TW200808953A - Process of cleaning a hard surface with zwitterionic copolymer - Google Patents

Abstract

The present invention relates to a process of cleaning a hard surface with a composition comprising a specific water-soluble or water-dispersible copolymer, said process comprises the steps of applying said composition onto said surface in diluted form and leaving said diluted composition to dry on said surface without rinsing said surface.

Description

200808953 (1) Bend Nine, Invention Description [Technical Field] The present invention relates to a method of cleaning a hard surface using a composition comprising a zwitterionic polymer having a defined structure. More particularly, it relates to a method of cleaning a hard surface in a so-called dilution/no-cleaning application, wherein a diluted type of composition comprising a zwitterionic polymer herein is applied to the hard surface and left in the Hard surface to dry. [Prior Art] Manufacturers of hard surface cleaning compositions continue to look for new ingredients that improve the utility of the composition. The present invention relates to a novel constituent for cleaning hard surfaces in so-called dilution/non-cleaning applications, such as flooring, tiles, work surfaces, ceramic surfaces, windows, curtains, covers, mirrors, household goods, etc. . In such a diluted/uncleaned hard surface cleaning application, wherein the hard surface cleaning composition is applied to the hard surface in its diluted form and left on the surface of the hard # to dry without washing the surface, in dilution/none The hard surface appearance obtained after cleaning hard surface cleaning applications is highly tailored. In fact, such a diluted/no-clean hard surface cleaning application not only provides a clean surface, but the hard surface should also exhibit no visible film formation and/or streaking. Furthermore, the hard surface should have a shiny appearance. In addition, providing antifouling properties to the hard surface, i.e., preventing or at least partially reducing soil deposits after the initial cleaning operation, is a desirable property. Furthermore, providing a next cleaning benefit to facilitate subsequent cleaning of the initially cleaned surface is a desirable feature in such diluted/non-cleaned hard surface cleaning applications. -5- 200808953 (2) SUMMARY OF THE INVENTION It has been found that film formation and/or stripe formation and glazing efficacy of compositions used in diluted/non-clean hard surface cleaning applications can be improved. Furthermore, it has been found that the antifouling of the compositions used in diluted/non-cleaned hard surface cleaning applications and the effectiveness of the next cleaning can be improved. Accordingly, it is an object of the present invention to provide a method of cleaning a hard surface using a liquid composition which has good film forming and/or strip forming efficiency, good lustering performance, good antifouling performance and good Useful for the next cleaning. It has been found that this object can be achieved by a method of cleaning a hard surface using a liquid composition as described above. Advantageously, the methods as described herein provide good cleaning performance. Another advantage of the present invention is that the method herein can be used to clean hard surfaces made of different materials, such as glazed and unglazed ceramic tiles, enamel, stainless steel, Inox 8, Formica®, B; Base, non-fluorene vinyl, linoleum, melamine, glass, plastic, and plasticized wood. SUMMARY OF THE INVENTION The present invention relates to cleaning a hard surface using a liquid composition comprising a water soluble or water dispersible copolymer as described below a method comprising the steps of applying a diluted form of the composition to the surface and leaving the diluted composition on the surface to dry without washing the surface. In an alternative embodiment, the invention Also included in this article -6- 200808953 (3)

The NT water-soluble or water-dispersible copolymer is a method of cleaning a hard surface using a liquid composition comprising a water-soluble or water-dispersible copolymer as described below, wherein the method comprises applying the composition of the purified form to The surface is a step in which good film formation and/or stripe formation performance and good light-emitting efficacy are achieved. DETAILED DESCRIPTION OF THE INVENTION φ Cleaning Hard Surface Methods The invention comprises a method of cleaning a hard surface using a liquid composition as described herein. In particular, the invention comprises a method of cleaning a hard surface using a liquid composition comprising a water soluble or water dispersible copolymer as described herein, the method comprising applying a diluted form of the composition to the surface and subjecting the dilution to The step of leaving the composition on the surface to dry without washing the surface. "Hard surface" means herein any type of surface found in a house, such as a kitchen or bathroom, such as a floor, a wall, Tiles, windows, cabinets, sinks, showers, shower curtains, washbasins, washrooms, trays, fixtures and fittings and different materials such as ceramics, vinyl, non-wax vinyl, linoleum, Melamine, glass, Inox®, Formica®, any plastic, plasticized wood, metal or any painted or painted or sealed surface and the like. Hard surfaces also include household appliances including, but not limited to, refrigerators, freezers, washing machines, automatic dryers, ovens, microwave ovens, dishwashers, and the like. In a preferred embodiment of the invention, the hard surface to be cleaned is the floor in 200808953 (4). Preferably, the hard surface to be cleaned in the methods herein is selected from the group consisting of ceramic surfaces. The compositions herein are applied in their diluted form. By "diluted" it is meant herein that the liquid composition is diluted by the user with a suitable solvent, typically water. The composition is diluted to a typical dilution concentration with 10 to 400 times, preferably 10 to 200 times, more preferably 10 to 100 times its weight, before use. The dilution recommended is a dilution of 1.2% of the composition in φ water. Dilution can be carried out just prior to application of the compositions herein to the hard surface to be cleaned, such as in a suitable container, such as a bucket, wherein an effective amount of the liquid composition herein is mixed with water. In a preferred embodiment, the method herein comprises the additional step of diluting the composition with a suitable solvent, preferably water, prior to applying the diluted form of the composition to the hard surface. In the methods herein, the composition is applied to the surface in a manner generally known to those skilled in the art. In fact, the composition can be applied to the surface by pouring or spraying the composition. Alternatively, the composition can be applied using a suitable tool such as a mop or cloth dipped into the diluted composition herein. Additionally, once applied to the surface, the composition can be agitated throughout the surface using a suitable tool. In fact, the surface can be wiped with a mop or cloth. During such a cleaning operation, portions of the compositions herein can be taken from any cleaning tool present, preferably in combination with soil originally present on the surface, and transferred to a bucket or other suitable container. Medium (twisted mop or cloth), the rest of the composition remains on the surface after the cleaning operation. In fact, the composition preferably remains at least partially on the surface at the end of the method of cleaning the surface of the -8-200808953 (5) yr, more preferably on the surface until the next cleaning operation, More preferably, it remains at least partially on the surface until the next cleaning operation. However, in the method of cleaning a hard surface according to the present invention, the composition is applied to the hard surface in a diluted form without cleaning the hard surface after application. In fact, the composition remains (at least partially) on the hard surface until it is dry. By "cleaning" it is meant herein that, after the step of applying the liquid composition herein to the hard surface, the hard surface cleaned by the method of the invention is contacted directly with a suitable amount of a suitable solvent, typically water. "Solid mass" as used herein means: 0.01 to 1 It water per square meter of hard surface, more preferably 0.1 π to lit water per square meter of hard surface. However, the hard surface cleaned by the method of the present invention may sometimes be cleaned in a subsequent cleaning process. Moreover, due to the normal use of the hard surface cleaned by the methods herein, it is sometimes possible to wet the hard surface by, for example, water or other liquid splashing onto the surface. Such subsequent cleaning methods or accidental hard surfaces should not be considered as surface cleaning within the meaning of the present invention. Moreover, the removal of portions of the composition applied to the hard surface during cleaning, such as by twisting the soiled composition from the mop or cloth, should not be considered as a surface cleaning within the meaning of the present invention. The hard surface to be treated can be soiled with a variety of soils, such as oil stains (such as grease soap, body fat, kitchen grease or burnt/sticky food residues found in kitchens and the like), granulated oil or so-called "Stain with lime flakes". "Stain containing lime flakes" as used herein means any pure lime flake stain, that is, any stain consisting of mineral deposits, -9-200808953 (6), and stains containing lime flakes, that is, not only Mineral deposits such as calcium carbonate and/or magnesium also contain soap (such as calcium stearate) and other oils (such as body fat). The composition of the liquid composition used in the method according to the invention is formulated into a liquid composition 〇φ with a 4 cm mandrel at 20 ° C (from 10 linear to 1 dynes in 2 minutes / In the case of a CSL2 10 0® Rheometer, the preferred composition herein has a viscosity of 1 cps or more at 20 ° C, more preferably 1 to 20,000 cps, and still more preferably 1 to 500 cps. The preferred composition herein is an aqueous composition, and therefore preferably comprises water, more preferably from 50% to 98%, even more preferably from 75% to 97%, and most preferably 80% by weight of the total composition. % to 97%. The acid-base oxime of the liquid composition according to the present invention may typically be from 〇 to 14. In a preferred embodiment, the pH range is from 7 to 14, preferably from 7.1 to 14, more preferably from 7.1 to 13, even more preferably from 7.1 to 12, and most preferably from 8.0 to 10. . In fact, it has been surprisingly found that in these preferred alkaline to neutral pH ranges, it is preferred to improve the grease cleaning performance in the range of alkaline acid and alkali. Therefore, the composition herein may additionally contain an acid or a base to properly adjust the acid-base hydrazine. Suitable acids for use herein are organic and/or inorganic acids. Preferred organic acids for use herein have a pKa of less than 6. Suitable organic acids are selected from the group consisting of citric acid, lactic acid, glycolic acid, succinic acid, glutaric acid and adipic acid, and mixtures thereof-10-200808953 (7). The acid mixture is commercially available from BASF under the trade name Sokalan® DCS. Suitable inorganic acids are selected from the group consisting of hydrochloric acid, sulfuric acid, phosphoric acid, and mixtures thereof. When present, typical concentrations of such acids are from 0.01% to 5.0% by weight of the total composition, preferably from 0.04% to 3.0%, more preferably from 0.05% to 1.5%. Suitable bases for use herein. It is an organic and/or inorganic base. The base to which φ is suitable herein is a caustic such as sodium hydroxide, potassium hydroxide and/or lithium hydroxide, and/or an alkali metal oxide such as sodium oxide and/or potassium or a mixture thereof. The preferred base is caustic, more preferably sodium hydroxide and/or potassium hydroxide. Other suitable bases include ammonia, ammonium carbonate, K2CO3, Na2CO3, and alcohol amines (e.g., monoethanolamine). When present, the typical concentration of such base is from 0. 0 1% to 5.0% by weight of the total composition, preferably from 0. 5 5 % to 3 · 0 %, more preferably from 1% to 〇 6 〇 / 〇Water-Soluble or Water-Dispersible Copolymer The water-soluble or water-dispersible copolymer herein is a water-soluble or water-dispersible copolymer I as described below or a water-soluble or water-dispersible copolymer II as described below. . The water-soluble or water-dispersible copolymer I of the present invention comprises a polymeric unit type: a) at least one monomer compound of the formula i: 200808953 (8)

