TW200813464A - High-resolution tracking of industrial process materials using trace incorporation of luminescent markers - Google Patents

Abstract

A method of marking an industrial process material including selectively incorporating a luminescent marker onto and/or into the industrial process material in a trace amount insufficient to be optically detectable in the presence of ambient light but sufficient to be non-destructively optically detectable in and/or on the industrial process material in situ in the field or on-site. The trace amount of the luminescent marker is used to track, identify or authenticate the industrial process material for at least one of material control, inventory control, stock control, process control, logistics control, quality control and pollution control.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a high-resolution trace of an industrial process material for a portable reader that incorporates a small amount of luminescent mark and utilizes a Detector. ^

High-resolution tracking of materials used in industrial manufacturing methods is essential for comprehensive material control, inventory control (or inventory control), process control, logistics control,: oral control, and pollution control. These controls ensure that the desired amount and quality of the industrial process can be obtained at the desired location and time required: The materials used and the materials are warranted from acquisition and processing to use and handling. The need for high-resolution tracking of industrial process materials by the public and private sectors has been raised by the fear of explosives and agrochemicals*, food/drug/fuel/feed quality and pollution, and illegal products. 2, mad products and building structures can be # sex, commodity price and environmental pollution. The interest in high-resolution tracking is also driven by consideration of materials and products. The concept of the life cycle is a species, from beginning to end, the energy households: Recognize that materials and products are obtained, processed, manufactured, blended, and transported through raw materials: 2. Use, reuse, maintenance, recycling, treatment, and waste management At the stage of the temple, there are economic and environmental influences. For the comprehensive product 2^ single 'materials' ~ or two manufacturing steps ~ the simple products produced require strong material tracking.夕 6 200813464 : Standardization, no difference, replaceable, exchangeable, can be essentially phased; The industrial system that can be obtained in large quantities or obtained from a variety of sources (4) is not easy to trace. Examples of such materials include both (products) and processed products (such as manufacturing materials, building materials, and industry), the low inherent visual identity of these materials enables high-resolution tracking: the use of luminescent markers to identify or identify high-priced items or Materials, : "糸 Security documents such as passports, banknotes, credit cards, checks, and items such as jewelry, poles, and other sub-items. But 'the previous illuminating marking system needs to be reliably detected in the surrounding light, or when it is profitable. Need to be complex and large-scale experimental spectrometer materials 2 = will: the concentration of luminescent materials used for tracking - generally low-cost business ^ a U production and mass sales of the Weiye process materials are not economic benefits. In addition, the use of 'experimental detection equipment... 丨:: Analytical chemists prepare samples in detail and cannot be used for off-site applications to screen large-scale samples with N-pass $. [Invention] According to the present invention, it is provided that , the method of capturing the industrial process materials for the seedlings, j, optionally adding a micro-money note to the industrial process material and adding thereto, wherein the amount of the luminescent mark is not Sufficient to detect in the surrounding light, it can be detected optically in the field or on-site non-destructive materials and/or on it. Control, 200813464, process control, logistics control, product control and pollution control are used to track, identify or identify the industrial process materials. This 13⁄4 also provides a way to pass through multiple work orders from above. h I Tian Xi's industry “Life cycle of materials ^ and method of nuclear production of the 4th (4th) material, the method comprising the following steps: Hunting selectively adds or adds a trace amount of luminescent label to the industrial process material to impart a unique luminescent reaction; and during the life cycle phase of the industrial process material, in the field by the in situ (four) derived from the industrial process material corresponding to the luminescence reaction of the unique pre-reaction to identify or remember the industry Process material. The present invention further provides a system comprising: a detective dragon, a bristles picker, which is designed to be used in the field or on site to impart industrial process materials and/or to be characterized by , a unique luminescence reaction of a component or structure; a collateral reservoir that collectively stores information about the process materials, products, π-pieces and/or structures and their corresponding unique luminescent reactions;曰令', which allows the processor to compare the luminescence response measured by the portable illuminating reader with the unique luminescence reaction stored in the 杳 杳 and 亥 枓 枓 library to identify or identify the filial structure The present invention also provides a collapsible, portable light-emitting reader that includes a spectrometer precursor and a spectrometer pre-measured. Arranged in an opaque garden having an opening defining a sample area, wherein the spectrometer source and the spectrometer (four) detector are substantially equidistant in the sample area, and the mouth is substantially blocked by the sample, Ding* The opaque panel essentially blocks the ambient light 8 200813464 from the spectrometer detector. [Embodiment]

<Terminal," luminescent label, as used herein, refers to a material or mixture of materials that has been previously non-existing-present glare or phosphorescent (radiating light). For example, according to any method of the present invention, the luminescent material is applied to the process (4) and the force-in-% 'the industrial process material is referred to as the luminescent material, and the mark s: ^" The specific process, the material, and/or the various materials of the process, each of which is added to the industrial process material, each provides a unique luminescent reaction luminescent material. According to the way, the addition of the luminescent mark gives the industrial process material a unique knowledge. Another 77 or other luminescent material comprising the luminescent label can be selected to provide the unique identifiability using its unique luminescent properties, such as its excitation and radiation frequency and intensity. Because & luminescent labels can include - or multiple individual or Luminescent materials having unique luminescent emission and/or excitation characteristics. Examples of luminescent materials that can be used individually or in combination as luminescent labels in the method of the present invention include: a) luminescent organic materials comprising the following: aromatic and hetero-aromatic Family monomers, such as phenyphenanthrene, anthracene, naphthalene, fluorescent yellow, fragrant i, biphenyl, benzoquinone, $, _ morphine, phenanthrene, morphine c, 0 丫〇 喧, 喧 、, 疋 草(primuiene) 'halogenated propionate, quaternary, maleimide, oxazole, rose red, naphthol, benzene, ethidium bromide, ethyl violet, fluorescamine, pentacene, 1,2- Styrene, p-terphenyl, purple, extended triphenyl, ketone and its derivatives, such as 9-mercapto acrylate, 2_naphthyl 9 200813464 acrylic acid, 9-vinyl window, 7r^ Deng I, 7-[4-(trifluoromethyl)coumarin] acrylonitrile imine 2 amine-based phenyl '2-amino D than bite, nitric acid methyl ^ bite, Diethyl decyl benzene, diamino benzene, evolved acetaminophen, methotrexate, 2 phenanthrene, 3 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 14, acridine orange, ^ Ding Huang olamin, azure eight and sputum, two yellow chlorophyll (Caleein blue), fragrant sulphate 6, coumarin 30, coumarin 6H, coumarin 1 〇 2, incense Bean ιι〇, fragrant phloem 153, coumarin 153, coumarin 48〇d, magenta γ, Ivan's H〇echst 33258, azinyl blue, Mithramycine A, Nile Red, Oxonol VI, rose Red B, Red fluorene, Bengal Rose, Unalizarin, Stone κ-T, cresol orange and its derivatives, such as phenol phenol violet perchlorate, 1,9-dimethylmethylene blue, dodecyl acridine orange bromide. Polymers such as fluorescent polymers, like poly (focal Melamine dianhydride-α/ί_3,6_: aminyl acridine), poly((4,4,_hexafluoroisopropylidene)diphthalic anhydride% sulphur), luminescent conjugated polymer, Like polydecyl, polyacetylene, polyphenylene ethynyl and polyphenylene vinyl. Polymers functionalized by luminescent dopants, such as poly(methyl acrylate 9), poly [ (Methyl methacrylate-co-(fluorescent scutellaria-acrylic acid vinegar)], poly[(decyl methacrylate-co- 9-decyl acrylate)]. b) luminescent metal complexes containing: metal complex emitters, such as a wide variety of ligands, gold, palladium, rhodium, iridium, silver, platinum, rhodium, boron, iridium, indium , ruthenium and rare earth metal complexes and derivatives thereof, such as bis(8-hydroxyquinolinate), (2, 2, hydrazinyl) dichloropalladium (II), (2, 2, - Batch of pyridine)dichloroplatinum (II), chlorobis(2-phenylene 10 200813464 pyridyl) ruthenium (III), 8-hydroxyquinoline aluminum salt, tetrakis(8-hydroxyquinolinate) aluminum, three ( Diphenylmethane decane), mono(5-aminomorpholine) ruthenium (ΠΙ), trichlorotri(arsenidine) ruthenium (III). Other examples are provided by the following scientific papers:, Metallized Molecular Materials for 茗奇生物 and its Analogues, 'Chemical Reviews, Volume 249, May 9-10, 2005, Issue 1 and "Photomolecular traps with analytes coordinated to transition metal complexes", Coordination Chemistry Reviews, Vol. 23 3-234, November 1, 2002, pp. 341-350. c) Phosphorescence containing the following: (where the following species represent doped and undoped systems; in other words, such as CaS: Tb, Cl means CaS (undoped), CaS: Tb·doped And CaS: Cl-doped): oxides such as CaO:Eu, CaO:Eu,Na,CaO:Sm, CaO:Tb, Th02:Eu, Th02:Pr, Th02:Tb, Y2〇3:Er, Y203: Eu, Υ203: Ηο, Y203: Tb, La203: Eu, CaTi03: Eu, CaTi03: Pr, SrIn204: Pr, Al, SrY204: Eu, SrTi03: Pr, Al, SrTi03: Pr, Y(P, V) 04: Eu, Y203: Eu, Y2 〇 3: Tb, Y203: Ce, Tb, Y2 〇 2S: Eu, (Y, Gd) 03: Eu, YV04: Dy. Citrate such as Ca5B2Si01(): Eu, Ba2Si04: Ce, Li, Mn, CaMgSi206: Eu, CaMgSi206: Eu/Mn, Ca2MgSi207: Eu/Mn, BaSrMgSi207: Eu, Ba2Li2Si207: Sn, Ba2Li2Si207: Sn, Mn, MgSrBaSi207: Eu, Sr3MgSi208: Eu, Mn, LiCeBa4Si4014: Mn, LiCeSrBa3Si4〇14: Mn. Halosilicates such as LaSi03Cl: Ce, Tb. Scales such as YP04:Ce, Tb, YP〇4:Eu, LaP04:Eu, 11 200813464

