TW200825145A - Metal containing polymer coating compositions and processes thereof and uses thereof - Google Patents

Abstract

A metal containing polymer coating compositions comprise at least a compound wherein: n=0-4;M=Sc, Y, Zn, Cd, Sn, Pb, Sb, Bi or Se; Xn=Cl-, Br-, I-, CO3(-2), OH-, RCOO- (R=alkyl chain C1 to C24), ArCOO- (Ar=aromatic 5 or 6 member ring), diketonate- (acetylacetonate-, benzoylacetonate-); the coating composition has high optical transmission (through light transmission 88% to 98%) and high refractive index (nD 1.55-1.70).

Description

200825145 IX. Description of the Invention: [Technical Field] The present invention relates to a coating composition for a photopolymer having a high refractive index and a high light transmittance and comprising a metal or an acrylate group, the composition being used for coating In a variety of _polymerization-free, such as polyethylene terephthalate H (pET), polycarbonate (PC) and diacetate (TAC), etc., and then cured by electromagnetic wave radiation to produce - cure coating, as produced An application of an optical film having a specific table structure. The optical film of this form is applied to, for example, a liquid crystal display panel (LCD), a brightness enhancement film (10) having a specific surface structure (Fs), and a diffusion film having a specific surface structure. Other applications of the coating layer include the fabrication of other forms of optical film, such as reflective films for road markings and holographic films for packaging and trademark security. [Prior Art] Due to the application of a brightness enhancement film (10) Fs) containing a specific surface structure, a diffusion film, and an optical film for a road marking, a high refractive index and a high light transmittance are required. Material, due to continued improvement of the wire of the punch. & Although it is possible to produce a composition having a high refractive index, as disclosed in = deleting 01_31, it is only necessary to disperse the dispersant powder of her woven, such as a metal oxide coating such as secret titanium on the surface of the polymeric coating layer. However, during the curing process +, this combination was transferred to a polymer-free 200825145 substrate. Such a (4) has a high rate of thorny, but is not suitable as a diffusion surface structure for fabricating a luminescent film scale as above depending on the liquid crystal display panel, since the coating layer contains a opaque dispersing agent fixed therein. , so that its light transmittance is low. Some prior art, such as the composition disclosed in U.S. Patent No. US20030021566, is a liquid, single-phase, homogeneous coating layer prior to polymerization, • after polymerization, one or more components are trapped like a dispersant. In the coating layer. The reason is that the compound of the coating layer does not have the function of the coating, and therefore, the coated towel which is turned and shouted in the visualized and hard buck is trapped in the polymer substrate, and is only incorporated into the polymerization like a dispersing agent. In the substrate. The result is an increase in the deficiencies (4), the reduction of the light rate and the riding of the silk, resulting in opacity. The coating layer of this form cannot be used as a brightness enhancing film, because the use of the coating layer will actually reduce the brightness of the brightness enhancing film, and the brightness enhancement will make the surface layer have a clear However, it is necessary to have a high light transmittance.

