200904747 九、發明說明： 【發明所屬之技術領域】 本案與氫氣產生裝置有關’更詳而言之，係利用金屬物質與酸性或鹼性 溶液反應產生氫氣，且便於攜行運送不受工作場地限制之氫氣產生裝置。 【先前技術】 氫元素為地球上相當普遍之元素之―，氫氣於傳統工程中廣泛地被利用 以進行金屬切割或焊接等工作’或是作為氣體燃料之用。而近年來所發展 -的燃料電池係利用從天然氣或水中分離出氫氣，加以壓縮後儲存分裝，輸 送，透過裝置於建築物、工廠或車輛内的燃料電池之反應進而發電。此項 以氫為燃料，結合自然界空氣中的氧氣經燃料電池反應後僅產生電力及 水，除此之外沒有其他排放物，可說是相當乾淨與環保的能源。而燃料電 池使用氫氣發電之便利性在於氫氣可以像石油一樣，將此一含有大量能源 之燃料包裝在一個小空間内來加以使用消費。而且，以氫氣做為燃料產生 之電力不像太陽能或風能電力，它可以在任何需要的地點與時間直接加以 ( 利用消費。因此近年來氫氣於能源工業的應用上更是受到大家重視。 工業製氫法工業法有電解法、烴裂解法、烴蒸氣轉化法、煉廠氣提取法 等，但上述所應用之方法都需要大型設備或電力輸入，並無法於每個地方 或場所裝置氫氣產生設備。因此，目前所製成之氫氣大多仍以高壓鋼瓶儲 氣之方式進行運送或儲存，由於高壓鋼瓶為了安全性等問題，需要具備有 一定之強度，以抵抗外力撞擊及畴之壓力，造成高翻瓶本身之體 積及重量增加，但事實上高壓鋼瓶所能儲存氫氣之容積非常之小，即使内 儲之氫氣壓縮到150個大氣壓力，高壓鋼瓶内所儲存氫氣之質量仍不到高壓 200904747 .鋼瓶質量的百分之一，儲存效率不彰。 【發明内容】 發明所欲解決之技術問題： -般工業上製造氫氣需要果多大型設備練製，並無法隨處設置，因此習 用氫氣之儲存或運送都需要藉由高壓細瓦容置，一旦高壓鋼瓶内存之氯氣 使用完畢後’鶴送駐輕定點顏充填，並無法立㈣充，造成工作 得中斷無法持續施工，對於使用者來說實為不便；且高壓鋼瓶本身的體積 ('及重量對運送之成本造成極大之影響，且紐鋼舰在使用上有安全之疑慮。 發明解決問题之技術手段： 一種可攜式氫氣機，其主要包含有： —氫氣機本體，其係具有-中空之反應室，該反應室具有—填料口及一 排放口，該填料Π可供使用者將反應溶液與金屬物f裝填人該反應室内， 以於其内進行化學反應產生氫氣； 一氣體壓力偵測組，其係可偵測反應室内之氣體壓力狀態； ί/ 一反應溶液偵測組，其係可偵測反應室内之反應溶液狀態； 一氣體輸出組，其係可將反應室内之氫氣輸出。 發明對照先贫技術之功效： 本發明係利用反應溶液與金屬物質直接產生氫氣使用，器材搬運方便、 設置容易，只需重複添加反應溶液及金屬物質，即可不斷產生氫氣，補充 十分容易’具有持續提供氫氣之特性，適合於各個工作場所或配合不同之 設備’如燃料電池、焊接機等設備使用； 本發明構成簡單’且氫氣之總產生量與氫氣機之總容積無關，而係與金 200904747 •屬物質及反應溶液之添加量相關，氫氣機可^^照設置場所及需求不同，設 计不同容量之產品，針對小型場所駐作攜行方便，可設計容積較小之產 品’便於攜帶運送；而針對大型場所可設計容雜大之定置式產品，以具 備較大的單次產氫氣量’增加重新添加金屬物質及反應溶液之時間間隔； 且本發明平常可將機器、反應溶液與金屬物質分開存放、運送，保存方 便、安全’且反應溶液係為預先調配完成的，使用者只需依照自己所需要 之氫氣量，添加相對應比例之金屬物質及反應溶液，不會造成氫氣之 广'. 只 (本發明之金屬材質係採用鋁金屬相關材料，可使用高純度鋁金屬，其來 源取得容易，亦可使用資源回收之銘金屬相關材料做為金屬材質來源，且 -可將紹金屬與其他金屬材質製成合金塊狀、條狀、片狀、碎粒狀或粉末狀， ..當所需求氫氣單位時間内之輸出量較大時，使用者只需要改換使用顆粒較 小之金屬材質，即可輕易地增加氫氣的產生反應速率，使用方式簡單方便。 【實施方式】 請參閱第-圖圖面所示’其係為本發明一種可攜式氫氣機之平面示意 I, 圖’其主要包含有： 一氫氣機本體（10)，其係具有一中空之反應室（u)，該反應室（u)係由 耐酸鹼之材質所製成，該反應室（11)具有一填料口（12)及一排放口（13)， 該填料口（12)係位於該反應室（11)之頂端處，以方便使用者自該填料口（12) 將反應溶液與金屬物質裝填入該反應室（11)内，該反應溶液可為酸性或鹼 性之溶液，而該金屬物質係為鋁金屬，以於其内進行化學反應產生氫氣； 其中，該填料口（12)係設有一密封蓋（121)可防止氫氣洩出；再者，該排放 口（13)係位於該反應室（11)底部，且其設有一底部洩放閥（131)以控制反應 200904747 . 溶液之排放者； 一氣體壓力偵測組(20)，其係包含有一與反應室（11)連通之氣體壓力表 (21) ’以顯示該反應室（11)内之氣體壓力狀態；其中，該氣體壓力偵測組 (20)更包含有一自動洩壓裝置(22)，該自動洩壓裝置(22)係可於反應室（u) 内氣體壓力大於預設之安全壓力值時自動洩壓，防止氣體壓力過大產生危 險； 一反應溶液偵測組(30)，包含有一反應溶液濃度顯示表(31)，該反應溶 液濃度顯示表（31)係可以顯示反應溶液之濃度或酸鹼值等方式，使操作人 員了解目前反應溶液之狀態；一溫度計(32)，其係可顯示反應溶液之溫度； 一液面顯示計（33)，該液面顯示計(33)係於該氫氣機本體（1〇)外側設有一 與反應室（11)相連通之透明觀測窗口（331)，該觀測窗口（331)上設有複數 之刻度’以顯示反應室（11)内反應溶液之液面高低； 一氣體輸出組(40)，其主要係為一氣體輸出管道(41)，該氣體輸出管道 (41)俾可將反應室（11)内之氫氣輸出至相對應之裝置内使用；該氣體輸出 組(40)更包含有一氣體流量計(42)，該氣體流量計(42)可偵測並顯示該氣 體輸出管道(41)内之氣體流量；一氣體流量控制閥（43)，該氣體流量控制 閥（43)可活動調整該氣體輸出管道(41)内之氣體流量，以符合使用者之需 求；一氣體過濾器（44)，該氣體過濾器（44)内裝設有不同之物理或化學濾 材，可針對輪出之氣體進行過濾及純化之動作，以除去輸出氣體中之水氣、 雜質或其他非氫氣氣體；-連結裝置⑹，其係可將該氣體輸出管道⑹ 連接至其他利贱氣進行運作之裝置’如燃料電池、氫氧焰切割機或氣氣 200904747 充填機等裝置。 明瞭上述結構後，以下係針對本發明之動作原理作一詳細說明： 如第二圖圖面所示，將該填料口（12)上方之密封蓋（121)旋鬆開啟，自 該填料口（12)將反應溶液裴填入該反應室（η)内，使用者可自該液面顯示 计（33)讀取添加之反應溶液之數量，並自該反應溶液濃度顯示表（3丨）了解 目前反應溶液之濃度或酸鹼值； 如第三圖圖面所示，當反應溶液添加完畢後，再將鋁金屬自該填料口（12) 裝填入該反應室（11)内，並將該密封蓋（丨21)旋緊封閉； 由於該反應溶液係為酸性或驗性溶液，當銘金屬進入反應室（11)後，會 與反應溶液產生化學反應，其反應式分別如下： (一） 鋁和鹼作用產生氫氣： 2 Al(s) + 2 OH + 6 H2O ==> 2 A1(0H)4- + 3H2(g)个 (二) 叙和酸作用產生氫氣： 2 Al(s) + 6 H+ ==> 2 A13+ + 3 H2(g)个 請參閱第四圖圖面所示，當紹金屬與反應溶液開始反應產生氣氣時，使 用者可自該氣顏力表⑵）讀取該反應室⑴）内之氣歷力狀態；當反應 室⑴）内之氣體壓力達到有效壓力後，即可開啟該氣體流量控制閥(43)， 當氣體開始輸出後該氣體流量計⑽可侧並顯示該氣體輸出管道(41)内 之氣體流量，使用者可依照所需調整氣體輸出流量，以將產生之氫氣輸出 