200829280 ^ 九、發明說明： [相關申請案] 本申請案係主張於2006 wM 0δ日所申請之日本國 專利申明木2006-302685號之優先權，其内容已併入本文 中。 【發明所屬之技術領域】 本發明係有關化糙料用色材，特別是有關鮮難不暗淡 ,之化粧料用色村。此外，亦係有關調配有此化輕料用色材 之彩粧化粧料。 【先前技術】 以往，為了使化粧料中所使用之色材顯現出鮮懿不暗 ，之=色’而持續地在進行各種嘗試。為了顯現 I:而=各種珍珠劑、和為了使色材顯現之㈣ 材二=色調而經由粉末表面處理技術提高色 此外，f綱發新穎色㈣本具有之色調的卫作 、>、貝在進行，但從藥事法等安 寺 料相當困難。 彳文“ 生之面來看，開發新穎之染 因此，希望使用現有之染料與非染料材料來門… 性兩且具有鮮懿不暗谈之新色調的色材。 ^文王 在專利文獻1中，揭示有使 如至一之球狀耐綸之皮膚洗淨劑進;^色之粒徑為 使用做為絲劑，染色後之•所具有之狀耐論係 調幾乎相同而無改變，而並非 ^染料之色 ，此不暗浹之新色調 319543 5 200829280 者。此外，其目的係在於提供皮膚洗淨劑 链料中使用之色材之技術範圍和應解決之任務不：：桩化 [專利文獻1]日本特開平5 —32〇〇41號公報 【發明内容】 (發明欲解決的課題） 本發明係有鑒於上述問題點而完成者，其目的在於 供安全性高且可顯現出•不暗淡之顏色的化粧料用色 材、及使用該色材之彩粧化粧料。 (解決課題的手段） 本發明人等有鑒於如上述之情形，經深入研究之結果 發現，含有分子量在10萬以下之聚醯胺粉末與化粧料用毕 料之化粧料用色材，其安全性高且顯現出現有色材無法顯 現之鮮艷而不暗淡的螢光色，因而完成本發明。 “本發明係含有重量平均分子量為i萬至10萬，且體積 平均粒徑為〇· 1至20/zm之聚醯胺粉末、與化粧料用染料 之化粧料用色材。此化粧料用色材主要係使用作為彩粧用 色材，但並非限定於此。 本發明係一種化粧料用色材之製造方法，係將化粧料 用^料 >谷解或分散於油分中’然後添加重量平均分子量為 1萬至10萬，且體積平均粒徑為〇· 1至20 Am之聚醯胺粉 末，並加熱混合而製造化粧料用色材之化粧料用色材之製 造方法。 本發明係一種調配有上述所記載之化粧料用色材而成 之彩粧·化链料。 319543 6 200829280 本發明係一種調配有上述所記載之化粧料用色材而成 之口紅。 (發明的效果） 根據本發明，能提供安全性高且顯現出鮮艷不暗淡之 螢光色之化粧料用色材及彩粧化粧料。 此外’根據本發明之化粧料用色材之製造方法，能製 造色穩定性良好，且能以簡易之方法製造鮮齡不暗淡之化 粧料用色材。 【實施方式】 (本發明之最佳形態） 以下，說明關於本發明之最佳之形態。 (化粧料用色材） 本發明之化粧料用色材係含有重量平均分子量為i萬 ^ 10萬’且體積平均粒徑為〇. 1至20"之聚醯胺粉末、 與化粧料用染料者。 之聚醯胺粉末以耐綸 本發明之化粧料用色材中所使用 粉末為佳。 耐綸可舉例如：耐給—β +人 1 . 耐、吻46、耐綸-6, 12共聚物 耐綸-11、耐綸-12等，1中 Ί 0 /、 b 乂耐綸-12、耐綸-6、耐綸 12共斌物為佳。耐綸 八q制1广％, 」舉例如：Nylon SP - 500(Tora 公司製，粒徑為1〇 以下，珅壯从丄 ^ ^ ^ 1 η 球狀粉末）、NylonSP-HKTora, 么司製，粒徑10/zm，球狀 司萝，初菸9n , &狀知末）、Nyl〇n SP-20(T〇ray公 口J衣，粒徑20/zm，球狀粉太） TR-l(T〇ray公司製，粒徑、。耐綸_6可舉例如：Tora] A m ’多孔質粉末）、Orgaso 1 319543 7 200829280 1002 D NAT C0S(ARKEMA公司製，粒徑2(^m，塊狀粉末） 等。耐綸-6，12共聚物可舉例如：心1〇1115〇以打{11[_5(){)() (Shinto Fine公司製，粒徑7//m，球狀粉末）等。上述各 粉末之分子量均係1萬至1〇萬者。 使用於本發明之化粧料用色材之聚酿胺粉末之分子量 以重量平均分子量為i萬至1〇萬者為佳，較好為！萬至6 萬者。若大於10萬，則鮮懿之顯色性變差，且不 螢光，。若分子量小於i萬，則由於作為化粧^之粉末 之結晶性不足，故調配困難。 此外，聚醯胺粉末之體積平均粒徑以〇1至 二 範圍者為佳，較好為2至15㈣者。若體積平均粒徑二 2〇#πι，則由於使用感變差故不佳。 :破::於，胺粉末之形狀’從螢光顯色性之觀點聋 看以球狀、多孔質狀者較塊狀者為佳。 所謂本發明中所使用之化粧料用染料係指 為化粧料用途之染料，特別是以鮮餘度之觀點而古，、、乍 溶性染料為佳，可舉例如：紅色218泸友、D以油。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 [Technical Field According to the Invention] The present invention relates to a color material for a roughened material, in particular, a color village which is difficult to dim and which is used for cosmetics. In addition, it is also a makeup cosmetic that is formulated with this color material for light materials. [Prior Art] Conventionally, various attempts have been made to make the color material used in the cosmetic material appear fresh and not dark. In order to visualize I: and = various kinds of pearls, and in order to make the color material appear (four) material = color tone, the color is improved by the powder surface treatment technology, and the novel color (four) has a color tone of the guard, > It is going on, but it is quite difficult to get it from the pharmacy law.彳文 “In terms of the raw surface, the development of novel dyes, therefore, it is hoped to use the existing dyes and non-dye materials to come to the door... Sexual and fresh color materials that are not confusing. ^Wenwang in Patent Document 1 , revealing that there is a skin-like detergent for spheroidal nylon; the particle size of the color is used as a silking agent, and the shape of the dyeing has almost the same and no change, and It is not the color of the dye, this is not a new color of 319543 5 200829280. In addition, its purpose is to provide the technical scope of the color material used in the skin detergent chain and the task to be solved:: Piled [ [Patent Document 1] Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. 