TW200837241A - Composite nonwoven with improved dimensional recovery - Google Patents

Composite nonwoven with improved dimensional recovery Download PDF

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Publication number
TW200837241A
TW200837241A TW096133827A TW96133827A TW200837241A TW 200837241 A TW200837241 A TW 200837241A TW 096133827 A TW096133827 A TW 096133827A TW 96133827 A TW96133827 A TW 96133827A TW 200837241 A TW200837241 A TW 200837241A
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Taiwan
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woven
fibers
fiber
web
composite
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TW096133827A
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Chinese (zh)
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Amato Raymond A D
Rui B Ferreira
Larry L Kinn
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Ahlstroem Oy
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/005Mechanical treatment
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/48Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation
    • D04H1/485Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation in combination with weld-bonding
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/492Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/498Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres entanglement of layered webs
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/14Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic yarns or filaments produced by welding
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/16Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/12Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/02Synthetic cellulose fibres
    • D21H13/04Cellulose ethers
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/02Synthetic cellulose fibres
    • D21H13/06Cellulose esters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10Organic non-cellulose fibres
    • D21H13/12Organic non-cellulose fibres from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H13/14Polyalkenes, e.g. polystyrene polyethylene
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10Organic non-cellulose fibres
    • D21H13/20Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H13/24Polyesters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10Organic non-cellulose fibres
    • D21H13/20Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H13/26Polyamides; Polyimides
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/10Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Nonwoven Fabrics (AREA)

Abstract

This invention relates to a micro-creped composite nonwoven having improved dimensional and thermal recovery (low distortion) allowing it to continuously adjust under dynamic end use conditions. This product incorporates the following properties: ease of tension, absorbency, breathability, launderability, stitch holding, strength and web uniformity. The end uses envisioned for this type of product include waistband and other interliners for the apparel market, sports and medical tapes, wraps and bandages, and functional packaging materials.

Description

200837241 九、發明說明: 【發明所屬之技術領域】 【先前技術】 彈性材料廣泛使用於各種應用,包括腰帶內裡、醫 療包裹物與繃帶、以及功能性包紮材料。彈性材料比非 彈性產品更具優勢,包括其對身體結構與移動的舒適 性,像是腰帶應用與醫療包裹物。此外,當彈性材料用 在醫療包裹物或繃帶時,藉施以定壓於受創或受傷區域 以提供醫療的舒適感。在醫療包裹物或繃帶應用上,爲 加速療效,彈性材料亦需具備透氣性使氧氣可傳送至受 傷區域並使水蒸氣與其他氣體自受傷區域逸散,以及具 備吸收力使血液與傷口分泌物可藉與繃帶直接接觸自 受傷區域移除。當彈性材料吸滿局部藥膏與其它治療處 理如:麻醉劑與後續治療敷劑時,亦須具備吸收力。 於服裝應用上如腰帶內裡或繡花底布,彈性材料的 優勢在於可變換吃紗成形、具高張力強度且在不破壞與 失去其彈性特質下可重複洗滌與適用乾洗程序。此產物 另一特徵爲當其在機械方向(MD direction)拉伸時, 在橫向方向(CD direction)上必須不減少或僅最少長 度減少。這在服裝應用上尤其重要,一些先前技術所使 用的材料在拉伸時傾向於橫向方向縮減長度,造成腰帶 外觀扭曲。通常當材料於一方向延伸時,會傾向於其他 兩個方向變薄(以材料的波森比描述)。具一些或所有 這些特質的彈性材料可用在這些範疇:服裝內裡、醫療 200837241 包裹物與繃帶、或功能性包紮領域。然而實務上提供具 一些或所有這些特質的彈性材料是困難的。 例如:由於不織布的可回復彈性延伸的限制,成衣 工業求助於昂貴的腰帶內裡如使用45度斜紋切割的梭 織物、或使用針織物、或使用含連續彈性體纖維的網、 或使用彈性體薄膜、或使用各式微網、或應用允許滑動 的重疊纖維區段的複雜腰帶設計。在醫療包裹物或繃帶 應用上,亦嚐試賦予可回復彈性材料特質吸收力、透氣 性與強度。 除了編入彈性材料層或纖維使得非織網之拉伸可 回復,其他方式爲對不織布縐處理或微縐處理。於縐處 理時,非織網附著至一總表面並使用刮刀自該表面移 除。於微縐處理時,當其在滾輪上移動或自其移除時, 藉由阻滯與壓縮該網達到非織網的可回復延伸特性。 不過’各種應用市場仍持續尋找合適的可回復延伸 非織材料’結合了其他所需應用特性並維持有經濟效益 花費在與簡單生產程序。 【發明內容】 定義 雙成份纖維或長絲(bicomponent fiber or filament):自各別的擠壓機擠壓聚合物源並同時紡出 以形成單束的纖維或長絲,藉此形成複合纖維或長絲。 通常會擠壓兩不同的聚合物,雖然雙成份纖維或長絲可 包括相同聚合物材料自不同擠壓機擠出的壓製品。擠出 -6- 200837241 的聚合物實質上安排在位於橫過雙成份纖維或長絲的 斷面的區分區域(distinct zone),且實質上沿著雙成 份纖維或長絲的長度連續延伸。雙成份纖維或長絲的結 構可爲對稱(如:鞘芯型或並排型)或不對稱(如:鞘 芯型平板印刷;整體爲圓形而纖維爲新月圖案。)。兩 種聚合物源的比例可爲例如(但非絕對)7 5/25、5 0/5 0、 25/75。 雙組成纖維(b i c ο n s t i t u e n t f i b e r ):混合兩或多種 自相同紡嘴擠壓出的聚合物形成的一種纖維。雙組成纖 維不具多種聚合物組成安排在相對位於橫過纖維的斷 面區的區分區域,且多種聚合物通常亦不沿著纖維總長 度連續,原纖維形成通常是隨機地開始與結束。雙組成 纖維有時候也稱作多組成纖維。 軋光(c a 1 e n d e r i n g ): —種於相對表面間壓製非織 材料表面的製程。相對表面包含平板壓盤與滾筒。可對 任一或兩相對表面加熱。任一或兩相對表面可含凸部。 纖維素材料(cellulose material):實質上包含纖 維素的一種材料。纖維素纖維來自人造來源(例如:再 生纖維素纖維或萊賽爾纖維)或天然來源如:纖維或木 本與非木本植物紙漿。木本植物含,例如落葉木與結毬 果樹。非木本植物含,例如棉、亞麻、非洲羽芒、西波 爾麻、馬尼拉麻、馬利筋、稻草、黃麻、大麻、與甘蔗 渣。 複合纖維或長絲(conjugate fiber or filament): 200837241 自不同擠壓機擠壓聚合物源並同時紡出以形成單束的 纖維或長絲,藉此形成纖維或長絲。複合纖維使用兩或 多種來自不同擠壓機的聚合物。通常擠壓聚合物實質安 排在位於橫過複合纖維或長絲的斷面的區分區域,且實 質上沿著複合纖維或長絲的長度連續延伸。複合纖維或 長絲的的形狀可爲任何形狀,只要方便生產者之所需應 用即可,如圓形、三葉、三角、狗骨型、平板或空心。 總處理與微縐處理(Creping and microcreping): 一種於機械方向緊實非織網的製程,添加至網上的一系 列一般不連續的小平行摺層。微縐處理與縐處理不同處 主要在於所附與摺層的尺寸。 橫向機器方向(CD) ( cross machine direction):此 方向垂直於機械方向。 丹尼(Denier ): —種用來定義長絲細度的單位, 以9 0 0 0公尺長絲的公克重量爲準。1丹尼的9 000公尺 長絲具有1公克質量。 垂墜性(D r a p e ):懸掛材料產生寬鬆或鬆垮縐摺 的能力。 彈性材料(Elastic Material ): —種可拉伸的材料, 特別指當施力釋放時會因延展性回復原來形狀或尺寸。 纖維(Fiber):特徵爲極高的長度與半徑比率的一 種材料。如文中所示’除非特別指明,纖維與長絲爲可 互換的。 長絲(Filament ):實質上爲連續的一種纖維。如 200837241 文中所示,除非特別指明,纖維與長絲爲可互換的。 硬木漿(Hardwood pulps):任何源自落葉木的纖 維材料,其經由機械方法像是紙漿硏磨機、或化學方式 如在高溫高壓下使用各種烹飪酒精,還原成其組成成 分。落葉木包含如赤楊、樺木、桉樹、橡樹、楊木、西 克莫無花果、香楓與胡桃木。 熱固定(Heat setting):於基材上使用熱與壓力以 完成某些所需效果的一種製程。在合成纖維製成的纖維 上,熱固定用來防止收縮或產生在洗滌或乾洗後會保留 下來的縐痕或摺襴。 水力纏絡(H y d r 〇 e n t a n g 1 e m e n t ):使用細、高壓水 噴射以使非織纖維交錯。水力纏絡即所知的水織 (s p u η 1 a c i n g ),藉由安排噴射水流可得到各式討喜的 美感效果。所·使用的水柱壓力通常與網的強度具直接關 聯,但系統設計亦佔重要因素。不同特性的非織網可水 力纏絡在一起以產生難以藉其他方式達到不同特性等 級的非織複合物。 天絲纖維(Lyocell):藉由直接溶解纖維素於有機 溶劑中,無須形成中間產物,接著將纖維素溶液及有機 溶劑擠出至凝固浴中所製得的人造纖維素材料。 機械方向(MD)(Machine direction):形成非織網材 料時,形成表面在纖維或長絲沉積方向上的移動方向。 機械粘合(Mechanical Bonding):在機械粘合中, 非織網的強度藉纖維物理纏絡所產生的纖維間摩擦力 -9- 200837241 達到。機械粘合有兩種形式’水力纏結即所知水力纏絡 與針軋。 、 熔吹纖維(Meltblown fiber):—種纖維’其係自 複數個細密的,通常爲環形的毛細管模擠出熔融熱塑性 材料作爲長絲進入高速氣體(如空氣)流而形成,高速 氣體流可使熔融熱塑材料長絲變細以降低其半徑。接著 高速氣體流乘載熔吹纖維並沉積於收集表面以形成隨 機分散熔吹纖維網。熔吹纖維一般爲連續的。熔吹程序 包括熔噴程序。 天然纖維漿(Natural fiber pulps):任何來自非木 質植物的纖維材料,經由機械方法像是紙漿硏磨機、或 化學方式如在高溫高壓下使用各種烹飪酒精,還原成其 組成成分。非木質植物包含如棉、亞麻、非洲羽芒、瓊 麻、馬尼拉麻、馬利筋、稻草、黃痲、大麻、與甘蔗渣。 針軋(N e e d 1 e p u n c h i n g ):在針軋中,特殊設計的 針於非織網上推進與拉出以交纏纖維。該網通常藉梳棉 完成但亦可包含紡粘(s p u η 1 a i d )與較少使用的濕粘網 (w e 11 a i d w e b s )。針軋可用於大部分纖維種類。 非熱塑型聚合物(Non-thermoplastic p〇lymer):任 何不屬於熱塑型聚合物定義的聚合物材料。 非織纖維、片與網(Nonwoven fabries,sheet and w e b ): —種具各自內交錯纖維結構的材料,但可識別 其形式非織布或針織纖維。非織材料可藉許多_ |呈形$ 如熔吹、紡粘(spunbonding )、梳棉與濕式佈層製程。 -10- 200837241 非織纖維的基礎重量通常以每平方公尺克重量(gsm) 表示。 聚合物(Polymer)- —種重複有機結構單元的長鏈 包含熱塑型與非熱塑型聚合物。通常含如均聚物,共聚 物例如嵌段、接枝、隨機與交替共聚合物,三聚物等等, 以及其混合與變形。此外,除非另特別限制,該項「聚 合物」含所有可能幾何形狀。幾何形狀可含例如同排、 對排與隨機對稱。 9 再生纖維素(Regeneratedcellulose):藉由對天然 纖維素做化學處理,形成可溶的化學衍生物或中間產物 並接著分解衍生物以產生纖維素而得到的造纖維素。再 生纖維素包含嫘縈紗而再生纖維素製程包含乙醯纖維 素的膠絲製造法(the viscose process)、銅錢法(the cuprammonium process )與巷化 ° 軟木漿(Softwood pulps):來自針葉樹的任何纖 維材料,經由機械方法像是紙漿硏磨機、或化學方式如 @ 在局溫局壓下使用多種录、飪酒精,還原成其構成成分。 針葉樹包含如西洋杉、冷杉、鐵杉、松樹與雲杉。 紡粘長絲(S p u n b ο n d f i 1 a m e n t ):藉由自複數個細 密的,通常爲環形的毛細管模紡嘴擠出熔融熱塑性材料 所形成的長絲。擠出長絲的半徑可藉例如噴射拉伸 (eductive drawing )及/或熟知的紡粘機構隨之快速降 低。紡粘纖維可具單尼範圍介於約〇· 1至5或更高且從 非織網的一端至相對端實質上爲連續。 -11- 200837241 紡粘非織網(Spunbond nonowoven web):(通常) 於單一製程中,自複數個細密的,通常爲環狀的毛細管 紡嘴中擠出至少一種熔融熱塑型材料做爲複數條長絲 所形成的網。長絲係部份退.火,然後拉伸以降低纖維的 丹尼’並提高纖維中分子的順向度。長絲通常爲連續且 當其沉積於收集表面上爲纖維狀棉絮時爲非黏的。接著 藉例如熱黏合、化學粘合劑、機械針軋、水力纏絡或其 組合黏合纖維狀棉絮以產生非織纖維。 短纖維(Staple fiber):形成或裁成纖維長度通常 爲1/4至8吋的一種纖維(0·6至20cm)。 實質上連續(substantially continuous):對於非織 網的聚合長絲,意指大多數藉由自噴孔擠出所形成的長 絲或纖維,在拉伸並接著裝塡在收集裝置時,仍維持連 續未斷裂之細絲。一些長絲可能在變細或拉伸製程中斷 裂,而實質上大多數的長絲仍維持完整的片的長度。 合成纖維(Synthetic fiber):包含人造材料如玻 璃、聚合物或聚合物之組合、金屬、碳、再生纖維素與 天絲纖維的一種纖維。 特克斯(Tex ):—種用來標示長絲細度的單位, 以每1 000公尺長絲的克重量表示。1特克斯的長絲指長 度1000公尺的長絲具1克重量。 熱塑型聚合物(Thermoplastic polymer):可熔化的 聚合物,當其暴露於熱時會軟化且冷卻至室溫時通常會 回復至其非軟化態。熱塑型材料包含如聚氯乙烯、一些 -12- 200837241 聚酯、聚醯胺、聚氟碳化物、聚烯烴、一些聚氨酯、聚 苯乙烯、聚乙烯醇、乙烯與至少一乙烯基單體(如:聚 (乙烯·醋酸乙烯酯))與壓克力樹脂的共聚合物。 網粘合(Web Bonding ):非織網,除了紡粘,在 其未黏合時具些微強度且需藉粘合加強。三種基本粘合 方式爲熱粘合、化學粘合與機械粘合。方式選擇的重要 性至少如網中纖維種類般影響其功能特性。 於一實施例之揭露提供了具可回復彈性拉伸的彈 ^ 性非織複合材料,其亦具高耐久性,這在服裝應用上爲 有利的,特別是在洗滌、乾燥及/或乾洗時的低或不收 縮。於另一實施例中之揭露則提供了具良好吸收性、柔 軟性與透氣性的彈性非織複合材料,其可使用在醫療與 運動包裹物、繃帶與線帶應用。 已發現微縐處理一水力纏絡的非織複合材料,其有 利的具有兩或多種非織部份,結合熱固定可達可回復彈 $ 性伸展之所需特性,使用之耐久性且仍具有整體良好吸 收性、柔軟性與透氣性。使用之耐久性之特徵爲洗滌、 乾洗、重複使用或長時間伸展後之完整回復性。此外更 發現藉由適當選擇粘合劑,產物可更有利的提供柔軟與 舒適,例如用在醫療應用、或提供耐用與不易移動例如 用在腰帶內裡應用。 一般而言,揭露之組成物與步驟可替代的調配以包 含、構成或本質上構成具有任何適當成分或此處揭露之 製程。組成物與步驟可爲附加或互換的,以便於配方中 •13- 200837241 缺少或實質上不具備任何成分、材料、組成、輔劑、使 用於習知技術的種類或製程,或此外對功能性達成及/ 或本發明目的爲非必要。 文中所使用的「約」意指數量或狀態修正可超出其 揭露只要其揭露優勢爲可理解的。 本發明可藉下列詳細描述、圖解、本發明實施例得 到較佳理解。 【實施方式】 ® 在一實施例中,彈性複合非織材料包含應用至第二 非織纖維底材的第一濕式(wet-formed )非織纖維部份。 第二非織底材爲預粘合網,如梳棉針織網、紡粘網 或梳棉水力纏絡網(通常表示爲水織)。非織底網基礎 重量可介於約15至約150g/m2,具底材之優勢爲基礎重 量可介於約20至約90g/m2。非織底材的優勢在於包含實 質爲連續之合成長絲如紡粘不織布,或由經機械紡粘的 φ 不連續梳棉短纖維構成如針乳或水力纏絡網。預紡黏之 型式一般不認爲是重要的。對熱粘合紡粘網而言,對點 紡粘(p q i n t b ο n e d )底材的紡粘區域低達約7 %與對平面 紡粘(flat boned)底材高至100%之預紡粘程度與型式 將改變。較佳非織底材爲點紡粘且一般具紡粘區域約1 〇 至約2 0 %。 第二非織底材纖維可含數個商業可得材料。有利地 底材纖維包括聚酯、聚醯胺與聚烯烴如聚乙烯與聚丙 烯、然而亦可使用其他纖維材料如嫘縈、棉、聚乳酸、 -14- 200837241 乙醯纖維素與壓克力。 濕式非織纖維第一部份包含合成短纖維、天然漿或 天然纖維與視需要地其他塡料及/或添加劑之混合物。塡 料及其他添加劑可在分散液形成時與流體與纖維結合以 添加不同期望的特性於形成的複合不織布。例如:當最 終產物用在醫療領域時,其可能需與塡料混合以具備生 物上有利的特性。材料如分子篩或類似化合物提供位置 吸引或留住合倂在濕式非織層的生物組成物,其幫助不 ® 織布所使用的環境維持無菌狀態。當然塡料量必須控制 在一定數量,使其不致對所需柔軟性、垂墜性與最終產 物的觸感造成不良影響。 第一非織纖維部份爲濕式。其典型包含形成必要的 纖維、紙漿與其他材料之流體分散液的一般步驟。流體 分散液沉積於有孔部件如纖維收集金屬網。一般透有孔 部件自分散液抽取流體以形成連續片狀的網材料。形成 ^ 的濕式網材料可使用已知方法如加熱罐、烘箱或加熱氣 體進一步乾燥。濕式非織網因其本質上尺寸穩定特性與 異方性特質爲較佳。第一濕式非織纖維部份可組成一般 實際用在提供不同功能特性至名子層的多層。 第一濕式非織纖維部份其優勢在於具範圍在約20 至約100g/m2的克數,其中最終產物在乾縐處理前的克數 範圍在約3 5至約2 5 0 g /m2,較佳爲範圍在3 5 - 1 60 g/m2。 封服裝應用而留’弟一'濕式非織纖維部份較佳含約1 0至 100%的軟木或硬木或其組合的天然漿,而剩餘纖維爲合 •15- 200837241 成纖維。其他應用可以預見其需要100 %合成纖維以預防 歸咎於纖維素纖維的外觀髒汙問題。較佳的合成纖維爲 聚酯如聚對苯二甲酸乙烯酯(PET),自約1至約6丹尼, 以約1.5丹尼爲佳;具纖維長度範圍爲約0.25至約0.75 吋(約6至約20mm ),以約0 · 25吋爲佳(約6mm )。 其他適當的合成纖維包含但不限於以聚烯烴爲來源的如 聚乙烯與聚丙烯、聚醯胺與嫘縈。 天然漿基本上可選自任一種漿與其摻合物。較佳的 ® 漿全部皆爲天然纖維素纖維且可含木質纖維如棉,雖軟 木製紙漿如雲杉、鐵杉、西洋杉、與松爲較佳,一般與 硬木製紙漿如桉樹組合使用。亦可使用非木漿如瓊麻、 洋麻、馬尼拉麻與其他。天然漿至多可爲最終產物重量 之約7 5 %,包括纖維、底網與粘合劑組成物。天然漿的 量可實質上基於複合系統中其他組成物與最終產物之需 求,如當所產生的複合不織布使用於醫療繃帶應用時所 ^ 需顯示之阻障能力。 第一非織纖維部份直接施用在第二非織底材。於一 實施例中,第一濕式非織纖維部份之材料分散於流體中 且該分散液施用在第二非織底材上。自第一非織纖維部 份提取流體以提供濕式複合材料。另一實施例中,第一 非織纖維部份沉積於有孔部件上如纖維收集網。自分散 液提取流體,通常經由有孔部件,以形成連續片狀的網 材料。形成的濕式網材料可用已知方法如加熱罐、烘箱 或加熱氣體進一步乾燥,以提供預先形成的第一非織纖 -16- 200837241 維邰份。預先形成的第一濕式非織纖維部份施用在第 非織底材以提供複合材料。 施用第一纖維部份至第二底材後,對複合材料施以 低至中壓水力纏絡操作如Viazmensky等人發佈的美國專 利案號Νο·5,009,747所述之型式,其全文在此倂入參考 資料。藉一連串流體噴射通過複合材料,以足夠力量直 底材 接冲擊第 並與之 而乂·纏兀成水力纏絡操作。使用一^連串或—^排200837241 IX. Description of the invention: [Technical field to which the invention pertains] [Prior Art] Elastic materials are widely used in various applications, including belt linings, medical wraps and bandages, and functional dressing materials. Elastic materials have advantages over non-elastic products, including their comfort for body structure and movement, such as belt applications and medical wraps. In addition, when the elastic material is used in a medical wrap or bandage, it is applied to the injured or injured area to provide medical comfort. In medical wraps or bandage applications, in order to accelerate the efficacy, the elastic material also needs to be breathable so that oxygen can be transported to the injured area and the water vapor and other gases escape from the injured area, and the absorption of blood and wound secretions It can be removed from the injured area by direct contact with the bandage. Absorptive force is also required when the elastic material is filled with topical ointments and other treatments such as anesthetics and subsequent treatment dressings. For apparel applications such as belt linings or embroidered base fabrics, the advantage of elastomeric materials is that they can be converted into yarn-forming, have high tensile strength and can be re-washed and applied dry-cleaning procedures without damaging or losing their elastic properties. Another feature of this product is that it must not decrease or only decrease in length in the CD direction when it is stretched in the MD direction. This is especially important in apparel applications where some of the materials used in the prior art tend to reduce the length in the transverse direction when stretched, causing the waistband to be distorted. Usually when the material is extended in one direction, it tends to be thinner in the other two directions (described by the material's Poisson ratio). Elastic materials with some or all of these qualities can be used in these areas: garment lining, medical 200837241 wraps and bandages, or functional dressing. However, it is practical to provide elastic materials with some or all of these qualities. For example, due to the limited elastically retractable stretch of non-woven fabrics, the garment industry resorts to expensive belts such as woven fabrics that use 45 degree twill cuts, or the use of knits, or the use of webs containing continuous elastomeric fibers, or the use of elastomeric films. Or use a variety of microgrids, or apply a complex waistband design that allows for overlapping overlapping fiber sections. In medical wraps or bandage applications, attempts have also been made to impart resilience, breathability and strength to resilient elastomeric materials. In addition to being woven into the elastic material layer or fibers, the stretching of the nonwoven web can be recovered, and the other methods are non-woven fabric treatment or micro-twisting treatment. During processing, the nonwoven web is attached to a total surface and removed from the surface using a doctor blade. Upon micro-twisting, as it moves over or removes from the roller, the retractable extension of the nonwoven web is achieved by retarding and compressing the web. However, 'various application markets continue to look for suitable recyclable extended non-woven materials' that combines other desirable application characteristics and maintains cost-effectiveness with simple production processes. SUMMARY OF THE INVENTION Definition of bicomponent fiber or filament: extruding a polymer source from a separate extruder and simultaneously spinning to form a single bundle of fibers or filaments, thereby forming a composite fiber or length wire. Two different polymers are typically extruded, although bicomponent fibers or filaments may comprise compacts extruded from different extruders of the same polymeric material. The polymer extruded -6-200837241 is arranged substantially in a distinct zone across the cross-section of the bicomponent fibers or filaments and extends substantially continuously along the length of the bicomponent fibers or filaments. The structure of the bicomponent fibers or filaments may be symmetrical (e.g., sheath-core or side-by-side) or asymmetrical (e.g., sheath-type lithography; the whole is circular and the fibers are crescent moon patterns). The ratio of the two polymer sources can be, for example, but not absolute, 7 5/25, 5 0/5 0, 25/75. A bicomponent fiber (b i c ο n s t i t u e n t f i b e r ): a fiber formed by mixing two or more polymers extruded from the same spinning nozzle. The bicomponent fibers do not have a plurality of polymer compositions arranged in a distinct region that is relatively transverse to the cross-sectional area of the fibers, and the plurality of polymers are generally not continuous along the total length of the fibers, and fibril formation typically begins and ends randomly. Double-component fibers are sometimes referred to as multi-component fibers. Calendering (c a 1 e n d e r i n g ): a process for pressing the surface of a non-woven material between opposing surfaces. The opposite surface contains a flat platen and a roller. Any or both of the opposing surfaces can be heated. Any one or both of the opposing surfaces may include protrusions. Cellulosic material: A material that substantially contains cellulose. Cellulose fibers are derived from artificial sources (e.g., regenerated cellulose fibers or lyocell fibers) or natural sources such as fibers or wood and non-woody plant pulp. Woody plants contain, for example, deciduous and knotted fruit trees. Non-woody plants, such as cotton, flax, African feathers, sultans, manila hemp, milkweed, straw, jute, hemp, and sugar cane. Conjugated fiber or filament: 200837241 Extrusion of a polymer source from different extruders and simultaneous spinning to form a single bundle of fibers or filaments, thereby forming fibers or filaments. The composite fiber uses two or more polymers from different extruders. Typically the extruded polymer is disposed substantially in a distinct region at the cross-section across the composite fibers or filaments and extends substantially continuously along the length of the composite fibers or filaments. The shape of the composite fiber or filament may be any shape as long as it is convenient for the manufacturer, such as a circular, trilobal, triangular, dog bone type, flat plate or hollow. Creping and microcreping: A process of compacting a non-woven net in a mechanical direction, adding a series of generally discontinuous small parallel folds to the web. The difference between the micro-twisting treatment and the enamel treatment is mainly in the size of the attached and folded layers. Cross machine direction: This direction is perpendicular to the machine direction. Denier: A unit used to define the fineness of filaments, based on the weight of the gramm filaments of 9000 meters. 