TW200817644A - A refrigerant and a refrigeration system - Google Patents

A refrigerant and a refrigeration system Download PDF

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Publication number
TW200817644A
TW200817644A TW96120942A TW96120942A TW200817644A TW 200817644 A TW200817644 A TW 200817644A TW 96120942 A TW96120942 A TW 96120942A TW 96120942 A TW96120942 A TW 96120942A TW 200817644 A TW200817644 A TW 200817644A
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TW
Taiwan
Prior art keywords
cold
coal
cold coal
mixed gas
refrigeration system
Prior art date
Application number
TW96120942A
Other languages
Chinese (zh)
Inventor
Gert Prang Jensen
Original Assignee
Elcold Frysere Hobro Aps
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Publication date
Application filed by Elcold Frysere Hobro Aps filed Critical Elcold Frysere Hobro Aps
Publication of TW200817644A publication Critical patent/TW200817644A/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02Materials undergoing a change of physical state when used
    • C09K5/04Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C09K5/042Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising compounds containing carbon and hydrogen only
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/02Alkenes
    • C07C11/04Ethylene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C9/00Aliphatic saturated hydrocarbons
    • C07C9/02Aliphatic saturated hydrocarbons with one to four carbon atoms
    • C07C9/10Aliphatic saturated hydrocarbons with one to four carbon atoms with four carbon atoms
    • C07C9/12Iso-butane
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B9/00Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
    • F25B9/002Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant
    • F25B9/006Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant the refrigerant containing more than one component
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2400/00General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
    • F25B2400/12Inflammable refrigerants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B40/00Subcoolers, desuperheaters or superheaters

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Devices That Are Associated With Refrigeration Equipment (AREA)
  • Lubricants (AREA)
  • Cooling Or The Like Of Semiconductors Or Solid State Devices (AREA)
  • Separation By Low-Temperature Treatments (AREA)

Abstract

A refrigerant for use in a refrigeration system. The refrigerant comprises a mixed gas of at least three different hydrocarbons, including isobutane (C4H10), ethene (C2H4) and methane (CH4). The mixed gas comprises at least 70% by weight of isobutane (C4H10). Using the refrigerant it is possible to obtain low refrigeration temperatures, e.g. below -79 DEG C, without the need for a cascade refrigeration system, and without the need for applying a hydrofluoride to the refrigerant. Thereby the refrigerant is environment friendly, and energy is conserved during the refrigeration process. Furthermore, a refrigeration system adapted to have the refrigerant filled into the refrigerant path.

Description

200817644 九、發明說明: 【發明所屬之技術領域】 本發明係有關於一種用於一冷凍系統的一種冷煤,特 別是關於一種冷煤,比傳統冷煤對環境更無害,且該冷媒 可提供低冷凍溫度。更甚地,本發明相關於一冷康系統, 其中根據本發明所述的冷煤係可被使用。 【先前技術】 般4知的冷束系統包含一冷束通道,其中可讓_ a 煤在其中流動。在該冷凍通道中,係設置數個組件,—般 為I縮器、冷凝器、擴充器以及蒸發器。該冷;東通道係為又 I 1的也就疋3兒s亥冷煤係封閉於該通道内。該壓縮器 取代為-排平行連接的壓縮器,此為一般的狀況,在冷滚 系統中,有許多冷煤站,舉例來⑨,此種冷滚系統係二般 5又置在超級市場中。 如上所述的冷凍系統,一般的功能如下所述,氣體冷 煤進入該壓縮H而被M縮,接下來該冷煤進人該冷凝器: 部:分至少被冷凝,也就是至少部分的冷煤係為液態當其離 開-亥…疑器日守。然後該冷煤通過一擴充器,舉例來說,以 擴充柵的形式控制在該系統中的冷煤的流動,而該;煤係 被擴充’也就是該冷煤的壓力減少。之後該冷煤進入基笋 器:其中該液狀冷煤便蒸發。因為此為一能量消耗程序: 熱係《境中抽出’藉此’一冷,東現象便在蒸發器的位置 產生。取後’氣體冷煤—再的進入該壓縮器。 6048-8921~PF/Ahddub 6 200817644 在冷珠系統中,如上所述的習知冷媒例如 R404a或R5G7係、可被使用,此種冷煤的缺點為其—般口可 使用在家庭或超市的冷㈣統中,也就是適用於料I約 5度C的冷;東溫度之冷煤或是適用於維持大約…度c 溫度的冷珠樞。 一 在-些應用中,更低的冷束溫度係需要的。