5-32-41. SUMMARY OF THE INVENTION The present invention has been made in view of the above problems, and its object is to provide high security and display. In the present invention, the present inventors have found that the molecular weight is 10, as a result of the above research, in view of the above-mentioned circumstances, the coloring material for the cosmetic material and the coloring material using the coloring material. Polyamide powder below 10,000 The present invention is completed by the use of a color material for a cosmetic material for cosmetics and cosmetics, and thus exhibits a vivid, non-dark fluorescent color which cannot be visualized by a coloring material, and thus the present invention has been completed. "The present invention contains a weight average molecular weight of i. A coloring material for a cosmetic material which has a volume average particle diameter of 〇·1 to 20/zm and a cosmetic material for a cosmetic material. The color material for cosmetics is mainly used as a color material for makeup, but is not limited thereto. The present invention relates to a method for producing a color material for cosmetics, which comprises dissolving or dispersing a cosmetic material in an oil component, and then adding a weight average molecular weight of 10,000 to 100,000, and a volume average particle diameter of 〇· A method for producing a coloring material for a cosmetic material which is a coloring material for a cosmetic material by heating and mixing the polyamidamine powder of 1 to 20 Am. The present invention relates to a makeup and chemical chain material in which the color material for cosmetics described above is blended. 319543 6 200829280 The present invention is a lipstick prepared by mixing the color material for cosmetics described above. (Effects of the Invention) According to the present invention, it is possible to provide a color material for cosmetics and a makeup cosmetic which have high safety and which exhibit a vivid color and a dull fluorescent color. Further, according to the method for producing a color material for a cosmetic according to the present invention, color stability can be improved, and a color material for a cosmetic material which is not dimmable can be produced by a simple method. [Embodiment] (Best Mode of the Invention) Hereinafter, the best mode of the invention will be described. (Color material for cosmetics) The color material for cosmetics of the present invention contains a polyamine powder having a weight average molecular weight of 10,000 Å and a volume average particle diameter of 〇. 1 to 20 quot; By. The polyamide powder is preferably a powder used in the color material for cosmetics of the present invention. Nylon can be given, for example, resistance to β-human 1. resistance, kiss 46, nylon-6, 12 copolymer nylon-11, nylon-12, etc., 1 middle Ί 0 /, b 乂 nylon -12 , nylon-6, nylon 12 total bin is better. Nylon SP-100 is widely used, for example: Nylon SP-500 (manufactured by Tora Co., Ltd., particle size is 1〇 or less, 珅 丄 ^ ^ ^ 1 η spherical powder), NylonSP-HKTora, 司司制, particle size 10/zm, globular sir, smear 9n, & the end