200916628 九、發明說明： 【發明所屬之技術領域】 本發明係關於-種載持銘奈米粒子之羽毛以及填充其 之羽毛製品。 【先前技術】 羽毛製品，特別是於羽毛被所填充之羽毛，一般而古 係使用鵝、鴨、及棲息在北極圈海岸線等之絨鴨（野生鴨°) 等水禽之羽毛。羽毛有相t於胸毛之絨毛（dGwn)與稱為羽 根之羽毛（feather)，兩者皆使用於羽毛製品。羽毛產地有 波蘭、匈牙利等之中歐、包含斯堪地那維亞半島之北歐、 及中國等。羽毛蓬鬆性優異作為蓋被之填充物縣於高級 材料之地位。由於清洗不充分之羽毛為產生臭味之原因， 因此要求事先將產生臭味之污物除去，以使得用來評估羽 毛洗淨程度之潔淨度與氧計數保持在一定水準。 在鉑之膠體中，鉑奈米粒子係在被保護劑所包圍之狀 態下，以1〜10〇nm(奈米）粒徑之懸濁液存在（以下，有時 將不米粒子與其周圍之保護劑的結合體稱為膠體液），已知 使用於燃料電池用觸媒、及汽車用排放廢氣處理觸媒（專利 文獻1)由於該鉑奈米粒子具有還原性，因此著眼於與活 性乳之還原與抗氧化性作用，亦有提案將其混合於化妝品 中（專利文g 2〜3)。又’作為#奈米粒子在纖維之應用而 。，亦有提案使鉑奈米粒子含於纖維素纖維中（專利文獻 4)〇 專利文獻1 :日本特開2004 — 263 222號公報 200916628 專利文獻2 : 專利文獻3 : 專利文獻4 : 【發明内容】 曰本特開2005~ 139102號公 W〇2〇〇5/〇18598 號公報 曰本特開2005— 245258號公報 ^ t 式使於羽毛被等所填充之羽毛中都姓 將试淨度與氧計數保持在-定水準之翻奈米粒子。持 本發明提供—種载持有將潔淨度與氧計數保持在一〜 水準之麵奈米粒子且具抗氧化疋 毛製品。 a U及填充其之羽 得到人等雖藉由使羽毛載持.奈米粒子，而 減性之羽毛，但卻無法獲得可滿足之 洗序·度之指標之潔淨度與氧 …/ 之結果，著眼於㈣粒子二數:之::再努力研究 例，發現拉“ 于。保遵其之保護劑的配合比 定水準並=比例則能將潔淨度與氧計數保持在- Α 、’ 5 0，具抗乳化性，從而產生本發明。又，亦發現 淨度與氧計數保持在—定水準，依保護劑種類， ，不未粒子與保護劑之配合比例會有不同。 界面H ’本發明之羽毛’係載持有以水溶性高分子及/或 子金“劑Γ護之始奈米粒子，其特徵在於：該紐奈米粒 /合拴阿分子及/或界面活性劑之配合比例，以質量比 二糸鉑奈米粒子：水溶性高分子及/或界面活性劑·· 〇·2 〜I :丨· 5。 又’本發明之羽毛’係載持有以鹽保言蔓之始奈 ;、沒子，其特徵在於：該鉑奈米粒子與檸檬酸鹽之配合比 200916628 例，以質量比計係紐奈米粒子：檸檬酸鹽 本發明之羽毛製。，总时斗 1 * 35 … 係將該羽毛填充於製品内部。 本發月之羽毛，藉由載持有保 高合孚》/ +田^ 又州不木拉子之水溶性 二子及/或界面活性劑、或檸檬酸鹽之配合比例設於既定 辄圍的翻奈米粒子’可形成 與氧計數（為使氧化劑將污毕之有機^(表^潔性之尺度） 需之氧量)保持於良好水準且呈=以化學的方式氧化所 τ不+且具抗虱化性的羽毛。 可期tl!之羽毛製品，藉由將該羽毛填充於製品内部， 能：來自身體周圍空氣層對身體造成不良影響 :Γ:本基加以分解的效果。羽毛填充於内部 :身右载持始奈米粒子，則可進一步提升 。 【貫施方式】 20〇5/t發明所使用之麵奈米粒子，例如係以觸 咖8破公報所記載之方法所提供，其平均粒徑以1 ^職較佳’以1〜3nm更佳，以1.5〜2.5nm最佳。又， ^ 貝里％以上之鉑奈米粒子的粒徑落入0.1〜1 〇nm之 洛入1〜3nm之範圍内更佳。如此，若鉑奈 /、粒子之粒徑分布狹窄且其平均粒徑在卜5·之範圍内， 則鈾不米粒子之比例會較高，而具有良好之抗氧化性。又， 主' 載持於羽毛時’可不使用黏結劑樹脂而直接載持於羽毛 表面。 〃本1明之载持始奈米粒子之羽毛係具有抗氧化性。抗 " 之測里方法將於之後說明。本發明之羽毛藉由具有 抗氧化性’除了推測可發揮與該專利文獻2〜3所提案之 200916628 化妝品相同之對人㈣^ 體車父佳的抗氧化性效果以外，亦可 能抑制羽毛本身之次各 ^』期待 。又，由於始奈米粒子具有觸 功能，因此可長時間使用。 、有觸媒之200916628 IX. Description of the Invention: [Technical Field to Which the Invention Is Applicable] The present invention relates to a feather carrying a seed of Ming Nano particles and a feather product filled therewith. [Prior Art] Feather products, especially feathers filled with feathers, are generally used in the feathers of waterfowl such as geese, ducks, and eider ducks (wild ducks) that inhabit the Arctic coastline. Feathers have a phase d to the chest hair (dGwn) and a feather called a feather, both of which are used in feather products. The feathers are produced in Central Europe such as Poland and Hungary, Nordic in Scandinavia, and China. Feather fluffy is excellent as a filler in the county of advanced materials. Since the insufficiently cleaned feathers are the cause of the odor, it is required to remove the odor-producing dirt in advance so that the cleanliness and the oxygen count for evaluating the degree of feather washing are maintained at a certain level. In the colloid of platinum, the platinum nanoparticles are present in a suspension of 1 to 10 〇 nm (nano) in a state surrounded by the protective agent (hereinafter, the non-rice particles are sometimes surrounded by A combination of a protective agent is called a colloidal liquid, and it is known that it is used for a fuel cell catalyst and an automobile exhaust gas treatment catalyst (Patent Document 1). Since the platinum nanoparticle has a reducing property, it focuses on active milk. The reduction and antioxidant effects have also been proposed to be mixed in cosmetics (patent text g 2~3). Also as a #nano particle in the application of fiber. There is also a proposal to contain platinum nanoparticles in cellulose fibers (Patent Document 4). Patent Document 1: JP-A-2004-263,222, No. 200916628 Patent Document 2: Patent Document 3: Patent Document 4:曰本特开2005~ 139102 公公〇W〇〇2〇〇5/〇18598 Bulletin 曰本特开2005- 245258号 ^ t-style in the feathers filled with feathers, etc. The oxygen count is maintained at a constant level of nano-particles. The present invention provides a seed-bearing nanoparticle having a cleanliness and oxygen count at a level of ~ and having an anti-oxidant wool product. a U and the feathers that fill it are obtained by letting the feathers carry the nanoparticles, but the feathers are reduced, but the cleanliness and oxygen of the index of the washing degree are not obtained. Focus on (4) Particles 2: It: Try harder to study the case and find that the pull of "protection agent" is the same as the level of the protection agent and the ratio can maintain the cleanliness and oxygen count at - Α , ' 5 0, with anti-emulsification, thereby producing the present invention. Also, it is found that the clarity and the oxygen count are maintained at a constant level, depending on the type of the protective agent, the ratio of the non-particles to the protective agent may be different. The feather of the invention carries a starting nanoparticle which is protected by a water-soluble polymer and/or a gold-based agent, and is characterized in that the ratio of the neon particle/mercapto molecule and/or surfactant is matched. To the mass ratio of bismuth platinum nanoparticles: water-soluble polymer and / or surfactant · · 〇 · 2 ~ I : 丨 · 5. Further, the 'feather of the present invention' carries a salt-protecting vine; the genus is characterized in that the ratio of the platinum nanoparticle to the citrate is 200916628, and the mass ratio is Rice Particles: Citrate made from the feather of the present invention. , always bucket 1 * 35 ... is to fill the feather inside the product. The feather of this month, set by the proportion of the water-soluble two-part and / or surfactant, or citrate of the holding of Baogao Fufu / + Tian ^ and the state of Muzizi in the established The rice particles can be formed in an oxygen count (to keep the oxidant to be oxidized) (the amount of oxygen required for the surface), to be in a good level and to be chemically oxidized. Degenerate feathers. Feather products that can be tl!, by filling the feathers inside the product, can: the air layer around the body has an adverse effect on the body: Γ: the effect of the base decomposition. The feathers are filled inside: the first nanoparticle is carried on the right side, which can be further improved. [Comprehensive application method] The surface nanoparticle used in the 20〇5/t invention is provided, for example, by the method described in the contact book, and the average particle diameter is preferably 1 to 3 nm. Good, best with 1.5~2.5nm. Further, the particle size of the platinum nanoparticles having a particle size of more than or equal to 2% is preferably in the range of 0.1 to 1 nm in the range of 1 to 3 nm. Thus, if the particle size distribution of the platinum/neugration particles is narrow and the average particle diameter is in the range of 5, the ratio of uranium non-rice particles is high, and the oxidation resistance is good. Moreover, the main 'when carried on feathers' can be directly carried on the surface of the feather without using a binder resin. The feathers of the primary nanoparticles contained in 〃本1明 have antioxidant properties. The method of anti-" will be explained later. In addition to the anti-oxidation effect of the human (four) body car body which is the same as the 200916628 cosmetics proposed in the patent documents 2 to 3, the feather of the present invention may also inhibit the feather itself. Each time ^" look forward to. Moreover, since the primary nanoparticles have a touch function, they can be used for a long time. Catalyst
