TW200832839A - High heat electrical connectors - Google Patents

Abstract

The present invention relates generally to the field of electrical connectors comprising either: (a) an immiscible blend of polymers having more than one glass transition temperature and one of the polymers has a glass transition temperature greater than 217 DEG Celsius; (b) a miscible blend of polymers having a single glass transition temperature greater than 180 DEG Celsius; or, (c) a single virgin polymer having a glass transition temperature of greater than 247 DEG Celsius,

Description

200832839 IX. Description of the Invention: [Technical Field] The present invention generally relates to the field of electrical connectors comprising at least a plug and at least one jack and optionally one or more shells The layer component, the or the shell component comprising one of: a) an immiscible blend of the polymer 'the polymer having one or more glass transition temperatures and one of the polymers Having a glass transition temperature greater than 217 degrees Celsius; b) a miscible compound of a polymer having a single-glass transition temperature greater than *10 degrees Celsius; or e) a mono-polymer, It has a glass transition temperature greater than 247 degrees Celsius. [Prior Art] In the industry, electricity, data and data can be supplied between two structures that are easily and quickly separated from each other when a predetermined event or time is reached (for example, after the release of the satellite or the multi-stage separation of the launch vehicle). / or power connections are often necessary. This connection typically takes the form of a two-part connection assembly called an electrical connector. &amp; contains - a unit with - or multiple plugs and a unit with a similar number of plugs; By way of example, a satellite may need to transmit a 41-pin connection between multiple stages of the carrier (or in a "stacked" configuration to an adjacent satellite) until the moment of release. The connector must be easy to fit, in place, for example, under severe travel conditions, and then easily released when the connection is no longer necessary. There are a large number of electrical connectors of different designs and sizes to serve a wide range of environments from home computer applications to aerospace applications. In these end applications, electrical connectors are subject to demanding performance requirements, such as excessive force, high 118322.doc -6-200832839 thermal % and long-term vibration, which requires electrical connectors made of high performance polymers . For example, in some aerospace applications, electrical connectors may experience up to 100 times the weight of gravity when, for example, a mouth gas fighter, missile or simulator containing an electrical connector performs a sharp turn at high speed. Electrical connectors must work well under these harsh conditions with their design and materials. Similarly, when an aircraft or rocket is in flight, there is a significant risk of fire due to an accident or a military aircraft enemy. Fire can be rapid (and crying and uncontrollable. The increased use of polymers for weight reduction in aerospace applications can exacerbate this problem because many polymers lose their B-characteristics at high temperatures. There is a continuing need in the art for an electrical connector made of a polymer to reduce weight and maintain its characteristics under high heat conditions. Another problem in the art is that the electrical connector tends to be initially fitted. (eg 'when the satellite is mounted to the launch vehicle') misalignment. Because the two (four) connector units are usually rigidly attached to their respective parts (one attached to the launching carrier and attached to the satellite), it is difficult to compare The small device (the satellite in this example) is positioned to accurately engage the pin with the socket. There is therefore a continuing need for a connector capable of limited movement to match the orientation of the other connector 2. - The solution that has been used is An adjustable screw with an elastomeric load that movably mounts the connector to the structure. This has been found to cause many problems. - The user must laboriously install the device And appropriate screws (if too tight, the magazine is so compressed that it does not exist, gap,,). Second /,, it occupies valuable space in applications where space is limited (the outer area required for the elastic The number of adjustable connectors grows geometrically and grows third. For the avoidance of electromagnetic interference, the rear axle is often necessary. Unfortunately, in order to allow the user to approach the spring to adjust the spring-loaded screw, after use The axis is impractical. Another problem with the prior art is that if the plug is rotated slightly relative to the jack, the device will not fit properly or the end of the plug may bend, causing equipment failure. A continuing need for electrical connectors that are resistant to heat, flame retardant, hardly release heat when burned, have high dimensional stability, are easily released when needed, and will remain connected under severe sleeve conditions. The background of the connector, the following describes an example of an electrical connector useful in applications where the connector is useful. · The beauty of peterson was awarded on November 9, 2004. No. 6,814,632 discloses an electrical connector system having an electrical contact structure, the electrical contact structure comprising: a conductive contact having a metal contact body having a hollow tubular portion, and a metal contactor, The contact body extends. A hollow non-gold I, the sleeve is connected to and extends from the hollow tubular portion of the contact body. The non-metallic sleeve and the hollow tubular portion are coaxial in a region where the hollow tubular portion and the non-metallic sleeve are connected to each other. A wire is inserted through the interior of the non-metallic sleeve and into the hollow tubular portion of the contact body and is crimped to the hollow tubular portion. The electrical contact structure is received in the electrical connector body. October 28, 1986 A guide and holding device is described in US Pat. And at least one pair of wafer holding members positioned at the 118322.doc 200832839. The inner member is releasably coupled to the first opposing wall and the other material is releasable Connected to the second wall, each component having a plurality of guiding portions and holding portions capable of guiding conductor wafers that can be inserted into each other in a stacked relationship into the housing and the holding portions being individually releasably The conductor wafer is secured within the housing; wherein each of the retention portions comprises: a spring-like clamp that projects inwardly. </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> </ RTI> <RTIgt; . The front end of the retaining member is folded back onto itself and fits into one of the openings in the connector housing to extend the retaining pin outwardly from the lateral portion to engage the inner surface of the connector housing. Acting to hold the retaining member in place within the connector housing. Additionally, the second pair of retaining pins extend inwardly into the connector housing passage to retain the terminal housing in place within the connector housing. The metal shell (connector housing) surrounding the terminal housing has a one-piece construction and is used in combination with a retaining member also formed of metal and is described as being stamped from a material having a desired spring characteristic, such as stainless steel. Forming. U.S. Patent No. 4 to David Gmter, issued May 22, 1989, discloses a one-piece structural protective shell of an electrical connector comprising a clamping member adhered to the interior of the protective sheath, the spring arms of the clamp being outwardly and Extending inwardly to lock the transverse ribs to the rear along the outwardly facing surface of the terminal module inserted into the shell. Each of the clamps includes an outwardly directed louver along one of the lateral edges of the body portion, and the projections are inserted outwardly through the associated longitudinal direction in the shell wall 118322.doc 200832839. To the slit and then along The outer surface of the shell is curved, preferably into the recess to be flush with the surface of the outer layer. The clamps cooperate along one of the upper inner surface and along one of the lower inner surfaces to maintain one of the plug-in pairs of the terminal modules. U.S. Patent No. 5,125,854, the pen connector assembly of Bassler et al., which is incorporated herein by reference, which incorporates a mask and a frame member, wherein at least the file is electrically conductive. A plurality of modular subassemblies are installed in the assembly. A locking mechanism is used to removably fasten each modular subassembly. Material and frame parts. The latching mechanism includes a projection extending from the mask and the frame member, wherein the projection has a slot that fits over the projection on the modular subassembly. U.S. Patent No. 5, i45, 4ii, issued to Pastal, et al., which is incorporated herein by reference to the entire entire entire entire entire entire entire entire entire disclosure The lug is integrally formed with the insert member. The lugs are spaced around the periphery of the outer surface of the insert member, and during insertion of the shell member, the lugs and the phase defined along the inner surface of the metal shell are quarantined. Many of the electrical connectors described above are used in aerospace applications, and in particular for signal and electrical transmissions due to the critical degree of reliable performance, the connectors must be extremely rigid. The outer (shell) of the splicer can be electrically conductive and provide electromagnetic shielding. The connector as a whole is tested for mechanical durability, chemical resistance and salt spray. For example, the aerospace connector is tested for vibration resistance according to the military standard MIL·STD_i 344, which requires no damage or electrical discontinuity after the vibration test. In addition to the requirements for the outer casing, the connector must provide means for securing the terminal module H8322.doc -10· 200832839 to the casing. The member used to fasten the module shall not interfere with the insertion of the module into the shell. The fastening member shall not be exposed to the external environment in a manner that may cause the fastening member to fail, and the module shall be provided in the shell. Carefully align. The latter feature ensures proper electrical engagement within the connector. Not only must the connector meet the technical requirements specified above, but as always, the cost of manufacturing the connector is an important consideration. SUMMARY OF THE INVENTION The present invention is directed to an electrical connector that includes an electrical module having at least one plug and or seven jacks, and (as appropriate) a selected one of the following: One or more shell layers of a blend of polymers or polymers. a) immiscible blends of polymers having more than one glass transition temperature and one of the polymers having one a glass transition temperature greater than 217 degrees Celsius; b) a miscible polymer of a polymer having a single glass transition temperature greater than 18 degrees Celsius; or a single primary polymer having - Glass transition temperature greater than 247 degrees Celsius. 〇 * The invention is also directed to an electrical connector as described above, wherein the polyether oximine has a hydrogen atom (8) to carbon atom (c) ratio between 0.4 and 0.85. The invention is also directed to the aforementioned electrical connector wherein the polylysine is substantially free of benzylated protons. 'Performance mode' Definition "Electrical connector" is a plug-in and jack connector device that includes a contact module and a shell module that can be integrated into one piece, and is used to provide two or more objects. Separable multi-channel data/electrical connections. 118322.doc 200832839 &quot;plugs&apos; means a male protuberance that completes electrical, signal, data or power connections when inserted into a jack. The Π jack ’’, as used herein, means a female recess into which a plug fits. The 'contact' or ''terminal module,&quot; refers to actual electrical connectors that permit transmission of electrical, signal, data or power connections when in contact with each other. The term "shell component" refers to an article that partially or completely surrounds a terminal module. For the purposes of the present invention, the term "metallized surface" means a surface covered by a coating comprising one or more metals. The composition &quot; refers to the molecular composition of the material whereby materials having different molecular compositions or structures For different compositions. Back Tg deducts a polymer having a glass transition temperature of 180. or more. The definition of a benzylic proton is well known in the art and, according to the present invention, comprises Directly chemically bonded to at least one aliphatic carbon atom such as a phenyl ring or a ruthenium to an aromatic ring, wherein the aliphatic carbon atom additionally has at least one proton directly bonded thereto. ▲In the present invention In general, substantially or essentially no benzyl group proton means that the polymer such as the polyindenine sulfone product has less than about 5 mole percent of the derivatized structural unit, and in some embodiments less than about 3 mole percent of the derivatized structure. Units and in other embodiments less than about 丨 mol % derived structural units, the structural units containing benzylated protons. No phenylhydrazine protons, also known as benzyl hydrogen, means that the polyether oxime article has Zero molar % of self-early derived structural units and endblocks containing a stupid methyl proton or benzyl group. The amount of benzyl group protons can be determined by conventional chemical analysis based on chemical structure. H8322.doc - 12-200832839 The term, the ratio of the number of hydrogen atoms to carbon atoms &quot; is the ratio of the number of hydrogen atoms in the polymer or the early w monomer of the polymer to the number of carbon atoms. This month also has 〇·45_〇85 or (9) or 0. = 0.75 or a shaped article of the number of hydrogen atoms to the number of carbon atoms. Ο Ο The present invention is also directed to the inclusion of essentially no benzyl group protons. A shaped article of a polyether. Another aspect of the invention is an article made of a polyether quinone or a conjugate of a = amine: amine having a smelting treatment: ^ enabling melting and partial forming There is a change in the relative amount during the period. This requires that the polymer has no or substantially no bond that will change its molecular weight during melting. (4) The benzyl group proton in the quinone imine changes the molecular weight in the usual accelerated melting, and the mh Reaction due to the formation of polymer The addition of the melt stability, the nature of one amine, 芸 #, 'do not bear the free of the methyl proton of the self-aromatic one: the temple-derived structural unit and the capping agent of poly-imine in use:: It may be preferred to use (4) after polymerization. = = The term "coating" means applied to a substrate or a thin layer called a substrate. In the present invention, the substrate is made up of - or a plurality of polymerization workers. Or a blend of polymers. The coating may comprise any material that is skilled in the coating on the substrate, including but not limited to alloy 2: multiple species: or multiple adhesives, one or more paints , - or a plurality of: a liquid suspension - a liquid suspension, - or a plurality of polymers (a small amount in the coating - having a composition different from that of the polymeric substrate). For the purposes of the present invention 'as long as the desired purpose for the finished product is mandatory. 118322.doc • 13. 200832839 The coating may be present on as many layers as possible on the substrate. The term ''thin'' as used above means that the coating on the article has a thickness at the thickest point of the coating that is less than the maximum straight line that passes through the center of gravity of the article and extends to (but does not pass) the outermost boundary of the article. length. The coating can be applied by any coating method known to the skilled artisan. For example, the coating may be applied by electrolysis, vapor deposition, vacuum evaporation, sputtering or mechanical means such as brush spray, calendering and roll coating. The present invention is directed to an electrical connector comprising at least one plug and at least one receptacle forming an electrical module, and (as appropriate) a polymer or polymer selected from the group consisting of: Shell component of the blend: the bismuth polymer comprises at least one immiscible blend of polyetherimine having more than one glass transition temperature and wherein the polyether quinone has greater than 2 degrees Celsius a glass transition temperature of 17 degrees; the polymer comprises at least one miscible blend of polysinoin having a single glass transition temperature greater than 18 degrees Celsius; or c) a single polyether A quinone imine having a glass transition temperature greater than 247 degrees Celsius. The present invention is also directed to a shaped article comprising poly-imine having a number of hydrogen atoms of from 〇·45 to 0.85 or 0.50 to 80·80 or 〇·55 to 0.75 or G.6G to G.7G. The present invention is also directed to shaped articles comprising substantially no benzylidene f- or a plurality of polyacrylamides. Another aspect of the present invention is an article made of a polyether quinone imine or a blend containing a polyether quinone which has a melt treatment and is capable of melting and partially forming a process. There is a relatively small change in molecular weight during this period. This requires that the polymer be free or substantially free of bonds that will change in molecular weight in the reaction 118322.doc -14-200832839. The presence of a phenylhydrazine proton in a polyether oximine is a reaction that generally changes the molecular weight during accelerated melting. Due to the increased melt stability of the resulting polymer, the polyether quinone imines derived from aromatic diamines, aromatic dianhydride-derived structural units and capping agents having essentially no benzoquinone protons are useful in some applications ( In particular, it relates to applications in which the separation from the smelting and smelting treatments after polymerization is preferred. Representative examples of substrate materials for use in shell components are listed below: A. Harder-based polymers or blends; polyoxynoxy copolymers; and isophthalic acid-derived polyaryl esters. High Tg polymer blend. Disclosed herein is an electrical connector comprising a polymer blend, wherein some or all of one of the surfaces of the polymer blend is coated by a cover, wherein the cover material has a different composition than the polymer blend, And wherein the polymer blend comprises: a) selected from the group consisting of polysulfone (psu), poly(phenyl sulfone) (PES) poly(phenylene ether sulfone) (PPSU) a first resin having a higher glass transition temperature (Tg to 180. 〇, b) a polyoxyalkylene copolymer such as polyoxymethylene or polyoxyethylene polycarbonate; and optionally, c) A resorcinol-based polyarylate compound in which the blend has a very low heat release value. 1. Blend polysulfone, polyether sulfone and polyphenylene ether oxime component Polysulfone, poly(ether sulfone) and poly(phenylene ether sulfone) useful in the articles described herein are, for example, US patents Thermoplastic resins as described in Nos. 3,634,355, 4,008,203, 4,108,837 and 4,175,175. Polylithic wind, poly(sulfuron) and poly(phenylene ether) are linear thermal thermoplastic polymers with many properties such as high temperature resistance, good electrical properties and good hydrolysis stability 118322.doc -15- 200832839 Attractive features. Polyfluorene comprises a repeating unit having the structure of formula I: ί 9 1 - RS-- Γ 〇 J (I) wherein R is an aryl group containing a carbon-carbon single bond, a carbon-oxygen bond or a carbon-carbon and a carbon-oxygen carbon The single bond and the single bonds form part of the polymer backbone. The poly(ether sulfone) comprises a repeating unit having both an ether bond and a hydrazone bond in the main chain of the polymer as shown in the formula:

ί ί 9 1 --Ar-S-Ar·—〇-- L 〇 J (II) wherein Ar and Ar' are aryl groups which may be the same or different. Ar and Ar may be the same or different. ¥ When Ar and Ar1 are both extended phenyl groups, the polymer is called poly(phenylene ether). When both Ar and Ar' are an aryl group, the polymer is referred to as a poly(exoaryl ether). The number of stone wind keys and the number of scale keys may be the same or different. An exemplary structure demonstrating when the number of sulfone bonds differs from the number of ether bonds is shown in formula (ΠΙ): 0 , -Ar-S-Ar1—O-Ar·, a 0-

II (III) 〇 - wherein Ar, Ar' and Ar, are the same or different aryl groups. Ar, Ar, and Arn may be the same or different. For example, Ar&amp;Ar may be a phenyl group and may be a bis(1,4-phenylene) isopropyl group. A variety of polysulfones and poly(ether sulfones) are commercially available, including polycondensation products of dihydroxydiphenyl sulfone and dichlorodiphenyl hydrazine, and polycondensation products of bisphenol A and/or biphenol and dichlorodiphenyl sulfone. Examples of commercially available resins include RADEL R, RADEL A, and UDEL, available from s〇 Way Co., Ltd., and 118322.doc -16-200832839 ULTRASON E, available from BASF Corporation. Methods for preparing polysulfones and poly(ether sulfones) are widely known and several suitable processes have been fully described in the art. Both methods, the carbonate process and the alkali metal hydroxide process are known to the skilled artisan. In the method of detecting a metal hydroxide, the double metal salt of the di(tetra) and the dibenzoyl compound are contacted under substantially anhydrous conditions in the presence of a dipolar, aprotic solvent. A carbonate process is also disclosed in the art, for example, in U.S. Patent No. 4,176,222, in which a phenolic and bidentate benzene type compound (for example) is combined with sodium carbonate or barium sulphate and a second alkali metal carbonate or heavy The carbonate is heated. Alternatively, polyhard and poly (Single 1) can be prepared by any of a variety of methods known in the art. The molecular weight of the polysulfone or poly(ether sulfone) (as indicated by the comparative viscosity data in a suitable solvent such as di-methane, tri-methane, N-methylpyrrolidone or the like) may be greater than or equal to About 3 dl/g, or more specifically, greater than or equal to about 0_4 dl/g and typically will not exceed about 15 dl/g. In some cases, the polysulfone or poly(ether oxime) weight average molecular weight may be from about 〇, 〇〇〇 to about 100,000 as determined by gel permeation chromatography using ASTM method D5296. In some cases, the polysulfone and poly(ether sulfone) can have a glass transition temperature of from about 180 °C to about 250 °C. When polysulfone, poly(ether sulfone) and poly(phenylene ether sulfone) are blended with the resins described herein, the polysulfone, poly(ether oxime) and poly(phenylene ether sulfone) will have greater than or It is equal to about 18 baht. The glass transition temperature (Tg) of bismuth. The barrier resin is further described in the ASTM method d6394 standard specification for sulfone plastics. In some cases, polysulfone, poly(ether oxime), and poly(phenylene ether sulfone) and their doping 118322.doc -17 200832839 will have an atomic ratio of hydrogen to carbon of less than or equal to about U5 (H) /c). Without being bound by theory, polymers having a higher carbon content (i.e., a lower ratio of hydrogen to carbon atoms) relative to the hydrogen content often exhibit improved enthalpy performance. These polymers have lower combustion values and can release less energy upon combustion. It can also be flammable and independent of any specific mechanism or mode of action that forms an insulating coking layer between the polymeric fuel and the source of ignition. It has been observed that these polymers have excellent flame resistance with a lower H/c ratio. . In some cases, the H/C ratio may be less than or equal to 0.75 or less than 〇·65. In other cases, a H/C ratio of greater than or equal to about 0.4 is preferred to give a polymeric structure having a "tough bond" to achieve melt processability. The H/c ratio of a given polymer or copolymer can be determined by its chemical structure (by counting the carbon and hydrogen atoms independently of any other atoms present in the chemical repeat unit). In polymer blends X, polysulfone, poly(ether sulfone) and poly(phenylene ether sulfone) and blends thereof may be present in a percentage of from about 丨 to about 99% by weight based on the total weight of the polymer blend. The quantity exists. Within this range, the amount of polysulfone, poly(ether sulfone), and poly(phenylene sulfone), and mixtures thereof, can be greater than or equal to about 2 weight percent 'more specifically, greater than or equal to about 50 weight percent, and More specific than Lu is greater than or equal to about 70 weight percent. The skilled artisan will know that the polylithic wind, I (scale) and poly(phenylene ether) and mixtures thereof may be from about 1 to about 99 weight percent of the total polymer blend (and in particular from 1 to 7 〇) The weight percentage of any real number between the weight percentages exists. 2. Polyoxymethane component of the blend The polyoxynoxy copolymer comprises any of the decane copolymers which are effective for improving the heat release performance of the composition. In some cases, it is possible to use polyetherimine, poly 118322.doc •18-200832839 ether oxime imide mill, polysulfone, poly(phenylene ether sulfone), poly(ether oxime) or poly(phenylene) An alkane copolymer of ether). In some cases, the decyl alkoxy polyether oxime imine or the diarrhea polycarbonate copolymer may be effective in reducing heat release and improving flow rate. Mixtures of different types of Zeolites are also covered. In one embodiment, the oxoxane copolymer comprises from about 5 to about 70% by weight of the decane content relative to the total weight of the copolymer and in other cases from 20 to about 5% by weight of the sulphur oxide content. The block length of the oxirane fragment of the ruthenium copolymer can have any effective length. In some examples, the block length can range from about 2 to about 70 decane repeats. In other instances, the oxetane block length can range from about 5 to about 5 repeat repeats 70. In many cases, dimethyloxane can be used. The decane polyether oxime copolymer is a specific conjugate of a ruthenium lactone copolymer which can be used in a polymer blend. Examples of such agglomerated oxygen-polyimine copolymers are shown in U.S. Patent Nos. 4,4,4,35, the entire disclosure of which is incorporated herein by reference. In one case, the oxyazepine polyamine copolymer can be prepared similarly to the polyether oxime oxime oxime, except for the σ 卩 of the organic monoamine reactant or all by, for example, the formula Iv In addition to the amine-terminated organic oxime, wherein g is a positive number from 1 to about 50, or more specifically about 5 to 々30, and R is a aryl having 2 to about another carbon atom Base, alkyl or arylalkyl. &amp; H2N- R1—Si-^〇Si-)〇Si—Ρ·~ΝΗ2

