TW200804457A - Polyester compositions which comprise cyclobutanediol and at least one phosphorus compound - Google Patents

Polyester compositions which comprise cyclobutanediol and at least one phosphorus compound Download PDF

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Publication number
TW200804457A
TW200804457A TW96110546A TW96110546A TW200804457A TW 200804457 A TW200804457 A TW 200804457A TW 96110546 A TW96110546 A TW 96110546A TW 96110546 A TW96110546 A TW 96110546A TW 200804457 A TW200804457 A TW 200804457A
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TW
Taiwan
Prior art keywords
polyester
mol
residue
dicarboxylic acid
mole
Prior art date
Application number
TW96110546A
Other languages
Chinese (zh)
Inventor
Ted Calvin Germroth
Gary Wayne Connell
Emmett Dudley Crawford
Thomas Joseph Pecorini
Douglas Stephens Mcwilliams
Benjamin Fredrick Barton
Damon Bryan Shackelford
Original Assignee
Eastman Chem Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US11/390,908 external-priority patent/US7462684B2/en
Priority claimed from US11/391,124 external-priority patent/US20060234073A1/en
Priority claimed from US11/390,809 external-priority patent/US7959998B2/en
Priority claimed from US11/390,847 external-priority patent/US20060287484A1/en
Priority claimed from US11/390,846 external-priority patent/US7955674B2/en
Priority claimed from US11/390,812 external-priority patent/US7959836B2/en
Priority claimed from US11/588,907 external-priority patent/US20070106054A1/en
Priority claimed from US11/588,527 external-priority patent/US20100087574A1/en
Priority claimed from US11/588,524 external-priority patent/US20100096589A1/en
Priority claimed from US11/588,906 external-priority patent/US8193302B2/en
Priority claimed from US11/588,554 external-priority patent/US20070100125A1/en
Priority claimed from US11/588,458 external-priority patent/US20070100122A1/en
Priority claimed from US11/588,883 external-priority patent/US20070105993A1/en
Priority claimed from US11/635,434 external-priority patent/US7737246B2/en
Priority claimed from US11/635,433 external-priority patent/US20070142511A1/en
Priority claimed from US11/706,791 external-priority patent/US20070232779A1/en
Priority claimed from US11/706,476 external-priority patent/US20070232778A1/en
Application filed by Eastman Chem Co filed Critical Eastman Chem Co
Publication of TW200804457A publication Critical patent/TW200804457A/en

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Abstract

Described as one aspect of the invention are polyester compositions containing: (I) at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) 70 to 100 mole% of terephthalic acid residues; (ii) 0 to 30 mole% of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and (iii) 0 to 10 mole% of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) a glycol component comprising: (i) 1 to 99 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and (ii) 1 to 99 mole% of cyclohexanedimethanol residues; and (II) at least one thermal stabilizer chosen from at least one phosphorus compound, reaction products thereof, and mixtures thereof; wherein the total mole% of the dicarboxylic acid component is 100 mole%, and wherein the total mole% of the glycol component is 100 mole%; wherein the inherent viscosity of the polyester is from 0.35 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25 DEG C.

Description

200804457 九、發明說明： 【發明所屬之技術領域】 本發明一般而言係關於聚酯組合物，製自對苯二曱酸或 其酯及其混合物，2,2,4,4-四曱基-1，3-環丁二醇、環己燒 二甲醇及至少一種磷化合物、其反應產物及其混合物，具 有兩種或兩種以上以下性質之獨特組合：高衝擊強度、高 玻璃轉移溫度（Tg)、勃度、特定固有黏度、低動脆性轉移 溫度、良好顏色與透明性、低密度、抗化學性、水解安定 性及長結晶化作用半衰期，其允許彼等容易地被製成物 件。本發明一般而言亦關於製造本發明聚酯組合物之方 法。 【先前技術】 聚對苯二曱酸（1，4_伸環己基二亞甲基）酯（PCT)，一種僅 僅以對苯二甲酸或其酯與環己烷二曱醇為基料之聚 醋’係為此項技藝中已知，且為市購可得。此聚酯從熔融 體冷卻時會迅速地結晶，使其極難以藉此項技藝中已知之 方法形成非晶質物件，譬如擠壓、射出成型等。為減緩 PCT之結晶速率，共聚酯可含有其他二羧酸類或二醇類製 成，譬如間苯二甲酸或乙二醇殘基。此等乙二醇殘基_或 間苯二甲酸-改質之PCT，亦為此項技藝中已知，且為市購 可得。 壓片及模製物件之一種常見共聚酯，係200804457 IX. DESCRIPTION OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates generally to polyester compositions made from terephthalic acid or its esters and mixtures thereof, 2,2,4,4-tetradecyl - 1,3-cyclobutanediol, cyclohexane dimethanol and at least one phosphorus compound, reaction products thereof and mixtures thereof, having a unique combination of two or more of the following properties: high impact strength, high glass transition temperature ( Tg), brilliance, specific intrinsic viscosity, low dynamic brittle transition temperature, good color and transparency, low density, chemical resistance, hydrolytic stability, and long crystallization half-life, which allow them to be easily fabricated into articles. The invention is also generally directed to a process for making the polyester compositions of the present invention. [Prior Art] Poly(p-phenylene terephthalate) (PCT), a kind of polymerization based only on terephthalic acid or its ester and cyclohexanedimethanol Vinegar's are known in the art and are commercially available. The polyester crystallizes rapidly as it cools from the melt, making it extremely difficult to form amorphous articles, such as extrusion, injection molding, etc., by methods known in the art. To slow the rate of crystallization of PCT, the copolyester may be formed from other dicarboxylic acids or glycols, such as isophthalic acid or ethylene glycol residues. Such ethylene glycol residues - or isophthalic acid - modified PCT are also known in the art and are commercially available. a common copolyester of compressed and molded articles,

但其在一些 119732.doc 用以製造薄膜、 製自對苯二甲酸、 200804457 性質中顯示缺失，譬如當足夠改質用乙二醇殘基被加入配 方中’以提供長結晶化作用半衰期時之玻璃轉移溫度與衝 擊強度。例如，製自對苯二甲酸、；1，4_環己烷二甲醇及乙 一醇殘基而具有足夠長結晶化作用半衰期之共聚酯，可提 供非晶質產物，其比本文所揭發之組合物顯示咸認為不期 望地較高之韌脆性轉移溫度與較低玻璃轉移溫度。 4,4’-亞異丙基二酚之聚碳酸酯（雙酚A聚碳酸酯）已被使 用作為此項技藝中已知聚酯之替代物，且為習知工程模製 塑膠。雙酚A聚碳酸酯為一種透明、高性能塑膠，具有良 好物理性質，譬如尺寸安定性、高熱抵抗性及良好衝擊強 度。雖然雙酚-A聚碳酸酯具有許多良好物理性質，但其相 對較高熔融黏度會導致不良熔融體加工性能，且聚碳酸酯 顯示不良抗化學藥品性。其亦難以熱成形。 含有2,2,4,4-四甲基-1，3-環丁二醇之聚合體，亦已一般 性地被描述於此項技藝中。但是，一般而言，此等聚合體 顯示高固有黏度、高熔融黏度及/或高Tg (玻璃轉移溫度或However, it is shown in some of the properties of 119732.doc used to make films, from terephthalic acid, 200804457, such as when sufficient modification is used to add ethylene glycol residues to the formulation to provide long crystallization half-life. Glass transfer temperature and impact strength. For example, a copolyester having a sufficiently long crystallization half-life from terephthalic acid, 1,4-cyclohexanedimethanol and an ethyl alcohol residue can provide an amorphous product, which is disclosed herein. The composition exhibits an undesirably higher ductile brittle transition temperature and a lower glass transition temperature. Polycarbonate of 4,4'-isopropylidenediol (bisphenol A polycarbonate) has been used as a substitute for the polyesters known in the art and is a conventional engineering molded plastic. Bisphenol A polycarbonate is a transparent, high performance plastic with good physical properties such as dimensional stability, high heat resistance and good impact strength. Although bisphenol-A polycarbonate has many good physical properties, its relatively high melt viscosity results in poor melt processing properties, and polycarbonate exhibits poor chemical resistance. It is also difficult to thermoform. Polymers containing 2,2,4,4-tetramethyl-1,3-cyclobutanediol have also been generally described in the art. However, in general, such polymers exhibit high intrinsic viscosity, high melt viscosity and/or high Tg (glass transition temperature or

Tg)，以致工業上所使用之設備可能不足以製造或後聚合 處理此等材料。 因此，於此項技藝中仍需要聚酯組合物，其包含至少一 種聚合體，具有兩種或多種性質之組合，選自至少一種下 列性質：韌度、高玻璃轉移溫度、高衝擊強度、水解安定 性、抗化學藥品性、長結晶化作用半衰期、低韌脆性轉移 溫度u顏色與透明性、較低密度及/或聚醋之可熱成 形性，同時保持在卫業中所使用標準設備上之加工性能。 119732.doc -9- 200804457 此外，在一具體實施例中，於此項技藝中仍需要一種可 較輕易製得適用於本發明之聚酯同時可避免至少一種以下 情形發生之方法：冒泡、斜角形成、色彩形成、發泡、逸 氣及無規律溶融程度（即，聚酯、聚酯之產製及加工系統 之脈動）。於此項技藝中亦需要一種可較輕易且大量（例 如，初步製程規模及/或商業產製）製得適用於本發明之聚 酉旨且同時可避免至少一種前述困難發生之方法。 【發明内容】 咸認某些製自對苯二曱酸、其酯或其混合物，環己烷二 甲醇’及2,2,4,4_四甲基-1，3-環丁二醇且包含特定至少一 種磷化合物、其反應產物及其混合物之聚酯組合物，在一 或多種下述性質上係優於此項技藝中已知之聚酯及聚碳酸 酉旨：該等性質包括高衝擊強度、水解安定性、韌度、抗化 學藥品性、良好顏色與透明性、長結晶化作用半衰期、低 韋刃脆性轉移溫度、較低比重及可熱成形性。咸認此等組合 物在耐熱性上係類似聚碳酸酯，而在標準工業設備上仍然 可加工。再者，此等聚酯具有提升之熱穩定性，因此使其 可較輕易地被製造且允許提升之下游物料加工。 於一具體實施例中，咸認本發明之至少一種方法可提供 較輕易且大量（例如，初步製程規模及/或商業產製）製得適 用於本發明聚酯组合物之任何聚酯，且同時避免至一 夕一種 以下情形發生：冒泡、斜角形成、色彩形成、發泡、逸氣 及無規律熔融程度（即，聚酯、聚酯之產製及加工系統之 脈動）。 119732.doc -10- 200804457 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至100莫耳％之對苯二曱酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至1〇莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含·· i) 2,2,4,4_四甲基-込夂環丁二醇殘基；及 Π)環己烷二甲醇殘基；及 (Π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至i〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高 20個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高 16個碳原子；與 (b) 二醇成份，其包含： i) 1至99莫耳％之2,2,4,4-四甲基-1，3-環丁二醇殘 基；及 119732.doc -11- 200804457 ii) 1至99莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二叛酸成份之總莫耳％為1〇〇莫耳G/。，且二醇成份之總 莫耳％為100莫耳％;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇1〇至 1·2公合/克；且其中聚酯具有以至⑼代之以。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) -一竣酸成份，其包含： i) 70至100莫耳％之對苯二甲酸殘基； 11) 〇至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 〇至1〇莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含·· i"至99莫耳。/。之2,2,4,4_四甲基]，3_環丁二醇 殘基；及 1U 1主yy昊耳％之環己 τ哔线丞；及 (II)至少一種熱穩定劑，1筏 ^其係選自至少一種磷化合物、 其反應產物及其混合物，· 其中二緩酸成份之總莫耳 莖且。/“μ 斗°為1GG莫耳％，且二醇成份之總 莫耳％為100莫耳❶/。；且 119732.doc -12· 200804457 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇 25克/5〇毫 升之濃度下，在25 C下測定時，聚酯之固有黏度為〇.35至 1.2公合/克；且其中聚酯具有85至200°C之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； 11) 0至30莫耳°/〇之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ιιι)0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 1至80莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基；及 11) 20至99莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種填化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為！ 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇·35至 1·2公合/克；且其中聚酯具有以至別代之以。 於一方面’本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： 119732.doc -13 - 200804457 (a)二羧酸成份，其包含： 1) 70至1〇〇莫耳％之對苯二甲酸殘基； η) 〇至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 111) 〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 一醇成份，其包含： 0 40至80莫耳％之2,2,4,4_四甲基]，>環丁二醪 殘基；及 i〇 20至60莫耳％之環己烷二甲醇殘基；及 (II)至少-種熱穩定劑，其係選自至少_種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為⑽莫耳％，1二醇成份之總 莫耳％為100莫耳％ ;且 其中當在6G/4G (重量/重量），四氯乙财，於G2a/5〇毫 升之辰度了纟25 C下測定時，聚自旨之固有黏度為〇·35至 1·2公合/克；且其中聚酯具有以至：⑽它之^^。 於一方面，本發明係關於一種聚醋組合物，其包含： (I)至少一種聚酯，其包含： (a)二叛酸成份，其包含： 0 70至1〇〇莫耳％之對笨二甲酸殘基； 11) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 0至10莫耳％之脂族二羧酸殘基，具有至高16 119732.doc -14- 200804457 個碳原子；與 (b)二醇成份，其包含： I) 40至65莫耳％之2,2,4,4-四甲基<，3-環丁二醇 殘基；及 II) 35至60莫耳％之環己烷二甲醇殘基；及 (Π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇.35至 1·2公合/克；且其中聚g旨具有85至2〇〇。^之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳〇/0之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 4〇至55莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基；及 ii) 45至60莫耳％之環己烷二甲醇殘基；及 119732.doc -15- 200804457 (II)至夕、種熱穩疋劑’其係選自至少一種構化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％，·且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇·35至 1.2公合/克，且其中聚g旨具有85至2〇〇 °c之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 0 70至1〇〇莫耳〇/〇之對苯二曱酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 III) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： I) 40至50莫耳。/。之2,2,4,4-四甲基-1，3-環丁二醇 殘基；及 II) 50至60莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於0.25克/50毫 119732.doc -16 - 200804457 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇 35至 ^公合/克：且其中聚酯具有^至之⑻它之丁^。 於一方面’本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) —魏酸成份，其包含： I) 70至100莫耳〇/〇之對苯二甲酸殘基； II) 〇至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及Tg), so that the equipment used in the industry may not be sufficient to manufacture or post-polymerize such materials. Accordingly, there is still a need in the art for a polyester composition comprising at least one polymer having a combination of two or more properties selected from at least one of the following properties: toughness, high glass transition temperature, high impact strength, hydrolysis Stability, chemical resistance, long crystallization half-life, low toughness brittle transfer temperature u color and transparency, lower density and / or thermoformability of polyester, while maintaining standard equipment used in the health industry Processing performance. Further, in a specific embodiment, there is still a need in the art for a method which makes it relatively easy to produce a polyester suitable for use in the present invention while avoiding at least one of the following situations: bubbling, Bevel formation, color formation, foaming, outgassing, and degree of irregular melting (ie, the production of polyester, polyester, and the pulsation of processing systems). There is also a need in the art for a method that is relatively easy and large (e.g., preliminary process scale and/or commercial production) to produce a package suitable for use in the present invention while avoiding at least one of the aforementioned difficulties. SUMMARY OF THE INVENTION Certain compounds are prepared from terephthalic acid, esters or mixtures thereof, cyclohexanedimethanol' and 2,2,4,4-tetramethyl-1,3-cyclobutanediol. A polyester composition comprising a particular at least one phosphorus compound, its reaction product, and mixtures thereof, is superior to one or more of the following properties of polyesters and polycarbonates known in the art: such properties include high impact Strength, hydrolytic stability, toughness, chemical resistance, good color and transparency, long crystallization half-life, low weft edge brittle transfer temperature, low specific gravity and thermoformability. It is believed that these compositions are similar to polycarbonate in heat resistance and are still processable on standard industrial equipment. Moreover, these polyesters have enhanced thermal stability, thus making them easier to manufacture and allowing for improved downstream material processing. In one embodiment, at least one of the methods of the present invention provides for the preparation of any polyester suitable for use in the polyester compositions of the present invention in a relatively easy and substantial manner (e.g., preliminary process scale and/or commercial production). At the same time, it is avoided that one of the following occurs: bubbling, beveling, color formation, foaming, outgassing, and irregular melting (ie, the production of polyester, polyester, and the pulsation of the processing system). 119732.doc -10- 200804457 In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 100 mol% of terephthalic acid residues; ii) 0 to 30 mol% of aromatic dicarboxylic acid residues having up to 2 carbon atoms; and iii) 0 to 1 mol% of fat a dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: i) a 2,2,4,4-tetramethyl-nonanecyclobutanediol residue; Π) a cyclohexanedimethanol residue; and (Π) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to i 〇〇 mol% a terephthalic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 20 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having Up to 16 carbon atoms; and (b) a diol component comprising: i) from 1 to 99 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; 119732.doc -11- 200804457 ii) 1 to 99 mole % of cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total mole % of the two tickic acid components is 1 〇〇 Mo Er G /. And the total molar % of the diol component is 100 mol%; and wherein when in 60/40 (w/w) phenol/tetrachloroethane, at a concentration of 2525 g/5 〇 ml, The intrinsic viscosity of the polyester when measured at 25 ° C is from 1 Torr to 1.2 cm / gram; and wherein the polyester has a substitution of (9). In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a monodecanoic acid component comprising: i) from 70 to 100 mole percent a phthalic acid residue; 11) an aromatic dicarboxylic acid residue having a hydrazine to 30 mol%, having up to 2 carbon atoms; and ill) an aliphatic dicarboxylic acid residue having 1% molar %, Has a maximum of 16 carbon atoms; and (b) a diol component, which contains ·· i" to 99 moles. /. 2,2,4,4_tetramethyl], 3_cyclobutanediol residue; and 1 U 1 main yy 昊% of cyclohexanthene oxime; and (II) at least one heat stabilizer, 1筏 ^ is selected from at least one phosphorus compound, its reaction product and mixtures thereof, and the total moiré of the two acid-lowering components. /"μ斗° is 1GG mol%, and the total molar % of the diol component is 100 moles/.; and 119732.doc -12· 200804457 where when 60/40 (w/w) phenol/four In the gaseous ethane, the inherent viscosity of the polyester is 〇35 to 1.2 com/g when measured at 25 C at a concentration of 25 g/5 〇ml; and the polyester has 85 to 200 ° C In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 〇〇 Mo % of terephthalic acid residues; 11) 0 to 30 moles per gram of aromatic dicarboxylic acid residues, having up to 2 carbon atoms; and ιιι) 0 to 10 mol% of aliphatic two a carboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: i) from 1 to 80 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutane a diol residue; and 11) 20 to 99 mole % of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one of a compound, a reaction product thereof, and a mixture thereof; The total mole % of the dicarboxylic acid component is! 〇〇 % by ear, and the total molar % of the diol component is 100 mol%; and wherein, in 60/40 (w/w) phenol/tetrachloroethane, at a concentration of 2525 g/5 〇ml When measured at 25 ° C, the inherent viscosity of the polyester is 〇·35 to 1.2 cm / gram; and wherein the polyester has a singularity. In one aspect, the invention relates to a polyester combination And comprising: (I) at least one polyester comprising: 119732.doc -13 - 200804457 (a) a dicarboxylic acid component comprising: 1) 70 to 1 mole % of terephthalic acid residue η) 〇 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and 111) 〇 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbons And (b) an alcohol component comprising: 0 40 to 80 mol% of 2,2,4,4_tetramethyl], > cyclobutane dioxime residue; and i〇20 to 60 mo And (II) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is (10) Moer%, the total amount of 1 diol component The ear% is 100% by mole; and when it is measured at 6G/4G (w/w), tetrachloroethylene, and G2a/5〇ml at 纟25 C, the intrinsic viscosity is 〇·35 to 1.2 cm/g; and wherein the polyester has: (10) it. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester, It comprises: (a) a two-rebel component comprising: 0 70 to 1 mol% of a para-dicarboxylic acid residue; 11) 0 to 30 mol% of an aromatic dicarboxylic acid residue having a supreme 2 碳 one carbon atom; and ill) 0 to 10 mol% of the aliphatic dicarboxylic acid residue having a height of 16 119732.doc -14-200804457 carbon atoms; and (b) a diol component comprising: I 40 to 65 mol% of 2,2,4,4-tetramethyl<,3-cyclobutanediol residues; and II) 35 to 60 mol% of cyclohexanedimethanol residue; (Π) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1% mol%, and the total amount of the diol component Ear % is 100% by mole; and where In 60/40 (w/w) phenol/tetrachloroethane, the inherent viscosity of polyester is 〇35 to 1.2 when measured at 25 ° C at a concentration of 25 g / 5 〇 ml. Combination / gram; and wherein polyg is intended to have 85 to 2 〇〇. ^Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 Torrole/ 0 terephthalic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 〇 to 10 mol% of an aliphatic dicarboxylic acid residue a base having up to 16 carbon atoms; and (b) a diol component comprising: i) 4 to 5 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol And ii) 45 to 60 mol% of cyclohexanedimethanol residue; and 119732.doc -15-200804457 (II), the thermal stabilizer is selected from at least one structural compound, The reaction product and mixture thereof; wherein the total molar % of the dicarboxylic acid component is 1% mol%, and the total molar % of the diol component is 100 mol%, and wherein when it is at 60/40 (weight) /wt) phenol / tetrachloroethane, at a concentration of 25.25 g / 5 〇 ml, when measured at 25 ° C, the inherent viscosity of polyester is 〇 · 35 to 1.2 com / g, and The poly g has a Tg of 85 to 2 ° C. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 0 70 to 1 Torrole/〇 a terephthalic acid residue; II) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and III) 0 to 10 mol% of an aliphatic dicarboxylic acid residue a group having up to 16 carbon atoms; and (b) a diol component comprising: I) 40 to 50 moles. /. 2,2,4,4-tetramethyl-1,3-cyclobutanediol residue; and II) 50 to 60 mol% of cyclohexanedimethanol residue; and (II) at least one heat stable And a mixture thereof is selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 100% by mole, and the total mole % of the diol component is 100% by mole; The inherent viscosity of the polyester when measured at 25 ° C at a concentration of 0.25 g / 50 119 732.doc -16 - 200804457 liters in 60/40 (w/w) phenol/tetrachloroethane It is 〇35 to ^common/gram: and wherein the polyester has ^(8) which is butyl. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a formic acid component comprising: I) 70 to 100 moles per gram Terephthalic acid residue; II) 〇 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms;

Hi) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 45至55莫耳0/〇之2,2,4,4_四甲基-1，3-環丁二醇 殘基；及 Π) 45至55莫耳％之環己烷二甲醇殘基；及 (Π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％;且 其中當在60/40 (重量/重量）酚/四氣乙烧中，於〇.25克/50毫 升之遭度下’在25 °C下測定時，聚酯之固有黏度為0.35至 1·2公合/克；且其中聚酯具有85至2〇〇它之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二叛酸成份，其包含： 119732.doc -17- 200804457 i) 70至100莫耳％之對苯二甲酸殘基； 11) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： I) 1至99莫耳％之2,2,4,4-四甲基-1，3_環丁二醇 殘基；及 II) 1至99莫耳％之環己烷二甲醇殘基；及 (c) 至少一種分支劑或其殘基；及 (II)至少一種熱穩定劑，其係選自至少一種填化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為100莫耳。且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為0.35至 1·2公合/克；且其中聚g旨具有^至^⑽力之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 1) 70至100莫耳％之對苯二曱酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高20 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 119732.doc -18- 200804457 個碳原子；與 (b)二醇成份，其包含： 0 1至99莫耳％之2,2,4,4-四曱基-1，3-環丁二醇 殘基；及 ii) 1至99莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為i 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之浪度下，在25 C下測定時，聚酯之固有黏度為〇 35至 0.75公合/克，且其中聚酯具有1〇〇至2〇〇。〇之丁^。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 1) 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳。/。之芳族二羧酸殘基 ，具有至高20 個碳原子；及 in) 0至10莫耳％之脂族二羧酸殘基，具有至高Μ 個碳原子；與 (b) 二醇成份，其包含·· 0 40至80莫耳％之2,2,4,4四甲基一以環丁二醇 殘基；及 ii) 20至60莫耳。/〇夕广^m ^ 夭吁/〇之％己烷二甲醇殘基；及 119732.doc .19- 200804457 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一魏酸成份之總莫耳％為1 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳。/。；且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇 25克/5〇毫 升之/辰度下，在25 C下測定時，聚酯之固有黏度為〇.35至 0.75公合/克，且其中聚酯具有11〇至2〇〇。〇之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： I) 70至1〇〇莫耳％之對苯二曱酸殘基； η) 0至30莫耳。/。之芳族二羧酸殘基，具有至高2〇 個碳原子；及 111)0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： Ο 40至65莫耳％之2,2,4,4_四甲基·•環丁二醇 殘基；及 II) 35至60莫耳％之環己烷二甲醇殘基；及 (II) 至少種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳％為i00莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 119732.doc 200804457 升之濃度下’在25°C下測定時，聚g旨之固有黏度為〇35至 0.75公合/克，且其中聚酯具有j 1〇至2〇〇〇c之丁^。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含·· (a) 二羧酸成份，其包含： 1) 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二叛酸殘基，具有至高2〇 個碳原子；及 ill) 0至10莫耳。/〇之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 40至55莫耳％之25254,4_四甲基4,3-環丁二醇 殘基；及 ii) 45至60莫耳0/〇之環己烧二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種填化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下’在25 °C下測定時，聚酯之固有黏度為〇·35至 0.75公合/克；且其中聚酯具有11〇至2〇〇ι之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 119732.doc -21 - 200804457 I) 70至100莫耳％之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高20 個碳原子；及 ill) 〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： I) 40至5〇莫耳％之2,2,4,4-四曱基·1，3-環丁二醇 殘基；及 II) 50至60莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一竣酸成份之總莫耳％為1 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇.25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇·35至 0.75公合/克；且其中聚酯具有11〇至2〇〇〇c之丁^。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 1) 70至1〇〇莫耳〇/〇之對苯二甲酸殘基； Π) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高 個碳原子；與 119732.doc •22· 200804457 (b)二醇成份，其包含： i) 45至55莫耳％之2,2,4,4_四甲基環丁二醇 殘基；及 η) 45至55莫耳0/〇之環己烷二曱醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之/辰度下，在25 C下測定時，聚酯之固有黏度為〇.35至 0.75公合/克；且其中聚_具有11〇至2〇〇。〇之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至100莫耳％之對苯二曱酸殘基； ii) 0至30莫耳％之芳族二繞酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳。/〇之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 40至80莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基；及 ii) 20至60莫耳％之環己烷二甲醇殘基；及 (Π)至少一種熱穩定劑，其係選自至少一種磷化合物、 119732.doc -23- 200804457 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之/辰度下，在25 C下測定時，聚酯之固有黏度為〇 35至 0.75公合/克；且其中聚酯具有u〇s2〇(rc之^^。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： I) 70至1〇〇莫耳％之對苯二曱酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： Ο 40至80莫耳％之2,2,4,4-四甲基-1，3·環丁二醇 殘基；及 η) 20至60莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之？辰度下，在25°C下測定時，聚酯之固有黏度為〇.35至 119732.doc -24- 200804457 〇·70公合/克；且其中聚酯具有11〇至2〇〇ί^之“。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 1) 70至1〇〇莫耳〇/〇之對苯二甲酸殘基； Π) 0至30莫耳％之芳族二羧酸殘基，具有至高20 個碳原子；及 ιιι)〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) —醇成份，其包含： i) 40至80莫耳％之2,2,4,4-四甲基-1，3_環丁二酵 殘基；及 η) 20至60莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種鱗化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中 升 ，於0.25克/50毫Hi) 0 to 10 mol% of the aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 1) 45 to 55 mTorr/2, 2, 4,4_tetramethyl-1,3-cyclobutanediol residue; and Π) 45 to 55 mol% of cyclohexanedimethanol residue; and (Π) at least one heat stabilizer, which is selected From at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1% by mole, and the total mole % of the diol component is 100% by mole; 60/40 (w/w) phenol/four-gas sulphur, at a temperature of 2525g/50ml', when measured at 25 °C, the inherent viscosity of polyester is 0.35 to 1.2 metric / gram; and wherein the polyester has a Tg of 85 to 2 Torr. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a di-retensive acid component comprising: 119732.doc -17- 200804457 i) 70 to 100 mole % terephthalic acid residue; 11) 0 to 30 mole % of aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mole % of aliphatic two a carboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: I) from 1 to 99 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutane And a residual diol residue; At least one compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 100 moles. And the total molar % of the diol component is 100 mol%; and wherein, in 60/40 (w/w) phenol/tetrachloroethane, at a concentration of 2525 g/5 〇ml, at 25 When measured at ° C, the inherent viscosity of the polyester is 0.35 to 1.2 cm / gram; and wherein the poly g is intended to have a Tg of ^ to ^ (10) force. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) from 70 to 100 mole percent of para-benzene a dicarboxylic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 20 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having a high 16 119732.doc -18- 200804457 carbon atoms; and (b) diol component, comprising: 0 1 to 99 mol% of 2,2,4,4-tetradecyl-1,3-cyclobutane An alcohol residue; and ii) from 1 to 99 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total molar % of the carboxylic acid component is i 〇〇 mol %, and the total molar % of the diol component is 100 mol %; and wherein in 60/40 (w/w) phenol/tetrachloroethane The intrinsic viscosity of the polyester is 〇35 to 0.75 com/g when measured at 25 C under the wave of 25 g/5 〇ml, and the polyester has 1 〇〇 to 2 〇〇. 〇之丁^. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 1 mole % Terephthalic acid residue; ii) 0 to 30 moles. /. An aromatic dicarboxylic acid residue having up to 20 carbon atoms; and in) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to Μ carbon atoms; and (b) a diol component Containing 0. 40 to 80 mole % of 2,2,4,4 tetramethyl one as a cyclobutanediol residue; and ii) 20 to 60 moles. /〇夕广^m ^ 夭 〇 /〇% hexane dimethanol residue; and 119732.doc .19- 200804457 (II) at least one heat stabilizer selected from at least one phosphorus compound, its reaction product and A mixture thereof; wherein the total mole % of a ferulic acid component is 1% by mole, and the total mole % of the diol component is 100 moles. /. And wherein the inherent viscosity of the polyester is 〇 when measured at 25 C in 60/40 (w/w) phenol/tetrachloroethane at 〇25 g/5 〇ml/min. 35 to 0.75 com/g, and wherein the polyester has 11 to 2 Torr. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: I) 70 to 1 mole % Terephthalic acid residue; η) 0 to 30 moles. /. An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and 111) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component, It comprises: Ο 40 to 65 mol% of 2,2,4,4-tetramethyl·cyclobutanediol residues; and II) 35 to 60 mol% of cyclohexanedimethanol residue; (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the monocarboxylic acid component is i00 mol%, and the total molar % of the diol component 100 mol%; and wherein when measured at 25 ° C in 60/40 (w/w) phenol/tetrachloroethane at a concentration of 25.25 g/5 〇 119732.doc 200804457 liters In the meantime, the intrinsic viscosity of the poly g is 〇35 to 0.75 com/g, and wherein the polyester has a din of j 1 〇 to 2 〇〇〇 c. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 1 mole % Terephthalic acid residues; ii) 0 to 30 mole % of aromatic di-retensive acid residues having up to 2 carbon atoms; and ill) 0 to 10 moles. / an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: i) 40 to 55 mol% of 25254, 4_tetramethyl 4,3-ring a butanediol residue; and ii) a 45 to 60 molar 0/〇 cyclohexane dimethanol residue; and (II) at least one heat stabilizer selected from at least one filler compound, a reaction product thereof, and a mixture; wherein the total mole % of the dicarboxylic acid component is 1% molar %, and the total molar % of the diol component is 100 mole %; and wherein when 60/40 (weight/weight) phenol/four In the case of ethyl chloride, at a concentration of 25 g/5 〇ml, the inherent viscosity of the polyester is 〇35 to 0.75 com/g when tested at 25 ° C; and the polyester has 11 〇 to 2 〇〇ι之Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 119732.doc -21 - 200804457 I) 70 to 100 mole % terephthalic acid residue; II) 0 to 30 mole % of aromatic dicarboxylic acid residue having up to 20 carbon atoms; and ill) 〇 to 10 mole % of aliphatic dicarboxylic acid An acid residue having up to 16 carbon atoms; and (b) a diol component comprising: I) 40 to 5 〇 mol% of 2,2,4,4-tetradecyl·1,3-cyclobutane a diol residue; and II) 50 to 60 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total molar % of the citric acid component is 1 〇〇 mol %, and the total molar % of the diol component is 100 mol %; and wherein when 60/40 (w/w) phenol/tetra-ethane In the concentration of 25 g / 5 〇 ml at 25 ° C, the inherent viscosity of the polyester is 〇 35 to 0.75 com / g; and the polyester has 11 〇 to 2 〇〇 〇c的丁^. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 1 Torrole/ Terephthalic acid residues; Π) 0 to 30 mol% of aromatic dicarboxylic acid residues having up to 2 carbon atoms; and iii) 0 to 10 mol% of aliphatic dicarboxylic acid residues a base having up to one carbon atom; and 119732.doc •22· 200804457 (b) a diol component comprising: i) 45 to 55 mol% of 2,2,4,4-tetramethylcyclobutanediol a residue; and η) 45 to 55 moles of a cyclohexanedikecanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total molar % of one of the carboxylic acid components is 100 mol%, and the total molar % of the diol component is 100 mol%; and wherein in 60/40 (w/w) phenol/tetrachloroethane The intrinsic viscosity of the polyester is 〇.35 to 0.75 com/g when measured at 25 C under 25 g / 5 〇 / min; and the poly _ has 11 〇 to 2 〇〇. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) from 70 to 100 mol% of para-benzene a diterpene acid residue; ii) 0 to 30 mol% of an aromatic diacid residue having up to 2 carbon atoms; and iii) 0 to 10 moles. / an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: i) 40 to 80 mol% of 2,2,4,4-tetramethyl- a 1,3-cyclobutanediol residue; and ii) 20 to 60 mol% of a cyclohexanedimethanol residue; and (Π) at least one heat stabilizer selected from at least one phosphorus compound, 119,732. Doc -23- 200804457 The reaction product and mixture thereof; wherein the total molar % of the dicarboxylic acid component is 1% mol%, and the total molar % of the diol component is 100 mol%; and wherein when 60 /40 (w/w) phenol/tetrachloroethane, at 25.25 g/5 〇ml/min, when measured at 25 C, the inherent viscosity of polyester is 〇35 to 0.75 com / And wherein the polyester has u〇s2〇(rc^^. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxyl An acid component comprising: I) 70 to 1 mole % terephthalic acid residue; II) 0 to 30 mole % of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; And in) 0 to 10 mol% of the aliphatic dicarboxylic acid residue, Having a maximum of 16 carbon atoms; and (b) a diol component comprising: Ο 40 to 80 mol% of 2,2,4,4-tetramethyl-1,3·cyclobutanediol residues; η) 20 to 60 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total of the dicarboxylic acid component The molar % is 100 mol %, and the total molar % of the diol component is 100 mol %; and wherein when 60/40 (w/w) phenol/tetrachloroethane, 〇 25 g/5 What about 〇ml? At the time of measurement, the inherent viscosity of the polyester is 〇.35 to 119732.doc -24-200804457 〇·70 com/g when measured at 25 ° C; and the polyester has 11 〇 to 2 〇〇 ί ^ In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 1 〇〇 Mo Deuterium/hydrazine terephthalic acid residue; Π) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 20 carbon atoms; and ιιι) to 10 mol% of aliphatic dicarboxylic acid An acid residue having a maximum of 16 carbon atoms; and (b) an alcohol component comprising: i) 40 to 80 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutane a leaven residue; and η) 20 to 60 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one scale compound, a reaction product thereof, and a mixture thereof; The total molar % of the carboxylic acid component is 1% mol%, and the total molar % of the diol component is 100 mol%; and wherein when it is in 60/40 (w/w) phenol/tetra-ethane l, at 0.25 g / 50 m

0·68公合/克；且其中 其中聚酯具有110至200°C之Tg。 於一方面，本發明係關於—種聚酯組合物，其包含： 於一方面， (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 1) 70至1〇〇莫耳％之對苯二甲酸殘基； 119732.doc -25- 200804457 U) 〇至3G莫耳％之芳族二缓酸殘基，具有至高20 個碳原子；及 iii)0至10莫耳％之脂族二㈣殘基具有至高 個碳原子；與 (b)二醇成份，其包含： 〇 1至99莫耳％之2,2,4,4•四甲基]，3_環丁二醇 殘基；及 U) 1至"莫耳％之環己烧二甲醇殘基；及 (II)至少-種熱穩定劑，其係選自至少—種磷化合物、 其反應產物及其混合物； 其中—叛酸成份之總莫耳％鼻1 〇 曾。/ 〇 天寸馬100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量)酚/四氯乙烷中，於〇 25克/5〇毫 升之濃度下，在下測定時，聚醋之固有黏度為〇35至 小於0.70公合/克；且其中聚酯具有11〇至2〇〇t>c之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 1) 70至100莫耳％之對苯二甲酸殘基； Π) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 119732.doc -26- 200804457 Ο 40至65莫耳％之2,2,4,4_四曱基_1，3-環丁二酵 殘基；及 η) 35至60莫耳〇/〇之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇·35至 1·2公合/克；且其中聚酯具有11〇至2〇〇。(：之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳〇/〇之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 〇至10莫耳％之脂族二叛酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 40至65莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基；及 Π) 35至60莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 119732.doc -27- 200804457 其中一羧酸成份之總莫耳％為1⑽替甘。/ ^ 六吁马1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在6G/4G (重量/重量）紛/四氣乙烧中，於〇.25克/5〇毫 升之濃度下’在饥下測定時，聚醋之固有黏度為〇.35至 0.75公合/克；且其中聚酯具有11〇至16〇它之Tg。 於-方面，本發明係關於一種聚醋組合物，其包含： (I) 至少一種聚酯，其包含： (a) —竣酸成份，其包含： i) 70至100莫耳％之對苯二甲酸殘基； II) 〇至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 III) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 40至65莫耳％之2,2,4,4-四甲基_1，3_環丁二醇 殘基；及 η) 35至60莫耳〇/〇之環己烷二曱醇殘基；及 (II) 至少種熱穩疋劑，其係選自至少一種填化合物、 其反應產物及其混合物； 其中二叛酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之/辰度下’在25C下測定時，聚醋之固有黏度為〇·35至 0.75公合/克；且其中聚酯具有11(^15(rc之Tg。 119732.doc -28- 200804457 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 一竣酸成份，其包含： i) 70至1〇〇莫耳％之對苯二曱酸殘基； 11) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ui)〇至10莫耳％之脂族二羧酸殘基，具有至高16 個破原子；與 (b) 二醇成份，其包含： I) 40至65莫耳〇/〇之2,2,4,4_四甲基_1，3_環丁二醇 殘基；及 II) 35至60莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳。/。；且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫 升之濃度下，在251下測定時，聚酯之固有黏度為〇.35至 公合/克；且其中聚酯具有12〇至13rC2Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 1) 70至1〇〇莫耳〇/〇之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 119732.doc -29· 200804457 個碳原子；及 iii) 〇至10莫耳％之脂族二叛酸殘基，具有至高16 個碳原子；與 (b) 一醇成份，其包含·· I) 40至65莫耳％之2,2,4,4_四甲基-。、環丁二醇 殘基；及 π) 35至60莫耳％之環己烷二曱醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一魏6^成份之總莫耳％為1⑽莫耳％，且二醇成份之總 莫耳％為100莫耳％;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下’在25 °C下測定時，聚酯之固有黏度為〇·35至 0.75公合/克；且其中聚酯具有12〇至135。〇之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二叛酸成份，其包含： i) 70至1〇〇莫耳〇/〇之對苯二曱酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 40至65莫耳％之2,2,4,4-四甲基-1，3·環丁二醇 119732.doc -30 - 200804457 殘基；及 u) 35至60莫耳％之環己烷二甲醇殘基；及 (π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中-缓酸成份之總莫耳⑻莫耳％，^二醇成份之總 莫耳％為100莫耳％;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之/辰度了纟25 c下測定時，聚g旨之固有黏度為〇·35至 1.2公合/克，·且其中聚酯具有13〇至145〇C2Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： I) 70至1〇〇莫耳％之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： I) 40至65莫耳％之2,2,4,4·四甲基-i，3-環丁二醇 殘基；及 II) 35至60莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩疋劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 119732.doc -31 - 200804457 莫耳％為100莫耳。/。；且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇35至 0.75公合/克；且其中聚酯具有13〇至145QC2Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： Ο 70至1〇〇莫耳％之對苯二甲酸殘基； η) 0至30莫耳。/〇之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ιιι)〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 4〇至65莫耳％之2,2,4,4-四甲基_1，3-環丁二醇 殘基；及 Π) 35至60莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種填化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之/辰度下，在25 C下測定時，聚酯之固有黏度為〇.35至 0.70公合/克；且其中聚酯具有130至145°C之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： 119732.doc •32· 200804457 (i)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至100莫耳％之對苯二甲酸殘基； U) 0至30莫耳％之芳族二㈣殘基，具有至高2〇 個碳原子；及 ill) 0至10莫耳％之脂族二羧酸殘基，具有至高 個碳原子；與 (b) -^醇成份，其包含： 〇 4〇至65莫耳％之2,2,4,4-四甲基-ΐ，3·環丁二醇 殘基；及 11) 35至60莫耳〇/〇之環己烷二甲醇殘基；及 (Π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二幾酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％;且 其中當在60/40 (重量/重量）盼/四氯乙烧中，於〇25克/5〇毫 " 彳之濃度下’在说下測定時，《之固有黏度為0.58至 1公合/克；且其中聚酯具有13〇至145〇CiTg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： I) 70至100莫耳％之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 119732.doc -33- 200804457 ill) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： 0 40至65莫耳％之2,2,4,4_四甲基<,3-環丁二醇 殘基；及 11) 35至60莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇58至 小於1公合/克；且其中聚酯具有13〇至145。〇之Tg。 於一方面’本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) ^一缓酸成份，其包含： 1) 70至100莫耳％之對苯二甲酸殘基； 1〇 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 〇至10莫耳。/。之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含·· i) 40至65莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基；及 119732.doc -34 - 200804457 ii) 35至60莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一魏®文成伤之總莫耳％為1 〇 〇莫耳％，且二醇成份之總 莫耳％為10 0莫耳％ ;且 其中當在60/40 (重量/重量）盼/四氣乙烧中，於〇25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇·58至 〇·75公合/克；且其中聚酯具有13〇至145^之丁§。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 1) 70至1〇〇莫耳〇/〇之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 0 4〇至65莫耳％之2,2,4,4-四曱基-1，3-環丁二醇 殘基；及 ii) 35至60莫耳％之環己烷二甲醇殘基；及 (II) 至少-種熱敎劑’其係選自至少—種鱗化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為】ηΛ曾瓦〇/ α ^ 夫吁馮100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 119732.doc -35- 200804457 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇 25克/5〇毫 升之?辰度下’在2 5 C下測定時，聚酯之固有黏度為〇 · 5 8至 0.72公合/克；且其中聚酯具有13〇至i45°C之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至100莫耳％之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： I) 40至65莫耳〇/〇之2,2,4,4-四甲基環丁二醇 殘基；及 II) 35至60莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳。/。為i 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇.25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇6至1 a泛/克，且其中聚酉旨具有13〇至i45〇c之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： 119732.doc -36 - 200804457 (a) 二羧酸成份，其包含： 1) 70至100莫耳〇/0之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 0至10莫耳。/〇之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： I) 40至65莫耳％之2,2,4,4-四曱基_1，3_環丁二醇 殘基；及 II) 35至60莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種構化合物、 其反應產物及其混合物； 其中一叛酸成伤之總莫耳％為1 〇 〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇·6至 小於1公合/克；且其中聚酯具有13〇至l45<JCiTg。 於一方面’本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： Ο)二羧酸成份，其包含： I) 70至100莫耳％之對苯二甲酸殘基； II) 〇至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 〇至10莫耳％之脂族二羧酸殘基，具有至高16 119732.doc -37- 200804457 個碳原子；與 (b)二醇成份，其包含·· 1) 40至65莫耳％之2,2,4,4_四甲基-1，3-環丁二醇 殘基；及 11) 35至60莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳。/。；且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇 25克/5〇毫 升之/辰度下，在25 °C下測定時，聚酯之固有黏度為〇6至 〇·75公合/克；且其中聚酯具有13〇至145它之丁§。 於方面，本發明係關於一種聚酯組合物，其包含·· (I)至少一種聚酯，其包含·· (a)二羧酸成份，其包含： i) 70至1〇〇莫耳〇/〇之對苯二甲酸殘基，· u) 〇至3〇莫耳％之芳族二羧酸殘基，具有至高20 個碳原子；及 iii)()至10莫耳％之脂族二羧酸殘基’具有至高16 個碳原子；與 (b)二醇成份，其包含： 二醇 1) 40至65莫耳％之2,2,4,4_四甲基」，3 殘基；及 ii) 35至60莫耳％之環己烷二甲醇殘基；及 119732.doc -38- 200804457 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳。/〇 ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇_6至 〇·72公合/克；且其中聚酯具有13〇至“代之丁^。 於一方面’本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳〇/〇之對苯二曱酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高20 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 1至99莫耳％之2,2,4,4_四甲基-1，3_環丁二醇 殘基；及 ii) 1至99莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳。/。；且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫 119732.doc •39· 200804457 升之濃度下，在25°C下測定時，聚酯之固有黏度為0.35至 1.2公合/克；且其中聚g旨具有I〕？至2〇〇。〇之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； 11) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 1至80莫耳％之2,2,4,4_四甲基-1，3-環丁二醇 殘基；及 ii) 20至99莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一竣&L成伤之總莫耳％為10 0莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下’在25 °C下測定時，聚酯之固有黏度為〇·35至 1.2公合/克；且其中聚酯具有127至200°C之Tg。 於一方面’本發明係關於一種聚g旨組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 119732.doc -40- 200804457 i) 70至100莫耳％之對苯二曱酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高汕 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： 1) 1至99莫耳％之2,2,4,4_四甲基]，3•環丁二醇 殘基；及 ii) 1至99莫耳％之環己烷二曱醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇 25克/5〇 耄升之濃度下，在25°C下測定時，聚酯之固有黏度為〇.35 至1.2公合/克；且其中聚酯具有大於148至至高2〇(rc之0·68 com/g; and wherein the polyester has a Tg of 110 to 200 °C. In one aspect, the invention relates to a polyester composition comprising: (1) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 1 〇对 耳 % % terephthalic acid residue; 119732.doc -25- 200804457 U) 〇 to 3G mol% of aromatic diacidic acid residue, having up to 20 carbon atoms; and iii) 0 to 10 mo The aliphatic di(tetra) residue of the ear % has a highest carbon atom; and the (b) diol component comprises: 〇1 to 99 mol% of 2,2,4,4•tetramethyl], 3_ring a butanediol residue; and U) 1 to " mol% of a cyclohexanedimethanol residue; and (II) at least a heat stabilizer selected from at least a phosphorus compound, a reaction product thereof, and a mixture thereof; wherein - the total mole of the tickic acid component is 1% of the nose. / 〇天寸马100% by mole, and the total molar % of the diol component is 100% by mole; and wherein when in 60/40 (w/w) phenol/tetrachloroethane, 〇25g/ At a concentration of 5 liters, the inherent viscosity of the vinegar is from 〇35 to less than 0.70 com/g; and wherein the polyester has a Tg of 11 〇 to 2 〇〇t>c. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 100 mole percent para-benzene a dicarboxylic acid residue; Π) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having a high 16 carbon atoms; and (b) diol component, which comprises: 119732.doc -26- 200804457 Ο 40 to 65 mol% of 2,2,4,4_tetradecyl-1,3-cyclobutane a leave residue; and η) a cyclohexane dimethanol residue of 35 to 60 moles per hydrazine; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; Wherein the total molar % of the dicarboxylic acid component is 1% mol%, and the total molar % of the diol component is 100 mol%; and wherein 60/40 (w/w) phenol/tetrachloroethylene In the case of alkane, at a concentration of 25 g / 5 〇 ml, the inherent viscosity of the polyester is 〇·35 to 1.2 cm/g when measured at 25 ° C; and the polyester has 11 〇 to 2〇〇. (Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 〇 a terephthalic acid residue of 〇mole/〇; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) up to 10 mol% of fat a quaternary acid residue having a maximum of 16 carbon atoms; and (b) a diol component comprising: i) 40 to 65 mol% of 2,2,4,4-tetramethyl-1,3- a cyclobutanediol residue; and Π) 35 to 60 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof 119732.doc -27- 200804457 The total molar % of one of the carboxylic acid components is 1 (10) tega. / ^ 六吁马1〇〇莫耳%, and the total molar % of the diol component is 100% by mole; and when it is in 6G/4G (W/W)/Four-burning, in 〇. At a concentration of 25 g/5 〇ml, the intrinsic viscosity of the vinegar is 〇35 to 0.75 com/g when measured under hunger; and the polyester has a Tg of 11 〇 to 16 。. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a phthalic acid component comprising: i) 70 to 100 mole percent para-benzene a dicarboxylic acid residue; II) an aromatic dicarboxylic acid residue of up to 30 mol%, having up to 2 carbon atoms; and III) an aliphatic dicarboxylic acid residue of 0 to 10 mol%, having a high 16 carbon atoms; and (b) a diol component comprising: 1) 40 to 65 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; a cyclohexanedimethanol residue of 35 to 60 moles per oxime; and (II) at least one heat stabilizer selected from the group consisting of at least one compound, a reaction product thereof, and a mixture thereof; The total molar % of the ingredients is 100 mole %, and the total molar % of the diol component is 100 mole %; and wherein when in 60/40 (weight/weight) phenol / tetrachloroethane, in 〇. 25 g / 5 〇 / / degree 'measured at 25 C, the inherent viscosity of the vinegar is 〇 · 35 to 0.75 com / g; and the polyester has 11 (^ 15 (rc Tg. 119732. Doc -28- 200804457 In one aspect, the invention relates to a An ester composition comprising: (I) at least one polyester comprising: (a) a citric acid component comprising: i) 70 to 1 mole % of a terephthalic acid residue; 11) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ui) to 10 mol% of an aliphatic dicarboxylic acid residue having a maximum of 16 broken atoms; b) a diol component comprising: I) 40 to 65 moles per mole of 2,2,4,4-tetramethyl-1,3_cyclobutanediol residues; and II) 35 to 60 moles And (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1〇 〇 mol%, and the total mole % of the diol component is 100 moles. /. And wherein the inherent viscosity of the polyester is 〇.35 to GM when measured at 251 in 60/40 (w/w) phenol/tetra-ethane at a concentration of 25 g/5 〇ml. And / gram; and wherein the polyester has 12 〇 to 13 r C 2 Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 1 Torrole/ Terephthalic acid residues; η) 0 to 30 mol% of aromatic dicarboxylic acid residues, having a maximum of 2〇119732.doc -29·200804457 carbon atoms; and iii) 〇 to 10 mol% An aliphatic two-rebel acid residue having a maximum of 16 carbon atoms; and (b) an alcohol component comprising: · I) 40 to 65 mol% of 2,2,4,4-tetramethyl-. a cyclobutanediol residue; and π) 35 to 60 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total molar % of a component of the wei 6 is 1 (10) mol %, and the total molar % of the diol component is 100 mol %; and wherein when the phenol/four is 60/40 (w/w) In the case of ethyl chloride, at a concentration of 25 g / 5 〇 ml, the inherent viscosity of the polyester is 〇·35 to 0.75 com/g when tested at 25 ° C; and the polyester has 12 〇 to 135 . Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a two-rebel component comprising: i) 70 to 1 Torrole/ a terephthalic acid residue; II) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ill) 0 to 10 mol% of an aliphatic dicarboxylic acid a residue having up to 16 carbon atoms; and (b) a diol component comprising: i) 40 to 65 mol% of 2,2,4,4-tetramethyl-1,3·cyclobutanediol 119732.doc -30 - 200804457 a residue; and u) 35 to 60 mol% of a cyclohexanedimethanol residue; and (π) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof And a mixture thereof; wherein - the total molar amount of the molybdenum component (8) mol%, the total molar % of the diol component is 100 mol%; and wherein when 60/40 (w/w) phenol/tetrachloroethylene In the alkane, when the 〇25g/5〇ml/min is measured at 纟25c, the intrinsic viscosity of the polyg is 〇35 to 1.2 com/g, and the polyester has 13〇 to 145. 〇C2Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: I) 70 to 1 mole % Terephthalic acid residue; II) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and in) 0 to 10 mol% of an aliphatic dicarboxylic acid residue, Having a maximum of 16 carbon atoms; and (b) a diol component comprising: I) 40 to 65 mol% of 2,2,4,4·tetramethyl-i,3-cyclobutanediol residues; And II) 35 to 60 mol% of a cyclohexanedimethanol residue; and (II) at least one thermal stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the dicarboxylic acid component The total molar % is 1% molar, and the total diol content of 119732.doc -31 - 200804457 is 100 moles. /. And wherein the inherent viscosity of the polyester is 〇35 when measured at 25 ° C in 60/40 (w/w) phenol/tetrachloroethane at a concentration of 25.25 g/5 〇ml. Up to 0.75 com/g; and wherein the polyester has 13 〇 to 145 QC2 Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: Ο 70 to 1 〇〇 mol% of a pair Phthalic acid residue; η) 0 to 30 moles. An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and an aliphatic dicarboxylic acid residue of up to 10 mol% having up to 16 carbon atoms; and (b) a diol Ingredients comprising: i) 4 to 6 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and Π) 35 to 60 mol% of cyclohexene An alkane dimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one of a compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1% by mole, And the total molar % of the diol component is 100 mol%; and wherein, in 60/40 (w/w) phenol/tetrachloroethane, at 〇25 g/5〇ml/min, The polyester has an intrinsic viscosity of from 3535 to 0.70 com/g when measured at 25 C; and wherein the polyester has a Tg of from 130 to 145 °C. In one aspect, the invention relates to a polyester composition comprising: 119732.doc • 32· 200804457 (i) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 100 mole % terephthalic acid residue; U) 0 to 30 mole % of aromatic di(tetra) residues having up to 2 carbon atoms; and ill) 0 to 10 mole % of aliphatic dicarboxylic acid An acid residue having a highest carbon atom; and a (b)-ol alcohol component comprising: 〇4〇 to 65 mol% of 2,2,4,4-tetramethyl-anthracene, 3·cyclobutane An alcohol residue; and 11) a cyclohexane dimethanol residue of 35 to 60 moles per hydrazine; and at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; Wherein the total mole % of the two acid components is 100 mole %, and the total mole % of the diol component is 100 mole %; and wherein when in 60/40 (weight/weight) / tetrachloroethane At the concentration of 25 grams / 5 〇 & quot quot 在 在 在 在 在 在 测定 测定 测定 测定 测定 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有 固有In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: I) from 70 to 100 mole percent of para-benzene a dicarboxylic acid residue; II) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and 119732.doc -33-200804457 ill) 0 to 10 mol% of aliphatic two a carboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 0 40 to 65 mol% of 2,2,4,4-tetramethyl<,3-cyclobutane An alcohol residue; and 11) 35 to 60 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total mole % of the carboxylic acid component is 1% mol%, and the total mole % of the diol component is 100 mol%; and wherein when it is in 60/40 (w/w) phenol/tetrachloroethane The intrinsic viscosity of the polyester is 〇58 to less than 1 com/g when measured at 25 ° C at a concentration of 25 g / 5 〇 ml; and wherein the polyester has 13 〇 to 145. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a slow acid component comprising: 1) from 70 to 100 mole percent A phthalic acid residue; 1 〇 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and in) 〇 to 10 mol. /. An aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: i) 40 to 65 mol% of 2,2,4,4-tetramethyl-1 a 3-cyclobutanediol residue; and 119732.doc-34 - 200804457 ii) 35 to 60 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one selected from the group consisting of at least one heat stabilizer a phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of a Wei® text wound is 1% molar %, and the total molar % of the diol component is 100% by mole; 60/40 (W/W) Hope/Four Ethylene Bake, the inherent viscosity of polyester is 〇·58 to 〇·75 g when measured at 25 ° C at a concentration of 25 g / 5 〇 ml / gram; and wherein the polyester has a stipulation of 13 〇 to 145 。. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 1 Torrole/ Terephthalic acid residues; η) 0 to 30 mol% of aromatic dicarboxylic acid residues having up to 2 carbon atoms; and in) 0 to 10 mol% of aliphatic dicarboxylic acid residues a base having up to 16 carbon atoms; and (b) a diol component comprising: from 4 4 to 65 mol% of 2,2,4,4-tetradecyl-1,3-cyclobutanediol And ii) 35 to 60 mol% of cyclohexanedimethanol residue; and (II) at least one chelating agent' selected from at least a species of scaly compound, a reaction product thereof, and a mixture thereof; The total molar % of the carboxylic acid component is η Λ Λ 〇 〇 / α ^ 芙 von 100 mol %, and the total molar % of the diol component is 100 mol %; and 119732.doc -35- 200804457 In 60/40 (w/w) phenol/tetra-ethane, the inherent viscosity of the polyester is 〇····················· 0.72 metric / gram; and wherein the polyester has a Tg of 13 〇 to i45 ° C . In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) from 70 to 100 mol% of para-benzene a dicarboxylic acid residue; η) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and in) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having a high 16 carbon atoms; and (b) a diol component comprising: I) 40 to 65 moles per mole of 2,2,4,4-tetramethylcyclobutanediol residues; and II) 35 to 60 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; and a total molar amount of the monocarboxylic acid component. /. Is i 〇〇 mol%, and the total molar % of the diol component is 100 mol%; and wherein when in 60/40 (w/w) phenol/tetra-ethane, 〇.25 g/5 At a concentration of 〇ml, the inherent viscosity of the polyester is 〇6 to 1 a mph/g when measured at 25 ° C, and the poly yttrium has a Tg of 13 〇 to i45 〇 c. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: 119732.doc -36 - 200804457 (a) a dicarboxylic acid component comprising: 1) 70 to 100 moles/0 terephthalic acid residue; η) 0 to 30 mole % of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ill) 0 to 10 moles. / an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: I) 40 to 65 mol% of 2,2,4,4-tetradecyl _ a 1,3_cyclobutanediol residue; and II) 35 to 60 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one structural compound, the reaction thereof a product and a mixture thereof; wherein the total mole % of a tickotropic wound is 1% molar %, and the total molar % of the diol component is 100% by mole; and wherein when at 60/40 (weight/weight) In phenol/tetrachloroethane, the intrinsic viscosity of the polyester is 〇·6 to less than 1 com/g when measured at 25 ° C at 25 ° C; and wherein the polyester It has 13〇 to l45<JCiTg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: Ο) a dicarboxylic acid component comprising: I) 70 to 100 mol% of p-benzoic acid Formic acid residue; II) an aromatic dicarboxylic acid residue of up to 30 mol%, having up to 2 carbon atoms; and in) up to 10 mol% of an aliphatic dicarboxylic acid residue, up to 16 119732.doc -37- 200804457 carbon atoms; and (b) diol component, including · 1) 40 to 65 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutene a diol residue; and 11) 35 to 60 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total mole % of the dicarboxylic acid component is 1% mol%, and the total mole % of the diol component is 100 moles. /. And wherein the inherent viscosity of the polyester is 〇 when measured at 25 ° C in 60/40 (w/w) phenol/tetrachloroethane at 〇25 g/5 〇ml/min. 6 to 〇·75 com/g; and wherein the polyester has 13 〇 to 145. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 Torrole /〇 terephthalic acid residue, u) 〇 to 3 〇% of the aromatic dicarboxylic acid residue, having up to 20 carbon atoms; and iii) () to 10 mol% of aliphatic two The carboxylic acid residue 'has a height of 16 carbon atoms; and (b) a diol component comprising: a diol 1) 40 to 65 mol% of 2,2,4,4-tetramethyl", 3 residues And ii) 35 to 60 mol% of cyclohexanedimethanol residue; and 119732.doc-38-200804457 (II) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and The mixture; wherein the total molar % of the monocarboxylic acid component is 100 mol%, and the total molar % of the diol component is 100 mol. /〇; and when in 60/40 (w/w) phenol/tetra-ethane, at a concentration of 25 g/5 〇 ml, the inherent viscosity of the polyester is 〇 at 25 ° C. _6 to 〇·72 com / gram; and wherein the polyester has 13 〇 to "substituted ^ ^. In one aspect" the invention relates to a polyester composition comprising: (I) at least one polyester, It comprises: (a) a dicarboxylic acid component comprising: i) 70 to 1 mole of fluorene/oxime terephthalic acid residue; ii) 0 to 30 mole % of aromatic dicarboxylic acid residue a base having up to 20 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 1) 1 to 99 2% 2,4,4,4-tetramethyl-1,3-cyclobutanediol residue; and ii) 1 to 99 mol% of cyclohexanedimethanol residue; and (II) at least A heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1% by mole, and the total mole % of the diol component is 100% Mohr./.; and where is at 60/40 (weight/weight In the phenol/tetra-ethane ethane, the intrinsic viscosity of the polyester is 0.35 to 1.2 com/g when measured at 25 ° C at a concentration of 25 g / 5 〇 119 732.doc • 39 · 200804457 liters; And wherein the polyg is intended to have a weight ratio of I?? to 2〇〇. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) two a carboxylic acid component comprising: i) 70 to 1 mole % terephthalic acid residue; 11) 0 to 30 mole % of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; And ill) 0 to 10 mol% of the aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 1) 1 to 80 mol% of 2, 2, 4 a 4-methyl-1,3-cyclobutanediol residue; and ii) 20 to 99 mole % of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of At least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the 竣 &L wound is 100% by mole, and the total molar % of the diol component is 100% by mole; In 60/40 (w/w) phenol/tetrachloroethane , at a concentration of 25 g / 5 〇 ml, when measured at 25 ° C, the inherent viscosity of the polyester is 〇 · 35 to 1.2 com / g; and the polyester has a Tg of 127 to 200 ° C In one aspect, the invention relates to a composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 119732.doc -40- 200804457 i) 70 to 100 mol% of terephthalic acid residues; η) 0 to 30 mol% of aromatic dicarboxylic acid residues having up to one carbon atom; and iii) 0 to 10 mol% of fat a dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 1) 1 to 99 mol% of 2,2,4,4-tetramethyl], 3•ring a butanediol residue; and ii) from 1 to 99 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof Wherein the total molar percentage of the dicarboxylic acid component is 100 mol%, and the total molar % of the diol component is 100 mol%; and wherein 60/40 (w/w) phenol/tetra-ethane In the concentration of 25 grams / 5 liters, When measured at 25 ° C, the inherent viscosity of the polyester is 〇.35 to 1.2 com / g; and wherein the polyester has a ≥ 148 to 2 〇 (rc)

Tg 〇 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) —竣酸成份，其包含： i) 70至100莫耳％之對苯二曱酸殘基； η) 0至30莫耳。/〇之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 〇至10莫耳％之脂族二羧酸殘基，具有至高16 119732.doc -41- 200804457 個碳原子；與 (b) 一'醇成份，其包含： 〇 4〇至65莫耳％之2,2,4,4_四甲基·1，3-環丁二醇 殘基；及 11) 35至60莫耳〇/0之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳。/。為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇 25克/5〇毫 升之/辰度下，在25 C下測定時，聚酯之固有黏度為〇 35至 1.2公合/克，且其中聚酯具有大於148至至高2〇〇它之^^。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： I) 70至1〇〇莫耳％之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 40至64.9莫耳％之2,2,4,4-四甲基·1，3-環丁二 醇殘基；及 ii) 35·1至60莫耳％之環己烷二甲醇殘基；及 119732.doc -42- 200804457 出)0.10至小於15莫耳％之改質用二醇，其係選 自至少-種下列二醇：乙二醇殘基、丙二 醇、丁二醇及其混合物；及 (II)至少一種熱穩定劑’其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二m酸成份之總莫耳％為⑽莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇·35至 1.2公合/克；其中聚酯具有8S至2〇(rc之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 0 70至100莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 〇至10莫耳％之脂族二竣酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含·· i) 4〇至65莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基；及 ii) 35至60莫耳〇/0之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 119732.doc •43· 200804457 其中二叛酸成份之總莫耳％為】 夭叩钩1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳。/。；且 其中田在60/40 (重篁/重量）紛/四氯乙烧中，於〇 25克/5〇 毫升之濃度下，在25°C下測定時，聚g旨之固有黏度為〇35 至1.2公合/克； 其中聚酯具有85至200°C之Tg，且 視需要地，其中在該聚合物聚合之前或在該聚合物聚合 期間加入一或多種分支劑。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) —竣酸成份，其包含： 0 70至1〇〇莫耳％之對苯二甲酸殘基； 11) 0至30莫耳％之芳族二羧酸殘基，具有至高Μ 個碳原子；及 ιιι)0至10莫耳％之脂族二羧酸殘基，具有至高U 個碳原子；與 (b) 二醇成份，其包含： i) 40至64.9莫耳％之2,2,4,4-四甲基-1，3_環丁一 醇殘基；及 Π) 35.1至60莫耳％之環己烷二甲醇殘基；及 iii) 0·10至小於15莫耳％之改質用二醇，其係選 自至少一種下列二醇：乙二醇殘基、内二 醇、丁二醇及其混合物；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 119732.doc •44· 200804457 其反應產物及其混合物； 其中一魏Ssl成伤之總莫耳％為1 〇 〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇.25克/5〇毫 升之/辰度下，在25 C下測定時，聚酯之固有黏度為〇 35至 0.75公合/克；其中聚酯具有11〇至“代之以。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含·· (a) -一叛酸成份，其包含： i) 70至1〇〇莫耳〇/〇之對苯二曱酸殘基； 11) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii)〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 40至65莫耳％之2,2,4,4·四甲基_1，3_環丁二醇 殘基；及 η) 35至60莫耳％之環己烷二甲醇殘基·，及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 “ 其中當在60/40 (重量/重量)酚/四氯乙烷中，於〇·25克/5〇毫 升之濃度下，在说下測定時，㈣之固有黏度為⑼至 119732.doc -45- 200804457 〇·75公合/克； 其中聚酯具有110至200 °C之Tg;且 視需要地，其中在該聚合物聚合之前或在該聚合物聚合期 間加入一或多種分支劑。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 0 70至1〇〇莫耳％之對苯二曱酸殘基； 11) 〇至30莫耳。/。之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) ^一酵成份，其包含： i) 1至99莫耳％之2,2,4,4-四甲基-1，3·環丁二醇 殘基；及 ii) 1至99莫耳〇/〇之環己烷二曱醇殘基；及 " (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇亳 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇_35至 1 · 2公合/克； 其中聚酯具有110至200°C之Tg。 119732.doc -46- 200804457 於一方面，本發明係關於一種聚酯組合物，其包含. (I)至少一種聚酯，其包含·· (a)二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； Π) 0至3〇莫耳％之芳族二叛酸殘基;具有至㈣ 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： 0 40至65莫耳％之2,2,4,心四甲基」，％環丁二醇 殘基；及 ii) 35至60莫耳％之環己烷二甲醇殘基；及 一種麟化合物 (II)至少一種熱穩定劑，其係選自至少 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之/辰度下，在25 C下測定時，聚酯之固有黏度為〇·35至 1.2公合/克； 其中聚酯具有110至200。(：之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 1) 70至1〇〇莫耳〇/〇之對苯二甲酸殘基； 119732.doc -47- 200804457 ii) 〇至30莫耳％之芳族二叛酸殘基，具有至高2〇 個碳原子；及 in) 〇至1〇莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： 0 40至64.9莫耳％之2,2,4,4-四甲基- i，3-環丁二 醇殘基；及 11) 35至59.9莫耳％之環己烷二甲醇殘基；及 iii) 0.10至小於15莫耳％之改質用二醇，其係選 自至少一種下列二醇：乙二醇殘基、丙二 醇、丁二醇及其混合物；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一叛S文成伤之總莫耳。/。為丨⑻莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇.25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇·35至 0.75公合/克，其中聚酯具有u〇至2〇〇。〇之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： Ο)二羧酸成份，其包含： 0 70至100莫耳〇/0之對苯二曱酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ㈣48· 119732.doc 200804457 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： i) 1至99莫耳〇/〇之2,2,4,4-四甲基-1，3·環丁二醇 殘基；及 η) 1至99莫耳0/〇之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一魏酸成份之總莫耳％為1 〇 〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之?辰度下，在25 C下測定時，聚酯之固有黏度為〇.35至 1.2公合/克； 其中聚酯具有110至200°C之Tg;且 視需要地，其中在該聚合物聚合之前或在該聚合物聚合期 間加入一或多種分支劑。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 1) 70至100莫耳％之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高 個碳原子；及 出)〇至U)莫耳％之脂族二叛酸殘基，具有至高“ 個碳原子；與 119732.doc •49- 200804457 (b) 二醇成份，其包含： i) 1至99莫耳％之2,2,4,4_四曱基-1，3-環丁二醇 殘基；及 ii) 1至99莫耳％之環己烷二曱醇殘基；及 (c) 至少一種分支劑；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為100莫耳。/()，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇 25克/5〇毫 升之濃度下’在25 °C下測定時，聚酯之固有黏度為〇·6至 〇·72公合/克；且其中聚酯具有11〇至2〇〇。〇之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 0 70至1〇〇莫耳〇/〇之對苯二甲酸殘基； U) 0至30莫耳％之芳族二緩酸殘基，具有至高2〇 個碳原子；及 in)0至Π)莫耳％之脂族二叛酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 大於40至99莫耳。/〇夕0 9 4 1 m ^ 天吁/〇之2,2,4,4-四曱基q，％環丁 二醇殘基；及 U) 1至小於6〇莫耳％之環己烧二甲醇殘基；及 119732.doc -50- 200804457 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二叛酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ •，且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇 25克/5〇毫 升之?辰度下，在25°C下測定時，聚酯之固有黏度為〇1〇至 1·2公合/克；其中聚g旨具有85至2〇〇。〇之Tg; 其中若乙二醇殘基存在於二醇成份中時，其於該聚酯中之 量係小於1 5莫耳〇/〇。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) —竣酸成份，其包含： i) 70至1〇〇莫耳〇/〇之對苯二甲酸殘基； 11) 0至30莫耳❶/。之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 〇 1〇至100莫耳〇/〇之2,2,4,4·四甲基_1，3-環丁二 醇殘基；及 Η)至高9〇莫耳％之環己烧二甲醇殘基，·及 ⑼至少-種熱穩定劑，其係選自至少一種鱗化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳0/為 吁。馮100莫耳％，且二醇成份之總 119732.doc -51 - 200804457 莫耳％為1 〇〇莫耳％。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) —竣酸成份，其包含： i) 70至100莫耳％之對苯二甲酸殘基； 11) 0至30莫耳。/。之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ui) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 25至10〇莫耳％之2,2,4,4-四甲基_1，3_環丁二 醇殘基；及 η)至咼75莫耳％之環己烷二甲醇殘基；及 (Π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳㈣⑽莫耳且其中該非晶形聚醋具有大於12代 之玻璃轉移溫度（Tg)。 於-方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 1) 70至1〇〇莫耳％之對苯二甲酸殘基； ϋ) 〇至30莫耳％之芳族二㈣殘基，具有至高2〇 個碳原子；及 119732.doc • 52 - 200804457 111) 〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： i) 1至99莫耳〇/〇之2,2,4,4_四甲基^，環丁二醇 殘基；及 11) 1至99莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種構化合物、 其反應產物及其混合物； 其中一叛S文成伤之總莫耳％為1 00莫耳％，且二醇成份之總 莫耳％為100莫耳。/〇 ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇1〇至 小於1公合/克；且其中聚酯具有85至125。〇之丁8。 於一方面’本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) —*竣酸成份，其包含： 1) 70至1〇〇莫耳％之對苯二曱酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) —*醉成份’其包含： 1) 1至99莫耳％之2,2,4,4_四曱基-1，3-環丁二醇 殘基；及 119732.doc -53 - 200804457 11) 1至99莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 u 其中當在60/40 (重量/重量）紛/四氣乙烧中，於0 25克/5〇毫 升之漢度下’在25°C下測定時’聚g旨之固有黏度為〇1〇至 小於1公合/克；且其中聚酯具有85至12〇。(：之1^。 於一方面，本發明係關於—種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： Ο)二羧酸成份，其包含： I) 70至100莫耳％之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： I) 1至99莫耳％之2,2,4,4_四甲基-1，3-環丁二醇 殘基；及 II) 1至99莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ •，且 119732.doc -54- 200804457 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25 C下測定時，聚酯之固有黏度為〇 35至 1.2公合/克；且其中聚酯具有以至^代之以。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 1) 70至1〇〇莫耳％之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 1至99莫耳％之2,2,4,4_四甲基-1，3_環丁二醇 殘基；及 ii) 1至99莫耳％之環己烧二甲醇殘基；及 (Π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一竣酸成伤之總莫耳％為10 0莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇·5至 1·2公合/克；且其中聚酯具有85至12〇它之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含·· (I)至少一種聚酯，其包含·· 119732.doc -55- 200804457 (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； 11) 0至30莫耳。/。之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ιιι)0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： I) 1至99莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基；及 II) 1至99莫耳〇/〇之環己烷二甲醇殘基；及 (Π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳❶/。為i 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳。/。；且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之?辰度下，在25。(：下測定時，聚酯之固有黏度為〇.35至 1.2公合/克；且其中聚酯具有以至^代之“。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)—緩酸成份’其包含： 1) 70至1〇〇莫耳％之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳％之脂族二羧酸殘基，具有至高16 119732.doc -56- 200804457 個碳原子；與 (b)二醇成份，其包含： 1) 1至99莫耳0/〇之2,2,4,4·四甲基-^―環丁二醇 殘基；及 ⑴1至"莫耳％之環己烧二甲醇殘基；及 (II)至少-種熱穩㈣，丨係選自至少—種填化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％;且 其中當在6G/4G (重量/重量贿/四氯乙燒中，於025克/5〇毫 升之浪度下，在25 C下測定時，聚酯之固有黏度為〇35至 1.2公合/克；且其中聚酯具有95sU5C)C2Tg。 於一方面，本發明係關於一種聚酯組合物，其包含·· (I)至少一種聚酯，其包含： (a) ^一叛酸成份，其包含： 1) 70至100莫耳〇/0之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ιιι)〇至10莫耳。/。之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 1至99莫耳％之2,2,4,4-四曱基-1，3_環丁二醇 殘基；及 η) 1至99莫耳％之環己烷二甲醇殘基；及 119732.doc -57- 200804457 (π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇 25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇.35至 小於1公合/克；且其中聚酯具有95至115。^之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含·· (I)至少一種聚酯，其包含： (a) 二竣酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； 11) 0至30莫耳。/。之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 5至小於50莫耳％之2,2,4,4-四甲基_1,3-環丁 二醇殘基；及 η)大於50至95莫耳〇/0之環己烷二曱醇殘基；及 (Π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重置/重量）酚/四氣乙烷中，於〇25克/5〇毫 119732.doc -58- 200804457 升之濃度下，在25t下敎時，聚醋之固有黏度為〇 %至 1·2公合/克，·且 · 其中聚酯具有85至125°C之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 1) 70至100莫耳〇/0之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 5至小於5〇莫耳％之2,2,4,4-四甲基- i，3_環丁 二醇殘基；及 Π)大於50至95莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一魏酸成份之總莫耳％為1 0 〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇 25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇.5〇至 1·2公合/克；且 其中聚酯具有85至120°C之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： 119732.doc -59- 200804457 (I) 至少一種聚酯，其包含： (a) 二缓酸成份，其包含： I) 70至1〇〇莫耳％之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 III) 0至10莫耳❻/。之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 10至30莫耳0/〇之2,2,4,4_四甲基-1，3_環丁二醇 殘基；及 η) 70至90莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一叛酸成份之總莫耳％為1 〇〇莫耳。/❶，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之丨辰度下’在2 5 C下測定時，聚醋之固有黏度為〇 · 5 〇至 1.2公合/克；且 其中聚醋具有85至120°C之Tg。於一具體實施例中，該聚 酯之Tg係100至120°C。 於一方面’本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： Ο)二竣酸成份，其包含： i) 70至100莫耳％之對苯二甲酸殘基； 119732.doc •60- 200804457 11) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： I) 15至25莫耳％之2,2,4,4-四甲基-i，3-環丁二醇 殘基；及 II) 75至85莫耳％之環己烷二曱醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳❹/。為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇·5〇至 1_2公合/克；且其中聚酯具有85至12〇〇c之以。於一具體實 施例中，該聚酯之Tg係1〇〇至i2〇°c。 於一方面’本發明係關於一種聚酯組合物，其包含： (I)至少一種聚g旨，其包含： (a)二羧酸成份，其包含： i) 70至1〇〇莫耳〇/0之對苯二甲酸殘基； π) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 119732.doc • 61 - 200804457 (b)二醇成份，其包含： i) 15至25莫耳％之2,2,4,4-四甲基_1，3_環丁二醇 殘基；及 11) 75至85莫耳％之環己烧二甲醇殘基；及 (Π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一羧酸成伤之總莫耳％為1 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇.5〇至 0.8公合/克；且其中聚酯具有以至12〇〇c之以。於一具體實 施例中，該聚酯之Tg係1〇〇至i2(rc。 於一方面’本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳〇/0之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii)〇至10莫耳。/。之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 15至25莫耳％之2,2,4,4-四甲基_1，3_環丁二醇 殘基；及 ii) 75至85莫耳％之環己烷二甲醇殘基；及 119732.doc •62- 200804457 (ιι)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳。/〇 ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇·5〇至 ❹^公合/克：且其中聚酯具有“至^代之丁^於一具體 實施例中，該聚酯之Tg係1〇〇至120。〇。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二竣酸成份，其包含： 1) 70至100莫耳％之對苯二甲酸殘基； ii) 0至30莫耳❹/。之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 1至99莫耳0/〇之2,2,4,4_四甲基-1，3-環丁二醇 殘基；及 ιι) 1至99莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 119732.doc -63 - 200804457 其中當在60/40 (重量/重量）酚/四氯乙烧中，㈣·25克/5〇毫 升之濃度下’在25°C下測定時，聚醋之固有黏度為〇35至 1·2公合/克；且其中聚酯具有1〇〇至12〇它之4。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二竣酸成份，其包含： 1) 70至1〇〇莫耳％之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) b至25莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基；及 ii) 75至85莫耳〇/〇之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二叛酸成份之總莫耳％為1 00莫耳。/。，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）紛/四氣乙院中，於〇_25克/50毫 升之濃度下’在2 5 °C下測定時，聚酯之固有黏度為0 · 5 0至 1.2公合/克；且其中聚酯具有1〇〇至i2〇°c之Tg。於一具體 實施例中，該聚酯之Tg係100至120°C。 於一方面，本發明係關於一種聚酯組合物，其包含： 119732.doc -64- 200804457 (i)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： I) 70至1〇〇莫耳〇/〇之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二竣酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： I) 5至小於50莫耳％之2,2,4,4-四甲基-i，3-環丁 一酵殘基；及 II) 大於50至95莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳。/。；且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇·5〇至 1_2公合/克；且其中聚酯具有”至^代之丁㊁。 於方面’本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) —幾酸成份，其包含： Ο 70至100莫耳％之對苯二曱酸殘基； i〇 〇至30莫耳％之芳族二竣酸殘基，具有至高2〇 個碳原子；及 119732.doc -65- 200804457 ill) 〇至10莫耳。/。之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： 1) 10至30莫耳0/〇之2,2,4,4·四甲基-1，3·環丁二醇 殘基；及 ii) 70至90莫耳％之環己烷二曱醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一緩自文成伤之總莫耳％為1 〇 〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇.5〇至 1.2公合/克；且其中聚酯具有95至115。〇之Tg。 於一方面’本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含·· (a) 二羧酸成份，其包含： i) 70至100莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ιιι)0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 15至25莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基；及 119732.doc •66- 200804457 ii) 75至85莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一缓酸成份之總莫耳％為1 〇 〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇·5〇至 1·2公合/克；且其中聚g旨具有95至115。〇之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚g旨，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳。/〇之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 5至小於50莫耳％之2,2,4,4·四甲基-1，3-環丁 二醇殘基；及 ii)大於50至95莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 119732.doc -67- 200804457 其中當在60/40 (重量/重量）酚/四氣乙燒中，於〇25克/5〇毫 升之濃度下’在25。(；下測定時’聚醋之固有黏度為〇5〇至 0·75公合/克；且其中聚酯具有85至125。〇之丁@。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基， 高2〇 個碳原子；及 111) 〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 β (b) 二醇成份，其包含： 1) 5至小於50莫耳％之2,2,4,4-四甲基-1，3·環丁 二醇殘基；及 π)大於50至95莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二酵成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇·5〇至 0.75公合/克；且其中聚酯具有85至12〇。〇之丁8。 於一方面，本發明係關於一種聚酯组合物，其包含： (I)至少一種聚酯，其包含： 119732.doc -68- 200804457 (a) 二羧酸成份，其包含： 1) 70至1〇〇莫耳％之對苯二曱酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 5至小於50莫耳。/〇之2,2,4,4-四甲基-1，3·環丁 二醇殘基；及 ii)大於50至95莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1 〇〇莫耳。/()，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之浪度下’在25 C下測定時，聚酯之固有黏度為〇 6〇至 0.75公合/克；且其中聚酯具有85至12〇1之Tg。 於一方面’本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 0 70至1〇〇莫耳％之對苯二甲酸殘基； η) 0至30莫耳。/。之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii)〇至10莫耳％之脂族二羧酸殘基，具有至高16 119732.doc -69- 200804457 個碳原子；與 (b) 一醇成份，其包含： I) 5至小於50莫耳％之2,2,4,4-四甲基-環丁 二醇殘基；及 η)大於50至95莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇 25克/5〇毫 升之/辰度下，在25 C下測定時，聚酯之固有黏度為〇 65至 0.75公合/克；且其中聚酯具有^至^代之以。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) ^一叛酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 5至小於50莫耳％之2,2,4,4_四甲基—L3環丁 一醇殘基；及 ii) 大於50至95莫耳％之環己烷二甲醇殘基；及 119732.doc -70- 200804457 (II)至少一種熱穩定劑’其係選自至少一種鱗化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）紛/四氯乙燒中，於〇25克/5〇毫 升之浪度下，在25 C下測定時，聚酿之固有黏度為〇.68至 〇·78公合/克；且其中聚酯具有以至^吖之^。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； 11) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個破原子；及 ιιι)0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 10至30莫耳％之2,2,4,4 -四甲基·ι，3_環丁二醇 殘基；及 ii) 70至90莫耳％之環己院二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種鱗化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在6_ (重量/重量）紛/四氣乙燒中，於〇·25克/5〇毫 119732.doc -71- 200804457 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇 5至 〇·8公合/克；且 其中聚酯具有85至12(TC之Tg。於一具體實施例中，該 聚酯之Tg係100至120°C。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) —緩酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； Π) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii)o至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) — 成份，其包含： 0 10至30莫耳％之2,2,4,4_四甲基·1，3_環丁二醇 殘基；及 Π) 70至90莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳。/。；且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇 25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇6至 〇·8公合/克；且 其中聚酯具有85至120°C之Tg。於一具體實施例中，該聚 119732.doc •72- 200804457 酯之Tg係100至120°C。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二魏酸成份，其包含·· I) 70至1〇〇莫耳％之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 10至30莫耳％之2,2,4,4-四曱基_1，3-環丁二醇 殘基；及 Π) 70至90莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳。/〇 ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於0.25克/50毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為0.50至 0.75公合/克；且其中聚酯具有85至120°C之Tg。於一具體 實施例中，該聚酯之Tg係100至120°C。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 119732.doc -73- 200804457 1) 70至100莫耳〇/〇之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ιιι)〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： 1) 15至25莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基；及 η) 75至85莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之》辰度下’在25 C下測定時，聚酯之固有黏度為〇 5〇至 0.75公合/克；且其中聚酯具有85至12〇。〇之Tg。於一具體 實施例中’該聚酯之Tg係1〇〇至120°C。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 1) 70至100莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ιιι)〇至10莫耳％之脂族二羧酸殘基，具有至高16 119732.doc -74 200804457 個碳原子；與 (b)二醇成份，其包含： i) 17至28莫耳％之2,2,4,4-四曱基_1，3_環丁二醇 殘基；及 ii) 72至83莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳。/。為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5()毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇.65至 〇·75公合/克；且其中聚酯具有85至12〇c>c之^^。於一具體 實施例中，該聚酯之Tg係1〇0至120。(：。 於—方面’本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： U)二羧酸成份，其包含： Ο 70至1〇〇莫耳％之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： 1) 17至28莫耳％之2,2,4,4·四甲基_1，3_環丁二醇 殘基；及 119732.doc -75· 200804457 ii) 72至83莫耳％之環己烷二曱醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一魏成伤之總莫耳％為1⑽莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇.65至 0.75公合/克；且其中聚酯具有1〇〇至12〇〇c之Tg。於一具體 實施例中，該聚酯之Tg係1〇〇至120。(：。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 1) 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 17至28莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基；及 ii) 72至83莫耳〇/〇之環己烷二甲醇殘基；及 (II) 至少一種熱穩疋劑，其係選自至少一種填化合物、 其反應產物及其混合物； 其中一魏酸成份之總莫耳％為1 〇 〇莫耳％，且二醇成份之總 119732.doc -76- 200804457 莫耳％為100莫耳。/。；且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇 25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇·7至 〇·8公合/克；且其中聚酯具有85至12〇〇c之“。於一具體實 施例中，該聚酯之Tg係1〇〇至i2(rc。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； 11) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 17至28莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基；及 ii) 72至83莫耳％之環己烷二甲醇殘基；及 (Π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1 〇〇莫耳。/。，且二醇成份之總 莫耳。/〇為100莫耳。/〇 ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇,25克/5〇毫 升之濃度下’在25 °C下測定時，聚酯之固有黏度為0.7至 0·8公合/克；且其中聚酯具有ι〇〇至i2〇〇c之Tg。於一具體 H9732.doc •77· 200804457 實施例中，該聚酯之Tg係1〇〇至12〇。(：。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： I) 70至1〇〇莫耳％之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 III) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 17至28莫耳％之2,2,4,4-四甲基_1，3-環丁二醇 殘基；及 η) 72至83莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳。/。為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之/辰度下，在25 C下測定時，聚酯之固有黏度為〇.65至 0.75公合/克，且其中聚醋具有1〇〇至us。。之Tg。於一具體 實施例中，該聚酯之Tg係1〇〇至12〇。〇。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 119732.doc -78 - 200804457 I) 70至100莫耳％之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 III) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) ^一醉成份’其包含： I) 5至小於50莫耳％之2,2,4,仁四曱基-丨，％環丁 二醇殘基；及 II) 大於50至95莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳。/〇 ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇 25克/5〇毫 升之濃度下，在25。(：下測定時，聚醋之固有黏度為〇.5〇至 〇·75公合/克；且其中聚酯具有％至^代之以。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 1) 70至1〇〇莫耳〇/0之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高 個碳原子；及 ιιι)〇至10莫耳％之脂族二羧酸殘基，具有至高Μ 個碳原子；與 119732.doc •79- 200804457 (b)二醇成份，其包含： 0 10至30莫耳％之2,2,4,4_四甲基-1，3-環丁二醇 殘基；及 11) 70至90莫耳％之環己烷二甲醇殘基；及 (Π)至y種熱穩定劑，其係選自至少一種鱗化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳。/。為i〇〇莫耳％，且二醇成份之總 莫耳。/〇為1 〇 〇莫耳％ ;且 其中田在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇·5〇至 0_75公合/克；且其中聚酯具有95至115。〇之以。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) —魏酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； Π) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) —醇成份’其包含： i) 15至25莫耳％之2,254,4_四甲基-1，3_環丁二醇 殘基；及 11) 75至85莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 119732.doc 200804457 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中备在60/40 (重量/重量）酚/四氣乙烧中，於〇25克/5〇毫 升之浪度下，在25 C下測定時，聚酯之固有黏度為〇·5〇至 0·75公合/克；且其中聚酯具有95至115。〇之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) *一竣酸成份’其包含： I) 70至1〇〇莫耳％之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ιιι)0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 15至25莫耳％之2,2,4,4-四曱基-1，3-環丁二醇 殘基；及 η) 75至85莫耳％之環己烷二甲醇殘基；及 (Π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳❶/❶為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重篁/重量）酚/四氣乙烷中，於〇25克/5〇毫 升之濃度下，在25。(：下測定時，聚醋之固有黏度為〇·6至 119732.doc -81 - 200804457 0·72公合/克；且其中聚酯具有95至115。〇之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含·· (I) 至少一種聚g旨，其包含： (a) 二羧酸成份，其包含： i) 70至100莫耳％之對苯二曱酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二致酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 〇·〇1至小於5莫耳％之2,2,4,4-四甲基- ΐ，3·環 丁二醇殘基； ii) 乙二醇殘基；及 iii) 視需要之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一竣酸成份之總莫耳％為1 〇 〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）紛/四氣乙烷中，於〇25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為0.35至 1·2公合/克；且其中聚酯具有60至11〇。〇之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 119732.doc -82- 200804457 i) 70至1〇〇莫耳％之對苯二甲酸殘基； II) 〇至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 III) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： 1) 0·01 至 4.5莫耳％之 2,2,4,4-四甲基-1，3-環丁二 醇殘基； ii) 乙二醇殘基；及 111)視需要之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於0.25克/50毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇.35至 1.2公合/克；且其中聚酯具有6〇至11〇。〇之丁§。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚g旨，其包含： U)二羧酸成份，其包含： i) 70至1〇〇莫耳〇/0之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 119732.doc -83 - 200804457 個碳原子；與 (b)二醇成份，其包含·· i) 0·01至4莫耳％之2,2,4,4-四甲基-1，3-環丁二 醇殘基； ii) 乙二醇殘基；及 111)視需要之環己烧二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一竣酸成份之總莫耳％為1 〇 〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下’在25°C下測定時，聚酯之固有黏度為〇·35至 1.2公合/克；且其中聚酯具有6〇至11〇。〇之4。 於一方面’本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： U)二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； η) 0至30莫耳。/〇之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 〇至ίο莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： Ο 〇·〇1至3莫耳％之2,2,4,4-四甲基-1，3-環丁二 醇殘基； 119732.doc -84 - 200804457 ii) 乙二醇殘基；及 iii) 環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一魏成伤之總莫耳％為1⑽莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇.25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇·35至 1.2公合/克；且其中聚g旨具有6(^u〇〇C2Tg。 於一方面’本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳。/〇之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 〇·〇1 至 2.0莫耳％ 之 2,2,4,4-四曱基 _1，3_ 環丁二 醇殘基； ii) 乙二醇殘基；及 iii) 視需要之環己烧二曱醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 119732.doc -85- 200804457 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇 25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇 35至 1.2公合/克；且其中聚酯具有6〇至11〇。〇之1^。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 1) 70至100莫耳％之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： Ο 0·01至1莫耳0/〇之2,2,4,4_四甲基-1，3-環丁二 醇殘基； ii) 乙二醇殘基；及 iii) 環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳❹/。為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇.35至 119732.doc -86- 200804457 1.2公合/克；且其中聚酯具有6〇至11〇艺之4。 於方面本發明係關於一種聚酯組合物，其包含·· (I) 至少一種聚酯，其包含·· (a) —羧酸成份，其包含·· 1) 70至100莫耳％之對苯二甲酸殘基，· η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 111) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) —醇成份，其包含： i) 0·01至小於1莫耳％之2,2,4,4-四甲基-i，3_環 丁二醇殘基； ii) 乙二醇殘基；及 iii) 環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一竣酸成份之總莫耳％為10 0莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇·35至 1.2公合/克；且其中聚酯具有60至ii(TC之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含·· (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 119732.doc -87- 200804457 I) 70至100莫耳％之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 III) 0至10莫耳。/。之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： 1) 〇·〇1至15莫耳％之2,2,4,4_四甲基十3，丁二 醇殘基； ii) 乙二醇殘基；及 iii) 環己烷二甲醇殘基；及 (II)至；一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇.35至 1·2公合/克；且其中聚g旨具有 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： i) 70至100莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二緩酸殘基，具有至高2〇 個碳原子；及 in) 〇至10莫耳％之脂族二羧酸殘基，具有至高16 119732.doc •88- 200804457 個碳原子；與 (b)二醇成份，其包含： i) 0.01至15莫耳％之2,2,4,4-四甲基·ι，3-環丁二 醇殘基； ii) 70至99.98莫耳％之乙二醇殘基；及 iii) 〇·〇1至15莫耳％之環己烷二甲醇殘基；及 (Π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一羰酸成伤之總莫耳％為1 〇 0莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為0·35至 1.2公合/克；且其中聚酯具有6〇至11〇1之丁§。 於一方面’本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) -一緩酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ιιι)〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： Ο 0·01 至 1〇 莫耳 0/〇之 2,2,4,4-四甲基 _1，3-環丁二 醇殘基； 119732.doc -89 - 200804457 ii) 乙二醇殘基；及 iii) 環己烷二甲醇殘基；及 (Π)至y 種熱知疋劑，其係選自至少一種構化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之ί辰度下，在25 C下測定時，聚酯之固有黏度為〇·35至 1_2公合/克，且其中聚酯具有6〇至ii〇c>c之丁呂。 於一方面，本發明係關於一種聚酯組合物，其包含·· (I) 至少一種聚酯，其包含： (a) 二致酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) o至1〇莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 〇·〇1至10莫耳％之2,2,4,4-四甲基_1，3_環丁二 醇殘基； ii) 80至99.98莫耳％之乙二醇殘基；及 iii) 0.01至10莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 119732.doc -90- 200804457 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇 25克/5〇毫 升之/辰度下，在25 C下測定時，聚酯之固有黏度為〇.35至 1.2公合/克；且其中聚酯具有6〇至11〇。〇之4。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： 0)二羧酸成份，其包含： I) 70至1〇〇莫耳％之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)-一醉成份’其包含：Tg In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a phthalic acid component comprising: i) 70 to 100 mole percent Terephthalic acid residue; η) 0 to 30 moles. / an aromatic dicarboxylic acid residue having a height of 2 〇 carbon atoms; and in) 〇 to 10 mol % of an aliphatic dicarboxylic acid residue having a maximum of 16 119,732. Doc -41- 200804457 carbon atoms; and (b) an 'alcohol component, which comprises: 〇4〇 to 65 mol% of 2,2,4,4_tetramethyl·1,3-cyclobutanediol a residue; and 11) a cyclohexane dimethanol residue of 35 to 60 moles/0; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total mole of monocarboxylic acid component. /. Is 1% mol%, and the total molar % of the diol component is 100 mol%; and wherein when 60/40 (w/w) phenol/tetrachloroethane, 〇25 g/5〇 At ML/min, the inherent viscosity of polyester is 〇35 to 1. 2 com / gram, and wherein the polyester has a mass greater than 148 to a height of 2 〇〇. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: I) 70 to 1 mole % Terephthalic acid residue; II) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue, Having a maximum of 16 carbon atoms; and (b) a diol component comprising: 1) 40 to 64. 9 mol% of a 2,2,4,4-tetramethyl·1,3-cyclobutanediol residue; and ii) 35·1 to 60 mol% of a cyclohexanedimethanol residue; and 119732 . Doc -42- 200804457 out)0. 10 to less than 15 mol% of a reforming diol selected from at least one of the following diols: ethylene glycol residues, propylene glycol, butylene glycol, and mixtures thereof; and (II) at least one heat stabilizer' It is selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the di-m acid component is (10) mol%, and the total molar % of the diol component is 100 mol%; In 60/40 (w/w) phenol/tetra-ethane, the inherent viscosity of the polyester is 〇35 to 1. when measured at 25 ° C at a concentration of 25 g / 5 〇 ml. 2 com/g; wherein the polyester has a Tg of 8S to 2 〇 (rc). In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 0 70 to 100 mol% of a terephthalic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii An aliphatic diteric acid residue of up to 10 mol% having a maximum of 16 carbon atoms; and (b) a diol component containing ·· i) 4 〇 to 65 mol% of 2, 2, 4 , 4-tetramethyl-1,3-cyclobutanediol residue; and ii) 35 to 60 moles/0 of cyclohexanedimethanol residue; and (II) at least one heat stabilizer, Selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; 119732. Doc •43· 200804457 The total mole % of the two components of the tickic acid is 〇〇%〇〇%, and the total molar % of the diol component is 100 moles. /. And the field is in the 60/40 (heavy weight / weight) / tetrachloroethane, at a concentration of 25 g / 5 〇 ml, measured at 25 ° C, the inherent viscosity of the poly g is 〇 35 to 1. 2 com/g; wherein the polyester has a Tg of from 85 to 200 ° C, and optionally one or more branching agents are added prior to polymerization of the polymer or during polymerization of the polymer. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a phthalic acid component comprising: 0 to 70% of a mole percent a phthalic acid residue; 11) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to Μ carbon atoms; and ιιι) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having a high U carbon atoms; and (b) diol components, which comprise: i) 40 to 64. 9 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanol residues; and Π) 35. 1 to 60 mol% of a cyclohexanedimethanol residue; and iii) from 0. 10 to less than 15 mol% of a reforming diol selected from at least one of the following diols: an ethylene glycol residue, Inner diol, butylene glycol, and mixtures thereof; and (II) at least one heat stabilizer selected from at least one phosphorus compound, 119,732. Doc •44· 200804457 The reaction product and mixture thereof; wherein the total molar % of a Wei Ssl wound is 1% molar %, and the total molar % of the diol component is 100% by mole; 60/40 (w/w) phenol/tetra-ethane, in 〇. At 25 g/5 〇m/min, the inherent viscosity of the polyester is 〇35 to 0 when measured at 25 C. 75 com/g; wherein the polyester has 11 〇 to "instead of. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising (a) - a repulsive acid component comprising: i) 70 to 1 mole of fluorene/oxime terephthalic acid residue; 11) 0 to 30 mole % of aromatic dicarboxylic acid residue, up to 2 One carbon atom; and iii) up to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 1) 40 to 65 mol% 2,2,4,4·tetramethyl-1,3_cyclobutanediol residue; and η) 35 to 60 mol% of cyclohexanedimethanol residue·, and (II) at least one heat stable The agent is selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total molar % of the dicarboxylic acid component is 1% mol%, and the total molar % of the diol component is 100 mol% And "wherein in 60/40 (w/w) phenol / tetrachloroethane, at a concentration of 〇 · 25 g / 5 〇 ml, when measured, the inherent viscosity of (d) is (9) to 119732. Doc -45- 200804457 〇·75 com/g; wherein the polyester has a Tg of from 110 to 200 ° C; and optionally, one or more branching agents are added prior to polymerization of the polymer or during polymerization of the polymer . In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 0 to 70% of a mole percent Benzoyl citrate residue; 11) 〇 to 30 moles. /. An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ill) up to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a yeast component Containing: i) 1 to 99 mole % of 2,2,4,4-tetramethyl-1,3·cyclobutanediol residues; and ii) 1 to 99 moles per mole of ring An alkane diol residue; and " (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1 〇〇 % by ear, and the total molar % of the diol component is 100% by mole; and wherein when in 60/40 (w/w) phenol/tetra-ethane, at a concentration of 克25 g/5 liter When measured at 25 ° C, the inherent viscosity of the polyester is 〇 _ 35 to 1 · 2 com / gram; wherein the polyester has a Tg of 110 to 200 ° C. 119732. Doc-46-200804457 In one aspect, the invention relates to a polyester composition comprising.  (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 mole % terephthalic acid residue; Π) 0 to 3 mole % An aromatic dibasic acid residue; having up to (four) carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component Including: 0 40 to 65 mol% of 2, 2, 4, tetramethyltetramine, % cyclobutanediol residues; and ii) 35 to 60 mol% of cyclohexane dimethanol residue; The compound (II) is at least one heat stabilizer selected from at least the reaction product thereof and a mixture thereof; wherein the total molar % of the dicarboxylic acid component is 100 mol%, and the total molar % of the diol component is 100 Molar%; and wherein the inherent viscosity of the polyester is measured at 25 C in 60/40 (w/w) phenol/tetrachloroethane at 〇25 g/5〇ml/min. For 〇·35 to 1. 2 com / g; wherein the polyester has 110 to 200. (Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 1 〇 〇 〇 〇 / 〇 terephthalic acid residues; 119,732. Doc -47- 200804457 ii) an aromatic dibasic acid residue of up to 30 mol%, having up to 2 carbon atoms; and in) 〇 to 1 mol% of an aliphatic dicarboxylic acid residue, Up to 16 carbon atoms; and (b) diol component, which comprises: 0 40 to 64. 9 mol% of 2,2,4,4-tetramethyl-i,3-cyclobutanediol residues; and 11) 35 to 59. 9 mol% of cyclohexane dimethanol residue; and iii) 0. 10 to less than 15 mol% of a reforming diol selected from at least one of the following diols: ethylene glycol residues, propylene glycol, butylene glycol, and mixtures thereof; and (II) at least one heat stabilizer, It is selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; /. It is 丨(8) mol%, and the total molar % of the diol component is 100 mol%; and wherein when it is in 60/40 (w/w) phenol/tetra-ethane, it is in 〇. At a concentration of 25 g / 5 Torr, the inherent viscosity of the polyester is 〇 35 to 0 when measured at 25 ° C. 75 com / g, of which polyester has u 〇 to 2 〇〇. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: Ο) a dicarboxylic acid component comprising: 0 70 to 100 moles / 0 of para-benzene Diterpenic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and (iv) 48·119732. Doc 200804457 iii) 0 to 10 mol% of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) diol component comprising: i) 1 to 99 moles/〇2, 2,4,4-tetramethyl-1,3.cyclobutanediol residue; and η) 1 to 99 moles of 0/〇 cyclohexanedimethanol residue; and (II) at least one heat stabilizer , the system is selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the one of the ferulic acid component is 1% by mole, and the total mole % of the diol component is 100% by mole; And when it is measured at 25 C in 60/40 (w/w) phenol/tetrachloroethane at ?25 g/5 〇 ml, the inherent viscosity of the polyester is 〇. 35 to 1. 2 com/g; wherein the polyester has a Tg of from 110 to 200 ° C; and optionally, one or more branching agents are added prior to polymerization of the polymer or during polymerization of the polymer. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) from 70 to 100 mole percent of para-benzene a dicarboxylic acid residue; η) 0 to 30 mol% of an aromatic dicarboxylic acid residue having a highest carbon atom; and a bismuth to U) mol% of an aliphatic di-retensive acid residue having a supple " One carbon atom; with 119732. Doc •49- 200804457 (b) a diol component comprising: i) from 1 to 99 mol% of 2,2,4,4-tetradecyl-1,3-cyclobutanediol residues; and ii) 1 to 99 mol% of a cyclohexanedimethanol residue; and (c) at least one branching agent; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof The total molar % of the dicarboxylic acid component is 100 moles. / (), and the total molar % of the diol component is 100 mol %; and wherein when in 60 / 40 (w/w) phenol / tetrachloroethane, at a concentration of 克 25 g / 5 〇 ml 'The inherent viscosity of the polyester when measured at 25 ° C is 〇·6 to 72·72 com/g; and the polyester has 11 〇 to 2 〇〇. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 0 70 to 1 Torrole/〇 Terephthalic acid residue; U) 0 to 30 mol% of aromatic di-acidic acid residue having up to 2 carbon atoms; and in) 0 to Π) mol% of aliphatic dibenzoic acid residues a group having up to 16 carbon atoms; and (b) a diol component comprising: i) greater than 40 to 99 moles. /〇夕0 9 4 1 m ^ 2,2,4,4-tetradecyl q,% cyclobutanediol residue of Tianyu/〇; and U) 1 to less than 6〇% of the ring Dimethanol residue; and 119,732. Doc-50-200804457 (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the two tickic acid components is 1% mol%, and The total molar % of the alcohol component is 100 mol% • and wherein, in 60/40 (w/w) phenol/tetrachloroethane, at 25 g / 5 ml, at 25 When measured at ° C, the intrinsic viscosity of the polyester is from 1 Torr to 1.2 cm / gram; wherein the poly g is intended to have 85 to 2 Torr. Tg; wherein if the ethylene glycol residue is present in the diol component, it is less than 15 moles per gram in the polyester. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a phthalic acid component comprising: i) 70 to 1 Torrole/ Terephthalic acid residues; 11) 0 to 30 moles /. An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ill 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component, It comprises: 〇1〇 to 100 moles/〇 of 2,2,4,4·tetramethyl-1,3-cyclobutanediol residues; and Η) up to 9〇% by mole of cyclohexane a dimethanol residue, and (9) at least one heat stabilizer selected from the group consisting of at least one scale compound, a reaction product thereof, and a mixture thereof; wherein the total mole of the dicarboxylic acid component is 0. Von 100 mole %, and the total amount of diol components 119,732. Doc -51 - 200804457 The % of Moer is 1% Mo. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a phthalic acid component comprising: i) from 70 to 100 mole percent of para-benzene Dicarboxylic acid residue; 11) 0 to 30 moles. /. An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ui) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component, It comprises: 1) 25 to 10 mole % of 2,2,4,4-tetramethyl-1,3_cyclobutanediol residue; and η) to 咼75 mol% of cyclohexane a methanol residue; and (Π) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 100% by mole, and the diol component The total mole (4) (10) Mo and wherein the amorphous polyester has a glass transition temperature (Tg) greater than 12 generations. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 1 mole % Terephthalic acid residue; ϋ) 〇 to 30 mol% of the aromatic di(tetra) residue having up to 2 carbon atoms; and 119,732. Doc • 52 - 200804457 111) 〇 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: i) 1 to 99 moles per mole 2,2,4,4_tetramethyl^, cyclobutanediol residue; and 11) 1 to 99 mol% of cyclohexanedimethanol residue; and (II) at least one heat stabilizer, It is selected from at least one structural compound, its reaction product, and a mixture thereof; wherein the total mole % of a rebellious wound is 100% by mole, and the total molar % of the diol component is 100 moles. /〇; and which is in 60/40 (w/w) phenol/tetrachloroethane, in 〇. The polyester has an intrinsic viscosity of from 1 Torr to less than 1 metric gram per gram of the coating at 25 ° C at a concentration of 25 g / 5 Torr; and wherein the polyester has 85 to 125. Ding Zhiding 8. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) - a phthalic acid component comprising: 1) 70 to 1 Torr % a terephthalic acid residue; η) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ill) 0 to 10 mol% of an aliphatic dicarboxylic acid residue a base having a maximum of 16 carbon atoms; and (b) a * drunk component comprising: 1) 1 to 99 mole % of 2,2,4,4_tetradecyl-1,3-cyclobutanediol Residue; and 119,732. Doc-53 - 200804457 11) 1 to 99 mol% of cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total molar % of the carboxylic acid component is 1% mol%, and the total molar % of the diol component is 100 mol%; and u wherein it is 60/40 (w/w) In the case of 0 25 g / 5 〇 ml, when measured at 25 ° C, the inherent viscosity of the polyg is 〇1 〇 to less than 1 com / g; and the polyester has 85 to 12 〇 . (1) In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: Ο) a dicarboxylic acid component comprising: I) 70 to 100 Mole% of terephthalic acid residues; II) 0 to 30 mol% of aromatic dicarboxylic acid residues having up to 2 carbon atoms; and in) 0 to 10 mol% of aliphatic dicarboxylic acid An acid residue having up to 16 carbon atoms; and (b) a diol component comprising: I) 1 to 99 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutane An alcohol residue; and II) from 1 to 99 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total molar % of the carboxylic acid component is 1% molar %, and the total molar % of the diol component is 100 mole % •, and 119732. Doc -54- 200804457 Where the intrinsic viscosity of polyester is 〇 when measured at 25 C in 60/40 (w/w) phenol/tetrachloroethane at a concentration of 25 g/5 〇ml 35 to 1. 2 com / g; and wherein the polyester has the same as that. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 1 mole % Terephthalic acid residue; η) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ill) 0 to 10 mol% of an aliphatic dicarboxylic acid residue, Having a maximum of 16 carbon atoms; and (b) a diol component comprising: 1) 1 to 99 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; And ii) from 1 to 99 mol% of a cyclohexane dimethanol residue; and (Π) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total molar % is 100% by mole, and the total molar % of the diol component is 100% by mole; and wherein when in 60/40 (w/w) phenol/tetrachloroethane, in 〇. At a concentration of 25 g / 5 Torr, the inherent viscosity of the polyester is 〇·5 to 1.2 cm/g when measured at 25 ° C; and the polyester has a Tg of 85 to 12 Å. In one aspect, the invention relates to a polyester composition comprising (I) at least one polyester comprising: 119732. Doc-55- 200804457 (a) A dicarboxylic acid component comprising: i) 70 to 1 mole % terephthalic acid residue; 11) 0 to 30 moles. /. An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component, It comprises: I) from 1 to 99 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and II) from 1 to 99 moles per hydrazine of cyclohexane a dimethanol residue; and (Π) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the monocarboxylic acid component has a total molybdenum/. It is % by mole, and the total mole % of the diol component is 100 moles. /. And where is in 60/40 (w/w) phenol/tetrachloroethane, in 〇. 25 grams / 5 〇 升 升 辰 辰 辰 辰 辰 辰 辰 辰 辰. (: When measured, the inherent viscosity of polyester is 〇. 35 to 1. 2 com/g; and wherein the polyester has the following. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) The acid component 'comprising: 1) 70 to 1 mole % terephthalic acid residue; η) 0 to 30 mole % of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; In) 0 to 10 mol% of the aliphatic dicarboxylic acid residue, having a maximum of 16 119,732. Doc -56- 200804457 carbon atoms; and (b) diol components, which comprise: 1) 2 to 2,4,4,4·tetramethyl-^-cyclobutanediol residues from 1 to 99 mol/0 And (1)1 to "Mole% of the cyclohexane-sintered dimethanol residue; and (II) at least one type of thermostable (four), the lanthanide is selected from at least a compound, a reaction product thereof, and a mixture thereof; The total molar % of the acid component is 100% by mole, and the total molar % of the diol component is 100% by mole; and wherein when it is at 6G/4G (weight/weight bribe/tetrachloroethane, 025g) The inherent viscosity of polyester is 〇35 to 1. when measured at 25 C under a wave of 5% 〇. 2 com / g; and wherein the polyester has 95sU5C) C2Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a retinic acid component comprising: 1) 70 to 100 moles per gram / 0 terephthalic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ιιι) to 10 mol. /. An aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 1) 1 to 99 mol% of 2,2,4,4-tetradecyl-1, 3_cyclobutanediol residue; and η) 1 to 99 mol% of cyclohexane dimethanol residue; and 119,732. Doc -57- 200804457 (π) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total molar % of the dicarboxylic acid component is 1% mol%, and The total molar % of the alcohol component is 100 mol%; and wherein, in 60/40 (w/w) phenol/tetrachloroethane, at a concentration of 25 g/5 〇ml, at 25 ° C When measured, the inherent viscosity of polyester is 〇. 35 to less than 1 com/g; and wherein the polyester has 95 to 115. ^Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a diterpene acid component comprising: i) 70 to 1 mole % Terephthalic acid residue; 11) 0 to 30 moles. /. An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and in) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component, It comprises: 1) 5 to less than 50 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residue; and η) a ring greater than 50 to 95 moles/0 a hexanediethanol residue; and (Π) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the monocarboxylic acid component is 1 〇〇 mole %, and the total molar % of the diol component is 100 mol%; and wherein when in 60/40 (replacement/weight) phenol/tetra-ethane, 〇25 g/5〇 119732. Doc -58- 200804457 At a concentration of liter, the inherent viscosity of the vinegar is 〇% to 1.2 cm/g at 25 Torr, and the polyester has a Tg of 85 to 125 °C. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 100 moles per gram of zero Terephthalic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to one carbon atom; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having a high 16 carbon atoms; and (b) a diol component comprising: i) 5 to less than 5 mole % of 2,2,4,4-tetramethyl-i,3-cyclobutanediol residue; And Π) a cyclohexane dimethanol residue greater than 50 to 95 mol%; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total molar % is 10% 〇 mol%, and the total molar % of the diol component is 100 mol%; and wherein when in 60/40 (w/w) phenol/tetra-ethane, in 〇 At a concentration of 25 g / 5 〇 ml, the inherent viscosity of the polyester is 〇 when measured at 25 ° C. 5〇 to 1·2 com/g; and wherein the polyester has a Tg of 85 to 120 °C. In one aspect, the invention relates to a polyester composition comprising: 119732. Doc -59- 200804457 (I) At least one polyester comprising: (a) a di-acidic acid component comprising: I) 70 to 1 mole % terephthalic acid residue; II) 0 to 30 Mohr % of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and III) 0 to 10 moles per gram. An aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 1) 10 to 30 moles of 0/〇 2,2,4,4_tetramethyl- 1,3_cyclobutanediol residue; and η) 70 to 90 mol% of cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, the reaction thereof The product and its mixture; one of the total mole % of the tickotropic component is 1 〇〇 mol. /❶, and the total molar % of the diol component is 100 mol%; and wherein when in 60/40 (w/w) phenol/tetrachloroethane, in 〇. 25 g / 5 〇 升 度 ’ ’ ' measured at 2 5 C, the inherent viscosity of the vinegar is 〇 · 5 〇 to 1. 2 com / gram; and wherein the vinegar has a Tg of 85 to 120 °C. In one embodiment, the polyester has a Tg of from 100 to 120 °C. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: Ο) diterpene acid component comprising: i) 70 to 100 mol% of p-terphenyl Formic acid residue; 119,732. Doc •60- 200804457 11) 0 to 30 mol% of aromatic dicarboxylic acid residues having up to 2 carbon atoms; and ill) 0 to 10 mol% of aliphatic dicarboxylic acid residues, having a high 16 carbon atoms; and (b) a diol component comprising: I) 15 to 25 mol% of 2,2,4,4-tetramethyl-i,3-cyclobutanediol residues; 75 to 85 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; Moer//. It is 1% mol%, and the total molar % of the diol component is 100 mol%; and wherein when it is in 60/40 (w/w) phenol/tetrachloroethane, it is in 〇. The intrinsic viscosity of the polyester is from 〇·5〇 to 1_2 com/g when measured at 25 ° C at a concentration of 25 g / 5 Torr; and wherein the polyester has 85 to 12 〇〇 c. In a specific embodiment, the Tg of the polyester is from 1 i to i2 〇 °c. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyglycol comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 Torrole /0 terephthalic acid residue; π) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and in) 〇 to 10 mol% of an aliphatic dicarboxylic acid a residue with a maximum of 16 carbon atoms; and 119,732. Doc • 61 - 200804457 (b) A diol component comprising: i) 15 to 25 mol% of 2,2,4,4-tetramethyl-1,3_cyclobutanediol residues; and 11) 75 to 85 mol% of a cyclohexane dimethanol residue; and (Π) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the monocarboxylic acid is damaged The ear % is 1 〇〇 mol %, and the total molar % of the diol component is 100 mol %; and wherein, in 60/40 (w/w) phenol/tetrachloroethane, 〇 25 g / At a concentration of 5 〇 ml, the inherent viscosity of the polyester is 〇 when measured at 25 ° C. 5〇 to 0. 8 com / gram; and wherein the polyester has a ratio of up to 12 〇〇 c. In one embodiment, the Tg of the polyester is from 1 to i2 (rc. In one aspect) the invention relates to a polyester composition comprising: (I) at least one polyester comprising: a) a dicarboxylic acid component comprising: i) 70 to 1 Torrole/0 terephthalic acid residue; η) 0 to 30 mole % of an aromatic dicarboxylic acid residue having a maximum of 2 One carbon atom; and iii) 〇 to 10 m. /. An aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 1) 15 to 25 mol% of 2,2,4,4-tetramethyl-1, 3_cyclobutanediol residue; and ii) 75 to 85 mol% of cyclohexane dimethanol residue; and 119,732. Doc 62-200804457 (I) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1% mol%, and The total mole % of the alcohol component is 100 moles. /〇; and which is in 60/40 (w/w) phenol/tetrachloroethane, in 〇. At a concentration of 25 g / 5 〇 ml, the inherent viscosity of the polyester is 〇·5〇 to ❹^公合/克 when measured at 25°C: and the polyester has “to In a particular embodiment, the polyester has a Tg of from 1 to 120. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a diterpene acid component comprising: 1) 70 to 100 mol% of a terephthalic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms And in) 0 to 10 mole % of the aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 1) 1 to 99 moles of 0/〇2, a 2,4,4-tetramethyl-1,3-cyclobutanediol residue; and ιι) 1 to 99 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer, Is selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total molar % of the dicarboxylic acid component is 100 mol%, and the total molar % of the diol component is 100 mol%; and 119732. Doc -63 - 200804457 Where the intrinsic viscosity of the vinegar is measured at a concentration of (4)·25 g/5 〇ml at 60/40 (w/w) phenol/tetrachloroethane, 'at 25 ° C 〇35 to 1.2 cm/g; and wherein the polyester has 1 to 12 〇 of 4 thereof. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a diterpene acid component comprising: 1) 70 to 1 mole % Terephthalic acid residue; η) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue, Having a maximum of 16 carbon atoms; and (b) a diol component comprising: i) b to 25 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; And ii) 75 to 85 moles/rhodium cyclohexane dimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total mole % of ingredients is 100 moles. /. And the total molar % of the diol component is 100% by mole; and wherein when in the 60/40 (W/W) / Siqiyiyuan, at a concentration of 〇25g/50ml 'in 2 When measured at 5 °C, the inherent viscosity of the polyester is 0 · 50 to 1. 2 com / gram; and wherein the polyester has a Tg of from 1 Torr to 2 Torr. In one embodiment, the polyester has a Tg of from 100 to 120 °C. In one aspect, the invention relates to a polyester composition comprising: 119732. Doc-64-200804457 (i) at least one polyester comprising: (a) a dicarboxylic acid component comprising: I) 70 to 1 mole of tertene/ruthenium terephthalic acid residue; II) 0 Up to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic diterpene residue having up to 16 carbon atoms; a diol component comprising: I) 5 to less than 50 mole % of 2,2,4,4-tetramethyl-i,3-cyclobutanyl residue; and II) greater than 50 to 95 moles % of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1〇〇 Molar%, and the total mole % of the diol component is 100 moles. /. And wherein the inherent viscosity of the polyester is 〇·5 when measured at 25 ° C in 60/40 (w/w) phenol/tetra-ethane at a concentration of 25 g/5 〇ml. 〇至1_2公合/克; and wherein the polyester has "to the second". In the aspect of the invention, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: a plurality of acid components comprising: Ο 70 to 100 mol% of terephthalic acid residues; i〇〇 to 30 mol% of an aromatic diterpene acid residue having up to 2 carbon atoms; And 119732. Doc -65- 200804457 ill) 〇 to 10 m. /. An aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 1) 10 to 30 moles of 0/〇 2,2,4,4·tetramethyl- 1,3·cyclobutanediol residue; and ii) 70 to 90 mol% of cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, The reaction product and the mixture thereof; wherein the total molar % of the sustained wound is 1% molar %, and the total molar % of the diol component is 100% by mole; and wherein when it is at 60/40 (weight/ Weight) phenol / tetrachloroethane, in 〇. At a concentration of 25 g / 5 Torr, the inherent viscosity of the polyester is 〇 when measured at 25 ° C. 5〇 to 1. 2 metrics/gram; and wherein the polyester has 95 to 115. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) from 70 to 100 mole percent a phthalic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ιιι0 0 to 10 mol% of an aliphatic dicarboxylic acid residue having Up to 16 carbon atoms; and (b) a diol component comprising: 1) 15 to 25 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; 119732. Doc • 66- 200804457 ii) 75 to 85 mole % cyclohexane dimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, its reaction product and mixtures thereof; The total molar % of the slow acid component is 1% mol%, and the total molar % of the diol component is 100 mol%; and wherein when in 60/40 (w/w) phenol/tetrachloroethane The intrinsic viscosity of the polyester when measured at 25 ° C at a concentration of 25 g / 5 〇 ml is 〇·5 〇 to 1.2 cm·g/g; and wherein the poly g is 95 to 115. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyglycol comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 mole % Terephthalic acid residue; ii) 0 to 30 moles. /〇 an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol a composition comprising: 1) 5 to less than 50 mole % of a 2,2,4,4·tetramethyl-1,3-cyclobutanediol residue; and ii) a ring greater than 50 to 95 mole % a hexane dimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1% molar % And the total molar % of the diol component is 100% by mole; and 119,732. Doc -67- 200804457 Where, in 60/40 (w/w) phenol/four-gas sinter, at a concentration of 克25 g/5 〇ml, at 25. (In the next measurement, the intrinsic viscosity of the vinegar is 〇5〇 to 0·75 com/g; and wherein the polyester has 85 to 125. 〇之丁@. In one aspect, the invention relates to a polyester combination And comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 mole % terephthalic acid residue; ii) 0 to 30 Molar% of an aromatic dicarboxylic acid residue, 2 carbon atoms higher; and 111) 〇 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and β (b) An alcohol component comprising: 1) 5 to less than 50 mol% of 2,2,4,4-tetramethyl-1,3·cyclobutanediol residue; and π) greater than 50 to 95 mol% a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1 〇〇 mole %, and the total molar % of the di-fermented ingredient is 100 mol%; and wherein, in 60/40 (w/w) phenol/tetra-ethane, at a concentration of 25 g / 5 ml, When measured at 25 ° C, the inherent viscosity of the polyester is 〇·5〇 to 0. 75 metrics/gram; and the polyester has 85 to 12 inches. Ding Zhiding 8. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: 119732. Doc-68- 200804457 (a) A dicarboxylic acid component comprising: 1) 70 to 1 mol% of a terephthalic acid residue; η) 0 to 30 mol% of an aromatic dicarboxylic acid residue a base having up to 2 carbon atoms; and ill) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 1) 5 to Less than 50 m. /〇2,2,4,4-tetramethyl-1,3·cyclobutanediol residue; and ii) greater than 50 to 95 mol% of cyclohexanedimethanol residue; and (II) at least A heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1 Torr. /(), and the total molar % of the diol component is 100 mol%; and wherein when 60/40 (w/w) phenol/tetrachloroethane, the radiance of 〇25 g/5 〇ml Under the 'measured at 25 C, the inherent viscosity of the polyester is 〇6〇 to 0. 75 metrics/gram; and wherein the polyester has a Tg of 85 to 12 〇1. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 0 to 70% of a mole percent Phthalic acid residue; η) 0 to 30 moles. /. An aromatic dicarboxylic acid residue having up to 2 碳 carbon atoms; and iii) 〇 to 10 mol% of an aliphatic dicarboxylic acid residue having a maximum of 16 119,732. Doc-69-200804457 carbon atoms; and (b) monool component comprising: I) 5 to less than 50 mol% of 2,2,4,4-tetramethyl-cyclobutanediol residues; η) a cyclohexane dimethanol residue greater than 50 to 95 mol%; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the dicarboxylic acid component The total molar % is 1% mol%, and the total molar % of the diol component is 100 mol%; and wherein when in 60/40 (w/w) phenol/tetra-ethane, in 〇25克 / 〇 ml / Chen degree, when measured at 25 C, the inherent viscosity of polyester is 〇65 to 0. 75 com / g; and wherein the polyester has ^ to ^ instead. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a retinic acid component comprising: i) 70 to 1 mole % Terephthalic acid residue; II) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ill) 0 to 10 mol% of aliphatic dicarboxylic acid residues , having a maximum of 16 carbon atoms; and (b) a diol component comprising: i) 5 to less than 50 mol% of a 2,2,4,4-tetramethyl-L3 cyclobutanol residue; Ii) greater than 50 to 95 mole % of cyclohexane dimethanol residue; and 119,732. Doc-70-200804457 (II) at least one heat stabilizer 'selected from at least one scaly compound, a reaction product thereof, and a mixture thereof; wherein the total molar % of the dicarboxylic acid component is 100 mol%, and the diol component The total molar % is 100% by mole; and wherein when measured at 25 C in 60/40 (w/w) radix/tetrachloroethane, at a wave of 25 g/5 〇ml The inherent viscosity of the brewing is 〇. 68 to 〇·78 com / gram; and wherein the polyester has a ^ ^ ^ ^. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 mole % Terephthalic acid residue; 11) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 atomic broken atoms; and ιιι) 0 to 10 mol% of an aliphatic dicarboxylic acid residue, Having a maximum of 16 carbon atoms; and (b) a diol component comprising: i) 10 to 30 mole % of 2,2,4,4-tetramethyl·ι, 3_cyclobutanediol residue; And ii) 70 to 90 mol% of cycloheximide dimethanol residue; and (II) at least one heat stabilizer selected from at least one of a scaly compound, a reaction product thereof, and a mixture thereof; The total molar % is 100% by mole, and the total molar % of the diol component is 100% by mole; and wherein when it is in 6_(w/w)/four gas, in 〇·25g/5 〇 119732. Doc -71- 200804457 At a concentration of liter, the inherent viscosity of the polyester is 〇5 to 公·8 com/g when measured at 25 ° C; and the polyester has a Tg of 85 to 12 (TC). In a particular embodiment, the polyester has a Tg of from 100 to 120 ° C. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) An acid component comprising: i) 70 to 1 mole % terephthalic acid residue; Π) 0 to 30 mole % of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; Iii) from 0 to 10 mol% of the aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) as a component comprising: 0 10 to 30 mol% of 2, 2, 4, 4_ a tetramethyl-1,3-cyclobutanediol residue; and Π) 70 to 90 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus A compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1% by mole, and the total mole % of the diol component is 100 moles. /. And wherein when measured at 25 ° C in 60/40 (w/w) phenol/tetra-ethane at a concentration of 25 g / 5 〇 ml, the inherent viscosity of the polyester is 〇6 to 〇·8 com/g; and wherein the polyester has a Tg of 85 to 120 °C. In a specific embodiment, the poly 119732. Doc •72- 200804457 The Tg of the ester is 100 to 120 °C. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a diweiler component comprising: · I) 70 to 1 mole % a terephthalic acid residue; II) 0 to 30 mole % of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and in) 0 to 10 mole % of an aliphatic dicarboxylic acid residue , having a maximum of 16 carbon atoms; and (b) a diol component comprising: i) 10 to 30 mol% of 2,2,4,4-tetradecyl-1,3-cyclobutanediol residues And Π) 70 to 90 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the dicarboxylic acid component The total mole % is 1% molar and the total mole % of the diol component is 100 moles. /〇; and wherein when in 60/40 (w/w) phenol/tetrachloroethane, at 0. At a concentration of 25 g / 50 ml, the inherent viscosity of the polyester is 0. 50 to 0. 75 metrics/gram; and wherein the polyester has a Tg of 85 to 120 °C. In one embodiment, the polyester has a Tg of from 100 to 120 °C. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 119732. Doc -73- 200804457 1) 70 to 100 moles per gram of terephthalic acid residues; η) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 2 carbon atoms; and ι ι An aliphatic dicarboxylic acid residue of up to 10 mol% having a maximum of 16 carbon atoms; and (b) a diol component comprising: 1) 15 to 25 mol% of 2, 2, 4, 4 a tetramethyl-1,3-cyclobutanediol residue; and η) 75 to 85 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one a phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total molar % of the dicarboxylic acid component is 100 mol%, and the total molar % of the diol component is 100 mol%; and wherein when at 60/40 (weight) /wt) Phenol / tetrachloroethane, in the 〇 25 g / 5 〇 ml of the "Temperature degree" when measured at 25 C, the inherent viscosity of the polyester is 〇 5 〇 to 0. 75 metrics/gram; and the polyester has 85 to 12 inches. Tg of Tg. In a specific embodiment, the Tg of the polyester is from 1 Torr to 120 °C. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) from 70 to 100 mole percent of para-benzene a dicarboxylic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ιιι) to 10 mol% of an aliphatic dicarboxylic acid residue having a high 16 119732. Doc -74 200804457 carbon atoms; and (b) diol component comprising: i) 17 to 28 mol% of 2,2,4,4-tetradecyl-1,3_cyclobutanediol residues And ii) 72 to 83 mol% of cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the dicarboxylic acid component The total number of ears. /. Is 1% mol%, and the total molar % of the diol component is 100 mol%; and wherein when in 60/40 (w/w) phenol/tetrachloroethane, at 25 g/5 ( The inherent viscosity of the polyester is 〇 when measured at 25 ° C. 65 to 〇·75 com/g; and wherein the polyester has 85 to 12 〇c>c. In one embodiment, the polyester has a Tg of from 1 to 0 to 120. (:) The present invention relates to a polyester composition comprising: (I) at least one polyester comprising: U) a dicarboxylic acid component comprising: Ο 70 to 1 〇〇 mol % Terephthalic acid residue; η) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue , having a maximum of 16 carbon atoms; and (b) a diol component comprising: 1) 17 to 28 mol% of 2,2,4,4·tetramethyl-1,3_cyclobutanediol residues ; and 119732. Doc-75·200804457 ii) 72 to 83 mol% of cyclohexanedimethanol residues; and (II) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total molar % of a Weicheng wound is 1 (10) mol%, and the total molar % of the diol component is 100 mol%; and wherein, in 60/40 (w/w) phenol/tetrachloroethane, The intrinsic viscosity of polyester is 〇 when measured at 25 ° C at a concentration of 25 g / 5 〇 ml. 65 to 0. 75 com/g; and wherein the polyester has a Tg of from 1 〇〇 to 12 〇〇c. In one embodiment, the polyester has a Tg of from 1 to 120. (1) In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 1 Torr % of terephthalic acid residues; ii) 0 to 30 mol% of aromatic dicarboxylic acid residues having up to 2 carbon atoms; and iii) 0 to 10 mol% of aliphatic dicarboxylic acid a residue having up to 16 carbon atoms; and (b) a diol component comprising: 1) 17 to 28 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol And ii) 72 to 83 moles per hydrazine of the cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one compound, its reaction product, and mixtures thereof; The total molar % of one of the ferulic acid components is 1% molar %, and the total diol component is 119,732. Doc -76- 200804457 Mole% is 100 m. /. And wherein the inherent viscosity of the polyester is 〇·7 when measured at 25 ° C in 60/40 (w/w) phenol/tetra-ethane at a concentration of 25 g/5 〇ml. Up to 8 com/g; and wherein the polyester has 85 to 12 〇〇c. In one embodiment, the Tg of the polyester is 1 〇〇 to i2 (rc. In one aspect, the invention A polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 mole percent terephthalic acid residue 11) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms And (b) a diol component comprising: 1) 17 to 28 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and ii) 72 to 83 a molar % cyclohexane dimethanol residue; and (Π) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1 〇〇莫耳./., and the total molar content of the diol component /〇 is 100 mol. /〇; and when it is measured at 25 °C in 60/40 (w/w) phenol/tetrachloroethane at a concentration of 25 g/5 〇ml , the inherent viscosity of polyester is 0. 7 to 0.8 cm/g; and wherein the polyester has a Tg of ι〇〇 to i2〇〇c. On a specific H9732. Doc •77· 200804457 In the examples, the Tg of the polyester is from 1〇〇 to 12〇. (1) In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: I) 70 to 1 〇〇 Mo % of terephthalic acid residues; II) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 2 carbon atoms; and III) 0 to 10 mole % of aliphatic dicarboxylic acid a residue having up to 16 carbon atoms; and (b) a diol component comprising: 1) 17 to 28 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol a residue; and η) 72 to 83 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total amount of acid components. /. Is 1% mol%, and the total molar % of the diol component is 100 mol%; and wherein when 60/40 (w/w) phenol/tetrachloroethane, 〇25 g/5〇 At ML/min, the inherent viscosity of polyester is 〇 when measured at 25 C. 65 to 0. 75 com / g, and the vinegar has 1 〇〇 to us. . Tg. In one embodiment, the polyester has a Tg of from 1 to 12 Torr. Hey. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 119732. Doc-78 - 200804457 I) 70 to 100 mol% terephthalic acid residues; II) 0 to 30 mol% of aromatic dicarboxylic acid residues having up to 2 carbon atoms; and III) 0 Up to 10 mol% of the aliphatic dicarboxylic acid residue having a maximum of 16 carbon atoms; and (b) a drunk component which comprises: I) 5 to less than 50 mol% of 2, 2, 4, kernel a tetradecyl-hydrazine, a % cyclobutanediol residue; and II) a cyclohexane dimethanol residue greater than 50 to 95 mole %; and (II) at least one heat stabilizer selected from at least one phosphorus A compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1% by mole, and the total mole % of the diol component is 100 moles. /〇; and wherein when in 60/40 (w/w) phenol/tetra-ethane, at a concentration of 25 g / 5 Torr, at 25. (: When measuring, the inherent viscosity of the vinegar is 〇. 5〇 to 〇·75 com/g; and the polyester has % to ^. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 1 Torrole/ 0 terephthalic acid residue; η) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to one carbon atom; and ιιι) to 10 mol% of an aliphatic dicarboxylic acid residue, Has up to 碳 carbon atoms; and 119,732. Doc •79- 200804457 (b) a diol component comprising: 0 10 to 30 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 11) 70 Up to 90% by mole of cyclohexanedimethanol residue; and (Π) to y kind of heat stabilizer selected from at least one scaly compound, a reaction product thereof, and a mixture thereof; . /. It is the % of 〇〇mol, and the total amount of diol components. /〇 is 1 〇 〇mol%; and wherein the field is in 60/40 (w/w) phenol/tetrachloroethane, in 〇. The intrinsic viscosity of the polyester is from 〇·5〇 to 0_75 com/g when measured at 25 ° C at a concentration of 25 g / 5 Torr; and wherein the polyester has 95 to 115. Take it easy. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a formic acid component comprising: i) 70 to 1 mole % Terephthalic acid residue; Π) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue, Has a maximum of 16 carbon atoms; and (b) an alcohol component which comprises: i) 15 to 25 mol% of 2,254,4-tetramethyl-1,3-cyclobutanediol residues; and 11) 75 Up to 85 mol% of cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, 119,732. Doc 200804457 The reaction product and mixture thereof; wherein the total molar % of the dicarboxylic acid component is 100 mol%, and the total molar % of the diol component is 100 mol%; and wherein it is prepared at 60/40 (weight/ The inherent viscosity of the polyester is 〇·5〇 to 0·75 com / gram when measured at 25 C under a wave of 克25 g/5 〇ml. Among them, the polyester has 95 to 115. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a monodecanoic acid component comprising: I) 70 to 1 mole % Terephthalic acid residue; II) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ιιι) 0 to 10 mol% of aliphatic dicarboxylic acid residues , having a maximum of 16 carbon atoms; and (b) a diol component comprising: 1) 15 to 25 mol% of 2,2,4,4-tetradecyl-1,3-cyclobutanediol residues And η) 75 to 85 mol% of a cyclohexanedimethanol residue; and (Π) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the carboxylic acid component The total molar amount/❶ is 100% by mole, and the total molar % of the diol component is 100% by mole; and wherein when it is in 60/40 (heavy weight/weight) phenol/tetra-ethane, 〇 25 g / 5 〇 ml at a concentration of 25. (: When measured, the inherent viscosity of the vinegar is 〇·6 to 119732. Doc -81 - 200804457 0·72 com/g; and the polyester has 95 to 115. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyglycol comprising: (a) a dicarboxylic acid component comprising: i) from 70 to 100 mol% a terephthalic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic diacid residue , having a maximum of 16 carbon atoms; and (b) a diol component comprising: i) 〇·〇1 to less than 5 mol% of 2,2,4,4-tetramethyl-anthracene, 3·cyclobutene a diol residue; ii) an ethylene glycol residue; and iii) a cyclohexane dimethanol residue as needed; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the citric acid component is 1 〇〇 mol %, and the total molar % of the diol component is 100 mol %; and wherein when 60/40 (w/w) In the tetra-ethane, the inherent viscosity of the polyester is 0. When measured at 25 ° C at 25 ° C. 35 to 1.2 cm / gram; and wherein the polyester has 60 to 11 inches. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 119732. Doc -82- 200804457 i) 70 to 1 mole % terephthalic acid residue; II) 〇 to 30 mole % of aromatic dicarboxylic acid residue, having up to 2 carbon atoms; and III 0 to 10 mol% of the aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 1) 0·01 to 4. 5 mol% of a 2,2,4,4-tetramethyl-1,3-cyclobutanediol residue; ii) an ethylene glycol residue; and 111) optionally a cyclohexanedimethanol residue; And (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 100 mol%, and the total molar amount of the diol component % is 100% by mole; and wherein when in 60/40 (w/w) phenol/tetrachloroethane, at 0. At 25 g / 50 ml, the inherent viscosity of polyester is 〇 when measured at 25 °C. 35 to 1. 2 com / gram; and wherein the polyester has 6 〇 to 11 〇. 〇之丁§. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyglycol comprising: U) a dicarboxylic acid component comprising: i) 70 to 1 Torrole/ 0 terephthalic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of aliphatic dicarboxylic acid residues Base, with a maximum of 16 119732. Doc -83 - 200804457 carbon atoms; and (b) diol components containing ·· i) 0·01 to 4 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutene a diol residue; ii) an ethylene glycol residue; and 111) optionally a cyclohexane dimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total molar % of the citric acid component is 1 〇〇 mol %, and the total molar % of the diol component is 100 mol %; and wherein 60/40 (w/w) phenol/ In tetrachloroethane, the inherent viscosity of the polyester is 〇·35 to 1. when measured at 25 ° C at a concentration of 25 g / 5 〇 ml. 2 com / gram; and wherein the polyester has 6 〇 to 11 〇. 〇 4. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: U) a dicarboxylic acid component comprising: i) from 70 to 1 mole percent Phthalic acid residue; η) 0 to 30 moles. / 〇 芳 aromatic dicarboxylic acid residue having up to 2 carbon atoms; and in) 〇 to ίο mol% of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) diol a composition comprising: Ο 〇·〇1 to 3 mol% of a 2,2,4,4-tetramethyl-1,3-cyclobutanediol residue; 119732. Doc-84 - 200804457 ii) an ethylene glycol residue; and iii) a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total molar % of one of the Wei's wounds is 1 (10) mol%, and the total molar % of the diol component is 100 mol%; and wherein it is in 60/40 (w/w) phenol/tetra-ethane , Yu Wei. The inherent viscosity of polyester is 〇·35 to 1. when measured at 25 ° C at 25 ° / 5 Torr. 2 com / gram; and wherein polyg is intended to have 6 (^u 〇〇 C2Tg. In one aspect the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a a dicarboxylic acid component comprising: i) 70 to 1 mole % terephthalic acid residue; η) 0 to 30 mole % of an aromatic dicarboxylic acid residue having up to 2 carbons Atom; and in) 0 to 10 moles. / an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: i) 〇·〇1 to 2. 0 mol% of 2,2,4,4-tetradecyl_1,3_cyclobutanediol residue; ii) ethylene glycol residue; and iii) cyclohexanol residue as needed; And (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; 119732. Doc -85- 200804457 wherein the total molar % of the dicarboxylic acid component is 100 mol %, and the total molar % of the diol component is 100 mol %; and wherein 60/40 (w/w) phenol/ In tetrachloroethane, the inherent viscosity of the polyester is 〇35 to 1. when measured at 25 ° C at a concentration of 25 g / 5 〇 ml. 2 com / gram; and wherein the polyester has 6 〇 to 11 〇. 〇之1^. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) from 70 to 100 mol% of para-benzene a dicarboxylic acid residue; η) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ill) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having a high 16 carbon atoms; and (b) a diol component comprising: Ο 0·01 to 1 molar 0/〇 2,2,4,4_tetramethyl-1,3-cyclobutanediol residue Ii) an ethylene glycol residue; and iii) a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total amount of ingredients is /. Is 1% mol%, and the total molar % of the diol component is 100 mol%; and wherein when 60/40 (w/w) phenol/tetra-ethane, 〇25 g/5〇 At a concentration of cc, the inherent viscosity of the polyester is 〇 when measured at 25 ° C. 35 to 119732. Doc -86- 200804457 1. 2 com / gram; and wherein the polyester has 4 〇 to 11 〇 4 of 4. The present invention relates to a polyester composition comprising: (I) at least one polyester comprising (a) a carboxylic acid component comprising: 1) 70 to 100 mol% of the pair a phthalic acid residue, η) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and 111) 0 to 10 mol% of an aliphatic dicarboxylic acid residue, Has a maximum of 16 carbon atoms; and (b) an alcohol component comprising: i) from 0. 01 to less than 1 mol% of 2,2,4,4-tetramethyl-i,3_cyclobutanediol a residue; ii) an ethylene glycol residue; and iii) a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total molar % of the citric acid component is 100% by mole, and the total molar % of the diol component is 100% by mole; and wherein, in 60/40 (w/w) phenol/tetrachloroethane, Yu Yu. The inherent viscosity of polyester is 〇·35 to 1. when measured at 25 ° C at a concentration of 25 g / 5 Torr. 2 com/g; and wherein the polyester has a Tg of 60 to ii (TC). In one aspect, the invention relates to a polyester composition comprising (I) at least one polyester comprising: a dicarboxylic acid component comprising: 119732. Doc -87- 200804457 I) 70 to 100 mol% terephthalic acid residues; II) 0 to 30 mol% of aromatic dicarboxylic acid residues having up to 2 carbon atoms; and III) 0 To 10 moles. /. An aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 1) 〇·〇1 to 15 mol% of 2,2,4,4-tetramethyl a 1,3-diol residue; ii) an ethylene glycol residue; and iii) a cyclohexanedimethanol residue; and (II) to; a heat stabilizer selected from at least one phosphorus compound, the reaction thereof a product and a mixture thereof; wherein the total molar % of the dicarboxylic acid component is 100 mol%, and the total molar % of the diol component is 100 mol%; and wherein when 60/40 (w/w) phenol/ In tetrachloroethane, the intrinsic viscosity of polyester is 〇 when measured at 25 ° C at a concentration of 25 g / 5 〇 ml. 35 to 1.2 liters/gram; and wherein polyg is intended to be in one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid a composition comprising: i) 70 to 100 mole % terephthalic acid residues; ii) 0 to 30 mole % of aromatic diacidic acid residues having up to 2 carbon atoms; and in) 〇 Up to 10 mol% of aliphatic dicarboxylic acid residues, with a maximum of 16 119,732. Doc •88- 200804457 carbon atoms; and (b) diol components, which contain: i) 0. 01 to 15 mole % of 2,2,4,4-tetramethyl·ι,3-cyclobutanediol residue; ii) 70 to 99. 98 mol% of an ethylene glycol residue; and iii) 〇·〇1 to 15 mol% of a cyclohexanedimethanol residue; and (Π) at least one heat stabilizer selected from at least one phosphorus compound And a reaction product thereof and a mixture thereof; wherein the total mole % of one carboxylic acid damage is 1 〇 0 mol%, and the total molar % of the diol component is 100 mol%; and wherein when at 60/40 ( Weight / weight) phenol / tetrachloroethane, in 〇. At a concentration of 25 g / 5 Torr, the inherent viscosity of the polyester is 0. 35 to 1. 2 com / g; and wherein the polyester has a 〇 § of 6 〇 to 11 〇. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a slow acid component comprising: i) 70 to 1 mole % Terephthalic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ιιι) to 10 mol% of aliphatic dicarboxylic acid residues , having a maximum of 16 carbon atoms; and (b) a diol component comprising: Ο 0·01 to 1 〇 Mo Er 0/〇 2,2,4,4-tetramethyl-1,3-cyclobutene Glycol residue; 119,732. Doc -89 - 200804457 ii) an ethylene glycol residue; and iii) a cyclohexanedimethanol residue; and (Π) to y an antispasmodic agent selected from at least one structural compound, a reaction product thereof, and a mixture; wherein the total molar % of the dicarboxylic acid component is 100 mol%, and the total molar % of the diol component is 100 mol%; and wherein when 60/40 (w/w) phenol/tetrachloroethylene In the alkane, Yu Yu. The inherent viscosity of the polyester is 〇35 to 1_2 com/g when measured at 25 C under 25 g/5 〇ml, and the polyester has 6 〇 to ii 〇 c> Lu. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a diacid component comprising: i) 70 to 1 mole % a terephthalic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) o to 1 mol% of an aliphatic dicarboxylic acid residue a base having up to 16 carbon atoms; and (b) a diol component comprising: i) 〇·〇1 to 10 mol% of 2,2,4,4-tetramethyl-1,3_cyclobutane Glycol residue; ii) 80 to 99. 98 mole % of ethylene glycol residues; and iii) 0. 01 to 10 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; 119732. Doc -90- 200804457 wherein the total molar % of the dicarboxylic acid component is 100 mol %, and the total molar % of the diol component is 100 mol %; and wherein 60/40 (w/w) phenol/ In tetrachloroethane, the intrinsic viscosity of polyester is 〇 when measured at 25 C at 25 g/5 〇 ml/min. 35 to 1. 2 com / gram; and wherein the polyester has 6 〇 to 11 〇. 〇 4. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: 0) a dicarboxylic acid component comprising: I) from 70 to 1 mole percent a phthalic acid residue; II) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ill) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having Up to 16 carbon atoms; and (b)-a drunk component' which contains:

