TW200906948A - Composition comprising metallocene polypropylene wax and carbon black - Google Patents

Abstract

The invention relates to compositions comprising metallocene polypropylene waxes with a dropping point and/or a softening point of from 70 to 130DEG C, and carbon black (CB), the compositions being in the form of masterbatches, compounds or conductive polymers, and their use for producing conductive polymers and articles made of conductive polymers.

Description

200906948 IX. INSTRUCTIONS OF THE INVENTION: TECHNICAL FIELD The present invention relates to a composition comprising a metallocene polypropylene wax and carbon black (CB) having a dropping point and/or a softening point of 7 (rc to 13 〇t). The composition is in the form of a parent mixture, a compound or a conductive polymer; and its use for producing a conductive polymer and an article made of the conductive polymer. [Prior Art] In the plastics industry, if often An additive in the form of a compound or a mixture of precursors. For the purposes of the present invention, the parent mixture is a composition comprising a carrier polymer and an additive 'wherein the additive is present in the parent mixture at a higher concentration than in the final application, and the carrier The polymer is generally not the final application polymer. The preferred concentration of the additive in the parent mixture is from 〇5 wt% to 9 wt%, more preferably from i wt% to 8 wt%, even more preferably 6 wt% to Within the range of 80% by weight, the weight % is the total weight of the parent mixture each time.

U. The compound of the present invention is a group comprising a polymer and an additive, wherein the additive is in the final concentration 2 of the final application or final product in the compound, and the polymer is the final application or the final The desired polymer of the article, such that the compound is formed into the desired shape of the final application or final article by only physical forming. The (four) 'conductive compound and the final product made of the conductive compound of the present invention are 10-6 ohms to 10 ohms, preferably 1 〇.5 ohms, m bauxite M·/ 吏 preferably 0,1 ohms. Surface resistance up to 1 〇 9 ohms. 13〇45〇.d〇c 200906948 Surface resistance is defined in accordance with DIN EN 03404] and is measured according to the ankle 6U40-2-3 if the test sample exhibits a size of at least 80 mm×l20 mm or a diameter of at least n〇mm . In the case where the test sample does not exhibit a size of at least 80 mm x 20 mm and does not exhibit a diameter of at least ιι (7), the surface resistance is based on IEC 93, with a flat sample of dimensions (10) mm MO mm and directly on the surface of the sample. The conductive silver coating was measured by a rectangular electrode having dimensions of a=4〇mm and b=3 mn^g=1(). Carbon black (10) containing as an additive, such as a parent mixture and/or compound for producing conductive fumarose, must meet stringent requirements: the compositions should have very low viscosity to produce good processability, which should have a high loading ^ ie high The CB concentration (characterized by weight percent of CB, unless otherwise stated, is based on the weight of the total composition) and should be possible to achieve the desired conductivity in the final article. Other requirements are: high thermal conductivity, good miscibility and phase in the final product of the parent mixture, and good dispersion of CB in the parent mixture and / or compound. ^ The mechanical and thermal properties of the final product, especially the minimal resistance to impact strength or thermal deformation. &Stretching Strong Conductive Polycarbonates are used to produce articles for use in areas or applications where there is a high risk of explosion; for the purposes of the present invention - are summarized as articles for use in explosion protection. Looking for it. . In addition, only conductive polyurenes can be electrostatically powdered by the object of the present invention, which will be referred to as electrostatic powder coating. . In addition, conductive polyhydrocarbons are used to produce packages that exhibit little electrostatic charge and are used, for example, in the packaging of electronic components. Conductive polyolefins are also used as bipolar plates for fuel cells. EP 244 626 A1 discloses cb in polymers. EP 1 777 258 A1 discloses the following composition in claim 1: Carbon nano reinforced (CNT) reinforced thermoplastic elastomer molding composition (9) (A) to (F), A) 5 weight ❶/. Up to 80% by weight of a mixture consisting of: A1) 1.1 Λ to 5% by weight (in eight) of a mixture consisting of: (8) 4.75 wt% to 95.25 wt% (by (4)) Cnt, and (a2) 95.25 wt% to 4.75 wt% (by (4)) of the salt of the water-soluble amphiphilic polymer, and A2) 50% by weight to 99.9% by weight (in terms of (eight)) a branched polymer (10) having a bimodal particle size distribution and consisting of (10): 40% by weight to 90% by weight of an elastomeric microparticle matrix (4) obtained by polymerizing the following materials, In terms of (a3): a31) 70% by weight to 100% by weight of at least one common dilute or at least potassium creatate crC8 alkyl ester, or a mixture thereof, a32) 0 to 30% by weight of at least one other mono-saturated unsaturated Monomer, and a33) 0 to 1% by weight of at least one polyfunctional crosslinking monomer; a4) 1% by weight to 6% by weight of the graft (4) consisting of the following: (a4): A41) 65 wt% to 95 wt% of at least one vinyl aromatic monomer, 130450.doc 200906948 a42) 5 wt% to 35 wt. /. Acrylonitrile, a43) 0 to 30% by weight of at least one monounsaturated monomer and "4" 〇 to 1% by weight of at least one type of polyfunctional crosslinking monomer; B) 20% by weight to 95% by weight of thermoplastic polymerization The substance (9), which has a viscosity value of 5 〇* to 12 〇, and is composed of the following: (B): Μ) 64% by weight to 81% by weight of at least an ethylene-based aromatic monomer , b2) 19% by weight to 36% by weight of acrylonitrile and b3) 0 to 30% by weight of at least one other monoethylenically unsaturated monomer; C) 0 to 5% by weight of thermoplastic polymer (C)' having 5 〇 ml / g to a viscosity value of V / 120 ml / g VN, and composed of the following, in (6): Chuan 62 weight. / to 81% by weight of at least a vinyl aromatic monomer, c2) 19% by weight Up to 38% by weight of acrylonitrile, and c3) 0 to 30% by weight of at least one other mono-saturated unsaturated monomer, wherein the viscosity values (4) of the components (8) and (C) differ by at least 5 units (_), or The acrylonitrile content differs by at least 5 units (% by weight), or the viscosity is at least 5 units different from the acrylonitrile content, and D) 0 to 50% by weight of the thermoplastic consisting of the following (9): Μ) 4% by weight to 96% by weight of at least a kind of ethylenic aromatic monomer, 4% to 96% by weight from methyl methacrylate, cis-succinic anhydride and butadiene At least one monomer consisting of a group of arsenic imines, and 〇 to a weight percent of acrylonitrile, wherein if present (9) is different from (8) and (c), E) 0 to 80% by weight amorphous or (semi) _ Crystalline Polymer and 130450.doc 200906948 F) 〇 to 50% by weight of additive (F). As mentioned above, 'known compositions cannot meet all current industrial needs. Need to meet current needs' and in detail have the required viscosity and load The CB precursor mixture is obtained in an amount to obtain the desired conductivity of the polyolefin. The parent mixture comprising the specific metallocene polypropylene wax and CB surprisingly exhibits improved properties. SUMMARY OF THE INVENTION Is composition Z comprising component a and component B, wherein § hai component A is a metallocene polypropylene wax having a dropping point and/or a softening point of 7 〇 to 13 ;; and the component B is carbon black Composition Z is preferably a parent mixture mb or a conductive polymer cP, wherein The electropolymer CP is preferably a conductive organic polymer. For the purpose of the present invention, the loading amount and specific surface resistance of the conductive polymer cp measured in the compression molded plate made of the conductive polymer cp are preferably smaller than Or equal to 130, especially preferably less than or equal to 12〇; the lower limit of each preferred upper limit of the LSSR is preferably ·15 _, especially preferably _1〇_, especially -ι_, especially -100, especially especially _1〇 Further, for the purpose of the present invention, the LSSR of the conductive polymer CP measured by the flat film made of the conductive polymer cp based on the ethyl bromide acetate copolymer is preferably less than or equal to (4), especially Preferably, it is less than or equal to (10), especially "at" or equal to 400, especially less than or equal to 300; the lower limit of each preferred upper limit of LSSR is -15 000 ', especially -10 000, especially -1000, especially - 100, especially especially _10. In addition, for the purpose of the present invention, the LSSR of the conductive polymer cp measured by a flat film made of a conductive poly-sigma CP based on linear low density polyethylene 130450.doc 200906948 is preferably less than or equal to 65. 〇, more preferably less than or equal to 385, or even more U is equal to or greater than 3 〇〇, the lower limit of each of the preferred upper limits of the LSSR is preferably .η just 'or better' 〇000 ' especially -1000, especially -100, Extremely especially -1 0. In addition, it is for the purpose of the present invention, by a conductive polymer based on polypropylene? The conductive polymer was measured by a flat film made of p. Preferably, the peach is less than or equal to 250, more preferably less than or equal to 2;; the lower limit of the preferred upper limit of the coffee is preferably 5 〇〇〇, especially preferably, especially, _1GGG, especially -100 Very special for _丨〇. The LSSR is calculated by the following method: the surface resistance (the logarithm of the absolute value of the ohmic illusion multiplied by the absolute value of the conductive polymer CP2CB loading (in % by weight), where the weight is % It is based on the total weight of the conductive polymer. Therefore, the 'afCB load of the board is reduced to 3% by weight and the surface resistance is 〇 〇 〇 5 5 5 5 ( ( ( ( 压缩 压缩 压缩The LSSR of the molded board is 135. Further, for the purpose of the present invention, the surface resistance of the conductive polymer CP measured by a flat film made of a conductive polymer cp based on ethylene-acetic acid ethylene-based copolymer or linear low-density polyethylene is preferred. Less than or equal to 9*, more preferably less than or equal to 9*105, even more preferably less than or equal to 9"〇4, especially less than: Ge is equal to 9*1〇3; the lower limit of each of the upper limits of the surface resistance is preferably 1Μ0· 5, more preferably 丨*^*, very especially 1>|51〇-3.