Formula IV can be prepared by any of the methods well known to those skilled in the art. 118322.doc -19- 200832839 Anthraquinone polyether oxime copolymer, including aromatic bis(ether anhydride) of formula V Reaction with an organic diamine of formula VII

Wherein T is a group of -〇-, -S-, -S〇2_ or formula-, wherein the divalent bond of the _〇_ or -0-Z-0- group is at 3,3', 3,4 ', 4, 3, or 4, 4 positions, and wherein Z includes, but is not limited to, a substituted or unsubstituted divalent organic group, such as: (a) an aromatic having from about 6 to about 20 carbon atoms a hydrocarbyl group and a halogenated derivative thereof; (b) a linear or branched chain alkyl group having from about 2 to about 20 broken atoms; (c) a cycloalkyl group having from about 3 to about 20 carbon atoms or (d) ) The divalent group of the formula:

(VI) wherein Q includes, but is not limited to, a divalent group selected from the group consisting of: -0-, -S-, -c(0)-, -S02-, -SO-, -CyH2y - (y is an integer from 1 to 8) and its fluorinated derivatives, including perfluoroalkylene. H2N-R1-NH2 (VII) wherein the group r1 in the formula VII includes, but is not limited to, a substituted or unsubstituted divalent organic group such as: (a) an aromatic having from about 6 to about 24 carbon atoms a hydrocarbyl group and a halogenated derivative thereof; (b) a linear or branched alkyl group having from about 2 to about 20 carbon atoms; a cycloalkyl group having from about 3 to about 2 carbon atoms or (sentence formula An example of a specific aromatic dianhydride and an organic diamine is disclosed in U.S. Patent Nos. 3,972,9,2 and 4,455,41, the entire disclosure of which is incorporated herein by reference. Said 118322.doc -20- 200832839 Examples of clarity include: 3,3-bis[4-(3,4-dicarboxyphenoxy)phenyl]propane dianhydride; 4,4f-bis (3,4-di Carboxyphenoxy)diphenyl ether dianhydride; 4,4f-bis(3,4-dicarboxyphenoxy)diphenyl sulfide dianhydride; 4,4,bis(3,4-dicarboxyphenoxy) Benzophenone dianhydride; 4,4'-bis(3,"dicarboxyphenoxy)diphenyl sulfone dianhydride; 2,2-bis[4-(2,3-dicarboxyphenoxy)phenyl Propane dianhydride; 4,4f-bis(2,3-diylphenoxy)diphenyl ether dianhydride; 4,4f-bis(2,3-dicarboxyphenoxy)diphenyl sulfide Anhydride; bis(2,3-dicarboxyphenoxy)benzophenone dianhydride; 4,4'-bis(2,3-dicarboxyphenoxy)diphenyl sulfone dianhydride; 4-(2,3 -dicarboxyphenoxy)_4,_(3,4-dicarboxyphenoxy)diphenyl'2-propane dianhydride; 4-(2,3-monocarboxyphenoxy)~4,-(3 , 4-dicarboxyphenoxy)diphenyl ether dianhydride; 4-(2,3-dicarboxyphenoxy)-heart (3,4-dicarboxyphenoxy)diphenyl sulfide dianhydride; 4- (2,3-dicarboxyphenoxy)_4,_(3,'dicarboxyphenoxy)diphenyl dianhydride; and, 4-(2,3-dicarboxyphenoxy)_4,_(3 , 4-dicarboxyphenoxy)diphenyl sulfone dianhydride, and mixtures thereof. In addition to the above-described oxirane diamines, examples of suitable diamines include ethylenediamine, propylamine, and trimethylene. Amine, di-ethyltriamine, tri-extension ethyltetramine, hexamethyleneamine, heptanediamine, octanediamine, decanediamine, decanediamine, hydrazine, 12_12 dans diamine, 1,18-ten Human diamine, 3_mercaptoheptane diamine, 4,4-dimethyl 118322.doc -21 - 200832839 Ο 庚 heptanediamine, 4-methylguanidine diamine, 5-methylindole diamine, 2 ,5· dimethylhexamethylenediamine, dimethylheptanediamine, 2,2- Methyl propylenediamine, Ν_methyl*aminopropyl)amine, 3-methoxyhexamethylenediamine, U.bis(3-aminopropyloxy)ethene, bis(3-aminopropyl) Sulfide, Μ_cyclohexanediamine, bis(4-aminocyclohexyl)methane, m-phenylenediamine, p-phenylenediamine, 2,4-diaminotoluene, diaminotoluene, and Xylene diamine, p-xylene diamine, 2-methyl- 4,6-diethyl #phenyl-diamine, 5-methyl-4,6-diethyl], 3-phenylene _Diamine, benzidine, 3,3'-dimethylbenzidine, 3,3,-dimethoxybenzidine, quinone diaminonaphthalene, bis(4-phenylene) oxime, double 214-amino-3,5-diethylphenyl) oxime, bis(4-aminophenyl)propane, 2,4-bis(amino-t-butyl)toluene, double (p- Amino-t-butylphenyl) bond, bis(p-methyl-o-aminophenyl)benzene (p-methyl-o-aminopentyl)benzene, 13-diaminoisopropylbenzene And bis(4-aminophenyl) sulfide, bis(4-aminophenyl), bis(4-aminophenyl)ether, and a combination comprising two or more of the foregoing. A specific example of the sulphur oxide diamine is 1,3_bis(3-aminopropyl)tetramethyldiazepine. In one embodiment, the diamine-based compound used in the oxydiamine is an aromatic diamine, especially m-phenylenediamine and p-phenylenediamine, sulfonyldiphenylamine, and mixtures thereof. The ether quinone imine copolymer can be formed by the reaction of a mixture of an organic diamine or a diamine of the formula VII with an amine-terminated organodecane which is as defined above. The diamine based component can be physically mixed prior to reaction with the dianhydride, thus forming a substantially random lack of copolymer. Alternatively, a block or alternating copolymer can be formed by selective reaction of hydrazine 11 and IV with a dianhydride (e.g., a dianhydride of formula V) to form a polyamidene block which is subsequently co-reacted. In another aspect, 118,322. doc -22-200832839, the oxime fire used to prepare the polyether oxime copolymer may have an anhydride rather than an amine functional end group. In one aspect, the oxoxane polyether oxime copolymer may have Formula VIII, wherein T, R', and g are as described above, b has a value from about 5 to about 100 and Ar1 has from 6 to about 36. a carbon aryl or alkylaryl group.

Formula VIII Ο In some of the alkoxyalkyl polyether oxime copolymers, the diamine component of the decane polyether oxime copolymer may contain from about 20 to 50 mole % of the amine-terminated organic stone of the formula Oxygen fired and about 50 to 80 mole % of the organic diamine of formula VII. In some of the oxy-oxygenated copolymers, the &apos;oxygenated component is derived from about 25 to about 4 mole percent of the amine or terminal anhydride organooxane. The polyoxymethylene copolymer component of the polymer blend may be present in an amount from about 0.1 to about 40 weight percent, or from about 1 to about 2 weight percent, based on the total weight of the polymer blend. In the above (4), the polyoxo copolymer may also be present in an amount of from 0.1 to about 10%, further from from 0 5 to about 50%. 3. The resorcinol-based polyarylate compound component of the blend is a resorcinol-based polyarylate compound which is a polymer comprising an arylated polyester structural unit. Hope to react with the aromatics. The at least part of the structural unit of the geminal poly(S) comprises i,3 • di-based phenyl, the formula of the formula D), which is commonly referred to throughout the specification as a resorcinol or resorcinol group. . Unless otherwise specified, resorcinol or inter-H8322.doc -23-200832839 benzenediol groups are understood to include unsubstituted 1,3-dihydroxybenzene and substituted two as used herein. Both hydroxybenzene. I〇p^〇i

R2n Formula IX In Formula IX, R2 is independently CM2 alkyl, 丨_c "aryl, c^c:24 alkylaryl, alkoxy or halogen at each occurrence, and 11 is 〇_4 In one embodiment, the resorcinol-based polyarylate compound resin comprises greater than or equal to about 50 mole percent of resorcinol and aryl dicarboxylic acid or is suitable for aryl esters. A unit of the reaction product of an aryl dicarboxylic acid derivative (for example, a carboxylic acid halide, a carboxylic acid ester, and a carboxylate) formed by a bond. Suitable dicarboxylic acids include monocyclic and polycyclic aromatic dicarboxylic acids. The monocyclic dicarboxylic acid includes isophthalic acid, terephthalic acid or isophthalic acid and terephthalic acid. Polycyclic dicarboxylic acid includes diphenyl dicarboxylic acid and diphenyl ether dicarboxylate. Acid and naphthalene dicarboxylic acid (for example, naphthalene-2,6-dicarboxylic acid). Therefore, in a consistent application, the polymer blend contains a thermally stable polymer, (J /, 八有苯苯一盼芳a base polyester unit (as illustrated by the formula) wherein R2 and η are as previously defined:

A hydrate comprising a resorcinol arylated polyester unit can be produced by an interfacial polymerization method. To prepare a polymer comprising a benzenediol arylated polyfluorene unit substantially free of anhydride linkages, a method can be used in which the first step combines the resorcinol group with the catalyst in water and substantially Water immiscible organic 118322.doc -24- 200832839 in a mixture of solvents. Suitable resorcinol compounds have the formula XI: Χί

R2n Formula XI wherein R2 is independently Cm alkyl, c6-c24 aryl, C7_C24 alkylaryl, alkoxy or halogen at each occurrence, and η is 0-4. The alkyl group, if present, is typically a straight chain, a branched chain or a cyclic alkyl group, and although it encompasses other ring positions, it is most often ortho to the two oxygen atoms. Suitable alkyl groups include, but are not limited to, methyl, ethyl, n-propyl, isopropyl, butyl, iso-butyl, tert-butyl, hexyl, cyclohexyl, decyl, decyl and aryl The alkyl group substituted with a benzyl group. In a particular embodiment, the alkyl group is a methyl group. Suitable dentate groups are bromo, chloro and indenyl. In various embodiments, the value can be from 〇 to 3, In one embodiment, it is 0 to 2, and in other embodiments is 〇 to 丨. In one embodiment, the resorcinol group is 2-methyl resorcinol. In another embodiment The resorcinol group is an unsubstituted stilbene group wherein ^ is zero. The method further comprises combining a catalyst with a reaction mixture. In various embodiments D, the catalyst can be based on an acid The total molar amount of chloride groups is present in a total amount of 〇·〇1 to i〇mol%, and in some embodiments is present in total ΐ2 to 6 mol% 。. Suitable catalysts include three a primary amine, a quaternary amine salt, a quaternary phosphonium salt, a hexaalkylguanidinium salt, and mixtures thereof. Suitable dicarboxylic acid aromatic di-forms may comprise an aromatic dicarboxylic acid derived from a monocyclic moiety. Di-vapors, illustrative examples of which include isodecyl dichloride, p-nonyl dichloride or a mixture of isodecyl and p-nonyl dichloride. Suitable dicarboxylic acid aromatic di- 118322.doc -25-200832839 =&amp;-carboxym species' may be included as an illustrative example including diphenyldipic acid di-emulsifier, diphenyl succinic acid dichloride, and naphthalene (d) a dichloride, especially f is naphthalene-2,6.dicarboxylic acid dichloride; or a mixture of monocyclic and polycyclic aromatic dicarboxylic acid dichloride. In one embodiment, dicarboxylic acid dichloride The compound comprises a mixture of isomeric bases and/or p-nonyl dichlorides (as generally described in the formula). Oxime TM and iso-decyl and one or two of the antimony dichloride towels In some μ yoke cases, the dicarboxylic acid dichloride contains an isodecyl group and a p-fluorenyl di vapor with an isodecyl group and a p-fluorenyl group about 25·4 〇: 丨 莫The mixture of ear ratios; in other embodiments the molar ratio is about 4·4_2·5:1; and in other embodiments the molar ratio is about 0.67-15:1. The dentate provides only one method of preparing the polymers mentioned herein. It also encompasses other routes for the production of resorcinol arylate linkages using (eg, 0) dicarboxylic acids, dicarboxylic esters (especially active esters). Or a dicarboxylate or a partial salt. A chain terminator (also sometimes referred to as a capping agent hereinafter) may also be used. The purpose of adding a chain terminator is to limit the inclusion of a resorcinol arylated polyester chain member. The molecular weight of the polymer, thus providing a polymer with controlled molecular weight and good processability. Typically, the chain terminator is added when the resorcinol arylate-containing polymer does not require reactive end groups for further use. In the absence of a chain terminator, the resorcinol arylate-containing polymer can be used in solution or recovered from solution for subsequent use, such as for the possible use of 118322.doc -26- 200832839 benzene The copolymer in the presence of a reactive end group (usually a hydroxyl group) on the diphenol arylated polyester fraction is formed. The chain terminator may be a single compound, a monoterpic acid chloride, a monochloroformate or a combination of two or more of the foregoing. Usually the 'chain terminator can be based on resorcinol (in the case of monophenolic compounds) and based on acid dichloride (in the case of monocarboxylic acid chlorides and/or monochloroformates) from 0.05 to 10 moles The amount of ear % is present. Suitable monophenolic compounds include monocyclic phenols such as phenol, Ci_C22 alkyl substituted phenol, p-cumyl phenol, p-tert-butyl phenol, hydroxy diphenyl; monoethers of diphenols, such as p-methoxy . The alkyl-substituted phenols include phenols having a branched chain alkyl substituent having from 8 to 9 carbon atoms as described in U.S. Patent No. 4,334, the disclosure of which is incorporated herein. In some embodiments, the monophenolic chain terminators are phenol, p-cumylphenol, and resorcinol monobenzoate. Suitable monocarboxylic acid chlorides include monocyclic monocarboxylic acid chlorides such as benzoquinone gasification, C-C22-based substituted benzamidine chloride, toluene chloride, i-substituted benzamidine , bromophenyl hydrazine chloride, cinnabar hydrazine, 4-nadimidobenzoyl chloride and mixtures thereof; polycyclic monocarboxylic acid vapors such as trimellitic anhydride chloride and naphthyl醯 chloride; and a mixture of monocyclic and polycyclic monocarboxylic acid chlorides. Chlorides of aliphatic monocarboxylic acids having up to 22 carbon atoms are also suitable. Functionalized chlorides of aliphatic monocarboxylic acids such as propylene sulfonium chloride and mercapto propylene oxime are also suitable. Suitable monochlorophthalic acid esters include monocyclic monogas phthalates such as phenyl phthalate, alkyl substituted phenyl chloroformate, p-cumyl phenyl phthalate, toluene benzoate And mixtures thereof. The chain terminator may be combined with resorcinol and may be included in the solution of the dicarboxylic acid dichloride 118322.doc -27-200832839' or may be added to the reaction mixture after the precondensate is produced. If a monocarboxylic acid chloride and/or a monochlorophthalic acid ester is used as the chain terminator, it is often introduced together with the dicarboxylic acid dihydrate. The chain terminators may also be added to the reaction mixture at a time when the chloride of the dicarboxylic acid has been substantially reacted or the reaction is completed. If a phenolic compound is used as the chain terminator, it may be added to the reaction mixture during the reaction in one embodiment, or in another embodiment between resorcinol and the acid dihydrate. It was added to the reaction mixture before the start of the reaction. When preparing a precondensate or a condensate containing a terminal hydroxy resorcinol arylate, the chain terminator may be absent or present only in minor amounts to aid in controlling the molecular weight of the polymer. In another embodiment, a branching agent such as a trifunctional or higher functional carboxylic acid chloride and/or a trifunctional or higher functional phenol may be included. Such branching agents, if included, can generally be used in amounts of from 0.005 to 1 mol%, respectively, based on the dicarboxylic acid dichloride or resorcinol used. Suitable branching agents include, for example, trifunctional or higher functional carboxylic acid chlorides, such as symmetrical trimellitic acid triacids, 3,3',4,4'-benzophenone tetracarboxylic acid tetrachloride, 1,4,5,8-naphthalenetetracarboxylic acid tetravaporate or pyromellitic acid tetrahydrate, and trifunctional or higher functional phenol such as 4,6-dimethyl-2,4,6-tri ( 4-hydroxyphenyl)-2-heptene, 4,6-dimethyl-2,4,6-tris(4-hydroxyphenyl)-heptane, H5-tris(4-hydroxyphenylbenzene, three (4-Hydroxyphenylethane, tris(4-hydroxyphenyl)-phenylmethane, 2,2-bis-[4,4-bis-(4-hydroxyphenyl)-cyclohexyl] propane, 2, 4-bis-(4-hydroxyphenylisopropylpro, tetra-(4-hydroxyphenyl)-methane, 2,6-bis-(2-hydroxy-5-methylbenzyl)-4-methyl, 2-(4-Hydroxyphenyl)_2-(2,4-dihydroxyphenyl)-propane, tetra-('[4-hydroxyphenylisopropyl l-phenoxyl.methane, 1,4- Bis-[(4,4-dihydroxytriphenyl)methyl b 118322.doc -28- 200832839 benzene. It is possible to first introduce a branching agent together with a meta-phenylene moiety, while an acid chloride branching agent can be combined with an acid. Dichloride is introduced together. In one of its embodiments, the article comprises as described A thermally stable meta-phenylene phenol arylated polyester of an anhydride linkage of at least two substrates of a substantially unbonded polyester chain. In a particular embodiment, the polyester comprises from meta-phenylene a dicarboxylic acid residue derived from a mixture of hydrazine and terephthalic acid (as illustrated in formula XIII)··

= where R2 is Cm-based, cvc^-based, alkyl-aryl, alkoxy or halogen, and n is 〇_4, and the melon is greater than or equal to about 256 in each embodiment. 'η is zero and m is from about 1 〇 to about 3 〇〇. The molar ratio of benzene sulphate to terephthalate is about 〇 25_4 〇: ι in one embodiment, and about 0·4-2.5: ι ' in another embodiment and in another embodiment In the example, it is about 67·ΐ 5:ι. Substantially free of anhydride linkage means that after about five minutes of heating the polymer at about the temperature of rc, the mixture is shown in the embodiment, less than 3% by weight, and in another embodiment less than 10,000%. In addition, as disclosed in the commonly-owned U.S. Patent No. 5,916,997, the inclusion of an isophthalic (tetra)-based copolymerized vinegar, which contains a soft segment. The soft block is used in Some sheets k of the polymer are indicated herein to be composed of non-aromatic monomer units. These non-aromatic monomer units are generally aliphatic and are known to impart flexibility to polymers containing soft blocks. Copolymer 118322.doc -29- 200832839 A copolymer comprising structural units of formula IX, XIV and XV··

〇十

Equation IX 〇 0 ΛΖΛ

Formula XIV (', &gt;^, R3/R〆,

Wherein R and η are as defined by uranium, Z1 is a divalent aryl group, r3 is a c3-2〇 linear chain extension group, a Cm branch chain extension group or a Chq ring or a bicyclic extension group, and R4 And R5 each independently represent 〇 or a ch2-〇1, wherein Formula XV contributes from about 1 to about 45 mole percent to the polyester. Additional Q embodiments provide compositions wherein Formula XV contributes from about 5 to about 40 mole percent to the ester linkage of the polyester in various embodiments, and in other embodiments from about 5 to about 10 percent to the polyester bond of the polyester. 20 mole percentage. Another embodiment provides a composition wherein, in one embodiment, R3 represents a Csa linear alkyl or Cw cycloalkyl, and in another embodiment R3 represents a C3 straight bond or a ring extension. Burning base. Formula XIV represents an aromatic dicarboxylic acid residue. The divalent aryl group of the formula may be derived from a suitable dicarboxylic acid residue as defined above in various shell examples, and in some embodiments comprises a phenyl group, an i, a phenyl group or a phenyl group. A naphthyl group or a combination of two or more of the foregoing. In various examples of the yoke of 118322.doc -30-200832839, ζ1 contains greater than or equal to the phenyl group in the soft block chain member. Zero. In the various embodiments of the formula Δ, in the other embodiments of the formula, the poly- aryl acetonate, which is mainly composed of m-benzophenone, is a combination of a carbonic acid, a &amp; Containing a resorcinol arylate which is combined with an organic carbonate fragrant fragment. In the copolymers

The fragment of the C resorcinol arylate chain member is substantially free of acid needle bonds. The absence of an acid anhydride bond on the shell means that it is about 28 () rhyme. The temperature of c is heated for five minutes after the copolymerization of the carbonic acid carbonate, i.e., less than 10% in the embodiment and less than 5% in the other embodiment. It is known that the segment contains a carbonated vinegar bond derived from the reaction of bisphenol with a carbonate forming substance such as carbon helium to form a polyvinyl acetate copolymer. For example, §, the resorcinol polyarylate compound carbonate copolymer may comprise meta-benzoic acid and terephthalic acid, resorcinol and a reaction product of bisphenol A and carbonium chloride. The resorcinol polyestercarbonate copolymer can be made in a manner such that, for example, by reacting resorcin with a dicarboxylic acid to form an aryl polyester block and then subjecting the block to a double The phenol and carbonate react to form a polycarbonate portion of the copolymer to minimize the number of bisphenol dicarboxylate linkages. For best results, the resorcinol content (REC) in the resorcinol polyester carbonate should be greater than or equal to about 50 mole percent of the polymer bond derived from resorcin. In some cases, depending on the application, greater than or equal to about 75 mole percent of the resorcinol derived bond, or even up to about 90 or 100 mole percent of REC may be desirable. The block copolyestercarbonate comprises a block comprising an alternating arylate block and an organic carbon 118322.doc -31 - 200832839 acid ester block, 妓平佑山^ /, a stone acid ester (as is usually found in the formula χνι Illustrated), installed φ P 2 » Μ达,·