1 Danny's 9 000 m filament has a mass of 1 g. Drape (D r a p e ): The ability of the suspension material to produce loose or loose folds. Elastic Material: A stretchable material, especially when the force is released, it will return to its original shape or size due to ductility. Fiber: A material characterized by an extremely high ratio of length to radius. As indicated herein, fibers and filaments are interchangeable unless otherwise indicated. Filament: A fiber that is substantially continuous. As indicated in the text 200837241, the fibers and filaments are interchangeable unless otherwise specified. Hardwood pulps: Any fibrous material derived from deciduous wood that is reduced to its constituents by mechanical means such as a pulp honing machine or by chemical means such as high temperature and pressure using various cooking alcohols. Deciduous trees include such as alder, birch, eucalyptus, oak, poplar, sycamore fig, fragrant maple and walnut. Heat setting: A process in which heat and pressure are applied to a substrate to accomplish certain desired effects. On fibers made of synthetic fibers, heat is fixed to prevent shrinkage or to cause scars or creases that may remain after washing or dry cleaning. Hydraulic entanglement (H y d r 〇 e n t a n g 1 e m e n t): Fine, high-pressure water jet is used to stagger the non-woven fibers. Hydraulic entanglement is known as water weave (s p u η 1 a c i n g ), and by arranging the jet stream, various aesthetic effects can be obtained. The water column pressure used is usually directly related to the strength of the net, but the system design also plays an important role. Non-woven webs of different characteristics can be hydraulically entangled to create non-woven composites that are difficult to achieve different grades by other means. Lyocell: A man-made cellulosic material obtained by directly dissolving cellulose in an organic solvent without forming an intermediate product, followed by extruding a cellulose solution and an organic solvent into a coagulation bath. Machine direction (Machine direction): When a non-woven mesh material is formed, the direction of movement of the surface in the direction in which the fibers or filaments are deposited is formed. Mechanical Bonding: In mechanical bonding, the strength of the nonwoven web is achieved by the interfiber friction generated by the physical entanglement of the fibers -9-200837241. There are two forms of mechanical bonding 'hydraulic entanglement, known as hydraulic entanglement and needle rolling. Meltblown fiber: a type of fine, usually annular, capillary-die extruded molten thermoplastic material formed as a filament into a high velocity gas (eg, air) stream, a high velocity gas stream The filaments of the molten thermoplastic material are tapered to reduce their radius. The high velocity gas stream is then loaded with meltblown fibers and deposited on a collecting surface to form a randomly dispersed meltblown web. Melt blown fibers are generally continuous. The melt blowing procedure includes a meltblowing procedure. Natural fiber pulps: Any fibrous material from non-woody plants that is reduced to its constituents by mechanical means such as a pulp honing machine or by chemical means such as high temperature and pressure using various cooking alcohols. Non-woody plants include, for example, cotton, flax, African feathers, kenaf, manila hemp, milkweed, straw, jute, hemp, and bagasse. Needle rolling (N e e d 1 e p u n c h i n g ): In needle rolling, specially designed needles are pushed and pulled on the nonwoven web to entangle the fibers. The web is usually completed by carding but may also contain spunbond (s p u η 1 a i d ) and less used wet-bonded webs (w e 11 a i d w e b s ). Needle rolling can be used for most fiber types. Non-thermoplastic p〇lymer: Any polymer material that is not a thermoplastic polymer definition. Nonwoven fabrics, sheets and w e b: - materials with interwoven fiber structures, but which can be identified as non-woven or knitted fibers. Non-woven materials can be borrowed from many _ | shapes such as melt blown, spunbonding, carding and wet fabric processes. -10- 200837241 The basis weight of non-woven fabrics is usually expressed in grams per square meter (gsm). Polymer - The long chain of repeating organic structural units contains both thermoplastic and non-thermoplastic polymers. Typically included are homopolymers, copolymers such as blocks, grafts, random and alternating copolymers, terpolymers, and the like, as well as mixtures and modifications thereof. In addition, the "polymer" contains all possible geometries unless otherwise specifically limited. The geometry may contain, for example, the same row, the opposite row, and the random symmetry. 9 Regenerated cellulose: A cellulose obtained by chemically treating natural cellulose to form a soluble chemical derivative or intermediate product and then decomposing the derivative to produce cellulose. The regenerated cellulose comprises crepe and the regenerated cellulose process comprises the viscose process of the acetaminophen, the cuprammonium process and the softwood pulps: any from the conifer The fiber material is reduced to its constituent components by mechanical means such as a pulp honing machine or chemical method such as @ under the pressure of the local temperature. Conifers include, for example, cedar, fir, hemlock, pine and spruce. S p u n b ο n d f i 1 a m e n t: a filament formed by extruding a molten thermoplastic material from a plurality of fine, usually annular, capillary die-spinning nozzles. The radius of the extruded filaments can be rapidly reduced by, for example, eductive drawing and/or the well known spunbonding mechanism. The spunbond fibers may have a single niger range of from about 1 to 5 or more and are substantially continuous from one end of the nonwoven web to the opposite end. -11- 200837241 Spunbond nonowoven web: (usually) extruding at least one molten thermoplastic material from a plurality of fine, usually annular, capillary nozzles in a single process as a plurality a net formed by filaments. The filaments are partially repelled and then stretched to reduce the fiber's Danny's and increase the molecular orientation of the fibers. The filaments are generally continuous and non-tacky when they are deposited on the collecting surface as fibrous batt. The fibrous batt is then bonded by, for example, thermal bonding, chemical bonding, mechanical pin rolling, hydroentangling, or a combination thereof to produce non-woven fibers. Staple fiber: A fiber (0.66 to 20 cm) formed or cut into a fiber length of usually 1/4 to 8 inches. Substantially continuous: For a filament of a non-woven web, it means that most of the filaments or fibers formed by extrusion from the orifice are maintained continuously while being stretched and then attached to the collection device. Unbroken filaments. Some filaments may break during the tapering or stretching process, while substantially most of the filaments still maintain the length of the complete sheet. Synthetic fiber: A fiber comprising an artificial material such as glass, a polymer or a combination of polymers, metal, carbon, regenerated cellulose and tencel fiber. Tex: A unit used to indicate the fineness of filaments, expressed in grams per 1,000 meters of filament. 1tex filaments refer to filaments of length 1000 meters with a weight of 1 gram. Thermoplastic polymer: A meltable polymer that softens when exposed to heat and typically returns to its non-softened state when cooled to room temperature. Thermoplastic materials include, for example, polyvinyl chloride, some -12-200837241 polyesters, polyamines, polyfluorocarbons, polyolefins, some polyurethanes, polystyrene, polyvinyl alcohol, ethylene, and at least one vinyl monomer ( Such as: poly(ethylene vinyl acetate) and copolymers of acrylic resin. Web Bonding: Non-woven mesh, except spunbond, has some micro strength when it is not bonded and needs to be strengthened by adhesion. The three basic bonding methods are thermal bonding, chemical bonding, and mechanical bonding. The importance of mode selection affects at least the functional properties of the fiber in the network. The disclosure of an embodiment provides a resilient, non-woven composite material having a resiliently stretchable stretch which is also highly durable, which is advantageous in apparel applications, particularly during laundering, drying and/or dry cleaning. Low or no contraction. The disclosure in another embodiment provides an elastic nonwoven composite having good absorbency, flexibility and breathability for use in medical and sports wrap, bandage and tape applications. It has been found that micro-twisting treats a hydroentangled non-woven composite material which advantageously has two or more non-woven portions which, in combination with heat fixation, can achieve the desired characteristics of resilience, the durability of use and still have Overall good absorption, softness and breathability. The durability of use is characterized by complete recovery after washing, dry cleaning, repeated use or long stretch. It has furthermore been found that by appropriate choice of adhesive, the product can be more advantageously provided with softness and comfort, for example for medical applications, or for providing durability and non-movability, for example for use in a belt. In general, the disclosed compositions and steps may be alternately formulated to comprise, constitute, or otherwise constitute a process having any suitable composition or disclosed herein. The compositions and steps may be additional or interchangeable to facilitate the absence or substantial absence of any ingredients, materials, compositions, adjuvants, types or processes used in conventional techniques, or in addition to functionality in the formulation. The achievement and / or the purpose of the invention is not necessary. As used herein, "about" means that the quantity or state correction may exceed its disclosure as long as its disclosure advantage is understandable. The invention can be better understood by the following detailed description, drawings, and embodiments of the invention. [Embodiment] ® In one embodiment, the elastic composite nonwoven material comprises a first wet-formed nonwoven fibrous portion applied to a second nonwoven fibrous substrate. The second nonwoven substrate is a pre-bonded web such as a carded knit web, a spunbond web or a carded hydroentangled web (generally referred to as water weave). The nonwoven base mesh may have a basis weight of from about 15 to about 150 g/m2 and a substrate basis weight of from about 20 to about 90 g/m2. Nonwoven substrates have the advantage of comprising a continuous synthetic filament such as a spunbond nonwoven, or a mechanically spun φ discontinuous carded staple fiber such as a needle or hydroentangled web. The type of pre-spun is generally not considered to be important. For thermally bonded spunbond webs, the spunbond area of the pqintb ned substrate is as low as about 7% and the degree of prespun adhesion to flat flat substrates is as high as 100%. The type will change. Preferably, the nonwoven substrate is spunbonded and typically has a spunbonded area of from about 1 Torr to about 20%. The second nonwoven substrate fiber can contain several commercially available materials. Advantageously, the substrate fibers include polyester, polyamide and polyolefins such as polyethylene and polypropylene, although other fibrous materials such as enamel, cotton, polylactic acid, -14-200837241 acetyl cellulose and acrylic can also be used. The first portion of the wet nonwoven web comprises a synthetic staple fiber, a natural pulp or a mixture of natural fibers and optionally other tanning materials and/or additives. The binder and other additives may be combined with the fluid and the fibers when the dispersion is formed to add different desired characteristics to the formed composite nonwoven fabric. For example, when the final product is used in the medical field, it may need to be mixed with the dip to provide biologically advantageous properties. Materials such as molecular sieves or similar compounds provide a location to attract or retain the biological composition of the wet non-woven layer, which helps maintain sterility in the environment in which the ® fabric is used. Of course, the amount of feed must be controlled to a level that does not adversely affect the desired softness, drape, and tactile properties of the final product. The first nonwoven fiber portion is wet. It typically involves the general step of forming the necessary fluid dispersion of fibers, pulp and other materials. The fluid dispersion is deposited on a porous member such as a fiber collecting metal mesh. Typically, the perforated component draws fluid from the dispersion to form a continuous sheet of mesh material. The wet web material forming ^ can be further dried using known methods such as heating cans, ovens or heated gases. Wet non-woven nets are preferred because of their inherent dimensional stability and anisotropy. The first wet non-woven fiber portion can be composed of a plurality of layers which are generally used to provide different functional properties to the name layer. The first wet non-woven fiber portion has the advantage of having a grams in the range of from about 20 to about 100 g/m2, wherein the final product has a grams in the range of from about 35 to about 250 g/m2 prior to the cognac treatment. Preferably, the range is from 3 5 to 1 60 g/m 2 . For the application of the garment, the wet-nonwoven fiber portion of the "Day-A" is preferably contained in a natural pulp of about 10 to 100% of softwood or hardwood or a combination thereof, and the remaining fiber is a composite fiber of 15-200837241. Other applications can foresee the need for 100% synthetic fiber to prevent the appearance of cellulose fibers from being contaminated. Preferred synthetic fibers are polyesters such as polyethylene terephthalate (PET), from about 1 to about 6 denier, preferably about 1.5 denier; fiber lengths ranging from about 0.25 to about 0.75 Torr (about 6 to about 20 mm), preferably about 0 · 25 ( (about 6 mm). Other suitable synthetic fibers include, but are not limited to, polyolefins such as polyethylene and polypropylene, polyamine and hydrazine. The natural pulp can be selected substantially from any of the pulps and blends thereof. The preferred ® pulps are all natural cellulose fibers and may contain wood fibers such as cotton. Although softwood pulps such as spruce, hemlock, cedar, and pine are preferred, they are generally used in combination with hardwood pulp such as eucalyptus. Non-wood pulp such as kenaf, kenaf, manila hemp and others can also be used. The natural pulp may be up to about 75 % by weight of the final product, including fibers, a bottom web and a binder composition. The amount of natural pulp can be substantially based on the needs of other compositions and end products in the composite system, such as the barrier capabilities that need to be exhibited when the resulting composite nonwoven is used in medical bandage applications. The first nonwoven fiber portion is applied directly to the second nonwoven substrate. In one embodiment, the material of the first wet nonwoven fibrous portion is dispersed in the fluid and the dispersion is applied to the second nonwoven substrate. A fluid is extracted from the first nonwoven fiber portion to provide a wet composite. In another embodiment, the first nonwoven web portion is deposited on a perforated member such as a fiber collection web. The fluid is extracted from the dispersion, typically via a perforated member, to form a continuous sheet of web material. The formed wet web material can be further dried by known methods such as a heating tank, an oven or a heated gas to provide a preformed first non-woven fabric. A preformed first wet nonwoven web portion is applied to the nonwoven substrate to provide a composite. After the application of the first fiber portion to the second substrate, the composite material is subjected to a low to medium pressure hydraulic entanglement operation as described in U.S. Patent No. 5,009,747, issued to the name of U.S. Pat. Reference materials. By a series of fluid jets through the composite material, the force is applied to the bottom of the substrate and entangled into a hydraulically entangled operation. Use a ^ string or - ^ row