Na3Ce(P04)2: Tb. Phytate such as YB03:Eu, LaB03:Eu, Sr03B203:Sm, MgYB04:Eu, CaYB04:Eu, CaLaB04:Eu,LaAlB206:Eu, YA15B4012:Eu, YAl5B4012:Ce,Tb,LaAl3B4012:Eu,

SrB8013: Sm, CaYB〇 803 7: Eu, (Y5Gd) B03: Tb, (Y, Gd) B03: Eu.

Aluminate and gallate such as YA103:Eu, YA103:Sm, YA103Tb, LaA103:Eu,LaA103:Sm, Y4A1209:Eu 'Y3A15012:Eu, CaAl204:Tb, CaTi〇9Al〇!〇3:Bi, CaYA104: Eu, MgCeA1019: Tb, Y3Al5012: Mn 〇 hybrid oxide such as LiIn02:Eu, LiIn02:Sm, LiLa02:Eu, NaY02:Eu, CaTi03:Pr, Mg2Ti04:Mn, YV04:Eu, LaV04:Eu, YAs04:Eu, LaAs04: Eu, Mg8Ge2OuF2: Mn, CaY2Zr06: Eu. Halides and oxyhalides such as CaF2: Ce/Tb, K2SiF6: Mn, YOBriEu, YOCl: Eu, YOF: Eu, YOF: Eu, LaOF: Eu, LaOChEu, (ErCl3) 0 25 (BaCl2) 0 75, LaOBr: Tb, LaOBr: Tm

CaS-type sulfides such as CaS: Pr, Pb, CH, CaS: Tb, CaS: Tb, Cl. Mixed sulfides and oxysulfides such as Y202S: Eu, Gd02S: Tb, Na123K0 42Eu0 12TiSi5013: xH20: Eu. Lamp and cathode ray tube phosphors, including rare earth doped phosphors. An "upconverter" or compound that emits more light than it absorbs, such as NaYF4: Er, Yb, YF3: Er, Yb, YF3: Tm, Yb. d) luminescent properties depending on the particle size of the quantum dot or nanoparticle material, 12 200813464 such as gold and other metal nanoparticles β due to. The cost associated with the above-mentioned luminescent materials at midnight is rarely naturally present in industrial process materials, making it suitable as an option for marking. In addition, the luminescent label is suitably selected from one or more luminescent materials that do not adversely affect physical properties or react with industrial process materials during manufacturing or during storage, shipping, or use. To ensure that the mark remains inert to the industrial process material, the luminescent material comprising the mark can be chemically or Φ physically modified. For example, the luminescent material can be comprised of one or more luminescent materials that are physically encapsulated into the outer skin. The sheath may be composed of a polymer (e.g., methacrylate, polypropylene, polyethylene or polystyrene) or a butterfly (e.g., rocky soil, beeswax, wax, vegetable wax or the like). The method of encapsulating a luminescent material with a polymer and a wax is a known technique. χ For industrial process materials with long life cycles, one or more of the luminescent materials used in the luminescent mark should be selected so that they are not easily degraded over time, so the luminescent material can be tracked for a long time. Examples of long-lived luminescent materials that may be suitable for use as luminescent markings include Ag-activated zinc sulfide, strontium, magnesium fluorogallate (in surface-embedded bottom, exposed to sunlight), benzene, phenanthrene and anthracene (In the body of the block inlaid base, no exposure to sunlight). The luminescent properties of these luminescent materials degrade slowly over time, so that they can be reliably and reproducibly produced over a longer period of time, which substantially or at least partially corresponds to the average life cycle of the relevant industrial process material. . / As used herein, industrial process materials, including but not limited to types of materials: 13 200813464 a) Materials for construction, including: Concrete cement wood treated wood clay and clay products glass / structural plastics and polymerization Plastic and polymer-sealed plastic and polymer composites Ceramics and metal alloys Stone asphalt and asphalt concrete paint anti-corrosion materials, such as paints, structural fabrics b) Including automobiles, locomotives, boats, air transport And materials used in structural and non-structural applications in transports of similar materials, including: rubber, vulcanized rubber and its compounds 200813464 矽 plastic composite epoxy resin ceramic materials and ceramic composite materials such as (but not limited to) brakes Adhesives, Glues, (Vehicle) Adhesive Metals and Metal Alloys Glass Polycarbonate @ Paints, base coats and primers modified products such as abrasive compounds, polishing and sealant antifouling materials and compounds low friction materials and compounds antistatic Compound lubricant cooling material Materials and Compounds Hydraulic Fluid Corrosion Resistant Additives and Compound Fabrics c) Materials used in the manufacture of articles, components, clothing and movables, including: plastics used as substrates for removable media such as, but not limited to, memory cards and electronic wafers Polymers and composites 15 200813464 Plastics and polymers and composites for use as substrates for computers, telephones, batteries and plastic appliances and components, toys Eight" Composites for glass structures Purpose epoxy resin ceramics φ Semiconductor fabrics Materials used in industrial manufacturing of electronic broadcasting and information technology-based articles, including: Ceramic plastic polymer composites, components such as circuit boards, processors and memory chips) Materials for large-scale industrial packaging of articles, components and movable products It includes: Paper plastic fabric f) Materials used in the primary industry and energy industry, including: Blocks used as commercial bulk chemicals and commodity materials 200813464 Propellant high energy materials policy sensitive materials and chemical cyanide precursors Chemical nuclear material aggregate ore and treated and semi-treated Ore _ aluminum nitrate other nitrate pesticides, herbicides and other potentially hazardous materials soil improver detergent minerals and agricultural commodities exchanged on the futures trading floor g) materials used in mixed industrial manufacturing, including: • music and its Precursor food additives and products of cosmetic wines Therefore, it can be seen from the above list that industrial process materials may be a standardized, and/or inconsistent, solid, liquid or gaseous medium with low inherent visual identity. It may include two or more industrial process pine M mixtures. When Heke's manufacturing process is added to the luminescent mark during the manufacturing process, it may be issued 17 200813464