-〇-R6—〇

The square-based moiety has a degree of polymerization (1) represented by melon, which in one embodiment is = or equal to about 4, in another embodiment greater than or equal to about 1 〇, in another embodiment greater than or Equal to about 2G and in still another embodiment from about 30 to about: 5 〇. The teachings of the organic carbonates of the P-sheets are in the embodiment - greater than or equal to about 2' in another embodiment from about 1 to about 20 and in still another embodiment from about 2 to about 200. . The partitioning of the blocks can be such as to provide the desired content of the copolymer having the aryl compound "and the desired weight ratio of the sulphate block." From about 10 to about 95% by weight, and in another embodiment from about 50 to about 95% by weight, based on the total weight of the polymer. -Although in the formula XVI, the isophthalate and the terephthalate are a mixture, but the aryl carboxylic acid residue may be derived from any suitable dicarboxylic acid residue as defined above or a mixture of suitable dicarboxylic acid residues, including aliphatic diacid dichloride. a dicarboxylic acid residue derived from a compound (so-called "soft block" fragment. In various embodiments, n is zero and the arylate block comprises a dicarboxylic acid residue derived from a mixture of an isophthalic acid residue and a #phthalic acid residue, wherein the isophthalic acid g is related to the para-benzene The diacid s is intended to be about 0. 25-4. 0:1 in the embodiment, about 0.4 to 2.5:1 in another embodiment, and 118322.doc -32 in another embodiment. In the case of 200832839, it is about 0.67-1.5:1. In the organic carbonate block, each R6 她 ancient she I is independently two when the mother-person appears: there is hearing. In various implementations, the base contains two (four) substituted aromatic hydrocarbon n compounds. "The total number of purposes is greater than or the knives are ruthenium, alicyclic or aryl. Suitable r6 groups include m-phenyl, ·Extension of phenyl, W-linked diphenyl, 4,4,_di-diethylene = phenyl, 2,2-bis (;4_Extension of phenylene fluorene f) ϋ 累 一[1Η-茚满] And a similar group, hydroxy-substituted aromatic hydrocarbons (named no or formula (general or specific) are disclosed in the US Patent No. mm. In some embodiments, each R6 is an aromatic organic group and in other embodiments The base of the formula χνπ: Α1—Υ—a2--

Wherein, the parent-Α1 and Α2 are monocyclic divalent aryl groups and γ is a bridging group in which one or two carbon atoms separate Α1 and Α2. The free valence bond in formula XVI1 is usually in the position of V and Α2 relative to Υ or in the para position W. The compound having the formula χνπ therein is bisphenol 'and for the sake of brevity' is sometimes used herein in the term &quot;bisphenol&quot; To represent a dibasic substituted aromatic hydrocarbon. However, it should be understood that this type of non-bisphenol compound can also be suitably used. In the formula XVII, '8 and 8' generally denote unsubstituted phenyl or its substituted organism, and the illustrative substituent(s) are alkyl, alkenyl and halogen (especially indifferent). . In the examples, the unsubstituted phenyl group is preferably a spoon and the # two are p-phenyl, but both may be o- or m--extension 118322.doc -33 - 200832839 phenyl Or one is o- or m-phenyl and the other is p-phenyl. The bridge base is _, where one or two atoms separate Α1 from Α2. In a particular embodiment, one atom separates Α from Α2. Illustrative groups of this type are _〇_, , -s〇_ or -S02-, methylene, cyclohexylmethylene, 2_[2.21]_bicycloheptylmethylene, ethylidene, isoform A propyl group, a neopentyl group, a cyclohexylene group, a cyclopentylene group, a cyclocyclododecyl group, an adamantyl group, and the like. Ο ϋ In some embodiments, an oxime-alkyl group (commonly referred to as "alkylene") is preferred. However, unsaturated groups are also included. In some embodiments, the bisphenol is 2,2-bis(4-hydroxyphenyl)propane (bisphenol A*BPA), wherein gamma is isopropylidene and a1 and A are each a pair of phenyl groups. Depending on the molar excess of the hydroquinone present in the reaction mixture, R6 in the carbonate block may at least partially comprise a resorcinol group. In other words, in some embodiments, a carbonate block of the formula may comprise a resorcinol group in combination with at least one other dihydroxy substituted aromatic hydrocarbon. Includes one-stage, diblock, and multi-block copolyestercarbonates. The chemical bond between the block comprising the resorcinol arylate chain member and the block comprising the organic carbonate chain member may comprise at least one of the following: an appropriate bis-acid residue of the aryl group and the organic The ester bond between the - 6-r6-〇-yl group of the carbonate group (for example as described generally in the formula ννπ), wherein R6 is as defined previously: 〇

a carbonate bond between the diphenic acid residue of the formula VIII and (b) the meta-phenyl aryl group aryl group and the organic carbonate group 118322.doc -34-200832839 4〇0) - 0- group (eg, χιχ) (shown in )), where scales 2 and n are as previously defined: 〇

Formula XIX In one embodiment, the &quot;copolyestercarbonate substantially comprises a bis-segmented copolymer' having a carbonate linkage between the resorcinol arylate block and the organobutate block. In another embodiment, the copolyestercarbonate substantially comprises a triblock carbonate-ester-carbonate copolymer having a carbonic acid between the resorcinol arylate block and the organic carbonate endblock Ester bond. The copolyestercarbonate having a sulphuric acid ester linkage between the thermally stable resorcinol arylate block and the organic carbonate block is typically comprised of a resorcinol arylate and in an embodiment at least A further preparation of a polymer containing at least two hydroxyl end sites in another embodiment. The oligomers typically have a weight average molecular weight of from about 10,0 (5) to about 4 Å, in one embodiment, and from about 15,000 to about 30,000 in another embodiment. The heat can be prepared by reacting the oligomers containing the resorcinol arylate with carbonium chloride, a chain terminator and a dihydroxy-substituted aromatic hydrocarbon in the presence of a catalyst such as a tertiary amine. It is the s 疋 疋 疋 vinegar carbonate g. In one case, the article may comprise a blend of resins selected from the group consisting of polysulfone, poly(ether sulfone), and poly(phenylene ether) and mixtures thereof; polyoxyloxy copolymer And the resorcinol-based polyaryl vinegar compound ^ is greater than or equal to 50 mol% of the aryl group (IV) is derived from the meta-benzene diene derivative ^ 118322.doc -35- 200832839 square vinegar bond. The polymer blend used to make the article is such that the amount of resorcinol-based polyaryl vinegar compound used can vary widely depending on the end use of the article: a change. For example, when the article is used for heat release or to the increase in peak heat release:: time is important for the end use. Nichiji's can maximize the resorcinol ester-containing: amount of polymer to reduce heat release and extend to The time period of peak heat release. In some cases, the meta-phenylene-based poly-aryl compound may be from about i to about 50 weight percent of the polymer blend. Some important compositions will have a total weight relative to the polymer blend. It is from about 1 Torr to about 5 Å by weight of a resorcinol-based polyarylate compound. In another embodiment, an article comprising a polymer blend comprising: a) from about 1 to about 99 weight percent polysulfone, poly(ether sulfone), and poly(phenylene ether sulfone) or a mixture; b) from about 0.1 to about 30% by weight of a polyoxyloxy copolymer; C) from about 99 to about 9% by weight of a resorcinol-based polyarylate compound containing greater than or equal to about 50 moles % succinol derived bond; d) 0 to about 20% by weight metal oxide, wherein the weight percentage is relative to the total weight of the polymer blend. In another aspect, it is contemplated that the polymer blend comprising the following materials X3 · mouth · a) from about 50 to about 99% by weight of polysulfone, poly(ether oxime), poly(phenylene ether) a sulfone) or a mixture thereof; b) from about 0.1 to about 1% by weight of a polyoxyloxy copolymer; 118322.doc -36 - 200832839 0 from about 1 to about 50% by weight of a resorcinol-based polyarylate a compound resin comprising greater than or equal to about 50 mole % of a benzenediol-derived linkage; d) from 0 to about 20 weight percent of a metal oxide; and e) from about 2 weight percent of a phosphorus-containing stabilizer. Β·High Tg blends of the following: lanthanum, cerium, PEIS and mixtures thereof; polyoxynized copolymers; and aryl polyester resins based on resorcinol. For example, a polyoxymethylene iodide copolymer or a polyoxymethylene polycarbonate copolymer p polyoxynoxy copolymer with high glass transition temperature (Tg) polyimine (pi), polyether sulfimine (PEI) The combination of a polyether oxime sulfone (PEIS) resin and a resorcinol-based polyarylate compound has an extremely low heat release value and improved solubility resistance. The resorcinol-derived aryl polyester may also be a copolymer containing a bond other than resorcinol, such as resorcinol-bisphenol A copolyestercarbonate. For best results, the resorcinol ester content (REC) should be greater than about 50 mole percent of the polymer bond derived from resorcinol. Higher REC may be preferred. In the case of I), an REC of more than 75 mol%, or even up to 9 或 or 100 mol%, of the meta-phenylene derivative bond may be desirable. The amount of the resorcinol-containing polymer used in the flame retardant blend can vary widely using any effective enthalpy for reducing heat release, increasing time to peak heat release, or improving resistance and decomposability. . In some cases, the polymer containing isophthalic acid S-stearate may be from about i% by weight to about weight percent of the polymer blend. Some important compositions will have between 1 and 5 % of the polystyrene-based polyester. In other cases, a blend of polyetherimide or polyetherimine sulfone with a high copolymer will have a single glass transfer of from about 150 to about 21 °C, 118322.doc -37 - 200832839 degrees (Tg ). The phenol-based polyarylate compound resin should contain greater than or equal to about 50 mole % derived from resorcinol or functionalized resorcinol and aryl dicarboxylic acid or suitable for aryl ester bonds. A unit of the reaction product of a dicarboxylic acid derivative (for example, a carboxylic acid halide, a carboxylic acid ester, and a carboxylate) formed. Further, resorcinol-based polyarylate compounds which can be used in accordance with the present invention are used in the context of other polymer blends. A copolyestercarbonate having at least one carbonate linkage between a retoxinic resin aralkylate block and an organic carbonate block is typically a polymer comprising a resorcinol arylate (by the present invention) Prepared by various embodiments and comprising at least one in one embodiment and at least two hydroxyl end sites in another embodiment. The oligomers typically have a weight average molecular weight of from about 10,000 to about 40,000 in one embodiment, and from about 15, from about 30,000 to about 30,000 in another embodiment. The presence of the resorcinol arylate-containing oligomer with carbon ruthenium chloride, at least one chain terminator, and at least one dihydroxy fluorenyl substituted aromatic hydrocarbon in a catalyst such as a tertiary amine The reaction is then carried out to prepare a thermally stable copolyestercarbonate. In one case, the polymer blend having improved flame retardancy comprises a resin selected from the group consisting of polyimine, polyether oxime, polyether sulfoxide, and mixtures thereof; polyoxyl copolymer And an aryl polyester resin mainly composed of resorcin, wherein the aryl polyester bond of 50 mol% or more is an aryl ester bond derived from resorcin. The term "polymer bond" or "a polymer bond" is defined as the reaction product of at least two monomers forming a polymer. In some cases, polyimine, polyetherimide, polyether oxime Imine 飒118322.doc -38- 200832839 2 The mixture has a hydrogen source of less than or equal to about G85 (important) = plant). It has a higher carbon content relative to the chlorine content (ie: the polymer often exhibits improved functions) These / have a lower combustion value and can release less energy when burning. It also Ο 形成 The formation of an insulating coking layer between the fuel and the fire source is independent of the line-like (four) fixed _ or mode, has been observed _ has better flame resistance than the polymers. In some cases, the H/c ratio can be: 0.85. In other cases, the ratio of 'greater than about 〇4 is better, and the pot can be obtained with sufficient The polymeric structure of the spun bond is thus achieved (iv) processing: The H/C ratio of a given polymer or copolymer can be determined by its chemical structure (by the rabbit atom and the hydrogen atom independent of any other atom present in the chemical repeat unit) Count). In some cases, flame retardant polymer blend Articles made of tantalum will have a heat release of less than about 65 kW_min/m2i for 2 minutes. In other cases, the peak heat release will be less than about 65 kW/m2e for more than about 2 minutes. And a beneficial aspect of the article made therefrom. In other cases, a time to peak heat release time of greater than about 4 minutes can be achieved. In some compositions, greater than or equal to about 50 mole percent of benzene is present. A blend of a diphenol-derived bond of a polyimine, a polyether quinone, a polyether oxime, and mixtures thereof with a polyoxyl copolymer and an aryl I polyester resin will be transparent. In one embodiment, the blend has a percent transmission greater than about 5%, as measured by ASTM method D1003 at a thickness of 2 mm. In other cases, the percentage of turbidity of such transparent compositions (eg, by ASTM method) 118322.doc -39- 200832839 measured by D1003 will be less than about 25%. In other embodiments, the percent transmission will be greater than about 60% and the percentage of turbidity will be less than about 2%. In other cases, the composition and Articles made therefrom will have a transparency of greater than about 5% a rate and a turbidity value of less than about 25% having a peak heat release of less than or equal to 5 〇 kw/m2. In a flame retardant blend towel, polyimine, polylysine, polyacetamid or The mixture may be present in a range of from about i to about 99 weight percent pp based on the total weight of the composition. Within this range, polyimine, polyether oximine, polyether sulfoxide or mixtures thereof The amount may be greater than or equal to about 20, more specifically greater than or equal to about 50, or more specifically greater than or equal to about 7 weight percent. In another embodiment, the composition comprises flame retardant polymerization of the following Blend: a) from about 1 to about 99% by weight of polyether oximine, polyether oxime imine and mixtures thereof, ◎ b), force 99 to about 1% by weight of aryl polyester resin And comprising from about 0.1 to about 30% by weight of the polyoxyalkylene copolymer, and from d to about 20% by weight of the metal oxide , wherein the weight percentage is relative to the total weight of the composition. In other aspects, a composition comprising a flame retardant polymer blend comprising: a) from 50 to about 99% by weight of a polyether quinone imine or a polyether quinone oxime resin, b) about 1 to about 5 % by weight of a resorcinol-based polyarylate compound having 118322.doc -40 - 200832839 containing greater than or equal to about 50 mole % of the benzenediol-derived bond C) about 0.1 To about 1% by weight of the polyoxyalkylene copolymer, d) from about 0 to about 2% by weight of the metal oxide, and e) from 0 to about 2% by weight of the phosphorus-containing stabilizer. Polyimine has the general formula (XX) 0 0

Ο

UL ” (Formula XX) wherein a is greater than 1, typically from about 1 Torr to about 1 Torr or more, or more specifically from about 10 to about 500; and wherein v is unrestricted A tetravalent linker, as long as the linker does not hinder the synthesis or use of the polyimine. Suitable linkers include, but are not limited to, (a) substituted or unsubstituted, saturated, unsaturated or aromatic monocyclic and polycyclic groups having from about 5 to about 50 carbon atoms, (b) having Substituted or unsubstituted, straight or branched chain, saturated or unsaturated alkyl group to about 30 carbon atoms, or a combination thereof. Preferred linkers include, but are not limited to, a tetravalent aryl group of formula (XXI), such as (Formula XXI) wherein w is a divalent group selected from the group consisting of: _s -c(0)-, -S02-, _SO-, -CyH2y- (y is an integer having a value of 丨 to 8) and a fluorinated derivative thereof, including a perfluoroalkylene group, or a group of the formula -0-Z-0-, wherein _w_ Or - 0-Z- 0-based one of the valence bonds is located at the 3,3', 3,4', 4,3' or 4,4' position, and its 118322.doc -41 - 200832839 where Z is as above definition. 2 may include an exemplary divalent base of the formula (χχπ) Ο

(Form XXII)

The R7 in the formula (XX) includes, but is not limited to, a substituted or unsubstituted divalent organic group such as: (4) an aromatic hydrocarbon group having from about 6 to about 24 carbon atoms; and a functionalized derivative; b) a linear or sub-bond having from about 2 to about 2 (s) carbon atoms; an alkyl group; (0 having a cycloalkyl group having from about 3 to about 24 carbon atoms or (d) a divalent group of the formula

(Formula VI) wherein Q is as defined above. Some classes of polyimines include polyamidimide 'polyether sulfoximine sulfones and polyether quinones', especially the melt processable polyether oximines known in the art, such as their preparation. The properties are described in U.S. Patent Nos. 3,803,085 to 118,322, doc-42 to 200832,839, and to the polyether oximine. The polyetherimide resin may comprise from about 10 to about 1000 or more, or more specifically from about 10 to about 500, structural units of the formula (ΧΧΠΙ).

(Formula XXIII) wherein Τ is -〇- or a group of the formula -〇-Ζ·〇_, wherein the 〇_ζ_ζ_〇_ group is in the divalent bond at 3,3', 3,4, 4, 3, or 4, 4 positions, and 2 of which are defined above. In one embodiment, the polyimine, polyetherimide or polyether sulfoxide may be a copolymer. It is also possible to use a mixture of polyimine, polyetherimide or polyetherimide. The polyether quinone imine can be prepared by any of the methods well known to those skilled in the art, including the reaction of an aromatic bis(ether anhydride) of formula (XVIII) with an organic diamine of the formula (νπ).

(Formula V) H2N-RLnh2 (Formula VII) wherein T and R1 are as defined above. Examples of specific aromatic dianhydrides and organic diamines are disclosed, for example, in U.S. Patent Nos. 3,972,902 and 4,455,410. Illustrative examples of aromatic dianhydrides include: 3,3_bis[4-(3,4-dicarboxyphenoxy)phenyl]propane dianhydride; 118322.doc -43- 200832839 4,4f-double (3 , 4-dicarboxyphenoxy)diphenyl ether dianhydride; bis(3,4-dicarboxyphenoxy)diphenyl sulfide dianhydride; 4,^-bis(3,4-dicarboxyphenoxy) Benzophenone dianhydride; 4,4, bis(3,4-dicarboxyphenoxy)diphenyl sulfone dianhydride; 2,2-bis[4-(2,3-dicarboxyphenoxy)phenyl Propane dianhydride; 4,4-bis(2,3-dicarboxyphenoxy)diphenyl ether; 4,4^bis(2,3-dicarboxyphenoxy)diphenyl sulfide dianhydride; 4,4'-bis(2,3-dioxaphenoxy)dibenzofluorone dianhydride;

Ο 4,4f-bis(2,3-dicarboxyphenoxy)diphenyl sulfone dianhydride; 4-(2,3-dicarboxyphenoxy)_4'-(3,'dicarboxyphenoxy) Phenyl 2,2-propane dianhydride; 4-(2,3-di-repentylphenoxy)-4'-(3,4-dioxaphenoxy)diphenyl ether dianhydride; 4-(2 ,3-dicarboxyphenoxy)-4,-(3,4-dicarboxyphenoxy)diphenyl sulfide dianhydride; 4-(2,3-dicarboxyphenoxy)-4f-(3, 4-dicarboxyphenoxy)benzophenone dianhydride; and, 4-(2,3-dicarboxyphenoxy)-4f-(3,4-dicarboxyphenoxy)diphenyl sulfone dianhydride Its various mixtures. Another class of aromatic bis(ether anhydrides) encompassed by the above formula (XVIII) includes, but is not limited to, wherein T has the formula (XXIV) and the ether bond (for example) is preferably located at 3, 3', 3, Compounds of the 4', 4, 3' or 4, 4' position and mixtures thereof, (Formula XXIV) and wherein Q is as defined above. 118322.doc -44- 200832839 Any diamine compound can be used. Examples of suitable compounds are ethylenediamine, propylenediamine, trimethylenediamine, diethylidenetriamine, triethylidenetetramine, hexamethylenediamine, heptanediamine, octanediamine, decanediamine, hydrazine. Diamine, 1,12-dodecanediamine, 1,18-octadecanediamine, 3-methylheptanediamine, 4,4-dimethylglyoxime, monoamine, 4-methylindole Amine, 5-methylindolediamine, 2,5-dimethylhexamethylenediamine, 2,5-dimethylheptanediamine, 2,2-dimethylpropanediamine, n-methyl-bis ( 3_Aminopropyl)amine, 3-decyloxyhexanediamine, 152_bis(3-aminopropyloxy)ethane, bis(3-aminopropyl) sulfide, anthracene ring Amine, bis-aminocyclohexyl)methane, m-phenylenediamine, p-phenylenediamine, 2,4-diaminotoluene, 2,6-diaminotoluene, m-xylylenediamine, p-xylenediamine , 2-methyl-4,6·diethyl-1,3-phenylene-diamine, 5-methyl-4,6-diethyl-hydrazine, 3-phenylene-diamine, Aniline, 3,3'-dimethylbenzidine, 3,3,dimethoxybenzidine, ι5_diaminone, bis(4-aminophenyl)methane, bis(4-amino)amino _3,5•diethylphenyl)methane, bis(4-aminophenyl)propane , 2,4-bis(p-amino-t-butyl)toluene, bis(p- &quot;amino-t-butylphenyl)ether, bis(p-methyl-o-aminophenyl) Benzene, bis(p-methyl♦aminopentyl)benzene, 1,3-diamino-4-picobenzene, bis-aminophenyl) sulfide, bis(4-aminophenyl) stone And bis (cardamine) phenyl (tetra). Mixtures of these compounds may also be used. Preferred diamines: the compound is a diamine, especially m-phenylenediamine and p-phenylenediamine, gamma diphenylamine and a mixture thereof. ^The implementation of the poly-imine resin comprises a structural unit according to the formula (X), wherein each R is independently a pair of people, the base is cut, the phenyl group or its mixed &amp; Divalent groups of formula (XXV) 118322.doc -45- 200832839 (Formula XXV) A number of processes for making polyimine, especially polyetherimine, include U.S. Patent Nos. 3,847,867, 3,852,242, and 3,803,085. And the methods disclosed in U.S. Patent Nos. 3,905,942, 3,983,093, and 4,443,591. .

