200904868 九、發明說明： 【發明所屬之技術領域】 树明為提供-種具高效率釋放負離子 體之製造方法’該方法係在電氣石粉體添加—預定= 碳系粉體，即能發揮相乘的釋放負離子和除臭與= 多功能效果；該製造方法簡易迅速、易大量生 具產業應用價值。 極 【先前技術】. 按’竹碳是具有超大表面積的多孔性材料， 極強的吸附力’同時也具有除臭和釋放負離子的功 ，效率隨竹碳的粒子大小有關，但是也有限制；而電氣 能 同 士’又稱碧1的天然礦物，具有釋放貞離子的功能 w其釋放負離子的功能，也有相同的極限。 然而利用該天然礦物藉以釋放負離？之相 =獻’有如：美國專利簡49 β卜咖72術、 US5967207 > US6509294 > US6449990 ^ US6475513 Μ200904868 IX. Invention: [Technical field of invention] Shuming provides a method for producing a high-efficiency release negative ion body. This method is added to tourmaline powder-predetermined = carbon-based powder, which can play a phase The release of negative ions and deodorization and = multi-functional effect; the manufacturing method is simple and rapid, and easy to produce a large number of industrial applications. Extreme [Prior Art]. According to 'Bamboo carbon is a porous material with a large surface area, extremely strong adsorption' also has the function of deodorizing and releasing negative ions. The efficiency depends on the particle size of bamboo carbon, but there are restrictions; Electric Energy Tongshi's natural mineral, also known as Bi-1, has the function of releasing strontium ions, and its function of releasing negative ions has the same limit. However, using this natural mineral to release the negative separation? The phase = offer is as follows: US Patent Jane 49 Beta Bu 72, US 5967207 > US6509294 > US6449990 ^ US6475513 Μ
，_92_專利案之主要技術内容：‘露 種製造竹碳摻合鹽基材料的方法。 该US5972467專利案之主要技術内容在於揭露— 種^造竹纖料的方法包含：利職力將竹管分裂成均 勾早獨分開之竹片；彻熱溫度充分消滅竹片内的昆蟲 蛋；利用樹及點膠舰合竹片形成杯狀器材。 'US5967207專利案之主要技術内容在於揭露__ 片成威尼斯窗簾的方法，該方法係將竹 切開後’進行漂白氧化，最後製成窗簾。 200904868 該US6509294專利案之主要技術内容在於揭露一 種做成除臭抗菌之食物贿及_崎，以竹碳加 氣石摻入黏合劑成為載體，再並加入至少一種如 chitosan、竹醋、conke]： acid形成不織布。 〇 泫隨49990專利案之主要技術内容在於揭露— 種置於洗衣_之_彡淨化容器，戰錢内之 脂及辦污^化容器，其淨化容器㈣無機材料為 Bmclon木奴和電氣石礦石比例大約75:25和95:5， 該淨化容H外表為輕f化之天錄膠或合成橡膠。 ;該US6475513專·之主要技術内容在於揭露一 種護膚膠囊其賴，賴膚職其職内容物含有碳化 ，及水轉狀魏劑，可肖郷職膚去肖質及吸收水 以上所述之習知專利，其所揭露之技術内容， 與本案此次所要申請之專利技術内容有相當之差, _92_ The main technical content of the patent case: ‘The method of making bamboo carbon blended salt-based materials. The main technical content of the US 5,972,467 patent is to disclose that the method for making bamboo fiber material comprises: splitting the bamboo tube into a bamboo piece which is separately separated from each other; and thoroughly removing the insect eggs in the bamboo piece; Use the tree and the glue boat to form a cup-shaped equipment. The main technical content of the 'US5967207 patent is to disclose the method of forming a Venetian curtain by cutting the bamboo into a bleaching oxidation and finally making a curtain. 