醇殘基； ii) 乙二醇殘基；及 iii) 環己烷二甲醇殘基；An alcohol residue; ii) an ethylene glycol residue; and iii) a cyclohexane dimethanol residue;

其反應產物及其混合物；a reaction product thereof and a mixture thereof;

莫耳％為100莫耳％ ;且Molar% is 100% by mole; and

升之濃度下，在25°C下測定時， 氣乙烷中，於0.25克/50毫 聚酯之固有黏度為0·35至At a concentration of liter, when measured at 25 ° C, the inherent viscosity of 0.25 g / 50 mM polyester in the ethane is 0. 35 to

•9K 119732.doc 200804457 1·2α e/克，且其中聚酯具有6〇至11〇它之丁羟。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二鲮酸成份，其包含： 0 70至100莫耳％之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 0.01至少於5莫耳％之2,2,4,4_四甲基十^環 丁二醇殘基； 11) 90至99.98莫耳％之乙二醇殘基，·及 ιιι)0·01至5莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 ~ 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫 升之濃度下’在25°C^測定時，聚醋之固有黏度為〇·35至 1·2公合/克，且其中聚醋具有6〇至u〇°c之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二叛酸成份，其包含： 119732.doc •92- 200804457 i) 70至100莫耳％之對苯二甲酸殘基； 11) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ιιι)0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： 1) 0·01 至 4.5莫耳％之 2,2,4,4_ 四甲基-i，3-環丁二 醇殘基； ii) 乙二醇殘基；及 iii) 環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種填化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳％為1 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇·35至 1.2公合/克，且其中聚酯具有6〇至11〇。〇之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： Ο)二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高20 個碳原子；及 iii) 〇至10莫耳％之脂族二羧酸殘基，具有至高16 119732.doc -93 - 200804457 個碳原子；與 (b) 一醇成份，其包含： 0 0.01至4莫耳〇/0之2,2,4,4_四甲基環丁二 醇殘基； Π)乙二醇殘基；及 iii)環己烷二甲醇殘基；及 (Π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之?辰度下，在25 C下測定時，聚酯之固有黏度為〇 35至 1.2公合/克；且其中聚酯具有6〇至j 1〇。[之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： 0)二羧酸成份，其包含： i) 70至100莫耳〇/0之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二叛酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： i) 〇·〇1至3莫耳％之2,2,4,4-四甲基-1,3-環丁二 醇殘基； 119732.doc -94- 200804457 ii)乙二醇殘基；及• 9K 119732.doc 200804457 1·2α e / gram, and wherein the polyester has 6 〇 to 11 〇 its butoxy. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a diterpene acid component comprising: 0 70 to 100 mol% of p-terphenyl Formic acid residue; η) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ill) 〇 to 10 mol% of an aliphatic dicarboxylic acid residue having a maximum of 16 And (b) a diol component comprising: i) 0.01 at least 5 mol% of 2,2,4,4-tetramethyl decylcyclobutanediol residue; 11) 90 to 99.98 a molar % ethylene glycol residue, and ιιι) 0·01 to 5 mol% of a cyclohexane dimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, The reaction product and the mixture thereof; wherein the total molar % of the one carboxylic acid component is 100 mol%, and the total molar % of the diol component is 100 mol%; and ~ wherein when at 60/40 (weight/weight) ) In phenol/tetra-ethane ethane, at a concentration of 25 g / 5 〇 ml, the inherent viscosity of the vinegar is 〇·35 to 1.2 cm/g, and the viscous is measured at 25 ° C. Vinegar has a Tg of 6 〇 to u 〇 °c. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a di-retensive acid component comprising: 119732.doc • 92- 200804457 i) 70 to 100 mol% of terephthalic acid residues; 11) 0 to 30 mol% of aromatic dicarboxylic acid residues having up to 2 carbon atoms; and ιιι) 0 to 10 mol% of aliphatic two a carboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 1) from 0. 01 to 4.5 mol% of 2,2,4,4_tetramethyl-i,3-ring a butanediol residue; ii) an ethylene glycol residue; and iii) a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one filler compound, a reaction product thereof, and a mixture thereof The total molar % of one of the carboxylic acid components is 1% molar %, and the total molar % of the diol component is 100 mole %; and wherein 60/40 (w/w) phenol/tetrachloride In ethane, the inherent viscosity of polyester is 〇35 to 1.2 com/g when measured at 25 ° C at 25 ° C, and the polyester has 6 〇 to 11 Hey. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: Ο) a dicarboxylic acid component comprising: i) from 70 to 1 mole percent a phthalic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 20 carbon atoms; and iii) up to 10 mol% of an aliphatic dicarboxylic acid residue having a high 16 119732.doc -93 - 200804457 carbon atoms; and (b) monool component comprising: 0 0.01 to 4 moles / 0 of 2, 2, 4, 4 - tetramethylcyclobutanediol residues ; Π) ethylene glycol residue; and iii) cyclohexane dimethanol residue; and (Π) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total molar % of the ingredients is 100% by mole, and the total molar % of the diol component is 100% by mole; and wherein when in 60/40 (weight/weight) phenol/tetrachloroethane, in 〇25 The inherent viscosity of the polyester is 〇35 to 1.2 com/g when measured at 25 C, and the polyester has 6 〇 to j 1 〇. [Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: 0) a dicarboxylic acid component comprising: i) from 70 to 100 moles per 00 a phthalic acid residue; ii) 0 to 30 mol% of an aromatic diremediate acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having Up to 16 carbon atoms; and (b) a diol component comprising: i) 〇·〇1 to 3 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol Base; 119732.doc -94- 200804457 ii) ethylene glycol residues;

Hi)環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一魏酸成份之總莫耳％為丨〇〇莫耳❶/。，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇·35至 1·2公合/克，且其中聚醋具有⑼至^代之丁^。 於一方面’本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 一叛酸成份，其包含： 1) 70至100莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 〇·〇1 至 2.0莫耳 ％之2,2,4,4·四甲基-1，3_環丁二 醇殘基； ii) 乙二醇殘基；及 iii) 環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種填化合物、 其反應產物及其混合物； 119732.doc -95- 200804457 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下’在25°C下測定時，聚酯之固有黏度為〇·35至 1.2公合/克；且其中聚酯具有⑼至^代之“。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) —竣酸成份，其包含： I) 70至100莫耳〇/〇之對苯二甲酸殘基； II) 0至30莫耳°/。之芳族二羧酸殘基，具有至高2〇 個碳原子；及 III) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 0·01至1莫耳％之2,2,4,4_四甲基- l，3-環丁二 醇殘基； ϋ)乙二醇殘基；及 iii)環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一竣酸成伤之總莫耳％為1 0 〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇 25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇.35至 119732.doc • 96 - 200804457 1·2公合/克；且其中聚酯具有⑼至“代之以。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚g旨，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳〇/〇之對苯二曱酸殘基； 11) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含·· 1) 〇·〇1至少於1莫耳0/〇之2,2,4,4-四甲基-1，3-環 丁二醇殘基； ii) 乙二醇殘基；及 iii) 環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一緩S文成伤之總莫耳％為1 〇 〇莫耳％，且二醇成份之總 莫耳％為100莫耳。/〇 ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25 C下測定時，聚酯之固有黏度為〇 35至 1.2公合/克；且其中聚酯具有6〇至11〇1之丁邑。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 119732.doc -97- 200804457 I) 70至100莫耳％之對苯二甲酸殘基； II) 0至30莫耳。/。之芳族二羧酸殘基，具有至高2〇 個碳原子；及 III) 〇至1〇莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： I) 〇·01至5莫耳％之2,2,4,4_四甲基環丁二 醇殘基； II) 90至99.98莫耳％之乙二醇殘基；及 ιιι)0·01至5莫耳％之環己烷二曱醇殘基；及 (Π)至y 種熱穩疋劑，其係選自至少一種鱗化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳❶為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇·35至 1.2公合/克；且其中聚g旨具有6〇至11〇。〇之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 119732.doc •98- 200804457 個碳原子；與 (b)二醇成份，其包含： I) 〇.〇1至少於5莫耳％之2,2,4,4_四甲基-1，3-環 丁二醇殘基； II) 大於90至99.98莫耳％之乙二醇殘基；及 in) 0.01至5莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ •，且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇35至 1.2公合/克；且其中聚酯具有6〇至11〇。〇之丁§。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 1) 70至1〇〇莫耳％之對苯二曱酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 〇至1〇莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) ._醇成份，其包含： 1) 0·01至4莫耳％之2,2,4,4·四甲基d，％環丁二 醇殘基； 119732.doc -99- 200804457 11) 91至99.98莫耳％之乙二醇殘基；及 iii) 0.01至5莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二酵成份之總 莫耳％為100莫耳。/。；且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之浪度下，在25°C下測定時，聚酯之固有黏度為〇·35至 1.2公合/克；且其中聚@旨具有6〇至11〇。〇之Tg。 於一方面，本發明係關於一種聚g旨組合物，其包含： (I) 至少一種聚酯，其包含： (a) 酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二緩酸殘基，具有至高 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 〇·〇1至3莫耳％之2,2,4,4-四甲基- ；ι，3_環丁二 醇殘基； ii) 92至99.98莫耳％之乙二醇殘基；及 iii) 0·01至5莫耳％之環己烷二曱醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 119732.doc •100· 200804457 其中一羧酸成份之總莫耳％為i00莫耳％，且二醇成份之總 莫耳°/。為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫 升之、/辰度下，在25 °C下測定時，聚酯之固有黏度為〇 35至 1.2公合/克；且其中聚酉旨具有6〇至11〇。〇之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 1) 70至1〇〇莫耳〇/〇之對苯二甲酸殘基； ii) 0至30莫耳❶/。之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 0·01至2莫耳％之2,2,4,4-四曱基_1，3_環丁二 醇殘基； ii) 93至99.98莫耳％之乙二醇殘基；及 111) 0.01至5莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇 35至 119732.doc -101- 200804457 1·2公合/克；且其中聚酯具有6〇至11〇。(：之1^。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) —竣酸成份，其包含： I) 70至100莫耳％之對苯二曱酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 0 0·01至1莫耳％之2,2,4,4-四曱基-1，3_環丁二 醇殘基； Π) 94至99.98莫耳。/〇之乙二醇殘基；及 iii)〇.〇l至5莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ :且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇·35至 1·2公合/克，且其中聚醋具有至u〇°c之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 119732.doc -102- 200804457 i) 70至100莫耳〇/〇之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 m) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： i) 0.01至少於1莫耳％之2,2,4,4-四甲基—u-環 丁二醇殘基； 11)大於94至99_98莫耳％之乙二醇殘基；及 iii) 0.01至5莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下，在25。(：下測定時，聚g旨之固有黏度為〇35至 U公合/克；且其中聚酯具有6〇至11〇。(：之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： Ο)二羧酸成份，其包含： I) 70至1〇〇莫耳％之對苯二曱酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及Hi) a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the one of the ferulic acid component is 丨〇〇 Moer//. And the total molar % of the diol component is 100 mol%; and wherein, in 60/40 (w/w) phenol/tetrachloroethane, at a concentration of 25 g/5 〇ml, at 25 When measured at ° C, the inherent viscosity of the polyester is 〇·35 to 1.2 cm/g, and the polyacetate has (9) to ^. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a retinic component comprising: 1) 70 to 100 mol% of para-benzene a dicarboxylic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having a high 16 carbon atoms; and (b) a diol component comprising: i) 〇·〇1 to 2.0 mol% of 2,2,4,4·tetramethyl-1,3-cyclobutanediol residues Ii) an ethylene glycol residue; and iii) a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one filler compound, a reaction product thereof, and a mixture thereof; 119732.doc - 95-200804457 wherein the total molar % of the dicarboxylic acid component is 100 mol%, and the total molar % of the diol component is 100 mol%; and wherein 60/40 (w/w) phenol/tetrachloride In ethane, the inherent viscosity of the polyester is 〇35 to 1.2 com/g when measured at 25 ° C at a concentration of 25 g / 5 〇 ml; and the polyester has (9) to "On one hand, this hair A polyester composition comprising: (I) at least one polyester comprising: (a) a phthalic acid component comprising: I) 70 to 100 moles per gram of terephthalic acid residues ; II) 0 to 30 moles of aromatic dicarboxylic acid residues having up to 2 carbon atoms; and III) 0 to 10 mole % of aliphatic dicarboxylic acid residues, up to 16 a carbon atom; and (b) a diol component comprising: 1) 0. 01 to 1 mol% of 2,2,4,4-tetramethyl-l,3-cyclobutanediol residue; ϋ) a glycol residue; and iii) a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total molar % is 10% 〇 mol%, and the total molar % of the diol component is 100 mol%; and wherein when in 60/40 (w/w) phenol/tetra-ethane, in 〇25 At a concentration of 5 〇ml, the inherent viscosity of the polyester is 〇.35 to 119732.doc • 96 - 200804457 1·2 com / g; and the polyester has (9) to “ Replace it with. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyglycol comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 Torrole /〇 terephthalic acid residue; 11) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of aliphatic dicarboxylic acid An acid residue having a maximum of 16 carbon atoms; and (b) a diol component comprising: 1) 〇·〇1 of at least 1 mole/0/〇2,2,4,4-tetramethyl- a 1,3-cyclobutanediol residue; ii) an ethylene glycol residue; and iii) a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, The reaction product and the mixture thereof; wherein the total molar % of the wounded S is 0% by mole, and the total molar % of the diol component is 100 moles. /〇; and wherein when measured at 25 C in 60/40 (w/w) phenol/tetrachloroethane at a concentration of 25 g/5 〇ml, the inherent viscosity of the polyester is 〇35 To 1.2 metric/g; and wherein the polyester has a bismuth of 6 〇 to 11 〇1. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 119732.doc-97-200804457 I) 70 to 100 mole % terephthalic acid residue; II) 0 to 30 moles. /. An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and III) from 1 to 1 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component , which comprises: I) 〇·01 to 5 mol% of 2,2,4,4_tetramethylcyclobutanediol residues; II) 90 to 99.98 mol% of ethylene glycol residues; and ι ι a 0. 01 to 5 mol% cyclohexane diol residue; and (Π) to y thermal stabilizer selected from at least one squama compound, a reaction product thereof, and a mixture thereof; The total molar amount of the acid component is 100% by mole, and the total molar % of the diol component is 100% by mole; and wherein when it is in 60/40 (w/w) phenol/tetra-ethane, At a concentration of 25 g / 5 〇 ml, the intrinsic viscosity of the polyester is 〇 35 to 1.2 com / g when measured at 25 ° C; and wherein the poly g is intended to have 6 〇 to 11 〇. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 mole % Terephthalic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue, Having a maximum of 16 119732.doc •98-200804457 carbon atoms; and (b) a diol component comprising: I) 〇.〇1 at least 5 mol% of 2,2,4,4_tetramethyl- a 1,3-cyclobutanediol residue; II) an ethylene glycol residue greater than 90 to 99.98 mol%; and in) 0.01 to 5 mol% of a cyclohexanedimethanol residue; and (II) at least A heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1% mol%, and the total mole % of the diol component is 100% Molar%, and wherein the intrinsic viscosity of the polyester is measured at 25 ° C at a concentration of 25 g / 5 〇 ml in 60/40 (w/w) phenol/tetrachloroethane. 〇35 to 1.2 com/g; and its Polyesters having 6〇 to 11〇. 〇之丁§. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 1 mole % a terephthalic acid residue; η) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and in) 〇 to 1 mol% of an aliphatic dicarboxylic acid residue a group having a maximum of 16 carbon atoms; and a (b).-alcohol component comprising: 1) 0·01 to 4 mol% of 2,2,4,4·tetramethyl d,% cyclobutanediol Residue; 119732.doc -99- 200804457 11) 91 to 99.98 mol% of ethylene glycol residues; and iii) 0.01 to 5 mol% of cyclohexanedimethanol residue; and (II) at least one heat a stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1% mol%, and the total molar % of the di-fermentation component is 100 moles . /. And wherein the inherent viscosity of the polyester is 〇· when measured at 25 ° C in 60/40 (w/w) phenol/tetrachloroethane at a wave of 25 g/5 〇ml. 35 to 1.2 com/g; and wherein the poly@ is intended to have 6 to 11 inches. Tg of Tg. In one aspect, the invention relates to a composition comprising: (I) at least one polyester comprising: (a) an acid component comprising: i) a 70% to 1% molar pair a phthalic acid residue; ii) 0 to 30 mol% of an aromatic diacidic acid residue having up to one carbon atom; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having a maximum of 16 And (b) a diol component comprising: i) 〇·〇1 to 3 mol% of 2,2,4,4-tetramethyl-; i, 3_cyclobutanediol residue Ii) 92 to 99.98 mol% of ethylene glycol residues; and iii) 0. 01 to 5 mol% of cyclohexanedimethanol residues; and (II) at least one heat stabilizer, which is selected From at least one phosphorus compound, a reaction product thereof, and a mixture thereof; 119732.doc • 100· 200804457 The total molar % of one of the carboxylic acid components is i00 mol%, and the total molar amount of the diol component is /. 100 mol%; and wherein when measured at 25 ° C in 25/40 (w/w) phenol/tetra-ethane, at 25 ° C / 〇 〇 The intrinsic viscosity of the ester is from 〇35 to 1.2 com/g; and wherein the polythene is intended to have from 6 to 11 Å. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 1 Torrole/ Terephthalic acid residues; ii) 0 to 30 moles /. An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and in) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component, It comprises: 1) 0. 01 to 2 mol% of 2,2,4,4-tetradecyl_1,3_cyclobutanediol residues; ii) 93 to 99.98 mol% of ethylene glycol residues And 111) 0.01 to 5 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the dicarboxylic acid The total molar % of the ingredients is 1% molar %, and the total molar % of the diol component is 100 mole %; and wherein in 60/40 (w/w) phenol/tetrachloroethane, At a concentration of 25 g / 5 〇 ml, the inherent viscosity of the polyester is 〇35 to 119732.doc -101- 200804457 1·2 com/g when measured at 25 ° C; and the polyester has 6 〇 To 11 baht. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a phthalic acid component comprising: I) 70 to 100 Molar% terephthalic acid residue; II) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ill) 〇 to 10 mol% of aliphatic two a carboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 0 0·01 to 1 mol% of 2,2,4,4-tetradecyl-1,3_cyclo Butanediol residue; Π) 94 to 99.98 mol. / 〇 乙二醇 ethylene glycol residue; and iii) 〇 1 to 5 mol % of cyclohexane dimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product and a mixture thereof; wherein the total molar % of the dicarboxylic acid component is 1% by mole, and the total molar % of the diol component is 100% by mole: and wherein when at 60/40 (weight/weight) ) In the phenol/tetrachloroethane, the intrinsic viscosity of the polyester is 〇·35 to 1.2 cm/g at a concentration of 25 g/5 〇ml at 25 ° C, and Polyacetate has a Tg to u〇°c. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 119732.doc -102- 200804457 i) 70 to 100 moles / oxime terephthalic acid residues; η) 0 to 30 mole % of aromatic dicarboxylic acid residues, having up to 2 carbon atoms; and m) 0 to 10 mole % of fat a dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: i) 0.01 at least 1 mol% of 2,2,4,4-tetramethyl-u-ring a butanediol residue; 11) an ethylene glycol residue greater than 94 to 99-98 mol%; and iii) 0.01 to 5 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer, It is selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total molar % of the dicarboxylic acid component is 1% mol%, and the total molar % of the diol component is 100 mol%; Wherein at 60/40 (w/w) phenol/tetrachloroethane, at a concentration of 2525 g/5 〇ml, at 25. (In the next measurement, the intrinsic viscosity of polyg is 〇35 to U com/g; and wherein the polyester has 6 〇 to 11 〇. (: Tg. In one aspect, the invention relates to a polyester combination And comprising: (I) at least one polyester comprising: Ο) a dicarboxylic acid component comprising: I) 70 to 1 mole % of a terephthalic acid residue; II) 0 to 30 a molar aromatic dicarboxylic acid residue having up to 2 carbon atoms;