The polystyrene, polyetherimide and polyetherimine sulfone may have a melt index of from about 〇·丨 to about 1 gram of master knife (g/min), such as a weight of 6.6 kilograms (kg). Measured by the American Society for Testing and Materials (ASTM) D 1238 at 340 to about 370 °C. In one embodiment, the polyetherimide resin has a weight average molecular weight (Mw) of from about 10,000 to about 15 Å per gram of g/mole, such as by using a polystyrene standard by gel Oxidized by chromatography. In another embodiment, the imine has an Mw of 20,000 to 60,000. The polyetherimide resins generally have an intrinsic viscosity greater than about 〇·2 dl per gram ((11/§), or, more specifically, from about 〇35 to about 7 dl/g, as in 25 〇 is measured in m-cresol. Examples of some polyether quinones useful in the blends described herein are listed in ASTM D5205, Standard Classification System for Polyetherimide (PEI) Materials, The block length of the heptane fragment of the copolymer may have any effective length. In some examples, it may be from 2 to 7 oxime oxirane repeating units. In other cases, the 'nonoxyalkylene block length may be From about 5 to about 3 repeat units. In many cases, dimethyloxane can be used. The decane polyether oxime copolymer is a specific embodiment of a siloxane copolymer that can be used. An example of a polyoxyalkyleneimine is shown in U.S. Patent Nos. 1,182,322, doc-46-200832839, 4, 404,350, 4, 808, 686, and 4, 690, 997. In one case, Ways to prepare polyether oxime oxane, except for some or all of the organic diamine reactants For example, where an amine terminated organooxane of formula XXII is substituted, wherein g is an integer having a value from 1 to about 50, in some other instances g may be from about 5 to about 30, and R is from about 2 to An aryl, an alkyl or an aryl group of about 20 carbon atoms. H2N-R'-Si-

C _ono 卜 - 叫 (Formula XXII) 〇 Some polyether oximine oxiranes may be obtained by a mixture of an organic diamine or a diamine of the formula XIX with an amine-terminated organic oxirane of the formula XXII and a formula XVIII Formed by the reaction of one or more dianhydrides. The diamine based component can be physically mixed prior to reaction with the dianhydride, thus forming a substantially random copolymer. Alternatively, a block or alternating copolymer may be formed by selective reaction of XIX and XXII with a dianhydride to form a polyamidene block which is subsequently co-reacted. In another case, the oxime used to prepare the polyether oxime copolymer may have an anhydride rather than an amine functional end group, as described in U.S. Patent No. 4,404,350. In one case, the oxoxane polyether oxime copolymer may have the formula ΧΧΠΙ ' wherein T, R, and g are as described above, η has a value of from about 5 to about 100 and Ar is from 6 to about 36 a carbon aryl or alkylaryl group.

(Formula XXIII) 118322.doc -47- 200832839 In some of the alkoxyalkyl polyether oximines, the amine group of one of the oxoxane polyether oxime copolymers may contain about 2 Torr. /. An amine-terminated organic oxime of about 〇 耳 χχ χχ π and an organic diamine of from about 50 to about 8 〇 mol % of the formula 在ιχ in some of the decane copolymers, the oxane component contains About 25 to about 4 〇 耳 ° /. Amine or terminal anhydride organic oxane. C. High Tg phase separated polymer blend. Also disclosed herein are phase separated polymer ruthenium containing a mixture of the following: a) polyaryletherketone (ρΑΕκ) ·· polyaryletherketone, polyaryl ketone, selected from the group consisting of: Polyether ketone and polyetheretherketone; and combinations thereof with a polyether sulfite wind (Ρ Ε IS) having a aryl hard group-containing bond greater than or equal to 50 mol%. Phase separation means that hydrazine and hydrazine 18 are present in the hybrid as separate chemical entities, which can be distinguished by using standard analytical techniques such as microscopy, differential scanning calorimetry or dynamic mechanical analysis to demonstrate at least two differences. A polymeric phase (one of which comprises an anthracene resin and one of which comprises a PEIS resin). In some cases, each phase will contain greater than about 8% by weight of the respective resin. In other instances, the blend will form separate domains having a size ranging from about 1 to about 5 microns, and in other cases, the domains will be from about 1 to about 20 microns. The domain size refers to the longest linear dimension exhibited by the microscopic method. The phase separation blend may be completely immiscible or may exhibit partial miscibility but must manifest (at least in the solid state) that the blend exhibits two or more different polymeric phases. The ratio of PAEK to PEIS can be any value of 118,322.doc -48 - 200832839 resulting in a blend having improved properties (i.e., better or worse than each resin alone depending on the end use application). The parts by weight may range from 1:99 to 99:1 depending on the end use application and the desired properties to be improved. The range can be from 15:85 to 85:15 or even from 25:75 to 75:25. Depending on the application, the ratio can range from 40:60 to 60:40. The skilled artisan will appreciate that changing the PAEK to PEIS ratio can achieve any real number within the stated range, depending on the desired result. The properties of the final blend that can be adjusted by varying the ratio of ingredients include heat distortion temperature and load carrying capacity. For example, in one embodiment, the polyether oxime oxime resin can be any amount effective to modify (i.e., improve by increasing) the carrying capacity of the PAEK blend on its own individual component. And exist. In some cases, the PAEK may be present in an amount from about 30 to about 70% by weight of the total mixture, and the amount of PEIS may be from about 70 to about 30% by weight, wherein the weight percentages are relative to the combined weight of PAEK and PEIS. In terms of. In some embodiments, the phase separated polymer blend will have a heat distortion temperature (HDT) greater than or equal to about 170 ° C by using ASTM method D5418 on a 3.2 mm rod at 0.46 MPa (66 psi). ) measured under. In other cases, the HDT at 0.46 MPA (66 psi) will be greater than or equal to 200 °C. In other cases, the carrying capacity of the PAEK-PEIS will be exhibited in Vicat temperature, as measured by ASTM Method D1525, at 50 Newtons (N), greater than or equal to about 200 °C. In other cases, the load carrying capacity of the phase separated polymer blend will be exhibited by a flexural modulus greater than or equal to about 200 megapascals (MPa), which is, for example, by an eight 8 deg] method. 5418 was measured at 200 ° 于 on a rod of 3.2 111111. The polymer blend can be isolated by making a suitable amount of PAEK in a molten state with an appropriate amount of PEIS to produce a phase 118322.doc -49 - 200832839. The two components, which are known to the skilled artisan to result in phase separation of the blend, can be combined. These methods include extrusion, sintering, and the like. Γ, as used herein, the term 'polyaryletherketone(ΡΑΕΚ)Π contains several polymer types containing an aromatic ring (usually a phenyl ring) bonded primarily by ketone and ether groups in different sequences. . Examples of the oxime resin include polyether ketones (poly), polyether ether ketones (PEEK), polyether ketone ether ketone ketones (oxime), and polyether ketone ketones (PEKK) and copolymers containing the same. And blends thereof. The PAEK polymer may comprise monomer units containing any sequence of aromatic rings (typically phenyl rings), keto groups and ether groups. Additional linkage groups may be present at low levels (e.g., less than 10 mole percent) as long as they do not fundamentally alter the properties of the PAEK resin. For example, it can be used in a phase separation compound to crystallize a number of polyaryletherketones having a melting point of about 300 °C. Examples of such crystalline polyaryletherketones are shown by structures XXVI, XXVII, XXVIII, XXIX and XXX.

u (XXVII) 118322.doc -50. (XXIX) (XXVIII) 200832839 〇1 IL_ (XXX) Other examples of crystalline polyaryl-ketones suitable for use herein may generally contain repeating units of the following formula (XXXI) Characterizing: (XXXI) Ο wherein Ar is a divalent aryl group independently selected from the group consisting of phenyl, terphenyl or anthranyl, and L is independently -〇-, &lt;(〇)_, _〇_A Buc(〇)_, _s_, _s〇2 or a direct bond and h is an integer having a value 〇 to about 10. Skilled artisans will be aware of the existence of well-understood patents and other literature on the formation and performance of polyaryletherketones. For example, some of the earlier works (such as U.S. Patent No. 3,065,205) are directed to the electrophilic aromatic substitution of an aromatic dimercapto halide with an unsubstituted aromatic compound such as diphenyl ether (for example, Fred _ Klein Ford catalyzes the reaction. The evolution of this category is achieved in U.S. Patent No. 4,175,175, the disclosure of which is, for example, by

U

The aromatic dihalide reacts with a nucleophilic aromatic substitution of an aromatic diol or a salt thereof to form a wide range of resins. One of the methods for preparing polyaryl ketones comprises heating a mixture of bisphenol (often reacted with its bisphenolate) with a substantially equimolar mixture of a bidentate benzene compound (or, in other cases, a phenol compound). In other cases, mixtures of such compounds can be used. For example, hydroquinone can be reacted with a di-aryl ketone such as dichlorobenzophenone or dibenzophenone to form a polyaryletherketone. In other cases, a dihydroxyaryl ketone such as dihydroxydibenzophenone can be polymerized with an aryl dihalide such as dichlorobenzene to form a PAEK resin. In other cases, 118322.doc -51 - 200832839 can react a dihydroxy aryl ether such as dihydroxydiphenyl ether with a dihaloaryl ketone such as difluorobenzophenone. In other variations, a dihydroxy compound having no ether bond such as dihydroxybiphenyl or hydrogen flooding may be combined with a di-i-based compound (for example, di-dichlorophenyl) which may have both an ether bond and a ketone bond. Ketone) reaction. In other cases, the diaryl ether carboxylic acid or carboxylic acid compound can be polymerized to form a polyarylene ether. Examples of such compounds are diphenyl ether carboxylic acid, diphenyl ether carboxylic acid chloride, phenoxy-p-oxybenzoic acid or mixtures thereof. In other cases p, the dicarboxylic acid or dicarboxylic acid halide may be condensed with a diaryl ether, for example, an isoindole chloride or a parafluorene (or a mixture thereof) may be reacted with the diphenyl ether to form a PAEK resin. . This process is described, for example, in U.S. Patent No. 4,176,222. The process packs, in the temperature range of 100 to 400 C, heats (1) a substantially equimolar mixture of the following: (a) bisphenol; and ... bidentate benzene type compound and / or (b.ii) halogen It is expected that in a monohalophenotype compound or a halogen, a halogen atom is activated by its ortho or para-C☆ group, together with sodium carbonate or sodium bicarbonate and a second alkali metal carbonate or heavy a mixture of carbonates having a higher number of atoms than the nano alkali metal carbonate or bicarbonate, the second alkali metal carbonate or bicarbonate being present such that 每·〇 is present per gram of sodium atom 〇ι to 0.2 g of the number of atoms above the metal atom, the total amount of metal carbonate or bicarbonate is such that at least each of the desired groups is present, and at least the molecule is present, and thereafter the polymer is self-generated Metal tooth separation is examined. However, other polyaryl-ketones may also be provided according to the mounting, as described in, for example, U.S. Patent No. 4,396,755. In these processes, such as (4) two 酉夂 '(b) monovalent aryl and monoaromatic bisacids and (4) combination of (4) and (b) of the reverse 118322.doc -52-200832839 should be in the fluoroalkane The presence of an acid (especially trifluoromethanesulfonic acid) is counterproductive. Additional polyaryletherketones can be prepared according to the process, as described, for example, in U.S. Patent No. 4,398,020, in which an aromatic dimercapto compound is polymerized with an aromatic compound and a mono-branched compound. The polyaryletherketone may have a comparative multi-span of greater than or equal to about 〇4 to about 5·〇 dl/g, as measured in concentrated sulfuric acid at 25 °C. The weight average molecular weight (Mw) of the PAEK may range from about 5,000 to about about bo'ooo g/m〇le. In other cases, Mw can range from about 10,000 to about 80,000 g/m〇le. The second resin component is a polyether sulfoxide (PEIS) resin. As used herein, PEIS comprises a structural unit having the formula (VII) wherein greater than or equal to about 50 mole % of the polymer bond has an aromatic milling group and

a (VII)

Or, more particularly, a tetravalent aryl group of (VIII), such as: a restricted tetravalent linker, as long as the link is synthesized or used. Suitable linkers include substituted or unsubstituted ring and polycyclic groups of about 50 carbon atoms; (b) having from 1 to about 30, straight or branched chains, saturated or not &gt; preferred linkers Including, but not limited to, the formula 118322.doc -53- (VIII) 200832839 Double view 5 ? Ο where w is, in some embodiments, a divalent group selected from the group consisting of: -S〇2-, -〇-, -s-, -C(〇)·, CyH2y_ (y is an integer having a value of 1 to 5) and a halogenated derivative thereof, which is a perfluoroalkylene group, or a formula -〇_!)_〇 - The basis. The group D may comprise a residue of a bisphenol compound. For example, D can be any of the molecules shown by the formula ιχ. H, ΌΓ, Ο

H3C Br Br CH;

The divalent bond of the 'W- or -〇_D_〇-yl group may be at 3,3, 3,^, or a mixture of the above compounds (IX) 4, 3' or 4, 4 may be used. For good melt stability H8322.doc -54- 200832839 Groups without benzylic protons are often preferred. Where w is a dance group is particularly important because it is a method of introducing a sulfone bond into a polysulfone ether quinone imide resin. As used herein, the term, polymer bond, or, a polymer bond, is defined as the reaction product of at least two monomers forming a polymer, wherein at least one of the monomers is A dianhydride or a chemical equivalent, and wherein the second monomer is a to one amine or a chemical equivalent. The polymer is contained on 100% of the bonds. A polymer having a 50 mol% aryl sulfone bond, for example, one half of its bond (in terms of moles) will comprise a dianhydride or diamine derived bond having at least one aryl sulfone group. Suitable dihydroxy-substituted aromatic hydrocarbons for use as precursors to the -0-D-0- group also include aromatic hydrocarbons of formula (X):

Each of R7 is independently hydrogen, chlorine, bromine, alkoxy, aryloxy or Ci3〇 monovalent hydrocarbon or hydrocarbyl group, and R8 and R9 are independently hydrogen, aryl, alkylfluoro or Cl-3G hydrocarbyl. Dihydroxy-substituted aromatic hydrocarbons useful as precursors to the group include those disclosed in U.S. Patent Nos. 2,991,273, 2,999,835, 3,028,365, 3,148,172, 3, by name or formula. Aromatic hydrocarbons of Nos. 153,008, 3,271,367, 3,271,368 and 4,217,438. Specific examples of dihydroxy-substituted aromatic hydrocarbons that may be used include, but are not limited to, bis(4-hydroxyphenyl)sulfone, bis(4-hydroxyphenyl)sulfide, bis(4-hydroxyphenyl)H8322. Doc -55- 200832839 Ether, bis(4-hydroxyphenyl) sulfoxide, hydrazine, 'dihydroxybenzene, 4,4,-oxydiphenol, 2,2-bis(4-hydroxyphenyl)hexafluoropropane, 4,4'-(3,3,5-tridecylcyclohexylene)biphenol, 4,4'-bis(3,5-dimercapto)biphenol-2',1-double ( 4-hydroxy-3-methylphenyl)cyclohexane; 4,4-bis(4-hydroxyphenyl)heptane; 2,4,-dihydroxydiphenylmethane, bis(2-hydroxyphenyl) Methane; bis(4-hydroxyphenyl)decane; bis(4-hydroxy-5-nitrophenyl)methane; bis(4-hydroxy-2,6-diamidino-3-methoxyphenyl)methane ; Μ-bis(4-hydroxyphenyl)ethane; hydrazine, 2_bis(4-hydroxyphenyl)ethane; bis-dihydroxy-2-phenylphenyl)ethane; 2,2-double (3 -phenyl-4-hydroxyphenyl)propane; 2,2-bis(4-hydroxy-3-methylphenyl)propane; 2,2-bis(4-hydroxy-3-methylphenyl)propane; 2.2-bis(4-hydroxy-3-isopropylphenyl)propane; 2,2-bis(4-hydroxy-3,5-dimethyl Phenyl)propane; 3,5,3',5'-tetrachloro-4,4,-dihydroxyphenyl)propane; bis(4-hydroxyphenyl)cyclohexylmethane; 2,2-bis(4- Hydroxyphenyl phenylpropane; 2,4,-dihydroxyphenyl; dihydroxynaphthalene; 2,6-dihydroxynaphthalene; hydroquinone; resorcinol; Cl-3 alkyl-substituted resorcinol; methyl Resorcinol, hydrazine, aryl dihydroxymethyl benzene; 2.2-bis(4-hydroxyphenyl)butane; 2,2-bis(4-hydroxyphenyl)_2-methylbutane; 丨, ^ double (4-phenyl)cyclohexane; 4,4,-dihydroxydiphenyl; 2-(3-methyl-4-hydroxyphenyl-2-(4-hydroxyphenyl)propane; 2-(3 ,5-dimercapto-4-hydroxyphenyl)-2-(4-hydroxyphenyl)propane; 2-(3-methyl-4-phenyl)-2-(3,5-dimethyl 4-(phenyl)propane; bis(3,5-dimethylphenyl-4-hydroxyphenyl)decane; 込^ bis(^-dimethylphenyl-4-hydroxyphenyl)ethane 2,2-bis(3,5-dimethylphenyl-4-hydroxyphenyl)propane; 2,4-bis(3,5-dimethylphenyl-4-hydroxyphenyl)-2_ Methylbutane; 3,3_bis(3,5-dimethylphenylhydroxyphenyl)pentane; 1,1_bis(3,5-didecylphenyl-4-phenyl)cyclopentane Alkane; ^-bis(3,5-dimethylphenyl-4-hydroxyphenyl) Cyclohexane; bis(3,5-dimethyl-4-hydroxyphenyl) sulfoxide, bis(3,5-didecylhydroxybenzene 118322.doc -56-200832839) wind and double (3, 5-Anthracenyl-4-phenyl-sulfide. A mixture comprising any of the aforementioned dihydroxy-substituted aromatic hydrocarbons may also be used. In a particular embodiment, the dihydroxy group containing a bisphenol having a sulfone bond is known to be important as 'because this is another way of introducing an aryl stone bond into the occludin. In other cases, the bisphenol-free benzoate-free bisphenol-derived material may be preferred to produce a polyether sulfite-like wind having excellent solubility stability. In the formula (VII), the R-based group is a diamine. a residue of a base compound or chemical equivalent, including but not limited to a substituted or unsubstituted divalent organic group such as: (a) an aromatic hydrocarbon group having from about 6 to about 24 carbon atoms and a halogenated derivative, (b) a linear or branched alkyl group having from about 2 to about 20 carbon atoms; (c) a cycloalkyl group having from about 3 to about 24 carbon atoms or (sentence formula Divalent base