有孔噴射爲較佳,而孔洞間之間隔實質定義於前述專 利。水力纒絡爲結合第一部份與第二底材的較佳方法, 因水力纏絡以交纏噴射提供於機械方向具平行線微圖案 之最終非織複合物。經微縐處理的水力纏絡複合物,水 力纏絡平行線與在橫向機械方向之微縐圖樣結合可產生 小方塊所需線樣。 以傳統方式乾燥經水力纏絡的非織複合材料。乾燥 後的複合材料以液態粘合劑處理,以提供最終使用之穩 定性,包括抗張強度、洗滌耐性、或根據其最終應用的 其他所需特性。藉已知方法如壓型機(size-press )、淋 幕塗布機(curtain coater)、噴霧塗布機(spray coater)、 泡沬噴塗機(foam coater )可完成添加粘合劑。合適粘 合劑包含化學粘合劑,即一般所知的液態分散粘合劑, 如壓克力、醋酸乙烯酯、聚酯、聚乙烯醇、與其他傳統 粘合劑系列。例如在醫療應用上,少量軟性壓克力粘合 劑可用於控制毛邊或用作特殊色料或染料的載體、或作 -17- 200837241 爲進一步強化非織複合物吸收性的濕潤劑的載體。這些 軟性粘合劑通吊歸類爲具範圍約-5至約· 3 5 °C之低玻璃 轉移溫度。對服裝應用個別而言,較佳粘合劑仍爲壓克 力,儘管其玻璃轉移溫度於範圍約〇至約3 〇 且特別設 計用在對纖維洗滌、乾燥與乾洗有嚴苛要求的腰帶。粘 合劑的含量佔整體最後非織複合材料約3至約35wt%, 具中間範圍如1 5至25 %對服裝應用來說是有利的,具約 20 %則爲較佳。粘合劑的含量整體最後非織複合材料約 ® 3至約3 5 wt %,而具範圍約3至約1 〇 %對醫療應用來說 是有利的。 在形成濕式非織片後,視需要以粘合劑做處理並乾 燥然後傳送至微縐處理製程。發明人相信例示之微縐處 理製程依循微纖處理之一般原則,特別是在傳入與移出 滾筒時延遲(retarding)與壓縮(compressing)濕式非 織板的組合,在濕式非織網上形成一系列小的,大致上 平行的摺層。摺層的峰與谷一般會在橫向機械方向上延 ^ 伸,如大致橫切於機械方向。非織網密實範圍爲1 0至5 0 %,較佳爲範圍在約1 5至約45 %。密實網之克數較佳範 圍在40-290g/m2,更佳範圍爲40- 1 85g/m2。依照說明書編 號C2715,美國麻州沃爾波的Micrex Corporation所提供 之微縐處理製程爲適當的。微縐處理機械在例如美國專 利3,260,778中則有更多詳細討論,雖然類似的乾縐處理 (dry-creping)可藉例如美國專利 3,23 6,7 1 8、3,8 1 0,280、 3,869,7 68、3,975,806、4,142,278、4,85 9,169 與 4,894,196 -18- 200837241 中所討論之機械達成。其他適合施行乾縐處理的替代方 法與裝置則在美國專利2,9 15,109與4,090,3 85中有討論。 微縐處理製程被理解爲以包含驅動軸(driven roll) 與用來壓製靠著驅動軸的足以使其往前移動的一或多個 纖維網的衝壓表面(pressing surface)、以及相對於網 前進方向且位於網平面方向的緩衝葉片(retarder blade ) 的葉片狀的乾總機(drycreper)所施行的乾總處理,其 葉片尖端維持在鄰近於驅動軸,乾縐機至少有一表面加 ® 熱熱塑型纖維組成至熱塑型纖維的熱固溫度。在較佳的 乾縐處理製程中,熱塑型纖維包含PET(聚酯)纖維及乾縐 機表面加熱至溫度介於250°F與350°F( 139°C與194°C )。 於製程狀況的其他實施例中,軸溫度可高些(如:可達 成較高速度與移除濕氣使纖維更快達到熱固溫度)或低 些(如:假如摩擦熱提供額外的熱給纖維)。加熱衝壓 表面及/或驅動軸。乾縐機之驅動軸包含一連續圓柱以配 置該軸,如需要可附內加熱器。內加熱器包含供熱流體 • 、、 通過的熱交換管路。熱流體可爲熱水、蒸氣、熱氣或燃 燒氣體、或油。在加熱衝壓表面的例子中’加熱模式可 爲熟知眾多方式之任一如電阻、蒸氣、熱水、熱氣體或 熱空氣。亦可使用輻射加熱或火焰預熱。同時施行乾縐 處理與熱固之方法可縮短網至少1 〇 %,增加片部件 (sheet member)之整體厚度。同時施行乾縐處理與熱固 之方法可縮短網在範圍介於約1 〇至5 0 % ° 於壓實處理時加熱網至溫度範圍在約1 2 1 °C (約 -19- 200837241 25 0°F)至約218°C (約425°F),較佳範圍在約149 °C (約300至40(TF),且更佳範圍在約182至 (3 60至3 80°F),以降低當產物暴露於連續加 縮或膨脹,尤其在服裝應用產物需經過右 (withstand process)以去除纖維縐痕’通常 ( 3 25°F) ,15分鐘。微縐處理時的上升溫度亦 微縐圖樣並使縐處理的濕式不織布與其分離、 維之組合毛邊降到最低。於微縐處理步驟後, 降至室溫。當目視時,縐圖樣足夠細密,而不 縐處理後的網的表面觸感。然而微縐處理步驟 的整體垂墜性並引入可回復性機械方向拉伸。 縐非織彈性材料實質顯示出改善的回復性伸展 含張力舒緩與低扭曲。尤其是當不織布於縱向 高達15%時,橫向長度並無增加。 在大略敘述之後,下列實例包含例示目的 明可被快速理解且除非特別指明否則不受本發 限。 實例 製作與測試適用於各式應用之標準複合 下列配方組合。 •由位於加拿大安大略省馬拉松的 Marathon 所提供的北方漂白軟木牛皮紙漿。 •聚酯(PET )樹脂,標示爲F61HC且由位於 西州 Kingsport的伊士曼化學公司提供,用來 至約204 約 193°C 熱時之收 t纔處理 爲 1 6 3 °C 需熱定型 不連續纖 將不織布 會改變微 改善了網 最終之微 特性,包 上伸展至 以使本發 明範圍所 網係使用 Pulp , Inc. 美國田納 製造紡粘 -20- 200837241 網。 •聚乙烯合成紙漿,標示爲Fybrel SWP E-400且由總部 位於日本東京的三井化學公司製造。 •水性壓克力乳液粘合劑,標示爲ECO E39 88,玻璃轉 移溫度爲+ 5 °C,由總部位於美國賓州費城的羅門哈斯公 司所提供。 接著使用下列技術測試標準樣品。 •根據TAPPI測試程序T410完成基重。 ♦ •根據TAPPI測試程序T41 1測量樣品厚度。 •根據TAPPI測試程序T414測量撕裂強度(Elmendorf Tear strength ) ° •根據TAPPI測試程序T494使用拉力試驗機(Zwick tensile tester )Z2.5 型測量抗張強度( tensile strength) 與拉伸 (elongation )。抓樣張力測試(Grab tensile testing )使用4吋寬6吋長的樣品,荷重速率(cr〇ss-head speed)爲12吋/分、顎口( jaw span)爲3吋與一般伸展 ^ 率。條狀張力測試(Strip tensile testing )使用1吋寬12 吋長的樣品,荷重速率爲1吋/分、顎口爲5吋且固定伸 展率。 以一般洗滌循環與乾燥清洗樣品以確定其外觀、收 縮百分率與延伸效能之回復百分率。以惠而浦洗衣機 LF A 5 700型施行洗衣循環,設定正常洗衣週期、使用中 溫水洗6分鐘。測量水溫爲約4 2 °C (約1 0 8 °F )。以攪拌 速度爲58 stroke/min清洗,接著有兩次脫水與其間的一 -21-A perforated jet is preferred, and the spacing between the holes is substantially defined by the aforementioned patent. The hydraulic enthalpy is a preferred method of combining the first portion with the second substrate, and the hydroentangled entanglement provides the final non-woven composite with parallel line micropatterns in the machine direction. The micro-twisted hydroentangled complex, the hydraulic entanglement parallel line combined with the microscopic pattern in the transverse mechanical direction produces the desired line of small squares. The hydroentangled nonwoven composite is dried in a conventional manner. The dried composite is treated with a liquid binder to provide stability for end use, including tensile strength, wash resistance, or other desirable characteristics depending on its end use. The addition of the binder can be accomplished by known methods such as a size-press, a curtain coater, a spray coater, and a foam coater. Suitable binders include chemical binders, commonly known as liquid dispersion binders such as acrylic, vinyl acetate, polyester, polyvinyl alcohol, and other conventional binders. For example, in medical applications, a small amount of soft acrylic adhesive can be used to control burrs or as a carrier for special colorants or dyes, or as a carrier for humectants to further enhance the absorbency of nonwoven composites -17-200837241. These soft adhesives are classified as having a low glass transition temperature ranging from about -5 to about 35 °C. For apparel applications, the preferred adhesive is still acrylic, although its glass transition temperature ranges from about 〇 to about 3 且 and is specifically designed for use in belts where fiber washing, drying and dry cleaning are critical. The binder content is from about 3 to about 35 wt% of the overall final nonwoven composite, with a median range of from 15 to 25% being advantageous for apparel applications, with about 20% being preferred. The binder content is from about 3 to about 35 wt% overall for the final nonwoven composite, and a range of from about 3 to about 1 〇% is advantageous for medical applications. After forming the wet nonwoven sheet, it is treated with an adhesive as needed and dried and then transferred to a micro-twisting process. The inventors believe that the illustrated micro-twisting process follows the general principles of microfiber processing, particularly in the combination of retarding and compressing wet non-woven boards when passing in and out of the drum, on wet non-woven webs. A series of small, substantially parallel folds are formed. The peaks and valleys of the fold will generally extend in the transverse mechanical direction, such as substantially transverse to the machine direction. The nonwoven web has a densification range of from 10 to 50%, preferably from about 15 to about 45%. The number of grams of the dense mesh is preferably in the range of 40 to 290 g/m2, more preferably in the range of 40 to 1 85 g/m2. The micro-treatment process provided by Micrex Corporation of Volbo, MA, USA is appropriate in accordance with the instruction number C2715. Micro-twisting machines are discussed in more detail, for example, in U.S. Patent No. 3,260,778, although a similar dry-creping can be utilized, for example, in U.S. Patents 3,23 6,7 1 8 , 3,8 1 0,280, 3,869. 7 68, 3,975,806, 4,142,278, 4,85 9,169 and 4,894,196 -18- 200837241 are mechanically agreed. Other alternative methods and devices suitable for performing cognac processing are discussed in U.S. Patents 2,9 15,109 and 4,090,3,85. The micro-twisting process is understood to include a driven roll and a pressing surface for pressing one or more webs against the drive shaft sufficient to move it forward, and advancing relative to the web. The dry total processing performed by the blade-like drycreper of the retarder blade in the direction of the net plane, the blade tip is maintained adjacent to the drive shaft, and the dryer has at least one surface plus heat The plastic fiber is composed of the thermosetting temperature of the thermoplastic fiber. In a preferred cognac process, the thermoplastic fibers comprise PET (polyester) fibers and the surface of the dryer is heated to temperatures between 250 °F and 350 °F (139 °C and 194 °C). In other embodiments of the process conditions, the shaft temperature can be higher (eg, higher speeds can be achieved with moisture removed to allow the fibers to reach the thermoset temperature faster) or lower (eg, if frictional heat provides additional heat to the shaft) fiber). Heat the stamped surface and/or the drive shaft. The drive shaft of the dryer includes a continuous cylinder to configure the shaft and an internal heater if required. The internal heater contains a heat exchange line that supplies the heating fluid. The hot fluid can be hot water, steam, hot or combustible gas, or oil. In the example of heating the stamped surface, the 'heating mode' can be any of a number of well known methods such as electrical resistance, steam, hot water, hot gases or hot air. Radiant heating or flame preheating can also be used. At the same time, the method of cognac treatment and thermosetting can shorten the net by at least 1% and increase the overall thickness of the sheet member. At the same time, the cognac treatment and the thermosetting method can shorten the mesh in the range of about 1 〇 to 50% °. During the compaction treatment, the heating net is heated to a temperature range of about 1 2 1 ° C (about -19-200837241 25 0 °F) to about 218 ° C (about 425 ° F), preferably in the range of about 149 ° C (about 300 to 40 (TF), and more preferably in the range of about 182 to (3 60 to 3 80 ° F), To reduce the exposure of the product to continuous shrinkage or expansion, especially in apparel applications, the product needs to go through the right (withstand process) to remove the fiber scar 'usually (3 25 °F), 15 minutes. The rise temperature of the micro-twisting treatment is also slightly绉 绉 绉 绉 绉 绉 绉 绉 绉 绉 绉 绉 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿 湿Surface feel. However, the overall drape of the micro-twisting step and the introduction of reversible mechanical stretching. 绉 Non-woven elastic material shows an improved recovery stretch with tension soothing and low distortion, especially when not woven in the longitudinal direction. At up to 15%, the lateral length does not increase. After a general narrative, the following The following examples are intended to be understood quickly and are not subject to this limitation unless otherwise specified. Example production and testing are applicable to a variety of standard combinations of the following formulas: • Northern bleached cork provided by Marathon, Marathon, Ontario, Canada Kraft pulp • Polyester (PET) resin, designated F61HC and supplied by Eastman Chemical Company, Kingsport, Western Australia, to a temperature of approximately 204 °C at approximately 193 °C to be treated as 1 6 3 °C The need to heat-set the discontinuous fiber to change the non-woven fabric will slightly improve the final micro-characteristics of the web, and the package will be stretched to allow the use of Pulp, Inc. in the scope of the invention to make spunbond -20-200837241 net. Ethylene synthetic pulp, labeled Fybrel SWP E-400 and manufactured by Mitsui Chemicals Co., Ltd., based in Tokyo, Japan. • Water-based acrylic emulsion adhesive, labeled ECO E39 88, glass transfer temperature + 5 °C, from headquarters Provided by Rohm and Haas Company, Philadelphia, PA. Next, use the following techniques to test standard samples. • Complete the base according to the TAPPI test procedure T410. ♦ • Measure the sample thickness according to the TAPPI test procedure T41 1. • Measure the tear strength according to the TAPPI test procedure T414 (Elmendorf Tear strength) ° • Measure the resistance according to the TAPPI test procedure T494 using the Zwick tensile tester Z2.5 Tensile strength and elongation. Grab tensile testing was performed using a 4 吋 wide 6 吋 sample with a load rate (cr〇ss-head speed of 12 吋/min, a jaw span of 3 吋 and a general extension rate). Strip tensile testing was performed using a 1 吋 wide 12 吋 sample with a load rate of 1 吋/min, a 颚 mouth of 5 吋 and a fixed elongation. The sample was washed in a general wash cycle and dried to determine the percent recovery of its appearance, percent shrinkage and elongation performance. The Whirlpool washing machine LF A 5 700 performs a laundry cycle, setting a normal washing cycle and washing with medium temperature for 6 minutes. The measured water temperature is about 4 2 ° C (about 108 ° F). Wash at a stirring speed of 58 strokes/min, followed by two dehydration and one -21-

200837241 次沖洗。第一次脫水使用3 4 0 r p m,最後一 5 15rpm。用於清洗與乾燥的樣品縱向長度爲 長度爲8.5吋。樣品與兩件用做壓艙物的中 驗室外套一同清洗。在每一洗衣循環時使用 Tide纖維去垢劑。 乾燥樣品於惠而浦乾衣機LAE 5700塑 熱設定爲8 5 °C ( 1 8 5 ° F )、3 0分鐘。樣品與两 物的中等尺寸棉實驗室外套一同乾燥。清沒 個別的清洗與乾燥後產生。測量樣品在三倡 的縱向長度與橫向長度。收縮百分率計算如 最後長度)/ (起始長度)X 1 00。 使用拉力試驗機Z2.5型測量循環抗張 tensile strength),用以確認可回復延伸程度 T494將樣品切割爲2吋寬與12吋長。裝置ί 的橡膠面頜,使用之顎口爲10吋,且荷重荽 分。設計拉力試驗拉伸樣品至不同長度,右 伸設定循環十次。在每一個十次循環,拉fi 始長度之預定程度,維持住拉伸1 5分鐘,5 置(0 %拉伸或1 0吋)。在第十次循環後, 品並測量總長度。可回復延伸百分率計算如 最後長度)xlOO。 樣品的熱氣收縮率藉調整樣品至 (325°F ) 15 分鐘,使用 Grieve & Henry ^ 乾燥前後測量縱向與橫向長度。用於熱氣g 次脫水使用 1 1吋且橫向 等尺寸棉實 20ml濃縮 施行,使用 件用做壓艙 收縮於三次 循環前與後 (起始長度- 強度(cycle 。根據TAPPI I品於3吋寬 :率爲10吋/ ]註記每一拉 3樣品至其原 t回復至原位 自頜移除樣 (起始長度/ 溫度163 °C 守流烘箱並在 3燥之樣品縱 -22- 200837241 向長度爲11吋且橫向長度爲8.5吋。於縱向用鉗子固定 樣品於烘箱內部中間高度的水平裝置上。收縮百分率計 算如(起始長度-最後長度)/ (起始長度)xlOO。此測試 係仿造用在抗縐纖維處理的溫度條件。 例1 此例顯示根據C27 1 5號說明書施行之微縐處理對 產物之收縮與可回復延伸的效果。於是藉先形成兩個別 的非織網,接著對其一起進行水力纏絡以形成兩層的最 ^ 終產物,來製造複合不織布。使用傾斜的金屬網紙製造 機,自由100%馬拉松軟木漿纖維所組成的纖維供給形成 3Og/m2濕式片,來製備第一網。成形後,將濕式片置於 20g/m2 PET網上,藉紡粘製程形成19%點紡粘區域。兩 不同網之合計重量50g/m2,接著藉由使其通過八個水力 歧管(manifolds ),以製程速度138m/min水力纏絡在一 起每一歧管具密度爲2000 holes/m、每個孔洞直徑爲92 微米。每一水力歧管壓力設定如下:歧管1設爲16ba:r ; 歧管2設爲24ba:r;歧管3設爲41bar;歧管4設爲50bar ; 歧管5設爲75bar ;歧管6、歧管7與歧管8設爲80bar。 經由水力纏絡歧管傳送網,使用單層PET細網目導管, 其網目數爲41x30.5/cm、厚度爲〇.33mm並標示爲Flex 310K,由Albany International提供。水力纒絡後,以壓 克力粘合劑,羅門哈斯化學公司提供的ECO 39 8 8型處理 複合網,以達到粘合劑含量佔總最後重量之約1 7 %。粘 合劑處理後,乾燥並儲存材料。整體材料基重爲60g/m2 -23- 200837241 並標不爲樣品A。樣品材料b係爲樣品A依照C2715號 說明書經Micrex® Corporation之微縐製程處理後。使用 25%密實度設定微縐處理樣品B,以速度23m/min與熱 定型溫度193 °C,產生每公分16-18個細脊。以相同密實 度與速度微縐處理樣品C,但不熱定型。複複合網的典 型數據與其微縐變型總結在下面兩表中。 表一.典型特性 樣品 A B C 特性 測量單位 基重 克/米2 60 96 79 厚度 微米 285 435 590 縱向抓樣張力測試 克 14200 16050 13300 橫向抓樣張力測試 克 11650 13150 11900 縱向斷裂伸張率 % 29.1 69.5 53.5 橫向斷裂伸張率 % 52.5 44.5 48.5 縱向撕裂強度. 克 200 360 360 橫向撕裂強度 克 280 455 625 熱收縮於163°C (325F) 15分鐘 % 9.6 0.0 *(1.4) 縱向洗滌收縮,3循環 % 2.8 1·1 *(15.9) 橫向洗滌收縮,3循環 % 0.7 0.5 0.4 這些樣品在三個洗滌與乾燥循環後以延伸取代收縮。 -24- 200837241200837241 times rinse. The first dewatering used 3 4 0 r p m and the last 5 15 rpm. The longitudinal length of the sample used for washing and drying is 8.5 Å. The sample is cleaned with two intermediate jackets for ballast. Tide fiber detergent is used at each laundry cycle. The dried sample was set at 8 5 ° C (1 8 5 ° F) for 30 minutes in a Whirlpool dryer LAE 5700. The sample was dried with a medium size cotton lab coat of both materials. Cleared after individual cleaning and drying. The longitudinal and lateral lengths of the samples were measured in three. The percent shrinkage is calculated as the final length) / (starting length) X 1 00. The tensile tensile strength of the Z2.5 was measured using a tensile tester to confirm the recoverable elongation. The T494 cut the sample to a width of 2 inches and a length of 12 inches. The rubber face of the device ί is 10 颚 and the load is divided. Design the tensile test to stretch the sample to different lengths and set the cycle ten times in the right direction. In each of the ten cycles, pull the fi to the predetermined length of the length, maintain the stretch for 15 minutes, and set 5 (0% stretch or 10 0). After the tenth cycle, measure and measure the total length. The percentage of recoverable extensions is calculated as the final length) xlOO. The hot gas shrinkage of the sample was adjusted to (325 °F) for 15 minutes and the longitudinal and lateral lengths were measured before and after drying using Grieve & Henry ^. It is used for heat g g dehydration using 1 1 吋 and transversely sized cotton 20 ml concentrated, and the parts used for ballast contraction before and after three cycles (starting length - strength (cycle. According to TAPPI I product at 3 吋 width) : rate 10 吋 / ] Note each pull 3 sample to its original t revert to in-situ self-clamp removal sample (starting length / temperature 163 °C baffling oven and in 3 dry sample longitudinal-22-200837241 The length is 11吋 and the lateral length is 8.5吋. The sample is fixed in the longitudinal direction with a pair of clamps on the horizontal height of the oven. The percentage of shrinkage is calculated as (starting length - last length) / (starting length) xlOO. Counterfeit temperature conditions for anti-caries fiber treatment. Example 1 This example shows the effect of micro-twisting treatment on the shrinkage and reversible extension of the product according to the instructions of C27 1 5, so that two other non-woven nets are formed. The composite nonwoven fabric is then produced by hydroentangling together to form the final product of the two layers. The fiber supply of the free 100% marathon softwood pulp fiber is used to form a 3Og/m2 wet type using a slanted metal mesh paper making machine. sheet To prepare the first web. After forming, the wet sheet was placed on a 20 g/m2 PET web, and a spunbonding process was used to form a 19% spunbonded area. The total weight of the two different webs was 50 g/m2, and then passed through Eight hydraulic manifolds are entangled at a process speed of 138 m/min. Each manifold has a density of 2000 holes/m and a diameter of 92 microns per hole. Each hydraulic manifold pressure is set as follows: Tube 1 is set to 16ba:r; manifold 2 is set to 24ba:r; manifold 3 is set to 41bar; manifold 4 is set to 50bar; manifold 5 is set to 75bar; manifold 6, manifold 7 and manifold 8 are set It is 80 bar. Via a hydraulic wrap manifold, a single-layer PET fine mesh catheter with a mesh size of 41x30.5/cm and a thickness of 〇.33mm and labeled Flex 310K, supplied by Albany International. Acrylic adhesive, ECO 39 8 8 treated composite net supplied by Rohm and Haas Chemical Company, to achieve a binder content of about 17% of the total final weight. After the adhesive treatment, dry and store Material. The basis weight of the whole material is 60g/m2 -23- 200837241 and the standard is not sample A. The sample material b is sample A according to C2715. After the book was processed by Micrex® Corporation's micro-twisting process, sample B was treated with 25% compactness and set at a speed of 23 m/min and a heat setting temperature of 193 ° C to produce 16-18 fine ridges per cm. The compactness and speed were slightly treated with sample C, but not heat set. The typical data of the complex composite network and its micro-deformation are summarized in the following two tables. Table 1. Typical Characteristics Sample ABC Characteristic Measurement Unit Basis Weight/m 2 60 96 79 Thickness Micron 285 435 590 Longitudinal Grab Tension Test Gram 14200 16050 13300 Lateral Grab Tension Test Gram 11650 13150 11900 Longitudinal Breakage Tensile Rate% 29.1 69.5 53.5 Transverse elongation at break % 52.5 44.5 48.5 Longitudinal tear strength. gram 200 360 360 transverse tear strength 280 455 625 heat shrinkage at 163 ° C (325 F) 15 minutes % 9.6 0.0 * (1.4) longitudinal wash shrinkage, 3 cycles % 2.8 1·1 * (15.9) Lateral wash shrinkage, 3 cycles % 0.7 0.5 0.4 These samples were shrunk with extension substitution after three wash and dry cycles. -24- 200837241