至其它利用氫氣進行運作之裝置内使用； 而當氣體輪出至該氣體過濾器⑽時，其内所襄設之物理或化學渡材， 200904747 可針對輸k纽進行過献純化之動作，贿麵域財 貝或，、他非虱线體；避免輸出氣體中之雜質或其他物質 成損害或影響使用效率； ^本身造 使用者可藉由該反應錢濃賴示表⑻之讀數了解目前反應溶液消 耗之狀況’纽應溶液濃度過辦即代錢氣即將制完畢，可待氯氣、，肖 耗完畢且氣·力表⑼指數降低至正傾力後，再_底部紐間⑽) 開啟排放出廢棄溶液(如第五圖圖面所示），此時使用者亦可自該液面顯示 計(33)顧、廢聽液是否排放乾淨，避錢留之廢棄魏影響後續之反應 效率；當廢棄溶液排放完畢後’細者⑼再重新添加反聽液及金屬物 質’即可再次產生氫氣使用； 而當銘金屬與反應溶液進行反應之過程中，使用者可藉由該溫度計⑽ 之指數，了解目前反應之速度是否過當…旦該溫度計⑽所顯示的溫度 急速上升，代表目前反應溶液及金屬物質反應過劇可能會造成危險，使用 者可緊急開啟該底部洩放閥（131)，排出部份反應溶液以降低反應速率，避 免發生危險； 再者，該氣體壓力偵測組(20)更包含有一自動洩壓裝置(22),該自動洩 壓裝置（22)係可於反應室（11)内氣體壓力大於預設之安全壓力值時自動洩 麗’防止氣體壓力過大產生危險； 為了因應不同裝置需求的氫氣產生反應速率不同，可將銘金屬製成塊 狀、條狀、片狀、碎粒狀或粉末狀，當所需求氫氣單位時間内之輸出量較 大時，使用者只需要改換使用顆粒較小之金屬材質，即可輕易地增加氫氣 200904747 . 的產生反應速率，使用方式簡單方便； 、雖然核是以-個最佳實關做綱，㈣概技藝魏在魏離本案 精神與範嘴下做各種不同形式的改變。以上所舉實施僅用以說明本案而 非用以限制本案之範圍。舉凡不違本案精神所從事的種種修改或變化， 俱屬本案申請專利範圍。200904747 IX. Description of the invention: [Technical field to which the invention pertains] This case relates to a hydrogen generating device. More specifically, it uses a metal substance to react with an acidic or alkaline solution to generate hydrogen gas, and is convenient to carry and transport without being restricted by the work site. Hydrogen generating device. [Prior Art] Hydrogen is a relatively common element on earth, and hydrogen is widely used in conventional engineering for metal cutting or welding, or as a gaseous fuel. In recent years, fuel cells have been developed by separating hydrogen from natural gas or water, compressing them, storing them, distributing them, and transmitting them through the reaction of fuel cells in buildings, factories, or vehicles. This hydrogen-based fuel, combined with the oxygen in the natural air, generates electricity and water only after being reacted by the fuel cell. There is no other emissions, and it is a relatively clean and environmentally friendly energy source. The convenience of using hydrogen to generate electricity in a fuel cell is that hydrogen can be used in a small space to be consumed in a small space like petroleum. Moreover, the electricity generated by using hydrogen as a fuel is not like solar or wind power, it can be directly used at any place and time (using consumption. Therefore, in recent years, hydrogen has been paid more attention to the application of the energy industry. The hydrogen production method includes electrolysis, hydrocarbon cracking, hydrocarbon vapor reforming, refinery gas extraction, etc., but the above-mentioned methods all require large equipment or power input, and it is not possible to install hydrogen in every place or place. Therefore, most of the hydrogen currently produced is still transported or stored in the form of high-pressure steel cylinders. Because of the safety and other problems, high-pressure steel cylinders need to have a certain strength to resist external impact and domain pressure. The volume and weight of the high-turning bottle itself increase, but in fact the volume of hydrogen stored in the high-pressure cylinder is very small. Even if the hydrogen stored in the cylinder is compressed to 150 atmospheres, the quality of the hydrogen stored in the high-pressure cylinder is still less than the high pressure. One percent of the quality of the cylinder, the storage