此舉例為 醫療應用狀況,例如是館存各種疫苗、血清或組織樣本: 此些產品-般必須被館存在低於_7…的溫度下,更甚 地,此數量級的冷;東溫度時常需要用於食品工冑,舉例來 說,是為了德在運送的過程中,該些被儲存的產品沒有 產生高於上述特別溫度’甚至^該產品從-運送裝置移 動到另'一個。 為了得到較低的冷凍溫度,各種方法係被使用,一種 方法係被稱為串接冷,東系統’其中二或更多的獨立冷象系 統係被使用,第m统冷卻接下來的冷n统的冷煤 適當的溫度等等,#由以一適當的方法選擇該冷煤, -有效的低冷來溫度係最後可被獲得,此方法的缺點為需 要使用兩個或更多的壓縮器,至少一個要用於此串接的每 個步驟中,因此該系統便非常損耗能量。 另外一個方法是所謂的混合氣體冷凍系統,其中使用 系、洗中的冷煤係為各種具有不同沸點的氣體混合,此 去係被使用#此些氣體中之—經歷一相轉換,此不是從 環境中耗損能量就是發送能量到環境中,依據相轉換的種 類而疋,故當此氣體具有最高沸點以蒸發該能量耗損,在 6〇48-8921-PF;Ahddub 200817644 吕亥条發係使用於冷;東該維姓#舰 哀、准持乳體,較佳係直到其開始冷 凝,此可發生在熱轉換器中,盔 τ 為了付到所需的包含兩種烴200817644 IX. Description of the Invention: [Technical Field] The present invention relates to a cold coal for a refrigeration system, and more particularly to a cold coal which is less harmful to the environment than conventional cold coal, and which is provided by the refrigerant Low freezing temperature. More particularly, the invention relates to a cold-war system in which a cold coal system according to the present invention can be used. [Prior Art] A well-known cold beam system includes a cold beam passage in which _ a coal flows. In this freezer channel, several components are provided, such as a reducer, a condenser, an expander, and an evaporator. The cold; the east channel is also I 1 and the 3 s cold coal system is enclosed in the channel. The compressor is replaced by a parallel-connected compressor. This is a general situation. In the cold-rolling system, there are many cold coal stations. For example, the cold rolling system is two in the supermarket. . The refrigeration system as described above, the general function is as follows, the gas cold coal enters the compression H and is contracted by M, and then the cold coal enters the condenser: part: at least condensed, that is, at least partially cold The coal system is in a liquid state when it leaves - Hai... The cold coal is then passed through an expander, for example, to control the flow of cold coal in the system in the form of a expansion grid, and the coal system is expanded', i.e., the pressure of the cold coal is reduced. The cold coal then enters the base: where the liquid cold coal evaporates. Because this is an energy consuming program: the heat system "extracts in the environment" to take a cold, the east phenomenon is generated at the position of the evaporator. Take the 'gas cold coal' - and then enter the compressor. 6048-8921~PF/Ahddub 6 200817644 In the cold bead system, a conventional refrigerant such as R404a or R5G7, as described above, can be used. The disadvantage of such a cold coal is that it can be used in a home or supermarket. In the cold (four) system, that is, it is suitable for the cold of material I about 5 degrees C; the cold coal of the east temperature or the cold bead of the temperature suitable for maintaining the temperature of about ... degrees c. In some applications, a lower cold beam temperature is required. This example is the status of a medical application, such as a library of various vaccines, serum or tissue samples: these products must generally be exposed to temperatures below _7..., and more often, this order of magnitude cold; For food processing, for example, in the process of transportation, the stored products do not produce higher than the above-mentioned special temperature 'even the product moves from the - transport device to the other one. In order to obtain a lower freezing temperature, various methods are used. One method is called tandem cooling, and the east system 'two or more of the independent cold image systems are used, and the mth system cools the next cold. The appropriate temperature of the cold coal, etc., # select the cold coal by an appropriate method, - an effective low cold temperature system can finally be obtained, the disadvantage of this method is the need to use two or more compressors At least one is to be used in each step of this series connection, so the system is very energy intensive. Another method is a so-called mixed gas refrigeration system