TW200811946A - Methods of removing extraneous amounts of molding material from a substrate - Google Patents

Methods of removing extraneous amounts of molding material from a substrate Download PDF

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Publication number
TW200811946A
TW200811946A TW96119348A TW96119348A TW200811946A TW 200811946 A TW200811946 A TW 200811946A TW 96119348 A TW96119348 A TW 96119348A TW 96119348 A TW96119348 A TW 96119348A TW 200811946 A TW200811946 A TW 200811946A
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TW
Taiwan
Prior art keywords
substrate
region
molding material
particulate component
plasma
Prior art date
Application number
TW96119348A
Other languages
Chinese (zh)
Inventor
James D Getty
Jiangang Zhao
Original Assignee
Nordson Corp
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Priority claimed from US11/420,840 external-priority patent/US20060201910A1/en
Application filed by Nordson Corp filed Critical Nordson Corp
Publication of TW200811946A publication Critical patent/TW200811946A/en

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Abstract

Methods for removing thin layers of extraneous multi-component molding material from one or more areas on a substrate. The methods include exposing the substrate to a plasma effective to remove a non-particulate component of the molding material from each area. The methods further include exposing the substrate to a non-plasma process effective to remove a particulate component of the molding material from the area.

Description

200811946 九、發明說明: ’且更明確地說,係關於用 組份模製材料薄層之處理方 【發明所屬之技術領域】 本發明大體係關於電漿處理 於自基材上之區域移除額外多 法0 【先前技術】 通常藉由電漿處理來修改與積體電路、 电封裝及jKi] 電路板有關之應用中所使用之基材的表面特性 在電子封裝中使用電聚處理(例如)來增加表面活化及:或表 面清潔度,以用於消除分層及結合失效、 一" 度、讀保曰曰片在電路板上之無空隙底部填充、移除氧化 物:增強晶粒附著及改良用於晶粒封裝之黏著。通常 -或多個基材置放於電漿處理系統中,且將每一美材之至 少一表面暴露至電聚。藉由物理滅鐘、化學辅助祕 反應性電聚物質所促進之化學反應及此等機制之 自表面移除最外原子層。物理或化學作用亦可用於調節表 面以改良諸如黏著之特性或自基材表面清潔不當 物0 ’、 在半導體製造期間,通常藉由導線結合 ^屬載體上之引線(諸如引線框架)電输1線框= :包括°+多襯墊’每―”具有用以將單-半導體晶粒虚 一電路,電㈣之暴露引線。-半導體晶粒附著至每一襯 墊且曰曰粒之外部電接觸點與引線之附近部分進行導線結 12J151.doc 200811946 體晶粒及其導線結合被封裝於—由一模製聚人 物“、、且成之封裝内部’該模製聚合物本體 ' 半導體晶粒及導線結合不受在處理、儲存及 】,、濩 所遭遇之m 儲存及製造製程期間 .晶粒所ίΓ環境的影響’以及耗散在操作期間自半導體 材料為填充右. 了犮之吊見的多組份模製200811946 IX. Description of the invention: 'and more specifically, the treatment of a thin layer of a molded material with a component. [Technical Field of the Invention] The large system of the present invention relates to the removal of plasma treatment from a region on a substrate. Extra multi-method 0 [Prior Art] Surface properties of substrates used in applications related to integrated circuits, electrical packages, and jKi] boards are typically modified by plasma processing. Electropolymerization is used in electronic packages (eg, ) to increase surface activation and: or surface cleanliness, to eliminate delamination and bonding failure, a " degree, read-and-preserve film on the board without voids underfill, remove oxide: enhance grain Adhesion and improvement for adhesion of the die package. Typically - or a plurality of substrates are placed in the plasma processing system and at least one surface of each of the sheets is exposed to electropolymerization. The outermost atomic layer is removed from the surface by physical quenching, chemical reactions promoted by chemically assisted reactive electropolymers, and such mechanisms. Physical or chemical effects can also be used to condition the surface to improve adhesion properties such as adhesion or cleaning from the substrate surface. During semiconductor manufacturing, wires are typically bonded by wires (such as leadframes). Wireframe = : includes ° + multi-pad 'each' has an exposed lead for the mono-semiconductor die virtual circuit, electric (four). - semiconductor die attach to each pad and externally The contact point and the vicinity of the lead wire are wire-bonded. 12J151.doc 200811946 The body die and its wire bond are packaged in a packaged polymer body, and the molded polymer body's semiconductor die And the wire bonding is not affected by the processing, storage and processing of the m during the storage and manufacturing process. The influence of the grain environment 以及 and the dissipation during the operation from the semiconductor material is filled right. Multi-component molding

在"钥—乳化矽或矽微粒或粒子之環氧樹脂基質。 在撫U程期間,將引線框架及多個附著式半導體晶板 二:兩個半模之間。一半模包括許多空腔,•一 、”體晶粒且界定封裝形狀 工 以試圖密封通向空腔之入口。被注入至欠在-起 :二内部之開放空間以用於封裝半導 導 :丨線L,模製材料可自半模之間的空腔中渗出且在= 成薄層或溢料(f 1 a s h)。此薄溢料 10微米之厚度。、、益粗盔古―A 才十/、有通吊小於約 裝半導^ θ ’、、,、告,因為其可能影響製造與封 …體晶粒之高品質電連接的能力。 在模製製程期間,可笋 來防止溢粗从 了糟由以V子來覆蓋引線框架之背面 木防止溢枓。然而,黏著 且在移除帶子之後伴拉“自f子轉移至引線框架背面 帶子為相對較卜Γ 物。另彳,適合於此應用之 移除會招致需=力/增加了製造成本,且帶子應用及 要$力成本且降低製程產量。 在拉裳之後,可葬由 料。此等移除方法學一 引線框架易受來自機: 途之缺陷。舉例而言, 之損害。化學製程可:二移:技術(編^ …、效,除非使用高度腐餘性化學 12115】.doc 200811946 品,此潛在地引發了工 6入 料處理的問題。雷射移*全及,過的腐钕性化學品之廢 引線框架上。 夕除為〒貴的且使殘餘碳殘餘物留在 因此, 製程。 需要一種可自基材有效地移 由於至少此等原因, 除額外模製材料之處理 【發明内容】 本發明之實施例解決In the "key-emulsified enamel or enamel particles or particles of epoxy resin matrix. During the U process, the lead frame and the plurality of attached semiconductor crystal plates are two: between the two mold halves. The half mold includes a plurality of cavities, a body granule and defines a package shape to attempt to seal the inlet to the cavity. It is injected into the underside: two internal open spaces for encapsulating the semiconducting:丨 line L, the molding material can ooze out from the cavity between the mold halves and be = thin layer or flash (f 1 ash). This thin material has a thickness of 10 micrometers. A only ten /, there is less than about the installation of semi-conducting ^ θ ',,,,,, because it may affect the ability to manufacture and seal the high-quality electrical connection of the body grain. During the molding process, can come Preventing the overflow from being obscured by covering the back side of the lead frame with V to prevent spillage. However, after the tape is removed, the tape is transferred from the f to the back of the lead frame to be relatively voicing. In addition, the removal of this application will incur the need to force / increase the manufacturing cost, and the tape application and cost, and reduce the process yield. After pulling the skirt, you can bury the material. These removal methods learn that the lead frame is susceptible to defects from the machine: For example, the damage. The chemical process can be: two shifts: technology (editing ..., efficiency, unless the use of high-corrosion chemistry 12115).doc 200811946 products, this potentially caused the problem of the processing of the material 6 processing. The waste lead frame of the rotted chemical. The eve is expensive and leaves residual carbon residue in the process. Therefore, it is necessary to effectively move from the substrate for at least these reasons, except for the additional molding material. Processing [Invention] The embodiment of the present invention solves