本發明之羽毛以TTQ 8 L 1903「羽毛測試方法所 之潔淨度為50〇mm以H ^ W規疋 上’氧計數為4.8mg以下較佳。主 得到此種羽毛，首券ν & 馬了 百先必須以水洗淨羽毛來預先除去 或夾雜物。此時，必項α 4 玄巧木物 。 亏 肩^主意不可將羽毛表面之油分完全除 :有時θ賦予羽毛製品抗菌劑或抗靜電劑等， 因此亦必須考岸、此望，降.σ ^專凊況，整體預先提高潔淨度並降低氧 δ下要又 本發明人等已知銘本半 不水粒子與其保護劑的配合比 對潔淨度及氧計數造点旦，嫩 成衫響。亦即，在使用水溶性高分子 及/或界面活性劑作為保護劑時，始奈米粒子與水溶性高分 子及^界面/性劑的配合比例，以質量比計係以始奈米粒 子.水溶性高分子及/或界面活性齊卜1 : 0.2〜1 : !.5較佳。 更佳為翻不米粒子.水溶性高分子及/或界面活性劑叫：〇 3 。若在該範"，料進—步良好發揮本發明之效 果。若始奈米粒子與水溶性萬公；芬/ ―、田^ > /分注同刀子及/或界面活性劑之配合 比例超過1 · 5，則會伟、，發、，致#政& p ° 曰使4乎度降低而氧計數升高。又，若 銘奈未粒子與水溶性；t；八rt / -1·、te 性间刀子及/或界面活性劑之配合比例小 於〇·2，則膠體會不稃宏，女且.主 曰个穂疋，合易造成鉑奈米粒子之凝集/沉 ;殿。 翻奈米粒子之保護劑’係使用水溶性高分子及/或界面 活性劑等。此等係發揮提升始之親溶劑性的作用。水溶性 200916628 高分子可列舉聚乙烯吡咯烷酮、聚乙烯醇、聚丙烯酸酯、 環糊精、胺基果膠 '及曱基纖維素等。亦可將此等兩種以 上組合使用。其中選擇上以聚乙烯吡咯烷酮對羽毛較佳。 又’亦可使用硫醇系保護劑等界面活性劑。 本發明人等亦發現為了將潔淨度及氧計數保持在一定 水準，依保護劑種類’鉑奈米粒子與保護劑之配合比例會 有不同。 已知若使用檸檬酸鹽作為鉑奈米粒子之保護劑，則可 取得較廣之鉑奈米粒子與擰檬酸鹽的配合比例。亦即，在 將使用有檸檬酸鹽作為保護劑之鉑奈米粒子載持於羽毛 時，鉑奈米粒子與檸檬酸鹽之配合比例，以質量比計係以 翻奈米粒子：檸檬酸鹽=1 : (^〜丨：35較佳。更佳為= 奈米粒子：檸檬酸鹽=1 : n : 30。若在該範圍内，則 可進一步良好發揮本發明之效果。m錄子與捧樣酸 鹽之配合比例超過35，則會使潔淨度降低而氧計數升高。 又，若鉑奈米粒子與檸檬酸鹽之配合比例小於〇 2，=膠 體會不穩定’容易造成鉑奈米粒子之凝集/沉澱。 本發明中將鉑奈米粒子載持於羽毛之方法，可使用以 下等方法’例如⑴將分散有翻奈米粒子之分散液 等塗布於羽毛，並加以乾燥、⑺將羽毛浸潰於 = 米粒子之分散液之後，以達成目的之載持量的方式夢軋： 寺擇乾後’並予以乾燥。若始奈米粒子之平均粒徑在卜5㈣ =:，則即使不使用黏結劑樹脂，亦可使舶奈米粒子 1接载持於羽毛表面故較佳。 9 200916628 此外，若使歸米粒子分散於黏結劑樹脂來使用時， 在將載持有鉑奈米粒子之羽毛填充至被套内部而作成羽毛 被的情況下，即可提高被褥全洗等時之絲耐久性。 黏結劑樹脂’可藉由在不妨礙羽毛之潔淨度、氧計數、 及蓬鬆性之範圍内來選擇使用量來使用公知之黏結劑樹 脂。例如’丙烯酸系樹脂、聚胺醋系樹脂、聚醋系樹醋、 聚醯胺系樹酯、聚矽氧系樹酯、及氟系樹酯等。 上述中’鉑奈米粒子之載持量雖無特別限定，但相對 於羽毛1 kg以20〜9〇"g較佳。更佳為载持量在2〇〜6〇 Μ。若載持量在該範圍内’則可進—步良好發揮本發明 之效果。在#自奈米粒子之載持量少於2“g時，抗氧化效 果會不足，在鉑奈米粒子之載持量超過90#g時，則對成 本不利，或對潔淨度、氧計數會有變差之趨勢。 本發明之羽毛製品，可列舉例如使用羽毛之保溫製品、 被褥、枕頭等寢具、及絨毛线、絨毛背4防寒服等。 、於羽毛被的情況，可將該羽毛填充至被套内部而製得。 被套只要是羽毛不會冒出者則並無特別限定。若使被套亦 載持鉑奈米粒子時，由於可提升抗氧化功能亦可分解接觸 身體部分之活性氧因此較佳。例如，在將該羽毛填充至被 套内部而製成單人覆蓋用羽毛被時，被套之尺寸以15〇咖 21〇_’习习毛填充量為10〜15kg/i件時，所得到之羽毛 破的厚度為12〜14cm左右。 (貫施例） 以下，使用實施例進一步具體說明本發明。此外，本 200916628 發明並非限於下述實施例。 1 ·潔淨度 依據JIS L 1903「羽毛測續古 ,ΛΛ 忒方法」之規定來測量。潔 难度右在5〇〇mm以上則判斷為合格。 2·氧計數 依據JIS L 1903「羽毛測贫太 J 4方法」之規定來測量。氧 汁數若在4.8mg以下則判斷為合格。 3·抗氧化性 以試管内（hl Vhr〇)進行抗氧化性分析時，已知使用 DPPH自由基試藥之方法方便性較高。 本發明中’構想出使用i，卜二苯基苦味肼基 U，l-diPhenyl-2_picrylhydrazinyh DppH)自由基消去法 ^ 測量程序如下。 (1) DPPH自由基測試液之調製 \ 採取甲醇5m卜乙醇5ml加以混合後，添加DppH而 製得25#河（微莫耳）之01>1^自由基測試液。所製得之1^1^ 自由基測試液係呈紫色。 (2) 將加工及未加工羽毛各採取〇lg至比色管（或試 管）。使樣品數η = 2。 (3) 將DPPH自由基測試液l〇mi注入上述比色管。 (4) 密封上部後充分振動後予以靜置。偶爾一邊振動 一邊觀察液體之顏色。自由基若減少則紫色會變淡、黃色 成分會增加。 (5)若紫色變淡、黃色成分增加而可在加工及未加工 200916628 羽毛確認到明確之色差時，則判定具有抗氧化性DppH自 由基消去能力（24小時以内）。 (實施例1) (1)銷奈米粒子 準備產品名為，，DX-9_”作以奈轉體液。此係翻 τ只；’子之平均粒徑$ 2·(電子顯微鏡（S腹）照片之判定） 之^奈米㈣液’且f量比以相對㈣奈米粒+ ι，配合 ::::比咯烷酮〇·5料保護劑者。又，當作成鉑奈米 精製成無确酸根等殘留，ΡΗ為中性，無離子性 、恶。性狀為淡黑色液體且易溶於水。該始奈米粒 子之)晨度為1 〇ppm。 (2)載持於羽毛 羽毛”備加拿大白色賴％質量％。該羽毛已藉由 :計數：M除去污染物。該羽毛本身之潔淨度為1 〇 〇 0 m m、 二 0叫。相對該羽毛lkg，使該麵奈米粒子其乾焊 質莖分別成為20/z s、。 烁 "g、80#g、90"g 之方式，將 冰口 ,作為點妹南|The feather of the present invention is preferably TTQ 8 L 1903 "The feather test method has a cleanliness of 50 〇 mm and H ^ W gauge. The oxygen count is 4.8 mg or less. The main feather is obtained, the first coupon ν & The first must be washed with water to pre-removal or inclusions. At this time, it must be α 4 metaphysical wood. Loss shoulder ^ idea can not completely remove the oil on the feather surface: sometimes θ to give feather products antibacterial agent or anti- Electrostatic agents, etc., therefore, it is also necessary to test the shore, this look, reduce the σ 凊 凊 , , , , , , , , , , , , σ σ σ σ σ σ σ σ σ σ 整体 整体 整体 整体 整体 本 本 本 本 本 本 本 本Compared with the cleanliness and oxygen count, the