200914086 九、發明說明： 【發明所屬之技術領域】 本發明係有關於-種用於高爾夫球桿頭之合金材料， 尤其是針對由數種不生鍚、不需電鍍防銹，具有節省成本， 更不會產生環保問題的材料所結合組成。 【先前技術】 按，就傳統高爾夫球桿頭所使用之材料，包括有3〇4 奥斯田鐵不銹鋼，431麻田鐵不銹鋼，17—4Ph析出硬化不 銹鋼’ 25-5雙相剛（50%奥斯田鐵加上50%肥粒鐵），1〇2〇 低％i鋼及9620低碳合金鋼。其中以ι〇20低碳鋼及9620低 碳合金鋼，也就是俗稱的軟鐵（mild steel)，雖然此軟鐵 可助使尚爾夫球桿頭之控球性最隹，但是由於軟鐵並無防 銹能力，需另外以電鑛來達到防銹效果，致使其應用於高 爾夫球桿頭上時，不僅會產生電鍍環保問題，而且製程成 本高，不符經濟效益，也造成業界僅能將上述材料用於價 格昂貴之高級品。 再加上，前述習用生產材料皆為既有材質，並非針對 高爾夫球桿頭之使用功能而開發，就以高爾夫球鐵桿頭而 言，由於其本身形狀變化較多，相對其鐵桿頭所使用之材 料必須具備有適當強度、高延展性、、等特性，若長期以 來使用低碳鋼製品來製造，不但產生前述電鑛環保問題， 200914086 而且也無法充分發揮高爾夫球桿頭於擊球使用上之實質效 果，實為目前業者亟需改善之處。 基於此，本發明人有鑑於上述昔知之用於高爾夫球桿 頭之生產材料存有不良問題，秉持著多年實務經驗，特別 針對高爾夫球桿頭之使用功能，投注大量心力予以研究、 改良，並經多次實驗、檢測及試用後，終於成功開發出一 用於高爾夫球桿頭之合金材料，得以有效克服解決傳統技 術之課題。 【發明内容】 本發明主要目的即在提供一種用於高爾夫球桿頭之合 金材料，係由數種以碳、石夕、猛、鉻、鎳、錦、鱗、硫， 以及9 5 %含微量叾炭化物及微細麻田散鐵之肥粒鐵所組合形 成一種不生銹、也不需電鍍防銹，具有節省成本，更不會 產生環保問題，使其於產業上具有絕對優勢的利用價值。 為達成本發明上述之技術手段，係提供一種用於高爾 夫球桿頭之合金材料，其合金材料中係包含有： 碳（C) 0. 08%max、石夕（Si) 1. 5%max、猛（Μη) 1. 5 %max、鉻（Cr) 16%〜28%max、鎳（Ni) l%max、 鈽（Ce) 1.5%max、磷（P) 0.03%max、硫（S) 0.02%， 其餘比例為鐵。 200914086 其中上述合金材料之95%以上為肥粒鐵組織，尚有微 量的碳化物及微細的麻田散鐵，使其製成之高爾夫球桿頭 之控球性與傳統軟鐵製成之高爾夫球桿頭相較下，更為優 勢。 其次，對於上述合金材料可採以脫腊或鍛造方式直接 成形高爾夫球鐵桿頭。 此外，對於上述合金材料可隨高爾夫球桿頭所需硬度 添加钥（Mo) 1 % max，以供強化剛性。 亦可讓上述肥粒鐵結晶組織更為細化而進一步增添鈦 (T i) 0. 5 % max 或結（Zr) 0. 5 % max 或 ( B) 0. 0 0 3 % max。 據此，結合上述峻、石夕、猛、絡、鎳、錦、填、硫、 鐵，以及微量的碳化物及微細的麻田散鐵、鉬、鈦（或锆 或领）所結合組成之合金材料，具有極佳強度、高延展性、 防銹及控球性等特性，可廣泛應用在高爾夫球桿頭之鐵 桿、沙坑挖起桿、推桿之球桿頭製造。 【實施方式】 首先，針對本發明所欲訴求之專利重點係在於一 種應用於高爾夫球桿頭之合金材料，主要強調其構成之元 素係包括有：碳、石夕、猛、鉻、錄、錦、填、硫、鐵，其 200914086 碳（C)為0· 08%max (最大值）；碳，為合金材料不 可或缺之非金屬元素，以含竣量在0. 08%值為最佳，其特 性除了為碳化物析出作用，亦使其穩定形成肥粒鐵組織。 矽（Si)為1. 5%max (最大值）；矽，為具有電磁特 性，耐熱性之非金屬元素，以含石夕量在1. 5%值為最佳， 可防止氣孔形成，增加收縮作用及鑄造液汁流動性。 猛（Μη)為1 · 5 % max (最大值）；猛，為金屬元素， 可去除合金材料中的氧化物，以含猛量在1. 5 % max值為最 佳，可有效消除硫對於合金材料造成熱脆性之有害影響。 鉻（Cr)為16%〜28% ;鉻，為金屬元素，具有耐磨 性、对餘性之特性，以含鉻量在16 %〜2 8 %值為最佳，為 合金材料中形成實質防銹之效果。 鎳（N i)為1 % max (最大值）；鎳，為金屬元素，具 有韋刃性增加，低溫衝擊抵抗增加之特性，以含鎳量在1 % 值為最佳，為合金材料產生極佳延展性。 飾（Ce)為1. 5%max (最大值）；鈽，為輕稀土元素 之一，以含鈽量1.5%值加入合金材料中，可起脫硫及脫 氧作用，改善常、低溫韌性、斷裂性、減少熱脆性並能改 善加熱工性。 填（P)為0. 03% max (最大值）；礙，為非金屬元素， 200914086 ?、 极憂粗，能增加硬度及抗拉強度，但於合金材料 中僅以含磷量〇. 〇3%為最佳，避免合金材料降低延展性 及韌性。 (S)為0.02% ;硫，為構成合金材料不可或缺之 非金屬7L素，故以含硫量〇 〇2%為標準。 一〜據此，透過上述碳、矽、錳、鉻、鎳、鈽、磷、硫在 料疋比例值下，其餘比例均以鐵為基材所組合而成合金材 ;具有極佳強度、高延展性、防錄等特十生，且由上述合 金材料之95%以上為肥粒鐵組織’尚有微量的碳化物及微 細的麻田散鐵，使其製成之高爾夫球桿頭之控球性與傳統 軟鐵製成之高爾夫球桿頭相較下，更為優勢。 再者，其次，對於上述由碳、矽、錳、鉻、鎳、鈽、 磷、硫、鐵所組成之合金材料可採以脫腊或鍛造方式直接 成形高爾夫球鐵桿頭。 除此之外’躲上述碳、矽、錳、鉻、鎳、鈽、磷、 硫及鐵所組成之合金材料，可隨高爾夫球椁頭所需硬度添 加鉬（Mo) (最大值），以供強化剛性。 亦可讓上述肥粒鐵組織結晶更為細化而進一步增添鈦 (Ti)0.5%max 或锆（Zr)0.5%max 或硼（B)〇 〇〇3%max。 據此’ Μ合上述碳、矽、錳、鉻、鎳、鈽、磷、硫、 200914086 鐵，並以微量的碳化物及微細的麻田散鐵，及增雜、鈦 一(或錯或硼）所結合組叙合錢料，使其具有極佳強度、 南延展性、_及控球性轉性，可廣泛應用在高爾夫球 桿頭之鐵桿、沙坑料桿、推桿之球桿頭製造。 因此，本發明上述之用於高爾夫球桿頭之合金材料，由 數種以碳、石夕、鍾、鉻、鎳、錦、鱗、硫及鐵所組成形成 -種不生錄、也不需電鍍防錄，具有節省成本，更不會產 生環保問題L並以95%含微量魏物及微細麻田散 鐵之肥粒鐵，以增加高爾夫球桿頭之控球性，及添加材料 硬度之鉬、助使結晶硬化之鈦（或錘或硼），俾達到所製成 之合金材料具有極佳強度、高延展性、防銹及控球性，使 其有別丽述複雜且高代價之傳統技術，不僅符合現今人金 材料需求之經濟效益，於產業上具有絕對優勢的利用價值： 上列詳細說明係針對本發明之一可行實施例之具體說 明，惟該實施例並非用以限制本發明之專利範圍，凡未兄 離本發明之技藝精神所為之等效實施或變更，均應包人' 本發明之專利範圍中。 