200904868 The main technical content of the US6509294 patent is to disclose a food deodorant and antibacterial food bribe and _ saki, using bamboo carbon aerated stone to incorporate a binder into a carrier, and then adding at least one such as chitosan, bamboo vinegar, conke] : acid forms a non-woven fabric. The main technical content of the 49949990 patent case is to disclose the kind of cleaning container that is placed in the washing machine, the fat in the battle money, and the sewage container. The purification container (4) inorganic material is Bmclon wood slave and tourmaline ore. The ratio is about 75:25 and 95:5, and the appearance of the purified volume H is a light-weighted natural rubber or synthetic rubber. The main technical content of the US6475513 is to expose a skin care capsule. The content of the skin is contained in the content of the skin, and the water-transformed Wei agent can be used to remove the skin and absorb the water. Knowing the patent, the technical content disclosed by it is quite different from the patented technical content to be applied for in this case.
案之專利技術内容不僅創新且具獨特:果，; 為本案申睛之目的。 【發明内容】 且於上収^補魏，在作法上較為複亲 二3，而本案之技術内容更是在目前尚未有掏 關經驗，乃朗長久努力研鋒事此方面之* 發設計財發明之—種「#效_ t 子之稷合粉體之製造方法」。 、鄭 本毛明之主要目的，在於提供—種具高效率釋放負 200904868 離子之嘎合粉體之f造方法，該方法係將、電鼻’石粉it與 碳系输體依最適化之混合比例製成複合粉體，並可將該 複合粉體與一附著物（如：高分子材料之發泡材料或化 學纖維材料）掺混熔融在一起做成產品，使得該產品能 藉由電氣石粉體與碳系粉體混合後之相乘特性，產生高 度壓電、熱電或相關物性，以發揮釋放大量負離子和除 臭與抑菌等多功能效果；本發明之製造方法簡易迅速、 易大量生產，故極具產業應用價值。 【實施方式】 為便於貴審查委員能對本發明之技術手段及運 作過程有更進一步之認識與瞭解，茲舉一實施例配合圖 式’詳細說明如下。 本發明係一種「具高效率釋放負離子之複合粉體之 製造方法’本發明之複合粉體包含至少一種礦石組成與 其他礦物粉體所組成，該複合粉體主要成分為電氣石粉 體’添加一預定比例的碳系粉體為辅助成分，藉以提高 電氣石微粒的電場效應，促進其負離子釋放和除臭與抑 囟荨夕功能效果；其中該電氣石粉體可為鐵電氣石、鋰 電氣石、錳電氣石、鉋電氣石或鎂電氣石；而該碳系粉 體可為竹碳、椰碳、活性碳或木碳。 在本發明中，該複合粉體之配製比例為電氣石粉 體與碳系粉體複合比為1〜20 : 99〜8G ;該電氣石粉體之 平均粉體粒徑大小為0. 〜l#m ;該碳系粉體之平均 粉體粒徑大小為5//m〜20/zm。 以下乃針對該複合粉體（電氣石粉體/碳系粉體） 200904868 HZ 粉體中之碳系（如：_粉體 其絲的騎分財得知，竹錢纽狀物 摘孔隙分佈極廣，該等大小孔徑不-的微細 孔道具有超強的吸附能力。 獅，係林發賴合粉體樣品的 t描式電子顯微鏡（Scanning ElectronThe patented technical content of the case is not only innovative but also unique: fruit, and the purpose of this case. [Summary of the Invention] In addition, it is more important to reinforce Wei in the practice, and the technical content of this case is that there is no relevant experience at the moment, and it is the long-term efforts of the research and development of this aspect. Inventively, a "manufacturing method of the powder of ## _ t子". The main purpose of Zheng Ben Mao Ming is to provide a method for producing a high-efficiency release of a negatively mixed powder of 200,904,868 ions, which is prepared by mixing the electric nose 'stone powderit' with the carbon-based transport body according to the optimum mixing ratio. a composite powder, which can be blended with an adherent (for example, a foamed material of a polymer material or a chemical fiber material) to form a product, so that the product can be made of tourmaline powder and The multiplying characteristics of the carbon-based powder after mixing produce high piezoelectricity, thermoelectricity or related physical properties, thereby exerting a multi-functional effect of releasing a large amount of negative ions, deodorizing and bacteriostatic; the manufacturing method of the present invention is simple, rapid, and mass-produced, Very industrial application value. [Embodiment] In order to facilitate the review and understanding of the technical means and operation process of the present invention, an embodiment will be described in