(XI) wherein Q includes, but is not limited to, a divalent thiol group selected from the group consisting of: S02 _0_, _S_, -c (〇l·, CyH2y- (y is a value i to about 5) Integer) and its derivatives, including perfluoroalkylene. In a particular embodiment, R is essentially free of benzyl hydrogen. The presence of benzyl protons can be inferred from the chemical structure. In some specific embodiments Suitable aromatic diamines comprise m-phenylenediamine; p-phenylenediamine; a mixture of m-phenylenediamine and p-phenylenediamine; isomeric methyl and 5-methyl-4'6-diethylphenylene-diamine Or a mixture thereof; bis &amp;aminophenyl)-2,2-propane; bis(2-chloro-4-ylamino-3,5-diethylphenyl)methane, 4,4, _ 118322.doc -57. 200832839 Diaminobiphenyl '3,4 ^diaminobiphenyl ' 4,4 ^diaminodiamine scale (sometimes referred to as 4,4'-diaminodiphenyl ether), 3, 4. Diaminodiphenyl ether, 3,3'-diaminodiphenyl ether, 4,4 guanidine diamino phenyl sulfone, 3,4 guanidine diamino phenyl sulfone, 3, 3, 2 Aminodiphenyl sulfone, 4,4'-diaminodiphenyl sulfide; 3,4f-diaminodiphenyl sulfide; 4,4'-diaminobenzophenone, 3,4'- Diaminobenzophenone, 4,4'-diaminodiphenylmethane (commonly referred to as 4,4»-methylenediphenylamine); 4,4'-bis(4-aminophenoxy) linkage Benzene, 4,4'-bis(3-aminophenoxy)biphenyl, 1,5-diaminonaphthalene; 3,3-dimercaptobenzidine; 3,3-dimethoxyoxybenzidine; Benzidine; m-diphenylene diamine; bis(aminophenoxy)anthracene, bis(aminophenoxy)benzene, 1,3-bis(3-aminophenoxy)benzene, 1,3- Bis(4-aminophenoxy)benzene, i,4-bis(4-aminophenoxy)benzene, bis(aminophenoxy)phenylsulfone, bis(4-(4-aminophenoxy) Phenyl) sulfone, bis(4-(3-aminophenoxy)phenyl)sulfone, diaminobenzilide, 3,3,-diaminobenzophenone, 4,4' -diaminobenzophenone, 2,2,-bis(4-(4-aminophenoxy)phenyl)propane, 2,2-bis[4-(4-aminophenoxy)benzene Hexafluoropropanol '4,4'-bis(aminophenyl)hexafluoropropane, anthracene, 3-diamino-4-diisopropylbenzene; anthracene, 2_bis(3-aminophenoxy) Ethylene; 2,4-bis(β-amino-t-butyl)toluene; bis(p-β-mercapto-o-aminophenyl)benzene; (p-_β-amino-t-butylphenyl) scales and 2,4-indole diamine. A mixture of two or more kinds of diamines may also be used. Monoaminodiphenyl hydrazine (DDS), bis(aminophenoxyphenyl)sulfone (BAps) and mixtures thereof are preferred aromatic diamines. The thermoplastic polysulfone ether iminoimides described herein may be derived from reactants comprising one or more aromatic diamines or chemically equivalent derivatives thereof and one or more of the tetracarboxylic acid cyclic dianhydrides (hereinafter Sometimes referred to as an aromatic dianhydride, an aromatic tetracarboxylic acid or a heat/recovery capable of forming a cyclic anhydride or a preformed polyisoximide 118322.doc • 58- 200832839. Further, at least a portion, or at least a portion of each of the reactants comprising the aromatic diamine and the aromatic dianhydride comprises - an aryl rock bond to cause polymerization of at least 5 G mole % The physical bond contains at least an aryl sulfone group. In a particular embodiment, all or each of the reactants comprising the aromatic diamine and the aromatic dianhydride have at least one sulfone linkage. Illustrative examples of the polymerization of the reactants to form a polymer comprising a cycloheximide bond and a sulfone bond include: 4'4_bis(3,4--mercaptophenoxy)diphenyl succinic anhydride 4.4-bis(2,3-disulfophenoxy)diphenyl succinic anhydride; 4-(2,3-dicarboxyphenoxy)_4,_(3,4-dicarboxyphenoxy)di Phenyl sulfone dianhydride and mixtures thereof. Other useful aromatic dianhydrides include: 2.2-bis(4-(3,4-dicarboxyphenoxy)phenyl)propane dianhydride; 4,4f-bis(3,4.dicarboxyphenoxy)diphenyl Ether dianhydride; 4,4'-bis(3,4-dicarboxyphenoxy)diphenyl sulfide dianhydride; 4,4'-bis(3,4-dicarboxyphenoxy)benzophenone Anhydride; 2.2-bis[4-(2,3-dicarboxyphenoxy)phenyl]propane dianhydride; 4,4f-bis(2,3-dicarboxyphenoxy)diphenyl ether dianhydride; 4.4- Bis(2,3-propylphenoxy)diphenylsulfonium dianhydride; 4,4,bis(2,3-dicarboxyphenoxy)benzophenone dianhydride; 2-[4-(3 , 4-monodecylphenoxy)phenyl][4-(2,3-diphenyloxy)phenyl]propandialdehyde; 4 - (2,3-dicarboxybenzoinyl)-4 , _(3,4-dicarboxyphenoxy)diphenyl ether II 118322.doc -59- 200832839 Anhydride; 4-(2,3-dicarboxyphenoxy)-4'-(3,4-dicarboxyl Phenoxy)diphenyl sulfide dianhydride; 4-(2,3-diweiphenoxy)-4'-(3,4-diweiphenoxy)benzophenone dianhydride; 5,8-naphthalenetetracarboxylic acid dianhydride; 3.4.3, 4·_benzophenone tetracarboxylic dianhydride; 2,3,3',4'-benzophenonetetracarboxylic dianhydride; Ο 3 , 4 , 3,4'-oxybisphthalic anhydride; 2,3,3,,4,-oxyphthalic anhydride; 3,3',4,4'-biphenyltetracarboxylic dianhydride; 2.3. 3, 4^biphenyltetracarboxylic dianhydride; 2,3,2',3f-biphenyltetrazine dianhydride; benzenetetracarboxylic dianhydride; 3.4.3, 4'-diphenyl sulfone tetracarboxylic acid Anhydride; 2,3,3·,4, diphenylsulfone tetracarboxylic dianhydride; I4-bis(3,4-dicarboxyphenoxy)phthalic anhydride; and, Q 2,2_bis (3,4 · Dicarboxyphenyl) hexafluoropropane dianhydride. Also included are polyfluorenated quinone imines having structural units derived from a mixture comprising two or more dianhydrides. In other instances, the polysulfone ether iodide has greater than or equal to about 5 mole % of the quinone imine bond derived from an aromatic ether anhydride which is oxy phthalic anhydride, in an alternate embodiment The polyethylidene iodide has from about 60 mole % to about 1 mole % of an oxydiphthalic anhydride derived quinone bond. In an alternate embodiment, from about 70 mole percent to about 99 mole percent of the quinone imine linkage is derived from oxy bisphthalic anhydride or a chemical specific. 118322.doc -60- 200832839 The term "π-oxyphthalic anhydride" means an oxygen cone of the formula (χΠ) and a dicarboxylic anhydride.

(XII) and derivatives thereof as defined below. The oxygen double-formic acid anhydride of the formula (XII) includes a 44'-oxygen or the like, and a mono-anhydride,

Ο 3,4'-Oxyphthalic anhydride, 3,3,-oxy phthalic anhydride, and any mixture thereof. For example, a polysulfone ether quinone imine having an oxime imine bond derived from oxy phthalic anhydride of greater than or equal to about 5 〇 mol% may be a 4, 4 oxy bisbenzene of the formula &quot;Η; Dicarboxylic anhydride structural unit derived.

(XIII) As mentioned above, a derivative of oxy phthalic anhydride can be used to produce a polysulfone ether imine. Examples of the derived anhydride group which can function as a chemical equivalent of oxy phthalic anhydride in the quinone imine formation reaction include an oxybisphthalic anhydride derivative of the formula (XIV).

Wherein the core of formula VII and the inverse 2 may be any of the following: hydrogen; alkyl; aryl. It may be the same as or different from R2 to produce oxydiphthalic anhydride acid, oxydiphthalic acid anhydride and oxy phthalic anhydride. The polyetheretherimine herein may include a quinone bond derived from a phthalic anhydride derivative having two derivatized anhydride groups, 118322.doc-61 - 200832839 phthalic anhydride derivative, for example, wherein oxybisphthalate The anhydride derivative has the formula (XV) II 0 0 (XV) wherein R!, R2, R3 and R4 of the formula (XV) may be any of the following: hydrogen;

Aryl. R!, R2, R3 and R4 may be the same or different to produce oxydiphthalic acid, oxydiphthalic (10) and oxydiphthalic acid ester. A copolymer comprising poly(decyl ether quinone) comprising a mixture of oxy phthalic anhydride having two, three or more different dianhydrides as listed above and having approximately a molar amount of a flexible bond a structural unit derived from an imidization reaction of an organic diamine. Further, it is also encompassed by having oxydiphthalic acid including a derivative thereof as defined above having greater than or equal to about 5 mole %. a quinone imine bond, and up to about 50 mole % of a copolymer of an alternative dianhydride different from oxy phthalic anhydride. That is, in some cases, it will be desirable to manufacture in addition to having greater than or equal to about 50 mole percent. The bond derived from oxy phthalic anhydride also includes an aromatic dianhydride different from oxy phthalic anhydride (such as bisphenol A dianhydride (BPADA), disulfone dianhydride, benzophenone dianhydride, Bis(phenoxynonylphenyl)hexafluoropropane dianhydride, bisphenol dianhydride, benzene a copolymer of quinone imine bonds derived from dicarboxylic acid (PMDA), biphenyl dianhydride, sulphur dianhydride, sulfonic dianhydride, and mixtures thereof. In another embodiment, a dianhydride as defined above Reaction with an aryl diamine having a sulfone linkage. In one embodiment, the polysulfone ether quinone imine comprises a structural unit derived from an aryldiamine group of the formula (χνι) 118322.doc-62-(XVI) 200832839. H2N—Ar ^S02—Ar~NH2 wherein fluorene may be an aryl group containing a single or multiple rings. Several aromatic rings may be bonded, for example, by an ether bond, a sulfone bond or more than one sulfone bond. The ring may also be fused. In an alternative embodiment, the amine group of the f-diamino sulfone may be a meta or para position between the sulfone bonds, for example as in formula (XVII) Γ 〇

SOo

NH〇 η2ν (XVII) Aromatic amines include, but are not limited to, for example, diaminodiphenyl sulfone (DDS) and bis(indolylphenoxyphenyl) sulfone (BAPS). The polyoxyether brewing imine can be produced by using the oxydiphenyl anhydride described above to form a polyamidene bond by reaction with an aryldiamine sulfone. In some embodiments, a poly(decyl ether imino) resin can be prepared by reacting an aromatic dianhydride monomer (or an aromatic bis(ether anhydride) monomer) with an organic diamine monomer, wherein the two monomers are in essence Exist in the amount of the molar amount, or one of the monomers is present in the reaction mixture in a molar excess of no more than about 20% molar excess, and preferably less than about 10%, relative to the other monomer. One or one of the monomers is present in the reaction mixture in a molar excess of no more than about 5%. In other cases, the monomer will be present in an amount that is less than 1% of the molar excess. A primary alkylamine such as methylamine can be used as the chain terminator. The first monoamine can also be used to cap or chain terminate the polysulfone ether imine (for example) to control the molecular weight of 118322.doc -63 - 200832839. In the implementation, $_monoamine package (iv) illustrative examples thereof include aniline, cycloaniline, perfluoro early amine, analogs thereof. The aromatic first monoamine female, natriuretic and early amine may have additional official At groups bonded to the aromatic ring: such as, but not limited to, aryl, alkyl, aryl, wei, xi, 1 醯: Basic element, "alkyl or aryl, alkyl aryl" aryl ketone group. Attached to the official table t Α π k test s this base should not hinder the molecular weight of the aromatic first monoamine ether imine The function of the sf J t wind s is suitable for the early amine compound listed in U.S. Patent No. 6,919,422. β 寻 Ο Ο Ο Ο 亦可 can also use the family of dicarboxylic acid containing a ring of liver and its base An acid anhydride is used to control the molecular weight of the polyimine oxime. Illustrative examples include phthalic anhydride, hydrazine-substituted phthalic acid (such as chlorophthalic anhydride) and the like. The anhydrides may have an aromatic Additional functional groups to which the ring is bonded, illustrative examples of which include the functional groups described above with respect to the aromatic first monoamine. In the second &amp; condition, polyethylidene iodide having a low content of iso-firing bonds may be In some PAEK. compounds, the presence of iso-alkylene bonds promotes miscibility, which reduces the high temperature. Carrying capacity and being undesirable. Miscible pEEK blends having a polymer containing an isoalkylene are described, for example, in U.S. Patent Nos. 5,79,3,9 and 5,171,796. In some months, the sub-alkali group in the lower middle of the brother may mean that less than 30 mol% of the polyglycolic imine bond will contain an isoalkylene group, and in other cases, polyetheretherimine The bond will contain less than 20 mole % of the iso-isoalkyl group. In other cases, less than 1 mole % of the iso-isoalkyl group will be present in the polysulfone ether oxime bond.

The polysalt ether iodide may have a melt index of from about 0.1 to about 10 grams per minute (g/min) as measured by the American Society for Testing and Materials (AStm) D1238 at 340-425 ° C 118322.doc -64 - 200832839 Measurement. In one embodiment, the polysulfone ether quinone imide resin has a weight average molecular weight (^~) of from about 10,000 to about 150,000 grams per mole (§/111〇1 phantom, such as penetration by gel using polystyrene standards) In another embodiment, the polysulfone ether imine has an Mw of 20,000 to 60,000 g/mole. Some examples of polysinoin are listed in ASTM D5205 &quot;Standard

Classification System for Polyetherimide (PEI) Materials&quot;

组 In the case of the month (especially when film and fiber formation are desired), the composition should be essentially free of fiber reinforcements such as glass, carbon, ceramic or metal fibers. Essentially, in some cases it means less than 5 wt/〇 of the entire composition. In other instances, the composition should have less than 1% by weight of the fiber reinforcement present. In other cases, it is useful to have a composition that gradually gains a certain degree of crystallinity upon cooling. This may be more important in articles with higher surface areas such as fibers and films, which will be attributed to their higher surface area, cool, and may not achieve sufficient crystallinity necessary for optimum performance: In some cases, the formation of 'crystallinity' is reflected in the crystallization temperature (4), which can be erroneously determined by a method such as differential scanning calorimetry (Dsc) (for example, the temperature of the maximum rate of crystallization can be measured as Need to be presented; as in the case of a cooling rate of _min), :: 2 about 24°. coffee. In other cases η, for example, and the slow cooling rate of the brewing, greater than or equal to about (" may be desirable. 钇 钇 温度 温度 在 在 在 在 在 在 在 一些 一些 一些 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合H8322.doc -65- 200832839 degrees (Tg) ' a first Tg from a PAEK resin or a partially miscible PAEK blend and associated with a polysulfone ether quinone imine resin or a mixture of the resins Second Tg. These glass transition temperatures can be measured by any conventional method such as DSC or Dynamic Mechanical Analysis (DMA). In some cases, the first U can be from about 12 Torr to about 2 〇〇 ° C and the second Tg may be from about 240 to about 350 ° C. In other cases, having a first Tg of about 28 〇 to about 35 (rCi or even more 可 may be useful. In some cases, Depending on the particular tree 爿曰, molecule S and composition of the blend, the Tg may be different or the transfer may partially overlap. In another embodiment, the polysulfone ether quinone imine PEAK blend will have about 380 ° C. 200 Pascal seconds to about 1 〇, 熔融 Pascal seconds (pa_s) melt viscosity, as by ASTM method D3835 The capillary rheometer is measured at a shear rate of 1 Torr to loooo i/sec. A resin blend at 38 (rc having a melt viscosity of about 2 〇〇 Pascal seconds to about 10,000 Pascal seconds will allow the composition to be more It is easy to form into articles by using melt processing techniques. In other cases, a lower melt viscosity of from about 200 to about 5,000 Pa_s would be useful. I) Another aspect of melt processing (especially PAEK described herein) - The high temperature required for the polysulfone ether quinone imine composition) is such that the melt viscosity of the composition is not subject to excessive changes during the molding or extrusion process. A method for measuring melt stability is to use a parallel plate rheometer The viscosity changes over time at, for example, 38 (the processing temperature of rc. In some cases, the initial viscosity should be retained greater than or equal to about 50% after being held at the appropriate temperature for greater than or equal to about 10 minutes. In other cases The change in melt viscosity for at least about 1 minute should be less than about 35% of the initial value. The initial melt viscosity value can be measured after melting the composition and averaging it from i to 5 knives. 118322.doc -66· 200832839 Wait 1-5 minutes before measuring (recording) viscosity to ensure that the sample is completely melted and averaged. A suitable method for measuring the relationship between melt viscosity and time is (for example) astm method D4440. Note that it can be moored ( P) or Pascal seconds (pa_s) to report the melt viscosity; 1 Pa-s = 10 P. C. The copolyether sulfimine useful polymer may also include a copolyether having a glass transition temperature of greater than or equal to about 21.8 cm. a copolymer of imines comprising the structural units of the formulae (1) and (II): Ο

Ο and depending on the situation, the structural unit of formula (III):

Wherein R1 comprises an unsubstituted C6_22 divalent aromatic hydrocarbon or a substituted c6-22 divalent aromatic 118322.doc-67-200832839 hydrocarbon comprising a halogen or alkyl substituent or a mixture of such substituents; The divalent group of the formula (ιν):

(IV) wherein the undesired positional isomer of the aromatic ring is Q or the para position, and Q is a co-mussel bond, -C(CH3)2 or a group consisting of formula (V) Members: (V) \\ I Γ _〇-, each, one c one, —S—, —c— 5

II I 〇0 cf3 and an alkylene or alkylene group having the formula 'CyHh, wherein y is an integer having a value of from 1 to about 5, and R 2 is a divalent aryl group; a unit of the formula (1) and a formula (η) The weight ratio of the units is in the range of about 99.9:0.1 and about 25:75. In the name of Brune Ue et al., issued on February 1, 2005, CQPOLYETl·lERI]V [IDESπ, US Patent No. 6,849,706 (the full text of which is incorporated herein by reference in its entirety) Copolymers having such elements are fully discussed.添加 Ε·Additional Additives to Blends In addition to the polymer component of the blend, other benefit compositions may be added to produce improved articles. Skilled artisans will appreciate that a wide range of ingredients can be added to the polymer to improve one or more manufacturing or performance properties. In some cases, a metal oxide can be added to the polymer of the present invention. In some cases, metal oxides can further improve flame resistance by reducing heat release and increasing the time to peak heat release. Titanium dioxide is important. Other metal oxides include oxidized, oxidized, oxidized, iron oxide, and transition metal oxides. In some cases, white 118322.doc -68-200832839 metal oxides may be desirable. Metal oxides can be used alone in combination with their metal oxides. The metal oxide can be used in any effective amount, in some cases from 0. 01 to about 20 weight 〇/〇 of the polymer blend. Other useful additives include aerosol inhibitors such as metal borate (e.g., boric acid), alkali metal or alkaline earth metal boric acid or other borate salts. In addition, other oxygen-containing compounds such as boric acid, boric acid ester, boron oxide or boron may be useful as the boron-containing compound. In addition, other flame retardant additives may be used, such as aryl phosphates and brominated aromatic compounds, including polymers containing bonds made from brominated aryl compounds. Examples of the toothed aromatic compound are brominated phenoxy resin, i-polystyrene, imide, brominated polycarbonate, brominated epoxy, and mixtures thereof. Conventional flame retardant additives such as phosphates, sulfonates and halogenated aromatic compounds can also be used. Mixtures of any or all of these flame retardants can also be used. Examples of the aromatic compound are a brominated phenoxy resin, a polyphenylene styrene, a dentate quinone imide, a brominated polycarbonate, a brominated epoxy resin, and a mixture thereof. Examples of the sulfonate are potassium perfluorobutane sulfonate, sodium toluene sulfonate, sodium benzene sulfonate, sodium dibenzene sulfonate, potassium diphenyl sulfone sulfonate and sodium decane sulfonate. In some cases, the metallite salt of the soil tester is preferred. Examples of sulphuric acid-based flame retardants are triaryl phosphate, tridecyl phenyl phosphate, triphenyl phosphate, bisphenol A phenyl diphosphate, resorcinol phenyl di-perlate, phenyl-double -(3,5,5'-tridecylhexyl phosphate), ethyl diphenyl phosphate, bis(2-ethylhexyl l·p-toluene phosphate, bis(2-ethylhexyl)-phosphate benzene Ester, tris-phosphonium phosphate, rhodamine-based fluorenyl-hydrogen_, bis(d-decyl)-p-toluene toluene, halogenated triphenyl phosphate, dibutylphenyl phosphate, 2 - chloroethyl phosphate II H8322.doc -69- 200832839 Alum (2,5,5'-dimethylhexyl) linolenic acid p-tolyl ester, 2-disc ethylhexyl diphenyl ester, diphenyl phosphate Base hydrogen esters, resorcinol diphosphates and the like. In some cases, flame retardant compositions having essentially no atomic atoms, especially bromine and chlorine, may be required. Essentially halogen free atoms are meant to be In embodiments, the composition has less than about 3% dentate by weight of the composition, and in other embodiments less than about 1% by weight of the composition contains a halogen atom. It is judged by ordinary chemical analysis. The composition may also include, in the case of a fluoropolymer, an amount of from 0.01 to about 5.0% by weight of the composition of the gas-containing polymer, depending on the case, which may be provided for providing the resin composition with anti-drip properties. Fluoropolymers are used in any of the following. Some possible examples of suitable fluoropolymers and methods for making fluoropolymers such as ruthenium 4 are disclosed in, for example, U.S. Patent Nos. 3,671,487, 3,723,373 and 3,383,092. Suitable fluoropolymers include homopolymers and copolymers comprising structural units derived from one or more fluorinated alpha olefin monomers. The term, fluorinated alpha olefin monomer, is meant to include At least one fluorine atom substituent oxene monomer. Some of the suitable fluorinated Q olefin monomers include, for example, fluoroethylene such as cf2 = cf2, chf = cf2, CHfCF2 and CHfCHF and such as CF3CF = CF2, cf3cf = Fluoropropene of chf, cf3ch=cf2, Cf3CH=CH2, CF3CF=CHF, chf2ch=chf and cf3cf=ch2. Some of the suitable fluorinated alpha-olefin copolymers include two or more fluorinated alpha-olefins Copolymerization of structural units derived from monomers (eg, poly(tetrafluoroethylene-hexafluoroethylene)) and comprising one or more non-fluorinated monoethylenically unsaturated monomers copolymerized with one or more fluorinated monomers and copolymerizable with fluorinated monomers Copolymers of derived structural units (e.g., poly(tetrafluoroethylene·extended ethyl-propylene) total 118322.doc -70-200832839). Suitable non-fluorinated monoethylenically unsaturated monomers include, for example, such as Ethylene propylene oxide, such as methacrylic acid methyl vinegar, butyl acrylate acrylate monomer and the like, wherein poly(tetrafluoroethylene) homopolymer (PTFE) is Good. 4 ΰ 可 § § § There are fillers and reinforcements, such as fiber glass, ground glass, glass beads, stone Η β Gan #, λ, τ tablets and their analogues. Can add such as talc,