Optical films, such as brightness enhancement films, are used in LCD backlight modules, involving unidirectional or .P geometry behavior, which are used to make the surface of the enamel _ from the surface structure of the optical film and the refractive index u of the layers in the middle, "2 , "3, ~.........M was changed. Through theoretical considerations, in various applications of optical films, the performance of the film is based on (4) the difference in refractive index between the layers is small ~ small and unique, for example, the greater the difference, the better the performance. In the application of the optical film 7 200825145, light enters from the air - such as the plastic substrate layer of PET and TAC. The light then enters from this layer - a hard coating layer that may have a surface structure. The refractive index of the empty PET and commercial PET—the fixed number depends on its own material properties. The film designer can normally choose the optical function of the brightness enhancement film in the LCD industry to produce a coating material with a higher recording density and an increasingly higher light transmittance, and then bonded to the polymer base. Materials such as m, PC and TAC to improve the function required to achieve the product, such as the spectral structure of the brightness enhancing film, are still required to have a coating layer with a higher refractive index and light transmittance. The refractive index of a hard polymer coating material is related to its optical density, generally in terms of the ratio of the silk. The bigger the face, the greater the rate of women, the closer the optical density is. #面断的路(四)Qing is a layer of skillful 'such as ... in "2, the path of the light is called the wavelength of the light, and its light is measured by the source of light, and the length of the light is 589 microns. By. The formula for obtaining the refractive index in the D lamp is expressed as follows: nD = Sin 0 丨 / sin 02 The resin before the coating is set. The refractive index of the coating composition is selected to have a molecular structure of 200825145. The per-resin component has a unique refractive index. The refractive index can be obtained by calculation of the Lorenz-Lorentz formula described below, and the refractive index of the coatable composition can be theoretically modeled without actual measurement. The formula for L〇renz_L〇rentz is as follows: iu-l= {1+2 [R] / V} / {1-2 [R] / v} where R is the refractive index of the molecule and V is the volume of the molecule. • The 9-sub-refractive value determines the molecular fold. Although the refractive index of all molecules can be increased by the tree (4). From the above formula, it can be seen that when the refractive index of the molecule is increased, the refractive index is increased, and when the volume of the molecule is increased, the refractive index is lowered. In this way, the resin composition transmittance can be patterned and designed; and so on, the refractive index of all hard coating compositions can be patterned and designed. Therefore, a molecule having a large molecular refractive index and a small product is required for designing a coating composition having a large refractive index. _ 彳 Calculate the sum of the refraction values of the traits and the degree of binding to obtain the refracting value of the numerator. Calculating the refractive index in the Lorenz-Lorentz formula ignores the side of the -value versus refractive index in the molecular refraction value. Actual tests and observations by Katritzky et al., and through testing and measuring 95 materials, it was found that at a wavelength of 589 3 microns, there are five kinds of refractive index n with determinants. The five determinants are: HUM0-LUM0 energy level, molecular heat of the constituent, maximum repulsive force of the c-H bond of the molecule, partial negative surface area, and number of F (fluorine) atoms. The energy level of HUM0-LUM0 is related to the polarizability of the atom, the maximum of the c-H bond of the molecule. 200825145 Repulsive force and mixed money, part of the surface area is related to the distribution of electrons of molecules or monomers. The number of 'F(fluorine) atoms can be Actual tests and observations of materials containing low refractive index of f(8) atoms were calculated. The position of the net of the molecular towel atom is different from the position of the atom and the surrounding nature of the atom. The total relationship exists, but there are many differences that are pointed out as differences between the entire molecular structure. The same elements do not always have the same atomic refraction value, and the difference is caused by the infiltration of the element's bound nature. Xuanqing's rate system is used to study the seams and obtain the thief, or to obtain the molecular difference between the identified related compositions. In the present invention, information on the refractive index of atoms has been collected and applied. In consideration of _ son and molecular _ _ consideration, we confirm the combination of the form of the financial network of the age of the molecule 'such as the third periodic table of the elements of the period of the Cheng and Ji, the second η zinc, cadmium, tin and lead in the 14th The selenium in the lanthanum, cerium, or group 16 of Group 15 will result in a polymer having a higher optical density and enhancing the 2' rate as long as the metal ion does not induce any color, and the metal ion is polymerized by the knot. The substrate is in the form of a network, and it is simply a matter of reading the color of the light. Of course, it is a transition metal characteristic, which is detrimental to the penetration of the Γ7, so we _ non-transition or false non-transition metal. Moreover, metals are not used because transition metals have a variety of stable oxidation modes, resulting in activities that often exhibit catalysis. 200825145 Through the knowing technology (such as the world's wisdom and wealth organization's open patent _9 ugly 5 to reveal tf), we can see that there is cross-linking 四 (four), including oxygen yuan Ke single financial polymerization (10) material, code · high with Qing The rate is attributed to the fact that the oxygen atoms have a souther atomic refraction value. Coatings containing such materials have been disclosed. • For the same reason, polymer materials containing sulfur also have high refractive index. It has been reported (as disclosed in the patent view of the United States _1) that the "having the same refractive index" of the sulfur polymerization is proportional to the mass of the sulfur and the molecular weight of the preliminary polymer. It is used to make polymer materials with high refractive index (such as the US Patent 2 side and US6184323). However, it has the disadvantage of being difficult to synthesize and has a low synthesis rate. It has a high refractive index and contains methacrylic acid. As a base polymer material, a sub-propylene disulfide ring has also been proposed (for example, Japanese laid-open patent JP 04_16141〇), whose refractive index is 1. 57-1. 61. It has been reported that halogen is used instead of aromatic or An aliphatic monomer can form a polymer material having a high refractive index. For example, U.S. Patent No. 4,721,377, U.S. Patent No. 4,200,,,,,,,,,,,,,,,,,,,,,,,,, Other reports presented by the invention and the specific disclosure of the domain to produce low refractive index polymer materials (such as