200914086 【圖式簡單說明】 【主要元件符號說明】200914086 IX. INSTRUCTIONS OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to an alloy material for a golf club head, and is particularly useful for cost savings by using several types of non-staining, non-plating rust prevention, A combination of materials that do not create environmental problems. [Prior Art] According to the materials used in traditional golf club heads, including 3〇4 Osbane iron stainless steel, 431 Ma Tiantie stainless steel, 17-4Ph precipitation hardened stainless steel '25-5 double phase just (50% Stone is added with 50% ferrite iron, 1〇2〇 low %i steel and 9620 low carbon alloy steel. Among them, ι〇20 low carbon steel and 9620 low carbon alloy steel, also known as mild steel, although this soft iron can help the ball control of the Shanlf club head is the most embarrassing, but due to soft iron There is no anti-rust ability, and it is necessary to use electric ore to achieve the anti-rust effect. When it is applied to the golf club head, it will not only cause environmental problems of electroplating, but also the high cost of the process, which is not economical, and the industry can only The materials are used in expensive high-end products. In addition, the above-mentioned conventional production materials are all existing materials, and are not developed for the function of the golf club head. In terms of the golf iron head, since the shape of the golf iron head is changed, the iron head is used. Materials must have appropriate strength, high ductility, and other characteristics. If long-term use of low-carbon steel products for manufacturing, not only the above-mentioned problems of environmental protection of electric mines, but also the full use of golf club heads in hitting the ball. The real effect is what the current industry needs to improve. Based on this, the inventors have in view of the above-mentioned problems in the production materials for golf club heads, and have many years of practical experience, especially for the function of the golf club head, and put a lot of effort into research and improvement, and After many experiments, tests and trials, we finally succeeded in developing an alloy material for golf club heads, which effectively overcomes the problem of solving traditional technology. SUMMARY OF THE INVENTION The main object of the present invention is to provide an alloy material for a golf club head, which is composed of several kinds of carbon, Shixia, Meng, Chromium, Nickel, Brocade, Sulphur, and 95%. The combination of strontium carbide and fine granulated iron and iron granules forms a kind of rust-free, electroplating and rust-proof, which saves costs and does not cause environmental problems, making it an absolute advantage in the industry. In order to achieve the above-mentioned technical means of the present invention, an alloy material for a golf club head is provided, wherein the alloy material comprises: carbon (C) 0. 08% max, Shi Xi (Si) 1. 5% max , 猛 ()η) 1. 