Hi) 〇至10莫耳％之脂族二緩酸殘基，具有至高16 119732.doc 200804457 個碳原子；與 (b)二醇成份，其包含： ^ 25至35莫耳〇/〇之2,2,4,4-四曱基-1，3-環丁二醇 殘基； II) 65至75莫耳％之環己烧二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 八中田在60/40 (重夏/重量)酚/四氯乙烷中，於〇·25克/5〇毫 升之/辰度下’在25 C下測定時，聚g旨之固有黏度為〇 35至 1·2公合/克；且其中聚酯具有11〇至13〇。(：之1^。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 1) 70至100莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二緩酸殘基，具有至高2〇 個碳原子；及 III) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) —酵成份，其包含： i) 25至35莫耳0/〇之2,2,4,4-四甲基-1，3_環丁二醇 殘基； ii) 65至75莫耳％之環己烷二甲醇殘基；及 119732.doc •104- 200804457 (π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1 〇〇莫耳。/。，且二醇成份之總 莫耳％為100莫耳。/。；且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於0.25克/50毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇·35至 1.2公合/克；且其中聚酯具有11〇至128。〇之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： I) 70至1〇〇莫耳〇/0之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： I) 25至35莫耳％之2,2,4,4_四甲基^，、環丁二醇 殘基； II) 65至75莫耳％之環己烷二甲醇殘基；及 (Π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一緩酸成份之總莫耳％ A 1 ft η曾甘0/ 六寸/0馬100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在6 0/40 (重量/重量）胁/ Α 四虱乙烷中，於0.25克/50毫 119732.doc -105- 200804457 升之/辰度下’在25°C下測定時，聚酯之固有黏度為〇 35至 1.2公合/克；且其中聚酯具有11〇至126<^之^^。 於一方面’本發明係關於一種聚酯組合物，其包含·· (I)至少一種聚酯，其包含·· (a) —竣酸成份’其包含： I) 70至100莫耳％之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 25至35莫耳％之2,2,4,4-四甲基-1，3·環丁二醇 殘基； 11) 65至75莫耳％之環己烷二甲醇殘基；及 (Π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳°/。為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下，在25°C下測定時，聚g旨之固有黏度為〇35至 1.2公合/克，且其中聚g旨具有至123°c之丁g。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 119732.doc • 106 - 200804457 i) 70至100莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： 1) 25至35莫耳％之2,2,4,4_四甲基-U-環丁二醇 殘基； ii) 65至75莫耳％之環己烷二甲醇殘基丨及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫 升之濃度下，在25。(：下測定時，聚酯之固有黏度為〇.35至 1.2公合/克；且其中聚酯具有11〇至12〇1之丁§。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： l) 70至1〇〇莫耳％之對苯二甲酸殘基； u) 〇至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 m) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 119732.doc -107· 200804457 (b)-一醇成份’其包含： 1) 25至35莫耳％之2,2,4,4-四甲基_ι，3-環丁二醇 殘基； η) 65至75莫耳〇/〇之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇 25克/5〇毫 升之浪度下，在25 °C下測定時，聚酯之固有黏度為〇·5至 1.2公合/克；且其中聚酯具有u〇s13(rc之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚g旨，其包含： (a) 二羧酸成份，其包含： I) 70至1〇〇莫耳％之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 III) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 0 25至35莫耳％之2,2,4,4-四甲基環丁二醇 殘基； ii) 65至75莫耳〇/0之環己烷二曱醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 119732.doc 200804457 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇·5至 1.2公合/克；且其中聚酯具有11〇至128。〇之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳〇/0之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高20 個碳原子；及 iii) 0至10莫耳％之脂族二叛酸殘基，具有至南16 個碳原子；與 (b) 二醇成份，其包含： i) 25至35莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基； ii) 65至75莫耳％之環己烷二曱醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1 〇〇莫耳。/。，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於0.25克/50毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為0.5至 119732.doc -109- 200804457 1.2公合/克；且其中聚酯具有^至^代之丁^。 於一方面，本發明係關於一種聚酯組合物，其包含·· (I) 至少一種聚酯，其包含·· (a) —竣酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 111) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 25至35莫耳％之2,2,4,4-四甲基-1，3-環丁二酵 殘基； η) 65至75莫耳〇/〇之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種填化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳。/。；且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇·5至 1.2公合/克；且其中聚醋具有11〇至123。〇之Tg。 於一方面’本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 一幾酸成份，其包含： 1) 70至100莫耳％之對苯二甲酸殘基； 119732.doc -110- 200804457 11) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： i) 25至35莫耳％之2,2,4,各四甲基-u·環丁二醇 殘基； 11) 65至75莫耳％之環己烷二曱醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下’在25 °C下測定時，聚酯之固有黏度為〇 5至 1.2公合/克，且其中聚酯具有11〇至12〇。〇之1^。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 一緩酸成份，其包含： 0 70至100莫耳〇/〇之對苯二甲酸殘基； 11) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳。/。之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含·· 119732.doc -111 - 200804457 〇 25至35莫耳0/〇之2,2,4,4_四甲基-1，3-環丁二酵 殘基； 11) 65至75莫耳％之環己烧二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 八中田在60/40 (重1/重量)酚/四氯乙烧中，於ο”克/5〇毫 升之濃度下’在25 °C下測定時，聚酯之固有黏度為〇6至 0.72么合/克，且其中聚酯具有11〇至13〇(^之丁@。 於一方面，本發明係關於_種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 一竣酸成份，其包含： 1) 70至1〇〇莫耳〇/〇之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) o至ίο莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 25至35莫耳％之2,2,4,4-四甲基4,3-環丁二 殘基； η) 65至75莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 119732.doc -112- 200804457 其中二羧酸成份之總莫耳％為1 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇·6至 0.72公合/克；且其中聚酯具 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 、 0 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳。/〇之脂族二叛酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 25至35莫耳％之2,2,4,4-四曱基-13·環丁二醇 殘基； ii) 65至75莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇·6至 0.72公合/克；且其中聚酯具有11〇至126。(：：之丁§。 119732.doc -113· 200804457 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 0 70至100莫耳％之對苯二曱酸殘基； ii) 0至30莫耳。/。之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 一醇成份，其包含： i) 25至35莫耳％之2,2,4,4·四甲基_1，3_環丁二醇 殘基； 11) 65至75莫耳〇/〇之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇 25克/5〇毫 升之》辰度下，在25 °C下測定時，聚酯之固有黏度為〇 6至 0.72公合/克；且其中聚酯具有11〇至123cCiTg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二曱酸殘基； 11) 0至30莫耳％之芳族二羧酸殘基，具有至高 119732.doc -114- 200804457 個碳原子；及 iii)〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： Ο 25至35莫耳。/〇之2,2,4,4-四甲基·ΐ，3-環丁二醇 殘基； 11) 65至75莫耳％之環己烷二甲醇殘基；及 (II)至夕種熱穩疋劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一魏酸成份之總莫耳％為i 〇〇莫耳。/。，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下’在25 °C下測定時，聚酯之固有黏度為〇·6至 0.72公合/克；且其中聚酯具有11〇至12〇。(^之1[^。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) —鼓酸成份，其包含： I) 70至100莫耳〇/0之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個石炭原子；與 (b) 一醇成份，其包含·· i) 25至35莫耳％之2,2,4,4-四甲基-1，3_環丁二醇 119732.doc -115- 200804457 殘基； ii) 65至75莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一竣®文成伤之總莫耳％為1 〇 〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ •，且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇.25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇·6至 〇.7公合/克；且其中聚酯具有1丨〇至13〇。〇之丁§。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳〇/0之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ιιι)0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 25至35莫耳％之2,2,4,4-四甲基-i，3-環丁二醇 殘基； ii) 65至75莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩疋劑’其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一竣酸成份之總莫耳。/。為1 〇〇莫耳。/❶，且二醇成份之總 119732.doc -116- 200804457 莫耳％為100莫耳且 其中當在6〇/4〇 (重量/重量）酚/四氯乙烷中，於0.25克/50毫 升之/辰度下，在25 C下測定時，聚酯之固有黏度為0.6至 〇·7公合/克；且其中聚酯具有11〇至128cC2Tg。 於一方面’本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； 11) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii)〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 25至35莫耳°/〇之2,2,4,4_四甲基_1，3_環丁二醇 殘基； 11) 65至75莫耳％之環己烷二甲醇殘基；及 (Π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳。/。，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇.6至 〇·7公合/克；且其中聚酯具有l1(^l26〇c之Tg。 於一方面’本發明係關於一種聚酯組合物，其包含： 119732.doc -117- 200804457 (i)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 0 70至100莫耳％之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 III) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) —酵成份’其包含： 0 25至35莫耳％之2,2,4,4-四甲基_1，3·環丁二醇 殘基； 1〇 65至75莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳°/〇為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫 升之濃度下’在25 °C下測定時，聚酯之固有黏度為〇_6至 0.7公合/克；且其中聚酯具有11〇至123。〇之以。 於一方面’本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) —致酸成份，其包含： i) 70至100莫耳％之對苯二甲酸殘基； ii) 〇至30莫耳％之芳族二叛酸殘基，具有至高2〇 個碳原子；及 119732.doc -118- 200804457 iii) 〇至10莫耳％夕日匕# 斗。之脂族二羧酸殘基，具有至高16 個碳原子；與 (b),一醉成份，其包含： 1) 25至35莫耳％之2,2,4，心四甲基十3-環丁二醇 殘基； 己烷二甲醇殘基；及 ii) 65至75莫耳。/❶之環 一種填化合物、 且二醇成份之總 (II)至少一種熱穩定劑，其係選自至少 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％， 莫耳％為100莫耳％;且 其中田在60/40 (重夏/重量）紛/四氯乙燒中，於0.25克㈣毫 升之/辰度下’在25 C下測定時，聚§旨之固有黏度為〇·6至 〇·7公合/克；且其中聚酯具有11〇至12〇。〇之以。 於一方面，本發明係、關於一種聚_組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 0 70至1〇〇莫耳％之對苯二甲酸殘基； 11) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： 1) 25至35莫耳％之2,2,4,4_四甲基4,3-環丁二醇 殘基； 119732.doc •119- 200804457 π) 65至75莫耳％之環己燒二尹醇殘基·及 (Π)至少一種熱穩定劑，其係選自至少-種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳。/。；且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇.6至 0.68公合/克；且其中聚酯具有U(^13(rC2Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 1) 70至100莫耳〇/0之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 25至35莫耳％之2,2,4,4-四甲基-1,3-環丁二醇 殘基； π) 65至75莫耳％之環己烷二曱醇殘基；及 (II) 至夕種熱穩疋劑’其係選自至少^一種填化合物、 其反應產物及其混合物； 其中一緩酸成份之總莫耳％為1⑽莫耳％，且二醇成份之總 莫耳％為100莫耳％;且 119732.doc •120· 200804457 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇.6至 0.68公合/克；且其中聚酯具有ll(^128cc之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含·· (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至100莫耳％之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： I) 25至35莫耳％之2,2,4,4-四甲基_ΐ，3·環丁二醇 殘基； II) 65至75莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二缓酸成份之總莫耳％為100莫耳％，2二醇成份之總 莫耳％為100莫耳％ ;且 其中田在60/40 (重1 /重量）龄/四氯乙烧中，於〇·25克/5〇毫 升之/辰度下纟25 C下測定時，聚酯之固有黏度為〇·6至 0.68么合/克，且其中聚酯具有11〇至126艺之 於方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： 119732.doc -121- 200804457 (a)二羧酸成份，其包含： 具有至高20 i) 70至1〇〇莫耳％之對苯二甲酸殘基 11) 0至30莫耳％之芳族二羧酸殘基， 個碳原子；及 iii)o至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： 0 25至35莫耳％之2,2,4,心四甲基心…環丁二醇 殘基； 11) 65至75莫耳％之環己烷二甲醇殘基；及 (Π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇_25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇 6至 0.68公合/克；且其中聚酯具 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 1) 70至1〇〇莫耳〇/〇之對苯二甲酸殘基； η) 0至30莫耳。/〇之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 〇至1〇莫耳％之脂族二羧酸殘基，具有至高16 119732.doc -122· 200804457 個碳原子；與 (b)二醇成份，其包含： I) 25至35莫耳％之2,2,4,4_四甲基環丁二醇 殘基； II) 65至75莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一魏酸成份之總莫耳％為1 〇〇莫耳。/。，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在6〇MO (重量/重量）酚/四氯乙烷中，於〇·25克/5〇毫 升之濃度下’在25°CT測定時，聚_之固有黏度為〇6至 0.68公合/克；且其中聚酯具有11〇至12〇c>c之丁^。 於一方面，本發明係關於一種聚酯組合物，其包含· (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： I) 70至1〇〇莫耳％之對苯二甲酸殘基； II) 0至30莫耳。/〇之芳族二羧酸殘基，具 之w 20 個碳原子；及 in) 0至10莫耳。/。之脂族二羧酸殘基，具有至高Η 個碳原子；與 (b) 二醇成份，其包含： 1) 28至38莫耳％之2,2,4,4-四甲基-1，3-環丁-含 殘基； ii) 62至72莫耳％之環己烷二甲醇殘基；及 119732.doc -123- 200804457 (II)至J/ 一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇 25克/5〇毫 升之浪度下，在25 C下測定時，聚酯之固有黏度為〇 35至 1.2公合/克；且其中聚酯具有11〇至13〇。(：：之1^。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； 11) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 28至38莫耳％之2,2,4,4_四甲基環丁二醇 殘基； ii) 62至72莫耳〇/〇之環己烷二甲醇殘基；及 (Π)至夕、種熱穩疋劑，其係選自至少一種填化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為i 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 119732.doc • 124 - 200804457 升之辰度下，在25 C下測定時，聚酉旨之固有黏度為〇 5至 a/克，且其中聚酉旨具有"ο至η。之Tg。 於方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) —魏酸成份，其包含： I) 70至100莫耳％之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ιιι)0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 0 28至38莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基； ii) 62至72莫耳％之環己烷二甲醇殘基；及 (Π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）紛/四氯乙烷中，於0 25克/50毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇·6至 0.72公合/克；且其中聚酯具有11〇至i3〇°C之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 119732.doc -125- 200804457 i) 70至100莫耳％之對苯二甲酸殘基； U) 〇至30莫耳％之芳族二羧酸殘基，具有至高20 個碳原子；及 111) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： 1) 28至38莫耳0/〇之2,2,4,4-四甲基-1，3-環丁二醇 殘基； ii) 62至72莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇 25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇6至 〇·7公合/克；且其中聚酯具有11〇至13〇。〇之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) —叛酸成份，其包含： 1) 70至100莫耳％之對苯二甲酸殘基； ii) 0至30莫耳❹/❶之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至1〇莫耳％之脂族二叛酸殘基，具有至高16 個碳原子；與 119732.doc -126- 200804457 (b)二醇成份，其包含： 1) 28至38莫耳％之2,2,4,心四甲基環丁二醇 殘基； 5 ii) 62至72莫耳％之環己院二甲醇殘基；及 (II)至少-種熱穩定劑’其係選自至少—種磷化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇 25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇6至 〇·68公合/克；且其中聚酯具有 於一方面’本發明係關於一種聚酯組合物，其包含： (I)至少種聚醋’其包含： (a) 二羧酸成份，其包含： 1) 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高Μ 個碳原子；與 (b) 二醇成份，其包含·· 1) 28至38莫耳0/〇之2,2,4,4-四甲基-1，3-環丁二醇 殘基； ii) 62至72莫耳〇/〇之環己烷二甲醇殘基，·及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 119732.doc -127- 200804457 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1 〇〇莫耳。/。，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇.25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為0.6至 0.682公合/克；且其中聚酯具有11〇至128。(^之Tg。 於一方面’本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) -—叛酸成份，其包含： i) 70至1〇〇莫耳％之對苯二曱酸殘基； 11) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 28至38莫耳％之2,2,4,4_四曱基_1，3_環丁二醇 殘基； ii) 62至72莫耳％之環己烷二曱醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二緩酸成份之總莫耳％為1 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之激度下，在25 °C下測定時，聚酯之固有黏度為〇.6至 119732.doc -128- 200804457 0_68公合/克；且其中聚酯具 於一方面’本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 1) 70至100莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個破原子；與 (b) 二醇成份，其包含： i) 28至38莫耳％之2,2,4,4-四甲基-1，3-環丁二酵 殘基； ii) 62至72莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）齡/四氣乙烷中，於〇 25克/50毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為0.6至 0.68公合/克；且其中聚酯具有11〇至i23〇c之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： i) 70至100莫耳％之對苯二曱酸殘基； 119732.doc -129- 200804457 ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) —醇成份，其包含： 0 28至38莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基； ii) 62至72莫耳％之環己烷二曱醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳。/。，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇.6至 0.68公合/克，且其中聚酯具有11〇至12〇。〇之Tg。 於一方面’本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 1) 70至1〇〇莫耳〇/0之對苯二曱酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳。/。之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 119732.doc -130- 200804457 i) 30至35莫耳％之2,2,4,4四甲基·匕^環丁二醇 殘基； 11) 65至70莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳％為i 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為0.35至 1.2公合/克；且其中聚酯具有11〇至13〇£>c之丁^。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) —魏酸成份，其包含： Ο 70至100莫耳〇/0之對苯二甲酸殘基； η) 0至30莫耳❶/❻之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 〇至1〇莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 〇 30至35莫耳％之2,2,4,4-四甲基_1，3_環丁二醇 殘基； ii) 65至70莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 119732.doc -131- 200804457 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於0.25克/50毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為0.35至 1.2公合/克；且其中聚g旨具有11〇至128。〇之丁§。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高20 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 30至35莫耳。/〇之2,2,4,4-四甲基-1，3-環丁二醇 殘基； ii) 65至70莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一緩Ssc成伤之總莫耳％為1 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇 .5至 1.2公合/克，且其中聚酯具有11〇至13〇。〇之Tg。 119732.doc -132· 200804457 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚g旨，其包含： (a) —竣酸成份，其包含： 1) 70至100莫耳〇/0之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 3〇至35莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基； Π) 65至70莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳。/。為1 〇〇莫耳。，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）紛/四氣乙烧中，於〇·25克/5〇毫 升之濃度下’在25 °C下測定時，聚酯之固有黏度為〇·5至 1.2公合/克；且其中聚酯具有11〇至128。〇之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： i) 70至1〇〇莫耳〇/0之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 119732.doc •133- 200804457 個碳原子；及 111)0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： I) 30至35莫耳％之2,2,4,4·四甲基-1，3-環丁二醇 殘基； II) 65至70莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二敌酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為1 〇 〇莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇.5至 1.2公合/克；且其中聚酯具有11〇至126。〇之丁邑。 於一方面’本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) —竣酸成份，其包含： i) 70至1〇〇莫耳〇/〇之對苯二甲酸殘基； η) 0至30莫耳。/。之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳❶/。之脂族二羧酸殘基，具有至高Μ 個碳原子；與 (b) 二醇成份，其包含： 1) 30至35莫耳％之2,2,4,4-四甲基-1，3_環丁二醇 119732.doc -134- 200804457 殘基； H) 65至70莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二魏酸成份之總莫耳。/。為100莫耳％，且二醇成份之總 莫耳％為100莫耳。/。；且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇 25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇.5至 1.2公合/克；且其中聚酉旨具有ι1〇至mi之Tg。 於一方面’本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳〇/0之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： I) 30至35莫耳。/〇之2,2,4,4_四曱基-1，3_環丁二醇 殘基； ii) 65至70莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二叛酸成份之總莫耳％為1 〇〇莫耳％，且二醇成份之總 119732.doc -135· 200804457 莫耳％為1〇〇莫耳且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇·25克/50毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為0.5至 1.2公合/克；且其中聚酯具有U(^i2〇〇c之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含·· (I) 至少一種聚酯，其包含·· (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； H) 0至30莫耳％之芳族二羧酸殘基，具有至高20 個碳原子；及 ui) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) ,一醇成份，其包含： i) 3〇至35莫耳％之2,2,4,4-四甲基-1，3·環丁二醇 殘基； Π) 65至70莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳。/〇 ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之浪度下，在25 C下測定時，聚酯之固有黏度為0.6至 〇·72公合/克；且其中聚酯具有11〇至13〇。(：：之1^。 於一方面，本發明係關於一種聚酯組合物，其包含： 119732.doc -136- 200804457 (i)至少一種聚酷，其包含： (a) —幾酸成份，其包含： I) 70至1〇〇莫耳％之對苯二甲酸殘基； II) 0至30莫耳。/。之芳族二羧酸殘基，具有至高2〇 個碳原子；及 III) 〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 一醇成份，其包含： 0 30至35莫耳％之2,2,4,4_四甲基_1，3_環丁二酵 殘基； 11) 65至70莫耳％之環己烷二甲醇殘基；及 ()至夕種熱穩定劑，其係選自至少一種鱗化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳。/❶為丄〇〇莫耳％，且二醇成份之總 莫耳％為10 0莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫 升之濃度下，在25。(：下測定時，聚酯之固有黏度為〇 6至 0.72公合/克，且其中聚酯具有11〇至128。〇之丁§。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含·· (a)二致酸成份，其包含： I) 70至100莫耳％之對苯二甲酸殘基； II) 〇至30莫耳。/❶之芳族二叛酸殘基，具有至高2〇 個碳原子；及 119732.doc -137· 200804457 iii) 0至10莫耳〇/〇之脂放— 月曰知一羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： 〇 30至35莫耳％之2,2,4,心四甲基巧，％環丁二醇 殘基； ii) 65至70莫耳％之璟p p 一 衣己说一甲醇殘基；及 (II)至少一種熱穩定劑，复将登白 /、你璉自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為〗ηπ曾甘0/ α ^ L v “六7 /0钓U)0莫耳〇/〇，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇.6至 0.72公合/克；且其中聚酯具有11(^126〇c之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： I) 70至1〇〇莫耳〇/0之對苯二曱酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳％之脂族二羧酸殘基’具有至高16 個碳原子；與 (b) 二醇成份，其包含·· 1) 3〇至35莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基； 119732.doc -138· 200804457 Π) 65至70莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇·25克/50毫 升之濃度下’在25 °C下測定時，聚酯之固有黏度為〇·6至 〇·72公合/克；且其中聚酯具有^岐^代之丁^ 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： I) 70至1〇〇莫耳〇/〇之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： Ο 30至35莫耳％之2,2,4,4-四甲基」，3_環丁二醇 殘基； 11) 65至70莫耳％之環己烷二曱醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物' 其反應產物及其混合物； 其中二㈣成份之總莫耳⑽莫耳％，且二醇成份之總 莫耳％為100莫耳％;且 〜 119732.doc -139- 200804457 其中當在6〇/4〇 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25°C下測定時，聚酉旨之固有黏度為〇 6至 〇 .72么a/克，且其中聚酯具有至12〇。〇之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) —竣酸成份，其包含： I) 70至1〇〇莫耳％之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高 個碳原子；及 III) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： Ο 30至35莫耳％之2,2,4,4_四甲基-1，3-環丁二醇 殘基； η) 65至70莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 " 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳。/。；且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為0.6至 0.68公合/克；且其中聚酯具有11(^13〇〇C2Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： 119732.doc -140- 200804457 (a) 二羧酸成份，其包含： i) 7〇至100莫耳％之對苯二甲酸殘基； u) 0至30莫耳％之芳族二叛酸殘基，具有至高2〇 個碳原子；及 ιιι)0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 〇 30至35莫耳。/。之^七仁四曱基-^ —環丁二酵 殘基； ii) 65至70莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在6_ (4量/重量，四氣乙烧中，於G.25克/50毫 升之浪度下’在25 C下測時，聚g旨之固有黏度為〇·6至 0.68公合/克；且其中聚酯具有128至13〇。〇之丁@。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) —觀酸成份，其包含： i) 70至100莫耳％之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 〇至10莫耳。/。之脂族二羧酸殘基，具有至高16 119732.doc -141 - 200804457 個碳原子；與 (b)二醇成份，其包含： 0 30至35莫耳％之2,2,4,4-四甲基-1，3-環丁二醅 殘基； II) 65至70莫耳％之環己燒二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇·6至 〇·68公合/克；且其中聚酯具有11〇至126QC2Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳〇/0之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 III) 0至10莫耳％之脂族二羧酸殘基，具有至高 個碳原子；與 (b) 二醇成份，其包含： 1) 30至35莫耳％之2,2,4,4-四甲基_ι，3-環丁二酿 殘基； Π) 65至70莫耳％之環己烷二甲醇殘基；及 119732.doc -142- 200804457 (II)至少-種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二缓酸成份之總莫耳％為！⑽莫耳％，且二醇成份之總 莫耳°/。為100莫耳％ ;且 其中當在60/4G (重量/重量，四氯乙炫中，於0 25克/5〇毫 升之濃度下，在25。(：下測定時，聚§旨之固有黏度為〇·6至 〇·68公合/克；且其中聚酯具有u〇至123艺之^^。 於一方面，本發明係關於一種聚酯組合物，其包含·· (I)至少一種聚酯，其包含·· (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳〇/〇之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) o至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 1) 30至35莫耳％之2,2,4,4-四曱基_1，3_環丁二醇 殘基； π) 65至70莫耳％之環己烷二曱醇殘基；及 (Π)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇 25克/5〇毫 119732.doc -143- 200804457 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇 6至 0.68公合/克；且其中聚酯具 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) —竣酸成份，其包含： I) 70至1〇〇莫耳〇/〇之對苯二甲酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 III) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 30至40莫耳％之2,2,4,4-四曱基-1,3-環丁二醇 殘基； Π) 60至70莫耳％之環己烷二曱醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳。/〇 ;且 其中當在60/40 (重量/重量）齡/四氯乙烧中，於0.25克/50毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為0.35至 12公合/克；且其中聚酯具有110至130°C之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 119732.doc -144- 200804457 1) 70至⑽莫耳％之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 111) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個石发原子；與 (b) —醉成份，其包含： 1} 3〇至40莫耳0/〇之2,2,4,4·四曱基-1，3-環丁二醇 殘基； ii) 60至70莫耳％之環己烷二甲醇殘基；及 (II)至v —種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二m酸成份之總莫耳％為刚莫耳％，且二醇成份之總 莫耳°/〇為1〇〇莫耳。/。；且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之/辰度下，在25 C下測定時，聚酯之固有黏度為〇.35至 1.2公合/克；且其中聚酯具有11〇至128它之以。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 0 70至100莫耳％之對苯二甲酸殘基； ii) 〇至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ui) 〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 119732.doc -145- 200804457 (b)二醇成份，其包含： I) 30至4〇莫耳％之2,2,4,4-四甲基_1，3_環丁二醇 殘基； II) 60至70莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為i 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇 25克/5〇毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為〇 5至 1.2公合/克；且其中聚酯具有11〇至13〇它之1^。 於方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 一^叛酸成份，其包含： I) 70至100莫耳％之對苯二甲酸殘基； ii) 〇至30莫耳％之芳族二羧酸殘基，具有至高 個碳原子；及 in) 〇至10莫耳％之脂族二羧酸殘基，具有至高Μ 個碳原子；與 (b) 二醇成份，其包含： 0 30至40莫耳％之2,2,4,4_四甲基心，％環丁二 殘基； ^ II) 60至7〇莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 119732.doc -146 - 200804457 其反應產物及其混合物； 其中一竣酸成份之總莫耳％為1 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之漢度下’在25 °C下測定時，聚酯之固有黏度為〇·5至 1·2公合/克；且其中聚酯具 於一方面，本發明係關於一種聚酯組合物，其包含·· (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 1) 70至100莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) —醉成份’其包含： i) 30至40莫耳％之2,2,4,4_四曱基-1，3-環丁二醇 殘基； Π) 60至70莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二敌酸成份之總莫耳％為1〇〇莫耳y。，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫 升之濃度下’在25°C下測定時，聚酯之固有黏度為〇·5至 119732.doc -147- 200804457 1.2公合/克；且其中聚酯具有11〇至126它之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 1) 70至1〇〇莫耳％之對苯二甲酸殘基； η) 0至30莫耳❶/。之芳族二羧酸殘基，具有至高2〇 個碳原子；及 lii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： Ο 30至40莫耳％之2,2,4,4-四曱基-1，3-環丁二醇 殘基； η) 60至70莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一竣酸成伤之總莫耳％為1 0 〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇·25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為0.5至 1·2公合/克；且其中聚酯具有11〇至123它之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含·· i) 70至100莫耳％之對苯二甲酸殘基； 119732.doc -148· 200804457 11) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ιιι)0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： I) 30至40莫耳％之2,2,4,4-四甲基-i，3-環丁二醇 殘基； II) 60至70莫耳％之環己烷二曱醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳％為i 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中备在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之/辰度下’在25 °C下測定時，聚酯之固有黏度為〇 5至 1,2公合/克；且其中聚酯具有110至120。(：之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) —魏酸成份，其包含： 0 70至1〇〇莫耳。/〇之對苯二曱酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 119732.doc -149- 200804457 Ο 30至40莫耳％之2,2,4,4_四甲基ο)-環丁二醇 殘基； Π) 60至70莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇6至 0·72公合/克，且其中聚酯具有 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含·· (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 3〇至40莫耳％之2,2,4,4-四甲基_1，3-環丁二醇 殘基； ii) 60至70莫耳〇/〇之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種麟化合物、 其反應產物及其混合物； 119732.doc -150- 200804457 其中一羧酸成份之總莫耳。/。為i 00莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於0.25克/50毫 升之濃度下，在25°C下測定時，聚酯之固有黏度為0·6至 0.72公合/克；且其中聚酯具有^❹至^代之“。 於一方面’本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： I) 70至1〇〇莫耳〇/〇之對苯二曱酸殘基； II) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 一醇成份，其包含： I) 30至40莫耳％之2,2,4,4-四甲基-1,3-環丁二醇 殘基； II) 60至70莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中一羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇 6至 0.72公合/克，且其中聚酯具有11〇至126它之丁 119732.doc -151- 200804457 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高20 個碳原子；及 iii) 〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 3〇至40莫耳％之2,2,4,4-四曱基-1，3_環丁二醇 殘基； ii) 60至70莫耳％之環己烷二甲醇殘基；及 (ii)至種熱知、疋劑’其係選自至少一種填化合物、 其反應產物及其混合物； 其中二竣酸成份之總莫耳％為100莫耳。/❶，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫 升之濃度下’在25 °C下測定時，聚酯之固有黏度為〇·6至 〇·72公合/克；且其中聚酯具有u〇至l23〇c之以。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a)二羧酸成份，其包含： 1) 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二叛酸殘基，具有至高2〇 119732.doc •152· 200804457 個碳原子；及 iii) 〇至1〇莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： i) 30至40莫耳％之2,2,4,4_四曱基^^―環丁二醇 殘基； ii) 60至70莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為！ 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳。/。；且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇 6至 0.72公合/克，且其中聚酯具有11〇至12〇。〇之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； II) 0至30莫耳❹/。之芳族二羧酸殘基，具有至高2〇 個碳原子；及 III) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) —醇成份，其包含： 1) 3〇至40莫耳％之2,2,4,4_四甲基-1，3-環丁二醇 119732.doc -153- 200804457 殘基； ii) 60至70莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1 〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳。/。；且 其中當在60/40 (重量/重量）盼/四氯乙烧中，於〇·25克/50毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為0.6至 0.68公合/克；且其中聚酯具有11〇至13〇。[之丁§。 於一方面，本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳〇/0之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二緩酸殘基，具有至高20 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個石炭原子；與 (b) 二醇成份，其包含： i) 30至40莫耳❶/^之^七仁四甲基-込弘環丁二醇 殘基； ii) 60至70莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為i00莫耳％，且二醇成份之總 119732.doc -154· 200804457 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氯乙烷中，於〇25克/5〇毫 升之濃度下’在25。(：下測定時，聚酯之固有黏度為〇·6至 〇_68公合/克；且其中聚酯具有11〇至128。〇之Tg。 於一方面’本發明係關於一種聚酯組合物，其包含： (I) 至少一種聚酯，其包含： (a) 二羧酸成份，其包含： 1) 70至100莫耳％之對苯二曱酸殘基； / · Π) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： Ο 30至40莫耳％之2,2,4,4-四甲基_1，3_環丁二醇 殘基； Π) 60至70莫耳％之環己烷二甲醇殘基；及 (II) 至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為100莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫 升之濃度下，在25 °C下測定時，聚酯之固有黏度為〇 6至 0.68公合/克，且其中聚酯具有11〇至126。〇之Tg。 於一方面，本發明係關於一種聚酯組合物，其包含： 119732.doc •155- 200804457 (i)至少一種聚酯，其包含： (a) 二羧酸成份，其包含： i) 70至100莫耳％之對苯二甲酸殘基； 11) 0至30莫耳。/。之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： Ο 30至40莫耳％之2,2,4,4-四甲基_1，3_環丁二酵 殘基； 11) 60至70莫耳％之環己烷二甲醇殘基；及 (II)至少一種熱穩定劑，其係選自至少一種磷化合物、 其反應產物及其混合物； 其中二羧酸成份之總莫耳％為1〇〇莫耳％，且二醇成份之總 莫耳％為100莫耳％ ;且 其中當在60/40 (重量/重量）酚/四氣乙烷中，於〇.25克/5〇毫 升之濃度下’在25°C下測定時，聚酯之固有黏度為〇.6至 0.68公合/克；且其中聚酯具有11〇至以代之“。 於一方面’本發明係關於一種聚酯組合物，其包含： (I)至少一種聚酯，其包含： (a) —緩酸成份，其包含： 1) 70至100莫耳％之對苯二甲酸殘基； η) 〇至30莫耳❶/。之芳族二羧酸殘基，具有至高2〇 個碳原子；及 119732.doc -156. 200804457 )0至10莫耳之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： 〇 3〇至4G莫耳％之2,2,4,4,甲基_1，3-環丁二醇 殘基； ⑴6〇至7〇莫耳％之環己燒二f醇殘基；及 (II)至少一種熱穩定劑，盆传 /、係選自至少一種磷化合物、 其反應產物及其混合物； 其中二錢成份之總莫耳⑽莫耳％，且二醇成份之總 莫耳％為100莫耳％;且 “ 其中當在6咖（重量/重請/四氯乙燒中，於0.25克/50毫 升之辰度下’在25°C下測定時，聚_之固有黏度為〇·6至 〇·68公合/克；且其中聚醋具有ιι〇至12代之 於一方面，本發明係關於一種製造適合用於本發明之任 何聚酯之方法，其包含下列步驟： (I)在選自15〇至25(rc之至少一溫度及選自〇至75 psig之 至上一壓力下加熱一混合物，其中該混合物包含： (a) 二羧酸成份，其包含·· i) 70至100莫耳％之對苯二甲酸殘基； 11) 0至30莫耳❶/。之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii)0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： 119732.doc -157- 200804457 i) 1至99莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基；及 ii) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1·0·1·5/1.〇 ; 其中步驟（I)中之混合物係在下列物質之存在下加 熱：（i)包含至少一種錫化合物之至少一種催化劑， 及，視需要，至少一種選自鈦、鎵、鋅、銻、鈷、 錳、鎂、鍺、鋰、鋁化合物及鋁化合物與氫氧化鋰 或氫氧化鈉之催化劑；及（Π)至少一種熱穩定劑，其 係選自至少一種磷化合物、其反應產物及其混合 物； (II)將步驟（I)之產物於230至320°C之溫度及至少一選自 從步驟（I)之最終壓力至〇.〇2托（絕對壓力）範圍内之 壓力下加熱1至6小時，以形成最終聚酯； 其中該最終聚酯之二羧酸成份之總莫耳％為1〇〇莫耳 %，且該最終聚酯之二醇成份之總莫耳％為1〇〇莫耳 /〇’其中當在60/40 (重量/重量）酚/四氣乙烷中，於 〇·25克/50毫升之濃度下，在251下測定時，該最終 聚醋之固有黏度為0.35至1.2公合/克；且其中該最終 聚酯具有85至200°C之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 何聚醋之方法，其包含下列步驟： (I)在選自150至250°C之至少一溫度及選自〇至75 psig之 119732.doc 200804457 至少一壓力下加熱一混合物，其中該混合物包含·· (a) -一竣酸成份，其包含： 1) 70至100莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二竣酸殘基，具有至高2〇 個碳原子；及 iii) 〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 1至99莫耳％之2,2,4,4-四曱基-1，3-環丁二醇 殘基；及 ii) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1.05-1.15/1.0 ; 其中步驟（I)中之混合物係在下列物質之存在下加 熱：（i)包含至少一種錫化合物之至少一種催化劑， 及，視需要，至少一種選自鈦、鎵、鋅、銻、鈷、 猛、鎮、鍺、鐘、銘化合物及銘化合物與氫氧化鐘 或氫氧化鈉之催化劑；及（ii)至少一種熱穩定劑，其 係選自至少一種磷化合物、其反應產物及其混合 物； (Π)將步驟（I)之產物於230至320°C之溫度及至少一選自 從步驟（I)之最終壓力至0·02托（絕對壓力）範圍内之 壓力下加熱1至6小時，以形成最終聚酯； 其中該最終聚酯之二羧酸成份之總莫耳％為100莫耳 119732.doc •159- 200804457 %，且該最終聚酯之二醇成份之總莫耳％為1〇〇莫耳 %，其中當在60/40 (重量/重量）酚/四氯乙烷中，於 0.25克/50毫升之濃度下，在25χ：τ測定時，該最終 IS曰之固有黏度為〇·35至1.2公合/克；且其中該最終 聚酯具有85至200°C之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 何聚酯之方法，其包含下列步驟： (I)在選自150至250°C之至少一溫度及選自〇至75 psig之 至少一壓力下加熱一混合物，其中該混合物包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳°/。之芳族二竣酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 1至99莫耳％之2,2,4,4-四甲基·1，3-環丁二醇 殘基；及 ii) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1·0_1.5/1.0 ; 其中步驟（I)中之混合物係在下列物質之存在下加 熱：（i)包含至少一種錫化合物之至少一種催化劑， 及，視需要，至少一種選自鈦、鎵、辞、銻、鈷、 119732.doc 200804457 鐘、鎂、鍺、鐘、銘化合物及銘化合物與氫氧化鐘 或氫氧，化鈉之催化劑； (II)將步驟（I)之產物於230至320°c之溫度、至少一選自 從步驟（I)之最終壓力至0.02托（絕對壓力）範圍内之 壓力及至少一種選自至少一種鱗化合物、其反應產 物及其混合物之熱穩定劑之存在下加熱1至6小時； 其中該最終聚酯之二羧酸成份之總莫耳％為1〇〇莫耳 %，且該最終聚酯之二醇成份之總莫耳％為1〇〇莫耳 % ;其中當在60/40 (重量/重量）酚/四氣乙烷中，於 〇·25克/50毫升之濃度下，在25°C下測定時，該最終 聚酯之固有黏度為0.35至1.2公合/克；且其中該最終 聚酯具有85至200°C之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 何聚酯之方法，其包含下列步驟： (I)在選自150至250°C之至少一溫度及選自〇至75 psig之 至少一壓力下加熱一混合物，其中該混合物包含： (a) 二羧酸成份，其包含： 0 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高Μ 個碳原子；與 (b) 二醇成份，其包含： 0 1至99莫耳％之2,2,4,4·四甲基環丁二醇 119732.doc 161 - 200804457 殘基；及 ii) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1_〇5_1·15/1·〇 ; 其中步驟（I)中之混合物係在下列物質之存在下加 熱：包含至少一種錫化合物之至少一種催化劑， 及’視需要’至少一種選自鈦、鎵 '辞、銻、録、 錳、鎂、鍺、鋰、鋁化合物及鋁化合物與氫氧化鋰 或氫氧化鈉之催化劑； (II)將步驟（I)之產物於230至32(rc之溫度、至少一選自 從步驟（I)之最終壓力至0 02托（絕對壓力）範圍内之 壓力及至少一種選自至少一種磷化合物、其反應產 物及其混合物之熱穩定劑之存在下加熱1至6小時； 其中該最終聚酯之二羧酸成份之總莫耳％為100莫耳 % ’且該最終聚酯之二醇成份之總莫耳％為1〇〇莫耳 %，其中當在60/40 (重量/重量）酚/四氯乙烷中，於 〇·25克/50毫升之濃度下，在乃它下測定時，該最終 聚酯之固有黏度為〇.35至12公合/克；且其中該最終 聚酯具有85至200°C之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 何聚酯之方法，其包含下列步驟： (I)在選自150至250°C之至少一溫度及選自〇至75 psig之 至；一壓力下加熱一混合物，其中該混合物包含： (a) —幾酸成份，其包含： 119732.doc -162- 200804457 Ο 70至100莫耳％之對苯二甲酸殘基； 1〇 〇至3〇莫耳％之芳族二羧酸殘:&，具有至高2〇 個碳原子；及 111)0至1〇莫耳％之脂族二缓酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： I) 1至99莫耳％之2,2,4,4-四甲基-1，3_環丁二醇 殘基；及 II) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1.0-1.5/1.0 ; 其中步驟（I)中之混合物係在下列物質之存在下加 熱：（i)包含至少一種錫化合物之至少一種催化劑， 及，視需要，至少一種選自鈦、鎵、鋅、銻、鈷、 錳、鎂、鍺、鋰、鋁化合物及鋁化合物與氫氧化鐘 或氫氧化鈉之催化劑；及（ii)至少一種熱穩定劑，其 係選自至少一種磷化合物、其反應產物及其混合 物； (II)將步驟（I)之產物於250至305 °C之溫度及至少一選自 從步驟（I)之最終壓力至0.02托（絕對壓力）範圍内之 壓力下加熱1至6小時，以形成最終聚酯； 其中該最終聚酯之二羧酸成份之總莫耳％為100莫耳 %，且該最終聚酯之二醇成份之總莫耳％為100莫耳 % ;其中當在60/40 (重量/重量）酚/四氯乙烷中，於 119732.doc -163- 200804457 0·25克750毫升之濃度下，在25°C下測定時，該最終 聚酯之固有黏度為〇·35至1.2公合/克；且其中該最終 聚酯具有85至200°C之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 何聚酯之方法，其包含下列步驟·· (I)在選自150至25 0°C之至少一溫度及選自0至75 psig之 至少一壓力下加熱一混合物，其中該混合物包含： (a) 二羧酸成份，其包含： i) 70至100莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 1至99莫耳％之2,2,4,4-四甲基-1，3_環丁二醇 殘基；及 ii) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1.05-1.15A.0 ; 其中步驟（I)中之混合物係在下列物質之存在下加 熱：（i)包含至少一種錫化合物之至少一種催化劑， 及，視需要，至少一種選自鈦、鎵、鋅 '銻、鈷、 鐘、鎂、鍺、鐘、鋁化合物及鋁化合物與氫氧化鐘 或氫氧化鈉之催化劑；及（ii)至少一種熱穩定劑，其 119732.doc •164· 200804457 係選自至少一種構化合物、其反應產物及其混合 物； (II)將步驟（I)之產物於250至305 °C之溫度及至少一選自 從步驟（I)之最終壓力至0.02托（絕對壓力）範圍内之 壓力下加熱1至6小時，以形成最終聚酯； 其中該最終聚酯之二羧酸成份之總莫耳％為100莫耳 %，且該最終聚酯之二醇成份之總莫耳％為100莫耳 °/〇 ;其中當在60/40 (重量/重量）酚/四氣乙烷中，於 0.25克/50毫升之濃度下，在25°C下測定時，該最終 聚酯之固有黏度為0.35至1.2公合/克；且其中該最終 聚酯具有85至200°C之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 何聚酯之方法，其包含下列步驟： (I)在選自150至25 0°C之至少一溫度及選自〇至75 pSig之 至少一壓力下加熱一混合物，其中該混合物包含： (a) 二羧酸成份，其包含： i) 70至100莫耳％之對苯二甲酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高 個碳原子；及 in) 0至10莫耳％之脂族二羧酸殘基，具有至高Μ 個碳原子；與 (b) 二醇成份，其包含： 0 1至"莫耳％之2,2,4,4-四甲基·1，3-環丁二醇 殘基；及 119732.doc -165- 200804457 ii) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1.0-1.5/1.0 ; 其中步驟（I)中之混合物係在下列物質之存在下加 熱·包含至少一種錫化合物之至少一種催化劑， 及，視需要，至少一種選自鈦、鎵、鋅、銻、鈷、 錳、鎂、鍺、鋰、鋁化合物及鋁化合物與氫氧化鋰 或氫氧化鈉之催化劑； (Π)將步驟（I)之產物於250至305 °C之溫度、至少一選自 從步驟（I)之最終壓力至〇·〇2托（絕對壓力）範圍内之 壓力及至少一種選自至少一種磷化合物、其反應產 物及其混合物之熱穩定劑之存在下加熱1至6小時； 其中該最終聚酯之二羧酸成份之總莫耳％為1〇〇莫耳 ’且該最終聚酯之二醇成份之總莫耳％為1〇〇莫耳 % ;其中當在60/40 (重量/重量）酚/四氯乙烷中，於 〇·25克/50毫升之濃度下，在乃艺下測定時，該最終 聚醋之固有黏度為心^至^公合/克；且其中該最終 聚酯具有85至200°C之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 何聚醋之方法，其包含下列步驟： (I)在選自15〇至25〇它之至少一溫度及選自〇至乃 至J 一壓力下加熱一混合物，其中該混合物包含： (a) —叛酸成份，其包含： i) 70至100莫耳％之對苯二甲酸殘基； 119732.doc 200804457 ii) 0至30莫耳％之芳族二羧酸殘基，具有至高 個碳原子；及Hi) 〇 to 10 mol% of the aliphatic di-acidic acid residue, having a maximum of 16 119732.doc 200804457 carbon atoms; and (b) a diol component comprising: ^ 25 to 35 moles / 〇 2 , 2,4,4-tetradecyl-1,3-cyclobutanediol residue; II) 65 to 75 mol% of cyclohexane-sintered dimethanol residue; and (II) at least one heat stabilizer, Is selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the monocarboxylic acid component is 1% molar %, and the total molar % of the diol component is 100% by mole; and In the 60/40 (heavy summer/weight) phenol/tetrachloroethane, the intrinsic viscosity of the polyg is 〇35 when measured at 25 C under 〇·25 g/5〇ml/min. Up to 1.2 cm / gram; and wherein the polyester has 11 to 13 inches. (1) In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 100 Mole% of terephthalic acid residues; ii) 0 to 30 mol% of aromatic diacidic acid residues having up to 2 carbon atoms; and III) 0 to 10 mol% of aliphatic dicarboxylic acid An acid residue having a maximum of 16 carbon atoms; and (b) a yeast component comprising: i) 25 to 35 moles of 0/〇 2,2,4,4-tetramethyl-1,3_cyclo a butanediol residue; ii) 65 to 75 mol% of a cyclohexanedimethanol residue; and 119732.doc •104-200804457 (π) at least one heat stabilizer selected from at least one phosphorus compound, The reaction product and a mixture thereof; wherein the total molar % of the dicarboxylic acid component is 1 Torr. /. And the total molar % of the diol component is 100 moles. /. And wherein the inherent viscosity of the polyester is 〇·35 to 1.2 when measured at 25 ° C in 60/40 (w/w) phenol/tetrachloroethane at a concentration of 0.25 g / 50 ml. Male / gram; and wherein the polyester has 11 to 128. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: I) 70 to 1 Torrole/ 0 terephthalic acid residue; II) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and in) 0 to 10 mol% of aliphatic dicarboxylic acid residues a base having up to 16 carbon atoms; and (b) a diol component comprising: I) 25 to 35 mol% of 2,2,4,4-tetramethyl^, a cyclobutanediol residue; II) 65 to 75 mol% of cyclohexanedimethanol residue; and (Π) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; Moer % A 1 ft η Zeng Gan 0 / 6 inch / 0 horse 100 mol %, and the total molar % of the diol component is 100 mol %; and when it is at 60 / 40 (weight / weight) / Α Α 虱 虱 于 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 在 在 在 在And the polyester has 11〇 to 126 <^^^^. In one aspect, the invention relates to a polyester composition comprising (I) at least one polyester comprising (a) a phthalic acid component comprising: I) 70 to 100 mol% Terephthalic acid residue; II) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ill) 0 to 10 mol% of an aliphatic dicarboxylic acid residue, Having a maximum of 16 carbon atoms; and (b) a diol component comprising: i) 25 to 35 mol% of a 2,2,4,4-tetramethyl-1,3-cyclobutanediol residue; 11) 65 to 75 mol% of a cyclohexanedimethanol residue; and (Π) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total of the dicarboxylic acid component The molar % is 1% molar %, and the total molar amount of the diol component is /. It is 100 mol%; and wherein it is in 60/40 (w/w) phenol/tetrachloroethane, in 〇. At a concentration of 25 g / 5 Torr, when measured at 25 ° C, the inherent viscosity of the poly g is 〇 35 to 1. 2 com / gram, and wherein the poly g has a gram of g to 123 ° c. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 119732. Doc • 106 - 200804457 i) 70 to 100 mol% of terephthalic acid residues; ii) 0 to 30 mol% of aromatic dicarboxylic acid residues having up to 2 carbon atoms; and iii) 0 Up to 10 mol% of the aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 1) 25 to 35 mol% of 2, 2, 4, 4_4 a methyl-U-cyclobutanediol residue; ii) 65 to 75 mol% of a cyclohexanedimethanol residue and (II) at least one heat stabilizer selected from at least one phosphorus compound, the reaction thereof a product and a mixture thereof; wherein the total molar % of the dicarboxylic acid component is 1% mol%, and the total molar % of the diol component is 100 mol%; and wherein when 60/40 (w/w) In phenol/tetra-ethane, at a concentration of 25 g/5 〇ml, at 25. (: When measured, the inherent viscosity of polyester is 〇. 35 to 1. 2 com / gram; and wherein the polyester has 11 〇 to 12 〇 1 §. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: l) 70 to 1 mole % a terephthalic acid residue; u) an aromatic dicarboxylic acid residue of up to 30 mol%, having up to 2 carbon atoms; and m) 0 to 10 mol% of an aliphatic dicarboxylic acid residue, Has a maximum of 16 carbon atoms; and 119,732. Doc -107· 200804457 (b)-Alcohol component 'comprising: 1) 25 to 35 mol% of 2,2,4,4-tetramethyl-ι,3-cyclobutanediol residue; η) 65 to 75 moles / oxime cyclohexane dimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total of the dicarboxylic acid component The molar % is 1% mol%, and the total molar % of the diol component is 100 mol%; and wherein when 60/40 (w/w) phenol/tetra-ethane, in 〇25 g The inherent viscosity of polyester is 〇·5 to 1. when measured at 25 °C under 5% 〇. 2 com/g; and wherein the polyester has a Tg of u 〇 s 13 (rc. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyglycol comprising: (a a dicarboxylic acid component comprising: I) 70 to 1 mole % terephthalic acid residue; II) 0 to 30 mole % of an aromatic dicarboxylic acid residue having up to 2 carbons Atom; and III) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 0 25 to 35 mol% of 2,2, a 4,4-tetramethylcyclobutanediol residue; ii) 65 to 75 moles/0 of cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one Phosphorus compound, 119732. Doc 200804457 The reaction product and mixture thereof; wherein the total molar % of the dicarboxylic acid component is 100 mol%, and the total molar % of the diol component is 100 mol%; and wherein when it is at 60/40 (weight/ The inherent viscosity of the polyester is 〇·5 to 1. when the weight is phenol/tetra-ethane at a concentration of 25 g/5 〇ml at 25 °C. 2 metrics/gram; and wherein the polyester has 11 to 128. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 Torrole/ 0 terephthalic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 20 carbon atoms; and iii) 0 to 10 mol% of aliphatic di-retensive acid residues , having up to 16 carbon atoms to the south; and (b) a diol component comprising: i) 25 to 35 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues And ii) 65 to 75 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total mole % of ingredients is 1 〇〇 Mo Er. /. And the total molar % of the diol component is 100 mol%; and wherein, in 60/40 (w/w) phenol/tetra-ethane, at 0. At a concentration of 25 g / 50 ml, the inherent viscosity of the polyester is 0. 5 to 119732. Doc -109- 200804457 1. 2 com / gram; and wherein the polyester has ^ to ^ generation of ding ^. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a phthalic acid component comprising: i) 70 to 1 Torr % terephthalic acid residue; η) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and 111) 0 to 10 mol% of aliphatic dicarboxylic acid residues a base having up to 16 carbon atoms; and (b) a diol component comprising: i) 25 to 35 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutane dialdehyde a η) 65 to 75 moles / oxime cyclohexane dimethanol residue; and (II) at least one heat stabilizer selected from at least one of a compound, a reaction product thereof, and a mixture thereof; The total mole % of the acid component is 1% molar %, and the total mole % of the diol component is 100 moles. /. And wherein the inherent viscosity of the polyester is 〇·5 when measured at 25 ° C in 60/40 (w/w) phenol/tetrachloroethane at a concentration of 25 g/5 〇ml. To 1. 2 com / g; and wherein the vinegar has 11 〇 to 123. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a plurality of acid components comprising: 1) 70 to 100 mol% of para-benzene Dicarboxylic acid residue; 119732. Doc-110-200804457 11) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having a high 16 carbon atoms; and (b) a diol component comprising: i) 25 to 35 mol% of 2,2,4, each tetramethyl-u.cyclobutanediol residue; 11) 65 to 75 a molar % cyclohexane dimethyl alcohol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the one carboxylic acid component is 1% mol%, and the total molar % of the diol component is 100 mol%; and wherein when 60/40 (w/w) phenol/tetrachloroethane, 〇25 g/5 〇ml At the concentration of 'measured at 25 ° C, the inherent viscosity of polyester is 〇 5 to 1. 2 com / gram, and wherein the polyester has 11 〇 to 12 〇. 〇之1^. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a slow acid component comprising: 0 70 to 100 moles per gram A phthalic acid residue; 11) 0 to 30 mole % of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and in) 0 to 10 moles. /. An aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 119,732. Doc -111 - 200804457 〇25 to 35 2,2,4,4_tetramethyl-1,3-cyclobutane diacetate residues; 11) 65 to 75 mol% of cyclohexane a dimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the monocarboxylic acid component is 1% mol%, and The total molar % of the diol component is 100 mol%; and Bazhongtian is in 60/40 (heavy 1/weight) phenol/tetrachloroethane at a concentration of ο"g/5 〇ml at 25 ° When measured under C, the inherent viscosity of polyester is 〇6 to 0. 72% gram/gram, and wherein the polyester has 11 〇 to 13 〇. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising : (a) a bismuth acid component comprising: 1) 70 to 1 mole of terephthalic acid residues per mole; ii) 0 to 30 mole % of aromatic dicarboxylic acid residues, Up to 2 carbon atoms; and iii) o to ίο mol% of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) diol components comprising: 1) 25 to 35 moles 2,2,4,4-tetramethyl 4,3-cyclobutane residue; η) 65 to 75 mol% of cyclohexanedimethanol residue; and (II) at least one heat stabilizer, It is selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; 119732. Doc -112- 200804457 wherein the total molar % of the dicarboxylic acid component is 1 〇〇 mol %, and the total molar % of the diol component is 100 mol %; and wherein when it is at 60/40 (weight/weight) In phenol/tetrachloroethane, Yu Yu. At a concentration of 25 g / 5 Torr, the inherent viscosity of the polyester is 〇·6 to 0 when measured at 25 ° C. 72 com/g; and wherein the polyester is in one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: , 0 70 to 1 mole % terephthalic acid residue; ii) 0 to 30 mole % of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 moles ear. / 〇 脂 aliphatic two oxonic acid residues, having a maximum of 16 carbon atoms; and (b) diol components, which comprise: 1) 25 to 35 mol% of 2,2,4,4-tetradecyl- 13·cyclobutanediol residue; ii) 65 to 75 mol% of cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof and a mixture; wherein the total molar % of the dicarboxylic acid component is 100 mol%, and the total molar % of the diol component is 100 mol%; and wherein when 60/40 (w/w) phenol/tetrachloroethylene In the alkane, the inherent viscosity of the polyester is 〇·6 to 0 when measured at 25 ° C at 25 ° C. 72 metrics / gram; and wherein the polyester has 11 〇 to 126. (:: Ding § 119732. Doc-113·200804457 In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 0 70 to 100 moles % of terephthalic acid residues; ii) 0 to 30 moles. /. An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and in) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) an alcohol component, It comprises: i) 25 to 35 mol% of 2,2,4,4·tetramethyl-1,3_cyclobutanediol residues; 11) 65 to 75 moles per hydrazine of cyclohexane a methanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 100 mol%, and the diol component The total molar % is 100% by mole; and wherein, in 60/40 (w/w) phenol/tetrachloroethane, at 25 ° C / 5 〇 ml, at 25 ° C When measured, the inherent viscosity of polyester is 〇6 to 0. 72 com / gram; and wherein the polyester has 11 〇 to 123 cCiTg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 mole % Terephthalic acid residue; 11) 0 to 30 mol% of aromatic dicarboxylic acid residue, having a high of 119,732. Doc -114- 200804457 carbon atoms; and iii) 〇 to 10 mol% of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) diol components comprising: Ο 25 to 35 ear. /〇2,2,4,4-tetramethyl-indole, 3-cyclobutanediol residue; 11) 65 to 75 mol% of cyclohexanedimethanol residue; and (II) to the evening A heat stabilizer, which is selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the one of the ferulic acid components is i 〇〇 mol. /. And the total molar % of the diol component is 100 mol%; and wherein when in 60/40 (w/w) phenol/tetrachloroethane, at a concentration of 〇25 g/5 〇ml 'at 25 When measured at °C, the inherent viscosity of polyester is 〇·6 to 0. 72 metrics / gram; and wherein the polyester has 11 〇 to 12 〇. (1) In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a drum acid component comprising: I) 70 to 100 moles/0 terephthalic acid residue; II) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 2 carbon atoms; and in) 0 to 10 mole % of fat a dicarboxylic acid residue having up to 16 carbon atoms; and (b) an alcohol component comprising: i) 25 to 35 mol% of 2,2,4,4-tetramethyl-1,3 _cyclobutanediol 119732. Doc-115-200804457 Residue; ii) 65 to 75 mol% of cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof One of the total mole % of the 成 文 injury is 1 〇〇 mol %, and the total molar % of the diol component is 100 mol % •, and wherein it is at 60/40 (w/w) phenol/ In the four-gas ethane, Yu Yu. At a concentration of 25 g / 5 Torr, the inherent viscosity of the polyester is 〇·6 to 〇 when measured at 25 °C. 7 metrics / gram; and wherein the polyester has 1 丨〇 to 13 〇. 〇之丁§. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 Torrole/ 0 terephthalic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ιιι) 0 to 10 mol% of an aliphatic dicarboxylic acid residue a base having up to 16 carbon atoms; and (b) a diol component comprising: 1) 25 to 35 mol% of 2,2,4,4-tetramethyl-i,3-cyclobutanediol And ii) 65 to 75 mol% of a cyclohexanedimethanol residue; and (II) at least one thermal stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total amount of ingredients. /. For 1 〇〇 Mo Er. /❶, and the total amount of diol components 119,732. Doc -116- 200804457 The molar % is 100 moles and wherein when it is 6 〇 / 4 〇 (w/w) phenol / tetrachloroethane, at 0. At 25 g / 50 ml / min, the inherent viscosity of the polyester is 0. 6 to 〇·7 com/g; and wherein the polyester has 11 〇 to 128 cC 2 Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 mole % Terephthalic acid residue; 11) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 〇 to 10 mol% of an aliphatic dicarboxylic acid residue, Having a maximum of 16 carbon atoms; and (b) a diol component comprising: i) 2,2,4,4_tetramethyl-1,3_cyclobutanediol residues of 25 to 35 mol/〇 11) 65 to 75 mol% of a cyclohexanedimethanol residue; and (Π) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the dicarboxylic acid component The total mole % is 1 〇〇 Mo Er. /. And the total molar % of the diol component is 100 mol%; and wherein, in 60/40 (w/w) phenol/tetra-ethane, at a concentration of 25 g/5 〇ml, at 25 When measured at °C, the inherent viscosity of polyester is 〇. 6 to 〇·7 com/g; and wherein the polyester has a Tg of l1 (^l26〇c. In one aspect) the invention relates to a polyester composition comprising: 119732. Doc-117-200804457 (i) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 0 70 to 100 mol% of terephthalic acid residues; II) 0 to 30 mol% An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and III) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a yeast ingredient It comprises: 0 25 to 35 mol% of 2,2,4,4-tetramethyl-1,3·cyclobutanediol residue; 1〇65 to 75 mol% of cyclohexanedimethanol residue And (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the monocarboxylic acid component is 1% molar %, and the diol component The total molar/〇 is 100% by mole; and wherein when measured at 25 ° C in a 60/40 (w/w) phenol/tetra-ethane at a concentration of 25 g/5 〇ml When the polyester has an inherent viscosity of 〇_6 to 0. 7 metrics / gram; and wherein the polyester has 11 〇 to 123. Take it easy. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) an acidogenic component comprising: i) from 70 to 100 mol% of para-benzene a dicarboxylic acid residue; ii) an aromatic two-rebel acid residue of up to 30 mol%, having up to 2 carbon atoms; and 119,732. Doc -118- 200804457 iii) 〇 to 10 mol% 夕日匕# Fight. An aliphatic dicarboxylic acid residue having a maximum of 16 carbon atoms; and (b) a drunk component comprising: 1) 25 to 35 mol% of 2, 2, 4, and a tetramethyl 10-3 Cyclobutanediol residue; hexane dimethanol residue; and ii) 65 to 75 moles. a ring-filling compound, and a total (II) of a diol component, at least one heat stabilizer selected from at least a reaction product thereof and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1 〇〇 % of ear, % of mole is 100% by mole; and wherein the field is in 60/40 (heavy summer/weight)/tetrachloroethane, at 0. 25 g (four) liters/min. under the measurement at 25 C, the intrinsic viscosity of 聚·6 to 〇·7 com / gram; and the polyester has 11 〇 to 12 〇. Take it easy. In one aspect, the invention relates to a poly-composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 0 70 to 1 mol% Terephthalic acid residue; 11) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ill) 0 to 10 mol% of an aliphatic dicarboxylic acid residue, Having a maximum of 16 carbon atoms; and (b) a diol component comprising: 1) 25 to 35 mol% of 2,2,4,4-tetramethyl 4,3-cyclobutanediol residues; 119732 . Doc • 119- 200804457 π) 65 to 75 mol% of cyclohexanol dihydric alcohol residue·and (Π) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total molar % of the dicarboxylic acid component is 1% molar %, and the total molar % of the diol component is 100 moles. /. And wherein the intrinsic viscosity of the polyester is 〇 when measured at 25 ° C in 60/40 (w/w) phenol/tetrachloroethane at a concentration of 25 g / 5 Torr. 6 to 0. 68 com / gram; and wherein the polyester has U (^13 (rC2Tg.) In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) two a carboxylic acid component comprising: 1) 70 to 100 moles/0 terephthalic acid residue; η) 0 to 30 mole % of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; And in) 0 to 10 mol% of the aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 1) 25 to 35 mol% of 2, 2, 4 , 4-tetramethyl-1,3-cyclobutanediol residue; π) 65 to 75 mol% of cyclohexanedimethanol residue; and (II) to the kind of thermal stabilizer It is selected from at least one filling compound, a reaction product thereof and a mixture thereof; wherein the total molar % of a slow acid component is 1 (10) mol%, and the total molar % of the diol component is 100 mol%; and 119732. Doc •120· 200804457 Where the intrinsic viscosity of the polyester is measured at 25 ° C in a 60/40 (w/w) phenol/tetrachloroethane at a concentration of 25 g/5 〇ml Hey. 6 to 0. 68 com/g; and wherein the polyester has a Tg of ll (^128 cc. In one aspect, the invention relates to a polyester composition comprising (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 100 mol% of a terephthalic acid residue; η) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; Iii) 0 to 10 mol% of the aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: I) 25 to 35 mol% of 2, 2, 4, 4-tetramethyl-oxime, 3·cyclobutanediol residue; II) 65 to 75 mol% of cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one a phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the two acid retarding components is 100% by mole, and the total molar % of the 2 glycol component is 100% by mole; and wherein the field is 60/40 (weight) 1 / weight of the age / tetrachloroethane, measured at 〇 · 25 g / 5 〇 ml / Hz under 25 C, the inherent viscosity of polyester is 〇 · 6 to 0. 68% gram/gram, and wherein the polyester has from 11 to 126, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: 119732. Doc-121-200804457 (a) a dicarboxylic acid component comprising: an aromatic dicarboxylic acid having a terephthalic acid residue of up to 20 i) 70 to 1 mol%, 11) 0 to 30 mol% a residue, one carbon atom; and iii) o to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 0 25 to 35 mol% 2, 2, 4, tetramethyl heart...cyclobutanediol residue; 11) 65 to 75 mol% of cyclohexane dimethanol residue; and (Π) at least one heat stabilizer, which is selected From at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1% mol%, and the total mole % of the diol component is 100 mol%; and wherein In 60/40 (w/w) phenol/tetrachloroethane, the inherent viscosity of polyester is 〇6 to 0 when measured at 25 °C at a concentration of 〇25 g/5 〇ml. 68 com/g; and wherein the polyester is in one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 1 〇〇 〇 〇 / 〇 terephthalic acid residues; η) 0 to 30 moles. / 〇 芳 aromatic dicarboxylic acid residue, having a height of 2 〇 carbon atoms; and in) 〇 to 1 〇 mol% of aliphatic dicarboxylic acid residues, with a maximum of 16 119,732. Doc -122· 200804457 carbon atoms; and (b) diol component comprising: I) 25 to 35 mol% of 2,2,4,4-tetramethylcyclobutanediol residues; II) 65 Up to 75 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of a ferulic acid component For 1 〇〇 Mo Er. /. And the total molar % of the diol component is 100 mol%; and wherein, in 6 〇 MO (w/w) phenol/tetrachloroethane, at a concentration of 〇·25 g/5 〇ml When measured by 25°CT, the intrinsic viscosity of poly_ is 〇6 to 0. 68 com/g; and wherein the polyester has 11 〇 to 12 〇 c> In one aspect, the invention relates to a polyester composition comprising (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: I) 70 to 1 mole % Terephthalic acid residue; II) 0 to 30 moles. / an aromatic dicarboxylic acid residue having a w 20 carbon atoms; and in) 0 to 10 moles. /. An aliphatic dicarboxylic acid residue having up to Η carbon atoms; and (b) a diol component comprising: 1) 28 to 38 mol% of 2,2,4,4-tetramethyl-1, 3-cyclobutane-containing residue; ii) 62 to 72 mol% cyclohexane dimethanol residue; and 119,732. Doc-123-200804457 (II) to J/ a heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total molar % of the dicarboxylic acid component is 100 mol%, and The total molar % of the alcohol component is 100 mol%; and wherein, in 60/40 (w/w) phenol/tetra-ethane, at 25 gram / 5 liters of the wave, at 25 C When measured, the inherent viscosity of polyester is 〇35 to 1. 2 com / g; and wherein the polyester has 11 〇 to 13 〇. (1: 1) In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 〇〇% by mole of terephthalic acid residues; 11) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 2 carbon atoms; and in) 0 to 10 mole % of fat a dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: i) 28 to 38 mole % of 2,2,4,4-tetramethylcyclobutanediol And ii) a cyclohexane dimethanol residue of 62 to 72 moles per oxime; and a thermal stabilizer which is selected from the group consisting of at least one compound, a reaction product thereof, and a mixture thereof; Wherein the total molar % of the dicarboxylic acid component is i 〇〇 mol %, and the total molar % of the diol component is 100 mol %; and wherein when 60/40 (w/w) phenol/tetrachloroethylene In the alkane, Yu Yu. 25 g/5 〇 119732. Doc • 124 - 200804457 At the time of the rise, the inherent viscosity of the sputum is 〇 5 to a / gram, and the 酉 具有 has a "ο to η. Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a formic acid component comprising: I) 70 to 100 mole percent of terephthalic acid Formic acid residue; II) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ιιι) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having a height of 16 a carbon atom; and (b) a diol component comprising: 0 28 to 38 mol% of a 2,2,4,4-tetramethyl-1,3-cyclobutanediol residue; ii) 62 to 72 mol% of cyclohexane dimethanol residue; and (Π) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total molar % of the dicarboxylic acid component is 1% mol%, and the total molar % of the diol component is 100 mol%; and wherein in 60/40 (w/w) argon/tetrachloroethane, at 0 25 g / 50 ml At the concentration, the inherent viscosity of the polyester is 〇·6 to 0 when measured at 25 °C. 72 com / g; and wherein the polyester has a Tg of 11 〇 to i3 〇 ° C. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 119732. Doc -125- 200804457 i) 70 to 100 mol% of terephthalic acid residues; U) 〇 to 30 mol% of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and 111) 0 to 10 mole % of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 1) 28 to 38 moles of 0/〇 2,2,4,4- a tetramethyl-1,3-cyclobutanediol residue; ii) 62 to 72 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound And a reaction product thereof and a mixture thereof; wherein the total molar % of the monocarboxylic acid component is 1% molar %, and the total molar % of the diol component is 100 mol%; and wherein when at 60/40 (weight) /wt) phenol / tetrachloroethane, at a concentration of 25 g / 5 〇 ml, the inherent viscosity of the polyester measured at 25 ° C is 〇 6 to 〇 · 7 com / g; The polyester has 11 to 13 inches. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a tetacid component comprising: 1) 70 to 100 mole percent para-benzene a dicarboxylic acid residue; ii) an aromatic dicarboxylic acid residue of 0 to 30 moles per hydrazine having up to 2 carbon atoms; and iii) 0 to 1 mole % of an aliphatic di-retensive acid residue , with a maximum of 16 carbon atoms; and 119,732. Doc-126- 200804457 (b) A diol component comprising: 1) 28 to 38 mol% of 2,2,4, tetramethylcyclobutanediol residues; 5 ii) 62 to 72 mol% a cyclohexane dimethanol residue; and (II) at least one type of heat stabilizer 'selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the monocarboxylic acid component is 1〇 〇mol%, and the total molar % of the diol component is 100 mol%; and wherein when in 60/40 (w/w) phenol/tetra-ethane, the concentration is 〇25 g/5 〇ml The polyester has an intrinsic viscosity of from 〇6 to 6868 ng/g when measured at 25 ° C; and wherein the polyester has on one hand the invention relates to a polyester composition comprising: I) at least a polyacetate comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 1 mole % terephthalic acid residue; ii) 0 to 30 mole % aromatic a dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to Μ carbon atoms; and (b) a diol component comprising · 1) 28 to 38 Mo Er 0 / 〇 2, 2, 4, 4- 4 a 1,3-cyclobutanediol residue; ii) 62 to 72 moles per mole of cyclohexane dimethanol residue, and (II) at least one heat stabilizer selected from at least one phosphorus Compound, 119732. Doc -127- 200804457 The reaction product and mixture thereof; wherein the total molar % of the dicarboxylic acid component is 1 〇〇 mol. /. And the total molar % of the diol component is 100 mol%; and wherein when in 60/40 (w/w) phenol/tetra-ethane, in 〇. At a concentration of 25 g / 5 Torr, the inherent viscosity of the polyester is 0 at 25 ° C. 6 to 0. 682 metrics / gram; and wherein the polyester has 11 〇 to 128. The invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) - a tickic acid component comprising: i) 70 to 1 〇〇 mol% of terephthalic acid residues; 11) 0 to 30 mol% of aromatic dicarboxylic acid residues, having up to 2 carbon atoms; and ill) 0 to 10 mol% of fat a dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: i) 28 to 38 mol% of 2,2,4,4_tetradecyl_1,3_ a cyclobutanediol residue; ii) 62 to 72 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof The total molar % of the two acid-lowering components is 1% molar %, and the total molar % of the diol component is 100% by mole; and wherein 60/40 (w/w) phenol/tetrachlorine In ethane, the intrinsic viscosity of polyester is 〇 when measured at 25 ° C under the excitation of 25 g / 5 〇 ml. 6 to 119732. Doc -128- 200804457 0_68Males / gram; and wherein the polyester is on the one hand, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid a composition comprising: 1) 70 to 100 mole % terephthalic acid residue; ii) 0 to 30 mole % of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 Up to 10 mol% of the aliphatic dicarboxylic acid residue having up to 16 atoms broken; and (b) a diol component comprising: i) 28 to 38 mol% of 2,2,4,4-tetra a methyl-1,3-cyclobutanedicarboxylic acid residue; ii) 62 to 72 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, The reaction product and mixture thereof; wherein the total molar % of the dicarboxylic acid component is 1% molar %, and the total molar % of the diol component is 100 mol%; and wherein when it is at 60/40 (weight/ In the weight of the age / tetra-ethane, the inherent viscosity of the polyester is 0 when measured at 25 ° C / 50 ml concentration at 25 ° C. 6 to 0. 68 com / gram; and wherein the polyester has a Tg of 11 〇 to i23 〇 c. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) from 70 to 100 mol% of para-benzene Diterpenic acid residue; 119732. Doc -129- 200804457 ii) 0 to 30 mol% of aromatic dicarboxylic acid residues having up to 2 carbon atoms; and iii) 0 to 10 mol% of aliphatic dicarboxylic acid residues, having a high 16 carbon atoms; and (b)-alcohol component comprising: 0 28 to 38 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; ii) 62 Up to 72 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total molar amount of the dicarboxylic acid component % is 1 〇〇 Mo Er. /. And the total molar % of the diol component is 100 mol%; and wherein, in 60/40 (w/w) phenol/tetra-ethane, at a concentration of 25 g/5 〇ml, at 25 When measured at °C, the inherent viscosity of polyester is 〇. 6 to 0. 68 metrics / gram, and wherein the polyester has 11 〇 to 12 〇. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 1 Torrole/ a terephthalic acid residue of 0; ii) 0 to 30 mole % of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 moles. /. An aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 119732. Doc -130- 200804457 i) 30 to 35 mol% of 2,2,4,4 tetramethyl·匕^cyclobutanediol residues; 11) 65 to 70 mol% of cyclohexanedimethanol residue And (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the one carboxylic acid component is i 〇〇 mol%, and the diol component The total molar % is 100% by mole; and wherein when measured at 25 ° C in 60/40 (w/w) phenol/tetrachloroethane at a concentration of 25 g/5 〇 ml, The inherent viscosity of polyester is 0. 35 to 1. 2 com / gram; and wherein the polyester has 11 〇 to 13 & gt. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a formic acid component comprising: Ο 70 to 100 moles/0 pair a phthalic acid residue; η) an aromatic dicarboxylic acid residue of 0 to 30 moles per hydrazine having up to 2 carbon atoms; and an) an aliphatic dicarboxylic acid residue having a enthalpy to 1 mole % a base having up to 16 carbon atoms; and (b) a diol component comprising: 〇30 to 35 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues And ii) 65 to 70 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; 119,732. Doc -131- 200804457 wherein the total molar % of the dicarboxylic acid component is 1% mol%, and the total molar % of the diol component is 100 mol%; and wherein when 60/40 (w/w) In phenol/tetra-ethane, at 0. At a concentration of 25 g / 50 ml, the inherent viscosity of the polyester is 0. 35 to 1. 2 com / gram; and wherein the poly g has a range of 11 〇 to 128. 〇之丁§. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 mole % a terephthalic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 20 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having Up to 16 carbon atoms; and (b) a diol component comprising: 1) 30 to 35 moles. 2,2,4,4-tetramethyl-1,3-cyclobutanediol residue; ii) 65 to 70 mol% of cyclohexanedimethanol residue; and (II) at least one heat a stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of a slow Ssc wound is 1% molar %, and the total molar % of the diol component is 100% Ear %; and wherein when measured at 25 ° C in 60/40 (w/w) phenol/tetra-ethane at a concentration of 25 g/5 〇 ml, the inherent viscosity of the polyester is 〇 . 5 to 1. 2 com / gram, and wherein the polyester has 11 〇 to 13 〇. Tg of Tg. 119732. Doc-132.200804457 In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyglycol comprising: (a) a phthalic acid component comprising: 1) 70 to 100 Molybdenum/0 terephthalic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ill) 0 to 10 mol% of aliphatic a dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: i) 3 to 35 mol% of 2,2,4,4-tetramethyl-1,3- a cyclobutanediol residue; Π) 65 to 70 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total molar amount of the dicarboxylic acid component. /. For 1 〇〇 Mo Er. And the total molar % of the diol component is 100 mol%; and wherein when in 60/40 (w/w)/four gas, at a concentration of 〇25 g/5 〇ml When measured at 25 °C, the inherent viscosity of polyester is 〇·5 to 1. 2 metrics/gram; and wherein the polyester has 11 to 128. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 Torrole/ 0 terephthalic acid residue; ii) 0 to 30 mol% of aromatic dicarboxylic acid residue, having a maximum of 2〇119732. Doc • 133- 200804457 carbon atoms; and 111) 0 to 10 mol% of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) diol components comprising: I) 30 to 35 Molar % of 2,2,4,4·tetramethyl-1,3-cyclobutanediol residue; II) 65 to 70 mol% of cyclohexanedimethanol residue; and (II) at least one a heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1% mol%, and the total mole % of the diol component is 1 〇 〇mol%; and wherein the intrinsic viscosity of the polyester is measured at 25 ° C at a concentration of 25 g / 〇 50 ml in 60 / 40 (w/w) phenol / tetrachloroethane Why? 5 to 1. 2 com / gram; and wherein the polyester has 11 〇 to 126. 〇之丁邑. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a phthalic acid component comprising: i) 70 to 1 Torrole/ Terephthalic acid residues; η) 0 to 30 moles. /. An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and in) 0 to 10 moles per gram. An aliphatic dicarboxylic acid residue having up to Μ carbon atoms; and (b) a diol component comprising: 1) 30 to 35 mol% of 2,2,4,4-tetramethyl-1, 3_cyclobutanediol 119732. Doc-134-200804457 Residue; H) 65 to 70 mol% of cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, its reaction product and mixtures thereof ; the total molars of diwei acid components. /. It is 100 mol%, and the total mole % of the diol component is 100 mol. /. And wherein the inherent viscosity of the polyester is 〇 when measured at 25 ° C in 60/40 (w/w) phenol/tetrachloroethane at a concentration of 25 g / 5 〇 liter. 5 to 1. 2 com/g; and wherein the sputum has a Tg of ι1〇 to mi. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 Torrole/ 0 terephthalic acid residue; η) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of aliphatic dicarboxylic acid residues a base having up to 16 carbon atoms; and (b) a diol component comprising: I) 30 to 35 moles. /〇2,2,4,4_tetradecyl-1,3_cyclobutanediol residue; ii) 65 to 70 mol% of cyclohexanedimethanol residue; and (II) at least one heat a stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the two retinoid components is 1% molar %, and the total diol component is 119732. Doc -135· 200804457 The molar % is 1 〇〇 mol and it is in 60/40 (w/w) phenol/tetrachloroethane at a concentration of 25 g / 50 ml at 25 ° C When measured, the inherent viscosity of the polyester is 0. 5 to 1. 2 com / gram; and wherein the polyester has a Tg of U (^i2〇〇c. In one aspect, the invention relates to a polyester composition comprising (I) at least one polyester comprising (a) a dicarboxylic acid component comprising: i) 70 to 1 mole % of terephthalic acid residues; H) 0 to 30 mole % of aromatic dicarboxylic acid residues, up to 20 a carbon atom; and ui) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) an alcohol component comprising: i) 3 to 35 mol% 2,2,4,4-tetramethyl-1,3·cyclobutanediol residue; Π) 65 to 70 mol% of cyclohexanedimethanol residue; and (II) at least one heat stabilizer It is selected from at least one phosphorus compound, its reaction product, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 1% molar %, and the total mole % of the diol component is 100 moles. /〇; and which is in 60/40 (w/w) phenol/tetrachloroethane, in 〇. The inherent viscosity of polyester is 0. When measured at 25 C under 25 g/5 〇 liters. 6 to 〇·72 com/g; and the polyester has 11 〇 to 13 〇. (:: 1^. In one aspect, the invention relates to a polyester composition comprising: 119732. Doc -136- 200804457 (i) At least one poly, comprising: (a) - a few acid components comprising: I) 70 to 1 mole % terephthalic acid residue; II) 0 to 30 Moor. /. An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and III) up to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) an alcohol component, It comprises: 0 30 to 35 mol% of 2,2,4,4_tetramethyl-1,3_cyclobutane diacetate residue; 11) 65 to 70 mol% of cyclohexane dimethanol residue And () to a thermal stabilizer, which is selected from at least one scaly compound, a reaction product thereof, and a mixture thereof; wherein the total mole of the monocarboxylic acid component. /❶ is 丄〇〇mol%, and the total molar % of the diol component is 100% by mole; and wherein when in 60/40 (w/w) phenol/tetra-ethane, in 〇25 g At a concentration of /5 〇 ml, at 25. (: When measured, the inherent viscosity of polyester is 〇 6 to 0. 72 metrics / gram, and wherein the polyester has 11 〇 to 128. 〇之丁§. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a diacid component comprising: I) from 70 to 100 mole percent Phthalic acid residues; II) 〇 to 30 moles. / ❶ 芳 aromatic two rebel acid residues, with a maximum of 2 碳 carbon atoms; and 119,732. Doc -137· 200804457 iii) 0 to 10 moles / 〇 放 — - 曰 曰 一 羧酸 羧酸 羧酸 , 具有 具有 具有 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸 羧酸2%, 2, 4, 4%, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4, 4 The heat stabilizer, the complex will be white, you will come from at least one phosphorus compound, its reaction products and mixtures thereof; the total molar % of the dicarboxylic acid component is ηηπ 曾甘0/ α ^ L v "six 7 / 0 fishing U) 0 mo 〇 / 〇, and the total molar % of the diol component is 100 mol %; and wherein when in 60 / 40 (w/w) phenol / tetrachloroethane, in 〇 25 g At a concentration of /5 〇 ml, the inherent viscosity of polyester is 〇 when measured at 25 °C. 6 to 0. 72 com/g; and wherein the polyester has a Tg of 11 (^126 〇c. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a a dicarboxylic acid component comprising: I) 70 to 1 Torrole/0 terephthalic acid residue; II) 0 to 30 mole % of an aromatic dicarboxylic acid residue having a maximum of 2 One carbon atom; and in) 0 to 10 mol% of the aliphatic dicarboxylic acid residue 'having a maximum of 16 carbon atoms; and (b) a diol component containing 1 · 3) to 35 mol % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residue; 119,732. Doc -138· 200804457 Π) 65 to 70 mol% of cyclohexane dimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The total mole % of the carboxylic acid component is 1% mol%, and the total mole % of the diol component is 100 mol%; and wherein when it is in 60/40 (w/w) phenol/tetrachloroethane , at a concentration of 25 g / 50 ml at a concentration of '50 ° C, the inherent viscosity of the polyester is 〇 · 6 to 〇 · 72 com / g; and the polyester has ^ 岐 ^ generation In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: I) 70 to 1 Torrole /〇 terephthalic acid residue; II) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and in) 0 to 10 mol% of aliphatic dicarboxylic acid a residue having up to 16 carbon atoms; and (b) a diol component comprising: Ο 30 to 35 mol% of 2,2,4,4-tetramethyl", 3_cyclobutanediol residue ; 11) 65 to 70 mol% of cyclohexane An alcohol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound's reaction product and a mixture thereof; wherein the total mole (10) mole % of the two (four) components, and the total amount of the diol component The ear % is 100% by mole; and ~ 119732. Doc -139- 200804457 Where, when measured at 25 ° C in 6 〇 / 4 〇 (w/w) phenol / tetrachloroethane at a concentration of 25 g / 5 〇 ml, The intrinsic viscosity is 〇6 to 〇. 72 a / gram, and wherein the polyester has up to 12 〇. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a phthalic acid component comprising: I) 70 to 1 Torr% Terephthalic acid residue; II) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to one carbon atom; and III) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having a high 16 carbon atoms; and (b) a diol component comprising: Ο 30 to 35 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; η) 65 Up to 70 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, < a reaction product thereof and a mixture thereof; wherein the total amount of the dicarboxylic acid component is The ear % is 1% molar %, and the total mole % of the diol component is 100 moles. /. And wherein the inherent viscosity of the polyester is 0. When measured at 25 ° C in 60/40 (w/w) phenol/tetrachloroethane at a concentration of 25 g / 5 Torr. 6 to 0. 68 com / gram; and wherein the polyester has 11 (^13 〇〇 C2Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: 119732. Doc-140- 200804457 (a) A dicarboxylic acid component comprising: i) from 7 to 100 mol% of terephthalic acid residues; u) from 0 to 30 mol% of aromatic dibasic acid residues, An aliphatic dicarboxylic acid residue having up to 2 carbon atoms; and 0 to 10 mol%, having up to 16 carbon atoms; and (b) a diol component comprising: 〇30 to 35 m . /.七) 65 二 二 ; ;; ii) 65 to 70 mol% of cyclohexane dimethanol residue; and (II) at least one heat stabilizer selected from at least one a phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total molar % of the monocarboxylic acid component is 100 mol%, and the total molar % of the diol component is 100 mol%; and wherein when 6_(4 amount / Weight, four gas in the burning, in G. 25 g / 50 liters of the wave 'measured at 25 C, the inherent viscosity of the poly g is 〇 · 6 to 0. 68 metrics/gram; and wherein the polyester has 128 to 13 inches. 〇之丁@. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) an acid-reactive component comprising: i) from 70 to 100 mol% of para-benzene Dicarboxylic acid residue; η) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and in) 〇 to 10 mol. /. An aliphatic dicarboxylic acid residue having a maximum of 16 119,732. Doc -141 - 200804457 carbon atoms; and (b) diol component comprising: 0 30 to 35 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanedifluoride residues And II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the dicarboxylic acid component The total molar % is 1% mol%, and the total molar % of the diol component is 100 mol%; and wherein when 60/40 (w/w) phenol/tetrachloroethane, in 〇25 The intrinsic viscosity of the polyester is 〇·6 to 68·68 com/g when measured at 25 ° C, and the polyester has 11 〇 to 126 QC 2 Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 Torrole/ 0 terephthalic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and III) 0 to 10 mol% of aliphatic dicarboxylic acid residue a base having a highest carbon atom; and (b) a diol component comprising: 1) 30 to 35 mol% of 2,2,4,4-tetramethyl-, i-cyclobutane ; Π) 65 to 70 mol% of cyclohexane dimethanol residue; and 119,732. Doc-142-200804457 (II) At least a heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the two acid retarding components is! (10) % by mole, and the total amount of diol components is mol/°. 100% by mole; and which is in the 60/4G (w/w, tetrachloroethylene, at a concentration of 0 25 g / 5 〇 ml, at 25 ° (: The viscosity is 〇·6 to 68·68 com / gram; and wherein the polyester has a 〇 to 123 艺 ^. In one aspect, the invention relates to a polyester composition comprising (I) at least A polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 mole of terephthalic acid / hydrazine terephthalic acid residue; ii) 0 to 30 mole % of aromatic a dicarboxylic acid residue having up to 2 carbon atoms; and iii) o to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 1) 30 to 35 mol% of 2,2,4,4-tetradecyl_1,3_cyclobutanediol residue; π) 65 to 70 mol% of cyclohexanedimethanol residue; And (Π) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1% molar %, and the total of the diol components Molar% is 100% by mole; and where is at 60/40 (weight/weight ) Phenol / tetrachloroethane at square 25 g / ml 5〇 119,732. Doc -143- 200804457 At a concentration of liter, the inherent viscosity of polyester is 〇 6 to 0 when measured at 25 ° C. 68 com/g; and wherein the polyester is in one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a phthalic acid component comprising: I) 70 to 1 〇〇 〇 〇 / 〇 terephthalic acid residues; II) 0 to 30 mole % of aromatic dicarboxylic acid residues, having up to 2 carbon atoms; and III) 0 to 10 mole % of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: i) 30 to 40 mole % of 2,2,4,4-tetra a 1,3-cyclobutanediol residue; Π) 60 to 70 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, The reaction product and the mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1% by mole, and the total mole % of the diol component is 100 moles. /〇; and wherein when in 60/40 (weight/weight) age / tetrachloroethane, at 0. At a concentration of 25 g / 50 ml, the inherent viscosity of the polyester is 0. 35 to 12 com/g; and wherein the polyester has a Tg of 110 to 130 °C. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 119732. Doc -144- 200804457 1) 70 to (10) mole % terephthalic acid residues; η) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 2 carbon atoms; and 111) 0 Up to 10 mol% of aliphatic dicarboxylic acid residues having up to 16 stone atoms; and (b) drunk ingredients comprising: 1} 3 〇 to 40 摩尔 0 / 〇 2, 2, 4 , 4·tetradecyl-1,3-cyclobutanediol residue; ii) 60 to 70 mol% of cyclohexanedimethanol residue; and (II) to v-type heat stabilizer, which is selected From at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the di-m acid component is just Momon%, and the total molar amount of the diol component is 1 Torr. /. And where is in 60/40 (w/w) phenol/tetrachloroethane, in 〇. At 25 g/5 〇 liter/min, the inherent viscosity of polyester is 〇 when measured at 25 C. 35 to 1. 2 com / gram; and wherein the polyester has 11 〇 to 128 of it. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 0 70 to 100 mol% of p-benzoic acid a formic acid residue; ii) an aromatic dicarboxylic acid residue of up to 30 mol%, having up to 2 carbon atoms; and ui) 〇 to 10 mol% of an aliphatic dicarboxylic acid residue, up to 16 One carbon atom; with 119732. Doc -145- 200804457 (b) a diol component comprising: I) 30 to 4 mole % of 2,2,4,4-tetramethyl-1,3_cyclobutanediol residues; II) 60 to 70 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total molar amount of the dicarboxylic acid component % is i 〇〇 mol%, and the total molar % of the diol component is 100 mol%; and wherein when 60/40 (w/w) phenol/tetrachloroethane, 〇25 g/5 At a concentration of 〇ml, the inherent viscosity of the polyester is 〇5 to 1. 2 com / gram; and wherein the polyester has 11 〇 to 13 〇 1 of it. In one aspect, the invention is directed to a polyester composition comprising: (I) at least one polyester comprising: (a) a retinoid component comprising: I) from 70 to 100 mole percent of para-benzene a dicarboxylic acid residue; ii) an aromatic dicarboxylic acid residue of up to 30 mol%, having up to one carbon atom; and in) an aliphatic dicarboxylic acid residue of from 10 mol%, up to Μ a carbon atom; and (b) a diol component comprising: 0 30 to 40 mol% of 2,2,4,4_tetramethyl core, % cyclobutane residue; ^ II) 60 to 7 〇 mo 5% by weight of cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, 119,732. Doc -146 - 200804457 The reaction product and mixture thereof; wherein the total mole % of a citric acid component is 1 〇〇 mol %, and the total molar % of the diol component is 100 mol %; and wherein /40 (W/W) Phenol/Tetrachloroethane, under the hardness of 25 g/5 〇ml, the inherent viscosity of polyester is 〇·5 to 1.2·2 when measured at 25 °C In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 70 to 100 mol% of terephthalic acid residues; ii) 0 to 30 mol% of aromatic dicarboxylic acid residues having up to 2 carbon atoms; and iii) up to 10 mol% An aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a drunk component comprising: i) 30 to 40 mol% of 2,2,4,4-tetradecyl-1,3 a cyclobutanediol residue; Π) 60 to 70 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof ; the total of the two components of the acid The mole % is 1 〇〇 mole y. And the total molar % of the diol component is 100 mol%; and wherein when in 60/40 (w/w) phenol/tetrachloroethane, in 〇. At a concentration of 25 g / 5 Torr, the inherent viscosity of the polyester is 〇 5 to 119,732 when measured at 25 ° C. Doc -147- 200804457 1. 2 com/g; and wherein the polyester has a Tg of 11 〇 to 126. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 1 mole % Terephthalic acid residue; η) 0 to 30 moles /. An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and li) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component, It comprises: Ο 30 to 40 mol% of 2,2,4,4-tetradecyl-1,3-cyclobutanediol residues; η) 60 to 70 mol% of cyclohexanedimethanol residue And (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of a tannic acid damage is 10% molar %, and the diol component The total molar % is 100% by mole; and wherein it is determined at 25 ° C in 60/40 (w/w) phenol/tetra-ethane at a concentration of 25 g/5 〇ml When the polyester has an inherent viscosity of 0. 5 to 1.2 cm / gram; and wherein the polyester has a Tg of 11 to 123. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 100 mole percent Phthalic acid residue; 119732. Doc -148· 200804457 11) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ιιι0 to 10 mol% of an aliphatic dicarboxylic acid residue having a high 16 carbon atoms; and (b) a diol component comprising: I) 30 to 40 mol% of 2,2,4,4-tetramethyl-i,3-cyclobutanediol residues; II) 60 to 70 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; The ear % is i 〇〇 mol %, and the total molar % of the diol component is 100 mol %; and it is prepared in 60/40 (w/w) phenol/tetrachloroethane at 25 g/ The inherent viscosity of the polyester is 〇5 to 1, 2 com/g when measured at 25 ° C/min; and the polyester has 110 to 120. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a formic acid component comprising: 0 70 to 1 〇〇 a terephthalic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) up to 10 mol% of fat a dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 119732. Doc -149- 200804457 Ο 30 to 40 mol% of 2,2,4,4_tetramethyl ο)-cyclobutanediol residue; Π) 60 to 70 mol% of cyclohexane dimethanol residue And (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1% by mole, and the diol component is The total molar % is 100% by mole; and wherein when measured at 25 ° C in 60/40 (w/w) phenol/tetra-ethane at a concentration of 25 g/5 〇 ml, The inherent viscosity of the polyester is from 〇6 to 0·72 com/g, and wherein the polyester has in one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising (a) a dicarboxylic acid component comprising: i) 70 to 1 mole % terephthalic acid residue; η) 0 to 30 mole % of an aromatic dicarboxylic acid residue having a maximum of 2 〇 one carbon atom; and iii) 0 to 10 mol% of the aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: i) 3 〇 to 40 mol% 2,2,4,4-tetramethyl-1,3-cyclobutanediol Group; ii) 60 to 70 mole square / square of cyclohexanedimethanol residues; and (II) at least one thermal stabilizer selected from at least one compound Lin, reaction products thereof, and mixtures thereof; 119,732. Doc -150- 200804457 The total mole of one of the carboxylic acid components. /. It is i 00 mol %, and the total molar % of the diol component is 100 mol %; and wherein when it is 60/40 (w/w) phenol/tetra-ethane, it is 0. At a concentration of 25 g / 50 ml, the inherent viscosity of the polyester is from 0.6 to 0 when measured at 25 ° C. 72 com / gram; and wherein the polyester has "" to "in one aspect" the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: I) 70 to 1 〇〇mole/〇 terephthalic acid residue; II) 0 to 30 mol% of an aromatic dicarboxylic acid residue having a maximum of 2〇 a carbon atom; and ill) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) an alcohol component comprising: I) 30 to 40 mol% of 2 , 2,4,4-tetramethyl-1,3-cyclobutanediol residue; II) 60 to 70 mol% of cyclohexanedimethanol residue; and (II) at least one heat stabilizer, Is selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the monocarboxylic acid component is 1% mol%, and the total mole % of the diol component is 100 mol%; When measured at 25 ° C in 60/40 (w/w) phenol/tetrachloroethane at a concentration of 25 g / 5 〇 ml, the inherent viscosity of the polyester is 〇 6 to 0. 72 metrics / gram, and the polyester has 11 〇 to 126 of it 119732. Doc-151-200804457 In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 〇 〇 mol % terephthalic acid residue; ii) 0 to 30 mol % of an aromatic dicarboxylic acid residue having up to 20 carbon atoms; and iii) 〇 to 10 mol % of aliphatic dicarboxylic acid An acid residue having up to 16 carbon atoms; and (b) a diol component comprising: i) 3 to 40 mol% of 2,2,4,4-tetradecyl-1,3_cyclobutane a diol residue; ii) 60 to 70 mol% of a cyclohexanedimethanol residue; and (ii) a heat-sensitive, tanning agent selected from at least one of a compound, a reaction product thereof, and a mixture thereof; The total mole % of the diterpenic acid component is 100 moles. /❶, and the total molar % of the diol component is 100 mol%; and wherein when in 60/40 (w/w) phenol/tetra-ethane, at a concentration of 〇25 g/5 〇ml' When measured at 25 ° C, the intrinsic viscosity of the polyester is from 〇·6 to 72·72 com/g; and wherein the polyester has a 〇 to l23 〇c. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 1 mole % Terephthalic acid residue; ii) 0 to 30 mol% of aromatic di-retensive acid residues, with a maximum of 2〇119732. Doc • 152 · 200804457 carbon atoms; and iii) 〇 to 1 mole % of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) diol components comprising: i) 30 to 40 mol% of 2,2,4,4_tetradecyl^^-cyclobutanediol residues; ii) 60 to 70 mol% of cyclohexanedimethanol residue; and (II) at least one heat a stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is! 〇〇 mol%, and the total mole % of the diol component is 100 moles. /. And wherein when measured at 25 ° C in 60/40 (w/w) phenol/tetra-ethane at a concentration of 25 g / 5 〇 ml, the inherent viscosity of the polyester is 〇6 to 0. 72 metrics / gram, and wherein the polyester has 11 〇 to 12 〇. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 mole % Terephthalic acid residue; II) 0 to 30 moles /. An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and III) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) an alcohol component, It comprises: 1) 3〇 to 40 mol% of 2,2,4,4_tetramethyl-1,3-cyclobutanediol 119732. Doc-153-200804457 Residue; ii) 60 to 70 mol% cyclohexane dimethanol residue; and (II) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixture thereof The total mole % of the dicarboxylic acid component is 1% by mole, and the total mole % of the diol component is 100 moles. /. And wherein the inherent viscosity of the polyester is 0. When measured at 25 ° C in 60/40 (w/w) / tetrachloroethane, at a concentration of 25 g / 50 ml. 6 to 0. 68 metrics / gram; and wherein the polyester has 11 〇 to 13 〇. [Ding §. In one aspect, the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 1 Torrole/ 0 terephthalic acid residue; ii) 0 to 30 mol% of aromatic diacidic acid residue having up to 20 carbon atoms; and iii) 0 to 10 mol% of aliphatic dicarboxylic acid residue , having a maximum of 16 carbon atoms; and (b) a diol component comprising: i) 30 to 40 moles per gram of tetradecyltetramethyl-indolecyclobutanediol residue; ii) 60 to 70 mol% of a cyclohexanedimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is I00% by mole, and the total amount of diol components is 119,732. Doc -154· 200804457 Mo % is 100 mol %; and wherein, in 60/40 (w/w) phenol/tetrachloroethane, at a concentration of 25 g/5 〇ml, at 25. (In the measurement, the inherent viscosity of the polyester is 〇·6 to 〇68 com/g; and wherein the polyester has 11 〇 to 128. The Tg of 〇. In one aspect, the invention relates to a polyester combination. And comprising: (I) at least one polyester comprising: (a) a dicarboxylic acid component comprising: 1) 70 to 100 mol% of terephthalic acid residues; / · Π) 0 to 30 mole % of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ill 0 to 10 mole % of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: Ο 30 to 40 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residue; Π) 60 to 70 mol% of cyclohexane a dimethanol residue; and (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total molar percentage of the dicarboxylic acid component is 100 mol%, and the diol The total molar % of the ingredients is 100 mol%; and wherein it is determined at 25 ° C at a concentration of 25 g / 〇 〇 60 in 60/40 (w/w) phenol / tetra-ethane. When the polyester has an inherent viscosity of 〇6 to 0. 68 metrics/gram, and wherein the polyester has 11 to 126. Tg of Tg. In one aspect, the invention relates to a polyester composition comprising: 119732. Doc • 155- 200804457 (i) at least one polyester comprising: (a) a dicarboxylic acid component comprising: i) 70 to 100 mole % terephthalic acid residues; 11) 0 to 30 moles . /. An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and in) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component, It comprises: Ο 30 to 40 mol% of 2,2,4,4-tetramethyl-1,3_cyclobutane diacetate residue; 11) 60 to 70 mol% of cyclohexanedimethanol residue And (II) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total mole % of the dicarboxylic acid component is 1% by mole, and the diol component is The total molar % is 100% by mole; and wherein it is in 60/40 (w/w) phenol/tetra-ethane, in 〇. At a concentration of 25 g / 5 Torr, the inherent viscosity of the polyester is 〇 when measured at 25 ° C. 6 to 0. 68 com/g; and wherein the polyester has 11 〇 to ". In one aspect" the invention relates to a polyester composition comprising: (I) at least one polyester comprising: (a) - a slow acid component comprising: 1) 70 to 100 mole % terephthalic acid residues; η) 〇 to 30 moles / of an aromatic dicarboxylic acid residue having up to 2 carbon atoms ; and 119732. Doc -156.  200804457) 0 to 10 moles of aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) diol component comprising: 〇3〇 to 4G mol% of 2,2,4,4 a methyl-1,3-cyclobutanediol residue; (1) 6 〇 to 7 〇 mol% of a cyclohexanol bis-alcohol residue; and (II) at least one heat stabilizer, a potlet/, selected from At least one phosphorus compound, a reaction product thereof, and a mixture thereof; wherein the total molar amount of the molybdenum component is (10) mol%, and the total molar % of the diol component is 100 mol%; and "wherein at 6 coffees (weight/ Re-invited / tetrachloroethane, at 0. At 25 g / 50 ml, the inherent viscosity of poly_ is 〇·6 to 〇·68 com/g when measured at 25 ° C; and the vinegar has ιι〇 to 12 generations The present invention relates to a process for the manufacture of any of the polyesters suitable for use in the present invention, comprising the steps of: (I) at least one temperature selected from 15 Å to 25 (rc) and from 〇 to 75 psig to the previous Heating a mixture under pressure, wherein the mixture comprises: (a) a dicarboxylic acid component comprising: i) 70 to 100 mole % terephthalic acid residues; 11) 0 to 30 moles per gram. An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component, It contains: 119732. Doc -157- 200804457 i) 1 to 99 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and ii) 1 to 99 mol% of cyclohexane a dimethanol residue; wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is 1·0·1·5/1. 〇; wherein the mixture in step (I) is heated in the presence of (i) at least one catalyst comprising at least one tin compound, and, if desired, at least one selected from the group consisting of titanium, gallium, zinc, bismuth, cobalt a catalyst of manganese, magnesium, lanthanum, lithium, an aluminum compound and an aluminum compound with lithium hydroxide or sodium hydroxide; and (Π) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof (II) The product of step (I) is at a temperature of from 230 to 320 ° C and at least one is selected from the final pressure from step (I) to 〇. Heating at a pressure within the range of 托 2 Torr (absolute pressure) for 1 to 6 hours to form a final polyester; wherein the total mole % of the dicarboxylic acid component of the final polyester is 1 〇〇 mol %, and the final The total molar % of the diol component of the polyester is 1 〇〇mol/〇' which is in the concentration of 〇·25 g/50 ml in 60/40 (w/w) phenol/tetra-ethane. When measured at 251, the intrinsic viscosity of the final polyester is 0. 35 to 1. 2 metrics/gram; and wherein the final polyester has a Tg of 85 to 200 °C. In one aspect, the invention relates to a method of making any of the polyesters suitable for use in the present invention comprising the steps of: (I) at a temperature selected from the group consisting of at least 150 to 250 ° C and selected from the group consisting of 〇 to 75 psig. 119732. Doc 200804457 heating a mixture at least under pressure, wherein the mixture comprises (a) a phthalic acid component comprising: 1) 70 to 100 mole % terephthalic acid residues; ii) 0 to 30 moles % of an aromatic diterpene acid residue having up to 2 carbon atoms; and iii) up to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol a composition comprising: i) from 1 to 99 mol% of a 2,2,4,4-tetradecyl-1,3-cyclobutanediol residue; and ii) from 1 to 99 mol% of cyclohexane a dimethanol residue; wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is 1. 05-1. 15/1. 0; wherein the mixture in step (I) is heated in the presence of (i) at least one catalyst comprising at least one tin compound, and, if desired, at least one selected from the group consisting of titanium, gallium, zinc, bismuth, cobalt , a catastrophe, a sulphur, a sulphur, a sulphur, a sulphur, a sulphur, a sulphuric acid, a catalyst, and a mixture thereof; and (ii) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof (Π) heating the product of step (I) at a temperature of from 230 to 320 ° C and at least one pressure selected from the final pressure of step (I) to a pressure within the range of 0.0002 Torr (absolute pressure) for 1 to 6 hours To form a final polyester; wherein the total mole % of the dicarboxylic acid component of the final polyester is 100 moles 119,732. Doc •159- 200804457%, and the total molar % of the diol component of the final polyester is 1% mol%, wherein in 60/40 (w/w) phenol/tetrachloroethane, at 0 . At a concentration of 25 g / 50 ml, the intrinsic viscosity of the final IS 〇 is 〇 35 to 1. 2 metrics/gram; and wherein the final polyester has a Tg of 85 to 200 °C. In one aspect, the invention relates to a method of making any of the polyesters suitable for use in the present invention, comprising the steps of: (I) at a temperature selected from the group consisting of at least 150 to 250 ° C and selected from the group consisting of 〇 to 75 psig. Heating a mixture under at least one pressure, wherein the mixture comprises: (a) a dicarboxylic acid component comprising: i) 70 to 1 mole % terephthalic acid residue; ii) 0 to 30 moles /. An aromatic diterpene acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component, It comprises: i) from 1 to 99 mol% of 2,2,4,4-tetramethyl·1,3-cyclobutanediol residues; and ii) from 1 to 99 mol% of cyclohexanedimethanol Residue; wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is 1.0·1. 5/1. 0; wherein the mixture in the step (I) is heated in the presence of: (i) at least one catalyst comprising at least one tin compound, and, if desired, at least one selected from the group consisting of titanium, gallium, yttrium, lanthanum, cobalt , 119732. Doc 200804457 Clock, Magnesium, Strontium, Bell, Ming Compound and Ming Compound with Hydrogen Chloride or Hydrogen Oxide, Sodium Catalyst; (II) The product of step (I) at a temperature of 230 to 320 ° C, at least one choice Since the final pressure of step (I) to 0. Heating in the presence of a pressure in the range of 02 Torr (absolute pressure) and at least one heat stabilizer selected from at least one scaly compound, a reaction product thereof, and a mixture thereof for 1 to 6 hours; wherein the dicarboxylic acid component of the final polyester The total molar % is 1% mol%, and the total molar % of the diol component of the final polyester is 1% mol%; wherein when 60/40 (w/w) phenol/four gas B In the alkane, the intrinsic viscosity of the final polyester is 0. at a concentration of 25 g / 50 ml at 25 ° C. 35 to 1. 2 metrics/gram; and wherein the final polyester has a Tg of 85 to 200 °C. In one aspect, the invention relates to a method of making any of the polyesters suitable for use in the present invention, comprising the steps of: (I) at a temperature selected from the group consisting of at least 150 to 250 ° C and selected from the group consisting of 〇 to 75 psig. Heating a mixture under at least one pressure, wherein the mixture comprises: (a) a dicarboxylic acid component comprising: 0 70 to 1 mol% of terephthalic acid residues; ii) 0 to 30 mol% An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to Μ carbon atoms; and (b) a diol component Contains: 0 1 to 99 mol% of 2,2,4,4·tetramethylcyclobutanediol 119732. Doc 161 - 200804457 Residue; and ii) 1 to 99 mol% of cyclohexanedimethanol residue; wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is 1 〇 5_1·15/1·〇; wherein the mixture in the step (I) is heated in the presence of at least one catalyst comprising at least one tin compound, and 'optionally at least one selected from the group consisting of titanium and gallium. a catalyst for the preparation of ruthenium, manganese, magnesium, ruthenium, lithium, aluminum compounds and aluminum compounds with lithium hydroxide or sodium hydroxide; (II) the product of step (I) at 230 to 32 (temperature of rc, at least one choice) Heating from the final pressure of step (I) to a pressure in the range of 0 02 Torr (absolute pressure) and at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, its reaction product and mixtures thereof for 1 to 6 hours; The total mole % of the dicarboxylic acid component of the final polyester is 100% by mole' and the total molar % of the diol component of the final polyester is 1% by mole, wherein at 60/40 (weight) /wt) phenol / tetrachloroethane, at a concentration of 〇 · 25 g / 50 ml, under it When measured, the intrinsic viscosity of the final polyester is 〇. 35 to 12 com/g; and wherein the final polyester has a Tg of 85 to 200 °C. In one aspect, the invention relates to a method of making any of the polyesters suitable for use in the present invention, comprising the steps of: (I) at a temperature selected from the group consisting of at least 150 to 250 ° C and selected from the group consisting of 〇 to 75 psig. To: heating a mixture under pressure, wherein the mixture comprises: (a) - a few acid components, comprising: 119,732. Doc -162- 200804457 Ο 70 to 100 mol% of terephthalic acid residues; 1 〇〇 to 3 〇 mol% of aromatic dicarboxylic acid residues: &, having up to 2 carbon atoms; and 111 a fatty acid residue of 0 to 1 mol%, having a maximum of 16 carbon atoms; and (b) a diol component comprising: I) 1 to 99 mol% of 2, 2, 4, 4-tetramethyl-1,3-cyclobutanediol residue; and II) 1 to 99 mol% of cyclohexanedimethanol residue; wherein the diol component/dicarboxylate added in step (I) The molar ratio of the acid component is 1. 0-1. 5/1. 0; wherein the mixture in step (I) is heated in the presence of (i) at least one catalyst comprising at least one tin compound, and, if desired, at least one selected from the group consisting of titanium, gallium, zinc, bismuth, cobalt a catalyst of manganese, magnesium, strontium, lithium, an aluminum compound and an aluminum compound with a hydroxide or a sodium hydroxide; and (ii) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof (II) The product of step (I) is at a temperature of from 250 to 305 ° C and at least one is selected from the final pressure of step (I) to 0. Heating at a pressure within the range of 02 Torr (absolute pressure) for 1 to 6 hours to form a final polyester; wherein the total mole % of the dicarboxylic acid component of the final polyester is 100% by mole, and the final polyester The total molar % of the diol component is 100 mol%; wherein when it is 60/40 (w/w) phenol/tetrachloroethane, at 119,732. Doc -163- 200804457 At a concentration of 750 ml at 0. 25 g, the final polyester has an intrinsic viscosity of 〇·35 to 1. 2 metrics/gram; and wherein the final polyester has a Tg of 85 to 200 °C. In one aspect, the invention relates to a method of making any of the polyesters suitable for use in the present invention, comprising the following steps: (I) at least one temperature selected from 150 to 250 ° C and selected from 0 to 75 Heating a mixture under at least one pressure of psig, wherein the mixture comprises: (a) a dicarboxylic acid component comprising: i) 70 to 100 mole % terephthalic acid residues; ii) 0 to 30 mole % An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component, It comprises: i) from 1 to 99 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and ii) from 1 to 99 mol% of cyclohexanedimethanol a residue; wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is 1. 05-1. 15A. 0; wherein the mixture in the step (I) is heated in the presence of: (i) at least one catalyst comprising at least one tin compound, and, if desired, at least one selected from the group consisting of titanium, gallium, zinc 'niobium, cobalt , a catalyst of a clock, magnesium, lanthanum, a bell, an aluminum compound and an aluminum compound with a hydroxide or a sodium hydroxide; and (ii) at least one heat stabilizer, 119,732. Doc • 164· 200804457 is selected from at least one structural compound, its reaction product and mixtures thereof; (II) the product of step (I) at a temperature of from 250 to 305 ° C and at least one selected from the final pressure from step (I) To 0. Heating at a pressure within the range of 02 Torr (absolute pressure) for 1 to 6 hours to form a final polyester; wherein the total mole % of the dicarboxylic acid component of the final polyester is 100% by mole, and the final polyester The total molar % of the diol component is 100 moles per gram; wherein when it is in 60/40 (weight/weight) phenol/tetra-ethane, it is at 0. At 25 g / 50 ml, the final polyester has an intrinsic viscosity of 0. 35 to 1. 2 metrics/gram; and wherein the final polyester has a Tg of 85 to 200 °C. In one aspect, the invention relates to a method of making any of the polyesters suitable for use in the present invention, comprising the steps of: (I) at least one temperature selected from 150 to 250 ° C and selected from 〇 to 75 pSig Heating a mixture under at least one pressure, wherein the mixture comprises: (a) a dicarboxylic acid component comprising: i) 70 to 100 mol% of terephthalic acid residues; η) 0 to 30 mol% An aromatic dicarboxylic acid residue having up to one carbon atom; and in) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to Μ carbon atoms; and (b) a diol component comprising: 0 1 to " mole % of 2,2,4,4-tetramethyl·1,3-cyclobutanediol residues; and 119732. Doc-165-200804457 ii) 1 to 99 mol% of cyclohexanedimethanol residue; wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is 1. 0-1. 5/1. 0; wherein the mixture in the step (I) is heated in the presence of at least one catalyst comprising at least one tin compound, and, if necessary, at least one selected from the group consisting of titanium, gallium, zinc, lanthanum, cobalt, manganese, a catalyst of magnesium, lanthanum, lithium, an aluminum compound and an aluminum compound with lithium hydroxide or sodium hydroxide; (Π) a product of step (I) at a temperature of from 250 to 305 ° C, at least one selected from the group consisting of step (I) Heating for a period of 1 to 6 hours in the presence of a pressure in the range of 〇·〇 2 Torr (absolute pressure) and at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, its reaction product, and mixtures thereof; wherein the final polyester The total mole % of the dicarboxylic acid component is 1 mole % and the total mole % of the glycol component of the final polyester is 1 mole %; wherein when 60/40 (weight/weight) In the phenol/tetrachloroethane, the intrinsic viscosity of the final polyester is determined by the concentration of 〇·25 g/50 ml, and the intrinsic viscosity of the final polyester is ^^^^^/g; and wherein the final polyester It has a Tg of 85 to 200 °C. In one aspect, the invention relates to a method of making any of the polyesters suitable for use in the present invention, comprising the steps of: (I) at least one temperature selected from the group consisting of 15 to 25 Å and selected from 〇 to even J Heating a mixture under pressure, wherein the mixture comprises: (a) an acid-removing component comprising: i) 70 to 100 mole % terephthalic acid residues; 119,732. Doc 200804457 ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to one carbon atom;

