200831711 九、發明說明: 【舍明所屬之技術領域】 本發明為一種氧氣濃度維持及 【先前技術】 醫療為地球上所廣泛翻的氣體,制是在人員 區的人員ί氣·1==,甚至賴山氧氣稀薄地 式纽=;===:,用大規模的氣體液化方 需求的工業界。此3,在卫2了魏’故而適用於具有大規模 台t方冰2卜在業技術領域,皆有數種氧氣製造的可 由離、水f解料。然而在生成方法的設計上, 用於Λ攜式(PQrtable)設備,即所謂可攜 大,對;間便的移動的設備,但傳統技術的魔 大對於褊贡型的乳氣設備而言,則完全盔法應用。 溫常療及特殊環境的需求考量上:可攜式且能在常 /凰吊=、作的氧軋面罩,已成為具備有相當潛力發展的重要設備。 檢視如習知技藝中的美國專利編號第6,638,4〇〇號 jectrochemical 〇xygen concentrat〇r」的發明專利,雖然利 ,毛化學原理,但電極板非為多孔型金屬板,且工作溫度(w〇rki^ emperature)高達5〇〇°c,且無法在常溫工作。 又如美國專利編號第5, 378, 345號「Ceramic solid e 1 ectro 1 yte-based e 1 ectrochem i ca 1 oxygen concentrator cell 」的>發明專利,雖然同樣利用電化學原理,但為多層電極板,且 。非為夕孔型金屬板’且工作溫度(動^呢Temperature)高達8〇〇 °C,且無法在常溫工作。 故而,能夠利用電化學氧氣還原的觀念,利用空氣中的氧氣, 5 200831711 由此得到高純度的氧氣已成為新一代杆 以減低設備的複雜度外’亦可以進—步降低製造If °除了可 【發明内容】200831711 IX. Description of the invention: [Technical field to which the invention belongs] The present invention is an oxygen concentration maintenance and [prior art] The medical treatment is a gas that is widely turned on the earth, and the system is a person in the personnel area, qi·1==, Even Laishan oxygen thin type New Zealand =; ===:, the industrial sector demanded by large-scale gas liquefaction. This 3, in Wei 2 Wei, is suitable for use in the field of large-scale Taiwanese ice 2, and there are several kinds of oxygen can be made from water and water. However, in the design of the generation method, it is used for a PQrtable device, that is, a so-called portable, paired, and mobile device, but the traditional technology is for the sputum-type milk device. Then the full helmet method is applied. The need for warm and special treatments: the portable and oxygen-rolled masks that can be used in normal/phoenix cranes have become important equipment with considerable potential for development. Inspecting the invention patent of U.S. Patent No. 6,638, 4 No. jectrochemical 〇xygen concentrat〇r in the prior art, although the principle of hair chemistry, but the electrode plate is not a porous metal plate, and the working temperature (w) 〇rki^ emperature) is up to 5〇〇°c and does not work at room temperature. Further, as the invention patent of "Ceramic solid e 1 ectro 1 yte-based e 1 ectrochem i ca 1 oxygen concentrator cell" of U.S. Patent No. 5,378,345, although the electrochemical principle is also utilized, it is a multilayer electrode plate. And. It is a non-holstered metal plate' and its operating temperature (Temperature) is as high as 8 ° C and it cannot work at room temperature. Therefore, the concept of electrochemical oxygen reduction can be utilized to utilize oxygen in the air. 5 200831711 Thus, high-purity oxygen has become a new generation of rods to reduce the complexity of the equipment, and it is also possible to reduce the manufacturing of If °. [Summary of the Invention]
j應及 變空===器且由陽極產生氧氣’調整改 空控氣:氧濃度進入本發明裝置的氧濃度調控器,或俗 本發明之電極係制大小絲組合之氣體通雜電極以 ,供氧氣進人及釋a的質傳職,並使用疏水性材魏作疏水性 ^丨面,半親水性介面以提供氣體進入或釋出時之路徑通暢,避免 水分子的淹沒泛溢,同時又能提供離子導體與電極介面的液 傳功能。 本發明之電極材質選用,在多孔型陰極使用可進行氧還原反 應之電催化觸媒,包括貴金屬如白金、或金屬氧化物如LaMn〇3, 或是大環金屬錯合物,如CoTMPP等,可使氧氣吸附於其表面,且 為導電的材料,提供電位調控以進行化學還原反應。 而本發明之多孔型陽極材料則選用尺寸安定性陽極 ^Dimensional Stable Anode,DSA)藉以提高反應面積以及在氧 氣產反應(Oxygen Evaluation Reaction, 0ER)中有較佳的穩定 性’包括材料有氧化鈦支撐之氧化釕之類的金屬氧化物。 本發明之離子傳導物質則可使用酸或鹼的溶液,如K〇H、h2S0 4專’在電極電解質組合的液密及氣密性考量,亦可使用氫離子或 6 200831711 ίϊίϊΓ傳導的高分子膜,或涵浸酸驗液的複w %兩極的纖維網或其他惰性材料。 旻σ材#或隔離陰 本务明之濃氧器最佳化設計,係 使電極電催化觸媒有較佳的反應速率。 