The arguments of Three Bond Technical's News Resins for Optics, released on July 1, 2004, contradict each other. It has also been reported that inclusion of gas and 11 200825145 hard polymer materials also leads to a decrease in refractive index. With the exception of bromine, some newspaper owners have pointed out that a monomer with a crosslinked network type containing bromine will give the polymer monomer a relatively high refractive index. For example, Japanese Laid-Open Patent Publication Nos. 59-184210 and 59-193915 disclose brominated bisphenol A type resins for the production of optical lenses. Further, U.S. Patent No. 5,932,626 and U.S. Patent No. 6,359,170, each of which uses a brominated methacrylic acid monomer to produce a polymer material having a high refractive index. It has been reported that nitrogen, fill and sulfur atoms lead to high refractive indices. U.S. Patent No. 2002, 215, 352, which is related to the triazine ring form monomer, especially the 3' dinitrohexene form monomer, can be used to produce a highly refractive, transparent optical resin. Most of the prior art described above is essentially based on organic crosslinked resins and dispersants. U.S. Patent No. US20030021566, Japanese Patent No. 2001049131, and the World Intellectual Property Organization Publication No. WO 2004/074884A1 disclose the use of a metal-containing resin based on the addition of a non-bonded metal compound or a transition metal compound to an ultraviolet curable coating material. However, this example is the addition of a metal compound or a transition metal compound as a dispersing agent, rather than a bonding form in a polymer substrate. However, due to the change of d-d electrons, there are many colors, and although the light transmittance is not lowered, the color is unstable. SUMMARY OF THE INVENTION In order to further improve and propose a new 12 200825145 material having a high refractive index and a high light transmittance, a reflective film for the road marking and a holographic film for use, including a surface-like thinning, The present invention has been made by the expansion. ' + This is the main purpose of providing a metallographic polymer = material 1 has a high refractive index and a high transparency, for the production of optical films such as Zeng Dang and diffusion films with a specific surface structure. The present invention provides a polymer-coated polymer material which can be used to produce an electronic device which requires an optical film having a high refractive index and a high light transmittance. Still another object of the present invention is to provide a method for producing a polymer coating composition comprising a metal, which can be used to produce an optical film which requires a high refractive index and a high light transmittance. The present invention comprises a metal polymer coating composition comprising at least one metal complex, which has a mixed sulfur compound, a sulphur-containing carbon group and a oxy-oxygen group or a county bud. One of the monomers or (four) is integrated into one of the towels. The towel of the metal is from the third shot of the element of the element, and the zinc in the group 12, the tin of the 14th group, the wrong, the first a metal ion of the 15th group, which has a high refractive index and a high light transmittance, and the compound is disintegrated (10) into a metal-containing photopolymer coating, and The cr object 'into* produces an optical film such as a brightness enhancement film or a diffusion film having a specific surface structure. The method for producing a polymer of the present invention, wherein the step comprises obtaining a polymer-coated polymer composition comprising a metal such that it functions as a metal, and the composition is formed into a polymer by 13 200825145. Fuben is a light-transfer, with 8(4) translucent, including a metal fault & object, wherein the metal is selected from the sharp and the third in the group 3 of the periodic table, the zinc, the ore in the group 12 Tin, wrong, metal ions of one of the selenium in the 15th group, or the selenium in the 16th group. The present invention has a brightness-enhancing film having a surface-specific structure, and is composed of the above-mentioned _ metal-containing polymer coating composition. The excavation of the surface-specific work of the present invention includes those produced by the above-described polymer-containing polymer-coated composition. The present invention has the function of having a surface-specific structure, and includes those produced by the above-described polymer-containing polymer-coated composition. The anti-fineness of the filament-converting structure of the present invention includes those of the above-mentioned metal-containing polymer coating composition. The optical device of the present invention comprises an optical film comprising one of the above-mentioned thinning, diffusion film, holographic film and retroreflective film. For other purposes and functions of the present invention, please refer to the drawings and the embodiments, which are described in detail below. [Embodiment] The present invention provides a metal complex in which the metal ion of the complex is a monomer or oligo 200825145 polymer having a co-sulfuryl group and a hydrogen or carboxyl group. It is a stable five- or six-membered ring. The monomer, due to the coordination filaments having the characteristics of the two buds, is a technique known to those skilled in the art, because the composition has high stability and sulfur, oxygen, metal, transition. The metal has a high atomic refractive index and gives the polymer a higher optical density, so that the coating composition can be planned to contain 0. 2-10% by weight of metal ions, completely bonded to the crosslinked network (tetra) structure. Therefore, it is converted into a coating material by electromagnetic wave radiation, and the cloth has a high refractive index of a refractive index of h 57 - h 7 and a high light transmittance of more than 88%. A feature of the present invention is to provide a composition of a liquid phase photopolymer of a fresh phase and a solventless type; a metal complex having a metal complex, a metal ion of the complex, a sulfur-rich carbon group and a hydrogen a monomer or a silky substance of the bud or the bud of the bud, the wire of which is from the scorpion of the third group of the periodic table, the zinc of the group 12, the ore, the group 14 Tin, wrong, metal ions of selenium in lanthanum, cerium, or group 16 of Group 15. The composition of the present invention can be polymerized by external electromagnetic radiation, especially ultraviolet rays. It is produced by the free radical bonding of the reaction between vinyl and vinyl. Such polymerizations are techniques known in the art. The compositions of the present invention are essentially free of solvents. This means that the polymerization will produce a product of a polymer in which there is no residual liquid and a gaseous solvent ejected' and does not include a separable polymer and a liquid solvent.