關聯之問題。為此且腿 、他與習知溢料移除製程木 於自其材本發明之一實施例,提供-㈣ 、土材上之區域移除模f姑粗$ + + + 一古# ^ 犋ι材抖里之方法。將基材暴露5 將姑从 飞大體上移除模製材料之非微粒組份的f 漿。接者,將基材暴霞 之微粒組份的非電漿=用以自區域移除模製材剩 ^。月之肖疋貫施例中,非電漿製程進一步包含刷 洗》暴材之區域中的桓擊士 接自㈣域料模製材料之微 粒組份。在本發明之另——^ 另特疋貫%例中,非電漿製程進一 步包含將基材之區域中的㈣材料置放成與有效用以自區 域移除模製材料之微粒組份的清潔液相接觸。 自隨附圖式及其描述,本發明之此等及其他優點應變得 更明顯。 【實施方式】 參看圖1,電漿處理系統10包括一由封閉一處理空間14 之壁所構成的處理腔室12。在電漿處理期間,將處理腔室 12欲封成與周圍環境不.透水。處理腔室】2包括一接取開口 (未圖示),該開口經組態以用於將基材2〇轉移至處理空間 I21I51.doc 200811946 14及自處理空間14轉移基材2〇。如熟習真空技術之一般技 術者所認識,用以抽空處理腔室12之處理空間14的真空泵 1 6可包含具有可控制抽汲速度之一或多個真空泵。准許處 理氣體以預定流動速率經由處理腔室12中所界定之入口端 自處理氣體源1 8進入處理空間14。通常藉由一質量流量 控制器(未圖示)來量計處理氣體自處理氣體源丨8至處理= 間14之流量。調整來自處理氣體源以之氣體的流動速率及 真空泵16之抽汲速率以提供適合於電漿產生之處理壓力及 %境。隨著自處理氣體源18引入處理氣體,同時持續地抽 工處理空間〗4,使得當存在電漿時,在處理空間1 *内持續 地交換新鮮氣體。 、 電源22與處理腔至12内部之電極台座24電輕接且將電功 率轉移至該電極台座24,在例示性處理系統1〇中,該電極 台座24支撐基材20。自電源22所轉移之功率有效用以自處 理二間14内所限制之處理氣體而鄰近於基材2〇來形成電漿 %,且亦控制直流(DC)自偏壓。雖然本發明並非被如此限 制但是電源22可為以約40 kHz與約13·5ό MHz之間(較佳 為約13.56 MHz)的頻率(雖然可使用其他頻率)及(例如)4〇 kHz時之約4000瓦特與约8〇〇〇瓦特之間或ΐ3·56 %取時之 3〇〇瓦特至2500瓦特之功率位準搔作之射頻(R^電源。然 而,一般熟習此項技術者應瞭解,不同的處理腔室設計可 允許不同的偏壓功率。一控制器(未圖示)搞接至電漿處理 系、、充1 0之各種組件以有助於對餘刻製程之控制。 電立處理系統1G可採取-般熟f此項技術者所理解之不 I21151.doc 200811946 π組恶,且因此,電漿處 示性組態。舉例而言,可二二!限於t文所描述之例 26且將其傳遞至處 :&至12之遂端處產生電漿 王間14以供電漿處理基材2〇中使用。 進一步理解電漿處理系統1〇包括圖 Μ· 操作所必需的袓件,^ 口丁之為糸統10之 間的㈣。〜於處理空間14與真空泵16之Linkage issues. To this end, and the legs, he and the conventional flash removal process wood from one of the embodiments of the present invention, provide - (d), the area on the soil material removal mold f abundance $ + + + one ancient # ^ 犋The method of ι material shaking. Exposing the substrate 5 will substantially remove the non-particulate component of the molding material from the fly. In addition, the non-plasma of the particulate component of the substrate is used to remove the molded material from the region. In the case of the Moonlight, the non-plasma process further includes the blaster in the area of the scrubbing material, which is taken from the microparticle component of the (4) domain material molding material. In another example of the present invention, the non-plasma process further includes placing the (four) material in the region of the substrate into a particulate component effective for removing the molding material from the region. Clean liquid phase contact. These and other advantages of the present invention will become more apparent from the drawings and description. [Embodiment] Referring to Figure 1, a plasma processing system 10 includes a processing chamber 12 formed by a wall enclosing a processing space 14. During the plasma processing, the processing chamber 12 is intended to be sealed from the surrounding environment. The processing chamber 2 includes an access opening (not shown) configured to transfer the substrate 2 to the processing space I21I51.doc 200811946 14 and transfer the substrate 2 from the processing space 14. As recognized by those of ordinary skill in the art of vacuum technology, the vacuum pump 16 for evacuating the processing space 14 of the processing chamber 12 can include one or more vacuum pumps having a controllable pumping speed. The process gas is permitted to enter the process space 14 from the process gas source 18 via the inlet end defined in the process chamber 12 at a predetermined flow rate. The flow of process gas from process gas source 丨8 to process = room 14 is typically measured by a mass flow controller (not shown). The flow rate of the gas from the process gas source and the pumping rate of the vacuum pump 16 are adjusted to provide a process pressure and a pH suitable for plasma generation. As the process gas is introduced from the process gas source 18, the process space 4 is continuously pumped so that fresh gas is continuously exchanged in the process space 1* when plasma is present. The power source 22 is electrically coupled to the electrode pedestal 24 inside the processing chamber 12 and transfers electrical power to the electrode pedestal 24. In the exemplary processing system 1 该, the electrode pedestal 24 supports the substrate 20. The power transferred from the power source 22 is effective to self-process the process gas limited within the two spaces 14 to form a plasma % adjacent to the substrate 2, and also to control direct current (DC) self-bias. Although the invention is not so limited, the power source 22 can be at a frequency between about 40 kHz and about 13.5 ό MHz (preferably about 13.56 MHz) (although other frequencies can be used) and, for example, 4 kHz. RF power (R^ power supply) between about 4,000 watts and about 8 watts or about 3.65% of the power of 3 watts to 2,500 watts. However, those who are familiar with the technology should understand Different processing chamber designs allow for different bias powers. A controller (not shown) is connected to the plasma processing system, charging various components to help control the process of the engraving process. The vertical processing system 1G can take the same understanding as the one skilled in the art. I21151.doc 200811946 π group evil, and therefore, the plasma is configured. For example, it can be two or two! Example 26 and pass it there: & to the end of the 12 to produce the plasma king 14 to power the slurry treatment substrate 2 。. Further understanding of the plasma processing system 1 〇 including the operation · necessary The condition of the mouth, ^ mouth of the 糸 between the 10 (four). ~ in the processing space 14 with the vacuum pump 1 6