根料傳導材質, 本發明之電化學濃氧器裝置將可 用電方式便利地調節氧氣供;電路,並使 糾ίίΓΐ氣漠氧器的設計為氣體擴散性電極,而廣㉟糾中 ?:於多孔性結構,因此可以有效的改善因為質^^ 極,擴散性電極作為空氣陰 在陽極程序的穩定性佳:因此尺寸安渡金屬氧化物 電解質所共_成的裝置。、狀寸蚁性電極作為陽極,與 本發明為可攜式,可在常溫常壓 ^ 皮膚覆蓋、污染氣體隔離等等需氧 5 為氧氣口罩’ 本濃氧器的最佳化設褒置。 將使電極電雜觸媒錄===獅子或質子傳導材質, 【實施方式】 學反置,主要為經由一電化 操作,主要目的乃作為維持成置可依電位或電流進行 且在=:==氣空氣中的氧氣 ’進行氧還原反應; 本多孔型陰j should be empty and === and the oxygen generated by the anode is adjusted to change the air control gas: the oxygen concentration enters the oxygen concentration regulator of the device of the present invention, or the gas system of the electrode system of the present invention For oxygen to enter and release a quality transfer, and use hydrophobic material Wei for hydrophobic surface, semi-hydrophilic interface to provide a smooth path for gas to enter or release, to avoid flooding of water molecules, At the same time, it can provide the liquid transfer function of the ionic conductor and the electrode interface. The electrode material of the present invention is selected from the group consisting of an electrocatalytic catalyst capable of performing an oxygen reduction reaction on a porous cathode, including a noble metal such as platinum, or a metal oxide such as LaMn〇3, or a macrocyclic metal complex such as CoTMPP. Oxygen can be adsorbed on its surface and is a conductive material that provides potential regulation for chemical reduction reactions. The porous anode material of the present invention uses a dimensionally stable anode (Dimensional Stable Anode, DSA) to increase the reaction area and has better stability in the Oxygen Evaluation Reaction (ERR). A metal oxide such as ruthenium oxide supported. The ion-conducting substance of the present invention can be used as a solution of an acid or a base, such as K〇H, h2S0 4 specifically in the liquid-tight and air-tightness of the electrode electrolyte combination, and can also use hydrogen ions or a polymer which is conducted in 200831711 ίϊίϊΓ Membrane, or a viscous acid test solution of a complex w% bipolar web or other inert material. The optimized design of the 旻σ材# or the isolated concentrating oxygen concentrator makes the electrode electrocatalytic catalyst have a better reaction rate. The root material conducting material, the electrochemical oxygen concentrator device of the invention can conveniently adjust the oxygen supply by electric means; the circuit and the design of the gas eliminator are gas diffusing electrodes, and the The porous structure can therefore effectively improve the stability of the diffuser electrode as the air cathode in the anode program because of the quality of the electrode: therefore, the size of the metal oxide electrolyte is common. The ant electrode is used as the anode, and the present invention is portable, and can be optimally set in an aerobic device, such as a normal temperature and pressure, a skin covering, a polluting gas, and the like. The electrode will be electrically mixed with the media ===lion or proton conductive material, [Embodiment] The inverse is mainly through an electrochemical operation, the main purpose is to maintain the formation according to potential or current and at =:= = oxygen in the air 'to carry out the oxygen reduction reaction; the porous type