15 200825145 In general, a polymerizable liquid, such as a monomer or oligomer, can be used as a solvent for other constituents such as metal chelate monomers or oligomers. A preferred embodiment of the composition of the present invention can be regarded as a photopolymerizable composition comprising a compound Ibr of a co-sulfuryl group and a mono-bud ligand of monohydrogenoxy group.

ΜΧη where: η is 〇-4; Μ is 铳, 纪, 锌, tin, tin, wrong, recorded, grade, selenium; Χη is a-, Br-, I-, C03(-2), OH-, RC00_ (R = alkyl chain Cl to C24), ArCOO- (Ar = aromatic five or six-membered ring), diketopyl (ethyl acetaminophen, benzoquinone acetonide). Compound I has a chelate formed by binding metal ions, the lanthanum of the third group of the periodic table of the periodic table, the rhetoric of the group 12, the tin of the group (4), the wrong, and the 15th group. , grade, or 砸 in the 16th family. Such monomers or oligo are formed into a single-phase, homogeneous, copolymerized film having a south-through and a high refractive index when dissolved in the _composition field-ultraviolet light. Compound I' can utilize commercial monomer or oligomer book_31 compound 16 200825145 π

Repair with the Lawesson reagent compound dish by Aldrich

The reaction was obtained. Lawesson reagent is known to those skilled in the art.

Convert the Roche base class to a sulfur group. The sulfur content of Compound I can be controlled by the amount of Lawesson reagent to prepare compound jy

And compound V 17 200825145

Br S SH \/ MXn H2c=ripf-CH2S_^~Br S SH Br, etc. Among the above compounds IV and V: η is 〇-4; Μ is sharp, Ji, 辞, Qian, tin, wrong, recorded, secret, Shixi; Χη is C1-, Br-, I-, C03 (-2 ), OH-, RCO 〇 ~ (r = burning its chain Cl to C24), ArCOO- (Ar = aromatic five or six-membered ring), diterpene (acetyl acetonyl, benzoyl acetonyl).

Another embodiment of the present invention is BR31 'Compound 1 [which can be reacted with a thiol to form a thioacetal derivative, Compound VI

This compound can be used as a chelating compound of bis(hetero). / As the monomer or oligomer of the compound I myj is applied to the optical film, it is a new and preferred embodiment. 18 200825145

The compounds I., IV, V and VI of another embodiment of the present invention can be used to oxidize a carbonyl group to a protecting group using a chemical reaction technique known to those skilled in the art.

More specifically, the invention can be considered to encompass the use of derivatives of synthetic BR31 to develop other oligomers having a di-bud ligand via the reaction of a carbonyl or hydroxide of BR31. In an embodiment of the invention, the metal compound (such as zinc bromide or zinc acetate) is mixed with the monomer of the compound hydrazine, mixed using a silvevsen type mixer, and the rotation rate is 100 rpm (rev/min), and the temperature is 9〇-12 (TC, vacuum pressure 10-15mm Hg (mm mercury column), for a period of 24 hours, to make a metal-containing monomer or oligomer metal complex (compound I, IV-VI) The compound is mixed with a monomer resin to form a metal-containing photopolymer coating composition. The composition comprises 1% to 40% by weight of a metal composition. The second feature of the present invention provides a method for preparing a polymer, The process comprises obtaining a polymerizable component according to the present invention, which is sufficiently affected by external influence to polymerize the component. 19 200825145 The second feature of the present invention also provides a method for producing a process by the method of the present invention. Polymer product. 1° _ The fourth feature of the present invention provides an optical grade film product comprising elemental turbidity f 3 岐 pure, g 12 shot of zinc, brocade, = 14 tin, wrong, In the 15th family of records, M, or 16th The polymer of the present invention is an optical film having a surface-specific structure, such as a prism sheet, a diffusion test guide wire, which has been described in the patent application US Pat. No. 4,452,449. In combination with an optical device or a part of an optical device, such as a display system, a hologram or a reflective system. A metal ion of the present invention incorporated in the composition is preferably used in a concentrated manner, and is not used in a liquid-repellent polymerization combination. Prepolymer. Such metal ions are generally non-transition metals and exhibit the most stable oxidation state in the composition. In addition to the metal-containing monomers and oligomers, other polymerizable liquid compositions of the present invention are preferably A polyepoxide, or more preferably a polyacrylate or a mixture thereof; however, other polymerization systems known to those skilled in the art can be used in the monomers or oligomers of the present invention. Suitable monomers or suitable Samples of the monomer of the oligomer include acrylate, methacrylate, epoxide, styrene, vinyl monomer, methyl styrene and other vinyl monomers A polymerizable liquid, preferably a mixture of polymerizable monomers and oligomers; a suitable monomer to oligomer weight ratio, an oligomer molecular weight of 200825145, an oligo viscosity, The optical (cleanness) and refractive index of the oligomer. The composition is a liquid that is viscous at 7〇〇5(10)〇cps and can be poured but viscous. It can be introduced into electromagnetic radiation to produce polymerization. The ultraviolet light acts with the photoinitiator of the composition of the invention to generate free radicals. The photoinitiator is typically the weight percent of the composition at 〇·M0%. Examples of suitable photoinitiators, but not limited to ketones such as ortho positions Aldehydes (for example, compounds containing ketones and aldehydes), 2, 2-dimethoxy-2-indolyl acetophenone, oxybenzophenone, anthrone, benzophenone, brewing, hydrazine , 丨-carbyl-cyclohexyl phenyl ketone (eg IRGACURE 184 from