表二.可回復延伸特性 A B C 每一循環 之拉伸 施力 可回復性 施力 可回復性 施力 可回復性 % 克/50毫米 % 克/50毫米 % 克/50毫米 % 2.5 5000 99.7 115 100 80 97.7 5.0 . 5470 98.7 205 100 95 97.4 7.5 6035 97.7 250 99.7 115 96.6 10 6555 96.5 352 99.7 300 95.8 15 7110 93.4 674 98.0 395 94.9 20 7615 90.4 1110 95.2 2637 85.7 25 8783 87.21 2100 92.3 3008 82.2 30 8950 85.0 3835 87.7 6570 80.0 35 斷裂 — 5200 84.8 6835 77.9 40 7135 80.9 7654 75.6 45 7700 78.1 8660 73.2 50 斷裂 — 斷裂 — 表一顯示縮性當其與無熱固定的微縐處理與無任 何微縐處理的樣品比較時藉微縐處理結合熱固定可達優 良的耐收縮性。 表二顯示藉微縐處理結合熱固定可達優良的可回 復延伸特性,如樣品B當樣品拉伸至25 %時可維持大於 90%可回復性,反之無熱固定的樣品若欲維持大於90% -25- 200837241 可回復性,樣品拉伸僅能低於20 %。無任何微縐處理的 樣品A拉伸在低於25%時可維持大於90%可回復性。施 力數據亦顯示張力舒緩相對於需較大施力進行拉伸使其 延展之未進行熱固定的另兩個樣品’於微總處理時進行 熱固定之樣品B爲較佳。 例2 第二標準複合不織布由100%合成纖維網所構 成,除了濕式頂面由100%三井化學的E400聚乙烯漿與 重量爲30g/m2之外,係藉與例1相同的一般方式製備。 底面(base phase )之外仍爲20g/m2PET紡粘網。水力纏 絡條件與例1不同,只使用4個歧管。每一水力歧管壓 力設定如下:歧管1設爲55bar;歧管2設爲41bar;歧 管3設爲48bar;歧管4設爲41bar。製程速度爲20m/min。 以羅門哈斯化學公司所提供的EC0 3988型壓克力粘合 劑處理水力纏絡複合材’使粘合劑含量佔最後總重量之 約1 7 %。粘合劑處理後’乾燥並儲存材料。整體材料基 重爲60g/m2。水力纒絡複合物依照C27 1 5號說明書,以 速度8m/min進行Micrex Corporation之微縐處理製程; 使用2 5 %密實度設定與熱固定溫度1 3 2 °C可產生細脊 16-18個/cm。表三與表四闡明此複合材料的典型特性包 含其可回復延伸性能。 -26- 200837241 表三.典型特性 特性 測量單位 基重 克/米2 65,5 厚度 微米 550 縱向抓樣張力測試 克 7 100 橫向抓樣張力測試 克 4 800 縱向斷裂伸張率 % 72.8 橫向斷裂伸張率 % 45.5 縱向撕裂強度 克 >1600 橫向撕裂強度 克 >1600 表四.典型特性 可回復延伸性能 施力(克/50毫米) 回復性(%) 每一循環 之拉伸 (%) 2.5 65 9 9.3 5.0 95 | 98.7 7.5 125 98.7 10 145 · 97.1 15 2 00 97.1 20 280 94.9 25 465 91.7 30 630 8 9.6 例3Table 2. Recoverable extension characteristics ABC Tensile force per cycle Recoverable force Recoverable force Recoverability % g / 50 mm % g / 50 mm % g / 50 mm % 2.5 5000 99.7 115 100 80 97.7 5.0 . 5470 98.7 205 100 95 97.4 7.5 6035 97.7 250 99.7 115 96.6 10 6555 96.5 352 99.7 300 95.8 15 7110 93.4 674 98.0 395 94.9 20 7615 90.4 1110 95.2 2637 85.7 25 8783 87.21 2100 92.3 3008 82.2 30 8950 85.0 3835 87.7 6570 80.0 35 Fracture - 5200 84.8 6835 77.9 40 7135 80.9 7654 75.6 45 7700 78.1 8660 73.2 50 Fracture - Fracture - Table 1 shows the shrinkage when it is compared with the sample without heat fixation and the sample without any microcrack treatment. Micro-twisting treatment combined with heat fixation provides excellent shrinkage resistance. Table 2 shows that the micro-twist treatment combined with heat fixation can achieve excellent reproducible elongation characteristics, such as sample B can maintain greater than 90% recoverability when the sample is stretched to 25%, and if not, the sample without heat fixation should be maintained above 90. % -25- 200837241 Recoverability, sample stretching can only be less than 20%. Sample A stretch without any micro-twisting maintains greater than 90% recoverability at less than 25%. The force application data also shows that the tension of the other two samples which are subjected to heat fixation with respect to the other two samples which are not subjected to heat fixation by stretching with a large amount of force, are preferably heat-fixed. Example 2 The second standard composite nonwoven fabric was composed of a 100% synthetic fiber web, except that the wet top surface was prepared by the same general method as in Example 1 except that the E400 polyethylene pulp of 100% Mitsui Chemicals and the weight was 30 g/m2. . Beyond the base phase is still a 20 g/m2 PET spunbond web. The hydraulic entanglement condition is different from that of Example 1, and only four manifolds are used. The hydraulic manifold pressure was set as follows: manifold 1 was set to 55 bar; manifold 2 was set to 41 bar; manifold 3 was set to 48 bar; manifold 4 was set to 41 bar. The process speed is 20m/min. The hydroentangled composite was treated with the EC0 3988 acrylic adhesive supplied by Rohm and Haas Chemical Company to make the binder content about 17% of the final total weight. After the adhesive is treated, the material is dried and stored. The overall material has a basis weight of 60 g/m2. The hydraulic enthalpy complex was subjected to the microcree treatment process of Micrex Corporation at a speed of 8 m/min according to the specification of C27 1 5; 16-18 of fine ridges were produced using a 25% solidity setting and a heat setting temperature of 1 3 2 °C. /cm. Tables 3 and 4 show that the typical properties of this composite include its recoverable elongation properties. -26- 200837241 Table 3. Typical characteristics and characteristics Measurement unit basis weight gram / m 2 65,5 thickness micron 550 longitudinal grab tension test gram 7 100 lateral grab tension test gram 4 800 longitudinal fracture elongation rate 72.8 transverse fracture elongation rate % 45.5 Longitudinal tear strength gram > 1600 transverse tear strength gram > 1600 Table 4. Typical characteristics Recoverable extension properties Force (g / 50 mm) Resilience (%) Stretch per cycle (%) 2.5 65 9 9.3 5.0 95 | 98.7 7.5 125 98.7 10 145 · 97.1 15 2 00 97.1 20 280 94.9 25 465 91.7 30 630 8 9.6 Example 3

除下列不同之外,依照例2製備另一標準樣品。頂 面層爲由100%馬拉松軟木漿形成的20g/m2濕式片,而 -27- 200837241 底面層爲80g/m2 PET紡粘網,在水力纏絡前其結合重量 爲100g/m2。四個水力歧管壓力設定如下:歧管1設爲 70bar ;歧管2設爲48bar ;歧管3設爲7〇bar ;歧管4設 爲34bar。以ECO 3 9 8 8粘合劑處理25%最後重量的水力 纏絡複合物,以達到最終重量136g/m2。水力纏絡複合物 依照 C2715號說明書,以速度 8m/min進行 Micrex Corporation之微縐處理製程;使用35%密實度設定與熱 固定溫度200°C可產生細脊22個/cm。表五闈明此複合材 ® 料的典型特性,表六顯示其在熱定型處理下施行與不施 .行微縐處理的可回復延伸特性。 表五.典型特性 樣品 微縐處理前 微縐處理後 特性 測量單位 基重 克/米2 136 186 厚度 微米 390 620 縱向抓樣張力測試 克 35700 41825 橫向抓樣張力測試 克 33500 39645 縱向斷裂伸張率 % 30 74.1 橫向斷裂伸張率 % 57.7 46.6 縱向撕裂強度 克 800 >1600 橫向撕裂強度 克 1240 >1600 熱收縮於325F,15分鐘 % 0 1.1 縱向洗滌收縮,3循環 % 1.8 1.3 橫向洗滌收縮,3循環 % 0.5 0 -28- 200837241 表六.可回復延伸性能 微縐處理前 微縐處理後 每一循環 之拉伸 施力 可回復性 施力 可回復性 (%) (克/50毫米) (%) (克/50毫米) (%) 5.0 16020 98.7 500 100 7.5 18160 97.7 600 99.7 10 17975 96.2 1060 99.3 15 19900 91.5 1600 98.7 20 20775 88.8 4185 95.2 25 22785 87.2 7220 91.5 表六顯示其優良可回復延伸性可藉具熱固定之微 縐處理來達到’如樣品可維持拉伸至25 %時可維持大於 9 0 %可回復性’反之無任何微縐處理的樣品欲維持大於 90%可回復性,樣品拉伸僅能低於20%。 施力數據亦闡明張力舒緩於微縐處理製程·後進行 爲較佳’正如需更大施力對抗拉伸樣品使其延展而不需 微縐處理。 當本發明前述之較佳實施例被用於闡明提出,前面 述敘並不視爲本發明之限制。因此各式變型、改寫與替 代皆可出現且不悖離本發明之精神與範圍。 【圖式簡單說明】 Μ 〇 【元件符號說明】 ίΕΕ 〇 -29-Another standard sample was prepared in accordance with Example 2 except for the following differences. The top layer is a 20 g/m2 wet sheet formed from 100% marathon softwood pulp, while the -27-200837241 bottom layer is a 80 g/m2 PET spunbond web having a combined weight of 100 g/m2 before hydroentanglement. The four hydraulic manifold pressures were set as follows: manifold 1 was set to 70 bar; manifold 2 was set to 48 bar; manifold 3 was set to 7 〇 bar; manifold 4 was set to 34 bar. The 25% final weight hydroentangled composite was treated with ECO 3 9 8 8 binder to achieve a final weight of 136 g/m2. Hydraulic Twisting Complex Micrex Corporation's micro-twisting process was carried out at a speed of 8 m/min in accordance with C2715 specification; a fine ridge of 22 pieces/cm was produced using a 35% compactness setting and a heat setting temperature of 200 °C. Table 5 shows the typical characteristics of this composite ® material. Table 6 shows the reproducible extension characteristics of the micro-twisting treatment performed under heat setting treatment. Table 5. Typical characteristics of the sample before micro-twisting treatment After micro-twisting treatment characteristic measurement unit basis weight g / m 2 136 186 thickness micron 390 620 longitudinal grab tension test gram 35700 41825 lateral grab tension test gram 33500 39645 longitudinal fracture elongation rate% 30 74.1 Transverse fracture elongation rate 57.7 46.6 Longitudinal tear strength gram 800 > 1600 transverse tear strength gram 1240 > 1600 heat shrinkage at 325F, 15 minutes % 0 1.1 longitudinal wash shrinkage, 3 cycles % 1.8 1.3 transverse wash shrinkage, 3 cycles% 0.5 0 -28- 200837241 Table 6. Recoverable elongation properties Tensile force per recovery after micro-twisting treatment Recoverable force-recoverable (%) (g / 50 mm) ( %) (g/50 mm) (%) 5.0 16020 98.7 500 100 7.5 18160 97.7 600 99.7 10 17975 96.2 1060 99.3 15 19900 91.5 1600 98.7 20 20775 88.8 4185 95.2 25 22785 87.2 7220 91.5 Table 6 shows its excellent recoverable extensibility It can be processed by heat-fixed micro-twisting to achieve a sample that can maintain more than 90% recoverability when the sample can be stretched to 25%. To maintain greater than 90% recoverability, the sample can only stretch less than 20%. The force data also clarified that the tension is soothing in the micro-twisting process. It is better to do it later. Just as more force is required to stretch the sample to stretch it without micro-twisting. The foregoing description of the preferred embodiment of the invention is intended to Various modifications, adaptations, and substitutions may be made without departing from the spirit and scope of the invention. [Simple description of the diagram] Μ 〇 [Description of component symbols] ίΕΕ -29 -29-

Claims (1)

200837241 十、申請專利範圍: 1 · 一種形成彈性複合非織網之方法,係具低能量可回復機 械方向彈性與優良等方特性,其特徵步驟如下: 提供一由複數條合成纖維所構成的黏合非織底網 材料; 提供複數種類合成纖維與纖維素材料; 任意分散該合成纖維與纖維素材料於流體中以形 成配料; • 沉積該配料於一具小孔之部件; 經由該具小孔之部件自該沉積配料移除流體以形 成一濕式非織網; 對該濕式非織網進行水力纏絡(hydroentangling ) 以在該型非織底網上形成一非織複合網; 微總處理(m i c r 〇 c r e p p i n g )該非織複合網達密實度 範圍介於約10%至約50%以形成一密實非織網;以及 於微縐處理時加熱該密實非織網以形成彈性非織 _ 網。 2.如申請專利範圍第1項之方法,其特徵在於: 於該型非織底網上直接沉積合成纖維與纖維素材 料之該流體配料; 經由該型非織底網自該沉積配料移除流體以形成 一濕式非織網頂面(t 〇 p p a h s e ); 對該濕式不織布頂面進行水力纏絡以在該型非織 底網上形成一非織複合網; 微縐處理該非織複合網達密實度範圍介於約1 〇 % -30- 200837241 至約50%以形成一密實非織網;以及 於微縐處理時加熱該密實非織網以形成該彈性非 織網。 3. 如申請專利範圍第1項或第2項之方法,其特徵在於該 非織底網爲連續紡黏(spunbonded )長絲之非織網。 4. 如申請專利範圍第1項或第2項之方法,其特徵在於該 非織底網爲熔吹(m e 11 b 1 〇 w η )長絲之非織網。 5. 如申請專利範圍第1項或第2項之方法,其特徵在於該 非織底網爲梳棉與針軋(needlepunched)的合成纖維之 非織網。 6. 如申請專利範圍第1項或第2項之方法,其特徵在於該 非織底網爲梳棉與水力纏絡式的合成纖維之非織網。 7. 如申請專利範圍第1項或第2項之方法,其特徵在於該 濕式非織網包含合成纖維漿。 8. 如申請專利範圍第1項至第7項中任一項之方法,其特 徵在於濕式非織網包含選自於軟木漿、硬木漿、棉花纖 維、棉短絨、天然纖維、天然纖維獎與其組合物之纖維 素材料。 9 ·如申請專利範圍第1項至第7項中任一項之方法,其特 徵在於濕式非織網包含選自於瓊麻、馬尼拉麻、亞麻、 洋麻、黃麻、赫納昆麻之纖維素材料。 1 0.如申請專利範圍第1項至第9項中任一項之方法,其特 徵在於合成纖維爲聚合纖維。 1 1 ·如申請專利範圍第1項至第1 0項中任一項之方法,其 特徵在於合成纖維係選自於乙醯纖維素、尼龍、聚烯 -31- 200837241 烴、聚酯、嫘縈與其組合物。 1 2 ·如申請專利範圍第1項至第1 1項中任一項之方法,甘 特徵在於添加樹脂粘合劑至水力纏絡式複合非織網之 步驟。 1 3.如申請專利範圍第5項或第6項之方法,其特徵在於彈 性複合非織網包含複數種合成黏合纖維,其至少部份熱 熔合爲合成短纖維。 1 4 ·如申請專利範圍第1項至第1 3項中任一項之方法,其 鲁 特徵在於彈性複合非織網具一基礎重量約40至約 290g/m2,較佳爲介於約 40g/m2至 185g/m2。 1 5 ·如申請專利範圍第1項至第1 4項中任一項之方法,I f寸徵在於治實複合非織網具至少15%之密眚度。 1 6 ·如申請專利範圍第1項至第1 5項中任一項之方法,其 牛寸徵在於密實複合非織網具不超過45%之密眚度。 1 7 ·如申請專利範圍第1項至第1 6項中任一項之方法,其 牛寸徵在於微縐處理時加熱複合非織網至溫度介於範圍 φ 約 1 2 1 °C 至約 2 1 8 °C。 1 8 ·如申請專利範圍第1項至第1 7項中任一項之方法,其 特徵在於微縐處理時加熱複合非織網至溫度介於範圍 約 149°C 至約 204°C。 1 9 ·如申請專利範圍第丨項至第1 8項中任一項之方法,係 用於改善非織網因清洗與乾燥循環所導致之收縮的耐 性。 20·如申請專利範圍第〗9項之方法,其特徵在於濕式非織 網更包含選自於軟木漿、硬木漿、棉花纖維、棉短絨、 -32· 200837241 天然纖維、天然纖維漿與其組合物之纖維素材料。 2 1 ·如申請專利範圍第1 9項或第20項之方法,其特徵在於 非織底網爲梳棉與針軋的合成纖維之非織網。 22·如申請專利範圍第19項或第20項之方法,其特徵在於 非織底網爲梳棉與水力纏絡式的合成纖維之非織網。 23·如申請專利範圍第21項或第22項之方法,其特徵在於 彈性.複合非織網包含複數種聚合纖維,其至少部份熱熔 合爲合成短纖維。 φ 24.如申請專利範圍第1項之方法,其特徵在於依照C271 5 號說明書施行微縐處理。 2 5 · —種多層物件,其特徵在於包含一層如申請專利範圍第 1項之該彈性複合非織網與至少一其他層。 2 6 .如申請專利範圍第2 5項之多層物件,其特徵在於該其 他層係選自於單片薄膜、多孔薄膜、網狀編織物、條子 稀西紗、非織網、梭織物、針織物與其組合物。 2 7 · —種服裝內襯,其特徵在於包含如申請專利範圍第1項 φ 之彈性複合非織網。 2 8 · —種腰帶結構物件,其特徵在於包含如申請專利範圍第 1項之彈性複合非織網。 29 · —繡花底布物件,其特徵在於包含如申請專利範圍第1 項之彈性複合非織網。 30·—種用於帽子裡之防汗襯圈結構,其特徵在於包含如申 請專利範圍第1項之彈性複合非織網。 3 1 · —種醫療繃帶,其特徵在於包含如申請專利範圍第1項 之彈性複合非織網。 -33- 200837241 32.—種醫療包裹物,其特徵在於包含如申請專利範圍第1 項之彈性複合非織網。 3 3. —種運動包裹物,其特徵在於其包含如申請專利範圍第 1項之彈性複合非織網。 34.—種動態包紮材料,其特徵在於包含如申請專利範圍第 1項之彈性複合非織網。 3 5.—種多層物件,其特徵在於包含一層如申請專利範圍第 1項之彈性複合非織網與一黏著層。 φ 3 6 . —種線帶物件,其特徵在於包含如申請專利範圍第3 5 項之多層黏著產物。 -34- 200837241 七、指定代表圖: (一) 本案指定代表圖為:無。 (二) 本代表圖之元件符號簡單說明: &gt;\\v 八、本案若有化學式時,請揭示最能顯示發明特徵的化學式: 200837241200837241 X. Patent application scope: 1 · A method for forming an elastic composite non-woven net, which has low energy and recoverable mechanical direction elasticity and excellent equivalence characteristics. The characteristic steps are as follows: Provide a bonding composed of a plurality of synthetic fibers Non-woven bottom mesh material; providing a plurality of types of synthetic fibers and cellulosic materials; arbitrarily dispersing the synthetic fibers and cellulosic materials in a fluid to form a furnish; and depositing the ingredients in a small hole; through the small holes The component removes fluid from the deposition batch to form a wet non-woven web; hydroentangling the wet non-woven web to form a non-woven composite web on the non-woven web; micro total processing (micr 〇crepping) The non-woven composite web has a densification range of from about 10% to about 50% to form a dense nonwoven web; and the dense non-woven web is heated to form an elastic nonwoven web during micro-twisting. 2. The method of claim 1, wherein: the fluid ingredient of the synthetic fiber and the cellulosic material is directly deposited on the non-woven bottom net; and the deposited ingredient is removed via the non-woven bottom net. Fluid forming a wet non-woven net top surface (t 〇ppahse); hydrolyzing the top surface of the wet non-woven fabric to form a non-woven composite net on the non-woven bottom net; micro-twisting the non-woven composite The mesh densification range is from about 1 〇% -30-200837241 to about 50% to form a dense non-woven net; and the dense non-woven net is heated to form the elastic non-woven net during micro-twisting. 3. The method of claim 1 or 2, wherein the nonwoven web is a non-woven web of continuous spunbonded filaments. 4. The method of claim 1 or 2, wherein the nonwoven web is a non-woven web of melt blown (m e 11 b 1 〇 w η ) filaments. 5. The method of claim 1 or 2, wherein the nonwoven web is a non-woven net of carded and needlepunched synthetic fibers. 6. The method of claim 1 or 2, wherein the non-woven bottom net is a non-woven net of carded and hydroentangled synthetic fibers. 7. The method of claim 1 or 2, wherein the wet nonwoven web comprises a synthetic fiber slurry. 8. The method of any one of claims 1 to 7, wherein the wet non-woven mesh comprises a selected from the group consisting of softwood pulp, hardwood pulp, cotton fiber, cotton linters, natural fibers, natural fibers. Awarded cellulosic material with its composition. The method according to any one of claims 1 to 7, characterized in that the wet non-woven net comprises a selected from the group consisting of Qiong Ma, Manila hemp, flax, kenaf, jute, and Hena Kun. Cellulose material. The method of any one of claims 1 to 9 wherein the synthetic fiber is a polymeric fiber. The method according to any one of claims 1 to 10, characterized in that the synthetic fiber is selected from the group consisting of acetonitrile, nylon, polyene-31-200837241 hydrocarbon, polyester, hydrazine萦 and its composition. 1 2 The method of any one of claims 1 to 11, wherein the method of adding a resin binder to the hydroentangled composite nonwoven web is characterized. A method according to claim 5, wherein the elastic composite nonwoven web comprises a plurality of synthetic binder fibers which are at least partially thermally fused into synthetic staple fibers. The method of any one of claims 1 to 13 wherein the elastic composite nonwoven web has a basis weight of from about 40 to about 290 g/m2, preferably about 40 g. /m2 to 185g/m2. 1 5 · If the method of any one of claims 1 to 14 is applied, the I f inch is at least 15% of the density of the cured composite nonwoven net. 1 6 · If the method of any one of claims 1 to 15 is applied, the density of the dense composite non-woven net is not more than 45%. 1 7 . The method of claim 1 , wherein the method of heating the composite nonwoven web to a temperature in the range of φ about 1 2 1 ° C to about 2 1 8 °C. The method of any one of claims 1 to 17, characterized in that the composite nonwoven web is heated to a temperature ranging from about 149 ° C to about 204 ° C during the micro-twisting treatment. 1 9 The method of any one of the claims to claim 18 is for improving the resistance of the nonwoven web due to shrinkage caused by the washing and drying cycle. 20. The method of claim 9, wherein the wet non-woven net further comprises a softwood pulp, a hardwood pulp, a cotton fiber, a cotton linters, a -32. 200837241 natural fiber, a natural fiber pulp and Cellulosic material of the composition. 2 1 The method of claim 19 or 20, wherein the non-woven bottom net is a non-woven net of carded and needle-punched synthetic fibers. 22. The method of claim 19 or 20, wherein the non-woven bottom net is a non-woven net of carded and hydroentangled synthetic fibers. 23. The method of claim 21, wherein the elastic nonwoven composite web comprises a plurality of polymeric fibers that are at least partially thermally fused to synthetic staple fibers. φ 24. The method of claim 1, wherein the method of micro-twisting is carried out in accordance with the specification of C271. A multilayer article comprising a layer of the elastic composite nonwoven web of claim 1 and at least one other layer. 2 6 . The multi-layer article of claim 25, wherein the other layer is selected from the group consisting of a single film, a porous film, a mesh woven fabric, a striped woven yarn, a non-woven mesh, a woven fabric, and a knitted fabric. And its composition. 2 7 · A garment lining characterized by comprising an elastic composite nonwoven web of the first item φ of the patent application. A belt structure member characterized by comprising an elastic composite nonwoven web according to item 1 of the patent application. 29 - An embroidered base fabric article characterized by comprising an elastic composite nonwoven web as claimed in claim 1. 30. An anti-sweat liner structure for use in a hat, characterized by comprising an elastic composite nonwoven web as claimed in claim 1. 3 1 - A medical bandage characterized by comprising an elastic composite nonwoven web as claimed in claim 1. -33- 200837241 32. A medical wrapper comprising an elastic composite nonwoven web according to item 1 of the patent application. 3 3. A sports wrap, characterized in that it comprises an elastic composite non-woven net as in claim 1 of the patent application. 34. A dynamic dressing material comprising an elastic composite nonwoven web according to item 1 of the patent application. 3 - A multi-layered article comprising a layer of an elastic composite nonwoven web of the first aspect of the patent application and an adhesive layer. Φ 3 6 . A tape-like article characterized by comprising a multilayer adhesive product as claimed in claim 35. -34- 200837241 VII. Designated representative map: (1) The representative representative of the case is: None. (2) A brief description of the symbol of the representative figure: &gt;\\v 8. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: 200837241 發明專利說明 ※申請案號:96133827 ※申請曰期: (本說明書格式、順序及粗體字,請勿任意更動,※.記健部分請勿填寫) P〇ifH ^(2000.01) 15/^(2006.01) 一、發明名稱··(中文/英文) Nhf ^(2006.01) ^ (2006.01) 具改良尺寸回復性之複合不織布 COMPOSITE NONWOVEN WITH IMPROVED DIMENSIONAL RECOVERY 二、 申請人:(共1人) 姓名或名稱:(中文/英文) 亞爾史壯公司 AHLSTROM CORPORATION 代表人··(中文/英文) 塞波凱土恩/Kettunen,Seppo 朱卡哈潘米/Haapaniemi,】ukka 住居所或營業所地址:(中文/英文) 芬蘭赫爾辛基Π-00130艾提雷斯普蘭納迪14號 Etelaesplanadi 14, FI-00130 Helsinki, Finland 國籍:(中文/英文) 芬蘭/Finland 三、 發明人:(共3人) 姓名:(中文/英文) 1. 雷蒙 A.德阿ί馬圖/D’ AMATO, RAYMOND A. 2. 路易 B.費瑞拉/FERREIRA,RUI Β· 3. 賴瑞 L.金/KINN,LARRY L. 國籍:(中文/英文) 1.〜3.美國/United States of America 200837241 四、聲明事項: □主張專利法第二十二條第二項□第一款或□第二款規定之事實,其 事實發生曰期為:年月曰。 