Hi) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個石炭原子；與 (b)二醇成份，其包含： i) 1至99莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基；及 Π) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1.05-1.15/1.0 ; 其中步驟（I)中之混合物係在下列物質之存在下加 熱：包含至少一種錫化合物之至少一種催化劑， 及，視需要，至少一種選自鈦、鎵、鋅、銻、鈷、 鐘、鎂、鍺、鋰、鋁化合物及鋁化合物與氫氧化鐘 或氫氧化納之催化劑； (Π)將步驟（I)之產物於250至305 °C之溫度、至少一選自 從步驟（I)之最終壓力至〇·〇2托（絕對壓力）範圍内之 壓力及至少一種選自至少一種碗化合物'其反應產 物及其混合物之熱穩定劑之存在下加熱1至6小時； 其中該最終聚酯之二羧酸成份之總莫耳％為100莫耳 %，且該最終聚酯之二醇成份之總莫耳〇/。為1 〇〇莫耳 % ;其中當在60/40 (重量/重量）酚/四氯乙烷中，於 〇·25克/50毫升之濃度下，在25°C下測定時，該最終 聚醋之固有黏度為0.35至1.2公合/克；且其中該最終 119732.doc -167- 200804457 聚酯具有85至200°C之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 何聚酯之方法，其包含下列步驟： ⑴在選自150至25(TC之至少一溫度及選自〇至75 psig之 至少一壓力下加熱一混合物，其中該混合物包含： U)二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； 11) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii)0至10莫耳％之脂族二緩酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： i) 1至99莫耳％之2,2,4,4·四甲基-1，3-環丁二醇 殘基；及 ii) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1.0-1.5/1.0 ; 其中步驟（I)中之混合物係在下列物質之存在下加 熱：（1)包含至少一種錫化合物之至少一種催化劑， 及，視需要，至少一種選自鈦、鎵、鋅、銻、鈷、 鍾、鎮、錯、鐘、紹化合物及紹化合物與氫氧化鲤 或氫氧化鈉之催化劑；及（ii)至少一種熱穩定劑，其 係選自至少一種磷化合物、其反應產物及其混人 物； ° 119732.doc -168- 200804457 (II)將步驟（I)之產物於23 0至320 °c之溫度及至少一選自 從步驟（I)之最終壓力至0.02托（絕對壓力）範圍内之 壓力下加熱1至6小時，以形成最終聚酯； 其中該最終聚酯之二羧酸成份之總莫耳％為1〇〇莫耳 。/〇，且該最終聚酯之二醇成份之總莫耳％為1 〇〇莫耳 % ;其中當在60/40 (重量/重量）酚/四氯乙烷中，於 0.25克/50毫升之濃度下，在25°C下測定時，該最終 聚酯之固有黏度為〇·35至1.2公合/克；且其中該最終 聚酯具有85至200°C之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 何聚酯之方法，其包含下列步驟： (I)在選自150至250°C之至少一溫度及選自0至75 Psig之 至少一壓力下加熱一混合物，其中該混合物包含·· (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳〇/0之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 1至99莫耳％之2,2,4,4_四甲基-1，3-環丁二醇 殘基；及 ii) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 119732.doc •169- 200804457 比例為 1·05·1.15/1·〇 ; 其中步驟（I)中之混合物係在下列物質之存在下加熱 以形成聚酯：（i)包含至少一種錫化合物之至少一種 催化劑，及，視需要，至少一種選自鈦、鎵、鋅、 銻、鈷、錳、鎂、鍺、鋰、鋁化合物及鋁化合物與 氫氧化鋰或氫氧化鈉之催化劑；及（Π)至少一種熱穩 定劑，其係選自至少一種磷化合物、其反應產物及 其混合物； (II)將步驟（I)之產物於230至320°c之溫度及至少一選自 從步驟（I)之最終壓力至0.02托（絕對壓力）範圍内之 壓力下加熱1至6小時，以形成最終聚酯； 其中該最終聚酯之二羧酸成份之總莫耳％為1〇〇莫耳 %，且該最終聚酯之二醇成份之總莫耳％為100莫耳 °/〇 ;其中當在60/40 (重量/重量）酚/四氯乙烷中，於 〇·25克/50毫升之濃度下，在25°C下測定時，該最終 聚酯之固有黏度為0.35至1.2公合/克；且其中該最終 聚酯具有85至200°C之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 何聚酯之方法，其包含下列步驟： (I)在選自150至250°C之至少一溫度及選自〇至75 psig之 至少一壓力下加熱一混合物，其中該混合物包含： (a) —竣酸成份’其包含： 〇 70至100莫耳％之對苯二甲酸殘基； 11) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 119732.doc -170- 200804457 個碳原子；及 iii) 〇至10莫耳％之脂族二羧酸殘基，具有至高Η 個碳原子；與 (b)二醇成份，其包含： i) 1至99莫耳％之2,2,4,4_四甲基^弘環丁二醇 殘基；及 ii) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1·(Μ·5/1.〇 ; 其中步驟（I)中之混合物係在下列物質之存在下加 熱：包含至少一種錫化合物之至少一種催化劑， 及，視需要，至少一種選自鈦、鎵、鋅、銻、鈷、 錳、鎂、鍺、鋰、鋁化合物及鋁化合物與氫氧化鋰 或氫氧化納之催化劑； (Π)將步驟⑴之產物於230至320Ό之溫度、至少一選自 從步驟（I)之最終壓力至〇 〇2托（絕對壓力）範圍内之 壓力及至少一種選自至少一種磷化合物、其反應產 物及其混合物之熱穩定劑之存在下加熱1至6小時， 以形成聚酯； 其中該最終聚酯之二羧酸成份之總莫耳％為1〇〇莫耳 % ,且該最終聚酯之二醇成份之總莫耳％為1〇〇莫耳 % ;其中當在60/40 (重量/重量）酚/四氯乙烷中，於 0.25克/50毫升之濃度下，在25它下測定時，該最終 聚酯之固有黏度為〇·35至1.2公合/克；且其中該最終 119732.doc -171 - 200804457 聚酯具有85至200°C之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 何聚酯之方法，其包含下列步驟： (I) 在選自150至250°C之至少一溫度及選自〇至75…匕之 至少一壓力下加熱一混合物，其中該混合物包含： (a) 二羧酸成份，其包含： i) 70至100莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個破原子；與 (b) 二醇成份，其包含： i) 1至99莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基；及 ii) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1.05-1.15/1.0 ; 其中步驟（I)中之混合物係在下列物質之存在下加 熱：包含至少一種錫化合物之至少一種催化劑， 及’視需要，至少一種選自鈦、鎵、鋅、銻、鈷、 短、鎮、錯、裡、銘化合物及銘化合物與氫氧化鐘 或氫氧化鈉之催化劑； (II) 將步驟（I)之產物於230至320°C之溫度、至少一選自 從步驟（I)之最終壓力至0.02托（絕對壓力）範圍内之 119732.doc -172- 200804457 壓力及至少一種選自至少一種構化合物、其反應產 物及其混合物之熱穩定劑之存在下加熱1至6小時， 以形成聚酯； 其中該最終聚酯之二羧酸成份之總莫耳％為1〇〇莫耳 %，且該最終聚酯之二醇成份之總莫耳％為1〇〇莫耳 % ;其中當在60/40 (重量/重量）酚/四氯乙烷中，於 〇·25克/5〇毫升之濃度下，在25°C下測定時，該最終 聚醋之固有黏度為〇·35至1_2公合/克；且其中該最終 聚酯具有85至200°c之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 何聚酯之方法，其包含下列步驟： (I)在選自150至250°C之至少一溫度及選自〇至75 psig之 至少一壓力下加熱一混合物，其中該混合物包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳。/0之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 1至99莫耳％之2,2,4,4-四甲基·1，3-環丁二醇 殘基；及 ii) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 119732.doc -173- 200804457 比例為 1.0-1.5/1.0 ; 其中步驟（I)中之混合物係在下列物質之存在下加 熱：（i)包含至少一種錫化合物之至少一種催化劑， 及’視需要’至少一種選自欽、嫁、辞、錄、錄' 鐘、鎮、錯、鐘、銘化合物及铭化合物與氫氧化鐘 或氫氧化鈉之催化劑；及（ii)至少一種熱穩定劑，其 係選自至少一種鱗化合物、其反應產物及其混合 物； (II)將步驟（I)之產物於230至320°C之溫度及至少一選自 從步驟（I)之最終壓力至〇.〇2托（絕對壓力）範圍内之 壓力下加熱1至6小時，以形成最終聚酯； 其中該最終聚酯之二羧酸成份之總莫耳％為1〇〇莫耳 %，且該最終聚酯之二醇成份之總莫耳％為100莫耳 %，其中當在60/40 (重量/重量）紛/四氯乙燒中，於 〇·25克/50毫升之濃度下，在25°C下測定時，該最終 聚酯之固有黏度為〇·35至1.2公合/克；且其中該最終 聚酯具有85至200°C之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 何聚酯之方法，其包含下列步驟： (I)在選自150至200°C之至少一溫度及選自〇至75 psig< 至少一壓力下加熱一混合物，其中該混合物包含： (a)二緩酸成份，其包含： 0 70至100莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 119732.doc -174- 200804457 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) —醉成份’其包含： i) 1至99莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基；及 ii) 1至99莫耳。/〇之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1·05_1·15/1·0 ; 其中步驟（I)中之混合物係在下列物質之存在下加 熱：（i)包含至少一種錫化合物之至少一種催化劑， 及，視需要，至少一種選自鈦、鎵、鋅、銻、鈷、 I孟、鎮、鍺、鐘、紹化合物及铭化合物與氫氧化鐘 或氫氧化鈉之催化劑；及（ii)至少一種熱穩定劑，其 係選自至少一種磷化合物、其反應產物及其混合 物； (Π)將步驟（I)之產物於230至320°C之溫度及至少一選自 從步驟（I)之最終壓力至0.02托（絕對壓力）範圍内之 壓力下加熱1至6小時，以形成最終聚酯； 其中該最終聚醋之二緩酸成份之總莫耳％為1 〇 〇莫耳 °/〇，且該最終聚酯之二醇成份之總莫耳％為100莫耳 % ;其中當在60/40 (重量/重量）酚/四氣乙烷中，於 0.25克/50毫升之濃度下，在25°C下測定時，該最終 聚酯之固有黏度為0.35至1·2公合/克；且其中該最終 119732.doc -175- 200804457 聚酯具有85至200°C之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 何聚酯之方法，其包含下列步驟： (I) 在選自150至200°C之至少一溫度及選自〇至75 psig之 至少一壓力下加熱一混合物，其中該混合物包含： (a) 二羧酸成份，其包含·· i) 70至100莫耳％之對苯二曱酸殘基； ii) 0至30莫耳％之芳族二魏酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二叛酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含·· i) 1至99莫耳％之2,2,4,4-四甲基-1，3_環丁二醇 殘基；及 ii) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1.0-1.5/1.0 ; 其中步驟（I)中之混合物係在下列物質之存在下加 熱：（i)包含至少一種錫化合物之至少一種催化劑， 及，視需要，至少一種選自鈦、鎵、鋅、錄、始、 猛、鎂、鍺、鐘、鋁化合物及銘化合物與氫氧化鐘 或氫氧化鈉之催化劑； (II) 將步驟⑴之產物於230至320°C之溫度、至少一選自 從步驟（I)之最終壓力至0_02托（絕對壓力）範圍内之 119732.doc -176- 200804457 壓力及至少一種選自至少一種磷化合物、其反應產 物及其混合物之熱穩定劑之存在下加熱!至6小時； 。其中該最終聚酯之二羧酸成份之總莫耳％為⑽莫耳 ’且該最終聚酯之二醇成份之總莫耳％為1〇〇莫耳 /、中田在60/40 (重量/重量）酚/四氯乙烷中，於 〇·25克/50毫升之濃度下，在抑下測定時，該最終 聚_之固有黏度為〇·35至12公合/克；且其中該最終 ^^酉旨具有85至200。〇之Tg。 於方面，本發明係關於一種製造適合用於本發明之任 何聚酯之方法，其包含下列步驟： (I)在選自150至200°C之至少一溫度及選自〇至75 psig之 至少一壓力下加熱一混合物，其中該混合物包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳〇/0之對苯二曱酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二叛酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 1至99莫耳％之2,2,4,4-四甲基_1，3_環丁二醇 殘基；及 ii) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1.05-1.15/1.0 ; 119732.doc -177- 200804457 其中步驟（i)中之混合物係在下列物質之存在下力口 熱：包含至少一種錫化合物之至少一種催化齊j， 及，視需要，至少一種選自鈦、鎵、鋅、錄、姑、 猛、鎂、鍺、鐘、铭化合物及銘化合物與氯氧化鐘 或氫氧化納之催化劑； (II)將步驟（I)之產物於230至320°c之溫度、至少_選自 從步驟（I)之最終壓力至0.02托（絕對壓力）範圍内之 壓力及至少一種選自至少一種構化合物、其反應產 物及其混合物之熱穩定劑之存在下加熱丨至6小時； 其中該最終聚酯之二羧酸成份之總莫耳％為1 〇〇莫耳 % ’且該最終聚酯之二醇成份之總莫耳％為1〇〇莫耳 % ;其中當在60/40 (重量/重量）酚/四氯乙烷中，於 〇·25克/50毫升之濃度下，在25°C下測定時，該最終 聚酯之固有黏度為0.35至1.2公合/克；且其中該最終 聚酯具有85至200°C之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 何聚酿之方法，其包含下列步驟： ⑴在選自I50至200°c之至少一溫度及選自〇至75 psig之 至少一壓力下加熱一混合物，其中該混合物包含： (a)二羧酸成份，其包含： i) 70至1〇〇莫耳〇/〇之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 119732.doc -178- 200804457 個碳原子；與 (b)二醇成份，其包含： i) 1至99莫耳％之2,2,4,4-四甲基-1，3_環丁二醇 殘基；及 ii) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1·〇·1·5/ΐ.〇 ; 其中步驟（I)中之混合物係在下列物質之存在下加 熱：（i)包含至少一種錫化合物之至少一種催化劑， 及’視需要，至少一種選自欽、麵►、辞、録、敍、 猛、鎮、鍺、鐘、銘化合物及銘化合物與氫氧化叙 或氫氧化鈉之催化劑；及（ii)至少一種熱穩定劑，其 係選自選自至少一種磷化合物、其反應產物及其混 合物； (II)將步驟（I)之產物於250至305 °C之溫度及至少一選自 從步驟（I)之最終壓力至〇·〇2托（絕對壓力）範圍内之 壓力下加熱1至6小時，以形成最終聚酯； 其中該最終聚酯之二羧酸成份之總莫耳％為1〇〇莫耳 %，且該最終聚酯之二醇成份之總莫耳％為1〇〇莫耳 °/〇 ;其中當在60/40 (重量/重量）酚/四氯乙烷中，於 0.25克/50毫升之濃度下，在25°C下測定時，該最終 聚酯之固有黏度為〇·35至1.2公合/克；且其中該最終 聚酯具有85至200°C之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 119732.doc -179- 200804457 何聚酯之方法，其包含下列步驟： (I) 在選自150至200°C之至少一溫度及選自〇至75 psig之 至少一壓力下加熱一混合物，其中該混合物包含： (a) 二羧酸成份，其包含： i) 70至100莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 1至99莫耳％之2,2,4,4-四甲基-1，3·環丁二醇 殘基；及 ii) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1·05_1·15/1.0 ; 其中步驟（I)中之混合物係在下列物質之存在下加 熱：（i)包含至少一種錫化合物之至少一種催化劑， 及，視需要，至少一種選自鈦、鎵、鋅、銻、鈷、 猛、鎭、鍺、經、銘化合物及銘化合物與氫氧化鐘 或氫氧化鈉之催化劑；及（ii)至少一種熱穩定劑，其 係選自選自至少一種磷化合物、其反應產物及其混 合物； (II) 將步驟（I)之產物於250至305°C之溫度及至少一選自 從步驟（I)之最終壓力至0.02托（絕對壓力）範圍内之 119732.doc -180- 200804457 壓力下加熱1至6小時，以形成最終聚酯； 其中該最終聚酯之二羧酸成份之總莫耳％為1〇〇莫耳 %，且該最終聚酯之二醇成份之總莫耳。/。為1〇〇莫耳 % ;其中當在60/40 (重量/重量）酚/四氯乙烷中，於 0.25克/50毫升之濃度下，在25 °C下測定時，該最終 聚酯之固有黏度為〇·35至1.2公合/克；且其中該最終 聚酯具有85至200°C之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 何聚酯之方法，其包含下列步驟： (I)在選自150至200°C之至少一溫度及選自0至75 psig之 至少一壓力下加熱一混合物，其中該混合物包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 in) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 1至99莫耳％之2,2,4,4-四曱基-1，3-環丁二醇 殘基；及 Π) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1.0-1.5/1.0 ; 其中步驟（I)中之混合物係在下列物質之存在下加 119732.doc -181 - 200804457 熱·包含至少一種錫化合物之至少一種催化劑， 及，視需要，至少一種選自鈦、鎵、鋅、銻、鈷、 錳、鎂、鍺、鋰、鋁化合物及鋁化合物與氫氧化鋰 或氫氧化鈉之催化劑； (Π)將步驟⑴之產物於25〇至3〇5aC之溫度、至少一選自 從步驟（I)之最終壓力至〇 〇2托（絕對壓力）範圍内之 壓力及至少一種選自至少一種磷化合物、其反應產 物及其混合物之熱穩定劑之存在下加熱1至6小時； 其中該最終聚酯之二羧酸成份之總莫耳％為1〇〇莫耳 % ’且該最終聚酯之二醇成份之總莫耳％為1〇〇莫耳 其中當在60/40 (重量/重量）酚/四氯乙烷中，於 〇·25克/50毫升之濃度下，在測定時，該最終 聚醋之固有黏度為〇·35至1·2公合/克；且其中該最終 聚酯具有85至200°C之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 何聚S旨之方法’其包含下列步驟： (I)在選自150至200°c之至少一溫度及選自〇至75 psig之 至少一壓力下加熱一混合物，其中該混合物包含： Ο)二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； 11) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 119732.doc -182- 200804457 (b) 一醇成份，其包含： 0 1至99莫耳％之2,2,4,4-四甲基-1，3-環丁二醇 殘基；及 U) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1.05-1.15/1.0 ; 其中步驟（I)中之混合物係在下列物質之存在下加 熱：包含至少一種錫化合物之至少一種催化劑， 及’視需要，至少一種選自鈦、鎵、辞、銻、鈷、 錳、鎂、鍺、鋰、鋁化合物及鋁化合物與氫氧化鋰 或氫氧化鈉之催化劑； (π)將步驟⑴之產物於250至305cc之溫度、至少一選自 從步驟（I)之最終壓力至〇·〇2托（絕對壓力）範圍内之 壓力及至少一種選自至少一種磷化合物、其反應產 物及其混合物之熱穩定劑之存在下加熱1至6小時； 其中該最終聚酯之二羧酸成份之總莫耳％為1〇〇莫耳 %，且該最終聚酯之二醇成份之總莫耳％為1〇〇莫耳 % ;其中當在60/40 (重量/重量）酚/四氣乙烷中，於 0 ·25克/5 0宅升之濃度下’在25 C下測定時，該最終 聚酯之固有黏度為0.35至1.2公合/克；且其中該最終 聚酯具有85至200°C之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 何聚酯之方法，其包含下列步驟： (I)在選自150至200°C之至少一溫度及選自〇至75 psig之 119732.doc -183- 200804457 至少一壓力下加熱一混合物，其中該混合物包含： (a) 二羧酸成份，其包含： 1) 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 ill) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 1至99莫耳％之2,2,4,4_四甲基-1，3-環丁二醇 殘基；及 ii) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1.0-1.5/1.0 ; 其中步驟（I)中之混合物係在下列物質之存在下加 熱：（0包含至少一種錫化合物之至少一種催化劑， 及’視需要，至少一種選自鈦、鎵、鋅、銻、鈷、 猛、鎂、鍺、鋰、鋁化合物及鋁化合物與氫氧化鋰 或氫氧化鈉之催化劑；及（ii)至少一種熱穩定劑，其 係選自選自至少一種磷化合物、其反應產物及其混 合物； (Π)將步驟⑴之產物於230至320°c之溫度及至少一選自 從步驟⑴之最終壓力至0.02托（絕對壓力）範圍内之 t力下加熱1至6小時，以形成最終聚i旨； 其中該最終聚酯之二叛酸成份之總莫耳％為1 00莫耳 119732.doc 200804457 〇且忒最、、、；聚酯之二醇成份之總莫耳％為i 〇〇莫耳 % ,其中當在60/40 (重量/重量）酚/四氯乙烷中，於 0.25克/50¾升之濃度下，在25它下測定時，該最終 聚醋之固有黏度為〇.35至12公合/克；且其中該最終 聚酯具有85至200。(3之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 何聚酯之方法，其包含下列步驟： (I)在選自15〇至200C之至少一溫度及選自〇至 75 psig之至少一壓力下加熱一混合物，其中 該混合物包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 1至99莫耳％之2,2,4,4-四甲基-1，3·環丁二醇 殘基；及 ii) 1至99莫耳％之環己烧二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二竣酸成份之莫耳 比例為 1 · 0 5 -1 · 1 5 /1 · 0 ; 其中夕驟（I)中之混合物係在下列物質之存在下加熱 以形成聚酯：（i)包含至少一種錫化合物之至少一種 119732.doc -185- 200804457 催化劑，及，視需要，至少一種選自鈦、鎵、鋅、 銻、鈷、錳、鎂、鍺、鋰、鋁化合物及鋁化合物與 氫氧化鋰或氫氧化鈉之催化劑；及（ii)至少一種熱穩 定劑，其係選自選自至少一種磷化合物、其反應產 物及其混合物； (II)將步驟（I)之產物於230至320°C之溫度及至少一選自 從步驟（I)之最終壓力至0.02托（絕對壓力）範圍内之 壓力下加熱1至6小時，以形成最終聚酯； 其中該最終聚酯之二羧酸成份之總莫耳％為1〇〇莫耳 %，且該最終聚酯之二醇成份之總莫耳％為1〇〇莫耳 % ;其中當在60/40 (重量/重量）酚/四氯乙烷中，於 〇·25克/50毫升之濃度下，在25°C下測定時，該最終 聚酯之固有黏度為〇·35至1.2公合/克；且其中該最終 聚酯具有85至200°C之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 何t S曰之方法，其包含下列步驟： (I)在選自150至200°C之至少一溫度及選自〇至75 psig之 至少一壓力下加熱一混合物，其中該混合物包含： (a)二幾酸成份，其包含： 1) 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高 個碳原子；及 ill) 0至10莫耳％之脂族二羧酸殘基，具有至高b 個碳原子；與 119732.doc 200804457 (b)二醇成份，其包含： i) 1至99莫耳％之2,2,4,4-四甲基-1，3_環丁二醇 殘基；及 ii) 1至99莫耳〇/〇之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1.0-1.5/1.0 ; 其中步驟（I)中之混合物係在下列物質之存在下加 熱：包含至少一種錫化合物之至少一種催化劑， 及，視需要，至少一種選自鈦、鎵、鋅、銻、鈷、 鐘、鎮、鍺、鐘、銘化合物及銘化合物與氫氧化鐘 或氫氧化鈉之催化劑； (II)將步驟（I)之產物於230至320°C之溫度、至少一選自 從步驟（I)之最終壓力至0.02托（絕對壓力）範圍内之 壓力及至少一種選自至少一種磷化合物、其反應產 物及其混合物之熱穩定劑之存在下加熱1至6小時， 以形成聚酯； 其中該最終聚酯之二羧酸成份之總莫耳％為i〇〇莫耳 %，且該最終聚酯之二醇成份之總莫耳％為100莫耳 % ;其中當在60/40 (重量/重量）酚/四氯乙烷中，於 〇·25克/50毫升之濃度下，在25°C下測定時，該最終 聚酯之固有黏度為〇·35至1.2公合/克；且其中該最終 聚酯具有85至200°C之Tg。 於一方面，本發明係關於一種製造適合用於本發明之任 何聚酯之方法，其包含下列步驟： 119732.doc -187- 200804457 (I) 在選自150至200 C之至少一溫度及選自〇至75 psig之 至少一壓力下加熱一混合物，其中該混合物包含·· (a) 二羧酸成份，其包含·· i) 70至100莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高 個碳原子；及 iii) 〇至ίο莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 1至99莫耳％之2,2,4,4-四甲基- 環丁二醇 殘基；及 ii) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1.05-1.15/1.0 ; 其中步驟（I)中之混合物係在下列物質之存在下加 熱：包含至少一種錫化合物之至少一種催化劑， 及’視需要，至少一種選自鈦、鎵、鋅、錄、銘、 猛、鎂、錯、鐘、紹化合物及紹化合物與氫氧化鐘 或氫氡化鈉之催化劑； (II) 將步驟（I)之產物於230至320°C之溫度、至少一選自 從步驟（I)之最終壓力至0.02托（絕對壓力）範圍内之 壓力及至少一種選自至少一種磷化合物、其反應產 物及其混合物之熱穩定劑之存在下加熱1至6小時， 以形成聚酿； 119732.doc •188- 200804457 其中該最終聚酯之二羧酸成份之總莫耳％為100莫耳 %，且該最終聚酯之二醇成份之總莫耳％為100莫耳 % ,其中當在60/40 (重量/重量）酚/四氣乙烷中，於 0.25克/50毫升之濃度下，在251下測定時，該最終 聚酯之固有黏度為〇·35至12公合/克；且其中該最終 聚醋具有85至20〇°c之Tg。 於一方面，τ用於本發明之聚醋含有至少一種無論如何 作為熱穩定劑之磷化合物。 於一方面，本發明之聚酯組合物含有至少一種聚碳酸 酉旨。 於一方面，本發明之聚酯組合物未含有聚碳酸酯。 於一方面，可用於本發明之聚酯含有小於15莫耳％乙二 醇殘基，例如0.01至小於15莫耳％乙二醇殘基。 於方面’可用於本發明之聚酯含有乙二醇殘基。 於一方面，可用於本發明之聚酯未含有乙二醇殘基。 於方面’可用於本發明之聚酯含有50至99.99莫耳％乙 —酵殘基。 於一方面，可用於本發明之聚酯未含有分枝劑，或者， 至少一種分枝劑係在無論是聚酯聚合之前或期間添加。 於方面，可用於本發明之聚酯含有至少一種分枝劑， 無關於其添加之方法或順序。 於一方面，可用於本發明之聚酯係製自無1，3-丙二醇或 1，4_丁二醇，無論是單獨或組合。在其他方面，丨，3_丙二 醇或1’4-丁一醇，無論是單獨或組合，可被使用於製造可 119732.doc 200804457 用於本發明之聚酯。 一於方面’可用於本發明之聚酯含有至的.Μ莫耳％乙 一酵殘基。 、於本發日月之—方面，可用於本發明特定以旨中之順 ’ ’，4四f基_1’3_板丁二醇之莫耳％係大於莫耳％， 或大於55莫耳％順式_2,2,4,4_四甲基^環丁二醇或大於 7〇莫耳％順式·2,2,4,4-四甲基_U·環丁二醇；其中順 式·2,2,4/-四甲基十3_環丁二醇與反式-μ〆〆·四甲 基-1，3-環丁二醇之總莫耳百分比係等於總計上⑽莫耳％。 於本發明之-方面，可用於本發明特定聚醋中之 〇2,2,4,4-四甲基]，3:環丁二醇異構物之莫耳％係30至70莫耳 之順式·2,2,4,4·四甲基·；ι，3_環丁二醇或3()至7()莫耳。乂之反 弋’2,4,4四甲基-1,3-環丁二醇；或4〇至6〇莫耳％之順 ’2,4,4甲基_ι，3_環丁二醇或4〇至6〇莫耳％之反 式·2,2,4,4·四甲基-1，3·環丁二醇；其中順式·2,2,4,4-四甲 基-1，3-環丁二醇與反式_2,2,4,4•四甲基·環丁二醇之總 莫耳百分比係等於總計100莫耳〇/0。 於一方面，某些可用於本發明之聚酯係為非晶質或半結 曰曰性。於一方面，某些可用於本發明之聚酯可具有相對較 低結晶度。某些可用於本發明之聚酯可因此具有實質上非 曰曰質形態學’意謂此等聚醋包含聚合體之實質上不規則區 域。 於一方面，可用於本發明之聚酯含有至少一種無論如何 作為熱穩定劑之磷化合物。 119732.doc 200804457 於一方面，可田认士μ "本發明之聚酯、聚酯組合物及/或方 例如，至少一種碟 法之熱穩定劑含有至少 ，主夕一種磷化合物， 酸酉旨0 於方面，彳用於本發明之聚酯及/或聚酉旨組合物含有 填原子。 於方面，可用於本發明之聚酯及/或聚酯組合物含有 錫原子。 於一方面，本發明之任何聚酯組合物含有至少一種錫化 合物及至少一種鈦化合物。 於一方面，任何製造可用於本發明之聚酯之方法可使用 至少一種錫化合物及至少一種鈦化合物。 於一方面，可用於本發明之磷化合物包含磷酸、亞麟 酸、膦酸、次膦酸、亞膦酸及其各式酯及鹽。該等酯可為 烧基、分支烷基、經取代烷基'二官能基烷基、烷基醚、 芳基及經取代芳基。 於一方面，可用於本發明之磷化合物包含至少一種熱穩 定劑’其係選自至少一種經取代或未經取代之烧基鱗酸酯 類、經取代或未經取代之芳基磷酸酯類、經取代或未經取 代之混合烷基芳基磷酸酯類、二亞磷酸酯類、磷酸鹽類、 氧化膦類及混合芳基烷基亞磷酸酯類、其反應產物及其混 合物。該磷酸酯類包含其中磷酸已完全酯化或僅部分酯化 之酯。 於一方面，可用於本發明之磷化合物包含至少一種熱穩 定劑，其係選自至少一種經取代或未經取代之烧基鱗酸酯 119732.doc -191- 200804457 類、經取代或未經取代之芳基磷酸酯類、混合之經取代或 未經取代之烷基芳基磷酸酯類、其反應產物及其混合物。 該填酸醋類包含其中磷酸已完全酯化或僅部分酯化之酯。 於一方面，可用於本發明之磷化合物係選自至少一種烷 基鱗酸s旨類、芳基磷酸酯類、混合烷基芳基磷酸酯類、其 反應產物及其混合物。 於一方面，任何本發明之聚酯組合物可包含至少一種芳 基填酸S旨。 於一方面’任何本發明之聚酯組合物可包含至少一種未 經取代之方基麟酸S旨。 於一方面，任何本發明之聚酯組合物可包含至少一種芳 基磷酸酯，其未經节基取代。 於一方面，任何本發明之聚酯組合物可包含至少一種三 芳基鱗酸醋。 於一方面，任何本發明之聚酯組合物可包含至少一種三 芳基磷酸酯，其未經节基取代。 於一方面’任何本發明之聚酯組合物可包含至少一種烷 基磷酸酯。 於一方面’任何本發明之聚酯組合物可包含三苯基磷酸 西曰及/或Merpol A。於一具體實施例中，任何本發明之聚酯 組合物可包含三苯基磷酸醋。 於一方面，可用於本發明之磷化合物可選自至少下列一 種物質：二亞_酸g旨類、構酸鹽類、氧化膦類及混合芳基 烷基亞磷酸酯類。 119732.doc -192- 200804457 於一方面，可用於本發明之磷化合物包含，但不限於， 至少一種二亞磷酸酯。 於一方面，可用於本發明之鱗化合物包含，但不限於， 至少一種二亞磷酸酯，其包括2,4,8，10-四噁基-3,9·二磷螺 [5.5]十一烷結構，例如，Westcm 619(GE專業化學品， CAS# 3806-34-6)及 / 或 Doverphos S-9228(Dover化學品， CAS# 154862-43-8)。 於一方面，可用於本發明之磷化合物包含至少一種混合 烧基芳基亞磷酸酯，例如，雙（2,4-異丙苯基苯基）季戊四 醇二亞磷酸酯，已知為Doverphos S-9228(Dover化學品， CAS # 154862-43-8)。 於一具體實施例中，可用於本發明之磷化合物包含至少 一種氧化膦。 於一具體實施例中，可用於本發明之磷化合物包含至少 一種磷酸鹽，例如，KH2P〇4及Ζη3(Ρ04)2。 於一方面，任何本案說明書中所述用於製造該聚酯組合 物及/或聚酯之方法包含至少一種本案說明書中所述之磷 化合物。 於一方面’任何本案說明書中所述用於製造任何該聚酯 組合物及/或聚酯之方法可包含至少一種二亞磷酸酯。於 一方面’任何本案說明書中所述用於製造任何該聚酯組合 物及/或聚醋之方法可包含至少一種二亞磷酸酯，其包括 2,4,8，10·四噁基_3,9_二磷螺[5.5]十一烷結構，例如weston 619(GE專業化學品，cas# 3806-34-6)及/或 Doverphos S_ 119732.doc -193- 200804457 9228(Dover化學品，cas# 154862 43 8)。 咸仏任何製造可用於本發明之聚酯之方法可用於製造任 何可用於本發明之聚酯。 於一方面，本發明任何方法之步驟（I)之所使用之壓力係 由選自0至75 psig之至少一種壓力所組成。於一具體實施 例中，本發明任何方法之步驟⑴之所使用之壓力係由選自 〇至50 psig之至少一種壓力所組成。 於一方面’本發明任何方法之步驟（π)之所使用之壓力 係由選自20至〇·〇2托（絕對壓力）之至少一種壓力所組成； 於一具體實施例中，本發明任何方法之步驟（π)之所使用 之壓力係由選自10至0·02托（絕對壓力）之至少一種壓力所 組成；於一具體實施例中，本發明任何方法之步驟（π)之 所使用之壓力係由選自5至0 · 0 2托（絕對壓力）之至少一種壓 力所組成；於一具體實施例中，本發明任何方法之步驟 (II)之所使用之壓力係由選自3至0.02托（絕對壓力）之至少 一種壓力所組成；於一具體實施例中，本發明任何方法之 步驟（II)之所使用之壓力係由選自20至0.1托（絕對壓力）之 至少一種壓力所組成；於一具體實施例中，本發明任何方 法之步驟（II)之所使用之壓力係由選自10至絕對壓 力）之至少一種壓力所組成；於一具體實施例中，本發明 任何方法之步驟（II)之所使用之壓力係由選自5至〇 · 1托（絕 對壓力）之至少一種壓力所組成；於一具體實施例中，本 發明任何方法之步驟（II)之所使用之壓力係由選自3至03 托（絕對壓力）之至少一種壓力所組成。 H9732.doc -194- 200804457 於本發明之任何方法， 可用於本發明之填化合物可於 酯化反應期間、聚縮人 、 ϋ反應期間或兩者中添加，及/或1 可於聚合反應後才添加。 ’、 万、方面’假使磷化合物係於酉旨 化反應及聚縮合反應之接士 後才添加，其係以佔最終聚酯總重 量之1至2重量％之量添加。 ;方面$加於本發明任何方法之步驟⑴中之二醇成 分/二羧酸成分之莫耳比為 1 > π υ U/1·0 ,於一方面，添加於 本叙明任何方法之步驟⑴中 I J甲之一転成分/二羧酸成分之莫 耳比為1.01-1.5/1.0 ;於一方而；丄 、 、方面’添加於本發明任何方法之 步驟（I) t之二醇成分/ 一翰辦# ν • 取刀/ 一竣酸成分之莫耳比為1.01- 1.3/1.0 ’於一方面，添加於本發明任何方法之步驟⑴中之 二醇成分/二羧酸成分之莫耳比4ι 〇ι_ΐ 2/ι 〇;於一方 面，添加於本發明任何方法之步驟（I)中之二醇成分/二羧 酸成分之莫耳比為l.OU.b/! 〇 万、 方面，添加於本發 明任何方法之步驟（I)中之-醴# 、 τ之一知成分/二羧酸成分之莫耳比 為1·01-1·1〇/1·〇 ;於一方面，夭士认丄外 万面添加於本發明任何方法之步 驟⑴中之二醇成分/二㈣成分之莫耳比為103·15/". 於一方面，添加於本發明任何方法之步驟⑴中之二醇成分 /二羧酸成分之莫耳比為丨03-丨3/1 π 万面，添加於 本發明任何方法之步驟⑴中之二醇成分/二羧酸成分之莫 耳比為im.o;於-方面，添加於本發明任何方法之 步驟⑴中之二醇成分/二鲮酸成分之莫耳比w 1· 15/1 ·0,於一方面，添加於本發 ^ 乃饪何方法之步驟（I)中 之一醇成分/二羧酸成分之莫耳比為1〇3_11〇/1 〇 ·於一方 119732.doc -195- 200804457 面，添加於本發明任何 J乃古之步驟（J)中之二 酸成分之莫耳比坪成刀/一竣 六寸比為1.05-1.5/1 ·〇 ;於一方而，、、兵上 任何方法之步驟⑴中之二八:、 、口於本發明 ! 〇5 j ^ 一知成/刀/二羧酸成分之莫耳比為 1·05_1·3/1·0 ;於一古 q ^方面，添加於本發明任何方法之步驟ω 中之二醇成分/ 一 ¥ ^κ } 成刀/_竣酸成分之莫耳比為105_12/10;於一 方面，添加於本發明任何方法之步驟⑴中之二醇成分/二 竣酸成分之莫耳j 〈旲耳比為1.05-1.15/1.ο ;及於一方面，添加於 本發明任何方法之步驟⑴中之二醇成分/二m酸成分之莫 耳比為 1·〇Μ·1〇/1 0。 、 於可用於本發明之聚酯之任何製造方法具體實施例中， 步驟（11)之加熱時間可為1至5小時。於可用於本發明之聚 -曰之任竹製&方法具體實施例中，步驟（II)之加熱時間可 為1至4小時。於可用於本發明之聚酯之任何製造方法具體 實施例中’步驟（Π)之加熱時間可為1至3小時。於可用於 本發明之聚酯之任何製造方法具體實施例中，步驟（π)之 加熱時間可為丨·5至3小時。於可用於本發明之聚酯之任何 製造方法具體實施例中，步驟（II)之加熱時間可為1至2小 時。 於一方面，任何本發明之聚酯組合物及/或方法可包含 至少一種本發明說明書中所述之錫化合物。 於一方面，任何本發明之聚酯組合物及/或方法可包含 至少一種錫化合物及，視需要，至少一種選自鈦、鎵、 辞、銻、餘、猛、鎮、鍺、鋰、銘化合物及銘化合物與氫 氧化鐘或氫氧化鈉之催化劑。 119732.doc -196· 200804457 於一方面，任何本發明之聚酯組合物及/或製造可用於 本發明之聚酯之方法可使用作為催化劑之至少一種錫化合 物及至少一種選自鈦化合物之催化劑來製備。 於可用於本發明之聚酯之任何製造方法具體實施例中， 酉旨化反應溫度可為自150°C至250。〇；或自150°C至245°C ; 或自150°C至240°C ;或自150°C至235°C ;或自15(TC至 230°C ;或自 150°C 至 225°C ;或自 150°C 至 220°C ;或自 150°C 至 215°C ;或自 150°C 至 210°C ;或自 150°C 至 205°C ; 或自150°C至200°C ;或自155°C至250°C ;或自155°C至 245°C ;或自 155°C 至 240°C ;或自 155°C 至 235°C ;或自 155°C 至 230°C ;或自 155°C 至 225°C ;或自 155°C 至 220°C ; 或自155°C至215°C ;或自155°C至210°C ;或自155°C至 205°C ;或自 155°C 至 200°C ;或自 160°C 至 250°C ;或自 160°C 至 245°C ;或自 160°C 至 240°C ;或自 160°C 至 235°C ; 或自160°C至230°C ;或自160°C至225°C ;或自160°C至 220°C ;或自 160°C 至 215°C ;或自 160°C 至 210°C ;或自 160°C 至 205°C ;或自 160°C 至 200°C ;或自 165°C 至 250°C ; 或自165°C至245°C ;或自165°C至240°C ;或自165°C至 235°C ;或自 165°C 至 230°C ;或自 165°C 至 225°C ;或自 165。(：至 220°C ;或自 165°C 至 215°C ;或自 165°C 至 210°C ; 或自165°C至205°C ;或自165°C至200°C ;或自17〇°C至 250°C ;或自 170°C 至 245°C ;或自 17〇°C 至 240°C ;或自 170°C 至 235°C ;或自 17〇°C 至 230°C ;或自 170°c 至 225°c ; 或自170°C至220°C ;或自17〇°C至215°C ;或自17〇°C至 119732.doc -197- 200804457 210°C ;或自 17(TC 至 205°C ;或自 170°C 至 200°C ;或自 175°C 至 250°C ;或自 175°C 至 245°C ;或自 175°C 至 24(TC ; 或自175°C至235°C ;或自175°C至230°C ;或自175°C至 225°C ;或自 175°C 至 220°C ;或自 175°C 至 215°C ;或自 175°C 至 210°C ;或自 175°C 至 205°C ;或自 175°C 至 200°C ; 或自180°C至250°C ;或自180°C至245°C ;或自180°C至 240°C ;或自 180°C 至 235°C ;或自 180°C 至 230°C ;或自 180°C 至 225°C ;或自 180°C 至 220°C ;或自 180°C 至 215°C ; 或自180°C至210°C ;或自180°C至205°C ;或自180°C至 200°C之至少一溫度。 於一方面，於可用於本發明之聚酯之任何製造方法具體 實施例中，聚縮合反應溫度可為自230°C至320°C ;或自 230°C 至 315°C ;或自 230°C 至 310°C ;或自 230°C 至 305°C ; 或自230°C至300°C ;或自230°C至295°C ;或自230°C至 285°C ;或自 230°C 至 280°C ;或自 230°C 至 275°C ;或自 230°C 至 270°C ;或自 230°C 至 265°C ;或自 230°C 至 260°C ; 或自235°C至320°C ;或自235°C至315°C ;或自235°C至 310°C ;或自 235°C 至 305°C ;或自 235°C 至 300°C ;或自 235°C 至 295°C ;或自 235°C 至 285°C ;或自 235°C 至 280°C ; 或自235°C至275°C ;或自235°C至270°C ;或自235°C至 265°C ;或自 235°C 至 260°C ;或自 240°C 至 320°C ;或自 240°C 至 315°C ;或自 240°C 至 310°C ;或自 240°C 至 305°C ; 或自240°C至300°C ;或自240°C至295°C ;或自240°C至 285°C ;或自 24(TC 至 280°C ;或自 240°C 至 275°C ;或自 119732.doc -198- 200804457 240°C 至 270°C ;或自 240°C 至 265°C ;或自 240°C 至 260°C ; 或自245°C至320°C ;或自245°C至315°C ;或自245°C至 310°C ;或自 245°C 至 305°C ;或自 245°C 至 300°C ;或自 245°C 至 295°C ;或自 245°C 至 285°C ;或自 245°C 至 280°C ; 或自245°C至275°C ;或自245°C至270°C ;或自245°C至 265°C ;或自 245°C 至 260°C ;或自 250°C 至 320°C ;或自 250°C 至 315°C ;或自 250°C 至 310°C ;或自 250°C 至 305°C ; 或自250°C至300°C ;或自250°C至295°C ;或自250°C至 285°C ;或自 250°C 至 280°C ;或自 250°C 至 275°C ;或自 250°C 至 270°C ;或自 250°C 至 265°C ;或自 250°C 至 260°C ; 或自255°C至320°C ;或自255°C至315DC ;或自255°C至 310°C ;或自 255°C 至 305°C ;或自 255°C 至 300°C ;或自 255°C 至 295°C ;或自 255°C 至 285°C ;或自 255°C 至 280°C ; 或自255°C至275°C ;或自255°C至270°C ;或自255°C至 265°C ;或自 255°C 至 260°C ;或自 260°C 至 320°C ;或自 260°C 至 315°C ;或自 260°C 至 310°C ;或自 260°C 至 305°C ; 或自260°C至300°C ;或自260°C至295°C ;或自260°C至 285°C ;或自 260°C 至 280°C ;或自 260°C 至 275°C ;或自 260°C至270°C之至少一溫度。 於一方面，於本發明方法中添加磷化合物可導致全部錫 原子及全部磷原子於最終聚酯中之重量比例為2_丨〇:丨。於 一具體實施例中，於本發明方法中添加磷化合物可導致全 部錫原子及全部磷原子於最終聚酯中之重量比例為5_9:1。 於一具體實施例中，於本發明方法中添加磷化合物可導致 119732.doc -199- 200804457 全部錫原子及全部磷原子於最終聚酯中之重量比例為6_ 8.1 於一具體實施例中，於本發明方法中添加填化合物 可導致全部錫原子及全部磷原子於最終聚酯中之重量比例 為 7:1 〇 於一方面，錫原子於可用於本發明之最終聚酯中之量， 以最終聚酯重量計，可為自15至400 ppm。 於一方面，錫原子於可用於本發明之最終聚酯中之量， 以最終聚酯重量計，可為自25至400 ppm。 於一方面，錫原子於可用於本發明之最終聚酯中之量， 以最終聚酯重量計，可為自40至200 ppm。 於一方面，錫原子於可用於本發明之最終聚酯中之量， 以最終聚酯重量計，可為自50至125 ppm。 於一方面，磷原子於可用於本發明之最終聚酯中之量， 以最終聚酯重量計，可為自1至1〇〇 ppm。 於一方面，磷原子於可用於本發明之最終聚酯中之量， 以最終聚酯重量計，可為自4至60 ppm。 於一方面，磷原子於可用於本發明之最終聚酯中之量， 以最終聚酯重量計，可為自6至20 ppm。 於一方面，填原子於可用於本發明之最終聚酯中之量， 以最終聚S旨重量計，可為自1至100 ppm;且錫原子於最終 聚酯中之量，以最終聚酯重量計，可為自15至4〇〇 。 於一方面，磷原子於可用於本發明之最終聚酯中之量， 以最終聚醋重量計，可為自1至100 ppm;且錫原子於最終 聚酯中之量，以最終聚酯重量計，可為自25至4〇〇 。 119732.doc •200- 200804457 於一方面，磷原子於可用於本發明之最終聚酯中之量， 以最終聚醋重量計，可為自4至60 ppm;且錫原子於最終 聚醋中之量，以最終聚醋重量計，可為自4〇至2〇〇 ppm。 於一方面，磷原子於可用於本發明之最終聚酯中之量， 以最終聚醋重量計’可為自6至20 ppm ;且錫原子於最終 聚酯中之量，以最終聚酯重量計，可為自5〇至125 ppm。 於方面，任何本案說明書中所述製造任何聚酯組合物 及/或聚酯之方法可含有至少一種混合烷基芳基亞磷酸 酯，例如，雙（2,4-異丙苯基苯基）季戊四醇二亞磷酸酯， 已知為 D〇verph〇S S-9228(D〇ver 化學品，cas# 154862 43_ 8) ° 於方面，任何本案說明書中所述製造任何聚酯組合物 及/或聚酯之方法可含有至少一種氧化膦。 於一方面，任何本案說明書中所述製造任何聚酯組合物 及/或聚酯之方法可含有至少一種磷酸鹽，例如，κΗ2ρ〇4 及 Ζη3(Ρ〇4)2 〇 於一方面，此等聚酯組合物係可用於製造物件，包括但 不限於擠壓、壓延及/或模製物件，包括但不限於射出成 型物件' 成型物彳、鑄造擠Μ成型物#、異形擠廢成 ㈣件、溶紡物件、熱成形物件、擠壓模製物件、射出吹 製物件、射出延伸吹製物件、擠壓吹製物件及擠壓延伸吹 製物件。該等物件包含但不限於薄膜、瓶、容器、薄片及/ 或纖維。 ；方面可用於本發明之聚酯組合物可以各種類型之 119732.doc 200804457 包括但不限於擠壓薄膜及/或薄片、 片、壓縮模製薄膜及/或薄片、溶液鑄造 製造薄膜及/或薄片之方法包括但不限於 薄膜及/或薄片使用， 壓延薄膜及/或薄片、 薄膜及/或薄片。製造 擠壓、壓延、壓縮模製及溶液鑄造。 而且’於#面’此等特定聚3旨組合物之利用會使在炼 融加工或熱成形前之乾燥步驟降至最低及/或免除。 【實施方式】 本發明可更容易地參考下文本發明某些具體實施例之詳 細說明與實施例而明瞭。根據本發明之㈣，本發明之某 些具體實施例係被描述於發明内容中，且進一步描述於下 文。本發明之其他具體實施例亦被描述於本文中。 咸“本發明之聚酯及/或聚酯組合物可具有兩種或多種 物理性質之獨特組合，#如中等或高衝擊強度、高玻璃轉 移溫度、抗化學藥品性、水解钱性、勒度、低勒脆性轉 移溫度、良好顏色與透明性、低密度與長結晶化作用半衰 期及良好加卫性能，於是容易地允許彼等被製成物件 本發明之-些具體實施例中，此等聚0旨具有良好衝擊強 度、耐熱性、抗化學藥品性、密度性質之獨特組合，及/ 或良好衝擊強度、耐熱性及加工性能性質之組合，及，或 兩種或多種所述性質之組合’其未曾在以前被認為存在於 聚酯組合物中，其包含如本文中所揭示之聚酯。 、於一具體實施例中，A信在根據本發明之製造聚醋之方 =期間使用本文中所描述之包含至少一種磷化合物之熱穩 定劑時，聚酯可較輕易地被製造，且不會有至少一種以下 119732.doc 200804457 情形發生··冒泡、斜角形成、色 錢r心☆ 逸氣及無 規律熔融程度(即’聚醋、聚醋之產製及加工系統之脈 動）。於一具體實施例中，咸認本發明之至少—種方法提 供較輕易且大量（例如’初步製程規模及/或商業產製）製得 適用於本發明聚酯組合物之任何聚酯，且同時避免至少一 種以上敘述困難發生之方法。 於本文中使用之"大量"一詞’係意欲包括可用於本發明 之聚酯係以大於100碎之量產製。於-具體實施例中，此 處所使用之"大量"一詞，包括可用於本發明之聚酯係以大 於1000磅之量產製。 於方面，可用於本發明之聚酯之製造方法可包含批次 或連續方法。 於一方面，可用於本發明之聚酯之製造方法可包含連續 方法。 、 當錫添加至本發明之聚酯及/或本發明之聚酯組合物及/ 或本發明之聚s旨製造方法時，其仙錫化合物之形式添加 至聚S曰製程中。添加至本發明之聚酯及/或本發明之聚酯 組合物及/或本發明之聚酯製造方法之錫化合物之量，可 以存在於最終聚酯中之錫原子形式量測，例如，以重量 ppm 〇 s 4添加至本發明之聚醋及/或本發明之聚自旨組合物及/ 或本發明之聚醋製造方法時，其係以磷化合物之形式添加 至聚酯製程中。 T添加至本發明之聚醋及/或本發明之聚酯組合物及/或 119732.doc 200804457 本發明方法之本發明磷化合物（例如，至少一種選自磷酸 西旨、二亞磷酸酯、磷酸鹽及混合烷基芳基亞磷酸酯之磷化 合物）之量，可以存在於最終聚酯中之磷原子形式量測， 例如’以重量ppm。 於本文中使用之”聚酯，，一詞，係意欲包括，，共聚酯”，且 應明瞭係意謂一種合成聚合體，經由一或多種雙官能性叛 酸類及/或多官能性羧酸類，與一或多種雙官能性羥基化 合物及/或多官能性羥基化合物之反應所製成。典型上， 雙官能性羧酸可為二羧酸，而雙官能性羥基化合物可為二 經醇’例如二醇類與二元醇類。於本文中使用之”二醇，，一 詞，係包括但不限於二元醇類、二酵類及/或多官能性經 基化合物，例如分枝劑。或者，雙官能性叛酸可為經基緩 酸’例如對-羥苯曱酸，而雙官能性羥基化合物可為芳族 核’帶有2個經基取代基，例如對苯二盼。於本文中使用 之’'殘基” 一詞，係意謂任何有機結構，自其相應之單體經 過聚縮合及/或酯化反應併入聚合體中。於本文中使用之” 重複單位”一詞，係意謂有機結構，具有二羧酸殘基與二 醇殘基’經過魏氧基結合。因此，例如，二竣酸殘基可衍 生自二羧酸單體或其有關聯之酸鹵化物、酯類、鹽類、酐 類及/或其混合物。再者，於本文中使用之”二酸"一詞包括 多官能性酸類，例如分枝劑。因此，於本文中使用之"二 羧酸” 一詞，係意欲包括二羧酸類與二羧酸之任何衍生 物，包括其有關聯之酸鹵化物、酯類、半酯類、鹽類、半 鹽類、酐類、混合酐類及/或其混合物，其可用於與二醇 119732.doc -204- 200804457 之反應方法中，以製造聚酯。於本文中使用之"對苯二甲 酸”-詞係意欲包括對苯二甲酸本身，及其殘基，以及對 苯二甲酸之任何衍生物，包括其有關聯之酸齒化物、酯 類、㈣自、鹽類、半鹽類、肝類、混合針類及/或其混 合物或其殘基，可用於與二醇之反應方法中，以製造聚 於本發明中使用之聚酯典型上可製自二羧酸類與二醇 類，其係以實質上相等比例反應，且係以其相應殘基被併 入聚酯聚合體中。目&，本發明之聚醋彳含有冑質上相等 莫耳比例之酸殘基（100莫耳％)與二醇（及/或多官能性羥基 化合物）殘基（100莫耳％)，以致重複單位之總莫耳數係等 於100莫耳％。因此，於本發明揭示内容中所提供之莫耳 百刀比可m夂殘基之總莫耳數、二醇殘I之總莫耳數或重 複單位之總莫耳數為基準。例如，含有30莫耳。間苯二甲 酸2聚醋，以總酸殘基為基準，係意謂聚酯含有30莫耳％ 間苯二甲酸殘基，纟自總計100莫耳％酸殘基。因此，在 每1〇〇莫耳酸殘基中，有3G莫耳間苯二甲酸殘基。在另一 項實例中，含有30莫耳％ 2,2，认四甲基_U3_環丁二醇之 聚知以總一醇殘基為基準，係意謂聚酯含有3 0莫耳％ 2=，4,4·四甲基環丁二醇殘基，來自總計1〇〇莫耳％二 醇殘基。因此，在每1〇〇莫耳二醇殘基中，有％莫耳 2,2,4,4_四甲基-^-環丁二醇殘基。 於本發明之直 八他方面，可用於本發明聚酯組合物之聚 酉曰其Tg可為下列範圍之至少一個·· 60至2〇(TC ; 60至 119732.doc 200804457 190°C ; 60至 180°C ; 60至 170°C ; 60至 160°C ; 60至 155°C ; 60 至 150°C ; 60 至 145°C ; 60 至 140°C ; 60 至 138°C ; 60 至 135°C ; 60至 130°C ; 60至 125°C ; 60至 120°C ; 60至 115°C ; 60 至 110°C ; 60 至 105°C ; 60 至 100°C ; 60 至 95°C ; 60 至 90°C ; 60至 85°C ; 60至 80°C ; 60至 75°C ; 65 至 200°C ; 65 至 190°C ; 65 至 180°C ; 65 至 170°C ; 65 至 160°C ; 65 至 155°C ; 65 至 150°C ; 65 至 145°C ; 65 至 140°C ; 65 至 138°C ; 65 至 135°C ; 65 至 130°C ; 65 至 125°C ; 65 至 120°C ; 65 至 115°C ; 65 至 110°C ; 65 至 105°C ; 65 至 100°C ; 65 至 95°C ; 65 至 90°C ; 65 至 85°C ; 65 至 80°C ; 65 至 75°C ; 70至 200°C ; 70至 190°C ; 70至 18(TC ; 70至 170°C ; 70至 160°C ; 70至 155°C ; 70 至 150°C ; 70 至 145°C ; 70 至 140°C ; 70 至 138°C ; 70 至 135°C ; 70至 130°C ; 70至 125°C ; 70至 120°C ; 70至 115°C ; 70 至 110°C ; 70 至 105°C ; 70 至 l〇(TC ; 70 至 95°C ; 70 至 90°C ; 70至 85°C ; 70至 80°C ; 70至 75°C ; 75 至 200。(3 ; 75 至 190°C ; 75 至 180°C ; 75 至 170°C ; 75 至 160°C ; 75 至 155°C ; 75 至 150°C ; 75 至 145°C ; 75 至 140°C ; 75 至 138°C ; 75 至 135°C ; 75 至 130°C ; 75 至 125°C ; 75 至 120°C ; 75 至 115。〇 ; 75 至 110°C ; 75 至 105°C ; 75 至 1〇〇。〇 ; 75 至 95°C ; 75 至 90°C ; 75 至 85°C ; 75 至 80°C ; 80 至 200°C ; 80 至 190°C ; 80 至 180°C ; 80 至 170°C ; 80 至 160°C ; 80 至 155°C ; 80 至 150°C ; 80至 145°C ; 80至 140°C ; 80至 138。〇 ; 80至 135°C ; 80 至 130°C ; 80 至 125°C ; 80 至 120°C ; 80 至 U5°C ; 80 至 110°C ; 80至 l〇5°C ; 80至 100t： ; 80至 95°C ; 80至 90°C ; 80 119732.doc 206- 200804457 至 85°C ; 85 至 200°C ; 85 至 190°C ; 85 至 180°C ; 85 至 170°C ; 85 至 160°C ; 85 至 155°C ; 85 至 150〇C ; 85 至 145°C ; 85 至 140°C ; 85 至 138°C ; 85 至 135°C ; 85 至 130°C ; 85 至 125°C ; 85 至 120°C ; 85 至 115°C ; 85 至 110°C ; 85 至 105°C ; 85 至 100°C ; 85 至 95°C ; 85 至 90°C ; 90 至 200°C ; 90 至 190°C ; 90至 180°C ; 90至 170°C ; 90至 160°C ; 90至 155°C ; 90 至 150°C ; 90 至 145°C ; 90 至 140°C ; 90 至 138°C ; 90 至 135°C ; 90至 130°C ; 90至 125°C ; 90至 120°C ; 90至 115°C ; 90 至 ll〇t： ; 90 至 105它；90 至 100t： ; 90 至 95t： ; 95 至 200°C ; 95 至 190°C ; 95 至 180°C ; 95 至 170°C ; 95 至 160°C ; 95 至 155°C ; 95 至 150°C ; 95 至 145°C ; 95 至 140°C ; 95 至 138°C ; 95 至 135°C ; 95 至 130°C ; 95 至 125°C ; 95 至 120°C ; 95 至 115°C ; 95 至 110°C :;95 至 105°C ;95 至 100°C ; 100至 200°C 100 至 190°C 100 至 180°C ; 100 至 170°C ; 100至 160°C 100 至 155〇C 100 至 150°C ; 100 至 145〇C ; 100至 140°C 100 至 138〇C 100 至 135〇C ; 100 至 130°C ; 100至 125〇C 100 至 120〇C 100 至 115〇C ; 100 至 110°C ; 105至 200°C 105 至 190〇C 105 至 180°C ; 105 至 170°C ; 105至 160°C 105 至 155°C 105 至 150°C ; 105 至 145〇C ; 105至 140°C 105 至 138〇C 105 至 135〇C ; 105 至 130〇C ; 105至 125〇C 105 至 120°C 105 至 115°C ; 105 至 110〇C ; 110至 200°C 110 至 190〇C 110 至 180〇C ; 110 至 170°C ; 110至 160°C 110 至 155〇C 110 至 150〇C ; 110 至 145〇C ; 110至 140°C 110 至 138〇C 110 至 135〇C ; 110 至 130°C ; 110至 119732.doc -207- 200804457Hi) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: i) 1 to 99 mol% of 2, 2, 4, a 4-tetramethyl-1,3-cyclobutanediol residue; and Π) 1 to 99 mol% of a cyclohexanedimethanol residue; wherein the diol component/dicarboxylate added in the step (I) The molar ratio of the acid component is from 1.05 to 1.15 / 1.0; wherein the mixture in the step (I) is heated in the presence of at least one catalyst comprising at least one tin compound, and, if desired, at least one selected from the group consisting of titanium , gallium, zinc, antimony, cobalt, bell, magnesium, antimony, lithium, aluminum compounds and aluminum compounds with a hydroxide or sodium hydroxide catalyst; (Π) the product of step (I) at 250 to 305 ° C a temperature, at least one selected from the group consisting of a final pressure from the step (I) to a pressure in the range of 〇·〇 2 Torr (absolute pressure) and at least one heat stabilizer selected from the group consisting of at least one bowl compound's reaction product and a mixture thereof Heating for 1 to 6 hours; wherein the total mole % of the dicarboxylic acid component of the final polyester is 100% by mole, and the final polyester is The total ingredient mole billion /. Is 1% molar %; wherein when measured at 25 ° C in 60/40 (w/w) phenol/tetrachloroethane at a concentration of 25 g / 50 ml, the final poly The inherent viscosity of vinegar is from 0.35 to 1.2 com/g; and wherein the final 119732.doc-167-200804457 polyester has a Tg of 85 to 200 °C. In one aspect, the invention relates to a method of making any of the polyesters suitable for use in the present invention, comprising the steps of: (1) at least one selected from the group consisting of 150 to 25 (at least one temperature of TC and selected from 〇 to 75 psig) Heating a mixture under pressure, wherein the mixture comprises: U) a dicarboxylic acid component comprising: i) 70 to 1 mole % terephthalic acid residue; 11) 0 to 30 mole % aromatic a dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic diacidic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: i) 1 to 99 mol% of 2,2,4,4·tetramethyl-1,3-cyclobutanediol residues; and ii) 1 to 99 mol% of cyclohexanedimethanol residue; Wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is from 1.0 to 1.5/1.0; wherein the mixture in the step (I) is heated in the presence of: (1) at least At least one catalyst of a tin compound, and, if necessary, at least one selected from the group consisting of titanium, gallium, zinc, lanthanum, cobalt, lanthanum, zheng, erh, zhong, shun, and a catalyst with cesium hydroxide or sodium hydroxide; and (ii) at least one heat stabilizer selected from at least one phosphorus compound, a reaction product thereof, and a mixed character thereof; ° 119732.doc -168- 200804457 (II) The product of step (I) is heated at a temperature of from 23 to 320 ° C and at least one pressure selected from the final pressure of step (I) to a pressure in the range of 0.02 Torr (absolute pressure) for 1 to 6 hours to form the final polyester. Wherein the total mole % of the dicarboxylic acid component of the final polyester is 1 Torr. /〇, and the total molar % of the diol component of the final polyester is 1 〇〇 mol %; wherein in 60/40 (w/w) phenol/tetrachloroethane, 0.25 g / 50 ml At the concentration, the final polyester has an intrinsic viscosity of from 35 to 1.2 deg/g as measured at 25 ° C; and wherein the final polyester has a Tg of from 85 to 200 ° C. In one aspect, the invention relates to a method of making any of the polyesters suitable for use in the present invention, comprising the steps of: (I) at least one temperature selected from 150 to 250 ° C and selected from 0 to 75 Psig Heating a mixture under at least one pressure, wherein the mixture comprises (a) a dicarboxylic acid component comprising: i) 70 to 1 Torrole/0 terephthalic acid residue; ii) 0 to 30 a molar aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) two An alcohol component comprising: i) from 1 to 99 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and ii) from 1 to 99 mol% of cyclohexane An alkane dimethanol residue; wherein the molar component of the diol component/dicarboxylic acid component added in the step (I) is 119732.doc • 169-200804457, and the ratio is 1.05·1.15/1·〇; wherein the step (I) The mixture is heated in the presence of the following materials to form a polyester: (i) at least one catalyst comprising at least one tin compound, and, if desired, at least one selected from the group consisting of titanium, gallium, zinc, antimony, a catalyst of manganese, magnesium, strontium, lithium, an aluminum compound and an aluminum compound with lithium hydroxide or sodium hydroxide; and (Π) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof (II) heating the product of step (I) at a temperature of from 230 to 320 ° C and at least one pressure selected from the final pressure of step (I) to a pressure within the range of 0.02 Torr (absolute pressure) for 1 to 6 hours. Forming a final polyester; wherein the total mole % of the dicarboxylic acid component of the final polyester is 1% molar %, and the total molar % of the diol component of the final polyester is 100 moles / 〇; Wherein the final polyester has an intrinsic viscosity of 0.35 to 1.2 when measured at 25 ° C in 60/40 (w/w) phenol/tetrachloroethane at a concentration of 25 g / 50 ml. Male/g; and wherein the final polyester has a Tg of 85 to 200 °C. In one aspect, the invention relates to a method of making any of the polyesters suitable for use in the present invention, comprising the steps of: (I) at a temperature selected from the group consisting of at least 150 to 250 ° C and selected from the group consisting of 〇 to 75 psig. Heating a mixture under at least one pressure, wherein the mixture comprises: (a) a tannin component comprising: 〇70 to 100 mol% of terephthalic acid residues; 11) 0 to 30 mol% of aromatics a dicarboxylic acid residue having a maximum of 2〇119732.doc -170-200804457 carbon atoms; and iii) 〇 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 碳 carbon atoms; and (b) a diol component comprising: i) from 1 to 99 mol% of 2,2,4,4-tetramethyl^cyclobutanediol residues; and ii) from 1 to 99 mol% of cyclohexane a methanol residue; wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is 1·(Μ·5/1.〇; wherein the mixture in the step (I) is in the following Heating in the presence of at least one catalyst comprising at least one tin compound, and, if desired, at least one selected from the group consisting of titanium, gallium, zinc, antimony, cobalt, manganese, magnesium, strontium, lithium, a compound and an aluminum compound with a catalyst of lithium hydroxide or sodium hydroxide; (Π) the product of step (1) at a temperature of from 230 to 320 Torr, at least one selected from the final pressure of step (I) to 〇〇 2 Torr (absolute pressure) Heating in the presence of at least one pressure stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof for 1 to 6 hours to form a polyester; wherein the total amount of the dicarboxylic acid component of the final polyester The molar % is 1% mol%, and the total molar % of the diol component of the final polyester is 1% mol%; wherein when 60/40 (w/w) phenol/tetrachloroethane The intrinsic viscosity of the final polyester is 〇35 to 1.2 com/g at a concentration of 0.25 g / 50 ml, and the final 119732.doc -171 - 200804457 polyester Having a Tg of from 85 to 200 ° C. In one aspect, the invention relates to a process for making any of the polyesters suitable for use in the invention, comprising the steps of: (I) at least one selected from the group consisting of 150 to 250 ° C Heating the mixture with at least one pressure selected from the group consisting of 〇 to 75...匕The composition comprises: (a) a dicarboxylic acid component comprising: i) 70 to 100 mol% of terephthalic acid residues; ii) 0 to 30 mol% of aromatic dicarboxylic acid residues, having a high 2 碳 one carbon atom; and iii) 0 to 10 mol% of the aliphatic dicarboxylic acid residue having a maximum of 16 broken atoms; and (b) a diol component comprising: i) 1 to 99 mol% a 2,2,4,4-tetramethyl-1,3-cyclobutanediol residue; and ii) 1 to 99 mol% of a cyclohexanedimethanol residue; wherein the step (I) is added The molar ratio of the diol component/dicarboxylic acid component is 1.05-1.15/1.0; wherein the mixture in the step (I) is heated in the presence of at least one catalyst comprising at least one tin compound, and Desirable, at least one catalyst selected from the group consisting of titanium, gallium, zinc, antimony, cobalt, short, zhen, y, y, ming and Ming compounds with hydrazine hydroxide or sodium hydroxide; (II) the product of step (I) At a temperature of 230 to 320 ° C, at least one selected from the final pressure of step (I) to 0.02 Torr (absolute pressure) of 119732.doc -172-200804457 pressure and at least one selected Heating in the presence of at least one compound, its reaction product, and a mixture thereof in the presence of a heat stabilizer for 1 to 6 hours to form a polyester; wherein the total mole % of the dicarboxylic acid component of the final polyester is 1 mole %, and the total molar % of the diol component of the final polyester is 1% mol%; wherein when 60/40 (w/w) phenol/tetrachloroethane, 〇·25 g/5 The intrinsic viscosity of the final polyester is 〇35 to 1_2 com/g when measured at 25 ° C; and wherein the final polyester has a Tg of 85 to 200 ° C. In one aspect, the invention relates to a method of making any of the polyesters suitable for use in the present invention, comprising the steps of: (I) at a temperature selected from the group consisting of at least 150 to 250 ° C and selected from the group consisting of 〇 to 75 psig. Heating a mixture under at least one pressure, wherein the mixture comprises: (a) a dicarboxylic acid component comprising: i) 70 to 1 mole. /0 terephthalic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of aliphatic dicarboxylic acid a residue having up to 16 carbon atoms; and (b) a diol component comprising: i) from 1 to 99 mol% of 2,2,4,4-tetramethyl·1,3-cyclobutanediol a residue; and ii) from 1 to 99 mol% of a cyclohexanedimethanol residue; wherein the ratio of the diol component/dicarboxylic acid component of the diol component to the step (I) is 119732.doc-173-200804457 1.0-1.5/1.0; wherein the mixture in step (I) is heated in the presence of (i) at least one catalyst comprising at least one tin compound, and at least one selected from the group consisting of: Recording, recording, and recording of 'Clock, Town, Wrong, Bell, Ming compounds and Ming compounds with hydroxide or sodium hydroxide catalysts; and (ii) at least one heat stabilizer selected from at least one scale compound a product and a mixture thereof; (II) the product of step (I) at a temperature of from 230 to 320 ° C and at least one selected from the final pressure from step (I) to 〇. 〇 2 Torr (absolutely Heating for 1 to 6 hours under pressure within the range of force) to form the final polyester; wherein the total mole % of the dicarboxylic acid component of the final polyester is 1% molar %, and the final polyester diol The total molar % of the ingredients is 100% by mole, which is measured at 25 ° C in a concentration of 〇 25 g / 50 ml at 60 / 40 (w/w) The final polyester has an intrinsic viscosity of 〇35 to 1.2 com/g; and wherein the final polyester has a Tg of 85 to 200 °C. In one aspect, the invention is directed to a method of making any polyester suitable for use in the present invention comprising the steps of: (I) at a temperature selected from the group consisting of at least 150 to 200 ° C and selected from 〇 to 75 psig < heating a mixture under at least one pressure, wherein the mixture comprises: (a) a di-acidic acid component comprising: 0 70 to 100 mol% of terephthalic acid residues; ii) 0 to 30 mol% An aromatic dicarboxylic acid residue having a maximum of 2〇119732. Doc -174- 200804457 carbon atoms; and iii) 0 to 10 mol% of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) - drunk ingredients' containing: i) 1 to 99 Molar % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residue; and ii) 1 to 99 moles. a cyclohexane dimethanol residue of hydrazine; wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is 1.05_1·15/1·0; wherein the step (I) The mixture is heated in the presence of (i) at least one catalyst comprising at least one tin compound, and, if desired, at least one selected from the group consisting of titanium, gallium, zinc, lanthanum, cobalt, Ig, town, lanthanum, bell And a catalyst for oxidizing a clock or a sodium hydroxide; and (ii) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; (Π) the step (I) The product is at a temperature of from 230 to 320 ° C and at least one selected from the final pressure from step (I) to zero. Heating at a pressure within the range of 02 Torr (absolute pressure) for 1 to 6 hours to form a final polyester; wherein the total molar % of the final sulphuric acid component of the final vinegar is 1 〇〇 mol/°, and The total molar % of the diol component of the final polyester is 100 mol%; wherein, in 60/40 (w/w) phenol/tetra-ethane, at 0. At 25 g / 50 ml, the final polyester has an intrinsic viscosity of 0. 35 to 1.2 cm / gram; and the final 119,732. Doc -175- 200804457 Polyester has a Tg of 85 to 200 °C. In one aspect, the invention relates to a method of making any of the polyesters suitable for use in the present invention, comprising the steps of: (I) at a temperature selected from the group consisting of at least one of 150 to 200 ° C and selected from the group consisting of 〇 to 75 psig. Heating a mixture under at least one pressure, wherein the mixture comprises: (a) a dicarboxylic acid component comprising: i) 70 to 100 mol% of terephthalic acid residues; ii) 0 to 30 mol% An aromatic diwei acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic diremediate residue having up to 16 carbon atoms; and (b) a diol component, It comprises: i) 1 to 99 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and ii) 1 to 99 mol% of cyclohexane a methanol residue; wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is 1. 0-1. 5/1. 0; wherein the mixture in the step (I) is heated in the presence of: (i) at least one catalyst comprising at least one tin compound, and, if desired, at least one selected from the group consisting of titanium, gallium, zinc, and , violent, magnesium, cerium, lanthanum, aluminum compound and catalyst of the compound with hydrazine hydroxide or sodium hydroxide; (II) the product of step (1) at a temperature of 230 to 320 ° C, at least one selected from the step (I) The final pressure is 119732 in the range of 0_02 Torr (absolute pressure). Doc -176- 200804457 Heating in the presence of pressure and at least one heat stabilizer selected from at least one phosphorus compound, its reaction product and mixtures thereof! to 6 hours; Wherein the total mole % of the dicarboxylic acid component of the final polyester is (10) Mo' and the total molar % of the diol component of the final polyester is 1 〇〇 Mo / / Nakata at 60 / 40 (weight / The weight of the phenol/tetrachloroethane in the concentration of 〇·25g/50ml, when measured under the restraint, the intrinsic viscosity of the final poly _ is 35 to 12 com/g; and the final The ^^ design has 85 to 200. Tg of Tg. In one aspect, the invention relates to a method of making any of the polyesters suitable for use in the present invention, comprising the steps of: (I) at least one temperature selected from 150 to 200 ° C and at least one selected from the group consisting of 〇 to 75 psig Heating a mixture under pressure, wherein the mixture comprises: (a) a dicarboxylic acid component comprising: i) 70 to 1 Torrole/0 terephthalic acid residue; ii) 0 to 30 moles % of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic di-retensive acid residue having up to 16 carbon atoms; and (b) a diol a composition comprising: i) from 1 to 99 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and ii) from 1 to 99 mol% of cyclohexane a dimethanol residue; wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is 1. 05-1. 15/1. 0; 119732. Doc-177-200804457 wherein the mixture in step (i) is hot-spotted in the presence of at least one catalyst comprising at least one tin compound, and, if desired, at least one selected from the group consisting of titanium, gallium, zinc , recording, abundance, magnesium, strontium, chime, Ming compound and Ming compound with chlorine oxidation clock or sodium hydroxide catalyst; (II) the product of step (I) at a temperature of 230 to 320 ° C, at least _ It is selected from the final pressure of step (I) to 0. Heating in the presence of a pressure in the range of 02 Torr (absolute pressure) and at least one heat stabilizer selected from at least one compound, its reaction product, and mixtures thereof for 6 hours; wherein the final polyester dicarboxylic acid component The total molar % is 1 〇〇 mol % 'and the total molar % of the diol component of the final polyester is 1 〇〇 mol %; wherein when 60/40 (w/w) phenol / tetrachloroethylene In the alkane, the intrinsic viscosity of the final polyester is 0. at a concentration of 25 g / 50 ml at 25 ° C. 35 to 1. 2 metrics/gram; and wherein the final polyester has a Tg of 85 to 200 °C. In one aspect, the invention relates to a method of making any of the brews suitable for use in the present invention, comprising the steps of: (1) at least one temperature selected from I50 to 200 ° C and at least one selected from the group consisting of 〇 to 75 psig Heating a mixture under pressure, wherein the mixture comprises: (a) a dicarboxylic acid component comprising: i) 70 to 1 mole of terephthalic acid / hydrazine terephthalic acid residue; ii) 0 to 30 mole % An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having a maximum of 16 119,732. Doc -178- 200804457 carbon atoms; and (b) diol components comprising: i) 1 to 99 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues And ii) 1 to 99 mol% of a cyclohexanedimethanol residue; wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is 1·〇·1·5/ Hey. 其中; wherein the mixture in step (I) is heated in the presence of (i) at least one catalyst comprising at least one tin compound, and 'optionally, at least one selected from the group consisting of chin, face ►, rhetoric, a catalyst of sulphur, sulphur, sulphur, sulphur, sulphur, sulphur, sulphur, and sulphuric acid; and (ii) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; (II) heating the product of step (I) at a temperature of from 250 to 305 ° C and at least one pressure selected from the final pressure of step (I) to a pressure within a range of 〇 2 Torr (absolute pressure) Up to 6 hours to form a final polyester; wherein the total mole % of the dicarboxylic acid component of the final polyester is 1% mol%, and the total mole % of the diol component of the final polyester is 1〇 〇莫耳°/〇; which is in 60/40 (w/w) phenol/tetrachloroethane, at 0. The final polyester has an intrinsic viscosity of 〇·35 to 1. when measured at 25 ° C at a concentration of 25 g / 50 ml. 2 metrics/gram; and wherein the final polyester has a Tg of 85 to 200 °C. In one aspect, the invention relates to a manufacturing 119732 which is suitable for use in the present invention. Doc-179-200804457 A method of polyester, comprising the steps of: (I) heating a mixture at a temperature selected from the group consisting of at least one temperature of from 150 to 200 ° C and at least one pressure selected from the group consisting of 〇 to 75 psig, wherein the mixture The invention comprises: (a) a dicarboxylic acid component comprising: i) 70 to 100 mol% of a terephthalic acid residue; ii) 0 to 30 mol% of an aromatic dicarboxylic acid residue having a maximum of 2〇 And iii) 0 to 10 mol% of the aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: i) 1 to 99 mol% of 2 , 2,4,4-tetramethyl-1,3·cyclobutanediol residue; and ii) 1 to 99 mol% of cyclohexanedimethanol residue; wherein the second is added in step (I) The molar ratio of the alcohol component/dicarboxylic acid component is 1.05_1·15/1. 0; wherein the mixture in step (I) is heated in the presence of (i) at least one catalyst comprising at least one tin compound, and, if desired, at least one selected from the group consisting of titanium, gallium, zinc, bismuth, cobalt , a catalyst of sulphur, hydrazine, hydrazine, hydrazine, hydrazine, and a compound of a hydrazine or a sodium hydroxide; and (ii) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture; (II) the product of step (I) at a temperature of from 250 to 305 ° C and at least one selected from the final pressure of step (I) to 0. 02 Torr (absolute pressure) within the range of 119,732. Doc -180- 200804457 Heating under pressure for 1 to 6 hours to form the final polyester; wherein the total mole % of the dicarboxylic acid component of the final polyester is 1% mol%, and the final polyester diol The total amount of ingredients. /. Is 1% molar; wherein when in 60/40 (w/w) phenol/tetrachloroethane, at 0. The final polyester has an intrinsic viscosity of 〇35 to 1. at a concentration of 25 g/50 ml at 25 °C. 2 metrics/gram; and wherein the final polyester has a Tg of 85 to 200 °C. In one aspect, the invention relates to a method of making any of the polyesters suitable for use in the present invention, comprising the steps of: (I) at a temperature selected from the group consisting of at least 150 to 200 ° C and selected from 0 to 75 psig Heating a mixture under at least one pressure, wherein the mixture comprises: (a) a dicarboxylic acid component comprising: i) 70 to 1 mole % terephthalic acid residue; ii) 0 to 30 mole % An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and in) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component, It comprises: i) from 1 to 99 mol% of 2,2,4,4-tetradecyl-1,3-cyclobutanediol residues; and Π) from 1 to 99 mol% of cyclohexanedimethanol a residue; wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is 1. 0-1. 5/1. 0; wherein the mixture in step (I) is added 119,732 in the presence of the following materials. Doc -181 - 200804457 Heat - at least one catalyst comprising at least one tin compound, and, if desired, at least one selected from the group consisting of titanium, gallium, zinc, lanthanum, cobalt, manganese, magnesium, lanthanum, lithium, aluminum compounds and aluminum compounds a catalyst of lithium hydroxide or sodium hydroxide; (Π) the product of step (1) at a temperature of from 25 Torr to 3 〇 5 aC, at least one selected from the final pressure of step (I) to 〇〇 2 Torr (absolute pressure) Heating at a pressure of at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof for 1 to 6 hours; wherein the total mole % of the dicarboxylic acid component of the final polyester is 1〇〇 Mohr%' and the total molar % of the diol component of the final polyester is 1 〇〇mol, which is in 60/40 (w/w) phenol/tetrachloroethane at 〇·25 g/50 At the concentration of cc, the intrinsic viscosity of the final polyester is 〇35 to 1.2 cm/g at the time of measurement; and wherein the final polyester has a Tg of 85 to 200 °C. In one aspect, the invention is directed to a method of making any of the poly(s) suitable for use in the present invention comprising the steps of: (I) at a temperature selected from the group consisting of at least 150 to 200 ° C and selected from 〇 to 75 psig. Heating a mixture under at least one pressure, wherein the mixture comprises: Ο) a dicarboxylic acid component comprising: i) 70 to 1 mole % terephthalic acid residue; 11) 0 to 30 mole % An aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and 119,732. Doc -182- 200804457 (b) a monool component comprising: 0 to 99 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and U) 1 Up to 99% by mole of cyclohexanedimethanol residue; wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is 1. 05-1. 15/1. 0; wherein the mixture in the step (I) is heated in the presence of at least one catalyst comprising at least one tin compound, and 'optionally, at least one selected from the group consisting of titanium, gallium, yttrium, lanthanum, cobalt, manganese, a catalyst of magnesium, lanthanum, lithium, an aluminum compound and an aluminum compound with lithium hydroxide or sodium hydroxide; (π) the product of step (1) at a temperature of from 250 to 305 cc, at least one selected from the final pressure of step (I) to 〇 Heating in the presence of a pressure in the range of 托 2 Torr (absolute pressure) and at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, its reaction product and mixtures thereof for 1 to 6 hours; wherein the final polyester dicarboxylic acid The total molar % of the ingredient is 1% mol%, and the total molar % of the diol component of the final polyester is 1% mol%; wherein when 60/40 (w/w) phenol/four In the gaseous ethane, the intrinsic viscosity of the final polyester is 0 when measured at a concentration of 0.25 g/5 0 liters at 25 C. 35 to 1. 2 metrics/gram; and wherein the final polyester has a Tg of 85 to 200 °C. In one aspect, the invention relates to a method of making any of the polyesters suitable for use in the present invention comprising the steps of: (I) at a temperature selected from the group consisting of at least 150 to 200 ° C and selected from the group consisting of 〇 to 75 psig. 119732. Doc-183-200804457 Heating a mixture under at least one pressure, wherein the mixture comprises: (a) a dicarboxylic acid component comprising: 1) 70 to 1 mole % terephthalic acid residue; ii) 0 Up to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and ill) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; a diol component comprising: i) from 1 to 99 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and ii) from 1 to 99 mol% a cyclohexane dimethanol residue; wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is 1. 0-1. 5/1. 0; wherein the mixture in the step (I) is heated in the presence of (0) at least one catalyst comprising at least one tin compound, and 'optionally, at least one selected from the group consisting of titanium, gallium, zinc, antimony, cobalt, a catalyst of lanthanum, magnesium, lanthanum, lithium, an aluminum compound and an aluminum compound with lithium hydroxide or sodium hydroxide; and (ii) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof (Π) the product of step (1) at a temperature of from 230 to 320 ° C and at least one selected from the final pressure of step (1) to 0. Heating in the range of 02 Torr (absolute pressure) for 1 to 6 hours to form the final polymerization; wherein the total mole % of the second polyester of the final polyester is 100 Å. Doc 200804457 〇 忒 、 、 、 ; ; 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯 聚酯. At a concentration of 25 g / 503⁄4 liter, the intrinsic viscosity of the final vinegar is 〇 when measured at 25. 35 to 12 metrics/gram; and wherein the final polyester has 85 to 200. (Tg of 3) In one aspect, the invention relates to a method of making any of the polyesters suitable for use in the present invention, comprising the steps of: (I) at least one temperature selected from 15 Torr to 200 C and selected from hydrazine Heating a mixture under at least one pressure of 75 psig, wherein the mixture comprises: (a) a dicarboxylic acid component comprising: i) 70 to 1 mole % terephthalic acid residue; ii) 0 to 30 mole % of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mole % of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: i) from 1 to 99 mole % of 2,2,4,4-tetramethyl-1,3.cyclobutanediol residue; and ii) from 1 to 99 mole percent of ring a di-methanol residue; wherein the molar ratio of the diol component/dicic acid component added in the step (I) is 1 · 0 5 -1 · 1 5 /1 · 0; wherein the cerium (I) The mixture is heated in the presence of the following materials to form a polyester: (i) at least one 119732 comprising at least one tin compound. Doc -185- 200804457 a catalyst, and, if desired, at least one catalyst selected from the group consisting of titanium, gallium, zinc, lanthanum, cobalt, manganese, magnesium, lanthanum, lithium, aluminum compounds and aluminum compounds with lithium hydroxide or sodium hydroxide; And (ii) at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, a reaction product thereof, and a mixture thereof; (II) the product of step (I) at a temperature of from 230 to 320 ° C and at least one selected from the group consisting of The final pressure of step (I) is 0. Heating at a pressure within the range of 02 Torr (absolute pressure) for 1 to 6 hours to form a final polyester; wherein the total mole % of the dicarboxylic acid component of the final polyester is 1 〇〇 mol %, and the final poly The total molar % of the diol component of the ester is 1% mol%; wherein in 60/40 (w/w) phenol/tetrachloroethane, at a concentration of 〇25 g/50 ml, When measured at 25 ° C, the final polyester has an intrinsic viscosity of 〇·35 to 1. 2 metrics/gram; and wherein the final polyester has a Tg of 85 to 200 °C. In one aspect, the invention relates to a method of making any t S曰 suitable for use in the present invention comprising the steps of: (I) at a temperature selected from the group consisting of at least 150 to 200 ° C and selected from 〇 to 75 psig Heating a mixture under at least one pressure, wherein the mixture comprises: (a) a diacid component comprising: 1) 70 to 1 mole % terephthalic acid residue; ii) 0 to 30 moles % of an aromatic dicarboxylic acid residue having up to one carbon atom; and ill) from 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to b carbon atoms; and 119,732. Doc 200804457 (b) a diol component comprising: i) from 1 to 99 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and ii) from 1 to 99 a cyclohexane dimethanol residue of molybdenum/ruthenium; wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is 1. 0-1. 5/1. 0; wherein the mixture in the step (I) is heated in the presence of at least one catalyst comprising at least one tin compound, and, if desired, at least one selected from the group consisting of titanium, gallium, zinc, lanthanum, cobalt, lanthanum, a catalyst of a town, a hydrazine, a bell, a compound, a compound, and a hydroxide or a sodium hydroxide; (II) a product of the step (I) at a temperature of from 230 to 320 ° C, at least one selected from the group consisting of the step (I) The final pressure is 0. Heating in the presence of a pressure in the range of 02 Torr (absolute pressure) and at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, its reaction product, and mixtures thereof to form a polyester; wherein the final polyester The total molar % of the dicarboxylic acid component is i〇〇 mol %, and the total molar % of the diol component of the final polyester is 100 mol %; wherein when 60/40 (w/w) phenol/ In tetrachloroethane, the intrinsic viscosity of the final polyester is 〇·35 to 1. when measured at 25 ° C at a concentration of 25 g / 50 ml. 2 metrics/gram; and wherein the final polyester has a Tg of 85 to 200 °C. In one aspect, the invention is directed to a method of making any of the polyesters suitable for use in the present invention comprising the following steps: 119732. Doc -187- 200804457 (I) heating a mixture at a temperature selected from at least one of 150 to 200 C and at least one pressure selected from the group consisting of 〇 to 75 psig, wherein the mixture comprises (a) a dicarboxylic acid component, Containing ·· i) 70 to 100 mol% of terephthalic acid residues; ii) 0 to 30 mol% of aromatic dicarboxylic acid residues having up to one carbon atom; and iii) 〇 to ίο莫% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: i) 1 to 99 mole % of 2,2,4,4-tetramethyl-ring a butanediol residue; and ii) from 1 to 99 mol% of a cyclohexanedimethanol residue; wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is 1. 05-1. 15/1. 0; wherein the mixture in the step (I) is heated in the presence of at least one catalyst comprising at least one tin compound, and 'optionally, at least one selected from the group consisting of titanium, gallium, zinc, lan, ming, yan, a catalyst of magnesium, pentane, hexagram, sulphate compound and sulphuric acid with sodium hydroxide or sodium hydride; (II) the product of step (I) at a temperature of 230 to 320 ° C, at least one selected from the step (I) The final pressure is 0. Heating in the presence of a pressure in the range of 02 Torr (absolute pressure) and at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, its reaction product and mixtures thereof for 1 to 6 hours to form a polymer; 119,732. Doc • 188- 200804457 wherein the total mole % of the dicarboxylic acid component of the final polyester is 100 mole %, and the total mole % of the diol component of the final polyester is 100 mole %, wherein at 60 /40 (w/w) phenol/tetra-ethane, at 0. The final polyester has an intrinsic viscosity of 〇35 to 12 com/g when measured at 251 at a concentration of 25 g/50 ml; and wherein the final polyester has a Tg of 85 to 20 〇 °C. In one aspect, the τ used in the present invention contains at least one phosphorus compound which acts as a heat stabilizer anyway. In one aspect, the polyester composition of the present invention contains at least one polycarbonate. In one aspect, the polyester composition of the present invention does not contain a polycarbonate. In one aspect, the polyester useful in the present invention contains less than 15 mole % ethylene glycol residues, such as 0. 01 to less than 15 mole % ethylene glycol residue. The polyester useful in the present invention contains an ethylene glycol residue. In one aspect, the polyester useful in the present invention does not contain ethylene glycol residues. The polyester useful in the present invention contains 50 to 99. 99 mole % B - leave residue. In one aspect, the polyester useful in the present invention does not contain a branching agent, or at least one of the branching agents is added prior to or during the polymerization of the polyester. In one aspect, the polyester useful in the present invention contains at least one branching agent, regardless of the method or sequence in which it is added. In one aspect, the polyesters useful in the present invention are prepared from 1,3-propanediol or 1,4-butanediol, either alone or in combination. In other aspects, hydrazine, 3-propanediol or 1'4-butanol, either alone or in combination, can be used in the manufacture of 119,732. Doc 200804457 A polyester used in the present invention. One aspect can be used in the polyester of the present invention. Μ莫耳% B A leaven residue. In the aspect of the present invention, it can be used in the specific aspect of the present invention, and the Mole% system of 4,4,f,j,3'3,butanediol is greater than MoM%, or greater than 55 Mo. Ear % cis _2,2,4,4_tetramethyl^cyclobutanediol or greater than 7 〇 mol % cis · 2,2,4,4-tetramethyl _U·cyclobutanediol; Wherein the total molar percentage of cis·2,2,4/-tetramethyldeca-3-cyclobutanediol and trans-μ〆〆·tetramethyl-1,3-cyclobutanediol is equal to the total (10) Moer%. In the aspect of the present invention, the oxime 2,2,4,4-tetramethyl], 3:cyclobutanediol isomer of the specific polyacetic acid of the present invention is 30 to 70 moles. Cis·2,2,4,4·tetramethyl·; ι, 3_cyclobutanediol or 3() to 7() Mo.乂 弋 弋 '2,4,4 tetramethyl-1,3-cyclobutanediol; or 4 〇 to 6 〇 mol% of cis '2,4,4 methyl _ι, 3 _ ring butyl Alcohol or 4 〇 to 6 〇 mol% of trans 2,2,4,4·tetramethyl-1,3·cyclobutanediol; wherein cis 2,2,4,4-tetramethyl The total molar percentage of -1,3-cyclobutanediol to trans-2,2,4,4tetramethylcyclobutanediol is equal to a total of 100 moles/0. In one aspect, certain of the polyesters useful in the present invention are amorphous or semi-zeissous. In one aspect, certain polyesters useful in the present invention can have relatively low crystallinity. Certain polyesters useful in the present invention may thus have substantially non-ruthenium morphology' meaning that such polyesters comprise substantially irregular regions of the polymer. In one aspect, the polyester useful in the present invention contains at least one phosphorus compound which acts as a heat stabilizer anyway. 119732. Doc 200804457 In one aspect, the field of polyester, polyester composition and/or party of the invention, for example, at least one heat stabilizer of the dish method contains at least one phosphorus compound, In one aspect, the polyester and/or polybenzazole compositions useful in the present invention comprise a filler atom. In one aspect, the polyester and/or polyester compositions useful in the present invention contain tin atoms. In one aspect, any of the polyester compositions of the present invention contains at least one tin compound and at least one titanium compound. In one aspect, any method of making a polyester useful in the present invention can utilize at least one tin compound and at least one titanium compound. In one aspect, the phosphorus compound useful in the present invention comprises phosphoric acid, linalic acid, phosphonic acid, phosphinic acid, phosphinic acid, and various esters and salts thereof. The esters can be alkyl, branched alkyl, substituted alkyl 'difunctional alkyl, alkyl ether, aryl and substituted aryl. In one aspect, the phosphorus compound useful in the present invention comprises at least one heat stabilizer selected from at least one substituted or unsubstituted alkyl squarate, substituted or unsubstituted aryl phosphate. Mixed, substituted or unsubstituted mixed alkyl aryl phosphates, diphosphites, phosphates, phosphine oxides, and mixed aryl alkyl phosphites, reaction products thereof, and mixtures thereof. The phosphates include esters in which the phosphoric acid has been fully esterified or only partially esterified. In one aspect, the phosphorus compound useful in the present invention comprises at least one heat stabilizer selected from at least one substituted or unsubstituted alkyl phthalate 119732. Doc-191-200804457 Classes, substituted or unsubstituted aryl phosphates, mixed substituted or unsubstituted alkyl aryl phosphates, reaction products thereof and mixtures thereof. The acid-filled vinegar comprises an ester in which the phosphoric acid has been completely esterified or only partially esterified. In one aspect, the phosphorus compound useful in the present invention is selected from the group consisting of at least one alkyl squaraine s, aryl phosphates, mixed alkyl aryl phosphates, reaction products thereof, and mixtures thereof. In one aspect, any of the polyester compositions of the present invention may comprise at least one aryl acid anhydride. In one aspect, any of the polyester compositions of the present invention may comprise at least one unsubstituted pericylic acid. In one aspect, any of the polyester compositions of the present invention may comprise at least one aryl phosphate which has not been substituted with a benzyl group. In one aspect, any of the polyester compositions of the present invention may comprise at least one triaryl squaric acid vinegar. In one aspect, any of the polyester compositions of the present invention may comprise at least one triaryl phosphate which has not been substituted with a benzyl group. In one aspect, any of the polyester compositions of the present invention may comprise at least one alkyl phosphate. In one aspect, any of the polyester compositions of the present invention may comprise triphenylphosphonium phosphate and/or Merpol A. In one embodiment, any of the polyester compositions of the present invention may comprise triphenyl phosphate. In one aspect, the phosphorus compound useful in the present invention may be selected from at least one of the following: di-acids, acid groups, phosphine oxides, and mixed aryl alkyl phosphites. 119732. Doc-192-200804457 In one aspect, the phosphorus compound useful in the present invention comprises, but is not limited to, at least one diphosphite. In one aspect, a scaly compound useful in the present invention comprises, but is not limited to, at least one diphosphite comprising 2,4,8,10-tetraoxa-3,9.diphospho[5. 5] Undecane structure, for example, Westcm 619 (GE Specialty Chemicals, CAS # 3806-34-6) and / or Doverphos S-9228 (Dover Chemical, CAS # 154862-43-8). In one aspect, the phosphorus compound useful in the present invention comprises at least one mixed alkyl ary phosphite, for example, bis(2,4-cumylphenyl)pentaerythritol diphosphite, known as Doverphos S- 9228 (Dover Chemicals, CAS # 154862-43-8). In one embodiment, the phosphorus compound useful in the present invention comprises at least one phosphine oxide. In one embodiment, the phosphorus compound useful in the present invention comprises at least one phosphate salt, for example, KH2P〇4 and Ζη3(Ρ04)2. In one aspect, the method for making the polyester composition and/or polyester described in any of the description herein comprises at least one phosphorus compound as described in the specification. The method for making any of the polyester compositions and/or polyesters described in any of the above descriptions may comprise at least one diphosphite. The method for making any of the polyester compositions and/or polyesters described in any of the descriptions of the present invention may comprise at least one diphosphite comprising 2,4,8,10·tetraoxa-3 , 9_ diphosphorus snail [5. 5] undecane structure, such as weston 619 (GE Specialty Chemicals, cas# 3806-34-6) and/or Doverphos S_ 119732. Doc -193- 200804457 9228 (Dover Chemicals, cas# 154862 43 8). Any of the methods of making the polyester useful in the present invention can be used to make any polyester useful in the present invention. In one aspect, the pressure used in step (I) of any of the methods of the invention consists of at least one pressure selected from 0 to 75 psig. In one embodiment, the pressure used in step (1) of any of the methods of the present invention consists of at least one pressure selected from the group consisting of 〇 to 50 psig. In one aspect, the pressure used in the step (π) of any method of the invention consists of at least one pressure selected from the group consisting of 20 to 托 2 Torr (absolute pressure); in one embodiment, any of the inventions The pressure used in the step (π) of the method consists of at least one pressure selected from 10 to 0.02 Torr (absolute pressure); in one embodiment, the step (π) of any method of the invention The pressure used is comprised of at least one pressure selected from 5 to 0 Torr (absolute pressure); in one embodiment, the pressure used in step (II) of any method of the invention is selected from the group consisting of 3 to 0. 02 (absolute pressure) consisting of at least one pressure; in one embodiment, the pressure used in step (II) of any method of the invention is selected from the group consisting of 20 to 0. At least one pressure of 1 Torr (absolute pressure); in one embodiment, the pressure used in step (II) of any method of the invention consists of at least one pressure selected from 10 to absolute pressure; In a specific embodiment, the pressure used in step (II) of any of the methods of the present invention consists of at least one pressure selected from 5 to 1 Torr (absolute pressure); in one embodiment, The pressure used in step (II) of any method of the invention consists of at least one pressure selected from 3 to 03 Torr (absolute pressure). H9732. Doc-194-200804457 In any of the methods of the present invention, the compound which can be used in the present invention can be added during the esterification reaction, during the polycondensation reaction, during the hydrazine reaction, or both, and/or 1 can be added after the polymerization reaction. . The 'phosphorus compound' is added after the binder of the hydrazine reaction and the polycondensation reaction, and is added in an amount of 1 to 2% by weight based on the total weight of the final polyester. The molar ratio of the diol component/dicarboxylic acid component in step (1) of any method of the present invention is 1 > π υ U/1·0, in one aspect, added to any of the methods described herein. In step (1), the molar ratio of one of the IJ and one of the dicarboxylic acid components is 1. 01-1. 5/1. 0; in one side; 丄, , aspect 'added to any method of the invention Step (I) t diol component / one Hanhan # ν • The molar ratio of the knife/one citric acid component is 1. 01- 1. 3/1. 0' In one aspect, the molar ratio of the diol component/dicarboxylic acid component added to the step (1) of any of the methods of the present invention is 4 ι 〇ι_ΐ 2/ι 〇; in one aspect, added to the steps of any of the methods of the present invention ( The molar ratio of the diol component/dicarboxylic acid component in I) is 1. OU. b/! 方面 、 方面 方面 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加· On the one hand, the molar ratio of the diol component/two (four) component added to the step (1) of any method of the present invention is 10:15/"  In one aspect, the molar ratio of the diol component/dicarboxylic acid component added to the step (1) of any of the methods of the present invention is 丨03-丨3/1 π 10,000 Å, added to the step (1) of any method of the present invention. The molar ratio of the diol component/dicarboxylic acid component is im. o; in aspect, the molar ratio w 1·15/1 ·0 of the diol component/dicic acid component added in the step (1) of any method of the present invention, on the one hand, added to the hair of the hair In the step (I) of the method, the molar ratio of the alcohol component/dicarboxylic acid component is 1 〇 3 _ 11 〇 / 1 〇 · on one side 119732. Doc -195- 200804457 No., added to any of the steps J (J) of the present invention, the acid component of the Mo Erbi ping knife / one 竣 six inch ratio is 1. 05-1. 5/1 ·〇; in one of the steps, (1) of the method of any one of the methods, (1), and the mouth of the invention! 〇5 j ^ The molar ratio of a knowing/knife/dicarboxylic acid component is 1·05_1·3/1·0; in the case of an ancient q^, the diol component added to the step ω of any method of the present invention / a ¥ ^κ } molar ratio of the knives / _ citric acid composition is 105_12 /10; In one aspect, the molar component of the diol component/dicapric acid component added to the step (1) of any of the methods of the present invention is 1. 05-1. 15/1. And on the one hand, the molar ratio of the diol component/dim acid component added to the step (1) of any of the methods of the present invention is 1·〇Μ·1〇/1 0. In a specific embodiment of any of the manufacturing methods of the polyester useful in the present invention, the heating time of the step (11) may be from 1 to 5 hours. In a specific embodiment of the bamboo & method which can be used in the present invention, the heating time of the step (II) may be from 1 to 4 hours. The heating time of the step (Π) in any of the manufacturing methods of the polyester which can be used in the present invention may be from 1 to 3 hours. In a specific embodiment of any method of manufacture of the polyester useful in the present invention, the heating time of step (π) may be from 5 to 3 hours. In a specific embodiment of any method of manufacture of the polyester useful in the present invention, the heating time of step (II) may be from 1 to 2 hours. In one aspect, any of the polyester compositions and/or methods of the present invention can comprise at least one tin compound as described in the present specification. In one aspect, any of the polyester compositions and/or methods of the present invention may comprise at least one tin compound and, if desired, at least one selected from the group consisting of titanium, gallium, sulphur, sputum, sulphur, sulphur, sulphur, lithium, and A compound and a compound of the title compound and a hydroxide or sodium hydroxide catalyst. 119732. Doc-196.200804457 In one aspect, any of the polyester compositions of the present invention and/or methods of making the polyester useful in the present invention can be prepared using at least one tin compound as a catalyst and at least one catalyst selected from the group consisting of titanium compounds. . In a specific embodiment of any method of manufacture of the polyester useful in the present invention, the reaction temperature may range from 150 ° C to 250 ° C. 〇; or from 150 ° C to 245 ° C; or from 150 ° C to 240 ° C; or from 150 ° C to 235 ° C; or from 15 (TC to 230 ° C; or from 150 ° C to 225 ° C; or from 150 ° C to 220 ° C; or from 150 ° C to 215 ° C; or from 150 ° C to 210 ° C; or from 150 ° C to 205 ° C; or from 150 ° C to 200 ° C; or from 155 ° C to 250 ° C; or from 155 ° C to 245 ° C; or from 155 ° C to 240 ° C; or from 155 ° C to 235 ° C; or from 155 ° C to 230 ° C; or from 155 ° C to 225 ° C; or from 155 ° C to 220 ° C; or from 155 ° C to 215 ° C; or from 155 ° C to 210 ° C; or from 155 ° C to 205 ° C; or from 155 ° C to 200 ° C; or from 160 ° C to 250 ° C; or from 160 ° C to 245 ° C; or from 160 ° C to 240 ° C; or from 160 ° C to 235 ° C; or from 160 ° C to 230 ° C; or from 160 ° C to 225 ° C; or from 160 ° C to 220 ° C; or from 160 ° C to 215 ° C; or from 160 ° C to 210 ° C; or from 160 ° C to 205 ° C; or from 160 ° C to 200 ° C; or from 165 ° C to 250 ° C; or from 165 ° C to 245 ° C; or from 165 ° C to 240 ° C; or from 165 ° C to 235 ° C; or from 165 ° C to 230 ° C; or from 165 ° C to 225 ° C; or from 165. (: to 220 ° C; or from 165 ° C 215 ° C; or from 165 ° C to 210 ° C; or from 165 ° C to 205 ° C; or from 165 ° C to 200 ° C; or from 17 ° C to 250 ° C; or from 170 ° C To 245 ° C; or from 17 ° ° C to 240 ° C; or from 170 ° C to 235 ° C; or from 17 ° ° C to 230 ° C; or from 170 ° C to 225 ° C; or from 170 °C to 220 ° C; or from 17 ° ° C to 215 ° C; or from 17 ° ° C to 119,732. Doc -197- 200804457 210 ° C ; or from 17 (TC to 205 ° C; or from 170 ° C to 200 ° C; or from 175 ° C to 250 ° C; or from 175 ° C to 245 ° C; or From 175 ° C to 24 (TC; or from 175 ° C to 235 ° C; or from 175 ° C to 230 ° C; or from 175 ° C to 225 ° C; or from 175 ° C to 220 ° C; or From 175 ° C to 215 ° C; or from 175 ° C to 210 ° C; or from 175 ° C to 205 ° C; or from 175 ° C to 200 ° C; or from 180 ° C to 250 ° C; or From 180 ° C to 245 ° C; or from 180 ° C to 240 ° C; or from 180 ° C to 235 ° C; or from 180 ° C to 230 ° C; or from 180 ° C to 225 ° C; or From 180 ° C to 220 ° C; or from 180 ° C to 215 ° C; or from 180 ° C to 210 ° C; or from 180 ° C to 205 ° C; or from 180 ° C to 200 ° C at least a temperature. In one aspect, in any embodiment of the method of making the polyester useful in the present invention, the polycondensation reaction temperature can be from 230 ° C to 320 ° C; or from 230 ° C to 315 ° C; From 230 ° C to 310 ° C; or from 230 ° C to 305 ° C; or from 230 ° C to 300 ° C; or from 230 ° C to 295 ° C; or from 230 ° C to 285 ° C; or From 230 ° C to 280 ° C; or from 230 ° C to 275 ° C; or from 230 ° C 270 ° C; or from 230 ° C to 265 ° C; or from 230 ° C to 260 ° C; or from 235 ° C to 320 ° C; or from 235 ° C to 315 ° C; or from 235 ° C to 310 ° C; or from 235 ° C to 305 ° C; or from 235 ° C to 300 ° C; or from 235 ° C to 295 ° C; or from 235 ° C to 285 ° C; or from 235 ° C to 280 ° C; or from 235 ° C to 275 ° C; or from 235 ° C to 270 ° C; or from 235 ° C to 265 ° C; or from 235 ° C to 260 ° C; or from 240 ° C to 320 ° C; or from 240 ° C to 315 ° C; or from 240 ° C to 310 ° C; or from 240 ° C to 305 ° C; or from 240 ° C to 300 ° C; or from 240 ° C to 295 ° C; or from 240 ° C to 285 ° C; or from 24 (TC to 280 ° C; or from 240 ° C to 275 ° C; or from 119,732. Doc -198- 200804457 240 ° C to 270 ° C; or from 240 ° C to 265 ° C; or from 240 ° C to 260 ° C; or from 245 ° C to 320 ° C; or from 245 ° C to 315 °C; or from 245 ° C to 310 ° C; or from 245 ° C to 305 ° C; or from 245 ° C to 300 ° C; or from 245 ° C to 295 ° C; or from 245 ° C to 285 °C; or from 245 ° C to 280 ° C; or from 245 ° C to 275 ° C; or from 245 ° C to 270 ° C; or from 245 ° C to 265 ° C; or from 245 ° C to 260 °C; or from 250 ° C to 320 ° C; or from 250 ° C to 315 ° C; or from 250 ° C to 310 ° C; or from 250 ° C to 305 ° C; or from 250 ° C to 300 °C; or from 250 ° C to 295 ° C; or from 250 ° C to 285 ° C; or from 250 ° C to 280 ° C; or from 250 ° C to 275 ° C; or from 250 ° C to 270 °C; or from 250 ° C to 265 ° C; or from 250 ° C to 260 ° C; or from 255 ° C to 320 ° C; or from 255 ° C to 315 DC; or from 255 ° C to 310 ° C ; or from 255 ° C to 305 ° C; or from 255 ° C to 300 ° C; or from 255 ° C to 295 ° C; or from 255 ° C to 285 ° C; or from 255 ° C to 280 ° C ; or from 255 ° C to 275 ° C; or from 255 ° C to 270 ° C; or from 255 ° C to 265 ° C; or from 255 ° C to 260 ° C; or from 26 0 ° C to 320 ° C; or from 260 ° C to 315 ° C; or from 260 ° C to 310 ° C; or from 260 ° C to 305 ° C; or from 260 ° C to 300 ° C; or from 260 ° C to 295 ° C; or from 260 ° C to 285 ° C; or from 260 ° C to 280 ° C; or from 260 ° C to 275 ° C; or from 260 ° C to 270 ° C at least one temperature. In one aspect, the addition of a phosphorus compound to the process of the present invention results in a weight ratio of all tin atoms and all phosphorus atoms in the final polyester of 2 丨〇:丨. In one embodiment, the addition of a phosphorus compound to the process of the present invention results in a weight ratio of all tin atoms and all phosphorus atoms in the final polyester of 5-9:1. In a specific embodiment, the addition of a phosphorus compound to the process of the invention results in 119,732. Doc -199- 200804457 The weight ratio of all tin atoms and all phosphorus atoms in the final polyester is 6_ 8. 1 In a specific embodiment, the addition of a compound in the process of the present invention results in a weight ratio of all tin atoms and all phosphorus atoms in the final polyester of 7:1. In one aspect, tin atoms are useful in the present invention. The amount in the final polyester, from 15 to 400 ppm by weight of the final polyester. In one aspect, the amount of tin atoms in the final polyester useful in the present invention can range from 25 to 400 ppm by weight of the final polyester. In one aspect, the amount of tin atoms in the final polyester useful in the present invention can range from 40 to 200 ppm by weight of the final polyester. In one aspect, the amount of tin atoms in the final polyester useful in the present invention can range from 50 to 125 ppm by weight of the final polyester. In one aspect, the amount of phosphorus atom in the final polyester useful in the present invention can range from 1 to 1 〇〇 ppm by weight of the final polyester. In one aspect, the amount of phosphorus atom in the final polyester useful in the present invention can range from 4 to 60 ppm by weight of the final polyester. In one aspect, the amount of phosphorus atom in the final polyester useful in the present invention can range from 6 to 20 ppm by weight of the final polyester. In one aspect, the amount of atoms to be added to the final polyester useful in the present invention may range from 1 to 100 ppm by weight of the final poly(S); and the amount of tin atoms in the final polyester, in the final polyester. The weight can be from 15 to 4 inches. In one aspect, the amount of phosphorus atom in the final polyester useful in the present invention may range from 1 to 100 ppm by weight of the final polyester; and the amount of tin atom in the final polyester, based on the final polyester weight. It can be from 25 to 4 inches. 119732. Doc • 200- 200804457 In one aspect, the amount of phosphorus atoms in the final polyester useful in the present invention may range from 4 to 60 ppm by weight of the final polyester; and the amount of tin atoms in the final polyester, It can be from 4 to 2 ppm by weight of the final polyester. In one aspect, the amount of phosphorus atom in the final polyester useful in the present invention can be from 6 to 20 ppm by weight of the final polyester; and the amount of tin atoms in the final polyester, based on the final polyester weight. It can range from 5〇 to 125 ppm. In any aspect, any of the methods of making any of the polyester compositions and/or polyesters described in the specification can contain at least one mixed alkyl aryl phosphite, for example, bis(2,4-cumylphenyl) Pentaerythritol diphosphite, known as D〇verph〇S S-9228 (D〇ver Chemical, cas# 154862 43_ 8) ° in terms of any of the polyester compositions and/or poly The ester method can contain at least one phosphine oxide. In one aspect, any of the methods of making any of the polyester compositions and/or polyesters described in the specification can contain at least one phosphate, for example, κΗ2ρ〇4 and Ζη3(Ρ〇4)2 in one aspect, such The polyester composition can be used in the manufacture of articles including, but not limited to, extruded, calendered, and/or molded articles including, but not limited to, injection molded articles 'formed articles 铸造, cast squeezing molded articles #, shaped extruded scraps (four) pieces , melt-spun articles, thermoformed articles, extruded molded articles, injection blown articles, injection stretch blow articles, extruded blow articles, and extruded stretch blow articles. Such items include, but are not limited to, films, bottles, containers, sheets, and/or fibers. Aspects of the polyester composition useful in the present invention are available in various types of 119,732. Doc 200804457 Methods including, but not limited to, extruded films and/or sheets, sheets, compression molded films and/or sheets, solution casting films and/or sheets including, but not limited to, films and/or sheets, calendered films and/or Or flakes, films and/or flakes. Manufacturing extrusion, calendering, compression molding and solution casting. Moreover, the use of such specific compositions as described above may minimize and/or eliminate drying steps prior to refining or thermoforming. [Embodiment] The present invention will be more readily described with reference to the detailed description of embodiments of the invention. Some specific embodiments of the present invention are described in the Summary of the Invention, and are further described below. Other embodiments of the invention are also described herein. Salty "The polyester and/or polyester composition of the present invention may have a unique combination of two or more physical properties, such as medium or high impact strength, high glass transition temperature, chemical resistance, hydrolysis, and degree. Low brittle transition temperature, good color and transparency, low density and long crystallization half-life and good edging properties, thus easily allowing them to be made into articles - in some embodiments of the invention, such 0 is intended to have a unique combination of good impact strength, heat resistance, chemical resistance, density properties, and/or a combination of good impact strength, heat resistance and processability properties, and, or a combination of two or more of said properties' It has not previously been considered to be present in a polyester composition comprising a polyester as disclosed herein. In one embodiment, A letter is used during the manufacture of the vinegar according to the present invention. When described as comprising a heat stabilizer for at least one phosphorus compound, the polyester can be relatively easily fabricated without at least one of the following 119,732. Doc 200804457 Situation occurs · bubbling, bevel forming, color money r heart ☆ out of gas and no regular degree of melting (ie 'polyacetate, polyester production and processing system pulse). In one embodiment, at least one of the methods of the present invention provides any polyester that is relatively easy and large (eg, 'primary process scale and/or commercially produced') to produce a polyester composition suitable for use in the present invention, and At the same time, avoid at least one of the above methods for describing the difficulty. The term "large amount" as used herein is intended to include polyesters useful in the present invention in quantities greater than 100. In the particular embodiment, the term "mass" as used herein, including the polyesters useful in the present invention, is produced in quantities greater than 1000 pounds. In one aspect, the method of making the polyester useful in the present invention can comprise a batch or continuous process. In one aspect, the method of making the polyester useful in the present invention can comprise a continuous process. When tin is added to the polyester of the present invention and/or the polyester composition of the present invention and/or the method of the present invention, the form of the tin compound is added to the polysulfonium process. The amount of tin compound added to the polyester of the present invention and/or the polyester composition of the present invention and/or the polyester manufacturing method of the present invention may be measured in the form of tin atoms present in the final polyester, for example, When the ppm by weight 〇s 4 is added to the polyester of the present invention and/or the composition of the present invention and/or the method for producing the polyester of the present invention, it is added to the polyester process in the form of a phosphorus compound. T is added to the polyester of the present invention and/or the polyester composition of the present invention and/or 119732. Doc 200804457 The amount of the phosphorus compound of the present invention (for example, at least one phosphorus compound selected from the group consisting of phosphoric acid, diphosphite, phosphate, and mixed alkyl aryl phosphite) may be present in the final polyester. The atomic form of phosphorus is measured, for example, in ppm by weight. As used herein, the term "polyester," is intended to include, copolyester, and it is understood that it means a synthetic polymer via one or more bifunctional tetanitics and/or polyfunctional carboxylic acids. The acid is prepared by reacting with one or more difunctional hydroxy compounds and/or polyfunctional hydroxy compounds. Typically, the difunctional carboxylic acid can be a dicarboxylic acid and the difunctional hydroxy compound can be a dihydric alcohol such as a glycol and a glycol. The term "diol" as used herein includes, but is not limited to, glycols, di-fermented and/or polyfunctional penta-based compounds, such as branching agents. Alternatively, bifunctional tracing can be By a base acid, such as p-hydroxybenzoic acid, the bifunctional hydroxy compound can be an aromatic nucleus with two thiol substituents, such as phenyl diphenyl. The ''residues' used herein. The term, meaning any organic structure, is incorporated into a polymer from its corresponding monomer by polycondensation and/or esterification. The term "repeating unit" as used herein, refers to an organic structure having a dicarboxylic acid residue bonded to a diol residue via a valeroxy group. Thus, for example, a diterpene acid residue can be derived from a dicarboxylic acid monomer or its associated acid halides, esters, salts, anhydrides, and/or mixtures thereof. Furthermore, the term "diacid" as used herein includes polyfunctional acids such as branching agents. Thus, the term "dicarboxylic acid" as used herein is intended to include dicarboxylic acids and Any derivative of a carboxylic acid, including its associated acid halides, esters, half esters, salts, semi-salts, anhydrides, mixed anhydrides and/or mixtures thereof, which can be used with diol 119,732. In the reaction method of doc-204-200804457, a polyester is produced. The term "terephthalic acid" as used herein is intended to include terephthalic acid itself, and its residues, as well as any derivatives of terephthalic acid, including the associated acid dentates, esters, (d) self-, salt, semi-salt, liver, mixed needles and / or mixtures thereof or residues thereof, which can be used in a reaction with a diol to produce a polyester which is typically used in the present invention. Produced from dicarboxylic acids and diols which are reacted in substantially equal proportions and incorporated into the polyester polymer with their corresponding residues. The <RTIgt; A molar ratio of acid residues (100 mole %) to diol (and/or polyfunctional hydroxy compound) residues (100 mole %) such that the total number of moles of repeating units is equal to 100 mole %. Accordingly, the number of moles of the moiré provided in the present disclosure is based on the total number of moles of the residue, the total number of moles of the diol residue I, or the total number of moles of the repeating unit. For example, 30 moles. Isophthalic acid 2 polyacetate, based on total acid residues, means that the polyester contains 30 moles. The isophthalic acid residue is from a total of 100 moles of acid residues. Thus, there is a 3G molar isophthalic acid residue per 1 mole of molybdenum residue. In another example, The polychlorination containing 30 mol% 2,2, tetramethyl-U3_cyclobutanediol is based on the total monool residue, which means that the polyester contains 30 mol% 2 =, 4, 4· The tetramethylcyclobutanediol residue is derived from a total of 1 mole % diol residue. Therefore, among every 1 mole of the diol residue, there are % Molar 2, 2, 4, 4 _ Tetramethyl-^-cyclobutanediol residue. In the aspect of the present invention, the polyglycol which can be used in the polyester composition of the present invention may have a Tg of at least one of the following ranges: 60 to 2 〇 ( TC; 60 to 119732. Doc 200804457 190 ° C; 60 to 180 ° C; 60 to 170 ° C; 60 to 160 ° C; 60 to 155 ° C; 60 to 150 ° C; 60 to 145 ° C; 60 to 140 ° C; 60 to 138 ° C; 60 to 135 ° C; 60 to 130 ° C; 60 to 125 ° C; 60 to 120 ° C; 60 to 115 ° C; 60 to 110 ° C; 60 to 105 ° C; 60 to 100 ° C; 60 to 95 ° C; 60 to 90 ° C; 60 to 85 ° C; 60 to 80 ° C; 60 to 75 ° C; 65 to 200 ° C; 65 to 190 ° C; 65 to 180 ° C; 65 to 170 ° C; 65 to 160 ° C; 65 to 155 ° C; 65 to 150 ° C; 65 to 145 ° C; 65 to 140 ° C; 65 to 138 ° C; 65 to 135 ° C; 130 ° C; 65 to 125 ° C; 65 to 120 ° C; 65 to 115 ° C; 65 to 110 ° C; 65 to 105 ° C; 65 to 100 ° C; 65 to 95 ° C; 65 to 90 ° C; 65 to 85 ° C; 65 to 80 ° C; 65 to 75 ° C; 70 to 200 ° C; 70 to 190 ° C; 70 to 18 (TC; 70 to 170 ° C; 70 to 160 ° C; 70 to 155 ° C; 70 to 150 ° C; 70 to 145 ° C; 70 to 140 ° C; 70 to 138 ° C; 70 to 135 ° C; 70 to 130 ° C; 70 to 125 ° C; 120 ° C; 70 to 115 ° C; 70 to 110 ° C; 70 to 105 ° C; 70 to l 〇 (TC; 70 to 95 ° C; 7 0 to 90 ° C; 70 to 85 ° C; 70 to 80 ° C; 70 to 75 ° C; 75 to 200. (3; 75 to 190 ° C; 75 to 180 ° C; 75 to 170 ° C; 75 To 160 ° C; 75 to 155 ° C; 75 to 150 ° C; 75 to 145 ° C; 75 to 140 ° C; 75 to 138 ° C; 75 to 135 ° C; 75 to 130 ° C; 75 to 125 °C; 75 to 120 ° C; 75 to 115. 