4 4 ash of limestone, mica, kaolin or microcrystalline kaolinite clay, vermiculite, quartz and heavy meteorite. The composition is also modified with an effective amount of an inorganic filler such as carbon fiber and carbon nanotubes, genus fibers, metal powder, conductive carbon, and other additives including nanoscale reinforcements. Other fillers that are skilled in the art can be used to provide shielding for the connector of the present invention. Other additives include antioxidants such as phosphites, phosphite diesters and hindered phenols. Phosphorus-containing stabilizers including triaryl phosphites and aryl phosphates are important useful additives. Compounds containing difunctional phosphorus can also be used. Stabilizers having a molecular weight greater than or equal to about 300 are preferred. It is useful to use a lining stabilizer having a molecular weight greater than or equal to about 50,000 in other intermediates. The phosphorus-containing stabilizer is usually present in the composition in an amount of from 0.05 to 0.5% by weight of the formulation. Colorants as well as light stabilizers and UV adsorbents may also be present in the blend. Glidants and mold release compounds are also included. Examples of the release agent are alkyl oleic acid acetonate such as pentaerythritol tetrastearate, glyceryl tristearate and ethyl sulphate monostearate. The release agent is typically present in the composition at 0.05 to 0.5% by weight of the formulation. Preferably, the release agent will have a relatively large amount of knives, typically greater than about 3 Torr, to prevent loss of the release polymer from the molten polymer mixture during the melt processing. H8322.doc -71 - 200832839, polymer blends for use in articles according to the invention may also include various additives such as nucleation, clarification, hardness and/or crystallization rate agents. These agents are used in a conventional manner and in a conventional amount. 3. Method for the manufacture of a blend according to the invention #The polymer blend used in the article according to the invention may be blended with the aforementioned ingredients by a plurality of methods, the methods involved in having a formulation A fine mix of materials for any additional additives. Preferred procedures include melt doping 纟' but solution blending is also possible. Because of the availability of melt blending equipment in commercial polymer processing, the smelting process is generally preferred, and illustrative examples of equipment used in the melt processing methods include co-rotation and counter-rotation. Extrusion crucibles, single-screw extrusion crucibles, co-kneaders, disc-filling treatments, and various other types of extrusion equipment. It is preferred to minimize the temperature of the melt during the process to avoid excessive degradation of the resin. In some embodiments, the melt treated composition exits processing equipment such as an extruder through a small exit orifice in the mold, and the resulting strand of molten resin is cooled by passing the strands through a water bath . The cooled strands can be chopped and/or molded into any suitable shape (i.e., granules) for ease of packaging, further processing, or for end use production. The blends discussed herein can be prepared by a variety of melt blending techniques. The use of a vacuum-ventilated single-screw or twin-screw extruder with a good-fit screw is preferred. In general, the extruder should be operated at a melt processing temperature ratio of ', and the plastic TK net is about 1 〇〇 c to about 15 〇. Hey.共同 Use a separate feeder or as a mixture to feed the mixture of ingredients in the feed port of the extruder. In some cases (for example, in a mixture of two or more resins), the first 118322.doc -72-200832839 first squeezes one part of the component in the first extrusion and then the second time_ It may be advantageous to add the remainder of the compound. The colorant is first pre-formed. It may be useful to mix it with the remainder of the resin composition. In other cases, it may be beneficial to add a portion of the mixture further downstream of the feed opening of the rake machine. After the extrusion, the polymer bristles are chopped or divided into appropriately sized granules which are stranded and cooled prior to use in the next manufacturing step. Preferred particles are from about 1/16 to 1/8 inch length, but the skilled artisan will appreciate that any particle size will be suitable. (d) (iv) (iv) A thermoplastic resin to remove water and mold it into the article of the present invention. About 135. . To about 15 (TC drying for about 4 to about 8 hours is more than (4), but the drying time will vary depending on the type of resin. Injection molding preferably uses suitable temperature, pressure and clamping to produce an article with a glossy surface. The melting temperature will be from about 1 Torr to about the Tg of the resin. The oil hot mold is preferred for the core resin. The molding temperature can range from about pit to (four) generation to about Temperatures of the 17th generation are preferred. It will be appreciated by those skilled in the art that many variations of such compounds and molding conditions can be used to make the compositions and articles of the present invention. Polymer blends in accordance with the present invention can also be used. Formed or manufactured as an elastic thin f: · coating, sheet, strip, tape, strip and the like. The elastic film sheet of the present invention can be produced by any method known in the art, including a blowing process Foaming double (four) to technology, two sets of foaming, double foaming and tentering frame), casting, hot forming process, extrusion coating process, profile extrusion and sheet extrusion process. The skilled artisan is well aware of compression &amp;&quot; ^, in which the polymer blend is placed in the mold 118322.doc -73- 200832839 Γ

In the U hole or in contact with the corrugated metal surface. It will then be applied to the polymer blend by means of a heat and/or force to achieve a given time, force and temperature, wherein the conditions are variable depending on the nature of the blend. The pressure of the molding tool forces the polymer conjugate to fill the entire cavity. Once the molded article is cooled, it can be removed by the aid of the ejection mechanism. After the process is completed, the polymer is blended. The material has been in the form of a cavity or a corrugated metal surface. The method of compression molding is not disclosed in U.S. Patent No. 4,698, the entire disclosure of which is incorporated herein by reference. Also commonly used in short fiber reinforced thermoplastic composites. Injection molding can be used to produce articles according to the present invention. Injection molding is a process in which the heating chamber is several times the amount necessary to manufacture the article. The amount of polymer admixture is heated to a viscous liquid and then injected into the cavity under force. The polymer blend remains high in the cavity until it cools and is then removed Injection molding and injection The forming apparatus is discussed in further detail in U.S. Patent Nos. 3,915,6,8, issued to Hujick, issued No. 3,3,2,243, and to the No. 2 (2) issued to Lameris. &gt; Large volume applications for gas and consumer products. The cycle time varies between 20 and 60 seconds. Injection molding also produces highly repeatable near-net shape parts. The ability to mold around inserts, holes and core materials is Another skilled skill will know whether injection molding is the best specific treatment for producing a second item according to the present invention. 堃 is a technique for the production of hollow thermoplastic products. Blowing involves the roots of Genkun The extruded tube of thermoplastic polymer is placed in the mold and sufficient air pressure is applied to the interior of the tube H8322.doc-74-200832839 to conform the exterior of the tube to the inner surface of the cavity. U.S. Patent No. 5,5 5 1,860 The method of performing blow molding to produce an article is described in further detail. Blow molding is not limited to producing a hollow article. For example, it can be manufactured by blowing a unit and then cutting the unit into two halves to produce two outer casings, Shell π. Single-bubble blown film process also been described (for example) described in

Encyclopedia of Chemical Technology, Kirk_〇thmer, Third Edition, John Wiley &amp; Sons, New York, 1981, Vol. 16, No. 41, p. 417 and vol. 18, pp. 191-192. The oriented film can be prepared by extrusion of a blown film or by drawing a cast or calendered film near a heat distortion temperature using conventional stretching techniques. For example, a multi-axial simultaneous stretching can be used from a tensioning applicator; the pantograph can be stretched in the χ-y direction to simultaneously or sequentially stretch in the plane x-y direction. It is also possible to use equipment having a continuous uniaxially stretched portion (such as a machine equipped with a portion for a differential roller that is stretched in the machine direction and a tenter frame portion for stretching in the transverse direction) to achieve a single axis And biaxial stretching. The thermoplastic molding system includes a thermoplastic extrusion die for extrusion of a thermoplastic panel, the panel having an adjustable die member for varying the thickness of the extruded material in different portions of the extruded panel ( That is, the dynamic mode is set to form a contour. The thermoplastic extrusion die has a trimmer for cutting the extruded thermoplastic sheet from a thermoplastic extrusion die. A plurality of thermoplastic molds, which may be vacuum or compression molds, are each mounted on a movable platform such as a rotary table to move the mold to a position at a time to accommodate the thermoplastic panels trimmed from the thermoplastic extrusion die. The molded part is formed in a variable thickness from a hot plate of a thermoplastic material that is fed from the extrusion die and is still hot. A plurality of dies are mounted to the platform to feed a mold into a loading position to receive the thermoplastic slab from the squeezing 118322.doc -75 - 200832839 and feed the second mold into the release position to automatically remove the formed part . The flat chamber can be a reciprocating or rotating platform and allows each molded part to be cooled while the other molded part receives the thermoplastic sheet. The thermoplastic molding process is provided with the step of selecting a thermoplastic extrusion die that is set according to a device that adjusts the thermoplastic laminate to vary the thickness of the extruded material through the different portions of the extruded panel. Heating the thermoplastic material to a fluid state and, by means of a far thermoplastic (which has been adapted to vary the thickness of the extruded material in different portions of the extruded panel), it will have The variable thickness extruded thermoplastic panel is trimmed to a predetermined size, and each trimmed panel of the hot thermoplastic material is directed onto the thermoforming mold, and the predetermined part in the molded mold is used to vary the thickness of the waiter component It is formed by a plate of material that is heated during extrusion of the material. Injection molding, thermoforming, pressure coating, profile extrusion and sheet extrusion are described in, for example, Plasties _13 _

Processes ^ Seymour S. Schwartz and Sidney H. Goodman. Van Nostrand Reinhold Company, New York, 1982, pp. 527 563, pp. 632-647 and 596_6. Vacuum molding can be used to produce a shaped article according to the present invention. According to this method, the formula is fixed by an iron frame or other device (which is assembled to a jig that makes handling easier)! A sheet of polymeric material is then introduced into a device wherein the sheets of polymeric material are heated by a ceramic heater or wire heater disposed in the upper and lower positions. The flakes begin to melt upon heating. The sheet is stretched in the frame while heating is continued after the collapse of the sheet. After the stretching is observed, the sheet can be molded with a uniform thickness and no wrinkles or other defects. At this time, the sheet frame is taken out from the apparatus of heat H8322.doc -76-200832839, positioned in close proximity to the mold, and vacuum molded under reduced pressure of barium atmospheric pressure, so that the desired molding can be obtained. article. Thereafter, the article can be cooled by air or water spray and the article can be taken out of the mold. According to the pressure molding, a sheet which is heated or otherwise easily handled is placed on the mold, and pressure is applied to the sheet so that the sheet is subjected to the application of pressure to assume the shape of the mold. 〇 亦可 It is also possible to use a stamping process to manufacture a product containing a resin according to the formula. By way of example, the polymer sheet of the formula I formed in the extrusion die is fitted to a vertical press and then from 5 to 500 kg/cmsup2 (preferably from 1 to 2 kg/cm.sup.2) The heat is molded under the pressure, so that the desired shaped article can be obtained. The mold is then cooled with air or water spray and the article is taken out of the mold. In this molding, the pressing time is usually at least 15 seconds, and is generally from 15 to 4 seconds. In order to improve the surface characteristics, it is preferable to perform molding under a two-stage M force condition. In the first stage, the polymer material is maintained at 1 (^2〇kg/cm sup.2, force! 5 to 40 seconds. Then at least 5 seconds to buckle to the second stage of 5〇卿2 The pressure 'is therefore a molded article with excellent surface smoothness. It is preferred to use a thermoplastic resin containing inorganic fillers with poor fluidity. ', Well-known for injection molding The process uses a resin having the formula 1 to "form out to form a resin into the cavity by pressure. The injection force is usually from v / mesh to 140 kg / cm.sup. 2 and preferably from ... to ^ kg/cm.sup.2. The skilled artisan will appreciate that articles made from the polymer blends disclosed herein by any of the techniques known in the art can be made into any desired 118322.doc-77- 200832839 Pen connector. This lookout d ^ ^ ' shape can be used for simple or multi-wall shapes for complex end-use applications. Too much miscellaneous connectors can be formed in this case. In which the electricity, 1 person _ + by various end-use applications (where the use of high-phase / joint cavity / energy cavity constraints These end uses include steam. f.). Continued σ 艮 ° service, electronics, lighting and medicine (to name a few devices, lining: examples include (but not limited to) computer connectors, power distribution: „Exporting I m such as television and telephone communication equipment, medical self-preparation, engine parts, car dry preparation, electric horse tl socket, lighting control set analog, including 22, equipment, communication equipment, computer and It is enclosed in a device that is molded in a snap-fit connector.

In accordance with the present invention, a coating having an I m I coated with a composition other than the composition of the polymer blended underneath the connector should include a skilled surface. All coatings known in the art of paints, sheets, films, and the like, including all types of connectors, can be metallized, for example, by using standard processes such as plasma deposition, sputtering, vacuum deposition. In accordance with the present invention, an early or multilayer coating can be applied to the article to impart additional properties such as electrical conductivity, electromagnetic shielding, scratch resistance, UV resistance, aesthetics, and the like. The second term &quot;paint&quot; is meant to include having about _. , 疋σ of paint, paint and polymer coatings from about (7) (10) to about 25 () thick. Skilled artisans will appreciate that any degree of coating can be used in accordance with the present invention, and that a particular range of thickness (... nm or even -50 nm) is only one of the coatings that can be used in one of the end uses covered by the present invention. The thickness of the coating (where the coating contains paint, metal and polymer): The present invention is also directed to sheets and films comprising a resin according to formula i which cover all or some of one or more of the surfaces of the article. Various methods are used to produce a finished polymeric article having a paint coating on one surface thereof, the article being made from a composition comprising a blend of polyetherimine according to formula I. According to a typical example of such methods, a primer or anchor coating is applied to all or part of the surface of the shaped article and it is then dried to form a coating. The exact method of covering all or part of one or more surfaces of a shaped article is not critical to the invention. For example, the coating can be applied via a quasi-coating technique, such as roll coating using a roll coater, spraying by using a spray (previously applied with or without a primer) In the case of a layer), dip coating, brushing or shower coating. For commercial or large-scale products of coated shaped articles, the use of spray blasting methods is effective. Yangyan's preferably uses a method of coating by using a robot. The full text of all patents, patent applications, and other publications disclosed herein is hereby incorporated by reference. EXAMPLES Without further elaboration, the skilled artisan can make and use the invention by using the description herein. The following examples are included to provide additional guidance to those skilled in the art of practicing the claimed invention. These examples are provided as representative of the work and contribute to the teachings of the present invention. Therefore, such examples are not intended to limit the scope of the invention in any way. All parts are by weight unless otherwise stated below. Example 1 For Example 1-9 H8322.doc -79- 200832839

Some properties were measured using the ASTM test method. All molded samples were conditioned for at least 48 hours at 50% relative humidity prior to testing. The reverse notched impact value was measured on a 3.2 mm thick rod at room temperature according to ASTM D256. The heat distortion temperature (HDT) was measured at 0.46 MPa (66 psi) on a 3.2 mm thick rod in accordance with ASTM D648. Tensile properties were measured on a 3.2 mm type I rod in accordance with ASTM method D638. Flexural properties were measured on a 3.2 mm rod in accordance with ASTM method D790. The Vicat temperature was measured at 50 N according to ASTM method D1 525. Differential Scanning Calorimetry (DSC) was performed according to ASTM method D3418 but using different heating and cooling rates. The sample was heated to 350 ° C at 20 ° C/min and cooled at 20 or 80 ° C/min to record the peak crystallization temperature (Tc). Dynamic mechanical analysis (DMA) was performed flexibly on a 3.2 mm rod at an oscillation frequency of 1 Hz at a heating rate of 3 °C /min. The DMA test was performed in accordance with ASTM method D54 18 at from about 30 to about 300 °C. The viscosity as a function of shear rate was measured on a capillary rheometer at 380 ° C according to ASTM method D3835 using a 1 x 10 mm mold. The pellets of the blend were dried at 150 ° C for at least 3 hours prior to testing at 10 radians/min using a parallel plate rheometer. Measuring at 380 ° C

Lj melt viscosity changes with time. The glass transition temperature (Tg) can be measured by several techniques known in the art (e.g., ASTM method D343 18). In measuring the Tg, different heating rates can be used, for example, from 5 to 30 ° C per minute or in other cases from 10 to 20 ° C per minute. The material PCE is a BPA copolycarbonate containing about 6% by weight of a 1:1 mixture of a phthalate and a terephthalate group and a residue BPA carbonate group, 118322.doc -80 - 200832839, its Mw ~2 8,3 00 and has a Tg of about 175 °C. PSEI-1 is a polyether ether prepared by the reaction of 4,4'-oxybisphthalic anhydride (ODPA) with about 4 parts of 4'-diaminodiphenyl sulfone (DDS). The quinone imine has a Mw of ~33,000 and a Tg of about 310 °C. PSEI-2 is a mixture of 4,4!-oxybisphthalic anhydride (〇dPA) and about 20 mol% of bisphenol a dianhydride (BPADA) by about 8 moles of molybdenum. A polyhard iminoimide copolymer prepared by reacting 4,4-diaminobiphenyl; &amp; wind (DDS) having a Mw of 28,000 and having a Tg of about 280 °C. PSEI-3 is a polycondensate prepared by the reaction of bisphenol A dianhydride (BPADA) with about 4,4,-aminodiphenyl hard (DDS). ,its

Mw ~ 34,000 and has a Tg of about 247 °C. PSEI-4 is a bisphenol a disodium salt and an equivalent molar amount of 1H-isoindole-1,3(2H)·dione, 2,2,-(sulfonate-2,1-benzene) A poly-hard ether quinone imine prepared by the reaction of bis[4-chloro-(9CI), which has a weight of about 265. 〇之

Tg 〇 The composition specified in Table 1 was used to prepare the formulation 丨_9 of the present invention. The amount of all components is expressed as parts by weight per hundred parts of resin (ph〇, where the total resin weight includes stabilizers (if isodecyl and p-nonyl diacids are present with bisphenol A) A polycarbonate (PCE) copolymer is prepared by reacting a single phase (chloroform/water) in the presence of a base and a triethylamine phase transfer catalyst. The synthetic details of this type of synthesis can be found, for example, in US patents. No. 5, 52, 258, line 13, column 15-45. The resulting polyestercarbonate copolymer has 6% by weight of ester units (as isophthalate and terephthalate units: Ig weight/weight of this mouth) and 4G% of the double-based A-based carbonated g. The ingredients specified in Table 1 are mixed together in the paint shaker 118322.doc _ 81 _ 200832839 and at 2_5 English The kiln was vacuum extruded on a single screw extruder at 80-90 rpm at 575-640 QF. The resulting blend was granulated and before injection molding into a 5 X 7 X 1/8 inch plate. The granules were dried for 4 hours at 275 ° F. The molding machine was set to a melt temperature of 675 cF and a molding temperature of 275 QF. For each sample during molding Row pair 2〇 ° gloss determined CIEL * value, and appearance of the green tile according ASTmd523 using standard gloss as measured twenty R. McDonald (ed.), &Quot;.. Colour

The cie brightness (L*) value is measured as described in Physics for Industry, Second Edition, The Society of Dyers and Colourists, Bradford, UK (1997). Appearance refers to subjective visual inspection of the color and translucency/opacity of molded parts.

Example 2

U. The above-described formulations 1, 2, 3, 4 and 5 of the present invention are injection molded into the shape of electrical connector plugs, sockets and shell members using one or more of the techniques described above. Example 3 Materials made according to Formulations 6, 7, 8, and 9 of Table 1 were injection molded into the cavity of the shape of the plug connector, the socket and the shell member of 118322.doc -82 - 200832839. Example 4 For Formulation 10-3 1, performance was measured using the ASTM test method. The melt flow rate (MFR) was applied to the dried pellets according to ASTM D1238 using a weight of 6.7 Kg at 295 °C. All molded samples were conditioned for at least 48 hours at 50% relative humidity prior to testing. The notched impact value was measured on a rod of 3 · 2 mm thick at room temperature according to ASTM D256. The heat distortion temperature (HDT) was measured at 1.82 MPa (264 psi) on a 3 · 2 mm thick rod in accordance with ASTM D64 8 . (Λ The peak impact energy is reported using a ASTM method D3763 on a 102 X 3.2 mm disc at 23 ° C. The peak impact energy is reported. The resistance is measured on a 3.2 mm type I rod according to ASTM method D638. Tensile properties were measured on a 3.2 mm rod according to ASTM method D790. Solubility resistance was measured on a 3.2 mm rod using ASTM method D543. Percent transmission was measured at 2.0 mm according to ASTM method D1003 (%T) And percentage of turbidity (%H). As measured by the method listed in FAR 25.853, use Ohio State

The University (OSU) heat release rate device was tested for heat release on a 15·2 χ 15·2 cm plate 〇 9 . The two-minute heat release was measured in units of kW-min/m2 (kilowatt minutes per square meter). The peak heat release is measured in units of kW/m2 (kilowatts per square meter). The time to peak pyrolysis is also measured in minutes. The heat release test method is also described in &quot;Aircraft Materials