of the know), Nyl〇n SP-20 (T〇ray male J clothing, particle size 20 / zm, spherical powder too) TR -l (manufactured by T〇ray, particle size, nylon _6, for example: Tora) A m 'porous powder), Orgaso 1 319543 7 200829280 1002 D NAT C0S (manufactured by ARKEMA, particle size 2 (^ m, a lumpy powder), etc. The nylon-6,12 copolymer may, for example, be a core of 1 to 1115 Å to make {11[_5(){)() (manufactured by Shinto Fine Co., Ltd., particle size 7//m, Spherical powder) and the like. The molecular weight of each of the above powders is from 10,000 to 10,000. The molecular weight of the polyamine powder used in the color material for cosmetics of the present invention is preferably from 10,000 to 10,000, and preferably from 10,000 to 10,000. Ten thousand to six thousand. If it is more than 100,000, the color rendering of the fresh enamel deteriorates and it does not fluoresce. When the molecular weight is less than 10,000, the crystallinity of the powder as a makeup is insufficient, so that the preparation is difficult. Further, the volume average particle diameter of the polyamide powder is preferably from 〇1 to 2, preferably from 2 to 15 (four). If the volume average particle diameter is 2 〇 #πι, it is not preferable because the use sensitivity is poor. : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : The dye for cosmetics used in the present invention refers to a dye which is used for cosmetics, and is particularly excellent in terms of freshness, and is preferably a hydrazine-soluble dye, and examples thereof include red 218 泸 friends and D. oil
Ctetrachlorotetrabro.on,^^^ , 漠營光素)、撥色2。"虎(二演勞光素)等 218號（四氯四演螢光素）特佳。當使用紅色1 :色 號等水溶性_時，㈣度㈣时也不切^光月色1 此外，本發明之化粧料用色材中所使用 = 料之調配量係相對於聚酿胺粉末而言，以〇 〇1$料用染 為佳，而以0.1至2質量％較佳。 .^質量％ 319543 8 200829280 *分係經由先將染料溶解或分散於 後過濾'而得到。末’且—邊加熱—邊授拌混合 溶劑時，也可在添加聚酿胺粉末後加熱使溶劑揮==之 :二:卜，當製造彩粧化粧料時，亦可將其二 fe胺粉末與染料一扣、、曰人 丄 κ ，、來 色材。 5，而在製造化粧料之製程中調製 (彩粧化粧料、口紅） 本發明之彩粧化㈣係調配上述域料 彩粧化粧料。 〇件HTJ取义 ^隸料可舉例如：口紅、#蜜紅等， 3、/之讀化㈣巾，不論其種類為何皆能適用。特 二^用於口紅’因其須表現鮮懿不暗淡之化粧料用色材 的效果。 關於本發明之彩链化粧料，可預先調製上述化粧料用 色材’然後將其添加至化粧料基材中而調製之，但也可先 將化粧料用染料溶解或分散於油分中，然後添加聚酿胺粉 末並力二、彳4進-步添加—般化輥料中所使用之成分而製 造。在操作性之_點卜 … ”、、上以如同後者在化粧料之製造階段 調‘化极料用色材為佳。 使用於本么曰月之彩粧化粧料之聚醯胺粉末之調配量係 以1 匕輕料總量之〇. 1至3〇質量％為佳，較佳為0. i至20 質量％ ’更佳為〇·；[至1 〇質量％。 此外，本發明之彩粧化粧料中所使用之化粧料用染料 319543 9 200829280 之調配量係以化粧料總量之0. 0003至 土 貝里％為佳，以 0.001至1·0質量％較佳’以0·0；!至〇·5質量％特佳。 在本發明之彩粧化粧料中，除卜、+、 L x 陈上述必須成分外，可依 需要適當調配一般彩粧化粧料中所你田^ 、 叮便用之成分，例如：保 濕劑、抗氧化劑、油性成分、界面活枓_ . _ .t 叫店T生劑、增黏劑、醇類、 粉末成分、水性成分、水、各種皮膚營養劑等。 、 (實施例） 惟’不應因此限 以下，依實施例更具體說明本發明 定解釋本發明之技術性範圍。 (試驗例1) 於顯色試驗及螢光試驗中，使用分子量不同之耐给， 並以下述之配方調製各口紅。顯色試驗係評估照射自=光 時之顯色；螢光試驗係評估照射^燈(黑光)時 (配方、製法） #、 將表i中記載之分子量不同之耐論粉末（平均粒徑10 P左右）5»量％、與紅色218號〇 〇5質量％添加至如表2 所記載之π紅se方中，並加熱至8Gt：、混合後冷卻至。 (顯色評估基準/螢光評估基準） 依照下述評估基準進行各樣品之評估，評估結果如表 1所示。 (方法） 觀察各樣品之紅色顯色狀態。 ◎:顯色強度高 〇：顯色良好 319543 10 200829280 △:略微顯色 X :不顯色 此外，在螢光測試中係評估照射UV燈（黑光）時之顯 色。 (方法） 觀察各樣品之螢光狀態。 ◎:觀察到高強度之螢光 〇：觀察到螢光 △:觀察到少許螢光 X :無法觀察到螢光 [表1 ]Ctetrachlorotetrabro.on, ^^^, Mo Yingguang), dial color 2. "虎(二演劳光素), etc. No. 218 (tetrachlorotetrafluoron) is especially good. When a water-soluble _ such as a red color: color number is used, (four) degrees (four) are not cut, and the light color is also used. In addition, the amount of the material used in the color material for cosmetics of the present invention is relative to the polystyrene powder. In general, it is preferable to use 〇〇1$, and it is preferably 0.1 to 2% by mass. .