in which a system of used, washed cold coal is mixed with various gases having different boiling points, which is used in the gas - undergoing a phase transition, which is not from The energy consumed in the environment is to send energy to the environment, depending on the type of phase transition, so when the gas has the highest boiling point to evaporate the energy loss, at 6〇48-8921-PF; Ahddub 200817644 Luhai strip is used in Cold; East.com surname# ship sorrow, quasi-holding milk, preferably until it begins to condense, this can happen in the heat exchanger, the helmet τ in order to pay for the required two hydrocarbons

類以及一氫氟化物(hydrof 11]Πτί L uuoride,HFC)之混合氣體冷煤 在之前可使用,此混合翁舻、人、时n 匕。巩體冷煤的缺點為HFX氣體不利於 環境’且該冷煤從環保觀點係不佳的。 【發明内容】 本發明之*目的為提供_ ;人® μ 捉仏々煤用於提供提供低冷凍溫 度,並比習知的冷煤具有對環境較佳的優點。 冷煤係可提供低冷凍溫 本發明之另一目的為提供一 度’並不需要多重壓縮器。 本發明之又-目的為提供—冷滚系統,係可提供低的 冷束溫度’並比習知的冷料、統具有對環境較佳的優點。 根據本發明之第-形態,上述及其他目的,係藉由提 供-用於一冷凍系統的一冷煤來完成,該冷煤包含一混合 氣體,具有三種不同的烴類(hydr〇carb〇n),包含異丁 = (iS〇bUtane ; C4Hl。)、乙烯(ethene ; C2H4)以及、甲: (methane; CH4),其中該混合氣體包含至少7〇%重量百分比 的異丁烷。 本發明的發明人驚訝的發現一混合氣體包含至少三種 不同的烴類(hydrocarbon),可使用為一冷煤用於在一冷凍 站提供非常低的冷凍溫度,4就是不需要串聯的冷凍系 統,藉此,只需要一壓縮器,相較於習知的串聯的冷束系 統可節省能源,更甚的,S為所f的冷煤係藉*三種或更 604 8-8 921-PF;Ahddub 8 200817644 多的煙類獲得’該混合氣體中的一氫氟化物係不需要,根 據地,本發明之冷煤係比習知的冷煤對環境較佳。 故根據本發明之第一形悲之冷煤係以對環境較佳的方 式提供非常低的冷凍溫度,部分係因為可比習知的串聯系 統郎約能源’部分係因為在冷煤中不需要氫氟化物豆a 非常具優勢的。 該混合氣體更可包含複數組成,例如是額外的煙類, 舉例是以不純型態之一或多個烴類或其他種類的氣體或液 體。 該混合氣體包含異丁烷(is〇butane ; d。)、乙稀 (ethene ; C2H4)以及甲烧(methane ; CH4),本發明的發明人 已發現該混合氣體特別適合一冷煤提供非常低的冷凍溫度 而不需要串聯的冷凍系、统。因為異丁烷在大氣壓力下具有 相對高的沸點(约為-16度C)’當乙烯以及甲烧在大氣壓力 下具有相對低的沸點(分別約為-1〇5度c及-18〇度c)。異 丁烧的蒸氣提供冷煤用於乙稀以及甲烧存在的混合氣體 中藉此口亥異丁烧在冷凝時幫助該乙稀以及甲烧。更甚地, 當其I發時’ $乙烯以及f燒之沸點係足夠地不同以提供 相似的貢獻給異丁烧。 是在70%以及80%之間,例如是在 丁院形成該混合氣體的主要部八, 給如上述的烴類,在該混合氣體中 提供所需程度的冷煤之方式選擇, 該混合氣體包含至少7 〇 %重 3:百分比的異丁烧,例如 70%以及75%之間,故異 因為異丁烷提供冷凍源 的異丁烷的量應該以可 藉由選擇相對大百分比 6048-8921-PF/Ahddub 9 200817644 對高程度便可被獲得 的異丁烷’其他烴類的冷凍源的相 此在一些應用中係具有優勢的。 烴類中之一 或等於-40度C, 或等於-16度C。 例如是大於或等於-25度C,例如是大於 擇-地或額外地,烴類中之至少一個可具有在大氣壓 力下之一沸點,其係小於或等於―丨〇〇度c,例如是小於或 等於-120度C ’例如是小於或等於_15〇度c。烴類中之一 個可具有在大氣壓力下之一彿點溫度為_12〇度(:至_1〇〇度 c,而烴類中之另一個可具有一弗點温度為小於或等於_15〇 又C在此例中,在条發%,具有較高沸點的烴類可被使 用為該具有較低沸點的冷柬。 在本發明的最佳實施例中,烴類中之一具有在大氣壓 力下之一沸點溫度大於或等於-40度c,烴類中之二具有在 大氣壓力下之一沸點溫度小於或等於-1〇〇度c,也就是說 烴類中之一具有相對高沸點而烴類中之二具有相對低沸 點,藉此,在蒸發時,具有高沸點的烴類提供冷凍源給其 他兩個如上述的煙類。 擇一地或額外地,烴類中之至少一個可在一氣液態區 域μ度乾圍為—45度C至-130度C,至少一壓力在一壓力 範圍為〇.2bar至35bar,此具有優勢為至少一烴類在一般 操作條件下係為在一氣液態區域,藉此此烴類可提供冷煤 以其他以上述方式給其他烴類。 该混合氣體可包含重量百分比在1%和69%之間的乙 10 6048-8921-PF/Ahddub 200817644 稀,例如是在1 %和5 0 %之間,例如是在5 %和4 0 %之間,例 如是在15%和30%之間,例如是在20%和25%之間。 擇一地或額外地,該混合氣體可包含重量百分比在1 % 和69%之間的甲烷,例如是在1%和50%之間,例如是在2% 和30%之間,例如是在3%和20%之間,例如是在5%和10% 之間。 根據一較佳實施例,該混合氣體包含重量百分比約71% 的異丁烷,重量百分比約24%的乙烯,以及重量百分比約 5%的甲烷,使用此混合氣體可獲得一79度c以下的冷凍溫 度,例如是-85度C以下或更低。如上所述,此種低的冷 凍溫度不需要串接的冷凍系統且不需要增加氳氟化物至冷 煤中。 根據本發明的第二形態’上述及其他目的係藉由提供 下述冷凍系統完成,該冷凍系統包含: 一壓縮器; 一冷凝器; 一熱轉換器; 一擴充器; 其中該壓縮器 '該冷凝器 议崎—政口口、〆 轉換态、該擴充器以 及μ瘵毛态係彼此連接於一冷 不逍道,其中該冷凌季鲚伤 設置有根據上述第一形能所、f |7末糸、、充係 中。 m相冷煤填充於該冷康通道 需要注意的是 6048-8921-PF;Ahddub 相關技術人士 可容易地了 解任何在本 11 200817644 發明中之第-形態之組合之其他的敘述可相同地與本發明 中之第二形態組合,反之亦然。 本毛明之第二形態提供一冷凍系統適用於應用本發明 之第形恶中之冷煤,根據地,根據本發明之第二形態之 ~凍系統適用在低能源耗損提供低冷凍溫度,而不需要將 特殊的需求於該冷;東系統之組件中,係、依據耐久性及堅固 性等等。 、、壓縮器、冷凝器、擴充器以及蒸發器之功能係如上所 述。該冷4系統更包含-熱轉換器,該熱轉換器較佳地係 以下述方式運作’該熱轉換器係被以相對方向流動的冷煤 通過,更詳細的敘述將會與第丨圖在下述說明。 、、該冷柬通道形成-封閉線路如前所述,較佳地,該冷 滚通道係至少大體密封地關閉。 、該冷凍系統可為一冰箱’根據本實施例,該蒸發器提 供冷煤至—冷;東量,其中該所需之產物可被儲存。因為被 提供之冷柬温度係、如上所述非常低,纟中的冷束量之儲存 溫度係對應地低,故該產物係在非常低的溫度被儲存,也 就是適用於儲存藥品,例如是儲存各種疫苗、血清或組織 樣本。同時該冰箱以一方式運作,其係非常類似於一般家 用冰箱之功能,藉此非常容易且簡單被安裝和驅動。 擇地,s亥冷凍系統可為一中央處理器的一冷卻裝 置’《又置在電腦裝置中的中央處理器將經常需要被冷卻, 此冷卻可藉由根據本發明之第二方向之冷束系統提供。在 此例中,該蒸發器應被設置以接近,較佳係以熱傳接觸於 6048-892l-PF;Ahddub 200817644 中央處理器之熱產生部份。 【實施方式】 本發明之實施例係詳細地敘述如下,並佐以圖示解 釋。以下的實施例不會限制本發明的範圍。 第1圖為一冷凍系統1 〇的概要圖,具有壓縮器丨i、 第一冷凝器12、過濾乾燥機13、第二冷凝器14、熱轉換 器15、擴充器16、蒸發器17以及蓄電池18以形成封閉線 路之方式連接。在該封閉線路中,根據本發明之第—形態 之冷煤係被允許流入,該冷凍系統1〇的功能將會參考使= -包含-混合氣體’具有異丁烷、乙烯以及甲烷之冷煤來 說明。 氣態冷煤進入該壓縮器U而被壓縮,該被壓縮冷煤之 後進入第一冷凝器12,其中該冷煤至少部分被冷凝,接下 來該冷煤進入過滤乾燥機13,故濕氣會在該系統中被吸收 而不潔的東西會被收集起來,然後該冷煤進入第二冷凝器 14使得該冷煤接受進一步的冷凝。 