Fire Test Handbook,, DOT/FAA/AR-OO/12, Chapter 5,, Heat

Release Test for Cabin Materials". Materials used in these formulations are the resorcinol ester polycarbonate (ITR) resin 118322.doc -83- 200832839 which is composed of isodecyl and palladium chloride. : 1 a mixture of a mixture of resorcinol, bisphenol A (BPA) and sulphur chloride. The ITR polymer is named by the approximate molar ratio of the ester bond to the carbonate bond. ITR9010 has a molar Between benzene phenolate bond, 8 mol% of benzenediol carbonate bond and about 10 mol. / BPA carbonate bond. Tg = 131. 〇 PEI = ULTEM 1000 polyether phthalimide, borrowed Made from the reaction of bisphenol A dianhydride with about the same molar amount of phenylenediamine from GEplastics. PEI-nonane is based on m-phenylenediamine, BpA-dianhydride and an average of about one polyoxyl a polyether quinone dimethyl methoxy olefin copolymer prepared by imidization of an atomic bis-aminopropyl functional methyl methoxy oxane having a "heavy / oxime oxane content and The gel was subjected to gel permeation chromatography to measure about 24, and 〇(10) of Μ 〇 PC was ΒΡΑ polycarbonate from GE Plastics, LEXAN 130. A mixture of a resorcinol-based polyester carbonate resin and a polyether phthalimide and a polyoxymethylene phthalimide copolymer resin in a 2.5-inch single-screw, vacuum-ventilated extruder The extrusion was carried out to prepare a blend. The compositions are listed as % by weight of the total composition, unless otherwise noted. The extruder was set to approximately 285 to 340 °C. The blend was run at about 9 rpm under vacuum. The extrudate was cooled, granulated and dried at 12 (rc drying. The test sample was injection molded using a cycle time of 3 sec. at a set temperature of 320-360 C and a molding temperature of 120 ° C. UV protection of the article Coatings. Formulations 10 and 1 of Table 2 indicate how the substitution of PC with resorcinol ester polycarbonate (ITR9 010) is given in the PEI/polyoxymethylene polyimide copolymer blend. Two minutes and a significant reduction in total heat release. Note that resorcinol ester polymerization 118322.doc -84- 200832839 The addition of carbonate can also increase the flow rate (in this case MFR = melt flow rate g/10 min, amount Measured at 29 5 ° C) and improved elongation at break. Table 2 〇 Formulation 10 11 PEI 76 76 ITR9010 10 20 PEl·矽 Oxygen 4 4 PC 10 0 Ti〇2 3 3 Heat release 2 minutes (kW- Min/m2) 10 12 peak (kWm2) 34 29 to peak time (Min) 4.60 4.50 295〇C MFR 3.0 3.6 Flexing modulus Kpsi 464 462 Flexural strength Kpsi 22.1 22.4 Tensile strength (Y) Kpsi 14.8 15.0 % elongation (B) 39 50 HDT 264 psi°C 163 164 Maximum energy load ft-lbs 54 56 Notched impact ft-lbs/in 1.4 1.3 Table 3 shows A series of PEI blends with various amounts of succinyl acrylate polycarbonate and 1 to 4% polyoxy oxy phthalimide copolymer. Formulations 12-18 all exhibited very low two minute heat release and Lower peak heat release. Samples all showed higher MFR indicating good melt flow. HDT was greater than 150 ° C in all examples. The formulations also had a deflection of 2400 Kpsi (2760 Mpa) 118322.doc -85- 200832839 Modulus. It is also noted that very low heat release can be achieved even with lower levels of polyetherimine (for example, polysqualimimine less than one and a half of the total blend of formulations 15 and 17) In this formulation, 12-18 had 3.0 parts per hundred (phr) of titanium dioxide and 0.1 phr of triaryl phosphite was present. Table 3 Formulation 12 13 14 15 16 17 18 PEI ITR9010 PEI-矽 Oxygen Alkane 56.5 42.5 1.0 78.0 20.0 2.0 63.0 35.0 2.0 48.0 50.0 2.0 69.5 27.5 3.0 46.0 50.0 4.0 76.0 20.0 4.0 All blends with 3 phr Ti〇2 & 0.1 phr triaryl phosphite Formulations 19 and 20 in Table 4 Shows the benefits of the addition of Ti〇2 for reducing heat release and increasing time to peak heat should. Note that Examples 19 and 2 can have excellent heat release properties, and Formulation 20 can have a slightly lower peak heat release value and a longer to peak heat time, which demonstrates the beneficial effects of metal oxide additions. Table 4 Formulations 19 20 21 22 23 24 25 PEI 67.5 67.5 68 58 19.15 18.40 17.65 ITR9010 30.0 30.0 20 30 80.0 80.0 80.0 PEl·oxane 2.5 2.5 2 2 0.75 1.50 2.25 PC 10 10 Triaryl phosphite 0.1 0.1 0.1 Ti〇2 0.0 3.0 3 3 Heat release 2 minutes (kW-min/m2) 16 12 17 15 23 18 18 Peak (kW/m2) 31 29 29 35 39 40 X yj 40 Time to peak (Min) 3.87 4.69 3.21 4.34 3.74 3.34 3.64 Comment Foam Foam Bubble Breaking > Checking Carbon; Checking Carbon &gt; Checking 118322.doc -86 - 200832839 Formulation 19 20 21 22 23 24 25 MFR 3.1 of 295 ° C 3.0 3.0 2.6 4.0 13.9 14.8 14.5 Flexural Modulus Kpsi 467 470 465 485 399 395 393 Flexural strength Kpsi 23.3 22.9 22.3 21.9 19.3 19.4 19.3 Tensile strength (Y) Kpsi 14.3 14.0 13.8 13.3 12.4 12.4 12.3 % elongation (B) 52 86 82 100 40 45 46 HDT264 psi°C 169 169 169 161 133 134 133 Maximum energy load ft-lbs 54 57 55 58 50.7 50.6 52.9 Notched impact ft-lbs/in 0.9 1.0 1.2 1.3 2.7 2.5 2.6 2.0 111111% transmittance 74.3 72.4 72.5 2.0 111111% turbidity 5.9 6.6 5.8 Table 4 Also show formulations 21 and 22. These blends combine resorcinol ester polycarbonate, polyether quinone imine and polydecyloxypolyimine copolymer with additional non-arylated polycarbonate, bisphenol A polycarbonate (PC) . These blends exhibit a flexural modulus of HDT, &gt;390 Kpsi (2691 Mpa) above 150 °C along with very low two minute and peak heat release values. Formulations 23, 24 and 25 are also shown in Table 4. These blends have a higher I resorcinol ester polycarbonate content. Even with a lower PEI oxime content and a lower PEI content, the blend can exhibit improved flame resistance as demonstrated by lower heat release values and longer to peak heat release times. Such blends can have excellent flow as exhibited by higher MFRs along with higher modulus and strength. The tensile elongation at break of all examples can be higher than 25%. Note that at 2.0 mm, the percent transmission can be above 70%, while the turbidity can be lower, even below 10% in these three component polymer blends. The notched impact strength is above 2.0 ft-lbs/in. Formulations 26, 27 and 28 are shown in Table 5. These blends have an equivalent of 118322.doc -87 - 200832839 content between the benzenediol ester polycarbonate and PEI. Even with a lower PEI oxime content (0.75 to 2.25 wt%), the blend can still indicate a lower heat release value. The blend may have a good flow exhibited by a higher MFR along with a higher modulus (&gt;390 Kpsi) and strength. The tensile elongation at break of all examples can be higher than 25%. Note that at 2.0 mm, the percent transmission is above 60%, while the turbidity is lower, below 10% in these polymer blends. Table 5 Example 26 27 28 29 30 31 PEI 49.15 48.40 47.65 79.15 78.40 77.70 ITR9010 50.0 50.0 50.0 20.0 20.0 20.0 PEI oxane 0.75 1.50 2.25 0.75 1.50 2.25 Triaryl phosphite 0.1 0.1 0.1 0.1 0.1 0.1 Heat release for 2 minutes (kW -min/m2) 14 12 13 13 10 9 Peak (kW/m2) 36 31 33 29 27 26 Time to peak (Min) 3.94 4.26 4.62 2.70 2.91 4.69 Foam foam foam foam beads Beads annotation carbon &gt; Check carbon residue carbon residue carbon residue carbon residue carbon residue 295 ° C MFR 6.7 6.9 7.0 2.1 2.1 2.3 flexural modulus Kpsi 441 430 433 467 473 473 flexural strength Kpsi 22.1 21.7 21.8 23.9 24.4 24.2 tensile strength (Y) Kpsi 13.9 13.7 14.1 16.0 15.8 15.7 % elongation (B) 38 54 80 95 72 28 HDT 264 psi °C 155 151 151 171 176 175 Maximum energy load ft-lbs f 61.1 53.1 59.6 58.3 57.1 62.2 Notched impact ft-lbs/in 1.4 1.6 1.5 1.0 1.0 1.2 2.0 mmi% transmission 73.0 72.4 68.8 72.1 70.1 66.4 2.0 111111 % turbidity 2.5 3.1 5.8 2.5 4.0 7.0 118322.doc -88 - 200832839 Formulation 29-3 1 is also shown in Table 5. These blends have a lower amount of meta- succinyl ester polycarbonate. With a very low PEI oxime content (0.75 to 2.25 wt%), the blend can still indicate lower heat release values and less time to peak heat release. The blend can exhibit flow useful for melt processing applications along with higher modulus (&gt;390 Kpsi) and strength. The tensile elongation at break in all of the examples was higher than 25%. Note that at 2.0 mm, the percent transmission can be above 60%, while the turbidity can be lower, below 10% in these polymer blends. ◎ Example 5 The performance was measured using the ASTM test method. The melt flow rate (MFR) was applied to the dried pellets according to ASTM D1238 using a weight of 6.7 Kg at 295 ° C. All molded samples were conditioned at 50% relative humidity for at least 48 hours prior to testing. According to ASTM D256 at room temperature The notched impact value was measured on a 3.2 mm thick rod. The heat distortion temperature (HDT) was measured at 1.82 MPa (264 psi) on a 3.2 111111 thick rod according to 8 乂 0648. According to ASTM method D638 at 3·2 Tensile properties were measured on a rod of type I of mm. Flexural properties were measured on a 3.2 mm rod according to ASTM method D790. As measured by the method listed in FAR 25.853, use Ohio State University ( The OSU) heat release rate device is tested for heat release at a thickness of 2.0 mm on a 15·2 x 15.2 cm sheet. The heat is measured in kW-min/m2 (kilowatt minutes per square meter) for two minutes. Release. The peak heat release is measured in kW/m2 (kilowatts per square meter). The maximum heat release time is also measured in minutes. The heat release test method is also described in 'Aircraft Materials Fire Test Handbook'. ,* DOT/FAA/AR-00/12 ' 118322.doc -89- 2 00832839 Chapter 5 ''Heat Release Test for Cabin Materials'. Materials used in these examples are the metaxyl phenolate polycarbonate (ITR) resin from isoindole and palladium chloride 1: A polymer prepared by the condensation of a mixture with meta-phenylene, double-aged A (BPA) and carbonium chloride. The ITR polymer is named by the approximate molar ratio of the bond to the carbonate bond. The ITR9010 has about 82. Molar% between the benzenediol ester bond, 8 mol% of the benzenediol carbonate bond and about 1 〇 mol% of the ugly octacarbonate bond. Tg = 131 ° C PEI-decane Polyfluorinated imine dimethyl sulphate prepared by imidization of m-phenylenediamine, BPA-dianhydride and bis-aminopropyl rivenyl polyphosphate containing an average of about 10 polyfluorene oxygen atoms An oxoxane copolymer having a decane content of about 34% by weight and a Μη of about 24,000 as measured by gel permeation chromatography. PSU is produced by the reaction of bismuth and dichlorodiphenyl hydrazine, and It is a polyfluorene sold by Solvay Co. as UDEL 1700. PES is produced by the reaction of dihydroxy phenyl sulfone and dichlorodiphenyl sulfone, and sold as ULTRASON E by BASF Co. Ether sulfone Note that blends according to this example having the 3 parts per hundred parts (phr) titanium dioxide (Ti〇2) was added during the compounds. Mixture of resorcinol-based polyester vinegar resin with polysulfone or polyether sulfone and polyoxymethylene phthalimide copolymer resin in a 25-inch single-screw, vacuum-ventilated extruder The extrusion was carried out to prepare a blend. The compositions are listed as % by weight of the total composition unless otherwise noted. Set the extruder to approximately 285 to 34 inches. Hey. The blend was run at about 9 rpm under vacuum. The extrudate was cooled, granulated and dried at 12 Torr. The test sample was injection molded using a 30 second cycle time at 32 〇 _36 (set temperature of rc and 12 〇 118322.doc 200832839 molding temperature. Formulation 32 of Table 6 shows resorcinol ester polycarbonate ( A blend of ITR9010), polysulfone (PSu) and polyoxyphthalocyanine copolymer (PEI-oxime) which gives a two minute minute and a very large reduction in peak heat release. The release is reduced from 63 kW-min/m2 to 47 kW-min/m2. The peak heat release can also be reduced from 120 kW/m2 to 75 kW/m2. The peak heat release time can also be increased from 2.56 minutes. By 3.72 minutes, the time during which the heat release reaches the maximum intensity is delayed. Formulation 33 shows the blending of polysulfone with polyethersulfone (PES) and ITR9010 and polyoxymethylene iodide f:. Heat release performance and improved flow. Table 6 Example* 32 33 34 PSu 62.5 31.25 62.5 PES 0 31.25 0 PEI oxime 2.5 2.5 2.5 ITR9010 35 35 35 Heat release 2 minutes (kW-min/m2) 47 57 31 Peak ( kW/m2) 75 75 65 to peak time (Min) 3.72 2.91 3.74 Appearance foam carbon residue foam carbon residue foam carbon residue 2 MFR of 85 ° C g / l 〇 min 13.8 11.9 10.9 blend with 3 phr Ti02 Example 6 Table 6, Formulation 34 shows resorcinol ester polycarbonate (ITR9010) and 2.5% by weight of polyfluorene Polyethersulfone (PES) blend of oxymethylene iminone copolymer. Formulation 34 can be burned according to the FAR/OSU test and produces foamed carbon slag for use as a barrier to flame propagation. It can also have a lower Heat release value, 118322.doc -91- 200832839 Longer to peak heat release time and used as a more effective barrier to flame spread. Example 7 Formulations 35 and 36 in Table 7 show PSU or PES and higher a blend of the content (60% by weight) of the benzenediol ester polycarbonate copolymer. The blend can exhibit a lower two minute heat release value and a lower peak heat release value. The foamed carbon residue of the flame-spreading barrier. Examples 35 and 36 also show higher melt flow, surprisingly not burning or flowing away from the flame during the FAR/OSU test. The blend can also exhibit higher deflection Modulus (2300 Kpsi or 2070 MPa) and higher flexural strength (215 Kpsi or 103.5 Mpa) and higher (25 0%) Elongation at break. Table 7 Example* 35 36 PSu 37.5 0 PES 0 37.5 PEI oxime 2.5 2.5 ITR9010 60 60 Heat release 2 minutes (kW-min/m2) 59 39 Peak (kW/m2) 70 58 Time to peak (Min) 2.65 2.40 Appearance foam Carbon residue foam Carbon at 295°C g/l〇min MFR 17.7 13.9 Flexural modulus Kpsi 382 399 Flexural strength Kpsi 17.6 18.3 Tensile strength (Y) Kpsi 11.0 11.7 Tensile modulus Kpsi 372 383 118322.doc -92- 200832839 Example* 35 36% elongation (B) 89 110 HDT 264 psi°C 134 132 Notched impact ft-lbs/in 2.6 3.5 with 3 phr Ti02* blending Example 8 A blend of fEI-3 and PSEI-4 resin was prepared by extrusion of a mixture of molten vermiculite in a 2.5 inch single screw, vacuum ventilator. The compositions are listed as % by weight of the total composition unless otherwise noted. The extruder was set to about 350 to 400 °C. The blend was run at about 90 rpm under vacuum. The extrudate was cooled, granulated and dried at 120 °C. The test sample was injection molded using a 30 second cycle time at a set temperature of 385-400 ° C and a molding temperature of 175 ° C. Performance was measured using the ASTM test method. The melt flow rate (MFR) was applied to the dried pellets at 367 ° C using a weight of 6.7 Kg according to ASTM D1238. All molded samples were adjusted for C for at least 48 hours prior to testing at 50% relative humidity. The notched impact value was measured on a 3.2 mm thick rod at room temperature according to ASTM D25 6. The heat distortion temperature (HDT) was measured at 0.46 MPa (66 psi) on a 3.2 111111 thick rod according to the person 8 □]^0648. Tensile properties were measured on a 3.2 mm type I rod in accordance with ASTM method D638. Flexural properties were measured on a 3.2 mm rod according to ASTM method D790. The tensile latent properties were measured on a 3.2 mm type I rod according to ASTM method D2990. Table 8 shows the good tensile and flexural properties of the filled and unfilled PSEI-3 and PSEI-4 systems. As seen in formulations 37 and 38, flexural and tensile properties can be enhanced by the addition of molten vermiculite to 118322.doc -93-200832839. Table 9 shows the enhanced anti-potential denaturation of the PSEI-3 and PSEI-4 systems compared to PEI (Ultem 1000). At 150 ° C, the PSEI system exhibits higher resistance to latent densities than the PEI system. At all temperatures, PSEI-4 exhibited better resistance to latent denaturation (i.e., lower % strain) than the PEI and PSEI-3 systems at 100 hours after testing. The filled PSEI systems 37 and 38 exhibited higher resistance to latent densities than the unfilled PSEI system. Table 8 调 Formulation PSEI-3 37 PSEI-4 38 PSEI-3 100 88 0 0 PSEI-4 0 0 100 88 Molten vermiculite 0 12 0 12 MFR of 367 ° C 1.7 1.1 5.5 0.6 Flexural modulus Kpsi 450 542 460 548 Flexural strength Kpsi 22.4 23.2 24.0 24.1 Tensile strength (Y) Kpsi 13.8 12.8 13.0 14.1 % elongation (B) 6.0 6.7 4.0 4.1 HDT 66 psi °C 237 233 248 256 Notched impact ft-lbs/in 1.30 0.52 0.82 0.59 Table 9. Anti-latent degeneration of PEI and PSEI formulations 118322.doc -94- 200832839 Sample temperature (°C) % Filler (pph) Stress (MPa) 100 Hrs% strain PEI 150 0 10 0.63 PSEI-3 150 0 10 0.528 PSEI-3 178 0 10 0.640 37 178 13.6 10 0.439 PSEI-4 150 0 10 0.395 PSEI-4 178 0 10 0.456 PSEI-4 200 0 10 0.549 38 178 13.6 10 0.339 38 200 13.6 10 0.477 ^, although reference has been made The present invention is described in the preferred embodiments, and it is understood by those skilled in the art that various changes can be made without departing from the scope of the invention. In addition, many modifications may be made to adapt a particular situation or material to the teachings of the invention without departing from the scope of the invention. Therefore, the invention is not intended to be limited to the specific embodiments disclosed, and the invention is intended to cover the invention. Ο 118322.doc 95·

Claims (1)