^质量% 319543 8 200829280 *The fraction is obtained by first dissolving or dispersing the dye in the post-filtration. At the end of the 'and-heating- while mixing the mixed solvent, it can also be heated after the addition of the polystyrene powder to make the solvent == two: Bu, when making makeup cosmetics, it can also be used Powder and dye one button, 曰人丄κ, and color materials. 5, and in the process of manufacturing a cosmetic preparation (cosmetic makeup, lipstick) The makeup of the present invention (4) is formulated with the above-mentioned domain makeup cosmetics. 〇 HT HT HT ^ 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶 隶Specially used for lipsticks, because they have to be used for the performance of fresh materials that are not dim. The color chain cosmetic of the present invention may be prepared by previously preparing the above-mentioned color material for cosmetics and then adding it to a cosmetic base material, but it is also possible to dissolve or disperse the cosmetic with a dye in the oil, and then The addition of the polystyrene powder is carried out in the same manner as in the step of adding the ingredients used in the generalized roll. In the operability of the point ......,, in the same as the latter in the manufacturing stage of the cosmetic material, it is better to use the color material for the use of the material. The blending of the polyamide powder used in this month's makeup cosmetics The amount is preferably 1 to 3 〇 mass%, preferably 0. i to 20 mass% 'more preferably 〇·; [to 1 〇 mass%. Further, the present invention is The amount of the dye 319543 9 200829280 used in the make-up cosmetic is 0. 0003 to the total amount of the cosmetic material, preferably 0.001 to 1.0% by mass, preferably 0. 0;!至〇·5质量% is particularly good. In the makeup cosmetic of the present invention, in addition to the above-mentioned essential components of Bu, +, L x Chen, the general makeup cosmetics can be appropriately blended as needed. Ingredients for use in sputum, such as: moisturizers, antioxidants, oily ingredients, interfacial activity _ . _ .t Shop T-agents, tackifiers, alcohols, powder ingredients, water-based ingredients, water, various skin nutrition Agents, etc., (Examples), but should not be limited to the following, and the present invention will be more specifically described by way of examples. (Experimental Example 1) In the color development test and the fluorescence test, resistances with different molecular weights were used, and each lipstick was prepared in the following formula. The color development test evaluated the color development when irradiated from the light; the fluorescence test When evaluating the irradiation lamp (black light) (formulation, preparation method) #, the resistance powder (the average particle diameter of about 10 P) of the molecular weights described in Table i is 5»% by weight, and the red 218 is 〇〇5 mass%. Add to the π red se square as shown in Table 2, and heat to 8 Gt:, mix and cool to. (Color Evaluation Evaluation/Fluorescence Evaluation Standard) The evaluation of each sample is performed according to the following evaluation criteria. Table 1. The method of observing the red coloration of each sample is observed. Coloration when irradiated with UV light (black light) (Method) The fluorescence state of each sample was observed. ◎: Fluorescence of high intensity was observed: Fluorescence was observed Δ: A little fluorescent X was observed X: Firefly could not be observed Light [Table 1]