Further, for the purpose of the present invention, the surface resistance of the conductive polymer cp measured by a flat film made of a polypropylene-based conductive poly-human CP is less than or equal to 9*1〇8, as compared with I 130450.doc 200906948, More preferably, it is less than or equal to 9*ι〇7, and is preferably less than 9*106, especially less than or equal to 9*10, and the lower limit of the upper limit of the surface resistance is preferably "1〇·5, more preferably Very especially 丨*10-3. For the purposes of the present invention, a metallocene polypropylene wax is a polypropylene wax prepared in the presence of a pentylene metal as a catalyst. The special ability of the metallocene catalyst is used for synthesis selectivity. And a novel polypropylene wax with a new characteristic profile. It is impossible to accurately combine and control the melting point, viscosity and molecular weight of the polypropylene wax without using a metallocene catalyst. Further, the conventional polypropylene wax prepared without using a metallocene catalyst has Significantly higher than the dropping point and/or softening point of 13crc. The preferred metallocene polypropylene wax has a temperature of 4 1 / 3 * 5 to 80 000 mPa * s, preferably 45 (10) measured at a temperature of rc (7) 〇mPa s, especially good 5〇〇1?3*3 to 1〇〇〇〇mPa |fs, especially in the range of 5 〇 to 7000 mPa*s. Viscosity can also be determined at temperatures other than 17 〇 ti depending on the nature of the wax. Preferably, in the case of polypropylene wax, homopolymerized wax and copolymerization In the case of wax, the viscosity is measured at 17 (TC); preferably in the case of polyethylene wax, the viscosity is measured at 140 ° C. In addition, the metallocene polypropylene wax is characterized by the absence of metallocene catalysis. The synthetic mass of the lower synthetic salt is narrower than the molar mass distribution. The mass distribution of the molar mass is the mass average molar mass (Mw value [g/m〇i]) and the number average molar mass (Μη value [g/ Mole]. Preferably, Μη is from 500 g/mol to 5 〇〇〇〇g/m〇i, more preferably from 丨〇〇〇g/mol to 35 000 g/m〇l, even more preferably 11〇 〇咖〇1 to 25 _ 130450.doc 12 200906948 g/mol ° Preferably, Mw is 1000 g/m〇u14 〇〇〇〇g/m 〇b better i9〇〇g/mol to 100 000 g/ M〇l, even more preferably 21〇〇g/m〇i to 7〇〇〇〇g/mol 〇 preferably 'Mw divided by Μη, hereinafter referred to as Mw/Mn value, preferably 1.0 to 3.0, More preferably 1.5 to 2.9, even better It is from ι·7 to 2.8; especially from 2.1 to 2.7, more particularly from 2.2 to 2.5; and in the case of conventional non-metallocene catalyzed waxes, the 'Mw/Mn value is at least 3.1 and can be as high as 7 or 8. The pentylene metal propylene is a propylene-based homopolymerized fluorene or copolymerized wax. The metallocene copolymer wax is preferably derived from propylene and at least one, preferably one, two or three, more preferably one propylene different from propylene. Ra_CH=CH2' is more preferably derived from propylene and ethylene; wherein Ra is H or a non-branched or branched alkyl group. Further, the metallocene polypropylene wax prepared in the presence of a metallocene as a catalyst is preferably propylene and 0.1% by weight to 50% by weight of ethylene and/or 〇1% by weight to 50% by weight of at least one of 4 to 2% carbon. a copolymer wax of an atomic branched or unbranched chain 1-olefin, more preferably a copolymer wax of propylene and 01% by weight to 5% by weight of ethylene; wherein the weight % is based on the total amount of the raw materials, and the The metal polypropylene wax has a ratio of 70. (: to 130. (: the dropping point and/or the softening point in the range. More preferably, the ethylene is used in an amount of from 1% by weight to 4% by weight. /❶, even more preferably from 3% by weight to 3% by weight. Wherein the weight % is based on the total amount of the raw materials 'that is, the total amount of the olefins. The preferred metallocene polypropylene crucible has a dropping point of from 85 ° C to 100 ° C. The preferred metallocene polypropylene wax has a temperature of 85 ° C to 1 0 (softening point of TC. 130450.doc • 13· 200906948 better) metallocene polypropylene wax has a measurement at 17 (TC temperature) at 40 mpa s to 1 〇〇〇〇 claw ~ ~ The viscosity in the range and 7 〇. to 130C, preferably 85C to 1 〇〇. The dropping point of 〇, or, preferably, the softening point of 8 5 C to 10 0 ° C. The metallocene polypropylene wax is at 17 〇. The viscosity below determines the drop point or softening point and is used for characterization: preferably, at a viscosity of less than about 15 GG mPa*s, and at a drop point of 15 〇〇mPah or above 1500 mPa* The softening point is determined in the case of viscosity of s. The metallocene polypropylene prepared in the presence of the metallocene as a catalyst is much more or less amorphous than the metallocene and can be additionally used if necessary. The quality is such that, in accordance with the purpose of the present invention, it is largely meant to exceed the weight/%, preferably more than 9% by weight, especially more than % by weight;; in particular, more than 99% by weight, in In each case, the weight % is based on the total weight of the wax. The metallocene polypropylene is prepared by using the metallocene compound of the formula (1). \ / Μ乂(I) R2 R4 The compound of the formula (la), 130450.doc •14· 200906948 R6

Rio formula (lb) compound

R6

And a compound of formula (Ic)

130450.doc -15 - 200906948 In the formulas (1), (10) and (Ib), M1 is the periodic table of the metal, preferably titanium, wrong '铪, sharp, sharp, sui, chrome, pin: crane 'youjia 0 R1 and R2 are the same or different and each independently of each other is a hydrogen atom; c_c alkyl group, preferably cvc3 alkyl group, especially methyl group; * 1 L 1 G pit oxy group, preferably

Ci-C3 alkoxy; c6-C1 () aryl, preferably c c ^ ^ ^ 6 C8 square; C6-Cl. An aryloxy group, preferably a C6_M-based oxy group·(10) group, preferably a CVC4 group; a C7_C4° aryl group, preferably a C7_~aryl group; 7-~Hyunylaryl, C; c8.C4〇^^^, im, c8-c12^^; or a halogen atom, preferably a chlorine atom. R and R are the same or different and each independently of each other is a monocyclic or polycyclic hydrocarbon group which forms a sandwich structure with the central atom M1. Preferably, it is a cyclopentadienyl group, a benzyl group, a tetrahydrogen group, a benzindenyl group or a group, and the basic skeleton in the basin may have other substituents or be bridged to each other. Further, the group may be a substituted nitrogen atom, wherein r24 has the meaning of - and preferably is a mercapto group, a tributyl group or a cyclohexyl group. R5, R6, R7, R8, Ό 9 Smoke D 1 〇 ^ and the ruler are the same or different and each independently of each other is a hydrogen atom; a halogen atom, preferably a dimethoate, a fluorine or a bromine atom; c丨-〇: 10 alkane

Base, preferably cvq alkyl; Ca Γ A "丞, c6-Cl. aryl, preferably c6_c8 aryl; c 丨 alkoxy, fortunately CVC3 alkoxy; _NRl62, _SRl6, · 〇 · ΐ 6, a -SiR163 or -PR162 group, wherein r16 3 , ^ horse q-Cw alkyl, preferably CVC3 alkyl ' or C6-C' anthracene, is more or less than the Geganhan u C8 square group, or R6 ' R7 ' R8 > R9 ^ p 10 λ, ± or R with a carbon atom to which a Si_ or p_ group is attached

In the case of R, it may be a halogen atom, preferably a 5 6 7 1 horse atom, or two adjacent groups to form 130450. doc • 16-200906948 The preferred ligand is a basic skeleton cyclopentadienyl group, benzene. Substituted or thiol substituted compound Α, tetrahydrogen R R 3 is R17 I R17 Ri7 R>7 1 ~M2——l J 1 —Μ2—1 1 Μ2 I > 1 —M2 — CRi9 —- R>7~〇1 R18 1 R's 1 Ris 1 2 , R'« Ris RI7 I -c I R18 RP I Ο—ΜΜ]-- I -M2- R'7 Ring

R18 I

Ris R18 :so. View 17, =A1Rl7, _Ge-, _Sn_, ·〇...s_ =NR17, =c〇, =PRi7<17 times to 〇)R, where r17, rI8 or different and each independently hydrogen Original + ; pixel atom 'same chlorine or desert atom; C1 C h I ± ' preferred fluorine, 7卞' C丨-c3G alkyl, preferably c]_c4