因為設置了第二冷凝器14,該冷煤進入該熱轉換器15 而熱便對著冷煤轉換以相對方向流入一分離管,此部分會 更一部地敘述於下,冷煤從熱轉換器15經過擴充器 而該冷煤的壓力便減少,而擴充的冷煤繼續進入蒸發器 蒸發,藉此以提供冷珠源,例如是冷珠量。該被蒸發冷煤 之後進入熱轉換器15,接下來,該冷煤進入蓄電池18,蓄 電池18運作為冷煤缓衝,此設置方式可補償冷煤之大量流 6048-8921-PF;Ahddub 13 200817644 動的文動為冷煤安裝之變動的結果。最後,該冷煤 進入該壓縮器1 1。 …在熱轉換器15中會發生下述狀況,在該冷煤從第二冷 旋器14進入熱轉換器J 5中 7 、的中,異丁烷進行從液態變為氣離 之相轉換,也就是A、胜由 ' %疋冷煤中的異丁烷從環境消耗能量, 提供冷凍源給冷煤的乙烯 ^ 廿^ 烯以及甲烷。在某點,乙烯將達到 彿點,箱*此開私1拉/>u尸 σ接文攸氣恶轉換為液態之相轉換, 是其係開始冷凝,當該冷详捲為、隹^ 也就 田4々媒接文進一步的冷凍時, 將同樣地開始冷凝,該冷 70 17 ^ 7承乂相對方向流動,也就是從茱 ^ 17進入熱轉換器15之冷煤傳 、:The mixed gas cold coal of the class and hydrofluoride (hydrof 11)Πτί L uuoride, HFC) can be used before, this mixes Weng, human, and time n 匕. The disadvantage of the body of cold coal is that HFX gas is not conducive to the environment' and the cold coal is not good from an environmental point of view. SUMMARY OF THE INVENTION The object of the present invention is to provide _; human® μ 仏々 仏々 coal for providing a low freezing temperature and having an environmentally superior advantage over conventional cold coal. Cold coal system can provide low freezing temperatures. Another object of the invention is to provide one degree 'without requiring multiple compressors. Still another object of the present invention is to provide a cold rolling system which provides a low cold beam temperature & which is advantageous over the environment compared to conventional cold materials. According to a first aspect of the invention, the above and other objects are achieved by providing a cold coal for use in a refrigeration system comprising a mixed gas having three different hydrocarbons (hydr〇carb〇n And comprising: isobutane = (iS〇bUtane; C4H1.), ethylene (ethene; C2H4) and a: (methane; CH4), wherein the mixed gas comprises at least 7% by weight of isobutane. The inventors of the present invention have surprisingly discovered that a mixed gas contains at least three different hydrocarbons, which can be used as a cold coal for providing a very low freezing temperature at a freezing station, and 4 is a refrigeration system that does not require a series connection. In this way, only one compressor is needed, which saves energy compared to the conventional series cold beam system. Moreover, S is the cold coal system of the f. * or 604 8-8 921-PF; Ahddub 8 200817644 A large number of cigarettes obtain a 'hydrogen fluoride system in the mixed gas. It is not necessary. According to the above, the cold coal of the present invention is better than the conventional cold coal. Therefore, the first shape of the cold coal according to the present invention provides a very low freezing temperature in a manner that is better for the environment, in part because it is comparable to the conventional tandem system, which is due to the fact that hydrogen is not required in cold coal. Fluoride beans a are very advantageous. The mixed gas may further comprise a plurality of constituents, such as additional flues, for example, one or a plurality of hydrocarbons or other kinds of gases or liquids in an impure form. The mixed gas contains isobutane (d.), ethene (C2H4), and methane (CH4). The inventors of the present invention have found that the mixed gas is particularly suitable for providing a very low cold coal. The freezing temperature does not require a series of freezing systems. Because isobutane has a relatively high boiling point (about -16 ° C) at atmospheric pressure's when ethylene and methyl sulphide have relatively low boiling points at atmospheric pressure (about -1 〇 5 degrees c and -18 分别, respectively). Degree c). The isobutyl burned vapor provides cold coal for use in the mixed gas in the presence of ethylene and methylation, whereby the isobutylate is used to aid in the condensation of the ethylene and the formazan. More specifically, the boiling point of the '$ethylene and f-fired' is sufficiently different when it is produced to provide a similar contribution to the