hair is twisted, that is, when using water-soluble polymer and/or surfactant as a protective agent, the initial nanoparticle and the water-soluble polymer and interface/sex The mixing ratio of the agent is based on the mass ratio of the starting nano particles. The water-soluble polymer and/or the interfacial activity are preferably 1: 0.2~1: !.5. More preferably the non-rice particles. Molecular and / or surfactants are called: 〇3. If in the standard, the feed is good The effect of the invention is as follows: if the initial nanoparticle and water-soluble Wangong; Fen / ―, Tian ^ > / dispensing with the knife and / or surfactant ratio of more than 1 · 5, will be Wei, hair , ##政& p ° 曰 4 4 4 4 4 而 4 4 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 铭 铭 铭 铭 铭 铭If the blending ratio is less than 〇·2, the colloid will not be macroscopic, and the female and the main 曰 穂疋 合 合 合 合 合 合 合 合 合 铂 铂 铂 铂 铂 铂 铂 铂 铂 铂 铂 铂 铂 铂 铂 铂 铂 铂 铂 铂 铂 铂 铂 铂 铂 铂Polymers and/or surfactants, etc. These systems play a role in enhancing the pro-solvent properties of the water. 200916628 Water-soluble 200916628 polymers include polyvinylpyrrolidone, polyvinyl alcohol, polyacrylate, cyclodextrin, and amino-based pectin. ' and sulfhydryl cellulose, etc. These two or more types may be used in combination. Among them, polyvinylpyrrolidone is preferably used for feathers. Further, a surfactant such as a thiol-based protective agent may be used. It has also been found that in order to maintain the cleanliness and oxygen count at a certain level, depending on the type of protective agent The mixing ratio of the platinum nanoparticle to the protective agent is different. It is known that when citrate is used as a protective agent for the platinum nanoparticle, a blending ratio of the platinum nanoparticle to the citrate can be obtained. That is, when the platinum nanoparticle using citrate as a protective agent is carried on the feather, the ratio of the platinum nanoparticle to the citrate is proportional to the mass ratio of the nanoparticle: citrate =1 : (^~丨: 35 is preferable. More preferably = nanoparticle: citrate = 1: n : 30. If it is within this range, the effect of the present invention can be further exerted satisfactorily. When the blending ratio of the acid salt exceeds 35, the cleanliness is lowered and the oxygen count is increased. Further, if the blending ratio of the platinum nanoparticles to the citrate is less than 〇 2, the colloid will be unstable, which tends to cause aggregation/precipitation of the platinum nanoparticles. In the method of the present invention, the platinum nanoparticle is carried on the feather, and the following method can be used, for example, (1) a dispersion in which the nanoparticle is dispersed is applied to the feather, and dried, and (7) the feather is immersed in the = meter. After the dispersion of the particles, the dream is carried out in such a way as to achieve the intended carrying amount: after the temple is dried, it is dried. If the average particle diameter of the primary nanoparticles is in the case of 5 (4) =:, it is preferable to carry the nanoparticle 1 on the surface of the feather even without using the binder resin. 