平均分子量 顯色 螢光 20, 000 ◎ 〇 45, 000 〇 〇 60, 000 Δ Δ 450, 000 X XAverage molecular weight Color development Fluorescence 20, 000 ◎ 〇 45, 000 〇 〇 60, 000 Δ Δ 450, 000 X X
[表2] 配合量（質量％) 聚乙細电 10 聚異丁烯 20 蘋果酸二異硬脂酯 20 曱基苯基聚矽氧烷 44· 9 生育酚 0. 05 各種耐論粉末 5 紅色218號 0. 05 11 319543 200829280 (試驗例2) 為了進行顏料之研究，調製如表3所示試驗例（2-1) 至（2-6)之各樣品，並測定400至750 nm之吸光度（反射率）。 [表3] 試驗例 (2 -1) (2-2) (2-3) (2 - 4) (2-5) (2-6) 調色基質 90 90 90 90 90 90 耐綸-1 1 5 一 — 一 — 5 紅色218號 0. 1 一 — — 0. 1 一 紅色202號 一 0· 1 — 一 — 一 紅色10 4號 一 一 — 0· 1 — — — — 一 — 0· 1 — 紅色106號 一 — — 一 一 —0· 1 一曱基聚石夕氧燒 ※2 4. 9 9. 9 9· 9 9. 9 9. 9 4. 9 合計 100 100 100 100 100 100 ※1 · Nylon SP-5 00(Toray公司製，粒徑1〇 # m以下，平均分子 量45000，球狀粉末） 表 3 中之紅色 202 號（Lithol Rubine BCA)、紅色 號之（1)(玫瑰紅（phl0Xin))、鐵丹係顏料。又，表3中所 稱之調色基質係指表2中從聚乙烯蠟至生育酚 (tocopherol)之配方。 第1圖係表示各試驗例在400至750nm之光反射率。 圖中二A至F分別表示試驗例（2_υ至（2_6)。如第i圖所 示二=(2 —D在4〇〇至55〇咖之波長範圍中可觀察至^收， 另-方面’與其他色材相較，在_nm附近之波[Table 2] Compounding amount (% by mass) Polyethylene fine 10 Polyisobutylene 20 Diisostearyl malate 20 Nonylphenyl polyoxyalkylene 44· 9 Tocopherol 0. 05 Various resistant powders 5 Red No. 218 0. 05 11 319543 200829280 (Test Example 2) For the study of the pigment, each sample of the test examples (2-1) to (2-6) shown in Table 3 was prepared, and the absorbance at 400 to 750 nm was measured (reflection). rate). [Table 3] Test Example (2 -1) (2-2) (2-3) (2 - 4) (2-5) (2-6) Toner Base 90 90 90 90 90 90 Nylon-1 1 5 一—一—5 Red No. 218 0. 1 One — — 0. 1 One red 202 No. 0·1 — One — One red 10 4 No. — 0· 1 — — — — One — 0· 1 — Red No. 106—一一—0· 1 一曱基聚石夕氧烧*2 4. 9 9. 9 9· 9 9. 9 9. 9 4. 9 Total 100 100 100 100 100 100 *1 · Nylon SP-5 00 (manufactured by Toray, particle size 1〇# m, average molecular weight 45000, globular powder) Red No. 202 (Lithol Rubine BCA), red number (1) (rose red (phl0Xin) in Table 3 )), iron-dan pigment. Further, the toner base referred to in Table 3 means the formulation from polyethylene wax to tocopherol in Table 2. Fig. 1 shows the light reflectance at 400 to 750 nm of each test example. In the figure, two A to F respectively show the test examples (2_υ to (2_6). As shown in the figure i, two = (2 - D can be observed in the wavelength range of 4 〇〇 to 55 〇 coffee, another aspect 'Waves near _nm compared to other color materials
觀察到很強的反射光譜，由此得知可獲得既有色材中戶 U 319543 12 200829280 有之獨特的顯色。 (實施例1) 口紅 以如下述所示之配方調製口紅。 (1)聚乙烯 1· 〇質量 (2)地蝶（ceresin) 12· 0 (3)棕櫚蝶（carnauba wax) 2. 0 (4)三安息香酸季戊四醇酯 20· 〇 (5)蓖麻油 15· 0 (6)葵花油 2· 0 (7) —甲基聚發氧烧 10. 0 (8)耐綸-6(分子量20, 〇〇〇) 10· 〇 (9)紅色218號 0· 1 (10)鐵丹 0· 5 (11)維生素E乙酸酯 適量 (12)生育酚 適量 (13)香料 適量 (14)二癸酸新戊二醇酯 (製法） 剩餘量 將此例中所示之各配方成分加熱至90。〇，攪寺 合、除泡後，填充至口紅容器中，冷卻至 此化粧料在制；止讲於Λ~々 Ο υ Ttn ^ j 丁十在衣k過釭中並無色材凝結 色優良。 問題發生， •混 r紅C 且顯 (實施例2) 口紅 以如下述所示之配方調製口 319543 13 200829280 (1) 微晶蠟 2· 0質量°/〇 (2) 地蠟 13· 0 (3) 聚丁烯 10· 0 (4) 液狀羊毛脂（lanol in) 2. 0 (5) 澳洲胡桃油脂肪酸植物固醇（phytosteryl)酯6· 0 (6) 蘋果酸二異硬脂酯 10.0A strong reflection spectrum was observed, and it was found that the unique color development of the U 319543 12 200829280 in the existing color material can be obtained. (Example 1) Lipstick A lipstick was prepared in a formulation as shown below. (1) Polyethylene 1· 〇 Mass (2) ceesin 12· 0 (3) Carnauba wax 2. 0 (4) Pentaerythritol tribenzoate 20· 〇 (5) Castor oil 15· 0 (6) Sunflower oil 2· 0 (7) —Methyl polyoxygenation 10. 