Cl-Cio fluoro, preferably cF. , methyl '· 乂 乂 good CF3 group, c6_Ci 〇 fluoroaryl; C6-C1Q aryl, preferably e 轮佳五贶 benzo pregnant c6 -c8 square base, Cl_c]. Alkoxy C4 alkoxy, especially methoxy. Preferred C-- "' soil, 匚2-〇丨0 fine base, preferably c, C7-C4 aralkyl, preferably, ^^ 2 4 Alkenyl

CsC 7Cl〇M base 'C8-C44 base dilute base c8-c benzyl alkenyl; or C7_C4 〇 基 k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k The atoms form a ring. Diterpenoid, bismuth or tin, preferably ruthenium or osmium. R13 is preferably =CR, I, =SiR"Rl8, =GeRl7Rl8, _〇, _S0, =PR17 or =p(0)Rl7. -S-R, R12 are the same or different and independently have r17 One of the meanings. I30450.doc -17- 200906948 m and η are the same or different and each is 〇, preferably 〇 or 1, wherein m plus η is 〇, 1 or 2, preferably 〇 or 1 R14 and R15 are the same or different and independently have one of the meanings of R 7 and Rls. Preferred metallocenes are: • Bis(1,2,3-tridecylcyclopentadienyl) dichloride鍅, • bis(1,2,4-trimethylcyclopentadienyl) digasification, • bis(1,2-dimethylcyclopentadienyl) zirconium dioxide, • double (1 , 3-dimercaptocyclopentadienyl) di-gasification, • bis(1·methylindenyl)zirconium dichloride, • bis(1-n-butyl-3-methylcyclopentadienyl) ) gasification error, • bis (2-methyl-4,6-di-isopropyl) dichloromethane, • bis(2-methyl) zirconium dichloride, • double (4) -methylmercapto)digasification, •bis(5-methylindenyl)zirconium dichloride, •bis(alkylcyclopentadienyl)phosphonium dichloride, •bis (alkyl) Zirconium chloride, • bis(cyclopentadienyl) dichloromethane, • bis(nodot) zirconium dichloride, • bis (methyl sulphate) dichloride, • double (positive Butylcyclopentadienyl) dichloromethane, • bis(octadecylcyclopentadienyl)phosphonium dichloride, • bis(pentamethylcyclopentadienyl)phosphonium dichloride, • double ( Trimethyldecylcyclopentadienyl) ruthenium dichloride, 130450.doc -18- 200906948 • biscyclopentadienyl diphenylmethyl zirconium, • biscyclopentadienyl dimethyl hammer, • double tetrahydrogen Mercapto zirconium dichloride, • dimethyl decyl-9-g cyclopentadienyl ruthenium dichloride, • diterpene base based bis-trimethyl pure red county): chlorinated wrong, • dimethyl Bis-~1_(2,4-dimethylcycloerythrenyl) trichloride, • dimethyl decyl bis-(2-mercapto-4,5-benzophenidyl) dichloride Zirconium, • dimethyl decyl bis-1-(2-indenyl _4-ethyl) digastron, • dimethyl decyl bis-(2-mercapto-4-isopropyl Base group) bismuth hydride, • dimethyl decyl bis-1-(2-methyl-4-phenylphenyl) digastric hammer, • dimethyl decyl double -1-(2- methyl Dibasic) zirconium dihydride, • dimethyl fluorenyl bis-1-(2-mercaptotetrahydroindenyl) ruthenium dichloride, • dimercaptoalkyl bis-1,4-nodal dichloride , • dimethyl decyl bis-l- benzyl dimethyl hydrazine, • dimethyl decyl bis-1-tetrahydro benzyl di-hydrogenated hydrazine, • diphenyl fluorenyl-9-burial ring Pentadienyl di-vaporized hydrazine, • diphenyl fluorenyl bis-1 -phenyl dichloride, • ethyl bis-(2-mercapto-4,5-benzo-pyrene) Zirconium dihydride, • Ethyl bis-(2-mercapto-4-phenylindenyl) di-vaporized hydrazine, • Ethyl bis-(2-methyltetrahydroindenyl) Zirconium gasification, • Ethyl bis-(4,7-dimercaptodecyl) di-gasification, • Ethyl di--1-nodal di-vaporization, • Ethyl double-1 - tetrahydroindenyl zirconium dichloride, • mercaptocyclopentadienyl di-lead, 130450-doc -19- 200906948 • isopropylidene (i-nodal) (cyclopentadienyl) Mistakes, • isopropylidene (9· Li) (cyclopentane county) two gasification faults, • phenyl methyl stone Xiyuan base double small (2-methyl) dichlorination, and 5 Hai, etc. A hospital or aryl derivative of a metallocene dichloride. The Early One Active Center Catalyst System was activated by a suitable cocatalyst using the method #gj. Suitable cocatalysts for the metallocene of formula (1) are those having a (iv) compound m(tetra)-burning or no-lu system, such as R'NH"BR214, R'PH4 xBR2l4, R203 CBR214* br213. , \ is 1 to 4, the groups R20 are the same or different than 'identical' and each independently of each other is CrC, alkyl or c6-C18 aryl, or two groups R2Q and the atom to which they are attached - form a ring And the groups R21 are the same or different, and are more similar to each other, and each of them is independently a substitutable group, a halogen-based group or a fluorine-substituted 4-8 n6-C18 square group. In particular, R2 is ethyl, propyl, butyl or phenyl' and r21 is phenyl, pentafluorophenyl, 3,5-bisdifluorodecylphenyl, mesitylene, xylene Base or phenyl group. In addition, it is often the case that the third component (four) holds a chemical for the poisoning of polar catalysts, and the organic compounds of the bis-butyls and others, and mixtures of such compounds are suitable for this purpose. A supported single active site catalyst can also be used depending on the method. Preferably, it is a catalyst system in which the residual content of the supported material and the cocatalyst in the product does not exceed 1 〇〇 PPm. The metallocene polypropylene (IV) is a known material which can be prepared according to MW or EP 384 264 A1. Preferred metallocene 4 propylene (10) by using a metallocene catalyst dimethyl sulphur-based bis- phenyl dichloride, sulphur _ according to the method reported in EP 3 84 264 A 130450.doc -20· 200906948 The artichoke is prepared according to an example polymerization. The method of 16 allows the propylene to be co-formed with ethylene or it can be used in a fine particulate state, preferably in the form of sprayed or impaired particles. Further, it is preferred that the dropping point and/or the softening point is (10) to the grafted metallocene polypropylene. Preferably, the grafted metallocene polypropylene is a metallocene polypropylene modified with 0.5% to 10% by weight of cis-butanol needles based on the total weight of the shoulder material used. The component oxime preferably comprises 2, 3 or 4 different metallocene polypropylenes, more preferably 1 or 2 metallocene polypropylenes - and even more preferably yokes. * "Not otherwise deducted" or the texture_specific surface area is determined by the Brunauer Emmet Teller (BET) adsorption surface area measured using nitrogen according to M D3037; this surface area will be referred to hereinafter as the surface area resistance. CB usually exhibits intrinsic conductivity, However, CB also has a negative effect on the polymeric resin 'for example, mechanical properties are reduced. By using a special range of cb, high conductivity can be achieved at low loadings, which for the purposes of the present invention are referred to as conductive Carbon Black (CCB). CCB has a specific range of oil absorption values and a BET surface within a specific range, whereby it is different from the conventional CB. The preferred CCB has a measurement of 1〇〇mi/1〇〇§ according to ASTM D2414. 5〇〇ml/1〇〇g, better 150 ml/ioo g to 400 mi/1〇〇g, even better 17〇ml/1〇〇g to 350 ml/l〇〇g oil absorption (〇 An). 2 preferred CCB has 30 m2/g to 2000 m2/g, more preferably 5〇^仏 to ^(10) m2/g' or even better 6〇m2/g to 125〇m2/g, especially 65 _ to · 130450.doc 200906948 m2/g BET surface area. CB and CCB are preferably available from Cabot, Phelps Dodge, Timcal, Degussa and Akzo. Part B, preferably using one type of CB, but it is also possible to use more than one CB, preferably 1, 2 or 3 CBs, especially 1 or 2 different CBs. In addition, a combination of CB and CNT and/or graphite Or a mixture may also be used as component B. Preferred CNTs are single-walled carbon nanotubes (SWCNTs) or multi-walled carbon nanotubes (MWCNTs), of which MWCNTs are preferred. Preferred CNTs have a range of 50 m2/g to 1000 m2. / g, particularly preferably from 200 m 2 /g to 600 m 2 /g, especially from 260 m 2 /g to 5 60 m 2 /g of BET surface area. It preferably has from 2 to 50 carbon layers, especially from 3 to 15 carbon layers MWCNTs constituting the wall structure. Preferred MWCNTs have an average outer diameter of 1 nm to 500 nm, preferably 2 nm to 100 nm, especially 3 nm to 60 nm, especially 3 nm to 20 nm (defined as the median of the number distribution) There are various techniques and methods for producing CNTs which differ depending on the production method or the catalyst particles. This makes the (in particular) CNTs have different catalyst residual contents. Preferably, the residual catalyst content is 20% by weight or low. 20% by weight, particularly preferably 8% by weight or less, especially 5% by weight or less, especially 3% by weight or less % 2CNT, wherein in each case based on the total weight of the wt% of the CNT count. The CNTs disclosed in WO 2006/050903 A are preferred and are obtainable by the methods disclosed in the publication of the teachings of the Japanese Patent Publication No. 130450. Thus, the disclosure of this document describes the technical features of the disclosed methods for producing carbon too ‘especially, ... card s and claims i to ° which can be obtained by coughing the carbon nanotubes are incorporated herein. In a particularly clear manner, it is therefore preferred to decompose the gaseous state (10) by means of a (four) homogeneous catalyst comprising Mn, co and a supported material, and the Μ and Μ are in the form of a metal in the total amount of the active component. ear. It is said that the amount of mol% is present and, as the case may be, the heterogeneous catalyst additionally contains - particularly preferably: a carbon nanotube having a diameter of 3 to 15 为主 and using the catalyst; a light hydrocarbon in the form of individual or mixture (such as aliphatic hydrocarbons and olefins) are preferably used as starting materials, and the process is preferably carried out continuously or batchwise based on the introduction of the catalyst and the formation of the carbon nanotubes formed with the spent catalyst, and preferably the catalyst The main catalytically active component is introduced into the reaction space in the form of an oxide, a partial reduction or a complete reduction, or a hydroxide. More details of this method can be found in the specification of W〇 2〇〇6/〇5〇9〇3 A. In particular, the carbon nanotubes produced in this manner surprisingly result in a composition z having a low viscosity and at the same time a high loading; the desired conductivity is obtained in the polyolefin; and the surface resistance of the polyolefin is low become possible. It is preferred to use a CNT coated with a polyester or ethylene-ethylene acetate copolymer. The s-shaped coating is preferably applied by in-situ polymerization. It is especially preferred to be MWCNT coated with polyethylene and polypropylene, especially polyethylene.