声=。定位於處理腔室12之處理空間㈣的適合於電聚 in内^置處。本發”期:多個基材2G可定位於處理腔 藉由單—處理製程以處理空間14中所提供之 电桌26來同時處理。 對基㈣之電漿處理有效地移除安置於基材 ㈣製材料撕,溢料)薄層。在先前製造階段期間,可 猎由模製製程來產峰洛#,# 、產生溢枓復盍區域。舉例而言’此等額外 ::區域可駐留於模製聚合物封裝内部的半導體晶粒 ^之電接觸點上。常見的模製材料為由有機基質(諸如 =合物或環氧樹脂)及無機填充劑(諸如二氧化石夕粒子,其 分散於該基質中以用於修改有機基質之特性)組成之複合 物0 對基材20之電漿處理為基於構成模製材料之有機基質及 無機_選擇性及刻速率在等效電漿條件下不 、::)提之兩P白段製程。使用兩個不同的製程階段會加速 、、、λ''夕矛' 因為第一階段經調適以相對於無機填充劑選擇 性=效移除有機基質,且第:階段經調適以相對於有機 基質選擇性地有效移除無機填充劑。—用於提供此等兩個 I21153.doc 200811946 電水之氣體混合物之組人 製程階段之方法係改變用以形成 物0Sound =. The processing space (4) located in the processing chamber 12 is suitable for electrical polymerization. The present invention: a plurality of substrates 2G can be positioned in the processing chamber by a single-treatment process to process the electricity table 26 provided in the space 14 for simultaneous processing. The plasma treatment of the base (4) is effectively removed and placed on the base. Material (4) material tearing, flashing) thin layer. During the previous manufacturing stage, you can hunt the molding process to produce peak Luo #, #, generate overflow 枓 reclamation area. For example, 'this extra:: area can Residing on the electrical contacts of the semiconductor die inside the molded polymer package. Common molding materials are organic substrates (such as = compound or epoxy) and inorganic fillers (such as dioxide dioxide particles, It is dispersed in the matrix for modifying the properties of the organic matrix. The composition of the composite 0 is treated by plasma treatment of the substrate 20 based on the organic matrix constituting the molding material and the inorganic _ selectivity and engraving rate in the equivalent plasma. Under conditions, no::)) Two P white stage processes. Two different process stages will be used to accelerate, ,, λ'' spurs because the first stage is adapted to be selective with respect to inorganic fillers = effect shift In addition to the organic matrix, and the first stage is adapted to the phase Effective to selectively remove the organic matrix .- inorganic filler for providing a gas mixture of these two methods I21153.doc 200811946 electric water phase of the group of people based change process was used to form 0

在該製程之第-階段中,將處理空間14中之基材2〇暴露 至由包括含氨氣體物質(例如,四氟化碳、三袁化氮或丄 氟化硫)及含減體物質(諸如氧氣(〇2))之富含氧之=體ς 合物所形成的電漿26。雖然不希望被理論约束,但是= 信’來自電漿26之氧之活性物質(例如,自由基及離二目 對較有效用於移除基材紙之由模製材料薄層所覆蓋的區 域中之有機基質。類似地,咸信’自電漿26起源之氟的活 性物質相對較有制於移除模製材料之無機填充劑。藉由 自富含氧之氣體混合物形成電漿26,有機基質之蝕刻速率 大於無機填錢之#刻速率。換言之,相對於無機填充劑 選擇性地移除有機基質。 上文所述第製私Ρ白b段之氣體混合物中含氧氣體物 質之體積濃度大於含氟氣體物質之體積濃度。結果,第一 :程階段之氣體混合物包括以多於50體積百分比令,之 濃度的含氧氣體物質。含氟氣體物質通常包含其餘氣體混 口物’但可故意地將諸如惰性氣體之其他氣體物質添加至 氣體混合物,只要含氧氣體物質具有大於含氟物質之濃度 的濃度即可° #然’殘餘大氣氣體及自腔室組件之除氣亦 使分壓有助於處理腔室12㈣之部分真空。最適合用於第 一製程階段中之氣體混合物包括約7〇 v〇〗%至約9〇 V〇l%之 3氧氣to物I。經發現尤其適合於該製程之此初始製程階 段的氣體混合物為80 v〇l%之含氧氣體物質及2〇 ν〇ι%之含 121I5I.doc 200811946 氟氣體物質。 第一階段之電漿26中所在力l 在之乳的活性物質有效地移除 基材20上之由模製材料薄; 7卞潯層所覆盍的區域中之有機基質。 雖然氟之活性物質移除此等 寺益枓覆盍區域中之無機填充 劑,但疋歸因於模製材料 七— 十之此組伤之相對較低的蝕刻速 率,第一階段之配方相對鮫盔 奴…、效甩於移除無機填充劑。結 果’在自填充劑之間的空間 ]大體上或部分地移除有機基質 殘餘無機填充_持橫跨在基材20之由溢料先前覆 、品或本土月預期·因為第二階段亦移除有機基質 (雖然以顯著較低之蝕刻速率 迷丰)所以在處理製程之第一階 ί又期間’有機基質不會必須 6 乂肩被70全移除,且可藉由第二製 私階段來部分地移除。當缺, 田…、馮^矛夕除溢料,可迭代該兩 個製程階段(若需要)。 在處理製程之第二製程階段中’將處理空間"中之基材 2〇暴露至自含敦物質(例如,四氟化碳、三氣化氮或六氣 化硫)與含氧氣體物質(諸如氧氣(〇2))之富含氣之氣體混合 生的電與第—製程階段相比’由此氣體混合 物所形成之電漿26相對於有機基質之钱刻速率具有無機填 充劑:升高的蝕刻速率。通常’在不破壞真空之情況下, 且較佳地,在不熄滅處理腔室12内部之電漿26之精況下, 完成氣體混合物之變化。此第二氣體混合物可包括與第— P白#又相同但是以不同相對比例來混合之兩種氣體物質。 通吊,虱體混合物中含氧氣體物質之體積濃度小於含氟 氣體物質之:普吞 ^ ^ ^ u 積/辰度。通吊,弟二(¾段之氣體混合物包括 I2I151.doc -12- 200811946 小於50 vol%之含氧氣體物質,且其餘混合物包含含敦氣 體物質。然而,只要含氧氣體物質具有小於含氟物質之濃 度的濃度,則可故意地將諸如惰性氣體之其他氣體物質添 加至氣體混合物。最適合用於第二製程階段中之氣體混合 物包含約70 vol%至約90 V〇l%之含氟氣體物質。經發現尤 其適合於該製程之此階段的氣體混合物為2〇 v〇1%之含氧 氣體物質及80 vol%之含氟氣體物質。In the first stage of the process, the substrate 2 in the processing space 14 is exposed to a substance including an ammonia-containing gas (for example, carbon tetrafluoride, tribasic nitrogen or antimony fluoride) and a reduced substance. A plasma 26 formed by an oxygen-rich = body conjugate such as oxygen (?2). Although not wishing to be bound by theory, it is believed that the active material from the oxygen of the plasma 26 (e.g., free radicals and off-axis pairs are more effective for removing the substrate paper from the area covered by the thin layer of molding material) In the organic matrix, similarly, the active material of fluorine originating from the plasma 26 is relatively more suitable for removing the inorganic filler of the molding material. By forming the plasma 26 from the oxygen-rich gas mixture, The etching rate of the organic matrix is greater than the rate of inorganic filling. In other words, the organic matrix is selectively removed relative to the inorganic filler. The volume of the oxygen-containing gas species in the gas mixture of the second-stage private white b-segment described above. The concentration is greater than the volume concentration of the fluorine-containing gas substance. As a result, the gas mixture in the first stage includes a concentration of the oxygen-containing gas substance in a concentration of more than 50 volume percent. The fluorine-containing gas substance usually contains the remaining gas mixture 'but Desirably, other gaseous substances such as an inert gas may be added to the gas mixture as long as the oxygen-containing gas substance has a concentration greater than the concentration of the fluorine-containing substance. Degassing of the chamber assembly also causes partial pressure to assist in processing a portion of the vacuum in chamber 12 (4). The gas mixture most suitable for use in the first process stage includes from about 7 〇v 〇 % to about 9 〇 V 〇 % Oxygen to material I. It has been found that the gas mixture which is particularly suitable for this initial process stage of the process is 80 v〇l% of the oxygen-containing gas substance and 2% ν%% of the 121I5I.doc 200811946 fluorine gas substance. The active material in the plasma of the stage is effectively removed from the active material of the substrate 20 by the thin matrix of the molding material; the organic matrix in the area covered by the layer of ruthenium. In addition to the inorganic fillers in the area of the temple, but due to the relatively low etch rate of the group of the seventh to tenth of the molding material, the formula of the first stage is relative to the helmet. The inorganic filler is removed. The result 'space in the self-filling agent' is to remove the organic matrix residual inorganic filler substantially or partially _ holding over the substrate 20 by the previous coating, the product or the local month Expected · because the second stage also removes the organic matrix (although significant The low etch rate is fascinating. Therefore, during the first stage of the process, the organic matrix does not have to be removed by 70, and can be partially removed by the second stage. , Tian..., Feng ^ spear eve, can iterate the two process stages (if needed). In the second process stage of the process, 'subject space> in the processing space> to the self-contained The substance (for example, carbon tetrafluoride, tri-nitrogen gas or hexa-sulfurized sulfur) is mixed with a gas-rich gas of an oxygen-containing gas substance (such as oxygen (〇2)), and the electricity is compared with the first stage of the process. The plasma 26 formed by the gas mixture thus has an inorganic filler relative to the organic matrix: an elevated etch rate. Typically, 'without breaking the vacuum, and preferably without extinguishing the processing chamber Under the fine condition of the internal plasma 26, the change of the gas mixture is completed. This second gas mixture may comprise two gaseous species that are identical to the first-P white # but mixed in different relative proportions. Through the suspension, the volume concentration of the oxygen-containing gas substance in the mixture of the corpus callosum is smaller than that of the fluorine-containing gas substance: the product of the engulf ^ ^ ^ u / the length.吊吊,二二 (3⁄4 paragraph gas mixture includes I2I151.doc -12- 200811946 less than 50 vol% of oxygen-containing gas substances, and the remaining mixture contains gas containing gas. However, as long as the oxygen-containing gas substance has less than fluorine-containing substances The concentration of the concentration may intentionally add other gaseous species such as an inert gas to the gas mixture. The gas mixture most suitable for use in the second process stage contains from about 70 vol% to about 90 V〇% of the fluorine-containing gas species. The gas mixture which was found to be particularly suitable for this stage of the process was 2 〇v 〇 1% of an oxygen-containing gas substance and 80 vol% of a fluorine-containing gas substance.