detail with reference to the drawings. The present invention relates to a method for producing a composite powder having a high-efficiency release negative ion. The composite powder of the present invention comprises at least one ore composition and other mineral powders, and the main component of the composite powder is tourmaline powder. A predetermined proportion of the carbon-based powder is an auxiliary component, thereby improving the electric field effect of the tourmaline particles, promoting the negative ion release and deodorization and suppressing the functional effects; wherein the tourmaline powder may be iron tourmaline or lithium electric Stone, manganese tourmaline, planing tourmaline or tourmaline; and the carbon powder may be bamboo carbon, coconut carbon, activated carbon or wood carbon. In the present invention, the composite powder is prepared in the proportion of tourmaline powder The ratio of the average powder size of the carbon powder is 0. 〜l#m; the average powder size of the carbon powder is 5//m~20/zm. The following is for the composite powder (tourmaline powder/carbon powder) 200904868 HZ The carbon system in the powder (for example: _ powder, its silk, the share of the money, The bamboo powder has a wide distribution of pores, and the pore sizes are not fine. The channel has a strong adsorption capacity. The lion, the Lin Fa Lai powder sample t-scanning electron microscope (Scanning Electron
Mwhdsc卯y，簡稱SEM)分析示意圖，由圖中可清楚 ( ' 看出，該等大小不一的細孔分佈在竹碳顆粒的表面，透 過竹碳表面上A、B兩點元素分析得知，兩點的元素組 成各不相同，說明A、B兩點是兩個不同的物質所組成， 進步元素分析（EDX)結果得知’該電氣石粉體顆粒 ，要是由氧（〇)、鋁（A1)、矽（Si)、鐵（Fe)和鈉（Na) 等元素組成’其中該氧（0)、銘（A1)、石夕（Si)和鐵 (Fe)元素的總和超過了 95重量百分比（Wf%)。 而該竹碳顆粒中以碳（C)元素含量為主，所占比 (j 例超過了 95重量百分比（wt%)，值得注意的是，這應 該是由於電氣石粉體顆粒塞到了竹碳顆粒表面上的孔 隙中，形成了一個“混合物”。 因此’在該電氣石粉體中添加一預定比例的竹碳 粉體’藉由該電氣石粉體塞進該竹碳的網絡孔狀結構 中’以及因為該電氣石粉體具有壓電性與熱電性，以及 因為該竹碳粉體具有良好的導電特性，兩粉體填充在一 基材中形成一個三維微導電網絡，因此得到優良的加成 作用’促進負離子的釋放效能。 在該電氣石粉體與該竹碳粉體以一預定比例混合 200904868 ^在90°C靜態測試條件下 釋放濃度達到148G個/cc; 孔負離子的 ，v 而田該複合粉體由該電氣石 ::體=，，同樣與該竹碳粉體以—預定比例混合 /二負離子的釋玫濃度分別為個 ^^為其他_之複合粉體高，這可能是由於該電 ，石粉體本身具有鱗概，因此當該複合·中之電 ^石粉體與該竹碳粉體以1定比例混合時，該電氣石Mwhdsc卯y, referred to as SEM) analysis diagram, can be clearly seen from the figure ('It can be seen that the pores of different sizes are distributed on the surface of bamboo carbon particles, and the elemental analysis of A and B on the surface of bamboo carbon is known. The composition of the two elements is different, indicating that the two points A and B are composed of two different substances. The progress of elemental analysis (EDX) results in 'the tourmaline powder particles, if it is made of oxygen (〇), aluminum Elemental composition of (A1), strontium (Si), iron (Fe), and sodium (Na), where the sum of the oxygen (0), inscription (A1), stone (Si), and iron (Fe) elements exceeds 95 Percentage by weight (Wf%). The content of carbon (C) in the bamboo carbon particles is the main content (j case exceeds 95 weight percent (wt%). It is worth noting that this should be due to tourmaline. The powder particles are plugged into the pores