200842074 九、發明說明·· 【發明所屬之技術領域】 本發明係關於一種熱塑性複合材料之強度補強方 法，尤其是關於一種將纖雉強化熱塑性複合材料與金屬件 相結合，藉以提升纖維強化熱塑性複合材料之局部機械強 度的纖維強化熱塑性複合材料之金屬補強方法。 【先前技術】 .複合材料種類繁多’其中以纖維強化複合材料(Fibe Reinforced Composite Material)應用較廣’其基本的組成篇 纖維及分子歸（matrix)，纖料妓複合㈣機械㈣ 的主要因素，㈣承勉要請，_微肢延伸，提違 材料剛性與抗麟及潛鱗；分子基材係由不同㈣ 樹脂麵或_，加人填料後加獨成各式各樣的塑義 ^該軸之_依其雜可分為熱隨（the_set)及 =性（thenn_stiehA_ ^早期複合材料是以数固 塑性樹脂複合材料具有製程簡易、加工變:性大點能 材料的破壞容忍度以及易於回收 b ^ 近年來研究與㈣的2料仙等❹，因此成為 優點量輕聽可塑性強的 i疲勞、抗腐鱗絕佳特性，其可廣泛應 用於航太、船舶、運輸、建材、带 ，、心 甩子、電器等設備結構中， 200842074 且有逐漸取代部分金屬材料的趨勢。然而，當以含有熱塑 性樹脂之纖維強化複合材料取代金屬時，該複合材料之機 械性此例如麗強度(compression strength)與耐磨損性 (abrasion resistance)並不如金屬佳，尤其是將此複合材料製 成需施力以作機械式彎折之物件，該複合材料易因反覆施 力折動而不斷被賴，致使物件魏性及耐祕不佳，使 其所得應用範圍受到限制。200842074 IX. INSTRUCTIONS · TECHNICAL FIELD OF THE INVENTION The present invention relates to a method for reinforcing a thermoplastic composite material, and more particularly to a fiber-reinforced thermoplastic composite material by combining a fiber-reinforced thermoplastic composite material with a metal member. A metal reinforcement method for fiber reinforced thermoplastic composites with local mechanical strength of the material. [Prior Art] A wide variety of composite materials, including Fibre Reinforced Composite Material, which is widely used as the main component of fiber and molecular matrix, fiber 妓 composite (4) machinery (4). (4) Cheng Hao should please, _ micro limb extension, lifting material rigidity and anti-lin and potential scale; molecular substrate is made of different (four) resin surface or _, adding filler and adding a variety of plastic meaning ^ the axis The _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ ^ In recent years, it has been studied with (4) 2 materials, etc., so it is an excellent feature of i-fatigue and anti-corrosion scales, which can be widely used in aerospace, shipbuilding, transportation, building materials, belts, and hearts. In the structure of equipment such as tweezers and electrical appliances, 200842074 has a tendency to gradually replace some metal materials. However, when a metal-reinforced composite material containing a thermoplastic resin is substituted for a metal, the composite material is used. Mechanical properties such as compression strength and abrasion resistance are not as good as metals, especially the composite material is made into an object that needs to be forced to be mechanically bent, and the composite material is susceptible to repeated The application of force is constantly being relied upon, resulting in the object's superiority and poor tolerance, which limits its application range.
【發明内容】 為改善纖維強化複合材料於取代金屬時，所致成品機 械性能不佳之缺點，並加強複合材料的耐雌，本發明將 提供-種纖_化熱塑性複合材料之金屬補強方法:藉由 熱塑性複合材料與金屬件之相互社人而， 人 仰反、、、口α，而達到提昇纖維強 化稷s材枓之局部機械性能，增進其缝強度與耐磨耗性 之目的。 本發明纖維強化熱塑性複合材料之金屬補強方法， 括下列步驟：提供-熱_複合材料與—金屬件；將以 件進行表面處理，藉以增進金屬件與_心 結合性；將金屬件置於-模具内㈣η I材抖間< 於金屬件上；進行轉，# & :性*合材料j 使敎塑性複= 性複合轉成型，^ :呈熔融狀而與金屬件相互. 工件。复中，#面~“ 屬件之熱塑性複合材串 、、处里係為於金屬件表面進行去一 脂處理之後，躲金料表岭佈=去除油抑 ，表面介質(primer)，而 200842074 ^面介質係為—接著促進劑，藉以增加金屬表面之接著 力’藉以促進金屬件與熱難複合材_之結合強度接者 性複合材料之金屬“方 法’可以間早快速之工序製程，達到加性 局部機械強度之目的，並提昇其_強度與耐磨 性複合材料，可用於製作需施力以 庫t進而擴增其於取代金屬製品時之 應用犯圍’同日诱低完全以金屬製作成品所需之 塑性複合材料之質輕、耐潮與抗賴等特性 亚兼備至屬般的強度及耐力度，大幅增進其實用性。 所絲合圖式進一步說明本發明的實論式，下述 ==的貫施例制關明本發明，並非用以限定本發明 =圍^何熟f此技藝者，在不脫離本發明之精神和範 以本•保護_ 【實施方式】 月同％茶閱第—圖、第二人圖與第二B圖，第一圖 實·鐘倾合獅之金屬補強方 、、备人机程不忍圖’第二A圖係本發明實施例方法中熱塑性 :::料與金屬件之示意圖，而第二B圖係本發明實施例 續⑽ΐ塑性複合材料結合金屬件之示意圖。本發明之纖 匕熱麵複合材料之金屬補財法，主要係將-熱塑 性硬合材料1〇置於一金屬件2〇上後，進行熱壓加工處 200842074 =，使熱塑性複合材料10與金屬件2〇相互結合並一體成 本發明實施例之處理方法，包括下列步驟··（^提供 -熱塑性複合材料與—金屬件S1G ;⑺將金屬件進行表面 處理S2°，藉明進金屬件與鋪性複合材料間之結合 f生（3)將孟屬件置於一模具内，並將熱塑性複合材料置於 金屬件^ S3G ’·（4)進行熱壓_，藉以使熱塑性複合材料 成型，並使麵性複合㈣之表面銳融狀而與金屬件相 互結合；以及(5)脫模S50，將結合有金屬件之熱塑性複合 材料工件由模具取出。 