Cathode)電極,即第—多孔型 陰極⑼麵 極之化學反财料^ 1马㈣原反應 〇2+2H2〇+4e -40H- ε〇- 〇.401y 200831711 離子iim2所示’為電解質離子導體’可使用驗或酸做為 丰銳右㈣^為兩雜間之導通。而因本發明賴反應在驗性 ii或作性能’因而採用氫氧傳導離子導體之有機高分 、s…、ί材料,都皆可做為本系統之電解質材料。 極,卽ί圖103所示,以一多孔型陽極(p〇r〇us An〇de)電 應方程孔型電極做為氧產生反應。本纽獅極之化學反Cathode) electrode, the first counter-cathode (9) surface chemical reaction material ^ 1 horse (four) original reaction 〇 2+2H2 〇 +4e -40H- ε〇- 〇.401y 200831711 ion iim2 shown as 'electrolyte ionic conductor 'You can use the test or acid as Feng Rui right (four) ^ for the conduction of the two miscellaneous. However, the organic high-concentration, s..., ί material of the hydrogen-oxygen-conducting ion conductor can be used as the electrolyte material of the system because of the inductive reaction or the performance of the present invention. Pole, as shown in Fig. 103, a porous anode (p〇r〇us An〇de) is used as an oxygen generating reaction. Ben Nuoshi's chemical reaction
^Η -〇2 + 4Θ- + 2Η2〇 ε〇=-〇. 401V 是且101之多孔型陰極’其_為氧還原之電極材料, 金力能的化合物’—般可使用貴金屬如鈾或碳支撐 或ίϊ衍生化^亦_7使卿太礦結構之金屬氧化物,如Ufn〇3^Η -〇2 + 4Θ- + 2Η2〇ε〇=-〇. 401V is a porous cathode of 101', which is an electrode material for oxygen reduction, a compound of Jinlien', generally using precious metals such as uranium or carbon Support or ϊ ϊ ^ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
FeOEP、簟供Γ物,亦可使用大環金屬錯合物FeTMPP,CoTMPP及 Fe(^專」,具氧氣吸附功能的化合物。 尸及 可成為中纽鶴極,其雜域_之電極結構, 粗細孔洞,、^為ϊϊΐίΐϋί道誠水奸泛溢的疏水 為尺ΐ:定咖’為氧產生之電極材料,亦 或其他因騎所了, 碍、、构狀,或疋做為氣體產生電 —丄人 ⑽之電解 200831711 第-圖101之多孔型陰極做為空氣中之氧進入之電極, 極’如第-圖1G3之多孔型陽極產生氧,糊第—圖1()4之 供電能並進行電化學反應’控制氧氣量,以做為可 攜式調節氧氣供應裝置。 々 明裝置所調控之氧氣濃度,#其濃度轉在所進 減献或是較低的氧氣濃度,即可達到所需之濃氧調 本發明之多孔型陰極與多孔型陽極電極,以及FeOEP, ruthenium donors, macrocyclic metal complexes FeTMPP, CoTMPP and Fe(^ special) compounds with oxygen adsorption function can also be used. The corpse can be used as the intermediate structure of the neutrons. Thick and thin holes, ^ is ϊϊΐ ΐϋ ΐϋ ΐϋ 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水- Electrolysis of 丄人(10) 200831711 The porous cathode of Fig. 101 is used as an electrode for oxygen in the air, and the pole of the porous anode of the first - Fig. 1G3 generates oxygen, and the power supply of the paste - Fig. 1 () 4 And carry out the electrochemical reaction to control the amount of oxygen as a portable regulator of oxygen supply. The concentration of oxygen regulated by the device, # concentration can be achieved by the reduction or lower oxygen concentration. The desired concentrated oxygen is used to adjust the porous cathode of the present invention and the porous anode electrode, and
用t適之製程及封裝結構,藉以確保電極材料與電解ΐ 通透進出,離子導體絕緣電極電路,提供離子通道等^為乳體 口置本f3置為可攜式’可在常溫常壓下使用,故可^為氧氣 ^置皮膚復蓋、污染氣體隔離場所等等,即需氧環境的氧氣調 明之本發^之雛實施_已’並_以限定本發 之等 【圖式簡單說明】 第一圖所示為本發明之實施方式。 【主要元件符號說明】 101多孔型陰極 102電解質離子導體 1 〇3多孔型陽極 104電源控制電路 9Use t suitable process and package structure to ensure that the electrode material and the electrolytic ΐ penetrate in and out, the ion conductor insulated electrode circuit, provide ion channels, etc. ^ is the milk body mouth set f3 is portable - can be under normal temperature and pressure Use, it can be ^ oxygen ^ set skin cover, contaminated gas isolation site, etc., that is, the oxygen-enhanced oxygen-enhanced hair of the hair of the implementation of the _ has 'and _ to limit the hair of the hair, etc. The first figure shows an embodiment of the present invention. [Main component symbol description] 101 porous cathode 102 electrolyte ion conductor 1 〇 3 porous anode 104 power supply control circuit 9