isobutylate. Between 70% and 80%, for example, the main part of the mixed gas is formed in the Dingyuan, and the hydrocarbons as described above are selected in a manner that provides a desired degree of cold coal in the mixed gas, the mixed gas Containing at least 7 〇% by weight of 3:10% isobutane, for example between 70% and 75%, so the amount of isobutane supplied by isobutane to the source of refrigeration should be chosen by a relatively large percentage of 6048-8921 - PF/Ahddub 9 200817644 This is advantageous in some applications for the high level of isobutane 'other hydrocarbons' refrigeration sources that can be obtained. One of the hydrocarbons is equal to -40 degrees C, or equal to -16 degrees C. For example, greater than or equal to -25 degrees C, such as greater than or equal to or additionally, at least one of the hydrocarbons may have a boiling point at atmospheric pressure, which is less than or equal to the degree of c, for example Less than or equal to -120 degrees C' is, for example, less than or equal to _15 degrees c. One of the hydrocarbons may have a temperature of _12 〇 (: to _1 c degrees c at atmospheric pressure, and the other of the hydrocarbons may have a temperature of less than or equal to _15 In this case, a hydrocarbon having a higher boiling point may be used as the colder having a lower boiling point. In a preferred embodiment of the present invention, one of the hydrocarbons has One of the boiling temperatures at atmospheric pressure is greater than or equal to -40 degrees C, and two of the hydrocarbons have a boiling point temperature at atmospheric pressure less than or equal to -1 〇〇 c, that is, one of the hydrocarbons is relatively high. The boiling point and two of the hydrocarbons have a relatively low boiling point, whereby, upon evaporation, the hydrocarbon having a high boiling point provides a source of refrigeration to the other two such as the above-mentioned cigarettes. Alternatively or additionally, at least one of the hydrocarbons One may have a dry circumference of -45 degrees C to -130 degrees C in a gas-liquid region, and at least one pressure in a pressure range of 〇.2bar to 35 bar, which has the advantage that at least one hydrocarbon is under normal operating conditions. In a gas-liquid region, whereby the hydrocarbon can provide cold coal to others in the above manner He is a hydrocarbon. The mixed gas may contain a weight percentage of between 1% and 69% of B 10 6048-8921-PF/Ahddub 200817644, for example between 1% and 50%, for example at 5% and Between 40%, for example between 15% and 30%, for example between 20% and 25%. Alternatively or additionally, the mixed gas may comprise between 1% and 69% by weight. Methane, for example between 1% and 50%, for example between 2% and 30%, for example between 3% and 20%, for example between 5% and 10%. In a preferred embodiment, the mixed gas comprises about 71% by weight of isobutane, about 24% by weight of ethylene, and about 5% by weight of methane, and the mixed gas can be used to obtain a freezing temperature of 79 degrees C or less. For example, it is -85 degrees C or less. As described above, such a low freezing temperature does not require a cascade refrigeration system and does not require the addition of ruthenium fluoride to the cold coal. According to the second aspect of the present invention, Other objects are accomplished by providing a refrigeration system comprising: a compressor; a condenser; a heat exchanger; The expander; wherein the compressor 'the condenser of the sakisaki - the government mouth, the 〆 transition state, the expander and the μ 瘵 态 彼此 彼此 彼此 彼此 彼此 彼此 彼此 彼此 彼此 彼此 彼此 , , , , , , , , , , , , The above-mentioned first shape energy, f |7 terminal, and charging system. The m-phase cold coal is filled in the cold-conducting channel and needs attention to 6048-8921-PF; Ahddub related art can easily understand any in this 