、於步驟S10中，熱塑性複合材料内所含纖維可為玻璃 纖維或碳纖維等纖維材質，而纖維之形式可為短纖、連續 長纖、編織纖維、及粉狀纖維等，其中又以具有良好強= 性之連續長纖為較佳；熱塑性複合材料内所含基材則可為 聚對苯二甲酸乙二醇酯（polyethylene terephtMah PET )、聚醯胺(polyamide，PA)、聚甲基丙烯酸甲醋 (polymethylmethacrylic，PMMA)、以及聚碳酸醋 (polycarbonate，PC)等熱塑性樹脂’而上述熱塑性複合材料 中纖維及基材僅係例示，並不以此為限，任何具有較佳強 度或所需特性之纖維材質，以及於加熱熔融時可流動之熱 塑性潜ί脂種類，皆可應用於此。而金屬件之材質可為鋁^ 鐵、、不鏽鋼、合金或其他金屬物質等。 於步驟S20中，表面處理過程係為先於金屬件表面進 行去除油污之脫脂處理，避免該些油污雜質干擾金屬件與 200842074 ^ = 5材制之結合，此麟處理謂舰脂劑去除 二萄件表面的油污，而所用脫脂劑可為有機溶劑、乳化 弹卜早-驗之溶㈣含絲面雜社複錯性介質，例 $ 3有表面雜泰純驗、獅曼三鈉、娃酸鈉、氫氧化納 等組成之複合雖介質，而上述赌方式及赌劑成份於 此僅係例示，並不以此為限’凡是可進行脫脂之方法以及 可有效脫脂之麟㈣可制於此。接著，於經脫脂處理 後之金屬件表面塗佈—表面介f (primei·)，職表面介質係 為一接著促進劑’其係由樹脂、界面活性劑及接著劑混合 組成之，可藉由改變被接著物表面之極性，進而增加金屬 表面之接著力，藉以提升金屬件與熱塑性複合材料間之接 者強度’並促進兩者之結合。 於步驟S30中，可先將金屬件依製程需求及用途而加 工，所需構型，再置於適當模具内，而此模具係可根據成 品實際應用時所需造型而設計，此時將熱塑性複合材料置 於金屬件上，以便進行後續步驟。 於熱壓S40過程中，係藉由加熱及施壓而使熱塑性複 合材料與金屬件相互結合’該步驟中之加熱處理可軟化熱 塑性複合材料，以便於之後施壓時，可使熱塑性複合材料 依模具型態而形成預定構型，且加熱程度需達可使熱塑性 複合村料表面呈溶融態之溫度，以利於熱塑性複合材料I 金屬件間之緊密結合，此時加壓使熱塑性複合材料與金屬 件相互結合並一體成型，其中，熱壓時其他細部程序係一 般業界習用之技術，於此並不進一步說明。此外，若欲將 200842074 熱塑性複合材料製成需施力以作機械式彎折之成品例如 厚型門靡開闕把手、騎車煞車手把等零組件時，可將全 屬件結合於熱塑性複合材料上需承力而f折作動處，以提 咼該處之耐磨損性及強度。 龍壓成狀熱塑性複合㈣與金屬伽結冷卻 後，便可進行賴S5G ’模具，並雜合有金屬件之 . 熱塑性複合材料成品自模具中取出，而脫模之詳細步驟係 . 一般業界習用之技術，於此並不進一步說明。 #合金屬件触之工序步賴便錢H由金屬件 之結合可增進熱塑性複合材料之壓縮強度與耐磨耗性等 機械性能，並可使其取代金屬製品時之應用範圍更廣泛， 藉以減少金屬用量而降低製作成本，同時保有金屬強度及 耐用性，使其在利用與使用上更為普及。 【圖式簡單說明】 率圖係本發明實施例纖維強化熱塑性複合材料之金屬 補強方法的流程示意圖。 第二A圖係本發明實施例方法中熱塑性複合材料與金屬 件之示意圖。 第二β圖係本發明實施例方法中熱塑性複合材料結合金屬 件之示意圖。 "口 【主要元件符號說明】 200842074 . 10 熱塑性複合材料 、 20 金屬件 S10 提供一熱塑性複合材料與一金屬件 S20 金脣件表面處理 S30 將熱塑性複合材料置於金屬件上 ^ S40 熱壓成型 S50 脫模 11SUMMARY OF THE INVENTION In order to improve the shortcomings of the fiber-reinforced composite material in replacing the metal, resulting in poor mechanical properties of the finished product, and to enhance the resistance of the composite material to the female, the present invention will provide a metal reinforcing method for the fiber-based thermoplastic composite material: The thermoplastic composite material and the metal parts are mutually friendly, and the human body is inverted, and the mouth α is used to achieve the purpose of improving the local mechanical properties of the fiber-reinforced 稷 s material and improving the seam strength and wear resistance. The metal reinforcing method for the fiber-reinforced thermoplastic composite material of the present invention comprises the following steps: providing a heat-composite material and a metal member; and surface-treating the member to improve the bonding of the metal member and the core; placing the metal member at - In the mold (4) η I material shaking room < on the metal parts; carry out, # & : sex * material j to make the plastic complex = composite composite transformation molding, ^: molten and metal parts to each other. Fuzhong, #面~" The thermoplastic composite string of the parts, after the de-fatting treatment on the surface of the metal parts, hiding the gold material ridge cloth = removing the oil, the surface medium (primer), and 200842074 ^Face medium is--the accelerator, in order to increase the adhesion of the metal surface, so as to promote the bonding strength of the metal part and the heat-resistant composite material. The metal "method" of the composite material can be processed quickly and quickly. The purpose of additive local mechanical strength, and to enhance its _ strength and wear resistance composite materials, can be used to make the application of force to expand the use of the library in order to expand its use in the replacement of metal products. The plastic composite material required for the finished product has the characteristics of light weight, moisture resistance and repellency, and