ϋ申請前已向下列國家(地區)申請專利: 【格式請依:受理國家(地區)、申請日、申請案號順序註記】 0有主張專利法第二十七條第一項國際優先權: 美國 2006/9/11 60/825,210 無主張專利法第二十七條第一項國際優先權: 主張專利法第二十九條第一項國内優先權: 【格式請依:申請日、申請案號順序註記】 主張專利法第三十條生物材料: □須寄存生物材料者: 國内生物材料【格式請依:寄存機構、日期、號碼順序註記】Invention Patent Description ※Application No.: 96133827 ※Application deadline: (The format, order and bold text of this manual, please do not change any more, ※. Please do not fill in the health section) P〇ifH ^(2000.01) 15/^( 2006.01) I. Name of the invention··(Chinese/English) Nhf ^(2006.01) ^ (2006.01) COMPOSITE NONWOVEN WITH IMPROVED DIMENSIONAL RECOVERY with improved dimensional recovery II. Applicant: (1 in total) Name: (Chinese / English) AHLSTROM CORPORATION Representative (·English/Chinese) Sebo Keltun/Kettunen, Seppo Jukahapanmi/Haapaniemi, ukaka Residence or business address: (Chinese / English) Helsinki, Finland -00130 Etiresplanadi 14, FI-00130 Helsinki, Finland Nationality: (Chinese / English) Finland / Finland III, inventor: (3 in total) Name: (Chinese / English) 1. Raymond A. De Alamatu / D' AMATO, RAYMOND A. 2. Louis B. Ferreira / FERREIRA, RUI Β · 3. Larry L. Kim / KINN, LARRY L. Nationality: (Chinese English) 1.~3. United States/United States of America 200837241 IV. Declarative matters: □ Proposal for the facts as stipulated in Article 22, Paragraph 2, Paragraph 1 or □ Paragraph 2 of the Patent Law Lunar New Year.申请 Before applying, you have applied for a patent to the following countries (regions): [Format: According to the order of the country (region), application date, and application number] 0 There is a claim for the first international priority of Article 27 of the Patent Law: US 2006/9/11 60/825,210 No Patent Law Article 27 Article 1 International Priority: Claiming Article 29 of the Patent Law, the first domestic priority: [Format please: application date, application Note on the order of the case] Claiming Article 30 Biomaterials of the Patent Law: □ Those who need to deposit biological materials: Domestic biological materials [format: Please note according to the order of the depository, date and number] 國外生物材料【格式請依:寄存國家、機構、日期、號碼順序註記】 I|不須寄存生物材料者· 所屬技術領域中具有通常知識者易於獲得時,不須寄存。 -2- 200837241 九、發明說明: 【發明所屬之技術領域】 本發明係關於具改良尺寸與熱回復性並允許在動 態使用情形下作連續調整之微縐複合不織布。 【先前技術】 彈性材料廣泛使用於各種應用,包括腰帶內裡、醫 療包裹物與繃帶、以及功能性包紮材料。彈性材料比非 彈性產品更具優勢,包括其對身體結構與移動的舒適 性,像是腰帶應用與醫療包裹物。此外,當彈性材料用. 在醫療包裹物或繃帶時,藉施以定壓於受創或受傷區域 以提供醫療的舒適感。在醫療包裹物或繃帶應用上,爲 加速療效,彈性材料亦需具備透氣性使氧氣可傳送至受 傷區域並使水蒸氣與其他氣體自受傷區域逸散,以及具 備吸收力使血液與傷口分泌物可藉與繃帶直接接觸自 受傷區域移除。當彈性材料吸滿局部藥膏與其它治療處 理如:麻醉劑與後續治療敷劑時,亦須具備吸收力。 於服裝應用上如腰帶內裡或繡花底布,彈性材料的 優勢在於可變換吃紗成形、具高張力強度且在不破壞與 失去其彈性特質下可重複洗滌與適用乾洗程序。此產物 另一特徵爲當其在機械方向(MD direction)拉伸時, 在橫向方向(CD direction)上必須不減少或僅最少長 度減少。這在服裝應用上尤其重要,一些先前技術所使 用的材料在拉伸時傾向於橫向方向縮減長度,造成腰帶 外觀扭曲。通常當材料於一方向延伸時,會傾向於其他 兩個方向變薄(以材料的波森比描述)。具一些或所有 這些特質的彈性材料可用在這些範疇:服裝內裡、醫療 200837241 包裹物與繃帶、或功能性包紮領域。然而實務上提供具 一些或所有這些特質的彈性材料是困難的。 例如:由於不織布的可回復彈性延伸的限制,成衣 工業求助於昂貴的腰帶內裡如使用45度斜紋切割的梭 織物、或使用針織物、或使用含連續彈性體纖維的網、 或使用彈性體薄膜、或使用各式微網、或應用允許滑動 的重疊纖維區段的複雜腰帶設計。在醫療包裹物或繃帶 應用上,亦嚐試賦予可回復彈性材料特質吸收力、透氣 性與強度。 除了編入彈性材料層或纖維使得非織網之拉伸可 回復,其他方式爲對不織布縐處理或微縐處理。於縐處 理時’非織網附著至一縐表面並使用刮刀自該表面移 除。於微縐處理時,當其在滾輪上移動或自其移除時, 藉由阻滞與壓縮該網達到非織網的可回復延伸特性。 不過,各種應用市場仍持續尋找合適的可回復延伸 非織材料,結合了其他所需應用特性並維持有經濟效益 花費在與簡單生產程序。 【發明內容】 定義 雙成份纖維或長絲(bicomponent fiber or filament) ’·自各別的擠壓機擠壓聚合物源並同時紡出 以形成單束的纖維或長絲,藉此形成複合纖維或長絲。 通常會擠壓兩不同的聚合物,雖然雙成份纖維或長絲可 包括相同聚合物材料自不同擠壓機擠出的壓製品。擠出 -6- 200837241 的聚合物實質上安排在位於橫過雙成份纖維或長絲的 斷面的區分區域(distinct zone),且實質上沿著雙成 份纖維或長絲的長度連續延伸。雙成份纖維或長絲的結 構可爲對稱(如:鞘芯型或並排型)或不對稱(如:鞘 芯型平板印刷;整體爲圓形而纖維爲新月圖案。)。兩 種聚合物源的比例可爲例如(但非絕對)75/25、50/5 0、 25/75 。 雙組成纖維(b i c ο n s t i t u e n t f i b e r ):混合兩或多種 自相同紡嘴擠壓出的聚合物形成的一種纖維。雙組成纖 維不具多種聚合物組成安排在相對位於橫過纖維的斷 面區的區分區域,且多種聚合物通常亦不沿著纖維總長 度連續,原纖維形成通常是隨機地開始與結束。雙組成 纖維有時候也稱作多組成纖維。 軋光(calendering ):—種於相對表面間壓製非織 材料表面的製程。相對表面包含平板壓盤與滾筒。可對 任一或兩相對表面加熱。任一或兩相對表面可含凸部。 纖維素材料(cellulose material):實質上包含纖 維素的一種材料。纖維素纖維來自人造來源(例如:再 生纖維素纖維或萊賽爾纖維)或天然來源如:纖維或木 本與非木本植物紙漿。木本植物含,例如落葉木與結毬 果樹。非木本植物含,例如棉、亞麻、非洲羽芒、西波 爾麻、馬尼拉麻、馬利筋、稻草、黃麻、大麻、與甘蔗 渣。 1¾ 口纖維或長絲(conjugate fiber or filament) 200837241 自不同擠壓機擠壓聚合物源並同時紡出以形成單束的 纖維或長絲,藉此形成纖維或長絲。複合纖維使用兩或 多種來自不同擠壓機的聚合物。通常擠壓聚合物實質安 排在位於橫過複合纖維或長絲的斷面的區分區域,且實 質上沿著複合纖維或長絲的長度連續延伸。複合纖維或 長絲的的形狀可爲任何形狀,只要方便生產者之所需應 用即可,如圓形、三葉、三角、狗骨型、平板或空心。 綴處理與微綴處理(Creping and microcreping): 一種於機械方向緊實非織網的製程,添加至網上的一系 列一般不連續的小平行摺層。微縐處理與縐處理不同處 主要在於所附與摺層的尺寸。 橫向機器方向(CD) ( cross machine direction):此 方向垂直於機械方向。 丹尼(Denier ): —種用來定義長絲細度的單位, 以9000公尺長絲的公克重量爲準。1丹尼的9000公尺 長絲具有1公克質量。 垂墜性(D r a p e ):懸掛材料產生寬鬆或鬆垮縐摺 的能力。 彈性材料(Elastic Material ): —種可拉伸的材料, 特別指當施力釋放時會因延展性回復原來形狀或尺寸。 纖維(Fiber ):特徵爲極高的長度與半徑比率的一 種材料。如文中所示,除非特別指明,纖維與長絲爲可 互換的。 長絲(Filament ):實質上爲連續的一種纖維。如 200837241 文中所示,除非特別指明,纖維與長絲爲可互換的。 硬木漿(Hardwood pulps):任何源自落葉木的纖 維材料,其經由機械方法像是紙漿硏磨機、或化學方式 如在高溫高壓下使用各種烹飪酒精,還原成其組成成 分。落葉木包含如赤楊、樺木、桉樹、橡樹、楊木、西 克莫無花果、香楓與胡桃木。 熱固定(Heat setting):於基材上使用熱與壓力以 完成某些所需效果的一種製程。在合成纖維製成的纖維 上,熱固定用來防止收縮或產生在洗滌或乾洗後會保留 下來的縐痕或摺撊。 水力纏絡(Hydroentanglement):使用細、高壓水 噴射以使非織纖維交錯。水力纒絡即所知的水織 (spunlacing),藉由安排噴射水流可得到各式討喜的 美感效果。所使用的水柱壓力通常與網的強度具直接關 聯,但系統設計亦佔重要因素。不同特性的非織網可水 力纏絡在一起以產生難以藉其他方式達到不同特性等 級的非織複合物。 天絲纖維(Lyocell):藉由直接溶解纖維素於有機 溶劑中,無須形成中間產物,接著將纖維素溶液及有機 溶劑擠出至凝固浴中所製得的人造纖維素材料。 機械方向(MD)(Machine direction):形成非織網材 料時,形成表面在纖維或長絲沉積方向上的移動方向。 機械粘合(Mechanical Bonding):在機械粘合中’ 非織網的強度藉纖維物理纒絡所產生的纖維間摩擦力 - 9- 200837241 達到。機械粘合有兩種形式,水力纒結即所知水力纏絡 與針車L。 熔吹纖維(Meltblown fiber): 一種纖維,其係自 複數個細密的,通常爲環形的毛細管模擠出熔融熱塑性 材料作爲長絲進入高速氣體(如空氣)流而形成,高速 氣體流可使熔融熱塑材料長絲變細以降低其半徑。接著 高速氣體流乘載熔吹纖維並沉積於收集表面以形成隨 機分散熔吹纖維網。熔吹纖維一般爲連續的。熔吹程序 包括熔噴程序。 天然纖維漿(Natural fiber pulps):任何來自非木 質植物的纖維材料,經由機械方法像是紙漿硏磨機、或 化學方式如在高溫高壓下使用各種烹飪酒精,還原成其 組成成分。非木質植物包含如棉、亞麻、非洲羽芒、瓊 麻、馬尼拉麻、馬利筋、稻草、黃麻、大麻、與甘蔗渣。 針軋(N e e d 1 e p u n c h i n g ):在針軋中,特殊設計的 針於非織網上推進與拉出以交纏纖維。該網通常藉梳棉 完成但亦可包含紡粘(spunlaid)與較少使用的濕粘網 (w e 11 a i d w e b s )。針軋可用於大部分纖維種類。 非熱塑型聚合物(Non-thermoplastic polymer):任 何不屬於熱塑型聚合物定義的聚合物材料。 非織纖維、片與網(Nonwoven fabrics, sheet and web ): —種具各自內交錯纖維結構的材料,但可識別 其形式非織布或針織纖維。非織材料可藉許多製程形成 如熔吹、紡粘(spunbonding )、梳棉與濕式佈層製程。 -10- 200837241 非織纖維的基礎重量通常以每平方公尺克雷s r 、 u运里、gsm) 表示。 聚合物(Polymer)- —種重複有機結構單元的長鍵 包含熱塑型與非熱塑型聚合物。通常含如均聚物,共聚 物例如嵌段、接枝、隨機與交替共聚合物,三聚物等等, 以及其混合與變形。此外,除非另特別限制,該項「聚 合物」含所有可能幾何形狀。幾何形狀可含例如同排、 對排與隨機對稱。 再生纖維素(Regenerated cellulose) ••藉由對天然 纖維素做化學處理,形成可溶的化學衍生物或中間產物 並接著分解衍生物以產生纖維素而得到的造纖維素。再 生纖維素包含嫘縈紗而再生纖維素製程包含乙醯纖維 素的膠絲製造法(the viscose process)、銅錢法(the cuprammonium process )與皇化。 軟木漿(Softwood pulps):來自針葉樹的任何纖 維材料,經由機械方法像是紙漿硏磨機、或化學方式如 在高溫高壓下使用多種烹飪酒精,還原成其構成成分。 針葉樹包含如西洋杉、冷杉、鐵杉、松樹與雲杉。 紡粘長絲(S p u n b ο n d f i 1 a m e n t ):藉由自複數個細 密的,通常爲環形的毛細管模紡嘴擠出熔融熱塑性材料 所形成的長絲。擠出長絲的半徑可藉例如噴射拉伸 (eductive drawing)及/或熟知的紡粘機構隨之快速降 低。紡粘纖維可具單尼範圍介於約0.1至5或更高且從 非織網的一端至相對端實質上爲連續。 -11- 200837241 紡粘非織網(Spunbond nonowoven web):(通常) 於單一製程中,自複數個細密的,通常爲環狀的毛細管 紡嘴中擠出至少一種熔融熱塑型材料做爲複數條長絲 所形成的網。長絲係部份退火,然後拉伸以降低纖維的 丹尼’並提高纖維中分子的順向度。長絲通常爲連續且 當其沉積於收集表面上爲纖維狀棉絮時爲非黏的。接著 藉例如熱黏合、化學粘合劑、機械針軋、水力纒絡或其 組合黏合纖維狀棉絮以產生非織纖維。 短纖維(Staple fiber):形成或裁成纖維長度通常 爲1/4至8吋的一種纖維(0.6至20cm)。 實質上連續(substantially continuous):對於非織 網的聚合長絲,意指大多數藉由自噴孔擠出所形成的長 絲或纖維,在拉伸並接著裝塡在收集裝置時,仍維持連 續未斷裂之細絲。一些長絲可能在變細或拉伸製程中斷 裂,而實質上大多數的長絲仍維持完整的片的長度。 合成纖維(Synthetic fiber):包含人造材料如玻 璃、聚合物或聚合物之組合、金屬、碳、再生纖維素與 天絲纖維的一種纖維。 特克斯(Tex ): —種用來標示長絲細度的單位, 以每1 000公尺長絲的克重量表示。1特克斯尚長絲指長 度1 000公尺的長絲具1克重量。 熱塑型聚合物(Thermoplastic polymer ):可熔化的 聚合物,當其暴露於熱時會軟化且冷卻至室溫時通常會 回復至其非軟化態。熱塑型材料包含如聚氯乙烯、一些 -12- 200837241 聚酯、聚醯胺、聚氟碳化物、聚烯烴、——些聚氨酯、聚 苯乙烯、聚乙烯醇、乙烯與至少一乙烯基單體(如:聚 (乙烯-醋酸乙烯酯))與壓克力樹脂的共聚合物。 網粘合(Web Bonding) ••非織網,除了紡粘,在 其未黏合時具些微強度且需藉粘合加強。三種基本粘合 方式爲熱粘合、化學粘合與機械粘合。方式選擇的重要 性至少如網中纖維種類般影響其功能特性。 於一實施例之揭露提供了具可回復彈性拉伸的彈 性非織複合材料,其亦具高耐久性,這在服裝應用上爲 有利的,特別是在洗滌、乾燥及/或乾洗時的低或不收 縮。於另一實施例中之揭露則提供了具良好吸收性、柔 軟性與透氣性的彈性非織複合材料,其可使用在醫療與 運動包裹物、繃帶與線帶應用。 已發現微縐處理一水力纒絡的非織複合材料,其有 利的具有兩或多種非織部份,結合熱固定可達可回復彈 性伸展之所需特性,使用之耐久性且仍具有整體良好吸 收性、柔軟性與透氣性。使用之耐久性之特徵爲洗滌、 乾洗、重複使用或長時間伸展後之完整回復性。此外更 發現藉由適當選擇粘合劑,產物可更有利的提供柔軟與 舒適,例如用在醫療應用、或提供耐用與不易移動例如 用在腰帶內裡應用。 一般而言,揭露之組成物與步驟可替代的調配以包 含、構成或本質上構成具有任何適當成分或此處揭露之 製程。組成物與步驟可爲附加或互換的,以便於配方中 -13- 200837241 缺少或實質上不具備任何成分、材料、組成、輔劑、使 用於習知技術的種類或製程,或此外對功能性達成及/ 或本發明目的爲非必要。 文中所使用的「約」意指數量或狀態修正可超出其 揭露只要其揭露優勢爲可理解的。 本發明可藉下列詳細描述、圖解、本發明實施例得 到較佳理解。 【實施方式】 在一實施例中,彈性複合非織材料包含應用至第二 非織纖維底材的第一濕式(w e t - f 〇 r m e d )非織纖維部份。 第二非織底材爲預粘合網,如梳棉針織網、紡粘網 或梳棉水力纒絡網(通常表示爲水織)。非織底網基礎 重重可介於約15至約150g/m2’具底材之優勢爲基礎重 量可介於約20至約90g/m2。非織底材的優勢在於包含實 質爲連續之合成長絲如紡粘不織布,或由經機械紡粘的 不連續梳棉短纖維構成如針軋或水力纏絡網。預紡黏之 型式一般不認爲是重要的。對熱粘合紡粘網而言,對點 紡粘(point boned )底材的紡粘區域低達約7%與對平面 紡粘(flat boned)底材高至100%之預紡粘程度與型式 將改變。較佳非織底材爲點紡粘且一般具紡粘區域約1 〇 至約2 0 %。 第二非織底材纖維可含數個商業可得材料。有利地 底材纖維包括聚酯、聚醯胺與聚烯烴如聚乙烯與聚丙 烯、然而亦可使用其他纖維材料如嫘縈、棉、聚乳酸、 •14- 200837241 乙醯纖維素與壓克力。 濕式非織纖維第一部份包含合成短纖維、天然漿或 天然纖維與視需要地其他塡料及/或添加劑之混合物。塡 料及其他添加劑可在分散液形成時與流體與纖維結合以 添加不同期望的特性於形成的複合不織布。例如:當最 終產物用在醫療領域時,其可能需與塡料混合以具備生 物上有利的特性。材料如分子篩或類似化合物提供位置 吸引或留住合倂在濕式非織層的生物組成物,其幫助不 織布所使用的環境維持無菌狀態。當然塡料量必須控制 在一定數量,使其不致對所需柔軟性、垂墜性與最終產 物的觸感造成不良影響。 第一非織纖維部份爲濕式。其典型包含形成必要的 纖維、紙漿與其他材料之流體分散液的一般步驟。流體 分散液沉積於有孔部件如纖維收集金屬網。一般透有孔 部件自分散液抽取流體以形成連續片狀的網材料。形成 的濕式網材料可使用已知方法如加熱罐、烘箱或加熱氣 體進一步乾燥。濕式非織網因其本質上尺寸穩定特性與 異方性特質爲較佳。第一濕式非織纖維部份可組成一般 實際用在提供不同功能特性至名子層的多層。 第一濕式非織纖維部份其優勢在於具範圍在約20 至約100g/m2的克數,其中最終產物在乾縐處理前的克數 車E圍在灼35至約250 g/m ’較佳爲範圍在3 5 -1 60 g/m2。 對服裝應用而言,第一濕式非織纖維部份較佳含約1 〇至 100%的軟木或硬木或其組合的天然漿,而剩餘纖維爲合 -15- 200837241 防 爲 .75 〇 如 的 軟 與 量 的 •需 所 中 部 散 網 箱 纖 成纖維。其他應用可以預見其需要100%合成纖維以預 歸咎於纖維素纖維的外觀饌汗問題。較佳的合成纖維 聚酯如聚對苯二甲酸乙烯酯(PET),自約1至約6丹尼 以約1.5丹尼爲佳;具纖維長度範圍爲約0.25至約〇 吋(約6至約20mm),以約0 · 2 5吋爲佳(約6mm ) 其他適當的合成纖維包含但不限於以聚烯烴爲來源的 聚乙烯與聚丙烯、聚醯胺與嫘縈。Foreign biomaterials [format: please note: country, organization, date, number order note] I|No need to deposit biomaterials · When there is general knowledge in the technical field that is easy to obtain, no deposit is required. -2- 200837241 IX. DESCRIPTION OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to a micro-twist composite nonwoven fabric having improved size and thermal recovery and allowing continuous adjustment in dynamic use. [Prior Art] Elastomeric materials are widely used in a variety of applications, including belt linings, medical wraps and bandages, and functional dressing materials. Elastic materials have advantages over non-elastic products, including their comfort for body structure and movement, such as belt applications and medical wraps. In addition, when elastic materials are used in medical wraps or bandages, they are applied to the injured or injured area to provide medical comfort. In medical wraps or bandage applications, in order to accelerate the efficacy, the elastic material also needs to be breathable so that oxygen can be transported to the injured area and the water vapor and other gases escape from the injured area, and the absorption of blood and wound secretions It can be removed from the injured area by direct contact with the bandage. Absorptive force is also required when the elastic material is filled with topical ointments and other treatments such as anesthetics and subsequent treatment dressings. For apparel applications such as belt linings or embroidered base fabrics, the advantage of elastomeric materials is that they can be converted into yarn-forming, have high tensile strength and can be re-washed and applied dry-cleaning procedures without damaging or losing their elastic properties. Another feature of this product is that it must not decrease or only decrease in length in the CD direction when it is stretched in the MD direction. This is especially important in apparel applications where some of the materials used in the prior art tend to reduce the length in the transverse direction when stretched, causing the waistband to be distorted. Usually when the material is extended in one direction, it tends to be thinner in the other two directions (described by the material's Poisson ratio). Elastic materials with some or all of these qualities can be used in these areas: garment lining, medical 200837241 wraps and bandages, or functional dressing. However, it is practical to provide elastic materials with some or all of these qualities. For example, due to the limited elastically retractable stretch of non-woven fabrics, the garment industry resorts to expensive belts such as woven fabrics that use 45 degree twill cuts, or the use of knits, or the use of webs containing continuous elastomeric fibers, or the use of elastomeric films. Or use a variety of microgrids, or apply a complex waistband design that allows for overlapping overlapping fiber sections. In medical wraps or bandage applications, attempts have also been made to impart resilience, breathability and strength to resilient elastomeric materials. In addition to being woven into the elastic material layer or fibers, the stretching of the nonwoven web can be recovered, and the other methods are non-woven fabric treatment or micro-twisting treatment. At the time of processing, the non-woven net was attached to a surface and removed from the surface using a doctor blade. Upon micro-twisting, as it moves over or removes from the roller, the retractable extension of the nonwoven web is achieved by retarding and compressing the web. However, various application markets continue to look for suitable recyclable extended non-woven materials that combine other desirable application characteristics and maintain cost-effectiveness with simple production processes. SUMMARY OF THE INVENTION [Bicomponent fiber or filaments are defined as '- extruding a polymer source from a separate extruder and simultaneously spinning to form a single bundle of fibers or filaments, thereby forming a composite fiber or Filament. Two different polymers are typically extruded, although bicomponent fibers or filaments may comprise compacts extruded from different extruders of the same polymeric material. The polymer extruded -6-200837241 is arranged substantially in a distinct zone across the cross-section of the bicomponent fibers or filaments and extends substantially continuously along the length of the bicomponent fibers or filaments. The structure of the bicomponent fibers or filaments may be symmetrical (e.g., sheath-core or side-by-side) or asymmetrical (e.g., sheath-type lithography; the whole is circular and the fibers are crescent moon patterns). The ratio of the two polymer sources can be, for example, but not absolute, 75/25, 50/5 0, 25/75. A bicomponent fiber (b i c ο n s t i t u e n t f i b e r ): a fiber formed by mixing two or more polymers extruded from the same spinning nozzle. The bicomponent fibers do not have a plurality of polymer compositions arranged in a distinct region that is relatively transverse to the cross-sectional area of the fibers, and the plurality of polymers are generally not continuous along the total length of the fibers, and fibril formation typically begins and ends randomly. Double-component fibers are sometimes referred to as multi-component fibers. Calendering: A process in which the surface of a non-woven material is pressed between opposing surfaces. The opposite surface contains a flat platen and a roller. Any or both of the opposing surfaces can be heated. Any one or both of the opposing surfaces may include protrusions. Cellulosic material: A material that substantially contains cellulose. Cellulose fibers are derived from artificial sources (e.g., regenerated cellulose fibers or lyocell fibers) or natural sources such as fibers or wood and non-woody plant pulp. Woody plants contain, for example, deciduous and knotted fruit trees. Non-woody plants, such as cotton, flax, African feathers, sultans, manila hemp, milkweed, straw, jute, hemp, and sugar cane. 13⁄4 conjugate fiber or filament 200837241 A polymer source is extruded from a different extruder and spun at the same time to form a single bundle of fibers or filaments, thereby forming fibers or filaments. The composite fiber uses two or more polymers from different extruders. Typically the extruded polymer is disposed substantially in a distinct region at the cross-section across the composite fibers or filaments and extends substantially continuously along the length of the composite fibers or filaments. The shape of the composite fiber or filament may be any shape as long as it is convenient for the manufacturer, such as a circular, trilobal, triangular, dog bone type, flat plate or hollow. Creping and microcreping: A process of compacting a non-woven net in a mechanical direction, adding a series of generally discontinuous small parallel folds to the web. The difference between the micro-twisting treatment and the enamel treatment is mainly in the size of the attached and folded layers. Cross machine direction: This direction is perpendicular to the machine direction. Denier: A unit used to define the fineness of filaments, based on the weight of the 9000-meter filament. 