11 Further description of the combination of the first aspect of the invention may be combined with the second aspect of the invention, and vice versa. The second aspect of the present invention provides a refrigeration system suitable for use in the application of the invention. Cold coal, according to the second aspect of the present invention, is suitable for providing low freezing temperatures at low energy consumption without requiring special requirements for the cold; in the components of the East system, based on durability and Rugged and so on. The functions of the compressor, condenser, expander and evaporator are as described above. The cold 4 system further includes a heat exchanger that preferably operates in the following manner 'The heat exchanger is passed through cold coal flowing in opposite directions, a more detailed description will be given below Description. The chilled passage forms a closed line as previously described. Preferably, the chilled passage is closed at least substantially in a sealed manner. The refrigeration system can be a refrigerator. According to this embodiment, the evaporator provides cold coal to - cold; the desired product can be stored. Since the cold temperature system provided is very low as described above, the storage temperature of the cold bundle in the crucible is correspondingly low, so the product is stored at a very low temperature, that is, it is suitable for storing medicines, for example Store a variety of vaccine, serum or tissue samples. At the same time, the refrigerator operates in a manner that is very similar to that of a general household refrigerator, thereby being installed and driven very easily and simply. Alternatively, the shai refrigeration system can be a cooling device for a central processor. 'The central processor that is placed in the computer device will often need to be cooled. This cooling can be cooled by the second direction according to the present invention. Provided by the system. In this case, the evaporator should be placed in close proximity, preferably in thermal transfer contact with the 6048-892l-PF; Ahddub 200817644 central heat generating portion of the central processor. [Embodiment] The embodiments of the present invention are described in detail below, and are illustrated by the accompanying drawings. The following examples do not limit the scope of the invention. 1 is a schematic view of a refrigeration system 1 ,, having a compressor 丨i, a first condenser 12, a filter dryer 13, a second condenser 14, a heat exchanger 15, an expander 16, an evaporator 17, and a battery. 18 is connected in such a way as to form a closed line. In the closed circuit, the cold coal system according to the first aspect of the present invention is allowed to flow in, and the function of the refrigeration system 1 将会 will refer to the cold coal having isobutane, ethylene and methane in the =-comprising-mixed gas. To illustrate. The gaseous cold coal enters the compressor U and is compressed. The compressed cold coal then enters the first condenser 12, wherein the cold coal is at least partially condensed, and then the cold coal enters the filter dryer 13, so that moisture will The unabsorbed material in the system is collected and the cold coal enters the second condenser 14 to allow the cold coal to undergo further condensation. Since the second condenser 14 is disposed, the cold coal enters the heat exchanger 15 and the heat is converted to the separation pipe in the opposite direction to the cold coal. This portion will be described more in the following, and the cold coal is converted from heat. The 15 passes through the expander and the pressure of the cold coal is reduced, and the expanded cold coal continues to vaporize into the evaporator, thereby providing a source of cold beads, such as a cold bead. After the evaporated cold coal enters the heat exchanger 15, the