has the same strength and resistance, which greatly enhances its practicability. The present invention is further described in the context of the present invention, and the following examples of the invention are not intended to limit the invention, and the present invention is not deviated from the present invention. Spirit and Fan by the protection of the _ [Implementation] Monthly with the % tea reading the first - map, the second person map and the second B map, the first map of the real clock lion and the metal reinforcement, the preparation of the machine can not bear Fig. 2A is a schematic view of a thermoplastic:: material and a metal part in the method of the embodiment of the present invention, and a second B is a schematic view of the (10) ΐ plastic composite material combined with the metal part according to the embodiment of the present invention. The metal filling method of the fiber-reinforced hot surface composite material of the invention mainly comprises placing the thermoplastic hard bonding material 1〇 on a metal piece 2,, and performing hot pressing processing at 200842074 = to make the thermoplastic composite material 10 and the metal The two parts are combined with each other and integrated into the treatment method of the embodiment of the invention, including the following steps: (providing - thermoplastic composite material and - metal part S1G; (7) surface treatment of metal parts S2 °, by means of metal parts and paving The combination of the composite materials (3) puts the Meng component in a mold, and places the thermoplastic composite material on the metal part ^S3G '·(4) for hot pressing_, thereby molding the thermoplastic composite material, and The surface of the planar composite (4) is sharply melted and combined with the metal member; and (5) the mold release S50, the thermoplastic composite workpiece combined with the metal member is taken out from the mold. In step S10, the thermoplastic composite material is The fiber-containing material may be a fiber material such as glass fiber or carbon fiber, and the fiber may be in the form of short fiber, continuous long fiber, woven fiber, and powder fiber, and the continuous filament having good strength = The substrate contained in the thermoplastic composite material may be polyethylene terephtMah PET, polyamide (PA), polymethylmethacrylic (PMMA), and poly a thermoplastic resin such as polycarbonate (PC), and the fibers and the substrate in the above thermoplastic composite are merely exemplified, and not limited thereto, any fiber material having better strength or desired properties, and when heated and melted The flowable thermoplastic latent grease type can be applied thereto, and the metal member can be made of aluminum, iron, stainless steel, alloy or other metal materials, etc. In step S20, the surface treatment process is preceded by the metal parts. The surface is degreased to remove oil stains, so as to prevent the oily impurities from interfering with the combination of the metal parts and the 200842074^=5 material system. The lining treatment means that the grease removes the oil on the surface of the two parts, and the degreasing agent used may be an organic solvent. Emulsified bombs early-tested dissolution (4) containing silk-faced miscellaneous media, such as $3 has a surface of miscellaneous pure test, Shiman trisodium, sodium silicate, sodium hydroxide and other components The medium, and the above-mentioned gambling methods and gambling ingredients are merely exemplified herein, and are not limited thereto. Any method capable of degreasing and lining which can be