1 Danny's 9000 meters filament has a mass of 1 gram. Drape (D r a p e ): The ability of the suspension material to produce loose or loose folds. Elastic Material: A stretchable material, especially when the force is released, it will return to its original shape or size due to ductility. Fiber: A material characterized by an extremely high ratio of length to radius. As indicated herein, the fibers and filaments are interchangeable unless otherwise indicated. Filament: A fiber that is substantially continuous. As indicated in the text 200837241, the fibers and filaments are interchangeable unless otherwise specified. Hardwood pulps: Any fibrous material derived from deciduous wood that is reduced to its constituents by mechanical means such as a pulp honing machine or by chemical means such as high temperature and pressure using various cooking alcohols. Deciduous trees include such as alder, birch, eucalyptus, oak, poplar, sycamore fig, fragrant maple and walnut. Heat setting: A process in which heat and pressure are applied to a substrate to accomplish certain desired effects. On fibers made of synthetic fibers, heat is fixed to prevent shrinkage or to cause scars or creases that may remain after washing or dry cleaning. Hydroentanglement: Use fine, high-pressure water jets to stagger non-woven fibers. Hydraulic sputum is known as spunlacing, and by arranging the jet stream, various aesthetic effects can be obtained. The water column pressure used is usually directly related to the strength of the mesh, but the system design also plays an important role. Non-woven webs of different characteristics can be hydraulically entangled to create non-woven composites that are difficult to achieve different grades by other means. Lyocell: A man-made cellulosic material obtained by directly dissolving cellulose in an organic solvent without forming an intermediate product, followed by extruding a cellulose solution and an organic solvent into a coagulation bath. Machine direction (Machine direction): When a non-woven mesh material is formed, the direction of movement of the surface in the direction in which the fibers or filaments are deposited is formed. Mechanical Bonding: In mechanical bonding, the strength of the non-woven mesh is achieved by the interfiber friction generated by the fiber-optic entanglement - 9-200837241. There are two forms of mechanical bonding, and the hydraulic knot is known as the hydraulic entanglement and the needle cart L. Meltblown fiber: A fiber formed by extruding a plurality of fine, usually annular, capillary die extruded molten thermoplastic materials into a stream of high velocity gas (e.g., air) which is melted at a high velocity gas stream. The thermoplastic material filaments are tapered to reduce their radius. The high velocity gas stream is then loaded with meltblown fibers and deposited on a collecting surface to form a randomly dispersed meltblown web. Melt blown fibers are generally continuous. The melt blowing procedure includes a meltblowing procedure. Natural fiber pulps: Any fibrous material from non-woody plants that is reduced to its constituents by mechanical means such as a pulp honing machine or by chemical means such as high temperature and pressure using various cooking alcohols. Non-woody plants include, for example, cotton, flax, African feathers, kenaf, manila hemp, milkweed, straw, jute, hemp, and bagasse. Needle rolling (N e e d 1 e p u n c h i n g ): In needle rolling, specially designed needles are pushed and pulled on the nonwoven web to entangle the fibers. The web is usually finished by carding but may also contain spunlaid and less used wet-bonded webs (w e 11 a i d w e b s ). Needle rolling can be used for most fiber types. Non-thermoplastic polymer: Any polymer material that is not a thermoplastic polymer definition. Nonwoven fabrics, sheets and webs: materials that have interwoven fiber structures in their respective shapes, but which can be used to identify non-woven or knitted fibers in their form. Nonwoven materials can be formed by a number of processes such as melt blowing, spunbonding, carding and wet lamination processes. -10- 200837241 The basis weight of non-woven fabrics is usually expressed in grams per metric gram of s r , u Yunli, gsm). Polymer - The long bond of a repeating organic structural unit contains both thermoplastic and non-thermoplastic polymers. Typically included are homopolymers, copolymers such as blocks, grafts, random and alternating copolymers, terpolymers, and the like, as well as mixtures and modifications thereof. In addition, the "polymer" contains all possible geometries unless otherwise specifically limited. The geometry may contain, for example, the same row, the opposite row, and the random symmetry. Regenerated cellulose • Cellulose obtained by chemically treating natural cellulose to form soluble chemical derivatives or intermediates and then decomposing the derivatives to produce cellulose. The regenerated cellulose comprises crepe and the regenerated cellulose process comprises the viscose process of the acetaminophen, the cuprammonium process and the emeraldization. Softwood pulps: Any fibrous material from conifers that is reduced to its constituents by mechanical means such as a pulp honing machine or by chemical means such as high temperature and pressure using a variety of cooking alcohols. Conifers include, for example, cedar, fir, hemlock, pine and spruce. S p u n b ο n d f i 1 a m e n t: a filament formed by extruding a molten thermoplastic material from a plurality of fine, usually annular, capillary die-spinning nozzles. The radius of the extruded filaments can be rapidly reduced by, for example, eductive drawing and/or the well known spunbonding mechanism. The spunbond fibers can have a single strand range of from about 0.1 to 5 or greater and are substantially continuous from one end of the nonwoven web to the opposite end. -11- 200837241 Spunbond nonowoven web: (usually) extruding at least one molten thermoplastic material from a plurality of fine, usually annular, capillary nozzles in a single process as a plurality a net formed by filaments. The filaments are partially annealed and then stretched to reduce the denier of the fibers and increase the forward orientation of the molecules in the fibers. The filaments are generally continuous and non-tacky when they are deposited on the collecting surface as fibrous batt. The fibrous batt is then bonded by, for example, thermal bonding, chemical bonding, mechanical pin rolling, hydraulic entanglement or a combination thereof to produce non-woven fibers. Staple fiber: A fiber (0.6 to 20 cm) formed or cut into a fiber length of usually 1/4 to 8 Å. Substantially continuous: For a filament of a non-woven web, it means that most of the filaments or fibers formed by extrusion from the orifice are maintained continuously while being stretched and then attached to the collection device. Unbroken filaments. Some filaments may break during the tapering or stretching process, while substantially most of the filaments still maintain the length of the complete sheet. Synthetic fiber: A fiber comprising an artificial material such as glass, a polymer or a combination of polymers, metal, carbon, regenerated cellulose and tencel fiber. Tex: A unit used to indicate the fineness of filaments, expressed in grams per 1,000 meters of filament. 1Texas filaments refer to filaments of length 1 000 m with a weight of 1 gram. Thermoplastic polymer: A meltable polymer that softens when exposed to heat and typically returns to its non-softened state when cooled to room temperature. Thermoplastic materials include, for example, polyvinyl chloride, some -12-200837241 polyester, polyamide, polyfluorocarbon, polyolefin, some polyurethane, polystyrene, polyvinyl alcohol, ethylene, and at least one vinyl A copolymer of a body (eg, poly(ethylene vinyl acetate)) and an acrylic resin. Web Bonding • Non-woven mesh, except for spunbond, has some micro strength when it is not bonded and needs to be strengthened by adhesion. The three basic bonding methods are thermal bonding, chemical bonding, and mechanical bonding. The importance of mode selection affects at least the functional properties of the fiber in the network. The disclosure of an embodiment provides an elastic non-woven composite material having a resilient elastic stretch which also has high durability, which is advantageous in apparel applications, particularly in washing, drying and/or dry cleaning. Or not shrinking. The disclosure in another embodiment provides an elastic nonwoven composite having good absorbency, flexibility and breathability for use in medical and sports wrap, bandage and tape applications. It has been found that micro-twisting treats a hydroentangled nonwoven composite material which advantageously has two or more non-woven portions which, in combination with heat fixation, can achieve the desired properties of resilient elastic stretch, durability and overall good Absorbency, softness and breathability. The durability of use is characterized by complete recovery after washing, dry cleaning, repeated use or long stretch. It has furthermore been found that by appropriate choice of adhesive, the product can be more advantageously provided with softness and comfort, for example for medical applications, or for providing durability and non-movability, for example for use in a belt. In general, the disclosed compositions and steps may be alternately formulated to comprise, constitute, or otherwise constitute a process having any suitable composition or disclosed herein. The compositions and steps may be additional or interchangeable to facilitate the absence or substantial absence of any ingredients, materials, compositions, adjuvants, types or processes used in the prior art, or functionalities in the formulation -13 - 200837241 The achievement and / or the purpose of the invention is not necessary. As used herein, "about" means that the quantity or state correction may exceed its disclosure as long as its disclosure advantage is understandable. The invention can be better understood by the following detailed description, drawings, and embodiments of the invention. [Embodiment] In one embodiment, the elastic composite nonwoven material comprises a first wet (w e t - f 〇 r m e d ) nonwoven fiber portion applied to the second nonwoven fiber substrate. The second nonwoven substrate is a pre-bonded web such as a carded knit web, a spunbond web or a carded hydraulic web (generally referred to as water weave). The nonwoven web basis weight may range from about 15 to about 150 g/m2' with a substrate basis weight of from about 20 to about 90 g/m2. Nonwoven substrates have the advantage of comprising a continuous synthetic filament such as a spunbond nonwoven, or a mechanically spunbonded discontinuous carded staple fiber such as a needle-rolled or hydroentangled web. The type of pre-spun is generally not considered to be important. For thermally bonded spunbond webs, the spunbond area of a point boned substrate is as low as about 7% and the degree of prespun adhesion to a flat boned substrate is as high as 100%. The style will change. Preferably, the nonwoven substrate is spunbonded and typically has a spunbonded area of from about 1 Torr to about 20%. The second nonwoven substrate fiber can contain several commercially available materials. Advantageously, the substrate fibers include polyester, polyamide and polyolefins such as polyethylene and polypropylene, although other fibrous materials such as enamel, cotton, polylactic acid, • 14-200837241 acetyl cellulose and acrylic can also be used. The first portion of the wet nonwoven web comprises a synthetic staple fiber, a natural pulp or a mixture of natural fibers and optionally other tanning materials and/or additives. The binder and other additives may be combined with the fluid and the fibers when the dispersion is formed to add different desired characteristics to the formed composite nonwoven fabric. For example, when the final product is used in the medical field, it may need to be mixed with the dip to provide biologically advantageous properties. Materials such as molecular sieves or similar compounds provide a location to attract or retain the biological composition of the wet non-woven layer that helps maintain the sterility of the environment in which the nonwoven is used. Of course, the amount of feed must be controlled to a level that does not adversely affect the desired softness, drape, and tactile properties of the final product. The first nonwoven fiber portion is wet. It typically involves the general step of forming the necessary fluid dispersion of fibers, pulp and other materials. The fluid dispersion is deposited on a porous member such as a fiber collecting metal mesh. Typically, the perforated component draws fluid from the dispersion to form a continuous sheet of mesh material. The wet web material formed can be further dried using known methods such as heating cans, ovens or heated gases. Wet non-woven nets are preferred because of their inherent dimensional stability and anisotropy. The first wet non-woven fiber portion can be composed of a plurality of layers which are generally used to provide different functional properties to the name layer. The first wet non-woven fiber portion has the advantage of having a grams in the range of from about 20 to about 100 g/m2, wherein the final product is in the range of 35 to about 250 g/m before the cognac treatment. It is preferably in the range of 3 5 -1 60 g/m 2 . For apparel applications, the first wet non-woven fibrous portion preferably contains from about 1% to about 100% natural pulp of softwood or hardwood or a combination thereof, and the remaining fibers are -15-200837241. The softness and quantity of the • need to be in the middle of the loose mesh box fiber. Other applications can foresee the need for 100% synthetic fibers to be attributed to the appearance of cellulose fibers. Preferred synthetic fiber polyesters such as polyethylene terephthalate (PET), preferably from about 1 to about 6 denier, are about 1.5 denier; fiber lengths ranging from about 0.25 to about 〇吋 (about 6 to About 20 mm), preferably about 0 · 25 ( (about 6 mm) Other suitable synthetic fibers include, but are not limited to, polyethylene and polypropylene, polyamine and hydrazine derived from polyolefin. 天然漿基本上可選自任一種漿與其摻合物。較佳 漿全部皆爲天然纖維素纖維且可含木質纖維如棉,雖 木製紙漿如雲杉、鐵杉、西洋杉、與松爲較佳,一般 硬木製紙漿如桉樹組合使用。亦可使用非木漿如瓊麻 洋麻、馬尼拉麻與其他。天然漿至多可爲最終產物重 之約7 5 %,包括纖維、底網與粘合劑組成物。天然 量可實質上基於複合系統中其他組成物與最終產物 求,如當所產生的複合不織布使用於醫療繃帶應用 需顯示之阻障能力。 第一非織纖維部份直接施用在第二非織底材。 實施例中,第一濕式非織纖維部份之材料分散於流 且該分散液施用在第二非織底材上。自第一非織纖 份提取流體以提供濕式複合材料。另一實施例中, 非織纖維部份沉積於有孔部件上如纖維收集網。自 液提取流體,通常經由有孔部件,以形成連續片狀 材料。形成的濕式網材料可用已知方法如加熱罐、 或加熱氣體進一步乾燥’以提供預先形成的第一非 -16- 200837241 維部份。預先形成的第一濕式非織纖維部份施用在第二 非織底材以提供複合材料。 施用第一纖維部份至第二底材後,對複合材料施以 低至中壓水力纏絡操作如Vi azme n sky等人發佈的美國專 利案號N〇.5,009,747所述之型式,其全文在此倂入參考 資料。藉一連串流體噴射通過複合材料,以足夠力量直 接冲擊第一濕式部份頂面,使表面纖維被推進第二底材 並與之,而交纏完成水力纏絡操作。使用一連串或一排 有孔噴射爲較佳’而孔洞間之間隔實質定義於前述專 利。水力纏絡爲結合第一部份與第二底材的較佳方法, 因水力纏絡以交纏噴射提供於機械方向具平行線微圖案 之最終非織複合物。經微縐處理的水力纏絡複合物,水 力纒絡平行線與在橫向機械方向之微縐圖樣結合可產生 小方塊所需線樣。 以傳統方式乾燥經水力纏絡的非織複合材料。乾燥 後的複合材料以液態粘合劑處理,以提供最終使用之穩 定性,包括抗張強度、洗滌耐性、或根據其最終應用的 其他所需特性。藉已知方法如壓型機(size-press)、淋 幕塗布機(curtain coater)、噴霧塗布機(spray coater)、 泡沬噴塗機(foam coater )可完成添加粘合劑。合適粘 合劑包含化學粘合劑,即一般所知的液態分散粘合劑, 如壓克力、醋酸乙烯酯、聚酯、聚乙烯醇、與其他傳統 粘合劑系列。例如在醫療應用上,少量軟性壓克力粘合 劑可用於控制毛邊或用作特殊色料或染料的載體、或作 -17- 200837241 爲進一步強化非織複合物吸收性的濕潤劑的載體。這些 軟性粘合劑通常歸類爲具範圍約-5至約-3 5 °C之低玻璃 轉移溫度。對服裝應用個別而言’較佳粘合劑仍爲壓克 力,儘管其玻璃轉移溫度於範圍約0至約30°C且特別設 計用在對纖維洗滌、乾燥與乾洗有嚴苛要求的腰帶。粘 合劑的含量佔整體最後非織複合材料約3至約35wt%, 具中間範圍如1 5至25 %對服裝應用來說是有利的,具約 20%則爲較佳。粘合劑的含量整體最後非織複合材料約 3至約35 wt%,而具範圍約3至約10%對醫療應用來說 是有利的。 在形成濕式非織片後,視需要以粘合劑做處理並乾 燥然後傳送至微縐處理製程。發明人相信例示之微縐處 理製程依循微縐處理之一般原則,特別是在傳入與移出 滾筒時延遲(retarding )與壓縮(compressing )濕式非 織板的組合,在濕式非織網上形成一系列小的,大致上 平行的摺層。摺層的峰與谷一般會在橫向機械方向上延 伸,如大致橫切於機械方向。非織網密實範圍爲10至50 %,較佳爲範圍在約1 5至約45 %。密實網之克數較佳範 圍在40-290g/m2,更佳範圍爲40-185g/m2。依照說明書編 號C27 1 5,美國麻州沃爾波的Micrex Corporation所提供 之微縐處理製程爲適當的。微縐處理機械在例如美國專 利3,260,778中則有更多詳細討論,雖然類似的乾縐處理 (dry-creping )可藉例如美國專利 3,236,7 1 8、3,8 1 0,280、 3,869,7 68、3,975,806、4,1 42,278、4,859,169 與 4,894,1 96 •18· 200837241 ^ 中所討論之機械達成。其他適合施行乾縐處理的替代方 法與裝置則在美國專利2,915,1〇9與4,090,385中有討論。 ^ 微縐處理製程被理解爲以包含驅動軸(driven roll) 與用來壓製靠著驅動軸的足以使其往前移動的一或多個 纖維網的衝壓表面(pressing surface)、以及相對於網 前進方向且位於網平面方向的緩衝葉片(retarder blade) 的葉片狀的乾綴機(drycreper )所施行的乾總處理,其 0 葉片尖端維持在鄰近於驅動軸,乾縐機至少有一表面加 熱熱塑型纖維組成至熱塑型纖維的熱固溫度。在較佳的 乾縐處理製程中,熱塑型纖維包含PET(聚酯)纖維及乾縐 機表面加熱至溫度介於250°F與3 50°F( 139°C與194°C )。 於製程狀況的其他實施例中,軸溫度可高些(如:可達 成較高速度與移除濕氣使纖維更快達到熱固溫度)或低 些(如:假如摩擦熱提供額外的熱給纖維)。加熱衝壓 表面及/或驅動軸。乾縐機之驅動軸包含一連續圓柱以配 φ 置該軸,如需要可附內加熱器。內加熱器包含供熱流體 通過的熱交換管路。熱流體可爲熱水、蒸氣、熱氣或燃 燒氣體、或油。在加熱衝壓表面的例子中,加熱模式可 爲熟知眾多方式之任一如電阻、蒸氣、熱水、熱氣體或 熱空氣。亦可使用輻射加熱或火焰預熱。同時施行乾縐 處理與熱固之方法可縮短網至少1〇%,增加片部件 (sheet member )之整體厚度。同時施行乾縐處理與熱固 之方法可縮短網在範圍介於約1〇至50%。 於壓實處理時加熱網至溫度範圍在約1 2 PC (約 •19- 200837241 250°F)至約218°C (約4251),較佳範圍在約149至約204 °C (約300至400°F),且更佳範圍在約182至約193°C (3 60至3 80°F) ’以降低當產物暴露於連續加熱時之收 縮或膨脹,尤其在服裝應用產物需經過抗縐處理 (withstand process)以去除纖維縐痕,通常爲163°C (325°F ),1 5分鐘。微縐處理時的上升溫度亦需熱定型 微縐圖樣並使縐處理的濕式不織布與其分離、不連續纖 維之組合毛邊降到最\氏。於微縐處理步驟後,將不織布 降至室溫。當目視時,縐圖樣足夠細密,而不會改變微 縐處理後的網的表面觸感。然而微縐處理步驟改善了網 的整體垂墜性並引入可回復性機械方向拉伸。最終之微 縐非織彈性材料實質顯示出改善的回復性伸展特性,包 含張力舒緩與低扭曲。尤其是當不織布於縱向上伸展至 高達15%時,橫向長度並無增加。 在大略敘述之後,下列實例包含例示目的以使本發 明可被快速理解且除非特別指明否則不受本發明範圍所 限。 實例 製作與測試適用於各式應用之標準複合網係使用 下列配方組合。 •由位於加拿大安大略省馬拉松的 Marathon Pulp,Inc. 所提供的北方漂白軟木牛皮紙漿。 •聚酯(PET)樹脂,標示爲F61HC且由位於美國田納 西州Kingsport的伊士曼化學公司提供,用來製造紡粘 -20- 200837241 網。 •聚乙烯合成紙漿,標示爲Fybrel SWP E-400且由總部 * 位於日本東京的三井化學公司製造。 •水性壓克力乳液粘合劑,標示爲EC0 E3 988,玻璃轉 移溫度爲+5 °C,由總部位於美國賓州費城的羅門哈斯公 司所提供。 接著使用下列技術測試標準樣品。 •根據TAPPI測試程序T410完成基重。 ® •根據TAPPI測試程序T411測量樣品厚度。 •根據ΤΑΡΡΊ測試程序T414測量撕裂強度(Elmendorf Tear strength )。 •根據TAPPI測試程序T494使用拉力試驗機(Zwick tensile tester )Z2.5 型測量抗張強度(tensile strength) 與拉伸 (elongation)。抓樣張力測試(Grab tensile testing)使用4吋寬6吋長的樣品,荷重速率(cross-head speed)爲12吋/分、顎口(jaw span)爲3吋與一般伸展 率。條狀張力測試(Strip tensile testing)使用1吋寬12 吋長的樣品,荷重速率爲1吋/分、顎口爲5吋且固定伸 展率。 以一般洗滌循環與乾燥清洗樣品以確定其外觀、收 縮百分率與延伸效能之回復百分率。以惠而浦洗衣機 LF A 57 00型施行洗衣循環,設定正常洗衣週期、使用中 溫水洗6分鐘。測量水溫爲約42°C (約108°F )。