Ri X* R2 X*R2 R4 X" (i)

I III H2C=C-Z-[CH2]n-N+[A- NTjm-B- N^-Rs

! II R3 R3 R6 where: phantom is a hydrogen atom, methyl or ethyl; r2, R3, R4, 115 and R6 are the same or different and are linear or branched Cl-C6 alkyl, hydroxyalkyl or amine m is an integer from 〇 to 1〇; η is an integer from 1 to 6; Ζ is a -C(0)0- or -C(0)NH- group or an oxygen atom; A is (CH2)P , p is an integer from 1 to 6; B is a linear or branched C2-C12 polymethylene chain optionally intercalated with one or more heteroatoms or hetero groups or optionally by one or more hydroxyl groups or Substituted with an amine group; XI is the same or different, is a counter ion; and (b) at least one hydrophilic monomer which carries a functional acidic group and can be copolymerized with (a) and can be ionized in an application medium (c) optionally, at least one monomeric compound having a neutral charge of ethylene unsaturation and copolymerizable with (a) and (b), preferably having a neutral charge of ethylene unsaturation, carrying one Or a plurality of hydrophilic groups, and a hydrophilic monomer compound copolymerizable with (a) and (b). -12- 200808953 (9) The monomer (a) can be prepared, for example, in accordance with the reaction scheme shown in column 2, line 40 to line 3, line 45 of US 6,569,261 to Rhodia, the disclosure of which is incorporated herein by reference. The resulting water-soluble or water-dispersible copolymers herein have a molecular weight of at least 1 000, advantageously at least 10,000; the range of up to 20,000,000, advantageously up to 10,000, 〇〇〇. Unless otherwise stated, when the term molecular weight is used, it will be referred to as the weight average molecular weight, expressed in grams per hr. The latter can be determined by aqueous gel permeation chromatography (GPC) or by measuring the intrinsic viscosity in IN NaN03 solution at 30 °C. The copolymer is preferably a random copolymer. Preferably, in the formula (i) of the monomer (a), Z is C(〇)0, C(0)NH or Ο, preferably C(0)NH; η is equal to 2 or 3, and In particular, the range of 3; m is 〇 to 2 and preferably equal to 〇 or 1, very particularly 0; B is -CH2-CH(OH)-(CH2)q, and q is 1 to 4, preferably equal to 1; The same or different 11^6 is methyl or ethyl. • The preferred monomer (a) is a quaternary-quaternary ammonium of the formula: ch3 χ- X*

I c=ch2 ch3 oh ch3 I I i ^ 0=C-NH-[CH2]3-N+.CH2-CH-CH2-N^-CH3

I I ch3 ch3 wherein X_ is a chloride ion. Other particularly advantageous monomers (a) are: -13- 200808953 (10) CH3 X' χ· χ·

I c=ch2 ch3 ch3 oh ch3

I I III 0 = C-NH-[CH2]3-N+[CH2]p-N+-CH2-CH-CH2-N+-CH3 CH3 ch3 ch3 ch3 wherein p = 2 to 4. The X anion is especially a halogen, preferably chlorine, sulfonate, sulfate, hydrosulfate, phosphate, phosphonate, citrate, formate and acetate. The monomer (b) is advantageously a C3-C8 carboxylic acid having a monoethylenic unsaturation, a sulfonic acid, a sulfuric acid, a phosphonic acid or a phosphoric acid, an anhydride thereof and a salt thereof and a mixture thereof which are soluble in water. Preferred monomers (b) are acrylic acid, methacrylic acid, _ ethacrylic acid, /3,/3-dimethacrylic acid, methylenemalonic acid, ethionyl acetic acid, allyl acetic acid, and ethylene Acetic acid, propylene glycol, crotonic acid, maleic acid, fumaric acid, itaconic acid, citraconic acid, mesaconic acid, hydrazine-(methylpropyl decyl) alanine, Ν-(acryl fluorenyl) Hydroxyglycine, sulfopropyl acrylate, sulfoethyl acrylate, sulfoethyl methacrylate, styrene sulfonic acid, vinyl sulfonic acid, vinyl phosphonic acid, phosphorus acrylate, phosphine acrylate, Phosphyl acrylate, propyl propyl acrylate, phosphorus ethyl methacrylate, phosphine ethyl methacrylate, phosphopropyl methacrylate, phosphapropyl methacrylate, and alkali metal and ammonium salts thereof, and mixtures thereof. Preferably, any of the monomers (c) includes Ci-C* alkyl esters of acrylamide, vinyl alcohol, acrylic acid and methacrylic acid, acrylic acid and methacrylic acid. 14-200808953 (11) m-

Ci-c4 via alkoxy esters, especially ethylene glycol and propylene glycol propionate and methacrylates, polyalkoxylated esters of acrylic acid and methacrylic acid, especially polyglycol and polypropylene glycol esters , acrylic acid or methacrylic acid with polyethylene glycol or polypropylene glycol (: 1-(325 monoalkyl ether ester, vinyl acetate, vinyl pyrrolidone or methyl vinyl ether and mixtures thereof. monomer (a) concentration It is advantageously from 3 to 80 mol%, preferably from 10 to 70 mol%. The monomer (b) concentration is advantageously from 10 to 95 mol%, preferably from 20 to 80 φ mol%. e) the concentration is advantageously from 0 to 50%, preferably from 0 to 30%. The molar ratio of the cationic monomer to the anionic monomer (a)/(b) is advantageously from 80/20 to 5/95, Preferably, it is 60/40 to 20/80. The water-soluble or water-dispersible copolymer I herein can be obtained according to the known techniques for preparing the copolymer, in particular, the free radical route of the starting ethylenically unsaturated monomer. Polymerization, the monomer is a known compound or can be easily obtained by a person skilled in the art by applying a general organic chemical synthesis method. The method disclosed in U.S. Patent No. 4,3,87,017 and European Patent No. 1,56,646. The radical polymerization is preferably carried out in an oxygen-free environment, for example, in an inert gas (helium, argon, and the like). The reaction is carried out in the presence of nitrogen. The reaction is carried out in an inert solvent, preferably ethanol and methanol, and more preferably in water. The polymerization is initiated by the addition of a polymerization initiator. The initiator used is in the art. Commonly used radical initiators. Examples include organic peroxy esters (tert-butyl peroxypivalate, pentyl peroxypivalate, tert-butyl peroxyethyl α-ethylhexanoate and Similarly; azo-type organic compounds such as azobis-decylpropane hydrochloride, azobisisobutyronitrile, azobis(2,4-dimethylvaleronitrile) and the like; inorganic and organic peroxidation Things, such as -15- 200808953 (12)

Mr. Hydrogen peroxide, benzyl peroxide, butyl peroxide and the like; redox initiation systems, such as those containing oxidants, such as peroxosulfates (especially ammonium peroxysulfate or alkali metal salts) And similar); chlorates and bromates (including inorganic or organic chlorates and / or bromates); reducing agents, such as sulfites and disulfites (including inorganic and / Or organic sulfites or disulfites; oxalic acid and ascorbic acid, and mixtures of two or more of these compounds. A preferred starting agent is a water-soluble starting agent. Sodium peroxodisulfate and azobismercaptopropane hydrochloride are particularly preferred. In an alternative form, the polymerization can be initiated using ultraviolet light illumination. The amount of initiator used is generally an amount sufficient to initiate polymerization. The initiator is preferably present in an amount of from 0.001 to about 5% by weight based on the total weight of the monomers; and preferably less than 0.5% by weight relative to the total weight of the monomers; relative to the total weight of the monomers, A preferred amount is from 0.005 to 0.5% by weight. The starter is added to the polymerization mixture continuously or discontinuously. When it is desired to obtain a high molecular weight copolymer, it is necessary to add a fresh initiator during the polymerization. Gradually • or discontinuous additions also make more efficient polymerizations and shorter reaction times possible. The polymerization is carried out under the reaction conditions of the effective polymerization of the monomer (a), the monomer (b) and the optional monomer (c) in an oxygen-free atmosphere. The reaction is preferably carried out at a temperature ranging from about 30 ° C to about 10 ° C, and preferably at a temperature of from 60 ° C to 90 ° C. An oxygen-free environment is maintained throughout the reaction', e.g., by maintaining nitrogen flow throughout the reaction. The water-soluble or water-dispersible copolymer 1 which is particularly preferred herein is as follows: -16- 200808953 (13)

CHS Η / ‘——NH— ( Ή2— CH« —

Clh X* CH3 X· C= —f ΓΗ 广 CHirf CH2—Cli 卞卞叫一* Cil •nh2 o' where x has an average of 0 to 50 mol%, preferably 0 to 30 mol%, y Having an average enthalpy of from 10 to 95% by mole, preferably from 20 to 80% by mole, Z having an average enthalpy of from 3 to 80% by mole, preferably from 10 to 70% by mole, and y/z The ratio is preferably from 4/1 to 1/2, and x + y + z = 10%, and X, y and z represent derivatives derived from acrylamide, acrylic acid (sodium salt) and diquaternary ammonium, respectively. % of the unit of the mole. The chemical structures of other preferred water-soluble or water-dispersible copolymers I herein are as follows: cih on ch^

Clh ί " I "11 recognition - * NCi I, one CM CM, one Ν ' leaf ΟΊ

• I ΓΗ; X CH% i i — count fH—丫^- ϋ=ί ON1 ΓΌΝ" CH3 NH2 o 〇 where x has a mean value of 0 to 50%, preferably 0 to 3% , y has an average enthalpy of 10 to 95 mol%, preferably 20 to 80 mol%, z has an average enthalpy of 3 to 80 mol%, preferably 1 〇 to 70 mol%, and y/z The ratio is preferably in the range of 4/1 to 1/2; -17 - 200808953 (14) OH CH% i I | —N4 —CH>一CH—CH>一Ν^€Η>·^ΝΗ II t

