strong hydrophobic properties. The water was also placed in a control of the untreated paper coated with the paper-coated polyurethane-filled insulator in Example XIII. On the sample, and the control sample immediately wetted as a result. The paper sample was observed to appear white, indicating the presence of an excess of methyl-based tris. Therefore, a more diluted solution may be used, such as - 2 to 3 volume percent of f-based trichlorocracking / pentane sulphur solution. Further, after the paper sample is fed to the ammonia gas chamber, the hydrogen acid (HC1) on the surface of the anticorrosive treatment can be removed.

25 200918709 [Simplified description of the drawings] Fig. 1 is a flow chart of the processing method of the present invention.

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Claims (1)

200918709, the scope of application for patents: the method of eccentricity, including a treatment of paper materials to provide corrosion protection: one person provides a preservative of a hydrocarbon burning solvent containing at least one decane-containing material and at least eight to y 5 carbon atoms And the preservative composition is applied to the paper material and permeable and diffusing the money-containing material into the paper material; the decane wherein the at least - money-containing material is methyl gas. For example, in the case of the application of the patent scope, the method of the second aspect of the invention, the method of the second aspect of the invention, wherein the preservative composition further comprises at least one material containing the pesticide. 3. The method of claim 2 The at least one insecticide-containing material is a boric anhydride. The method of claim </ RTI> wherein the at least one furnace solvent is at least one of pentane, heptane, hexane, and combinations thereof. 5. For the method of applying for patent scope » 1 'the at least one of the raw materials containing Shi Xi burning is methyl trichloromethane. 6. If the scope of application for the patent or the item ς s _ The method of 3 or 4 or 5, which further includes a method of removing the hydrochloric acid attached to the surface of the paper material in the anticorrosive treatment by air-milk. 27 200918709 7. Paper made by the method of item 1 or item 2 or item 3 or item 4 or item 5. 8. A paper obtained by the method of claim 6 of the patent application. 1, 28