自後者製程階段之富含氟之氣體混合物產生之 中的活性物質比自第-製程階段之富含氧之氣體混== 產生之電漿26中的活性物質更有效地移除殘餘無機填充 劑。結果,與僅使用具有模製材料之僅-組份之較高钱刻 速率之早一氣體混合物的一階段製程相比,自基材Μ上之 文影響區域移除溢料所需要之整個製程時間減少。由本發 明之兩個階段製程所貢獻之製程時間的此總體減少顯著地 增加了系統產量。 八在電漿處理期間,可覆蓋基材2〇之易受電漿損害之部 分’以防止或顯著地降低電裝暴露。每一階段之暴 將取決於電盤#、套 ^ m 1 士 ^ 力率、處理腔室12之特性,及溢料之特徵 旱又)蝕刻速率及製程均勻性將取決於電漿參數, b括(仁不限於)輸入功率、系統壓力及處理時間。 本U克知移除技術之各種缺陷 區域在未借助於、H 4 巧误表材科涛 、式化學㈣技術、機械㈣或使 H月ΛΤ破移除。 ^ 需要的模製用於移除不 士噚層或覆蓋引線框架之電接觸點的溢料薄 121151.doc -13- 200811946 層。此等薄層由封裝由模製材料構成之各別封裝内部的引 線框架所載運之晶粒的模製製程產生。The active material in the production of the fluorine-rich gas mixture from the latter stage of the process is more effective than the active material in the plasma 26 produced from the first stage of the process. . As a result, the entire process required to remove the flash from the affected area of the substrate is compared to a one-stage process using only a gas mixture having a higher rate of the component-only material. Time is reduced. This overall reduction in process time contributed by the two-stage process of the present invention significantly increases system throughput. 8. During the plasma treatment, the portion of the substrate 2 that is susceptible to damage by the plasma may be covered to prevent or significantly reduce the exposure of the electrical device. The storm at each stage will depend on the electric disk #, the set ^ m 1 force rate, the characteristics of the processing chamber 12, and the characteristics of the flash. The etching rate and process uniformity will depend on the plasma parameters, b Including (in addition to) input power, system pressure and processing time. The various defects of the Ukrain removal technology are removed by means of H 4, the accidental material, the chemical (4) technology, the mechanical (4) or the H-moon. ^ The required molding is used to remove the non-swarf layer or cover the electrical contact points of the lead frame. 121151.doc -13- 200811946 Layer. These thin layers are produced by a molding process that encapsulates the die carried by the lead frames inside the respective packages of molded materials.

在使用時且參看圖1 ’將基材20定位於處理腔室12内部 之處理空間14中的適合於電漿處理之位置處。接著,藉由 真空泵16來抽空處理空間14。在兩個製程階段期間,自^ 理氣體源18引人處理氣體流以將處理腔室η中之部分真= 升高至適合的操作壓力,通常在約150 mT〇rr至约25二 mTon·之範圍内,且較佳在約8〇〇之範 圍内’以用於提供增強之餘刻速帛,同時以真空㈣來主 動地抽空處理空間14。激勵電源22以用於將電功率供應至 電極台座24,該電極台座24在處理空間14中鄰近於基材 產生電漿26,且對電極台座24進rDC自偏壓。 將基材20在兩階段處理製程中暴露至電漿持續足夠用於 自基材20上之區域移除以溢料之形式之過量模製材料的個 別階段暴露日㈣。具體言之,將基材轉露至自含氧氣體 物質與含氟氣體物質之富含氧之氣體混合物所產生的第一 電衆持續足以大體上移除溢料之有機基f的持續時間。在 移除模製材料之非微粒組份的此第一階段期間,有機基質 之$刻速率大於無機填充劑之蝕刻速率。接著,將基=2〇 暴露至自含氧氣體物質與含氟氣體物質之富含氟之氣體混 合物所產生的第二電漿持續足以大體上移除溢料之無機填 充劑的持續時間。在移除模製材料之微粒組份的此第二階 段期間,無機填充劑之蝕刻速率大於有機基質之蝕刻速 率。 121I51.doc -14· 200811946 ~將基材20暴露至第—及第二電㈣而無需自處理腔室 12移除基材20(亦即,當處理氣體混合物變化時,不熄滅 電漿)。較佳地,基材20在處理製程之兩個階段期間保持 於同-處理位置中。可根據需要而迭代或重複該兩個製程 階段以完成溢料移除,其可取決於溢料厚度。在完成處理 製程之第二階段之後,熄滅電漿 _ Λ % 然而,在斷開功率之 别或之後’可能存在與溢料移除益 夕于、熟關之頜外電漿處理步 驟。 參看圖2且在本發明之替代性實施例中,處理製程之第 二基於電漿之製程階段可由基 制 街丞於非電漿之製程(諸如化學 衣程、機械製程或化學與機械掣 戍械I私之組合)替代。由盔機 填充劑構成之粒子28(亦即,模製材料之微粒組份)在第— ^程階段大體上移除有機基質之結束之後保持於基㈣之 一區域上。在移除有機基質 拉丄、 貝之後,精由此等化學及/或機 械製程而可易於接取粒子28以供移除。 藉由將基材20暴露至清潔台 〇之%纟兄,可大體上移除粒The substrate 20 is positioned at a location suitable for plasma processing in the processing space 14 inside the processing chamber 12 when in use and with reference to Figure 1 '. Next, the processing space 14 is evacuated by the vacuum pump 16. During the two process stages, the process gas stream 18 introduces a process gas stream to raise a portion of the process chamber η to a suitable operating pressure, typically from about 150 mT rr to about 25 m mon. Within the range, and preferably in the range of about 8 ', is used to provide enhanced reverberation speed while actively evacuating the processing space 14 with vacuum (d). The power source 22 is energized for supplying electrical power to the electrode pedestal 24, which produces a plasma 26 adjacent to the substrate in the processing space 14, and is self-biased by rDC to the electrode pedestal 24. Exposure of substrate 20 to the plasma in a two-stage process continues for a sufficient period of exposure time (4) for excess molding material in the form of flash to be removed from the area on substrate 20. Specifically, the first electricity generated by the substrate being exposed to the oxygen-rich gas mixture from the oxygen-containing gas species and the fluorine-containing gas species continues for a period of time sufficient to substantially remove the organic radical f of the flash. During this first phase of removal of the non-particulate component of the molding material, the organic substrate has a higher engraving rate than the inorganic filler. Next, the base = 2 暴露 is exposed to a second plasma produced from the fluorine-containing gas mixture of the oxygen-containing gas species and the fluorine-containing gas species for a duration sufficient to substantially remove the inorganic filler of the flash. During this second stage of removing the particulate component of the molding material, the etch rate of the inorganic filler is greater than the etch rate of the organic substrate. 121I51.doc -14· 200811946 ~ The substrate 20 is exposed to the first and second electricity (four) without removing the substrate 20 from the processing chamber 12 (i.e., when the process gas mixture changes, the plasma is not extinguished). Preferably, substrate 20 is maintained in the same-processing position during both stages of the processing process. The two process stages can be iterated or repeated as needed to complete the flash removal, which can depend on the flash thickness. After the second stage of the process is completed, the plasma _ Λ % is extinguished. However, after the power is turned off or after, there may be an external plasma processing step that is beneficial to the removal of the flash. Referring to Figure 2 and in an alternative embodiment of the present invention, the second plasma-based process stage of the process can be performed by a non-plasma process (such as chemical process, mechanical process, or chemical and mechanical process). Replacement of the weapon I private). The particles 28 (i.e., the particulate component of the molding material) composed of the helmet filler are held on one of the bases (4) after the end of the organic removal of the organic substrate in the first stage. After removal of the organic matrix, the particles and the mechanical process can be readily accessed for removal by chemical and/or mechanical processes. By removing the substrate 20 to the cleaning station, the particles can be substantially removed.