〇; 75 to 110 ° C; 75 to 105 ° C; 75 to 1 〇〇. 〇; 75 to 95 ° C ; 75 to 90 ° C ; 75 to 85 ° C ; 75 to 80 ° C ; 80 to 200 ° C ; 80 to 190 ° C ; 80 to 180 ° C ; 80 to 170 ° C ; 80 to 160 ° C; 80 to 155 ° C; 80 to 150 ° C; 80 to 145 ° C; 80 to 140 ° C; 80 to 138. 〇; 80 to 135 ° C; 80 to 130 ° C; 80 to 125 ° C; 80 to 120 ° C; 80 to U 5 ° C; 80 to 110 ° C; 80 to l 〇 5 ° C; 80 to 100 t: 80 to 95 ° C; 80 to 90 ° C; 80 119,732. 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155〇C 110 至 120〇C ; 110 至 115〇C ; 115 至 200〇C ; 115至 115 至 180°C ; 115 至 170°C ; 115 至 160〇C ; 115至 115 至 150〇C ; 115 至 145〇C ; 115 至 140〇C ; 115至 115 至 135〇C ; 115 至 130°C ; 115 至 125〇C ; 115至 120 至 200〇C ; 120 至 190°C ; 120 至 180°C ; 120至 120 至 160〇C ; 120 至 155〇C ; 120 至 150〇C ; 120至 120 至 140〇C ; 120 至 138〇C ; 120 至 135°C ; 120至 125 至 200〇C ; 125 至 190°C ; 125 至 180°C ; 125至 125 至 160〇C ; 125 至 155〇C ; 125 至 150°C ; 125至 125 至 140°C ; 125 至 138。。； 125 至 135〇C ; 127至 127 至 190°C ; 127 至 180°C ; 127 至 170°C ; 127至 127 至 150〇C ; 127 至 145°C ; 127 至 140°C ; 127至 127 至 135〇C ; 130 至 200°C ; 130 至 190°C ; 130至 130 至 170°C ; 130 至 160〇C ; 130 至 155〇C ; 130至 130 至 145〇C ; 130 至 140°C ; 130 至 138°C ; 130至 135 至 200〇C ; 135 至 190°C ; 135 至 180°C ; 135至 135 至 160〇C ; 135 至 155〇C ; 135 至 150°C ; 135至 135 至 140°C ; 140 至 200〇C ; 140 至 190°C ; 140至 140 至 170°C ; 140 至 160〇C ; 140 至 155°C ; 140至 140 至 145〇C ; 148 至 200〇C ; 148 至 190°C ; 148至 148 至 170°C ; 148 至 160〇C ; 148 至 155〇C ; 148至 大於148至200°C ;大於148至190°C ;大於148至 ;大於148至170°C ;大於148至160°C ;大於148至 ;150 至 200°C ; 150 至 190°C ; 150 至 180°C ; 150 至 119732.doc -208- 200804457 170°C ; 150 至 160; 155 至 190°C ; 155 至 180°C ; 155 至 170 °C ;及 155至 165°C。 於本發明之其他方面，供可用於本發明之聚酯用之二醇 成份，包括但不限於至少一種下列範圍組合：1至99莫耳 % 2,2,4,4-四甲基_i，3-環丁二醇與1至99莫耳％環己烷二甲 醇；1至95莫耳％ 2,2,4,4-四甲基-i，3-環丁二醇與5至的莫 耳％環己烷二甲醇；莫耳％ 2,2,4,4·四甲基_丨，3_環丁 二醇與10至99莫耳％環己烷二曱醇；1至85莫耳％ 2,2,4,4_ 四曱基-1，3-環丁二醇與15至99莫耳％環己烷二甲醇；1至 8〇莫耳％ 2,2,4,4_四甲基4,3-環丁二醇與2〇至99莫耳％環己 烷一甲醇，1至75莫耳％ 2,2,4,心四甲基]，3_環丁二醇與25 至99莫耳％環己烷二甲醇；ι7〇莫耳％ Μ，#四甲基_ 1，3_環丁二醇與30至99莫耳%環己烷二甲醇"至“莫二 2^2,4,4-四甲基]，3_環丁二醇與35至99莫耳％環己燒q 醇；1至60莫耳％ 2,2,4,4_四甲基」}環丁二醇與4〇至99莫 耳％认環己燒二甲醇；1至55莫耳％ 2,2,4,4·四甲基十3、· 裱丁二醇與45至"莫耳％環己烷二甲醇，·莫耳％ 醇’ 1至45莫耳％ 2,2,4,4 -四甲其q^ 土 -1,3 -% 丁 二醇與 55 至 99 望 耳％環己烷二甲醇；！至4〇莫耳 、 斗/〇 2,2,4,4·四甲基-1，3·環丁 一醇與60至99莫耳〇/0環己惊-田 +衣己烷一甲醇；1至35莫耳％ 22“ 四甲基13-環丁二醇與65至99 ，2,4,4· π莫耳。/。…”基…二耳…燒二甲“至 ’基m衣丁二醇與70至99莫耳％頊？ 燒二甲醇；山5莫耳％2,2,4,4 其耳仏己 口 r丞_ι，3_ί哀丁二醇與75 H9732.doc 200804457 至"莫耳％環己炫二甲醇；1至2G莫耳％ 2,2,4,4_四甲基· 1，3-環丁二醇與80至99莫耳％環己燒二甲醇；m莫耳％ 2,2,4,4-四曱基]，3_環丁二醇與85至99莫耳％環己烧二甲 醇；1至1〇莫耳％ 2,2,4,4·四甲基-U-環丁二醇與90至99莫 耳％環己烧二甲醇；及⑴莫耳％ 2,2,4,4_四甲n3_環丁 二醇與95至99莫耳〇/〇環己烷二甲醇。 於本發明之其财面，供可詩本發明之㈣用之二醇 成份，包括但不限於至少一種下列範圍組合：3至1〇莫耳 % 2,2,4,4_四甲基]，3_環丁二醇與9〇至97莫耳％環己炫二甲 醇；3至9莫耳％ 2,2,4,4_四f基]，3_環丁二醇與”至”莫 耳❶/。環己烧二甲醇；及3至8莫耳％ 2,2,4,4_四甲基Μ.環丁 二醇與92至97莫耳〇/〇環己烷二甲醇。 、於本發明之其他方面，供可用於本發明之聚酯用之二醇 成份，包括但不限於至少一種下列範圍組合：5至99莫耳 % 2,2,4,4-四甲基環丁二醇與1至95莫耳％環己烷二甲 醇，5至95莫耳％ 2,2,4,扣四甲基十弘環丁二醇與^”莫 耳％環己烧二甲醇；5至9〇莫耳％ 2,2,4，心四甲基環丁 二醇與10至95莫耳％環己烷二甲醇；5至85莫耳％ 2,2,4,4_ 四甲基-1,3-環丁二醇與15至95莫耳％環己烷二甲醇，· 5至 8〇莫耳％ 2,2,4,4·四甲基·1，3·環丁二醇與2G至95莫耳％環己 烧二甲醇；5至75莫耳％ 2,2,4,4-四甲基-a環丁二醇與25 至95莫耳％環己烷二甲醇；5至7〇莫耳％ 2,2,4,4_四甲基_ 1，3-環丁二醇與3〇至95莫耳％環己烧二甲醇；5至65莫耳％ 2,2,4,4-四甲基環丁二醇與35至95莫耳〇/〇環己烷二甲 119732.doc -210- 200804457 醇，5至60莫耳〇/〇 2,2,4,4·四甲基]，3_環丁二醇與40至95莫 耳％環己烷二甲醇；5至55莫耳％ 2,2,4,4_四甲基環丁 一醇與45至95莫耳〇/〇環己烷二曱醇；及5至5〇莫耳％ 2,2,4,4-四甲基心，％環丁二醇與5〇至95莫耳％環己烷二甲 醇。 於本發明之其他方面，供可用於本發明之聚酯用之二醇 成份，包括但不限於至少一種下列範圍組合：5至小於5〇 莫耳/〇 2,2’4,4-四f基_1，3_環丁二醇與大於5〇至95莫耳％環 己烧二甲醇；5至45莫耳％ 2,2,4,4_四甲基]，3_環丁二醇與 55至95莫耳％環己院二甲醇；5至4〇莫耳％ 2,2,4，心四甲基_ 1，3-環丁二醇與6〇至95莫耳％環己烷二甲醇；$至乃莫耳％ 2’2,4,4-四甲基-1，3-環丁二醇與65至95莫耳〇/〇環己烷二甲 醇，5至小於35莫耳％ 2,2,4,4_四甲基-Μ-環丁二醇與大於 65至95莫耳％環己烧二甲醇；5至3()莫耳％ 2,2,4,4_四甲基_ 1，3-壤丁二醇與7〇至95莫耳％環己烷二甲醇；$至乃莫耳％ 2,2,4,4-四甲基汔夂環丁二醇與乃至％莫耳％環己烷二甲 醇，5至20莫耳％ 2,2,4,4_四甲基環丁二醇與8〇至㈣ 耳％環己炫二甲醇；5至15莫耳％ 2,2,4,4_四甲基.Μ環丁 二醇與85至95莫耳％環己院二甲醇；5至1〇莫耳％ Μ〆〆-四甲基-1，3·環丁二醇與9〇至95莫耳％環己院二甲醇:大於 5至小於1〇莫耳％ 2,2,4,4•四甲基^%環丁二醇與小於叩至 大於95莫耳％環己烧二甲醇；55莫耳％至95莫耳％ 2’2’4,4·四f基-Μ-環丁二醇與94 5莫耳％至列$莫耳％環 己烧二f醇’·及6至9莫耳％ 2,2,4,4·四甲基.以環丁二醇 119732.doc •211- 200804457 與94至91莫耳％環己烷二甲醇。 於本發明之其他方面，供可用於本發明之聚酯用之二醇 成份，包括但不限於至少一種下列範圍組合· 1〇至99莫耳 % 2,2,4,4-四甲基環丁二醇與丨至卯莫耳％環己烷二甲 醇，10至95莫耳％ 2,2,4,4-四f基」，3_環丁二醇與$至如莫 耳％環己烷二甲醇；10至9〇莫耳％ 2,2,4,4_四甲基]，3_環丁 二醇與1G至9G莫耳％環己烧二甲醇；1()至85莫耳％ 2,2,4,心 四甲基-1，3·環丁二醇與15至9〇莫耳0/〇環己烷二甲醇；⑺至 80莫耳/〇 2,2,4,4-四甲基-丨，；^環丁二醇與2〇至9〇莫耳。义環己 烷一甲醇，10至75莫耳〇/〇 2,2,4,4-四甲基-i，3-環丁二醇與 25至90莫耳％環己烷二甲醇；1〇至7〇莫耳％ 2,2,4,4-四甲 基-1，3-環丁二醇與3〇至9〇莫耳％環己烷二甲醇·⑺至“莫 耳/: 2,2,4,4-四甲基]，％環丁二醇與35至9〇莫耳％環己烧二 甲醇’ 10至60莫耳％ 2,2,4,4_四甲基環丁二醇與4〇至 二莫耳％環己燒二甲醇；聰55莫耳％ 2,2,4,4四甲基# 環丁二醇與45至9G莫耳％環am至㈣耳^ ’2’4’4四甲基」，3_環丁二醇與5〇至9〇莫耳％環己烷二甲 醇；至小於50莫耳％ 2,2从四甲基十3_環丁二醇鱼大 於5〇謂莫耳％環己燒二甲醇；H)至45莫耳。/。2,2,4,4_四甲 基^，3_壤丁二醇與55至90莫耳％環己烷二甲醇；1〇至40莫 耳％ 2,2,4,4-四甲基]，％環丁二醇與6〇至9〇莫耳％環己烧二 甲醇；1〇至35莫耳％2,2,4，心四甲基汔3_環丁二醇與“至 90莫耳％環己烧二〒醇；10至小於35莫耳％ 2,2,4，心四甲 基丁二醇與大於65至90%環己烷二甲醇；1〇至3〇莫 H9732.doc -212- 200804457 耳％ 2,2,4,4-四甲基_ι，3-環丁二醇與7〇至9〇莫耳％環己烷二 甲醇；10至25莫耳〇/〇 2,2,4,4_四甲基]，3·環丁二醇與乃至 9〇莫耳％環己烷二曱醇；1〇至2〇莫耳％ 2,2,4,4_四甲基_丨，3_ 環丁二醇與80至90莫耳％環己烷二甲醇；及1〇至15莫耳％ 2,2,4,4-四甲基-L3-環丁二醇與85至9〇莫耳％環己烷二甲 醇。 於本發明之其他方面，供可用於本發明之聚酯用之二醇 成份’包括但不限於至少一種下列範圍組合· 1〇至1〇〇莫 耳％ 2,2,4,4-四甲基-i，3-環丁二醇與〇至9〇莫耳％環己烷二 甲醇；大於10至99莫耳％ 2,2,4,4·四甲基-1，3_環丁二醇與J 至小於90莫耳。/c)環己烷二甲醇；大於10至95莫耳％ 2,2,4,4_ 四甲基-1，3-環丁二醇與5至小於9〇莫耳％環己烷二甲醇； 大於10至90莫耳❶/。2,2,4,4_四甲基·1，3_環丁二醇與1〇至小 於90莫耳％環己烷二甲醇；大於1〇至85莫耳％ 2,2,4,4_四甲 基-1，3-環丁二醇與15至小於9〇莫耳％環己烷二甲醇；大於 10至80莫耳％ 2,2,4,4_四甲基-1，3_環丁二醇與2〇至小於9〇 莫耳％環己烷二甲醇；大於10至75莫耳％ 2,2,4,4-四甲基· 1，3-環丁二醇與25至小於9〇莫耳％環己烷二甲醇；大於1〇 至70莫耳。/◦ 2,2,4,4·四甲基環丁二醇與3〇至小於9〇莫 耳％環己烷二甲醇；大於10至65莫耳％ 2,2,4,4·四甲基十夂 環丁二醇與35至小於9〇莫耳％環己烷二甲醇；大於1〇至6〇 莫耳❶/◦ 2,2,4,4-四甲基-1，3_環丁二醇與4〇至小於9〇莫耳％環 己烷二甲醇；大於10至55莫耳％ 2,2,4,4_四甲基_丨，3_環丁 二醇與45至小於90莫耳％環己烷二甲醇；大於1〇至5〇莫耳 119732.doc 213· 200804457 % 2,2,4,4_四甲基-π環丁二醇與％至小於％莫耳％環己烧 二甲醇；大於10至小於50莫耳％ 2,2,4,心四甲基環丁 ，醇與大於50至小於90莫耳％環己烷二甲醇；大於1〇至45 莫耳％ 2,2,4,4-四甲基]，3, 丁二醇與55至小於如莫耳^環 己烧二甲醇；大於10至4〇莫耳％ 2,2,4,4_四甲基]，3_環丁 二醇與60至小於90莫耳％環己烷二甲醇；大於1〇至35莫耳 % 2,2,4,4-四甲基-l，3-環丁二醇與65至小於 二甲醇"〇至小於34莫耳％2,2,4—^ 與大於66至90莫耳％環己院二甲醇；大於1〇至3〇莫耳〇/〇 2,2,4,4-四甲基]，3_環丁二醇與7〇至小於9〇莫耳％環己烷二 甲醇；大於H)至25莫耳％ 2,2,4,4_四甲基環丁二醇與 75至小於90莫耳％環己烷二甲醇；大於1〇至2〇莫耳％ 2,2’4,4-四甲基-1，3_環丁二醇與8〇至小於9〇莫耳％環己烷二 甲醇，及大於10至15莫耳％ 2,2,4,4_四甲基環丁二醇 與85至小於90莫耳％環己烷二甲醇。 、於本發明之其他方面，供可用於本發明之聚酯用之二醇 成份，包括但不限於至少一種下列範圍組合·丨丨至99莫耳 % 2,2,4,4·四甲基]，％環丁二醇與丨至89莫耳％環己烷二甲 醇；11至95莫耳％ 2,2,4,4-四甲基〇環丁二醇與5至89莫 耳％環己烧二f醇；11謂莫耳％ 2,2,4,4-四甲基-1，3·環丁 -醇與10至89莫耳％環己烧二甲醇；Us85莫耳％ 2,2,4，心 四甲基-1，3-環丁二醇與^至⑽莫耳^❶環己烷二甲醇：“至 莫耳/〇 2,2’4,4-四甲基]，3_環丁二醇與2〇至89莫耳％環己 烧甲醇’11至75莫耳％ 2,2,4,4·四甲基-1，3-環丁二醇與 119732.doc •214- 200804457 25至89莫耳％環己烷二甲醇；u7〇莫耳％ Μ〆〆·四甲 基-1，3-環丁二醇與3〇至89莫耳％環己烷二甲醇；丨丨至“莫 耳。/〇 2,2,4,4-四甲基環丁二醇與35至89莫耳％環己烧二 甲醇；11至60莫耳％ 2,2,4,4_四甲基·1>3_環丁二醇與悔 89莫耳％環己烧二甲醇；^55莫耳％ 2,2,4,4_四甲基n 環丁二醇與45至89莫耳％環己烷二甲醇；丨丨至“莫耳％ 2’2’4’4·四甲基+3·環丁二醇與5〇至89莫耳％環己燒二甲 醇；11至小於50莫耳％ 2,2,4,4-四甲基_u_環丁二醇與大 於50至89莫耳％環己烧二甲醇；“至^莫耳％ 2,2,4,4_四甲 基-1，3-環丁二醇與55至89莫耳％環己烷二甲醇；丨丨至利莫 耳％ 2,2,4,4-四甲基_U_環丁二醇與6〇至89莫耳％環己烧二 甲醇，11至35莫耳％ 2,2,4,4-四甲基-i，3-環丁二醇與65至 89莫耳。/。環己炫二甲醇；u至3〇莫耳％ 2,2,4,4_四甲基.π 環丁二醇與70至89莫耳％環己烷二甲醇；Π至24莫耳％ 2,2’4,4-四甲基]，3_環丁二醇與76至89莫耳％環己烷二甲 醇；及11至25莫耳％ 2,2,4,4_四曱基」，3_環丁二醇與乃至 89莫耳％環己燒二甲醇。 於本發明之其他方面，供可用於本發明之聚酯用之二醇 成份，包括但不限於至少一種下列範圍組合：12至99莫耳 % 2,2,4,4-四甲基4,3•環丁二醇與1至88莫耳％環己烷二甲 醇；12至95莫耳％ 2,2,4,心四甲基-1，3·環丁二醇與5至88莫 耳％環己烷二甲醇；12至9〇莫耳％ 2,2,4,4_四甲基<，3-環丁 二醇與10至88莫耳％環己烷二f醇；12至85莫耳％ 2,2,4,4_ 四甲基-1，3-環丁二醇與15至88莫耳％環己烷二甲醇；η至 119732.doc -215- 200804457 80莫耳％ 2,2,4,4-四甲基-1，3-環丁二醇與2〇至88莫耳％環己 烷二甲醇；12至75莫耳％ 2,2,4,4-四甲基環丁二醇與 25至88莫耳％環己烷二曱醇；12至7〇莫耳％ 2,2,4,4_四甲 基_1，3-環丁二醇與30至88莫耳％環己烷二甲醇；12至“莫 耳％ 2,2,4,4-四甲基_1，3-環丁二醇與35至88莫耳〇/〇環己烷二 甲醇；12至60莫耳％ 2,2,4,4_四甲基_l53_環丁二醇與4〇至 88莫耳％環己烷二甲醇；12至55莫耳％ 2,2,4,4_四甲基]，3一 環丁 一醇與45至88莫耳％環己烧二甲醇；至5〇莫耳〇/〇 2,2,4,4-四甲基環丁二醇與5〇至88莫耳％環己烷二甲 醇；12至小於50莫耳％ 2,2,4,4-四甲基_l53_環丁二醇與大 於50至88莫耳％環己烷二甲醇；12至45莫耳％ 2,2,4,4_四甲 基-1,3-環丁二醇與55至88莫耳％環己烷二甲醇；12至4〇莫 耳％ 2,2,4,4-四甲基-ΐ，3·環丁二醇與6〇至88莫耳％環己烷二 甲醇，12至35莫耳％ 2,2,4,4-四甲基-；ι，3-環丁二醇與65至 88莫耳％環己烷二甲醇；12至3〇莫耳〇/〇 2,2,4,4·四甲基]，％ 環丁二醇與70至88莫耳％環己烷二甲醇；12至24莫耳％ 2,2,4,4-四甲基十3_環丁二醇與76至88莫耳％環己烷二甲 醇，及12至25莫耳％ 2,2,4,4_四甲基_ι，3_環丁二醇與乃至 88莫耳％環己烷二甲醇。 於本發明之其他方面，供可用於本發明之聚酯用之二醇 成份，包括但不限於至少一種下列範圍組合：13至99莫耳 % 2,2,4,4-四甲基义％環丁二醇與α87莫耳％環己烧二甲 醇’ 13至95莫耳％ 2,2,4,4-四甲基'3-環丁二醇與5至87莫 耳％環己烧二甲醇；13至9G莫耳％ 2,2,4,4_四甲基#環丁 119732.doc -216 - 200804457 二醇與10至87莫耳％環己烷二甲醇；13至85莫耳％ 2,2,4,4_ 四甲基-1，3-環丁二醇與15至87莫耳％環己烷二甲醇；η至 8〇莫耳％ 2,2,4,4-四甲基二醇與別㈣莫耳％環己 炫二f醇；13至75莫耳02,2,4,4-四甲基-U-環丁二醇與 25至87莫耳％環己烷二甲醇；13至7〇莫耳％ Ha四甲 基-1，3-環丁二醇與3〇至87莫耳％環己烷二甲醇；。至“莫 耳％ 2,2,4,4-四甲基-1，3·環丁二醇與35至87莫耳％環己烧二 甲醇；U至60莫耳％ 2,2,4,4_四甲基.π環丁二醇與扣至 87莫耳％環己炫二甲醇，· 13至55莫耳。/。2,2,4,4·四甲基]3_ 環丁二醇與45至87莫耳％環己烷二甲醇，· U至50莫耳％ 2’2,4,4·四甲基+3·環丁二醇與5〇至87莫耳％環己烧二甲 醇；至小於50莫耳％ 2,2,4,4.四甲基]，3_環丁二醇與大 於50至87莫耳％環己燒二甲醇；13至45莫耳。Μ，#四甲 基-l，3_環丁二醇與55至87莫耳％環己院二甲醇；至扣莫 耳。/: 2,2,4,4-四甲基 環丁二醇與6〇至87莫耳％環己烷二 甲醇’· 13至35莫耳％ 2,2,4,4_四甲基·環丁二醇與“至 8.7莫耳％環己烧二甲醇；13至3G莫耳％ 2,2,4,4·四甲基-1，3-環丁二醇與70至87莫耳％環己烷二甲醇；i3至24莫耳％ 2:2:4,4-四甲基#環丁二醇與〜至87莫耳％環己烧二甲 醇，及13至25莫耳％ 2,2,4,4_四甲基]，3_環丁二醇與乃至 87莫耳％環己烷二甲醇。 於本發明之其他方面，供可用於本發明之聚醋用之 。成份，包括但不限於至少一種下列範圍組合："至的莫耳 % 2,2,4,4·四甲基]，3_環丁二醇與丄至％莫耳％環己烷二甲 119732.doc -217- 200804457 醇。；他95莫耳％2,2,4,4四甲基·u.環丁二醇與5至㈣ 己燒二甲醇；14至90莫耳％ 2,2,4,4-四甲基]3環丁 二醇與啦崎耳％環己院醇；14至85莫耳％ Μ，# 四甲基·1，3-環丁二醇與15至86莫耳％環己烧二甲醇；14至 80莫耳％ 2,2,4,4·四甲基.n環了二醇與加至％莫耳％環己 烷一甲醇，14至75莫耳％ 2,2,4,4_四甲基•環丁二醇與 25 至 86 莫耳 、 斗。衣己烷一甲醇；14至7〇莫耳0/〇 2,2,4 4_四甲 基:u-環丁二醇與30至86莫耳%環己烧二甲醇；14至“莫 耳。:.’2,4,4·四甲基]，3_環丁二醇與”至％莫耳％環己炫二 甲知，14至6〇莫耳％ 2,2,4,4·四甲基-1，3-環丁二醇愈4〇至 _耳％環己院二甲醇；14至55莫耳％ 2,2，M_四甲基^ %丁二酵與45至86莫耳％環己烧二甲醇；W5〇莫耳％ ，四甲基丨，3-% 丁二醇與50至86莫耳〇/0環己烷二甲 醇；14至小於5〇莫耳％ 2,2，M-四甲基]，3_環丁二醇盘大 於50至86莫耳％環？焓-田γ … ^ 衣己烷一甲醇，· 14至45莫耳％ 2,2,4,4_四甲 土 〇-1’3-環丁二醇與55至86莫耳％環己院二甲醇· μ至仰莫 耳％ 2,2,4,4·四甲基_1，3_環丁二醇與60至86莫耳％環己炫二 ^耳14至35莫耳％ 2,2,4,4·四甲基-Μ_環丁二醇與65至 =耳。轉己炫二甲醇；14至3。莫耳％2,2,4,4_叫^ 7〇至86莫耳％環己烧二甲醇’· 14至24莫耳％ ^，，四甲基-1，3·環丁二醇與％至86莫耳％環己燒二甲 醇；及14至25莫耳％ 2,2 > ㈣例己烧二甲醇。 Ί1，3,丁二醇與75至 於本發明之其他方面，供可用於本發明之聚醋用之二醇 119732.doc -218- 200804457 成份，包括但不限於至少一種下列範圍組合：15至99莫耳 % 2,2,4,4-四甲基-u-環丁二醇與u85莫耳％環己烷二甲 酵，15至95莫耳％ 2,2,4,4-四甲基_丨，3·環丁二醇與5至85莫 耳％環己燒二曱醇；15至9〇莫耳％ 2,2,4,4_四甲基.a環丁 二醇與10至85莫耳％環己烷二甲醇；15至85莫耳％ ;，2,4\_ 四曱基-1，3-環丁二醇與15至85莫耳％環己烷二甲醇；15至 8〇莫耳％ 2,2,4,4·四甲基+3-環丁二醇與2〇至肊莫耳％環己 烷二曱醇；15至75莫耳％ 2,2,4,4-四甲基環丁二醇盘 25至85莫耳％環己烷二甲醇；15至7〇莫耳％ 2,2,4,4_四甲 基-1，3-環丁二醇與3〇至85莫耳％環己烷二甲醇；15至μ莫 耳％ 2,2,4,4-四甲基環丁二醇與乃至“ 甲醇咖莫一一-二 85莫耳％環己烧二甲醇；15至55莫耳％ 2,2,4,4·四甲基_n 環丁二醇與45至85莫耳％環己烷二甲醇；15至5〇莫耳％ 2,2,4,4-四甲基十弘環丁二醇與5〇至85莫耳％環己烷二甲 醇；15至小於50莫耳％ 2,2,4,4_四甲基^3·環丁二醇與大 於50至85莫耳％環己烧二甲醇；15至45莫耳％ Μ，#，心四甲 基-1，3-環丁二醇與55至85莫耳％環己烷二甲醇’· ^至扣莫 耳％ 2,2,4,4-四甲基.u.環了二醇與6〇至85莫耳％環己炫二 甲醇；15至35莫耳％ 2,2,4,4_四甲基Μ·環丁二醇與^至 ^莫耳％環己院二甲醇；15至戦耳％ 2,2,4,4-四甲基 環丁二醇與70至85莫耳％環己烷二甲醇；^至乃莫耳％ 2二2’4,4-四甲基-μ —環丁二醇與乃至“莫耳％環己烧二甲 醇’及15至24莫耳％ 2,2,4,4_四甲基]，3·環丁二醇與乃至 119732.doc -219- 200804457 85莫耳％環己燒二甲醇。 於本發明之其他方面，供可用於本發明之聚酯用之二醇 成份，包括但不限於至少一種下列範圍組合· 2〇至99莫耳 % 2,2,4,4-四甲基]，3-環丁二醇與1至8〇莫耳％環己烷二甲 醇，20至95莫耳％ 2,2,4,4-四f基_1，3-環丁二醇與5至8〇莫 耳％環己烷二甲醇；20至9〇莫耳％ 2,2,4,4_四甲基-U-環丁 一醇與10至80莫耳。/。環己烷二甲醇，· 2〇至85莫耳％ 2,2,4,4_ 四甲基-1，3-環丁二醇與15至8〇莫耳％環己烷二甲醇；2〇至 莫耳4 2,2,4,4-四甲基- i，3-環丁二醇與2〇至8〇莫耳0/❶環己 烧二甲醇；20至75莫耳％ 2,2,4，心四？基山％環丁二醇與 25至8〇莫耳％環己烷二甲醇；20至70莫耳〇/〇 2,2,4,4-四甲 基_1，3_環丁二醇與3〇至8〇莫耳％環己烷二甲醇；汕至“莫 耳/〇 2,2,4,4-四甲基_1，3_環丁二醇與35至8〇莫耳環己烷二 甲醇；20至60莫耳％ 2,2,4,4_四f基巧，3環丁二醇與扣至 8〇莫耳％環己燒二甲醇；2G至55莫耳％ 2,2,4,4_四甲基 壞丁二醇與45至8〇莫耳％環己烷二甲醇；2〇至5〇莫耳％ 2’2,4,4-四甲基環丁二醇與5〇至8〇莫耳〇乂環己烷二甲 醇，20至小於5〇莫耳％ 2,2,4,4_四甲基-丨，3_環丁二醇及大 於5〇至8〇莫耳〇/〇環己烧二甲醇；20至45莫耳％ 2,2,4,4-四甲 基-1，3-環丁二醇與55至8〇莫耳％環己烷二曱醇；2〇至扣莫 耳2’2’4，心四曱基“，3_環丁二醇與60至80莫耳％環己烧二 甲醇’ 20至35莫耳❶/〇 2,2,4,4_四甲基-μ•環丁二醇與“至 莫耳％環己烧二甲醇；2〇至3G莫耳％ 2,2,4,4_四曱基十^ 環丁二醇與70至80莫耳％環己烷二甲醇·，及20至25莫耳％ 119732.doc 200804457 2,2,4,4-四甲基_U_環丁二醇與75至μ ^二y 醇。 、於本發明之其他方面，供可用於本發明之聚1旨用之二醇 成伤包括但不限於至少一種下列範圍組合：25至㈧莫耳 。。2’2,4,4四甲基十夂環丁烷二醇與a”莫耳％環己烷二 甲醇，25至95莫耳％ 2,2,4，心四甲基環丁二醇與巧乃 莫耳。/。環己烧二甲醇；25至9G莫耳％ 2,2，μ_四甲基^環 丁二醇與1〇至75莫耳％環己烷二甲醇；25至85莫耳％ 2:2,4,4-四f基ή 丁二醇與15至75莫耳％環己烷二甲 醇，25至80莫耳％ 2,2,4,心四甲基」，^環丁二醇與2〇至乃 莫耳％環己烧二甲醇；25至75莫耳％ 2,2,4,4•四甲基]，3環 丁二醇與25至75莫耳％環己烧二甲醇；25至7()莫耳％ 2.2.4.4- 四甲基環丁二醇與3〇至75莫耳％環己烷二甲 醇；25至65莫耳％ 2,2,4,4-四甲基_l，3-環丁二醇與35至75 莫耳％環己院二甲醇；25至60莫耳％ 2,2,4,4_四甲基·D環 丁二醇與40至75莫耳％環己烷二甲醇；乃至“莫耳^ 2.2.4.4- 四甲基_1，3_環丁二醇與45至75莫耳％環己烷二甲 醇；25至50莫耳％ 2,2,4,4-四甲基·1，3-環丁二醇與5〇至75 莫耳％環己烷二甲醇；25至小於5〇莫耳％ 2,2,4,4·四甲 基'3·環丁二醇與大於5〇至75莫耳％環己烷二甲醇；25至 45莫耳％ 2,2,4,4-四甲基-ΐ，3-環丁二醇與55至75莫耳％環己 烷二甲醇；25至40莫耳％ 2,2,4,4_四甲基環丁二醇與 60至75莫耳％環己烷二甲醇；25至35莫耳％ 2,2,4,4_四甲 基-1，3-環丁二醇與65至75莫耳％環己烷二甲醇；及以至⑽ 119732.doc -221 - 200804457 醇與70至75莫耳％環己烷 莫耳％ 2,2,4,4_四甲基-1，3-環丁 二甲 if·。 於本發明之其他方面，供可用於本發明之聚S旨用之二醇 。成份’包括但不限於至少_種下列範圍組合：3G至99莫耳 ’2,4,4 eg甲基_1>3_環丁二醇與u 莫耳％環己烧二甲 醉，3〇至95莫耳％ 2,2,4,4·四甲基·1，3·環丁二醇與5至70莫 耳％環己烧二甲醇；3〇至9〇莫耳％ 2,2,4,4-四甲基·^-環丁 二醇與1G至7G莫耳％環己烧二甲醇；30至85莫耳％ 2,2,4,4_ 四甲基-1，3-環丁二醇與15至7〇莫耳％環己炫二甲醇；％至 8〇莫耳％ 2,2,4,4·四甲基·Μ·環丁二醇與20至7〇莫耳％環己 烧一甲醇，30至75莫耳％ 2,2,4,4_四甲基·^3•環丁二醇與 25至70莫耳％環己烧二甲醇；3〇至7〇莫耳％ 2，w·四甲 基-1，3-環了二醇與30至7〇莫耳％環己炫二甲醇；3〇至㈣ 耳/〇 2,2,4,4-四甲基{3·環丁二醇與35至7〇莫耳％環己烧二 甲醇；30至60莫耳％ 2,2,4,4四甲基^·環丁二醇與概 1〇莫耳％環己炫二甲醇；3G至55莫耳％ 2,2,4,4·四甲基-H 環丁二醇與45至7〇莫耳％環己烧二甲醇；％至％莫耳％ 2二2’4’4-四f基-a環丁二醇與5〇至7〇莫耳％環己烧二甲 醇’ 30至小於50莫耳％ 2,2,4,4•四甲基.Μ·環丁二醇與大 於5〇至7〇莫耳〇/〇ί哀己烧二甲醇；3〇至45莫耳％ 心四甲 基-1，3-環丁烷二醇與55至7〇莫耳％環己烷二甲醇；％至4〇 莫耳❶/。2,2,4,4-四f基_!，3_環丁二醇與6〇至7〇莫耳％環己烷 二甲醇；30至35莫耳％ 2,2,4,4_四甲基環丁二醇與Μ 至70莫耳％環己烷二甲醇。 119732.doc 222- 200804457 於本發明之其他方面，供可用於本發明之㈣用之二醇 成份，包括但不限於至少-種下列範圍組合：35至99莫耳 2’2’4’4 izg甲基裒丁二醇與工至65莫耳。環己烷二甲 醇，· 35至95莫耳％ 2,2,4,心四甲基.u-環丁二醇與 耳％環己烧二甲醇；35至90莫耳％ 2,2,4,4-四甲基-π環丁 -醉與10至65莫耳％環己烧二甲醇；35至85莫耳％ 2,2,4，心 四甲基-1，3-環丁二醇與15至65莫耳％環己烧二甲醇；μ至 80莫耳/。2,2,4,4_四甲基{3.環丁二與2()至65莫耳。乂環己 烧-甲醇，35至75莫耳％ 2,2,4,4-四甲基-i，3-環丁二醇與 25至65莫耳％環己燒二甲醇，· 35至7()莫耳％ m心四甲 基-1，3-核丁二醇與3〇至65莫耳％環己烷二甲醇；Μ至6莫 耳，’4’4四甲基-1，3_環丁二醇與35至65莫耳％環己烷二 甲醇；35至60莫耳％ 2,2,4,4_四甲基]，3_環丁二醇與避 65莫耳％環己烧二甲醇；35至55莫耳％2,2,4,4_四甲基# 環丁二醇與45至65莫耳％環己烧二甲醇；35至5〇莫耳％ 2,2,4,4-四甲基m衷丁二醇與5〇至65莫耳％環己燒二甲 醇’ 35至小於5〇莫耳％ 2,2,4,心四甲基Μ·環丁二醇與大 於50至65莫耳％環己燒二甲醇；35至45莫耳％ m心四甲 基-1，3-環丁二醇與55至65莫耳％環己烷二甲醇，· ”至扣莫 耳％ 2,2,4,4-四甲基_i，3_環丁二醇與6〇至65莫耳％環己烷^ 甲醇。 於本發明之其他方面，供可用於本發明之聚酯用之二醇 成份，包括但不限於至少一種下列範圍組合· 4〇1至1〇〇 莫耳/〇 2,2,4,4-四甲基_丨，弘環丁二醇與is 59 9莫耳％環己 119732.doc 200804457 烷二甲醇’· 40至99莫耳％ 至60莫耳％環己卜^ ，甲基十3_%丁二醇與1 斗0衣己烷一歹醇；40至95莫耳％ 2,2,4,4•四甲 基_1，3_環丁二醇與5至6〇莫耳％環己貌二f醇·4〇至莫 耳％2,2,4,4·四甲基]，3_環丁二醇與1〇至6〇 、 甲醇，· 40至85莫耳％ 2,2,44_四 烷一 5，，— w r丞-1，3_核丁二醇盥15至 6〇莫耳。/。環己炫二〒醇；4〇至8〇莫耳％ 2,2,4,4_四〒基·! 3· 環丁二醇與2〇至60莫耳％環己燒二甲醇；40至75莫耳％ ，’’四甲基-1’3-% 丁二醇與25至6〇莫耳％環己烷二甲 醇；4〇至7〇莫耳％ 2,2,4,4-巧基-1，3-環丁二醇與30至60 莫耳❶環己烧二甲醇；40至65莫耳。/^从四甲基^環 丁二醇與35至60莫耳％環己烷二甲醇；4〇至6〇莫耳％ 2:2,4,4-四甲基十弘環丁二醇與⑽至6〇莫耳％環己烷二甲 醇，40至55莫耳％ 2,2,4,4_四甲基_1>3_環丁二醇與似的 莫耳％環己烧二甲醇；4〇至小於5〇莫耳％ 2,2,4,4_四甲 基-1，3-環丁二醇與大於5〇至6〇莫耳％環己烷二甲醇· 4〇至 50莫耳％ 2,2,4,4-四甲基.Μ.環丁二醇與5〇至6〇莫耳％環己 烧二甲醇，·及40至45莫耳％ 2,2,4,4_四甲基丁二醇 與55至60莫耳％環己烷二甲醇。 於本發明之其他方面，供可用於本發明之聚酯用之二醇 成伤，包括但不限於至少一種下列範圍組合：45至丨〇〇莫 耳/〇 2,2,4,4-四曱基_i，3·環丁二醇與〇至55莫耳％環己烷二 甲醇；45至99莫耳％ 2,2,4,4·四甲基]，3_環丁二醇與u55 莫耳/〇環己烧一甲醇，45至95莫耳％ 2,2,4,4·四曱基-1，3-環 丁 一醇與5至55莫耳％環己烷二甲醇；45至9〇莫耳％ 119732.doc -224- 200804457 2^，4,4_四甲基.以環丁二醇與1()至55莫耳％環己& 4 醇；45至85莫耳％ 2,2,4,4_四甲基_u•環丁二醇與15至^ 莫耳％環己烧二甲醇；45至戦耳％ 2,2,4,4四甲基·^-環 丁二醇與20至55莫耳％環己烷二甲醇；判至乃莫耳二 2二2,4,4_四甲基環丁二醇與25至55莫耳％環己烧二甲 醇；45至70莫耳％ 2,2,4,4_四f基」）-環丁二醇與3〇至55 莫耳％環己烧二甲醇；45至65莫耳％ 2,2,4,4_四甲基·^•環 丁二醇與35至55莫耳％環己烧二甲醇；45至6()莫耳。乂 2,2,4,4.四甲基-a環丁二醇與4〇至55莫耳％環己烧二甲 醇；大於45至55莫耳％ 2,2,4,4-四甲基Μ.環丁二醇盘U 至小於55莫耳％環己烧二甲醇；45至55莫耳％ Μ，#四甲 基-1，3-環丁二醇與45至55莫耳％環己烷二甲醇；及“至“ 莫耳％ 2,2,4,4-四甲基十弘環丁二醇與5〇至6〇莫耳。環己烷 二甲醇。 於本發明之其他方面，供可用於本發日月之聚δ旨用之二醇 成份，包括但不限於至少一種下列範圍組合：大於5〇至99 莫耳％ 2’2,4,4-四甲基]，3_環丁二醇與u j、於5〇莫耳％環 己烧二甲醇；大於50至95莫耳％ 2,2,4,4_四甲基·以·環丁 -醇與5至小於5G莫耳％環己燒二甲醇；大於％至％莫耳％ 2,2,4,4-四甲基_ΐ，3·環丁二醇與1〇至小於5〇莫耳％環己烷二 曱醇；大於50至85莫耳％ 2,2,4,4_四甲基]，3_環丁二醇與 15至小於5〇莫耳％環己烷二甲醇；大於50至80莫耳％ 2,2,4,4_四甲基_1，3_環丁二醇與⑼至小於⑼莫耳％環己烧二 甲醇；大於50至75莫耳％ 2,2,4,4_四甲基^環丁二醇： 119732.doc •225- 200804457 25至小於50莫耳％環己烷二甲醇；大於5〇至7〇莫耳％ 2,2,4,4·四甲基-1，3·環丁二醇與30至小於50莫耳％環己烷二 曱醇，大於50至65莫耳％ 2,2,4,4-四甲基- l，3-環丁二醇與 35至小於50莫耳％環己烷二甲醇；大於5〇至6〇莫耳％ 2,2,4,4_四甲基-1，3_環丁二醇與4〇至小於5〇莫耳％環己烷二 甲醇。 於本發明之其他方面，供可用於本發明之聚酯用之二醇 成份，包括但不限於至少一種下列範圍組合：大於51至99 莫耳/〇 2’2,4,4-四甲基_ι，3_環丁二醇與J至小於49莫耳％環 己烷二甲醇；大於51至95莫耳％ 2,2,4,4_四甲基•環丁 二醇與5至小於49莫耳％環己烷二甲醇；大於51至9〇莫耳％ 2,2,4,4-四甲基13-環丁二醇與1〇至小於49莫耳％環己烧二 甲醇，大於51至85莫耳〇/〇 2,2,4,4-四甲基^，3-環丁二醇與 15至小於49莫耳％環己烷二甲醇；大於51至80莫耳％ 2,2,4,4-四甲基]，3-環丁二醇與2〇至小於的莫耳^環己烧二 甲醇；大於51至75莫耳％ 2,2,4,4-四甲基環丁二醇鱼 25至小於49莫耳％環己燒二甲醇；大於51至70莫耳％ ，，，甲基i，3·環丁二醇與30至小於49莫耳％環己烷二 甲醇，大於51至65莫耳％ 2,2,4,4-四甲基-1，3-環丁二醇鱼 35至小於49莫耳％環己燒二甲醇；及大於Η·莫耳％ ^2；4,4·四甲基]，3·環丁二醇與4G至小於49莫耳％環己燒二 甲醇。 於本發明之其他方面， 面供可用於本發明之聚酯用之二醇 成份，包括但不限於至少一 」種下列範圍組合：55至99莫耳 119732.doc •226· 200804457 % 2,2,4,4-四甲基]，3_環丁二醇與以仏莫耳％環己烷二甲 醇；55至95莫耳％ 2,2,4,心四^基巧义環丁二醇與5至45莫 耳％環己烷二甲醇；55至90莫耳％ 2,2,4,4_四甲基]，3_環丁 一醇與10至45莫耳％環己烷二甲醇；55至85莫耳。〆〇 2,2,4,4_ 四甲基·1，3·環丁二醇與15至45莫耳0/〇環己烷二甲醇，·乃至 80莫耳/❶2,2,4,4-四甲基_ι，3-環丁二醇與2〇至45莫耳％環己 烷二甲醇，· 55至75莫耳％ 2,2,4,4_四甲基义3_環丁二醇與 25至45莫耳〇/〇環己院二甲醇；55至7〇莫耳〇/〇 2,2,4，心四甲 基-1，3-環丁二醇與3〇至45莫耳％環己烷二甲醇；”至“莫 耳％ 2,2,4,4_四甲基―丨，％環丁二醇與35至45莫耳％環己烷二 甲醇；及55至60莫耳％ 2,2,4,4_四甲基d，％環丁二醇與4〇 至45莫耳％環己烷二甲醇。 於本發明之其他方面，供可用於本發明之聚酯用之二醇 成份，包括但不限於至少一種下列範圍組合· 6〇至99莫耳 % 2,2,4,4-四甲基-13-環丁二醇與1至4〇莫耳％環己烷二甲 醇，60至95莫耳％ 2,2,4,4_四甲基_1，3_環丁二醇與5至4〇莫 耳％環己烷二甲醇；60至9〇莫耳％ 2,2,4,4_四甲基·•環丁 二醇與10至40莫耳％環己烷二甲醇；6〇至85莫耳％ 四甲基-1，3-環丁二醇與15至4〇莫耳％環己烷二甲醇；的至 80莫耳/〇 2,2,4,4-四甲基-l，3-環丁二醇與2〇至40莫耳〇/。環己 烧二甲醇；60至75莫耳％ 2,2,4,4_四甲基·以環丁二醇與 25至40莫耳〇/〇環己烷二甲醇；及60至70莫耳％ 2,2,4,4-四甲 基-1，3-環丁二醇與3〇至4〇莫耳0/〇環己烷二甲醇。 於本發明之其他方面，供可用於本發明之聚酯用之二醇 119732.doc •227- 200804457 成份，包括但不限於至少一種下列範圍組合：65至99莫耳 % 2,2,4,4_四甲基{3-環丁二醇與^^莫耳％環己烷二甲 醇，65至95莫耳％ 2,2,4,4-四甲基十％環丁二醇與5至35莫 耳％環己烧二甲醇；65至9〇莫耳％ 2,2,4,4•四甲基環丁 二醇與10至35莫耳％環己烷二甲醇；65至85莫耳％ 2,2j，4_ 四甲基-1，3_環丁二醇與15至35莫耳0/〇環己烷二甲醇，65至 80莫耳％ 2,2,4,4_四甲基_1，3_環丁二醇與2()至35莫耳％環己 烧二甲醇；65至75莫耳％ 2,2，M_四甲基]，3_環丁二醇與 25至35莫耳％環己烧二甲醇；及65至7()莫耳％ 2,2,4,4_四甲 基-1，3-環丁二醇與3〇至35莫耳％環己烷二甲醇。 於本發明之其他方面，供可用於本發明之聚酯用之二醇 成份，包括但不限於至少一種下列範圍組合：7〇至99莫耳 2,2,4,4-四甲基環丁二醇與1至3〇莫耳％環己烷二甲 酉予，70至95莫耳％ 2,2,4,4_四甲基-丨’3•環丁二醇與5至3〇莫 耳％環己烷二甲醇；7〇至9〇莫耳％ 2,2,4,4_四曱基·以-環丁 一酉子與10至30莫耳％環己烷二甲醇；7〇至85莫耳％ 2,2,4,4_ 四曱基-1,3-環丁二醇與15至3〇莫耳。/〇環己烷二甲醇；7〇至 80莫耳％ 2,2,4,4-四甲基_1，3_環丁二醇與2〇至3〇莫耳％環己 烧甲醇，70至75莫耳％ 2,2,4,4-四甲基·ι，3·環丁二醇與 25至30莫耳％環己燒二甲醇。 於本發明之其他方面，供可用於本發明之聚酯用之二醇 成份’包括但不限於至少一種下列範圍組合：75至99莫耳 〇/〇 2,2,4,4·四甲基-1，3·環丁二醇與1至25莫耳％環己烷二甲 醇’ 75至95莫耳％ 2,2,4,4·四甲基-ΐ，3·環丁二醇與5至25莫 119732.doc 200804457 耳％環己炫二甲醇；75至90莫耳％ 2,2,4,4_四甲基.Μ-環丁 -享” 10至25莫耳％環己烷二甲醇；及75至莫耳％ 2/，4,4_四甲基-1，3·環丁二醇與b至25莫耳％環己炫二甲 醇。 、於本發明之其他方面，供可用於本發明之㈣用之二醇 成份，包括但不限於至少一種下列範圍組合：8〇至Μ莫耳 % 2,2,4,4-四甲基{3.環丁二醇與J至2〇莫耳％環己烧二甲 醇；嶋95莫耳％ 2,2,4,4·㈣基·u環丁二醇與$至辦 耳％環己烧二曱醇；80至9〇莫耳％ 2,2,4,4_四甲基.Μ-環丁 二醇與10至20莫耳％環己烷二甲醇。 於本心Θ之其他方面’供可用於本發明之聚自旨用之二醇 成份，包括但不限於至少一種下列範圍組合：37至8〇莫耳 % 2,2’4,4-四甲基-a環丁二醇與2〇至63莫耳％環己烧二甲 醇；40至小於45莫耳％ 2,2,4,4·四甲基.π環丁二醇與大 於55至60莫耳％環己烧二甲醇；大祕至”莫耳％ Μ，# 四甲基-1，3-壤丁二醇與45至小於55莫耳％環己烷二甲醇； 及46至55莫耳％ 2,2,4,4-四甲基-u-環丁二醇與45至54莫 耳％環己燒二甲醇；及46至65莫耳％ 2,2,4,4·四甲基·D-環 丁二醇與35至54莫耳％環己烷二甲醇。 於本發明之其他方面，供可用於本發明之聚醋用之二醇 成份，包括但不限於至少一種下列範圍組合：〇 〇1至^莫 耳％ 2’2’4’4_四甲基-:^-環了二醇與85至99%莫耳❶乂環己 烧二甲醇；Ο.ίΗ至小於15莫耳％ 2,2,4,4四甲基]，3·環丁二 醇與大於85至99.99莫耳％環己院二甲醇；〇〇m莫耳％ 119732.doc -229· 200804457 2,2,4,4-四甲基山弘環丁二醇與“至外的莫耳％環己烷二 甲醇，0.01至13莫耳％ 2,2’4,4-四甲基-1，3_環丁二醇與87至 99."莫耳％環己烧二甲醇；〇.〇1至12莫耳％ 2,2,4,4·四甲 基丁二醇與88至99 99莫耳％環己烷二甲醇；至 11莫耳％ 2,2,4,4·四甲基W·環丁二醇與89至99·99莫耳％ 環己烧二甲醇；〇.〇1至1〇莫耳％ 2,2,4,4_四甲基.Μ·環丁二 醇與90至99.99莫耳％環己烧二甲醇；〇〇1至小於1〇莫耳。 2,2,4,4·四甲基―1，3-環丁二醇與大於90至99.99莫耳％環己 院二甲醇；G.G1至9莫耳％ 2,2,4,4_四甲基十3•環丁二醇盘 以至队外莫耳％ W-環己院二甲醇；〇〇1至8莫耳 2,2,4,4_四甲基-1，3·環丁二醇與92至99.99莫耳％環己烷二 甲醇，0.01至7莫耳％ 2,2,4,4_四甲基-環丁二醇與^至 99."莫耳％環己炫二甲醇’· 〇.〇1至5莫耳％ 2,2,4,4·四甲 基環丁二醇與95至99·99莫耳0/〇環己烷二甲醇；〇㈦至 小於5莫耳。/。2,2,4,4_四甲基.以環丁二醇與大於95至99 99 料％環己院二甲醇；0.01至4.5莫耳％2,2,4,4四甲基^ 〇環丁二醇與95 5至99 99莫耳0/〇環己烷二甲醇；耳 j 2,2,4,4·四甲基-1,3-環丁二醇與96至99.99莫耳％環己俨 二甲醇；〇·(Η至3·5莫耳％2,2,4,4_四甲基]，3_環丁二醇: 96.5至99·99莫耳％環己烧二甲醇；0.01至3莫耳％ 2,2,4 4_ 四甲基_1，3_環丁二醇與97至99 99莫耳％環己烷二甲醇. _至以莫耳％ 2’2’4,4-四甲基#環丁二醇與97.5至 =99_%環己院二甲醇’· ^⑴莫耳％ 四甲 土環丁二醇與98至99.99莫耳％環己烷二甲醇，❶^至 119732.doc -230- 200804457 1·5莫耳〇/〇 2,2,4,4-四甲基_153_環丁二醇與98.5至9999莫耳 %環己烧二甲醇；OWM莫耳％ 2,2,4,心四？基]，環丁 一醇與99至99.99莫耳％環己燒二甲醇；及〇〇1至〇.5莫耳％ 2,2,4,4-四甲基-1，3·環丁二醇與99.5至99.99莫耳％環己烷二 甲醇。 於本發明之其他方面，其中2,2,4，心四甲基'弘環丁二 醇之莫耳百分比係以GG1至小於5莫耳％存在，以二醇成份 之莫耳百分比等於100莫耳％為基準，且其中CHDM之存在 係為選用的，供可用於本發明之聚酯用之二醇成份，包括 但不限於至少下列範圍組合·· 0 01至小於5莫耳％ 2,2,4,4_ 四甲基-1，3-裱丁二醇殘基、〇 〇1至大於95莫耳％乙二醇殘 基及0至99.98莫耳％環己烷二甲醇；〇〇1至小於5莫耳％ 2,2,4,4-四甲基-i，3_環丁二醇殘基、〇 〇1至大於99·98莫耳％ 乙二醇殘基及0.01至99.97莫耳％環己烷二甲醇；〇〇1至小 於5莫耳％ 2,2,4,4-四甲基]，3_環丁二醇殘基、〇〇1至大於 90莫耳％乙二醇殘基及5至99·98莫耳％環己烷二甲醇· 至小於5莫耳％ 2,2,4,4-四甲基環丁二醇殘基、〇〇1至 大於85莫耳％乙二醇殘基及1〇至99 98莫耳％環己烷二甲 醇；0.01至小於5莫耳％ 2,2,4,4_四甲基-丨少環丁二醇殘 基、0.01至大於80莫耳％乙二醇殘基及15至9998莫耳％環 己烷二曱醇；〇.〇1至小於5莫耳％ 2,2,4,4_四甲基環丁 一醇殘基、0.01至大於75莫耳％乙二醇殘基及2〇至99·98莫 耳己烷二甲醇；O.Oi至小於5莫耳％ 2,2,4,4_四甲 基-1，3-環丁二醇殘基、〇·〇1至大於7〇莫耳％乙二醇殘基及 119732.doc -231 - 200804457 25至99·98莫耳％環己院二甲醇；0()1至大於65莫耳％乙二 醇殘基與30至99.98莫耳％環己烷二甲醇；〇〇1至小於5 = 耳％ 2,2,4,4-四甲基·ι，3-環丁二醇殘基、〇〇1至大於6〇莫耳 %乙二醇殘基及35至99·98莫耳％環己烷二甲醇；〇〇1至小 於5莫耳％ 2,2,4,4-四甲基-l53_環丁二醇殘基、〇〇1至大於 55莫耳％乙二醇殘基及4〇至99 98莫耳％環己烷二甲醇； 〇.〇1至小於5莫耳％ 2,2,4,4-四甲基{3.環丁二醇殘基、 0.01至大於50莫耳％乙二醇殘基及45至99 98莫耳。環己烷 二甲醇；0.01至小於5莫耳％ 2,2,4,4>_四甲基丁二醇 殘基、0.01至大於45莫耳。/。乙二醇殘基及5〇至99 98莫耳％ %己烷二甲醇；0·01至小於5莫耳0/〇 2,2,4,4_四甲基十弘環 丁二醇殘基、〇·01至大於4〇莫耳％乙二醇殘基及55至99.98 莫耳％環己烷二甲醇；0·01至小於5莫耳％ 2,2,4,4_四甲 基-1，3-裱丁二醇殘基、〇 〇1至大於35莫耳％乙二醇殘基及 60至99.98莫耳％環己烷二甲醇；〇 〇1至小於5莫耳％ 2,2,4，^四甲基-1，3·環丁二醇殘基、0.01至大於30莫耳％乙 二醇殘基及65至99.98莫耳％環己烷二甲醇；〇〇1至小於5 莫耳/❶2,2,4,4-四甲基β1，3_環丁二醇殘基、〇〇1至大於。莫 耳％乙二醇殘基及70至99·98莫耳％環己烷二甲醇；〇〇1至 小於5莫耳％ 2,2,4,4-四曱基-υ·環丁二醇殘基、〇〇1至大 於2〇莫耳％乙二醇殘基及75至99.98莫耳％環己烷二曱醇； 0.01至小於5莫耳％ 2,2,4,4-四甲基-ΐ，3·環丁二醇殘基、 〇·〇ΐ至大於15莫耳％乙二醇殘基及8〇至99 98莫耳。環己烷 一甲醇，0.01至小於5莫耳〇/〇 2,2,4,4_四甲基環丁二醇 119732.doc •232· 200804457 殘基、0.01至大於10莫耳％乙二醇殘基及85至99 98莫耳％ 環己烷二甲醇；0.01至小於5莫耳％ 2,2,4，心四甲基义弘環 丁一醉殘基、0.01至大於5莫耳％乙二醇殘基及9〇至99 98 莫耳％%己烷二甲醇；〇.01至小於5莫耳％ 2,2,4,4·四甲 基-1，3-環丁二醇殘基與〇.〇1至大於5莫耳％乙二醇殘基及 至99.98莫耳％環己烷二甲醇。 於本發明之其他方面 其中2,2,4,4-四甲基_ι，3-環丁二 醇之莫耳百分比係以〇〇1至5莫耳％存在，以二醇成份之莫 耳百分比等於100莫耳％為基準，且其中CHDM之存在係為 必須的’供可用於本發明之聚g旨用之：醇成份，包括但不 限於至少下列範圍組合·· 0·01至5莫耳％ 2,2,4,4-四甲 基_1，3_% 丁二醇殘基、89至大於94.99莫耳。/〇乙二醇殘基及 5至1〇莫耳％環己烷二甲醇；〇·〇1至5莫耳％ 2,2,4,4_四甲 基丨’夂缞丁二醇殘基、89至大於94.99莫耳％乙二醇殘基及 5至1〇莫耳％環己烷二甲醇；〇·〇1至5莫耳％ 2,2,4,4-四曱 基1’3-% 丁二醇殘基、84至大於89·99莫耳％乙二醇殘基及 1〇至15莫耳％環己烷二甲醇；〇·〇1至5莫耳％ 2,2,4,4-四甲 基/，3_% 丁二醇殘基、79至84.99莫耳％乙二醇殘基及15至 20莫耳/〇裱己烷二甲醇；〇 〇1至5莫耳〇/〇 2,2,4,4·四甲 基丨，3-% 丁二醇殘基、74至79.99莫耳％乙二醇殘基及20至 2 5 ♦一 jsi 〇/ 了四 _ 、 展己烷二甲醇；0.01至5莫耳％ 2,2,4,4·四甲 基-1，3 -環丁 — π Λ 4 一知殘基、69至74·99莫耳。/〇乙二醇殘基及25至 3 0莫可(y 、 0展己烷二曱醇；0·01至5莫耳％ 2,2,4,4-四甲 基""1，3 -環丁 — # 一知殘基、64至69·99莫耳％乙二醇殘基及30至 119732.doc •233 200804457 5莫耳〇/〇環己烧二甲醇；0.01至5莫耳％ 2,2,4,4-四曱 基環 τ -龄# # —%殘基、59至04.99莫耳％乙二醇殘基與35至 4〇莫耳％環产ρ 一 衣己庇一甲醇；0·01至5莫耳％ 2,2,4,4-四甲 基-1，3 -環丁 —齡冷# ^ 一知殘基、54至59.99莫耳％乙二醇殘基及40至 5莫耳％ %己燒二甲醇；〇·〇1至5莫耳％ 2,2,4,4-四甲 基丁二醇殘基、49至54.99莫耳％乙二醇殘基及45至 50莫耳0/〇被己燒二甲醇；〇 〇1至5莫耳0/〇 2,2,4,4_四甲 土 / -衣丁二醇殘基、44至49.99莫耳％乙二醇殘基及50至 55莫耳/〇被己烧二甲醇；〇 〇1至5莫耳0/〇 2,2,4,4_四曱 基/’3β% 丁二醇殘基、39至44.99莫耳％乙二醇殘基及55至 0莫耳/〇%己烧二曱醇；〇〇1至5莫耳％ 2,2,4,仁四甲 基丁二醇殘基、34至39.99莫耳％乙二醇殘基及60至 65莫耳〇/〇環己烧二甲醇；〇 〇1至5莫耳。/〇 2,2,4,4-四甲 基/，3β% 丁二醇殘基、29至34.99莫耳％乙二醇殘基及65至 70莫耳％環己烷二甲醇；〇 〇ι至$莫耳％ 2,2,4,4_四曱 土 衣丁二醇殘基、24至29.99莫耳％乙二醇殘基及70至 75莫耳％環己烷二甲醇；0 01至5莫耳％ 2,2,4,4·四曱 基/，弘％ 丁二醇殘基、19至24.99莫耳％乙二醇殘基及75至 80莫耳％環己烧二甲醇；0.01至5莫耳％ 2,2,4,4_四甲 基丁二醇殘基、^至^㈧莫耳％乙二醇殘基及⑽至 85莫耳％環己烷二曱醇；〇 〇1至5莫耳0/〇 2,2,4,4四甲 基丁二醇殘基、9至14 99莫耳％乙二醇殘基及85至 9〇莫耳％環己烷二甲醇；〇 〇1至5莫耳。/〇 2,2,4,4_四甲 基丨，3-^ 丁二醇殘基、4至9.99莫耳％乙二醇殘基及9〇至95 H9732.doc •234- 200804457 莫耳％環己燒二甲醇；及〇·Μ5莫耳％ 2,2,4,4-四甲 基-U-環丁二醇殘基、95至99 99莫耳％乙二醇殘基及〇至5 莫耳。/〇環己燒二甲醇。 於任何具體實施例中，其中2,2,4,4•四甲基_丨，3_環丁二 醇之莫耳百分比係以001至5莫耳％存在以二醇成份之莫 耳百分比等於100莫耳％為基準，且其中CHDM之存在係為 必須的’可用於本發明之聚酷之二醇成分亦可包含存在 〇.〇1至少於5莫耳。/。之TMCD之具體實施例，且於環己烷二 甲醇及/或乙：醇殘基中之對應還原反應係預㈣於本發 明之範圍中。 =醇成份亦可含有下列2,2,4,4_四甲基]，3_環丁二醇殘 基I&圍之.0.01至W莫耳％ ; 0.01至9.5莫耳％ 〇 0^9 莫耳％，· 〇.〇1至8.5莫耳％; 〇.〇1至8莫耳％; 〇〇m莫耳 〇·〇1至5.5莫耳％ ; 0.01至5莫耳％ ; 〇 〇1至少於5莫耳％ ; 〇 · 〇 1 至 4 · 5 莫耳 ％; 0.01 至 4堇互^/ · λ λ t 7- ^ 主4莫耳/〇，0·01至3.5莫耳％ ; 0·01 至3莫耳％; 0.01至25直且。/ · π η 1 7* ^ ύ其耳彳，0·01至2·〇莫耳％ ; 0.01至2.5 莫耳％; 0.01至2莫耳％· ηηιπ 1广分 兵耳/〇 , 〇·01至^莫耳。/。，· 0.01至1·〇莫耳 % ;及0.01至0.5莫耳％。 於某些具體實施例中，—艘占八 Μ Τ 一知成分之剩餘物可含有，但不 限於，任何量之環己烷二甲 吁久/ ¾乙一醇，只要二醇成 份之總量等於100莫耳％即可。 除了上文提出之二醇類以外， r J用於本發明聚酯組合物 之聚酯，可製自1，3-丙二醇、〗4_ 丁 - γ β廿 畔A，4 丁一醇及其混合物。意 119732.doc -235 - 200804457 欲涵蓋的是，製自丙二醇、M_ 丁二醇及其混合物之 本發明組合物，可具有至少一個本文中所述之範圍，至 少-個本文中所述之固有黏度範圍，及/或至少一個本文 中所述之二醇或二酸範圍。此外或在替代方式中，，自 丙二醇W，4_T二醇及其混合物之聚§旨，亦可製自^ 核己烷二甲醇，以至少一個下列量：〇1至99莫耳。m 至90莫耳％ ; H8〇莫耳％ ; 〇 l7〇莫耳m的莫耳 %; 0.1至50莫耳％; n4〇莫耳％; 〇1至35莫耳％;〇1 至30莫耳0.1至25莫耳0.1至20莫耳。/0; n15莫耳 莫耳％; 莫耳％; 1至99莫耳％; i至90莫 耳％ 耳％ 耳％ 耳％ 耳％ 耳％; 1至8〇莫耳1至70莫耳％; 1至6〇莫耳。/。； U50莫 1至40莫耳％;丨屈莫耳％;丨錢莫耳％·丨至25莫 1至20莫耳％; u15莫耳％; ljLi()莫耳％;⑴莫 5至8〇莫耳％; 5至7G莫耳。/。； 5至60莫耳％; 5至5〇莫 5至4〇莫耳％; 5至35莫耳％; 5至30莫耳％; 5至25莫 5至20莫耳％;與5至15莫耳％; 5至1〇莫耳1〇至 "莫耳。/°; 10至90莫耳％; 至80莫耳10至70莫耳％. 莫莫耳％，·㈣莫 耳％;1〇至戰耳％;1()至25莫耳％;1()至2()莫耳％;1〇至 15莫耳％; 2G至"莫耳％; 2仏95莫耳％;跑轉耳％. 2〇至7〇莫耳％ ; 20至60莫耳％ ; 20至50莫耳％ ; 2〇至4〇莫 耳/。，20至35莫耳。/。，20至30莫耳。/。；及2〇至25莫耳％。 關於本發明之具體實施例，可用於本發明之聚醋，當在 60/4〇 (重里/重1)紛/四氯乙烷中，於ου克毫升之濃度 119732.doc -236- 200804457 下，在25 °C下測定時，可顯示至少一個下列固有黏度： 〇·1〇至1.2公合/克，0·10至1_1公合/克；〇·ι〇至1公合/克； 0.10至小於1公合/克；0.10至0.98公合/克；〇·ΐ〇至0.95公合 /克；0.10至0.90公合/克；〇·1〇至〇·85公合/克；〇.1〇至0.80 公合/克；0.10至0.75公合/克；〇·ΐ〇至小於〇·75公合/克； 0.10至0.72公合/克；0.10至0.70公合/克；〇.1〇至小於〇·7〇 公合/克；0.10至〇·68公合/克；0.10至小於〇·68公合/克； 0.10至0.65公合/克；0.10至0.6公合/克；0.10至0.55公合/ 克；0.10至0.5公合/克；0.10至0.4公合/克；〇.1〇至0.35公 合/克；0.20至1.2公合/克；0·20至1.1公合/克；0.20至1公 合/克；0·20至小於1公合/克；0·20至0.98公合/克；0.20至 〇·95公合/克；0·20至0.90公合/克；0·20至0.85公合/克； 0.20至0_80公合/克；0.20至0.75公合/克；0.20至小於0.75 公合/克；0.20至0.72公合/克；0_20至0.70公合/克；0.20至 小於0.70公合/克；0.20至0.68公合/克；0.20至小於0.68公 合/克；0.20至0.65公合/克；0.20至0.6公合/克；0.20至 〇·55公合/克；0.20至0.5公合/克；0.20至0.4公合/克；0.20 至0.35公合/克；0.35至1.2公合/克；0.35至1.1公合/克； 0.35至1公合/克；0.35至小於1公合/克；0.35至0.98公合/ 克；0.35至0.95公合/克；0.35至0.90公合/克；〇·35至0·85 公合/克；0.35至0.80公合/克；〇·35至0.75公合/克；〇·35至 小於0.75公合/克；0.35至0.72公合/克；0.35至0.70公合/ 克；0.35至小於0.70公合/克；〇·35至0.68公合/克；0.35至 小於0·68公合/克；0.35至0.65公合/克；0.40至1.2公合/ 119732.doc -237- 200804457 克；0·40至1·1公合/克；〇·40至1公合/克；〇·4〇至小於1公 合/克；0.40至0.98公合/克；0.40至0.95公合/克；0.40至 〇·90公合/克；〇·4〇至0.85公合/克；0.40至0.80公合/克； 〇·40至0.75公合/克；0.40至小於0.75公合/克；0.40至0.72 公合/克；0.40至0.70公合/克；0·40至小於〇·70公合/克； 〇·40至〇·68公合/克；0.40至小於0.68公合/克；0·40至0.65 公合/克；大於0·42至I·2公合/克；大於〇·4；2至1.1公合/克； 大於0.42至1公合/克；大於0.42至小於1公合/克；大於0.42 至0.98公合/克；大於0.42至0.95公合/克；大於0.42至0.90 公合/克；大於0.42至0·85公合/克；大於0.42至0.80公合/ 克；大於0·42至0·75公合/克；大於0.42至小於0.75公合/ 克’·大於0.42至0.72公合/克；大於〇·42至0.70公合/克；大 於0.42至小於0.70公合/克；大於〇·42至0.68公合/克；大於 〇·42至小於〇·68公合/克；及大於0.42至0.65公合/克。 關於本發明之具體實施例，可用於本發明之聚酯，當在 60/40 (重量/重量）酚/四氣乙烷中，於〇25克/5〇毫升之濃度 下’在25 °C下測定時，可顯示至少一個下列固有黏度： 0.45至1.2公合/克；0.45至1.1公合/克；〇·45至1公合/克； 〇·45至〇·98公合/克；0.45至0.95公合/克；0.45至0.90公合/ 克；〇·45至0.85公合/克；0.45至0.80公合/克；0.45至0.75 公合/克；0.45至小於0.75公合/克；〇·45至0.72公合/克； 〇_45至0.70公合/克；〇·45至小於〇·7〇公合/克；0.45至0.68 公合/克；0.45至小於0.68公合/克；〇·45至0.65公合/克； 〇·50至1.2公合/克；〇·5〇至1.1公合/克；〇5〇至1公合/克； 119732.doc -238 - 200804457 0.50至小於1公合/克；0·50至〇·98公合/克；0.50至0.95公合 /克；0.50至0.90公合/克；0.50至0.85公合/克；0.50至0.80 公合/克；0.50至0.75公合/克；0.50至小於〇_75公合/克； 〇·50至0.72公合/克；0_50至〇·70公合/克；〇.5〇至小於〇.7〇 公合/克；0·50至0.68公合/克；〇·50至小於〇·68公合/克； 〇·50至0·65公合/克；0.55至1.2公合/克；0.55至1.1公合/ 克；0·55至1公合/克；0.55至小於1公合/克；〇·55至0.98公 合/克；0·55至0.95公合/克；0·55至0.90公合/克；0.55至 0.85公合/克；0.55至0.80公合/克；0.55至0.75公合/克； 0.55至小於0.75公合/克；0.55至0.72公合/克；0.55至0.70 公合/克；0.55至小於0.70公合/克；0.55至0.68公合/克； 0.55至小於0.68公合/克；0.55至0.65公合/克；0.58至1.2公 合/克；0.58至1·1公合/克；0.58至1公合/克；0.58至小於1 公合/克；0.58至0.98公合/克；0.58至0.95公合/克；0.58至 〇·90公合/克；0.58至0.85公合/克；0.58至0.80公合/克； 0.58至0.75公合/克；0.58至小於0.75公合/克；0·58至0·72 公合/克；0.58至0.70公合/克；0.58至小於0.70公合/克； 0.58至0.68公合/克；0.58至小於0.68公合/克；0.58至0.65 公合/克；0.60至1.2公合/克；0.60至1.1公合/克；0·60至1 公合/克；0.60至小於1公合/克；0.60至0.98公合/克；0.60 至0.95公合/克；0.60至0.90公合/克；0.60至0.85公合/克； 0.60至0.80公合/克；0.60至〇·75公合/克；0.60至小於〇·75 公合/克；〇·60至0.72公合/克；0·60至0.70公合/克；〇·60至 小於0.70公合/克；0.60至0.68公合/克；0.60至小於〇·68公 119732.doc -239- 200804457 合/克；0.60至0.65公合/克；0.65至1.2公合/克；〇·65至1.1 公合/克；〇·65至1公合/克；〇·65至小於1公合/克；〇·65至 0.98公合/克；0.65至0.95公合/克；〇·65至0.90公合/克； 0·65至0.85公合/克；0.65至0.80公合/克；〇·65至0.75公合/ 克；0.65至小於〇·75公合/克；〇·65至0.72公合/克；〇·65至 0.70公合/克；〇·65至小於0.70公合/克；〇·68至1.2公合/ 克；0.68至1.1公合/克；〇·68至1公合/克；〇68至小於^々 合/克；0.68至0.98公合/克；〇·68至〇·95公合/克；〇68至 0.90公合/克；0.68至0.85公合/克；〇.68至〇8〇公合/克； 0.68至0.75公合/克；〇·68至小於〇·75公合/克；〇68至〇72 公合/克；大於0.76公合/克至1>2公合/克；大於〇 %公合/克 至1.1公合/克；大於0.76公合/克至i公合/克；大於〇76公 合/克至小於1公合/克；大於0·76公合/克至〇98公合/克； 大於〇·76公合/克至ο·%公合/克；大於〇 %公合/克至〇9〇公 合/克；大於0.80公合/克至丨·2公合/克；大於〇 8〇公合/克至 1.1公合/克；大於0.80公合/克至丨公合/克；大於〇8〇公合/ 克至小於1公合/克；大於〇·8〇公合/克至12公合/克，·大於 0.80公合/克至0.98公合/克’·大於〇 8〇公合/克至〇95公合/ 克；大於0.80公合/克至〇·9〇公合/克。 意欲涵蓋的是，可詩本發明之組合物可具有至少一個 本文中所述之固有黏度範圍，與至少—個關於本文中所述 、、且口物之單體範圍，除非另有述及。亦意欲涵蓋的是，可 用於本發明之組合物可具有至少—個本文中所述之城 圍’與至少一個關於本文中所述組合物之單體範圍，除非 119732.doc -240- 200804457 另有述及。亦意欲涵蓋的是，可用於本發明之組合物可具 有至少一個本文中所述之固有黏度範圍，至少一個本文中 所述之Tg範圍，及至少一個關於本文中所述組合物之單體 範圍，除非另有述及。 於一項具體實施例中，對苯二甲酸可作為起始物質使 用。於另-項具體實施例中，對苯二甲酸二甲料作為起 始物質使用。於又另一項具體實施例中，對苯二甲酸與對 苯一甲酸二甲酯之混合物可作為起始物質及/或作為中間 物質使用。 在某些具體實施例中，對苯二甲酸殘基或其酯，例如對 苯二甲酸二甲酯，或對苯二甲酸殘基與其酯之混合物，可 構成用以形成可用於本發明聚酯之一部份或全部二羧酸成 份。在某些具體實施例中，對苯二甲酸殘基可構成用以形 成本發明聚酯之一部份或全部二羧酸成份。在某些具體實 施例中’可使用較高含量之對苯二甲酸，以製造較高衝擊 強度聚酯。對本揭示内容之目的而言，術語："對笨二甲 酸”與，，對苯二甲酸二甲酯”可於本文中交換使用。於一項 具體實施例中，對苯二甲酸二甲酯係為用以製造可用於本 發明聚酯之一部份或全部二羧酸成份。對本揭示内容之目 的而言’術語·· ”對苯二甲酸”與”對苯二甲酸二甲酯"可於 本文中交換使用。在所有具體實施例中，7〇至1〇〇莫耳 0/〇;或80至100莫耳％;或9〇至1〇〇莫耳％;或99至1〇〇莫耳 °/〇 ’或1 00莫耳％範圍之對苯二甲酸及/或對苯二甲酸二甲 酯及/或其混合物，均可使用。 119732.doc -241 · 200804457 除了對苯二曱酸以外，可用於本發明聚酯之二羧酸成份 可包含至尚30莫耳％、至高2〇莫耳％、至高1〇莫耳％、至 阿5莫耳％，或至高丨莫耳％ 一或多種改質用芳族二綾酸 類。又另一項具體實施例，係含有〇莫耳％改質用芳族二 羧：類。因此’若存在日夺’意欲涵蓋的是，一或多種改質 用芳族二羧酸類之量，其範圍可涵蓋任何此等前述終點 值，包括例如0.01至30莫耳％、〇 〇1至2〇莫耳％、〇 〇1至1〇 莫耳％、〇.〇1至5莫耳。/。及㈣至】莫耳％。於一項具體實施 例中，可用於本發明中之改質用芳族二叛酸類包括但不限 於具有至高20個碳原子者’且其可為線性、對位取向或對 稱可用於本發明之改質用芳族二叛酸類之實例包括但不 限於間苯二曱酸、4,4，_聯苯基二羧酸、m_，H Μ、 2,7-蕃二叛酸及反式_4,4，_二苯乙稀二叛酸，及其醋類。於 -項具體實施例中’改質用芳族二羧酸為間苯二甲酸。 可用於本發明聚酯之羧酸成份，可進一步以至高莫耳 %，譬如至高5莫耳％或至高i莫耳％一或多種含有2_16個碳 原子之脂族二羧酸類改質，例如環己烷二甲酸、丙二酸、 玻拍酸、戊二酸、己二酸、庚二酸、辛二酸、壬二酸及十 ，烷二酸二羧酸類。某些具體實施例亦可包含〇〇1或至ι〇 莫耳％言如0.1或1〇莫耳％，^ι〇莫耳％，5至1〇莫耳％ 之-或多種改質用脂族二羧酸類。又另一項具體實施例， 係含有0莫耳％改皙用日匕& _ , 、知無二羧酸類。二羧酸成份之總莫155〇C 110 to 120〇C; 110 to 115〇C; 115 to 200〇C; 115 to 115 to 180°C; 115 to 170°C; 115 to 160〇C; 115 to 115 to 150〇C; To 145〇C; 115 to 140〇C; 115 to 115 to 135〇C; 115 to 130°C; 115 to 125〇C; 115 to 120 to 200〇C; 120 to 190°C; 120 to 180°C 120 to 120 to 160 ° C; 120 to 155 ° C; 120 to 150 ° C; 120 to 120 to 140 ° C; 120 to 138 ° C; 120 to 135 ° C; 120 to 125 to 200 ° C; To 190 ° C; 125 to 180 ° C; 125 to 125 to 160 ° C; 125 to 155 ° C; 125 to 150 ° C; 125 to 125 to 140 ° C; 125 to 138. . 125 to 135 〇C; 127 to 127 to 190 ° C; 127 to 180 ° C; 127 to 170 ° C; 127 to 127 to 150 ° C; 127 to 145 ° C; 127 to 140 ° C; 127 to 127 To 135〇C; 130 to 200°C; 130 to 190°C; 130 to 130 to 170°C; 130 to 160〇C; 130 to 155〇C; 130 to 130 to 145〇C; 130 to 140°C 130 to 138 ° C; 130 to 135 to 200 ° C; 135 to 190 ° C; 135 to 180 ° C; 135 to 135 to 160 ° C; 135 to 155 ° C; 135 to 150 ° C; To 140 ° C; 140 to 200 ° C; 140 to 190 ° C; 140 to 140 to 170 ° C; 140 to 160 ° C; 140 to 155 ° C; 140 to 140 to 145 ° C; 148 to 200 ° C 148 to 190 ° C; 148 to 148 to 170 ° C; 148 to 160 ° C; 148 to 155 ° C; 148 to greater than 148 to 200 ° C; greater than 148 to 190 ° C; greater than 148 to; greater than 148 to 170 ° C; greater than 148 to 160 ° C; greater than 148 to; 150 to 200 ° C; 150 to 190 ° C; 150 to 180 ° C; 150 to 119732.doc -208 - 200804457 170 ° C; 150 to 160; 155 to 190 ° C; 155 to 180 ° C; 155 to 170 ° C; and 155 to 165 ° C. In other aspects of the invention, the diol components useful in the polyesters of the present invention include, but are not limited to, at least one of the following ranges: from 1 to 99 mole % 2,2,4,4-tetramethyl-i , 3-cyclobutanediol with 1 to 99 mole % cyclohexane dimethanol; 1 to 95 mole % 2,2,4,4-tetramethyl-i,3-cyclobutanediol with 5 to Molar% cyclohexanedimethanol; mol% 2,2,4,4·tetramethyl-hydrazine, 3_cyclobutanediol and 10 to 99 mol% cyclohexanedimethanol; 1 to 85 Mo Ear % 2,2,4,4_ tetradecyl-1,3-cyclobutanediol with 15 to 99 mol% cyclohexanedimethanol; 1 to 8 mol% 2,2,4,4_4 Methyl 4,3-cyclobutanediol with 2〇 to 99mol% cyclohexane-methanol, 1 to 75mol% 2,2,4, cardiotetramethyl], 3_cyclobutanediol and 25 To 99 mol% cyclohexane dimethanol; ι7 〇 mol % Μ, #四摩尔_ 1,3_cyclobutanediol and 30 to 99 mol% cyclohexane dimethanol" to "Mo 2 ^2,4,4-Tetramethyl], 3_cyclobutanediol and 35 to 99 mol% cyclohexanal q alcohol; 1 to 60 mol% 2,2,4,4_tetramethyl"} Cyclobutanediol and 4〇 to 99mol% of cyclohexanal dimethanol; 1 to 55 mol% 2,2,4,4·tetramethyl-10-3, · Butylene glycol with 45 to "mol% cyclohexane dimethanol, · mol% alcohol '1 to 45 mol% 2,2,4,4 -tetramethyl q^ soil-1,3 - % butanediol with 55 to 99 spectacles % cyclohexane dimethanol; To 4〇莫耳, 斗/〇 2,2,4,4·tetramethyl-1,3·cyclobutanol and 60 to 99 moles/0 cyclohexanide-field + hexane-methanol; 1 to 35 mol% 22" tetramethyl 13-cyclobutanediol with 65 to 99, 2, 4, 4 · π mol. /...." base ... two ears ... burn dimethyl "to ' base m clothes Butanediol with 70 to 99 mol% 顼? burned dimethanol; mountain 5 mol%2,2,4,4 耳仏口口丞rι_ι,3_ί哀丁diol and 75 H9732.doc 200804457 "Mole% cyclohexanthrene dimethanol; 1 to 2G mole% 2,2,4,4_tetramethyl·1,3-cyclobutanediol and 80 to 99 mol% cyclohexane dimethanol; m mol% 2,2,4,4-tetradecyl], 3_cyclobutanediol and 85 to 99 mol% cyclohexane dimethanol; 1 to 1 mol% 2,2,4,4 · tetramethyl-U-cyclobutanediol with 90 to 99 moles of cyclohexane dimethanol; and (1) mole % 2,2,4,4_tetramethyl n3_cyclobutanediol with 95 to 99 moles Deafness/〇cyclohexanedimethanol. In the context of the present invention, the diol component for use in (4) of the invention may include, but is not limited to, at least one of the following ranges: 3 to 1 mole % 2, 2,4,4_tetramethyl], 3_cyclobutanediol and 9〇 to 97mol% cyclohexene Dimethanol; 3 to 9 mol% 2,2,4,4_tetrafyl], 3_cyclobutanediol and "to" molybdenum/cyclohexane dimethanol; and 3 to 8 mol% 2,2,4,4_tetramethylguanidine.cyclobutanediol and 92 to 97 moles/oxime cyclohexane dimethanol. In other aspects of the invention, for use in the polyester useful in the present invention. The diol component, including but not limited to at least one of the following ranges: 5 to 99 mole % 2,2,4,4-tetramethylcyclobutanediol and 1 to 95 mole % cyclohexanedimethanol, 5 to 95 mol% 2,2,4, deducted tetramethylthene cyclobutanediol and ^"mol% cyclohexane dimethanol; 5 to 9 〇 mol% 2,2,4, cardiac tetramethyl ring Butanediol with 10 to 95 mole % cyclohexane dimethanol; 5 to 85 mole % 2,2,4,4_tetramethyl-1,3-cyclobutanediol and 15 to 95 mole % cyclohexane Alkanediethanol, · 5 to 8 〇 mol % 2,2,4,4·tetramethyl·1,3·cyclobutanediol and 2G to 95 mol% cyclohexane dimethanol; 5 to 75 mol % 2,2,4,4-tetramethyl-a cyclobutanediol with 25 to 95 mole % cyclohexanedimethanol; 5 to 7 mole % 2,2,4,4_tetramethyl 1,3-cyclobutanediol with 3 to 95 moles of cyclohexane dimethanol; 5 to 65 mole % 2,2,4,4-Tetramethylcyclobutanediol with 35 to 95 moles/〇cyclohexanedimethyl 119732.doc -210- 200804457 alcohol, 5 to 60 moles/〇2,2, 4,4·tetramethyl], 3_cyclobutanediol and 40 to 95 mol% cyclohexanedimethanol; 5 to 55 mol% 2,2,4,4-tetramethylcyclobutanol 45 to 95 moles per hydrazine cyclohexane decyl alcohol; and 5 to 5 moles % 2,2,4,4-tetramethyl core, % cyclobutanediol and 5 Å to 95 mole % ring Hexane dimethanol. In other aspects of the invention, the diol components useful in the polyesters of the present invention include, but are not limited to, at least one combination of the following: 5 to less than 5 〇 Mohr/〇2, 2'4, 4-F Base_1,3_cyclobutanediol with more than 5 〇 to 95 mol% of cyclohexane dimethanol; 5 to 45 mol% of 2,2,4,4-tetramethyl], 3_cyclobutanediol With 55 to 95 moles of cycloheximide dimethanol; 5 to 4 moles of moles 2,2,4, cardiotetramethyl 1,3-cyclobutanediol and 6 to 95 moles of cyclohexane Dimethanol; $ to moll% 2'2,4,4-tetramethyl-1,3-cyclobutanediol with 65 to 95 moles per hydrazine cyclohexane dimethanol, 5 to less than 35 moles % 2,2,4,4_tetramethyl-fluorene-cyclobutanediol with more than 65 to 95 mol% cyclohexane dimethanol; 5 to 3 () mol% 2, 2, 4, 4_4 Methyl 1,3- 1,3-ditylene glycol and 7 〇 to 95 mol % cyclohexane dimethanol; $ to molimo% 2,2,4,4-tetramethylguanidinium diol and even % mol % cyclohexane dimethanol, 5 to 20 mol % 2,2,4,4_tetramethylcyclobutanediol and 8 〇 to (4) 耳% cycloheximide dimethanol; 5 to 15 mol% 2,2,4,4_tetramethyl.indole butylcyclohexane with 85 to 95 mol% of cycloheximide 5 to 1 〇 mol % Μ〆〆-tetramethyl-1,3·cyclobutanediol and 9 〇 to 95 mol% of cycloheximide dimethanol: greater than 5 to less than 1 〇 mol % 2,2 , 4,4•tetramethyl^%cyclobutanediol with less than 叩 to more than 95 mol% cyclohexane dimethanol; 55 mol% to 95 mol% 2'2'4,4·4 f base- Μ-cyclobutanediol with 94 5 mole % to column $ mole % cyclohexane bis-alcohol '· and 6 to 9 mole % 2,2,4,4·tetramethyl. Cyclobutanediol 119732.doc •211- 200804457 with 94 to 91 mol% cyclohexanedimethanol. In other aspects of the invention, the diol component for the polyester useful in the present invention includes, but is not limited to, at least one of the following ranges: 1 to 99 mole % 2,2,4,4-tetramethyl ring Butanediol and hydrazine to 卯mol% cyclohexanedimethanol, 10 to 95 mol% 2,2,4,4-tetraf-based, 3-cyclobutanediol and $ to mol% cyclohexene Alkanediethanol; 10 to 9 moles % 2,2,4,4-tetramethyl], 3_cyclobutanediol and 1G to 9G mol% cyclohexane dimethanol; 1 () to 85 moles % 2,2,4, cardiac tetramethyl-1,3·cyclobutanediol and 15 to 9 〇 molar 0/〇 cyclohexane dimethanol; (7) to 80 mol/〇2, 2, 4, 4 - tetramethyl-hydrazine, ; ^ cyclobutanediol with 2 to 9 moles. Cyclohexane-methanol, 10 to 75 moles/〇2,2,4,4-tetramethyl-i,3-cyclobutanediol and 25 to 90 mol% cyclohexanedimethanol; Up to 7 〇 mol % 2,2,4,4-tetramethyl-1,3-cyclobutanediol with 3 〇 to 9 〇 mol % cyclohexane dimethanol · (7) to "mole /: 2, 2,4,4-Tetramethyl],% cyclobutanediol and 35 to 9 〇mol % cyclohexane dimethanol '10 to 60 mol% 2,2,4,4_tetramethylcyclobutane Alcohol with 4〇 to 2mol% cyclohexane dimethanol; Cong 55m% 2,2,4,4 tetramethyl#cyclobutanediol with 45 to 9G mol% ring am to (four) ear ^ '2 '4'4 tetramethyl", 3_cyclobutanediol with 5〇 to 9〇 mol% cyclohexanedimethanol; to less than 50 mol% 2,2 from tetramethyltri-3-cyclobutanediol Fish greater than 5 〇 is said to mol% cyclohexanal dimethanol; H) to 45 moles. /. 2,2,4,4_tetramethyl^,3_diabetic diol and 55 to 90 mol% cyclohexanedimethanol; 1 〇 to 40 mol% 2,2,4,4-tetramethyl ], % cyclobutanediol with 6〇 to 9〇 mol% cyclohexane dimethanol; 1〇 to 35mol% 2,2,4, tetramethylguanidine 3_cyclobutanediol and “to 90” Molar% cyclohexanol dihydric alcohol; 10 to less than 35 mol% 2,2,4, cardiotetramethylbutanediol and greater than 65 to 90% cyclohexanedimethanol; 1 〇 to 3 〇 Mo H9732. Doc -212- 200804457 Ear % 2,2,4,4-tetramethyl-ι, 3-cyclobutanediol and 7〇 to 9〇 mol% cyclohexanedimethanol; 10 to 25 moles/〇 2,2,4,4_tetramethyl],3·cyclobutanediol and even 9〇 mol% cyclohexanedimethanol; 1〇 to 2〇mol% 2,2,4,4_four Methyl-hydrazine, 3_cyclobutanediol and 80 to 90 mol% cyclohexanedimethanol; and 1 to 15 mol% of 2,2,4,4-tetramethyl-L3-cyclobutanediol 85 to 9 mole % cyclohexane dimethanol. In other aspects of the invention, the diol component for the polyester useful in the present invention includes, but is not limited to, at least one of the following ranges: 1 to 1 〇〇 Molar% 2,2,4,4-tetramethyl-i,3-cyclobutanediol and hydrazine to 9 Molar% cyclohexanedimethanol; greater than 10 to 99 mol% 2,2,4,4·tetramethyl-1,3-cyclobutanediol with J to less than 90 mol. /c) cyclohexane Dimethanol; greater than 10 to 95 mole % 2,2,4,4_tetramethyl-1,3-cyclobutanediol and 5 to less than 9 mole % cyclohexane dimethanol; greater than 10 to 90 moles ❶/. 2,2,4,4_tetramethyl·1,3_cyclobutanediol and 1 〇 to less than 90 mol% cyclohexanedimethanol; greater than 1 〇 to 85 mol% 2,2, 4,4_tetramethyl-1,3-cyclobutanediol with 15 to less than 9 〇 mol % cyclohexane dimethanol; greater than 10 to 80 mol % 2,2,4,4_tetramethyl- 1,3_cyclobutanediol with 2〇 to less than 9〇 mol% cyclohexanedimethanol; greater than 10 to 75 mol% 2,2,4,4-tetramethyl·1,3-cyclobutane Alcohol with 25 to less than 9 〇 mol % cyclohexane dimethanol; greater than 1 〇 to 70 mol. / ◦ 2,2,4,4·tetramethylcyclobutanediol and 3 〇 to less than 9 〇 mole % cyclohexane dimethanol; greater than 10 to 65 mol% 2,2,4,4·tetramethyldecanecyclobutanediol and 35 to less than 9 mol% cyclohexane dimethanol; greater than 1 Torr to 6〇莫耳❶/◦ 2,2,4,4-tetramethyl-1,3_cyclobutanediol and 4〇 to less than 9〇 Ear % cyclohexane dimethanol; greater than 10 to 55 mole % 2,2,4,4_tetramethyl-oxime, 3_cyclobutanediol and 45 to less than 90 mole % cyclohexanedimethanol; greater than 1〇至5〇莫耳119732.doc 213· 200804457 % 2,2,4,4_tetramethyl-πcyclobutanediol and % to less than % mol% cyclohexane dimethanol; greater than 10 to less than 50 Molar% 2,2,4, tetramethylcyclobutane, alcohol with greater than 50 to less than 90 mol% cyclohexanedimethanol; greater than 1 〇 to 45 mol% 2,2,4,4-tetra Base], 3, butanediol and 55 to less than, for example, Moere^cyclohexanediethanol; greater than 10 to 4 moles % 2,2,4,4-tetramethyl], 3_cyclobutanediol 60 to less than 90 mol% cyclohexanedimethanol; greater than 1 Torr to 35 mol% 2,2,4,4-tetramethyl-l,3-cyclobutanediol and 65 to less than dimethanol" To less than 34 mol% 2,2,4-^ and greater than 66 to 90 mol% cycloheximide dimethanol; greater than 1 〇 to 3 〇 mo 〇 / 〇 2,2,4,4-tetramethyl] , 3_cyclobutanediol and 7〇 to less than 9〇 mol% cyclohexane dimethanol; greater than H) to 25 mol% 2,2,4,4-tetramethylcyclobutanediol and 75 to less than 90 mole % cyclohexane dimethanol; greater than 1 〇 to 2 〇 Ear % 2,2'4,4-tetramethyl-1,3-cyclobutanediol and 8 Å to less than 9 〇 mol % cyclohexane dimethanol, and greater than 10 to 15 mol % 2,2, 4,4_Tetramethylcyclobutanediol and 85 to less than 90 mol% cyclohexanedimethanol. In other aspects of the invention, the diol component for use in the polyester useful in the present invention includes, but is not limited to, at least one of the following ranges: 丨丨 to 99 mol % 2,2,4,4·tetramethyl ], % cyclobutanediol and hydrazine to 89 mole % cyclohexane dimethanol; 11 to 95 mole % 2,2,4,4-tetramethylguanidinium diol and 5 to 89 mole % ring Benzene di-alcohol; 11 is mol% 2,2,4,4-tetramethyl-1,3·cyclobutanol and 10 to 89 mol% cyclohexane dimethanol; Us85 mol% 2, 2,4, cardiotetramethyl-1,3-cyclobutanediol and ^ to (10) mol ❶ cyclohexane dimethanol: "to moir / 〇 2, 2 '4, 4-tetramethyl], 3_cyclobutanediol with 2〇 to 89mol% cyclohexanol methanol '11 to 75mol% 2,2,4,4·tetramethyl-1,3-cyclobutanediol and 119732.doc • 214- 200804457 25 to 89 mole % cyclohexane dimethanol; u7 〇 mol % Μ〆〆 · tetramethyl-1,3-cyclobutanediol and 3 〇 to 89 mol % cyclohexane dimethanol; Go to "Mor. /〇2,2,4,4-Tetramethylcyclobutanediol with 35 to 89 mol% cyclohexane dimethanol; 11 to 60 mol% 2,2,4,4_tetramethyl·1> 3_cyclobutanediol and repentant 89 mol% cyclohexane dimethanol; ^55 mol% 2,2,4,4_tetramethyl n-cyclobutanediol and 45 to 89 mol% cyclohexane Methanol; 丨丨 to "mol% 2'2'4'4 · tetramethyl + 3 · cyclobutanediol and 5 〇 to 89 mol % cyclohexane dimethanol; 11 to less than 50 mol % 2, 2,4,4-Tetramethyl_u_cyclobutanediol with greater than 50 to 89 mol% cyclohexane dimethanol; "to ^ mol% 2,2,4,4_tetramethyl-1, 3-cyclobutanediol with 55 to 89 moles of cyclohexanedimethanol; hydrazine to Limoor% 2,2,4,4-tetramethyl-U-cyclobutanediol with 6 to 89 moles Ears are hexanes diethanol, 11 to 35 mole % 2,2,4,4-tetramethyl-i,3-cyclobutanediol and 65 to 89 moles. /. Cyclohexanol dimethanol; u to 3 〇 mol% 2,2,4,4_tetramethyl.πcyclobutanediol and 70 to 89 mol% cyclohexanedimethanol; Π to 24 mol% 2 , 2'4,4-tetramethyl], 3_cyclobutanediol and 76 to 89 mol% cyclohexanedimethanol; and 11 to 25 mol% 2,2,4,4_tetradecyl" , 3_cyclobutanediol and even 89 moles of cyclohexane dimethanol. In other aspects of the invention, the diol components useful in the polyesters of the present invention include, but are not limited to, at least one of the following combinations: 12 to 99 mole % 2,2,4,4-tetramethyl 4, 3•cyclobutanediol with 1 to 88 mol% cyclohexanedimethanol; 12 to 95 mol% 2,2,4, cardiotetramethyl-1,3·cyclobutanediol and 5 to 88 mol % cyclohexane dimethanol; 12 to 9 moles % 2,2,4,4_tetramethyl <, 3-cyclobutanediol with 10 to 88 mol% cyclohexane di-fol; 12 to 85 mol% 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 15 Up to 88 mol % cyclohexane dimethanol; η to 119732. Doc -215- 200804457 80 mole % 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 2〇 to 88mol% cyclohexanedimethanol; 12 to 75mol% 2 2,4,4-tetramethylcyclobutanediol with 25 to 88 mol% cyclohexanedimethanol; 12 to 7 mol% 2,2,4,4_tetramethyl-1,3 - cyclobutanediol with 30 to 88 moles of cyclohexanedimethanol; 12 to "mol% 2,2,4,4-tetramethyl-1,3-cyclobutanediol with 35 to 88 moles 〇/〇cyclohexanedimethanol; 12 to 60 mol% 2,2,4,4-tetramethyl-l53-cyclobutanediol and 4 to 88 mol% cyclohexanedimethanol; 12 to 55 Molar% 2,2,4,4_tetramethyl], 3-cyclobutanol and 45 to 88 mol% cyclohexane dimethanol; to 5 〇mol/〇2,2,4,4- Tetramethylcyclobutanediol with 5〇 to 88mol% cyclohexanedimethanol; 12 to less than 50mol% 2,2,4,4-tetramethyl-l53_cyclobutanediol with greater than 50 to 88 mole % cyclohexane dimethanol; 12 to 45 mole % 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 55 to 88 mole % cyclohexanedimethanol; Up to 4 〇 mol% 2,2,4,4-tetramethyl-oxime, 3·cyclobutanediol and 6〇 to 88 mol% cyclohexanedimethanol, 12 to 35 mol% 2,2, 4,4- Methyl-; i, 3-cyclobutanediol with 65 to 88 moles of cyclohexanedimethanol; 12 to 3 moles of oxime / oxime 2,2,4,4·tetramethyl], % cycline Glycol with 70 to 88 mol% cyclohexanedimethanol; 12 to 24 mol% 2,2,4,4-tetramethyltris-cyclobutanediol and 76 to 88 mol% cyclohexane Methanol, and 12 to 25 mole % 2,2,4,4_tetramethyl_ι, 3_cyclobutanediol and even 88 mole % cyclohexane dimethanol. In other aspects of the invention, available The diol component for the polyester of the present invention includes, but is not limited to, at least one of the following ranges: 13 to 99 mol % 2,2,4,4-tetramethyl-yi-cyclobutanediol and α87 mol % Cyclohexane dimethanol '13 to 95 mol% 2,2,4,4-tetramethyl '3-cyclobutanediol and 5 to 87 mol% cyclohexane dimethanol; 13 to 9 G mol% 2 , 2, 4, 4_ tetramethyl #环丁119732. Doc-216 - 200804457 diol with 10 to 87 mol% cyclohexanedimethanol; 13 to 85 mol% 2,2,4,4_tetramethyl-1,3-cyclobutanediol with 15 to 87 Mo Ear % cyclohexane dimethanol; η to 8 〇 mol % 2,2,4,4-tetramethyl diol and other (tetra) mol % cyclohexanol hexanol; 13 to 75 moles 02, 2, 4,4-Tetramethyl-U-cyclobutanediol with 25 to 87 mol% cyclohexanedimethanol; 13 to 7 mol% Ha tetramethyl-1,3-cyclobutanediol and 3 〇 To 87 mol% cyclohexane dimethanol; To "mol% 2,2,4,4-tetramethyl-1,3.cyclobutanediol and 35 to 87 mol% cyclohexanol dimethanol; U to 60 mol% 2,2,4, 4_tetramethyl. Π-cyclobutanediol and deducted to 87 mol% cyclohexanthene dimethanol, · 13 to 55 m. /. 2,2,4,4·tetramethyl]3_cyclobutanediol with 45 to 87 mol% cyclohexanedimethanol, · U to 50 mol% 2'2,4,4·tetramethyl+3 · Cyclobutanediol and 5 〇 to 87 mol% of cyclohexanol dimethanol; to less than 50 mol% 2,2,4,4. Tetramethyl], 3_cyclobutanediol with more than 50 to 87 moles of cyclohexane dimethanol; 13 to 45 moles. Μ, #四基基-l,3_cyclobutanediol and 55 to 87 mol% of cycloheximide dimethanol; to demon. /: 2,2,4,4-tetramethylcyclobutanediol and 6〇 to 87mol% cyclohexanedimethanol'·13 to 35mol% 2,2,4,4_tetramethyl· Cyclobutanediol with "to 8. 7 mol% cyclohexane dimethanol; 13 to 3 G mol% 2,2,4,4·tetramethyl-1,3-cyclobutanediol and 70 to 87 mol% cyclohexanedimethanol; i3 Up to 24 mol% 2:2:4,4-tetramethyl#cyclobutanediol with ~ to 87 mol% cyclohexane dimethanol, and 13 to 25 mol% 2,2,4,4_four Methyl], 3_cyclobutanediol and even 87 mole% cyclohexanedimethanol. In other aspects of the invention, there is provided a polyester for use in the present invention. Ingredients, including but not limited to at least one of the following ranges: "to Mox% 2,2,4,4·tetramethyl], 3_cyclobutanediol and hydrazine to % mol% cyclohexane 119732. Doc -217- 200804457 Alcohol. ; he 95% of the 2,2,4,4 tetramethyl·u. Cyclobutanediol with 5 to (tetra) hexaned dimethanol; 14 to 90 mol% 2,2,4,4-tetramethyl]3 cyclobutanediol with rasaki ear cyclohexanol; 14 to 85 Mo Ear % Μ, # tetramethyl 1,3-cyclobutanediol with 15 to 86 mol% cyclohexane dimethanol; 14 to 80 mol% 2,2,4,4·tetramethyl. The n-ring diol is added to % mol% cyclohexane-methanol, 14 to 75 mol% 2,2,4,4-tetramethyl-cyclobutanediol and 25 to 86 m. Benzene-methanol; 14 to 7 〇 Mo Er 0 / 〇 2, 2, 4 4 - tetramethyl: u-cyclobutanediol with 30 to 86 mol% cyclohexane dimethanol; 14 to "mole .:. '2,4,4·tetramethyl], 3_cyclobutanediol and "to % mol% cycloheximidine, 14 to 6 mol% 2,2,4,4·tetramethyl -1,3-cyclobutanediol is 4 〇 to _ ear% cycloheximide dimethanol; 14 to 55 mol% 2,2, M_tetramethyl^% diacetyl and 45 to 86 mol% ring Dimethyl hexane; W5 〇mol%, tetramethyl hydrazine, 3-% butanediol and 50 to 86 moles / 0 cyclohexane dimethanol; 14 to less than 5 〇 mole % 2, 2, M -Tetramethyl], 3_cyclobutanediol disk is greater than 50 to 86 mol% ring? 焓-田 γ ... ^ hexane-methanol, · 14 to 45 mol% 2, 2, 4, 4_ four Metaruthal-1'3-cyclobutanediol with 55 to 86 mol% cycloheximide dimethanol·μ to yammo% 2,2,4,4·tetramethyl_1,3_cyclobutane Alcohol with 60 to 86 mol% cyclohexanol 2 ^ ears 14 to 35 mol% 2,2,4,4·tetramethyl-indole-cyclobutanediol and 65 to = ear. 14 to 3. Molar%2,2,4,4_called ^7〇 to 86mol%% hexanes dimethanol'·14 to 24mol% ^,, tetramethyl-1,3·cyclobutene Glycol and % to 86 mol% cyclohexanol dimethanol; and 14 to 25 mol% 2,2 > (d) hexane dimethanol. Ί 1,3, butanediol 75 to the other aspects of the present invention, can be used for the present invention use polyester diols of 119,732. Doc-218- 200804457 Ingredients, including but not limited to at least one of the following ranges: 15 to 99 mole % 2,2,4,4-tetramethyl-u-cyclobutanediol and u85 mole % cyclohexane A leaven, 15 to 95 mol% 2,2,4,4-tetramethyl-oxime, 3·cyclobutanediol and 5 to 85 mol% cyclohexanol; 15 to 9 mol% 2,2,4,4_tetramethyl. a cyclobutanediol with 10 to 85 mol% cyclohexane dimethanol; 15 to 85 mol%; 2,4\_tetradecyl-1,3-cyclobutanediol with 15 to 85 mol% Cyclohexanedimethanol; 15 to 8 moles % 2,2,4,4·tetramethyl+3-cyclobutanediol and 2〇 to 肊mol % cyclohexanedimethanol; 15 to 75 moles Ear % 2,2,4,4-tetramethylcyclobutanediol tray 25 to 85 mol % cyclohexane dimethanol; 15 to 7 mole % 2,2,4,4_tetramethyl-1 , 3-cyclobutanediol with 3〇 to 85mol% cyclohexanedimethanol; 15 to μmol% 2,2,4,4-tetramethylcyclobutanediol and even “methanol - two 85 mol % cyclohexane dimethanol; 15 to 55 mol% 2,2,4,4·tetramethyl-n cyclobutanediol and 45 to 85 mol% cyclohexane dimethanol; 15 to 5〇mol% 2,2,4,4-tetramethylthenecyclobutanediol and 5〇 to 85mol% cyclohexanedimethanol; 15 to less than 50mol% 2,2,4,4 _ tetramethyl ^ 3 · cyclobutanediol with more than 50 to 85 moles of cyclohexane dimethanol; 15 to 45 mole % Μ, #, heart tetramethyl-1,3-cyclobutanediol and 55 To 85 mol % cyclohexane dimethanol '· ^ to demon mole % 2,2,4,4-tetramethyl. u. Cyclohexane with 6〇 to 85mol% cyclohexanthimethanol; 15 to 35mol% 2,2,4,4_tetramethylguanidine·cyclobutanediol and ^ to ^mol% Methanol; 15 to 2% 2,2,4,4-tetramethylcyclobutanediol and 70 to 85 mol% cyclohexanedimethanol; ^ to molimo% 2 2 2'4,4 -tetramethyl-μ-cyclobutanediol and even "mole% cyclohexane dimethanol" and 15 to 24 mol% 2,2,4,4-tetramethyl],3·cyclobutanediol Even 119732. Doc -219- 200804457 85 moles of cyclohexane dimethanol. In other aspects of the invention, the diol component for use in the polyester useful in the present invention includes, but is not limited to, at least one of the following ranges: 2 to 99 mole % 2,2,4,4-tetramethyl] , 3-cyclobutanediol with 1 to 8 moles of mol% cyclohexanedimethanol, 20 to 95 moles of 2,2,4,4-tetraf-1,3-cyclobutanediol and 5 to 8 〇 mol % cyclohexane dimethanol; 20 to 9 〇 mol % 2,2,4,4-tetramethyl-U-cyclobutanol with 10 to 80 mol. /. Cyclohexane dimethanol, · 2 〇 to 85 mol % 2,2,4,4_ tetramethyl-1,3-cyclobutanediol and 15 to 8 〇 mol % cyclohexane dimethanol; Molar 4 2,2,4,4-tetramethyl-i,3-cyclobutanediol with 2 〇 to 8 〇 Mo Er 0 / ❶ hexane hexane dimethanol; 20 to 75 mol % 2, 2, 4, heart four? Jishan% cyclobutanediol with 25 to 8 moles of mol% cyclohexanedimethanol; 20 to 70 moles/〇2,2,4,4-tetramethyl-1,3_cyclobutanediol and 3 〇 to 8 〇 mol % cyclohexane dimethanol; 汕 to "mol / 〇 2,2,4,4-tetramethyl-1,3_cyclobutanediol and 35 to 8 〇 Mo earrings hexane two Methanol; 20 to 60 mol% 2,2,4,4_tetraf-based, 3-cyclobutanediol and deducted to 8 〇mol % cyclohexane dimethanol; 2G to 55 mol% 2,2, 4,4_tetramethyl succinimide with 45 to 8 〇 mol % cyclohexane dimethanol; 2 〇 to 5 〇 mol % 2'2,4,4-tetramethylcyclobutanediol and 5 〇 to 8 〇 〇乂 〇乂 cyclohexane dimethanol, 20 to less than 5 〇 mol% 2,2,4,4_tetramethyl-hydrazine, 3_cyclobutanediol and greater than 5 〇 to 8 〇 Mo Deafness/ring ring hexane dimethanol; 20 to 45 mol% 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 55 to 8 mol% cyclohexane decyl alcohol 2〇到扣莫耳2'2'4,心四曱基",3_cyclobutanediol with 60 to 80 moles of cyclohexane dimethanol' 20 to 35 moles/〇2,2, 4,4_tetramethyl-μ•cyclobutanediol with “to mol%% cyclohexane dimethanol; 2〇 to 3G mol% 2,2,4,4_tetradecyl-10- Cyclobutanediol with 70 to 80 mol% cyclohexanedimethanol·, and 20 to 25 mol% 119732. Doc 200804457 2,2,4,4-Tetramethyl_U_cyclobutanediol and 75 to μ^di yol. In other aspects of the invention, diol injections useful for the purposes of the present invention include, but are not limited to, at least one combination of the following ranges: 25 to (eight) moles. . 2'2,4,4 tetramethyldecenecyclobutanediol with a"mol% cyclohexanedimethanol, 25 to 95 mol% 2,2,4, tetramethylcyclobutanediol巧乃莫耳./. Cyclohexane dimethanol; 25 to 9G mol% 2,2, μ_tetramethyl^cyclobutanediol and 1〇 to 75 mol% cyclohexane dimethanol; 25 to 85 Molar% 2:2,4,4-tetraf-butyl butylene glycol and 15 to 75 mol% cyclohexanedimethanol, 25 to 80 mol% 2,2,4, tetramethyltetramine", ^ Cyclobutanediol with 2〇 to Namol% cyclohexane dimethanol; 25 to 75 mol% 2,2,4,4•tetramethyl], 3 cyclobutanediol and 25 to 75 mol% ring Digested dimethanol; 25 to 7 () mol% 2. 2. 4. 4-tetramethylcyclobutanediol with 3〇 to 75mol% cyclohexanedimethanol; 25 to 65mol% 2,2,4,4-tetramethyl-1,3-cyclobutanediol 35 to 75 mol% cycloheximide dimethanol; 25 to 60 mol% 2,2,4,4_tetramethyl·D cyclobutanediol and 40 to 75 mol% cyclohexanedimethanol; Moer ^ 2. 2. 4. 4-tetramethyl-1,3_cyclobutanediol with 45 to 75 mol% cyclohexanedimethanol; 25 to 50 mol% 2,2,4,4-tetramethyl·1,3-ring Butanediol with 5〇 to 75 mol% cyclohexanedimethanol; 25 to less than 5〇 mol% 2,2,4,4·tetramethyl '3·cyclobutanediol with more than 5〇 to 75 Ear % cyclohexane dimethanol; 25 to 45 mol % 2,2,4,4-tetramethyl-indole, 3-cyclobutanediol and 55 to 75 mol % cyclohexane dimethanol; 25 to 40 Molar% 2,2,4,4_tetramethylcyclobutanediol with 60 to 75 mol% cyclohexanedimethanol; 25 to 35 mol% 2,2,4,4_tetramethyl-1 , 3-cyclobutanediol with 65 to 75 mol% cyclohexanedimethanol; and even (10) 119,732. Doc -221 - 200804457 Alcohol with 70 to 75 mol% cyclohexane Molar% 2,2,4,4_tetramethyl-1,3-cyclobutane dimethyl if. In other aspects of the invention, there are provided diols useful in the polymerization of the present invention. Ingredients 'including but not limited to at least _ combinations of the following ranges: 3G to 99 moles '2,4,4 eg methyl_1> 3_cyclobutanediol and u mole% cyclohexanol, 3〇 Up to 95 mol% 2,2,4,4·tetramethyl·1,3·cyclobutanediol and 5 to 70 mol% cyclohexane dimethanol; 3〇 to 9〇 mol% 2,2, 4,4-Tetramethyl·^-cyclobutanediol with 1G to 7G mol% cyclohexane dimethanol; 30 to 85 mol% 2,2,4,4_tetramethyl-1,3-cyclobutane Glycol with 15 to 7 moles of mol% cyclohexanol; % to 8 mole % 2,2,4,4·tetramethyl·Μ·cyclobutanediol and 20 to 7 mole % ring One methanol, 30 to 75 mol% 2,2,4,4_tetramethyl·^3•cyclobutanediol and 25 to 70 mol% cyclohexane dimethanol; 3〇 to 7〇莫耳% 2,w·tetramethyl-1,3-cyclohexanediol and 30 to 7 moles of mol% cyclohexanthimethanol; 3〇 to (4) ear/〇2,2,4,4-tetramethyl{ 3·cyclobutanediol and 35 to 7 moles of mol% cyclohexane dimethanol; 30 to 60 mol% 2,2,4,4 tetramethyl^·cyclobutanediol and 1 mol% ring Dioxane dimethanol; 3G to 55 mol% 2,2,4,4·tetramethyl-H cyclobutanediol and 45 to 7 mol% cyclohexane dimethanol % to % mol% 2 2 2'4'4-tetraf-a-cyclobutanediol and 5 to 7 moles of mol% cyclohexane dimethanol '30 to less than 50 mol% 2,2, 4,4•tetramethyl. Μ·cyclobutanediol with more than 5 〇 to 7 〇 〇 〇 〇 哀 哀 己 己 ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; 心 心 心 心 心 心 心 心 心 心 心 心 心〇 mol % cyclohexane dimethanol; % to 4 〇 mo ❶ /. 2,2,4,4-tetraf-based _!, 3_cyclobutanediol and 6〇 to 7〇 mol% cyclohexanedimethanol; 30 to 35 mol% 2,2,4,4_four Methylcyclobutanediol and hydrazine to 70 mole % cyclohexane dimethanol. 119732. Doc 222-200804457 In other aspects of the invention, diol components useful in (4) of the invention include, but are not limited to, at least one of the following ranges: 35 to 99 moles 2'2'4'4 izg methyl Butylene glycol and work to 65 moles. Cyclohexanedimethyl alcohol, · 35 to 95 mol % 2, 2, 4, tetramethyl. U-cyclobutanediol and ear % cyclohexane dimethanol; 35 to 90 mol% 2,2,4,4-tetramethyl-πcyclobutan-drunk and 10 to 65 mol% cyclohexane dimethanol 35 to 85 mol% 2,2,4, tetramethyl-1,3-cyclobutanediol and 15 to 65 mol% cyclohexane dimethanol; μ to 80 mol/. 2,2,4,4_tetramethyl {3. Ring dibutyl with 2 () to 65 m. Anthracycline-methanol, 35 to 75 mol% 2,2,4,4-tetramethyl-i,3-cyclobutanediol and 25 to 65 mol% cyclohexane dimethanol, ·35 to 7 () Moer % m heart tetramethyl-1,3-nuclear butanediol with 3 〇 to 65 mol% cyclohexane dimethanol; Μ to 6 mol, '4'4 tetramethyl-1,3 _cyclobutanediol with 35 to 65 mol% cyclohexanedimethanol; 35 to 60 mol% 2,2,4,4-tetramethyl], 3_cyclobutanediol and avoiding 65 mol% ring Dimethyl alcohol; 35 to 55 mol% 2,2,4,4_tetramethyl# cyclobutanediol and 45 to 65 mol% cyclohexane dimethanol; 35 to 5 mol% 2,2 , 4,4-tetramethyl m-butyl butanediol with 5 〇 to 65 mol% of cyclohexanol dimethanol '35 to less than 5 〇 mol% 2,2,4, tetramethylguanidine·cyclobutane Alcohol with greater than 50 to 65 mol% cyclohexane dimethanol; 35 to 45 mol% m heart tetramethyl-1,3-cyclobutanediol and 55 to 65 mol% cyclohexane dimethanol, · ” To Moss % 2,2,4,4-tetramethyl-i,3_cyclobutanediol and 6 to 65 mol% cyclohexane^methanol. In other aspects of the invention, for use in the present invention The diol component of the polyester of the invention includes, but is not limited to, at least one of the following ranges · 4〇1 bonded to 1〇〇 mole / square 2,2,4,4-tetramethyl-_ Shu, Hong cyclobutanediol and is 59 9 mole% cyclohexyl 119,732. Doc 200804457 Alkane dimethanol '· 40 to 99 mol % to 60 mol % cyclohexene ^, methyl deca 3_% butanediol and 1 bucket 0 hexane hexanol; 40 to 95 mol % 2, 2,4,4•Tetramethyl-1,3_cyclobutanediol with 5 to 6 〇mol % ring hexanol · 4 〇 to mol % 2,2,4,4·tetramethyl ], 3_cyclobutanediol with 1〇 to 6〇, methanol, · 40 to 85 mol% 2,2,44_tetradecane-5,,-wr丞-1,3_nuclear butanediol盥15 To 6 〇 Mo Er. /. Cyclohexanol; 4〇 to 8〇mol% 2,2,4,4_tetradecyl·! 3·cyclobutanediol and 2〇 to 60mol% cyclohexane dimethanol; 40 to 75 mol%, ''tetramethyl-1'3-% butanediol with 25 to 6 mol% cyclohexane dimethanol; 4 〇 to 7 〇 mol% 2,2,4,4-巧Base-1,3-cyclobutanediol with 30 to 60 moles of cyclohexane dimethanol; 40 to 65 moles. /^ from tetramethylcyclobutanediol with 35 to 60 mol% cyclohexanedimethanol; 4〇 to 6〇 mol% 2:2,4,4-tetramethylthenecyclobutanediol (10) to 6 〇 mol % cyclohexane dimethanol, 40 to 55 mol % 2,2,4,4_tetramethyl_1> 3_cyclobutanediol and similar mol% cyclohexane dimethanol 4〇 to less than 5〇 mol% 2,2,4,4_tetramethyl-1,3-cyclobutanediol with more than 5〇 to 6〇 mol% cyclohexanedimethanol·4〇 to 50 Molar% 2,2,4,4-tetramethyl. Hey. Cyclobutanediol with 5〇 to 6〇 mol% cyclohexane dimethanol, and 40 to 45 mol% 2,2,4,4-tetramethylbutanediol and 55 to 60 mol% cyclohexene Alkanediethanol. In other aspects of the invention, diols useful in the polyesters useful in the present invention include, but are not limited to, at least one combination of the following ranges: 45 to 丨〇〇mol/〇2, 2, 4, 4-4 Mercapto-i,3·cyclobutanediol and hydrazine to 55 mol% cyclohexanedimethanol; 45 to 99 mol% 2,2,4,4·tetramethyl], 3_cyclobutanediol U55 mol/〇 ring hexane-methanol, 45 to 95 mol% 2,2,4,4·tetradecyl-1,3-cyclobutanol and 5 to 55 mol% cyclohexanedimethanol; 45 to 9 moles % 119732. Doc -224- 200804457 2^,4,4_tetramethyl. Cyclobutanediol with 1 () to 55 mol% cyclohexan & 4 alcohol; 45 to 85 mol% 2,2,4,4_tetramethyl-u•cyclobutanediol with 15 to ^ Mo Ear % cyclohexanol dimethanol; 45 to 戦 2 % 2,2,4,4 tetramethyl·^-cyclobutanediol and 20 to 55 mol % cyclohexane dimethanol; 2,4,4_tetramethylcyclobutanediol with 25 to 55 mol% cyclohexane dimethanol; 45 to 70 mol% 2,2,4,4_tetrafyl")-cyclobutane Alcohol with 3〇 to 55 mol% cyclohexane dimethanol; 45 to 65 mol% 2,2,4,4_tetramethyl·^•cyclobutanediol and 35 to 55 mol% cyclohexane Methanol; 45 to 6 () Moule.乂 2,2,4,4. Tetramethyl-a cyclobutanediol with 4 to 55 mole % cyclohexanol; greater than 45 to 55 mole % 2,2,4,4-tetramethylguanidine. Cyclobutanediol disk U to less than 55 mol% cyclohexane dimethanol; 45 to 55 mol% Μ, #tetramethyl-1,3-cyclobutanediol and 45 to 55 mol% cyclohexane Methanol; and "to" Mox% 2,2,4,4-tetramethylthenecyclobutanediol with 5 to 6 moles of Mo. Cyclohexane dimethanol. In other aspects of the invention, diol components useful for the purposes of the present invention include, but are not limited to, at least one combination of the following ranges: greater than 5 Å to 99 mM % 2'2, 4, 4 Tetramethyl], 3_cyclobutanediol and uj, 5 〇 mol % cyclohexane dimethanol; greater than 50 to 95 mol % 2,2,4,4_tetramethyl···cyclobutene- Alcohol with 5 to less than 5G mol% cyclohexane dimethanol; greater than % to % mol% 2,2,4,4-tetramethyl-hydrazine, 3·cyclobutanediol and 1〇 to less than 5〇 Ear % cyclohexanedimethanol; greater than 50 to 85 mole % 2,2,4,4-tetramethyl], 3_cyclobutanediol and 15 to less than 5 mole % cyclohexane dimethanol; More than 50 to 80 mol% 2,2,4,4-tetramethyl-1,3_cyclobutanediol and (9) to less than (9) mol% cyclohexane dimethanol; greater than 50 to 75 mol% 2, 2,4,4_tetramethyl^cyclobutanediol: 119732. Doc •225- 200804457 25 to less than 50 mol% cyclohexanedimethanol; greater than 5 〇 to 7 〇 mol % 2,2,4,4·tetramethyl-1,3·cyclobutanediol and 30 to Less than 50 mol% cyclohexanedimethanol, greater than 50 to 65 mol% 2,2,4,4-tetramethyl-l,3-cyclobutanediol and 35 to less than 50 mol% cyclohexane Dimethanol; greater than 5 〇 to 6 〇 mol % 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 4 Å to less than 5 〇 mol % cyclohexane dimethanol. In other aspects of the invention, diol components useful in the polyesters of the present invention include, but are not limited to, at least one combination of the following: greater than 51 to 99 moles per square 2'2,4,4-tetramethyl. _ι, 3_cyclobutanediol with J to less than 49 mol% cyclohexane dimethanol; greater than 51 to 95 mol% 2,2,4,4-tetramethyl •cyclobutanediol and 5 to less than 49 mole % cyclohexane dimethanol; greater than 51 to 9 mole % 2,2,4,4-tetramethyl 13-cyclobutanediol and 1 to less than 49 mole % cyclohexane dimethanol, Greater than 51 to 85 moles per oxime 2,2,4,4-tetramethyl^,3-cyclobutanediol and 15 to less than 49 mole % cyclohexanedimethanol; greater than 51 to 80 mole % 2 , 2,4,4-tetramethyl], 3-cyclobutanediol and 2 〇 to less than Mo ^ hexane hexane dimethanol; greater than 51 to 75 mol % 2,2,4,4-tetra Base ring butanediol fish 25 to less than 49 mol% cyclohexane dimethanol; greater than 51 to 70 mol%, , methyl i,3·cyclobutanediol and 30 to less than 49 mol% cyclohexane Dimethanol, greater than 51 to 65 mol% 2,2,4,4-tetramethyl-1,3-cyclobutanediol fish 35 to less than 49 mol% cyclohexane dimethanol; and greater than Η·mole % ^2 4,4-tetramethyl], 3-cyclobutanediol and less than 49 mole% to 4G cyclohexyl dimethanol burn. In other aspects of the invention, the diol components useful in the polyesters of the present invention include, but are not limited to, at least one of the following ranges: 55 to 99 moles 119,732. Doc •226· 200804457 % 2,2,4,4-tetramethyl], 3_cyclobutanediol with 仏mol % cyclohexane dimethanol; 55 to 95 mol % 2, 2, 4, heart ^基基义义cyclobutanediol with 5 to 45 mol% cyclohexanedimethanol; 55 to 90 mol% 2,2,4,4-tetramethyl], 3_cyclobutanol and 10 to 45 mole % cyclohexane dimethanol; 55 to 85 moles. 〆〇2,2,4,4_tetramethyl·1,3·cyclobutanediol with 15 to 45 mol 0/〇 cyclohexane dimethanol, or even 80 mol/❶2,2,4,4- Tetramethyl-ι,3-cyclobutanediol with 2〇 to 45mol% cyclohexanedimethanol, ·55 to 75mol% 2,2,4,4_tetramethylyi 3_cyclobutane Alcohol with 25 to 45 moles / oxime ring diethanol; 55 to 7 〇 Mo 〇 / 〇 2, 2, 4, heart tetramethyl-1,3-cyclobutanediol and 3 〇 to 45 Mo Ear % cyclohexane dimethanol;" to "mol% 2,2,4,4_tetramethyl-oxime, % cyclobutanediol and 35 to 45 mol% cyclohexanedimethanol; and 55 to 60 Molar % 2,2,4,4-tetramethyl d,% cyclobutanediol and 4 to 45 mole % cyclohexane dimethanol. In other aspects of the invention, the diol component for use in the polyester useful in the present invention includes, but is not limited to, at least one of the following ranges: 6 to 99 mole % 2,2,4,4-tetramethyl- 13-cyclobutanediol with 1 to 4 moles of mol% cyclohexanedimethanol, 60 to 95 mole % 2,2,4,4-tetramethyl-1,3_cyclobutanediol and 5 to 4 〇 mol % cyclohexane dimethanol; 60 to 9 〇 mol % 2,2,4,4-tetramethyl·cyclobutanediol and 10 to 40 mol % cyclohexane dimethanol; 6 〇 to 85 mol% tetramethyl-1,3-cyclobutanediol with 15 to 4 mol% cyclohexane dimethanol; to 80 mol/〇2,2,4,4-tetramethyl-l , 3-cyclobutanediol with 2 to 40 moles /. Cyclohexane dimethanol; 60 to 75 mol% 2,2,4,4-tetramethyl·cyclobutanediol and 25 to 40 moles per hydrazine cyclohexane dimethanol; and 60 to 70 moles % 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 3 Torr to 4 Torr Mo/0 cyclohexanedimethanol. In other aspects of the invention, there is provided a diol for use in the polyester of the invention 119732. Doc •227- 200804457 Ingredients, including but not limited to at least one of the following ranges: 65 to 99 mole % 2,2,4,4_tetramethyl {3-cyclobutanediol and ^^ mol% cyclohexane Dimethanol, 65 to 95 mol% 2,2,4,4-tetramethyldecacyclobutanediol and 5 to 35 mol% cyclohexane dimethanol; 65 to 9 mol% 2,2, 4,4•tetramethylcyclobutanediol with 10 to 35 mol% cyclohexanedimethanol; 65 to 85 mol% 2,2j,4_tetramethyl-1,3_cyclobutanediol and 15 to 35 mole 0/〇 cyclohexane dimethanol, 65 to 80 mol% 2,2,4,4_tetramethyl-1,3_cyclobutanediol and 2 () to 35 mol% cyclohexane Dimethanol; 65 to 75 mol% 2,2,M_tetramethyl], 3_cyclobutanediol and 25 to 35 mol% cyclohexane dimethanol; and 65 to 7 () mol% 2, 2,4,4-tetramethyl-1,3-cyclobutanediol and 3 to 35 mole % cyclohexanedimethanol. In other aspects of the invention, the diol component for use in the polyester useful in the present invention includes, but is not limited to, at least one of the following combinations: 7 to 99 moles of 2,2,4,4-tetramethylcyclobutane Glycol with 1 to 3 mol% cyclohexane dimethyl hydrazide, 70 to 95 mol% 2,2,4,4_tetramethyl-丨'3•cyclobutanediol and 5 to 3 〇 mo Ear % cyclohexane dimethanol; 7 〇 to 9 〇 mol % 2,2,4,4_tetradecyl·cyclo-cyclohexane and 10 to 30 mol% cyclohexanedimethanol; 7〇 to 85 Molar% 2,2,4,4_tetradecyl-1,3-cyclobutanediol with 15 to 3 Torr. /〇cyclohexanedimethanol; 7〇 to 80mol% 2,2,4,4-tetramethyl-1,3_cyclobutanediol and 2〇 to 3〇 mol% cyclohexane methanol, 70 Up to 75 mol% 2,2,4,4-tetramethyl·ι,3·cyclobutanediol and 25 to 30 mol% cyclohexane dimethanol. In other aspects of the invention, the diol component for use in the polyester useful in the present invention includes, but is not limited to, at least one combination of the following: 75 to 99 moles per gram of 2,4,4,4·tetramethyl. -1,3·cyclobutanediol with 1 to 25 mol% cyclohexanedimethanol '75 to 95 mol% 2,2,4,4·tetramethyl-indole, 3·cyclobutanediol and 5 To 25 Mo 119732. Doc 200804457 Ear % cyclohexanol methanol; 75 to 90 mole % 2,2,4,4_tetramethyl. Μ-cyclobutane-enrichment 10 to 25 mol% cyclohexanedimethanol; and 75 to mol% 2/, 4,4-tetramethyl-1,3·cyclobutanediol and b to 25 mol %cyclohexyl dimethanol. In other aspects of the invention, the diol component for use in (4) of the invention includes, but is not limited to, at least one of the following ranges: 8 〇 to Μ mol % 2, 2, 4 , 4-tetramethyl {3. Cyclobutanediol with J to 2 〇mol % cyclohexane dimethanol; 嶋95 mol% 2,2,4,4·(tetra)yl·ucyclobutanediol and $ to ear% hexanone Alcohol; 80 to 9 moles % 2,2,4,4_tetramethyl. Μ-cyclobutanediol and 10 to 20 mol% of cyclohexanedimethanol. In other aspects of the present invention, the diol components useful in the present invention include, but are not limited to, at least one combination of the following ranges: 37 to 8 mole % 2,2'4,4-tetra Base-a cyclobutanediol with 2 to 63 moles of cyclohexane dimethanol; 40 to less than 45 mole % 2,2,4,4·tetramethyl. Π-cyclobutanediol with more than 55 to 60 mol% of cyclohexane-sintered dimethanol; large secret to "mole% Μ, #tetramethyl-1,3-d-butylene glycol and 45 to less than 55 mol% ring Hexane dimethanol; and 46 to 55 mol% 2,2,4,4-tetramethyl-u-cyclobutanediol and 45 to 54 mol% cyclohexane dimethanol; and 46 to 65 mol% 2,2,4,4·tetramethyl·D-cyclobutanediol and 35 to 54 mol% cyclohexanedimethanol. In other aspects of the invention, a diol for use in the polyester of the invention Ingredients, including but not limited to at least one of the following ranges: 〇〇1 to ^mol% 2'2'4'4_tetramethyl-:^-cyclohexane and 85 to 99% molybdenum Burning methanol; Η to less than 15 mol% 2,2,4,4 tetramethyl], 3·cyclobutanediol and greater than 85 to 99. 99 mol% cycloheximide dimethanol; 〇〇m mol% 119732. Doc -229· 200804457 2,2,4,4-Tetramethylshanhongcyclobutanediol and "extra molar % cyclohexane dimethanol, 0. 01 to 13 mol% 2,2'4,4-tetramethyl-1,3-cyclobutanediol and 87 to 99. "Mole% cyclohexane burnt methanol; 〇. 〇1 to 12 mol% 2,2,4,4·tetramethylbutanediol and 88 to 99 99 mol% cyclohexanedimethanol; to 11 mol% 2,2,4,4·4 Base W·cyclobutanediol and 89 to 99·99 mol% cyclohexane dimethanol; 〇1 to 1〇% 2,2,4,4_tetramethyl. Μ·cyclobutanediol and 90 to 99. 99 mole % cyclohexane dimethanol; 〇〇 1 to less than 1 〇 mol. 2,2,4,4·tetramethyl-1,3-cyclobutanediol with greater than 90 to 99. 99 mol% cycloheximide dimethanol; G. G1 to 9 mole % 2,2,4,4_tetramethyl-10-3 cyclobutanediol disk to the outside of the team%% W-cyclohexyl dimethanol; 〇〇1 to 8 moles 2,2, 4,4_tetramethyl-1,3·cyclobutanediol and 92 to 99. 99 mole % cyclohexane dimethanol, 0. 01 to 7 mol % 2,2,4,4_tetramethyl-cyclobutanediol and ^ to 99. "Mole% Cyclohexamethylene Diethanol'· 〇. 〇1 to 5 mol% 2,2,4,4·tetramethylcyclobutanediol and 95 to 99·99 mol 0/〇 cyclohexane dimethanol; 〇 (seven) to less than 5 mol. /. 2,2,4,4_tetramethyl. Taking cyclobutanediol and more than 95 to 99 99% of cycloheximide dimethanol; 01 to 4. 5 mol% 2,2,4,4 tetramethyl^ 〇cyclobutanediol with 95 5 to 99 99 mol 0/〇 cyclohexane dimethanol; ear j 2,2,4,4·tetramethyl -1,3-cyclobutanediol with 96 to 99. 99 mol % cyclohexanyl dimethanol; 〇 · (Η to 3 · 5 mol % 2, 2, 4, 4 - tetramethyl), 3 - cyclobutanediol: 96. 5 to 99·99 mol% cyclohexane dimethanol; 0. 01 to 3 mole % 2,2,4 4_ tetramethyl-1,3_cyclobutanediol and 97 to 99 99 mole % cyclohexane dimethanol.  _ to mol% 2'2'4,4-tetramethyl #cyclobutanediol and 97. 5 to =99_% Cycloheximide dimethanol ’· ^(1) Moer % Tetracarbacyclobutane diol and 98 to 99. 99 mole % cyclohexane dimethanol, ❶ ^ to 119732. Doc -230- 200804457 1·5 moles / 〇 2,2,4,4-tetramethyl _153_cyclobutanediol and 98. 5 to 9999 moles % ring-burned dimethanol; OWM mole % 2, 2, 4, heart four? Base], cyclobutanol and 99 to 99. 99 mole % cyclohexane dimethanol; and 〇〇 1 to 〇. 5 mol% 2,2,4,4-tetramethyl-1,3·cyclobutanediol and 99. 5 to 99. 99 mole % cyclohexane dimethanol. In other aspects of the invention, the molar percentage of 2,2,4, cardiac tetramethyl'-cyclobutanediol is present in GG1 to less than 5 mol%, and the molar percentage of the diol component is equal to 100 mo The ear % is the reference, and wherein the presence of CHDM is optional, and the diol component for the polyester useful in the present invention includes, but is not limited to, at least the following range combination ·· 0 01 to less than 5 mol % 2,2 , 4,4_ tetramethyl-1,3-butanediol residue, 〇〇1 to more than 95% by mole of ethylene glycol residue and 0 to 99. 98 mole % cyclohexane dimethanol; 〇〇1 to less than 5 mol% 2,2,4,4-tetramethyl-i,3_cyclobutanediol residue, 〇〇1 to greater than 99.98 Molar % ethylene glycol residue and 0. 01 to 99. 97 mole % cyclohexane dimethanol; 〇〇1 to less than 5 mol% 2,2,4,4-tetramethyl], 3_cyclobutanediol residue, 〇〇1 to more than 90 mol% Ethylene glycol residue and 5 to 99.98 mole % cyclohexane dimethanol · to less than 5 mole % 2,2,4,4-tetramethylcyclobutanediol residue, 〇〇1 to greater than 85 Mole % ethylene glycol residue and 1 〇 to 99 98 mol% cyclohexane dimethanol; 0. 01 to less than 5 mol% 2,2,4,4_tetramethyl-hydrazinol cyclobutanediol residue, 0. 01 to more than 80 mol% ethylene glycol residue and 15 to 9998 mol% cyclohexane didecyl alcohol; 〇1 to less than 5 mol% 2,2,4,4_tetramethylcyclobutanol residue, 0. 01 to more than 75 mol% ethylene glycol residue and 2 to 99.98 mole hexane dimethanol; O. Oi to less than 5 mol% 2,2,4,4_tetramethyl-1,3-cyclobutanediol residue, 〇·〇1 to more than 7〇 mol% ethylene glycol residue and 119732. Doc -231 - 200804457 25 to 99·98 mol% cycloheximide dimethanol; 0 () 1 to more than 65 mol % ethylene glycol residue and 30 to 99. 98 mole % cyclohexane dimethanol; 〇〇1 to less than 5 = ear % 2,2,4,4-tetramethyl·ι,3-cyclobutanediol residue, 〇〇1 to greater than 6〇 Ear % ethylene glycol residue and 35 to 99.98 mol % cyclohexane dimethanol; 〇〇 1 to less than 5 mol % 2,2,4,4-tetramethyl-l53_cyclobutanediol residue Base, 〇〇1 to more than 55 mol% ethylene glycol residue and 4〇 to 99 98 mol% cyclohexane dimethanol; 〇1 to less than 5 mol% 2,2,4,4-tetramethyl {3. Cyclobutanediol residue, 0. 01 to greater than 50 mole % ethylene glycol residues and 45 to 99 98 moles. Cyclohexane dimethanol; 0. 01 to less than 5 mol% 2,2,4,4>_tetramethylbutanediol residue, 0. 01 to more than 45 m. /. Ethylene glycol residue and 5〇 to 99 98 mol% % hexane dimethanol; 0·01 to less than 5 mol 0/〇2,2,4,4_tetramethylthenecyclobutanediol residue 〇·01 to more than 4 〇mol % ethylene glycol residues and 55 to 99. 98 mole % cyclohexane dimethanol; 0. 01 to less than 5 mole % 2,2,4,4_tetramethyl-1,3-butanediol residue, 〇〇1 to more than 35 moles % ethylene glycol residue and 60 to 99. 98 mol% cyclohexane dimethanol; 〇 〇1 to less than 5 mol% 2,2,4,^ tetramethyl-1,3·cyclobutanediol residue, 0. 01 to more than 30 mol% of ethylene glycol residues and 65 to 99. 98 mol% cyclohexane dimethanol; 〇〇1 to less than 5 mol/❶2,2,4,4-tetramethyl β1,3_cyclobutanediol residue, 〇〇1 to greater than. Mole% ethylene glycol residue and 70 to 99.98 mol% cyclohexanedimethanol; 〇〇1 to less than 5 mol% 2,2,4,4-tetradecyl-indole·cyclobutanediol Residue, 〇〇1 to greater than 2 〇mol % ethylene glycol residues and 75 to 99. 98 mol% cyclohexane didecyl alcohol; 0. 01 to less than 5 mol% 2,2,4,4-tetramethyl-hydrazine, 3·cyclobutanediol residue, 〇·〇ΐ to more than 15 mol% ethylene glycol residue and 8〇 to 99 98 Moer. Cyclohexane-methanol, 0. 01 to less than 5 moles / 〇 2,2,4,4_tetramethylcyclobutanediol 119732. Doc •232· 200804457 Residue, 0. 01 to greater than 10 mol% ethylene glycol residue and 85 to 99 98 mol% cyclohexane dimethanol; 01 to less than 5 mol% 2,2,4, heart tetramethylyihong ring Ding Yi drunk residue, 0. 01 to more than 5 mole % ethylene glycol residue and 9 to 99 98 mole % hexane dimethanol; 01 to less than 5 mol% 2,2,4,4·tetramethyl-1,3-cyclobutanediol residue and hydrazine. 〇1 to more than 5 mol% ethylene glycol residues and up to 99. 98 mole % cyclohexane dimethanol. In other aspects of the invention, the molar percentage of 2,2,4,4-tetramethyl-, 3-cyclobutanediol is present in 〇〇1 to 5 mol%, with the diol component of the molar The percentage is equal to 100% by mole based on the reference, and wherein the presence of CHDM is necessary 'for the purposes of the present invention: alcohol components, including but not limited to at least the following range combinations · 0·01 to 5 Ear % 2,2,4,4-tetramethyl-1,3_% butanediol residue, 89 to greater than 94. 99 moles. / 〇 ethylene glycol residue and 5 to 1 〇 mol % cyclohexane dimethanol; 〇 · 〇 1 to 5 mol % 2, 2, 4, 4 - tetramethyl 丨 ' butyl diol residue 89 to greater than 94. 99 mole % ethylene glycol residue and 5 to 1 mole % cyclohexane dimethanol; 〇 · 〇 1 to 5 mole % 2,2,4,4-tetradecyl 1'3-% butyl Alcohol residue, 84 to greater than 89.99 mol% ethylene glycol residue and 1 to 15 mol% cyclohexanedimethanol; 〇·〇1 to 5 mol% 2,2,4,4-tetra Methyl/, 3_% butanediol residue, 79 to 84. 99 mole % ethylene glycol residue and 15 to 20 moles / hexane hexane dimethanol; 〇〇 1 to 5 moles / 〇 2, 2, 4, 4 · tetramethyl hydrazine, 3-% butyl Glycol residue, 74 to 79. 99 mole % ethylene glycol residue and 20 to 2 5 ♦ a jsi 〇 / tetra _, hexane dimethanol; 0. 01 to 5 mol% 2,2,4,4·tetramethyl-1,3-cyclobutane — π Λ 4 a known residue, 69 to 74·99 mol. / 〇 ethylene glycol residue and 25 to 30 Moco (y, 0 hexane didecyl alcohol; 0. 01 to 5 mol% 2,2,4,4-tetramethyl"" 3 - cyclobutyl - # a known residue, 64 to 69. 99 mole % ethylene glycol residue and 30 to 119732. Doc •233 200804457 5 Moer/〇 ring hexanes dimethanol; 0. 01 to 5 mol% 2,2,4,4-tetradecyl base ring τ -age# # -% residue, 59 to 04. 99 mol % glycol residue with 35 to 4 〇 mol % loop ρ 衣 衣 一 一 methanol; 0·01 to 5 mol % 2,2,4,4-tetramethyl-1,3 - Ring Ding - Age Cold # ^ I know the residue, 54 to 59. 99 mole % ethylene glycol residue and 40 to 5 mole % hexanol dimethanol; 〇 · 〇 1 to 5 mole % 2,2,4,4-tetramethylbutanediol residue, 49 to 54. 99 mole % ethylene glycol residue and 45 to 50 moles of 0 / 〇 are burned dimethanol; 〇〇 1 to 5 moles 0 / 〇 2, 2, 4, 4_ four soil / - 衣丁二Alcohol residue, 44 to 49. 99 mole % ethylene glycol residue and 50 to 55 moles / 〇 are burned dimethanol; 〇〇 1 to 5 mol 0 / 〇 2, 2, 4, 4 4 tetradecyl / '3β% Alcohol residue, 39 to 44. 99 mol% ethylene glycol residue and 55 to 0 mol/〇% hexanol; 〇〇1 to 5 mol% 2,2,4, lintetramethylbutanediol residue, 34 to 39. 99 mole % ethylene glycol residue and 60 to 65 moles / oxime cyclohexane dimethanol; 〇 〇 1 to 5 moles. /〇 2,2,4,4-tetramethyl/, 3β% butanediol residue, 29 to 34. 99 mol % ethylene glycol residue and 65 to 70 mol % cyclohexane dimethanol; 〇〇ι to $ mol % 2, 2, 4, 4 4 tetradecyl butyl diol residue, 24 to 29. 99 mol% ethylene glycol residue and 70 to 75 mol% cyclohexane dimethanol; 0 01 to 5 mol% 2,2,4,4·tetradecyl/, Hong% butanediol residue, 19 to 24. 99 mole % ethylene glycol residue and 75 to 80 mole % cyclohexane dimethanol; 0. 01 to 5 mole % 2,2,4,4_tetramethylbutanediol residue, ^ to ^ (eight) molar % ethylene glycol residue and (10) to 85 mole % cyclohexanedimethanol; 〇1 to 5 molar 0/〇2,2,4,4 tetramethylbutanediol residue, 9 to 14 99 mole % ethylene glycol residue and 85 to 9 mole % cyclohexane dimethanol ; 〇〇 1 to 5 moles. /〇 2,2,4,4_tetramethyl hydrazine, 3-^ butane diol residue, 4 to 9. 99 mol% ethylene glycol residue and 9〇 to 95 H9732. Doc •234- 200804457 Moule% hexamethylene dimethanol; and 〇·Μ5 mol% 2,2,4,4-tetramethyl-U-cyclobutanediol residue, 95 to 99 99 mol % B The diol residue and hydrazine to 5 moles. / 〇 ring hexanes dimethanol. In any particular embodiment, wherein the molar percentage of 2,2,4,4•tetramethyl-hydrazine, 3_cyclobutanediol is present in the range of 001 to 5 mol%, the molar percentage of the diol component is equal to 100% Mo is the basis, and wherein the presence of CHDM is essential. The poly diol component that can be used in the present invention may also be present. 〇1 is at least 5 m. /. Specific examples of TMCD, and corresponding reduction reactions in cyclohexanedimethanol and/or B:ol residues are pre-(4) within the scope of the present invention. The alcohol component may also contain the following 2,2,4,4-tetramethyl], 3_cyclobutanediol residues I& 0. 01 to W Moll%; 0. 01 to 9. 5莫耳% 〇 0^9 Moer%,· 〇. 〇1 to 8. 5 mole%; 〇. 〇1 to 8 mol%; 〇〇m Moer 〇·〇1 to 5. 5 mole%; 0. 01 to 5 mol%; 〇 〇1 at least 5 mol%; 〇 · 〇 1 to 4 · 5 mol %; 0. 01 to 4 堇 mutual ^ / · λ λ t 7- ^ main 4 molar / 〇, 0·01 to 3. 5 mol%; 0·01 to 3 mol%; 0. 01 to 25 straight and. / · π η 1 7* ^ ύ 彳 彳, 0·01 to 2·〇莫耳%; 0. 01 to 2. 5 莫%%; 0. 01 to 2 莫%% ηηιπ 1 wide points 兵 / / 〇, 〇 · 01 to ^ Mo Er. /. ,· 0. 01 to 1·〇莫耳% ; and 0. 01 to 0. 5 moles %. In some embodiments, the remainder of the octopus component may contain, but is not limited to, any amount of cyclohexane dimethyl hydrazine / 3⁄4 ethyl alcohol, as long as the total amount of diol components is equal to 100% can be. In addition to the diols set forth above, r J is used in the polyester of the polyester composition of the present invention, and can be prepared from 1,3-propanediol, 4-1,4-buty-gamma β-A, 4-butanol, and mixtures thereof. . Meaning 119732. Doc-235 - 200804457 It is intended that the compositions of the invention, prepared from propylene glycol, M-butanediol, and mixtures thereof, may have at least one of the ranges described herein, at least one of the inherent viscosity ranges described herein, And/or at least one of the diol or diacid ranges described herein. In addition or in the alternative, the propylene glycol W, 4_T diol and mixtures thereof may also be prepared from nucleus hexanedimethanol in at least one of the following amounts: 〇1 to 99 moles. m to 90% by mole; H8〇Moole%; 〇 l7〇 Mo M of the molar %; 0. 1 to 50 mol%; n4 mol%; 〇1 to 35 mol%; 〇1 to 30 mol. 1 to 25 moles 0. 1 to 20 moles. /0; n15 mole %; mole %; 1 to 99 mole %; i to 90 mole % ear % ear % ear % ear % ear %; 1 to 8 moles 1 to 70 mole % 1 to 6 〇 Mo Er. /. U50 Mo 1 to 40 mol %; 丨屈莫耳%; 丨钱莫耳%·丨 to 25 莫1 to 20 mol%; u15 mol%; ljLi() mol%; (1) Mo 5 to 8 〇莫耳%; 5 to 7G Mo. /. 5 to 60 mol%; 5 to 5 mol 5 to 4 mol%; 5 to 35 mol%; 5 to 30 mol%; 5 to 25 mol 5 to 20 mol%; and 5 to 15 Moer%; 5 to 1 〇 Mo Er 1〇 to " Mo Er. /°; 10 to 90 mol%; to 80 mol 10 to 70 mol%.  Momo%%, (4) Moer%; 1〇 to the ear%; 1() to 25 mol%; 1() to 2() mol%; 1〇 to 15 mol%; 2G to "Moer%;2仏95mol%; running ear%.  2〇 to 7〇% by mole; 20 to 60% by mole; 20 to 50% by mole; 2〇 to 4〇莫/. 20 to 35 moles. /. 20 to 30 moles. /. ; and 2〇 to 25mol%. With respect to a specific embodiment of the present invention, the polyacetic acid which can be used in the present invention, when in 60/4 Torr (heavy/heavy 1) vinegar/tetrachloroethane, is at a concentration of υ gram of 119,732. Under doc -236- 200804457, at least one of the following intrinsic viscosities can be displayed when measured at 25 °C: 〇·1〇 to 1. 2 com / g, 0. 10 to 1_1 com / g; 〇 · ι〇 to 1 com / g; 0. 10 to less than 1 com / g; 0. 10 to 0. 98 com / g; 〇 · ΐ〇 to 0. 95 communes / gram; 0. 10 to 0. 90 com / g; 〇 · 1 〇 to 〇 · 85 com / g; 〇. 1〇 to 0. 80 communes / gram; 0. 10 to 0. 75 com / g; 〇 · ΐ〇 to less than 〇 · 75 com / g; 0. 10 to 0. 72 com / g; 0. 10 to 0. 70 communes / gram; 〇. 1〇 to less than 〇·7〇 公合/克; 0. 10 to 〇·68 com/g; 0. 10 to less than 〇·68 com/g; 0. 10 to 0. 65 com / g; 0. 10 to 0. 6 communes / gram; 0. 10 to 0. 55 mm / g; 0. 10 to 0. 5 com / g; 0. 10 to 0. 4 communes / gram; 〇. 1〇 to 0. 35 com / g; 0. 20 to 1. 2 com / g; 0 · 20 to 1. 1 com / g; 0. 20 to 1 com / g; 0. 20 to less than 1 com / g; 0 · 20 to 0. 98 communes / gram; 0. 20 to 〇·95 communes/gram; 0·20 to 0. 90 com / g; 0 · 20 to 0. 85 com / g; 0. 20 to 0_80 com / g; 0. 20 to 0. 75 com / g; 0. 20 to less than 0. 75 com / g; 0. 20 to 0. 72 com / g; 0_20 to 0. 70 com / g; 0. 20 to less than 0. 70 com / g; 0. 20 to 0. 68 com / g; 0. 20 to less than 0. 68 com / g; 0. 20 to 0. 65 com / g; 0. 20 to 0. 6 communes / gram; 0. 20 to 〇·55 mm/g; 0. 20 to 0. 5 com / g; 0. 20 to 0. 4 communes / gram; 0. 20 to 0. 35 communes / gram; 0. 35 to 1. 2 com / g; 0. 35 to 1. 1 com / g; 0. 35 to 1 com / g; 0. 35 to less than 1 com / g; 0. 35 to 0. 98 communes / gram; 0. 35 to 0. 95 com / g; 0. 35 to 0. 90 com / g; 〇 · 35 to 0 · 85 com / g; 0. 35 to 0. 80 com / g; 〇 · 35 to 0. 75 com / g; 〇 · 35 to less than 0. 75 com / g; 0. 35 to 0. 72 com / g; 0. 35 to 0. 70 com / g; 0. 35 to less than 0. 70 com / g; 〇 · 35 to 0. 68 com / g; 0. 35 to less than 0·68 com/g; 0. 35 to 0. 65 com / g; 0. 40 to 1. 2 communes / 119732. Doc -237- 200804457 gram; 0.40 to 1.1 mil/g; 〇40 to 1 com/g; 〇·4〇 to less than 1 com/g; 40 to 0. 98 communes / gram; 0. 40 to 0. 95 com / g; 0. 40 to 〇·90 com/g; 〇·4〇 to 0. 85 communes / gram; 0. 40 to 0. 80 com / g; 〇 · 40 to 0. 75 com / g; 0. 40 to less than 0. 75 com / g; 0. 40 to 0. 72 com / g; 0. 40 to 0. 70 com / g; 0 · 40 to less than 〇 · 70 com / g; 〇 · 40 to 〇 · 68 com / g; 40 to less than 0. 68 com / g; 0 · 40 to 0. 65 com / g; greater than 0. 42 to I · 2 com / g; greater than 〇 · 4; 2 to 1. 1 com / g; greater than 0. 42 to 1 com / g; greater than 0. 42 to less than 1 com / g; greater than 0. 42 to 0. 98 com / g; greater than 0. 42 to 0. 95 com / g; greater than 0. 42 to 0. 90 com / g; greater than 0. 42 to 0.85 mm/g; greater than 0. 42 to 0. 80 com / g; greater than 0. 42 to 0. 75 com / g; greater than 0. 42 to less than 0. 75 com / g '· is greater than 0. 42 to 0. 72 com / g; greater than 〇 · 42 to 0. 70 com / g; greater than 0. 42 to less than 0. 70 com / g; greater than 〇 · 42 to 0. 68 com / g; greater than 〇 · 42 to less than 〇 · 68 com / g; and greater than 0. 42 to 0. 65 metrics / gram. With respect to specific embodiments of the invention, the polyester useful in the present invention, at 60/40 (w/w) phenol/tetra-ethane, at a concentration of 25 g/5 〇ml at 25 °C At the time of the next measurement, at least one of the following intrinsic viscosities may be displayed: 45 to 1. 2 com / g; 0. 45 to 1. 1 com / g; 〇 · 45 to 1 com / g; 〇 · 45 to 〇 · 98 com / g; 0. 45 to 0. 95 com / g; 0. 45 to 0. 90 com / g; 〇 · 45 to 0. 85 communes / gram; 0. 45 to 0. 80 com / g; 0. 45 to 0. 75 com / g; 0. 45 to less than 0. 75 com / g; 〇 · 45 to 0. 72 com / g; 〇 _45 to 0. 70 com / g; 〇 · 45 to less than 〇 · 7 〇 public / gram; 0. 45 to 0. 68 com / g; 0. 45 to less than 0. 68 communes / gram; 〇 · 45 to 0. 65 com / g; 〇 · 50 to 1. 2 com / g; 〇 · 5 〇 to 1. 1 com / g; 〇 5 〇 to 1 com / g; 119,732. Doc -238 - 200804457 0. 50 to less than 1 com/g; 0.50 to 〇·98 com/g; 0. 50 to 0. 95 communes / gram; 0. 50 to 0. 90 communes / gram; 0. 50 to 0. 85 communes / gram; 0. 50 to 0. 80 communes / gram; 0. 50 to 0. 75 com / g; 0. 50 to less than 〇_75 com/g; 〇·50 to 0. 72 com / g; 0_50 to 〇 · 70 com / g; 〇. 5〇 to less than 〇. 7〇 公合/克; 0·50 to 0. 68 com / g; 〇 · 50 to less than 〇 · 68 com / g; 〇 · 50 to 0 · 65 com / g; 0. 55 to 1. 2 com / g; 0. 55 to 1. 1 com / g; 0. 55 to 1 com / g; 0. 55 to less than 1 com / g; 〇 · 55 to 0. 98 in total / gram; 0 · 55 to 0. 95 com / g; 0 · 55 to 0. 90 communes / gram; 0. 55 to 0. 85 communes / gram; 0. 55 to 0. 80 com / g; 0. 55 to 0. 75 com / g; 0. 55 to less than 0. 75 com / g; 0. 55 to 0. 72 com / g; 0. 55 to 0. 70 com / g; 0. 55 to less than 0. 70 com / g; 0. 55 to 0. 68 com / g; 0. 55 to less than 0. 68 com / g; 0. 55 to 0. 65 com / g; 0. 58 to 1. 2 com / g; 0. 58 to 1.1 com / g; 0. 58 to 1 com / g; 0. 58 to less than 1 com / g; 0. 58 to 0. 98 communes / gram; 0. 58 to 0. 95 com / g; 0. 58 to 〇·90 com/g; 0. 58 to 0. 85 communes / gram; 0. 58 to 0. 80 com / g; 0. 58 to 0. 75 com / g; 0. 58 to less than 0. 75 com / g; 0 · 58 to 0 · 72 com / g; 0. 58 to 0. 70 com / g; 0. 58 to less than 0. 70 com / g; 0. 58 to 0. 68 com / g; 0. 58 to less than 0. 68 com / g; 0. 58 to 0. 65 communes / gram; 0. 60 to 1. 2 com / g; 0. 60 to 1. 1 com / g; 0. 60 to 1 com / g; 0. 60 to less than 1 com / g; 0. 60 to 0. 98 communes / gram; 0. 60 to 0. 95 com / g; 0. 60 to 0. 90 communes / gram; 0. 60 to 0. 85 com / g; 0. 60 to 0. 80 com / g; 0. 60 to 〇·75 com / g; 0. 60 to less than 〇·75 com/g; 〇·60 to 0. 72 com / g; 0. 60 to 0. 70 com / g; 〇 · 60 to less than 0. 70 com / g; 0. 60 to 0. 68 com / g; 0. 60 to less than 〇·68 public 119,732. Doc -239- 200804457 合/g;0. 60 to 0. 65 com / g; 0. 65 to 1. 2 com / g; 〇 · 65 to 1. 1 com / g; 〇 · 65 to 1 com / g; 〇 · 65 to less than 1 com / g; 〇 · 65 to 0. 98 communes / gram; 0. 65 to 0. 95 com / g; 〇 · 65 to 0. 90 com / g; 0·65 to 0. 85 communes / gram; 0. 65 to 0. 80 com / g; 〇 · 65 to 0. 75 com / g; 0. 65 to less than 〇·75 com/g; 〇·65 to 0. 72 com / g; 〇 · 65 to 0. 70 com / g; 〇 · 65 to less than 0. 70 com / g; 〇 · 68 to 1. 2 communes / gram; 0. 68 to 1. 1 com / g; 〇 · 68 to 1 com / gram; 〇 68 to less than ^ 々 / gram; 0. 68 to 0. 98 com / g; 〇 · 68 to 〇 · 95 com / g; 〇 68 to 0. 90 communes / gram; 0. 68 to 0. 85 communes / gram; 〇. 68 to 〇8〇公合/克; 0. 68 to 0. 75 com / g; 〇 · 68 to less than 〇 · 75 com / g; 〇 68 to 〇 72 com / g; greater than 0. 76 com / g to 1 > 2 com / g; greater than 〇 % com / g to 1. 1 com / g; greater than 0. 76 com / gram to i com com / gram; greater than 〇 76 com / gram to less than 1 com / gram; greater than 0 · 76 com / gram to 〇 98 com / gram; greater than 〇 · 76 com /克至ο·%公合/克; greater than 〇% commensal / gram to 〇 9 〇 com com / gram; greater than 0. 80 com / g to 丨 · 2 com / g; greater than 〇 8 〇 com / g to 1. 1 com / g; greater than 0. 80 com / g to 丨 合 / gram; greater than 〇 8 〇 com / gram to less than 1 com / g; greater than 〇 · 8 〇 com / gram to 12 com / gram, · greater than 0. 80 com / g to 0. 98 com / g '· is greater than 〇 8 〇 com / g to 〇 95 com / g; greater than 0. 80 com / g to 〇 · 9 〇 com / g. It is intended that the compositions of the present invention may have at least one of the intrinsic viscosity ranges described herein, and at least one of the ranges of monomers described herein, and the mouthpieces, unless otherwise stated. It is also intended that the compositions useful in the present invention may have at least one of the ranges described herein and at least one monomer range with respect to the compositions described herein, unless 119,732. Doc -240- 200804457 is also mentioned. It is also contemplated that compositions useful in the present invention can have at least one intrinsic viscosity range as described herein, at least one Tg range described herein, and at least one monomer range with respect to the compositions described herein. Unless otherwise stated. In one embodiment, terephthalic acid can be used as a starting material. In another embodiment, the terephthalic acid dimethylate is used as the starting material. In yet another embodiment, a mixture of terephthalic acid and dimethyl p-benzoate can be used as a starting material and/or as an intermediate. In certain embodiments, a terephthalic acid residue or an ester thereof, such as dimethyl terephthalate, or a mixture of terephthalic acid residues and esters thereof, can be formed to form a polyester useful in the present invention. One or all of the dicarboxylic acid components. In some embodiments, the terephthalic acid residue can be formed to form part or all of the dicarboxylic acid component of the inventive polyester. In certain embodiments, higher levels of terephthalic acid can be used to make higher impact strength polyesters. For the purposes of this disclosure, the term: "p-dioic acid" and, dimethyl terephthalate" can be used interchangeably herein. In one embodiment, dimethyl terephthalate is used to make a portion or all of the dicarboxylic acid component useful in the polyesters of the present invention. For the purposes of this disclosure, the terms 'terephthalic acid' and 'dimethyl terephthalate" may be used interchangeably herein. In all embodiments, 7 to 1 mole. 0/〇; or 80 to 100 mol%; or 9〇 to 1〇〇% by mole; or 99 to 1〇〇mol/〇' or 100%% terephthalic acid and/or Dimethyl terephthalate and/or mixtures thereof can be used. Doc -241 · 200804457 In addition to terephthalic acid, the dicarboxylic acid component which can be used in the polyester of the present invention may be contained up to still 30 mol%, up to 2 mol%, up to 1 mol%, to 5 Mole%, or up to Mole % of one or more aromatic diterpenoids for modification. Yet another specific embodiment is an aromatic dicarboxylic acid: a class of 〇mol% modified. Thus, the term "if present" is intended to cover the amount of one or more modified aromatic dicarboxylic acids, which may encompass any such endpoint value, including, for example, zero. 01 to 30% by mole, 〇 〇1 to 2 〇% by mole, 〇 〇1 to 1〇 莫%, 〇. 〇 1 to 5 moles. /. And (4) to 】%. In one embodiment, the modified aromatic ditoxanic acid useful in the present invention includes, but is not limited to, those having up to 20 carbon atoms' and which may be linear, para-oriented or symmetric for use in the present invention. Examples of modified aromatic ditoponic acids include, but are not limited to, isophthalic acid, 4,4, _biphenyl dicarboxylic acid, m_, H Μ, 2,7-fanic acid, and trans _4 , 4, _ diphenylethylene dibenzoic acid, and its vinegar. In the specific embodiment, the aromatic dicarboxylic acid for reforming is isophthalic acid. The carboxylic acid component which can be used in the polyester of the present invention can be further modified to a high molar percentage, such as up to 5 mole % or up to 1 mole % of one or more aliphatic dicarboxylic acids having 2 to 16 carbon atoms, such as a ring. Hexanedicarboxylic acid, malonic acid, vitreous acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid and decamuedioic acid dicarboxylic acid. Some embodiments may also include 〇〇1 or ι〇. 1 or 1 〇 mol%, ^ι〇mol%, 5 to 1 〇 mol% - or a plurality of modified aliphatic dicarboxylic acids. Yet another specific embodiment contains 0 mole % modified sputum & _, known as a dicarboxylic acid. The total amount of dicarboxylic acid