= in the industrial process materials or added to the industrial process materials. When the industrial process material is obtained in a solid form, the luminescent marking process material is added after being manufactured and mixed with it. In this manner, the electro-optic light can be coated on the surface (or a portion thereof) of the industrial process material, and thus is added to the industrial process material, and the luminescent mark can be referred to as "add, enter", In the case of the enamel material, the luminescent mark is added during the process step and is located in the final material. Another example is the addition of the luminescent indicia to the manufacture of industrial process materials in a manner that is permeable to the process materials. Thus, the luminescent mark can be incorporated into and/or added to the industrial process material by physical addition and/or chemical addition. For example, physical addition can include physical capture of luminescent (tetra) molecules, particles or aggregates within a bulk structure or structural composition. Specific examples of physical addition include: seeding of the linear scale spheroidal particles of the wet cement prior to the damp cement; driving the molecular luminescent dye to the wood pore structure at a higher pressure; and suspending or dissolving the luminescent dye In bulk chemicals and preservatives in liquefied form. Chemical addition can include creating an attractive interaction between the luminescent dye molecules, particles or aggregates and the bulk material itself. Specific examples of chemical addition include: adsorption of molecular dyes to yarns and yarns; cationic luminescent dyes form ion pairs with negatively charged vermiculite particles in sand fillers for cement; and aromatic dyes and aromatics The formation of a π_π attraction interaction between the chemical-based blocks 0 In order for the luminescent target to be an effective marker of the method of the invention, it must occur in a detectable amount. The term, micro-, as used herein, refers to an amount that is only present in a small amount or that requires only a small amount to be illuminable in the presence of ambient light. The amount is preferably between per billion and less than the mass of the material of the industrial process. To understand 2, the trace of the luminescent mark will present glory or dish light, but not in the amount of fluorescent or phosphorescent light that would otherwise cause the industrial process material to fluoresce under ambient light. Thus, the addition of the luminescent mark to or on the industrial process material in accordance with the method of the present invention does not provide any visual knowledge of the industrial process material when viewed by the naked eye. The presence of the luminescent mark itself does not affect the normal physical appearance of the industrial process material. The present method includes the addition of a luminescent mark, wherein the luminescent mark can be composed of a plurality of luminescent materials. Preferably, the plurality of luminescent materials form a luminescent mark. The luminescent material is selected such that the luminescent materials produce discontinuities, electronic transitions (radiation spectra) and/or exhibit different intensities in these transitions. The use of f-type luminescent materials can be developed - the intensive coding process is used to join the work chapter _ private! * + l The characteristic radiation produced by the luminescent material on or in the enamel material can identify the material. For example, a coding process involves the addition or inclusion of a mark comprising one or more luminescent materials in a different amount to a sanitary process material, thereby imparting a unique luminescence spectrum to the enamel material. This spectral signature can be extremely noisy and detailed. This unique spectrum itself can be used to identify the industrial process material ^ Within: This spectrum can be stored digitally in such spectra. The paired algorithm is identified in this database. The luminescent material in the spectral fingerprint changes in an almost infinite variety of luminescent markers, which can then be used to mark industrial process materials. ® 19 200813464 Another Fanchang factory flat code process provides N kinds of luminescent materials as luminescent markers (each with discontinuous electronic transitions), each of which has a distinguishable state, so that Μη different states can be defined in a single inch. . In the case where the two states may or may not have the presence of a light-emitting material ==2, the encoding process will therefore be derogable from the bottom or carry code. In the case where the three states may be that the luminescent material exists in two distinguishable intensities or that the luminescent material does not exist = 3, the code will be defined by the bottom 3 code or the triad code. Therefore, a higher order code that is superior to the second order code advantage can be formed because less luminescent material is needed to encode the same amount of information. In another example, the flat code method includes utilizing a luminescent mark that imparts one or the same property to the process material of the process, wherein the unique property can only be observed under extremely specific measurement or pre-measurement conditions. For example, luminescence can be used to emit a characteristic spectrum at very specific temperatures, stresses, concentrations, solvations, vapors, magnets, or similar external physical conditions. In ._ 娆 π to a characteristic spectrum or observed combined spectrum to encode material with - unique identification. Examples of this aspect include, but are not limited to, the use of the following luminescent indicia (1) when and with special polarized or anisotropic light (including benefits, , , , , , , , , Release to the opposite sex, shot %, radiation specific polarization or specifically with light with - or more specific frequencies and connections; each of the two sex lights, and (9) pulse sequence intensity characteristics: The light of the nature. # Release a specific spectrum or intensity of 2 (4) code technology can be used to add or add to the material % material - Auntie unique identification, its 20 200813464 Each of the luminescent indicia can optionally comprise - or a plurality of luminescent materials. The use of these codes in the methods of the present invention provides for the identification of generally unrecognizable industrial process materials. This life cycle tracks the industrial process materials, It is particularly important to monitor the existence of some of the manufacturing process materials, because these industrial process materials are susceptible to improper or illegal disposal at the end of their useful life and may cause environmental pollution. Manufacturers, consumers and law enforcement agencies monitor any illegal trade in industrial process materials or legally replaced poor materials that may affect the manufacturer's warranty and may also provide useful information when establishing arguments against prosecutors. The tracking method will include the steps of identifying the industrial process material, for example, at the manufacturing site, to identify the material, and to determine that the material has not been replaced in transit, during many lifecycle stages. The industrial process material can be processed to manufacture a product. The product can be as standard as the industrial process material, no difference, can be T generation, can be money, can be manufactured in the same form in the same form and can be taken in large quantities. A bulk product or product can be a high-priced item. Therefore, the life Tuesday:: method can include an identification step that includes (iv) measuring a luminescent mark in a bulk product or a high product. The method is preferably used to track the Industrial Process 4 or derived from industrial process materials and bulk products. Moreover, it is understood that the industrial process materials are transformed into one Product, if necessary, the detection of the luminescent mark on the product. Who _ is also made by privately out the 3 hai product sample to be used in the experimental type of inserting plate. The advantage of the specific performance of the portable reader of the present invention means that the illuminating mark can be detected without invasiveness, that is, without the detection of the product in the field in the past. 200813464 The luminescent material has been previously proposed for testing organisms. The method does not use the luminescent mark bioassay to test the industrial process material. The other advantage of the specific performance of the method of the present invention is that the stock sub-control of manufacturing a large volume of industrial process materials per tweezer is made. Process materials are inherently difficult to distinguish between a batch and a batch-batch: the inventory is therefore negative for all the materials produced, and the moonshell hunting is added by a unique luminescence generation.

The code is delivered to different batches of industrial process materials, and the entire inventory control method is implemented. The manufacture of hazardous chemicals is of particular importance when the legal regulations are responsible for all materials produced and provide information about the material's whereabouts at any given time. Another related advantage of the present invention is the process control. For example, as discussed above, when finalizing the inventory control method, it is easier to identify batches of specific industrial process materials that may be defective due to machining errors. The preparation of materials for a particular industrial process consists of a number of process stages, each stage of which: monitoring can be accomplished by adding a different luminescent mark during a particular stage of fabrication. In this way, the characteristics of the final material can be obtained step by step, whereby the efficiency of each stage can be monitored and the process parameters can be changed as necessary. Other more specific applications of the method of the invention are as follows: a) Concrete aspects can be used to help understand the distribution of batches and manufacturers containing large concrete structures that may originate from multiple batches of different manufacturers. Different luminescent materials form the luminescent indicia in different amounts to produce different and complex codes of the above type to distinguish between different batches of concrete. Although only 22 200813464 can be used for long-term dry, original gamma, language, and general 3 months, the concrete can be measured and &&> can be accurately found, limited, and soil batches if necessary. Coagulation of the specifications of the b-ports b) Wood aspects Glossy:: After processing, the wood consisting of one or more luminescent materials is added during the thinning process. Therefore, the wood chips in the so-called house structure can be evaluated at ±::::: to evaluate the success of the == treatment used. In addition, the illuminating indicia can be indicated by two A divisions or wood source woodland or any other desired variable #. ^日述! More detailed information about the wood, its treatment, its source and its operation can be embedded by the coding combination of different luminescent materials produced by the eve. For example, 'To help understand batch, manufacturer or woodland allocations, different and complex combinations of different luminescent dyes can be added to = and treated wood. _ c) Mineral processing Freshly mined ores, such as iron ore, may be marked by spraying with a suitable luminescent marking solution. A small amount of luminescent label can be permeable and/or adhered to the ore to make it clear. The ore can then be placed one by one on a railway train that is transported to the ore processing center. The machining center can be used by other mines. After the railroad has been transported, the ore can be deposited in mines containing ore from all other mines. Although ore from different mountains may have to be processed under slightly different conditions, it may be important to keep track of the source of each ore batch. The ore is therefore tested immediately prior to processing to confirm the presence of the luminescent mark 23 200813464 which identifies its source and its optimum conditions for reinforcement. The processing technique is then optimized for maximum efficiency when processing the ' This method can be modified to provide more detailed information on the ore of the n X special batch, such as the flood season, time and precise location (mine body) in the mine where the _石颂石 is available. This can be achieved by illuminating the ore and specifying the batch of each unique identification address, 1 L χ ^ 4 The first labeling solution is added to the coding combination of the above-mentioned versatile luminescent material. d) fiber aspects