9 200916628 In addition, when the particles of the nanoparticles are dispersed in the binder resin, when the feathers carrying the platinum nanoparticles are filled into the quilt and the feathers are formed, the bedding can be improved. Silk durability. The binder resin ' can be used by using a known binder resin by selecting the amount to be used without impeding the cleanliness of the feathers, the oxygen count, and the bulkiness. For example, 'acrylic resin, polyamine vinegar resin, polyester vinegar, polyamide amine resin, polyoxynphthyl resin, and fluorophylline. The amount of the above-mentioned "platinum nanoparticles" is not particularly limited, but is preferably 20 to 9 Å in terms of 1 kg of feathers. More preferably, the carrying amount is between 2〇6〇6Μ. If the amount of the support is within this range, the effect of the present invention can be satisfactorily achieved. When the loading amount of #from nano particles is less than 2"g, the antioxidant effect will be insufficient. When the carrying amount of platinum nanoparticles exceeds 90#g, the cost is unfavorable, or the cleanliness and oxygen count are The feather product of the present invention may, for example, be a heat insulating product using feathers, bedding such as a bedding or a pillow, and a winter clothing such as a pile yarn or a pile back. In the case of a feather, it may be used. The feather is filled into the inside of the quilt. The quilt is not particularly limited as long as the feather does not emerge. If the quilt is also loaded with platinum nanoparticles, the activity of the body part can be decomposed due to the enhancement of the antioxidant function. Oxygen is therefore preferred. For example, when the feather is filled into the quilt cover to make a single-use feather, the size of the quilt is 15 15 21 〇 ' 习 习 习 习 习 习 习 习 习 习 习 , , , , , , , , , , The thickness of the obtained feather is 12 to 14 cm. (Examples) Hereinafter, the present invention will be further specifically described by way of examples. The invention of the present invention is not limited to the following examples. 1 · Cleanliness according to JIS L 1903" Feather measurement continues, ΛΛ 忒 Method” to measure. It is judged to be qualified if the difficulty is 5 〇〇mm or more. 2. Oxygen count The measurement is carried out in accordance with JIS L 1903 "Feather Measurement Method J 4 Method". When the number of oxygenated juices is 4.8 mg or less, it is judged to be acceptable. 3. Antioxidant property When the oxidation resistance analysis is carried out in a test tube (hl Vhr〇), it is known that the method using DPPH free radical reagent is highly convenient. In the present invention, it is conceivable to use i, diphenyl benzoate, U, l-diPhenyl-2_picrylhydrazinyh DppH) radical elimination method ^ The measurement procedure is as follows. (1) Preparation of DPPH free radical test solution \ After mixing 5 ml of methanol 5 m ethanol, add DppH to prepare 01# river (micro-mole) 01 > 1 free radical test solution. The 1^1^ free radical test solution prepared was purple. (2) Take 加工 lg from the processed and unprocessed feathers to the colorimetric tube (or test tube). Make the number of samples η = 2. (3) Inject the DPPH radical test solution l〇mi into the above colorimetric tube. (4) After the upper part is sealed, it is fully vibrated and then allowed to stand. Occasionally vibrate while observing the color of the liquid. If the free radicals are reduced, the purple color will become lighter and the yellow component will increase. (5) If the purple color becomes lighter and the yellow component increases, it can be processed and unprocessed. When the feather is confirmed to have a clear color difference, it is judged to have the antioxidant DppH free radical elimination ability (within 24 hours). (Example 1) (1) Pinnacle particle preparation product name, DX-9_" is used to convert body fluids. This system turns τ only; 'The average particle diameter of the child