Ciba Speciality Chemicals), 2-carbo-2-methyl-1-phenyl-1-propanone such as Dar〇cur 1173 (from Ciba Specialty Chemicals); 2 methyl-1 -(4-decylthiophenyl) ) 1-2 ketone-1-acetone (chemcure-709 from Chembridge International Corporation). The present invention is a radiation curable composition, preferably comprising an oligomer of (mercapto) acrylate monomolecular and (meth) acrylate. Typical polymerizations are initiated by the polymerization of free radicals initiated by electromagnetic radiation, which may involve the polymerization of cations. The cationically polymerized system of the present invention comprises the following composition: a) a monomer, an oligomer or a preliminary polymer capable of undergoing cationic polymerization; usually having at least one epoxide or ethylene in the monomer, oligomer or preliminary polymer a diethyl ether group; b) a cationic initiator capable of generating free radicals upon irradiation with radio wave radiation, 21 200825145 and C) a metal-containing oligomer of the invention. The composition of the polymerizable cation of the present invention comprises an epoxy group, a cyclic ether (such as an alicyclic epoxide group), a cyclic sulfide, a cyclic imine, a lactone, a vinyl ether, and other ethylene having many electrons. a base compound and a compound of an alcohol and an epoxide. Specifically, (5) examples of ionic polymerization compounds, such as: (a) include: bisphenol A type epoxy resin; bisphenol A epoxy acrylate (such as Sartomer CN124); brominated double Phenol a type resin; bisphenol D type epoxy resin, double expectation F type epoxy resin (such as EPLL0Y 8220); epoxy phenolicated bisphenol A epoxy acrylate (such as EPLL0Y 7138); Oxygen resin (such as ERSYS RDGE, Hubron); epoxy resin; epoxy acrylate (such as CN112B70, Sartomer); o-cresol acetal; tridecyl propane glycidyl ether; isoprenol glycidol Ether; 〗 〖6-Hexyl alcohol diglycidyl ether; diphenyl phenyl glycidyl ether; vinyl glycidyl / by slit, epoxy methyl acrylate (such as Sartomer 379); alicyclic epoxy resin (eg UVR-6110, 6105, 6107, 6128, 6000, 6100 and 6216 from Dow). 1 example of a cationic polymerization initiator, a compound which can be used, for example, (b) includes a dipyridyl sulfonium salt (for example, hexafluorokunate, hexafluoroantimonic acid, trifluoromethyl oxalic acid) , a diaryl iodonium salt (for example, tetrafluoroboric acid, six-folded acid, six 22 200825145 fluoroantimonic acid), a ferrocenium salt, and azoisobutyronitrile (AIBN). The composition of the winter invention for use in certain preferred embodiments includes: a) a cationically polymerizable preliminary polymer and a radical polymerizable preliminary polymer; b) a cationic initiator material; c) a radical type Starter material. The cationic photoinitiator used in the preferred embodiment of the present invention can cause the cationically polymerizable preliminary polymer to initiate polymerization on the side of the electromagnetic wave radiation or when it is actually heated. Particularly preferred cationic photopolymerization starting materials for use in the present invention include anthraquinone salts. The present invention will further depend on the following: _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Wherein 'includes a light guide sheet, a first diffusion sheet 2, a second diffusion sheet 22, a rib 3, a reflection film 4, and a fluorescent light source 5. The first diffusion sheet 21, the second diffusion sheet 22, the first ruthenium film 31, and the first 稜鏡32 having a surface-specific structure can be fabricated, as disclosed in U.S. Patent No. 542,449; The producer of the a-coating composition. 23 200825145 The refractive index is measured at 25 degrees Celsius (unless in a different state) using an Abbe refractometer. The viscous system is at 25. (: When using a Brookfield PiOgfammable DV- Π type viscous measuring device, · 3 rotors, speed 100 printed 111 (rpm). The composition and metal used are familiar to the technology and can be obtained from commercial sources. For example, Sartomer 601 (ethoxylated bisphenol a diacrylate) is obtained from Cray Valley. 31 series from Japanese company Q) aiichi Kogyo Seiyaku Co. Limited, Japan). Sartomer CN124 (double plex A epoxy vinegar) is from Cray Valley. Darocur 1173 (2-hydroxy-2-mercapto-1-phenyl-1-propanone) is from Ciba Specialty Chemical. Lanthanum and cerium in Group 3 of the Periodic Table, zinc in Group 12, tin in the 14th group, ruthenium in the Group 14, the surface, or the metal salt of the stone in the ΐβ group From Aldrich. Lawessons reagents are from Aldrich. ACM0 (acryloylmorpholine) is from Rahn. TBBDA (tetrabromobisphenol epoxidized acrylic) from Aldrich. Example 1 This formulation consisted of the following composition in a brown UV-resistant bottle, heated to 7 ° C, agitated, mixed until all solids were dissolved.