5 % max, chromium (Cr) 16% ~ 28% max, nickel (Ni) l% max, 钸 (Ce) 1.5% max, phosphorus (P) 0.03% max, sulfur (S) 0.02%, the remaining proportion is iron. 200914086 Among them, more than 95% of the above alloy materials are ferrite-grained iron, and there are traces of carbides and fine granulated iron, which makes the golf ball head made of golf ball and traditional soft iron golf ball. The head is better than the lower one. Secondly, for the above alloy material, the golf iron head can be directly formed by dewaxing or forging. In addition, for the above alloy material, a key (Mo) of 1% max may be added with the hardness required for the golf club head for reinforcing rigidity. Further, the above fermented iron crystal structure may be further refined to further add titanium (T i) 0.5% max or knot (Zr) 0.5% max or (B) 0. 0 0 3 % max. Accordingly, an alloy composed of the above-mentioned combination of Jun, Shi Xi, Meng, Luo, Ni, Jin, Fill, Sulfur, Iron, and trace amounts of carbide and fine granita iron, molybdenum, titanium (or zirconium or collar) The material has excellent strength, high ductility, rust prevention and ball control. It can be widely used in the manufacture of golf club irons, sand pit wedges and putter club heads. [Embodiment] First, the patent focus on the invention is based on an alloy material applied to a golf club head, and the main elements of the composition are: carbon, stone eve, fierce, chrome, recorded, brocade And the amount of strontium is 0. 08% is the best value. The carbon content is 0. 08% is the best. In addition to its carbide precipitation, its properties also stabilize the formation of ferrite iron structure.矽(Si) is 1. 5% max (maximum); 矽, is a non-metallic element having electromagnetic properties and heat resistance, and the value of 1.5% is best in the case of containing a stone, which prevents the formation of pores and increases Shrinkage and fluidity of the casting sap.猛 (Μη) is 1 · 5 % max (maximum); fierce, is a metal element, can remove the oxide in the alloy material, with a turbulent amount of 1.5% max value is the best, can effectively eliminate sulfur for Alloy materials cause harmful effects of hot brittleness. Chromium (Cr) is 16%~28%; chromium, which is a metal element, has wear resistance and residuence characteristics, and the chromium content is preferably 16%~28%, which is the essence of the alloy material. Anti-rust effect. Nickel (N i ) is 1 % max (maximum); nickel is a metal element with a sharp edge increase and low temperature impact resistance. The nickel content is preferably 1%, which is the best for alloy materials. Excellent extension. (Ce) is 1. 5% max (maximum); 钸, one of the light rare earth elements, added to the alloy material with a value of 1.5% of cerium, can be used for desulfurization and deoxidation, improving normal and low temperature toughness, Fracture, reduced hot brittleness and improved heating workability. Fill (P) is 0. 03% max (maximum); hinder, non-metallic element, 200914086 ?, extremely rough, can increase hardness and tensile strength, but only phosphorus content in alloy materials. 