耳％為議莫耳％。於-具體實施例中，己：酸及/或戊I 酸係提供於本發明之改質wn酸類成份中。 119732.doc »242- 200804457 本發明之改質用脂族二羧酸類可包含二氫節二羧酸類， 例如，二氫節-1，3-二羧酸類及/或苯基二氫節二羧酸 類。於一具體實施例中，該二羧酸可被選自至少一種 1，2,3-三甲基_3_苯基二氫茚_4，，5•二羧酸及三甲基巧_ 羧基-3-(4-羧基苯基）二氫茚二羧酸。根據本發明之目的， 任何$载於美國第2006/0004151A1號專利申請案（發明名 稱·含有二氫茚分子團之共聚物及其摻合物；申請權人為 通用電氣公司）中之二氫節二羧酸類可作為落於本發明範 圍中之至少一種改質用脂族二羧酸使用。美國第 2006/00041 51A1號專利申請案全文中關於二氳茚二羧酸類 之記載係併入本文中作為參考。 可使用對苯二甲酸之酯類及其他改質用二羧酸類或其相 應酯類及/或鹽類，以代替二羧酸類。二羧酸酯類之適當 實例包括但不限於二甲基、二乙基、二丙基、二異丙基、 一丁基及二苯基酯類。於一項具體實施例中，酯類係選自 下列之至少一種··甲基、乙基、丙基、異丙基及苯基酯 類。 關於所欲之聚酯，順式/反式2,2,4,4•四甲基_丨，3_環丁二 醇之莫耳比可自純順式、純反式及順式/反式混合物之間 改變。於某些具體實施例中，順式及/或反式2,2,4,4_四甲 基_1，3-裱丁二醇之莫耳百分比係大於5〇莫耳％之順式及小 於50莫耳％之反式；或大於55莫耳％之順式及小於45莫耳 /〇之反式，或30至70莫耳％之順式及7〇至3〇莫耳％之反 式，或40至60莫耳％之順式及6〇至4〇莫耳％之反式；或％ 119732.doc -243 - 200804457 至70莫耳％之反式及5〇至3〇莫耳％之順式；或5〇至川莫耳 %之順式及50至30莫耳％之反式；或6〇至7〇莫耳％之順式 及30至40莫耳％之反式；或大於7()莫耳％之順式及小於^ 莫耳％之反式；其中順式及反式⑽+四甲基-^環丁二 醇之莫耳百分比總和係等於1〇〇莫耳％。於額外之一具體 實施例+ ’順式/反式2,2,4,4-四f基]，3_環丁二醇之莫耳 比可在50/50至0/100之範圍内改變，例如，介於侧至 20/80之間。 環己烷二甲醇可為順式、反式或彼等之混合物，例如， 具有60: 40至40: 60之順式/反式比’或7〇:川至別：7〇 之順式/反式比。力另一具體實施例中，反式環己烧二甲 醇可以60至80莫耳％之量存在且順式環己烧二甲醇可以2〇 至40莫耳％之量存在 其中順式環己烷二甲醇及反式環己 烷二甲醇之總百分比係等於1〇〇莫耳％。於一特定具體實 施例中’反式環己燒二甲醇可以6G莫耳％之量存在且順式 環己烷二甲醇可以40莫耳％之量存在。於特定具體實施例 中，反式環己烷二甲醇可以70莫耳％之量存在且順式環己 烷二甲醇可以30莫耳％之量存在。環己烷二甲醇之任何 1，4-異構物或其混合物可存在於本發明 可用於本發明之聚酯 之二醇成份中。於一具體實施例中 包含1，4-環己烧二甲醇。於一具體實施例中，可用於本發 明之聚酯包含1，4·環己烷二甲醇及匕％環己烷二甲醇。順 式/反式1，4-環己烷二甲醇之莫耳比可在5〇/5〇至〇/ι〇〇之範 圍内改變，例如，介於40/60至20/80之間。 119732.doc •244- 200804457 立：-具體實施例中，可用於本發明之聚酯組合物之聚酯 部份之二醇成份，可含有98莫耳％或較少之一或多種改質 用二醇類，其不為2,2,4,4_四甲基{3-環丁二醇或環己烧 一甲％ ,於一項具體實施例中，可用於本發明之聚酯組合 物之聚酯部份之二醇成份可含有5〇至98莫耳％一或多種改 質用二醇類，其不為2,2,4,4_四甲基_丨，3_環丁二醇或環己 烷二甲醇，·於一項具體實施例中，可用於本發明之聚_組 合物之聚酯部份之二醇成份可含有25莫耳％或更少之一或 夕種改質用二醇類，其不為2,2,4,4_四甲基'^環丁二醇 或％己烷二甲醇；於一項具體實施例中，可用於本發明之 聚酯組合物之聚酯部份之二醇成份可含有2〇莫耳％或更少 之一或多種改質用二醇類，其不為2,2,4，心四甲基U，3-環 丁一醇或環己烷二甲醇；於一項具體實施例中，可用於本 發明之聚酯組合物之聚酯部份之二醇成份可含有15莫耳％ 或更；一或多種改質用二醇類。於一項具體實施例中，可 用於本發明之聚酯組合物之聚酯部份之二醇成份可含有1 〇 莫耳％或更少一或多種改質用二醇類。於一項具體實施例 中，可用於本發明之聚酯組合物之聚酯部份之二醇成份可 含有5莫耳％或更少一或多種改質用二醇類。於一項具體 實施例中，可用於本發明之聚酯組合物之聚酯部份之二醇 成份可含有3莫耳％或更少一或多種改質用二醇類。於一 項具體實施例中，可用於本發明之聚酯組合物之聚酯部份 之二醇成份可含有〇莫耳％或更少一或多種改質用二醇 類。某些具體實施例，亦可含有〇 〇1至98莫耳％，譬如〇 119732.doc -245 - 200804457 至98莫耳％’ 1至98莫耳％，5謂莫耳％，或1()至98莫耳％ 之一或多種改質用二醇類。 醇係被排除作為改質用二醇。 可用於本發明聚酯之改質用二醇類係指2,2,4,4_四甲 基_1’3-壌丁二醇與環己烷二甲醇以外之二醇類，且可含有 2至16個碳原子。適當改質用二醇類之實例包括但不限於 乙二醇殘基、^•丙二醇、丨，3_丙二醇、新戊二醇、I〆· 丁 二醇、1，5-戊二醇、以·己二醇、對_二甲苯二醇、聚四甲 基一醇及其混合物。於一項具體實施例中，改質用二醇為 乙二醇。於另一項具體實施例中，改質用二醇類包括但不 限於至 種丨，3-丙二醇與ι，4-丁二醇。於另一項具體實 施例中，乙二醇殘基係被排除作為改質用二醇。於另一項 體只施例中，1，3_丙二醇與丨，^丁二醇係被排除作為改 質用二醇類。於另一項具體實施例中，2,2_二甲基 '夂丙 可用於本發明聚酯組合物之聚酯及/或聚碳酸酯，可佔〇 至10莫耳百分比，例如0 01至5莫耳百分比、〇…至}莫耳 百分比、0.05至5莫耳百分比、0.05至1莫耳百分比或〇」至 〇·7莫耳百分比，以無論是二醇或二酸殘基之總莫耳百分 比為基準；個別地，分枝單體（於本文中亦稱為分枝劑）之 一或多個殘基，具有3個或更多個羧基取代基、羥基取代 基或其組合。在某些具體實施例中，分枝單體或分枝劑可 在聚酯之聚合反應之前及/或期間及/或之後添加。可用於 本發明之聚醋，因此可為線性或分枝狀。聚碳酸酯亦可為 線性或分枝狀。在某些具體實施例中，分枝單體或分枝劑 119732.doc 246- 200804457 在二！酸酿之聚合反應之前及/或期間及/或之後添加。 :早體之實例包括但不限於多官能性酸類或多官能性 醇類：、譬如苯三甲酸、偏苯三軒、邮苯四甲酸二 -、，甲基丙烷、甘油、異戊四醇、檸檬酸、酒石酸、 3·經戍二酸等。於—項具體實施例中，分枝單體殘基可包 3 〇·1至0.7莫耳百分比之一或多種殘基，選自下列之至少 :種：偏苯三肝、苯四甲酸二酐、甘油、花楸 ::。氺己烷三醇、異戊四醇、三羥甲基乙烷及/或對稱 苯:甲^ °可將分枝單體添加至聚δ旨反應混合物中，或與 呈辰縮物形式之聚酯摻合，如在美國專利案號5,654,347與 5,696，176巾所述者’其關於分枝單體之揭示内容係併於本 文供參考。 本發明之聚S旨可包含至少—種鏈延長劑。合適之鍵延長 匕括但不限於，多官能性（例如，但不限於，雙官能 性)異氰酸酯、多官能性環氧化物，例如，環氧化酚醛清 漆及苯氧基树g曰。在某些具體實施例中，鏈延長劑可在聚 合反應製程尾段或在聚合反應製程之後添加。假使在聚合 反應製程之後添加，鏈延長劑可於轉化製程期間，例如射 出模製或擠壓，藉由化合或添加之方式併入。鏈延長劑之 使用量隨所使用之特定單體組合物及所欲之物裡性質而改 變，但一般而言係約〇」至約1〇重量％，例如約〇」至約5重 量％，以聚酯總重量為基準。 可用於本發明聚酯之玻璃轉移溫度（Tg)係使用得自 Thermal Analyst儀器之 TA DSC 2920,在 2(rc/分鐘之掃描 119732.doc -247- 200804457 速率下測定。 曰！：在17rc下藉由某些可用於本發明聚酿顯示之長結 :乍用+衣期（例如大於5分鐘），故其能夠製造物件，包 =不㈣射出模製物件、射出吹製物件、射出延伸吹製 _成型薄膜、擠壓成型薄片、擠壓吹製物件及擠 壓延伸吹製物及纖維。係本發料提供之製造物件之一實 例為熱可成型薄片。 本發明之聚醋可為非晶質或半結晶性。於—方面，某些 可用於本發明之聚輯可具有相對較低結晶度。某些可用於 本發明之聚酯可因此具有實質上非晶質形態學，意謂此等 聚酯包含聚合體之實質上不規則區域。 :-項具體實施例中，"非晶質"聚醋可具有結晶化作用 半衰期在170t下大於5分鐘’或在17〇。。下大於1〇分鐘， 或在下大於50分鐘，或在⑽下大於1〇〇分鐘。於 本發明之一項具體實施例中，結晶化作用半衰期可在170 °C下大於moo分鐘。於本發明之另一項具體實施例中， 可用於本發明聚酯之結晶化作用半衰期可在170 t大於 10,000分鐘。聚酯之結晶化作用半衰期，當於本文中使用 時，可使用熟諳此藝者所習知之方法度量。例如，聚酯之 結晶化作用半衰期以’可藉由試樣經由雷射與光檢測器之 光透射，作為時間之函數，在溫度控制加熱夾片臺上度量 而測得。此度量可經由使聚合體曝露至溫度Tmax，然後 使其冷部至所要之溫度而達成。然後，可將試樣藉由加熱 夾片臺保持在所要之溫度下，同時施行透光率度量，作為 119732.doc -248- 200804457 :間之函數。最相’試樣可為視覺上透明，具有高透光 :田$樣、纟°aB時變成*透明。結晶化作用半衰期為透 率在最初透光率與最後透光率間之中途下之時間。 Tmax係被定義為使試樣之結晶性相域（若結晶性相域存在 時）溶解所需要之溫度。可將試樣加熱至Tmax，以在結晶 化作用半衰期度量之前調理試樣。絕對了咖溫度對各= 合物係為不同。例如，可將pcT加熱至大於29〇。〇之某種 溫度，以熔解結晶性相域。 如實例之表1與圖1中所示，對於增加結晶化作用半衰 期，意即關於聚合體達到其最高結晶度一半所需要之時 間，2,2,4,4-四曱基_1，3_環丁二醇係比其他共單體譬如乙 二醇與間苯二甲酸更有效。藉由降低PCT之結晶速率，意 即增加結晶化作用半衰期，以經改質pct為基料之非晶質 物件，可藉此項技藝中已知之方法製造，譬如擠壓、射出 成型等。如表1中所示，此等材料可顯示比其他經改質 PCT共聚酯較高之玻璃轉移溫度與較低之密度。 對本發明之一些具體實施例，此等聚酯可在與加工性能 結合之韌度上顯示改良。例如，稍微地降低可用於本發明 聚酯之固有黏度’會造成更可加工之熔融黏度，同時保持 聚酯之良好物理性質，譬如韌度與耐熱性。 於一項具體實施例中，當在迴轉式溶融體流變計上，於 290°C下，在1弧度/秒下度量時，可用於本發明聚酯之溶 融黏度係低於30,000泊。於一項具體實施例中，當在迴轉 式熔融體流變計上，於290°C下，在1弧度/秒下度量時， 119732.doc -249- 200804457 可用於本發明聚酯之熔融黏度係低於20,〇〇〇泊。 於一項具體實施例中，當在迴轉式熔融體流變計上，於 290°C下，在1弧度/秒下度量時，可用於本發明聚酯之熔 融黏度係低於1 〇,〇〇〇泊。於一項具體實施例中，當在迴轉 式熔融體流變計上，於290°c下，在1弧度/秒下度量時， 可用於本發明聚酯之熔融黏度係低於15,〇〇〇泊。於另一項 具體實施例中，當在迴轉式炼融體流變計上，於290。〇 下，在1狐度/秒下度量時，可用於本發明聚酯之熔融黏度 係低於6,000泊。 於一項具體實施例中，某些可用於本發明之聚酯可為視 覺上透明。"視覺上透明"一詞，在本文中係被定義為當以 目視方式檢查時，可感覺得到之濁度、霧度及/或混沌不 存在。於另一項具體實施例中，當聚酯與聚碳酸酯（包括 但不限於雙齡A聚碳酸酯）摻合時，摻合物可為視覺上透 明。 在本發明之其他具體實施例中，可用於本發明之聚酯可 具有黃色指數（ASTM D-1925)低於50或低於2〇。 於一項具體實施例中，可用於本發明之聚酯及/或本發 明之聚酯組合物，具有或未具有調色劑，可具有顏色值 a及b ，其可使用由Hunter聯合實驗室公司（Rest〇n， Va)所製造之Hunter Lab mtrascan光譜比色計測定。顏色 测疋為在無論是聚酯顆粒或自彼等射出成型或擠壓成型之 板塊或其他用品上度篁數值之平均。其係藉由(國際 照明委員會）之L*a*b*顏色系統（經翻譯）測定，其中L*表示 H9732.doc -250· 200804457 明tc座標，a*表示紅色/綠色座標，及b*表示黃色/藍色座 軚。在某些具體實施例中，可用於本發明聚酯之b*值可 為-10至低於10，而L*值可為50至90。在其他具體實施例 中了用於本發明I®旨之b*值可存在於下列範圍之一 中：_1〇至 9 ’· _1〇至 8 ; _10至 7 ; _1〇至 6 ; _1〇至 5 ;，至 4 ’· -10至3 ; _1〇至2 ; _5至9 ; -5至8卜5至7卜5至6 ; _5至 5 ; -5至4，· _5至3卜5至2 ; 0至9 ; 〇至8 ; 〇至7 ; 〇至6 ; 〇至 5’ 0至 4; 0至 3; 〇至 2; 1至 1〇; n u8; a?; β 6，1至5, 1至4; 1至3;及1至2。在其他具體實施例中， 可用於本發明聚酯之L*值可存在於下列範圍之一中：⑼至 6〇 ; 50 至 70 ; 50 至 80 ; 5〇 至 9〇 ; 6〇至7〇 ; 6〇至8〇 ;的至 90 ; 70至 80 ; 70至 90。 在以對苯二甲酸、乙二醇及丨，4_環己烷二甲醇為基料之 共聚酯中，增加1，4-環己烷二曱醇之含量，可改良韌度， 當藉土 ASTM D256度量時，其可在切口 Iz〇d衝擊強度試驗 中藉由韌脆性轉移溫度測得。經由以1,4-環己烷二甲醇 降低韌脆性轉移溫度之此種韌度改良，咸認係由於m-環 己院二甲醇在共聚醋中之撓性與構形行為而發生。併入 2’2’4’4四甲基+3.環丁二醇至pcT中，咸認係經由降低韌 脆性轉移溫度，而改良韌度，如實例之表2與圖2中所示。 這在2,2,4,4·四甲基-1，3·環丁二醇之剛性下，是令人意外 的。 。於-項具體實施例中，可用於本發明之聚醋展現低於〇 C延!生-至-脆性過渡溫度，基於1〇_密爾切口，於"8·英吋 119732.doc -251 - 200804457 厚棒塊，根據ASTMD256測得。 切口 Izod衝擊強度，如ASTM D256中所描述者，係測量 早刃度之常用方法。本發明可用於本發明之聚酯可具有一或 多個下列性質。於一項具體實施例中，可用於本發明之聚 醋顯示切口 Izod衝擊強度為至少150 j/ni (3呎旁/英对）， 在23°C下，使用10-密爾切口，於3 ·2毫米（1/8-英吋）厚棒塊 中’根據ASTM D256測得；於一項具體實施例中，可用於 本發明之聚酯顯示切口 IZ0(j衝擊強度為至少（4〇〇 j/m) 7 5 叹-碎/英忖，在23 °C下，使用10-密爾切口，於3.2毫米 (1/8-英吋）厚棒塊中，根據aSTm D256測得；於一項具體 實施例中，可用於本發明之聚酯顯示切口 Iz〇d衝擊強度為 至少1000 J/m (18呎-磅/英吋），在231下，使用1〇_密爾切 口’於3_2毫米（1/8-英吋）厚棒塊中，根據astm D256測 得。於一項具體實施例中，可用於本發明之聚酯顯示切口 Izod衝擊強度為至少15〇 J/m (3呎_磅/英吋），在23。〇下， 使用10-密爾切口，於6·4毫米（1/4_英吋）厚棒塊中，根據 ASTM D256測得；於一項具體實施例中，可用於本發明之 聚醋顯示切口 Izod衝擊強度為至少（4〇〇 J/m) 7·5呎-镑/英 吋，在23°c下，使用10-密爾切口，於6.4毫米（1/4-英吋）厚 棒塊中，根據ASTM D256測得；於一項具體實施例中，可 用於本^明之聚酯顯示切口〖如^衝擊強度為至少 (18尺方/奂忖），在23〇c下，使用1〇•密爾切口，於I#毫米 (1/4-英时）厚棒塊中，根據ASTmd256測得。 於另一項具體實施例中，某些可用於本發明之聚酯，當 119732.doc -252- 200804457 在〇°C下度量時，當與在-下度量，使用1〇_密爾切口， 於1/8•英忖厚棒塊中，根據ASTM D256測得之切口 Izod衝 擊強度比較時’可顯示增加切口 1：2〇4衝擊強度為至少3。/〇或 至少5%或至少1〇%或至少15%。此外，當在〇。(：至3〇。〇下 度ΐ，使用10-密爾切口，於1/8_英吋厚棒塊中，根據 ASTM D256測得時，某些其他聚酯亦可顯示保持切口 Iz〇d 衝擊強度在正或負5〇/〇内。 於又另一項具體實施例中，當在23 °C下，使用10-密爾 切口’於1/4•英吋厚棒塊中度量，根據ASTM D256測得 時，當與相同聚酯，在相同溫度下，使用1〇_密爾切口， 於1/8-英吋厚棒塊中度量，根據ASTM D256測得時之切口 Izod衝擊強度比較時，某些可用於本發明之聚酯可顯示保 持在切口 Izod衝擊強度中，具有不超過7〇%之損失。 於一項具體實施例中，本發明之聚酯在厚切片中顯示優 越切口韌度。切口 12〇(1衝擊強度，如在ASTM D256中所述 者為種度里韌度之常用方法。當藉由iz〇d方法測試 時’聚合體可顯示無論是完全斷裂破壞模式，#中待測試 樣斷裂成兩個不同部份，或部份或無斷裂破壞模式，其中 :寺測：樣仍然保持為一個部份。完全斷裂破壞模式係伴隨 :低此1破壞。部份與無斷裂破壞模式係伴隨著高能量破 壞：用以度量IZ〇d韌度之典型厚度為1/8"。在此厚度下， 亟；聚合體顯示部份或無斷裂破壞模式，聚碳酸酯為 一種值得注意之實例。但是，當待測試樣之厚度被增加至 1M時，無市售非晶質材料顯示部份或無斷裂破壞模式。 119732.doc -253 - 200804457 於一項具體實施例中，本發明實例之組合物，當在Iz〇d中 使用1/4”厚試樣測試時，顯示無斷裂破壞模式。 於一項具體實施例中，可用於本發明之聚酯可顯示至少 一個下列密度：於23°C下，密度低於1.3克/毫升；密度低 於1.2克/毫升；於23。〇下，密度低於1.18克/毫升；於23°C 下’逾度為0·70至1.2克/毫升；於23 °C下，密度為〇·70至 1_3克/毫升；於231下，密度為〇7〇至小於^克/毫升；於 23°C下’密度為0.75至1.2克/毫升；於23°C下，密度為0.75 至小於1.2克/毫升；於23°C下，密度為0.80至1.2克/毫升； 於23°C下，密度為0.80至低於12克/毫升；於23〇c下，密 度為0.90至1.2克/毫升；於23°C下，密度為1·〇至1.2克/毫 升，於23°C下，密度為1·〇至1·3克/毫升；於23°C下，密度 為1.1至1.2克/毫升；於23〇C下，密度為1·13至1.3克/毫 升；於23°C下，密度為丨·;^至ι·2克/毫升；於23°C下，密 度為0.80至ι·ΐ8克/毫升；於23°C下，密度為0.80至小於 1.18克/毫升；於23°C下，密度為ι·〇至小於1.18克/毫升； 於23C下’密度為至小於118克/毫升。 在一些具體實施例中，利用可用於本發明之聚酯組合 物’會使在溶融加工及/或熱成形前之乾燥步驟降至最低 及/或免除。 在一具體實施例中，可用於本發明之熱穩定劑可為有機 化合物’例如’含有_化或未豳化取代基之亞磷酸酯。熱 穩定劑可包含廣大範圍之業界已知之構化合物，例如， 膦、亞磷酸酯、次膦酸酯、亞膦酸二酯、次磷酸酯、膦酸 119732.doc •254- 200804457 酯、氧化膦及磷酸酯。熱穩定劑之實例包括磷酸三丁酯、 磷酸三乙酯、磷酸三丁氧基乙酯、第三丁基苯基二苯基磷 酸酯、2-乙基己基二苯基磷酸酯、乙基二甲基磷酸酯、異 癸基二苯基磷酸酯、磷酸三月桂酯、磷酸三苯酯、磷酸三 甲苯酚酯、三（二曱苯基）磷酸酯、第三丁基苯基二苯基磷 酸酯、間苯二酚雙（二苯基磷酸酯）、填酸三节酯、苯基乙 基麟酸醋、三曱基硫代填酸自旨（trimethyl thionophosphate)、苯基乙基硫代磷酸酯、二甲基曱基膦酸 酯、二乙基甲基膦酸酯、二乙基戊基膦酸酯、二月桂基甲 基膦酸酯、二苯基甲基膦酸酯、二节基甲基膦酸酯、二苯 基甲苯酚基膦酸酯、二甲基甲苯酚基膦酸酯、二甲基甲基 硫代膦酸酯、苯基二苯基次磷酸酯、节基二苯基次磷酸 酯、甲基二苯基次磷酸酯、三曱基氧化膦、三苯基氧化 鱗、二下基乳化鱗、4-甲基二苯基氧化麟、亞填酸三乙 酯、亞.碟酸三丁酯、亞麟酸三月桂酯、亞磷酸三苯酯、亞 私S文二下醋、本基二乙基亞填酸g旨、苯基二甲基亞填酸 醋、苄基二甲基亞磷酸酯、二甲基甲基亞膦酸二酯、二乙 基戊基亞膦酸二酯、二苯基甲基亞膦酸二酯、二节基甲基 亞膦酸二酯、二甲基曱苯酴基亞膦酸二酯、甲基二曱基次 膦酸醋、甲基二乙基次膦酸酯、苯基二苯基次膦酸酯、甲 基二苯基次膦酸酯、节基二苯基次膦酸酯、三苯基膦、三 节基膦及曱基二苯基膦。在一具體實施例中，三苯基氧化 膦在可用於本發明聚酯之製造方法及本發明之聚酯組合物 中係排除作為熱穩定劑。 119732.doc -255 - 200804457 在一具體實施例中，可用於本發明之熱穩定劑可為先前 所述之任何基於磷之酸，其中酸化合物之一或多個氫原子 (連結至氧或磷原子）係以烷基、分支烷基、經取代烷基、 烷基醚、經取代烷基醚、烷基_芳基、烷基_經取代芳基、 芳基、經取代芳基及其混合物替代。在另一具體實施例 中，可用於本發明之熱穩定劑包括，但不限於，前述化合 物其中至少一個連結至化合物氧原子之氫原子係經金屬離 子或銨離子替代。 酉旨類含有烷基、分支烷基、經取代烷基、烷基醚、芳基 及/或經取代芳基基團。酯類亦可含有至少一個烧基基團 及至少一個芳基基團。存在於特定磷化合物中之酯基團之 數ϊ可從零至高達基於存在於所使用之磷化合物上之經基 數里所此允許之最大值之間變化。舉例言之，烧基鱗酸西旨 可包含一或多個單-、二-及三-烷基磷酸酯類；芳基磷酸酯 包含一或多個單·、二-及三-芳基磷酸酯類；且烷基磷酸酯 及/或芳基磷酸酯亦包含，但不限於，具有至少一個烷基 及一個芳基之混合烷基芳基磷酸酯類。 在一具體實施例中，可用於本發明之熱穩定劑包含，但 不限於’填酸、亞填酸、次膦酸、膦酸或亞膦酸之烧基、 芳基或混合烷基芳基酯類或部分酯類。烷基或芳基基團可 含有一或多個取代基。 於一方面，可用於本發明之填化合物包含至少一種熱穩 定劑’其係選自至少一種經取代或未經取代之烷基磷酸酯 類、經取代或未經取代之芳基磷酸酯類、經取代或未經取 119732.doc -256- 200804457 代之混合烷基芳基磷酸酯類、二亞磷酸酯類、磷酸鹽類、 氧化膦類及混合芳基烷基亞磷酸酯類、其反應產物及其混 合物。該磷酸酯類包含其中磷酸已完全酯化或僅部分酯化 之酯類。 在一具體實施例中，例如，可用於本發明之磷化合物可 包含至少一種磷酸酯。 於一方面，可用於本發明之磷化合物包含至少一種熱穩 定劑，其係選自至少一種經取代或未經取代之烷基磷酸酯 類、經取代或未經取代之芳基磷酸酯類、混合之經取代或 未經取代之烷基芳基磷酸酯類、其反應產物及其混合物。 該磷酸酯類包含其中磷酸已完全酯化或僅部分酯化之酯 類0 在另一具體實施例中，可用於本發明之磷化合物可包 含，但不限於，係選自至少一種烷基磷酸酯類、芳基磷酸 酯類、混合烷基芳基磷酸酯類、其反應產物及其混合物。 在某些具體實施例中，可用於本發明之磷酸酯類係該等 其中磷酸酯上之基團包含烷基、烷氧基-烷基、苯基或經 取代苯基者。此等填酸酯於本文中一般係指院基及/或芳 基磷酸酯類。某些較佳具體態樣包含三烷基磷酸酯類、三 芳基磷酸酯類、烷基二芳基磷酸酯類、二烷基芳基磷酸醋 類及該專鱗酸g旨之混合物，其中烧基基團較佳含有2至12 個碳原子，而芳基基團較佳係苯基。 代表性的烧基及分支烧基基團較佳係該等含有1至1 2個 碳原子之基團，包括，但不限於，乙基、丙基、異丙基、 119732.doc -257- 200804457 丁基、己基、環己基、2-乙基己基、辛基、癸基及十二 基。經取代之烧基包括，但不限於，該等含有至少一個魏 酸基團及其酯、羥基、胺基及酮基等之烷基。 代表性的烷基-芳基及經取代烷基-芳基基團係該等其中 烷基部分含有1至12個碳原子且芳基為苯基或經取代苯 基，其中苯環上任何碳位置之氫原子係經烷基、分支烷 基、芳基及羥基等取代。較佳芳基基團包括苯基或經取代 苯基，其中苯環上任何位置之氫原子係經烷基、分支烷 基、芳基及羥基等取代。 在一具體實施例中，可用於本發明中作為熱穩定劑之磷 酸酯類包含，但不限於，二丁基苯基磷酸酯、磷酸三苯 酯、磷酸三甲苯酚酯、磷酸三丁酯、三_2_乙基己基磷酸 酯、磷酸二辛酯及/或其混合物，包括磷酸三丁酯及磷酸 二甲苯酚酯之特定混合物與異十六基二苯基磷酸酯及2_乙 基己基二苯基磷酸酯之混合物。 在一具體實施例中，可用於本發明中作為熱穩定劑之磷 酸酯類包含，但不限於，至少一種下列物質：三烷基磷酸 S旨類、三芳基磷酸醋類、烷基二芳基磷酸酯類及混合烷基 芳基磷酸酯類。 在-具體實施例中’可用於本發明中作為熱穩定劑之麟 酸_類包含，但不限於，至少_種下列物質··三炫基填酸 酯類、烷&二芳基磷酸酯类員及混合烷基芳基磷酸酯類。 在-具體實^例中’可用於本發明中作為熱穩定劑之鱗 酸S旨類包含，但不限於，至少一種下列物質：彡芳基磷酸 119732.doc -258- 200804457 酯類及混合烷基芳基磷酸酯類。 在一具體實施例中，至少一種可用於本發明之熱穩定劑 包含，但不限於，三芳基磷酸酯類，例如，三苯基磷酸 酯。在一具體實施例中，至少一種熱穩定劑包含，但不限 於，Merpol A。在一具體實施例中，至少一種可用於本發 明之熱穩疋劑包含’但不限於，三苯基填酸g旨及Merpol A 中至少一者。Merpol A係商業尚可自stepan化學品公司及/ 或杜邦公司獲得之填酸酯。Merpol A之CAS註冊號碼咸信 為 CAS Registry # 37208-27-8。 在一具體實施例中，本發明之聚酯組合物及/或方法可 含有2 -乙基己基·一苯基鱗酸醋。 在一具體實施例中，可用於本發明之磷化合物包含，但 不限於，至少一種二亞磷酸醋。 在一具體實施例中，可用於本發明之磷化合物包含，但 不限於，至少一種二亞磷酸酯，其包括2,4,8，1〇_四噁基_ 3,9_二磷螺[5.5]十一烷結構，例如，West〇n 619(GE專業化 學品，CAS# 3806-34-6)及 / 或 Doverph〇s s_9228(D〇veMb 學品，CAS# 154862-43-8)。 在一具體實施例中，可用於本發明之磷化合物包含至少 一種氧化膦。 在-具體實施例中，可用於本發明之嶙化合物包含至少 -種混合烷基芳基亞磷酸酯類’例如，雙(2,4-異丙苯基苯 基）季戊四醇二亞碌酸醋’已知為Doverph〇s 8_9228(〇_ 化學品，CAS # 154862_43·8)。 119732.doc -259- 200804457 在一具體實施例中，任何本案說明書中所述用於製造該 聚酷組合物及/或聚酯之方法包含至少一種本案說明書中 所述之磷化合物。 在一具體實施例中，任何本案說明書中所述用於製造任 何該聚_組合物及/或聚酯之方法可包含至少一種二亞磷 酸6旨。 在一具體實施例中，任何本案說明書中所述用於製造任 何該聚酯組合物及/或聚酯之方法可包含至少一種二亞磷 酸醋’其包括2,4,8，10-四噁基-3,9_二磷螺[5.5]十一烷結 構，例如 Weston 619(GE專業化學品，cAS# 3806-34_6)及 / 或 DoverphosS-9228(Dover化學品，CAS# 154862-43-8)。 在一具體實施例♦，任何本案說明書中所述用於製造任 何該聚酯組合物及/或聚酯之方法可包含至少一種氧化 膦。 在一具體實施例中，任何本案說明書中所述用於製造任 何該聚酯組合物及/或聚酯之方法可包含至少一種混合烧 基芳基亞磷酸酯類，例如，雙（2,4_異丙苯基苯基）季戊四 醇一亞磷酸g旨’已知為Doverphos S_9228(Dover化學品， CAS # 154862-43-8)。 本發明之聚酯組合物及/或製造聚酯組合物之方法可含 有一熱穩定劑。 π熱穩定劑”一詞，意欲包括其反應產物在内。儘管，，熱 穩定劑”一詞使用於說明書全文中，本發明並無意欲為任 何特定操作理論所限制。用於與本發明熱穩定劑連、纟士 H9732.doc • 260· 200804457 反應產4勿-㈣係意指任何介於熱穩定劑及任何用於製造 聚醋之單體之聚縮合或醋化反應產物以及介於催化劑及任 何其他型態添加劑之聚縮合或_化反應產物。 當磷添加至本發明之聚酯及/或聚酯組合物及/或聚酯之 製造方法時，其係以本文中所描述之鱗化合物形式添加， 例如，至少一種二亞磷酸酯、至少一種磷酸鹽等。添加至 本發明之聚酯及/或本發明之聚酯組合物及/或本發明方法 之磷化合物（例如，至少一種二亞磷酸酯）之量，可以存在 於最終聚酯中之磷原子形式量測，例如，以重量。 於1合反應或後績製造程序期間添加之熱穩定劑量可包 含，但不限於，1至5000 Ppm ; 1至1000 ppm ; 1至9〇〇 ppm ’ 1至 800 ppm; 1至 700 ppm· 1至 600 ppm; 1至 500 ppm，1至 400 ppm; 1至 350 ppm; 1至 300 ppm; 1 至250 ppm，1 至 200 ppm ; 1 至 150 ppm ; 1 至 100 ppm ; 10至 5000 ppm，10至 1〇〇〇 ppm ; 1〇 至 9〇〇 ppm; 1〇至 800 ppm; 10 至 700 ppm ; 10至 600 ppm ; 10至 500 ppm ; 10至 400 ppm ; 10 至 350 ppm ; 10至 300 ppm ; 10至 250 ppm ; 10至 200 ppm ; 10至150 ppm ; 10至100 ppm，基於聚酯組合物之總重。 在一具體實施例中，於聚合反應期間添加之本發明磷化 合物（例如，二亞磷酸酯及磷酸酯等）之量係選自以下範 圍：1至 5000 ppm; 1至 1〇〇〇 ppm; 1至 900 ppm; 1至 800 ppm; 1 至 700 ppm ； 1 至 600 ppm ； 1 至 500 ppm ； 1 至 400 ppm; 1 至 350 ppm ； 1 至 300 ppm; 1 至 250 ppm; 1 至200 ppm; 1 至 150 ppm; 1 至 100 ppm; 1 至 60 ppm; 2至 5000 119732.doc -261- 200804457 ppm ; 2 至 1000 ppm ; 2至 900 ppm ; 2至 800 ppm ;2至 700 ppm ; 2 至 600 ppm ； 2 至 500 ppm ； 2 至 400 ppm ；2 至 350 ppm ; 2 至 300 ppm ； 2 至 250 ppm ； 2 至 200 ppm ；2 至 150 ppm ; 2 至 100 ppm ； 2 至 60 ppm ； 2 至 20 ppm ； 3 至 5000 ppm ; 3 至 1000 ppm ; 3 至 900 ppm ; 3 至 800 ppm ;3 至 700 ppm. 3 至 600 ppm ; 3 至 500 ppm ； 3 至 400 ppm ；3 至 350 ppm ; 3 至 300 ppm ； 3 至 250 ppm ； 3 至 200 ppm ；3 至 150 ppm ; 3 至 100 ppm ； 3 至 60 ppm ; 3 至 20 ppm ； 4 至 5000 ppm ; 4 至 1000 ppm ; 4至 900 ppm ； 4至 800 ppm ;4至 700 ppm ; 4 至 600 ppm ； 4 至 500 ppm ； 4 至 400 ppm ；4 至 350 ppm ; 4 至 300 ppm ； 4 至 250 ppm ； 4 至 200 ppm ；4 至 150 ppm ; 4 至 100 ppm ； 4 至 60 ppm ; 4 至 20 ppm ； 5 至 5000 ppm ; 5 至 1000 ppm ； 5 至 900 ppm ； 5 至 800 ppm ；5 至 700 ppm ; 5 至 600 ppm ； 5 至 500 ppm ； 5 至 400 ppm ；5 至 350 ppm ; 5 至 300 ppm ; 5 至 250 ppm ; 5 至 200 ppm ；5 至 150 ppm ; 5 至 100 ppm ; 5 至 60 ppm ； 5 至 20 ppm ； 6 至 5000 ppm ; 6 至 1000 ppm ; 6至 900 ppm ； 6至 800 ppm ；6至 700 ppm ; 6 至 600 ppm ； 6 至 500 ppm ; 6 至 400 ppm ；6 至 350 ppm ; 6 至 300 ppm ； 6 至 250 ppm ; 6 至 200 ppm ；6 至 150 ppm ; 6 至 100 ppm ; 6 至 60 ppm ; 6 至 20 ppm ； 7 至 5000 ppm ; 7 至 1000 ppm ; 7至 900 ppm ； 7至 800 ppm ；7至 700 ppm ; 7 至 600 ppm ； 7 至 500 ppm ； 7 至 400 ppm ；7 至 350 ppm ; 7 至 300 ppm ； 7 至 250 ppm ； 7 JL 200 ppm ；7 至 150 ppm ; 7 至 100 ppm ； 7 至 60 ppm ； 7 至 20 ppm ； 8 至 5000 119732.doc •262- 200804457 8至 1000 ppm ; 8 至 600 ppm ； 8 至 300 ppm ； 8 至 100 ppm ; 9至 1000 ppm ; 9 至 600 ppm ； 9 至 300 ppm ； 9 至 100 ppm ; ppm ppm ppm ppm ppm ppm ppm ppm 8 至 900 ppm ; 8至 800 ppm; 8至 700 8 至 500 ppm ; 8 至 400 ppm ; 8 至 350 8 至 250 ppm ； 8 至 200 ppm ； 8 至 150 8 至 60 ppm ； 8 至 20 ppm ； 9 至 5000 9 至 900 ppm; 9至 800 ppm; 9至 700 9 至 500 ppm ； 9 至 400 ppm ; 9 至 350 9至 250 ppm; 9至 200 ppm; 9至 150 9 至 60 ppm ； 9 至 20 ppm ； 10 至 5000 ppm 10至 1000 ppm ; 10至 900 ppm 700 ppm ； 10至 600 ppm ; 10至 500 ppm ; 10至 400 ppm ; 10 至 350 ppm ; 10至 300 ppm ; 10至 250 ppm ; 10至 200 ppm ; 10 至 150 ppm; 10 至 100 ppm; 10 至 60 ppm; 10 至 20 ppm; 50至 5000 ppm ； 50至 1000 ppm ； 50至 900 ppm ； 50至 800 ppm ; 50至 700 ppm ； 50至 600 ppm ; 50至 500 ppm ; 50至 400 ppm ; 50至 350 ppm ; 50至 300 ppm ; 50至 250 ppm ; 50 至 200 ppm; 50 至 150 ppm; 50 至 100 ppm; 50 至 80 ppm; 100 至 5000 ppm; 100 至 1000 ppm; 100 至 900 ppm; 100 至 800 ppm ; 100 至 700 ppm ; 100 至 600 ppm ; 100 至 500 ppm ； 100 至 400 ppm ； 100 至 350 ppm ； 100 至 300 ppm ； 100 至 250 ppm ; 100 至 200 ppm ; 100 至 150 ppm ; 150 至 5000 ppm; 150 至 1000 ppm; 150 至 900 ppm; 150 至 800 ppm ； 150 至 700 ppm ； 150 至 600 ppm ； 150 至 500 ppm ； 150至 400 ppm ; 150至 350 ppm ; 150至 300 ppm ; 150至 250 ppm ； 150至 200 ppm ; 200至 5000 ppm ; 200至 1000 ppm ; 119732.doc -263 - 200804457 200至 900 ppm ; 200至 800 ppm ; 200至 700 ppm ; 200至 600 ppm ； 200 至 500 ppm ； 200 至 400 ppm ； 200 至 350 ppm ； 200 至 300 ppm ; 200 至 250 ppm ; 250 至 5000 ppm ; 250 至 1000 ppm ； 250 至 900 ppm ； 250 至 800 ppm ； 250 至 700 ppm ； 250 至 600 ppm ； 250 至 500 ppm ； 250 至 400 ppm ； 250 至 350 ppm ; 250 至 300 ppm ； 500 至 5000 ppm ； 300 至 1000 ppm ; 3 00 至 900 ppm ; 3 00 至 800 ppm ; 300 至 700 ppm ； 300 至 600 ppm ； 300 至 500 ppm ； 300 至 400 ppm ； 300至350 ppm; 350至5000 ppm ; 350至1000 ppm ; 350至 900 ppm ； 350 至 800 ppm ； 350 至 700 ppm ； 350 至 600 ppm ; 350至500 ppm ; 350至400 ppm;基於聚酯組合物總重 量且係以最終聚酯中之磷原子形式量測。 本發明進一步關於聚合體摻合物。此摻合物包含： (a) 5至95重量％至少一種上述聚酯；與 (b) 5至95重量％至少一種聚合體成份。 聚合體成份之適當實例包括但不限於尼龍，與本文中所 述者不同之聚酯，聚醯胺，譬如得自DuPont之ZYTEL® ; 聚苯乙烯、聚苯乙烯共聚物、苯乙烯丙烯腈共聚物、丙烯 腈丁二烯苯乙烯共聚物、聚（甲基丙烯酸甲酯）、丙烯酸系 共聚物，聚（醚-醯亞胺類），譬如ULTEM® (聚（醚-醯亞 胺），得自通用電氣公司）；聚苯醚類，譬如聚（2,6-二甲基 苯醚），或聚（苯醚）/聚苯乙烯摻合物，譬如NORYL 1000®(聚（2,6-二甲基苯醚）與聚苯乙烯樹脂之摻合物，得 自通用電氣公司）；聚苯硫類；聚苯硫/颯類；聚（酯-碳酸 119732.doc -264- 200804457 醋類）；聚碳酸酯類，譬如LEXAN®(聚碳酸酯，得自通用 電氣公司）；聚颯類；聚颯醚類；及芳族二羥基化合物之 聚（¾-酮類）；或任何前述聚合體之混合物。摻合物可藉此 項技藝中已知之習用加工技術製成，譬如溶融摻合或溶液 摻合。於一項具體實施例中，聚碳酸酯並未存在於聚酯組 合物中。若將聚碳酸酯使用於可用於本發明聚酯組合物之 摻合物中，則此摻合物可為視覺上透明。但是，可用於本 發明之聚酯組合物亦意欲涵蓋排除聚碳酸酯，以及加入聚 碳酸自旨。 可用於本發明之聚碳酸酯可根據已知程序製成，例如經 由使二經基芳族化合物與碳酸酯先質，譬如光氣、齒基甲 酸酯或碳酸酯，分子量調節劑、酸接受劑及催化劑一起反 應。製備聚破酸酯之方法係為此項技藝中已知，且係描述 於例如美國專利4,452,933中，其中關於製備聚碳酸酯之揭 示内容係據此併於本文供參考。 適當碳酸酯先質之實例包括但不限於溴化碳醯、氯化碳 醯或其混合物；碳酸二苯酯；二（_苯基）碳酸酯，例如碳 酸二（三氯苯）酯、碳酸二（三溴苯）酯等；二（烷基苯基）碳酸 酯，例如碳酸二（甲苯）酯；碳酸二（萘）酯；碳酸二（氯基莕） 西曰或其混合物；及二經紛之雙_基甲酸醋。 適當分子量調節劑之實例包括但不限於酚、環己醇、甲 醇，烷基化酚類，譬如辛基酚、對_第三_丁基_酚等。於一 項具體實施例中，分子量調節劑為酚或烷基化酚。 酸接受劑可為無論是有機或無機酸接受劑。適#有㈣ 119732.doc -265 · 200804457 接文劑可為三級胺，且包括但不限於一些物質，嬖如吡 ::三乙胺、二甲苯胺、三丁胺等。無機酸接受劑可為無 卿疋鹼金屬或鹼土金屬之氫氧化物、碳酸鹽、重碳酸踏 磷酸鹽。 息5 用於製造可用於本發明之聚碳酸酯之催化劑包括但不限 於典型上會幫助單體與光氣之聚合反應者。適當催化劑包 2但不限於三級胺類，譬如三乙胺、三丙胺、n，n_二甲苯 胺，四級銨化合物，例如溴化四乙銨、溴化鯨蠟基三乙 銨、碘化四-正_庚基銨、漠化四正_丙基銨、氯化四甲基 錢、氫氧化四·甲基敍、魏四正·丁基錄、氯化爷基三甲 基銨，及四級鱗化合物，例如漠化正.丁基三苯基鱗與溪 化甲基三苯基鱗。 可用於本發明聚醋組合物之聚碳酸s旨，亦可為共聚醋碳 I知類，譬如在美國專利3，169，121 ; 3,207,814 ; 4,156,069 , 4,430,484 ； 4,465,820^ 4,981,898 中所述者，其中關於來自各美國專利之共聚醋碳酸醋之揭 示内容，係併於本文供參考。 可用於本發明之共聚§旨碳酸醋，可為市購而得及/或可 措此項技藝中已知之方法製備。例如，其典型上可經由至 少-種二羥基芳族化合物與光氣及至少一種二羧酸氯化 物尤二疋乳化異酉大醯、氣化對苯二甲酿或兩者之浪合物 反應而獲得。 此外，可用於本發明之聚醋組合物與聚合物捧合組合 物，亦可含有聚醋組合物總重量之〇〇1至25重量％之常用 119732.doc -266 - 200804457 添加劑’譬如著色劑、染料、脫模劑、火焰阻滯劑、增塑 唞成核劑，安定劑，包括但不限於uv安定劑、熱安定 劑及/或其反應產物，填料與衝擊改質劑。此項技藝中所 白知且可用於本發明之典型市購可得衝擊改質劑之實例， 包括但不限於乙烯/丙烯三元聚合體；官能基化之聚烯 烴，譬如含有丙烯酸曱酯及/或甲基丙烯酸縮水甘油酯 者，苯乙烯系嵌段共聚合衝擊改質劑；及各種丙烯酸系核 芯/殼層類型衝擊改質劑。亦意欲涵蓋使此種添加劑之殘 基作為聚酯組合物之一部份。 補強材料可用於本發明之組合物中。補強材料可包括但 不限於碳纖絲、矽酸鹽、雲母、黏土、滑石、二氧化鈦、 石夕灰石、玻璃薄片、玻璃珠及纖維，以及聚合體纖維，及 其組合。於一項具體實施例中，補強材料包括玻璃，譬如 玻璃纖維纖絲，玻璃與滑石、玻璃與雲母及玻璃與聚合體 纖維之混合物。 供使用於本發明方法以製造可用於本發明之聚酯之適當 催化劑包含至少一種錫化合物。本發明之聚酯組合物亦可 包含至少一種可用於本發明方法之錫化合物。其他催化劑 可包括但不限於以鈦、鎵、辞、録、始、猛、鎂、鍺、經 及鋁化合物及鋁化合物與氫氧化鋰或氫氧化鈉。於一具體 實施例中，催化劑可為至少一種錫化合物及至少一種鈦化 合物之組合。 催化劑量之範圍可涵蓋從10 ppm至20,000 ppm或10至 10,000 ppm，或 10 至 5000 ppm 或 10 至 1000 ppm 或 10 至 500 119732.doc -267· 200804457 ppm，或l〇至300卯瓜或⑺至以❻，以催化劑金屬為基準及 以最後聚合體之重量為基準。此方法可以無論是批次或連 續方法進行。於一具體實施例中，催化劑係一錫化合物。 於一具體實施例中，催化劑係一單獨之錫化合物。於一具 體實施例中，錫化合物可被用於酯化反應或聚縮合反應或 兩者之中。於另一具體實施例中，催化劑係一可用於酯化 反應中之聚酯中之單獨錫化合物。 一般而言，於一具體實施例中，錫化合物催化劑係以約 0.005%至約0.2%之量使用，以二羧酸或二羧酸酯之總重為 基準。一般而言，於一具體實施例中，只有少於約7〇〇 ppm之元素錫作為殘餘物存在於聚酯中，以聚酯總重量為 基準。 當錫添加至本發明之聚酯及/或聚酯組合物及/或聚酯之 製造方法時，其係以本文中所描述之錫化合物形式添加。 添加至本發明之聚酯及/或本發明之聚酯組合物及/或本發 明方法之錫化合物之量，可以存在於最終聚酯中之錫原子 形式里測’例如’以重量ppm 〇 於另一具體實施例中，催化劑係使用於酯化反應中之單 獨一錫化合物，其量為1〇 ppm至2〇,〇〇〇 ppm ;或1〇至 10,000 ppm ;或 1〇 至 5〇〇〇 ppm ;或 10 至 4500 ppm;或 10 至 4000 ppm;或 1〇 至 3500 ppm;或 10 至 3000 ppm;或 1〇 至 2500 ppm;或 1〇 至 2000 ppm;或 1〇 至 1500 ppm;或 1〇 至 1000 ppm;或 1〇 至 5〇〇 ppm;或 10 至 300 ppm;或 10 至 250 ppm ;或 15 ppm至 20,000 ppm ;或 15至 10,000 ppm，；或 15 119732.doc -268- 200804457 至 5000 ppm;或 15 至 4500 ppm ;或 15 至 40 00 ppm ;或 15 至 3500 ppm;或 15 至 3000 ppm;或 15 至 2500 ppm ;或 15 至 2000 ppm ;或 15 至 1500 ppm ;或 15 至 1000 ppm ;或 15 至 500 ppm;或 15至 400 ppm;或 15至 300 ppm;或 15至 250 ppm;或 20 ppm 至 20,000 ppm ；或 20 至 10,000 ppm ；或 20 至 5000 ppm ;或 20至 4500 ppm ;或 20至 4000 ppm ;或 20至 3500 ppm ;或 20 至 3000 ppm ;或 20 至 2500 ppm ;或 20 至 2000 ppm;或 20 至 1500 ppm;或 20 至 1000 ppm ;或 20 至 500 ppm ；或 20至 300 ppm ;或 20至 250 ppm ;或 25 ppm至 20.000 ppm ；或 25 至 10,000 ppm ；或 25 至 5000 ppm;或 25 至 4500 ppm ;或 25至 4000 ppm ;或 25至 3500 ppm ;或 25至 3000 ppm ；或 25 至 2500 ppm ；或 25 至 2000 ppm ；或 25 至 1500 ppm;或 25 至 1000 ppm;或 25 至 500 ppm;或 25 至 400 ppm ；或 25 至 300 ppm ;或 25 至 250 ppm ;或 30 ppm 至 20.000 ppm;或 30 至 10,000 ppm;或 30 至 5000 ppm;或 30 至 4500 ppm ;或 30至 4000 ppm ;或 30至 3500 ppm ;或 30至 3000 ppm ;或 30 至 2500 ppm ;或 30 至 2000 ppm ;或 30 至 1500 ppm ;或 30至 1000 ppm ;或 30至 500 ppm ;或 30至 300 ppm ；或 30 至 250 ppm ；或 35 ppm至 20,000 ppm ；或 35 至 10.000 ppm,；或 35至 5000 ppm ;或 35至 4500 ppm ;或 35至 4000 ppm ;或 35至 3500 ppm ；或 35至 3000 ppm ;或 35 至 2500 ppm ；或 35 至 2000 ppm ；或 35 至 1500 ppm ;或 35 至 1000 ppm ；或 35至 500 ppm ;或 35至 300 ppm ；或 35至 250 ppm ;或 40 ppm至 20,000 ppm ；或 40至 10,000 ppm ；或 40 119732.doc -269· 200804457 至 5000 ppm ;或 40至 4500 ppm ;或 40至 4000 ppm ;或 40至 3500 ppm ;或 40至 3000 ppm ;或 40至 2500 ppm ;或 40至 2000 ppm ;或 40 至 1500 ppm ;或 40 至 1000 ppm ;或 40 至 500 ppm ；或 40 至 300 ppm ；或 40 至 250 ppm ;或 40 至 200 ppm ;或 45 ppm至 20,000 ppm ;或 45至 10,000 ppm,；或 45 至 5000 ppm ;或 45 至 4500 ppm ;或 45 至 4000 ppm ;或 45 至 3500 ppm ;或 45 至 3000 ppm ;或 45 至 2500 ppm ;或 45 至 2000 ppm ;或 45 至 1500 ppm ;或 45 至 1000 ppm ;或 45 至 500 ppm ;或 45至 300 ppm ;或 45至 250 ppm ;或 50 ppm至 20,000 ppm ;或 50至 10,000 ppm，；或 50至 5000 ppm ;或 50 至 4500 ppm ;或 50至 4000 ppm ;或 50至 3500 ppm ;或 50至 3000 ppm ；或 50 至 2500 ppm ；或 50 至 2000 ppm ；或 50 至 1500 ppm ；或 50 至 1000 ppm;或 50 至 500 ppm ;或 50 至 300 ppm ;或 50 至 250 ppm ;或 50 至 200 ppm ;或 50 至 150 ppm ;或50至125 ppm ;基於聚酯組合物總重量且係以最終 聚酯中之錫原子形式量測。 於一具體實施例中，本發明之聚酯可使用至少一種錫化 合物做為催化劑來加以製備。舉例而言，在美國專利 2,720,507中所述者，其中關於錫催化劑之揭示内容，係併 於本文供參考。該等催化劑係含有至少一個有機基團之錫 化合物。該等催化劑同時包含二價或四價錫化合物，其具 有如下通式： A. M2(Sn(OR)4) B. MH(Sn(OR)4) 119732.doc -270- 200804457 c. Mf(Sn(OR)4) D. Mf(HSn(OR)4)2 E. M2(Sn(OR)6) F. MH(Sn(OR)6) G. Mf(Sn(OR)6) H. Mf(HSn(OR)6)2 I. Sn(OR)2 J. Sn(OR)4 K. SnR，2 L. SnR，4 M. R，2SnO Ν·The ear % is % of the mole. In a specific embodiment, the acid and/or pentanoic acid is provided in the modified wn acid component of the present invention. 119732. Doc »242- 200804457 The aliphatic dicarboxylic acid for modification of the present invention may contain dihydrogenated dicarboxylic acids, for example, dihydrogen-1,3-dicarboxylic acids and/or phenyldihydrotaphthalened dicarboxylic acids. In a specific embodiment, the dicarboxylic acid may be selected from at least one 1,2,3-trimethyl-3-phenyldihydroindole-4,5-dicarboxylic acid and trimethyl-carboxyl -3-(4-carboxyphenyl)indolinedicarboxylic acid. In accordance with the purpose of the present invention, any of the dihydrogen nodules in U.S. Patent Application Serial No. 2006/0004151 A1 (the title of the invention, the copolymer containing the indoline molecule and its blend; the applicant is General Electric) The dicarboxylic acid can be used as at least one modified aliphatic dicarboxylic acid falling within the scope of the present invention. The disclosure of the diterpene dicarboxylic acid in the entire patent application of U.S. Patent Application Serial No. 2006/00041, the entire disclosure of which is incorporated herein by reference. Instead of dicarboxylic acids, terephthalic acid esters and other modified dicarboxylic acids or their corresponding esters and/or salts can be used. Suitable examples of dicarboxylic acid esters include, but are not limited to, dimethyl, diethyl, dipropyl, diisopropyl, monobutyl and diphenyl esters. In one embodiment, the ester is selected from the group consisting of at least one of the following: methyl, ethyl, propyl, isopropyl and phenyl esters. For the desired polyester, the cis/trans 2,2,4,4•tetramethyl-丨, 3_cyclobutanediol molar ratio can be from pure cis, pure trans and cis/reverse The mixture varies between the formulas. In some embodiments, the molar percentage of cis and/or trans 2,2,4,4-tetramethyl-1,3-butanediol is greater than 5 〇 mol% of cis and Trans is less than 50 mol%; or more than 55 mol% cis and less than 45 mol/〇 trans, or 30 to 70 mol% cis and 7 〇 to 3 〇 mol% inverse Formula, or 40 to 60 mol% cis and 6 〇 to 4 〇 mol% trans; or % 119732. Doc -243 - 200804457 to 70% of the trans and 5〇 to 3〇% of the cis; or 5〇 to the 莫 % 及 and 50 to 30 摩尔% of the trans; or 6 〇 to 7 〇 耳 % 顺 and 30 to 40 摩尔 % of trans; or greater than 7 () 摩尔 % of cis and less than ^ 莫 % of trans; where cis and trans (10) + The molar percentage of tetramethyl-cyclobutanediol is equal to 1% molar %. In an additional embodiment + 'cis/trans 2,2,4,4-tetraf-yl>, the molar ratio of 3_cyclobutanediol can vary from 50/50 to 0/100 , for example, between the sides to 20/80. The cyclohexanedimethanol may be in the form of cis, trans or a mixture thereof, for example, having a cis/trans ratio of 60:40 to 40:60 or 7 〇: Chuan to Bie: 7 〇 cis / Trans ratio. In another specific embodiment, the trans-cyclohexanedimethanol may be present in an amount of from 60 to 80 mol% and the cis-cyclohexane dimethanol may be present in an amount of from 2 to 40 mol% of the cis-cyclohexane. The total percentage of dimethanol and transcyclohexanedimethanol is equal to 1 mole %. In a particular embodiment, 'trans cyclohexanedimethanol can be present in an amount of 6 G mole % and cis cyclohexane dimethanol can be present in an amount of 40 mole percent. In a particular embodiment, transcyclohexanedimethanol can be present in an amount of 70 mole percent and cis cyclohexanedimethanol can be present in an amount of 30 mole percent. Any 1,4-isomer of cyclohexanedimethanol or a mixture thereof may be present in the diol component of the polyester useful in the present invention. In one embodiment, 1,4-cyclohexaned dimethanol is included. In one embodiment, the polyester useful in the present invention comprises 1,4-cyclohexanedimethanol and 匕% cyclohexanedimethanol. The molar ratio of cis/trans 1,4-cyclohexanedimethanol can vary from 5 〇/5 Torr to 〇/ι ,, for example, between 40/60 and 20/80. 119732. Doc • 244- 200804457 立: In a specific embodiment, the diol component of the polyester portion of the polyester composition of the present invention may contain 98 mol% or less of one or more diols for modification. a class which is not 2,2,4,4_tetramethyl{3-cyclobutanediol or cyclohexanone. In one embodiment, it can be used in the polymerization of the polyester composition of the present invention. The diol component of the ester moiety may contain from 5 to 98 mole % of one or more glycols for modification, which are not 2,2,4,4-tetramethyl-oxime, 3-butanediol or Cyclohexanedimethanol, in one embodiment, the diol component of the polyester portion useful in the poly-composition of the present invention may contain one of 25 mol% or less or a glycol which is not 2,2,4,4-tetramethyl'cyclobutanediol or %hexanediethanol; in one embodiment, it can be used in the polymerization of the polyester composition of the present invention The diol component of the ester moiety may contain 2% by mole or less of one or more modified glycols, which are not 2, 2, 4, cardiac tetramethyl U, 3-cyclobutanol or Cyclohexane dimethanol; in a specific embodiment, can be used in the present invention Part of the polyester composition of the glycol ester component may contain 15 mole% or more; modified with one or more glycols. In one embodiment, the diol component of the polyester portion useful in the polyester composition of the present invention may contain 1% by mole or less of one or more modifier diols. In one embodiment, the diol component of the polyester portion useful in the polyester composition of the present invention may contain one or more modifying diols of 5 mole % or less. In one embodiment, the diol component of the polyester portion useful in the polyester composition of the present invention may contain one or more modifier diols in an amount of 3 mole percent or less. In one embodiment, the diol component of the polyester portion useful in the polyester composition of the present invention may contain one or more diols for modification. Certain embodiments may also contain 〇1 to 98% by mole, such as 119 119732. Doc -245 - 200804457 to 98 mole % 1 to 98 mole %, 5 means mole %, or 1 () to 98 mole % One or more modified glycols. The alcohol system is excluded as a diol for reforming. The diol used for the modification of the polyester of the present invention means a glycol other than 2,2,4,4-tetramethyl-1'3-indobutylene glycol and cyclohexanedimethanol, and may contain 2 to 16 carbon atoms. Examples of suitable diols for modification include, but are not limited to, ethylene glycol residues, propylene glycol, hydrazine, 3-propylene glycol, neopentyl glycol, hydrazine, butanediol, 1,5-pentanediol, Hexanediol, p-xylene glycol, polytetramethylol, and mixtures thereof. In one embodiment, the upgrading diol is ethylene glycol. In another embodiment, the diols for upgrading include, but are not limited to, to guanidine, 3-propanediol and iota, 4-butanediol. In another specific embodiment, the ethylene glycol residue is excluded as a diol for upgrading. In the other embodiment, 1,3_propanediol and hydrazine and butyl glycol were excluded as the diol for reformation. In another specific embodiment, 2,2-dimethyl 'cyanate can be used in the polyester and/or polycarbonate of the polyester composition of the present invention, which can be up to 10 mole percent, such as 0 01 to 5 mole percentage, 〇... to } mole percentage, 0. 05 to 5 mole percentage, 0. Percentage of 05 to 1 mole or 〇" to 〇7 moles, based on the percentage of total moles of diol or diacid residues; individually, branched monomers (also referred to herein as The branching agent) has one or more residues having 3 or more carboxyl substituents, hydroxyl substituents, or a combination thereof. In some embodiments, the branching monomer or branching agent can be added before and/or during and/or after the polymerization of the polyester. It can be used in the polyester of the present invention, and thus can be linear or branched. Polycarbonates can also be linear or branched. In some embodiments, the branching monomer or branching agent 119732. Doc 246- 200804457 In the second! Addition before and/or during and/or after the acidizing polymerization. Examples of early bodies include, but are not limited to, polyfunctional acids or polyfunctional alcohols: for example, benzenetricarboxylic acid, benzotrizene, benzoic acid di-, methyl propane, glycerol, pentaerythritol, Citric acid, tartaric acid, 3· azelaic acid, and the like. In a specific embodiment, the branched monomer residue may comprise from 3 〇·1 to 0. One or more residues of 7 mole percentage, at least selected from the group consisting of: trimellitic liver, pyromellitic dianhydride, glycerin, calyx ::. Hexanetriol, pentaerythritol, trimethylolethane, and/or symmetrical benzene: methyl peroxide can be added to the poly-δ reaction mixture, or in the form of a polycondensate The ester blending is as described in U.S. Patent Nos. 5,654,347 and 5,696,176, the disclosures of which are incorporated herein by reference. The poly(S) of the present invention may comprise at least one chain extender. Suitable bond extensions include, but are not limited to, polyfunctional (e.g., without limitation, bifunctional) isocyanates, polyfunctional epoxides, for example, epoxidized novolacs and phenoxy ethoxylates. In some embodiments, the chain extender can be added at the end of the polymerization process or after the polymerization process. If added after the polymerization process, the chain extender can be incorporated by way of compounding or addition during the conversion process, such as injection molding or extrusion. The amount of the chain extender used varies depending on the particular monomer composition used and the nature of the desired material, but generally ranges from about 〇 to about 1% by weight, for example from about 〇 to about 5% by weight, Based on the total weight of the polyester. The glass transition temperature (Tg) useful for the polyesters of the present invention was obtained using TA DSC 2920 from Thermal Analyst Instruments at 2 (rc/min scan 119732. Doc -247- 200804457 Measured at rate. Hey! : Under 17rc, by using some of the long knots that can be used in the present invention, it can be used to manufacture articles, package = not (4) injection molded articles, injection blown articles. , injection stretch blow molding _ formed film, extruded sheet, extruded blow article and extruded stretch blow and fiber. An example of a manufactured article provided by the present invention is a thermally formable sheet. The polyester of the present invention may be amorphous or semi-crystalline. In some aspects, certain of the compositions useful in the present invention can have relatively low crystallinity. Certain polyesters useful in the present invention may thus have substantially amorphous morphology, meaning that such polyesters comprise substantially irregular regions of the polymer. In the specific embodiment, "amorphous" polyacetate may have a crystallization half-life of greater than 5 minutes at 170 t' or at 17 Torr. . Lower than 1 minute, or greater than 50 minutes below, or greater than 1 minute at (10). In one embodiment of the invention, the crystallization half-life can be greater than moo minutes at 170 °C. In another embodiment of the invention, the crystallization half-life of the polyester useful in the present invention can be greater than 10,000 minutes at 170 t. The crystallization half-life of the polyester, as used herein, can be measured using methods well known to those skilled in the art. For example, the crystallization half-life of the polyester can be measured by the light transmission of the sample via the laser and photodetector as a function of time on a temperature controlled heating chuck. This metric can be achieved by exposing the polymer to a temperature Tmax and then allowing it to cool to the desired temperature. Then, the sample can be held at the desired temperature by heating the chuck table while performing the light transmittance measurement as 119732. Doc -248- 200804457 : A function between. The most phase sample can be visually transparent and has a high light transmission: when the field is sampled, when it is 纟°aB, it becomes *transparent. The half-life of crystallization is the time during which the transmittance is between the initial transmittance and the final transmittance. Tmax is defined as the temperature required to dissolve the crystalline phase of the sample (if present in the crystalline phase domain). The sample can be heated to Tmax to condition the sample prior to crystallization half-life measurment. Absolutely, the coffee temperature is different for each compound. For example, pcT can be heated to greater than 29 〇. A certain temperature of 〇 to melt the crystalline phase. As shown in Table 1 of the Examples and Figure 1, for increasing the crystallization half-life, meaning the time required for the polymer to reach half of its highest crystallinity, 2,2,4,4-tetradecyl_1,3 _Cyclobutanediol is more effective than other comonomers such as ethylene glycol and isophthalic acid. By reducing the crystallization rate of PCT, i.e., increasing the half-life of crystallization, an amorphous article based on modified pct can be produced by methods known in the art, such as extrusion, injection molding, and the like. As shown in Table 1, these materials can exhibit higher glass transition temperatures and lower densities than other modified PCT copolyesters. For some embodiments of the invention, such polyesters may exhibit improvements in toughness in combination with processability. For example, slightly lowering the inherent viscosity of the polyesters that can be used in the present invention results in a more processable melt viscosity while maintaining the good physical properties of the polyester, such as toughness and heat resistance. In one embodiment, the melt viscosity of the polyester useful in the present invention is less than 30,000 poise when measured on a rotary melt rheometer at 290 ° C at 1 radians per second. In one embodiment, when measured on a rotary melt rheometer at 290 ° C at 1 radians / sec, 119,732. Doc -249- 200804457 The melt viscosity of polyesters useful in the present invention is less than 20, anchorage. In one embodiment, the melt viscosity of the polyester useful in the present invention is less than 1 Torr when measured on a rotary melt rheometer at 290 ° C at 1 radians per second. Anchorage. In one embodiment, the melt viscosity of the polyester useful in the present invention is less than 15, when measured at 1 radians per second at 290 ° C on a rotary melt rheometer. Parking. In another specific embodiment, when on a rotary smelting rheometer, at 290. The melt viscosity of the polyester useful in the present invention is less than 6,000 poise when measured at 1 fox/sec. In one embodiment, certain of the polyesters useful in the present invention may be visually clear. The term "visually transparent" is defined herein as the turbidity, haze, and/or chaos that is perceived to be absent when examined visually. In another specific embodiment, the blend can be visually clear when the polyester is blended with a polycarbonate, including but not limited to a two-aged A polycarbonate. In other embodiments of the invention, the polyester useful in the present invention may have a yellowness index (ASTM D-1925) of less than 50 or less than 2 Torr. In a specific embodiment, the polyesters useful in the present invention and/or the polyester compositions of the present invention, with or without toner, may have color values a and b, which may be used by Hunter United Laboratories The Hunter Lab mtrascan spectral colorimeter was manufactured by the company (Rest〇n, Va). Color Measure is the average of the values of the granules on either the polyester granules or the panels or other articles from which they are injection molded or extruded. It is determined by the L*a*b* color system (translated) of the International Commission on Illumination, where L* stands for H9732. Doc -250· 200804457 The tc coordinates, a* for red/green coordinates, and b* for yellow/blue coordinates. In some embodiments, the b* value useful for the polyesters of the present invention may range from -10 to less than 10, and the L* value may range from 50 to 90. In other embodiments, the b* value for the present invention may exist in one of the following ranges: _1 〇 to 9 '· _1 〇 to 8; _10 to 7; _1 〇 to 6; _1 〇 to 5 ;, to 4 '· -10 to 3; _1〇 to 2; _5 to 9; -5 to 8b 5 to 7b 5 to 6; _5 to 5; -5 to 4, · _5 to 3b 5 to 2; 0 to 9; 〇 to 8; 〇 to 7; 〇 to 6; 〇 to 5' 0 to 4; 0 to 3; 〇 to 2; 1 to 1 〇; n u8; a?; β 6,1 to 5, 1 to 4; 1 to 3; and 1 to 2. In other specific embodiments, the L* value of the polyester useful in the present invention may be present in one of the following ranges: (9) to 6:50 to 70; 50 to 80; 5 to 9; 6 to 7 6〇 to 8〇; to 90; 70 to 80; 70 to 90. In the copolyester based on terephthalic acid, ethylene glycol and hydrazine, 4_cyclohexane dimethanol, increasing the content of 1,4-cyclohexanedimethanol can improve the toughness. When measured by soil ASTM D256, it can be measured by the ductile brittle transition temperature in the notched Iz〇d impact strength test. This toughness improvement is achieved by lowering the ductile-brittle transition temperature with 1,4-cyclohexanedimethanol, which occurs due to the flexibility and conformation behavior of m-cyclohexyl dimethanol in the copolymerized vinegar. Incorporating 2'2'4'4 tetramethyl+3. From cyclobutanediol to pcT, the salty taste improved the toughness by lowering the ductile brittle transition temperature, as shown in Table 2 and Figure 2 of the Examples. This is surprising under the rigidity of 2,2,4,4·tetramethyl-1,3·cyclobutanediol. . In a specific embodiment, the polyester that can be used in the present invention exhibits a lower than 〇 C extension! raw-to-brittle transition temperature, based on a 1 〇 mil slit, at "8·英吋 119732. Doc -251 - 200804457 Thick rods, measured according to ASTM D256. The incision Izod impact strength, as described in ASTM D256, is a common method of measuring early edge. The polyesters useful in the present invention may have one or more of the following properties. In one embodiment, the vinegar useful in the present invention exhibits an Izod impact strength of at least 150 j/ni (3 Å/in pairs), and a 10 mil slit at 23 ° C, at 3 • 2 mm (1/8-inch) thick bar in 'measured according to ASTM D256; in one embodiment, the polyester useful in the present invention shows the incision IZ0 (j impact strength is at least (4〇〇) j/m) 7 5 sigh-broken/mile, at 23 °C, using a 10-mil cut, at 3. In a 2 mm (1/8-inch) thick bar, measured according to aSTm D256; in one embodiment, the polyester useful in the present invention exhibits a slit Iz〇d impact strength of at least 1000 J/m ( 18 呎-lb/inch), at 231, using a 1 〇 mil cut 'in a 3 2 mm (1/8-inch) thick bar, measured according to astm D256. In one embodiment, the polyester useful in the present invention exhibits an Izod impact strength of at least 15 〇 J/m (3 呎 lb / ft) at 23. Underarm, using a 10-mil cut in a 6.4 mm (1/4 _ inch) thick bar, measured according to ASTM D256; in one embodiment, can be used in the polyester display of the present invention The impact strength of the incision Izod is at least (4〇〇J/m) 7·5呎-pounds/inch, at 23°c, using a 10-mil cut, at 6. In a 4 mm (1/4-inch) thick bar, measured according to ASTM D256; in one embodiment, the polyester can be used in the present invention to show a cut such as an impact strength of at least (18 square feet /奂忖), at 23 °c, using a 1 〇 Mill cut in I# mm (1/4-inch) thick bars, measured according to ASTMd256. In another embodiment, some of the polyesters useful in the present invention are as 119,732. Doc -252- 200804457 When measured at 〇°C, using the 1〇_Mil cut, in 1/8• inch thick bars, the Izod impact strength measured according to ASTM D256 when measured at 〇°C When compared, 'can increase the incision 1:2〇4 impact strength is at least 3. /〇 or at least 5% or at least 1% or at least 15%. Also, when in the hustle. (: to 3 〇. Under the ΐ, using a 10-Mil cut, in a 1/8_ inch thick bar, when measured according to ASTM D256, some other polyesters can also show the incision Iz〇d The impact strength is within plus or minus 5 〇 / 。. In yet another embodiment, when measured at 23 ° C, using a 10-mil cut 'in a 1/4 • inch thick bar, according to ASTM D256 is measured when compared to the same polyester at the same temperature using a 1 密 mil slit, measured in a 1/8-inch thick bar, and the Izod impact strength is measured according to ASTM D256. Certain polyesters useful in the present invention can be shown to remain in the Izod impact strength of the slit with a loss of no more than 7%. In one embodiment, the polyester of the present invention exhibits superior cuts in thick sections. Toughness. Incision 12〇 (1 impact strength, as described in ASTM D256 is a common method of toughness in the species. When tested by the iz〇d method, the polymer can show either the complete fracture failure mode, #中的测试样破成成成成成成成成成成成成成成成成成成成成成成成成成成成成成成成成成; It remains as a part. The complete fracture failure mode is accompanied by: low damage. Partial and non-fracture failure modes are accompanied by high energy damage: the typical thickness used to measure IZ〇d toughness is 1/8" At this thickness, 聚合; the polymer shows partial or no fracture failure mode, and polycarbonate is a noteworthy example. However, when the thickness of the sample to be tested is increased to 1 M, no commercially available amorphous material is displayed. Partial or no failure mode. 119732. Doc-253 - 200804457 In one embodiment, the composition of the examples of the invention exhibits a fracture-free failure mode when tested using a 1/4" thick sample in Iz〇d. In a particular embodiment The polyester useful in the present invention can exhibit at least one of the following densities: at 23 ° C, the density is less than 1. 3 g / ml; density is lower than 1. 2 g / ml; at 23. Under the armpit, the density is below 1. 18 g / ml; at 23 ° C 'overdue is 0. 70 to 1. 2 g / ml; at 23 ° C, the density is 〇 · 70 to 1 3 g / ml; at 231, the density is 〇 7 〇 to less than ^ g / ml; at 23 ° C 'density is 0. 75 to 1. 2 g / ml; at 23 ° C, the density is 0. 75 to less than 1. 2 g / ml; at 23 ° C, the density is 0. 80 to 1. 2 g / ml; at 23 ° C, the density is 0. 80 to less than 12 g / ml; at 23 ° c, the density is 0. 90 to 1. 2 g / ml; at 23 ° C, the density is 1 · 〇 to 1. 2 g / ml, at 23 ° C, the density is 1 · 〇 to 1.3 g / ml; at 23 ° C, the density is 1. 1 to 1. 2 g / ml; at 23 ° C, the density is from 1.13 to 1. 3 g/ml; at 23 ° C, the density is 丨·;^ to ι·2 g/ml; at 23 ° C, the density is 0. 80 to ι·ΐ8 g/ml; at 23 ° C, the density is 0. 80 to less than 1. 18 g / ml; at 23 ° C, the density is ι·〇 to less than 1. 18 g/ml; at 23 C, the density is less than 118 g/ml. In some embodiments, utilizing the polyester composition's useful in the present invention minimizes and/or eliminates the drying step prior to melt processing and/or thermoforming. In a particular embodiment, the heat stabilizer useful in the present invention may be an organic compound 'e.g., a phosphite containing a _ or undeuterated substituent. The heat stabilizer may comprise a wide range of structurally known compounds, for example, phosphines, phosphites, phosphinates, phosphite diesters, hypophosphites, phosphonic acids 119732. Doc •254- 200804457 Esters, phosphine oxides and phosphates. Examples of the heat stabilizer include tributyl phosphate, triethyl phosphate, tributoxyethyl phosphate, t-butylphenyl diphenyl phosphate, 2-ethylhexyl diphenyl phosphate, ethyl two Methyl phosphate, isodecyl diphenyl phosphate, trilauryl phosphate, triphenyl phosphate, tricresyl phosphate, tris(diphenyl) phosphate, tert-butylphenyl diphenyl phosphate , resorcinol bis(diphenyl phosphate), acid-filled tri-ester, phenyl ethyl linoleic acid, trimethyl thionophosphate, phenylethyl phosphorothioate, Dimethyldecylphosphonate, diethylmethylphosphonate, diethylpentylphosphonate, dilaurylmethylphosphonate, diphenylmethylphosphonate, di-knotylmethyl Phosphonate, diphenyl cresyl phosphonate, dimethyl cresyl phosphonate, dimethyl methyl thiophosphonate, phenyl diphenyl phosphinate, benzyl diphenyl Phosphate ester, methyl diphenyl phosphite, trimethyl phosphine oxide, triphenyl oxidized scale, bis- emulsified scale, 4-methyl diphenyl oxidized lin, sub-filled acid Ester, ethylene. Tributyl succinate, trilauryl linoleate, triphenyl phosphite, sub-sweet vinegar, benzyl sulphate, phenyl dimethyl acetal, benzyl Dimethyl phosphite, dimethylmethylphosphinic acid diester, diethyl amylphosphonate diester, diphenylmethylphosphinic acid diester, di-n-methyl methylphosphinic acid diester , dimethyl phthalic acid phosphinic acid diester, methyl dimethyl phosphinate, methyl diethyl phosphinate, phenyl diphenyl phosphinate, methyl diphenyl Phosphonates, benzyldiphenylphosphinates, triphenylphosphines, trisylphosphines and decyldiphenylphosphines. In one embodiment, triphenylphosphine oxide is excluded as a heat stabilizer in the polyester process useful in the process of the invention and in the polyester compositions of the present invention. 119732. Doc-255 - 200804457 In a specific embodiment, the heat stabilizer useful in the present invention may be any of the phosphorus-based acids previously described, wherein one or more hydrogen atoms of the acid compound (linked to oxygen or phosphorus atoms) It is replaced by an alkyl group, a branched alkyl group, a substituted alkyl group, an alkyl ether, a substituted alkyl ether, an alkyl-aryl group, an alkyl-substituted aryl group, an aryl group, a substituted aryl group, and a mixture thereof. In another embodiment, the heat stabilizer useful in the present invention includes, but is not limited to, the hydrogen atom of at least one of the foregoing compounds bonded to the oxygen atom of the compound is replaced by a metal ion or an ammonium ion. The group contains an alkyl group, a branched alkyl group, a substituted alkyl group, an alkyl ether, an aryl group and/or a substituted aryl group. The esters may also contain at least one alkyl group and at least one aryl group. The number of ester groups present in a particular phosphorus compound can vary from zero up to the maximum allowed based on the number of bases present on the phosphorus compound used. For example, succinic acid may comprise one or more mono-, di-, and tri-alkyl phosphates; the aryl phosphate comprises one or more mono-, di-, and tri-aryl phosphates. Esters; and alkyl phosphates and/or aryl phosphates also include, but are not limited to, mixed alkyl aryl phosphates having at least one alkyl group and one aryl group. In a particular embodiment, the heat stabilizer useful in the present invention comprises, but is not limited to, a sulphuric, aryl or mixed alkyl aryl group of an acid-filled, sub-acidic acid, phosphinic acid, phosphonic acid or phosphonite. Ester or partial ester. The alkyl or aryl group may contain one or more substituents. In one aspect, the fill compound useful in the present invention comprises at least one heat stabilizer 'selected from at least one substituted or unsubstituted alkyl phosphate, substituted or unsubstituted aryl phosphate, Substituted or not taken 119732. Doc-256-200804457 Instead of mixed alkyl aryl phosphates, diphosphites, phosphates, phosphine oxides and mixed arylalkyl phosphites, reaction products thereof and mixtures thereof. The phosphates include esters in which the phosphoric acid has been completely esterified or only partially esterified. In a specific embodiment, for example, the phosphorus compound useful in the present invention may comprise at least one phosphate ester. In one aspect, the phosphorus compound useful in the present invention comprises at least one heat stabilizer selected from at least one substituted or unsubstituted alkyl phosphate, substituted or unsubstituted aryl phosphate, Mixed substituted or unsubstituted alkyl aryl phosphates, reaction products thereof, and mixtures thereof. The phosphates comprise esters in which the phosphoric acid has been fully or only partially esterified. In another embodiment, the phosphorus compounds useful in the present invention may comprise, but are not limited to, selected from at least one alkyl phosphate. Esters, aryl phosphates, mixed alkyl aryl phosphates, reaction products thereof, and mixtures thereof. In certain embodiments, phosphates useful in the present invention are those wherein the group on the phosphate comprises an alkyl group, an alkoxy-alkyl group, a phenyl group or a substituted phenyl group. Such fillers are generally referred to herein as pendant and/or aryl phosphates. Some preferred embodiments include trialkyl phosphates, triaryl phosphates, alkyl diaryl phosphates, dialkyl aryl phosphates, and mixtures of the scallops. The radical group preferably contains from 2 to 12 carbon atoms, and the aryl group is preferably a phenyl group. Representative alkyl and branched alkyl groups are preferably those having from 1 to 12 carbon atoms, including, but not limited to, ethyl, propyl, isopropyl, 119,732. Doc -257- 200804457 Butyl, hexyl, cyclohexyl, 2-ethylhexyl, octyl, decyl and dodecyl. Substituted alkyl groups include, but are not limited to, such alkyl groups containing at least one of the formic acid groups and their esters, hydroxyl groups, amine groups, and ketone groups. Representative alkyl-aryl and substituted alkyl-aryl groups are those wherein the alkyl moiety contains from 1 to 12 carbon atoms and the aryl group is a phenyl or substituted phenyl group, wherein any carbon on the phenyl ring The hydrogen atom at the position is substituted with an alkyl group, a branched alkyl group, an aryl group, a hydroxyl group or the like. Preferred aryl groups include a phenyl group or a substituted phenyl group in which a hydrogen atom at any position on the benzene ring is substituted with an alkyl group, a branched alkyl group, an aryl group, a hydroxyl group or the like. In a specific embodiment, the phosphates useful as heat stabilizers in the present invention include, but are not limited to, dibutyl phenyl phosphate, triphenyl phosphate, tricresyl phosphate, tributyl phosphate, and the like. _2_ethylhexyl phosphate, dioctyl phosphate and/or mixtures thereof, including a specific mixture of tributyl phosphate and xylenol phosphate with isohexadecyl diphenyl phosphate and 2-ethylhexyl a mixture of phenyl phosphates. In a specific embodiment, the phosphates useful as heat stabilizers in the present invention include, but are not limited to, at least one of the following: trialkylphosphoric acid S, triaryl phosphate, alkyl diaryl Phosphates and mixed alkyl aryl phosphates. In a specific embodiment, the linonic acid which is useful as a heat stabilizer in the present invention includes, but is not limited to, at least one of the following substances: triterpenoids, alkane & diaryl phosphate Classes and mixed alkyl aryl phosphates. The serotonic acid S which can be used in the present invention as a heat stabilizer in the present invention includes, but is not limited to, at least one of the following: arylene phosphate 119732. Doc -258- 200804457 Esters and mixed alkyl aryl phosphates. In a specific embodiment, at least one heat stabilizer useful in the present invention includes, but is not limited to, triaryl phosphates such as triphenyl phosphate. In a specific embodiment, the at least one heat stabilizer comprises, but is not limited to, Merpol A. In one embodiment, at least one of the thermal stabilizers useful in the present invention comprises, but is not limited to, triphenyl acid g and at least one of Merpol A. Merpol A is commercially available from Stepan Chemicals and/or DuPont. The CAS registration number for Merpol A is CAS Registry # 37208-27-8. In a particular embodiment, the polyester compositions and/or methods of the present invention may comprise 2-ethylhexyl-monophenyl vinegar. In a specific embodiment, the phosphorus compound useful in the present invention comprises, but is not limited to, at least one diphosphite. In a specific embodiment, the phosphorus compound useful in the present invention comprises, but is not limited to, at least one diphosphite comprising 2,4,8,1〇-tetraoxo-3,9-diphosphorus [ 5. 5] Undecane structure, for example, West〇n 619 (GE Specialized Chemicals, CAS# 3806-34-6) and / or Doverph〇s s_9228 (D〇veMb, CAS# 154862-43-8). In a specific embodiment, the phosphorus compound useful in the present invention comprises at least one phosphine oxide. In a specific embodiment, the ruthenium compound useful in the present invention comprises at least one mixed alkyl aryl phosphite 'for example, bis(2,4-cumylphenyl)pentaerythritol di succinic acid vinegar' Known as Doverph〇s 8_9228 (〇_ chemical, CAS # 154862_43·8). 119732. Doc-259-200804457 In a specific embodiment, the method for making the polycool composition and/or polyester described in any of the description herein comprises at least one phosphorus compound as described in the specification. In a specific embodiment, any of the methods described in the specification for making the poly-composition and/or polyester may comprise at least one diphosphite. In a specific embodiment, any of the methods described in the specification for making any of the polyester compositions and/or polyesters can comprise at least one diphosphite vinegar comprising 2, 4, 8, 10-tetracaine Base-3,9_diphosphorus snail [5. 5] Undecane structure, such as Weston 619 (GE Specialty Chemicals, cAS# 3806-34_6) and / or Doverphos S-9228 (Dover Chemical, CAS # 154862-43-8). In a specific embodiment ♦, any of the methods described in the specification for making any of the polyester compositions and/or polyesters can comprise at least one phosphine oxide. In a specific embodiment, any of the methods described in the specification for making any of the polyester compositions and/or polyesters can comprise at least one mixed alkyl ary phosphite, for example, bis (2, 4) _Phenylphenylphenyl)pentaerythritol monophosphite g is known as Doverphos S_9228 (Dover Chemical, CAS # 154862-43-8). The polyester composition of the present invention and/or the method of producing the polyester composition may contain a heat stabilizer. The term "π heat stabilizer" is intended to include the reaction product. Although the term "heat stabilizer" is used throughout the specification, the invention is not intended to be limited by any particular theory of operation. Used in connection with the heat stabilizer of the present invention, Gentleman H9732. Doc • 260· 200804457 Reaction Product 4—(四) means any polycondensation or acetification reaction product between the heat stabilizer and any monomer used to make the polyacetate and the polymerization of the catalyst and any other type of additive Condensation or _ reaction product. When phosphorus is added to the method of producing the polyester and/or polyester composition and/or polyester of the present invention, it is added in the form of a scaly compound described herein, for example, at least one diphosphite, at least one Phosphate and the like. The amount of phosphorus compound (e.g., at least one diphosphite) added to the polyester of the present invention and/or the polyester composition of the present invention and/or the method of the present invention may be present in the form of a phosphorus atom in the final polyester. Measure, for example, by weight. The heat stable dose added during the 1st reaction or the subsequent manufacturing process may include, but is not limited to, 1 to 5000 Ppm; 1 to 1000 ppm; 1 to 9 ppm ppm '1 to 800 ppm; 1 to 700 ppm·1 Up to 600 ppm; 1 to 500 ppm, 1 to 400 ppm; 1 to 350 ppm; 1 to 300 ppm; 1 to 250 ppm, 1 to 200 ppm; 1 to 150 ppm; 1 to 100 ppm; 10 to 5000 ppm, 10 To 1〇〇〇ppm; 1〇 to 9〇〇ppm; 1〇 to 800ppm; 10 to 700 ppm; 10 to 600 ppm; 10 to 500 ppm; 10 to 400 ppm; 10 to 350 ppm; 10 to 300 ppm 10 to 250 ppm; 10 to 200 ppm; 10 to 150 ppm; 10 to 100 ppm based on the total weight of the polyester composition. In one embodiment, the amount of the phosphorus compound (eg, diphosphite, phosphate, etc.) of the present invention added during the polymerization is selected from the range of from 1 to 5000 ppm; from 1 to 1 ppm; 1 to 900 ppm; 1 to 800 ppm; 1 to 700 ppm; 1 to 600 ppm; 1 to 500 ppm; 1 to 400 ppm; 1 to 350 ppm; 1 to 300 ppm; 1 to 250 ppm; 1 to 200 ppm; 1 to 150 ppm; 1 to 100 ppm; 1 to 60 ppm; 2 to 5000 119,732. Doc -261- 200804457 ppm ; 2 to 1000 ppm ; 2 to 900 ppm ; 2 to 800 ppm ; 2 to 700 ppm ; 2 to 600 ppm ; 2 to 500 ppm ; 2 to 400 ppm ; 2 to 350 ppm ; 2 to 300 2 to 250 ppm; 2 to 200 ppm; 2 to 150 ppm; 2 to 100 ppm; 2 to 60 ppm; 2 to 20 ppm; 3 to 5000 ppm; 3 to 1000 ppm; 3 to 900 ppm; 3 to 800 Ppm; 3 to 700 ppm.  3 to 600 ppm ; 3 to 500 ppm ; 3 to 400 ppm ; 3 to 300 ppm ; 3 to 250 ppm ; 3 to 200 ppm ; 3 to 150 ppm ; 3 to 100 ppm ; 3 to 60 ppm ; 3 to 20 ppm ; 4 to 5000 ppm ; 4 to 1000 ppm ; 4 to 800 ppm ; 4 to 700 ppm ; 4 to 600 ppm ; 4 to 500 ppm ; 4 to 400 ppm ; 4 to 350 ppm ; 4 to 300 ppm ; 4 to 250 ppm ; 4 to 200 ppm ; 4 to 100 ppm ; 4 to 60 ppm ; 4 to 20 ppm ; 5 to 5000 ppm ; 5 to 1000 ppm ; 5 to 900 ppm ; 5 to 800 ppm ; 5 to 700 ppm ; 5 to 600 ppm ; 5 to 400 ppm ; 5 to 350 ppm ; 5 to 300 ppm ; 5 to 250 ppm ; 5 to 200 ppm ; 5 to 150 ppm ; 5 to 100 ppm ; 5 to 60 ppm ; 5 to 20 ppm ; 6 to 5000 ppm ; 6 to 1000 ppm ; 6 to 900 ppm ; 6 to 800 ppm ; 6 to 700 ppm ; 6 to 600 ppm ; 6 to 500 ppm ; 6 to 400 ppm; 6 to 350 ppm; 6 to 300 ppm; 6 to 250 ppm; 6 to 200 ppm; 6 to 150 ppm; 6 to 100 ppm; 6 to 60 ppm; 6 to 20 ppm 7 to 5000 ppm ; 7 to 1000 ppm ; 7 to 900 ppm ; 7 to 800 ppm ; 7 to 700 ppm ; 7 to 600 ppm ; 7 to 500 ppm ; 7 to 400 ppm ; 7 to 350 ppm ; 7 to 300 ppm ; 7 to 250 ppm; 7 JL 200 ppm; 7 to 150 ppm; 7 to 100 ppm; 7 to 60 ppm; 7 to 20 ppm; 8 to 5000 119732. Doc •262- 200804457 8 to 1000 ppm; 8 to 600 ppm; 8 to 300 ppm; 8 to 100 ppm; 9 to 1000 ppm; 9 to 600 ppm; 9 to 300 ppm; 9 to 100 ppm; ppm ppm ppm ppm ppm Ppm ppm ppm 8 to 900 ppm; 8 to 800 ppm; 8 to 700 8 to 500 ppm; 8 to 400 ppm; 8 to 350 8 to 250 ppm; 8 to 200 ppm; 8 to 150 8 to 60 ppm; 8 to 20 Ppm; 9 to 5000 9 to 900 ppm; 9 to 800 ppm; 9 to 700 9 to 500 ppm; 9 to 400 ppm; 9 to 350 9 to 250 ppm; 9 to 200 ppm; 9 to 150 9 to 60 ppm; To 20 ppm ; 10 to 5000 ppm 10 to 1000 ppm ; 10 to 900 ppm 700 ppm ; 10 to 600 ppm ; 10 to 500 ppm ; 10 to 400 ppm ; 10 to 350 ppm ; 10 to 300 ppm ; 10 to 250 ppm ; 10 to 200 ppm; 10 to 150 ppm; 10 to 100 ppm; 10 to 60 ppm; 10 to 20 ppm; 50 to 5000 ppm; 50 to 1000 ppm; 50 to 900 ppm; 50 to 800 ppm; 50 to 700 ppm; 50 to 600 ppm; 50 to 500 ppm; 50 to 400 ppm; 50 to 350 ppm; 50 to 300 ppm; 50 to 250 ppm; 50 to 200 ppm; 50 to 150 ppm; 50 to 100 ppm; 50 to 80 ppm; 1 00 to 5000 ppm; 100 to 1000 ppm; 100 to 900 ppm; 100 to 800 ppm; 100 to 700 ppm; 100 to 600 ppm; 100 to 500 ppm; 100 to 400 ppm; 100 to 350 ppm; 100 to 300 ppm; 100 to 250 ppm; 100 to 200 ppm; 100 to 150 ppm; 150 to 5000 ppm; 150 to 1000 ppm; 150 to 900 ppm; 150 to 800 ppm; 150 to 700 ppm; 150 to 600 ppm; 150 to 500 ppm; 150 to 400 ppm; 150 to 350 ppm; 150 to 300 ppm; 150 to 250 ppm; 150 to 200 ppm; 200 to 5000 ppm; 200 to 1000 ppm; 200 to 900 ppm ; 200 to 800 ppm ; 200 to 700 ppm ; 200 to 600 ppm ; 200 to 400 ppm ; 200 to 350 ppm ; 200 to 300 ppm ; 200 to 250 ppm ; 250 to 5000 ppm ; 250 to 1000 ppm ; 250 to 900 ppm ; 250 to 800 ppm ; 250 to 700 ppm ; 250 to 600 ppm ; 250 to 500 ppm ; 250 to 400 ppm ; 250 to 350 ppm ; 250 to 300 ppm ; 500 to 5000 ppm; 300 to 1000 ppm; 3 00 to 900 ppm; 300 to 800 ppm; 300 to 700 ppm; 300 to 600 ppm; 300 to 500 ppm; 300 to 400 ppm; 300 to 350 ppm; Ppm; 350 to 1000 ppm; 350 to 900 ppm; 350 to 800 ppm; 350 to 700 ppm; 350 to 600 ppm; 350 to 500 ppm; 350 to 400 ppm; based on the total weight of the polyester composition and the final polyester The atomic form of phosphorus is measured. The invention further relates to polymer blends. The blend comprises: (a) from 5 to 95% by weight of at least one of the above polyesters; and (b) from 5 to 95% by weight of at least one polymeric component. Suitable examples of polymeric components include, but are not limited to, nylon, polyesters different from those described herein, polyamines such as ZYTEL® from DuPont; polystyrene, polystyrene copolymers, styrene acrylonitrile copolymerization , acrylonitrile butadiene styrene copolymer, poly(methyl methacrylate), acrylic copolymer, poly(ether-quinone imine), such as ULTEM® (poly(ether-imine)) From General Electric Company; polyphenylene ethers, such as poly(2,6-dimethylphenyl ether), or poly(phenylene ether)/polystyrene blends, such as NORYL 1000® (poly(2,6-) a mixture of dimethyl phenyl ether and polystyrene resin, available from General Electric Company; polyphenylene sulfide; polyphenylene sulfide/indole; poly(ester-carbonate 119732. Doc -264- 200804457 vinegar); polycarbonates such as LEXAN® (polycarbonate, available from General Electric Company); polyfluorenes; polyether ethers; and aromatic dihydroxy compounds (3⁄4-ketones) Or a mixture of any of the foregoing polymers. Blends can be made by conventional processing techniques known in the art, such as melt blending or solution blending. In one embodiment, the polycarbonate is not present in the polyester composition. If the polycarbonate is used in a blend that can be used in the polyester compositions of the present invention, the blend can be visually clear. However, the polyester compositions useful in the present invention are also intended to encompass the exclusion of polycarbonate, as well as the incorporation of polycarbonate. The polycarbonates useful in the present invention can be prepared according to known procedures, for example, by subjecting a dimeric aromatic compound to a carbonate precursor, such as phosgene, dentate or carbonate, molecular weight regulators, acid accepting The agent and the catalyst are reacted together. Processes for the preparation of the polyoxalates are known in the art and are described, for example, in U.S. Patent 4,452,933, the disclosure of which is incorporated herein by reference. Examples of suitable carbonate precursors include, but are not limited to, cesium bromide, cesium chloride or mixtures thereof; diphenyl carbonate; bis(phenyl)carbonate, such as bis(trichlorobenzene) carbonate, carbonic acid (tribromophenyl)ester; bis(alkylphenyl)carbonate, such as di(toluene) carbonate; di(naphthalene) carbonate; di(chlorophenyl) hydrazine or a mixture thereof; Double _ carboxylic acid vinegar. Examples of suitable molecular weight regulators include, but are not limited to, phenol, cyclohexanol, methanol, alkylated phenols such as octylphenol, p-third-butyl phenol, and the like. In a specific embodiment, the molecular weight modifier is a phenol or an alkylated phenol. The acid acceptor can be either an organic or inorganic acid acceptor.适#有(四) 119732. Doc -265 · 200804457 The borne agent can be a tertiary amine and includes, but is not limited to, some substances such as pyr::3-triethylamine, xylylamine, tributylamine, and the like. The inorganic acid acceptor may be a hydroxide, carbonate or bicarbonate phosphate which is free of alkali metal or alkaline earth metal. Catalyst 5 Catalysts useful in the manufacture of polycarbonates useful in the present invention include, but are not limited to, those which typically aid in the polymerization of monomers with phosgene. Suitable catalyst package 2, but not limited to tertiary amines, such as triethylamine, tripropylamine, n, n-dimethylaniline, quaternary ammonium compounds, such as tetraethylammonium bromide, cetyl triethylammonium bromide, iodine Tetra-n-heptyl ammonium, desertified tetra-n-propyl ammonium, tetramethyl chlorinated acid, tetramethyl sulphate, Wei Sizheng, butyl, chloro-trimethylammonium, and Grade scale compounds, such as desertification. Butyl triphenyl scales and sulphate methyltriphenyl scales. It can be used in the polyacetate composition of the present invention, and can also be known as a copolymerized vinegar carbon I, as described in U.S. Patent Nos. 3,169,121, 3,207,814, 4,156,069, 4,430,484, 4,465,820, 4,981,898, wherein The disclosure of copolymerized vinegar carbonates from various U.S. patents is incorporated herein by reference. Copolymeric carbonates useful in the present invention can be prepared commercially and/or can be prepared by methods known in the art. For example, it is typically emulsified by at least one dihydroxy aromatic compound with phosgene and at least one dicarboxylic acid chloride, bismuth oxime, by vaporization of benzoic acid or by a combination of both. obtain. Further, the polyester vinegar composition and the polymer conjugate composition which can be used in the present invention may also contain 〇〇1 to 25% by weight of the total weight of the vinegar composition. Doc -266 - 200804457 Additives such as colorants, dyes, mold release agents, flame retardants, plasticizing nucleating agents, stabilizers, including but not limited to uv stabilizers, thermal stabilizers and / or their reaction products, Filler and impact modifier. Examples of typical commercially available impact modifiers known in the art and useful in the present invention include, but are not limited to, ethylene/propylene terpolymers; functionalized polyolefins such as decyl acrylate and / or glycidyl methacrylate, styrene block copolymerization impact modifier; and various acrylic core / shell type impact modifier. It is also intended to cover the residues of such additives as part of the polyester composition. Reinforcing materials can be used in the compositions of the present invention. Reinforcing materials may include, but are not limited to, carbon filaments, niobium, mica, clay, talc, titanium dioxide, shisha, glass flakes, glass beads and fibers, and polymeric fibers, and combinations thereof. In one embodiment, the reinforcing material comprises glass, such as glass fiber filaments, glass and talc, glass and mica, and a mixture of glass and polymeric fibers. Suitable catalysts for use in the process of the invention to make polyesters useful in the present invention comprise at least one tin compound. The polyester composition of the present invention may also comprise at least one tin compound useful in the process of the present invention. Other catalysts may include, but are not limited to, titanium, gallium, ruthenium, ruthenium, ruthenium, magnesium, osmium, and aluminum compounds and aluminum compounds with lithium hydroxide or sodium hydroxide. In one embodiment, the catalyst can be a combination of at least one tin compound and at least one titanium compound. The amount of catalyst can range from 10 ppm to 20,000 ppm or 10 to 10,000 ppm, or 10 to 5000 ppm or 10 to 1000 ppm or 10 to 500 119732. Doc -267· 200804457 ppm, or l〇 to 300卯 or (7) to ❻, based on the catalyst metal and based on the weight of the final polymer. This method can be done in either batch or continuous methods. In one embodiment, the catalyst is a tin compound. In one embodiment, the catalyst is a separate tin compound. In a specific embodiment, the tin compound can be used in an esterification reaction or a polycondensation reaction or both. In another embodiment, the catalyst is a separate tin compound that can be used in the polyester in the esterification reaction. In general, in one embodiment, the tin compound catalyst is about 0. 005% to about 0. It is used in an amount of 2% based on the total weight of the dicarboxylic acid or dicarboxylic acid ester. In general, in one embodiment, only less than about 7 〇〇 ppm of elemental tin is present as a residue in the polyester, based on the total weight of the polyester. When tin is added to the method of producing the polyester and/or polyester composition and/or polyester of the present invention, it is added in the form of a tin compound as described herein. The amount of the tin compound added to the polyester of the present invention and/or the polyester composition of the present invention and/or the method of the present invention may be measured in the form of a tin atom present in the final polyester, for example, by weight ppm. In another embodiment, the catalyst is used in the esterification reaction as a single tin compound in an amount from 1 ppm to 2 Torr, 〇〇〇 ppm; or from 1 10,000 to 10,000 ppm; or from 1 〇 to 5 〇〇. 〇ppm; or 10 to 4500 ppm; or 10 to 4000 ppm; or 1 to 3500 ppm; or 10 to 3000 ppm; or 1 to 2500 ppm; or 1 to 2000 ppm; or 1 to 1500 ppm; 1〇 to 1000 ppm; or 1〇 to 5〇〇ppm; or 10 to 300 ppm; or 10 to 250 ppm; or 15 ppm to 20,000 ppm; or 15 to 10,000 ppm; or 15 119732. Doc -268- 200804457 to 5000 ppm; or 15 to 4500 ppm; or 15 to 40 00 ppm; or 15 to 3500 ppm; or 15 to 3000 ppm; or 15 to 2500 ppm; or 15 to 2000 ppm; or 15 to 1500 Pppm; or 15 to 1000 ppm; or 15 to 500 ppm; or 15 to 400 ppm; or 15 to 300 ppm; or 15 to 250 ppm; or 20 ppm to 20,000 ppm; or 20 to 10,000 ppm; or 20 to 5000 ppm Or 20 to 4500 ppm; or 20 to 4000 ppm; or 20 to 3500 ppm; or 20 to 3000 ppm; or 20 to 2500 ppm; or 20 to 2000 ppm; or 20 to 1500 ppm; or 20 to 1000 ppm; 20 to 500 ppm; or 20 to 300 ppm; or 20 to 250 ppm; or 25 ppm to 20. 000 ppm ; or 25 to 10,000 ppm ; or 25 to 5000 ppm ; or 25 to 4500 ppm ; or 25 to 4000 ppm ; or 25 to 3500 ppm ; or 25 to 3000 ppm ; or 25 to 2500 ppm ; or 25 to 2000 ppm Or 25 to 1500 ppm; or 25 to 1000 ppm; or 25 to 500 ppm; or 25 to 400 ppm; or 25 to 300 ppm; or 25 to 250 ppm; or 30 ppm to 20. 000 ppm; or 30 to 10,000 ppm; or 30 to 5000 ppm; or 30 to 4500 ppm; or 30 to 4000 ppm; or 30 to 3500 ppm; or 30 to 3000 ppm; or 30 to 2500 ppm; or 30 to 2000 ppm Or 30 to 1500 ppm; or 30 to 1000 ppm; or 30 to 500 ppm; or 30 to 300 ppm; or 30 to 250 ppm; or 35 ppm to 20,000 ppm; or 35 to 10. 000 ppm,; or 35 to 5000 ppm; or 35 to 4500 ppm; or 35 to 4000 ppm; or 35 to 3500 ppm; or 35 to 3000 ppm; or 35 to 2500 ppm; or 35 to 2000 ppm; or 35 to 1500 Pppm; or 35 to 1000 ppm; or 35 to 500 ppm; or 35 to 300 ppm; or 35 to 250 ppm; or 40 ppm to 20,000 ppm; or 40 to 10,000 ppm; or 40 119,732. Doc -269· 200804457 to 5000 ppm; or 40 to 4500 ppm; or 40 to 4000 ppm; or 40 to 3500 ppm; or 40 to 3000 ppm; or 40 to 2500 ppm; or 40 to 2000 ppm; or 40 to 1500 ppm Or 40 to 1000 ppm; or 40 to 500 ppm; or 40 to 300 ppm; or 40 to 250 ppm; or 40 to 200 ppm; or 45 ppm to 20,000 ppm; or 45 to 10,000 ppm, or 45 to 5000 ppm Or 45 to 4500 ppm; or 45 to 4000 ppm; or 45 to 3500 ppm; or 45 to 3000 ppm; or 45 to 2500 ppm; or 45 to 2000 ppm; or 45 to 1500 ppm; or 45 to 1000 ppm; 45 to 500 ppm; or 45 to 300 ppm; or 45 to 250 ppm; or 50 ppm to 20,000 ppm; or 50 to 10,000 ppm, or 50 to 5000 ppm; or 50 to 4500 ppm; or 50 to 4000 ppm; 50 to 3500 ppm; or 50 to 3000 ppm; or 50 to 2500 ppm; or 50 to 2000 ppm; or 50 to 1500 ppm; or 50 to 1000 ppm; or 50 to 500 ppm; or 50 to 300 ppm; or 50 to 250 ppm; or 50 to 200 ppm; or 50 to 150 ppm; or 50 to 125 ppm; based on the total weight of the polyester composition and based on the tin in the final polyester Atomic form measurement. In one embodiment, the polyester of the present invention can be prepared using at least one tin compound as a catalyst. For example, the disclosure of the tin catalyst is described in U.S. Patent No. 2,720,507, the disclosure of which is incorporated herein by reference. These catalysts are tin compounds containing at least one organic group. The catalysts simultaneously comprise a divalent or tetravalent tin compound having the following general formula: A.  M2(Sn(OR)4) B.  MH(Sn(OR)4) 119732. Doc -270- 200804457 c.  Mf(Sn(OR)4) D.  Mf(HSn(OR)4)2 E.  M2(Sn(OR)6) F.  MH(Sn(OR)6) G.  Mf(Sn(OR)6) H.  Mf(HSn(OR)6)2 I.  Sn(OR)2 J.  Sn(OR)4 K.  SnR, 2 L.  SnR, 4 M.  R, 2SnO Ν·