子28。有利地,可在清潔A u ,、口 〇中私除來自模製材料之大體 上所有粒子2 8 ’以在不會對其士 七比、 曰對基材表面引入顯著的缺陷密度 之炀況下在基材表面上提伴女 ^ 扠仏大體上無粒子28之區域。經清 β之基材區域可包含整個基 才表面或總表面區域之一部 刀。在處理製程之第一製程士 #、、、°束之後,有機基質之殘 餘夏可保持黏附至粒子28, ^ ^ 口此,猎由非電漿製程來移 除0 /月 >乐台3 0可包括一由_或客 -夕個刷子所構成之洗滌器,該 121151.doc 200811946 或該等刷子鞋ώ ι 刷洗製程而自基材2〇至少部分地移除粒 心:土材2〇固持於清潔台30中,使得承載粒子28之表 =不文阻’此為清潔提供接取。洗滌器之每一刷子具有通 常由聚合物(諸如聚乙酸乙烯酉旨(PVA))所形成之鬃毛,其 接觸基材2G之承載粒子⑽表面且自該表面清掃粒子μ。 刷子鬃毛對基材20所施加之壓力足夠低,使得基材2〇不受 仙及由刷洗作用所引起之類似行為的損害。然而,鬃毛 、皆土材2G所%加之麼力應足以將粒子與刷子 增加至可克服相關聯之黏著力處的點。 μ刷子可為(例如)功率驅動之圓筒形刷子,其具有呈現圓 Π $刷洗表面之從向突出之集毛。可在一對此等圓筒形刷 子之間運送基材20,使得刷洗作用為雙側的,或者,鬃毛 可僅接觸基材2G之-側。或者,刷子可為旋轉襯塾,其具 有-大體上平行之鬃毛陣列’該等#毛接觸基材Μ之一或 兩側且壬現一平坦刷洗表面。若基材2〇之一側不需要刷 洗,則可將刷洗作用限制至基材2〇之被粒子28污染的側。 藉由提昇鬆齡子28之以或吸力,可_或另外增大 刷先作用刷子亦可經組態以將清潔液流傳遞至基材別以 用於鬆散粒子28之流體輔助移除。熱亦可用以添加至或促 進粒子移除。本發明預期能夠自基材20消除粒子28之其他 類型的構造。 田暴路至π溧。3 0之壞境時,基材2〇可由塔盤或夾具 (未圖示)支撐。共同讓渡之美國申請案第11/〇〇3,〇62號中 揭示了適合用於«處理系統10之電漿處理期間且隨後適 121151 .doc -16- 200811946 σ用於清潔台30之粒子移除期間的夹具,該申讀案以全文 引用的方式振人士 ^ i ^ 1汁入本文中。或者,不同夾具可用於電漿處理 系先1〇及巧潔台30中。可自處理腔室12運送基材20,且當 駐留於夾具上時,將基材20引入至清潔台30中。 可在清潔台30中使用不依賴於液體清潔劑且不依賴於接 其他乾燥製程,以用於自基材20移除粒子2S之至少一 在本备明之乾燥製程替代性實施例中,清潔台3 0可 一或多個高壓空氣喷射,其引導衝擊基材20之空氣流 〆八戽體"!L。空氣流與基材2 0之衝擊促使移除粒子2 8。 。。 乾秌製耘替代性實施例中,清潔台30可包括一雷射 ,/、此夠以具有適於汽化粒子28之波長的輻射束來切除 粒子2 8。可脸, γ / 、 將啫如鼠之反應性氣體引導至射束周圍之區 / 乂有助於雷射輻射與粒子28之間的化學反應。 在又—乾燥製程替代性實施例中,清潔台3何包括一紅 外加熱裝置’其藉由調諧紅外輻射之頻率以匹配粒子之構 成材料的振動頻率來移除無機填充劑之殘餘粒子,該紅外 加熱裝置相對於基材20選擇性地加熱粒子28。以此方式將 =子28加熱至—汽化溫度以用於作為揮發性物質来移除。 乾燥製程替代性實施例中’清潔台3〇可包括c〇2或 虱低溫喷射裝置,其藉由涉. 旦 /曰、,、工賀射物質至粒子28之動 里轉移的物理力來移除粒子28。 ^ 右粒子28帶電,且在另一 乾丈木I %替代性實施例中青潔 除m 办σ30可包括-有效用以移 除或埂轉粒子28上之靜電電荷之裝置。 子邮基材2〇之間作用的吸引力來促進對粒子28之㈣。 121151.doc -17- 200811946 在又—乾燥製程替代性實施例巾,清潔台30可 於移除粒子28之真空或吸力。 、^藉由通_依賴於用以執行表面清潔之液劑(其擺脫 土 、…機填充劑之殘餘粒子28)的移除技術來移除粒 子2_8二為此且在本發明之替代性實施例中,清潔台30可包 括族射頭’其將清潔液之蔟射噴射於基材20上。該蔟射 ,可由各發射清潔液流以衝擊基材2()之了或多個個別喷嘴 ^忒巧泳液可為水,較佳經去離子或超純的,且可含 2 一溶解添加劑,諸如界面活性劑,其可防止在粒子則 Γ材Γ:“除之後粒子28重新附著或重新沈積於基材2。 ml液亦可包合一酸性水溶液”諸如經緩衝之氫氟酸 ⑽白〜卜清潔液潤濕基材2G ’且當該清潔液流過基材 洗救·^材2G排"’該清潔液自基材20之表面遷移或沖 之L動之至少一部分。可藉由旋轉基材20來促進清潔液 清潔台30内部之用……排“,或將其收集於 ,·、击 用於過慮以移除粒子以的承接盤(catch ηΓ ’使得可再循環該m基㈣上之殘餘清潔 液可藉由空氣乾燥或藉由乾燥器中。、 除,且可包括旋轉以促進液體歸。,、、、乾燥製程來移 之::IV ΐ或聲學壓力波施加至來自與清潔台30相關聯 Α材或聲學傳感器的清潔液’可增大被喷射於 “才0上之以液的清潔作用。該等傳 於選擇'!傳遞或未聚焦以用於廣域傳遞。聲學塵力: 粒子黏著力以促進對粒子28自 之移除,且可促使將 121J51.doc 200811946 粒子28自基材2〇推開以減小或防止重新附著。若基材2〇之 表面具有突出構形,則將聲學麗力波施加至清潔液可能尤 其增強粒子移除。聲學麼力波可在約20 kHz至約4〇〇 kHz 之門的起曰波頻率範,圍内或在约35〇與!顚乙之間的超高頻 音波頻率範圍内。 在本發明之替代性實施例♦,清潔台30可包括填充有清 潔液浴之貯槽。㈣㈣浸沒於該浴巾持教以自基材別 ^之裝載微粒之區域移除粒子2 8之至少—顯著部分的持續 守間在被况,又時,可旋轉、振盪或另外在浴内移動基材 2〇以進一步促進粒子清潔。可根據需要而將基材別部分地 次沒於浴中或完全浸沒於浴中以清潔粒子28。經移除之粒 子28可懸浮於浴中或可積聚於貯槽之一部分中。清潔有效 性將取決於清潔液之溫度與化學性質及浸沒時間。 /月泳台30可進一步包括一聲學或音波傳感器,其與浴連 通以用於執行非接觸清潔。在將基材2〇浸沒於浴之清潔液 中之後,將基材20暴露至來自傳感器之高頻聲學壓力波持 ,足以藉由自基材2 0去除粒子2 8之至少一部分來促進清潔 的%間。聲學壓力波在浴中自傳感器傳播穿過由清潔液所 界疋之轉移介質至承載粒子28之基材2〇。聲學壓力波將能 昼轉移至基材20及殘餘無機填充劑之粒子28,其可用於自 基材20清潔及去除無機填充劑之殘餘粒子28。選擇傳感器 之操作之頻率(且因此選擇聲學波之頻率)以促進有效的攪 動及粒子移除。聲學壓力波可在約2〇 kHz至約400 kHz之 間的超音波頻率範圍内或在約35〇 kHz與1 MHz之間的超高 121151.doc 19 200811946 頻音波頻率範圍内。適合的傳感器包括(但不限於)壓電裝 置:清潔有效性可取決於麼力波之強度、清潔液之溫度與 化學性質、清潔時間,及基材定向。 在本發明之另一替代性實施例中,清潔台30可包括一研 ' 冑絲’其載運為漿料形式之液體清潔劑以有效甩於移除 粒子28。該漀料可包含:液體化學载劑,其與粒子28以化 學方法相互作用;及化學載劑中所載運之研磨微粒… • ^磨概塾相對於基材2〇之運動合作以用於移除無機填綠 材料之殘餘粒子28。精嫁地選擇及控制漿料組份,以便在 自基材20之表面移除最小量之材料時移除無機填充劑材料 之殘餘粒子2 8。 "用於移除無機填充騎料之殘餘粒子2 8之此等非電聚技 術可具有減少全部溢料移除之整個處理時間的益處。結 果,可改良製程產量。 將在以下實例中描述本發明之其他細節及實施例。 • 實例 根據本發明,以兩階段電漿製程來處理载運許多模製封 裝且在?丨線框架之電5丨線上具有可觀察之溢料㈣線框 ^以製造封裝之模製材料為填充:氧切之環氧樹 知。第-製程階段使用CF4(80sccm)及〇2(32〇sccm)之氣體 混合物(根據進入電槳腔室之流動速率而量測)以在彻 mT叫腔室塵力時形成電漿。將引線框架暴露至該電聚 持續大約五(5)分鐘。電聚功率在13 56 MHz之操作頻率時 為約5〇〇瓦特。當檢測引線框架時,觀察到第一階段有效 121151.doc -20- 200811946 地移除薄區域中之環氧樹脂。 在移徐被氧樹脂之絲 一" 麦,一虱化矽填充劑保持於引線框架 上作為殘餘物。在引 將七古 引線框架仍在處理腔室内部且未熄滅電 ^_ &况下,轉變氣體混合物以與處理製程之 弟一階段符合。接菩,# η 者弟二階段使甩CF4(240 sccm)及 / ⑽)之氣體混合物,其再次產生_町。叮之腔室 屋力。將引線框架暴露至此電漿持續大約五(5)分鐘。電, 功率在之操作頻率時為⑽q瓦特。在該處理之 ==之後,移除二氧化石夕填充劑,且觀察到引線框架大 體上無溢料。 雖然已藉由對各種實施例之描述而說明本發明,且雖然 已相當詳細地描述此等實施例,但是申請者之意圖並非將 附加申請專利範圍之範#限制於此細節或以任何方式將附 加申請專利範圍之範嗨限制於此細節。熟習此項技術者將 易於明白額外優點及修改。因此,本發明在其更寬態樣上 )不限於特定細節、代表性設備與方法’及所展示且描述之 說明性實例。因此’在不脫離申請者之通用發明性概令之 精神或範嘴的情況下’可自此等細節做出偏離。本發明之 範疇本身應僅由附加申請專利範圍所界定。 【圖式簡單說明】 圖1為根據本發明用於電槳處理基材之電漿處理系統的 圖示。 、 圖2為根據本發明之替代性實施例用於供圖]之電敗處理 系統使用之清潔台的圖示。 121151.doc -21 - 200811946 【主要元件符號說明】 10 電漿處理系統 12 處理被室 14 處理空間 16 真空泵 18 處理氣體源 20 基材 22 電源 24 電極台座 26 電漿 28 粒子 30 清潔台 121I51.doc -22-Sub 28. Advantageously, substantially all of the particles 28 8 ' from the molding material can be privately removed in the cleaning A u , the mouth so as not to introduce a significant defect density to the surface of the substrate on the substrate. Under the surface of the substrate, the area where the female fork is substantially free of particles 28 is provided. The substrate region of the clear beta may comprise one of the entire base surface or the total surface area. After the first process of the process, #, , ,,,, the residual of the organic matrix remains adhered to the particles 28, ^ ^ mouth, the hunting is removed by the non-plasma process 0 / month > 0 may include a scrubber consisting of a _ or a guest-night brush, the 121151.doc 200811946 or the brush shoe ώ ι brushing process to at least partially remove the core from the substrate 2: soil 2〇 It is held in the cleaning station 30 so that the surface of the carrier particles 28 is not blocked. This provides access for cleaning. Each brush of the scrubber has a bristles typically formed of a polymer, such as polyvinyl acetate (PVA), which contacts the surface of the carrier particle (10) of the substrate 2G and sweeps the particles μ from the surface. The pressure applied by the brush bristles to the substrate 20 is sufficiently low that the substrate 2 is not damaged by the similar behavior caused by the brushing action. However, the bristles and the 2G of the soil should be sufficient to increase the particles and the brush to a point where the associated adhesion can be overcome. The μ brush can be, for example, a power-driven cylindrical brush having a set of hairs that protrude from the upward direction of the brushed surface. The substrate 20 can be transported between such cylindrical brushes such that the brushing action is bilateral, or the bristles can only contact the side of the substrate 