Ciu X CH', x* c=

' I ~tcH> - one CH meter (3⁄4-c-f- 〇sss:c

I ^ I SO>Na cih mu wherein X has a 〇 to 5 〇 mol %, preferably 〇 to 30 mol % of the average 値, y has 1 〇 to 95 摩尔%, preferably 2 〇 to 8 The average value of 〇mol is 値, z has 3 to 80 moles. /. Preferably, the average enthalpy of from 1 〇 to 7 〇 mol %, and the y/z ratio is preferably from 4/1 to 1/2;

OU ^—Cih—Cli—ml—^cn2irm cu% χ· c=o tuc--Nf—CH-ί II CH, X′ —fCHr—CHirfCfib—CHiTfCH^' nh2

SO^Ha ch3 wherein x has 0 to 50 mol%, preferably 〇 to 30 mol%, and the average 値' y has an average 値10 to 95 mol%, preferably 20 to 80 mol%, z It has an average enthalpy of 3 to 80 旲%, preferably 1 〇 to 7 〇 mol%, and the y/z ratio is preferably from 4/1 to 1/2; 18 - (15) 200808953

Wherein X has a mean enthalpy of from 0 to 50 mol%, preferably from 〇 to 30 mol%, an average 値' y of from 10 to 95 mol%, preferably from 20 to 80 mol%, ζ from 3 to 80 The molar % is preferably an average 〇 of 1 〇 to 7 〇 mol %, and the y/z ratio is preferably from 4/1 to 1/2; H>c one 一(ή2—ch— ("3 x CH? χ C=0 ( H ——CHiTtCHv—C1t~ OH 03⁄4 ONa where x has a G to 50% by mole, preferably 〇 to 30% of the average 値' y has 1 0 to 9 5 mol % ' is preferably an average of 2 〇 to 80 摩尔%, redundant with 3 to 80 mol %, preferably an average of i 〇 to 7 〇 mol %, and y/z The ratio is preferably from 4/1 to 1/2; or -19-200808953 (16) OH II Π3 ('-11-CB)-Cfl γη, rr Γ

-CH 广广N+«t〇i·越NH cn% cr c=〇——CH甘CH2—NH> HjC- r>#c, 〇—c Cti3 *ch2—so3h CHj book where x has 0 to 5 0 The ear %, preferably the average enthalpy of 〇 to 30% by mole, y has an average 値 of 10 to 95% by mole, preferably 20 to 80% by mole, and z has 3 to 80% by mole. Preferably, it is an average of 10 to 7 mole %, and the ratio of y/z is preferably from 4/1 to 1/2. The water-soluble or water-dispersible copolymer II of the present invention comprises a polymeric unit type: d) at least one monomer compound having the formula ii: _ Ri R2 R4 (ϋ)

I II H2C=C-[CH2]n-N^-[CH2]m.C = CH2 X'

I

Rb where:

Ri and R4 are independently a straight or branched alkyl group of H or Cu; R2 and R3 are independently a linear or branched Cb6 alkyl group, a hydroxyalkyl group or an aminoalkyl group, preferably a methyl group; η and m Independent is an integer from 1 to 3; -20- 200808953 (17) X· is _ _ _ sub-compatible with the water-soluble or water-dispersible nature of the polymer; e) at least one having acid functionality and monomer d) copolymerizing a# an ionized hydrophilic monomer in the medium, which is used in the medium; and f) optionally, with one or several hydrophilic groups, copolymerizable with the monomer d) se) The neutral charge of the ethylenically unsaturated hydrophilic monomer compound, the ratio of monomer d) to monomer e) is in the range of from 60:40 to 5:95. More preferably, Ri is hydrogen, R2 is methyl, R3 is methyl, R4 is hydrogen, and m and η are equal to 1. The ion X_ is preferably selected from the group consisting of halogen, sulfate, hydrosulfate, phosphate, citrate, formate and acetate. The monomer (e) and any monomer (f) make the copolymer II hydrophilic. The copolymer II according to the invention advantageously has a molecular weight of at least 1000, advantageously at least 10,0 GG; from up to 20,000,000, advantageously up to 10,000,000. Unless otherwise indicated, when referring to molecular weight, this will be the weight average molecular weight in grams per mole. This can be determined by aqueous condensation 0# Φ Oxygen Chromatography (GPC) or by measuring the intrinsic viscosity at 30 ° C in IN NaC03 solution. Copolymer II is preferably a random copolymer. The monomer (d) preferably has the following structure: ch3 h2c=ch-ch2-n+-ch2-ch = ch2 χ·

I ch3 where x- is as defined above. A particularly preferred monomer (d) is one in which the plant is of the formula C1, which is known to be diallyldimethylammonium chloride; -21 - 200808953 (18) (DADMAC). The monomer (e) is advantageously a water-soluble c 3 · C 8 carboxylic acid, sulfonic acid, sulfuric acid, phosphonic acid or phosphoric acid containing a single ethyl unsaturation, an anhydride thereof and a water-soluble salt thereof. Preferred monomers are selected from the group consisting of acrylic acid, mercaptoacrylic acid, ethacrylic acid, /3,/3-dimethacrylic acid, methylenemalonic acid, vinyl acetic acid, allyl acetic acid, ethylene acetic acid, and sub- Propylacetic acid, crotonic acid, maleic acid, fumaric acid, itaconic acid, citraconic acid, mesaconic acid, strontium-(methylpropanyl) φ alanine, Ν_(acryloyl)hydroxyglycolic acid , sulfopropyl acrylate, sulfoethyl acrylate, sulfoethyl methacrylate, styrene sulfonic acid, vinyl sulfonic acid, vinyl phosphonic acid, phosphorus acrylate, phosphine acrylate, propyl propyl acrylate , phosphine propyl acrylate, phosphorus ethyl methacrylate, phosphine ethyl methacrylate, propyl propyl methacrylate, phosphapropyl methacrylate, and ammonium and alkali metal salts of these acids and mixtures thereof. The monomer (f) is a C i -C 4 alkyl ester selected from the group consisting of acrylamide, vinyl alcohol, acrylic acid and methyl propyl storage acid, ci - c 4 hydroxy alkane ester of acrylic acid and methacrylic acid, especially ethylene Alcohol and propylene glycol acrylates and methacrylates, polyalkoxylated esters of acrylic acid and methacrylic acid, especially polyglycol and polypropylene glycol esters. The monomer (d) content is advantageously from 5 mol% to 60 mol%, preferably from 20 mol% to 50 mol%. The monomer (e) content is advantageously from 〇 mol % to 95 mol % ', preferably from 20 mol % to 80 mol %. The monomer (f) content is advantageously from 〇 mol % to 50 mol %, preferably from 5 mol % to 30 mol %. The molar ratio d:e is preferably from 50:50 to 10:90. The copolymer II of the present invention can be obtained according to the known technique for preparing a copolymer, -22-200808953 (19), in particular, a radical-mediated polymerization by an ethylenically unsaturated starting monomer, the starting list The body is a known compound or can be readily obtained by those skilled in the art, using a general synthetic method of organic chemistry. It is preferred to obtain a water-soluble solution by copolymerizing a monomer having a quaternary ammonium functional group and two groups containing ethylene unsaturation and a monomer having a group capable of ionizing in an application medium to form an anionic unit. The water- or water-dispersible copolymer II' and the ratio of the first monomer to the second monomer are within a given range. The polymerization from φ by the base is described earlier in detail in the association with the agglomerated copolymer I. The following copolymer π is the most excellent: DADMAC / acrylic acid / acrylamide copolymer, DADMAC / maleic acid copolymer, DADMAC / sulfonic acid copolymer, DADMAC / acidic monomer molar ratio of 60:40 to Between 5:95, preferably between 50:50 and 10:90. DADMAC stands for diallyldimethylammonium chloride. Preferred copolymers II are available from Rhodia; alternatives are available from Reckitt-Benckiser under the tradename Merquat 280. Especially good • Copolymer II is