〇 3% is the best to avoid alloy materials to reduce ductility and toughness. (S) is 0.02%; sulfur is a non-metallic 7L element which is indispensable for the alloy material, so the sulfur content is % 2%. According to this, through the above carbon, bismuth, manganese, chromium, nickel, bismuth, phosphorus, sulfur at the ratio of the ratio of the material, the remaining proportions are combined with iron as the base material; the alloy has excellent strength and high strength. Extensibility, anti-recording, etc., and more than 95% of the above alloy materials are ferrite-grained iron structures. There are still a small amount of carbides and fine Ma Tian loose iron, which makes the golf club head control ball. Sex is more advantageous than the golf club head made of traditional soft iron. Further, secondly, the above-mentioned alloy material composed of carbon, niobium, manganese, chromium, nickel, ruthenium, phosphorus, sulfur, and iron may be directly formed into a golf iron head by dewaxing or forging. In addition, 'the above-mentioned alloy materials composed of carbon, bismuth, manganese, chromium, nickel, strontium, phosphorus, sulfur and iron can add molybdenum (Mo) (maximum value) with the hardness required for the golf club head. For reinforcement rigidity. It is also possible to further refine the above-mentioned ferrite iron structure crystals to further increase titanium (Ti) 0.5% max or zirconium (Zr) 0.5% max or boron (B) 〇〇 〇〇 3% max. According to this, 'the above carbon, bismuth, manganese, chromium, nickel, antimony, phosphorus, sulfur, 200914086 iron, with a small amount of carbides and fine granulated iron, and miscellaneous, titanium one (or wrong or boron) The combined group combines the money to make it have excellent strength, south ductility, _ and ball control, and can be widely used in the manufacture of golf club irons, sand pits and putter club heads. . Therefore, the above-mentioned alloy material for golf club heads of the present invention is composed of several kinds of carbon, stone, bell, chromium, nickel, brocade, scale, sulfur and iron. Electroplating anti-recording, cost-saving, and will not cause environmental problems L and 95% containing trace amounts of Weiwu and fine Ma Tian loose iron ferrite, to increase the golf ball head ball control, and add material hardness of molybdenum It helps the crystal hardened titanium (or hammer or boron), and the alloy material produced has excellent strength, high ductility, rust prevention and ball control, making it a complicated and costly tradition. The technology is not only in line with the economic benefits of today's human gold material demand, but also has an absolute advantage in the industry. The above detailed description is specific to one of the possible embodiments of the present invention, but the embodiment is not intended to limit the present invention. The scope of the patents, the equivalent implementation or modification of the technical spirit of the invention, should be included in the patent scope of the invention. 200914086 [Simple description of the diagram] [Key component symbol description]