It is preferred to use CNTs which are easily dispersed by modifying or activating the surface. A particularly preferred surface treatment for CNTs is by means of plasma or gamma light, of which MWCNTs are preferably plasma treated. 130450.doc -23 - 200906948 CNTs are preferably obtained from Mitsui, Arkema, Nanocyl, Thomas Swan & Co Ltd., CNI and especially Bayer Material Science AG. Preferably, one type of CNT is used, but one or more types of CNTs may be used, preferably 1, 2 or 3, especially 1 or 2 different CNTs. Preferred graphite has 30 g to 300 g of phthalic acid dibutyl vinegar (DBP) / 100 g ', preferably 4 § to 17 〇 g DBP / 100 g, especially 50 g to 150 g, according to DIN 53601 DBP/100 g DBP oil absorption. Preferably, the graphite has a BET surface area of from 1 μm to 5 Å m2/g, particularly preferably from i m2/g to 4 〇 m2/g ', especially from 1.5 m2/g to 30 m2/g. Naturally occurring graphite and synthetically produced graphite can be used. Graphite is preferably obtained from Timcal 'SGL Carb〇n or Nati〇nale Heart Graphite. Preferably, the weight of 1:19 to CNT and CB is preferably 1:99 to 99:1, especially 19:1, especially 1:9 to 1:1. It is especially preferable that the weight of 1:90 to CNT and graphite is 1:99 to Μ, especially 90:1, especially 1:85 to 1:1. It is particularly preferable that the weight of graphite and CB is from 1:99 to 99:1, especially 1:19 ’, especially 1〇:1 to 1:ι.

More preferably, 60 parts by weight of graphite, based on the weight of the total composition z.