以攪拌 速度爲5 8 stroke/min清洗,接著有兩次脫水與其間的一 -21-The natural pulp can be selected substantially from any of the pulps and blends thereof. Preferably, the pulps are all natural cellulose fibers and may contain wood fibers such as cotton. Although wood pulp such as spruce, hemlock, cedar, and pine are preferred, generally hardwood pulp such as eucalyptus is used in combination. Non-wood pulp such as Qiongma kenaf, Manila hemp and others can also be used. The natural pulp may be at most about 75 % by weight of the final product, including fibers, a bottom web and a binder composition. The natural amount can be substantially based on other compositions and final products in the composite system, such as when the resulting composite nonwoven is used in medical bandage applications. The first nonwoven fiber portion is applied directly to the second nonwoven substrate. In an embodiment, the material of the first wet nonwoven fibrous portion is dispersed in a stream and the dispersion is applied to the second nonwoven substrate. The fluid is extracted from the first nonwoven fiber to provide a wet composite. In another embodiment, the nonwoven web portion is deposited on a perforated member such as a fiber collection web. The fluid is extracted from the liquid, typically via a perforated member, to form a continuous sheet of material. The formed wet web material can be further dried by known methods such as heating cans, or heated gas to provide a preformed first non-16-200837241 dimension portion. A preformed first wet nonwoven web portion is applied to the second nonwoven substrate to provide a composite. After applying the first fiber portion to the second substrate, the composite material is subjected to a low to medium pressure hydraulic entanglement operation as described in U.S. Patent No. 5,009,747, issued to the name of Break into the reference here. A series of fluid jets are passed through the composite material to directly impact the top surface of the first wet portion with sufficient force to cause the surface fibers to be advanced into the second substrate and entangled to complete the hydraulic entanglement operation. It is preferred to use a series or a row of apertured jets and the spacing between the apertures is substantially defined by the aforementioned patent. Hydraulic entanglement is a preferred method of combining the first portion with the second substrate, and the hydroentanglement is provided by the entanglement spray to provide the final non-woven composite with parallel line micropatterns in the machine direction. The micro-twisted hydroentangled complex, the parallel line of hydraulic enthalpy and the microscopic pattern in the transverse mechanical direction can produce the desired line of small squares. The hydroentangled nonwoven composite is dried in a conventional manner. The dried composite is treated with a liquid binder to provide stability for end use, including tensile strength, wash resistance, or other desirable characteristics depending on its end use. The addition of the binder can be accomplished by known methods such as a size-press, a curtain coater, a spray coater, and a foam coater. Suitable binders include chemical binders, commonly known as liquid dispersion binders such as acrylic, vinyl acetate, polyester, polyvinyl alcohol, and other conventional binders. For example, in medical applications, a small amount of soft acrylic adhesive can be used to control burrs or as a carrier for special colorants or dyes, or as a carrier for humectants to further enhance the absorbency of nonwoven composites -17-200837241. These soft adhesives are generally classified as having a low glass transition temperature ranging from about -5 to about -3 5 °C. For apparel applications, the preferred binder is still acrylic, although its glass transition temperature ranges from about 0 to about 30 ° C and is specifically designed for use in belts where fiber washing, drying and dry cleaning are critical. . The binder content is from about 3 to about 35 wt% of the overall final nonwoven composite, with a median range of from 15 to 25% being advantageous for apparel applications, with about 20% being preferred. The binder content is from about 3 to about 35 wt% of the total final nonwoven composite, with a range of from about 3 to about 10% being advantageous for medical applications. After forming the wet nonwoven sheet, it is treated with an adhesive as needed and dried and then transferred to a micro-twisting process. The inventors believe that the illustrated micro-twisting process follows the general principles of micro-twisting, particularly in the combination of retarding and compressing wet non-woven boards when passing in and out of the drum, on wet non-woven webs. A series of small, substantially parallel folds are formed. The peaks and valleys of the fold generally extend in the transverse mechanical direction, such as generally transverse to the machine direction. The nonwoven web has a densification range of from 10 to 50%, preferably from about 15 to about 45%. The number of grams of the dense mesh is preferably in the range of 40 to 290 g/m2, more preferably in the range of 40 to 185 g/m2. According to the manual number C27 1 5, the micro-treatment process provided by Micrex Corporation of Volbo, MA is suitable. Micro-twisting machines are discussed in more detail, for example, in U.S. Patent No. 3,260,778, although similar dry-creping can be utilized, for example, in U.S. Patents 3,236,7,8, 3,8,0,280, 3,869,7,68. The machines discussed in 3,975,806, 4,1 42,278, 4,859,169 and 4,894,1 96 •18· 200837241 ^ were reached. Other alternative methods and devices suitable for performing cognac processing are discussed in U.S. Patents 2,915,1,9 and 4,090,385. ^ The micro-twisting process is understood to include a driven roll and a pressing surface for pressing one or more webs against the drive shaft sufficient to move it forward, and relative to the net The dry total process performed by the blade-like drycreper of the retarder blade in the direction of the web, the zero blade tip is maintained adjacent to the drive shaft, and the dryer has at least one surface heating The thermoplastic fibers constitute a thermosetting temperature to the thermoplastic fibers. In a preferred cognac process, the thermoplastic fibers comprise PET (polyester) fibers and the surface of the dryer is heated to temperatures between 250 °F and 3 50 °F (139 ° C and 194 ° C). In other embodiments of the process conditions, the shaft temperature can be higher (eg, higher speeds can be achieved with moisture removed to allow the fibers to reach the thermoset temperature faster) or lower (eg, if frictional heat provides additional heat to the shaft) fiber). Heat the stamped surface and/or the drive shaft. The drive shaft of the dryer consists of a continuous cylinder to accommodate the shaft, and an internal heater can be attached if required. The inner heater contains a heat exchange line through which the heating fluid passes. The hot fluid can be hot water, steam, hot or combustible gas, or oil. In the example of heating the stamped surface, the heating mode can be any of a number of well known methods such as electrical resistance, steam, hot water, hot gases or hot air. Radiant heating or flame preheating can also be used. At the same time, the method of cognac treatment and thermosetting can shorten the net by at least 1% and increase the overall thickness of the sheet member. At the same time, the method of cognac treatment and thermosetting can shorten the mesh in the range of about 1〇 to 50%. Heating the web during compaction to a temperature in the range of about 1 2 PC (about 19-200837241 250 °F) to about 218 ° C (about 4251), preferably in the range of about 149 to about 204 ° C (about 300 to 400 °F), and more preferably in the range of about 182 to about 193 ° C (3 60 to 3 80 ° F) 'to reduce shrinkage or expansion when the product is exposed to continuous heating, especially in apparel applications Withstand process to remove fiber scars, typically 163 ° C (325 ° F), 15 minutes. The rising temperature at the time of micro-twisting also requires heat setting of the micro-pattern and the separation of the wet-type non-woven fabric of the enamel treatment and the combination of the discontinuous fibers to the maximum. After the micro-twisting step, the non-woven fabric was lowered to room temperature. When visually inspected, the 绉 pattern is sufficiently fine to not change the surface feel of the mesh after the micro 绉 treatment. However, the micro-twisting step improves the overall drape of the web and introduces a reversible mechanical stretch. The final micro-non-woven elastic material exhibits an improved recovery stretch characteristic, including soothing tension and low distortion. Especially when the non-woven fabric is stretched up to 15% in the longitudinal direction, the lateral length does not increase. The following examples are intended to be illustrative only, and are not to be construed as limiting. EXAMPLES Fabrication and testing Standard composite networks for a variety of applications use the following combination of formulations. • Northern bleached softwood kraft pulp supplied by Marathon Pulp, Inc., Marathon, Ontario, Canada. • Polyester (PET) resin, designated F61HC, supplied by Eastman Chemical Company, Kingsport, Tennessee, USA, for the manufacture of spunbond -20-200837241. • Polyethylene synthetic pulp, labeled Fybrel SWP E-400, manufactured by Mitsui Chemicals, Inc., headquartered in Tokyo, Japan. • Aqueous acrylic emulsion adhesive, labeled EC0 E3 988, with a glass transfer temperature of +5 °C, supplied by Rohm and Haas Company, Philadelphia, PA. Standard samples were then tested using the following techniques. • Complete the basis weight according to the TAPPI test procedure T410. ® • Measure the sample thickness according to the TAPPI test procedure T411. • Elemdorf Tear strength is measured according to the ΤΑΡΡΊ test procedure T414. • Tensile strength and elongation were measured according to the TAPPI test procedure T494 using a Zwick tensile tester Model Z2.5. Grab tensile testing used a 4 吋 wide 6 吋 sample with a cross-head speed of 12 吋/min, a jaw span of 3 吋 and a general extension. Strip tensile testing was performed using a 1 吋 wide 12 吋 sample with a load rate of 1 吋/min, a 颚 mouth of 5 吋 and a fixed elongation. The sample was washed in a general wash cycle and dried to determine the percent recovery of its appearance, percent shrinkage and elongation performance. The Whirlpool washing machine LF A 57 00 is used for the laundry cycle, which is set to normal laundry cycle and washed with medium temperature for 6 minutes. The water temperature was measured to be about 42 ° C (about 108 ° F). Wash at a stirring speed of 5 8 strokes/min, followed by two dehydrations with a -21- 200837241 次沖洗。桌~^次脫水使用340rpm,最後一 515rpm。用於清洗與乾燥的樣品縱向長度爲 長度爲8.5吋。樣品與兩件用做壓艙物的牛 驗室外套一同清洗。在每一洗衣循環時使用 Tide纖維去垢劑。 乾燥樣品於惠而浦乾衣機LAE 5700塑 熱設定爲85°C ( 185°F)、30分鐘。樣品與讳 物的中等尺寸棉實驗室外套一同乾燥。清沒 個別的清洗與乾燥後產生。測量樣品在三個 的縱向長度與橫向長度。收縮百分率計算如 最後長度)/ (起始長度)X100。 使用拉力試驗機Z2.5型測量循環抗張 t e n s i 1 e s t r e n g t h ),用以確認可回復延伸程度 T494將樣品切割爲2吋寬與1 2吋長。裝置櫝 的橡膠面頜,使用之顎口爲10吋,且荷重速 分。設計拉力試驗拉伸樣品至不同長度, 伸設定循環十次。在每一個十次循環,拉併 始長度之預定程度,維持住拉伸1 5分鐘,立 置(0%拉伸或10吋)。在第十次循環後, 品並測量總長度。可回復延伸百分率計算如 最後長度)xlOO。 樣品的熱氣收縮率藉調整樣品至 (3 25°F ) 15 分鐘,使用 Grieve &amp; Henry ί 乾燥前後測量縱向與橫向長度。用於熱氣_ 次脫水使用 11吋且橫向 等尺寸棉實 20ml濃縮 :施行,使用 丨件用做壓艙 t收縮於三次 循環前與後 (起始長度- 強度(cycle 。根據TAPPI I品於3吋寬 :率爲1 0吋/ I註記每一拉 i樣品至其原 ί回復至原位 自頜移除樣 (起始長度/ 溫度 163 °C ί流烘箱並在 3燥之樣品縱 -22- 200837241 向長度爲11吋且橫向長度爲8.5吋。於縱向用鉗子固定 樣品於烘箱內部中間高度的水平裝置上。收縮百分率計 算如(起始長度-最後長度)/(起始長度)X 1 0 Q。此測試 係仿造用在抗縐纖維處理的溫度條件。 例1 此例顯示根據C27 1 5號說明書施行之微縐處理對 產物之收縮與可回復延伸的效果。於是藉先形成兩個別 的非織網,接著對其一起進行水力纏絡以形成兩層的最 終產物,來製造複合不織布。使用傾斜的金屬網紙製造 機,自由1 00 %馬拉松軟木漿纖維所組成的纖維供給形成 3 Og/m2濕式片,來製備第一網。成形後,將濕式片置於 2Og/m2 PET網上,藉紡粘製程形成19%點紡粘區域。兩 不同網之合計重量50g/m2,接著藉由使其通過八個水力 歧管(manifolds ),以製程速度138m/min水力纒絡在一 起每一歧管具密度爲2000 holes/m、每個孔洞直徑爲92 微米。每一水力歧管壓力設定如下··歧管1設爲16b ar ; 歧管2設爲24bar;歧管3設爲41bar;歧管4設爲50bar; 歧管5設爲75bar ;歧管6、歧管7與歧管8設爲80bar。 經由水力纏絡歧管傳送網,使用單層PET細網目導管, 其網目數爲41x30.5/cm、厚度爲〇.33mm並標示爲Flex 310K,由Albany International提供。水力纒絡後,以壓 克力粘合劑,羅門哈斯化學公司提供的ECO 39 8 8型處理 複合網,以達到粘合劑含量佔總最後重量之約17%。粘 合劑處理後,乾燥並儲存材料。整體材料基重爲60g/m2 -23- 200837241 並標示爲樣品A。樣品材料b係爲樣品A依照C27 15號 說明書經Mic]:ex⑧ Corporation之微縐製程處理後。使用 25%密實度設定微縐處理樣品b,以速度23m/min與熱 定型溫度1 9 3 °C,產生每公分1 6 -1 8個細脊。以相同密實 度與速度微縐處理樣品C,但不熱定型。複複合網的典 型數據與其微縐變型總結在下面兩表中。 表一.典型特性 樣品 A B C 特性 測量單位 基重 克/米2 60 96 79 厚度 微米 285 435 590 縱向抓樣張力測試 克 14200 16050 1 3300 橫向抓樣張力測試 克 11650 13150 11900 縱向斷裂伸張率 % 29.1 69.5 53.5 橫向斷裂伸張率 % 52.5 44.5 48.5 縱向撕裂強度 克 200 360 3 60 橫向撕裂強度 克 280 455 625 熱收縮於163°C (325F) 15分鐘 % 9.6 0.0 *(1.4) 縱向洗滌收縮,3循環 % 2.8 1.1 *(15.9) 橫向洗滌收縮,3循環 % 0.7 0.5 0.4 這些樣品在三個洗滌與乾燥循環後以延伸取代收縮。 -24- 200837241 表二.可回復延伸特性 A B C 每一循環 之拉伸 施力 可回復性 施力 可回復性 施力 可回復性 % 克/50毫米 % 克/50毫米 % 克/50毫米 % 2.5 5000 99.7 115 100 80 97.7 5.0 5470 98.7 205 100 95 97.4 7.5 6035 97.7 250 99.7 115 96.6 10 6555 96.5 352 99.7 300 95.8 15 7110 93.4 674 98.0 395 94.9 20 7615 90.4 1110 95.2 2637 85.7 25 8783 87.21 2100 92.3 3008 82.2 30 8950 85.0 3835 87.7 6570 80.0 35 斷裂 — 5200 84.8 6835 77.9 40 7135 80.9 7654 75.6 45 7700 78.1 8660 73.2 50 斷裂 — 斷裂 一 表一顯示縮性當其與無熱固定的微縐處理與無任 何微纔處理的樣品比較時藉微縐處理結合熱固定可達優 良的耐收縮性。 表二顯示藉微縐處理結合熱固定可達優良的可回 復延伸特性,如樣品B當樣品拉伸至2 5 %時可維持大於 90%可回復性,反之無熱固定的樣品若欲維持大於90% -25- 200837241 可回復性,樣品拉伸僅能低於20%。無任何微縐處理的 樣品A拉伸在低於25%時可維持大於90%可回復性。施 力數據亦顯示張力舒緩相對於需較大施力進行拉伸使其 延展之未進行熱固定的另兩個樣品,於微縐處理時進行 熱固定之樣品B爲較佳。 例2 第二標準複合不織布由1 00 %合成纖維網所構 成,除了濕式頂面由100%三井化學的E400聚乙烯漿與 重量爲30g/m2之外,係藉與例1相同的一般方式製備。 底面(base phase )之外仍爲20g/m2PET紡粘網。水力纏 絡條件與例1不同,只使用4個歧管。每一水力歧管壓 力設定如下:歧管1設爲55bar ;歧管2設爲41 bar ;歧 管3設爲48bar;歧管4設爲41b ar。製程速度爲20 m/ min。 以羅門哈斯化學公司所提供的ECO 3988型壓克力粘合 劑處理水力纏絡複合材,使粘合劑含量佔最後總重量之 約1 7 %。粘合劑處理後,乾燥並儲存材料。整體材料基 重爲60g/m2。水力纏絡複合物依照C2715號說明書,以 速度8m/min進行Micrex Corporation之微縐處理製程; 使用25%密實度設定與熱固定溫度132。(:可產生細脊 16-18個/cm。表三與表四闡明此複合材料的典型特性包 含其可回復延伸性能。 -26- 200837241 表三.典型特性 特性 測量單位 基重 克/米2 65.5 厚度 微米 550 縱向抓樣張力測試 克 7100 橫向抓樣張力測試 克 4800 縱向斷裂伸張率 % 72.8 橫向斷裂伸張率 % 45.5 縱向撕裂強度 克 &gt;1600 橫向撕裂強度 克 &gt;1600 表四.典型特性 可回復延伸性能 施力(克/50毫米) 回復性(%) 每一循環 之拉伸 (%) 2.5 65 99.3 5.0 95 98.7 7.5 125 98.7 10 · 145 97.1 15 200 97.1 20 280 94.9 25 465 91.7 30 630 89.6 例3200837241 times rinse. The table was dehydrated using 340 rpm and the last 515 rpm. The longitudinal length of the sample used for washing and drying is 8.5 Å. The sample is cleaned with two pieces of the outer test kit for ballast. Tide fiber detergent is used at each laundry cycle. The dried sample was set at 85 ° C (185 ° F) for 30 minutes on a Whirlpool dryer LAE 5700. The sample was dried with a medium size cotton lab coat of the sputum. Cleared after individual cleaning and drying. The sample was measured in three longitudinal lengths and lateral lengths. The percent shrinkage is calculated as the final length) / (starting length) X100. The tensile tester Z2.5 was used to measure the cyclic tension t e n s i 1 e s t r e n g t h ) to confirm the recoverable elongation. The T494 cut the sample into a width of 2 与 and a length of 12 吋. The rubber face of the device , is 10 颚, and the load is fast. Design the tensile test to stretch the sample to different lengths and set the cycle ten times. At each ten cycles, pull the initial length to a predetermined extent, and maintain the stretch for 15 minutes, standing (0% stretch or 10 吋). After the tenth cycle, measure and measure the total length. The percentage of recoverable extensions is calculated as the final length) xlOO. The hot gas shrinkage of the sample was adjusted to (3 25 °F) for 15 minutes and the longitudinal and lateral lengths were measured before and after drying using Grieve &amp; Henry ί. For hot air _ sub-dewatering using 11 吋 and horizontal equal-size cotton 20 ml concentration: implementation, using the 丨 piece for ballast t shrink before and after three cycles (starting length - strength (cycle. According to TAPPI I product in 3吋 Width: The rate is 1 0 吋 / I Note each pull i sample to its original ί return to the in situ self-jaw removal sample (starting length / temperature 163 ° C ί flow oven and in the dry sample longitudinal -22 - 200837241 The length is 11吋 and the lateral length is 8.5吋. The sample is fixed in the longitudinal direction with a pair of clamps on the horizontal height of the middle of the oven. The percentage of shrinkage is calculated as (starting length - last length) / (starting length) X 1 0 Q. This test is based on the temperature conditions used for anti-caries fiber treatment. Example 1 This example shows the effect of micro-twisting treatment on the shrinkage and reversible extension of the product according to the instructions of C27 1 5, so that two forms are formed first. Other non-woven nets, which are then hydraulically entangled to form a two-layer final product, to make a composite non-woven fabric. Using a slanted metal mesh paper making machine, a fiber supply consisting of free 100% marathon softwood pulp fibers is formed. 3 O g/m2 wet sheet to prepare the first net. After forming, the wet sheet was placed on a 2Og/m2 PET net to form a 19% point spunbonded area by a spunbonding process. The total weight of the two different nets was 50g/m2. Then, by passing it through eight hydraulic manifolds, the process speed is 138 m/min, and each manifold has a density of 2000 holes/m and a diameter of 92 micrometers per hole. The manifold pressure is set as follows: • manifold 1 is set to 16b ar; manifold 2 is set to 24 bar; manifold 3 is set to 41 bar; manifold 4 is set to 50 bar; manifold 5 is set to 75 bar; manifold 6 and manifold 7 With manifold 8 set to 80 bar. Via a hydraulic wrap manifold transfer network, using a single layer of PET fine mesh conduit with a mesh size of 41x30.5/cm and a thickness of 〇.33mm and labeled Flex 310K, courtesy of Albany International After the hydraulic splicing, the ECO 39 8 8 treated composite mesh supplied by Rohm and Haas Chemical Company was used to achieve a binder content of about 17% of the total final weight. After the adhesive treatment Dry and store the material. The basis weight of the whole material is 60g/m2 -23- 200837241 and is labeled as sample A. The sample material b is sample A. After the treatment of the C27 No. 15 specification by Mic]:ex8 Corporation, the sample b was treated with 25% compactness and set at a speed of 23 m/min and a heat setting temperature of 1 3 3 ° C, resulting in 1 6 cm per cm. -1 8 fine ridges. Sample C was treated with the same compactness and speed, but not heat set. The typical data of the complex composite network and its micro-transformation are summarized in the following two tables. Table 1. Typical Characteristics Sample ABC Characteristic Measurement Unit Basis Weight/m 2 60 96 79 Thickness Micron 285 435 590 Longitudinal Grab Tension Test Gram 14200 16050 1 3300 Lateral Grab Tension Test Gram 11650 13150 11900 Longitudinal Breakage Tensile Rate% 29.1 69.5 53.5 Transverse fracture elongation % 52.5 44.5 48.5 Longitudinal tear strength gram 200 360 3 60 Transverse tear strength 280 455 625 Heat shrinkage at 163 ° C (325 F) 15 minutes % 9.6 0.0 * (1.4) Longitudinal wash shrinkage, 3 cycles % 2.8 1.1 *(15.9) Lateral wash shrinkage, 3 cycles % 0.7 0.5 0.4 These samples were shrunk with extension substitution after three wash and dry cycles. -24- 200837241 Table 2. Recoverable extension characteristics ABC Tensile force per cycle Recoverable force Recoverable force Recoverability % g / 50 mm % g / 50 mm % g / 50 mm % 2.5 5000 99.7 115 100 80 97.7 5.0 5470 98.7 205 100 95 97.4 7.5 6035 97.7 250 99.7 115 96.6 10 6555 96.5 352 99.7 300 95.8 15 7110 93.4 674 98.0 395 94.9 20 7615 90.4 1110 95.2 2637 85.7 25 8783 87.21 2100 92.3 3008 82.2 30 8950 85.0 3835 87.7 6570 80.0 35 Fracture - 5200 84.8 6835 77.9 40 7135 80.9 7654 75.6 45 7700 78.1 8660 73.2 50 Fracture - Fracture Table 1 shows the shrinkage when it is treated with non-heat-fixed micro-defects and samples without any micro-treatment In comparison, micro-twisting treatment combined with heat fixation can achieve excellent shrinkage resistance. Table 2 shows that the micro-twisting treatment combined with heat fixation can achieve excellent reproducible elongation characteristics, such as sample B can maintain greater than 90% recoverability when the sample is stretched to 25 %, whereas if the sample without heat is to be maintained more than 90% -25- 200837241 Recoverability, sample stretching can only be less than 20%. Sample A stretch without any micro-twisting maintains greater than 90% recoverability at less than 25%. The force data also showed that the tension relief was better than the other two samples which were not subjected to heat fixation by stretching with a large force, and which was heat-fixed during the micro-twisting treatment. Example 2 The second standard composite nonwoven fabric consisted of 100% synthetic fiber web, except that the wet top surface was made of 100% Mitsui Chemical's E400 polyethylene pulp and the weight was 30 g/m2, in the same general manner as in Example 1. preparation. Beyond the base phase is still a 20 g/m2 PET spunbond web. The hydraulic entanglement condition is different from that of Example 1, and only four manifolds are used. The hydraulic manifold pressure was set as follows: manifold 1 was set to 55 bar; manifold 2 was set to 41 bar; manifold 3 was set to 48 bar; manifold 4 was set to 41b ar. The process speed is 20 m/min. The hydroentangled composite was treated with ECO 3988 Acrylic Adhesive supplied by Rohm and Haas Chemical Company to make the binder content approximately 17% of the final total weight. After the adhesive is processed, the material is dried and stored. The overall material has a basis weight of 60 g/m2. The hydraulic entanglement compound was subjected to a micro-cylinder treatment process of Micrex Corporation at a speed of 8 m/min in accordance with the specification of C2715; a setting of 25% compactness and a heat setting temperature of 132 were used. (: can produce fine ridges 16-18 / cm. Table 3 and Table 4 clarify that the typical characteristics of this composite material include its reproducible elongation properties. -26- 200837241 Table 3. Typical characteristic characteristics measurement unit basis weight / m 2 65.5 Thickness Micron 550 Longitudinal Grab Tension Test Gram 7100 Horizontal Grab Tension Test Gram 4800 Longitudinal Fracture Tensile Rate % 72.8 Transverse Fracture Tensile Rate % 45.5 Longitudinal Tear Strength Gram > 1600 Transverse Tear Strength Gram > 1600 Table IV. Typical Characteristics Recoverable extension performance (g/50 mm) Recovery (%) Tensile per cycle (%) 2.5 65 99.3 5.0 95 98.7 7.5 125 98.7 10 · 145 97.1 15 200 97.1 20 280 94.9 25 465 91.7 30 630 89.6 Example 3 除下列不同之外,依照例2製備另一標準樣品。