Q· 119732.doc -271 - 200804457 R OAcQ· 119732.doc -271 - 200804457 R OAc

V 〆 'OAc 其中M為鹼金族金屬，例如鋰、鈉或鉀；為鹼土族金 屬，例如Mg、Ca或Sr ;每個R代表含有1至8個碳原子之烷 基；每個R’代表選自由含有1至8個碳原子之烷基（即，r基 團）及含有6至9個碳原子之苯系芳基（即，苯基、曱苯基、 苄基及苯乙基等基團）所組成之取代基；及AC代表衍生自 含有2至18個碳原子之醯基（即，乙醯基、丁醯基、月桂醯 基、苯甲醯基及硬脂醯基等）。 新穎雙金屬烧氧化物催化劑可如Meerwein，Ann. 476, 113 (1929)所述般製造。如同Me er we in所顯示，此等催化 劑不僅僅只是兩種金屬烧氧化物之混合物，而係具有似鹽 結構之明確化合物，即，前述化學式A至Η所描述之化合 物。Meerwein所未明確敘述者可由近似於Meerwein所提出 之實施例及方法之程序製備。 其他錫化合物亦可以如同下列文章中所描述之各種方法 製得： 關於二芳基二鹵化錫（化學式P)之製備，參見Ber. 62, 996 (1929); J. Am. Chem. Soc. 49, 1369 (1927)。關於二烷 基二鹵化錫（化學式p)之製備，參見J· Am· Chem. Soc. 47, 2568 (1925) ; C.A· 41，90 (1947)。關於二芳基二氧化錫（化 學式 M)之製備，參見 j Am. Chem· Soc. 48，1054 (1926)。 關於四芳基錫化合物（化學式κ)之製備，參見C.A. 32, 5387 119732.doc -272- 200804457 (1938)。關於烷氧錫（化學式J)之製備，參見C.A. 24，586 (1930)。關於烷基錫鹽（化學式Q)之製備，參見CA. 31， 4290。關於烷基錫化合物（化學式K及L)之製備，參見C.A. 35, 2470 (1941): C.A· 33, 5357 (1939)。關於混合烷基芳基 錫（化學式K及L)之製備，參見C.A· 31，4290 (1937): C.A. 3 8，33 1 (1944)。關於其他未被該等文獻涵蓋之錫化合物， 參見 Krause 及 V. Grosse 之 ’’Die Chemie der Metal-Organischen Verbindungen·丨’文章，Gebroder-Borntrager於 1937年公開於柏林。 烷氧錫（化學式I及J)及雙金屬烷氧化物（化學式A至Η)含 有複數個R取代基，其可代表直鏈及支鏈烷基兩者，例如 二乙氧基、四甲氧基、四丁氧基、四-第三-丁氧基及四己 氧基等。 烷基衍生物（化學式Κ及L)含有一或多個經由直接c-Sn鍵 結連接至錫原子之烷基，例如二丁基錫、二己基錫、四丁 基錫、四乙基錫、四甲基錫及二辛基錫等。四烷基基團中 之兩者可以一個氧原子取代以形成具有化學式Μ之化合 物，例如二甲基氧化錫、二乙基氧化錫、二丁基氧化錫及 二庚基氧化錫等。於一具體實施例中，催化劑包含二甲基 氧化錫。 可藉由使一烧基氧化錫與驗金屬燒氧化物於醇溶液反應 形成錯合物（例如使二丁基氧化錫與乙氧基鈉反應等），從 而形成具有化學式Ν之化合物，此等化合物特別適合做為 催化劑使用。此化學式意欲代表所述反應產物。含有烧基 119732.doc -273 - 200804457 及烷氧基之錫化合物亦為有用之催化劑（參見化學式〇)， 例如，二乙氧基二乙基錫、二丁氧基二丁基錫及二曱氧基 二己基錫等。 衍生自二烧基氧化錫與羧酸或氫氯酸反應之鹽亦特別具 有作為催化劑之價值，參見化學式Ρ及Q。此等催化性縮合 劑包括二醋酸二丁基錫、二丁酸二乙基錫、二月桂酸二丁 基錫、二苯甲酸二甲基錫、二丁基二氯化錫、二乙基二氯 化錫、二辛基二氯化錫及二硬脂酸二己基錫等。 可製備其中一或多個R，基團代表苯系芳基（例如，苯 基甲本基及下基專）之具有化學式K、L及Μ之錫化合 物。舉例言之，二苯基錫、四苯基錫、二苯基二丁基錫' 一甲笨基二乙基錫、二苯基氧化錫、二节基錫、四苄基 錫、一（Β-苯基乙基）氧化錫及二苄基氧化錫等。 可用於本發明之催化劑包含，但不限於，一或多個以下 物貝·參-2-乙基己酸丁基錫、二醋酸二丁基錫 '二丁基氧 化錫及二甲基氧化錫。 土 ，但不 二醋酸 於一具體實施例中，可用於本發明之催化劑包含 限於’-或多個以下物質··參_2•乙基己酸丁基錫、 二丁基錫、二丁基氧化錫及二甲基氧化錫。 使用基於錫之催化劑來製備聚醋之方法已為人廣泛知 心，且係記載於前述美國專利2,720,507中。 可用於本發明之聚酯組合物之聚酯部份 已知之方法製成，例如藉由在均相溶液中 熔融體中之酯交換方法，及藉由兩相界面 ’可藉由文獻上 之方法，藉由在 方法。適當方法 119732.doc •274· 200804457 包括但不限於使一或多種二羧酸類與一或多種二醇類，在 100C至315°c之溫度下，於0.1至76〇毫米Hg之壓力下反應 之步驟’歷經足以形成聚酯之時間。參閱美國專利 3,772,405，關於製造聚酯之方法，關於此種方法之揭示内 容係據此併於本文供參考。 如同美國專利2,720,507中所進一步揭示，聚酯一般而言 可藉由將二羧酸或二羧酸酯與二醇在本文中所述之錫催化 劑之存在下，於一高溫下（其在縮合期間逐漸升高至高達 約225 C至310°C )及一惰性氛圍中縮合，且在縮合反應後 期使縮合反應在低壓下進行，其揭示内容係據此併於本文 供參考。 於另一方面，本發明係關於一種製造本發明共聚酯之方 法。於一具體實施例中，該方法關於製造包含對苯二甲 酉夂、2,2,4,4-四甲基_1，3_環丁二醇及ι，4-環己烧二曱醇之共 聚酯。該方法包含下列步驟： (A) 將包含可用於本發明聚酯之單體之混合物，於至少一 種錫催化劑存在下，在150至250°C之溫度下加熱，歷 經足以產生最初聚酯之時間； (B) 藉由在230至320°C之溫度下加熱1至6小時以聚縮合步 驟（A)之最初聚醋；及 (C) 移除任何未反應之二醇類。 於一具體實施例中，該方法關於製造包含對苯二甲酸、 2,2,4,4-四曱基-1，3-環丁二醇及1，4-環己烧二甲醇之共聚 酯，其包含下列步驟： 119732.doc -275- 200804457 (A)將包含可用於本發 種錫催化劑存在下 明聚酯之單體之混合物，於至少一 在150至240°C之溫度下加熱，歷V 〆 'OAc wherein M is an alkali gold group metal such as lithium, sodium or potassium; is an alkaline earth metal such as Mg, Ca or Sr; each R represents an alkyl group having 1 to 8 carbon atoms; each R' Representing a benzene-based aryl group selected from an alkyl group having 1 to 8 carbon atoms (i.e., an r group) and having 6 to 9 carbon atoms (i.e., phenyl, anthracenylphenyl, benzyl, and phenethyl) a substituent consisting of a group; and AC representing a thiol group derived from 2 to 18 carbon atoms (i.e., an ethyl group, a butyl group, a lauryl group, a benzamidine group, a stearyl group, etc.). Novel bimetallic calcined oxide catalysts can be made as described by Meerwein, Ann. 476, 113 (1929). As shown by Me er we in, these catalysts are not only a mixture of two metal oxide oxides, but a compound having a salt-like structure, that is, the compounds described in the above Chemical Formulas A to 。. Those not explicitly recited by Meerwein may be prepared by procedures analogous to the examples and methods set forth by Meerwein. Other tin compounds can also be prepared as described in the following articles: For the preparation of diaryltin dihalide (chemical formula P), see Ber. 62, 996 (1929); J. Am. Chem. Soc. 49 , 1369 (1927). For the preparation of a dialkyltin dihalide (chemical formula p), see J. Am. Chem. Soc. 47, 2568 (1925); C.A. 41, 90 (1947). For the preparation of diaryltin dioxide (chemical formula M), see j Am. Chem. Soc. 48, 1054 (1926). For the preparation of the tetraaryltin compound (chemical formula κ), see C.A. 32, 5387 119732.doc-272-200804457 (1938). For the preparation of alkoxy tin (Formula J), see C.A. 24,586 (1930). For the preparation of alkyl tin salts (chemical formula Q), see CA. 31, 4290. For the preparation of alkyl tin compounds (chemical formulas K and L), see C.A. 35, 2470 (1941): C.A. 33, 5357 (1939). For the preparation of mixed alkyl aryl tins (chemical formulas K and L), see C.A. 31, 4290 (1937): C.A. 3 8,33 1 (1944). For other tin compounds not covered by such literature, see Krause and V. Grosse's ''Die Chemie der Metal-Organischen Verbindungen·丨' article, published by Gebroder-Borntrager in Berlin in 1937. The alkoxy tins (chemical formulas I and J) and the double metal alkoxides (chemical formula A to oxime) contain a plurality of R substituents which may represent both linear and branched alkyl groups, such as diethoxy, tetramethoxy Base, tetrabutoxy, tetra-tert-butoxy and tetrahexyloxy. Alkyl derivatives (chemical formulas and L) contain one or more alkyl groups attached to a tin atom via a direct c-Sn linkage, such as dibutyltin, dihexyltin, tetrabutyltin, tetraethyltin, tetramethyltin And dioctyl tin and so on. Both of the tetraalkyl groups may be substituted with one oxygen atom to form a compound having the formula ,, such as dimethyl tin oxide, diethyl tin oxide, dibutyl tin oxide, and diheptyl tin oxide. In one embodiment, the catalyst comprises dimethyl tin oxide. A compound having a chemical formula can be formed by reacting a calcined tin oxide with a metal oxide oxide in an alcohol solution to form a complex (for example, reacting dibutyltin oxide with sodium ethoxide). The compounds are particularly suitable for use as catalysts. This chemical formula is intended to represent the reaction product. A tin compound containing a thiol group 119732.doc -273 - 200804457 and an alkoxy group is also a useful catalyst (see chemical formula), for example, diethoxydiethyltin, dibutyltin dibutyltin and dimethoxyl Dihexyltin and the like. Salts derived from the reaction of a dialkyltin oxide with a carboxylic acid or hydrochloric acid are also particularly useful as catalysts, see the chemical formulas Q and Q. Such catalytic condensing agents include dibutyltin diacetate, diethyltin dibutylate, dibutyltin dilaurate, dimethyltin dibenzoate, dibutyltin dichloride, diethyltin dichloride, Dioctyltin dichloride and dihexyltin distearate. Tin compounds of the formulae K, L and hydrazine may be prepared in which one or more R groups represent a phenyl aryl group (e.g., a phenylmethyl group and a lower group). For example, diphenyltin, tetraphenyltin, diphenyldibutyltin'-monophenyldiethyltin, diphenyltin oxide, di-n-butyltin, tetrabenzyltin, one (Β-benzene) Base ethyl) tin oxide and dibenzyl tin oxide. Catalysts useful in the present invention include, but are not limited to, one or more of the following salts of butyltin-2-ethylhexanoate, dibutyltin diacetate, dibutyltin oxide, and dimethyltin oxide. Soil, but not diacetic acid In a specific embodiment, the catalyst useful in the present invention is limited to '- or more of the following substances · · _2 ethyl butyl hexanoate, dibutyl tin, dibutyl tin oxide and two Methyl tin oxide. The use of tin-based catalysts for the preparation of polyesters is well known and is described in the aforementioned U.S. Patent 2,720,507. The polyester portion of the polyester composition of the present invention can be produced by a known method, for example, by a transesterification method in a melt in a homogeneous solution, and by a two-phase interface 'by the method of the literature With the method. Suitable methods 119732.doc • 274· 200804457 include, but are not limited to, reacting one or more dicarboxylic acids with one or more glycols at a temperature of from 100 C to 315 ° C at a pressure of from 0.1 to 76 mm Hg The step 'has experienced a time sufficient to form the polyester. See U.S. Patent No. 3,772,405, the disclosure of which is incorporated herein by reference. As further disclosed in U.S. Patent No. 2,720,507, the polyester can generally be obtained by the use of a dicarboxylic acid or a dicarboxylic acid ester with a diol in the presence of a tin catalyst as described herein at a high temperature (which is during condensation). The condensation is gradually increased up to about 225 C to 310 ° C) and the condensation is carried out in an inert atmosphere, and the condensation reaction is carried out at a low pressure in the late stage of the condensation reaction, the disclosure of which is hereby incorporated by reference. In another aspect, the invention is directed to a method of making a copolyester of the invention. In one embodiment, the method relates to the manufacture of terephthalic acid, 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and ι,4-cyclohexanol Copolyester. The method comprises the steps of: (A) heating a mixture comprising monomers useful in the polyester of the invention in the presence of at least one tin catalyst at a temperature of from 150 to 250 ° C for a period of time sufficient to produce the original polyester (B) removing the first polycondensate of the polycondensation step (A) by heating at a temperature of 230 to 320 ° C for 1 to 6 hours; and (C) removing any unreacted glycol. In one embodiment, the method relates to the manufacture of a copolymer comprising terephthalic acid, 2,2,4,4-tetradecyl-1,3-cyclobutanediol, and 1,4-cyclohexane-sintered methanol An ester comprising the following steps: 119732.doc -275- 200804457 (A) a mixture comprising monomers useful in the presence of a tin catalyst in the presence of a tin catalyst of the present invention, heated at a temperature of at least one of 150 to 240 ° C ,calendar

經足以產生最初聚 (B)藉由在240至320°C 驟（A)之最初聚酯；及 酯之時間； 之溫度下加熱1至6小時以聚縮合步 (C)移除任何未反應之二醇類。 酯化步驟（A)之反應時間與所選擇之溫度、壓力及二醇 與-缓酸之進料莫彳比有關。i少一 _碟化合物（舉例言 之至>、種麟酸酯）可被添加至步驟（A)、步驟（B)及/或 步驟（A)及步驟（B)中。 於一具體實施例中，步驟（A)可進行至直到5〇重量％或莫 耳％2,2,4,4-四甲基-1，3-環丁二醇已被反應為止。步驟（A) 可在〇至100 psig之壓力下進行。”反應產物”一詞，當伴隨 著本發明之熱安定劑使用時，係指在熱安定劑與任何用於 製造聚酯之單體間之聚縮合或酯化反應之任何產物，以及 在催化劑與任何其他類型添加劑間之聚縮合或酯化反應之 產物。 典型地，步驟（B)及步驟（C)可在相同時間下進行。該等 步驟可藉由此技術領域中已知之方法進行，例如，藉由將 反應混合物置於0.002 psig至低於常壓之壓力下，或藉由 掮動熱氮氣使其遍及混合物。 於一具體實施例中，本發明係關於一種製造適合用於本 發明之任何聚酯之方法，其包含下列步驟： (I)在選自150至250°C之至少一溫度及選自0至75 psig之 119732.doc -276- 200804457 至少一壓力下加熱一混合物，其中該混合物包含： (a) 二羧酸成份，其包含： 1) 70至1〇〇莫耳〇/〇之對苯二曱酸殘基； Π) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii)〇至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 1至99莫耳％之2,2,4,4-四甲基·1，3-環丁二醇殘 基；及 ii) 1至99莫耳。/〇之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1·0·1·5/1.0 ; 其中步驟（I)中之混合物係在下列物質之存在下加熱：（i) 包含至少一種錫化合物之至少一種催化劑，及，視需要， 至少一種選自鈦、鎵、鋅、錄、钻、猛、鎖、鍺、叙、銘 化合物及鋁化合物與氫氧化鋰或氫氧化鈉之催化劑；及 (II)將步驟（I)之產物於230至320 °C之溫度及至少一選自 從步驟（I)之最終壓力至0.02托（絕對壓力）範圍内之壓力下 加熱1至6小時，以形成最終聚酯； 其中該最終聚酯之二羧酸成份之總莫耳％為1〇〇莫耳％， 且該最終聚酯之二醇成份之總莫耳。/。為100莫耳％。 於一具體實施例中，本發明係關於一種製造適合用於本 發明之任何聚酯之方法，其包含下列步驟： 119732.doc -277- 200804457 (I)在選自150至250°C之至少一溫度及選自〇至75 psig之 至少一壓力下加熱一混合物，其中該混合物包含： U)二羧酸成份，其包含： i) 70至1〇〇莫耳〇/0之對苯二曱酸殘基； η) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii)0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： i) 1至99莫耳％之2,2,4,4-四甲基·1，3-環丁二醇殘 基；及 ii) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1.0-1.5/1.0 ; 其中步驟（I)中之混合物係在下列物質之存在下加熱： (i)包含至少一種錫化合物之至少一種催化劑，及，視 需要，至少一種選自鈦、鎵、鋅、銻、鈷、錳、鎂、 鍺、鐘、紹化合物及銘化合物與氫氧化鐘或氫氧化納 之催化劑；及 (Π)將步驟（I)之產物於230至320 °C之溫度及至少一選自 從步驟（I)之最終壓力至0.02托（絕對壓力）範圍内之壓力下 加熱1至6小時，以形成最終聚酯； 其中該最終聚酯之二羧酸成份之總莫耳％為100莫耳％，且 該最終聚酯之二醇成份之總莫耳°/。為100莫耳％。 119732.doc -278 - 200804457 於一具體實施例中，本發明係關於一種製造適合用於本 發明之任何聚酯之方法，其包含下列步驟： (I)在選自150至200°C之至少一溫度及選自〇至75 psig之 至少一壓力下加熱一混合物，其中該混合物包含： (a) 二羧酸成份，其包含： i) 70至100莫耳％之對苯二甲酸殘基； ii) 0至30莫耳。/〇之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： i) 1至99莫耳％之2,2,4,4-四甲基- l，3_環丁二醇殘 基；及 ii) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1.0-1.5/1.0 ; 其中步驟（I)中之混合物係在下列物質之存在下加熱： 包含至少一種錫化合物之至少一種催化劑，及，視需 要，至少一種選自鈦、鎵、鋅、銻、鈷、錳、鎂、 鍺、鋰、鋁化合物及鋁化合物與氫氧化鋰或氫氧化鈉 之催化劑；及 (Π)將步驟（I)之產物於230至320°c之溫度及至少一選自 從步驟（I)之最終壓力至0.02托（絕對壓力）範圍内之壓力下 加熱1至6小時，以形成最終聚酯； 119732.doc • 279- 200804457 其中该最終聚S旨之一叛酸成份之總莫耳％為1 Q Q莫耳％ · 其中該最終聚酯之二醇成份之總莫耳％為1〇〇莫耳％ ; 其中至少一種構化合物（舉例言之，至少一種磷酸酯）係被 添加至步驟（I)、步驟（II)及/或步驟（I)及步驟（11)中；且 其中該麟化合物（舉例言之，至少一種磷酸酯）的添加導致 可用於本發明之最終聚酯中之總錫原子與總磷原子之重量 比為 2-10 : 1。 於一具體實施例中，本發明係關於一種製造適合用於本 發明之任何聚酯之方法，其包含下列步驟： ⑴在選自150至200°C之至少一溫度及選自〇至75 psig之 至少一壓力下加熱一混合物，其中該混合物包含： (a) 二羧酸成份，其包含： i) 70至1〇〇莫耳％之對苯二甲酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) —酵成份’其包含： i) 1至99莫耳％之2,2,4,4-四曱基-1，3-環丁二醇殘 基；及 ΰ) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1·0·1·5/1.〇 ; 其中步驟（I)中之混合物係在下列物質之存在下加熱： 119732.doc 200804457 包含至少一種錫化合物之至少一種催化劑，及，視需 要，至少一種選自鈦、鎵、辞、銻、銘、猛、鎂、 鍺、鋰、鋁化合物及鋁化合物與氫氧化鋰或氫氧化鈉 之催化劑；及 (Π)將步驟⑴之產物於230至320°C之溫度及至少一選自 從步驟（I)之最終壓力至〇.〇2托（絕對壓力）範圍内之壓力下 加熱1至6小時，以形成最終聚酯； 其中該最終聚酯之二羧酸成份之總莫耳％為1〇〇莫耳0/〇 ; 其中該最終聚酯之二醇成份之總莫耳％為1〇〇莫耳％ ; 其中至少一種磷化合物（舉例言之，至少一種磷酸酯）係被 添加至步驟（I)、步驟（Π)及/或步驟⑴及步驟（H)中，·且 其中該磷化合物（舉例言之，至少一種磷酸酯）的添加導致 可用於本發明之最終聚酯中之總錫原子與總磷原子之重量 比為 2-10 : 1。 舉例言之，在先前四個段落中，至少一種磷化合物可被 添加至該方法之步驟（1)、步驟（„)及/或步驟⑴及步驟（Μ) 中於具體實施例中，鱗化合物係被添加至步驟⑴中。 磷化合物可包含任何本文中所述及者，例如，至少__ S夂酯。可用於本發明之熱穩定劑可包含至少一種磷化合 在製造可用於本發明之聚δ|之任何本發明方法中，至少 種熱穩疋d、其反應產物及其混合物可於酯化反應 間、聚縮合反應期間或兩者期間添加，或於後聚合反應眸 添加。於-具體實施例中，可用於本發明任何方法之：穩 119732.doc -281- 200804457 定劑可於s旨化反應期間添加。於一具體實施例中，假使熱 穩定劑係於聚縮合反應期間及酯化反應期間添加，其係以 1至2重量％之量添加，以最終聚酯總重為基準。於一具體 實施例中，熱穩定劑可包含至少一種可用於本發明之碌化 合物。於一具體實施例中，熱穩定劑可包含至少一種磷酸 酯。於一具體實施例中，熱穩定劑可包含至少一種鱗化合 物，其係於酯化反應期間添加。於一具體實施例中，熱穩 定劑可包含至少一種磷酸酯，其係於酯化反應期間添加。 於一具體實施例中，咸信在根據本發明之製造聚酯之方 法期間使用本文中所描述之包含至少一種磷化合物之熱穩 定劑時，聚酯可較輕易地被製造，且不會有至少一種以下 情形發生：胃泡、斜角形成、色彩形成、發泡、逸氣及無 規律熔融程度（即，聚酯、聚酯之產製及加工系統之脈 動）。於另一具體實施例中，咸認本發明之至少一種方法 提供較輕易且大量（例如，初步製程規模及/或商業產製）製 得可用於本發明之聚_，且同時避免至少_種以上敛述困 難發生之方法。 於本文中使用之，，大量”-詞，係意欲包括可用於本發明 之聚酉旨係以大於H)㈣之量產製。於—具體實施例中，此 處所使用之，，大量”一詞，包括可用於本發明之聚醋係以大 於1000磅之量產製。 於-方面，可用於本發明之聚醋之製造方法可包含批次 或連續方法。 於方面，可用於本發明之聚酉旨之製造方法可包含連續 119732.doc -282· 200804457 方法。 咸#任何可用於本發明之聚酯之製造方法可用於製造可 用於本發明之聚g旨。 酯化步驟（I)之反應時間與所選擇之溫度、壓力及二醇與 二羧酸之進料莫耳比有關。 於一具體實施例中，本發明任何方法之步驟（H)之所使 用之壓力係由選自20至〇·〇2托（絕對壓力）之至少一種壓力 所組成，於一具體實施例中，本發明任何方法之步驟（II) 之所使用之壓力係由選自10至0.02托（絕對壓力）之至少一 種壓力所組成；於一具體實施例中，本發明任何方法之步 驟（Π)之所使用之壓力係由選自5至0.02托（絕對壓力）之至 少一種壓力所組成；於一具體實施例中，本發明任何方法 之步驟（II)之所使用之壓力係由選自3至0.02托（絕對壓力） 之至少一種壓力所組成；於一具體實施例中，本發明任何 方法之步驟（II)之所使用之壓力係由選自2〇至〇1托（絕對壓 力）之至少一種壓力所組成；於一具體實施例中，本發明 任何方法之步驟（II)之所使用之壓力係由選自10至01托（絕 對壓力）之至少一種壓力所組成；於一具體實施例中，本 發明任何方法之步驟（II)之所使用之壓力係由選自5至01 托（絕對壓力）之至少一種壓力所組成；於一具體實施例 中，本發明任何方法之步驟（II)之所使用之壓力係由選自3 至〇 · 1托（絕對壓力）之至少一種壓力所組成。 於一具體實施例中，添加於本發明任何方法之步驟⑴中 之二醇成分/二羧酸成分之莫耳比為l.〇-le5/1〇 ;於一具體 119732.doc -283 - 200804457 實施例中，添加於本發明任何方法之步驟⑴中之二醇成分 /二叛酸成分之莫耳比以扎15/1〇;於一具體實施例 中，添加於本發明任何方法之步驟⑴中之二醇成分/二缓 酸成分之莫耳比鼻1 Π1 ! 方去之步驟⑴中之二醇成分/二羧酸成分之 、‘、、、·卜1·2’1.0 ;於-具體實施例中，添加於本發明 任何方法之步驟⑴中之二醇成分/二叛酸成分之莫耳比為 1.01-1.15/U;於—具體實施例中，添加於本發明任何方 法之步驟（I)中之二醇成分/二叛酸成分之莫耳比為 .10/1.0 ’於_具體實施例中，添加於本發明任； 法之步驟（1)中之二醇成分/二羧酸成分之莫 1·〇3 1.5/1.G ’於—具體實施例中，添加於本發明任法 Γ:=中之二醇成分/二…分之 .·.，於-具體實施例中，添加於本發 之步驟（I)中之二醇成分/二叛酸成分之莫 = in觀於—具體實施例中’添加於本發明任何方法 之步驟⑴中之二醇成分/二羧酸成分之莫耳 imsn.o;於—具體實施例巾，添明： 法之步驟⑴中之二醇成分/二缓酸成分：月任= 1 03-1 10/1 〇 ·认 之莫耳比為 法之步驟⑴具體實施例中’添加於本發明任何方 i。…/10.於之一酵成分/二缓酸成分之莫耳比為 .1.5/1.0,於—具體實施例中，添加於本 之步驟（I)中之二醇成分/二羧醆成分之 去 iwu ;於—具體實施例中，添加於本發明任= 119732.doc 200804457 之步驟（i)中之二醇成分/二羧酸成分之莫耳比為 1.05-1.2/1.0 ;於一具體實施例中，添加於本發明任何方法 之步驟（I)中之二醇成分/二羧酸成分之莫耳比為 1·〇5-1· 15/1.0 ;及於一具體實施例中，添加於本發明任何 方法之步驟（I)中之二醇成分/二羧酸成分之莫耳比為 1.01-1.10/1.0 。 於可用於本發明之聚酯之任何製造方法具體實施例中， 步驟（II)之加熱時間可為1至12小時；或1至6小時；或 小時；或1至4小時；或1至3小時；或ι·5至3小時；或丨至^ 小時。於一具體實施例中，步驟（„)之加熱時間可為15至 3小時。 於一具體實施例中，磷化合物於本發明方法中的添加導 致可用於本發明之最終聚酯中之總錫原子與總磷原子之重 量比為2-10: 1。於一具體實施例中，磷化合物於本發明 方法中的添加導致可用於本發明之最終㈣中之總錫原子 合物於本發明方法中的添加導致可用於本發明之最終聚醋 中之總錫原子與總磷原子之重量比為6·8 :丄。於—具體實 施例中，料合物於本㈣方法巾的添加導致可心本發 明之最終聚酯中之總錫原子與總磷原子之重量比為7 · 1 舉例言之，存在於最終聚醋中之錫原子及鱗原子：重量可 以ΡΡΙΏ方式量測，且可獲得如前述任何最終聚自旨中之總錫 原子與總填原子之重量& 於一具體實施例中 錫原子於可用於本發明之最終聚酯 119732.doc -285- 200804457 中之量，以最終聚酯重量計，可為自15至400 ppm。 於一具體實施例中，錫原子於可用於本發明之最終聚醋 中之量，以最終聚酯重量計，可為自25至400 ppm。 於一具體實施例中，錫原子於可用於本發明之最終聚酉旨 中之量，以最終聚酯重量計，可為自40至200 ppm。 於一具體實施例中，錫原子於可用於本發明之最終聚酯 中之量，以最終聚酯重量計，可為自50至125 ppm。 於一具體實施例中，填原子於可用於本發明之最終聚酯 中之量，以最終聚酯重量計’可為自1至100 ppm。 於一具體實施例中，鱗原子於可用於本發明之最終聚g旨 中之量，以最終聚酯重量計，可為自4至60 ppm。 於一具體實施例中，磷原子於可用於本發明之最終聚酯 中之量，以最終聚酯重量計，可為自6至20 ppm。 於一具體實施例中，磷原子於可用於本發明之最終聚酯 中之量，以最終聚S旨重量計’可為自1至100 ppm ;且錫原 子於最終聚酯中之量，以最終聚酯重量計，可為自15至 400 ppm 0 於一具體實施例中，磷原子於可用於本發明之最終聚酯 中之量，以最終聚S旨重量計’可為自1至100 ppm ;且錫原 子於最終聚酯中之量，以最終聚酯重量計，可為自25至 400 ppm 〇 於一具體實施例中，磷原子於可用於本發明之最終聚醋 中之量，以最終聚醋重量計’可為自4至60 ppm ;且錫原 子於最終聚酯中之量，以最終聚酯重量計，可為自4〇至 119732.doc -286- 200804457 200 ppm 〇 於一具體實施例中，磷原子於可用於本發明之最終聚酯 中之量，以最終聚酯重量計，可為自6至2〇 ppm ;且錫原 子於最終聚酯中之量，以最終聚酯重量計，可為自5〇至 125 ppm 〇 本發明進一步關於由前述方法製得之聚酯組合物。 本發明進一步關於包含本發明聚酯組合物之薄膜及/或 薄片。將聚酯製成薄膜及/或薄片之方法係為此項技藝中 所習知。本發明薄膜及/或薄片之實例包括但不限於擠壓 成型薄膜及/或薄片、壓延薄膜及/或薄片、壓縮模製薄膜 及/或薄片、溶液鑄造薄膜及/或薄片。製造薄膜及/或薄片 之方法，包括但不限於擠壓、壓延、壓縮模製及溶液鑄 造。 由可用於本發明之薄膜及/或薄片製得之潛在物件之實 例包括，但不限於，經單轴延伸薄膜、經雙軸延伸薄膜、 收縮薄膜（不論是否經單轴或雙軸延伸）、液晶顯示器薄膜 (包括，但不限於，擴散片、補償膜及保護膜）、熱成型薄 片、繪圖技藝薄膜、戶外標誌、天窗、塗層、塗覆物件、 塗刷物件、積層物、層合物件及/或多壁薄膜或薄片。 本文中所用之’’繪圖技藝薄膜”一詞意指以熱可硬化墨水 (例如加熱可硬化墨水或空氣可硬化墨水）或輻射可硬化墨 水（例如紫外線可硬化墨水）印刷於其上或其中之薄膜。’，可 硬化” 一詞意指可經歷聚合反應及/或交聯反應。除了墨水 之外，繪圖技藝薄膜亦可視需要包含亮光漆、塗層、積層 119732.doc •287- 200804457 物及黏合劑。 熱硬化或空氣硬化墨水之實例涉及分散於一或多種標準 載體樹酯中之顏料。顏料可為4B色料（PR57)、2B色料 (PR48)、Lake 紅 C(PR53)、lithol 紅（PR49)、氧化鐵 (PR101)、永固紅R(PR4)、永固紅2G(P05)、〇比σ坐琳_橘 (Ρ013)、二芳基黃（ΡΥ12，13，14)、單唑黃（ργ3,5,98)、酞 菁綠（PG7)、酞菁藍、β形式（ΡΒ15)、群青色（ΡΒ02)、永固 紫（PV23)、二氧化鈦（PW6)、碳黑（熔爐/通道）（ΡΒ7)、 ΡΜΤΑ粉紅、綠、藍、紫（PR81，PG 1，ΡΒ1，PV3)、銅氰亞 鐵酸鹽染料錯合物（PR169，PG45，ΡΒ62，PV27)或其類似 物。（前述括號内之識別資料請參考由Society of Dyers and Colourists所製備之一般顏料指南）。可使用此等顏料及其 組合而獲得各種顏色，包括但不限於白色、黑色、藍色、 紫色、紅色、綠色、黃色、青綠色、品紅色或橘色。 其他墨水實例（包括輻射硬化墨水）係揭示於美國專利 5,382,292中，該專利關於此等墨水之揭示係併入本文中做 為參考。 用於標準墨水之典型載體樹酯之實例包括該等具有硝化 纖維素、酿胺、胺基甲酸醋、環氧化物、丙稀酸S旨及/或 酯官能性分子團者。標準載體樹酯包括一或多種硝化纖維 素、聚醯胺、聚胺基甲酸酯、乙基纖維素、乙酸丙酸纖維 素、（甲基）丙烯酸酯、聚（乙烯醇縮丁醛）、聚（醋酸乙烯 酯）、聚（氯乙烯）及其類似物。此等樹酯可經摻合，具廣泛 使用性之摻合物包括硝化纖維素/聚醯胺及硝化纖維素/聚 119732.doc -288 - 200804457 胺基曱酸_。 墨水樹s旨通常可被溶劑化或分散於—或多種溶劑中。典 :可用溶劑包括，不限於’水、醇類(例如乙醇、卜丙 醇”丙知等）、醋酸酯（例如醋酸正丙酯）、脂肪族烴類、 芳香族煙類（例如甲苯）及賴。此等溶劑典型以足以提供 墨^至少15秒（例如至少2()秒、至少25秒或25至邱）黏性 之里併入，以技藝中已知之#2 Zahll cup量測。 於-具體實施例中’聚8旨具有足以提供熱可成型性及方 便印刷之Tg值。 於-具體實施例中，繪圖技藝薄膜具有至少—種選自熱 可成型性、勒性、清澈性、耐化學品性、Tg及彈性之性 質0 用中，例如，模内裝飾物 繪圖技藝薄膜可為光滑或 繪圖技藝薄膜可使用於各種應 件、印有凸飾物件及加硬物件。 經紋飾。 繪圖技藝薄琪之實例包括但不 个吸於名牌、薄膜關閉覆蓋 物（例如供設備使用）；購買展 处，，无衣機上之平扫壶握 中裝飾用面板，·冰箱上之平坦接 一飞杈 一搔觸面板（例如電容式觸控 板陣列），·烘箱上之平板·汽車用 A旱用之裝飾用内部修整 聚酯積層物）,·汽車用之儀錶群； （^如 町，于機覆盍層；加熱盥诵 風控制顯W，·汽車儀錶板；汽車絲變換面板·汽車 錄板用之控制顯示器或警告信號；家用器具上之飾面、找 度盤或顯不器；洗衣機上之飾 ^ 機上之飾面、標度盤或顯示器； 磲 电丁衮置用之鍵墊；可移 119732.doc -289- 200804457 動電話機、個人數位助理（PDA或手握式電腦）或遠距控制 用之鍵墊；電子裝置用之顯示器；手握式電子裝置譬如電 話機與PDA之顯示器；可移動或標準電話機用之面板與罩 殼；電子裝置上之字標；及手握式電話機上之字標。 多壁薄膜或薄片係指以由藉由垂直肋材互相連接之多層 所組成外觀形式擠壓成型之薄片。多壁薄膜或薄片之實例 包括但不限於戶外庇護所（例如溫室與商用頂篷）。 包含可用於本發明之聚酯組合物之擠壓成型物件之實例 包括，但不限於，熱成型薄片、供繪圖技藝應用之薄膜， 戶外標誌、、天窗、多壁薄膜、供塑膠玻璃積層物用之薄 膜，及液晶顯示器（LCD)薄膜’包括但不限於用於lcd之 擴散薄片、補償薄膜及保護性薄膜。 落於本發明範圍之包含本發明聚酯組合物之其他物件包 括，但不限於，安全器具/運動器具（例如但不限於··安全 庇罩、面罩、運動護目鏡（壁球、滑雪等）、警用鎮暴盾）、 波紋薄片物件、娛樂/戶外運輸工具及設備（例如但不限 於：草地拖拉機、雪地車、摩托車擋風玻璃、露營車窗、 高爾夫球車擋風玻璃、喷器式滑雪板）、住宅用及商用照 明（例如但不限於：散光器、公司、住家及商用固定設 備、高強度放電（HID)照明）、電信設備/商業設備/電子設 備（例如但不限於：手機外殼、電視外殼、電腦外殼、立 體音響外殼、PDA等）、光學媒體、曬黑床、多壁薄片、 擠壓成型物件、硬質醫療包裝、靜脈内裝置、透析濾器外 ^ 液/σ療谷器、殺菌谷器（例如嬰兒護理殺菌容器）、 119732.doc -290- 200804457 奶嘴、工具柄（例如作x 不限於·螺絲起子、鐵鎚等）、熱塑 性物件、聲障、汽車外_箭 、 卜観（別燈覆喊、後燈覆殼、側窗、 可開閉汽車車頂）、硬皙喵叔。/ 更貝4耗口口 /工業包裝、管狀物、淋浴 器、熱水澡桶、機琴士雈札 ^ 或為防濩物、販賣機展示面板、計量器、Remove any unreacted by the polycondensation step (C) by an amount sufficient to produce the initial poly(B) by heating at the temperature of 240 to 320 ° C (A) of the original polyester; and the ester at a temperature of 1 to 6 hours. Glycols. The reaction time of the esterification step (A) is related to the selected temperature, pressure, and feed enthalpy ratio of the diol to the retarding acid. The i-disc compound (for example, >, the phytate) may be added to the step (A), the step (B) and/or the step (A) and the step (B). In one embodiment, step (A) can be carried out until up to 5% by weight or mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol has been reacted. Step (A) can be carried out at a pressure of up to 100 psig. The term "reaction product" as used in connection with the thermal stabilizer of the present invention means any product of the polycondensation or esterification reaction between the thermal stabilizer and any monomer used to make the polyester, and in the catalyst A product of a polycondensation or esterification reaction with any other type of additive. Typically, step (B) and step (C) can be carried out at the same time. These steps can be carried out by methods known in the art, for example, by placing the reaction mixture at a pressure of from 0.002 psig to below atmospheric pressure, or by tumbling hot nitrogen over the mixture. In one embodiment, the invention is directed to a method of making any of the polyesters suitable for use in the present invention comprising the steps of: (I) at a temperature selected from the group consisting of at least 150 to 250 ° C and selected from 0 to 75 psig 119732.doc -276- 200804457 Heating a mixture at least under pressure, wherein the mixture comprises: (a) a dicarboxylic acid component comprising: 1) 70 to 1 Torrole/〇 对 Benzene a decanoic acid residue; Π) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 〇 to 10 mol% of an aliphatic dicarboxylic acid residue having a high 16 carbon atoms; and (b) a diol component comprising: i) from 1 to 99 mol% of 2,2,4,4-tetramethyl·1,3-cyclobutanediol residues; ) 1 to 99 moles. a cyclohexane dimethanol residue of hydrazine; wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is 1·0·1·5/1.0; wherein the step (I) The mixture is heated in the presence of: (i) at least one catalyst comprising at least one tin compound, and, if desired, at least one selected from the group consisting of titanium, gallium, zinc, lithography, drilling, smashing, locking, sputum, sigma, a compound of the compound and the aluminum compound and lithium hydroxide or sodium hydroxide; and (II) the product of the step (I) at a temperature of from 230 to 320 ° C and at least one selected from the final pressure of the step (I) to 0.02 Torr Heating at a pressure in the range of (absolute pressure) for 1 to 6 hours to form a final polyester; wherein the total mole % of the dicarboxylic acid component of the final polyester is 1% mol%, and the final polyester The total molar amount of the diol component. /. It is 100% by mole. In one embodiment, the invention is directed to a method of making any of the polyesters suitable for use in the present invention, comprising the steps of: 119732.doc-277-200804457 (I) at least selected from 150 to 250 ° C Heating a mixture at a temperature and at least one pressure selected from the group consisting of 〇 to 75 psig, wherein the mixture comprises: U) a dicarboxylic acid component comprising: i) 70 to 1 Torrole/0 of para-benzoquinone Acid residue; η) 0 to 30 mol% of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having a height of 16 a carbon atom; and (b) a diol component comprising: i) from 1 to 99 mol% of a 2,2,4,4-tetramethyl·1,3-cyclobutanediol residue; and ii) 1 to 99 mol% of a cyclohexanedimethanol residue; wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is 1.0-1.5/1.0; wherein the step (I) The mixture is heated in the presence of: (i) at least one catalyst comprising at least one tin compound, and, if desired, at least one selected from the group consisting of titanium, gallium, zinc, antimony, cobalt, manganese, magnesium, a catalyst of ruthenium, ruthenium, sulphate and a compound with a hydrazine hydroxide or sodium hydroxide; and (Π) a product of step (I) at a temperature of from 230 to 320 ° C and at least one selected from the group consisting of step (I) The pressure is heated to a pressure in the range of 0.02 Torr (absolute pressure) for 1 to 6 hours to form a final polyester; wherein the total mole % of the dicarboxylic acid component of the final polyester is 100 mol%, and the final poly The total molar content of the diol component of the ester. It is 100% by mole. 119732.doc -278 - 200804457 In one embodiment, the invention is directed to a method of making any of the polyesters suitable for use in the present invention comprising the steps of: (I) at least selected from 150 to 200 ° C Heating a mixture at a temperature and at least one pressure selected from the group consisting of 〇 to 75 psig, wherein the mixture comprises: (a) a dicarboxylic acid component comprising: i) from 70 to 100 mol% of a terephthalic acid residue; Ii) 0 to 30 moles. /〇 an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol a composition comprising: i) from 1 to 99 mol% of 2,2,4,4-tetramethyl-l,3-cyclobutanediol residues; and ii) from 1 to 99 mol% of cyclohexane a dimethanol residue; wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is 1.0-1.5/1.0; wherein the mixture in the step (I) is heated in the presence of the following materials: At least one catalyst comprising at least one tin compound, and, if desired, at least one selected from the group consisting of titanium, gallium, zinc, lanthanum, cobalt, manganese, magnesium, lanthanum, lithium, aluminum compounds, and aluminum compounds with lithium hydroxide or sodium hydroxide Catalyst; and (Π) heating the product of step (I) at a temperature of from 230 to 320 ° C and at least one pressure selected from the final pressure of step (I) to a pressure within the range of 0.02 Torr (absolute pressure) from 1 to 6 Hours to form the final polyester; 119732.doc • 279- 200804457 where the total molar amount of one of the final polysole components is 1 QQ Mo %% The total molar % of the diol component of the final polyester is 1% mol%; wherein at least one structural compound (for example, at least one phosphate) is added to the step (I), the step (II), and / or in step (I) and step (11); and wherein the addition of the lining compound (for example, at least one phosphate) results in the weight of total tin atoms and total phosphorus atoms in the final polyester useful in the present invention The ratio is 2-10: 1. In one embodiment, the invention is directed to a method of making any of the polyesters suitable for use in the present invention comprising the steps of: (1) at a temperature selected from the group consisting of at least 150 to 200 ° C and selected from the group consisting of 〇 to 75 psig Heating a mixture under at least one pressure, wherein the mixture comprises: (a) a dicarboxylic acid component comprising: i) 70 to 1 mole % terephthalic acid residue; ii) 0 to 30 moles % of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) 0 to 10 mol% of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a yeast ingredient 'It contains: i) 1 to 99 mol% of 2,2,4,4-tetradecyl-1,3-cyclobutanediol residues; and ΰ) 1 to 99 mol% of cyclohexane a methanol residue; wherein the molar ratio of the diol component/dicarboxylic acid component added in the step (I) is 1·0·1·5/1. 〇; wherein the mixture in the step (I) is in the following Heating in the presence of: 119732.doc 200804457 at least one catalyst comprising at least one tin compound, and, if desired, at least one selected from the group consisting of titanium, gallium, rhodium, ruthenium, mi, ram, magnesium, a catalyst of lithium, aluminum compound and aluminum compound with lithium hydroxide or sodium hydroxide; and (Π) the product of step (1) at a temperature of from 230 to 320 ° C and at least one selected from the final pressure of step (I) to hydrazine Heating at a pressure within the range of 托 2 Torr (absolute pressure) for 1 to 6 hours to form a final polyester; wherein the total mole % of the dicarboxylic acid component of the final polyester is 1 〇〇 mol 0 / 〇; Wherein the total molar % of the diol component of the final polyester is 1% mol%; wherein at least one phosphorus compound (for example, at least one phosphate) is added to step (I), step (Π) And/or in steps (1) and (H), and wherein the addition of the phosphorus compound (for example, at least one phosphate) results in the weight of total tin atoms and total phosphorus atoms in the final polyester useful in the present invention. The ratio is 2-10: 1. For example, in the previous four paragraphs, at least one phosphorus compound may be added to step (1), step („) and/or step (1) and step (Μ) of the method in a specific embodiment, a scale compound Is added to step (1). The phosphorus compound may comprise any of those described herein, for example, at least __S decyl ester. The heat stabilizer useful in the present invention may comprise at least one phosphide compound useful in the manufacture of the present invention. In any of the processes of the present invention, at least one heat stable d, a reaction product thereof, and a mixture thereof may be added during the esterification reaction, during the polycondensation reaction, or both, or may be added after the post polymerization reaction. In a specific embodiment, it can be used in any of the methods of the present invention: Stabilization 119732.doc -281-200804457 The fixative can be added during the s reaction. In a specific embodiment, if the heat stabilizer is during the polycondensation reaction and Addition during the esterification reaction, which is added in an amount of from 1 to 2% by weight, based on the total weight of the final polyester. In one embodiment, the heat stabilizer may comprise at least one compound useful in the present invention. One In a particular embodiment, the heat stabilizer can comprise at least one phosphate ester. In one embodiment, the heat stabilizer can comprise at least one scaly compound that is added during the esterification reaction. In one embodiment, the heat stabilizer is thermally stable. The agent may comprise at least one phosphate ester which is added during the esterification reaction. In one embodiment, the heat of the at least one phosphorus compound described herein is used during the method of making a polyester according to the present invention. In the case of stabilizers, polyesters can be easily produced without at least one of the following: gastric vesicles, bevel formation, color formation, foaming, outgassing, and irregular melting (ie, polyester, poly The production of the ester and the pulsation of the processing system. In another embodiment, at least one of the methods of the present invention provides a relatively easy and substantial (eg, preliminary process scale and/or commercial production) for use in the present invention. The invention of the poly_, and at the same time avoids at least _ above the method of arranging difficulties. As used herein, a large number of "-words" are intended to include the poly sputum that can be used in the present invention. Department of greater than H) (iv) of the production system. In the specific embodiment, the term "a large amount" as used herein, including the polyacetate which can be used in the present invention, is produced in an amount of more than 1000 lb. In terms of the method for producing the vinegar of the present invention. A batch or continuous process may be included. In one aspect, the method of manufacture useful in the present invention may comprise a continuous process of 119732.doc-282.200804457. Salt # Any manufacturing process of the polyester useful in the present invention may be used in the manufacture. It can be used in the present invention. The reaction time of the esterification step (I) is related to the selected temperature, pressure and feed molar ratio of the diol to the dicarboxylic acid. In one embodiment, any of the present invention The pressure used in step (H) of the method consists of at least one pressure selected from the group consisting of 20 to 〇 2 Torr (absolute pressure), and in one embodiment, step (II) of any method of the invention The pressure used is comprised of at least one pressure selected from 10 to 0.02 Torr (absolute pressure); in one embodiment, the pressure used in the steps of any of the methods of the invention is selected from 5 to 0.02 Torr (absolute pressure) At least one pressure consisting of; in one embodiment, the pressure used in step (II) of any method of the invention consists of at least one pressure selected from 3 to 0.02 Torr (absolute pressure); In a particular embodiment, the pressure used in step (II) of any of the methods of the present invention consists of at least one pressure selected from 2 Torr to 1 Torr (absolute pressure); in one embodiment, any of the present invention The pressure used in step (II) of the method consists of at least one pressure selected from 10 to 01 Torr (absolute pressure); in one embodiment, the step (II) of any method of the invention is used. The pressure system consists of at least one pressure selected from 5 to 01 Torr (absolute pressure); in one embodiment, the pressure used in step (II) of any method of the invention is selected from the group consisting of 3 to 〇·1 At least one pressure of the pressure (absolute pressure). In one embodiment, the molar ratio of the diol component/dicarboxylic acid component added to the step (1) of any of the methods of the present invention is 1. 〇-le5/1 〇;于一一个119732.do c - 283 - 200804457 In the examples, the molar ratio of the diol component / the two-rebel component added to the step (1) of any of the methods of the present invention is 15/1 〇; in a specific embodiment, added to the present invention The diol component of the method (1) / the molybdenum component of the second acid retardant component is the same as the diol component/dicarboxylic acid component in the step (1), ', ,, ···1·2' 1.0; in a specific embodiment, the molar ratio of the diol component/di-rebel component added to step (1) of any of the methods of the present invention is 1.01-1.15 / U; in a specific embodiment, added to the present invention The molar ratio of the diol component/secondary oxic acid component in the step (I) of any method is .10/1.0'. In the specific embodiment, the diol is added to the step (1) of the present invention; In the specific embodiment, the diol component of the present invention is added to the diol component of the present invention: ??? In a specific embodiment, the diol component/secondary oxic acid component added to step (I) of the present invention is in the form of 'additional' to any method of the present invention. The diol component of the step (1) / the molar component of the dicarboxylic acid component is imsn.o; in the specific embodiment towel, adding: the diol component / the second acid retarding component in the step (1) of the method: monthly = 1 03- 1 10/1 认· 莫 莫 莫 为 为 步骤 步骤 步骤 莫 莫 莫 莫 莫 莫 莫 莫 莫 莫 莫 莫 莫 莫 莫 莫 莫 莫 莫 莫The ratio of the molar ratio of the one of the fermented ingredients to the diacidic acid component is 1.5/1.0. In the specific embodiment, the diol component/dicarboxylated component added to the step (I) of the present invention is In the specific embodiment, the molar ratio of the diol component/dicarboxylic acid component added in the step (i) of the present invention is =1 732 732.doc 200804457 is 1.05-1.2/1.0; In an embodiment, the molar ratio of the diol component/dicarboxylic acid component added to the step (I) of any of the methods of the present invention is 1·〇5-1·15/1.0; and in a specific embodiment, added to The molar ratio of the diol component/dicarboxylic acid component in the step (I) of any of the methods of the present invention is from 1.01 to 1.10 / 1.0. In a specific embodiment of any method of manufacture of the polyester useful in the present invention, the heating time of step (II) may be from 1 to 12 hours; or from 1 to 6 hours; or hours; or from 1 to 4 hours; or from 1 to 3 Hours; or ι·5 to 3 hours; or 丨 to ^ hours. In one embodiment, the heating time of the step (() can be from 15 to 3 hours. In one embodiment, the addition of the phosphorus compound to the process of the invention results in total tin that can be used in the final polyester of the present invention. The weight ratio of atoms to total phosphorus atoms is from 2 to 10: 1. In one embodiment, the addition of a phosphorus compound in the process of the invention results in a total tin atom ate that can be used in the final (iv) of the invention in the process of the invention. The addition in the final polyacetate of the present invention results in a weight ratio of total tin atoms to total phosphorus atoms of 6.8: 丄. In a particular embodiment, the addition of the composition to the method (4) method towel results in The weight ratio of total tin atoms to total phosphorus atoms in the final polyester of the present invention is 7.1. For example, the tin atoms and scale atoms present in the final polyester: the weight can be measured in the manner of The weight of the total tin atom and the total filled atom in any of the foregoing final polymerizations & in one embodiment, the tin atom is in the final polyester 119732.doc-285-200804457 which can be used in the present invention to ultimately Polyester weight meter, can be 15 to 400 ppm. In one embodiment, the amount of tin atoms in the final polyester useful in the present invention may range from 25 to 400 ppm by weight of the final polyester. In one embodiment, tin The amount of atoms in the final polymerization useful in the present invention may range from 40 to 200 ppm by weight of the final polyester. In one embodiment, the tin atom is used in the final polyester useful in the present invention. The amount, based on the weight of the final polyester, may range from 50 to 125 ppm. In one embodiment, the amount of atoms to be used in the final polyester of the present invention may be from 1 by weight of the final polyester. Up to 100 ppm. In one embodiment, the scalar atom can be used in the final polymerization of the present invention in an amount from 4 to 60 ppm, based on the weight of the final polyester. In one embodiment, phosphorus The amount of atoms in the final polyester useful in the present invention may range from 6 to 20 ppm by weight of the final polyester. In one embodiment, the amount of phosphorus atom in the final polyester useful in the present invention. , from the final weight of the poly" can be from 1 to 100 ppm; and the tin atoms in the final poly The amount, based on the weight of the final polyester, may range from 15 to 400 ppm. In one embodiment, the amount of phosphorus atom in the final polyester useful in the present invention is based on the weight of the final poly From 1 to 100 ppm; and the amount of tin atoms in the final polyester, from 25 to 400 ppm by weight of the final polyester. In one embodiment, the phosphorus atom is used in the final polymerization of the present invention. The amount in the vinegar may be from 4 to 60 ppm by weight of the final polyester; and the amount of tin atoms in the final polyester may be from 4 to 119,732.doc -286 - based on the weight of the final polyester. 200804457 200 ppm In one embodiment, the amount of phosphorus atom in the final polyester useful in the present invention may be from 6 to 2 ppm by weight based on the weight of the final polyester; and the tin atom is in the final polyester. The amount may range from 5 to 125 ppm based on the weight of the final polyester. The invention further relates to the polyester composition prepared by the foregoing process. The invention further relates to films and/or sheets comprising the polyester compositions of the invention. Methods of forming polyester into films and/or flakes are well known in the art. Examples of films and/or sheets of the present invention include, but are not limited to, extruded films and/or sheets, calendered films and/or sheets, compression molded films and/or sheets, solution cast films and/or sheets. Methods of making films and/or sheets, including but not limited to extrusion, calendering, compression molding, and solution casting. Examples of potential articles made from films and/or sheets useful in the present invention include, but are not limited to, uniaxially stretched films, biaxially stretched films, shrink films (whether or not uniaxially or biaxially extended), Liquid crystal display film (including, but not limited to, diffusion sheet, compensation film and protective film), thermoformed sheet, graphic art film, outdoor sign, skylight, coating, coated article, painted article, laminate, laminate And / or multi-walled film or sheet. The term ''drawing art film' as used herein means printed thereon or in a heat hardenable ink (eg, heat hardenable ink or air hardenable ink) or radiation hardenable ink (eg, ultraviolet hardenable ink). The term 'hardenable' means that it can undergo a polymerization reaction and/or a crosslinking reaction. In addition to ink, graphic arts films may also include varnish, coating, and laminates as needed. 117732.doc •287- 200804457 and adhesives. Examples of thermally or air hardened inks involve pigments dispersed in one or more standard carrier resins. The pigments can be 4B colorant (PR57), 2B coloring material (PR48), Lake red C (PR53), lithol red (PR49), iron oxide (PR101), permanent red R (PR4), permanent red 2G (P05) ), 〇 σ 坐 sit _ orange (Ρ 013), diaryl yellow (ΡΥ 12, 13, 14), unizolium yellow (ργ3, 5, 98), phthalocyanine green (PG7), phthalocyanine blue, β form ( ΡΒ15), ultramarine blue (ΡΒ02), permanent violet (PV23), titanium dioxide (PW6), carbon black (melting furnace/channel) (ΡΒ7), ΡΜΤΑ pink, green, blue, purple (PR81, PG 1, ΡΒ 1, PV3) , copper ferrocyanide dye complex (PR169, PG45, ΡΒ62, PV27) or an analogue thereof. (For the identification information in parentheses above, please refer to the General Pigment Guide prepared by Society of Dyers and Colourists). These pigments and combinations thereof can be used to obtain a variety of colors including, but not limited to, white, black, blue, purple, red, green, yellow, cyan, magenta, or orange. Other examples of inks, including radiation hardening inks, are disclosed in U.S. Patent No. 5,382,292, the disclosure of which is incorporated herein by reference. Examples of typical carrier resins for standard inks include those having nitrocellulose, amine, urethane, epoxide, acrylic acid and/or ester functional groups. Standard carrier resins include one or more of nitrocellulose, polyamine, polyurethane, ethyl cellulose, cellulose acetate propionate, (meth) acrylate, poly(vinyl butyral), Poly(vinyl acetate), poly(vinyl chloride) and the like. These dendrimers can be blended, and blends with wide applicability include nitrocellulose/polyamide and nitrocellulose/poly 119732.doc-288 - 200804457 amino decanoic acid. The ink tree s can generally be solvated or dispersed in - or a plurality of solvents. Code: Usable solvents include, but are not limited to, 'water, alcohols (such as ethanol, propanol), etc.), acetates (such as n-propyl acetate), aliphatic hydrocarbons, aromatic tobaccos (such as toluene), and These solvents are typically incorporated in a viscosity sufficient to provide ink for at least 15 seconds (e.g., at least 2 (seconds), at least 25 seconds, or 25 to eq), as measured by #2 Zahll cup as known in the art. In a particular embodiment, 'poly 8 has a Tg value sufficient to provide thermal formability and ease of printing. In a particular embodiment, the graphic art film has at least one selected from the group consisting of thermoformability, characterization, clarity, Properties of chemical resistance, Tg and elasticity 0 In use, for example, in-mold decorative drawing technology films can be smooth or graphic arts films can be used for a variety of applications, printed with convex objects and hardened objects. Examples of drawing techniques include: but not sucking on brand names, film closures (for equipment use); buying exhibitions, flat panels in the non-clothing pans, and decorative panels on the refrigerator. a fly-on touch panel (for example Capacitive touch panel array), the flat plate on the oven, the interior trimming polyester laminate for the dry decoration of the automobile, and the instrument cluster for the automobile; (^如町, in the machine covering layer; heating盥Hurricane control display W, · car dashboard; car wire conversion panel · control panel or warning signal for car recording board; veneer on the household appliance, find dial or display device; decoration on the washing machine ^ on the machine Finishing, dial or display; key pad for 衮 ; ;; 119732.doc -289- 200804457 mobile phone, personal digital assistant (PDA or hand-held computer) or remote control key pad Display for electronic devices; displays for hand-held electronic devices such as telephones and PDAs; panels and covers for removable or standard telephones; wordmarks on electronic devices; and wordmarks on hand-held telephones. Film or sheet refers to a sheet that is extruded in the form of an appearance consisting of multiple layers joined to each other by vertical ribs. Examples of multi-walled films or sheets include, but are not limited to, outdoor shelters (eg, greenhouses and commercial canopies). can Examples of extruded articles of the polyester composition of the present invention include, but are not limited to, thermoformed sheets, films for graphic arts applications, outdoor signs, skylights, multi-wall films, films for plastic glass laminates And liquid crystal display (LCD) film 'including but not limited to diffusion sheets, compensation films and protective films for lcd. Other articles comprising the polyester composition of the invention falling within the scope of the invention include, but are not limited to, safe Appliances/sports equipment (such as, but not limited to, safety shelters, face masks, sports goggles (squash, ski, etc.), police town storm shields), corrugated sheet items, entertainment/outdoor vehicles and equipment (such as but not limited to : lawn tractors, snowmobiles, motorcycle windshields, camper windows, golf car windshields, sprayer skis), residential and commercial lighting (such as but not limited to: diffusers, companies, homes and businesses) Fixed equipment, high-intensity discharge (HID) lighting), telecommunication equipment/commercial equipment/electronic equipment (such as but not limited to: mobile phone casing, TV casing, Computer case, stereo casing, PDA, etc.), optical media, tanning bed, multi-walled sheet, extruded article, rigid medical packaging, intravenous device, dialysis filter, liquid/sigma therapy, sterilization bar For example, baby care sterilization container), 119732.doc -290- 200804457 nipple, tool handle (for example, x is not limited to, screwdriver, hammer, etc.), thermoplastic objects, sound barriers, car outside _ arrows, divination Shout, back light cover, side windows, can open and close the car roof), hard uncle. / More shell 4 consumption mouth / industrial packaging, tubes, showers, hot tubs, machine singers ^ or for anti-smashing, vending machine display panels, gauges,

運動及奴樂（例如游泳、、也图撼 舰A 予冰池圍襴、體育場椅、曲棍球冰場、Sports and slaves (such as swimming, but also the ship A to the ice pool cofferdam, stadium chairs, hockey ice rink,