I30450.doc •24· 200906948 1:1, especially 1:1〇 to l:1. In one embodiment of the invention, component B preferably contains both CB and graphite. In another embodiment of the invention, component B additionally preferably contains only cb, and is neither graphite nor CNT. The weight of the component A and the component B in the composition Z is preferably from 1:99 to 99:1, particularly preferably from 1:90 to 90:1, especially 丨:to. When component B contains neither graphite nor CNT, the weight of component A to component B in composition z is preferably from 1:1 to 1:5 〇, more preferably from 1:1 to 1:4 〇. , even better, from 1:1 to 1:35, especially from 1:1 to 1:2〇, more especially from 1:1 to 1:10. When component B contains CB, it also contains graphite and/or Or CNT, the weight of component A to component B in composition Z is preferably from 1:1 to 1:99, more preferably from 1:1 to 1.90, even more preferably to ι:85, especially 1: 1 to 1:5 〇, more particularly 1:1 to 1:40, and even more especially 1:1 to 1:35. Composition Z preferably contains a dispersing agent as the other component c. Particularly preferred dispersants are polar acid esters of long-chain alcohols, especially alkyl sulfonates, neoalkoxy titanates, neoalkoxy phthalates, monoalkoxy titanates, monoalkoxy zirconiums. Sodium oxime, and especially sodium alkyl sulfonate and sodium sulfonate. Composition Z preferably contains, as optional optional component F, a stearate, more preferably a stearate selected from the group consisting of calcium stearate and stearic acid. Component F preferably contains one or more stearates, more preferably one or two stearates, or even more preferably a stearate. The weight of component B to component F is preferably from 1:1 to 1:100, more preferably from 1:10 to 1:8, even more preferably from 1:30 to 130450.doc •25·200906948 1:70 The bismuth composition ζ preferably contains a polar or non-polar non-metallocene polyolefin wax or a metallocene polyolefin different from a dropping point and/or a softening point of 70 t to 13 (rc metallocene polypropylene wax, or both, Three 'four or five polar and/or non-polar non-metallocene polyolefin waxes or mixtures of metallocene polyolefin waxes having a dropping point and/or softening point of 70 to 13 (TC metallocene polypropylene wax) As other component D. The non-pentametal t-thin group is a polyolefin wax produced using a catalyst which is not a metallocene catalyst. The preferred non-metallocene polyolefin wax is ethylene or a high carbon having 3 to 1 carbon atoms. a homopolymer of 1-olefin or a copolymer thereof. Preferably, one or two polar and/or non-polar non-metallocene polyolefin waxes or one or two different from the dropping point and/or softening point are 70 ° C to 130 T: metallocene polypropylene wax metallocene polycarbonate pier. Μ non-metallocene polyene butterfly or different from the dropping point and / or softening point is 7 〇. The metallocene polyanthracene of the metallocene polypropylene pier of 130C is used as a component for the day of tr'. It is better to use a dropping point and/or a softening point of 7 〇. 匚 to 13 〇. Bad as group injury A, and 1 kind of non-metallocene polyolefin bismuth or 1 metallocene polyolefin wax different from dropping point and/or softening point of 70 ° C to 130. D. The preferred non-metallocene polysmoke is a polyethylene wax made of Ziegla Natta catalyst. Different from the point of dropping and/or the softening point of the metallocene polypropylene. Preferred metallocene polyolefin lanthanide is selected from the group consisting of metallocene polyethylene wax and dropping point 130450.doc -26- 200906948 or softening point higher than 13 (TC, more preferably 135 ° C to 17 (TC, even better 140 °) a group of metallocene polypropylene waxes of C to 170 ° C. These are different from the dropping point and / or softening point of 70. Metallocene polypropylene butterfly metallocene polyolefin wax of 〇 to 130 ° C can also be connected a metallocene polyolefin. Preferably, the grafting is carried out in an amount of from 5% by weight to 1% by weight of maleic anhydride based on the total weight of the raw materials used; more preferably, The branches are carried out on a metallocene polyethylene wax or on a metallocene polypropylene having a dropping point or a softening point higher than 130 ° C. Preferably, the dropping point and/or the softening point is 7 〇艽 to 〖3. 〇. The metallocene polypropylene wax of the metallocene polypropylene wax has a particle size of 5〇〇g/m〇l to 5〇〇〇〇g/mol, more preferably 1〇00 g/m〇i to 35〇〇〇g. /in 〇丨, even better 〇〇 / g / mol to 25000 g / m 〇 Μ η. Preferably, different from the dropping point and / or softening point is 7 〇. The metallocene polyolefin wax of the metallocene polypropylene wax of 丨3〇〇c has a 〇〇〇g/m〇l to 14〇〇〇〇g/mol, more preferably 19〇〇g/m〇i to Looooo g/m〇1, even better Mw of 21〇〇g/mol to 70,000 g/mol. Preferably, in the case of a metallocene polyolefin wax different from the metallocene polypropylene wax having a dropping point and/or a softening point, the Mw/Mn value is preferably from 1.0 to 3.0, more preferably from h5 to 2 9, Even more preferably 丨7 to 2 8; especially 2.1 to 2.7; more particularly 2.2 to 2.5. The non-metallocene polydihydrocarbene preferably has a weight average molar mass Mw in the range of from 丨〇〇〇 to 2〇〇〇〇g/mol and/or an amount ranging from up to 15,000 g/mol The average molar mass Μη. The weight of the component Α and the component D is preferably 1 〇: 1 to 1:1 〇, particularly preferably 4:1 130450.doc -27- 200906948 to 1:4, especially 3:1 to 1:3. The present invention further provides a composition Z which contains the organic polymer component P as another component in addition to the component A and the component B. Preferably, component P is selected from the group consisting of thermoplastic polycondensates, styrene polymers, polyamines, polyacrylates, polyacetals, polyadditions, polyolefins, polyolefin copolymers. And polyacrylate copolymer. Component P is preferably selected from the group consisting of thermoplastic polycondensates, particularly thermoplastic polyesters, especially polycarbonate (PC) 'polybutylene terephthalate (pBT) and polyethylene terephthalate (PET). Group. Component P is preferably selected from the group consisting of stupid ethylene polymers, preferably polystyrene (PS), styrene-acrylonitrile copolymer (SAN), acrylonitrile-polybutadiene-styrene graft polymer (ABS), and A group consisting of styrene-ethylene-butadiene-styrene block copolymer (SEBS). Component P is preferably selected from the group consisting of polyamines, particularly polyamido 46 (PA46, polyamido 6/6t (PA6/6T)), polyamido 6 (PA6), polyamido 12 (PA12) and poly A group consisting of indoleamine 6·6 (ΡΑ6.6). The component hydrazine is preferably selected from the group consisting of polyacrylates and polyacrylate copolymers, particularly polymethyl methacrylate (methylene) and copolymers of ethylene and methyl acrylate. The component hydrazine is preferably selected from the group consisting of polyacetal, particularly preferably polyoxymethylene (hydrazine). The component hydrazine is preferably selected from the group consisting of polyadditions, more preferably the polyadduct is a polyamino phthalate, particularly preferably a thermoplastic polyurethane elastomer (TPU). 130450.doc -28 - 200906948 Component p is preferably selected from the group consisting of polyolefins and polyolefin copolymers. More preferably, component p is selected from the group consisting of polyolefins, polyolefin copolymers and polyacrylate copolymers, and even more preferably polyolefin or polyolefin copolymers. When the composition Z is a conductive polymer CP, the component P is preferably a polyolefin or a polyolefin copolymer. The preferred polyolefin or polyolefin copolymer as component P is selected from the group consisting of: • polyethylene (PE), preferably high density polyethylene (HDPE), medium density polyethylene (MDPE), low Density polyethylene (LDPE), linear low density polyethylene (LLDPE), metallocene low density polyethylene (mLDPE) and metallocene linear low density polyethylene (mLLDPE), • Polypropylene (PP), preferably polypropylene homopolymer (PPH), polypropylene random copolymer (PP-R) and polypropylene block copolymer (PP-block-COPO), • polyolefin plastic, preferably 1-octene and ethylene polymer, and • PE copolymer, preferably ethylene-vinyl acetate copolymer (EVA), copolymer of ethylene-acetic acid ester (EMA), copolymer of ethylene and butyl acrylate (EBA), ethylene and Ethyl acrylate copolymer (EEA), cyclic olefin copolymer (COC); • preferably selected from the group consisting of: • PE, preferably HDPE, LDPE and LLDPE, • PP, preferably PPH, PP- R and PP-block-COPO, • Polyolefin plastic, preferably 1-octene and ethylene polymer, and • PE copolymer, preferably EVA And EMA. 130450.doc -29- 200906948 Composition z preferably contains a thermoplastic polymer, especially a copolymer of ethylene and methyl acrylate as the other component E. When it is desired to produce a composition Z containing a polymer selected from the group consisting of pc, PBT, PET, PS, SAN, ABS, PA6 or PA6.6 as component P, it is preferred to use the component £. Composition Z preferably contains from 0.1% by weight to 1% by weight. /. The sum of component A and component b, and 〇 to 99.9% by weight of other substances, preferably components C, D, E and/or F; wherein in each case the weight % is the total of the composition Z Weight; and the weight of component A and component B. The weight % of /〇 and other substances is always added up to 100% by weight. When S, 'and 5' Z is the parent mixture μ B 'the composition Z preferably contains 1% by weight to 100% by weight, more preferably 50% by weight to 1% by weight, even more preferably 7% by weight to 100% % by weight, especially 95% to 1% by weight, of the sum of component VIII and component hydrazine, wherein in each case the weight % is based on the total reset of the composition ,, more particularly the composition Ζ component Α and composition Β composition. When the composition Z is the parent mixture MB and the component B contains only CB and neither graphite nor CNTs, the composition Z preferably contains 3% by weight to 90% by weight, particularly preferably 5 parts by weight. Up to 5% by weight, in particular from 1% by weight to 4% by weight, in particular, from 〇% by weight to 35% by weight of component B, wherein in each case the weight. /. It is based on the total weight of the composition Z. When composition Z is the parent mixture MB, composition Z preferably contains from 6.0% to 90% by weight, more preferably from 7.5% to 90% by weight, even more preferably from 25% by weight to 90% by weight, especially 55% by weight. ❹/. Up to 90% by weight of component A, wherein in each case the weight % is based on the total weight of the composition Z. 130450.doc -30· 200906948 Composition z preferably comprises: 5% by weight to 90% by weight. Component p, 〇·1% by weight to 95% by weight of the sum of component a and component B, and optionally 0 to 94.95 by weight. /. Other substances 'better component c, D, E and/or F; and wherein the weight % of component A, component B and component p and the weight % of other substances are always added to 100 weight 〇 / 〇 , and the weight in which in various cases. It is based on the total weight of the composition z. Composition 2 particularly preferably contains from 1% by weight to 90% by weight. /. In particular, 12.5 weights 〇/0 to 90% by weight of component p, wherein in each case the weight % is based on the total weight of the composition z. § When the composition Z is the conductive polymer cp and contains the component p, the sum of the component a and the component B is preferably from 〇丨% by weight to 9% by weight, wherein in each case the % by weight is the composition Z Total weight. When the composition Z is a conductive polymer CP and the component b contains only CB and neither graphite nor CNT, the composition z preferably contains 〇丨% by weight to 丨5 by weight 〇/〇, even more preferably 0.5% ❶/ . Up to 12.5% by weight, especially i% by weight to 125% by weight, especially 2% by weight. /◦ to 12.5% by weight of component B, wherein in each case the % by weight is based on the total weight of the composition Z. Preferably, when composition Z is conductive polymer CP and component B contains only CB and is neither graphite nor CNT, composition 2 preferably contains from 1% by weight to 45% by weight, more preferably 2% by weight. Up to 4% by weight, even more preferably from 2.5% to 35% by weight, especially from 2.5% by weight to 3% by weight of component A, wherein in each case the weight % is based on the total weight of the composition Z. More preferably, when composition Z is a conductive polymer cp and component B contains only 130450.doc -31 · 200906948

When neither graphite nor CNT is present, the composition Z preferably contains 0.1% by weight to 15% by weight of the component B and 1% by weight to 45% by weight of the component A; more preferably 5% by weight to 12.5% by weight of the component B and 2% by weight to 40% by weight of component A; even more preferably 1% by weight to 12.5% by weight of component B and 2,55% by weight to 35% by weight of component A; especially 2% by weight to 12.5% by weight of component B and 2.5% by weight to 30% by weight of component A; wherein the weight in each case. /. It is based on the total weight of the composition Z. When the composition Z is a conductive polymer CP and the component b contains both CB and graphite, the composition Z preferably contains from 0.1% by weight to 5% by weight, even more preferably from 5% by weight to 12.5% by weight. In particular, from 1% by weight to 125% by weight, in particular 2% by weight to 12.5% by weight of CB, wherein in each case the % by weight is based on the total weight of the composition Z. Preferably, when the composition z is a conductive polymer CP and the component B contains both CB and graphite, the composition Z preferably contains 丨〇% by weight to 9% by weight, more preferably 15% by weight to 85% by weight. Graphite, wherein in each case the weight % is based on the total weight of the composition Z. Preferably, when composition Z is a conductive polymer CP and component B contains both cB and graphite, composition z preferably contains from 9% by weight to 89.9% by weight, more preferably from 3% by weight to 8% by weight. % component A, wherein in each case the weight % is based on the total weight of the composition Z. More preferably, when composition Z is a conductive polymer cp and component B contains 130450.doc -32-200906948 CNT also contains graphite, composition z has a content of 0.1% by weight to 15% by weight of CB and 1 weight. . /. Up to 89.9 wt% of component A; more preferably 55 wt% to 125 wt% CB and 3 wt%. /〇 to 80% by weight of component A; wherein in each case the weight % is based on the total weight of the composition Z. Especially when the composition z is a conductive polymer CP and the component b contains both cb and graphite, the composition z preferably contains 0.1% by weight to 15% by weight. /〇 CB and 1 weight. /〇 to 89.9 wt% of component A and 1 wt% to 9 wt% of graphite; more preferably 0.5 wt% to 12.5% wt% CB and 3 wt% to 80 wt%/〇 component A and 15 wt% Up to 85% by weight of graphite; wherein in each case the % by weight is based on the total weight of the composition Z. Composition Z preferably contains 〇. 1% by weight to 10% by weight, particularly preferably 〇丨% by weight