Preferred water soluble or water dispersible copolymers herein are available from Rhodia. In the composition of the present invention, the water-soluble or water-dispersible copolymer herein is preferably present in an amount of from 0.001% to 10% by weight based on the weight of the composition, more preferably from 5% to -23 to 200808953 ( 20) 1%, the best is o.oi% to 0.5%. It has been found that the presence of specific water-soluble or water-dispersible copolymers in the liquid compositions used to clean hard surfaces in diluted/non-clean applications provides improved film formation and/or streak formation performance and improved Brightening efficacy is compared to the use of a composition that does not contain the specific water-soluble or water-dispersible copolymers herein for the same diluted/non-cleaned hard surface cleaning application. In addition, it has been found that the presence of a particular water-soluble or water-dispersible copolymer herein can be used in a liquid composition for cleaning hard surfaces in a diluted/non-cleaning application using the method of the present invention. Provides improved stain resistance to the hard surface after the initial cleaning operation. Furthermore, the presence of a particular water-soluble or water-dispersible copolymer herein in the liquid composition used to clean the hard surface during dilution/non-cleaning applications can be initially cleaned using the compositions of the present invention in accordance with the methods of the present invention. The improved next cleaning performance is then provided to the hard surface. Because of its nature, after cleaning applications with diluted/non-cleaned hard surfaces, the residue remains on the hard surface being cleaned in this application. In fact, since the cleaning composition applied to the surface is not cleaned from the surface, the cleaning composition and a portion of the dirt present on the hard surface remain substantially on the surface (the other portion is used as needed for dilution/ Any tool that is not cleaned and cleaned (such as a mop) is taken away). Such residues often result in visible film and/or streaks on the cleaned hard surface and may disrupt the hard surface of the hard surface. Furthermore, the cleaned surface is susceptible to contamination due to its normal use. In fact, different types of markings, dirt, stains and the like are deposited on hard surfaces after use (for example, dirt stuck to the sole falls on the floor). -24- 200808953 (21) Surprisingly, it has been found that the liquid composition used in cleaning applications including the copolymer in a diluted/non-cleaned hard surface provides an increase in residue remaining on the hard surface after cleaning ( A composition that is transparent after drying. This increase in transparency results in less or no visible residue, which in turn helps the film and/or the stripe to be almost or even not visible on the cleaned hard surface, and is also cleaned. The improved shine of the hard surface helps. In addition, it has been surprisingly found that on the hard surface initially cleaned with φ according to the method of the present invention, the soil deposit is reduced or even prevented. In fact, the so-called antifouling properties were observed. Moreover, it has been surprisingly found that the next cleaning benefit was observed on the hard surface initially cleaned with the composition of the present invention using the method of the present invention. In fact, subsequent cleaning operations on the initially cleaned surface are facilitated. In an alternative embodiment, the invention also encompasses the use of a water soluble or water dispersible copolymer herein to clean a hard surface using a liquid composition comprising a water soluble or water dispersible copolymer herein, wherein # The method comprises the step of applying a composition of the pure form to the hard surface, wherein there is good film forming and/or strip forming efficiency and good lightening performance. "Precision type" means herein the liquid composition Directly applied to the surface to be treated, but not diluted by the user prior to (immediately) application, i.e., the liquid composition herein is applied to a hard surface as described herein. It has been found that the water solubility of the liquid compositions used to clean hard surfaces is comparable to the use of compositions containing no specific water soluble or water dispersible copolymers herein, in the same pure hard surface cleaning applications used to clean hard surfaces. Water Dispersibility - 25 - 200808953 (22) The presence of a copolymer may provide improved film formation and/or stripe forming performance as well as improved shine performance. Because of its nature, after a hard surface cleaning application, the residue can remain on the hard surface cleaned for this application. In fact, after a clean cleaning application, the cleaned hard surface may or may not be cleaned. Even if the hard surface is cleaned after a clean cleaning application, the residue of the cleaning composition (although diluted) can remain on the hard surface due to insufficient cleaning and increased concentration due to the initial application to the φ hard surface. Therefore, the cleaning composition and a part of the dirt existing on the hard surface can remain on the surface. Such residues often result in visible films and/or streaks on the cleaned surface and can distort the hard surface. Surprisingly, it has been found that the inclusion of the copolymer in the liquid composition used in neat hard surface cleaning applications provides a composition that increases the transparency (after drying) of the residue remaining on the hard surface after cleaning. Things. As listed above, this increase in transparency results in less or no visible φ residue, which in turn contributes significantly to the fact that the film and/or stripes are hardly or even partially visible on the cleaned hard surface. It also helps to improve the shine of the cleaned hard surface. Film Forming / Stripe Forming and Brightening Test Method Film Forming/Strip Forming and Brightening Efficacy of Dilute Hard Surface Cleaning Compositions were evaluated using the following test methods: Hard surface cleaning compositions were diluted to 1.2% concentration in normal tap water (Decontamination solution), adjusted with CaCl2 as needed to achieve the desired special hydraulic hardness of -26-200808953 (23), mostly 16gpg. Apply 19 grams (+ /·〇.2g) of the decontamination solution to the Vileda® cloth (20 cm χ 9 cm), then gently wipe the four black-gloss ceramic tiles (each 2 (^ 2 5 cm), about 1 gram (+ / - 〇. 2 grams) of the decontamination solution is left on the tile. After that, the tile is at constant temperature (22 t ) and constant humidity (30-40% relative) Under static humidity, it was left to dry and was not cleaned. It was estimated by visual evaluation that the tile cleaned with the polymer-containing washing solution was compared to the tile cleaned with the same but no polymer-containing washing solution. Film formation/streak shaping and/or illuminating efficacy can be assessed by visual grading. Visual grading can be performed by a panel of skilled personnel using a strip score unit (PSU). To evaluate film formation of a given composition / For stripe shaping and/or illuminating performance, PSU scales can be applied, with a range of 0 (film formation/strip formation and/or illuminating impression indicating the difference between the given compositions, as well as film formation/strip formation). Not bright) to 6 (specify good film formation / strip for a given composition Forming and/or illuminating impressions, also # and no visible film forming/stripe forming; superior brightness. The film forming/streaking and illuminating performance of the undiluted hard surface cleaning composition was evaluated using the following test methods. 1 ml of hard surface cleaning composition is applied neatly to two black glossy ceramic tiles (each 20x25 cm), then gently wiped with wet Vileda® cloth (20 cm x 9 cm, containing 10 g water) After this, the Vileda® fabric was twisted 10 times under running tap water. The tile was cleaned twice with this twisted/washed Vileda cloth (containing 10 grams of water) at constant temperature (22 ° C) and constant Allow to dry and dry under wet (3 0-40 relative humidity) -27- 200808953 (24) The film formation/stripe forming and/or illuminating efficacy of the composition can be evaluated by visual grading as described above. Antifouling and next time Cleaning Benefit Test Method The following test method was used to evaluate the next cleaning/antifouling performance of the diluted hard surface cleaning composition. By using Wet Abrasian φ Scrub Tester-Ref. 903PG/SA/B" from Sheen Instruments Limited, which is One with 4 cleaning tracks 4 linear washers for sponge holders, pre-treated clean white ceramic tiles (ex Villeroy & Bosch® UT01 Serie Unit 1-size 7x25 cm) with the product to be analyzed and referenced. Two cleaning For the track, use a 20 ml (+ / -0.2 ml) 1.2% detergent solution (see above for preparation) of a wet sponge (yellow cellulose sponge, Type 7 ex Spontex US-wet sponge total weight = 22 g + /-2 g) was pre-adjusted and the other two cleaning tracks were preconditioned with a 1.2% wash solution containing 20 ml (+ / -0.2 ml) of reference detergent solution. The tiles were pretreated for 20 cycles, and then the tiles were dried at a constant temperature (25 ° C) and humidity (70% relative humidity) for at least 2 hours, preferably overnight. A soil mixture of the polymerized oil and the particulate soil was prepared and 0.08 5 grams of the soil mixture was uniformly dispersed on the pretreated tile. After application, the contaminated tiles are allowed to stand for 3-5 hours at a constant temperature (25 ° C) and humidity (70% relative humidity), preferably overnight. To interactively evaluate the cleaning performance of the test and reference detergent solutions, record the use of the above, 'Wet Abrasian Scrub Tester' with a 1.2% decontamination associated with 20 -28 - 200808953 (25) liters (+ / -0.2 mL) The number of times the sponge of the solution is contacted with any component'. The liquid composition according to the present invention may contain different optional components according to the desired technical benefit and the surface to be pretreated. Any suitable components used herein include surfactants and constructs. , chelating agents, polymers, buffers, bactericides, preservatives, hydrotropes, colorants, stabilizers, free radical scavengers, bleaches, bleach activators, enzymes, soil suspending agents, dye transfer agents, brightening Agents, dusting agents, dispersants, dye transfer inhibitors, pigments, polyalkylenes, perfumes and/or dyes. Surfactants The compositions herein may comprise nonionic, anionic, zwitterionic and amphoteric surfactants. And mixtures thereof. The surfactant is preferably present in an amount of from 1% to 20% by weight of the composition herein. Suitable surfactants Those selected from the group consisting of nonionic, anionic, zwitterionic and amphoteric surfactants having a hydrophobic chain of from 8 to 18 carbon atoms. Examples of suitable surfactants are described in M c C ut che ο η ' s V ο 1 · 1 : E mu 1 sifiers and Detergents, North American Ed., McCutcheon, MC Publishing Co., 2 002. Preferably, the aqueous composition comprises from 0.01% to 20%, preferably from 0.5% to 10% %, and most preferably from 1% to 5% surfactant. -29- 200808953 (26) Nonionic surfactants are highly preferred for use in the compositions of the invention. Suitable for nonionic surface actives. Non-limiting examples of the agent include alcohol alkoxides, alkyl polysaccharides, amine oxides, block copolymers of ethylene oxide and propylene oxide, fluorosurfactants, and cerium-based surfactants. The aqueous composition comprises from 0.01% to 20%, more preferably from 0.5% to 10%, and most preferably from 1% to 5%, of a nonionic surfactant. A preferred class of nonionic surfactants for use in the present invention. Is an alkyl φ ethoxylate. The alkyl ethoxylate of the present invention Linear or branched, and containing 8 to 16 carbon atoms in the hydrophobic tail chain, and 3 ethylene oxide units to 25 ethylene oxide units in the hydrophilic head group. Examples of alkyl ethoxylates Includes Neodol 91-6®, Neodol 91- supplied by S he 11 C 〇r ρ 〇rati ο η (P · Ο . Β ο X 2 4 6 3, 1 S he 11 P 1 aza, Houston, Texas) 8® and A1 fonic 8 1 0-6 0® supplied by Condea Corporation (900 Threadneedle PO Box 1 9029, Houston, TX). More preferably, the alkyl ethoxylate contains from 9 to 12 carbon atoms in the hydrophobic tail chain and from 4 to 9 • oxide units in the hydrophilic head group. The most preferred alkyl ethoxylate is C9-iiE05, available from Shell Chemical Company under the tradename Neodol 91-5®. Nonionic ethoxylates can be derived from branched alcohols. For example, the alcohol can be made from a branched olefinic feedstock such as propylene or butene. In a preferred embodiment, the branched alcohol is 2-propyl-1-heptanol or 2-butyl-1-octanol. The desired branched alcohol ethoxylate is 2-propyl-1-heptyl E07/A07, which is manufactured and sold by BASF Corporation under the trade name Lutensol XP 79/ XL79. Another class of nonionic surfactants suitable for the present invention are the alkyl poly-30-200808953 (27) saccharides. Such surfactants are disclosed in U.S. Patent Nos. 4,565,647, 5,776,872, 5,8, 83,062 and 5,906,973. Among the alkyl polysaccharides, alkyl polyglycosides containing 5 and/or 6 carbon sugar rings are preferred, while those containing 6 carbon sugar rings are preferred, and those having a derivative derived from glucose. A 6 carbon sugar ring, such as an alkyl polyglucose ("APG"), is optimal. The APG chain long alkyl substituent is preferably a saturated or unsaturated alkyl moiety having 8 to 16 carbon atoms and an average chain length of 10 carbon atoms. C8-C16 alkyl polyglucose ^ is commercially available from a variety of suppliers (eg, Simusol® surfactant available from Seppic Corporation, 75 Quai d 9 Or say 5 7 5 3 2 1 Paris, Cedex 7? France, Glucopon 220® from Cognis Corporation, Postfach 13 01 64, D 40 5 5 1, Dusseldorf, Germany,