efficiency is not good. [Summary of the Invention] The technology to be solved by the invention Problem: In general, the production of hydrogen in the industry requires a lot of large-scale equipment to be trained, and it cannot be set anywhere. Therefore, the storage or transportation of conventional hydrogen needs to be accommodated by high-pressure fine tiles. Once the chlorine in the high-pressure cylinder is used, the crane is sent. In the light fixed point filling, and can not stand (four) charge, resulting in interruption of work can not continue construction, it is inconvenient for the user; and the volume of the high-pressure cylinder itself (' and weight have a great impact on the cost of transportation, and New Zealand The steel ship has safety concerns in its use. Technical means for solving the problem: A portable hydrogen machine mainly comprises: a hydrogen machine body, which has a hollow reaction chamber, and the reaction chamber has a packing port And a discharge port, the filler cartridge is adapted for the user to load the reaction solution and the metal material f into the reaction chamber to perform a chemical reaction to generate hydrogen gas therein; and a gas pressure detecting group capable of detecting the reaction chamber Gas pressure state; ί / a reaction solution detection group, which can detect the state of the reaction solution in the reaction chamber; a gas output group, which can be the reaction chamber The hydrogen output. The invention compares the effect of the first lean technology: The invention utilizes the reaction solution and the metal material to directly generate hydrogen gas, and the device is convenient to transport and easy to set up, and only needs to repeatedly add the reaction solution and the metal substance to continuously generate hydrogen and supplement. It is very easy to 'have the characteristics of continuous supply of hydrogen, suitable for use in various workplaces or with different equipments such as fuel cells, welding machines, etc.; the invention is simple in construction' and the total amount of hydrogen produced is independent of the total volume of the hydrogen machine. The system is related to the addition of the substance and the reaction solution. The hydrogen machine can be designed according to different installation places and needs, and the products with different capacities can be conveniently transported for small places, and the volume can be designed to be small. The product 'is convenient for carrying and carrying; and for large-scale places, it is possible to design a large-sized fixed-type product to have a larger single-time hydrogen production amount' to increase the time interval of re-adding metal substances and reaction solutions; and the present invention can usually be used for machines. The reaction solution is stored and transported separately from the metal material, which is convenient and safe to store. The reaction solution is pre-mixed, and the user only needs to add a corresponding proportion of the metal substance and the reaction solution according to the amount of hydrogen required by the user, and does not cause a wide range of hydrogen. Only (the