The luminescent indicia comprised of one or more luminescent materials can be selected to be strongly bonded to natural or synthetic fiber 'filaments, yarns and the like. In a specific color: waste, a low amount of luminescence T can be added to the dye used for dyeing yarns, threads and the like. When the material of the (four) material is used, the yarn and the yarn are preferably combined with the luminescent mark. With the portable reader of the present invention, the presence of the luminescent indicia on the fibers, yarns or threads can be determined unambiguously and unambiguously. Alternatively, the synthetic fibers can be made under conditions in which one or more specific luminescent codes can be added to the fibers in whole portions. For example, the synthetic fibers can be (IV) or extracted to contain - or a plurality of providing - or a plurality of luminescent codes for discerning the luminescent material mixture. Such fibers are then spun into yarns or threads and the like. Such yarns or threads may be different from 4 and from time to time in fabrics or materials, where such yarns or threads may be used as, "marking fibers"; in other words, they are used to provide the entire fabric or garment - manufacture, lot or similar If necessary, the above methods can be modified to provide basic or detailed information, including information on the specific batch of fibers, yarns, sources and operational information or information about the wood used, such as dyeing date and time, dye manufacturing.商与染 24 200813464 Lot number. This can be achieved by adding a luminescent mark consisting of a variety of luminescent materials to the dye or the fibers used and specifying the illuminant combination - unique identification address as described above. In this way, for example, the processing conditions, the dye used, the dyeing used, the fiber manufacturing technology, the fiber manufacturer, the fiber handling procedure, and the owner or label holder of the fiber, yarn or thread. Detailed information is incorporated into the material. e) Luminous markings in the food product that can be made up of - or multiple luminescent materials approved for use as food additives Adding to or on food or food or into mass-produced music or medicines. If necessary, 'add a small amount of luminescent mark to provide basic or detailed information about these industrial process materials, including information about the materials, For example, the date and time of manufacture, the batch number, the manufacturing method, the packaging method, and the manufacturer's identification. This can be achieved by specifying a combination of luminescent materials that contain luminescent markers—a unique identification address. (4) The above can be expected from the database. Details. Then the health and safety issues concerning the specific food, drug or drug containing the luminescent mark can be studied using information that is clearly embedded in the material. f) Explosives and their predecessors / because of evil (four) transfer Danger, the material that can be used to make a bomb must be: all manufacturing, distribution, storage, and up to (including) its material, closely monitored when sub-transformed into a form suitable for making bombs. Explosive materials, ranging from military explosives, such as plastic bombs to fertilizers, such as Shi Xiaoyu Ming. The difference between the title - the sample of the explosive or potentially explosive material and the other - the same sample. Because of 25 200813464, the explosion (or potentially explosive) of the same product, which can be stored together, calculated: the quality of the manufacturing must be the same for multiple phases, Therefore, the height may be in the disk; for all kinds of mouth and bottom - calculation, so its unauthorised transfer capacity can be double-calculated or completely incapable of making a sufficiency..., detect it. Or, the purpose of evil exists ^ Do not transfer immediately before H point, so the unrecognizable mouth can be 1: in this case τ, the explosive material that has been transferred =: is not manufactured or treated as unmanufactured. Another type may be the same Imitation ΓΓ 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸 爆炸The possibility is due to the inability to distinguish between any explosive material sample and the next one. Reliable material = material solution (4) in the preparation of materials or pre-explosion =1: no doubt (4) unique identification in all parts of the sample. A luminescent mark is added to the tumbling material as described above by a plurality of illuminating sites, and each luminescent material combination is assigned a unique identification bit that is reversible. In this way, the address that can be distinguished from the lower one is made of an indecent material: intervening = sample b in the manufacture of the explosive or potential explosion = between 'a new bit of each subsequent sample can be provided according to the predetermined address order: The addresses can be generated in the sample using an automated method that automatically adds the samples to the sample according to a predetermined sequence during the manufacturing process. In this way, the sequence of addresses can be exempted from human damage. Inventory can be carried out in any stage of manufacturing, warehousing, distribution or subsequent logistics procedures until 26 200813464 is used or converted into a form that is not suitable for making bombs. Inventory can be finalized Because it includes checking whether all expected addresses exist. Any address that does not exist will immediately and clearly indicate the error, and can directly and clearly indicate the source of the error and investigate it. Therefore, it can avoid or reduce the double counting or leakage during the counting period. In addition, it can also prevent immediate transfer and replacement with imitation materials after manufacture and before the first inventory. By storing and monitoring the address of the site Monitor the distribution chain of each sample and determine if it has been transferred and where it has moved (if transferred). In this way, the weak link in the distribution key can be easily identified 'so the allocation can be broken The integrity of the chain. The application of the above method can be suitably achieved with luminescent indicia comprising one or more luminescent materials, wherein the luminescent materials are highly compatible with explosive materials because they do not alter the primary physical properties of the explosive material or Reacting with these materials. Vacuum stability and friction sensitivity tests can be used to evaluate the suitability of luminescent markers containing one or more luminescent materials to track explosive materials. Φ g) Spray paint is widely used in illegal graffiti creation. Medium, a form of destructive art that applies paint to objects owned by others. In order to prevent the smear and identify the perpetrator of the artistic act, the individual paint cans can be added to one or more of the forensic evidence. Luminescent indicia of different luminescent materials to provide a unique identification address for each of the above types of cans. By keeping the record of the purchaser of the individual aerosol paint canister and using the above-mentioned reader to determine the address of the paint used in the graffiti creation, it is possible to identify the individual paint cans used and the individual purchasers. In this way, it can be monitored. Individual sprays 27 200813464 Paint cans are distributed to monitor, detect and prevent their illegal use. In addition, aerosol paints and lacquers can be used to identify fixed assets such as hawks, tables, chairs, computers and office furniture. At any stage, the source and owner of the asset can be determined by simply measuring the presence of the luminescent mark. h) Metal parts in 4 metal (four) f ” depending on the presence of the alloy substrate 1 = The fact that the existence of the object is 'special' when it is marked. Even if the forensic evidence or the trace amount of each of the luminescent materials contained in the metal alloy may interfere with the necessity of the metal, the overall properties of the metal are affected by its crystal structure and crystal orientation η. Even the addition of a luminescent mark of a puller or a trace amount of one or more luminescent materials to the alloy substrate may interfere with the gold twin structure and adversely affect the properties of the overall metal. For these and other reasons, the addition of such materials to the entire material will pre-treat the alloy substrate or the crystalline nature of the metal or metal alloy! The role, so straightforward, can't be; the light material can be easily added to or added to the metal. 2' When the luminescent material is physically added during the process of forming a molten metal, the luminescent properties of most luminescent materials generally deteriorate. However, the technology that is now commercially available can be used by the particle to == to serve it and its carrier medium specific power and thermal energy system: account. This combination of power and thermal energy is generally (but not necessarily, "produced in industrial thermal and cold spray processes. In these technologies 28 200813464

The particles are effectively accelerated to a high speed and then collided with the metallic gold surface. The collision process is performed by embedding or adhering the particles to the surface of the metal or metal alloy or:: or or at the surface. Such spray processes are currently occurring in commercial environments, and such spray processes are generally formulated to spray materials in gold " instead of electrolysis or to create other protections against oxidation and corrosion. For example, commercially available cold spray (or cold aerated) technology can produce a gas nozzle that is cooler than a thermal spray process such as powder helium, gas arc, plasma arc, and high velocity oxy-fuel spray coatings. Electrical metal coating techniques can be used to embed one or more luminescent indicia into the metal and its surface to impart specific power and thermal energy to the device. Although many luminescent materials are fragile, their properties are generally stress-dependent, such as shear stresses generated during collisions; poor, but many luminescent materials have been found to utilize cold spray techniques to retain light properties without The effect is significantly worse or coated on the metal. Therefore, the cold spray technique is an example suitable for conventional metal coating techniques, which can be used to include one or the other species in a manner that does not significantly adversely affect the crystal structure of the metal or metal alloy or the thermal history of the metal or metal alloy. The luminescent mark of the luminescent material is embedded, smashed, infiltrated, welded or fixed or adhered to the metal. Therefore, the main desired mechanical properties of the metal are not affected by the marking method. Further, after the metal has been produced in a specific industrial process, such a power and thermal bonding method is additionally applied. For example, such marks can be applied to metal aircraft parts after they are manufactured. This can mark parts individually, in batches, or in any other desired format, 29 200813464. DETAILED DESCRIPTION OF THE RING FIG. 1 illustrates a J-system 100 for field-biting tracking of the luminescent mark 1 applied to the industrial process material 7 and/or thereon. When the luminescent mark 1 is emitted by the light of the wavelength F1, the JL dissipates the light of the spectrum 2 containing the unique wavelength fl 1 . In order to detect the luminescent mark added to and/or on the 工 耘 耘 ,