is $ 2 · (electron microscope (S belly) The judgment of the photo) ^Nei (four) liquid 'and the amount of f is relative to (four) nanoparticle + ι, with:::: pyrrolidone 〇 · 5 material protection agent. Also, as a platinum nanofine made no It is a residue such as acid, which is neutral, non-ionic and toxic. The trait is light black liquid and soluble in water. The initial particle size is 1 〇ppm. (2) It is carried in feather feathers. Prepare Canadian White Lai% by mass. The feather has been removed by : Count: M. The feather itself has a cleanliness of 1 〇 〇 0 m m and two zeros. Relative to the feather lkg, the dry solder stem of the surface nanoparticle was 20/z s, respectively. Shuo "g, 80#g, 90"g way, will be the ice mouth, as the point sister South |
片 烯I糸樹脂（高松油脂製HIRESIN TS 686相對於羽毛ik2而亡q、 載持、乾燥。 …⑼之/刀散液以噴霧器加以 將所製得之羽毛的評估結果表示於表卜 12 200916628 [表i] 始奈米粒子乾燥質量（#g) 20 60 "----- 80 0〇 潔淨度(mm) 700 670 600 氧計數(mg) 4.6 4.6 4.8 D Uv/ Λ Q 抗氧化性(DPPH自由基消去能力） 有 有 有 有 從表1可知，本發明實施例1之羽毛，其潔淨度、氧 計數、及抗氧化性皆合格。將該羽毛填充至被套内部製成 覆蓋用羽毛被。羽毛填充量以1.2kg/l件。所製得之羽毛 被的厚度為12cm，與未載持鉑奈米粒子者為同等。又，實 際測試使用後，睡眠覆蓋感覺係與未載持鉑奈米粒子者為 同等。 (實施例2) 除了僅使用未混入作為黏結劑之丙烯酸系樹脂分散液 之點不同之外’其餘之舶奈米粒子、載持於羽毛則與實施 例1相同。 將所製得之羽毛的評估結果表示於表2。 [表2] 鉑奈米粒子乾燥質量(Vg) 20 60 80 潔淨度(mm) 750 700 60Π 90 — 1 .m. 氧計數(mg) 4.6 4.6 4 s 500 Λ Ο 抗氧化性(DPPH自由基消去能力） 有 有 • · Ο 有」 4.8 有 13 200916628 從表2可知，本發明實施例2之羽毛，盆潔淨产、氧 計數、及抗氧化性皆合格。將該羽毛填充至被套内畜;製成 覆盍用羽毛被。羽毛填充量m2kg/1件。所製得之羽毛 被的厚度為12,與未載持始奈米粒子者為同等。又，實際 ㈣使用I ’睡眠覆蓋感覺係與未載持翻奈米粒子者為同丁 等。 (實施例3 ) (1) 鉑奈米粒子 準備產品名為”DX— 8030S”作為銘奈米勝體液。此係 ?未粒子之平均粒徑為2nm(電子顯微鏡(sem)照片之判 ^之銘奈米膠體液，且質量比以相對於韵奈米粒子i，配 离;^丙稀酸鈉G·5作為保護劑者。使其成PH為中性，無 離子性物質之狀態。，降 太丄 生狀為，炎黑色液體且易溶於水。該鉑 奈米粒子之濃度為2〇ppm。 (2) 載持於羽毛 羽毛係準備加拿大白色羽絨％質量％。該羽毛已藉由 二乾燥除去污染物。該羽毛本身之潔淨度為讎_、 平。數為0mg。相對該羽毛lkg，使兮舶太半#p 質量分別成A g使遠鉑奈未粒子其乾烯 劑之分m、“、4〇/zg之方式，以喷霧器將無黏結 政液加以載持、乾燥。 將所製得之羽毛的估結果表示於表3。 14 200916628 [表3] 鉑奈米粒子乾燥質量（以2) 20 40 潔淨度(mm) 500 5〇〇 氧計數(mg) 4.8 4 8 抗氧化性(DPPH自由基消去能力） 有 有 從表3可知，本發明實施例3之羽毛，其潔淨度、氧 =數、及抗氧化性皆合格。將該羽毛填充至被套内部製成 覆蓋用羽毛被。羽毛填充量以1.2kg/l件。所製得之羽毛 被的厚度A 12cm，與未載持鉑奈米粒子者為同等。又，實 際測試使用後’睡眠覆蓋感覺係與未載持鉑奈米粒子者為 同等。 (實施例4 ) (U銘奈米粒子 銘太！備產品名為，’DX—8〇3〇v”作為翻奈米膠體液。此係 心…'拉子之平均粒徑$ 2nm(電子顯微鏡(SEM)照片之判 ^有H奈^體液’且f量^目對於#奈米粒子1，配 口有#棣酸三鈉29作我 離+卜““ 29作為保遵劑者。使其成pH為中性，益 離子性物質之狀態。性狀 … 夺乎朽工 性狀為/犬黑色液體且易溶於水。該鉑 不水粒子之濃度為1〇ppm。 (2)載持於羽毛 羽毛係準備加拿大白色$ M Q<; 水洗、乾燥除去… 質量％。該羽毛已藉由 氧計數為0、 5木句。該羽毛本身之潔淨度為100〇mm、 0L該羽毛lkg，使㈣奈米粒子其乾燥 15 200916628 以噴霧器將 質量分別成為20 # g、40 // g、60 y g之方式 無黏結劑之分散液加以載持、乾燥。 將所製得之羽毛的評估結果表示於表4。 翻奈米粒子乾燥質量(//g) 20 潔淨度(min') ~~~~----—. 500 ---— 4.8 氧計數(mg) 抗氧化性(DPPH自由基消去能力） 有 其潔淨度、氧 被套内部製成 所製得之羽毛 同等。又，實 奈米粒子者為 從表4可知’本發明貫施例4之羽毛， 計數、及抗氧化性皆合格。將該羽毛填充至 覆蓋用羽毛被。羽毛填充量以1 2kg/l件。 被的厚度為1 2cm，與未載持鉑奈米粒子者為 際測試使用後，睡眠覆蓋感覺係與未載持銘 同等。 \ (比較例1) (1) 鉑奈米粒子 準備產品名為”DX— 8080T”作為鉑奈米膠體液。此係 鉑示米粒子之平均粒徑為2nm(電子顯微鏡（SEM)照片之判 定）之鉑奈米膠體液，且質量比以相對於鉑奈米粒子丨，配 合聚丙烯酸2作為保護劑者。性狀為淡黑色液體且易溶於 水。該鉑奈米粒子之濃度為20ppm。 (2) 載持於羽毛 16 200916628 羽毛係準備加拿大白色羽絨95質量％。該羽毛已藉由 一先乾h除去污染物。該羽毛本身之潔淨度為^刪_、 ::數為Omg。相對該羽毛…，使該鉑奈米粒子其乾燥 二量各成A 6心、8G//g、9()以之方式，將混合有作為 :結劑之丙烯酸系樹脂(高松油脂製腿刪刪相 、於羽毛1kg而言1Gg)之分散液以噴霧器加α載持、乾燥。 將所製得之羽毛的評估結果表示於表5。 [表5] 60 80 90 340 ------ 340 , 300 _4.8 4.8 4.9 有 有 有 鉑奈米粒子乾燥質量(# g) 潔淨度(mm)___ 氧計數(mg) 抗氧化性(DPPH自由基消去能 從表5可知 ’比較例1之羽丰，抒对" 淨声妨甘Λ 毛抗虱化性雖合格但潔 X、乳β十數其中一項或兩項為不合格。 (比較例2) 劑之丙烯酸系樹脂分散液 载持於羽毛則與比較例1 除了僅使用未混入作為黏結 之點不同，其餘之鉑奈米粒子、 相@。 果表示於表 將所製得之羽毛的評估結 17 200916628 [表6] 鉑奈米粒子乾燥質量(μ g) 60 80 90 潔淨度(mm) 400 400 350 氧計數(mg) 4.8 4.8 4.9 抗氧化性(DPPH自由基消去能力） 有 有 有 從表6可知，比較例2之羽毛，抗氧化性雖合格但潔 淨度、氧計數其中一項或兩項為不合格。 