To 5 wt%, especially 0 5 wt% to 3 wt% of component c, wherein in each case the wt% is based on the total weight of the composition Z. The composition Z preferably contains from 0.1% by weight to 50% by weight, particularly preferably from 1% by weight to 40% by weight, in particular from 15% by weight to 35% by weight, of component E, wherein in each case the weight % is in the composition The total weight of Z. The invention further provides a method of producing composition Z, characterized in that component A and component B and any other components are physically mixed with one another. Mixing of the components can be carried out in one step or in a plurality of steps. Mixing commonly used in the industry: extruder, mixing device for physical mixing, can use plastic wins and splicing device's preferably selected from the group consisting of the following devices 130450.doc -33- 200906948 kneading machine, press, Injection molded chronograph and blade mixer. When composition 7 is the parent mixture MB, it is mixed with Dreams &曰人播二Γ Good for the machine, kneading machine and / 戍 blade w machine. Although the composition z is a conductive polymer, the mixing is preferably an extruder, a force machine and an injection molding machine, and particularly preferably a squeeze; the mixing is preferably continuous or batchwise, and the Yujiu construction continues. In the case of the parent mixed MB, it is preferable to carry out the pressing or kneading by the rolling pressure, especially by extrusion, and in the case of the conductive polymer CP, preferably by It is carried out by pressing or pressing, preferably by extrusion. The mixing is preferably carried out at a temperature of from 8 Torr to 300 °C. In the case of the matrix mixture chamber, the mixing is preferably carried out at a temperature of, in particular, to the temperature of 15 generations; in the case of a conductive polymer 〇>, the mixing is preferably in the 8th generation to the 3rd, especially Good (10). c to a temperature of 280 °C. The mixing time is preferably from 5 sec to 36 h, more preferably from 5 to 25 h, even more preferably from 5 sec to 1 〇 h. In the case of continuous mixing, the mixing time is preferably 5 h, particularly preferably 10 sec to 15 min. In the case of batch mixing, the mixing time is preferably from 1 min to i〇h, especially for melon to ^' especially for - to ... especially for hawthorn, especially for 2 mi η to 15 mi η. In the case of the conductive polymer CP, the component oxime and the component oxime are preferably mixed with the component ρ in the form of the parent composition MB. Further, a premix of the parent mixture mash and the granulated component P is preferably used in physical mixing. The invention further provides the use of composition Z for producing a conductive polymer cP or for use as a conductive polymer cp of 130450.doc-34-200906948. When composition Z is the parent mixture MB, composition Z is preferably used to produce a conductive polymer CP, particularly for producing a conductive polyolefin. When composition Z is a conductive polymer CP, composition 2 is preferably used to produce a conductive polyolefin or as a conductive polyolefin. When composition Z contains a component £, composition z is preferably used to produce a conductive non-polyolefin polymer or as a conductive non-polyolefin polymer. The production of a conductive poly-baked hydrocarbon from the composition Z, in particular the electrically conductive polymer CP, is carried out in a manner similar to that described above for the production of the composition 2, in particular the electrically conductive polymer CP, in a similar method step and process parameters. For the purpose of the present invention, the conductive material of the conductive material has a surface resistance of 1 〇 6 ohms to 10 ohms, preferably 1 〇 5 ohms to 10 ohms, especially 〇 1 ohm to 1 〇 9 ohms. The polymer. The group σ Z|sc is preferably used to produce or be used as an electrically conductive polymer suitable for explosion protection and/or an article made of a conductive polymer. The guide: preferably used to produce or be used as an article which can be coated with a conductive conductive material by electrostatic powder coating and/or made of a conductive polymer. The composition Ζ is preferably used in a package for producing a carrier rate or as a compound which produces almost no static charge. For the purposes of the present invention, there is almost no charge 乂 乂 忍 忍 1 1 〇 6 ohms, especially ... to...: Table: ': Good 1. , ..., (10) What is the electrical charge rate of the initial charge between the electrostatic discharges according to Dm En

61340-2-1 measurement. S40·5-1 is defined and according to DIN EN 130450.doc -35- 200906948', and σ substance z is preferably used for producing or as a conductive polymer which can be used as a bipolar plate in a fuel cell, preferably conductive poly Olefins. In addition, the composition z is suitable as an additive in a polymer or as a polymer 'especially for mechanical reinforcement and for increasing electrical conductivity, and also as a material for gas and storage therein' for coloring and for flame retardancy The agent is used as an electrode material or for generating a conductor track (ec) ndue (10) plus (8) and a conductive structure and as an emitter in a display. Composition 2 is preferably used or used as a polymer, ceramic or metal composite for improving electrical conductivity or thermal conductivity and mechanical properties for use in or as a conductive coating and composite, as a colorant for batteries Cold plagiarism, display (such as a flat screen display) or phosphor, used as a power system, used as a storage medium for, for example, hydrogen or a clock, for use as a film of, for example, a purified gas Catalyst or as a supporting material for, for example, a catalytically active component of a chemical reaction, for use in a fuel cell, for use in the medical field, for example as a framework for controlling the growth of cellular tissues, for use in the frequency domain, for example as a marker, and for For chemical and physical analysis (eg for use in atomic force microscopy); for the production or use as a conductive polymer suitable for bursting, for explosion protection, and/or articles made of conductive polymers, and or for use as The colored conductive polymer and/or the article made of the conductive polymer can be coated by electrostatic powder. It is used to produce or be used as a package for producing a hand-conducting polymer, exhibiting a charge rate, for producing or for use as a fuel cell. Port 130450.doc • 36· 200906948 Composition z may contain other components, preferably * colorants 'where organic and inorganic dyes and pigments may be used as colorants; for organic pigments, azo or diazo pigments are preferred, Coated azo or diazo pigments or polycyclic pigments, preferably polycyclic pigments are diketopyrroloxime, phthalocyanine, quinacridone, anthracene, dioxazine, anthracene, thioindigo, diaryl Base or quinophthalone pigment; for inorganic pigments, it is preferred to use a metal oxide suitable for coloring, a mixed oxide 'aluminum sulfate, a chromate, a metal powder, a pearlescent effect pigment (mica), a luminescent pigment, titanium oxide, cadmium - lead pigment, iron oxide, agglomerate, nickel titanate, cobalt pigment or chromium oxide; • fillers such as vermiculite, zeolite, citrate, such as aluminum citrate, sodium citrate 'calcium citrate, White peony, talc; • Auxiliaries, preferred blowing agents, nucleating agents, peroxides, antioxidants; • Antistatic agents, preferably glyceryl stearate, glyceryl monostearate, alkylamine, B Oxylated alkylamine, daunyl acid, glycerin Or mixtures thereof (blends); • UV absorbers and hindered amine light stabilizers (HALS) compounds, slip agents, antifogging agents, anti-condensing agents and/or suspension stabilizers, flame retardants; antioxidants or other Conventional plastic additives; • or a mixture of the above. The composition in the form of a parent mixture MB or a conductive polymer CP is surprisingly characterized by a low viscosity which can be obtained simultaneously with a high CB loading; in particular, a parent mixture MB of up to 20 can be achieved. % by weight, even 130450.doc • 37- 200906948 up to 25% by weight, in many cases even up to 5% by weight and sometimes even higher CB loading, where % by weight is based on the total weight of the parent mixture mb The viscosity does not deteriorate so that the precursor mixture MB is no longer produced and processed, or the parent mixture is not formed at all; in addition, the desired conductivity and the desired low surface resistance are obtained in the conductive polyolefin. High solids content and low viscosity make it less expensive to introduce additives into the polymer; it also minimizes wear on the mold and makes it possible to quickly homogenize and evenly distribute CB. In Composition Z, CB is well dispersed and/or distributed in the parent mixture and/or composition. The quality of the dispersion and/or distribution is qualitatively determined by optical means on a pressed (compression molded) sheet or film (e.g., using a section), and is further high. The dispersion and/or distribution of the gradation is such that the standard deviation of the surface resistance measured at different locations of the sample is low, and the standard deviation is usually determined by selecting one position. The fluidity, impact toughness, heat distortion temperature (i.e., deflection temperature under load), and tensile strength also meet the requirements. Viscosity or flowability is determined according to DIN ISO 1133 and is expressed as the melt flow rate MFR. The impact toughness is determined according to DIN EN IS〇. 'The heat distortion temperature (ie the deflection temperature under load) is determined according to din en ISO 75-1' The tensile strength is determined in accordance with DIN εν ISO 527-1. Other test methods: Unless otherwise specified, product characteristics are determined by:

Molecular distribution, ie Mw, by gel permeation chromatography (GPC) according to DIN 55672, but at a temperature of 135 ° C and in the solvent 1,2-dibenzene (where the wax is completely dissolved) And determination of Μη value; calibration using commercially available PE standards. 130450.doc -38 - 200906948 The dropping point (...) was measured according to DIN 51801/2 using an Ubbelohde dropping point meter. The ring/ball softening point was determined according to DIN ΕΝ 1427 (°c). Unless otherwise stated, for the sake of precision, if the softening point is given in integer form in the specification or patent application, it stands for "〇〇c", for example "130°〇" represents "130.0° (:". Determination of soil viscosity (mpa*s) according to DIN 53018. Density according to ISO 1183 (g/cmq. Determination of molar mass (GPC) by gel chromatography. Volume determined by DIN EN ISO 60 Density (kg/m3) The saponification value (mg κΟΗ/g) was determined by ISO 3 68 1. The acid value (mg KOH/g) was determined by ISO 2114. The modulus of elasticity was determined by DIN EN ISO 527-1 ( MPa;). Determination of vinyl acetate content by Fourier transform infrared spectroscopy (Fourier_Transf〇rmati() ns_IR-Spectroscopy (FTIR)), calibrated using commercially available EVA-standards. Determined by atomic absorption spectrometry (AAS) The metal content was calibrated using commercially available metal standards. The ash content was determined by annealing the residue at 900 ° C for 60 min in a muffie furnace. By laser diffraction Mastersizer 2000, Fa. Malvern Determine the d50 value. Sample preparation: a small amount (about 0.5 g to 3 g The sample was ultrasonically treated for 5 min and suspended in a solution of 0.5 ml Arkopal N 090, 3 drops of isopropanol and 2 μl of water. 130450.doc -39- 200906948 Method for determining surface resistance SR-1 is based on DIN ΕΝ 61340-2-3. Method for determining surface resistance SR-2 is based on IEC 93. Melting point measurement method: Scanning calorimetry (DSC) according to IS〇3 1 46. Extruder torque [Nm] and extrusion The melt pressure of the handpiece is measured on the machine and is a measure of the viscosity or fluidity of the melt in the extruder. [Embodiment] Materials used in the examples: Component A1: Polypropylene metallocene polyolefin wax , which has a viscosity of 1700 mPa*s to 1900 mPa*s measured at rc, 85 (a softening point of 3 to 88 〇C, a value of Μη of 6700 g/mol, and a Mw value of 15500 g/mol) , 2, 3

Mw/Mn value and density from 0.86 g/cm3 to 0.89 g/cm3. Component A2: Polypropylene metallocene polyolefin wax having a viscosity of 190 mPa*s to 210 mPa*s measured at i7〇°c, a dropping point of 88°C to 93°C, 2900 g/mol Μ η value, Mw value of 6400 g/mol, 2.2 g/m〇i

Mw/Mn value and density from 0.86 g/cm3 to 0.89 g/cm3. Component B1: CB having an oil absorption value (〇AN) per 320 ml/l 〇〇 g and a BET surface area greater than 700 m 2 /g. Component B2: MWCNT' is produced by decomposing gaseous smoke via a heterogeneous catalyst comprising Mn, Co and a supported material, wherein Co and Μη are in the form of metal in an amount of 2 mol based on the active component content. % to % mol% is present 'and optionally contains Mo, and these MWcNTs have an average outer diameter of 10 nm to 16 nm (defined as the median value), from 130450.doc -40- 200906948 3 The wall structure composed of up to 15 carbon layers 'less than 6% by weight of the residual catalyst contains a length of f '1 micron to 10 microns and a bulk density of 15 〇 kg/m3 to 350 kg/m3. Component B3: Synthetic graphite having a DBP oil absorption value of 52 g of dibutyl phthalate (DBP) / 100 g and a BET surface area of 3 m2 / g, measured according to DIN 53601. Component B4: CB having an oil absorption value (〇an) of 70 ml/10 〇 g. Component C1.C! 2_c 18 alkyl sodium sulphate having an active substance content of at least 9 〇 by weight based on the total amount. Component D1: a non-polar polyethylene butterfly homogenate produced using a Ziegler-Natta catalyst having a viscosity of 640 mPa*s to 660 mPa*s measured at 14 ° C, between n7 The dropping point in the range of 〇c to i22ac, the density of 〇92 g/cm3 to 0.94 g/cm3 (measured at 2〇. under the )), the acid value of KOH/g, Μ 1800 g/m〇l The value is a Mw value of 5600 g/mol, a Mw/Mn value of 3.1, and a saponification value of 〇mg KOH/g. Component D2: a non-polar polyethylene weak homopolymer produced using a Ziegler-Natta catalyst having a viscosity of 280 mPa*s to 320 mPa*s measured at 14 °C, between 127 The drop point from 〇c to i32〇c, 密度.96 g/cm3 to 0.98 g/cm3 (measured at 2 (rc), 〇mg K〇H/g, 1600 g/ The η value of mol, the Mvv value of 4800 g/mol, the Mw/Mn value of 3.0, and the d50 value of 7.0 micron to 9.8 micron. Component D3: the polyethylene terephthalene polyolefin modified by maleic anhydride, It has a viscosity of 130 mpa*s to 150 mPa*s measured at 140 °C, a dropping point of 122C to 125C, and a density of 〇·97 g/cm3 to 1.00 g/cm3, 130450.doc -41 - 200906948 Μ value of 1200 g/mol, Mw value of 3000 g/mol, Mw/Mn value of 2.5 and acid value of 17 mg KOH/g to 19 mg KOH/g. Component D4: partially saponified lignite wachs, It has a viscosity of 280 mPa*s to 340 mPa*s measured at 120 ° C, a dropping point in the range of 96 ° C to 104 ° C, and a density of 0.99 g/cm 3 to 1.04 g/cm 3 (at 20 °) Measured under C), acid value from 9 mg KOH/g to 14 mg KOH/g and soap from 108 mg KOH/g to 115 mg KOH/g Component FI: Zinc stearate having a metal content of 11% and a melting point of I20t. Component F2: calcium stearate having an ash content of 1% by weight and a melting point of 155. Component P1: Polypropylene block copolymer (PP·block-COP〇) having a MFR of density of 4 g/l〇min of 0.90 g/cm 3 and an elastic modulus of 1200 MPa. Component P3: ethylene-vinyl acetate Copolymer (EVA) having a MFR of 7952 g/cm3 density of 7 g/10 min (measured at 190 〇C/2.16 kg) and a vinyl acetate content of 27.5% by weight in terms of EVA. P4: Linear low density polyethylene (LldPE) with a density of 0.90 g/cm3 'i_〇g/i〇min MFR (measured at 19 (rc/2 16 kg) and an elastic modulus of 80 MPa) Component P5: PPH having a density of 0.91 g/cm3, an MFR of 120 g/l 〇min (measured at 230 ° C / 2.16 kg) and an elastic modulus of 1450 MPa. Unless otherwise indicated, % by weight referred to hereinafter is based on the total weight of the mixture or article; parts are parts by weight; "ex" means instance, 130450.doc •42·200906948 "cpexn means comparison Example; "T-Extr" shows the temperature of the extruder (°C); "CB-L" means "load of carbon black" and is the content (% by weight) of CB, wherein the weight % is the composition Total weight. Ex or cpex 1 to 15 The various components of the examples were homogenized together on a twin-screw extruder to obtain the corresponding parent mixture, and the details and results are given in Tables A and B. For Example 15 for the production of MB15, 25 parts of component A1, 50 parts of component B4, 12.5 parts of component D4 and 12.5 parts of component F2 were used, and T-Extr was 100 ° C to 160 ° C.

Table A ex Parent mixture T-Extr Component used [parts] rci A1 B1 D1 D2 F1 P1 P3 P4 1 MB1 100 to 160 50 25 15 8.5 1.5 — --- — 2 MB2 140 to 190 54 20 16 8.5 1.5 -- - — — 3 MB3 140 to 190 36.5 15 7.5 4 0.5 36.5 — 4 MB4 140 to 190 6.5 15 7.5 4 0.5 ___ 66.5 — cpex5 MB5 200 to 230 — 15 — --- — 85 — cpex6 MB6 200 to 230 a 25 — — — 75 cpex7 MB7 200 to 230 —- 25 9.0 5.0 1.0 --- 60 8 MB8 200 to 230 7.5 25 9,0 5,0 1,0 — 52.5 9 MB9 200 to 230 12.5 30 — — — — — 57.5 cpex10 MB10 220 to 230 — 15 — an 85 — --- 11 MB11 100 to 160 75 25 — — — — — — — cpex12 MB12 — — — 25 75 — — — — — cpex13 MB13 200 to 230 —— — 30 12.5 ——— —— --- — 57.5 14 MB14 200 to 230 6.25 30 6.25 — --- ... 57.5 130450.doc -43 - 200906948 Table B ex CB-L MFR Parameter MFR Result Parent Mix [% by weight] "°C/kgl [g/10 mini 1 MB1 25 190/10 16 2 MB2 20 190/10 > 100 3 MB3 15 190/10 > 100 4 MB4 15 190/10 40 cp Ex5 MB5 15 190/10 8 cpex6 MB6 25 230/21.6 5.5 cpex7 MB7 25 230/21.6 6.0 8 MB8 25 230/21.6 8 9 MB9 30 230/21.6 0.2 cpex10 MB10 15 ... ... 15 MB15 50 190/21.6 28 11 MB11 25 230/21.6 > 100 cpex12 MB12 25 --- --- cpex13 MB13 30 230/21.6 1.96 14 MB14 30 230/21.6 1.6 MB5 is extremely hard and difficult to distribute in polymers. MB 10 and MB 12 are extremely fragile and difficult to granulate or produce on conventional parent mixture equipment because no particles are formed. Use a conventional premix. Ex or cpex 51 to 55, 63 to 65 and 71 to 75