The presence of 1 is to irradiate the eosinophilic material 4 with F1 and collect any light emitted by the material 7 and check to see if the light of the wavelength fi 1 is earlier. A portable light-emitting reader 3 can be used for this task. In the reader 3, when the attached computer 12 is activated, the light is traced back to #4 a 4 , and the light of the wavelength F1 is generated by the special/original 4 . The computer 12 includes at least one processor instruction that handles crying %, (not shown), and can be executed by at least one processor. Depending on the situation, the light source 4 can also generate light of other wavelengths F2, F3, and F4Fm after being commanded by the computer. The light generated by the light source 4 can be collected and transmitted by the optical fiber or fiber optic component bundle 5 as appropriate. The shelling device 3 can be configured by line-of-sight arrangement instead of the fiber collector 5, wherein the line of sight arrangement is transmitted directly from the light source 4 to the material 7 〇 at the front end of the j fiber or fiber bundle 5 (or in line of sight) In the case of the factory; at the hole of the shell, the light of the wavelength F1 leaves and falls on the material 7 containing a small amount of luminescence =. Because only traces (or forensic evidence) of the luminescence 2 can appear in the material 7, it illuminates only very weakly (far less than 2 minutes per minute). Since the ambient light can interfere with the detection method, the use of the reader 3 is excluded. This is done by the elastic cap 30 200813464 to :) the way the hole is taken at the front end of the reading 11 3 to reach the second =: the reader front is shaped into any of the imaginary or particle Ϊ of the ... The table (four) shape and substantially blocks the US spur line from entering the region immediately adjacent the front end 6 of the reader and the material 7. Any resulting light system of the material 7 > job 4 is collected by the front end 隹ΓΓ fiber or fiber optic component bundle 8. These are transmitted to the spectrum m9, wherein the spectrometer 9 comprises suitable photosensitive elements 1 可 which detect the presence of the wavelength fu. The light gamma meter, 9 can be any conventional instrument that can test the light of the specific frequency of the parallel material 7 . The instrument may comprise, for example, at least the following elements: (4) The photosensitive element m(b), which can be electrically registered to the presence of light, can limit a specific buckle or a frequency control element that controls the frequency of the incident light. Examples of the photosensitive member 10 include, for example: (a) a fluorescent spectrometer or the like; (8) a suitable CCD wafer or the like; (4) a photodiode or the like; (4) (d) a tube or the like; (4) a semiconductor or A light-irradiating h of the selected frequency produces a similar material that is electrically reactive; and (1) a photoactive chemical that can signal in any manner that the light of the selected frequency is present. Examples of the frequency (four) component include, for example: (4) dispersing and separating the human light into its constituent frequencies, and then the constituent frequencies can each be measured and slit; and (b) selectively permitting Only light of a particular frequency passes, thus allowing selectivity to only check for bandpass, cutoff or other filters of these frequencies. The photosensitive element 10 transmits the measured data along the cable 11a to the connected % thin 12, which calculates the spectrum or the measured frequency and determines the luminescent mark based on the presence or absence of light of the wavelength fi1. does it exist. The 31 200813464 computer 12 can repeatedly turn on and off the light source 4 (using the electrical winding lb) to check for the presence or absence of a signal generated by the photosensitive element 10 due to the emission wavelength f11. The computer 12 can therefore mathematically verify the observed value by repeating or integrating the data. The computer 12 can also turn the light source 4 on and off at different points in time to collect data from the photosensitive element 1 ,, thereby deleting false or background data or producing a special reaction or reaction pattern that is unique to the luminescent mark used. As illustrated in Figure 1, the reader 3 can utilize, for example, the following: tools: (1) a laptop or personal digital assistant (PDA) 12 and a suitable wired or wireless network 11; (ii) The USB2000 compact spectrometer 9 supplied by Ocean Optics (Dunediii, Florida USA) and (iii) the VSL_337 compact ultraviolet laser 4 equipped with the optical collector 5 supplied by Laser Science. Alternatively, light source 4 may comprise, for example, one or more of the following: (1) a light-emitting diode (led) operating at 25 0-3 65 nanometers, the latter being supplied by Nicho Corporation of Sakamoto, ( ϋ) a ρχ2 pulsed gas source supplied by cean 〇pties; and (iii) a commercially available LED capable of generating a plurality of visible and infrared radiations ranging from 365 Å to 11 Å. A variety of other solid or incandescent light sources 4 can be used. A light source can be added to the light-emitting elastic cap as appropriate. A pulse generator, such as the Datapulse 100A and LED or other activation circuit board supplied by Systron-Donner, Inc., can be placed between the laptop 12 and the light source 4 to produce a well-controlled light pulse, as appropriate. The fiber-optic electron microscope 6 can be used to transmit excitation light and, for example, qBIF4〇〇_uv_vis, a 400-micron-thick bifurcated fiber optic cable supplied by 〇c_ 〇ptics. The fiber optic cable comprises two layers of fibers; an outer bundle

Around the bundle 5. The outer bundle end is inserted into an optical fiber mounted on the laser. The end of the inner bundle 5 is inserted into an optical fiber mounted on the spectrometer 9. At the front end of the light and cable 6, the two fiber bundles are combined in a so-called, reflective probe. Reflective probes are typically comprised of a metal component that encases two bundles of fibers and provides a small lip behind the end of the fiber. It is desirable to tilt this lip (for example, 30 degrees) when measuring at this angle. In operation, the analytical sample is held against the reflective probe; the purpose of the lip is to eliminate as much as possible the external ambient light in the space between the front end 6 of the fiber and the sample 7. Because the lip on the probe is metal, it generally does not provide a perfect complementary fit to the sample surface. It does not itself block all ambient light present in the space between the front end 6 of the reader and the sample 7. To overcome this difficulty, manufacturers of such probes also supply large anodized aluminum blocks containing reflective probes that fit snugly into the receiving holes; these aluminum blocks are referred to as, reflective probe holders. Dimensions (typically 7 cm x 4 cm), these holders can also block ambient light, but not all ambient light. To eliminate the presence of ambient light and to use trace amounts (or forensics in February) a luminescent mark composed of one or more luminescent materials, a light-dissipating cap 6a made of heavy rubber is adhered to the read H front end 6 (or connected to the reader hole without using a photonic pole) The cap h is composed of a black conical shape in which the reflection k胄6 (or the reader hole) is pushed: a sleeve of the cap 6a is tightly mounted on the reflection probe 6 On the first fortunately, the rubber cone is glued to the rubber sleeve close to the middle of the cone-P-ilt cone contains _ series concentric round rubber lip, when the reading 33 200813464 is squeezed towards the sample surface Moved to Japan, 1 Γ /, each blocked the surrounding light. Rubber cap 6a is under test Ambient light can be eliminated during the process. The read operation € 3 of the supplied silk Currie

〇 Fine Coffee 32 (trademark) or 〇〇IChem spectrometer operating software control. Alternatively, the firmware can be used to control the operation of the reading. The software turns the laser 4 on and off and collects and processes the data received from the spectrometer 9. The entire reader 3, including the control computer and its battery, can be loaded into a shoebox-sized volume to make the reader 3 fully portable. The cap 6a on the front end 6 of the reader allows the reader to be routinely used in field operations, allowing for the guilty and easy in-situ determination of the amount of forensic luminescent material present in the industrial process material. The rubber cap 6af contributes to this traceability. For example, the above view = 4 produces approximately 10 microjoules of power per pulse. Using this light, 4 and the reader 3 and the rubber cap, it can be measured in routine field measurements: city: the presence of thick... in concrete, (4) the specific illuminating mark. It can also be achieved that the law does not completely eliminate all the surrounding light. The reader 3 can use the detection algorithm (or pass) to detect the presence of the luminescence. Many possible tilting algorithms can be formulated in the two-in-example debt algorithm, where multiple luminescence is used in the system: < Characteristic radiation spectroscopy is stored in the data stored in computer 12. By referring to the database, it is possible to identify the light mark 1 stored in the industrial process material 7. Thus, for example, when the frequency F! - is 'the luminescent mark i emission is stored in the form of 2, stored in the battery... as the spectrum J. The library also contains a plurality of other luminescent materials containing the predetermined luminescent mark 7. 200813464 radiation spectrum. When the industrial process material 7 is irradiated with light of a frequency F1, a - spectrum is directly generated. This spectrum is compared to the spectral spectra of each database by an algorithm. ^ The spectrum seen corresponds to 2a (within the expected variation range), and the industrial process material 7-specifically contains the luminescent mark i. # In this way, the presence of a trace amount of a predetermined predetermined luminescent mark in the m material 7 can be detected. This method can be repeated for combinations of a variety of other luminescent indicia 1 and industrial process materials 7.