【圖式簡單說明】 無 【主要元件符號說明】 無 \+ 18Phenene I 糸 resin (HIRESIN TS 686 made of Takamatsu oil is dead q, carried, and dried with respect to feather ik2. (9) / Knife liquid is expressed by a sprayer. The evaluation result of the obtained feather is shown in Table 12 200916628 [Table i] Dry quality of the starting nanoparticle (#g) 20 60 "----- 80 0〇 Cleanliness (mm) 700 670 600 Oxygen count (mg) 4.6 4.6 4.8 D Uv/ Λ Q Oxidation resistance (DPPH radical scavenging ability) There are some feathers according to the first embodiment of the present invention, which are qualified for cleanliness, oxygen count, and oxidation resistance. The feather is filled into the quilt cover to make a covering feather. The feather filling amount is 1.2kg/l. The thickness of the feathers produced is 12cm, which is equivalent to those of the platinum nanoparticles. However, after the actual test, the sleep coverage sensory and unloaded The platinum nanoparticle is equivalent. (Example 2) The same thing as in Example 1 except that only the other points of the acrylic resin dispersion which is not mixed with the binder are used. The evaluation results of the obtained feathers are shown in Table 2. [Table 2] Nanoparticle dry mass (Vg) 20 60 80 Cleanliness (mm) 750 700 60Π 90 — 1 .m. Oxygen count (mg) 4.6 4.6 4 s 500 Λ Ο Oxidation resistance (DPPH free radical elimination ability) Yes • · Ο有” 4.8 有13 200916628 It can be seen from Table 2 that the feathers of the second embodiment of the present invention are qualified for clean production, oxygen count, and oxidation resistance. The feathers are filled into the quilt inner animal; The feather filling amount is m2kg/1 piece. The thickness of the feather is 12, which is the same as that of the unloaded nanoparticle. In addition, the actual (4) use I's sleep coverage sensory system and unsupported The rice particles are the same, etc. (Example 3) (1) The platinum nanoparticle preparation product name is "DX-8030S" as the Ming Naisheng body fluid. The average particle diameter of the non-particles is 2 nm (electron microscope) (sem) photo judgment of the Ming Nai colloidal liquid, and the mass ratio is relative to the rhyme nanoparticle i, dissociated; ^ sodium acrylate sodium G · 5 as a protective agent. Make it PH neutral, The state of the non-ionic substance. It is too sturdy, it is black liquid and soluble in water. The concentration of the platinum nanoparticles is 2 (2) Supported in feather feathers to prepare Canadian white down% by mass. The feather has been removed by two drying. The feather itself has a cleanliness of 雠_, ping. The number is 0mg. Relative to the feather lkg The mass of the 兮 太 太 # p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p The estimated results of the obtained feathers are shown in Table 3. 14 200916628 [Table 3] Drying quality of platinum nanoparticles (2) 20 40 Cleanliness (mm) 500 5 〇〇 oxygen count (mg) 4.8 4 8 Oxidation resistance (DPPH free radical elimination ability) There are from Table 3 It can be seen that the feather of Example 3 of the present invention is qualified for its cleanliness, oxygen number, and oxidation resistance. The feather is filled into the inside of the quilt cover and covered with feathers. The feather filling amount is 1.2kg/l. The obtained feather was a thickness of 12 cm, which was equivalent to that of the uncoated platinum nanoparticle. Further, after the actual test, the sleep coverage sensory system is equivalent to those who do not carry the platinum nanoparticle. (Example 4) (U Ming Nai particle Ming Tai! Prepared product name, 'DX-8〇3〇v" as a nano-colloidal colloidal liquid. This core... 