metal material of the invention is made of aluminum) Metal-related materials, high-purity aluminum metal can be used, the source of which is easy to obtain, and the metal-related materials of resource recovery can also be used as the source of metal materials, and - the metal and other metal materials can be made into alloy blocks and strips. , flake, granule or powder, .. When the required output of hydrogen per unit time is large, the user only needs to change the metal material with smaller particles to easily increase the reaction rate of hydrogen production. The method of use is simple and convenient. [Embodiment] Please refer to the figure of the first drawing, which is a schematic diagram of a portable hydrogen machine of the present invention. FIG. 2 mainly includes: a hydrogen machine body (10) having a hollow The reaction chamber (u) is made of an acid and alkali resistant material, and the reaction chamber (11) has a filling port (12) and a discharge port (13), and the filling port (12) ) is located at the top of the reaction chamber (11) to facilitate the user to fill the reaction solution and metal substance into the reaction chamber (11) from the filling port (12), the reaction solution may be acidic or alkaline And the metal material is aluminum metal for chemical reaction therein to generate hydrogen gas; wherein the filler port (12) is provided with a sealing cover (121) to prevent hydrogen gas from leaking; further, the discharge port (13) is located at the bottom of the reaction chamber (11), and is provided with a bottom bleed valve (131) to control the reaction 200904747. The emitter of the solution; a gas pressure detecting group (20), which contains a reaction a gas pressure gauge (21) connected to the chamber (11) to show the gas pressure in the reaction chamber (11) The gas pressure detecting group (20) further includes an automatic pressure relief device (22), wherein the gas pressure in the reaction chamber (u) is greater than a preset safety pressure value. Automatic pressure relief to prevent danger of excessive gas pressure; a reaction solution detection group (30), including a reaction solution concentration display table (31), the reaction solution concentration display table (31) can indicate the concentration of the reaction solution or The pH value allows the operator to know the state of the current reaction solution; a thermometer (32) which shows the temperature of the reaction solution; a liquid level display (33), which is attached to the liquid level display (33) The outside of the hydrogen machine body (1〇) is provided with a transparent observation window (331) communicating with the reaction chamber (11), and the observation window (331) is provided with a plurality of scales ' to display the reaction solution in the reaction chamber (11). a liquid output group (40), which is mainly a gas output pipe (41), and the gas output pipe (41) can output the hydrogen in the reaction chamber (11) to the corresponding device. Used; the gas output group (40) further contains a gas a meter (42), the gas flow meter (42) can detect and display the gas flow rate in the gas output pipe (41); a gas flow control valve (43), the