Alternatively, the radiation light beast 2 can & a special and unique wave peak containing frequency f11, and any other light-emitting mark i in the system 1 cannot emit light of the frequency f11 after being irradiated with frequency light. The detection algorithm can be borrowed, and the marker 1 operates in conjunction with the presence of the peak in the emitted light «曰 in the light emitted by the frequency F1. Therefore, when the industrial process material 7 is irradiated with light of a frequency F1, the detection algorithm can be inspected using a conventional spectral matching technique regardless of whether or not a peak of a specific intensity is observed at the frequency fn. The presence of this peak confirms the presence of luminescent label 1. The method can be repeated for other luminescent indicia 1 comprising one or more luminescent materials having unique luminescent peaks. Similarly, the simultaneous presence of the luminescent materials i, 2, 3, and 4.n 7 in the diversity of the component luminescent materials i can be measured, wherein the luminescent materials of the respective components are irradiated with light of a wavelength Fi to emit true or different radiation wavelengths fll, f 12 , f13 , fl4 ".fln light. The reader 3 can be designed to carry out an example program in which the illumination wavelength is then changed to other wavelengths F2, F3, F4~Fm', each of which emits a specific wavelength fml, one or more kinds of luminescent materials 1-n, Light of fm2, fm3, fm4...fmn. In this case, each of the luminescent materials 35 added to the luminescent mark 1 in the industrial process material 7 can emit at least one important and unique wavelength fmn light when irradiated with light of a single wavelength Fm, but Other wavelengths? When the light of 111 is illuminated, it will not emit light. It is possible to use a luminescent material of a luminescent material containing light of a plurality of wavelengths emitted at a plurality of irradiation wavelengths, provided that the radiation systems do not interfere with each other. Figure 2 depicts an example set of radioactive materials of a luminescent material 丨_13, wherein the luminescent materials are selectively used individually as luminescent labeling forms for luminescent labeling. When irradiated with F1, the luminescent material '= strongly emits light of different wavelengths, but when irradiated with F2_F5, there is no significant light emission. Similarly, when irradiated with F2, the luminescent material 6_7 does emit light, but no light is emitted at any other irradiation wavelength. When irradiated with F3, only the luminescent material 8_9 is effectively emitted and its specific emission wavelength is significantly different. Only when the light is emitted by F4, the luminescent material M2 is specifically light-emitated and only when irradiated with F5; the light material 13 is strongly exposed. When illuminated at two different Fm wavelengths, the luminescent material 5 is strongly diffused. However, the emission wavelength is specific to other luminescent materials that emit light when illuminated at these wavelengths. Therefore, the existence of a bond with a mixture of materials 1-13 does not cause ambiguity. Continuous illumination by wavelengths F1-F5 may comprise 发光- by the luminescent material. The illuminating standard of the illuminating mark $1 "The process material 7 sample and the determination of the presence or absence of each expected wavelength fmn' can be determined that the luminescent material _ μ is present. The presence or absence of the luminescent material of the target provides a binary code |〇= does not exist, 1=exist), many combinations of these luminescent materials are possible. In this way, industrial process materials can be assigned a distinction that is unique to all other possible addresses, addresses, (or codes) ) ' _ distinguishes from the same, but the same item marked by the luminescent mark 1 containing the luminescent material 1-13. 36 200813464 Figure 3 depicts an exemplary matrix of binary code (or "address", which is derived from the above composition The illuminating label $i has the same non-existence with the presence of the luminescent material. If all of the luminescent materials are absent, no clear information can be provided. 'One of the luminescent materials must always be present; the material will ideally be rare material' is not freely available and any other luminescent material benefits mimic its properties. In the example depicted in the figure, the component luminescence is selected: material 1 is always present. When this material is not widely and widely available, it is used as a reference mark for the use of this technology. In the case of an industrial process material containing a trace amount of 13 kinds of luminescent materials, a binary code miimum' is produced and becomes a unique address of the industrial process material. If all but except luminescent material 2 are present in another industrial process material, the address is iGiiiimill but all but the luminescent material 3 are present in another industrial process material, which provides its binary code Address 11J) 1111111U1. This method provides a number of different possible binary codes whereby a plurality of different industrial process materials can be distinguished, each marked by a luminescent mark i composed of a combination of different luminescent materials 1·13 and each having its own address. According to an algorithm suitable for performing - or a plurality of specific methods, quality or logistics control tasks, the reader 3 as depicted in Figure i can also be programmed to detect and compare one of the luminescent markers contained therein. The intensity of the radiance of the plurality of luminescent materials ϋ algorithm may include measuring the source of light (if it is pulsed, or immediately after starting the light source) in a range of ultraviolet, visible, and infrared regions, at _" wavelength The digital amplitude of the received signal. The expected "wavelength" is the wavelength at which any deliberately incorporated luminescent material 37 200813464 will be strongly diffused. For example, when "u τ 7 M f 丄 mud, the expected wavelength is: fn, fl2, fl3 &fl4; with F2 illumination =, the expected wavelength is: f25, f26 and f27; when irradiated with F3, the expected wavelength is · f38, f39 and f310; when irradiated with F4, the expected wavelength is ^ (4), f41Uf412; and when irradiated with F5, the expected wavelength is: (5) 〇 and 仙. For each sample irradiated with light of a wavelength Fm, the expected wavelength is sequentially stored in the memory chip of the reader 3 as a function of the amplitude data. If the expected amplitude of the received wavelength exceeds the empirically determined threshold, register "1" in the memory box of the wavelength. If no, register as, 〇". Then edit the resulting TM, sequentially into the target 3. Said M. This editing method must take into account two or more different waves of luminescent materials that emit light at two or more different wavelengths fmn. For example, in Figure 2, the luminescent material 5 is illuminated at wavelength F2. It is also emitted at the wavelength f45 when it is irradiated with the wavelength F4. In order to register the entire luminescent material 5, it is necessary to register the following as "wide: f25 and F4M when irradiated with μ" In this way, the unique binary code of the type shown in Fig. 3 is obtained. If the simple existence or non-existence of the comparative luminescent material is replaced (''〇, ^ is comparable to the specific radiation peak of the car) Intensity, then higher order coding can be performed. For example, if the luminescence mark 1 is not present, it is represented by 〇, and the mark is all present (maximum intensity) is represented by 2 and is present at half intensity. J and 2 code ( In other words, the editing of the triad code. This type of code contains more permutations and combinations than the triad code and is therefore more complex. 38 200813464 General 'If in a system containing q non-interfering illuminating marks, each can be parsed The maximum number of levels of intensity in the particular radiation peak is p, which can then generate a (P+1) level code. This code will have (P + i) q possible permutations and combinations. The above detection algorithm and luminescence coding The technique represents only one method of generating a luminescent code whereby the industrial process material 7 containing the luminescent mark 1 can be clearly identified. _ Referring to Figure 4 'Industrially produced material 28 includes, for example, in the form of a water-based liquid for use in industry such as tanning Special or bulk chemicals in leather or mining mines. Luminescent markings 2 containing water-soluble luminescent materials are tracely soluble in chemicals 28. The resulting solution 29 is then used in industrial processes (eg, for processing and tanning leather or by ore bodies) The mineral is extracted, which is then rinsed into the waste water reservoir 29 for processing and destruction. The industrial process product (eg, leather or partially processed ore) Containing a small or small amount of luminescent mark 2 〇 and thus emitting a light of a particular wavelength fl 2 when illuminated with light of wavelength F 1. This light φ glow intensity provides a dose for the chemical 28 used and its use. Further, the movement of the chemical 28 and the final result can be measured by the subsequent distribution of the luminescent indicia 20 to the periphery of the wastewater reservoir 29. If the chemical 28 flows out of the wastewater reservoir 29, it seeps. Leak 3 〇 to the environment can be tracked and limited by means of the reader 3 searching for the illuminating mark 20, wherein the sigma gain 3 has been adjusted to be sensitive to the special micro-radiation of the wavelength η 2 under the illumination of the wavelength ρ 1 . If the chemical 28 enters the groundwater surface, its movement in the ground can be measured by looking for the 39 200813464 signal of the luminescent mark having a concentration as low as ippm in the surface cell 31. Therefore, it is easy to detect the origin and cause of this overflow and obtain measurements that comply with relevant regulations and the environment. Moreover, if the illuminating indicia 20 is only available for use in a mink factory or mine under consideration, the origin of the leather or partially processed minerals cannot be resectedly marked on the product. More detailed information can be embedded in the bulk or special chemical πα 28 by the use of luminescent indicia 20, wherein the delta-specific luminescent markings 2 are each composed of a combination of different luminescent materials of the above-described versatility that have been encoded. φ Figures 5 and 5 illustrate an integrated portable illuminating reader 200 that is specifically designed to optically detect a small amount of luminescent indicia in industrial process materials in the field or in the field. The reader 2A includes a portable spectrometer 210, such as a portable 〇cean 〇ptics S1 spectrometer. The pupil 210 0 has a front embedding portion 22, in which an optical input port 230 is arranged. Two light emitting diodes (LEDs) 24 are also arranged on opposite sides of the optical input port 23 of the spectrometer 21 in the embedding portion 220. One or both of the LEDs 240 can emit optical radiation having a wavelength in the range of from about 25 nanometers to about φ micrometers. However, depending on the particular application, both LEDs 240 can emit optical radiation that exceeds this wavelength range. Depending on the size and power of the LED and the application involved, the reader 2 can include more than two LEDs 240, preferably used to have an emission wavelength ranging from about 25 nanometers to 365 nanometers. The optically-radiated LED 24 〇 because a substantial proportion of suitable luminescent markings have a strong absorption in this wavelength range and therefore also emit light as or substantially as strong as they can under these conditions. Therefore, LEDs 24, which operate in the wavelength range of 250 meters to 365 耄 micrometers, can be used to illuminate extremely diverse luminescent markers. Moreover, the use of such LEDs 240 allows them to be used in smaller amounts than in the case of LEDs 24 其他 of other frequencies. As shown in Fig. 5A, the LED 240 is arranged on either side of the optical input port 23 of the spectrometer 210 in the post-entry portion 220 to illuminate an area immediately adjacent to the optical input port 230 and located therebelow. When this region is illuminated, the portion of the optical radiation emitted by any of the luminescent markers in this region is directed to and captured by the optical input 埠no of the spectrometer 210. If necessary, a fiber "section" or a small lens (not shown) can be loaded into the optical input port 230 to assist or facilitate the light harvesting. The embedded portion of the outer casing 22 is surrounded by a flexible opaque panel 250 (e.g., a rubber panel) when the reader 200 is placed on or adjacent to the industrial process material of interest. The opaque coaming plate excludes the ambient light of the optical input 埠23〇 of the spectrometer. However, in certain applications, other types of accessories that effectively exclude ambient light can be used. For example, a slit containing a spring-loaded outer casing that is customized to conform to the material of interest can be used. The spectrometer 210 and the LED 240 are connected to a custom circuit board 260 disposed on the surface of the spectrometer 21 and are coupled by the circuit board 26 to a small battery 27 that is adapted to supply power to the reader 2 assembly. Control it. The circuit board 260 includes an LED driver circuit board that allows the microprocessor 280 included on the circuit board 26 to turn the LED 24 on and off. The circuit board 260 also includes a display 290 and a switch 3 to activate/deactivate the reader 2 and perform other functions. The microprocessor 28 can program the data, such as a detection algorithm, via the attached data. The reader can be downloaded to the microprocessor using the 41 200813464, which is used by the reader, and then its action is controlled when the reader 200 is activated. The reader 200 is enclosed in a custom housing 31A that contains the outermost visible body of the reader 200. The layer 310 is wrapped around the display 29, the rubber louver 250, and the switch 3〇〇 in an aesthetically pleasing package. The reader 2 thus constructed is small and fully portable, and is about the size of a large pocket computer. It is highly applicable in many ways and can be applied to a variety of operational actions and detection algorithms to detect large differences in luminescent markers. The reader 200 can be coupled to a wireless and/or wired network for wireless and/or wired communication with a remote control television, such as a central server. The invention will now be described in the following examples. These examples are not to be considered as limiting the invention in any way. In the following Examples 1-3, the luminescent label i is phenyphenanthrene, which absorbs light of a wavelength of 337 nm (F1 for the purposes of these examples) and emits light of a specific wavelength of 367 nm ( Fn) for the purposes of these examples. The luminescent mark 2 is an Ag-activated vulcanization which absorbs light (fi) having a wavelength of 337 nm and specifically emits light of 451 nm (fl2 of the purpose of these examples). The luminescent label 3 is a Mn-activated magnesium fluorogallate which emits light having a wavelength of 658 nm (fl3 for the purpose of these examples) at 337 nm irradiation (F1 for the purpose of these examples). Luminescent Mark 4 is a ruthenium that absorbs 337 nm of light and specifically emits 425 nm of light (Π4 for the purposes of these examples) 〇42 200813464 Example 1: Quality and logistics control of concrete and cement products will be illuminated by 1 15 g) was dissolved in a dichloromethane solution containing 15 g of polymethyl methacrylate (PMMA) polymer. This solution was spray dried using a commercial spray drier to obtain a luminescent mark 1 containing ι〇/〇 weight/weight ratio encapsulated by fine polymer beads. A small amount of luminescent mark 5 grams (in 150 grams of PMMA polymer) was suspended in a single batch of concrete (7 cubic meters) in a 2" «car. The two Us are then operated at maximum speed for 4 minutes, as in the ready-mix concrete industry. The mixer was then set to a low speed and the car was advanced to the dumping position where the concrete batch was again mixed for 2 minutes at maximum speed. After dumping and hardening, the precise location of the concrete batch and its boundaries within other poured concrete batches can be measured by a reader examining the surface of the concrete structure. The reader is as described in Figure i and can be adjusted to generate Η and detect fii. The reader is composed of a laptop computer, a USB 2000 small spectrometer supplied by 〇cean〇ptics, and a small UV laser of the VSL-377 supplied by the company (10), which is a uv laser system. Equipped with a fiber optic connector (a 100A pulse generated by Systron_D〇nner), the fiber optic cable is