'The average particle size of the puller is $ 2nm (electronic The microscope (SEM) photo judged that there is H Na body fluid 'and f quantity ^ for the # nano particle 1, with the mouth of trisodium citrate 29 for me to leave + "" 29 as a compliant agent. Its pH is neutral, the state of the ionic substance is good. The trait... The trait of decay is / black liquid of dog and soluble in water. The concentration of the platinum non-aqueous particles is 1〇ppm. (2) Feather feathers are prepared in Canada White $ M Q<; Washed, dried and removed...% by mass. The feather has been counted by oxygen to 0, 5 sentences. The feather itself has a cleanliness of 100〇mm, 0L the feather lkg, so that (4) Drying of nanoparticles 15 200916628 The dispersion of the non-adhesive agent is carried and dried by means of a sprayer to a mass of 20 #g, 40 // g, 60 yg. The evaluation result of the obtained feather is expressed in Table 4. Dry quality of nano-particles (//g) 20 Cleanliness (min') ~~~~-----. 500 ---- 4.8 Oxygen count (mg) Antioxidant (DPPH free It has the same cleanliness and feathers made by the inside of the oxygen quilt. Also, the solid nano particles are known from Table 4, and the feathers of the fourth embodiment of the present invention are qualified, and the counts and oxidation resistances are all qualified. The feather is filled to cover feathers. The feather filling amount is 12 kg/l. The thickness of the quilt is 12 cm, and the test is used after the test is not carried out with the platinum nanoparticles not loaded. Holding the same level. \ (Comparative Example 1) (1) The platinum nanoparticle preparation product name is "DX-8080T" as the platinum nano colloidal liquid. The average particle diameter of the platinum-based rice particles is 2 nm (electron microscope (SEM) The determination of the photo of the platinum nano colloidal liquid, and the mass ratio is relative to the platinum nanoparticles, and the polyacrylic acid 2 is used as a protective agent. The property is a pale black liquid and is easily soluble in water. The concentration is 20ppm. (2) Loaded on feather 16 200916628 Feather is prepared for 95% by mass of Canadian white down. The feather has been removed by a dry h. The cleanliness of the feather itself is ^ _, :: Is Omg. Relative to the feather..., make the platinum nanoparticle Disperse the amount of the A 6 core, 8 G//g, and 9 () in a dry manner, and mix the acrylic resin (the leg-cut phase of the Takamatsu oil and the 1 Gg of the feather 1 kg) as a binding agent. The liquid was carried and dried by a sprayer with α. The evaluation results of the obtained feathers are shown in Table 5. [Table 5] 60 80 90 340 ------ 340 , 300 _4.8 4.8 4.9 Platinum was present Nanoparticle dry mass (# g) Cleanliness (mm) ___ Oxygen count (mg) Antioxidant (DPPH free radical elimination can be seen from Table 5) Comparative Example 1 Yufeng, 抒 对 " Net Sounds Although the hair resistance is not acceptable, one or both of the X and the milk beta are unqualified. (Comparative Example 2) The acrylic resin dispersion liquid of the agent was carried on the feathers, and the other platinum nanoparticles and phase @ were different from the comparative example 1 except that only the point where the adhesion was not mixed was used. The results are shown in the evaluation of the feathers produced in the table. 17 200916628 [Table 6] Platinum nanoparticles dry mass (μg) 60 80 90 Cleanliness (mm) 400 400 350 Oxygen count (mg) 4.8 4.8 4.9 Antioxidant (DPPH free radical elimination ability) There are some feathers of Comparative Example 2, although the oxidation resistance is acceptable, but one or both of the cleanliness and the oxygen count are unacceptable. [Simple diagram description] None [Main component symbol description] None \+ 18