頂 面層爲由100%馬拉松軟木漿形成的20g/m2濕式片,而 -27- 200837241 底面層爲80g/m2 PET紡粘網,在水力纒絡前其結合重量 爲lOOg/m2。四個水力歧管壓力設定如下:歧管1設爲 7 0bar ;歧管2設爲48bar ;歧管3設爲70bar ;歧管4設 爲34bar。以ECO 39 8 8粘合劑處理25%最後重量的水力 纏絡複合物,以達到最終重量136g/m2。水力纒絡複合物 依照 C2715號說明書,以速度 8m/min進行 Micrex Corporation之微縐處理製程;使用35%密實度設定與熱 固定溫度200°C可產生細脊22個/cm。表五闡明此複合材 料的典型特性,表六顯示其在熱定型處理下施行與不施 行微縐處理的可回復延伸特性。 表五.典型特性 樣品 微縐處理前 微縐處理後 特性 測量單位 基重 克/米2 136 186 厚度 微米 390 620 縱向抓樣張力測試 克 35700 41825 橫向抓樣張力測試 克 33500 39645 縱向斷裂伸張率 % 30 74.1 橫向斷裂伸張率 % 57.7 46.6 縱向撕裂強度 克 800 &gt;1600 橫向撕裂強度 克 1240 &gt;1600 熱收縮於325F,15分鐘 % 0 L1 縱向洗滌收縮,3循環 % 1.8 1.3 橫向洗滌收縮,3循環 % 0.5 0 -28- 200837241 表六·可回復延伸性能 微縐處理前 微綴處理後 每一循環 之拉伸 施力 可回復性 施力 可回復性 (%) (克/50毫米) (%) (克/50毫米) (%) 5.0 16020 98.7 500 100 7.5 18160 97.7 600 99.7 10 17975 96.2 1060 99.3 15 19900 91.5 1600 98.7 20 20775 88.8 4185 95.2 25 22785 87.2 7220 91.5 表六顯示其優良可回復延伸性可藉具熱固定之微 縐處理來達到,如樣品可維持拉伸至25 %時可維持大於 90%可回復性,反之無任何微縐處理的樣品欲維持大於 90%可回復性,樣品拉伸僅能低於20%。 施力數據亦闡明張力舒緩於微縐處理製程後進行 爲較佳,正如需更大施力對抗拉伸樣品使其延展而不需 微總處理。 當本發明前述之較佳實施例被用於闡明提出,前面 述敘並不視爲本發明之限制。因此各式變型、改寫與替 代皆可出現且不悖離本發明之精神與範圍。 【圖式簡單說明】 〇 【元件符號說明】 Μ 〇 -29- 200837241 五、中文發明摘要: 本發明係關於具改良尺寸與熱回復性(低扭曲)並允 V 許在動態使用情形下作連續調整之微縐複合不織布°此產 物包含下列特性··張力舒緩、有吸收力、透氣性、可洗條 性、變換吃紗成形法(s t i t c h h ο 1 d i n g )、強度以及網均齊 度(web uniformity )。此型產物的關聯應用包含腰帶與其 他成衣市場的內裡’運動與醫療膠帶、包裹物與繃帶’以 及功能性的包紮材料。 六、英文發明摘要:Another standard sample was prepared in accordance with Example 2 except for the following differences. The top layer is a 20 g/m2 wet sheet formed from 100% marathon softwood pulp, while the -27-200837241 bottom layer is a 80 g/m2 PET spunbond web having a combined weight of 100 g/m2 before hydraulic warping. The four hydraulic manifold pressures were set as follows: manifold 1 was set to 70 bar; manifold 2 was set to 48 bar; manifold 3 was set to 70 bar; manifold 4 was set to 34 bar. A 25% final weight hydraulic entanglement complex was treated with ECO 39 8 8 binder to achieve a final weight of 136 g/m2. Hydraulic enthalpy complex According to C2715, Micrex Corporation's micro-twisting process was carried out at a speed of 8 m/min; a fine ridge of 22 pieces/cm was produced using a 35% compactness setting and a heat setting temperature of 200 °C. Table 5 illustrates the typical characteristics of this composite material. Table 6 shows the reproducible elongation characteristics of the composite material subjected to heat setting treatment without or without micro-twisting treatment. Table 5. Typical characteristics of the sample before micro-twisting treatment After micro-twisting treatment characteristic measurement unit basis weight g / m 2 136 186 thickness micron 390 620 longitudinal grab tension test gram 35700 41825 lateral grab tension test gram 33500 39645 longitudinal fracture elongation rate% 30 74.1 Transverse fracture elongation rate 57.7 46.6 Longitudinal tear strength gram 800 &gt; 1600 transverse tear strength gram 1240 &gt; 1600 heat shrinkage at 325F, 15 minutes % 0 L1 longitudinal wash shrinkage, 3 cycles % 1.8 1.3 transverse wash shrinkage, 3 cycles% 0.5 0 -28- 200837241 Table VI·Recoverable extension properties Tensile force per recovery after micro-six treatment before treatment. Recoverability (%) (g/50 mm) %) (g/50 mm) (%) 5.0 16020 98.7 500 100 7.5 18160 97.7 600 99.7 10 17975 96.2 1060 99.3 15 19900 91.5 1600 98.7 20 20775 88.8 4185 95.2 25 22785 87.2 7220 91.5 Table 6 shows its excellent recoverable extensibility It can be achieved by heat-fixing micro-twisting treatment, such as the sample can maintain more than 90% recoverability when stretched to 25%, and vice versa. The product is intended to maintain greater than 90% recoverability, and the sample stretch can only be less than 20%. The force data also clarifies that the tension is soothed after the micro-twisting process is better, as more force is applied to stretch the sample to stretch it without micro-processing. The foregoing description of the preferred embodiment of the invention is intended to Various modifications, adaptations, and substitutions may be made without departing from the spirit and scope of the invention. [Simple description of the diagram] 〇 [Description of component symbols] Μ 〇-29- 200837241 V. Abstract of the invention: The present invention relates to improved size and thermal recovery (low distortion) and allows V to be continuous under dynamic use conditions. Adjusted micro-composite composite non-woven fabric ° This product contains the following characteristics: · Soothing tension, absorbency, breathability, washableness, transforming yarn forming method (stitchh ο 1 ding), strength and net uniformity ). The associated applications for this type of product include the inner lining 'sports and medical tapes, wraps and bandages' of the belt and other ready-to-wear markets, as well as functional dressing materials. Sixth, English invention summary: This invention relates to a micro-creped composite nonwoven having improved dimensional and thermal recovery (low distortion) allowing it to continuously adjust under dynamic end use conditions. This product incorporates the following properties: ease of tension, absorbency, breathability, launderability, stitch holding, strength and web uniformity. The end uses envisioned for this type of product include waistband and other interliners for the apparel market, sports and medical tapes, wraps and bandages, and functional packaging materials. 200837241 十、申請專利範圍: 1. 一種形成彈性複合非織網之方法,係具低能量可回復機 械方向彈性與優良等方特性,其特徵步驟τ : 提供一由複數條合成纖維所構成的黏合非織底網 材料;, 提供複數種類合成纖維與纖維素材料; 任意分散該合成纖維與纖維素材料於流體中以形 成配料; 沉積該配料於一具小孔之部件; 經由該具小孔之部件自該沉積配料移除流體以形 成一濕式非織網; 對該濕式非織網進行水力纒絡(hydroentangling ) 以在該型非織底網上形成一非織複合網; 微綴處理(microcrepping)該非織複合網達密實度 範圍介於約10%至約50%以形成一密實非織網;以及 於微縐處理時加熱該密實非織網以形成彈性非織 網。 2·如申請專利範圍第1項之方法,其特徵在於: 於該型非織底網上直接沉積合成纖維與纖維素材 料之該流體配料; 經由該型非織底網自該沉積配料移除流體以形成 一濕式非織網頂面(toppahse); 對該濕式不織布頂面進行水力纏絡以在該型非織 底網上形成一非織複合網; 微縐處理該非織複合網達密實度範圍介於約丨〇 % -30- 200837241 至約50%以形成一密實非織網;以及 ' 於微縐處理時加熱該密實非織網以形成該彈性非 • 織網。 3. 如申請專利範圍第1項或第2項之方法,其特徵在於該 非織底網爲連續紡黏(spunbonded )長絲之非織網。 4. 如申請專利範圍第1項或第2項之方法,其特徵在於該 非織底網爲熔吹(meltblown )長絲之非織網。 5. 如申請專利範圍第1項或第2項之方法,其特徵在於該 非織底網爲梳棉與針乳(needlepunched)的合成纖維之 非織網。 6. 如申請專利範圍第1項或第2項之方法,其特徵在於該 非織底網爲梳棉與水力纏絡式的合成纖維之非織網。 7. 如申請專利範圍第1項或第2項之方法,其特徵在於該 濕式非織網包含合成纖維漿。 8. 如申請專利範圍第1項至第7項中任一項之方法,其特 徵在於濕式非織網包含選自於軟木漿、硬木漿、棉花纖 φ 維、棉短絨、天然纖維、天然纖維漿與其組合物之纖維 素材料。 9 ·如申請專利範圍第1項至第7項中任一項之方法,其特 徵在於濕式非織網包含選自於瓊麻、馬尼拉麻、亞麻、 洋麻、黃麻、赫納昆麻之纖維素材料。 10·如申請專利範圍第1項至第9項中任一項之方法,其特 徵在於合成纖維爲聚合纖維。 1 1 ·如申請專利範圍第丨項至第1 0項中任一項之方法,其 特徵在於合成纖維係選自於乙醯纖維素、尼龍、聚烯 -3卜 200837241 烴、聚酯、嫘縈與其組合物。 1 2 ·如申請專利範圍第1項至第1 1項中任一項之方法,其 ^ 特徵在於添加樹脂粘合劑至水力纏絡式複合非織網之 步驟。 1 3 ·如申請專利範圍第5項或第6項之方法,其特徵在於彈 性複合非織網包含複數種合成黏合纖維,其至少部份熱 熔合爲合成短纖維。 1 4.如申請專利範圍第1項至第1 3項中任一項之方法,其 Φ 特徵在於彈性複合非織網具一基礎重量約40至約 290g/m2,較佳爲介於約 40g/m2 至 185g/m2。 1 5 _如申請專利範圍第1項至第1 4項中任一項之方法,其 特徵在於密實複合非織網具至少1 5 %之密實度。 1 6.如申請專利範圍第1項至第1 5項中任一項之方法,其 特徵在於密實複合非織網具不超過45 %之密實度。 1 7.如申請專利範圍第1項至第1 6項中任一項之方法,其 特徵在於微縐處理時加熱複合非織網至溫度介於範圍 φ 約 1 2 1°C 至約 2 1 8 °C。 1 8 ·如申請專利範圍第1項至第1 7項中任一項之方法,其 特徵在於微縐處理時加熱複合非織網至溫度介於範圍 約 149°C 至約 204°C。 1 9 ·如申請專利範圍第1項至第1 8項中任一項之方法,係 用於改善非織網因清洗與乾燥循環所導致之收縮的耐 性。 20.如申請專利範圍第19項之方法,其特徵在於濕式非織 網更包含選自於軟木漿、硬木漿、棉花纖維、棉短絨、 -32- 200837241 天然纖維、天然纖維漿與其組合物之纖維素材料。 21. 如申請專利範圍第19項或第20項之方法,其特徵在於 非織底網爲梳棉與針軋的合成纖維之非織網。 22. 如申請專利範圍第19項或第20項之方法,其特徵在於 非織底網爲梳棉與水力纒絡式的合成纖維之非織網。 23·如申請專利範圍第21項或第22項之方法,其特徵在於 彈性複合非織網包含複數種聚合纖維,其至少部份熱熔 合爲合成短纖維。 24.如申請專利範圍第1項之方法,其特徵在於依照C27 15 號說明書施行微縐處理。 25 . —種多層物件,其特徵在於包含一層如申請專利範圍第 1項之該彈性複合非織網與至少一其他層。 26. 如申請專利範圍第25項之多層物件,其特徵在於該其 他層係選自於單片薄膜、多孔薄膜、網狀編織物、條子 稀西紗、非織網、梭織物、針織物與其組合物。 27. —種服裝內襯,其特徵在於包含如申請專利範圍第1項 之彈性複合非織網。 28. —種腰帶結構物件,其特徵在於包含如申請專利範圍第 1項之彈性複合非織網。 29. —繡花底布物件,其特徵在於包含如申請專利範圍第1 項之彈性複合非織網。 3 0.—種用於帽子裡之防汗襯圈結構,其特徵在於包含如申 請專利範圍第1項之彈性複合非織網。 3 1.—種醫療繃帶,其特徵在於包含如申請專利範圍第1項 之彈性複合非織網。 -33- 200837241 3 2 . —種醫療包裹物,其特徵在於包含如申請專利範圍第1 1 項之彈性複合非織網。 ’ 33.—種運動包裹物,其特徵在於其包含如申請專利範圍第 1項之彈性複合非織網。 34.—種動態包紮材料,其特徵在於包含如申請專利範圍第 1項之彈性複合非織網。 3 5. —種多層物件,其特徵在於包含一層如申請專利範圍第 1項之彈性複合非織網與一黏著層。 • 36.—種線帶物件,其特徵在於包含如申請專利範圍第35 項之多層黏著產物。This invention relates to a micro-creped composite nonwoven having improved dimensional and thermal recovery (low distortion) allowing it to continuously adjust under dynamic end use conditions. This product incorporates the following properties: ease of tension, absorbency, breathability, launderability, stitch holding , the strength uses web uniformity. The end uses envisioned for this type of product include waistband and other interliners for the apparel market, sports and medical tapes, wraps and bandages, and functional packaging materials. 200837241 X. Patent application scope: 1. One form The method of elastic composite non-woven net has the characteristics of low energy recoverable mechanical direction elasticity and excellent equivalence, and the characteristic step τ: providing a bonded non-woven bottom net material composed of a plurality of synthetic fibers; a fiber and a cellulosic material; arbitrarily dispersing the synthetic fiber and the cellulosic material in a fluid to form a furnish; depositing the component in a small hole; through the small hole Removing a fluid from the deposition batch to form a wet non-woven web; hydroentangling the wet non-woven web to form a non-woven composite web on the non-woven web; (microcrepping) The non-woven composite web has a densification range of from about 10% to about 50% to form a dense nonwoven web; and the dense non-woven web is heated to form an elastic nonwoven web during micro-twisting. 2. The method of claim 1, wherein: the fluid component of the synthetic fiber and the cellulosic material is directly deposited on the non-woven bottom net; and the deposited ingredient is removed via the non-woven bottom net. Fluid forming a wet non-woven mesh top surface (toppahse); hydrolyzing the top surface of the wet non-woven fabric to form a non-woven composite net on the non-woven bottom net; micro-twisting the non-woven composite net The densification range is from about 丨〇% -30 to 200837241 to about 50% to form a dense non-woven web; and 'the dense non-woven web is heated during micro-twisting to form the elastic non-woven web. 3. The method of claim 1 or 2, wherein the nonwoven web is a non-woven web of continuous spunbonded filaments. 4. The method of claim 1 or 2, wherein the nonwoven web is a non-woven web of meltblown filaments. 5. The method of claim 1 or 2, wherein the nonwoven web is a non-woven net of carded and needlepunched synthetic fibers. 6. The method of claim 1 or 2, wherein the non-woven bottom net is a non-woven net of carded and hydroentangled synthetic fibers. 7. The method of claim 1 or 2, wherein the wet nonwoven web comprises a synthetic fiber slurry. 8. The method of any one of claims 1 to 7, wherein the wet non-woven mesh comprises a selected from the group consisting of softwood pulp, hardwood pulp, cotton fiber φ, cotton linters, natural fibers, Cellulosic material of natural fiber pulp and its compositions. The method according to any one of claims 1 to 7, characterized in that the wet non-woven net comprises a selected from the group consisting of Qiong Ma, Manila hemp, flax, kenaf, jute, and Hena Kun. Cellulose material. The method of any one of claims 1 to 9 wherein the synthetic fiber is a polymeric fiber. The method according to any one of claims 1 to 10, characterized in that the synthetic fiber is selected from the group consisting of acetonitrile, nylon, polyene-3, 200837241 hydrocarbon, polyester, hydrazine.萦 and its composition. The method of any one of claims 1 to 11, which is characterized by the step of adding a resin binder to the hydroentangled composite nonwoven web. The method of claim 5, wherein the elastic composite nonwoven web comprises a plurality of synthetic binder fibers which are at least partially thermally fused into synthetic staple fibers. The method of any one of claims 1 to 13 wherein the Φ is characterized in that the elastic composite nonwoven web has a basis weight of from about 40 to about 290 g/m2, preferably about 40 g. /m2 to 185g/m2. The method of any one of claims 1 to 14, characterized in that the dense composite nonwoven web has a density of at least 15%. The method of any one of claims 1 to 5, wherein the dense composite nonwoven web has a density of no more than 45%. The method of any one of claims 1 to 16, wherein the composite nonwoven web is heated to a temperature ranging from about 1 2 1 ° C to about 2 1 during the micro-twisting treatment. 8 °C. The method of any one of claims 1 to 17, characterized in that the composite nonwoven web is heated to a temperature ranging from about 149 ° C to about 204 ° C during the micro-twisting treatment. 1 9 The method of any one of claims 1 to 18 is for improving the resistance of the nonwoven web due to shrinkage caused by the washing and drying cycle. 20. The method of claim 19, wherein the wet non-woven net further comprises a combination selected from the group consisting of softwood pulp, hardwood pulp, cotton fiber, cotton linters, -32-200837241 natural fibers, natural fiber pulp, and combinations thereof. Cellulose material. 21. The method of claim 19 or 20, wherein the nonwoven web is a non-woven web of carded and needle rolled synthetic fibers. 22. The method of claim 19, wherein the non-woven bottom net is a non-woven net of carded and hydroentangled synthetic fibers. 23. The method of claim 21, wherein the elastic composite nonwoven web comprises a plurality of polymeric fibers that are at least partially thermally fused to synthetic staple fibers. 24. The method of claim 1, wherein the method of micro-twisting is performed in accordance with the specification of C2715. 25. A multilayer article comprising a layer of the elastic composite nonwoven web of claim 1 and at least one other layer. 26. The multi-layer article of claim 25, wherein the other layer is selected from the group consisting of a monolithic film, a porous film, a mesh woven fabric, a sliver woven yarn, a non-woven mesh, a woven fabric, a knitted fabric and combination. 27. A garment lining comprising an elastic composite nonwoven web of claim 1 of the patent application. 28. A waist belt structure article, characterized by comprising an elastic composite nonwoven web according to item 1 of the patent application. 29. An embroidered base fabric article, characterized by comprising an elastic composite nonwoven web according to item 1 of the patent application. 3 0. An anti-sweat liner structure for use in a hat, characterized by comprising an elastic composite nonwoven web as claimed in claim 1. 3 1. A medical bandage comprising an elastic composite nonwoven web as in claim 1 of the patent application. -33- 200837241 3 2. A medical wrapper comprising an elastic composite nonwoven web as claimed in claim 11. </ RTI> A sports wrap, characterized in that it comprises an elastic composite non-woven net as in claim 1 of the patent application. 34. A dynamic dressing material comprising an elastic composite nonwoven web according to item 1 of the patent application. 3 5. A multilayer article comprising a layer of an elastic composite nonwoven web according to item 1 of the patent application and an adhesive layer. • 36. A tape item comprising a multilayer adhesive product as claimed in claim 35. -34- 200837241 七、指定代表圖·· (一)本案指定代表圖為:無。 ^ (二)本代表圖之元件符號簡單說明: ΛI I Γ. 11111 J\\\ 八、本案若有化學式時,請揭示最能顯示發明特徵的化學式:-34- 200837241 VII. Designation of Representative Representatives (1) The representative representative of the case is: None. ^ (2) A brief description of the symbol of the representative figure: ΛI I Γ. 11111 J\\\ VIII. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention:
TW096133827A 2006-09-11 2007-09-11 Composite nonwoven with improved dimensional recovery TW200837241A (en)

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