on the surface of the bamboo carbon particles to form a "mixture". Therefore, 'adding a predetermined proportion of bamboo carbon powder to the tourmaline powder' is inserted into the tourmaline powder. Bamboo carbon in the network pore structure 'and because the tourmaline powder has piezoelectricity and pyroelectricity, and because The bamboo carbon powder has good electrical conductivity characteristics, and the two powders are filled in a substrate to form a three-dimensional micro-conducting network, thereby obtaining an excellent additive function to promote the release efficiency of negative ions. The tourmaline powder and the bamboo The carbon powder is mixed at a predetermined ratio of 200,904,868 ^ at a static test condition of 90 ° C to release a concentration of 148 G / cc; the pore anion, v and the composite powder from the tourmaline:: body =, also with The bamboo carbon powder is mixed with the predetermined ratio of the two negative ions, respectively, and the composite powder is higher than the other composite powder. This may be due to the electricity, the stone powder itself has a scale, so when the composite The tourmaline powder is mixed with the bamboo carbon powder in a predetermined ratio, the tourmaline
，體可均㈣里的分散於該竹碳粉體的孔湖，造成熱 壓電效應的產生’而貞離子效能也隨著溫度升高 而增加。 另外凊參閱第二圖所示，係為本發明複合粉體比 例含量對負離子釋放濃度分析示意圖，由圖中可清楚看 出，該複合粉體的平均空氣負離子的釋放濃度均隨著溫 度升高而增加，如：在90t靜態測試條件下，當該複 合粉體中之電氣石粉體和竹碳粉體以一預定比例混合 時，其空氣負離子的釋放濃度最高約為1480個/cc，並 為35°C靜態測試條件下所測得的2. 8倍左右。 請參閱第三圖所示，係為本發明複合粉體溶液在 不同溫度下之電導率分析示意圖，由圖中可清楚看出， 該複合粉體中之竹碳溶液在透過和水分子相互間的接 觸’有效地在水中解離水分子成負離子而提升電導率， 且其隨溫度提升電導率的趨勢’與前述複合粉體樣品的 平均空氣負離子的釋放濃度隨溫度變化的趨勢是一致 的。此結論進一步地證實，該複合粉體在液態水或空氣 中均具備明顯之熱電特性。 200904868 除此之外，本料係進—步地可將職合粉體捧 混在一附著物内，該附著物可為一高分子材料，且兮二 =子材料泛指所有熱塑性及/或熱固性之彈性體材二 pV、pu:乙：膠(_ /聚丙烯(PP)或 (pin 子材料亦可為發泡材料如：聚氨酉旨 ()聚乙婦（PE)、聚丙烯（pp)、聚苯乙婦 做成之發糊H料㈣ 擠虔時的壓縮特性，# ”賴及又到 而達到夫曰發揮自身的壓熱電效能， 料觀量膽域抑_多功能效 ίΓί: 可為化學纖維材料（如：聚乙稀對 成之紡ϋ 口PET)經聚丙稀（pp)、尼龍(NYL⑽等）做 果(如下^ r=2)放負離子及除臭與抑菌等多功能效 表L 雄維平号 j離子濃度 纖維中複方粉體含量(wt%) 5 10 15 20 .120 150 190 180 150 170 200 140 -— 測試條件 -—--- 25°C靜置 25 C拍打 ~~~~-- ^^il®^425cm2 抗菌效率％ ^AATCC 100) 1 1 5 10 15 20 97.46 97.93 97.88 L---J 98.87 98. 99 200904868 凡乙丙橡膠/聚丙烯複方發泡體平均負離子濃度 子濃度(個/cc) 發泡體中複方粉體含量（wt%) ----— 測試條件 1 5 10 15 20 25t靜置 190」 240 250 280 210 25°C拍打 210 ------ 230 275 310 250 ，言％積為 25cm2 發泡體中複方粉體含 量Cwt%) 1 5 10 15 20 抗菌效率％ (AATCC 100) 99,83 99.86 99,89 99. 93 99.95 以下乃針_複合粉體（電氣石粉體/碳系粉體） ，混在高分子材料之熱祕及/或熱陳之雜體材料 最適化平均含量之進一步說明。 一 Μ參閱第賴所示，當該複合粉體含量由〇 5重 量百分比⑽）增加到Μ重量百分比（_時，盆 分散在該熱塑轉性體樣品之平均錄會由8 5_增 大到38. ，、約是原先粒徑的2〜13倍左右；又，告 該複合粉體含量由G. 5 —增加mo wm 熱塑性/熱固性彈性體樣品之平均粒徑，則大約由5 7 _增加至15. 範圍’約是原先粒徑的1〜6倍左 右，明顯較同等條件下的熱塑性彈性體樣品之平均粒徑 要小些。 另外在該熱塑性彈性體樣品，當該複合粉體含量 =wm曾加到5 w爾，其分散在該熱塑性彈性體 樣品中之平均粒徑只是緩慢地由8.增加到μ ^ 11 200904868 體含量由5爾加到1〇w爾 =在_錄彈性體樣品中之平触徑，卻快速^ .顯著地提升到38. 8/zm。 、 在熱塑性/熱固性彈性體 勢：當該複合粉體含量由〇 5 的趨 二放在_塑性/熱固性彈性體樣 : 增加到8.一;而當該=體： 彈性體==:;:=?熱塑性/熱固性 15.7"m。 =則由8.5_顯著增加到 入伞、針騎熱雜，固性·體樣品及含複 二==/熱固性彈性體樣品，在各測試條件下 、千貞離子的槪濃度之進-步說明。 清參閱第五圖所示，該熱塑性/熱固 t 2宂靜置測試條件下的平均空氣負離子的二 =僅為30條c ; #該複綱混人物 品塑料後，其平均空氣負離子的釋放濃度 二溫度與壓力之增加而增力口； 田後口杨體此入的含量接近一最適化值時，其 負離子的釋放濃度均_最大值，如：在坑靜^狀 心下其平均空氣負離子的釋放濃度分別約為挪及 4〇〇個/(X ’是同樣測量條件下純熱塑性 樣品平触綿離子釋放濃度的6料。