Glucopon 225®, Glucopon 425®, Plantaren 2 0 0 0 N®, Plantaren 20 00 N UP®). Another class of nonionic surfactants suitable for the present invention are amine oxides. Amine oxides, especially those containing from 10 carbon atoms to 16 carbon atoms in a hydrophobic chain, are effective because they have a strong cleaning effect and utility even below 0.10%. In addition, c1G_16 amine oxides, especially (12-14 amine oxides, are superior perfume solubilizers. Alternatively, the nonionic detergent surfactants used herein typically comprise from 8 to 16 carbons. An alkoxylated alcohol in the hydrophobic alkyl chain of an alcohol. A typical alkoxylated group is a propoxy group or a combination of an ethoxy group and a propoxy group which produces an alkyl ethoxypropoxy group. This compound is commercially available from Rhodia (40 Rue de la Haie-Coq F-933 06, Aubervilliers C6dex, France) under the trade name Antarox® and from Shell Chemical under the trade name Nonidet®-31. - 200808953 (28) Also suitable for use in the present invention is a fluorinated nonionic surfactant. A particularly suitable fluorinated nonionic surfactant is Fluorad F170 (3M Corporation, 3 M Center, St. Paul, MN, USA) o Fluorad F170 has the formula C8F17S02N(CH2-CH3)(CH2CH20)x. Also suitable for use in the present invention is a ruthenium-based surfactant. One example of these forms of surfactant is available from Dow. Chemical (1691 N. Swede Road, Midland, Michigan, USA) Silw Et L7604 The condensation product of ethylene oxide with a hydrophobic base formed by the condensation of propylene oxide with propylene glycol is also suitable for use herein. The hydrophobic portion of these compounds preferably has a molecular weight of from 1500 to 1800 and is water insoluble. The addition of the polyoxyethylene moiety to the hydrophobic portion results in an increase in the water solubility of the entire molecule, and the liquid character of the product is maintained up to a point where the polyoxyethylene content accounts for about 50% of the total weight of the condensation product, which corresponds to a maximum of 40 moles of ethylene oxide. Condensation. Examples of compounds of this type include certain commercially available Pluronic® surfactants marketed by BASF. Chemically, such surfactants have 0〇)\(?〇8〇)2 Or (PO)x(EO)y(PO)z, wherein X, y and z are from 1 to 100, preferably from 3 to 50. Pluronic® surfactants are known to be good wetting surfactants and are even better. Descriptions of Pluronic® surfactants and their properties, including wetting properties, can be found in the booklet entitled "BASF Performance Chemicals Plutonic® & Tetronic® Surf actants" from BASF. Other suitable but not preferred nonionic surfactants include polyoxyethylene condensates of alkyl alcohols, for example, having a linear or branched chain configuration from 6 to 32-200808953 (29) to 12 carbon atoms. A condensation product of an alkyl alkylphenol with ethylene oxide in an amount equal to 5 to 25 moles of ethylene oxide per mole of alkylphenol. The alkyl substituents in such compounds may be derived from oligomeric propylene, diisobutylene, or other sources derived from isooctane, n-octane, isodecane or n-decane. Other nonionic surfactants which may be used include those derived from natural sources, such as sugars, and include Cs-Q6 N-alkylglucamide surfactants. φ Anionic surfactants as used herein are generally known to those skilled in the art. Preferably, the anionic surfactants used herein include alkyl sulfonates, alkyl aryl sulfonates, alkyl sulfates, alkyl alkoxylated sulfates, C6-C2Q alkyls. Alkoxylated straight or branched diphenyl oxide disulfonates or mixtures thereof. Alkyl sulfonates suitable for use herein include the water-soluble salts or acids of the formula rso3m wherein R is a C6-C2() straight or branched saturated or unsaturated alkyl group, preferably 〇8- €: 18 alkyl, and more preferably C1G-C16 alkyl, and Μ # is hydrazine or cation, such as an alkali metal cation (such as sodium, potassium, lithium), or ammonium or substituted ammonium (such as methyl-, Dimethyl and trimethylammonium cations and quaternary ammonium cations such as tetramethylammonium and dimethylpiperidinyl cations and derived from alkylamines such as ethylamine, diethylamine, triethylamine, And mixtures thereof and analogs thereof, quaternary ammonium cations). Suitable alkylaryl sulfonates for use herein include the water-soluble salts or acids of the formula RS 3 m wherein R is a saturated or unsaturated alkyl group which is c6-c2G straight or branched, preferably hydrazine. 8-(:18 alkyl, and more preferably an aryl group substituted by a c1G-c16 alkyl group, preferably a benzyl group, and the oxime is a ruthenium or a cation such as a base-33-(30) (30)200808953 metal a cation (such as sodium, potassium, lithium, calcium, magnesium, and the like), or an ammonium or substituted ammonium (such as methyl-, dimethyl, and trimethylammonium cations and a quaternary ammonium cation such as tetramethylammonium) And dimethyl piperidine cations and quaternary mirror cations derived from alkylamines such as ethylamine, diethylamine 'triethylamine, and mixtures thereof and the like thereof.. €:14- An example of an alkanesulfonate of €16 is Hostapur® S AS from Hoechst. Commercially available alkylarylsulfonates are lauryl arylsulfonates from Su. Ma. Particularly preferred alkyls. The aryl sulfonate is commercially available from Albright & Wilson under the trade name Nansal 8 alkyl phenyl sulfonate. Suitable alkyl sulfate surfactants are A person of the formula RiSCUM, wherein Ri is a hydrocarbon group selected from the group consisting of a linear or branched alkyl group having 6 to 20 carbon atoms and an alkylphenyl group having 6 to 18 carbon atoms in the alkyl group. a cation such as an alkali metal (e.g., sodium, potassium, lithium, calcium, magnesium, and the like), or an ammonium or substituted ammonium (e.g., methyl-, dimethyl, and trimethylammonium cations and a quaternary ammonium cation, for example, Tetramethylammonium, and dimethylpiperidine iron cations and quaternary ammonium cations derived from alkylamines such as ethylamine, diethylamine, triethylamine, and mixtures thereof and the like. Particularly preferred branched alkyl sulfates for use herein are those having from 1 to 14 total carbon atoms, such as Isalchem 123 AS®. Isalchem 123 AS® commercially available from Enichem is 94% branched Ci2 -i3 Surfactant. This material can be described as CHs-iCHOm-CHidOSOsNaMCHOn-CI^, where n + m = 8-9. Further, preferred alkyl sulfates are those in which the alkyl chain contains a total of 12 carbon atoms. Alkyl sulfates, ie 2-butyloctylsulfate-34- 200808953 (31) sodium. Salt commercially available from Condea, under the trade name Isofol® 12S. The particularly suitable linear alkyl sulphonates include ci2-Cl6

Amino acid salt, such as Hostapur® SAS, commercially available from Hoechst, is an alkyl alkoxylated sulfate surfactant suitable for use herein according to the formula R(A)mS03M' wherein R is unsubstituted c6 a -C2 fluorene group or a hydroxyalkyl group having a C6-C2 decyl moiety, preferably c?2-C2 decyl or hydroxyalkyl φ, more preferably C12-C18 alkyl or hydroxyalkyl a is an ethoxy or propoxy unit, m is greater than 0, typically between 0.5 and 6, more preferably between 0.5 and 3, and the ruthenium is ruthenium or cation, which may be, for example, a metal test (eg Sodium, potassium, lithium, calcium, magnesium, etc.), or ammonium or substituted ammonium cations. Alkyl ethoxylated sulfates and alkyl propoxylated sulfates are contemplated herein. Specific examples of substituted ammonium cations include methyl-, dimethyl- and trimethylammonium cations and quaternary ammonium cations such as tetramethylammonium, dimethylpiperidinyl cations and derived from alkanolamines such as Ethylamine, diethylamine, triethylamine, and mixtures thereof and analogs thereof, cations. Exemplary surfactants are Ci2-c18 alkyl polyethoxylated (1.0) sulfate (Cu-CuEU.OeM), C12-C18 alkyl polyethoxylated (2.25) sulfate (C12-C18E) (2.25) SM), 0:12-(: 18-alkyl polyethoxylated (3·0) sulfate (Ci2-C18E (3.0) SM) and (:12-(:18 alkyl polyethoxylate) a sulfated (4.00) sulfate (C12-C18E (4.0) SM) wherein hydrazine is conveniently selected from the group consisting of sodium and potassium. Suitable for linear or branched C6-C2 decyl alkoxylations herein. The diphenyl oxide disulfonate surfactant is in accordance with the following formula: -35- 200808953 (32)