Sartomer 601 45% wt (% by weight) CN124 26% wt 24 200825145 ACM0 Ί. 5% wt Darocur 1173 6% wt TBBDA 1. 5% wt Methylstyrene 2% wt Compound I 8% wt Gas coating hybrid prepared in -gold On the ep film, the die has a deep 5G micron groove structure. Then, the PET substrate of the micron-micron (model: Τ0Υ_Μ_ placed above the compound, and gently pressed with a series to make it completely into the concave, then with - υ 骑, (irradiation intensity 46 47 The mW/cm 'wavelength is 300-400 μm, measured by an international photometer.) After exposure for 5 seconds without moving, a transparent UV-curable film having a refractive index of 1.60 is obtained. The coating composition was prepared, as in Example 1, mixed 45 grams

And a refractive index of 1.59 and 1.64, respectively. Sartomer 601, 25 g of CN124, 5 g of methyl styrene, 20 g of compound I and 5 g of Darocurll 73, respectively, the refractive index of the liquid composition and the cured polymer film were 1.59 and 1.64, respectively. Example 3 A coating composition was prepared, as in Example 1, mixing 45 grams of Sartomer 601, 25 grams of CN124, 5 grams of methyl styrene, 20 grams of 25 200825145 compound hydrazine, and 5 grams of hydrazine Darocurll 73. The refractive index of the composition and the cured polymer film were 1.58 and 1.62, respectively. Example 4 A coating composition was prepared, as in Example 1, mixed 45 grams

Sartomer 601, 25 grams of CN124, 5 grams of decyl stupid ethylene, 20 grams of compound hydrazine and 5 grams of Darocurll 73, the liquid composition and cured polymeric film have refractive indices of 1.59 and 1.64, respectively. Example 5 A coating composition was prepared, as in Example 1, mixed 45 grams

Sartomer 601, 25 g of CN124, 5 g of methyl styrene, 20 g of compound hydrazine and 5 g of Darocurll 73, the liquid composition and the cured polymer film have refractive indices of 1.9 and 1,62, respectively. As described above, the present invention is a method in which a metal compound (such as zinc bromide or zinc acetate) is mixed with a monomer of a compound ruthenium to form a metal complex of a metal-containing monomer or oligomer (Compound I, IV-VI), having a high refractive index and high light transmittance, and mixing a bismuth compound with a monomer resin to form a metal-containing photopolymer coating composition, thereby producing an optical film such as a brightness enhancement film or a diffusion film having a specific surface structure membrane. The above description is merely an embodiment that utilizes the technical content of the present invention, and any modifications and variations made by the present invention are subject to the scope of the present invention, and are not limited to those disclosed in the embodiments. . 26 200825145 [Simple description of the diagram] Figure 1 is a schematic diagram of the LCD backlight module. [Main component symbol description] 21 first diffusion sheet 31 first prism film 4 reflection film 1 light guide sheet 22 second diffusion sheet 32 first 稜鏡 5 fluorescent light source

27

Claims (1)