gas flow control valve (43) can be adjusted The gas flow rate in the gas output pipe (41) to meet the needs of the user; a gas filter (44), the gas filter (44) is provided with different physical or chemical filter materials, which can be used for the rotation The gas is filtered and purified to remove moisture, impurities or other non-hydrogen gases in the output gas; - a coupling device (6) that connects the gas output conduit (6) to other devices that operate the gas Fuel cell, oxyhydrogen flame cutting machine or gas gas 200904747 filling machine and other devices. After the above structure is clarified, the following is a detailed description of the principle of operation of the present invention: As shown in the second drawing, the sealing cover (121) above the filling port (12) is loosely opened from the filling opening ( 12) The reaction solution is filled into the reaction chamber (η), and the user can read the amount of the added reaction solution from the liquid level display meter (33), and learn from the reaction solution concentration display table (3丨) The concentration or pH value of the current reaction solution; as shown in the third figure, after the reaction solution is added, the aluminum metal is loaded into the reaction chamber (11) from the filling port (12), and The sealing cover (丨21) is tightly closed; since the reaction solution is an acidic or an experimental solution, when the metal enters the reaction chamber (11), it will chemically react with the reaction solution, and the reaction formulas are as follows: The action of aluminum and alkali produces hydrogen: 2 Al(s) + 2 OH + 6 H2O ==> 2 A1(0H)4- + 3H2(g) (2) The acid acts to produce hydrogen: 2 Al(s) + 6 H+ ==> 2 A13+ + 3 H2(g) Please refer to the figure in the fourth figure, when the metal reacts with the reaction solution. When the gas is gas, the user can read the gas force state in the reaction chamber (1)) from the gas force table (2)); when the gas pressure in the reaction chamber (1)) reaches the effective pressure, the gas flow control valve can be opened (43) When the gas starts to output, the gas flow meter (10) can side and display the gas flow rate in the gas output pipe (41), and the user can adjust the gas output flow rate as needed to output the generated hydrogen to other hydrogen utilization. Used in the operating device; and when the gas is taken out to the gas filter (10), the physical or chemical material that is built in it, 200904747 can be used for the purification of the k-news. , he is not a scorpion body; avoid impurities or other substances in the output gas to damage or affect the efficiency of use; ^ the user can use the reaction to see the reading of the table (8) to understand the current consumption of the reaction solution' The concentration of the solution should be completed soon, and the chlorine gas can be used. After the gas consumption is completed, the gas and force meter (9) index is reduced to the positive pressure, and then the bottom line (10) is opened to discharge the waste solution. As shown in the figure of the fifth figure, the user can also use the liquid level display meter (33) to check whether the waste liquid is