effectively degreased can be made here. Next, the metal after degreasing treatment Surface coating - surface me (primei), the surface medium is a follow-up accelerator' which is composed of a mixture of a resin, a surfactant and an adhesive, which can be changed by changing the polarity of the surface of the substrate. Increasing the adhesion of the metal surface, thereby improving the strength between the metal member and the thermoplastic composite material' and promoting the combination of the two. In step S30, the metal member can be processed according to the process requirements and uses, and the desired configuration is required. Then, it is placed in a suitable mold, and the mold can be designed according to the shape required for the actual application of the finished product. At this time, the thermoplastic composite material is placed on the metal member for the subsequent steps. In the process of hot pressing S40, the thermoplastic composite material and the metal member are combined by heating and pressing. The heat treatment in the step can soften the thermoplastic composite material, so that when the pressure is applied, the thermoplastic composite material can be The mold type forms a predetermined configuration, and the degree of heating needs to reach a temperature at which the surface of the thermoplastic composite material is dissolved, so as to facilitate the tight bonding between the thermoplastic composite material I, and the thermoplastic composite material and the metal are pressed at this time. The pieces are combined and integrally formed, and other detailed procedures during hot pressing are generally used in the industry, and are not further described herein. In addition, if the 200842074 thermoplastic composite material is to be made into a product that needs to be applied for mechanical bending, such as a thick sill opening handle, a bicycle handlebar handle, and the like, the whole component can be combined with the thermoplastic composite. The material needs to bear the force and f fold to improve the wear resistance and strength of the place. The thermoplastic composite (4) and the metal condensate are cooled, and then the S5G 'mold can be used, and the metal parts are mixed. The thermoplastic composite material is taken out from the mold, and the detailed steps of the demoulding are. The technology is not further explained here. #合金属件接触的步骤步钱钱H The combination of metal parts can improve the mechanical properties such as compressive strength and wear resistance of thermoplastic composite materials, and can be used in a wider range of applications when replacing metal products, thereby reducing The amount of metal is used to reduce the manufacturing cost, while maintaining the strength and durability of the metal, making it more popular in use and use. BRIEF DESCRIPTION OF THE DRAWINGS The rate chart is a schematic flow chart of a metal reinforcing method for a fiber-reinforced thermoplastic composite material according to an embodiment of the present invention. The second A is a schematic view of a thermoplastic composite material and a metal member in the method of the embodiment of the present invention. The second beta diagram is a schematic representation of a thermoplastic composite bonded metal component in a method of the present invention. "口【Main component symbol description】 200842074 . 10 Thermoplastic composite material, 20 Metal parts S10 Provide a thermoplastic composite material and a metal part S20 Gold lip surface treatment S30 Put thermoplastic composite material on metal parts ^ S40 Hot press forming S50 stripping 11