2G. Alternatively, the brush may be a rotating lining having a substantially parallel array of bristles that are either one or both sides of the substrate and present a flat brushed surface. If one side of the substrate 2 does not require brushing, the brushing action can be limited to the side of the substrate 2 that is contaminated by the particles 28. By increasing the suction or suction of the pines 28, the brush-action brush can also be configured to transfer the flow of cleaning liquid to the substrate for fluid-assisted removal of the loose particles 28. Heat can also be used to add to or promote particle removal. The present invention contemplates the ability to eliminate other types of construction of particles 28 from substrate 20. Tiancao Road to π溧. In the case of a 30° environment, the substrate 2〇 may be supported by a tray or a jig (not shown). U.S. Application Serial No. 11/3, No. 62, which is incorporated herein by reference, discloses the use of the particles for the cleaning station 30, which is suitable for use in the plasma treatment process of the treatment system 10 and subsequently adapted to 121151 .doc -16 - 200811946 σ During the removal of the fixture, the application is in the form of a full-text reference to vibrate people ^ i ^ 1 juice into this article. Alternatively, different fixtures can be used in the plasma processing system first and in the smart table 30. The substrate 20 can be transported from the processing chamber 12 and introduced into the cleaning station 30 when residing on the fixture. At least one of the particles 2S for removing particles 2S from the substrate 20 may be used in the cleaning station 30 independent of the liquid cleaning agent and independent of other drying processes. In an alternative embodiment of the drying process of the present specification, the cleaning station 30 may be one or more high pressure air jets that direct the air impinging on the substrate 20 to flow the octopus "! L. The impact of the air stream with the substrate 20 causes the particles 28 to be removed. . . In an alternative embodiment, the cleaning station 30 can include a laser, which is capable of cutting the particles 28 with a beam of radiation having a wavelength suitable for vaporizing the particles 28. The face, γ / , directs the reactive gas of the mouse to the area around the beam / 乂 contributes to the chemical reaction between the laser radiation and the particles 28. In an alternative embodiment of the drying process, the cleaning station 3 includes an infrared heating device that removes residual particles of the inorganic filler by tuning the frequency of the infrared radiation to match the vibration frequency of the constituent materials of the particles. The heating device selectively heats the particles 28 relative to the substrate 20. In this way, = 28 is heated to a vaporization temperature for removal as a volatile material. In an alternative embodiment of the drying process, the 'cleaning station 3' may include a c〇2 or 虱 low-temperature spraying device that is moved by the physical force involved in the transfer of the material to the particle 28 Except particle 28. ^ The right particle 28 is charged, and in another alternative embodiment, the sigma 30 may include a means for effectively removing or twirling the electrostatic charge on the particle 28. The attraction of the sub-mail substrate 2 作用 acts to promote the particle (28). 121151.doc -17- 200811946 In a re-drying alternative embodiment towel, the cleaning station 30 can remove the vacuum or suction of the particles 28. Removing the particles 2_8 by means of a removal technique that relies on the liquid agent used to perform surface cleaning, which is free of residual particles 28 of the filler, and is an alternative implementation of the present invention. In an example, the cleaning station 30 can include a family head that sprays a cleaning liquid onto the substrate 20. The jetting may be performed by each of the emitted cleaning liquids to impinge on the substrate 2() or a plurality of individual nozzles. The water may be water, preferably deionized or ultrapure, and may contain 2 dissolved additives. , such as a surfactant, which prevents the crucible in the particle: "After the particle 28 is reattached or re-deposited on the substrate 2. The ml can also contain an acidic aqueous solution" such as buffered hydrofluoric acid (10) white ~ Bu cleaning liquid wets the substrate 2G 'and when the cleaning liquid flows through the substrate, the cleaning material 2G row " 'the cleaning liquid migrates from the surface of the substrate 20 or at least a part of the L movement. By rotating the substrate 20, the inside of the cleaning liquid cleaning station 30 can be promoted... or "collected," and used to take care of the particles to remove the particles (catch ηΓ 'to make recyclable The residual cleaning liquid on the m-base (four) may be dried by air or by a dryer, and may include rotation to promote liquid return,,,, drying process to move: :IV ΐ or acoustic pressure wave Applying to the cleaning fluid from the coffin or acoustic sensor associated with the cleaning station 30 can increase the cleaning effect of the liquid being sprayed on the "only 0. The transmission is selected or not focused for wide use. Domain Transfer. Acoustic Dust: Particle adhesion to promote the removal of particles 28 and may cause the 121J51.doc 200811946 particles 28 to be pushed away from the substrate 2 to reduce or prevent re-attachment. The surface has a protruding configuration, and the application of the acoustic Lily wave to the cleaning liquid may particularly enhance the particle removal. The acoustic force wave can be in the range of the chopping frequency of the gate from about 20 kHz to about 4 kHz. Or the ultra-high frequency sound frequency range between about 35 〇 and 顚 顚In an alternative embodiment of the present invention, the cleaning station 30 may include a sump filled with a cleaning liquid bath. (d) (d) immersed in the bath