200832839 X. Patent application scope: An electrical connector comprising at least one plug and a jack constituting an electric module and an optional shell element comprising a polymer or polymer blend, Or the polymer is free from the group consisting of: the immiscible blend of one or more polymers comprising polyether sulfimine, such as a polymer having more than one glass transition temperature, Wherein the water ether imine has a glass transition temperature greater than 217 degrees Celsius; ... a miscible blend of polymers of one or more polyether quinones having a temperature greater than 180 degrees Celsius a single glass transition temperature; or a single polyether having a glass transition temperature greater than 247 degrees Celsius, such as the electrical connector of claim 1, wherein the polyether sulfimine has a relationship of about 〇·4 The ratio of hydrogen atoms to carbon atoms between 〇·85. 3. The electrical connector of claim 1, wherein the poly-imine is substantially free of a benzoic matrix. 4. The electrical connector of claim 1, comprising an immiscible blend of polymers having more than one glass transition temperature, and wherein the non-polyetherimine polymer has a greater than about Glass transition temperature of 18 degrees Celsius. 5. The electrical connector of claim 1 comprising a polymer miscible blend having a single glass transition temperature greater than 2 degrees Celsius. 6. The electrical connector of claim 1, comprising a single polyetherimine polymer having a glass transition temperature greater than one degree Celsius. 7 · The electrical connector of claim 1, which comprises free polyfluorene, polyether stone, polyphenyl 118322.doc 200832839, called stone wind and its mixture, g 丘 取 之 之 一 一 一 树脂 、 、 、 a second resin and a mixture comprising a resorcinol-based aryl polyacetate: a third resin of ruthenium, wherein the ratio is greater than or equal to the mole %: poly _ is derived from meta-benzene benzene The aryl vinegar bond. The electric connector of the month 7 is in which the polyoxy-copolymer is free from the following, and the selected ones are selected from the group consisting of polyethylenimine, polyether oxime, and oxygen. Imine stone fengxi oxygen burning, polycarbonate 石 石 oxygen burning, poly vinegar carbon (Λ Μ曰矽 、, polysulfone oxirane, polyether sulfone oxirane, polyphenylene ether sulfone oxirane and 9. The electrical connector of claim 7, wherein the polyoxo copolymer content is from 0.1 to about 10.0% by weight of the polymer blend. ίο. The electrical connector of claim 7, wherein The polyoxynoxy copolymer has a siloxane content of from 5 to about 70% by weight. 11. The electrical connector of claim 7, wherein the polysulfone, polyether sulfone, polyphenylene ether sulfone, and mixtures thereof have a hydrogen atom to carbon atom ratio of less than or equal to 〇85. 〇I2. The electrical connector of claim 1, further comprising one or more metal oxides in an amount of from 0.1 to 20% by weight based on the weight of the polymer blend The electrical connector of claim 7, wherein the resorcinol-based aryl group has the structure shown below: And wherein at least one of R*C1M2 alkyl, c0-C24 aryl, alkylaryl, alkoxy or dentate 118322.doc 200832839; and η is 〇_4 and m is at least about 8. 14. The electrical connector of claim 7, wherein the poly(n-(tetra) main poly- _ 曰 is a copolymer containing a carbonate bond having the structure shown below: Wherein R is at least one of C^2 alkyl, CpC24 aryl, alkylaryl, alkoxy or saccharin, η is 0-4, R5 is at least one divalent organic group, m is about 4-150 and ρ It is about 2-200. 15. The electrical connector of claim 14, wherein the R5 is derived from a bisphenol compound. The electrical connector of claim 1, wherein the immiscible, phase-separable polymer blend comprises a mixture of the following: a) self-contained polyarylene ether, polyarylene aryl ketone 1, polyscale a first resin component selected from one or more of a ketone and a polyscale scale; and b) a second resin component comprising at least one polysulfone ether quinone imine, the at least one polyethyl ether oxime The imine has a bond containing at least one aryl fluorenyl group of greater than or equal to 5 〇 mol%. 17. The electrical connector of claim 16, wherein the polyethylenimine contains an aryl sulfone bond and an aryl ether bond such that at least 50 mole percent of the repeating unit of the polysulfone ether sulfimine contains at least one aromatic An ether bond, at least one aryl sulfone bond, and at least two aryl imine bonds. 18. The electrical connector of claim 16, wherein at least 50 mole percent of the polysulfone ether quinone imine linkages are derived from oxy phthalic anhydride or a chemical equivalent thereof. 19. The electrical connector of claim 16, wherein less than 3 moles of polysulfone ether oxime bond is derived from a diamine or dianhydride containing an isoalkylene group. 20. The electrical connector of claim 1, wherein the shaped article has a heat distortion temperature (HDT) greater than or equal to 170 C, which is in accordance with ASTM method D648 at 66 psi (0.46 Mpa) at a 3.2 cm Measure on the sample. The electrical connector of claim 16, wherein the polysulfone ether iodide comprises from 30 to about 70% by weight of the entire shaped article. 22. The electrical connector of claim 16, wherein the shaped article has less than 5% by weight of fiber reinforcement. 23. The electrical connector of claim 16, wherein the shaped article has a modulus greater than about 200 MPa at 2 〇〇〇c, the modulus being measured on a 3.2 mm sample by ASTM D5418. 24. The electrical connector of claim 16, wherein the shaped article has a melt viscosity from 2 Torr to 10,000 Pascal seconds, which is measured at 380 ° C by ASTM method D3835. 25. The electrical connector of claim 16, wherein the shaped article has a melt viscosity that does not change by more than 35% from its initial value after 10 minutes at 380 °C. The electrical connector of claim 16, wherein the polysulfone ether imine is substantially free of a benzoquinone matrix. 27. The electrical connector of claim 16, wherein the one or more polyaryletherketones, polyaryl ketones, polyketones, and polys have a crystalline melting point from 300 ° C to 380 ° C. 28. The electrical connector of claim 16, wherein the polyethylenimine has a glass transition temperature (Tg) from 250 °C to 350 °C. 118322.doc 200832839 29· ^ Electrical connector of claim i having at least two different glass transition temperatures as measured by the astm method D54u, wherein the first glass transition temperature 俦, from 12G ° CS 2 GG ° C and The second glass transition temperature is from 25 "c to 350 °C. 30. The electrical connector of claim 1, comprising a first resin selected from the group consisting of free polyimine, polydecyl imine, polyether sulfoxide, and mixtures thereof, comprising a polyoxyloxy copolymer a second resin and a blend of a third resin comprising a resorcinol-based aryl polyester resin, wherein greater than or equal to 50 mol% of the aryl polyester bonds are derived from meta-benzene An aryl ester bond of a diphenol. 31. The electrical connector of claim 30, wherein the polyoxynoxy copolymer is one or more selected from the group consisting of: polyfluorene iodide, polyether oxime, oxygen Alkanes, polyether oxime sulfoxide oxiranes, polycarbonate siloxanes, polyester carbonate oxiranes, polysulfone oxanes, polyether sulfone siloxanes, and polyphenylene ether sulfone oxiranes. 32. The electrical connector of claim 30, wherein the polyoxymethylene copolymer content is from 0.1 to about 1% by weight of the polymer blend. 33. The electrical connector of claim 30, wherein the polyoxynoxy copolymer has a decane content of from 5 to 7% by weight. 34. The electrical connector of claim 30, wherein the polyimine, polyetherimine, polyetherimine, and mixtures thereof have a hydrogen to carbon ratio of less than or equal to 〇75. 35. The electrical connector of claim 30, further comprising from 0.1 to 20% by weight, based on the weight of the polymer blend, of one or more metal oxides. The electrical connector of claim 3, wherein the resorcinol-based aryl poly® has the structure shown below: Wherein R is at least one of cN12 alkyl, C0_C24 aryl, alkylaryl, alkoxy or a lignin, η is 0-4 and m is at least about 8. 37. The electrical connector of claim 30, wherein the resorcinol-based polyester resin is a copolymer comprising a carbonate bond having the structure shown below: 〇 wherein R is at least one of Ci—ualkyl, C^C:24 aryl, alkylaryl, alkoxy or halogen′ η is 0-4, and R 5 is at least one divalent organic group, m It is about 4-150 and p is about 2-200. 3 8 · Electrical connection of the item 7 7 wherein R5 is derived from a compound of two ages. The electrical connector of claim 1, wherein the polyether oxime is made of the following: (a) an arsenic anhydride selected from the group consisting of: bisphenol a dianhydride, Oxidative phthalic anhydride, pyromellitic dianhydride, phthalic anhydride, sulphate dianhydride, sulphur dianhydride, benzophenone dianhydride, and mixtures thereof; and, 118,322.doc 200832839 (b) Free An aromatic diamine selected from the group consisting of m-phenylenediamine, p-phenylenediamine, diaminodiphenyl sulfone, diaminodiphenyl ether, bisaminophenoxybenzene, bisaminophenoxy linkage Benzene, bisaminophenyl phenyl sulfone, February sulfonate, and a mixture thereof. 40. The electrical connector of claim 1 wherein the shaped article comprises a copolyetherimine having a glass transition temperature of at least about 21 8t: the copolyetherimine comprising formulas (I) and (II) Structural units: And, depending on the situation, the structural unit of formula (III): Ο wherein R1 comprises unsubstituted C: 6-22 divalent aromatic hydrocarbon or substituted c6 22 divalent aromatic cigarette comprising a halogen or alkyl substituent or a mixture of such substituents; or formula (IV) Bivalent base: 118322.doc 200832839 wherein the undetermined positional isomer of the ring is Q ρ i &lt; meta or para, and Q is a covalent bond or a free (V) group selected 屮 &lt; member: 0 II -S - II 0 (V) 0 II -c- and an alkyl or alkylene group having the formula CyH2y, wherein /, Ty is an integer from 1 to 5 including Ο end points, and R2 is a divalent aromatic group The weight ratio of the unit of formula (1) to the unit of formula (I) is in the range of about 99.9:0.1 and about 25:75. 41. The electrical connector of claim 40, which comprises having a greater than 225. It is a combination of polyether oximine. 42. The electrical connector of claim 40, which comprises a copolyether quinone imine comprising the structural unit of formula (III). 43. The electrical connector of claim 40, wherein the ... is derived from at least one diamine selected from the group consisting of m-phenylenediamine, p-phenylamine, 2-methyl-4,6-di Ethyl-1,3-phenylenediamine, 5-methyl-4,6-diethyl Q phenylenediamine, bis(4-aminophenyl)_2,2-propane, bis(2-chloro-4) -amino-3,5-diethylphenyl)methane, 4,4,-diaminobiphenyl, 3,4,-diaminobiphenyl, 4,4 guanidine diaminodiphenyl ether, 3, 4'-diaminodiphenyl ether, 4,4,-diaminodiphenyl sulfone, 3,4'-diaminodiphenyl sulfone, 4,4,-diaminobenzophenone, 3,4, - Diaminobenzophenone, 2,4-nonylphenylenediamine and mixtures thereof. 44. The electrical connector of claim 4, wherein R2 is derived from at least one dihydroxy-substituted aromatic hydrocarbon of formula (VI): HO—D—〇H wherein D has the structure of formula (VII): 118322 .doc 200832839 (VII) wherein Α1 represents an aryl group; Γ Ο a —(Y1)m I (R3)p I (Y1)m ^ A1 IA 1 t tz SA — E contains a sulfur-containing bond, a sulfide, a sulfoxide, Sulfone; phosphorus-containing bond, oxetyl group, phosphinium group; ether bond; carbonyl; tertiary nitrogen group; fluorene-containing bond, hair, hard-burning oxy; cycloaliphatic group; cyclopentylene, 3, 3, 5-trimethylcyclopentylene, cyclohexylene, 3,3-dimethylcyclohexylene, 3,3,5-trimethylcyclohexylene, methylcyclohexylene, 2-[2.2.1 ]_联亚环庚基, 亚新戊基, 亚环十五基, 雅衣衣11^烧基, 亚金刚烧基; extension base or sub-alkyl, the base case can be connected to a moiety of one or more fused rings of one or more aryl groups of a monohydroxy substituent; an unsaturated alkylene group; or selected from the group consisting of a pendant or alkylene group and free of each of the following: Partially linked two or more alkyl or sub-alkyl Alkyl··aromatic bond; tertiary nitrogen bond; ether bond; carbonyl bond; ruthenium bond, decane, decyloxy; sulfur-containing bond, sulfide, ruthenium, osmium; phosphorus-containing bond, phosphinyl group and phosphine Sulfhydryl; R3 comprises hydrogen; monovalent hydrocarbon, alkenyl, allyl, alkyl, aryl, arylalkyl, alkaryl or cycloalkyl; Υ1 is independently free of each of the following at each occurrence Selected from the group. Inorganic atom, halogen; inorganic group, nitro; organic group, monovalent hydrocarbon group, alkenyl group, allyl group, alkyl group, aryl group, aralkyl group, alkylaryl group, cycloalkyl group and alkoxy group; , the letter &quot;m&quot; represents any integer from zero and includes zero to V for the number of positions available for replacement; 118322.doc 200832839 The letter V, indicating a self-zero and including zero to E alternative position The number of integers; the letter "t&quot; means an integer at least equal to one; the child S table is not an integer that is specific to zero or 'one; and, ''U&quot; means any integer including zero. 45. An electrical connector of 40, wherein the R2 structural unit in each of the formulas (Ι), (π), and (111) is a phase 46. The electrical connector of claim 40, wherein at least a portion of the R2 structural units of at least two of the formulas (Ι), (π), and (ΙΠ) are different. 47. a connector wherein R2 is derived from at least one dihydroxy-substituted aromatic hydrocarbon selected from the group consisting of: 4,4'-(cyclopentylene)biphenyl; 4,4,-( 3,3,5-trimethylcyclopentylene), a 4,4'-(cyclohexylene)biphenyl dip; 4,4'-(3,3-dimethylcyclohexylene Biphenyldiphenol; 4,4'-(3,3,5-trimethylcyclohexylene)biphenol; 4,4'-(methylcyclohexylene)biphenyl; 4,4 , _bis(3,5-dimethyl) phenyl group, 1,1-bis(4-carbyl-3-methylphenyl)cyclohexene; 4,4_bis (4-phenyl) ), 2,4'-di-diphenyldiphenylmethane; double d-phenyl)methane; bis(4-phenyl)carbazide; bis(4-cysyl-5-nitrobenzene) A); bis(4-hydroxy-2,6-diamidino-3-methoxyphenyl)methane; 151_bis(4-hydroxyphenyl)ethane, 1,2-bis(4-hydroxyl Phenyl) ethane; 1,1_bis(4-hydroxy-2-chlorophenyl) Ethane; 2,2-bis(4-hydroxyphenyl)propane; 2,2-bis(3-phenyl-4-hydroxyphenyl)propane, 2,2-bis(4-carbyl-3- Nonylphenyl) propane; 2,2-bis(4-transethylethyl)propyl; 2,2-bis(4-yl-3-isopropylphenyl)propane; 2-bis(4-cysyl-3,5-monomethylphenyl)propane; (3,5,3,5'-tetrachloro-4,4'-di 118322.doc -10- 200832839 hydroxy Phenyl)propane; bis(4-hydroxyphenyl)cyclohexyldecane; 2,2-bis(4-hydroxyphenyl)-1-phenylpropane; 2,4,-dihydroxyphenylsulfone; dihydroxynaphthalene, 2,6-dihydroxynaphthalene; hydroquinone; resorcinol; Cw alkyl substituted resorcinol; 2,2_bis-(4-hydroxyphenyl)butane; 2,2-bis-(4 _hydroxyphenyl)_2·decylbutane; 匕^bis-(4-phenyl)cyclohexane; bis-(4-hydroxyphenyl); bis-(4-hydroxyphenyl)sulfide; (3-mercapto-4-hydroxyphenyl)-2-(4-hydroxyphenyl)propane; 2-(3,5-dimethyl-4-hydroxyphenyl)-2-(4-hydroxyphenyl) Propane; 2-(3-methyl-4-hydroxyphenyl)-2-(3,5-dimethyl-4-hydroxyphenyl)propane; bis-(3,5-dimethylphenylhydroxybenzene) 1, decane; 1,1-bis-(3,5-dimethylphenylhydroxyphenyl)ethane; 2,2-bis-( 3,5-Dimethylphenyl-4-hydroxyphenyl)propane; 2,4-bis 3,5-dimethylphenyl-4-hydroxyphenyl)-2-methylbutane; 3,3_ Bis-(3,5-dimethylphenyl-4-hydroxyphenyl)pentane; 1,1-bis-(3,5-dimethylphenyl-4-hydroxyphenyl)cyclopentane; a bis-(3,5-dimethylphenyl-4-hydroxyphenyl)cyclohexane; bis-(3,5-dimethylphenyl-4-hydroxyphenyl)sulfide, 3-(4- Hydroxyphenyl trimethylindan _5-alcohol, 丨_(4-hydroxyphenyl)-1,3,3-trimethyl fluorenyl-5-ol, 2,2,2,,2,-tetrahydrogen -3,3,3,,3, tetramethyl-spirobis[1H_ 茚]-6,6-diol. 48. The electrical connector of claim 40, wherein the R2 is at least one selected from the group consisting of a dihydroxy-substituted aromatic hydrocarbon of the formula (X) and a dihydroxy-substituted aromatic hydrocarbon of the formula (X). A dihydroxy substituted aromatic hydrocarbon: Ζ1 ζ1 118322.doc 11 200832839 Chlorine, hydrazine or hydrazine monovalent hydrocarbon group or hydrocarbon oxygen, the limiting condition is that at least one Z1 is gas or each of R5 is independently hydrogen group 'each Z1 is hydrogen, chlorine or bromine; Each of R5 is independently as defined above, and 1^ and Rh are independently hydrogen or C1_30. 49. The electrical connector of claim 40, 50. The electrical connector of claim 40, the structural unit of the terminator. 5 1 · The electrical connector of claim 50, at least the halogenated halane, chloroalkane, aryl halide 2 (XVIII) chloride selected from the group consisting of: wherein R 2 is derived from a double A. It further comprises a derivative derived from at least one chain wherein the chain terminator is free of the following unsubstituted or substituted members: hexyl chloride and formula (XVII) and (XVII) (XVIII) Wherein the chloro substituent is at the 3 or 4 position and Z3AZ4 comprises a substituted or unsubstituted alkyl or aryl group. The electrical connector of claim 50, wherein the chain terminator is at least one member selected from the group consisting of: monochlorobenzophenone, monochlorodiphenyl sulfone ; monochloroimine; 4-chloromethyl quinone imine, 4-chlorobutyl quinone imine, 4-chloro-N-octadecyl imine, 3-chloromethyl fluorene Amine, 3-oxobutylimine, 3-chloro-N-octadecyl imine, 4-chloro-N-phenylimine, 3-chlorophenylimine; single Substituted bis-indenylamine; monochlorobisindole imidobenzene; 1-[indole-(4-chloroindenido)]-3-(indenyl-indenyl)benzene; chlorine酞醯imino)]-3-(N-nonimino)benzene; monochlorobiguanide diphenyl hard, monochlorobiguanide benzophenone, monochlorobiguanide Iminophenyl ether; 4-[N-(4-chloroindenido)]phenyl-4,-(N-nonimino)phenyl ether; 4-[N-(3-chloroindole)醯imino)phenyl]-4,-(N-nonimino)phenyl ether and the corresponding isomers of the two compounds derived from 3,4 diaminodiphenyl. 53. The electrical connector of claim 40, wherein the weight ratio of the unit of formula I to the unit of formula 1 is in the range of about 99:1 and about 25:75. 54. The electrical connector of claim 40, which has a heat distortion temperature of at least 205 ° C at 〇·455 MPa. 55. The electrical connector of claim 40 having a heat distortion temperature of at least 210 ° C at 0.455 MPa as measured by ASTM method D648. 5 6. The electrical connector of claim 40 having a transition temperature between a brittleness and a ductile state of at most 30 °C as measured by ASTM method D3763. The electrical connector of claim 1, wherein the polyetherimine has a weight average molecular weight in a range between about 20, 〇〇〇 and about 80,000, which is relative by gel permeation chromatography. Determined according to polystyrene standards. 118322.doc -13- 200832839 58 - An electrical connector comprising a single polyether quinone, wherein all or part of one or more surfaces of the shaped article is coated with a cover material, wherein the cover material has A composition different from the shaped article, and wherein the shaped article comprises a single polyetherimine having a glass transition temperature greater than 247 degrees Celsius. 59. The electrical connector of claim 1 comprising a blend of polymers, wherein all or a portion of one or more surfaces of the shaped article are passed through a cover sheet Coating, wherein the covering material has a different composition than the shaped article, and wherein the shaped article comprises a blend of polymers comprising at least one polymer having a glass transition temperature greater than 217 degrees Celsius Ether quinone imine. 60. The electrical connector of claim 1, wherein the electrical connector comprises a resin blend of: a) a first resin selected from the group consisting of polysulfone, polyethersulfone, poly a phenyl ether sulfone and a mixture thereof; b) a second resin comprising a polyoxyloxy copolymer; c) a third resin comprising a resorcinol-based aryl-based resin, wherein greater than or equal to 5 Torr The reason why the % aryl polyester bond is derived from the aryl ester bond of resorcinol, and d) the fourth resin selected from the group consisting of: or a plurality of resins: polyaryl bond, polycarbonate , polyester carbonate, polyarylate, polyamine and polyester. The electrical connector of the Moonman 1, wherein the shaped article comprises a single-phase amorphous resin blend selected from the group consisting of free polysquaria, and a single phase blend comprising polyester and polyetherimine . Further included is a compound containing at least 62. The electrical connector of any one of claim 1, a boron atom. The electrical connector of any one of claims 1 to 2 having less than about 60 1 &lt;:1\\^111丨11/1112 as measured by FAR 25.853 Minute peak heat release 0. 64. The electrical connector of any of claim 1 having a total heat release of less than about 80 kW/m2 as measured by FAr 25·853. The electrical connector of any of claim 1 wherein the shaped article comprises a polymer blend having greater than or equal to about 50% as measured by ASTM D63 8 Break tensile elongation. 66. The electrical connector of any of the preceding claims, wherein the flame retardant polymer blend has a deflection of greater than or equal to about 3 〇〇 KPsi (2〇7〇Mpa) as measured by ASTM D790. The number of curves. 67. The electrical connector of any one of the items of the present invention, wherein the shaped article is freely smashed, selected from the group consisting of: a sheet, a film, a multilayer sheet, a fiber, a ruthenium film, a multilayer film, a mold Parts, extruded profiles, coated parts and foams. Having at least 69_if the request item has at least 7 0 · If the request item has at least 7 1 · If the request item has at least 7 2 · The electrical connector of any one of claim 1 wherein the electrical connector comprises a 218 Tg material of °C or above. The electrical connector of any of the preceding claims, wherein the electrical connector comprises a material having a Tg of 219 ° C or more. The electrical connection of any one of the items 1 is the material of the electrical connector comprising a Tg of 220 ° C or above. The electrical connector of any of the items, wherein the electrical connector comprises an electrical connector of any one of materials 1 of Tg of 221 ° C or more, wherein the electrical connector comprises 118322.doc -15- 200832839 has at least 7 3 · as requested item has at least 7 4 · as requested item has at least 7 5 · as requested item has at least 7 6 · as requested item has at least 7 7 · as requested item has at least 7 8 · as requested item has At least 7 9 · If the request item has at least 8 0 · If the request item has at least 8 1. If the request item has at least 8 2 · If the request item has at least 8 3 · If the request item has at least 84. If the request item has at least 84. Material of T or more Tg. An electrical connector of any one of the items wherein the electrical connection is a material of Tg of 223 ° C or more. An electrical connector of any one of the items wherein the electrical connection is a material of Tg of 224 ° C or more. An electrical connector of any one of the items wherein the electrical connection is a material of Tg of 225 ° C or more. The electrical connector of any one of the above, wherein the electrical connection is a material of Tg of 230 ° C or above. The electrical connector of any one of the above, wherein the electrical connection is a material of Tg of 235 ° C or more. The electrical connector of any of the preceding claims, wherein the electrical connection is a material of Tg of 240 ° C or more. The electrical connector of any one of the above, wherein the electrical connection is a material of Tg of 245 ° C or above. The electrical connector of any one of the above, wherein the electrical connection is a material of Tg of 250 ° C or more. The electrical connector of any of the preceding claims, wherein the electrical connection is a material having a Tg of 255 ° C or more. The electrical connector of any of the preceding claims, wherein the electrical connection is a material having a Tg of 260 ° C or above. The electrical connector of any of the preceding claims, wherein the electrical connection is a material of Tg of 265 ° C or above. The electrical connector of any one of the preceding claims, wherein the electrical connector comprises a genus comprising a device comprising a genus containing a genus containing a device comprising a device comprising a device comprising a device comprising a device comprising a device comprising 118322 .doc -16- 200832839 A material having at least one Tg of 270 ° C or more. The electrical connector of any of the claims, wherein the electrical connector comprises a material having at least one Tg of 275 ° C or more. The electrical connector of any of the preceding claims, wherein the electrical connector comprises a material having at least one Tg of 300 ° C or more. The electrical connector of any of the preceding claims, wherein the electrical connector comprises a material having at least one Tg of 350 C or more. 88. The electrical connector of any of clause 1, wherein the electrical connector comprises a material having at least one Tg between about 225 ° C and 250 ° C. The electrical connector of any of the preceding claims, wherein the electrical connector comprises one having at least one at about 250. The electrical connector of any one of the preceding claims, wherein the electrical connector comprises at least one of at about 275 ° C and 300 °. The material of the Tg between C. 9 1 · The electrical connector of any one of ng, j, minus 1, wherein the electrical connector comprises at least one between about 300 ° C and 350 ° C The material of Tg. 118322.doc 17- 200832839 VII. Designated representative map: (1) The representative representative of the case is: (none) (2) The symbol of the symbol of the representative figure is simple: 8. If there is a chemical formula in this case, please Reveal the chemical formula that best shows the characteristics of the invention: (none) ϋ 118322.doc