The 400 nm micron thick bifurcated fiber optic cable supplied by Ocean Optics is a tool that carries excitation and emission light. The fiber optic cable includes two layers of fiber optic bundles arranged around an inner bundle. The end of the outer bundle is inserted into an optical fiber mounted on the laser. The end of the inner bundle is inserted into the optical meaning of the spectrometer. The tip end of the probe is equipped with a cap which is made up of a conical rubber sleeve 43 200813464 J. The wide rubber cone is attached to the conical rubber of the cap: f. This cone contains a series of concentric, round rubber lips that block the surrounding light when the two ends are pressed against the surface of the sample. The ^ operation is controlled by the OOIBase37 (quotient) supplied by 0cean 〇Ptics. Detection can be accomplished by sliding the front end of the reader over the concrete surface. The presence of fu in the emission spectrum of the concrete after irradiation with F1 indicates the physical location of the batch. # When η is incident, other batches containing no such φ matte material 1 do not produce a clear signal fl 1 . The luminescent materials 2 and 3 can be used to mark concrete by means of F i and after detecting m and fl3 respectively. Example 2. Processing Quality and Logistics Control of Wood and Wood Products The light mark 4 marks the wood product. The luminescent mark 4 was dissolved in a commercial wood preservative solution in an amount of 〇 3% by weight/weight, wherein the preservative solution consisted of a petroleum solvent and a strong soluble insecticide. The resulting mixture contains a preservative and a trace of luminescent label 4. • Fill the wood sheet with glutinous rice X7 cm X7 cm) with preservative treatment wood f. This barrel is for non-commercial laboratory for testing purposes only. (d) Sealed and placed under partial vacuum (85 KPa) for 15 minutes. The wood preservative solution containing the luminescent mark is then filled back into the bucket via the inlet port. The preservative penetrates into the wood with a luminescent mark. A positive pressure (700 kPa) was then applied to the barrel for 5 minutes to drive the preservative solvent into the wood as much as possible. After releasing this force, release the barrel seal and remove the wood. As described in Fig. 1, the surface of the wood surface is examined by the reader. 44 200813464 When the light of the wavelength F1 is not irradiated, it uniformly emits light of a wavelength of fi4. Therefore, the exterior of the wood is uniformly treated by the antiseptic solution. When the wood chips are sawed into two pieces, the reader observes the new cut surface to reveal the light with the wavelength fi, and the (4) surface also emits light of the wavelength f14. Therefore, this analysis is revealed. The exterior and interior of the wood are uniformly marked by the illuminating mark 4. Capital Example 3: Spray paint for asset management 1. Propellant, clarified air-dry lacquer or enamel and 〇 · 5% by weight