雜體 由於電氣石粉體本身具有熱電性和壓電性兩特 性，所以在混入有複合粉體之熱塑性/熱固性彈性體樣 12 200904868 品與純熱雜/翻性雜雜品，其在溫度升高和壓 力^化下的平均空氣負離子的釋放濃度，都較常溫靜置 狀態:的結果要高—些；此外，也可能是當溫度超過 50 CN·加速了複合粉體之熱塑性/熱固性彈性體樣品 ，近的水”的蒸發運動，從*更有利於電氣石粉體對空 乳中水的電轉用，因此平触氣貞離子轉放濃度也 來的更高一些。 ,然而電氣石粉ϋ具有壓電效應，因此造成在相同 電氣石粉體含量下之熱塑性/熱固胜彈性體樣品’均較 純熱塑性/油性雜雜品具備難之獄負離子的 效果；而竹碳粉體树也有釋放貞離子絲，藉以適量 的添加作為伽成分來提高電氣石碰的電場效應，因 此電氣石粉體與竹碳粉體產生加成效果，進而提升負離 子釋放效果。 月ij述本發明複合粉體之製造方法，係將至少一種礦 石組成與其他礦物粉體組成，在高度潔淨環境下，經由 特定量技摘產生之複合碰，練合粉體主要 成分為電氣石粉體，添加一預定比例的碳系粉體為輔助 成分，藉以產生高度壓電、熱電或相關物性之負離子釋 放功能；其中該特定研磨能量技術包含物體撞擊或能量 衝撞、機械能混合或其他氣、液流體混合之加工方式。 此外，本發明所產生之複合粉體，係可混掺於可具 抽絲或發泡級條件之高分子材料（如：尼龍、聚酯、聚 丙烯、聚乙烯 '聚胺酯、尼龍等），並使成為母粒型式 之方式形成，以在特定溫度的條件下使欲混掺之高分子 13 200904868 特定混掺方式所產生;其中該特定混摻 ⑴抽、^條件之高分子㈣之機械混掺方式： ^南分子材料（如：聚乙烯對苯二甲酸醋 Ετ)、聚丙烯（pp)、尼龍(NYL〇N)等）樣品 調配適當比例與預先混合之電氣石與竹碳複 合粉體’於螺桿擠壓機中進行摻混。螺桿操The body can be dispersed in the hole lake of the bamboo carbon powder, causing the generation of the thermal piezoelectric effect, and the cesium ion efficiency also increases with increasing temperature. In addition, as shown in the second figure, it is a schematic diagram of the ratio of the proportion of the composite powder to the negative ion release concentration of the present invention. It can be clearly seen from the figure that the average air anion release concentration of the composite powder increases with temperature. And increase, for example, under the static test condition of 90t, when the tourmaline powder and the bamboo carbon powder in the composite powder are mixed in a predetermined ratio, the release concentration of air negative ions is about 1480/cc, and 2倍左右。 The measured under static conditions of 35 ° C measured about 2.8 times. Please refer to the third figure, which is a schematic diagram of the conductivity analysis of the composite powder solution of the present invention at different temperatures. It can be clearly seen from the figure that the bamboo carbon solution in the composite powder is between the permeation and the water molecules. The contact 'effectively dissociates water molecules into negative ions in water to increase conductivity, and its tendency to increase conductivity with temperature' is consistent with the tendency of the average air anion release concentration of the aforementioned composite powder samples to change with temperature. This conclusion further confirms that the composite powder has significant thermoelectric properties in liquid water or air. 200904868 In addition, the material can be mixed into a deposit in a step, the attachment can be a polymer material, and the second = sub-material refers to all thermoplastic and / or thermoset Elastomers 2 pV, pu: B: glue (_ / polypropylene (PP) or (pin material can also be foaming materials such as: Polyurethane () Polyethylene (PE), polypropylene (pp ), the polystyrene-made woman made the paste H material (four) the compression characteristics of the squeezing, # ” 赖 又 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 达到 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰It can be used for chemical fiber materials (such as polyethylene, woven polyester, nylon (NY), etc.) (eg, ^r=2) for negative ions, deodorization and inhibition. Functional effect table L Xiongweiping j ion concentration fiber compound powder content (wt%) 5 10 15 20 .120 150 190 180 150 170 200 140 -- Test conditions----- 25 °C static 25 C Beat ~~~~-- ^^il®^425cm2 Antibacterial efficiency% ^AATCC 100) 1 1 5 10 15 20 97.46 97.93 97.88 L---J 98.87 98. 99 200904868 Ethylene-propylene rubber/polypropylene compound foam Average negative Subconcentrator concentration (units/cc) Foam body compound powder content (wt%) ----- Test conditions 1 5 10 15 20 25t standing 190" 240 250 280 210 25 °C tapping 210 --- --- 230 275 310 250 , the % product is 25cm2 in the foam compound powder content Cwt%) 1 5 10 15 20 Antibacterial efficiency% (AATCC 100) 99,83 99.86 99,89 99. 93 99.95 The following is the needle _Composite powder (tourmaline powder/carbon powder), further description of the optimum content of the optimum content of the thermal material of the polymer material and/or the heat of the hybrid material. As shown in the first column, when the composite powder content is increased from 〇5 weight percent (10) to Μ weight percent (_, the average number of pots dispersed in the thermoplastic rotatory sample is increased by 85 _ To 38., about 2 to 13 times the original particle size; and, to report the composite powder content by G. 5 - increase the average particle size of the mo wm thermoplastic / thermosetting elastomer sample, then about 5 7 _ Increase to 15. The range 'is about 1 to 6 times the original particle size, which is significantly smaller than the average particle size of the thermoplastic elastomer sample under the same conditions. Also in the thermoplastic elastomer sample, when the composite powder content =wm was added to 5 hr, and the average particle size dispersed in the thermoplastic elastomer sample was only slowly increased from 8. to μ ^ 11 200904868. The body content was increased from 5 Å to 1 〇 Å = _ recorded elasticity The flat contact diameter in the bulk sample is rapidly increased to 38. 8/zm. In the thermoplastic/thermosetting elastomer potential: when the composite powder content is placed by the 〇5 _ plastic/thermosetting elasticity Body: Increase to 8. One; and when the body: Elastomer ==:;:=? Thermoplastic/thermosetting 15.7&q Uot;m. = from 8.5_ significantly increased to the umbrella, needle riding hot, solid body sample and containing complex ===/thermosetting elastomer sample, under each test condition, the concentration of strontium ions Step-by-step description. As shown in the fifth figure, the average air anion under the thermoplastic/thermosetting t 2 宂 static test condition is only 30 pieces of c = ## The release concentration of the average air anion is increased by the increase of temperature and pressure. When the content of the poplar body is close to an optimum value, the release concentration of the negative ions is _maximum, such