0 (8) Nylon-6 (molecular weight 20, 〇〇〇) 10· 〇 (9) Red 218 No. 0· 1 ( 10) iron oxide 0 · 5 (11) vitamin E acetate amount (12) tocopherol amount (13) the right amount of spices (14) dipentanoic acid neopentyl glycol ester (manufacturing method) The remaining amount shown in this example Each formulation component is heated to 90. 〇, stir the temple, remove the bubble, fill it into the lipstick container, and cool it until the makeup is in the system; stop at Λ~々 Ο υ Ttn ^ j Ding 10 in the clothing k over the 并无 并无 并无 并无 并无 并无 并无 并无 并无 并无 并无 并无 并无 并无 并无 并无 并无 并无 并无The problem occurred, • mixed r red C and obvious (Example 2) Lipstick was formulated as shown below. 319543 13 200829280 (1) Microcrystalline wax 2·0 mass °/〇(2) Ground wax 13· 0 ( 3) Polybutene 10· 0 (4) Liquid lanolin (lanol in) 2. 0 (5) Australian walnut oil fatty acid phytosteryl ester 6· 0 (6) Diisostearyl malate 10.0
(7)二異硬脂酸甘油酯 (8) 氧硬脂酸異硬脂酯 1〇.〇 (9) 甲氧桂皮酸辛酯 5.0 (1 〇 )甲基苯基聚矽氧烷 5.0 (11) 鯊烧（squalane) 1 · 〇 (12) 耐綸-6(分子量 20, 000) 1.0 (13) 硫酸鋇 2 0 (14 )紅色 2 2 3 號 0 05 (15)鐵丹被覆雲母欽 〇1 i (16)生育酚 (17)香料 (18 )三辛酸甘油醋 (製法） 適量 適量 剩餘量 將此例中所示之各配方成分加熱至90°C，攪拌•混 合、除泡後’ i真充至口紅容器中，冷卻至5。。，而得到口 紅此化粧料在製造過程中並無色材凝結之問題發生，而 且顯色優良。 (實施例3) 口紅 14 319543 200829280 以如下述所示之配方調製口紅。 (1) 聚乙烯堪 10.0質量％ (2) 堪地里拉堪（candel i 1 la wax) ο 〇 5· 0 15. 0 (3) 聚丁烯 (4) 三異硬脂酸甘油酯 (5)四-2-乙基己酸季戊四醇酯 15 0 (6 )二聚物二亞麻油酸二（異硬脂/植物固醇）酯1 〇. 〇 (7)磷酸氫鈣 / U · 5 '(8)耐綸-12(分子量 50, 000) 3 〇 (9) 紅色218號 π。 (10) 鐵丹 (11) 黑氧化鐵 (12) 氧化鈦 2· 3 0· 2 適量 剩餘量 (13) 青色1號 (14) 生育驗 ι (15)流動石犧 (製法） 將此例中所示之各配方成分加埶 合、除泡德，檢— …主’攪拌·混 。除泡後，填充至口紅容器+，冷卻至 、 紅。此化粧料在萝迕涡浐由、， ’而付到t 且顯色優良。 疋、、σ之問題發生，| (實施例4)唇蜜 以如下述所示之配方調製唇蜜。 (1)流動石纖 !Q· 〇質量％ 319543 15 200829280(7) Diisostearic acid glyceride (8) Isostearyl oxystearate 1 〇. 〇 (9) Octyl methoxycinnamate 5.0 (1 〇) methyl phenyl polyoxy siloxane 5.0 (11) Shark (squalane) 1 · 〇 (12) nylon-6 (molecular weight 20,000) 1.0 (13) barium sulfate 2 0 (14) red 2 2 3 number 0 05 (15) iron dandelion covered mica cheng 〇 1 i (16) Tocopherol (17) Perfume (18) Tricaprylic glycerin (preparation method) Appropriate amount of residual amount The ingredients of the formula shown in this example are heated to 90 ° C, stirred, mixed, defoamed, and then filled with Cool to 5 in the lipstick container. . And the lipstick is obtained. This cosmetic material has no problem of coloring of the coloring material during the manufacturing process, and the color development is excellent. (Example 3) Lipstick 14 319543 200829280 A lipstick was prepared in a formulation as shown below. (1) Polyethylene is 10.0% by mass (2) Candel i 1 la wax ο 〇5· 0 15. 0 (3) Polybutene (4) Triisostearic acid glyceride (5) Pentaerythritol tetra-2-ethylhexanoate 15 0 (6 ) Dimer dilinoleic acid di(isostearate / phytosterol) ester 1 〇. 〇 (7) calcium hydrogen phosphate / U · 5 '(8 ) nylon-12 (molecular weight 50,000) 3 〇 (9) red 218 π. (10) Iron (11) Black iron oxide (12) Titanium oxide 2· 3 0· 2 Appropriate amount (13) Cyan No. 1 (14) Fertility test (15) Flowing stone sacrifice (preparation method) In this case Each of the ingredients shown in the formula is blended, defoamed, and tested - the main 'stirring and mixing. After defoaming, fill the lipstick container + and cool to red. This cosmetic material is applied to the radish, and is applied to t and has excellent color development. The problem of 疋, σ occurred, | (Example 4) Lip Gloss Lip gloss was prepared in a formulation as shown below. (1) Flowing stone fiber! Q· 〇 mass% 319543 15 200829280