Mark 1 or 4 (in other words, 0.5 grams per 100 grams of content) is charged with gas (4):. The machine used to package the aerosol is a proprietary c〇i〇rPak 3 gram air-cooled I paint filling system, which is powered by a gas-controlled aerosol filling machine and a proprietary pre-I clothing/ A mixture of a granule and a propellant. The asset is sprayed with the sol and the lacquer/paint is dried. The identification of the wavelength fu and the cut = the method of "coughing (as described in Example ,, its emission wavelength F1) sweeping across the surface of the tribute. Unless the context requires it, it should be understood throughout In this patent specification and the following claims, the word "comprising" and "comprising", ",", ", ", ", ", ", ", " Integer group. Any prior publication (or information derived from it) in this (4) specification or any reference to ▲ known material is not and should not be used as confirmation or acknowledgement or in any construction of the prior publication (or by ^ ^ 1 From the information of He Shengzhi) or the known material, the form of this patent specification is related to the part of the 'I-money-like general knowledge-part. [Simplified illustration] 45 200813464 Now by reference only The invention is described in a non-limiting example manner in which the drawings are

Figure 1 is a flow chart showing the specific performance of a field process material system in the field or on-site tracking, identification or identification. Figure 2 is a representation of the emission wavelengths of the 13 luminescent materials different from each other; Figure 3 is a binary code representation of the presence or absence of the emission wavelengths of the 13 luminescent materials different from each other; Figure 4 is a description of the tracking using the addition of trace luminescent markers A flow chart of bulk chemicals; and Figure 5A is a perspective enlarged view of an integrated portable light-emitting reader in accordance with the present invention, and Figure 5B is a perspective view of the device of Figure 5a in assembled form. [Main component symbol description] 1 luminescent mark 2 spectrum 2a spectrum 3 reader 4 light source 5 fiber; fiber component bundle; fiber collector; inner bundle 6 reader front end; reading hole; fiber optic cable 6a elastic cap; Cap 7 Industrial Process Materials 8 Second Fiber; Fiber Optic Component Beam; Outer Beam 46 200813464 9 Spectrometer 10 Photosensitive Element 11 Wired or Wireless Network 11a Cable 11b Cable 12 Computer; Personal Digital Assistant (PDA) 13 Mixer 20 Illuminated Mark 28 Chemistry Products; industrial materials 29 waste water storage 30 leakage 31 surface pool 100 system 200 integrated portable light-emitting reader 210 portable spectrometer 220 front embedded part 23 0 optical input 埠 240 light-emitting diode 250 flex opaque Enclosure 260 Circuit Board 270 Battery 280 Microprocessor 290 Display 300 Switch 47 200813464 310 Enclosure FI Wavelength fll Wavelength

Claims (1)

200813464 X. Patent application scope: A method for marking industrial process materials, which comprises selectively adding: a government affairs light mark to the industrial process material and/or adding thereto, which makes the luminescent mark Adding (4) is not sufficient to detect it in the presence of ambient light, but it can be detected optically in the field or in the private material and/or on it in the field or on the spot. Obtained, wherein the micro 1 luminescent mark is used for material control, storage control, inventory control, process control, logistics (4), quality control, and pollution control at least __ to trace, identify or identify the industrial process material. The method according to claim 1, wherein the industrial process material is a solid, liquid or gaseous medium having a low m-identifiable standardized and/or indistinguishable. 3. According to the method of claim 1 or 2 of the patent scope, the industrial process materials are cement, concrete, too good ^ soil, ore, plastic, fiber, food, paint, metal, explosive precursor materials and At least one of the explosive materials. 4 · According to the method of applying for patents 筮丨$月号W target 111, the illuminating mark contains one or more individual or common images of the ancient 4 Shizheng IJ, with a 4 inch lead radiation and/or excitation Characteristic luminescent material. 5 · According to the method of applying for a patent rib around; the method of the first item, wherein the trace amount is between lPPb and less than the mass of the industrial process material. 6 · According to the method of applying for patent ribs g f f 犯 犯 犯 犯 犯 犯 犯 犯 犯 犯 犯 犯 犯 犯 犯 犯 犯 犯 犯 犯 犯 犯 犯 犯 犯 犯 犯 犯7 · According to the method of applying for a patent range, the illuminating mark 49 200813464 can be optically detected by an optical projection of a wavelength range of 25 G nm to 365 nm. 8. The method of claim 1, wherein the illuminating indicia is optically detectable in the field or in the field by a portable illuminating reader. 9 methods for tracking the industrial process material from the life cycle stages of a plurality of industrial process materials, the method comprising the steps of: φ hunting by selectively adding or adding a trace amount of luminescent mark to the industrial process material Giving it a unique luminescent reaction; and identifying or identifying in situ or on-site during the life cycle phase of the industrial process material by in situ detection of a luminescent reaction from the industrial process material corresponding to the unique luminescent reaction The industrial process material. 10. The method of claim 9, wherein the industrial private material is a standardized, and/or non-different, solid, liquid or gaseous medium having low inherent visual identity.眷U. The method according to claim 9 or 10, wherein the industrial garment private material is at least one of cement, concrete, wood, ore, plastic, fiber, food, paint, metal, explosive precursor material and explosive material. By. 12. The method of claim 9, wherein the luminescent label comprises one or more luminescent materials individually or collectively having a unique luminescent emission and/or excitation characteristic. 13. The method of claim 9, wherein the trace amount of light is between 1 ppb and less than 1% of the mass of the industrial process material. 200813464 according to the method of claim 9 wherein the trace amount of light Markings are not used in biological testing of the process materials. ^ 彳 明 专利 专利 专利 专利 专利 专利 专利 , , , , , , 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 The method of claim 9, wherein the illuminating mark is optically measured in situ in the field or in the field by a portable illuminating reader. 17. The method of claim 9, wherein the unique initial response represents a unique code corresponding to the industrial process material. 18. The method of claim 1, wherein the unique generation: the external system is represented by one or more predetermined illuminating parameters and/or illuminating algorithms. 19. According to claim 17 or 18 The code is additionally represented by a relative presence and/or non-existence of a plurality of luminescent emissions and/or excitation characteristics associated with a plurality of L-containing stimuli including the luminescent mark, respectively. ^9 of the branch, in which the information about the material and the unique luminescence reaction it is given is in a poor repository. The method according to the scope of the patent application 帛9, which is the industrial system. 22. The life cycle phase includes at least two of raw material acquisition, processing, preparation, blending, transportation, distribution, use, reuse, maintenance, recycling, and disposal of the used blade. According to Article 9 of the scope of application for patents, the industrial system 裎铋祖# ^ 1 additionally includes the products of the chasing, the products, parts or structures of the jewels, and the products or parts of the helmets Structure." According to the method of the ninth application of the patent scope, the material of the method is to take the seven industry garments in multiple batches..., or to process and impart the industrial process materials to the 'man's unique luminescent reaction. 1 save | > μ 4 system. "Arrangement of eight storage λ control or inventory control for the tracking system of industrial process materials, including 24. One portable light-emitting reader, its system +, Japanese,,, and you become a wilderness Or on-site detection of unique luminescent reactions imparted to industrial process materials and/or from products, materials or structures; a depleted reservoir that is associated with storage of materials, products, components and/or The structure and the information corresponding to the unique luminescence reaction given thereto; the processor refers to +, which compares the device with the portable illuminator The luminescence reaction obtained by the measurement and the unique luminescence reaction stored in the library are identified to identify or identify the industrial process material, product, component and/or structure. 25. A portable illuminating reader comprising a spectrometer source and a spectrometer detector, wherein the optical path is generally arranged in an opaque enclosure having an opening defining a sample area, wherein the spectrometer source and spectrometer detect The device is substantially equidistant on the sample zone, and wherein the opaque panel substantially shields ambient light from the spectrometer 1 detector when the opening is substantially blocked by the sample. The portable illuminating reader of claim 25, wherein the spectrometer source comprises at least one light emitting diode having a wavelength in the range of 25 〇 to 3 65 耄. 27. The portable illuminating reading according to claim 25 or 26, wherein the opening of the opaque panel is adapted to substantially encapsulate an industrial material or a product, component and/or structure formed therefrom sample. Eleven, circle: as the next page 53