cold coal enters the battery 18, and the battery 18 operates as a cold coal buffer. This arrangement compensates for the large flow of cold coal 6048-8921-PF; Ahddub 13 200817644 The dynamic movement is the result of changes in the installation of cold coal. Finally, the cold coal enters the compressor 11. In the heat exchanger 15, the following situation occurs, in which the cold coal enters the heat exchanger J 5 from the second cold-rotator 14, and the isobutane undergoes a phase transition from a liquid to an air-off. That is, A, wins the energy from the environment by the isobutane in the '% 疋 cold coal, provides the chilled coal to the cold coal of ethylene and methene. At a certain point, ethylene will reach the point of the Buddha, and the box will be converted into a liquid phase. In the case of further freezing of the field 4, the condensing will start similarly, and the cold 70 17 ^ 7 will flow in the opposite direction, that is, the cold coal passing from the 茱^ 17 into the heat exchanger 15,

器14朝向擴充考16之太心疋弟一冷嘁 兄益16之方向流動之冷煤較低的溫度,因A 熱係在冷煤之兩個流動之間轉換,其具有的結果 器1 7朝向蓄電池j 8 ‘、、,攸裔叙 乙烯以及# …、煤机幫助冷部以相對方向流動的 、元,故冷卻冷煤幫助溫暖的冷 甲院的冷凝點。 友的冷煤達到乙細以及 第苎係第1圖之冷凍系統1 〇中的冷烊的彳# 圖。P7 t: 士— 丁而々屎的循%之相位 〇卜5表示冷滚系統中的特殊點,此 應的參考數丰滅庐-山七 、便用對 數子被払不出來,在第1圖中,從點!至點2# 換哭15,:!:冷…4朝向擴充器16之方向通過熱轉 下:而r,二清楚的表示此結果為冷煤的溫度係為 ,定義出減少。當冷煤已經完全的進入為液態, 以疋義出-位在液態相以及兩㈣界的曲㈣ 從點2至點3,冷煤係通過擴充器]6,從第 _ 楚了解其結果為溫度下降(因為壓 & /月 ;)田垓能量係維 6048-8921~pp/Ahddub 14 200817644 持在-定值,更甚地,此兩相區域係再次第被進入。 從黑"至點4’該冷煤係通過蒸 煤接受蒸發,從第2圖可清楚了 就疋该冷 ㈡1 β楚了解其結果為該溫度係 在一定值,因為相轉換發生。 θ 、維持 知生4旎置係增加,也就是能旦 從環境消耗,藉此以提供冷凍源。 疋此里 仗點4至點5,該;ρ —々 巧冷媒係攸瘵發器〗7朝向蓄電池 之方向通過熱轉換器1 5,從第2 攸弟Ζ圈可清楚了解其結果為 量和溫度增增加了。 本發明雖以較伟每# /丨1 k ^只知例揭露如上,然其並非用以限定 本發明的範圍,任仿辦M ^ , 订所屬技術領域中具有通常知識者,在 不脫離本發明之精神 w ?甲和乾圍内,當可做些許的更動與潤 飾,因此本發明之仅媒# ' '、ϋ範圍當視後附之申請專利範圍所界 定者為準。 【圖式簡單說明】 弟1圖係根據本發 ^ ^ χ月之一貫施例之一冷柬糸統之概要 U 〇 及弟2圖係為相办 — ^ 仅圖顯示第1圖之冷凍系統中之冷煤 11〜壓縮器; 13〜過濾乾燥機; 15〜熱轉換器; 【主要元件符號說明】 1 〇〜冷凍系統; 12〜第一冷凝器; 14〜第二冷凝器; 6048-8921-PF;Ahddub 15 200817644 16〜擴充器; 17〜蒸發器; 1 8〜蓄電池。 6048-8921-PF;Ahddub 16The 14 is oriented toward the lower temperature of the cold coal flowing in the direction of the expansion of the test, and the A heat is converted between the two flows of the cold coal, and the result is 1 7 Facing the battery j 8 ',,, 攸 叙 乙烯 以及 and #..., the coal machine helps the cold part to flow in the opposite direction, so cooling the cold coal helps the condensation point of the warm cold hospital. The cold coal of the friend reaches the fineness and the cold 烊# of the freezing system 1 in the first figure of the third system. P7 t: Shi - Ding and 々屎 循 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的In the picture, from the point! To point 2# change to cry 15,:! : Cold...4 is turned toward the direction of the expander 16 by heat transfer: and r, two clearly indicates that the result is that the temperature of the cold coal is defined as a decrease. When the cold coal has completely entered the liquid state, the 疋 meaning is in the liquid phase and the two (four) boundaries of the song (four) from point 2 to point 3, the cold coal system passes through the expander]6, from the first _ Chu understand the result is The temperature drops (because of the pressure & / month;) the field energy system dimension 6048-8921~pp/Ahddub 14 200817644 held at - fixed value, more widely, this two-phase area was once again entered. From the black " to the point 4', the cold coal system is subjected to evaporation by steaming, as can be seen from Fig. 2, the cold (2) 1 β Chu knows that the temperature is at a certain value because the phase transition occurs. θ, maintenance of the know-how 4 旎 system is increased, that is, energy can be consumed from the environment, thereby providing a source of refrigeration. In this case, point 4 to point 5, this; ρ - 冷 冷 冷 冷 〗 〗 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 Increased. The present invention has been disclosed above with reference