(2)聚異丁烯 (3) 蘋果酸二異硬脂酯 (4) 棕櫚酸糊精 (5) 耐綸-12(分子量5〇, 000) (6) 橘色201號 (7) 鐵丹 (8) 黃色氧化鐵 0.2 (9) 二氧化鈦 0· 6 (10) 紅色 202 號 〇. 1 (11) 生育酚 適量 (12) 香料 適量 (13) 二異硬脂酸甘油酯 剩餘里 (製法） 將此例中所示之各配方成分加熱至9(TC，攪拌·抑 合、除泡後，填充至口紅容器中，冷卻至而得到口紅。 此化粧料在製造過程中並無色材凝結 色優良。 碭發i (實施例5)眼影 項 以如下述所示之配方調製眼影 (1)絹雲母（serici te)(2) Polyisobutylene (3) Diisostearyl malate (4) Palmitic acid dextrin (5) Nylon-12 (molecular weight 5 〇, 000) (6) Orange 201 (7) Titan (8) Yellow iron oxide 0.2 (9) Titanium dioxide 0· 6 (10) Red 202 〇. 1 (11) Tocopherol amount (12) Flavor amount (13) Diisostearic acid glyceride remaining (preparation method) Each of the ingredients shown in the formula is heated to 9 (TC, stirred, restrained, and defoamed, filled into a lipstick container, and cooled to obtain a lipstick. This cosmetic material has no excellent coloring color during the manufacturing process. i (Example 5) Eye shadow item modulates eye shadow in a formulation as shown below (1) seric te
C2)雲母 (3) 聚曱基丙烯酸曱醋 (4) 合成雲母 (5)氧化鈦被覆雲母 16 200829280 (6) 氧化鐵 1· 5 (7) 氮化硼 5· 0 (8 )滑石 剩餘量 (9) 耐綸-6(分子量 20, 000 ) 1 0. 0 (10) 紅色218號 (11) 鯊烷 ： (12) 二甲基聚矽氧烷 ： (13) 單油酸山梨醇酐酯 | (14) 防腐劑 適量 (15) 香料 適量 (製法） 將（1)至（8)之各成分粉碎混合後，在其中加入將（9) 至（13)在80°C加熱混合而成之化粧料用色材，在中皿中成 型而得眼影。此化粧料在製造過程中並無色材凝結之問題 發生，而且顯色優良。 (實施例6) 口紅 以如下述所示之配方調製口紅。 1. 0質量％ 12. 0 2. 0 20. 0 15. 0 2. 0 10. 0 (1) 聚乙烯 (2) 地堪 (3) 棕櫊蝶 (4) 三安息香酸季戊四醇酯 (5) 蓖麻油 (6) 葵花油 (7) 二甲基聚矽氧烷 17 319543 200829280 (8) 对綸-6(分子量20, 000) (9) 紅色218號 (10) 鐵丹 (11) 維生素E乙酸酯 (12) 生育酚 (13) 香料 (14) 二癸酸新戊 二醇酉旨 (製法） 10. ο 0· 1 0· 5 適量 適量 適量 剩餘量 a 一於溶解成分（9)之油分中添加成分（8)，一邊加熱一邊 攪拌此合，過濾而得預先製備之化粧料用色材。將此色材 與剩餘之各配方成分一同加熱至9(rc，攪拌•混合、除泡 後，填充至口紅容器中，冷卻至5。〇而得到口紅。此化粧 料在製造過程中並無色材凝結之問題發生，而且顯色優良。 (實施例7) 口紅 . 以如下述所示之配方調製口紅。 2.0質量％ 13 10 (1) 微晶壞 (2) 地蠟 (3) 聚丁烯 (4) 液狀羊毛脂 (5) 〜：洲胡桃油脂肪酸植物固醇酯 10 10 10. 5· (6) 蘋果酸二異硬脂酯 (Ό二異硬脂酸甘油酯 (8)羥基硬脂酸異硬脂酯 、9)曱氧桂皮酸辛酯 319543 18 200829280 (10)甲苯基聚矽氧烷 5. 0 (11)鯊烷 1.0 (12)耐綸-6(分子量20, 〇〇〇) 1. 0 (13)硫酸鋇 2. 0 (14)紅色223號 0. 05 (15)鐵丹被覆雲母鈦 0· 1 (16)生育酚 適量 (17)香料 適量 (18)三辛酸甘油酯 剩餘量 (製法） 於溶解成分（14)之油分中添加成分（12)，一面加熱一 面攪拌混合，過濾而得預先製備之化粧料用色材。將此色 材與剩餘之各配方成分一同加熱至9(rc，攪拌•混合、除 泡後，填充至口紅容器中，冷卻至5。〇而得到口紅。此化 l 桩料在製造過程中並無色材凝結之問題發生，而且顯^ 良。 、炎 (實施例8)唇蜜 以如下述所示之配方調製唇蜜。 10· 0質量％ 10· 0 10. 0 10· 0 (1) 流動石蠟 (2) 聚異丁烯 (3) 蘋果酸二異硬脂酯 (4) 標搁酸糊精 (5) 耐綸-12(分子量50, 0〇〇) (6) 橘色201號 319543 19 200829280 (7 )鐵丹 (8) 黃色氧化鐵 (9) 一乳化欽 (10) 紅色202號 適量 適量 剩餘量 (11) 生育紛 (12) 香料 (13) 二異硬脂酸甘油酯 (製法） 於溶解成分（6)、（10)之油分中添加成分（5)，一面力 熱-面混合，韻而得預先製備之化_用色=。: 此色材與剩餘之各配方成分一同加熱至9〇。〇,攪拌·、θ、 合、除泡後，填充至口紅容器中，冷卻至5。〇而^到口: 此化粧料在製造過程中並無色材凝結之問題發生，而且 色優良。 、 實施例1至8所得之任一種彩粧化粧料皆呈現鮮豔不 ^ 暗淡之色彩。 【圖式簡單說明】 第1圖表示試驗例2在400至750nm之光反射率與波 長之關係。 319543 20C2) Mica (3) Polydecyl acrylate vinegar (4) Synthetic mica (5) Titanium oxide coated mica 16 200829280 (6) Iron oxide 1· 5 (7) Boron nitride 5· 0 (8) Residual amount of talc ( 9) Nylon-6 (molecular weight 20, 000) 1 0. 0 (10) Red 218 (11) Squalane: (12) Dimethyl polyoxane: (13) Sorbitan monooleate | (14) Appropriate amount of preservative (15) Proper amount of flavor (preparation method) After pulverizing and mixing the components of (1) to (8), adding the makeup obtained by heating (9) to (13) at 80 °C The material is colored in a medium dish and formed into an eye shadow. This cosmetic material has no problem of coloring of the coloring material during the manufacturing process, and the color development is excellent. (Example 6) Lipstick A lipstick was prepared in a formulation as shown below. 