Wherein 1 is a c6-c2 〇 straight or branched saturated or unsaturated alkyl group, preferably a C12-C18 alkyl group, and more preferably a C14-c16 alkyl group, and X+ is a ruthenium or a cation' such as an alkali metal cation. (eg sodium, potassium, lithium, calcium, magnesium and the like). Particularly suitable c6-c2() alkyl alkoxylated linear or branched diphenyl oxide disulfonate surfactants for use herein are C12 branched diphenoxy oxides. Sulfonic acid and C! 6 linear diphenyl oxide disulfonate sodium salt, both commercially available from D〇W under the trade names Dowfax 2A1® and Dowfax 8390®. Other anionic surfactants useful herein include soap salts (including, for example, sodium, potassium, ammonium, and substituted ammoniums such as mono-, di-, and tri-ethanolamine salts) 'C8-C24 olefin sulfonate, Sulfonated polycarboxylic acids prepared by sulfonation of pyrolysis products of alkaline earth metal citrate, such as those described in British Patent Specification 1, 〇 82, 179, C8-C24 alkyl polyglycol ether sulfates ( Containing up to 1 mole of ethylene oxide); sulfonic acid alkyl esters such as sulfonic acid C14-16 methyl ester; mercaptoglycerol sulfonate, fatty oil based glycerol sulfate, alkylphenol oxyethylene ether sulfate, Alkyl phosphates, isoethene sulfonates such as decyl isoethene sulfonate, N-mercapto taurine, alkyl succinate and sulfosuccinate, sulfosuccinic acid Esters (especially saturated and unsaturated C^-C! 8 monoesters) 'diesters of sulfosuccinic acid (especially saturated and unsaturated C6-C14 diesters)' thiol creatinates, Sulfate of alkylpolysaccharide-36- 200808953 (33) Esters, such as sulfates of alkyl polyglycosides (non-ionic non-sulfur Compounds), alkyl polyethoxy carboxylates, for example, the formula R0(CH2CH20)kCH2C00-M+, wherein 11 is <:8-(:22, and k is an integer from 0 to 10, and Μ It is a cation forming a soluble salt. Resin acids and hydrogenated resin acids are also suitable, such as rosin, hydrogenated rosin, and resin acids and hydrogenated resin acids present or derived in tall oil. Another example is in ''Surface Active' Agents and Detergents, (Vol. I and II ^ by Schwartz, Perry and Berch). The different surfactants are also commonly disclosed in U.S. Patent 3,929, issued to Laughlin et al. 678, column 23, line 5, line 8 to column 29, column 23. The zwitterionic surfactant represents another preferred class of surfactants in the context of the present invention. Zwitterionic surfactants contain cations in the broad range of acid and base bismuth. The cationic and anionic groups are on the same molecule. Typical cationic groups are quaternary ammonium groups, although other positively charged groups such as 锍Φ and hydroxy groups can also be used. Typical anionic groups are Carboxylate And sulfonates, preferably sulfonates, although other groups such as sulfates, phosphates and the like may also be used. Some general examples of such detergents are described in the following patent documents: U.S. Patent 2,082,275, A specific example of 2,702,279 and 2,255,082 〇 zwitterionic surfactants is 3-(N-dodecyl-indole dimethyl)-2-hydroxypropane-1-sulfonate (sultanate sultaine) )), which is available from McIntyre Company (2460 1 Governors Highway, University Park, Illinois 60466, USA) under the trade name -37-200808953 (34) as Mackam LHS®. Another particular zwitterionic surfactant is C12-14 mercaptodecyl propylene (hydroxypropene) sultaine, available from McIntyre under the tradename 50-SB®. Other highly useful zwitterionic surfactants include hydrocarbyl groups such as fatty alkenes betaine. A highly preferred amphoteric surfactant is Empigen BB®, a coconut dimethyl betaine manufactured by Albright & Wilson. Another equally preferred zwitterionic surfactant is Mackam 35 HP, which is a φ coconut amidinopropyl betaine manufactured by McIntyre. Another preferred class of surfactants comprises an amphoteric surfactant group. A suitable amphoteric surfactant is <:8-0:16 guanylaminoglycolate surfactant ('amphotigmentate'). Another suitable amphoteric surfactant is the c8-c16 guanamine-alkyl extended propionate surfactant ('ampho-propionate'). Other suitable amphoteric surfactants are surfactants such as dodecyl hydrazine-aminopropionic acid, N-alkyl taurine, for example, dodecyl groups according to the teachings of U.S. Patent 2,6,5,072. Prepared by the reaction of an amine with iso-vinyl sulfonic acid, N-higher carbon alkyl aspartic acid, for example, according to the teachings of U.S. Patent 2,438,09 1 and under the trade name "Miranol®" "Products sold and described in U.S. Patent 2,528,3,78. The weight ratio of the water-soluble or water-dispersible copolymer herein to the nonionic, anionic, amphoteric, zwitterionic surfactant or a mixture thereof is 1: 1 0 0 to 1 0 : 1, more preferably 1: 5 0 To 1:1. Chelating Agents One of any of the compounds used herein includes a chelating agent or a mixture thereof -38 - 200808953 (35). The chelating agent may be incorporated into the compositions herein in an amount ranging from 重量 % to 1 〇 · 〇 % ′ preferably 〇. 〇 1 % to 5 · 〇 %. Suitable phosphonate chelating agents for use herein may include alkali metal ethane 1-hydroxydiphosphonates (HEDP), alkylene poly(alkylphosphonates), and aminophosphonate compounds, including amine groups. Aminotris(methylphosphonic acid) (ATMP), triazidetrimethylphosphonate (NTP), ethylenediaminetetramethylphosphonate, and diamethylenetriamine Phosphonate (DTPMP) φ. The phosphonate compound is present in its acid form or as a different cationic salt in some or all of its acid functionality. Preferred phosphonate chelating agents for use herein are di-extended ethyltriamine pentamethylphosphonate (DPTMP) and ethane 1-hydroxydiphosphonate (HEDP). Such phosphonate chelators are commercially available from Monsanto under the trade name DEQUEST®. Polyfunctionally substituted aromatic chelating agents are also useful in the compositions herein. See U.S. Patent 3,8 1 2,044 issued to Connor et al. A preferred compound acid form of this form is a dihydroxydisulfo-benzene such as 1,2.dihydroxy-3,5.disulfobenzene. Preferred biodegradable chelating agents for use herein are ethylenediamine hydrazine, hydrazine oxadicarboxylic acid or an alkali metal or alkaline earth metal or ammonium salt thereof or a substituted ammonium salt or a mixture thereof. Ethylenediamine hydrazine, hydrazine succinic acid, in particular (S, S) isomers, is described in U.S. Patent 4,704,233, issued to Hartman and Perkins on November 3, 1987. Ethylenediamine N,N,-disuccinic acid is, for example, commercially available from Palmer Research Laboratories under the trade name ssEDDS8. The aminocarboxylates useful herein include ethylenediaminetetraacetate-39-200808953 (36), di-ethyltriamine pentaacetate, di-ethyltriamine pentaacetate (DTP A). ), N-hydroxyethyl ethylenediamine triacetate, triaza-acetate, ethylenediamine tetrapropionate, tri-ethyltetraamine hexaacetate, ethanol-diglycine, C Diaminetetraacetic acid (PDTA) and methylglycine diacetic acid (MGDA), all of which are in the acid form or in the form of their alkali metal salts, money salts and substituted ammonium salts. Particularly useful aminocarboxylates herein are di-extended ethyltriaminepentaacetic acid, propylenediaminetetraacetic acid (PDTA) (which is, for example, commercially available from BASF under the trade name Trilon FS®) and Methylglycine diacetic acid (MGDA). Additional carboxylate chelating agents for use herein include salicylic acid, aspartic acid, glutamic acid, glycine, malonic acid or mixtures thereof. Fatty Acid The liquid composition of the present invention may contain a fatty acid or a mixture thereof as an optional component. ® The fatty acid used in this article is the base salt of C8-C24 fatty acid. Such base salts include salts of fully saturated metals such as sodium, potassium and/or lithium salts of fatty acids and ammonium and/or alkylammonium salts, preferably sodium salts. Preferred fatty acids for use herein contain from 8 to 22, preferably from 8 to 20 and more preferably from 8 to 18 carbon atoms. Suitable fatty acids may be selected from the group consisting of caprylic acid, capric acid, lauric acid, meat citrate, palmitic acid, a mixture of stearic acid, oleic acid and fatty acids which are suitably hardened and derived from natural sources, such as vegetable or animal esters such as palm oil, olive oil, coconut oil, soybean oil, castor oil, tallow, peanut oil, Yu-40 - 200808953 (37) Oil and fish oil and / or babassu oil. For example, coconut fatty acids are commercially available from UNICHEMA under the trade name PRIFAC 5900®. Fatty acids are desirable herein because they reduce the formation of retentive foams in the liquid compositions used in the methods of the present invention. Typically, the liquid composition herein may comprise up to 6% by weight of the total composition, preferably from 1% to 2%, more preferably from 0. 1% to 1%, and most preferably from 0.2%. Up to 0.8% of this fatty acid. Branched Fatty Alcohol The liquid composition of the present invention may comprise a branched fatty alcohol or a mixture thereof as a highly preferred optional ingredient. Such suitable compounds are, for example, the commercially available Isofol® series, such as Isofol® 12 (2-butyl octanol) or Isofol® 16 (2-hexyl sterol) commercially available from Condea. Preferably, the branched fatty alcohol is selected from the group consisting of 2-butyl octanol, 2-hexyl decyl alcohol, and mixtures thereof. More preferably, the 2-alkyl alkanol is 2-butyl octanol. Typically, the liquid compositions herein may comprise up to 2%, preferably from 0.10% to 1.0%, more preferably from 0.1% to 0.8%, most preferably from 0.1% to 0.5% by weight of the total composition of the branched fatty acid. Solvent The liquid composition of the present invention may comprise a solvent or a mixture thereof as an optional component -41 - 200808953 (38) % Suitable solutions are selected from the group consisting of having 4 to 14 carbon atoms, preferably 6 to 12 carbon atoms, And more preferably ethers or diethers of 8 to 10 carbon atoms; glycols or alkoxylated glycols; alkoxylated aromatic alcohols; aromatic alcohols; alkoxylated aliphatic alcohols Classes; aliphatic alcohols; Cs-Ci 4 alkyl and cycloalkyl hydrocarbons and halocarbons; C6-C! 6 glycol ethers; terpenes; The diols useful herein are those according to the formula HO-CR^R^OH, wherein R2 is independently a hydrazine or a C2-C1() saturated or unsaturated aliphatic hydrocarbon chain and/or a φ ring. The diols useful herein are dodecanediol and/or propylene glycol. The alkoxylated glycols useful herein are those according to R^AK-UH wherein R is 1 to 20, preferably 2 to 15, more preferably saturated or unsaturated of hydrazine, OH, linear or branched. An alkyl group of 2 to 10 carbon atoms, wherein R1 is H or a linear or unsaturated saturated or unsaturated group of 1 to 20, preferably 2 to 15, more preferably 2 to 10 carbon atoms, and hydrazine is an alkoxy group. The group is preferably an ethoxy group, a methoxy group and/or a propoxy group, and η is 1 to 5, preferably 1 to 2. Alkoxylated diols useful herein are methoxy stearyl alcohol and/or ethoxy ethoxyethanol. # Alkoxylated aromatic alcohols as used herein are those according to the formula R-(A)n-OH wherein R is from 1 to 20, preferably from 2 to 15, more preferably from 2 to 10 carbon atoms. a aryl group substituted by a non-alkyl group, wherein A is an alkoxy group, preferably a butoxy group, a propoxy group and/or an ethoxy group, and η is from 1 to 5, preferably from 1 to 2. Integer. Suitable alkoxylated aromatic alcohols are benzyloxyethanol and/or benzyloxypropanol. The aromatic alcohols to be used herein are those according to the formula R-OH wherein the alkyl group is substituted with i to 20, preferably 1 to 15, more preferably 1 to 10 carbon atoms or substituted by a non-hospital group. base. For example, the aromatic alcohols useful herein are benzyl alcohol-42-200808953 (39) The alkoxylated aliphatic alcohols useful herein are those according to the formula R-(A)n-OH, wherein R is straight or divided a saturated or unsaturated group of 1 to 20, preferably 2 to 15, more preferably 3 to 12 carbon atoms, wherein A is an alkoxy group, preferably a butoxy group, a propoxy group and/or a An oxy group, and η is an integer of from 1 to 5, preferably from 1 to 2. Suitable alkoxylated aliphatic straight or branched alcohols are butoxypropoxypropanol (η-BPP), butoxyethanol, butoxypropanol (η-ΒΡ), ethoxylate Ethanol, 1-methylpropoxyethanol, 2-methylbutoxyethanol or a mixture thereof. Butoxypropoxypropanol is commercially available from Dow Chemical under the trade name n-BPP. Butoxypropanol is commercially available from Dow Chemical. The aliphatic alcohols useful herein are those according to formula R-OH wherein R is a straight or branched saturated or unsaturated 1 to 20, preferably 2 To 15, more preferably an alkyl group of 5 to 12 carbon atoms. Incidentally, the aliphatic branched alcohol is not the 2-alkyl alkanol described above. Suitable aliphatic alcohols are methanol, ethanol, propanol, isopropanol or mixtures thereof. The terpenes suitable for use herein are monocyclic terpenes, bicyclic terpenes and/or acyclic terpenes. Suitable terpenes are: D-decadiene; terpene; pine oil; terpinene; terpene derivatives such as menthol, terpineol, geraniol, thymol; and lemongrass or lemongrass Alcohol type ingredients. Other suitable solvents include butyl diglycol ether (BDGE), hexanediol, butyl triethylene glycol ether, teramilic alcohol, and the like. BDGE is commercially available from Union Carbide or BASF under the trade name Butyl CARBITOL®. -43- 200808953 (40) m Preferably, the solvent is selected from the group consisting of butoxypropoxypropanol, butyl diglycol ether, benzyl alcohol, butoxypropanol, ethanol, methanol, isopropanol, and Glycols and mixtures thereof. More preferably, the solvent is selected from the group consisting of butoxypropoxypropanol, butyl diglycol ether, benzyl alcohol, butoxypropanol, ethanol, methanol, isopropanol, and mixtures thereof. Even more preferably, the solvent is selected from the group consisting of butyl diglycol ether, butoxy propanol, ethanol, and mixtures thereof. Typically, the liquid composition herein may comprise up to 30%, preferably from 1% to 25%, more preferably from 1% to 20%, and most preferably from 2% to 1% by weight of the total composition. The solvent or a mixture thereof. In a preferred embodiment, the solvent contained in the liquid composition of the present invention is a volatile solvent or a mixture thereof, preferably a volatile solvent or a mixture thereof in combination with other solvents or mixtures thereof. Perfume The liquid composition of the present invention may comprise a perfume or a mixture thereof; the mash is any component of a preferred stomach. Perfume as used herein includes materials that provide an olfactory effect and/or any "chemical" odor that may be present in the product. The composition herein may contain a perfume or a mixture thereof in an amount of up to 5.0% by weight of the total composition, preferably from 0.01% to 2.5%, more preferably from 5% to 1.5%, even more preferably. . 1 % to 1. 〇%. Constructing Agent The liquid composition of the present invention may also comprise a building agent or a mixture thereof as -44-200808953 (41) 瓤 as an optional component. Suitable building agents for use herein include polycarboxylates and polyphosphates and salts thereof. Typically, the compositions of the present invention comprise up to 20.0% by weight of the total composition, preferably from 0.1% to 10.0%, and more preferably from 0.5% to 5.0%, of the builder or mixtures thereof. Free Radical Scavenger The compositions of the present invention may comprise a free radical scavenger. φ Suitable radical scavengers for use herein include the conventional mono- and dihydroxy substituted benzenes and analogs thereof, alkyl carboxylates and aryl esters, and mixtures thereof. Preferred radical scavengers for use herein include di-tert-butylhydroxytoluene (BHT), hydroquinone, di-tert-butylhydroquinone, mono-tert-butylhydroquinone, tert-butylhydroxyanisole. , benzoic acid, toluic acid, catechol, tert-butylcatechol, benzylamine, 1,1,3-tris(2-methyl-4-hydroxy-5-tert-butylphenyl)butane, N-propyl decanoate or a mixture thereof, and highly preferred is di-tert-butylhydroxytoluene. Such free radical scavengers such as n-propyl decanoate are commercially available from Nipa Laboratories under the trade name Nipanox S 1 2 . When used, the free radical scavenger is typically present herein in an amount of up to 10%, preferably from 0. 01% to 0.5% of the total composition. The presence of a free radical scavenger contributes to the chemical stability of the compositions of the present invention. Other non-limiting examples of other adjuvants are: enzymes such as proteases, hydrotropes such as sodium toluenesulfonate, sodium cumenesulfonate and potassium xylene sulfonate, and -45-200808953 (42) % aesthetic enhancing ingredients For example, a coloring agent, as long as it does not adversely punch the film forming/streak forming. The composition may also contain one or more colored dyes or pigments. If present, the dye, pigment, and non-present dye will comprise from 0.1 ppm to 50 ppm by weight of the aqueous composition. The composition of the composition herein may be packaged in a suitable detergent known to those skilled in the art. In the package. The liquid composition is preferably packaged in a conventional decontaminant plastic bottle. [Embodiment] EXAMPLES The following examples are intended to illustrate the compositions used in the method of the present invention, but are not intended to limit the scope of the invention. The following liquid compositions are prepared by sequentially using the listed ratios in combination with the following ingredients to form a homogeneous mixture (% of solution is based on the weight of the active material). Alkoxy nonionic surfactant AB C9-11 E05 4.5 - C12,14E05 1.5 - C10AO7 - 3.5 C12,14E021 - - Anionic surfactant NaLAS 0.5 0.2 CDEFG 9.0 4.0 3.0 - 6.0 0.5 0.7 - - - - - 30 - 2.0 - - - 0.4 1.5 0.2 0.5 0.4 -46 200808953 (43)