200825145 X. Patent application scope: 1. A metal-containing polymer coating composition comprising at least a metal complex, wherein the metal ion of the complex compound has a co-sulfide carbon group and a hydroxyl group or a combination of a monomer or a silk of a bud ligand, wherein the metal is selected from the group consisting of the sharp and the subordinates of the 3rd group of the 7L prime periodic table, and the words, edits, and Metal ions of Φ in one of the tin, the wrong, the fifteenth in the fifteenth group, the silver, or the litmus in the group 14. . ·-Shenqiao patent dry coffers1 rewarded metal-containing polymer coatings, which are far metal complex compounds I H2C=C—ΓΤ H1 s \/ Br _ MXn where: π is 〇-4; Μ is sharp, 钇, zinc, cadmium, tin, lead, antimony, bismuth, selenium; Χη is α-, Br-, I- , C03(-2), OH-, RC00 I. Brush 〇, 嗣 嗣; Ar = one of the aromatic five or six-membered rings; R = alkyl bond ci to C24 ' One of the bases of propyl group or benzoquinone. 3. For the application of the polymer coating composition containing the metal, 28 200825145 wherein the metal complex compound IV h2c Where: 10η is 0-4; Μ is Zhu, Ji, Zinc, Tin, Tin, Wrong, 锑, Face, Shixi; Χη is CBu, Br-, I-, C03(-2), OH-, RC00 - ArCOO-dione; Ar = one of the aromatic five or six membered rings; R = alkyl chain Cl to C24; the diketo group is one of acetylacetonate or benzoylacetonate. 4. The metal-containing polymer coating composition according to claim 1, wherein the metal complex compound V Br Br H2C=g H~|—CH2S S SH \/ ΜΧη where: η is 0-4; Μ is 铳, I 乙, 锌, 编, tin, 锑, 锑, 丝, 石西; 29 200825145 Xn is Cl -, Br-, Bu, C03 (-2), 〇H_, RC〇〇_, should, diketone; Ar = a five or six-membered ring of the aromatic wire; R = silk bond α to Q24 'two The ketone group is one of the acetylacetone group or the benzoyl propyl g group. 5. If applying for a polymer coating composition containing a metal, the metal complex compound VI Br BrI—CH2〇_H^~Br MXn where: n is 0-4; M is lanthanum, cerium, zinc, cadmium, tin, lead, antimony, bismuth, selenium; Xn is C, Br-, I-, C03(-2), OH-, RC00-, ArCOO-, dimercapto 'Ar = one of the aromatic five or six-membered rings; r = alkyl chain ci to C24; di-based acetylacetonate or One of the phenylhydrazine acetonide bases. 6. The metal-containing polymer coating composition according to claim 1, wherein the metal complex compound VII 200825145 H2e=S*"7^G^TCH2 sx a oh Where: n is 0-4; φ M is 铳·, 纪, 锌, 编, tin, 错, 录, 银, 石石; Χη is a-, Br~, I-, c〇3 (~2), OH-, RCOO-ArCOO-, diketone, Ar = one of the aromatic five or six-membered rings; R = alkyl chain π to C24; the diketone group is acetylacetonate or benzoylacetonate One. 7. A general polymer coating composition comprising a metal, wherein the composition comprises from 1% to 4% by weight of a metal composition. The metal-containing polymer coating composition as described in any one of claims 1 to 6, wherein the monomer or oligomer comprises a liquid acrylate monomer or oligopolymer. 9. The metal-containing polymer coating composition of claim 7, wherein the monomer or oligomer comprises a liquid acrylate monomer or oligopolymer. The metal-containing polymer coating composition according to any one of claims 1 to 6, wherein the monomer or oligomer comprises a liquid ethylene oxide monomer or an oligomer. The metal-containing polymer coating composition of claim 7, wherein the monomer or oligomer comprises a liquid ring-containing ethylenic monomer or oligopolymer. The metal-containing polymer coating composition according to any one of claims 1 to 6, further comprising a dissolved initiator. The metal-containing polymer coating composition of claim 7, further comprising a dissolved initiator. The metal-containing polymer coating composition of claim 8, further comprising a dissolved initiator. The metal-containing polymer coating composition as described in claim 9 further comprising a dissolved initiator. The metal-containing polymer coating composition according to the first aspect of the invention, further comprising a dissolved initiator. • 17 (6) The scope of the patent application includes the metal (iv) molecular coating composition, and the step-by-step includes a dissolved initiator. The metal-containing polymer coating composition according to claim 12, wherein the 5 hai initiator is one of a radical type initiator or a ruthenium cation initiator. 19. The metal-containing polymer coating composition according to the invention of claim No. I3, wherein the ruthenium initiator is a radical type initiator or a cationic initiator 32 200825145 one of them. The metal-containing polymer coating composition as described in claim 14, wherein the initiator is one of a radical type initiator or a cationic initiator. The metal-containing polymer coating composition according to claim 15, wherein the δ hai initiator is one of a radical type initiator or a cationic initiator. The metal-containing polymer coating composition according to Item 16 of the invention, wherein the far-starting agent is one of a radical type initiator or a cationic initiator. Substance J: one of the metal-containing polymer-coated combination basins described in Item 17 of the patent scope of the invention, which is one of a starter-free radical initiator or a cationic initiator. A method for producing a polymer, the method comprising the steps of: obtaining a polymer coating composition comprising the metal according to any one of items 1 to 6, when the core is subjected to the action of 1 magnetic wave radiation. The composition is formed into a polymer. 25 Fan Park No. 7 is a method for collecting a substance, the steps of which include obtaining - such as the patented surface light-emitting m containing a gold sorghum composition, which is subjected to an electricity, _ , a method for producing a polymer, the steps of which include obtaining a metal-containing cerium molecular coating composition as described in claim 8 of 2008. The composition is formed into a polymer when subjected to electromagnetic radiation. 