1. 0% by mass 12. 0 2. 0 20. 0 15. 0 2. 0 10. 0 (1) Polyethylene (2) Ground (3) Brown butterfly (4) Pentaerythritol tribenzoate (5) Castor oil (6) Sunflower oil (7) Dimethyl polyoxane 17 319543 200829280 (8) Poly-6 (molecular weight 20,000) (9) Red 218 (10) Iron (11) Vitamin E B Acid ester (12) Tocopherol (13) Perfume (14) Didecanoic acid neopentyl glycol (method) 10. ο 0· 1 0· 5 Appropriate amount of the right amount of a residue in the dissolved component (9) The component (8) is added thereto, and the mixture is stirred while heating, and filtered to obtain a color material for a cosmetic prepared in advance. Heat this color material together with the remaining ingredients to 9 (rc, stir, mix, defoam, fill into the lipstick container, and cool to 5. 〇 to get a lipstick. This cosmetic has no color material in the manufacturing process. The problem of coagulation occurred and the color development was excellent. (Example 7) Lipstick. Lipstick was prepared in a formulation as shown below. 2.0% by mass 13 10 (1) Microcrystalline (2) Ground wax (3) Polybutene ( 4) Liquid lanolin (5) ~: Chau walnut oil fatty acid phytosterol ester 10 10 10. 5· (6) Diisostearyl malate (glycerol diisostearate (8) hydroxy stearate Isostearyl acid, 9) octyl oxonium citrate 319543 18 200829280 (10) tolyl polyoxyalkylene 5. 0 (11) squalane 1.0 (12) nylon-6 (molecular weight 20, 〇〇〇) 1 0 (13) barium sulfate 2. 0 (14) red 223 0. 05 (15) iron oxide coated mica titanium 0 · 1 (16) tocopherol amount (17) the right amount of (18) tricaprylin residue (Production Method) The component (12) is added to the oil component of the dissolved component (14), and the mixture is stirred while being heated, and filtered to obtain a color material for a cosmetic prepared in advance. The ingredients are heated together to 9 (rc, stirred, mixed, defoamed, filled into a lipstick container, cooled to 5. 〇 and a lipstick is obtained. This pile of l material does not have the problem of color material condensation during the manufacturing process, and良 良 良 良 良 良 良 良 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 Diisostearyl malate (4) Standard acid dextrins (5) Nylon-12 (molecular weight 50, 0〇〇) (6) Orange 201 319543 19 200829280 (7) Titan (8) Yellow Iron Oxide (9) Emulsified Chin (10) Red No. 202 Appropriate amount Residual amount (11) Fertility (12) Perfume (13) Diisostearic acid glyceride (preparation method) In dissolved components (6), (10) The component (5) is added to the oil component, and the surface is heated to the surface to be mixed, and the rhyme is prepared in advance. _Color =:: This color material is heated to 9 一 together with each of the remaining components. 〇, stirring·, θ After filling, defoaming, filling into the lipstick container, cooling to 5. 〇 and ^ to the mouth: This cosmetic material does not have the problem of color material condensation during the manufacturing process, and the color is excellent. All of the makeup cosmetics obtained in Examples 1 to 8 exhibited vivid colors which were not dim. [Simplified description of the drawings] Fig. 1 shows the relationship between the light reflectance and the wavelength of the test example 2 at 400 to 750 nm. 319543 20