to the above, but it is not intended to limit the scope of the present invention, and it is not necessary to deviate from the general knowledge in the technical field of the present invention. In the spirit of the invention, in the case of a nail and a dry fence, when a certain amount of movement and retouching can be made, the scope of the invention is only defined by the scope of the patent application. [Simple diagram of the schema] The brother 1 is based on the consistent example of this issue. The summary of the cold card system U 〇 and the brother 2 are related to each other - ^ Only the figure shows the freezing system of Figure 1. In the cold coal 11 ~ compressor; 13 ~ filter dryer; 15 ~ heat exchanger; [main component symbol description] 1 〇 ~ refrigeration system; 12 ~ first condenser; 14 ~ second condenser; 6048-8921 -PF; Ahddub 15 200817644 16~ expander; 17~ evaporator; 1 8~ battery. 6048-8921-PF; Ahddub 16

Claims (1)

200817644 十、申請專利範圍: 1 · 一種冷煤,適用於一冷凍系統,該冷煤包含一混合 氣體,具有二種不同的烴類(hydrocarb〇n),包含異丁烷 (isobutane ; C4Hl〇、乙烯(ethene ; C2H4)以及甲烷 (methane; CL)’其中該混合氣體包含至少7〇%重量百分比 的異丁烧。 2·如申請專利範圍第1項所述之冷煤,其中該烴類之 一具有一在大氣壓力下之沸點為大於或等於-40度c。 3·如申請專利範圍第1《2項所述之冷煤,其中該烴 類之一具有一在大氣壓力下之沸點為小於或等於―丨⑽度 〇. 2bar至35bar為一蒸氣狀態。 4 ·如申請專利範圍第1 其中該烴類之至少一個在一 下且在一壓力範圍為 至3項中任一項所述之冷煤, 溫度範圍為-45度C至130度C 5. 如申請專利範圍帛1至4項中任一項所述之冷煤, 其中該混合氣體包含7()%與75%之間重量百分比的異丁烧 6. 如申明專利範圍第i至5項中任一項所述之冷煤, 其中該混合氣體包含1%與69%之間重量百分比的乙烯。 7·如申請專利範圍第1至6項中任一項所述之冷煤, 其中該混合氣體包含1%與69%之間重量百分比的甲烧。 8· —種冷凍系統,包含: 一壓縮器; 一冷凝器; 一熱轉換器; 6048-8921-PF;Ahddub 17 200817644 一擴充器; 一蒸發器; 其中該壓縮器、該冷凝器、該熱轉換器、該擴充器以 及該蒸發器係彼此連接於一冷凍通道;其中該冷涞系統係 設置有上述申請專利範圍第丨至7項中任一項所述之冷煤 填充於該冷凍通道中。 9·如申請專利範圍第8項所述之冷滚系統, Z、中 3 玄 凍通道係至少大體密封地關閉。 7 統,其中 1 〇·如申請專利範圍第8或9項所述之 该冷;東糸統係為一冰箱。 冷凍系 統,其中 11·如申請專利範圍第8或9項所述之 該冷凍系統係為一中央處理器的一冷卻妒置 6048-8921-PF/Ahddub 18200817644 X. Patent application scope: 1 · A cold coal suitable for a refrigeration system containing a mixed gas with two different hydrocarbons (hydrocarb〇n) containing isobutane (C4H1〇, Ethylene (ethene; C2H4) and methane (methane; CL) wherein the mixed gas comprises at least 7% by weight of isobutyl sinter. 2. The chilled coal according to claim 1, wherein the hydrocarbon A cold coal having a boiling point at atmospheric pressure of greater than or equal to -40 degrees C. 3. The cold coal according to claim 1, wherein one of the hydrocarbons has a boiling point at atmospheric pressure. Less than or equal to 丨(10) degrees 〇. 2bar to 35bar is a vapor state. 4 · As claimed in claim 1 wherein at least one of the hydrocarbons is at a point and in a pressure range of any one of 3 The cold coal, the temperature range of -45 degrees C to 130 degrees C. 5. The cold coal according to any one of claims 1 to 4, wherein the mixed gas comprises a weight between 7 ()% and 75% Percentage of isobutanol 6. As stated in paragraphs i to 5 of the scope of the patent The chilled coal according to any one of claims 1 to 6, wherein the mixed gas comprises: 1% and 69% by weight of the chilled coal, wherein the mixed gas comprises 1% and 69% by weight of the tortoise. 8. A refrigeration system comprising: a compressor; a condenser; a heat exchanger; 6048-8921-PF; Ahddub 17 200817644 an expander; Wherein the compressor, the condenser, the heat exchanger, the expander and the evaporator are connected to each other in a freezing passage; wherein the cold heading system is provided with any of the above-mentioned claims A cold coal is filled in the freezing passage. 9. The cold rolling system according to item 8 of the patent application, the Z and the medium 3 frozen channel are closed at least in a substantially sealed manner. 7 System, wherein 1 · The cold as described in claim 8 or 9; the Dongpu system is a refrigerator. The refrigeration system, wherein the refrigeration system is a central treatment as described in claim 8 or 9. a cooling device 6048-8921-PF /Ahddub 18
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