discharged cleanly, avoiding the waste and leaving the waste to affect the subsequent reaction efficiency; when the waste solution is discharged After the completion, the thinner (9) re-adding the anti-listening liquid and the metal substance can regenerate the hydrogen; and when the metal reacts with the reaction solution, the user can understand the current reaction by the index of the thermometer (10). Whether the speed is too high... Once the temperature indicated by the thermometer (10) rises rapidly, it means that the reaction of the current reaction solution and the metal substance may cause danger. The user can emergencyly open the bottom bleed valve (131) to discharge part of the reaction solution. The reaction rate is reduced to avoid danger; further, the gas pressure detecting group (20) further comprises an automatic pressure relief device (22), which is capable of gas pressure in the reaction chamber (11) Automatically leaks when the safety pressure value is greater than the preset value. Prevents the danger of excessive gas pressure. In order to meet the different reaction rates of hydrogen required by different devices, the metal can be made of Ming metal. Shape, strip, flake, granule or powder. When the required output of hydrogen per unit time is large, the user only needs to change the metal material with smaller particles to easily increase hydrogen 200904747. The reaction rate is simple and convenient to use; although the core is based on the best practice, (4) the general skill Wei Wei made various changes in the spirit of the case and the fan. The above implementations are for illustrative purposes only and are not intended to limit the scope of the present invention. All kinds of modifications or changes that are not in violation of the spirit of the case are the scope of patent application in this case.
11 200904747 . 【圖式簡單說明】 第一圖為本發明之平面示意圖。 第二圖為本發明之動作示意圖（一）。 第三圖為本發明之動作示意圖（二）。 第四圖為本發明之動作示意圖（三）。 第五圖為本發明之動作示意圖（四）。 【主要元件符號說明】 氫氣機本體(10) 反應溶液濃度顯示表（31) 反應室（11) 溫度計(32) 填料口（12) 液面顯示計（33) 排放口（13) 透明觀測窗口（331) 密封蓋（121) 氣體輸出組(40) 底部洩放閥（131) 氣體輸出管道(41) 氣體壓力偵測組(20) 氣體流量計(42) 氣體壓力表(21) 氣體流量控制閥（43) 自動洩壓裝置(22) 氣體過濾器（44) 反應溶液彳貞測組（30) 連結裝置（45) 1211 200904747 . [Simple description of the drawings] The first figure is a schematic plan view of the present invention. The second figure is a schematic diagram of the action of the present invention (1). The third figure is a schematic diagram of the action of the present invention (2). The fourth figure is a schematic diagram of the action of the invention (3). The fifth figure is a schematic diagram of the action of the present invention (4). [Main component symbol description] Hydrogen engine main body (10) Reaction solution concentration display table (31) Reaction chamber (11) Thermometer (32) Packing port (12) Liquid level display meter (33) Discharge port (13) Transparent observation window ( 331) Sealing cap (121) Gas output group (40) Bottom bleed valve (131) Gas output pipe (41) Gas pressure detection group (20) Gas flow meter (42) Gas pressure gauge (21) Gas flow control valve (43) Automatic pressure relief device (22) Gas filter (44) Reaction solution detection group (30) Connection device (45) 12