The various components in the examples were premixed with component P3 in a tumble mixer and mixed and homogenized in a Brabender single screw extruder with a mixing zone, T-Extr of 130 ° C to 150 ° C, The details are given in C. A flat film of 1 mm thickness was obtained by extrusion through a flat film die. The flat membrane was placed under conditions of 23 ° C and 50% relative humidity for at least 24 hours. The measured values are given in Table C. 130450.doc 44- 200906948 Table C Ex Components used [parts] CB-L SR-1 LSSR MB1 MB2 MB3 MB4 MB5 P3 ί weight%] [ohm] 51 30 --- ___ ... 70 7.5 1*10" 619 52 ... 37.5 ——— ___ ___ 62.5 7.5 7*105 329 53 --- - one 50 one·_ 50 7.5 3*106 364 54 — — 50 ... 50 7.5 5*10" 658 cpex55 - one ___ 50 50 7.5 5*1012 714 63 one --- 58.3 • ring ___ 41.7 8.75 5*1〇3 283 64 --- — 58.3 41.7 8.75 8*103 299 cpex65 --- --- — —— 58.3 41.7 8.75 Γ2*1〇9 712 71 40 --- • er· _____ ... 60 10.0 2*1〇4 430 73 66.7 ... ____ 33.3 10.0 5*103 370 74 — ---- ——— 66.7 ___ 33.3 10.0 2*1〇3 330 cpex75 — — — 66.7 33.3 10.0 1*1〇7 700 ex or cpex 81 to 85, 91 to 95 Premix the various components of the example with component P4 in the tumble mixer and Mixing and homogenizing in a Brabender single-screw extruder with mixing zone, T-Exti^19 (TC to 200〇c, given in the table). 1 mm thickness is obtained by extrusion through a flat film die Membrane. Place the flat membrane at 23. (: and 50% relative Article degree of DU

At least 24 hours under the taste. The measured values are given in Table D.

Ex used for 1 MB6 MB7 MB8 MB9 MB11 P4 cpex81 30 --- —— — 70, cpex82 --- 30 — — ... 70 83 — --- 30 ___ • Police · 70 84 — — _ 25 75~ 85 — --- ___ 30 —— 70 cpex91 40 --- ——— ... 6Γ 93 — — 40 ... 60~ 94 — --- ... 33.3 66.7 95 — — — 40 6 (Γ 130450.doc •45·200906948 ex or cpex 101, 102 and 103 The various components of the examples were premixed with the component PI in a tumble mixer and mixed in a Brabender single screw extruder with a mixing zone and Homogenization, T-Extr is 240 ° C to 250 ° C, the details are given in Table E. A flat film of 1 mm thickness is obtained by extrusion through a flat film die. The flat film is placed at 23 ° C and 50%. Under normal humidity conditions for at least 24 hours. The measured values are given in Table E. Table E Ex Components used [parts] CB-L SR-1 LSSR MB1 MB10 MB15 P1 [% by weight] [ohm] 101 20 — — 80 5.0 4*107 190 cpex 102 — 33.3 — 66.7 5.0 3*1〇" 287 103 --- --- 30 70 15 1200 693 cpex 121 and 122 Put the various components of the example together on a twin-screw extruder Homogenized The parent mixture is obtained; the details are given in Table F. Table F ex Parent mixture T-Extr Component used [parts] rci A2 B1 B2 B3 C1 D3 P5 cpexl21 MB121 230 to 260 — 5 78 — — 17 cpex122 MB 122 100 to 130 78 — 20 ___ 2 — — The parent mixture MB 1 21 is extremely brittle and difficult to granulate. The parent mixture MB 122 is not brittle and can be easily granulated. ex or cpex 133, 134 and 135 The various components in the examples are Mixed and homogenized in a Brabender single screw extruder with mixing zone, T-Extr from 260 ° C to 275 ° C, in all experiments Brabender single screw extruder speed was constant at 80 revolutions per minute; Extruded through a flat film die to obtain a 1.5 mm thick plate; in Table G, 130450.doc -46- 200906948

Details D Table G Ex plate used [parts] Torque melt pressure SR-2 MB121 MB 122 fNml [bar] [ohm] cpexl33 EP133 100 — 44.0 185 0.99 134 EP134 95 5 29.0 101 0.70 135 EP135 90 10 25.0 90 0.59 130450.doc -47-

Claims (1)

200906948 X. Patent Application Range: 1. A composition Z comprising component A and component B, wherein the component A is a metallocene polypropylene wax having a dropping point and/or a softening point of WOt, the dropping point system By using an Ubbelohde dropping point meter according to DIN 518 〇 1/2 敎, and the softening point is determined by using a ring/ball according to DIN ΕΝ 1427; and the component Β is carbon black. The composition of π1, wherein the metallocene polypropylene wax has a dropping point of from 85 ° C to 100 ° C. 3. The composition z of claim 1 or 2, characterized in that the metallocene polypropylene wax has a softening point of from 851: to 1 Torr. 4. The composition z according to one or more of items 1 to 3, characterized in that the metallocene polyolefin wax has a measurement at a temperature of 17 (rc) ranging from 4 〇 mPa*s to 80 000 mPa* The viscosity in the range of s, which is determined by 53〇i8. 5. The composition z of one or more of items 1 to 4, characterized in that the carbon black has a size of 30 m2/g to 2〇00 M2/giBET surface area, which is measured using nitrogen according to ASTM D3 037. 6. Composition z according to one or more of claims 5 to 5, characterized in that the carbon black has a concentration of 100 ml/100 g to 500 ml An oil absorption value of /100 g, which is measured according to ASTM D2414. 7. A composition z according to one or more of claims 1 to 6, characterized in that the weight ratio of the group A to the component β is 1 : 99 to 99: 1. 8. The composition z of one or more of the claims 丨 to 7 is characterized in that the group 130450.doc 200906948 compound z contains 0-1% by weight to 1 〇〇 weight ❶ / ( The sum of the component A and the component B' and the weight of 99.9 by weight. Other substances; wherein in each case the weight ❶ / is based on the total weight of the composition Z; The weight % of component A and component B and the weight % of other substances are always added to 1% by weight. 9. A composition z of one or more of items 1 to 8 characterized in that the composition Z The organic polymer is contained as the other component p. I. The composition z of claim 9, wherein the component p is selected from the group consisting of thermoplastic polycondensate, styrene polymer, polyfluorene. Amine, polyacrylate, polyacetal, polyaddition, polyolefin, polyolefin copolymer and acrylate-derived copolymer Q II · Composition 9 or 1 〇 composition z, characterized in that Composition z comprises from 5% by weight to 9% by weight of component p, from 1% by weight to 95% by weight of the sum of component A and component B, such as claims 1 to 8 As defined in the first or more, and as the case may be up to 94.95 wt% of other substances; and wherein the weight % of component A, component B and component p and the weight % of other substances are always added up to 100% by weight, and Wherein in each case the weight % is based on the total weight of the composition Z. 12. One of claims 1 to 11 A plurality of compositions z, characterized in that the composition Z contains a dispersing agent as the other component c. 1 3 _ a composition z of one or more of claims 1 to 12, characterized in that the group 130450.doc 200906948 The substance z contains a copolymer of ethylene and methyl acrylate as the other component e. 14. A method of producing a composition 2 of one or more of claims 1 to 13, characterized in that the component eight and the group Pure and any other components are physically mixed with each other. A method of producing composition z according to claim 14, characterized in that a device selected from the group consisting of the following devices is used as a mixing device for physical mixing, an extruder, a kneader, a press, an injection molding machine, and a blade. Mixer. 16. The method of making composition z of claim 14 or 15, wherein the mixing is at 80. (: to 300. (At a temperature of 3. 17. The method of producing composition z according to one or more of claims 14 to 16, characterized in that the mixing time is from 5 seconds to 36 hours. Use of the composition Z of claim 1 to 13 or more, which is used for the manufacture of a conductive polymer CP or as a conductive polymer cp. 19. Use of a composition z as one or more of the claims β13 Used as an additive in polymers or as a polymer, especially for mechanical reinforcement and for increasing electrical conductivity, also as a material for gas and energy storage for coloring and as a flame retardant, for use as a flame retardant Electrode material or polymer for use in conductor tracks and conductive structures and as emitters in displays, for use in or as a polymer, ceramic or metal composite material for improved electrical conductivity or thermal conductivity and mechanical properties. Or as a conductive coating and composite: using the author's color reagent for batteries, condensers, displays (such as flat-screen displays) or phosphors, as field-effect transistors, as storage media, for film use Catalyst or as a supporting material, Fuel cell, using 130450.doc 200906948 in the medical field, for the field of diagnosis, B mu and for chemical and physical analysis 'for the manufacture or use of articles made of conductive polymers for knives suitable for explosion protection, Used in the manufacture or production of polymers, and/or in the form of <RTI ID=0.0>>> Producing a conductive polymer that exhibits almost no static charge buildup' for use in the manufacture or use as a conductive polymer that can be used as a bipolar plate in a fuel cell, preferably a conductive polyolefin. 130450.doc 200906948 VII. Designated representative map · (1) The representative representative of the case is: (none) (2) The symbol of the symbol of the representative figure is simple: 8. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: (none) 130450.doc