towel to remove at least particles from the area of the substrate. - a significant portion of the continuous continuation of the situation, and in turn, can rotate, oscillate or otherwise move the substrate 2 in the bath to further promote particle cleaning. The substrate can be partially absent in the bath or Completely immersed in the bath to clean the particles 28. The removed particles 28 can be suspended in the bath or can accumulate in a portion of the sump. The effectiveness of the cleaning will depend on the temperature and chemistry of the cleaning solution and the immersion time. The stage 30 can further include an acoustic or sonic sensor in communication with the bath for performing non-contact cleaning. After immersing the substrate 2 in the bath cleaning solution, the substrate 20 is exposed to high frequency acoustics from the sensor. The pressure wave is sufficient to promote the cleaning between % by removing at least a portion of the particles 28 from the substrate 20. The acoustic pressure wave propagates from the sensor through the sensor through the transfer medium bounded by the cleaning liquid to the carrier particle Substrate 2 of the substrate 28. Acoustic pressure waves will transfer to the substrate 20 and residual inorganic filler particles 28, which can be used to clean and remove residual particles of the inorganic filler 28 from the substrate 20. Selection of sensor operation The frequency (and therefore the frequency of the acoustic wave) to promote efficient agitation and particle removal. Acoustic pressure waves can be in the ultrasonic frequency range between about 2 kHz to about 400 kHz or at about 35 kHz and 1 Ultra-high between MHz 121151.doc 19 200811946 In the frequency range of the frequency wave. Suitable sensors include, but are not limited to, piezoelectric devices: the effectiveness of cleaning can depend on the strength of the force wave, the temperature and chemical properties of the cleaning fluid, Cleaning time, and substrate orientation. In another alternative embodiment of the invention, the cleaning station 30 can include a dredging wire that is carried as a liquid detergent in the form of a slurry to effectively remove the particles 28. The dip material may comprise: a liquid chemical carrier that chemically interacts with the particles 28; and the abrasive particles carried in the chemical carrier... • The grinding mechanism cooperates with the substrate 2〇 for movement Residual particles 28 other than the inorganic green filler material. The slurry component is selected and controlled to preferentially remove residual particles 28 of the inorganic filler material as the minimum amount of material is removed from the surface of the substrate 20. " These non-electropolymerization techniques for removing residual particles of inorganically filled riders can have the benefit of reducing the overall processing time of all flash removal. As a result, process throughput can be improved. Further details and embodiments of the invention are described in the following examples. • Example According to the present invention, many molded packages are handled in a two-stage plasma process and are in? An observable flash (4) wire frame on the electric 5 丨 line of the 丨 line frame ^ is filled with the molding material for the package: oxygen-cut epoxy tree. The first-process stage uses a gas mixture of CF4 (80 sccm) and 〇2 (32 〇 sccm) (measured according to the flow rate into the paddle chamber) to form a plasma when the chamber dust is called mT. The lead frame is exposed to the electropolymer for about five (5) minutes. The electrical power is about 5 watts at an operating frequency of 13 56 MHz. When the lead frame was inspected, it was observed that the first stage was effective 121151.doc -20-200811946 to remove the epoxy in the thin area. In the case of moving the yoke resin, a sputum filler is held on the lead frame as a residue. In the case where the seven-lead lead frame is still inside the processing chamber and is not extinguished, the gas mixture is converted to conform to the first stage of the processing process. Take the buddhist, # η, the second phase of the 甩 CF4 (240 sccm) and / (10)) gas mixture, which is again produced _ town. The chamber of the house. The leadframe is exposed to this plasma for approximately five (5) minutes. Electricity, power is (10) q watts at the operating frequency. After the == of the treatment, the silica dioxide cermet filler was removed and it was observed that the lead frame was substantially free of flash. The present invention has been described by way of a description of various embodiments, and although the embodiments have been described in considerable detail, the application is not intended to limit the scope of the appended claims. The scope of the additional patent application is limited to this detail. Those skilled in the art will readily appreciate the additional advantages and modifications. Therefore, the invention in its broader aspects is not limited to the specific details, the representative device and method, and the illustrative examples shown and described. Therefore, deviations may be made from such details without departing from the spirit or the generality of the applicant's general inventiveness. The scope of the invention should be defined solely by the scope of the appended claims. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a view showing a plasma processing system for an electric paddle treating substrate according to the present invention. Figure 2 is a diagram of a cleaning station for use with the electrical defeat processing system of the accompanying drawings in accordance with an alternative embodiment of the present invention. 121151.doc -21 - 200811946 [Description of main components] 10 Plasma processing system 12 Treatment chamber 14 Processing space 16 Vacuum pump 18 Gas source 20 Substrate 22 Power supply 24 Electrode pedestal 26 Plasma 28 Particle 30 Cleaning station 121I51.doc -twenty two-