as: The release concentration of the average air negative ions in the heart is about 4 / / (X ' is the 6-material release concentration of the pure thermoplastic sample under the same measurement conditions. The hybrid has thermoelectricity due to the tourmaline powder itself. Two characteristics of properties and piezoelectricity, so the thermoplastic/thermosetting elastomer sample 12 200904868 and the pure hot/turning impurity are mixed with the average air anion at elevated temperature and pressure. The release concentration is more static than normal temperature: The result should be high--in addition; it may also be when the temperature exceeds 50 CN·accelerated the thermoplastic/thermosetting elastomer sample of the composite powder, the near-water evaporation movement, from * is more conducive to tourmaline powder to empty milk The transfer of water in the middle water, so the concentration of the flat-touch gas ion transfer is also higher. However, the tourmaline meal has a piezoelectric effect, thus causing the thermoplastic/thermoset elastomer under the same tourmaline powder content. The sample 'has a pure thermoplastic/oily miscellaneous product with the effect of difficult prison anion; and the bamboo carbon powder tree also releases the cerium ion wire, so that the appropriate amount of addition as a gamma component can improve the electric field effect of the tourmaline collision, so the tourmaline powder The body and the bamboo carbon powder have an additive effect, thereby enhancing the negative ion release effect. The invention relates to a method for manufacturing a composite powder of the present invention, which comprises at least one ore composition and other mineral powders, and in a highly clean environment, a composite bump produced by a specific amount of technical picking, the main component of the powder is tourmaline. Powder, adding a predetermined proportion of carbon-based powder as an auxiliary component, thereby generating a negative piezoelectric release function of high piezoelectricity, thermoelectricity or related physical properties; wherein the specific abrasive energy technology includes object impact or energy collision, mechanical energy mixing or other gas , the processing method of liquid and fluid mixing. In addition, the composite powder produced by the present invention can be blended into a polymer material (such as nylon, polyester, polypropylene, polyethylene 'polyurethane, nylon, etc.) which can be subjected to spinning or foaming conditions, and It is formed into a master batch type, which is produced by a specific blending method of the polymer 13 200904868 to be blended under a specific temperature condition; wherein the specific blending (1) is mechanically mixed with the polymer (4) Method: ^South molecular materials (such as: polyethylene terephthalate Ε ) )), polypropylene (pp), nylon (NYL 〇 N), etc.) sample mix appropriate proportion and pre-mixed tourmaline and bamboo carbon composite powder ' Blending was carried out in a screw extruder. Screw operation