Isalchem 8 AS NaCS 1.5 0.7 1.7 3,0 1.4 0.8 0.8 Neutralizing base surfactant C12-14AO 0.2 - - 0.1 0.5 earning polymer 0.1 — - 0.15 - 0.075 - Copolymer I Copolymer II 0.1 0.15 0.05 0.1 Chelating agent DTPMP 0.1 0.1 0.2 - 0.15 - 0.1 Buffer Na2〇〇3 0.2 0.4 1.0 1.0 0.6 - 0.5 Citric 1.0 - 0.8 0.7 0.5 1.0 - Caustic 0.8 - 0.3 0.4 0.3 0.7 - Recalcitrant foam control fatty acid 0.8 0.3 0.3 0.2 0.2 0.3 0.2 Isofol 12 Positive - - - 0.5 - - Solvent EtOH - - Cocoon - - 1.0 n-BP - - - - 5.5 3.0 MEA - - - - - 0.7 - Traces and water to 100 pH 9.5 9.5 9.5 9.5 Ϊ0.0 11.0 9.5 Copolymer I was prepared by Rhodia and derived from a molar ratio of 3 3/67 bis-quaternary ammonium and acrylic acid -47 - 200808953 (44) ♦ Copolymer II was prepared by Rhodia and derived from a molar ratio of 40 /60 DADMAC and Acrylic C9-11 E05 is a C9-11 E05 nonionic surfactant commercially available from ICI or Shell. C12,14 E05 is a C12,14 E05 nonionic surfactant commercially available from Huls, A&W or Hoechst. CIO A07 is a non-isomerized surfactant commercially available from BASF for alkoxylation under the trade name Lutensol XL 70®. C12,14 E021 is a C12,14 E021 nonionic surfactant.

NaLAS is a linear sodium alkylbenzene sulfonate commercially available from A&W.

NaCS is a sodium cumene sulfonate commercially available from A&W. Isalchem® AS is a 0:12-13 sulfate surfactant commercially available from Enichem. Φ C 12-14 A0 is a C1 2-14 amine oxide surfactant. DTPMP is a commercially available diethyltriamine pentamethylphosphoric acid from Solutia.

Isfol 12® is a commercially available 2-butyl octanol from Condea. n-BP is a commercially available n-butoxypropanol from DOW Chemicals. Ethanol is commercially available from Condea. MEA is a monoethanolamine commercially available from Condea. These liquid compositions are used in the methods as disclosed herein and provide good film formation and/or stripe forming performance and good hair when -48-200808953 (45) release/non-clean hard surface cleaning applications Bright performance. In addition, these liquid compositions provide good antifouling performance and good next cleaning benefits when used in re-dilution/non-clean hard surface cleaning applications. In addition, these liquid compositions provide good film formation and/or stripe forming performance as well as good shine performance when used in precision hard surface cleaning applications.