Claims (1)

200811946 十、申請專利範圍: 1 ·種用於自一基材上之一區域移除具有一微粒組份及 非微粒組份之一模製材料量之方法,該方法包含: 將名基材暴路至一有效用以自該區域移除該模製 之該非微粒組份的電漿;及 將該基材暴露至-有效用以自該區域移除該模製材剩 之該微粒組份的非電漿製程。 士明求項1之方法,其中將該基材暴露至該非電漿製程 包含: J該區域中之該模製材料與一有效用以自該區域移除 该微粒組份之清潔液接觸。 3 ·如請求項2之方法,苴中佶哕卩衿击&gt; Μ 、、主 -中使仏域中之该模製材料與該 /月/糸液接觸進一步包含: 』將曰波成讀供至該清潔液以用於增強該微粒組份自 该區域之移除。 4. :請求項2之方法’其中使該區域中之該模製材㈣ 清潔液接觸進—步包含: ^ 在該模製材料與該清潔液接觸時产 製材料。 了冲』冼忒Q域中之該模 5. 如請求項2之方法,其中使該區域 猶 清潔液接觸進_步包含: 中之邊模製材料與該 使該區域中之該模製材料與去離子水接觸。 6·如請求項2之方法,其中使該區 制 清潔液接觸進_步包含: ”之该模製材料與該 121151.doc 200811946 將該基材至少部分地浸沒於該清潔液之— 清潔液來潤濕該區域。 以用該 7.如請求項2之方法,其中使該區域中 清潔液接觸進—步包含: 模1材枓與該 • 將该基材浸沒於該清潔液之一浴中。 • 8.&gt;冑求項2之方法’其中使㈣域中 清潔Μ材枓與該 φ 以该清潔液來噴射該區域中之該模製材料。 I Sr方法’其中使該區域中之該模製材料與該 /月碌液接觸進一步包含: 使該清潔液流過該區域中之該模製材料。 Θ求項1之方法,其中將該基材之該 電漿製程包含·· 次暴路至该非 份刷洗該區域中之該模製材料以自該區域移除該微粒組 • 11.如請求項〗之方法,其中將 電漿製程包含: £域暴露至該非 二或多個高塵空氣噴射衝擊該區域中之模製材料, 而自该區域移除該微粒組份。 r托項1之方法’其中將該基材之該 電漿製程包含·· 巧暴路至该非 的:二自一雷射器之一輻射束引導至該基材之該區域中 軼製材料處以用於汽化該微粒組份。 13.如請求項12之方法,其.進一步包含: 12II51.doc 200811946 將一反應性氣體供應至該區域以促進該輻射束與該微 粒組份之間的化學反應。 14, 如請求項丨之方法,其中將該基材之該區域暴露至該非 電漿製鞋包含: 將紅外輻射引導至該區域中之該模製材料以促進對該 微粒組份之加熱。 15. 如請求項丨之方法,其中將該基材之該區域暴露至該非 電漿製程包含: 將一低溫流體引導至該基材之該區域中的該模製材 料。 16·如明求項丨之方法,其中將該基材之該區域暴露至該非 電漿製程包含: 移除或逆轉該區域中該微粒組份上之—靜電電荷。 17·如請求項1之方法,其中將該基材之該區域暴露至該非 電漿製程包含: 使該區域中之該模製材料與有效用以自該區域移除該 微粒紐份之一研磨襯墊及該研磨襯墊上所載運之一槳料 接觸。 121151.doc200811946 X. Patent Application Range: 1 . A method for removing a molding material having a particulate component and a non-particulate component from a region on a substrate, the method comprising: Roadway to a plasma effective to remove the molded non-particulate component from the region; and exposing the substrate to - effectively removing the particulate component remaining from the molding material from the region Plasma process. The method of claim 1, wherein the exposing the substrate to the non-plasma process comprises: J. the molding material in the region is in contact with a cleaning fluid effective to remove the particulate component from the region. 3. According to the method of claim 2, the smashing &gt; Μ , , the main-medium contact area of the molding material in contact with the / month / sputum further comprises: The cleaning liquid is supplied to enhance removal of the particulate component from the area. 4. The method of claim 2, wherein the contacting of the molding material (four) cleaning liquid in the region comprises: ^ producing a material when the molding material comes into contact with the cleaning liquid. The method of claim 2, wherein the method of claim 2, wherein the region is in contact with the cleaning liquid, comprises: molding the material in the middle side and the molding material in the region Contact with deionized water. 6. The method of claim 2, wherein contacting the zone cleaning liquid into the step comprises: "the molding material and the 121151.doc 200811946 at least partially immersing the substrate in the cleaning liquid - the cleaning liquid To wet the area. The method of claim 2, wherein the contacting the cleaning liquid in the area comprises: molding the material and immersing the substrate in one of the cleaning liquids 8. 8. The method of claim 2, wherein the cleaning material in the (four) domain is sprayed with the cleaning material to spray the molding material in the region. I Sr method 'where the region is made The contacting of the molding material with the moon liquid further comprises: flowing the cleaning liquid through the molding material in the region. The method of claim 1, wherein the plasma process of the substrate comprises: Sub-storming to the non-partially brushing the molding material in the area to remove the particle group from the area. 11. The method of claim 1, wherein the plasma process comprises: exposing the domain to the non-two or more a high-dust air jet impacts the molding material in the area, The region removes the particulate component. The method of claim 1 wherein the plasma process of the substrate comprises: • a violent path to the non-: a radiation beam from one of the lasers is directed to the substrate The material in the region of the material is used to vaporize the particulate component. 13. The method of claim 12, further comprising: 12II51.doc 200811946 supplying a reactive gas to the region to promote the radiation beam A chemical reaction between the particulate components. The method of claim 1, wherein exposing the region of the substrate to the non-plasma shoe comprises: directing infrared radiation to the molding material in the region Promoting heating of the particulate component. 15. The method of claim 1, wherein exposing the region of the substrate to the non-plasma process comprises: directing a cryogenic fluid to the mold in the region of the substrate The method of claim </ RTI> wherein the exposing the region of the substrate to the non-plasma process comprises: removing or reversing the electrostatic charge on the particulate component of the region. The method of item 1, which Exposing the region of the substrate to the non-plasma process comprises: subjecting the molding material in the region to a polishing pad effective to remove the particulate component from the region and transporting the polishing pad One of the blades is in contact. 121151.doc
TW96119348A 2006-05-30 2007-05-30 Methods of removing extraneous amounts of molding material from a substrate TW200811946A (en)

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