=溫度為150-25(TC ;轉迷為8~15Hz ，經過 高溫融溶的高分子複合體，經螺桿的擠壓流 入紡絲盒内再從紡絲板噴出後冷卻延伸成具 負離子釋放的人造絲。 (2)發泡級條件之咼分子材料之母粒製造方式： 5亥成為母粒型式形成方式之高分子材料，係 可以熱塑性（如：氫化熱塑性丁苯橡膠、熱塑 性丁腈橡膠、三元乙丙橡膠等及熱固性彈性 體（如：氨基類、多元酯、環氧樹脂、尿素曱 搭樹脂、酚曱醛）樣品調配適當比例共摻混， 其摻混比例約為15/95-75/5，並加入7%-20% 的紛酸樹脂及5%-1〇%氣化亞錫催化劑與預先 混合之電氣石與竹碳複合粉體，於螺桿擠壓 機中進行摻混。附著於經由擠壓（螺桿轉速為 5-lOHz ;操作溫度為i50-250°C)及延伸能量 所形成之線性形狀之棒狀物；經過冷卻水槽 (5-10°C )使連續線狀複合高分子體固化最後 通過切粒機之旋轉刀具切製成粒。 14 200904868 按’上述詳細說明為針對本發明之一種較佳之可行 貝把例5兒明而已，惟該實施例並非用以限定本發明之申 請專利範圉’舉凡其他未脫離本發明所揭示之技藝精神 下所7G成之均等變化與修飾變更，均應包含於本發明所 涵蓋之專利範圍中。 【圖式簡單說明】 第圖係，本發明複合粉體樣品的掃描式電子顯微鏡 分析示意圖。 第二圖係為本發明複合粉體比例含量對負離子釋放濃 度分析示意圖。 第三圖係為本發明複合粉體溶液在不同溫度下之電導 率分析示意圖。 第四圖係林發明複合粉體含量調整時，其分散在孰塑 性彈性體樣品/熱固性彈性體樣品中之平均粒徑分 析不意圖。 在不同溫度下對負離子釋 第五圖係為本發明複合粉體 放濃度之分析示意圖。 【主要元件符號說明】 無 15= temperature is 150-25 (TC; reversal to 8~15Hz, high temperature melted polymer composite, which is squeezed into the spinning box by screw extrusion and then ejected from the spinning plate and then cooled to form negative ion release. (2) Masterbatch of molecular materials in foaming grade conditions: 5 Hai is a polymer material in the form of masterbatch type, which can be thermoplastic (eg hydrogenated thermoplastic styrene butadiene rubber, thermoplastic nitrile rubber, Samples of EPDM rubber and thermosetting elastomers (such as amino groups, polyesters, epoxy resins, urea resin, phenolic furfural) are blended in appropriate proportions, and the blending ratio is about 15/95- 75/5, and adding 7%-20% acid resin and 5%-1〇% vaporized stannous catalyst and pre-mixed tourmaline and bamboo carbon composite powder, blended in a screw extruder. Attached to a rod of linear shape formed by extrusion (screw speed of 5-10 Hz; operating temperature of i50-250 ° C) and extension energy; continuous linear composite through a cooling water tank (5-10 ° C) The polymer is solidified and finally cut into pellets by a rotary cutter of a pelletizer. 14 200904 </ RTI> </ RTI> </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> </ RTI> <RTIgt; The equivalent changes and modifications of the following 7G should be included in the patent scope covered by the present invention. [Simplified description of the drawings] The figure is a schematic diagram of scanning electron microscope analysis of the composite powder sample of the present invention. The figure is a schematic diagram of the ratio of the proportion of the composite powder to the negative ion release concentration of the invention. The third figure is a schematic diagram of the conductivity analysis of the composite powder solution of the invention at different temperatures. The fourth figure is the adjustment of the composite powder content of the invention The average particle size analysis of the sample dispersed in the ruthenium plastic elastomer sample/thermosetting elastomer is not intended. The fifth diagram of the negative ion release at different temperatures is a schematic diagram of the analysis of the concentration of the composite powder of the present invention. Description] No 15