-49 -

Claims (1)

200808953 (1) X. Patent application 1. A method for cleaning a hard surface using a composition comprising a water-soluble or water-dispersible copolymer, the method comprising applying a diluted type of the composition to the surface and diluting the composition The composition remains on the surface to dry without washing the surface, wherein the water-soluble or water-dispersible copolymer is a water-soluble or water-dispersible copolymer I comprising: a) at least one formula i Monomeric compounds: Ri X·I H2C=CZ.[CH2]„ R2 X' r2 R4I X· (i) R3 R3 Re where: 1 is a hydrogen atom, methyl or ethyl; R2, R3, R4, R5 and R6 are the same or different Is a linear or branched Ci-Cs alkyl, hydroxyalkyl or aminoalkyl group; m is an integer from 〇 to 10; η is an integer from 1 to 6; Ζ is -C(0)0- or -C(0)NH- group or oxygen atom; A is (CH2)P, p is an integer from 1 to 6; B is a linear or branched CyCi2 polymethylene chain, optionally inserted one or more a hetero atom or a hetero group or optionally substituted by one or more hydroxyl or amine groups; XI is the same or different, is a counter ion; and -50- 200808953 (2) • i (b) at least one carrying function a hydrophilic monomer which is copolymerizable with (a) and which can be ionized in an application medium; (C) optionally, at least one vinyl unsaturation having a neutral charge and (a) And (b) a copolymerized monomeric compound, preferably having a neutrality of what is unsaturation, carrying one or more hydrophilic groups, and being copolymerizable with (a) and (b) a monomeric compound; or comprise the following functionalities Water-soluble or water-dispersible copolymer 11 : Φ d) at least one monomer having the formula ii: Ri R2 R4 (8) HaC^C-tCH^n-ir-tCH^^C = CH2 Χ· I r3 where: ^ And ^ is independently H or C^6 straight or branched alkyl; ^ R2 and R3 are independently a straight or branched Cid alkyl, hydroxyalkyl or aminoalkyl group, preferably a methyl group; η and m are independently an integer from 1 to 3; X· is a counter ion; e) at least one hydrophilic monomer having acid functionality and copolymerizable with monomer d) and capable of being ionized in a medium And f) optionally, an ethylenically unsaturated hydrophilic monomer compound having one or several hydrophilic groups and copolymerizable with the monomers d) and hydrazine, a monomer d) The ratio of monomer e) is in the range of 60:40 to 5:95; 200808953 (3) 混合物 or a mixture of water-soluble or water-dispersible copolymer I and water-soluble or water-dispersible copolymer II. The method of item 1, wherein in the monomer (a(i)), Z is -C(0)0-, -C(0)NH- or an oxygen atom; η is equal to 2 or 3; m is from 0 to 2 Within the range; 8 is -(:112-011(011)-((:112)£1,1 Is a 1 to 4; and φ Ri to R6 are the same or different, and are methyl or ethyl. 3. The method of claim 1 or 2, wherein the polymer comprises: (c) at least one neutral A monomeric compound copolymerizable with (a) and (b) with ethylene unsaturation of charge. 4. The method of claim 3, wherein (c) is a neutrally charged ethylene unsaturation, carrying one or more hydrophilic groups and copolymerizable with (a) and (b) Hydrophilic monomeric compound. ® 5 · The method of claim 1, wherein (b) is a Cs-C s carboxylic acid, sulfonic acid, sulfuric acid, phosphonic acid or phosphoric acid having a monoethylenic unsaturation. 6. The method of claim 2, wherein the water-soluble or water-dispersible copolymer is 3 to 8 mol% monomer (a); 1 to 95 mol% monomer (b); Obtained by copolymerization of 0 to 50 mol% of monomers. 7. The method of claim 1, wherein the monomer (a) and the monomer (b) have a total monomer (a) to a total monomer (b) weight of from 80/20 to 5/95. Ear ratio. 8. The method of claim 1, wherein in the monomer (d ( ϋ - 52 - 200808953 (4) Ο )) η is equal to 1; m is equal to 1; χ - preferably selected from halogen, sulfate, Hydrogen sulfate, phosphate, citrate, formate and acetate; and R! is hydrogen, R2 is methyl, R3 is methyl, and R4 is hydrogen. 9. The method of claim 1, wherein the monomer (e) is selected from the group consisting of C3-C8 carboxylic acid containing monoethylenic unsaturation, sulfonic acid, sulfuric acid, phosphonic acid, and phosphoric acid. 10. The method of claim 1, wherein the monomer (f) is present and is selected from the group consisting of acrylamide, vinyl alcohol, Cr C4 alkyl ester of acrylic acid and methacrylic acid, and Ci-C# hydroxyl group of acrylic acid and methacrylic acid. Alkyl esters, especially ethylene glycol and propylene glycol esters of acrylic acid and methacrylic acid, polyalkoxylated esters of acrylic acid and methacrylic acid, especially polyglycol esters and polypropylene glycol esters. #11. The method of claim 1, wherein the proportion of the monomer d) to the monomer e) is between 50:50 and 10:90. The method of claim 1, wherein the composition comprises the water-soluble or water-dispersible copolymer I as the water-soluble or water-dispersible copolymer. The method of claim 1, wherein the composition comprises the water-soluble or water-dispersible copolymer II as the water-soluble or water-dispersible copolymer. The method of claim 1, wherein the water-soluble or water-53-200808953 (5) 分散 dispersible copolymer is present in an amount of from 0.001% to 10% by weight based on the total weight of the composition. The method of claim 1, wherein the composition remains at least partially on the surface at the end of the method of cleaning the hard surface, preferably at least partially remaining on the surface until subsequent cleaning operations . The method of claim 1, wherein the composition additionally comprises a surfactant or a mixture thereof. The method of claim 16, wherein the surface active φ agent is present in an amount of from 0.01% to 20% by weight of the composition. 18. The method of any one of claims 16 and 17, wherein the weight ratio of the water-soluble or water-dispersible copolymer to the surfactant or a mixture thereof is between 1:100 and 10:1. Jia is between 1:50 and 5:1. 1 9. Use of a water-soluble or water-dispersible copolymer in a method of cleaning a hard surface using a liquid composition comprising the water-soluble or water-dispersible copolymer, wherein the method comprises applying a diluted type of the composition to the a step of leaving the diluted composition on the surface to dry without washing the surface, providing good film formation and/or stripe formation performance, good shine performance, good antifouling performance, and A good potency for the next cleaning, and wherein the water-soluble or water-dispersible copolymer is a water-soluble or water-dispersible copolymer comprising the following functionalities: a) at least one monomeric compound of the formula i: Ri X· R2X_R2 R4 X· (i) I 111 Hpc-z-fayn-NlA- nVb- n^r5 III R3 R3 -54- 200808953 (6) where: 1 is a hydrogen atom, methyl or ethyl; r2, R3 And R4, R5 and R6 are the same or different and are a linear or branched C1-C6 alkyl group, a hydroxyalkyl group or an aminoalkyl group; m is an integer of 〇 to 1〇; η is an integer of 1 to 6; φ Ζ is a -C(0)0- or -C(0)NH- group or an oxygen atom; A is (CH2)P, and p is 1 to 6 Integer; B is a linear or branched 2 polymethylene chain optionally substituted with one or more heteroatoms or hetero groups or optionally substituted with one or more hydroxyl or amine groups; Differently, is a counter ion; and (b) at least one hydrophilic monomer which carries a functional acidic group and which can be copolymerized with (a) and which can be ionized in an application medium; Φ (c) optionally, at least a monomeric compound having a neutral charge of ethylene unsaturation and copolymerizable with (a) and (b), preferably having a neutral charge of ethylenic unsaturation, carrying one or more hydrophilic groups, And a hydrophilic monomer compound copolymerizable with (a) and (b); or a water-soluble or water-dispersible copolymer comprising the following functional groups: d) at least one monomer having the formula: -55- 200808953(7) Ri R2 R4 (6) H2C=C-[CH2] CH2]mC = CH2 R3 χ· where: 1 and 1^4 are independently η or Cw straight or branched alkyl; R2 and R3 are independently straight or branched Ci-6 alkyl, hydroxyalkyl or Aminoalkyl, preferably methyl; η and m are independently an integer from 1 to 3; X. is a counterion; and e) at least one has acid functionality and can be copolymerized with monomer d) and can be in the medium a hydrophilic monomer that is ionized, the monomer being used in the medium; and f) optionally having one or more hydrophilic groups to copolymerize the neutral charge with the monomers d) and e) Ethylene unsaturated hydrophilic monomer compound, the ratio of monomer d) to monomer e) is in the range of 60:40 to 5:95; or water-soluble or water-dispersible copolymer I and water-soluble or water-dispersible copolymerization a mixture of substances 11. Use of a water-soluble or water-dispersible copolymer in a method of cleaning a hard surface using a liquid composition comprising the water-soluble or water-dispersible copolymer, wherein the method comprises applying a pure form thereof a step of the composition on the hard surface, which provides good film formation and/or stripe formation performance and good light-emitting efficacy, and wherein the water-soluble or water-dispersible copolymer is a water-soluble or water-containing functional group Dispersible copolymer I: a) at least one monomeric compound of formula i: -56- 200808953 (8) (i) Ri X· R2X* R2 R4 X' H2C=CZ-[CH2]n.N+[A- R3 R3 Re wherein: 1 is a hydrogen atom, a methyl group or an ethyl group; and r2, R3, R4, 115 and R6 are the same or different and are a straight or branched alkyl group, a hydroxyalkyl group or an aminoalkyl group; m is an integer from 〇 to 1〇; η is an integer from 1 to 6; Ζ is a -C(0)0- or -C(0)NH- group or an oxygen atom; A is (CH2)P, p is 1 An integer of up to 6; B is a linear or branched C2-C12 polymethylene chain optionally substituted with one or more heteroatoms or hetero groups or optionally substituted with one or more hydroxyl or amine groups And (b) at least one hydrophilic monomer which carries a functional acidic group and which can be copolymerized with (a) and which can be ionized in an application medium; , at least one monomeric compound having a neutral charge of ethylene unsaturation and copolymerizable with (a) and (b), preferably having a neutral charge of ethylene unsaturation, carrying one or more hydrophilicities a hydrophilic monomer compound copolymerizable with (a) and (b); or a water-soluble or water-dispersible copolymer containing the following functionalities: -57- 200808953 (9) d) at least one Monomers having the formula: Ri R2 R4 (ϋ) = CH2 X· I r3 where: 1^ and & 4 are independently H or Cu straight or branched alkyl; • R2 and R3 are independently linear Or branched Ci_6 alkyl, hydroxyalkyl or aminoalkyl, preferably methyl; η and m are independently an integer from 1 to 3; X- is a counterion; e) at least one has acid functionality a hydrophilic monomer copolymerized with monomer d) and capable of being ionized in a medium, the monomer being used in the medium; and f) optionally having one or several hydrophilic groups and monomers d) and e) copolymerizing a neutrally charged ethylenically unsaturated hydrophilic monomer compound, the ratio of the monomer d) to the monomer e) in the range of 60·40 to 5:95; or water-soluble or water A mixture of a dispersible copolymer I and a water-soluble or water-dispersible copolymer II. -58 - 200808953 Ming said that there is no simple keu: rhyme is a map of the map and the map is replaced by the map. • The representation of the table represents the book without a set of two fingers. Γν VIII. If there is a chemical formula in this case, please reveal the best display. Chemical formula of the invention: Ri X- R2 X* R2 R4 X' (1) R3 R3 Re