27. A method of making a polymer, the method comprising the step of obtaining a polymer-coated composition comprising a metal as described in claim 9 Subject to an electromagnetic wave In the action of the shot, the composition is formed into a polymer. 28· A method for producing a polymer, the steps of which include obtaining a polymer coating composition comprising a metal as described in item 10 of the target The composition is formed into a polymer when subjected to an electromagnetic wave radiation. 29. A method of producing a polymer, the method comprising the steps of: obtaining a polymer comprising a metal as described in claim 11 When the composition is coated to be subjected to an electromagnetic wave radiation, the composition is formed into a polymer. The method of making a muscle-polymer, the steps of which include obtaining - as described in item 12 of the patent φ range The metal-containing polymer coating composition is subjected to an electromagnetic wave to cause the composition to be polymerized. w A method for producing a polymer, the steps of which include obtaining the patent application scope The metal-containing polymer coating composition according to Item 13 is subjected to an electromagnetic wave to cause the composition to form a polymer. 32 - / - A polymer is produced The method comprises the steps of: obtaining a polymer coating composition comprising a metal as described in the patent application, wherein the composition is formed into a polymer when subjected to an electro-optical action. 34 200825145 参33· A method for producing a polymer, the method comprising the steps of: obtaining a polymer coating composition comprising a metal according to claim 15 of the patent application, which is subjected to electromagnetic radiation to form a polymerization composition 34. A method for producing a polymer, the method comprising the steps of: obtaining a polymer coating composition comprising a metal according to claim 16 of the patent application, subjecting it to an electromagnetic wave radiation, The composition forms a polymer. _ 3 soil method for producing a polymer, the method comprising the steps of: obtaining a polymer coating composition comprising a metal as described in claim 17 of the patent application, subjecting it to electromagnetic radiation When applied, the composition is formed into a polymer. 6. A method of producing a polymer, the method comprising the steps of: obtaining a polymer-coated polymer coating composition as described in claim 18, wherein the composition is subjected to an electromagnetic wave A polymer is formed. 37 — The method for producing a polymer, the method comprising the steps of: obtaining a polymer coating composition comprising a metal as described in claim 19, subject to an electromagnetic wave. The composition is formed into a polymer. 38 a - a method for producing a polymer, the method comprising the steps of: obtaining a polymer coating composition comprising a metal according to the second aspect of the patent field, wherein the electromagnetic coating is subjected to an electromagnetic wave The composition forms a polymer. 39—* A method of making a polymer, the method comprising the steps of obtaining a polymer coating composition comprising a metal as described in claim 21, and subjecting it to a magnetic radiation of 200825145 To make the hybrid lion into a polymer. A method for the production of a polymer, the step of which comprises obtaining a polymer coating composition comprising a metal as described in claim 22, which is subjected to an electromagnetic wave radiation A polymer is formed. A method for producing a polymer, the method comprising the steps of: obtaining a polymer coating composition comprising a metal as described in claim 3, which is subjected to an electromagnetic wave gamma, so that the composition is employed Polymer. 42. The method of producing a polymer according to claim 24, wherein the electromagnetic wave radiation is ultraviolet light. 〃 43 _ •: - an optical film with a light transmission greater than 88%, including a metal complex, check, 'metal is selected from the mirrors of the third periodic table of the periodic table, the battle of the 12th family a metal ion among the tin, the wrong, the lanthanum, the silk, or the code of the group 16 of the cadmium group 14. ★ A brightness enhancing film of the shape II having a surface-specific structure, including a metal-containing polymer coating composition as described in any one of the above claims. By. 45 Scope The first type of expansion of a ship having a surface-specific structure, including the metal-containing polymer coating composition as described in the application of the patent No. 1 to 6 of the article, has a specific form The inclusion of a metal-containing polymer as described in the application of the patent 36 46. _ 200825145 cloth composition fell 1 i 6 item. 47· — species range 1 to 6 producers. A light-reflecting film having a surface-specific structure, comprising the metal-containing polymer coating composition according to any one of the claims of the patent application. The optical film of the item 43. _ 'The optical device comprises a brightness enhancement film having the form of the structure as described in the patent application. 5〇 Surface-type optical device, including the duck-reading system of the surface feature structure as described in the 45th patent of the patent application. The I-type optical device 'includes a brightness-increasing film having a form of structure and structure as described in claim 46 of the patent application. The surface specific device ′ includes the anti-domain system as described in the 47th item of the patent application. 37