露天結構體、雪場吊車1h R 琢巾旱）、魚缸、眼用產品、裝飾用障蔽 窗及汽車内觀（儀錶群）。 本發明進-步關於本文中所述之瓶子。將聚醋製成瓶子 之方法係為此項技藝中所習知。瓶子之實例包括但不限於 以下瓶子，譬如藥物用拖· 臼名 切用瓶，4c兒瓶，水瓶；汁液瓶；大的 商用水瓶’具有重量為至8⑽克；飲料瓶，其包括但不 限於兩升瓶、20盘司瓶、16·9盘司瓶；醫藥用瓶；個人護 理用瓶、碳酸化清涼飲料瓶；熱充填瓶；水瓶；醇性飲料 版，譬如啤酒瓶與葡萄酒瓶；及包含至少—個把柄之瓶 子。此等瓶子包括但不限於射出吹製瓶、射出延伸吹製 瓶、擠Μ吹製觀及擠壓延伸吹製瓶。製造瓶子之方法包括 但不限於擠壓吹製、擠壓延伸吹製、射出吹製及射出延伸 吹製^各情況中’本發明進一步關於用以製造各該航子 之預成形物（或迷料）。 此等瓶子包括但不限於射出吹製瓶、射出延伸吹製瓶、 擠壓吹製瓶及擠壓延伸吹製瓶。製造瓶子之方法包括但不 限於擠壓吹製、擠壓延伸吹製、熱成型、射出吹製及射出 延伸吹製。 容器之其他實例包括但不限於供化粧品與個人護理應用 119732.doc -291- 200804457 之容器，包括沲；^ 、 于、廣口瓶、小玻瓶及管件；滅菌容器； 餐平& 1、鍋，食物淺盤或盤子；冷凍食品盤子；可微 ?食物盤子；熱充填容器、非晶質蓋或薄片，以密封或覆 蓋艮物血子’ R物儲存容器，例如箱子、轉鼓、水壺、杯 子、碗，包括但不限於被使用於餐廳小器具者；飲料容 器；密封條封口食物容器；離心機轉筒；冑空清潔器罐， 及收集與處理罐。 本文所述I廳小為具” 一詞意指任何使用於飲食或供食 之容器。餐廳小器具之實例包括水壺、杯子、視需要含柄 之馬克杯（包括裝飾性馬克杯、單壁或雙壁馬克杯、加壓 馬克杯、真空馬克杯）、碗（例如餐碗、湯碗、沙拉碗）及盤 (例如餐盤，如自助餐盤、淺碟及晚餐盤）。 於一具體實施例中，用作餐廳小器具之容器可耐受大於 0°C (例如2°C)至5°C之冷藏溫度。於另一具體實施例中，餐 廳小器具容器可耐受蒸汽處理及/或商業洗碗機條件。於 另一具體實施例中，餐廳小器具容器可耐受微波條件。於 一具體實施例中，餐廳小器具容器具有至少一種選自韋刃 性、清澈性、耐化學品性、Tg、水解穩定性及洗碗機穩定 性之性質。 於一具體實施例中，含有本發明聚酯組合物之醫藥裝置 包括，但不限於，含有紫外光（UV)可硬化、以聚石夕氧為主 之塗層之醫藥裝置，該醫藥裝置包含含有環丁二醇之聚 酯，該塗層位於醫藥裝置表面之至少一部分，其可改善蛋 白質抗性及生物可相容性、可塗覆於各種基材上且克服先 119732.doc -292- 200804457 前揭示方法中所遭遇之數種困難。 於-：體實施例中’本發明包含含有任何本文中所述組 士壯_从 片材形式，且具有嵌入其 中之裝飾性材料。 本文所述"食物儲存容器"意指其在一般用於儲存及/或供 應食物及/或飲料之溫度下（由冷束溫度至如低溫烤箱或教 飲機之高溫），可儲在月/ $也虛上 …、 存及或供應熱及/或冷食物及/或飲 料。於一具體實施例中，食物 抑 物氧化速度。於另—且體實施密封以減低食 具體實_巾，食物料容器可用於 展=供應食物給進餐顧客。於一具體實施例中’食物儲 存谷盗可用於冷;東櫃中儲存食物，例如低於代之溫 如-a至η：(如]8。〇)。於—具體實施例中，食物儲存容 益可用於冷滅櫃中儲存食物，例如大於代至代之溫度 =匕於一具體實施例中’食物儲存容器可财受蒸汽處 n先碗機條件。於另—具體實施財，食 存容器可耐受微波條件。 食物儲存容器之實例包括，但不限於，自助餐平底基 :二助餐平底蒸盤、食物淺盤、熱飲機及冷飲機(例如 ’人、自動熱飲機或冷飲機)及食物儲存箱。 於-具體實施例中’食物儲存容器具有至少一種選自動 性m耐化學品性、Tg及水解穩定性之額外性質。 :本發明之-具體實施例中，提供一種藉由施加熱及壓 =多種積層物或”三明治結構"而獲得之熱塑性物 ，、至少-種所述積層物依序包含⑴至少—層位於上 119732.doc 200804457 方之薄片材料，（2)至少一種裝飾性材料及（3)至少一種位. 於下方之薄片材料。視需要，可於（1)及（2)之間及/或（2)及 (3)之間使用一黏合層。”三明治結構”之（丨）、（2)及/或（3)中 任何一者可包含本發明之任何組合物。 本文所用”眼用產品”意指有度數眼鏡鏡片、無度數眼鏡 鏡片、太陽眼鏡鏡片、及眼鏡及太陽眼鏡鏡框。 於一具體實施例中，眼用產品係選自染色眼鏡鏡片及加 硬眼鏡鏡片。於一具體實施例中，眼鏡鏡片，例如染色眼 鏡鏡片及加硬眼鏡鏡片，包含至少一種偏光膜或偏光添加 物。 於一具體實施例中，當此產品為鏡片時，其具有154至 1·56之折射係數。 於一具體實施例中，眼用產品可具有至少一種選自韋刀 性、清澈性、耐化學品性（例如可耐受鏡片清潔劑、油、 髮型產品等）、T g及水解穩定性之性質。 本文所用”戶外標諸’’ 一詞意指由本文所述聚酯形成之表 面，或含有以本文中所述聚酯或聚酯膜塗覆之符號（例如 數字、字母、字、圖畫等）、圖案或設計之表面。於_具 體實施例中，該標誌可耐受典型氣候條件，例如雨、雪、 冰刨、凍雨、高濕度、熱、風、陽光、或其組合，一段足 夠之時間，例如1天至數年或更久。 戶外標誌之實例包括’但不限於，廣告牌、霓虹燈廣告 牌、電致發光廣告牌、電廣告牌、螢光廣告牌及發光二極 體（LED)顯示器。其他例示性之標誌包括，但不限於， 119732.doc -294- 200804457 色標誌、乙烯裝飾標誌、熱成型標誌及加硬標誌。 於一具體實施例中，戶外標誌具有至少一種選自熱可成 型性、勤性、清澈性、耐化學品性及以之性質。 本文所用”販賣機展示面板，，一詞意指販賣機上之前或側 面板’其係供消費者觀看陳列販賣之物品或關於此等物品 之廣告之用。於一具體實施例中，販賣機展示面板係販賣 機之視覺上透明之面板，消費者可經由此觀看陳列販賣 之物品。於其他具體實施例中，販賣機展示面板可具有足 夠硬度以容納内容物於機器之中及/或防止故意破壞及/或 偷竊。 於一具體實施例中，販賣機展示面板可具有技藝中廣泛 知悉之尺寸，例如用於零食、飲料、爆米花或郵票/票卡 販貝機之平面展示面板或用於口香糖販賣機或糖果販賣機 之膠囊狀展示面板。 於一具體實施例中，販賣機展示面板可視需要包含廣告 媒介或產敏識別指標。此等資訊可由技藝中廣泛知悉^方 法施加’例如絲網印刷。 ；/、體實施例中，販賣機展示面板可承受—1 〇 〇 °C至 120丨C之間之溫度。於另一具體實施例中，藉由添加例如 至少-種本文中所述之Uv添加劑，Μ賣機展示面板具有 抗UV性。 於一具體實施例中，販賣機展示面板具有至少一種選自 熱可成型性、韌性、清澈性、耐化學品性及Tg之性質。 本文所用”購買展示處”一詞意指全部或部分封閉之盒 119732.doc 200804457 子，其具有至少-個視覺上透明之面板以供展示物件之 用。購買展示處時常用於零售店中，以供達到抓住消費者 目光之目的。購買展示處之實例包括，但不限於，密封之 牆架、檯面板、密封之佈告座、展示盒（例如紀念品展示 盒）、標誌框架及供電腦光碟（例如cd&dvd)用之盒。購 買展示處可包括搁板及額外之容器，例如雜誌或小冊子用 之支托物。於此技術領域中具有通常知識者依據所欲展示 之物件可立即地想像購買展示處之形狀及尺寸。舉例言 展示處可如同珠寶盒一般小’或可為供展示多項紀念 品之較大橋植。 於一具體實施例中，購買展示處具有至少一種選自動 性、清澈性、耐化學品性、Tg&水解穩定性之性質。 本文所用"靜脈内裝置，，一詞意指由聚合性材料製得之組 件’其係用於將流體（例#藥物及營養素）施加至病人金液 中。於一具體實施例卜靜脈内裝置係一堅硬組件。 靜脈内裝置之實例包括γ接頭配件、luer組件、濾器、 止水拴、歧管及閥。Y接頭具有"Y”形狀，包括具第一通道 之第一臂、具第二通道之第二臂及與第一臂及第二臂連接 之第三臂’其具有與第一通道及第二通道連通之第三通 道。luer組件可包括luerl〇eks、接頭及閥。 +於-具體實施例中，靜脈内裝置可财受殺菌處理，例如 咼壓蒸汽殺菌、環氧乙烷氣體殺菌、輻射殺菌及乾熱殺 菌。於一具體實施例中，靜脈内裝置具有至少一種選自勃 性、清澈性、耐化學品性、Tg及水解穩定性之性質。 119732.doc -296- 200804457 本文所用"透析渡器外殼"一詞意指具有複數個用於支樓 中空纖維或管之開口之保護性外殼，該中空纖維或管係: 於將透析液導入或排出患者。於一具體實施例中，保護性 外殼之一開口之橫截面積為0.001平方公分至少於5〇平方 公分。 於一具體實施例中，透析濾器外殼具有至少一種選自韌 性、清澈性、耐化學品性、Tg及水解穩定性之性質。¥ 本文所用"血液治療容器"一詞意指該等供施加血液至患 者及自患者抽取血液用之容器。血液治療容器之實例包ς 和氧器、卡式盒、離心碗、收集及處理罐、泵芯、㈣ port外殼及透析器外殼。和氧器可自患者靜脈血液中移除 二氧化碳’將氧氣導入抽取出之企液中使其轉換成動脈 血，然後再將充氧血導入患者體内。其餘容器可用於暫時 儲藏抽取或儲存血，在其被施加至患者之前。 :-具體實施例中，血液治療容器可耐受殺菌處理，例 如门壓1忒权g ί裒氧乙烷氣體殺菌、輻射殺菌及乾熱殺 菌。於一具體實施例中，血液治療容器具有至少一種選自 韌性、清澈性、耐化學品性、TgA水解穩定性之性質。 本文所用”器具部件”一詞意指用於連結器具之堅硬件。 於〃體實知例中，器具部件可部分或全部與器具分離。 於-具體實施例中，器具部件係典型由聚合物製得者。於 -錢J施例中，器具部件係視覺上透明的。 态:邛件之實例包括該等必須具備韌性及耐久性者，例 /、R U加工機、攪拌器、攪拌機及切碎機使用之杯及 119732.doc -297- 200804457 碗’可耐受冷藏及冷凍溫度（例如大於例如2〇c)至5〇c 之冷藏溫度或低於(TC之冷凍溫度（例如-2〇至，例如_18 °c))之部件，例如冷藏櫃及冷凍櫃拖盤、箱及擱板；在高 達90 C具有足夠水解穩定性之部件，例如清洗機門板、蒸 汽吸塵器冑、茶壺及咖啡壺；及真空吸塵器罐及塵杯。 於一具體實施例中，器具部件具有至少一種選自韌性、 清澈性、耐化學品性、Tg、水解穩定性及洗碟機穩定性之 性質。器具部件亦可選自蒸汽吸塵器罐，#，於一具體實 鉍例中，可具有至少一種選自韌性、清澈性、耐化學品 性、Tg及水解穩定性之性質。 於一具體實施例中，可用於器具部件之聚S旨具有105至 140 C之Tg ’且器具部件係選自真空吸塵器罐及塵杯。於 另-具體實施例中，可用於器具部件之聚酉旨具有12〇至15〇 。。之丁8，且器具部件係選自蒸汽吸塵器罐、茶壺及咖啡 壺0 本文所用"天窗"-詞意指光可穿透板板，其牢固於屋頂 表面而形成天花板之-部份。於—具體實施例中，後板為 堅更的合%足以達到穩定性及耐久性之尺寸，且技藝 人士可立即地決定該等尺寸。於—具體實施例中，天窗嵌 板具有大於3/16英奴厚度，例如至少1/2英时之厚度。 於’、體貝施例中，天窗嵌板係視覺上透明的。於一具 體實施例中’ &窗嵌板可傳送至少35%可見光，、至 50%，至少 75%，至少 8〇()/ ^ f 〇至乂 90%，或甚至至少95%可 見光。於一具體實施例中，&窗丧板包括至少-種而添 119732.doc .298· 200804457 加劑，其允許天窗嵌板阻擋高達_、9G%或高達95% uv 光。 於具體實施例中，天窗嵌板可具有至少一種選自熱成 型性、韌性、清澈性、耐化學品性及、之性質。 本文所用”戶外庇護所，，一詞意指可針對自然力（例如陽 光、雨、雪 '風及寒冷等）提供至少一些防護之屋頂及域 牆型結構，其具有至少—個堅固欲板。於—具體實施例 中，戶外庇護所具有至少一個屋頂及/或一或多個牆。於 -具體實施例中，戶外庇護所具有足以達到穩定性及耐久 性之尺寸，且技藝人士可立即地決定該等尺寸。於一具體 實施例中，戶外庇護所嵌板具有大於3/16英吋之厚度。 於一具體實施例中，戶外庇護所嵌板係視覺上透明的。 於一具體實施例中，戶外庇護所嵌板可傳送至少35%可見 光，至少50%，至少75%，至少8〇%，至少9〇%，或甚至至 少95%可見光。於一具體實施例中，戶外庇護所嵌板包括 至少一種uv添加劑，其允許戶外庇護所阻擋高達8〇%、 90%或高達95% UV光。 戶外庇護所之實例包括安全鑲嵌玻璃、運輸候車亭（例 如公車候車亭）、電話亭及抽煙亭。於一具體實施例中， 當戶外庇護所係運輸候車亭、電話亭或抽煙亭時，其具有 至少一種選自熱成型性、韌性、清澈性、耐化學品性及Tg 之性質。於一具體實施例中，當戶外庇護所係安全鑲嵌玻 璃時，其具有至少一種選自韌性、清澈性、耐化學品性及 Tg之性質。 H9732.doc •299· 200804457 本文所用"頂篷"一詞意指 雪、風及寒冷等）提供至少力（例如陽光、雨、 體實施例中，屋頂型結構戶外;二=頂結構。於-具 , 邊所具有’全部或部分， 尺板，例如具有足以達到穩定性及耐久性之 可立即地決定該等尺寸。於-具體實施 頂蓬欣板具有大於3/16英时之厚度，例如至少1/2英 吋之厚度。 於-具體實施例中，頂篷嵌板係視覺上透明的。於一具 體實施例巾’頂篷嵌板可傳送至少35%可見光，至少 鄉，至少75%，至少8G%，至少9G%，或甚至至少95%可 見光。於一具體實施例中，頂篷嵌板包括至少一種。乂添 加劑，其允許頂篷阻擋咼達80%、90%或高達95。/。UV光。 頂篷之實例包括經遮蔽走道、採光天窗、日光室、飛機 座艙罩及雨篷。於一具體實施例中，頂篷具有至少一種選 自韌性、清澈性、耐化學品性、Tg及彈性之性質。 本文所用π聲障” 一詞意指一堅硬結構，其可降低聲音從 此結構一側之一處至此結構另一側之另一處之穿透量，相 較於沒有聲障時介於此相同距離之兩處之聲音穿透量而 言。降低聲音穿透量之效力可藉由技藝中已知方法評估。 於一具體實施例中，降低之聲音穿透量在25%至90%之範 圍内。 於一具體實施例中，聲障可以透聲分類值分級，如同， 例如ASTM Ε90(建築隔間隔音測試法（Standard Test Method for Laboratory Measurement of Airborne Sound 119732.doc -300- 200804457Open-air structures, snowmobile cranes 1h R 旱 towel), fish tanks, ophthalmic products, decorative barrier windows and car interiors (instrument group). The invention proceeds further with regard to the bottles described herein. The method of making a vinegar into a bottle is well known in the art. Examples of bottles include, but are not limited to, bottles such as drug tweezers, bottles, 4c bottles, water bottles; juice bottles; large commercial water bottles having a weight of up to 8 (10) grams; beverage bottles, including but not limited to Two-liter bottle, 20-disc bottle, 16.9 plate bottle; medical bottle; personal care bottle, carbonated refreshing bottle; hot-fill bottle; water bottle; alcoholic beverage version, such as beer bottle and wine bottle; A bottle containing at least one handle. Such bottles include, but are not limited to, injection blown bottles, injection stretch blow bottles, squeeze blown views, and extrusion stretch blow bottles. Methods of making bottles include, but are not limited to, extrusion blow molding, extrusion stretch blow molding, injection blow molding, and injection stretch blow molding. [The present invention further relates to preforms (or fans) for making each of the carriers. material). Such bottles include, but are not limited to, injection blow bottles, injection stretch blow bottles, extrusion blow bottles, and extrusion stretch blow bottles. Methods of making the bottle include, but are not limited to, extrusion blow molding, extrusion stretch blow molding, thermoforming, injection blow molding, and injection stretch blow molding. Other examples of containers include, but are not limited to, containers for cosmetics and personal care applications 119732.doc -291-200804457, including 沲;, ,, jars, vials, and fittings; sterilization containers; meal & Pots, food trays or plates; frozen food trays; micro-food trays; hot-fill containers, amorphous lids or sheets to seal or cover the blood of the stools, such as boxes, drums, kettles , cups, bowls, including but not limited to those used in restaurant gadgets; beverage containers; sealed strip sealed food containers; centrifuge drums; hollow cleaner tanks, and collection and treatment tanks. The term "I Hall" as used herein means any container used for eating or serving. Examples of restaurant utensils include kettles, cups, mugs with handles as needed (including decorative mugs, single wall or Double-walled mugs, pressurized mugs, vacuum mugs, bowls (eg bowls, soup bowls, salad bowls) and dishes (eg dishes such as buffet plates, saucers and dinner plates). The container used as a restaurant widget can withstand refrigeration temperatures greater than 0 ° C (eg, 2 ° C) to 5 ° C. In another embodiment, the restaurant widget container can withstand steam treatment and/or Commercial dishwasher condition. In another embodiment, the restaurant appliance container can withstand microwave conditions. In one embodiment, the restaurant appliance container has at least one selected from the group consisting of sharp edges, clarity, and chemicals. Properties, Tg, hydrolytic stability, and stability of the dishwasher. In one embodiment, the medical device containing the polyester composition of the present invention includes, but is not limited to, ultraviolet light (UV) hardenable, poly Shi Xi oxygen-based coating doctor A device comprising a cyclobutanediol-containing polyester disposed on at least a portion of a surface of a medical device that improves protein resistance and biocompatibility, can be applied to various substrates, and overcomes 119732.doc -292- 200804457 Several difficulties encountered in the methods disclosed above. In the ":" embodiment, the present invention encompasses any of the compositions described herein, and has a decorative form embedded therein. Sexual material. The "food storage container" as used herein means the temperature at which it is generally used for storage and/or supply of food and/or beverages (from cold beam temperature to high temperatures such as low temperature ovens or teaching machines). It can be stored in the month / $ also on the ..., save and or supply hot and / or cold food and / or beverage. In a specific embodiment, the food inhibits the oxidation rate. In addition - and the body is sealed to reduce food specific The food container can be used for the display of food to the food customer. In a specific embodiment, the food storage grain can be used for cold; the food stored in the east cabinet, for example, lower than the temperature of the like -a to η: (eg] 8. 〇). In the embodiment, the food storage capacity can be used to store food in the cold-extinguishing cabinet, for example, the temperature is higher than the generation== In a specific embodiment, the food storage container can be subjected to the steaming condition. - The specific implementation of the food storage container can withstand microwave conditions. Examples of food storage containers include, but are not limited to, buffet flat base: two-serve flat-bottom steaming pan, food tray, hot drinks machine and cold drink machine (such as 'people, Automatic hot drink machine or cold drink machine) and food storage box. In a specific embodiment, the 'food storage container has at least one additional property of selective chemical resistance, chemical resistance, Tg and hydrolytic stability. In the example, a thermoplastic obtained by applying heat and pressure = a plurality of laminates or "sandwich structure" is provided, and at least one of the laminates comprises (1) at least the layer is located above 119732.doc 200804457 a sheet material, (2) at least one decorative material, and (3) at least one sheet material underlying. An adhesive layer may be used between (1) and (2) and/or between (2) and (3) as needed. Any of (丨), (2) and/or (3) of the "sandwich structure" may comprise any of the compositions of the present invention. As used herein, "ophthalmic product" means a lens having a degree, a lens without a degree, a lens for a pair of sunglasses, and a frame for glasses and sunglasses. In one embodiment, the ophthalmic product is selected from the group consisting of a dyed eyeglass lens and a hardened eyeglass lens. In one embodiment, the spectacle lens, such as a dyed ophthalmic lens and a hardened spectacle lens, comprises at least one polarizing film or polarizing additive. In one embodiment, when the product is a lens, it has a refractive index of 154 to 1.56. In one embodiment, the ophthalmic product can have at least one selected from the group consisting of scalpel, clear, chemical (eg, lensable, oil, hair, etc.), Tg, and hydrolytic stability. nature. The term "outdoor label" as used herein refers to a surface formed from the polyesters described herein, or a symbol (eg, numbers, letters, words, drawings, etc.) coated with a polyester or polyester film as described herein. Surface of a pattern or design. In particular embodiments, the sign can withstand typical climatic conditions such as rain, snow, ice planing, freezing rain, high humidity, heat, wind, sunlight, or a combination thereof for a sufficient period of time For example, 1 day to several years or longer. Examples of outdoor signs include 'but not limited to, billboards, neon billboards, electroluminescent billboards, electric billboards, fluorescent billboards, and light-emitting diodes (LEDs). Other exemplary signs include, but are not limited to, 119732.doc -294-200804457 color mark, vinyl decorative mark, thermoformed mark, and hardened mark. In one embodiment, the outdoor sign has at least one selected from the group consisting of heat Formability, diligence, clarity, chemical resistance and properties. The term "selling machine display panel," means the front or side panel of a vending machine. The items on sale or advertising of these items of use. In one embodiment, the vending machine display panel is a visually transparent panel of the merchandiser through which the consumer can view the merchandise for sale. In other embodiments, the vending machine display panel can be sufficiently rigid to contain contents in the machine and/or to prevent vandalism and/or theft. In one embodiment, the vending machine display panel can be of a size that is widely known in the art, such as a flat display panel for snacks, beverages, popcorn or stamp/cards, or for chewing gum vending machines or candy sales. The capsule display panel of the machine. In one embodiment, the vending machine display panel may optionally include an advertising medium or a production sensitivity indicator. Such information may be widely known in the art of application, such as screen printing. In the embodiment, the vending machine display panel can withstand a temperature between -1 〇 〇 ° C and 120 ° C. In another embodiment, the vending machine display panel is UV resistant by the addition of, for example, at least one of the Uv additives described herein. In one embodiment, the vending machine display panel has at least one property selected from the group consisting of thermoformability, toughness, clarity, chemical resistance, and Tg. As used herein, the term "purchase display" means a fully or partially enclosed box 119732.doc 200804457 having at least one visually transparent panel for use in displaying objects. Buying showrooms is often used in retail stores to capture the eyes of consumers. Examples of purchase displays include, but are not limited to, sealed wall frames, countertops, sealed bulletinators, display boxes (such as souvenir display boxes), sign frames, and boxes for computer discs (such as cd&dvd). Purchase displays can include shelves and additional containers, such as magazines or booklets. Those having ordinary skill in the art can immediately imagine the shape and size of the display according to the object to be displayed. For example, the display can be as small as a jewel case or can be a larger bridge for displaying multiple commemorative items. In one embodiment, the purchase display has at least one property selected for automation, clarity, chemical resistance, Tg & hydrolytic stability. As used herein, "intravenous device," means a component made of a polymeric material' that is used to apply fluids (e.g., drugs and nutrients) to a patient's gold solution. In a specific embodiment, the intravenous device is a rigid component. Examples of intravenous devices include gamma fittings, luer components, filters, water stop, manifolds, and valves. The Y connector has a "Y" shape, including a first arm having a first passage, a second arm having a second passage, and a third arm coupled to the first arm and the second arm, having a first passage and a The third channel is connected to the second channel. The luer assembly can include luerl〇eks, joints, and valves. In the specific embodiment, the intravenous device can be sterilized, such as steam sterilization, ethylene oxide gas sterilization, Radiation sterilization and dry heat sterilization. In one embodiment, the intravenous device has at least one property selected from the group consisting of bovine, clear, chemical, Tg, and hydrolytic stability. 119732.doc -296- 200804457 The term "dialysis vessel casing" means a protective casing having a plurality of openings for the hollow fiber or tube of the branch, the hollow fiber or tube system: for introducing or discharging the dialysate into the patient. In one embodiment, the opening of one of the protective outer casings has a cross-sectional area of 0.001 square centimeter of at least 5 square centimeters. In one embodiment, the dialysis filter housing has at least one selected from the group consisting of toughness, clarity, chemical resistance, T g and the nature of hydrolytic stability. The term "blood treatment container" as used herein means the container for applying blood to and from the patient. Examples of blood treatment containers include oxygen and card Box, centrifuge bowl, collection and treatment tank, pump core, (4) port shell and dialyzer shell. And oxygen can remove carbon dioxide from the patient's venous blood'. Introduce oxygen into the extracted liquid to convert it into arterial blood. The oxygenated blood is then introduced into the patient. The remaining containers can be used for temporary storage or storage of blood before it is applied to the patient.: - In particular embodiments, the blood treatment container can withstand sterilization, such as door pressure 1 Sterilization, radiation sterilization, and dry heat sterilization. In one embodiment, the blood treatment container has at least one property selected from the group consisting of toughness, clarity, chemical resistance, and TgA hydrolytic stability. The term "apparatus component" as used herein refers to a hardware used to attach an appliance. In the embodiment of the body, the appliance component may be partially or completely separated from the appliance. In the case of the appliance, the component is typically made of a polymer. In the example of the device, the component of the device is visually transparent. Examples: Examples of the component include such toughness and durability, eg, RU Cups for processing machines, blenders, blenders and shredders and 119732.doc -297- 200804457 bowls can withstand refrigeration and freezing temperatures of freezing and freezing temperatures (eg greater than eg 2〇c) to 5〇c or below ( Parts of the TC's freezing temperature (eg -2 〇 to, eg _18 °c), such as refrigerated cabinets and freezer trays, boxes and shelves; parts with sufficient hydrolytic stability up to 90 C, such as washing machines Door panels, steam cleaners, teapots and coffee makers; and vacuum cleaner tanks and dust cups. In one embodiment, the appliance component has at least one property selected from the group consisting of toughness, clarity, chemical resistance, Tg, hydrolytic stability, and dishwasher stability. The appliance component may also be selected from a steam cleaner can, #, in a specific embodiment, may have at least one property selected from the group consisting of toughness, clarity, chemical resistance, Tg, and hydrolytic stability. In one embodiment, the concentrating S that can be used for the appliance component has a Tg' of 105 to 140 C and the appliance component is selected from the group consisting of a vacuum cleaner can and a dust cup. In another embodiment, the set of components that can be used for the appliance has a 12 to 15 inch. . Ding 8, and the appliance components are selected from the group consisting of a steam cleaner jar, a teapot, and a coffee maker. The "skylight" used herein refers to a light transmissive panel that is secured to the roof surface to form a portion of the ceiling. In a particular embodiment, the back panel is of a firmer size sufficient to achieve stability and durability, and the skilled artisan can immediately determine the dimensions. In a particular embodiment, the sunroof panel has a thickness greater than 3/16 ny, such as at least 1/2 inch. In the case of the body, the skylight panel is visually transparent. In one embodiment, the & window panel can deliver at least 35% visible light, up to 50%, at least 75%, at least 8 〇 () / ^ f 〇 to 乂 90%, or even at least 95% visible light. In one embodiment, the & window panel includes at least one additive 119732.doc .298. 200804457 additive that allows the skylight panel to block up to _, 9G% or up to 95% uv light. In a particular embodiment, the sunroof panel can have at least one property selected from the group consisting of thermal formability, toughness, clarity, chemical resistance, and the like. As used herein, the term "outdoor shelter" means a roof and domain wall structure that provides at least some protection against natural forces (such as sunlight, rain, snow 'wind and cold, etc.), which has at least a strong plate. In a specific embodiment, the outdoor shelter has at least one roof and/or one or more walls. In a particular embodiment, the outdoor shelter has dimensions sufficient for stability and durability, and the skilled person can immediately decide In a specific embodiment, the outdoor shelter panel has a thickness greater than 3/16 inches. In one embodiment, the outdoor shelter panel is visually transparent. In one embodiment The outdoor shelter panel can deliver at least 35% visible light, at least 50%, at least 75%, at least 8%, at least 9%, or even at least 95% visible light. In one embodiment, the outdoor shelter panel Includes at least one uv additive that allows outdoor shelters to block up to 8〇%, 90% or up to 95% UV light. Examples of outdoor shelters include safety inlaid glass, transport shelters (eg bus shelters) a telephone booth and a smoking booth. In an embodiment, when the outdoor shelter is a transport shelter, a telephone booth or a smoking booth, it has at least one selected from the group consisting of thermoformability, toughness, clarity, chemical resistance, and Tg. In a specific embodiment, when the outdoor shelter is safely inlaid with glass, it has at least one property selected from the group consisting of toughness, clarity, chemical resistance and Tg. H9732.doc •299· 200804457 used herein. The term "canopy" means snow, wind and cold, etc.) to provide at least force (eg sunlight, rain, body embodiment, roof-type structure outdoors; two = top structure. - with, with "all or part of the side" The ruler, for example having sufficient stability and durability, can immediately determine the dimensions. The embodiment has a thickness greater than 3/16 inches, such as at least 1/2 inch. In a specific embodiment, the canopy panel is visually transparent. In one embodiment, the canopy panel can transmit at least 35% visible light, at least 75%, at least 8 G%, at least 9 G%, Or even at least 95% In a specific embodiment, the canopy panel includes at least one enamel additive that allows the canopy to block up to 80%, 90%, or up to 95% of UV light. Examples of canopies include shaded walkways A skylight, a sunroom, an aircraft canopy, and an awning. In one embodiment, the canopy has at least one property selected from the group consisting of toughness, clarity, chemical resistance, Tg, and elasticity. The term means a rigid structure that reduces the amount of penetration of sound from one side of the structure to the other of the other side of the structure, compared to two sounds at the same distance without a sound barrier. In terms of penetration, the effectiveness of reducing the amount of sound penetration can be assessed by methods known in the art. In one embodiment, the reduced sound penetration is in the range of 25% to 90%. In one embodiment, the acoustic barrier can be classified by sound grading, as in, for example, ASTM Ε90 (Standard Test Method for Laboratory Measurement of Airborne Sound 119732.doc -300-200804457

Transmission Loss of Building Partition))及 ASTM E413(聲 音傳送分級測定法（Classification of Rating Sound Insulation))中所述。STC 55障蔽物可將喷射機引擎聲音 (〜130分貝）降低至60分貝（落於典型辦公室之音量範圍）。 隔音室可具有0至20分貝之音量大小。技藝人士可建構及 配置音障以達到所欲STC級別。於一具體實施例中，聲障 具有至少20之STC級別，例如20至60之級別。 於一具體實施例中，聲障包含複數個嵌板，其經連結及 配置以達成所欲障蔽物外形。可沿著街道及高速公路使用 聲障以抑制汽車噪音。另外，可於住家或辦公室使用聲 障’作為不連續單一嵌板或複數個嵌板，或插入牆壁、地 板、天花板、門板及/或窗戶結構中。 於一具體實施例中，聲障係視覺上透明的。於一具體實 施例中，聲障可傳送至少35%可見光，至少5〇%，至少 75%，至少80%，至少90%，或甚至至少95%可見光。於一 具體實施例中，聲障包括至少一種uv添加劑，其允許聲 障阻播高達8〇%、90%或高達95% UV光。 於一具體實施例中，聲障具有至少一種選自韌性、清澈 性、耐化學品性及Tg之性質。 本文所用’’溫室”一詞意指用於植物耕種及/或保護之封閉 結構。於一具體實施例中，溫室可維持耕種植物所欲之濕 又及氣體（氣氣、一氧化碳及氮氣等）含量，且同時可針對 自然力（例如陽光、雨、雪、風及寒冷等）提供至少_些防 護。於一具體實施例中，溫室屋頂具有，全部或部分，至 119732.doc 200804457 少-個堅固嵌板，例如具有足以達到穩定性及财久性之尺 寸’且技藝人士可立即地決定該等尺寸。於一具體實施例 中，溫室喪板具有大於3/16英时之厚度，例如至少1/2英时 之厚度。 於-具體實施例中，溫錢㈣視覺上透明的。於一具 體實加例巾’實質上所有溫室之屋頂及牆壁係視覺上透明 的於具體實施例中，溫室後板可傳送至少35%可見 光至/ 50/〇，至少75〇/。，至少8Q%，至少，&甚^ 少95%可見光。於—具體實施例中，s室欲板包括至少一 種uv添加齊！，其允許溫室嵌板阻擒高達嶋、嶋或高達 95% UV光。 於-具體實施例中，溫室具有至少一種選自韌性、清澈 性、耐化學品性及Tg之性質。 、本文所用，，光學媒介，，—詞意指其中資訊係藉由使用雷射 光（例如於可見光波長之光，諸如具有600至700奈米波 光）輻射δ己錄之資訊儲存媒介。藉由雷射光輻射，記 2層之i"輻射區域局部地受熱而改變其物理或化學特性， 2而忑錄層之經輻射區域形成凹陷。由於所形成凹陷之光 、不同於忒等未經輻射區域，數位資訊從而被光學性 地.己錄。經記錄資訊可藉由重製程序加以讀取，重製程序 一般而言包括以具有與用於記錄程序相同波長之雷射光輻 射'己錄層，及偵測介於凹陷及周圍之光反射差異之步驟。 、，一具體實施例中，光學媒介包含具有螺旋形預溝槽之 透月碟、置於預溝槽之中之記錄染料層，於其上資訊藉由 119732.doc 200804457 雷射光輻射記錄及光反射層。光學媒介可視需要由消費者 紀錄。於一具體實施例中，光學媒介係選自光碟（CDs)及 數位視訊影碟（DVDs)。光學媒介可以具有預紀錄資訊之形 式販售，或以可記錄碟之形式販售。 於一具體實施例中，至少一種下例物質包含根據本發明 之聚酯’·基板、光學媒介之至少一種保護層及光學媒介之 記錄層。 於一具體實施例中，光學媒介具有至少一種選自韌性、 清澈性、耐化學品性、以及水解穩定性之性質。 本文所用”嬰兒護理殺菌容器”一詞意指安裝用以容納嬰 兒護理產品以供嬰兒護理產品居家殺菌之容器。於一具體 實施例中，嬰兒護理殺菌容器係奶瓶殺菌容器。 於一具體實施例中，嬰兒護理殺菌容器具有至少一種選 自韌性、清澈性、耐化學品性、Tg、水解穩定性及洗碗機 穩定性之性質。 本文所用”奶嘴”包含以堅硬嘴擋板環繞之乳頭狀突起物 (例如，供嬰兒吸允及/或咬），其中堅硬嘴擋板視需要連接 有把手，其係供嬰兒或監督成人緊握及/或握持奶嘴之便 利結構。把手可為堅硬的或彈性的。 於一具體實施例中，奶嘴可由多重組件製得。例如，乳 頭狀突起物可穿過嘴擋板中間孔洞。把手可（或不可）整體 性的連接至嘴擋板。把手可為堅硬的或彈性的。 於另-具體實施例中，奶嘴之乳頭狀突起物及嘴擔板係 以-整體早兀方式形成。一般而言，塑膠的選擇係取決於 119732.doc -303 - 200804457 提供相對堅硬嘴擋板及把手之需求。於一具體實施例中， 奶嘴之乳頭狀突起物可較堅硬但仍然可供嬰兒吸允及/或 咬。 於一具體實施例中，奶嘴具有至少一種選自韌性、清澈 性、耐化學品性、Tg、水解穩定性及洗碗機穩定性之性 本文所用”密封條封口食物容器”一詞意指用於儲存食物 及/或飲料之彈性容器或袋，其中食物及/或飲料係密封其 中供長期非冷凍儲存。密封條封口食物容器可包含至少一 種聚醋I ’例如單層或多層容器。於—具體實施例中，多 層谷器包含光反射内層，例如金屬薄膜。 於-具體實施例中，至少一種選自蔬菜、水果、榖物、 尉、肉、肉產品、乳品、醬料、調味料及供培用品之食材 係含納於後封條封口食物容器中。 於-具體實施例中，密封條封口食物容器具有至少一種 選自韌性、清激性、耐化學品性、Tg及水解穩定性之性 本文所用’，玻璃稽居铷”^ 一.Transmission Loss of Building Partition)) and ASTM E413 (Classification of Rating Sound Insulation). The STC 55 baffle reduces the jet engine sound (~130 dB) to 60 decibels (which falls within the typical office volume range). The soundproof room can have a volume of 0 to 20 decibels. Skilled people can construct and configure sound barriers to achieve the desired STC level. In one embodiment, the acoustic barrier has an STC rating of at least 20, such as a level of 20 to 60. In one embodiment, the acoustic barrier includes a plurality of panels that are coupled and configured to achieve the desired barrier shape. Sound barriers can be used along streets and highways to suppress car noise. Alternatively, the sound barrier can be used at home or in the office as a discontinuous single panel or panel, or into a wall, floor, ceiling, door panel, and/or window structure. In one embodiment, the acoustic barrier is visually transparent. In a specific embodiment, the acoustic barrier can deliver at least 35% visible light, at least 5%, at least 75%, at least 80%, at least 90%, or even at least 95% visible light. In one embodiment, the acoustic barrier comprises at least one uv additive that allows the acoustic barrier to block up to 8%, 90% or up to 95% UV light. In one embodiment, the acoustic barrier has at least one property selected from the group consisting of toughness, clarity, chemical resistance, and Tg. The term 'greenhouse' as used herein refers to a closed structure for plant cultivation and/or protection. In one embodiment, the greenhouse maintains the desired wetness and gas (air, carbon monoxide, nitrogen, etc.) of the cultivated plant. The content, and at the same time, provides at least some protection against natural forces (such as sunlight, rain, snow, wind, cold, etc.) In one embodiment, the greenhouse roof has, in whole or in part, to 119732.doc 200804457 less-sturdy The panels, for example, have dimensions sufficient for stability and durability, and the skilled artisan can immediately determine such dimensions. In one embodiment, the greenhouse panels have a thickness greater than 3/16 inches, such as at least 1 Thickness of /2 inches. In the specific embodiment, the warmth (four) is visually transparent. In a specific embodiment, the roof and wall of the greenhouse are substantially transparent in a specific embodiment, the greenhouse The backsheet can deliver at least 35% visible light to /50/〇, at least 75 〇/., at least 8Q%, at least, & 95% less visible light. In a particular embodiment, the s-room plate includes at least one uv Add to It allows the greenhouse panel to block up to 嶋, 嶋 or up to 95% UV light. In a particular embodiment, the greenhouse has at least one property selected from the group consisting of toughness, clarity, chemical resistance and Tg. , optical media, - means the information storage medium in which the information is transmitted by using laser light (for example, light of visible wavelengths, such as having 600 to 700 nm of light). By laser radiation, Note that the layer 2 i"radiation area is locally heated to change its physical or chemical properties, 2 and the radiant area of the smear layer forms a depression. Since the light formed by the depression is different from the unirradiated area such as 忒, the digital information Recorded information can be read by a re-programming process. The re-programming process generally includes the recording of the laser light with the same wavelength as the recording program, and the detection medium. The step of reflecting the difference between the light in the recess and the surrounding area. In one embodiment, the optical medium comprises a translucent disk having a spiral pre-groove, and a recording dye layer disposed in the pre-groove. Information is recorded by the 119732.doc 200804457 laser radiation recording and light reflecting layer. The optical medium may be recorded by the consumer as needed. In one embodiment, the optical medium is selected from the group consisting of compact discs (CDs) and digital video discs (DVDs). The medium may be sold in the form of pre-recorded information or sold as a recordable disc. In one embodiment, at least one of the following materials comprises at least one of the polyester's substrate, optical medium, according to the present invention. The recording layer of the layer and the optical medium. In one embodiment, the optical medium has at least one property selected from the group consisting of toughness, clarity, chemical resistance, and hydrolytic stability. The term "baby care sterilization container" is used herein. Refers to a container that is installed to hold a baby care product for home sterilization of baby care products. In one embodiment, the baby care sterilization container is a bottle sterilization container. In one embodiment, the baby care sterilization container has at least one property selected from the group consisting of toughness, clarity, chemical resistance, Tg, hydrolytic stability, and dishwasher stability. As used herein, a "nipple" includes a nipple that is surrounded by a hard mouth flap (for example, for a baby to suck and/or bite), wherein the hard mouth flap is attached with a handle as needed for the infant or supervising the adult to grip And / or a convenient structure for holding the pacifier. The handle can be hard or elastic. In one embodiment, the teat can be made from multiple components. For example, the nipple can pass through the middle hole of the mouth baffle. The handle can be (or cannot be) integrally attached to the mouthpiece. The handle can be hard or elastic. In another embodiment, the nipple nipple and the mouth slab are formed in an overall early manner. In general, the choice of plastic depends on the need for a relatively rigid mouth baffle and handle. 119732.doc -303 - 200804457. In one embodiment, the nipple's nipples may be stiffer but still allow the baby to absorb and/or bite. In one embodiment, the nipple has at least one selected from the group consisting of toughness, clarity, chemical resistance, Tg, hydrolytic stability, and stability of the dishwasher. The term "sealing strip sealed food container" as used herein means An elastic container or bag for storing food and/or beverages, wherein the food and/or beverage is sealed therein for long-term non-frozen storage. The weatherstrip food container may comprise at least one polyester I' such as a single or multi-layer container. In a particular embodiment, the multi-layered barn comprises a light reflecting inner layer, such as a metal film. In a specific embodiment, at least one food selected from the group consisting of vegetables, fruits, sorghum, sorghum, meat, meat products, dairy products, sauces, seasonings, and medicinal products is contained in a back seal sealed food container. In a specific embodiment, the weatherseal sealed food container has at least one property selected from the group consisting of toughness, clarification, chemical resistance, Tg, and hydrolytic stability, as used herein.

含超過一種含有本發明 種含有本發明聚酯組合物之塗層。 。於其他具體實 塗層， 片。玻 例中， 施加積， 面或兩 119732.doc -304· 200804457 施例中，玻璃積層物包含多重玻璃基材及超過一種含有本 發明聚S旨組合物之塗層。 玻璃積層物之實例包括窗玻璃（例如用於高樓建築及建 築物入口之窗玻璃）安全玻璃、用於運輸工具應用（例如汽 車、公車、噴射機、裝甲車）之擋風玻璃、防彈玻璃、保 王T璃（例如用於銀行）、防颱玻璃、飛機座艙罩、鏡子、 太陽玻璃肷板、平板顯示器及防爆玻璃。玻璃積層物可為 、兔上透月的、務狀的、餃刻狀的或圖案化的。 於一具體實施例中，玻璃積層物可抵抗_100至120。〇之 ’皿度。於另—具體實施例中，玻璃積層物可藉由添加例如 >'種如本文中所述之uv添加劑，從而具備抗性。 將本發明之薄膜及/或薄片層合至玻璃之方法係此技術 領：中具有通常知識者所熟知。不使用黏合層之層合方式 2由真空層合完成。A了在玻璃層及積層物間獲得有效 口於一具體實施例中，玻璃具有低表面糙度。 力或者，可使用雙面黏合帶、黏合層、或凝膠層（藉由施 加，例如，熱熔融物、壓感或熱感黏合劑而獲得）或UV或 電子束可硬化黏合劑將本發明積層物結合至玻璃。黏合層 了，加至玻璃薄片、積層物或兩者，且可藉由剝除層加以 保蠖，剝除層可於正要層合前移除。 於一具體實施例中，玻璃積層物具有至少一 性、清㈣、耐化學品性、水解穩定性ATg之性質。、 對本揭不内容之目的而言，，，重（wt)，，一詞係意謂置，，重 (weight)"。 H9732.doc -305- 200804457 下述實例係進一步說明本發明之聚酯可如何製造與評 估’且係意欲純粹為本發明之舉例，並非意欲限制其範 圍。除非另有指明，否則份數為重量份數，溫度係以度c 表不或係在室溫下，而壓力係在於或接近大氣壓。 實例 下述實例描述一般製備聚酯之方法，及與含丨〆-環己烷 二甲醇及/或乙二醇殘基但缺乏2,2,4,4_四甲基-13-環丁二 醇之聚酯比較時，使用2,2,4,4-四甲基-1，3-環丁二醇（及多 種順/反混合物）對於多種聚酯性質（韌度、玻璃轉移溫度、 固有黏度等）之效應。此外，根據下述實例，本發明所屬 領域中具有通常知識者將明瞭如何將本發明之熱安定劑用 以製備含彼等之聚酯之方法中。 度量方法 聚酯之固有黏度係在60/40(重量/重量）紛/四氣乙烷中， 於0.25克/50¾升之》辰度下’於25 °C下測定，且以公合/克 方式紀錄。 除非另有述及，否則玻璃轉移溫度係使用得自More than one coating comprising the polyester composition of the invention containing the invention. . For other specific coatings, tablets. In the glass case, the application of the product, the surface or the two 119732.doc -304.200804457, the glass laminate comprises a plurality of glass substrates and more than one coating comprising the composition of the present invention. Examples of glass laminates include glazing (such as glazing for high-rise buildings and entrances to buildings) safety glass, windshields for transportation applications (such as cars, buses, jets, armored vehicles), bullet-proof glass, Baowang T-glass (for example, for banks), anti-Taiwan glass, aircraft canopy, mirror, solar glass fascia, flat panel display and explosion-proof glass. The glass laminate can be a rabbit, a moon-shaped, a haggard, a dumpling or a pattern. In one embodiment, the glass laminate is resistant to _100 to 120. 〇之 ” In another embodiment, the glass laminate may be rendered resistant by the addition of, for example, > 'uv additives as described herein. The method of laminating the film and/or sheet of the present invention to glass is well known to those of ordinary skill in the art. The lamination method 2 without using an adhesive layer is completed by vacuum lamination. A. Obtaining an effective barrier between the glass layer and the laminate. In one embodiment, the glass has a low surface roughness. Alternatively, a double-sided adhesive tape, an adhesive layer, or a gel layer (obtained by application of, for example, a hot melt, a pressure sensitive or heat sensitive adhesive) or a UV or electron beam hardenable adhesive can be used. The laminate is bonded to the glass. The adhesive layer is applied to the glass flakes, laminate or both, and can be removed by stripping the layer, which can be removed before being laminated. In one embodiment, the glass laminate has at least one property, a clear (four), chemical resistance, and hydrolytic stability ATg. For the purpose of this content, the weight (wt), the term means "set," and "weight". The following examples are illustrative of how the polyesters of the present invention can be made and evaluated, and are intended to be purely exemplary of the invention, and are not intended to limit the scope thereof. Unless otherwise indicated, parts are parts by weight, temperature is expressed in degrees c or at room temperature, and pressure is at or near atmospheric pressure. EXAMPLES The following examples describe the general preparation of polyesters, and with hydrazine-cyclohexanedimethanol and/or ethylene glycol residues but lacking 2,2,4,4-tetramethyl-13-cyclobutane Comparison of polyesters with alcohols using 2,2,4,4-tetramethyl-1,3-cyclobutanediol (and various cis/trans mixtures) for a variety of polyester properties (toughness, glass transition temperature, inherent The effect of viscosity, etc.). Moreover, according to the following examples, those of ordinary skill in the art to which the present invention pertains will understand how to use the thermal stabilizers of the present invention in the preparation of polyesters containing them. The intrinsic viscosity of polyester is determined in 60/40 (w/w) pentane/tetra-ethane, at 0.25 g / 503⁄4 liters at 25 ° C, and in gram/g Way record. Unless otherwise stated, the glass transition temperature is obtained from

Thermal Analyst儀器之 TA DSC 2920儀器，在2〇。〇/分鐘之 掃描速率下，根據ASTMD3418測定。 組合物之二醇含量與順/反比例係藉由質子核磁共振 (NMR)光譜學測定。所有NMR光譜係被記錄在jEQL Eclipse Plus 600MHz核磁共振光譜儀上，使用無論是氯仿_ 三氟醋酸(7〇_30體積/體積）對聚合體，或者對寡聚合試 樣，為60/40(重量/重量）酚/四氯乙烷，並添加氘化氯仿供 119732.doc -306 - 200804457 ，鎖:對2,2,4,4·四甲基-1，3·環丁二醇共振之吸收峰指 =’係經由對模式2,2,4,4_四甲基M·環丁二醇之單-與二 苯甲酸，之比較而施行。此等模式化合物係密切地近似聚 合體與寡聚物中所發現之共振位置。 入結化作用半衰期tm，係藉由度量試樣經由雷射與光 :測态之透光率，作為時間之函數，在溫度控制加熱夾片 臺上測得。此度量係以下述方式達成，使聚合體曝露至溫 fTmax’然後使其冷卻至所要溫度。㈣，藉由加熱失片 堂，將試樣保持在所要之溫度下，同時施行透光率度量， 作為時間之函數。最初，試樣為視覺上透明，具有高透光 率’而當試樣結晶時變成不透明。結晶化作用半衰期係被 記錄為透光率在最初透光率與最後透㈣間之中途下之時 門Tmax係被疋義為使試樣之結晶性相域（若結晶性相域存 在時）熔解所需要之溫度。在下文實例中報告之Tmax，係表 不將各試樣加熱以在結晶化作用半衰誠量之前調理試樣 之溫度。Tmax溫度係依組合物而定，且典型上對各聚醋為 不同。例如，PCT可能必須被加熱至大於29(rc之某種溫 度，以熔解結晶性相域。 密度係使用梯度密度管柱，在23t:下測定。 於本文巾報融黏度係_流變學動態分析器 (舰Π)度量。㈣黏度係在頻率範圍為u4〇〇弧度/秒 下，於所報告之溫度下，作為剪切速率之函數度量。零剪 切熔融黏度（η。）為藉此項技藝中已知之模式，經由將數據 外推所估計零剪切速率下之炫融黏度。此步驟係自動地藉 119732.doc •307· 200804457 由流變學動態分析器（RDA II)軟體進行。 使聚合體於溫度範圍從80至l〇(TC下，在真空烘箱中乾 燥24小時，並於Boy 22S模製機上射出成型，而得 1/8χ1/2χ5-英吋與1/4xl/2x5_英吋撓曲棒塊。將此等棒塊切 割成2.5英对長度，並根據ASTM D256，向下切1/2英对寬 度凹口，而具有10-密爾切口。於23°c下之平均12〇(1衝擊強 度係由5份試樣上之度量值測得。 此外’將5份試樣在不同溫度下，使用5 °c增量測試，以 測定韌脆性轉移溫度。韌脆性轉移溫度係被定義為5〇%試 樣以如由ASTM D256所表示之脆性方式破裂之溫度。 本文中所報告之顏色值係CIELAB L*、a*、及b*值，其 係使用Hunter Lab Ultrascan XE光譜計（Hunter聯合實驗室 公司，Reston，Va·)，根據 ASTM D 6290-98 及 ASTM E308- 99，以下列參數測得：（i)D65照明體，（2)1〇度觀測，（3) 包含特定角度之反射模式，（4)大區域視野，（5)丨"孔大 小。在經研磨以通過6毫米篩網之聚合體顆粒上進行此測 量。 本發明聚酯中之泡沫百分比係根據下列方式測量。將由The Thermal Analyst instrument's TA DSC 2920 instrument is available in 2〇. 〇/min at the scanning rate, determined according to ASTM D3418. The diol content and cis/inverse ratio of the composition are determined by proton nuclear magnetic resonance (NMR) spectroscopy. All NMR spectra were recorded on a jEQL Eclipse Plus 600 MHz NMR spectrometer using either chloroform-trifluoroacetic acid (7 〇 30 volume/vol) for the polymer, or for the oligopolymerized sample, 60/40 (weight) /wt) phenol / tetrachloroethane, and added deuterated chloroform for 119732.doc -306 - 200804457, lock: absorption of 2,2,4,4·tetramethyl-1,3·cyclobutanediol resonance Peak finger = ' is performed by comparing the mono- and dibenzoic acid of the mode 2,2,4,4-tetramethyl M.cyclobutanediol. These model compounds closely approximate the resonance sites found in the polymer and oligomer. The half-life tm of the incorporation is measured by measuring the light transmission through the laser and the light: measured state as a function of time on a temperature controlled heating chuck. This measurement is achieved by exposing the polymer to a temperature fTmax' and then allowing it to cool to the desired temperature. (d), by heating the lost piece, keeping the sample at the desired temperature while performing a measure of light transmission as a function of time. Initially, the sample was visually transparent, had a high light transmission' and became opaque when the sample crystallized. The half-life of crystallization is recorded as the light transmittance at the time between the initial light transmittance and the last transmittance (4). The gate Tmax is derogated to make the crystal phase of the sample (if the crystalline phase exists) The temperature required for melting. The Tmax reported in the examples below is not to heat each sample to condition the temperature of the sample prior to crystallization. The Tmax temperature is dependent on the composition and is typically different for each polyester. For example, PCT may have to be heated to a temperature greater than 29 (rc) to melt the crystalline phase domain. Density is measured using a gradient density column at 23t: in this paper, the melt viscosity system _ rheological dynamics Analyzer (ship) metric. (4) Viscosity is measured in the frequency range u4 〇〇 radians / sec, as a function of shear rate at the reported temperature. Zero shear melt viscosity (η.) The pattern known in the art is based on extrapolating the estimated viscous viscosity at zero shear rate. This step is automatically performed by the Rheology Dynamic Analyzer (RDA II) software by 119732.doc • 307· 200804457 The polymer was dried at a temperature ranging from 80 to 10 Torr (TC) in a vacuum oven for 24 hours and injection molded on a Boy 22S molding machine to obtain 1/8 χ 1/2 χ 5 - 吋 and 1/4 x 1 / 2x5_inch flexing bar. These bars are cut to 2.5 inches length and cut down to 1/2 inch width notch according to ASTM D256, with a 10-mil cut. At 23°c The average of 12 〇 (1 impact strength is measured from the measured value on 5 samples. In addition, '5 samples are in At the same temperature, a 5 °c increment test was used to determine the ductile-brittle transition temperature. The ductile-brittle transition temperature was defined as the temperature at which 5 % of the sample was broken in a brittle manner as indicated by ASTM D256. The color values are CIELAB L*, a*, and b* values using a Hunter Lab Ultrascan XE spectrometer (Hunter United Laboratories, Reston, Va.) according to ASTM D 6290-98 and ASTM E308-99. Measured with the following parameters: (i) D65 illuminator, (2) 1 degree observation, (3) reflection mode with specific angle, (4) large area field of view, (5) 丨 " hole size. This measurement was carried out on polymer particles passing through a 6 mm screen. The percentage of foam in the polyester of the invention was measured according to the following manner.

MicroLiter Analytical Supplies，Suwanee，Ga·提供之 20 毫升 頂層空間取樣瓶置於實驗天平，加入5克乾燥聚合體並記 錄重量。隨後小心地添加水至取樣瓶滿，隨後記錄此重 量。記錄重量差異（wtl)，且用以估計取樣瓶及不含泡沫之 聚合體的體積。此值係用於所有後續操作中。在每次試驗 中，將5克乾燥聚合體添加至一乾淨頂層空間取樣瓶中。 119732.doc •308- 200804457 將一隔膜蓋附加至取樣瓶頂部，以乾燥氮氣將取樣瓶滌氣 約1分鐘。移除滌氣管線，且將一裝配有鼓泡器之乾燥氮 管線插入該隔膜蓋，以確保在加熱期間可在取樣瓶中維持 大氣壓力（周圍壓力）之惰氣。取樣瓶隨後置於一預熱至 300°C之加熱器中（經鑽孔以用於排放，然而緊密地貼合取 樣瓶），維持在該加熱器歷時15分鐘。隨後移出取樣瓶且 於實驗台上以空氣冷卻。取樣瓶冷卻後，移除取樣瓶之頂 部，且將取樣瓶置於實驗天平並稱重。記錄重量後，小心 地添加水至完全充滿該取樣瓶並記錄其重量。在此處上下 文中，完全充滿該取樣瓶裝置與將水加入取樣瓶頂部經判 斷係與測量（wtl)時之高度相同。計算重量差異（wt2)。由 自wtl減去wt2，可得到因聚合體起泡所致之被取代水之量 (wt3=wtl-wt2)。假設此試驗中水的密度是1，可將重量轉 變成體積，Vl=wtl，V2=wt2且V3=wt3。以下式計算，，聚 酯中之泡沫％’’ ： ”聚酯中之泡沫％”=〜3/[(5克聚合體/單位 為克/毫升之乾燥聚酯密度）+V3]。在此式中，包含約45莫 耳％2,2,4,4·四甲基-l，3-環丁二醇之本發明乾燥聚酯之密度 為1.17克/毫升。對於具有組成範圍為40%至50%莫耳 TMCD之試驗聚目旨，此1 · 17克/毫升值沒有顯著地改變。約 20莫耳％ TCMD之乾燥聚酯之密度值為ι·ΐ8克/毫升。泡沫 %為在後-試驗聚合體中之空隙體積的體積％。在加熱及冷 卻後之最終聚合體樣品的視覺等級亦可被測定。 下列實例中錫用量（Sn)係以每百萬份中之金屬重量份 (ppm)方式報告，且使用 PANanalytical Axios Advanced 119732.doc -309- 200804457 wavelength dispersive x-射線螢光光譜儀藉由χ—射線螢光 (xrf)測得。相似地’麟用量以元素填之ppm方式報告，且 使用相同儀器藉由xrf測得。 所選聚酯樣品之10-密爾薄膜係使用Carver壓機，在240 C下壓縮模製。在上述薄膜上測量固有黏度。 除非另有指明，否則使用於下述實例中之1，4環己烧二 甲醇之順/反比例為大約30/70，且範圍可為35/65至 25/75。除非另有指明，否則使用於下述實例之2,2,4,4_四 甲基-1，3-環丁二醇之順/反比例為大約5〇/5〇。 下列縮寫係應用於整個實施例與圖中： TPA 對苯二甲酸 DMT 對苯二甲酸二甲酯 TMCD 2,2,4,4-四甲基-1，3-環丁二醇 CHDM 1，4-環己烷二甲醇 IV 固有黏度 TPP 磷酸三苯基酯 DBTO 氧化二丁基錫 DMTO 氧化二甲基錫 η〇 —* --------—一___ 零剪切熔融黏度 Tg 玻璃轉移溫度 Tbd 韌脆性轉移溫度 Tmax 結晶化作用半衰期度量用之調理溫度 實例1 119732.doc -310- 200804457 口此^係說明2,2,4,4_四甲基·環丁二醇係比乙二醇 或，苯二甲酸更有效降低pct之結晶速率。此外，此實例 六、月2,2,4,4-四甲基_1，3_環丁二醇於玻璃轉移溫度與密 度上之利益。 多種共聚醋係按下文所述製備。此等共聚酉旨均以2〇〇 ppm氧化二了基錫作為觸媒而製成，以使觸媒_與濃度 在結晶化作用研究期間對於成核作用之影響降至最低。 M-環己烷二f醇之順/反比例為31/69 ,而2,2,4,4_四甲 基-1，3-環丁二醇之順/反比例係報告於表丨中。 對此實例之目的而言，試樣具有足夠類似之固有黏度， 於是有效地排除其作為結晶速率度量上之變數。 自溶融體之結晶化作用半衰期度量，係在14〇至2〇〇。〇之 溫度下，於HTC增量下施行，且係報告於表丨中。對各試 樣之最快速結晶化作用半衰期’係被採取為結晶化作用半 衰期作為溫度函數之最低值，典型上係發生在17〇至18〇它 附近。試樣之最快速結晶化作用半衰期係作圖於圖i中， 作為對PCT改質之莫耳％共單體之函數。 數據顯示2,2,4,4-四甲基]，3_環丁二醇係比乙二醇與間 苯二甲酸更有效降低結晶速率（意即增加結晶化作用半衰 期）。此外，2,2,4,4-四甲基環丁二醇會增加^且降^ 密度。 119732.doc -311- 200804457 表1 結晶化作用半衰期（分鐘） 實例 共單艘 (莫耳 IV (公合/克) 密度 (克/毫升) TS (°C) Tmax (°C) 於 140°C 下 (分鐘） 於 150°C 下 (分鐘） 於 160°C 下 (分鐘） 於 170°CT (分鐘） 於 180。(；下 (分鐘） 於 190〇C 下 (分鐘） 於 200eC 下 (分鐘） 1A 20.2 % A2 0.630 1.198 87.5 290 2.7 2.1 1.3 1.2 0.9 1.1 1.5 1B 19.8 % B 0.713 1.219 87.7 290 2.3 2.5 1.7 1.4 1.3 1.4 1.7 1C 20.0 % C 0.731 1.188 100.5 290 >180 >60 35.0 23.3 21.7 23.3 25.2 1D 40.2 % A2 0.674 1.198 81.2 260 18.7 20.0 21.3 25.0 34.0 59.9 96.1 1E 34.5 % B 0.644 1.234 82.1 260 8.5 8.2 7.3 7.3 8.3 10.0 11.4 1F 40.1 % C 0.653 1.172 122.0 260 >10天 >5天 >5天 19204 >5天 >5天 >5天 1G 14.3 % D 0.6463 1.188 103.0 290 55.0 28.8 11.6 6.8 4.8 5.0 5.5 1在表1中聚酯二醇成份之其餘部份為1,4-環己烷二甲醇；而在表1中聚 酯二羧酸成份之其餘部份為對苯二甲酸二甲酯；若二羧酸未被描述， 則其係為100莫耳％對苯二甲酸二甲酯。 2 100莫耳％ 1，4-環己烷二甲醇。 3 薄膜係自實例1 G之經研磨聚酯，於240°C下壓製。所形成之薄膜具有 固有黏度值為0.575公合/克。 4薄膜係自實例1H之經研磨聚酯，於240°C下壓製。所形成之薄膜具有 固有黏度值為0.0.652公合/克。 其中：A 為間苯二甲酸 B 為乙二醇 C 為2,2,4,4-四甲基-1，3-環丁二醇（約50/50順/反） D 為2,2,4,4-四甲基-1,3-環丁二醇（98/2順/反） E 為2,2,4,4-四甲基-1,3-環丁二醇（5/95順/反） 如表1與圖1中所示，2,2,4,4-四甲基-1，3-環丁二醇係比 其他共單體譬如乙二醇與間苯二甲酸，更有效增加結晶化 作用半衰期，意即使聚合體達到其最高結晶度一半所需要 -312- H9732.doc 200804457 之時間。藉由降低PCT之結晶速率（增加結晶化作用半衰 期如本文中所述，以2,2,4,4•四甲基·u•環丁二醇改質 之PCT為基料之非晶質物件，可藉此項技藝中已知之方法 製造。如表1中所示，&等材料可比其他經改質PCT共聚 酯顯示較高之玻璃轉移溫度與較低之密度。 於表1上所示聚酯之製備，係描述於下文中。MicroLiter Analytical Supplies, Suwanee, Ga. supplied a 20 ml top space sample vial placed on an experimental balance, adding 5 grams of dry polymer and recording the weight. The water was then carefully added until the sample bottle was full and then the weight was recorded. The weight difference (wtl) was recorded and used to estimate the volume of the sample bottle and the polymer without foam. This value is used in all subsequent operations. In each test, 5 grams of dry polymer was added to a clean top space sample bottle. 119732.doc •308- 200804457 Attach a septum cap to the top of the vial and purge the vial with dry nitrogen for approximately 1 minute. The scrubbing line is removed and a dry nitrogen line equipped with a bubbler is inserted into the septum cap to ensure inert gas at atmospheric pressure (ambient pressure) can be maintained in the sampling bottle during heating. The vial was then placed in a heater preheated to 300 ° C (drilled for discharge, but tightly fitted to the sample vial) and maintained at the heater for 15 minutes. The sample bottles were then removed and air cooled on the bench. After the sample bottle has cooled, the top of the sample bottle is removed and the sample bottle is placed on the test balance and weighed. After recording the weight, carefully add water to completely fill the vial and record its weight. Here, in the context, the filling of the sampling bottle device is the same as the height at which the water is added to the top of the sampling bottle and judged (wtl). Calculate the weight difference (wt2). By subtracting wt2 from wtl, the amount of substituted water due to foaming of the polymer (wt3 = wtl - wt2) can be obtained. Assuming that the density of water in this test is 1, the weight can be converted into a volume, Vl = wtl, V2 = wt2 and V3 = wt3. The foam %'' in the polyester is calculated by the following formula: "% foam in the polyester" = ~3/[(5 g of polymer/unit of dry polyester density in g/ml) + V3]. In the formula, the dry polyester of the present invention comprising about 45 mol% of 2,2,4,4·tetramethyl-l,3-cyclobutanediol has a density of 1.17 g/ml. For a test with a composition range of 40% to 50% Mox TMCD, this 1 17 g/ml value did not change significantly. A density of about 20 mol% of the dried polyester of TCMD is ι·ΐ8 g/ml. The % foam is the volume % of the void volume in the post-test polymer. The visual grade of the final polymer sample after heating and cooling can also be determined. In the following examples, the amount of tin (Sn) is reported in parts per million (ppm) of the metal, and the PANanalytical Axios Advanced 119732.doc -309-200804457 wavelength dispersive x-ray fluorescence spectrometer is used by x-ray. Fluorescent (xrf) measured. Similarly, the amount of Lin was reported in ppm by element and was measured by xrf using the same instrument. The 10-mil film of the selected polyester sample was compression molded at 240 C using a Carver press. The intrinsic viscosity was measured on the above film. Unless otherwise indicated, the cis/reverse ratio of 1,4 cyclohexane dimethyl acetal used in the following examples is about 30/70, and the range may be 35/65 to 25/75. The cis/reverse ratio of 2,2,4,4-tetramethyl-1,3-cyclobutanediol used in the following examples was about 5 〇/5 〇 unless otherwise specified. The following abbreviations are used throughout the examples and figures: TPA terephthalic acid DMT dimethyl terephthalate TMCD 2,2,4,4-tetramethyl-1,3-cyclobutanediol CHDM 1,4 -cyclohexanedimethanol IV intrinsic viscosity TPP triphenyl phosphate DBTO dibutyltin oxide DMTO dimethyltin η 〇 - * -------- - ___ zero shear melt viscosity Tg glass transition temperature Tbd ductile-brittle transition temperature Tmax crystallization half-life measurement conditioning temperature example 1 119732.doc -310- 200804457 This is a description of 2,2,4,4_tetramethylcyclobutanediol compared to ethylene glycol Or, phthalic acid is more effective in reducing the crystallization rate of pct. In addition, this example has the benefit of the monthly transfer temperature and density of 2,2,4,4-tetramethyl-1,3-cyclobutanediol. A variety of copolymerized vinegars were prepared as described below. These copolymerizations were all made with 2 〇〇 ppm of bismuth sulphide as a catalyst to minimize the effect of catalyst _ and concentration on nucleation during crystallization studies. The cis/reverse ratio of M-cyclohexanedi-fol is 31/69, and the cis/inverse ratio of 2,2,4,4-tetramethyl-1,3-cyclobutanediol is reported in the Table. For the purposes of this example, the sample has a sufficiently similar intrinsic viscosity and is effectively excluded as a variable in the crystallization rate metric. The half-life measure of the crystallization of the autolytic melt is between 14 〇 and 2 〇〇. At the temperature of 〇, it is carried out in HTC increments and is reported in the table. The fastest crystallization half-life for each sample is taken as the lowest value of the crystallization half-life as a function of temperature, typically occurring around 17 〇 to 18 〇. The fastest crystallization half-life of the sample is plotted in Figure i as a function of the ML% comonomer for PCT modification. The data shows that 2,2,4,4-tetramethyl], 3_cyclobutanediol is more effective than ethylene glycol and isophthalic acid in reducing the rate of crystallization (i.e., increasing the half-life of crystallization). In addition, 2,2,4,4-tetramethylcyclobutanediol increases the density and decreases the density. 119732.doc -311- 200804457 Table 1 Crystallization half-life (minutes) Example of a single vessel (Molar IV (common / gram) Density (g / ml) TS (°C) Tmax (°C) at 140 ° C Lower (minutes) at 150 ° C (minutes) at 160 ° C (minutes) at 170 ° CT (minutes) at 180 ° (; (minutes) at 190 ° C (minutes) at 200 ° C (minutes) 1A 20.2 % A2 0.630 1.198 87.5 290 2.7 2.1 1.3 1.2 0.9 1.1 1.5 1B 19.8 % B 0.713 1.219 87.7 290 2.3 2.5 1.7 1.4 1.3 1.4 1.7 1C 20.0 % C 0.731 1.188 100.5 290 >180 > 60 35.0 23.3 21.7 23.3 25.2 1D 40.2 % A2 0.674 1.198 81.2 260 18.7 20.0 21.3 25.0 34.0 59.9 96.1 1E 34.5 % B 0.644 1.234 82.1 260 8.5 8.2 7.3 7.3 8.3 10.0 11.4 1F 40.1 % C 0.653 1.172 122.0 260 > 10 days > 5 days > 5 days 19204 >5 days>5 days>5 days 1G 14.3 % D 0.6463 1.188 103.0 290 55.0 28.8 11.6 6.8 4.8 5.0 5.5 1 In Table 1, the remainder of the polyester diol component is 1,4-cyclohexane Methanol; and in Table 1, the remainder of the polyester dicarboxylic acid component is dimethyl terephthalate; if the dicarboxylic acid is not Said, it is 100 mol% dimethyl terephthalate. 2 100 mol% 1,4-cyclohexane dimethanol. 3 film is from the example 1 G of ground polyester, at 240 ° C The film was formed to have an intrinsic viscosity of 0.575 metric/g. 4 The film was pressed from the ground polyester of Example 1H at 240 ° C. The film formed had an intrinsic viscosity of 0.0652 mm. Combination / gram. Where: A is isophthalic acid B is ethylene glycol C is 2,2,4,4-tetramethyl-1,3-cyclobutanediol (about 50/50 cis / reverse) D is 2,2,4,4-Tetramethyl-1,3-cyclobutanediol (98/2 cis/reverse) E is 2,2,4,4-tetramethyl-1,3-cyclobutanediol (5/95 cis/reverse) As shown in Table 1 and Figure 1, 2,2,4,4-tetramethyl-1,3-cyclobutanediol is more than other comonomers such as ethylene glycol. The phthalic acid is more effective in increasing the crystallization half-life, meaning that the time required for the polymer to reach half of its maximum crystallinity is -312-H9732.doc 200804457. By reducing the crystallization rate of PCT (increasing the crystallization half-life as described herein, PCT based on 2,2,4,4 • tetramethyl·u•cyclobutanediol modified amorphous material It can be made by the method known in the art. As shown in Table 1, materials such as & can exhibit higher glass transition temperatures and lower densities than other modified PCT copolyesters. The preparation of the polyester is described below.

實例1A 此實例係說明製備具有80莫耳％對苯二甲酸二甲醋殘 基、20莫耳％間苯二甲酸二甲醋殘基及⑽莫耳％ 環己 烧一甲醇殘基（28/72順/反）標的組成之共聚酯。 广6.63克對苯二甲酸二甲g旨、55·2“4_環己烷二甲 醇、14.16克間苯二甲酸二甲酯及〇 〇419克氧化二丁基錫之 混合物置於裝有氮人π管、金屬㈣器及短蒸镏管柱之 500毫升燒瓶中。將此燒瓶置於已被加熱至2丨〇之伍德 氏孟屬浴中。在整個實驗中，將攪拌速度設定至 RpM將燒瓶之内容物在21〇〇c下加熱5分鐘，然後使溫度 逐漸增加至290 C，歷經30分鐘。將反應混合物在29〇π下 保持60分鐘，然後逐漸施加真空，歷經下一個$分鐘，直 到粍瓶内部壓力達到1〇〇毫米Hg為止。於下一個5分鐘内， 使燒瓶内部壓力進一步降至〇·3毫米Hg。〇·3毫米Hg之壓力 係被保持總共時間為9〇分鐘，以移除過量未反應之二醇 類。獲得高熔融黏度、視覺上透明及無色聚合體，具有玻 璃轉移溫度為87.5°C，且固有黏度為〇·63公合/克。NMR分 析』示聚合體係由j 〇〇莫耳％丨，4_環己烧二甲酵殘基與2〇·2 119732.doc -313- 200804457 莫耳％間苯二甲酸二甲酯殘基所組成。EXAMPLE 1A This example illustrates the preparation of 80 mole % terephthalate residue, 20 mole % dimethyl phthalate residue, and (10) mole % cyclohexane-methanol residue (28/ 72 cis/re) standard composition of the copolyester. A mixture of 6.63 g of terephthalic acid dimethyl ketone, 55·2 "4_cyclohexane dimethanol, 14.16 g of dimethyl isophthalate and 〇〇4 g of dibutyltin oxide was placed in a nitrogen-containing π Tube, metal (four) and short steaming column in a 500 ml flask. Place the flask in a Woody Mum bath that has been heated to 2 Torr. Throughout the experiment, set the stirring speed to RpM. The contents were heated at 21 ° C for 5 minutes and then gradually increased to 290 C for 30 minutes. The reaction mixture was held at 29 〇 π for 60 minutes, then gradually applied vacuum for the next $ minute until The internal pressure of the bottle reaches 1 mm Hg. The internal pressure of the flask is further reduced to 〇3 mm Hg in the next 5 minutes. The pressure of 〇·3 mm Hg is maintained for a total time of 9 , minutes. Excess unreacted glycols were removed. High melt viscosity, visually clear and colorless polymer was obtained with a glass transition temperature of 87.5 ° C and an intrinsic viscosity of 〇·63 com/g. NMR analysis showed polymerization system By j 〇〇莫耳%丨, 4_环己烧二Fermentation residues 2〇 · 2 119732.doc -313- 200804457 between mole% dimethyl isophthalate residues composed.

實例1B 此實例係說明製備具有100莫耳％對苯二曱酸二甲酯殘 基、20莫耳％乙二醇殘基及80莫耳。/〇 1，4-環己烷二甲醇殘 基（32/68順/反）標的組成之共聚酯。 將77.68克對苯二甲酸二曱酯、50.77克1，4-環己烷二甲 醇27.81克乙二醇及0.0433克氧化二丁基錫之混合物置於裝 有氮入口管、金屬攪拌器及短蒸餾管柱之500·毫升燒瓶 中。將燒瓶置於已被加熱至200°C之伍德氏金屬浴中。在 整個實驗中，將攪拌速度設定至200 RPM。將燒槪之内容 物在200°C下加熱60分鐘，然後使溫度逐漸增加至21〇ι， 歷經5分鐘。將反應混合物在210°C下保持120分鐘，然後 在30分鐘内加熱至高達280°C。一旦在280°C下，即在下一 個5分鐘内逐漸施加真空，直到燒瓶内部壓力達到ι〇〇毫米 Hg為止。於下一個10分鐘内，使燒瓶内部壓力進一步降至 0-3毫米Hg。0.3毫米Hg之壓力係被保持總共時間為9〇分 鐘，以移除過量未反應之二醇類。獲得高熔融黏度、視覺 上透明及無色聚合體，具有玻璃轉移溫度為87/rc，且固 有黏度為〇·71公合/克。NMR分析顯示聚合體係由19 8莫耳 %乙二酵殘基所組成。EXAMPLE 1B This example illustrates the preparation of a dimethyl terephthalate residue, 20 mole % ethylene glycol residue and 80 moles. /〇 A copolyester of the composition of the 1,4-cyclohexanedimethanol residue (32/68 cis/reverse). A mixture of 77.68 g of dinonyl terephthalate, 50.77 g of 1,4-cyclohexanedimethanol 27.81 g of ethylene glycol and 0.0433 g of dibutyltin oxide was placed in a nitrogen inlet tube, a metal stirrer and a short distillation tube. Column in a 500 ml flask. The flask was placed in a Wood's metal bath that had been heated to 200 °C. The stirring speed was set to 200 RPM throughout the experiment. The contents of the simmer were heated at 200 ° C for 60 minutes, and then the temperature was gradually increased to 21 〇 for 5 minutes. The reaction mixture was held at 210 ° C for 120 minutes and then heated up to 280 ° C in 30 minutes. Once the vacuum was gradually applied at 280 ° C, i.e., within the next 5 minutes, until the internal pressure of the flask reached ι 〇〇 mm Hg. The internal pressure of the flask was further reduced to 0-3 mm Hg in the next 10 minutes. A pressure of 0.3 mm Hg was maintained for a total time of 9 〇 minutes to remove excess unreacted glycols. A high melt viscosity, visually clear, and colorless polymer is obtained with a glass transition temperature of 87/rc and a solid viscosity of 〇71 com/g. NMR analysis showed that the polymerization system consisted of 198 mol% of the residue.

實例1C 此實例係說明製備具有100莫耳％對苯二曱酸二甲醋殘 基、20莫耳。/〇 2,2,4,4-四甲基-1，3-環丁二醇殘基及8〇莫耳％ 1，4-環己烷二甲醇殘基（3 1/69順/反）標的組成之共聚酯。 119732.doc -314- 200804457EXAMPLE 1C This example illustrates the preparation of a 100 mM % terephthalic acid dimethyl vinegar residue, 20 moles. /〇2,2,4,4-Tetramethyl-1,3-cyclobutanediol residue and 8〇 mol% 1,4-cyclohexanedimethanol residue (3 1/69 cis/reverse) The standard composition of the copolyester. 119732.doc -314- 200804457

將77.68克對苯二甲酸二^甲酉旨、48 4^^4-環己燒二甲 醇17.86克2,2,4,4-四甲基_l53_環丁二醇及〇〇46克氧化二丁 基錫之混合物置於裝有氮人口管、金屬㈣器及短蒸館管 柱之5〇〇_毫升燒瓶中。此聚酯係以類似實例1A中所述之方 式製成。獲得高熔融黏度、視覺上透明及無色聚合體，具 有玻璃轉移溫度為100.51，且固有黏度為〇·73公合/克。 NMR分析顯示聚合體係由8〇·5莫耳％丨，4_環己烷二τ醇殘 基與19.5莫耳％ 2,2,4,4-四甲基-1，3-環丁二醇殘基所組成。 實例1D 此實例係說明製備具有100莫耳％對苯二甲酸二甲酯殘 基、40莫耳％間苯二甲酸二甲酯殘基及1〇〇莫耳％ ι4·環己 烷二甲醇殘基（28/72順/反）標的組成之共聚酯。 將42.83克對苯二甲酸二甲酯、55 26克U4_環己烷二甲 醇、28.45克間苯二甲酸二甲酯及〇 〇419克氧化二丁基錫之 混合物置於裝有氮入口管、金屬攪拌器及短蒸餾管柱之 500-毫升燒瓶中。將燒瓶置於已被加熱至21〇〇c之伍德氏 金屬浴中。在整個實驗中，將攪拌速度設定至2〇〇 rpm。 將燒瓶之内容物在210°C下加熱5分鐘，然後使溫度逐漸增 加至290 C，歷經30分鐘。將反應混合物在29〇它下保持6〇 分鐘，然後逐漸施加真空，歷經下一個5分鐘，直到燒瓶 内部壓力達到100毫米Hg為止。於下一個5分鐘内，使燒瓶 内部壓力進一步降至〇·3毫米Hg。〇·3毫米Hg之壓力係被保 持總共時間為90分鐘，以移除過量未反應之二醇類。獲得 高熔融黏度、視覺上透明及無色聚合體，具有玻璃轉移溫 119732.doc -315- 200804457 度為n ’且固有黏度狀67公合/克。nmr分析顯示聚 合體係由1〇〇莫耳％认環己烧二甲醇殘基與後2莫耳％間 本一甲酸二甲酯殘基所組成。77.68 g of terephthalic acid dimethicone, 48 4^^4-cyclohexane dimethanol 17.86 g of 2,2,4,4-tetramethyl-l53_cyclobutanediol and 〇〇46 g of oxidation The mixture of dibutyltin was placed in a 5 〇〇-ml flask equipped with a nitrogen population tube, a metal (four) device, and a short steaming column. This polyester was made in a manner similar to that described in Example 1A. A high melt viscosity, visually clear and colorless polymer is obtained with a glass transition temperature of 100.51 and an intrinsic viscosity of 〇·73 com/g. NMR analysis showed that the polymerization system consisted of 8 〇·5 mol % 丨, 4 _ cyclohexane diol alcohol residue and 19.5 mol % 2,2,4,4-tetramethyl-1,3-cyclobutanediol Residue consists of. EXAMPLE 1D This example illustrates the preparation of 100 mM % dimethyl terephthalate residue, 40 mole % dimethyl isophthalate residue and 1 〇〇 mol % ι4 · cyclohexane dimethanol residue A copolyester consisting of a base (28/72 cis/reverse). A mixture of 42.83 g of dimethyl terephthalate, 55 26 g of U4_cyclohexanedimethanol, 28.45 g of dimethyl isophthalate and 419 g of dibutyltin oxide was placed in a nitrogen inlet tube, metal Agitator and short distillation column in a 500-ml flask. The flask was placed in a Wood's metal bath that had been heated to 21 °C. The stirring speed was set to 2 rpm throughout the experiment. The contents of the flask were heated at 210 ° C for 5 minutes and then gradually increased to 290 C for 30 minutes. The reaction mixture was held at 29 Torr for 6 Torr and then gradually applied with vacuum for the next 5 minutes until the internal pressure of the flask reached 100 mm Hg. The internal pressure of the flask was further lowered to 〇·3 mm Hg in the next 5 minutes. The pressure of 〇·3 mm Hg was maintained for a total time of 90 minutes to remove excess unreacted glycols. A high melt viscosity, visually clear and colorless polymer is obtained with a glass transition temperature of 119732.doc - 315 - 200804457 degrees n ' and an inherent viscosity of 67 com/g. The nmr analysis showed that the polymerization system consisted of 1 〇〇 mol % 环 己 hexane dimethanol residue and 2 mM % dimethyl methacrylate residue.

實例1E 二甲酯殘 二甲醇殘 此實例係說明製備具有100莫耳％對苯二曱酸 基、40莫耳％乙二醇殘基及6〇莫耳％丨，4_環己烷 基（31/69順/反）標的組成之共聚酯。 將81.3克對苯二甲酸二甲酯、42 85克1，4_環己烷二甲醇 34.44克乙二醇及0.0419克氧化二丁基錫之混合物置於裝有 氮入口管、金屬攪拌器及短蒸顧管柱之5〇〇_毫升燒瓶中。 將燒瓶置於已被加熱至20(TC之伍德氏金屬浴中。在整個 實驗中’將擾拌速度設定至200 RPM。將燒甑之内容物在 200°C下加熱60分鐘，然後使溫度逐漸增加至21〇〇c，歷經 5分鐘。將反應混合物在210°C下保持120分鐘，然後在3〇 分鐘内加熱至高達280°C。一旦在280°C下，即在下一個5 分鐘内逐漸施加真空，直到燒瓶内部壓力達到1 〇〇毫米Hg 為止。於下一個10分鐘内，使燒觀内部壓力進一步降至 0.3耄米Hg。0.3毫米Hg之壓力係被保持總共時間為9〇分 鐘，以移除過量未反應之二醇類。獲得高熔融黏度、視覺 上透明及無色聚合體，具有玻璃轉移溫度為82 ·Γ(：，且固 有黏度為0.64公合/克。NMR分析顯示聚合體係由34·5莫耳 %乙二醇殘基所組成。EXAMPLE 1E Dimethyl Ester Residual Methanol Residue This example illustrates the preparation of 100 mole % terephthalic acid base, 40 mole % ethylene glycol residue and 6 mole % 丨, 4 - cyclohexane group ( 31/69 cis/re) standard composition of the copolyester. A mixture of 81.3 g of dimethyl terephthalate, 42 85 g of 1,4-cyclohexane dimethanol 34.44 g of ethylene glycol and 0.0419 g of dibutyltin oxide was placed in a nitrogen inlet tube, a metal stirrer and a short steaming Take care of the column in a 5 〇〇 _ ml flask. The flask was placed in a Wood's metal bath that had been heated to 20 (TC. The scavenging speed was set to 200 RPM throughout the experiment. The contents of the crucible were heated at 200 ° C for 60 minutes and then allowed to bring the temperature Gradually increase to 21 ° C for 5 minutes. The reaction mixture is held at 210 ° C for 120 minutes and then heated up to 280 ° C in 3 minutes. Once at 280 ° C, in the next 5 minutes Gradually apply vacuum until the internal pressure of the flask reaches 1 〇〇 mm Hg. In the next 10 minutes, the internal pressure of the burning is further reduced to 0.3 H Hg. The pressure of 0.3 mm Hg is maintained for a total time of 9 〇 minutes. To remove excess unreacted glycols. Obtain high melt viscosity, visually clear and colorless polymer with a glass transition temperature of 82 · Γ (:, and an intrinsic viscosity of 0.64 com / gram. NMR analysis shows polymerization The system consists of 34.5 mol% ethylene glycol residues.

實例1F 此實例係說明製備具有1〇〇莫耳％對苯二甲酸二甲酯殘 119732.doc -316- 200804457 基=〇莫耳％ 2,2,4,心四甲基]，3_環丁二醇殘基及6〇莫耳％ 1，4-環己燒二甲醇殘基（3 1/69順/反）標的組成之共聚酯。 >將77·4克對苯：甲酸二甲酯、36.9克1，4_環己烷二甲 醇、32.5克2,2,4,4-四甲基]，3_環丁二醇及〇〇46克氧化二 I基錫之此合物置於裝有氮入口管、金屬攪拌器及短蒸餾 & #之500毫升燒瓶中。將燒瓶置於已被加熱至21 〇 t之 伍4、氏金屬洛中。在整個實驗中，將攪拌速度設定至2⑻ 麵。將燒瓶之内容物在2阶下加熱3分鐘，然後使溫度 逐漸增加至26〇°C，歷經3〇分鐘。將反應混合物在260t下 保持120刀鐘，然後在30分鐘内加熱至高達290。(：。一旦在 〇胃c下即在下一個5分鐘内逐漸施加真空，直到燒瓶内 ^壓力達到100毫米Hg為止。於下一個5分鐘内，使燒觀内 W壓力進-步降至〇 3毫米Hg。〇·3毫米取之壓力係被保持 總共時間為90分鐘，以移除過量未反應之二醇類。獲得高 溶融黏度、視覺上透明及無色聚合體，具有玻璃轉移溫度 為122C，且固有黏度為〇·65公合/克。nmr分析顯示聚合 體係由59·9莫耳％ μ-環己燒二甲醇殘基與4〇1莫耳％ 2,2,4,4_四甲基-1，3_環丁二醇殘基所組成。EXAMPLE 1F This example illustrates the preparation of a dimethyl ether terephthalate residue 119732.doc-316-200804457 base = 〇mol% 2,2,4, cardiac tetramethyl], 3_ ring A copolyester consisting of a butanediol residue and a 6 〇 mol% 1,4-cyclohexane-small dimethanol residue (3 1/69 cis/reverse). > 77.4 g of p-benzoic acid: dimethyl formate, 36.9 g of 1,4-cyclohexanedimethanol, 32.5 g of 2,2,4,4-tetramethyl], 3 -cyclobutanediol and hydrazine This compound of 46 g of bis(I)tin oxide was placed in a 500 ml flask equipped with a nitrogen inlet tube, a metal stirrer and a short distillation & The flask was placed in a metal metal that had been heated to 21 〇 t. The stirring speed was set to 2 (8) faces throughout the experiment. The contents of the flask were heated in 2nd order for 3 minutes, and then the temperature was gradually increased to 26 ° C for 3 minutes. The reaction mixture was held at 260 Torr for 120 knives and then heated up to 290 over 30 minutes. (: Once the sputum is c, the vacuum is gradually applied in the next 5 minutes until the pressure in the flask reaches 100 mm Hg. In the next 5 minutes, the W pressure in the burning chamber is further reduced to 〇3. Millimeter Hg. The pressure of 3 mm is maintained for a total time of 90 minutes to remove excess unreacted glycol. Obtain a high melt viscosity, visually clear and colorless polymer with a glass transition temperature of 122C. And the intrinsic viscosity is 〇·65 com/g. The nmr analysis shows that the polymerization system consists of 59·9 mol% μ-cyclohexane dimethanol residue and 4〇1 mol% 2,2,4,4_4 The base-1,3_cyclobutanediol residue is composed of.

實例1G 此實例係說明製備具有丨〇〇莫耳0/。對苯二甲酸二甲酯殘 基、⑼莫耳％ 2,2,4,4:四甲基]，環丁二醇殘基（98/2順/反） 及8〇莫耳％丨，4·環己烧二曱醇殘基（3 1/69順/反）標的組成之 共聚酯。 將77.68克對苯二甲酸二甲酯、48.46克i，仁環己烷二曱 119732.doc -317- 200804457 醇20.77克2,2,4,4-四甲基-l，3-環丁二醇及0·046克氧化二丁 基錫之混合物置於裝有氮入口管、金屬攪拌器及短蒸餾管 柱之500耄升燒瓶中。將燒槪置於已被加熱至2 1 〇艺之伍 德氏金屬浴中。在整個實驗中，將攪拌速度設定至2〇〇 RPM。將燒瓶之内容物在21(rc下加熱3分鐘，然後使溫度 逐漸增加至260°C，歷經30分鐘。將反應混合物在26(Γ(：τ 保持120分鐘，然後在30分鐘内加熱至高達29〇。〇。一旦在 290°C下，即在下一個5分鐘内逐漸施加真空，直到燒瓶内 4壓力達到100耄米Hg為止’並使擾拌速度亦降至1 〇〇 RPM。於下一個5分鐘内，使燒瓶内部壓力進一步降至〇.3 毫米Hg ’並使攪拌速度降至50 rpm。〇·3毫米Hg之壓力係 被保持總共時間為60分鐘，以移除過量未反應之二醇類。 獲得高溶融黏度、視覺上透明及無色聚合體，具有玻璃轉 移溫度為103 C，且固有黏度為〇·65公合/克。NMR分析顯 示聚合體係由85.7莫耳％ 1，4-環己烧二甲醇殘基與14·3莫 耳％ 2,2,4,4-四甲基-1，3-環丁二醇殘基所組成。 實例1Η 此實例係說明製備具有100莫耳％對苯二甲酸二甲酯殘 基、20莫耳。/〇 2,2,4,4-四甲基環丁二醇殘基（5/95順/反） 及80莫耳％ 1，4-環己烷二曱醇殘基（31/69順/反)標的組成之 共聚酯。 將77.68克對苯二甲酸二甲酯、48.46克1，4-環己烧二曱 醇、20.77克2,2,4,4-四甲基- l，3-環丁二醇及〇.〇46克氧化二 丁基錫之混合物置於裝有氮入口管、金屬攪拌器及短蒸館 119732.doc -318. 200804457 管柱之500-毫升燒瓶中。將燒瓶置於已被加熱至2i(rc之 伍德氏金屬浴中。於實驗開始時，將攪拌速度設定至2〇〇 RPM。將燒瓶之内容物在21〇t下加熱3分鐘，然後使溫度 逐漸增加至26(TC，歷經30分鐘。將反應混合物在26(Γ(：下 保持120分鐘，然後在3〇分鐘内加熱至高達29〇它。一旦在 290°C下，即在下一個5分鐘内，逐漸施加真空，使用1〇〇 宅米Hg之投定點’且亦使授拌速度降至1〇〇 rpm。於下一 個5分鐘内，使燒瓶内部壓力進一步降至〇·3毫米Hg之設定 點，並使攪拌速度降至50 RPM。此壓力係被保持總共時 間為60分鐘’以移除過量未反應之二醇類。應指出的是， 真空系統未能達到上文所指出之設定點，但產生足夠真 空，以製造高熔融黏度、視覺上透明及無色聚合體，具有 玻璃轉移溫度為99°C，且固有黏度為〇·73公合/克。NMR分 析顯示聚合體係由85莫耳％ 1，4 -環己烧二甲醇殘基與15莫 耳％ 2,2,4,4-四甲基-1，3-環丁二醇殘基所組成。 實例2 此實例說明2,2,4,4-四曱基-1，3·環丁二醇改善了以pcT為 主之共聚酯（含對苯二甲酸及1,4-環己烧二甲醇之聚酯）的 韌度。 以2，2,4,4-四甲基-1,3 -環丁二醇為主之共聚酯係以下述 方法製備。在所有樣品中，1，4-環己烧二甲醇之順/反比例 約3 1/69。以乙二醇及1，4-環己烧二甲醇為主之共聚酯係市 售聚酯。實例2Α之共聚酯（Eastar PCTG 5445)係得自伊士 曼化學公司。實例2B之共聚酯係得自伊士曼化學公司，商 119732.doc -319- 200804457 品名為Spectar。實例2C及實例2D係根據適用實例1A所述 之步驟，於試驗工廠規模上製備（各為15-磅批料），且具有 下列表2所述之固有黏度及玻璃轉移溫度。實例2C係經製 備以具有300 ppm之標的錫用量（氧化二丁基錫）。最終產 物包含295 ppm錫。實例2C之聚酯的顏色值係l* = 77.11、 a*= _1·50及b* = 5.79。實例2〇係經製備以具有3〇〇 ppm之標 的錫用量（氧化二丁基錫）。最終產物包含3〇7叩㈤錫。實 例20之聚8旨的顏色值係乙* = 66.72、&*=-1.22及1)* = 16.28。 材料係射出成型形成棒塊，且隨後切凹口用於Iz〇d試 驗。獲得為溫度函數之切口 12〇(1衝擊強度，並報告於表2 中。 對一所給樣品，IZ0d衝擊強度在一短溫度間隔中經受一 主要轉移。舉例而言，以38莫耳％乙二醇為主之共聚酯的 IZ〇d衝擊強度在丨5及20°C經受此轉移。此轉移溫度係與破 壞模式、跪度/在較低溫度之低能量破壞及韌度/在較高溫 度之高能量破壞方面之改變有關。此溫度轉移稱為韌脆性 轉移溫度Tbd，為韌度之測量。Tbd係報告於表2且對共單 體之莫耳％ %於圖2。 數據顯示相較於乙二醇（其增加PCT之Tbd)，將2,2,4,4-四甲基-1，3-環丁二醇加入pCT可降低Tbd及改善韌度。 119732.doc 200804457 表2 切口 Izod衝擊能量（吸-碎/英忖） 實例 共單體 (莫耳％)1 IV (公合/克） Tg (°C) Tbd (°C) 於 -20 °C 於 -15 °C 於 -10 °c 於 -5 °C 於 0 °c 於 5 °C 於 10 pc 於 15 °C 於 20 °C 於 25 °C 於 30 °C 2A 38.0 % B 0.68 86 18 ΝΑ ΝΑ ΝΑ 1.5 ΝΑ ΝΑ 1.5 1.5 32 32 ΝΑ 2B 69.0 % B 0.69 82 26 ΝΑ ΝΑ ΝΑ ΝΑ ΝΑ ΝΑ 2.1 ΝΑ 2.4 13.7 28.7 2C 22.0 % C 0.66 106 -5 1.5 ΝΑ 12 23 23 ΝΑ 23 ΝΑ ΝΑ ΝΑ ΝΑ 2D 42.8 % C 0.60 133 -12 2.5 2.5 11 ΝΑ 14 ΝΑ ΝΑ ΝΑ ΝΑ ΝΑ ΝΑ 1 表中聚酯二醇成份之其餘部份為1，4-環己烷二曱醇。所有聚合體係自100 莫耳％對苯二甲酸二甲酯製得。 NA=不可取得。 其中：B 為乙二醇 C 為2,2,4,4_四甲基-1，3-環丁二醇（50/50順/反） 實例3 此實例說明2,2,4,4-四甲基-1，3-環丁二醇可改善以PCT為 主之共聚酯（含對苯二甲酸及1，4-環己烷二甲醇之聚酯）的 韌度。此實例中所製備之聚酯包含15至25莫耳％之2,2,4,4-四甲基-1，3_環丁二醇殘基。 以對苯二甲酸二甲基酯、2,2,4,4_四甲基4，％環丁二醇 及U4-環己烷二甲醇（3 1/69順/反）係如下述方法製備且具有 表3所示之組成及性質。表3中將聚酯中二醇類組份平衡至 100莫耳％者為丨，4-環己烷二甲醇（3 1/69順/反）。 材料係射出成型形成3·2毫米及6_4毫米厚之棒塊，且隨 後切凹口用於IZ0d衝擊試驗。獲得23〇c之切口 Iz〇d衝擊強 度，並報告於表3中。於棒塊上測量密度、Tg及結晶化作 119732.doc -321 - 200804457 用半衰期。在錠塊上於290°C測量熔融黏度。 表3 特定聚酯各種性質之彙整 實例 TMCD 莫耳％ %順式 TMCD 錠塊 IV (公合/克) 模製棒塊 IV (公合/克) 3.2 mm 厚棒塊 於 23°C 之切口 Izod (焦耳/公尺） 6.4 mm 厚棒塊 於 23°C 之切口 Izod (焦耳/公尺） 比重 (克/毫升） Tg (°C) 於170〇C 自熔融物 結晶化作 用半衰期 (分鐘） 於290°C 1弧度/秒 熔融黏度 (Poise) A 15 48.8 0.736 0.707 1069 878 1.184 104 15 5649 B 18 ΝΑ 0.728 0.715 980 1039 1.183 108 22 6621 C 20 ΝΑ 0.706 0.696 1006 1130 1.182 106 52 6321 D 22 ΝΑ 0.732 0.703 959 988 1.178 108 63 7161 E 21 ΝΑ 0.715 0.692 932 482 1.179 110 56 6162 F 24 ΝΑ 0.708 0.677 976 812 1.180 109 58 6282 G 23 ΝΑ 0.650 0.610 647 270 1.182 107 46 3172 Η 23 47.9 0.590 0.549 769 274 1.181 106 47 1736 I 23 48.1 0.531 0.516 696 352 1.182 105 19 1292 J 23 47.8 0.364 ΝΑ NA NA NA 98 NA 167 NA=不可取得。Example 1G This example illustrates the preparation of a molar Mo/0/. Dimethyl terephthalate residue, (9) mol% 2,2,4,4:tetramethyl], cyclobutanediol residue (98/2 cis/reverse) and 8 〇mol %丨, 4 A copolyester of the composition of a cyclohexanol residue (3 1/69 cis/reverse). 77.68 g of dimethyl terephthalate, 48.46 g of i, cyclohexane hexane 117732.doc -317- 200804457 alcohol 20.77 g of 2,2,4,4-tetramethyl-l,3-cyclobutane A mixture of alcohol and 0. 046 g of dibutyltin oxide was placed in a 500 liter flask equipped with a nitrogen inlet tube, a metal stirrer and a short distillation column. Place the simmer in a bath that has been heated to 2 1 〇 之. The stirring speed was set to 2 〇〇 RPM throughout the experiment. The contents of the flask were heated at 21 (rc for 3 minutes, then gradually increased to 260 ° C for 30 minutes. The reaction mixture was held at 26 (Γ (: τ for 120 minutes, then heated up to 30 minutes) 29〇.〇 Once the pressure is gradually applied at 290 ° C, that is, within the next 5 minutes, until the pressure in the flask reaches 100 H Hg, and the scavenging speed is also reduced to 1 〇〇 RPM. Within 5 minutes, the internal pressure of the flask was further reduced to 〇.3 mm Hg' and the stirring speed was reduced to 50 rpm. The pressure of 〇·3 mm Hg was maintained for a total time of 60 minutes to remove excess unreacted two Alcohols. Obtain high melt viscosity, visually transparent and colorless polymer with a glass transition temperature of 103 C and an intrinsic viscosity of 〇·65 com/g. NMR analysis shows that the polymerization system consists of 85.7 mol% 1,4- The cyclohexane-small dimethanol residue is composed of 14·3 mol% 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues. Example 1 This example illustrates the preparation with 100 m. % dimethyl terephthalate residue, 20 mol. / 〇 2,2,4,4-tetramethylcyclobutanediol residue 5/95 cis/reverse) and 80 mol% of a 1,4-cyclohexanedimethanol residue (31/69 cis/reverse) of the composition of the copolyester. 77.68 g of dimethyl terephthalate, a mixture of 48.46 g of 1,4-cyclohexanedipinediol, 20.77 g of 2,2,4,4-tetramethyl-l,3-cyclobutanediol and 〇.〇46 g of dibutyltin oxide Nitrogen inlet tube, metal stirrer and short steaming hall 119732.doc -318. 200804457 In a 500-ml flask in a column. The flask was placed in a 2i (rc Wood's metal bath). At the beginning of the experiment, The stirring speed was set to 2 〇〇 RPM. The contents of the flask were heated at 21 Torr for 3 minutes, then the temperature was gradually increased to 26 (TC over 30 minutes. The reaction mixture was maintained at 26 (Γ:: 120) Minutes, then heat up to 29 在 in 3 〇 minutes. Once at 290 ° C, that is, within the next 5 minutes, gradually apply vacuum, use 1 〇〇 米 H Hg's vote point 'and also make the mixing speed Drop to 1 rpm. Within the next 5 minutes, the internal pressure of the flask was further reduced to a set point of 〇·3 mm Hg and the agitation speed was reduced to 50 RPM. Maintain a total time of 60 minutes' to remove excess unreacted glycols. It should be noted that the vacuum system failed to reach the set point indicated above, but produced sufficient vacuum to produce a high melt viscosity, visually transparent And a colorless polymer having a glass transition temperature of 99 ° C and an intrinsic viscosity of 〇·73 com/g. NMR analysis showed that the polymerization system consisted of 85 mol% 1,4 -cyclohexanediethanol residue and 15 mol The ear is composed of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues. Example 2 This example demonstrates that 2,2,4,4-tetradecyl-1,3·cyclobutanediol improves the pcT-based copolyester (containing terephthalic acid and 1,4-cyclohexane). Toughness of polyester of methanol). A copolyester mainly composed of 2,2,4,4-tetramethyl-1,3-cyclobutanediol was prepared in the following manner. In all the samples, the cis/reverse ratio of 1,4-cyclohexanol dimethanol was about 3 1/69. Copolyesters based on ethylene glycol and 1,4-cyclohexane dimethanol are commercially available polyesters. Example 2 Copolyester (Eastar PCTG 5445) was obtained from Eastman Chemical Company. The copolyester of Example 2B was obtained from Eastman Chemical Company, trader 119732.doc -319-200804457 and the name was Spectar. Example 2C and Example 2D were prepared on a pilot plant scale (15-lb batch each) according to the procedure described in Application Example 1A, and had the intrinsic viscosity and glass transition temperature as described in Table 2 below. Example 2C was prepared to have a tin usage (dibutyltin oxide) of 300 ppm. The final product contained 295 ppm tin. The color values of the polyester of Example 2C were l* = 77.11, a*=_1·50, and b* = 5.79. Example 2 was prepared to have a tin amount (dibutyltin oxide) of 3 〇〇 ppm. The final product contains 3〇7叩(f)tin. The color values of the poly 8 of Example 20 are B* = 66.72, &*=-1.22 and 1)* = 16.28. The material was injection molded to form a rod, and then the notch was used for the Iz〇d test. A 12 〇 (1 impact strength) is obtained as a function of temperature and reported in Table 2. For a given sample, the IZ0d impact strength is subjected to a major transfer in a short temperature interval. For example, at 38 mol% B The IZ〇d impact strength of the diol-based copolyester is subjected to this transfer at 丨5 and 20 ° C. This transfer temperature is associated with failure mode, twist/low energy breakdown at lower temperatures and toughness/in comparison This is related to the change in high-energy high-energy destruction. This temperature transfer is called the ductile-brittle transition temperature Tbd, which is a measure of toughness. The Tbd is reported in Table 2 and the % of the comonomer is shown in Figure 2. Addition of 2,2,4,4-tetramethyl-1,3-cyclobutanediol to pCT reduces Tbd and improves toughness compared to ethylene glycol (which increases Tbd of PCT). 119732.doc 200804457 2 Incision Izod impact energy (absorbed-broken/inch) Example comonomer (mol%) 1 IV (common/gram) Tg (°C) Tbd (°C) at -20 °C at -15 °C At -10 °c at -5 °C at 0 °c at 5 °C at 10 pc at 15 °C at 20 °C at 25 °C at 30 °C at 2 ° 38.0 % B 0.68 86 18 ΝΑ ΝΑ ΝΑ 1.5 ΝΑ ΝΑ 1.5 1. 5 32 32 ΝΑ 2B 69.0 % B 0.69 82 26 ΝΑ ΝΑ ΝΑ ΝΑ ΝΑ ΝΑ 2.1 ΝΑ 2.4 13.7 28.7 2C 22.0 % C 0.66 106 -5 1.5 ΝΑ 12 23 23 ΝΑ 23 ΝΑ ΝΑ ΝΑ ΝΑ 2D 42.8 % C 0.60 133 -12 2.5 2.5 11 ΝΑ 14 ΝΑ ΝΑ ΝΑ ΝΑ ΝΑ ΝΑ 1 The remainder of the polyester diol component in the table is 1,4-cyclohexanedimethanol. All polymerization systems are made from 100 mol% dimethyl terephthalate. NA=Not available. Where: B is ethylene glycol C is 2,2,4,4_tetramethyl-1,3-cyclobutanediol (50/50 cis/reverse) Example 3 Description of this example 2 , 2,4,4-Tetramethyl-1,3-cyclobutanediol improves PCT-based copolyesters (polyesters containing terephthalic acid and 1,4-cyclohexanedimethanol) Toughness. The polyester prepared in this example contains 15 to 25 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues. Ester, 2,2,4,4-tetramethyl 4,% cyclobutanediol and U4-cyclohexanedimethanol (3 1/69 cis/trans) were prepared as described below and had the composition shown in Table 3. And the nature. In Table 3, the diol component in the polyester is balanced to 100 mol%, which is 丨, 4-cyclohexyl Dimethanol (3 1/69 cis / trans). The material was injection molded to form bars of 3·2 mm and 6-4 mm thick, and the subsequent notches were used for the IZ0d impact test. A 23 〇c incision Iz〇d impact strength was obtained and reported in Table 3. Density, Tg and crystallization were measured on bars 119732.doc -321 - 200804457 with half-life. The melt viscosity was measured at 290 ° C on the ingot. Table 3 Summary of various properties of specific polyesters TMCD Mo % % cis TMCD ingot IV (common / gram) Molded bar IV (common / gram) 3.2 mm thick bar at 23 ° C slit Izod (Joules/meter) 6.4 mm thick bar at 23 °C slit Izod (Joules/meter) Specific gravity (g/ml) Tg (°C) at 170 °C Self-melting crystallization half-life (minutes) 290 ° C 1 radians / sec. Melt viscosity (Poise) A 15 48.8 0.736 0.707 1069 878 1.184 104 15 5649 B 18 ΝΑ 0.728 0.715 980 1039 1.183 108 22 6621 C 20 ΝΑ 0.706 0.696 1006 1130 1.182 106 52 6321 D 22 ΝΑ 0.732 0.703 959 988 1.178 108 63 7161 E 21 ΝΑ 0.715 0.692 932 482 1.179 110 56 6162 F 24 ΝΑ 0.708 0.677 976 812 1.180 109 58 6282 G 23 ΝΑ 0.650 0.610 647 270 1.182 107 46 3172 Η 23 47.9 0.590 0.549 769 274 1.181 106 47 1736 I 23 48.1 0.531 0.516 696 352 1.182 105 19 1292 J 23 47.8 0.364 ΝΑ NA NA NA 98 NA 167 NA=Not available.

實例3A 在200 ppm觸媒參（2-乙基己酸）丁基錫存在下，將21.24 磅（49.71克-莫耳）對苯二甲酸二甲基酯、14.34磅（45_21 克-莫耳）1，4-環己烷二曱醇及4_58磅（14.44克-莫耳）2,2,4,4-四甲基-1，3_環丁二醇一起反應。在氮滌氣下，在裝配有冷 凝塔、真空系統及HELICONE-型攪拌器之18-加侖不鏽鋼 壓力瓶中進行反應。使攪拌器在25 RPM運作，將反應混 合物溫度增加至250°C及將壓力增加至20 psig。反應混合 物在25 0°C及20 psig壓力下維持2小時。壓力隨後以3 psig/ -322- 119732.doc 200804457 分鐘速率降低至〇 psig。隨後將反應混合物溫度增加至270 °C及將壓力降低至90毫米Hg。在270°C及90毫米Hg維持1 小時時間之後，將攪拌器速度降低至丨5 rPM，將反應混 合物溫度增加至290°C且將壓力降低至<1毫米Hg。將反應 混合物維持在290°C及<1毫米Hg之壓力下直到加至攪拌器 之動力不再增加（70分鐘）。隨後使用氮氣將壓力瓶之壓力 增加至1大氣壓。隨後自該壓力瓶擠壓該模製聚合體。研 磨該冷卻、經擠製聚合體，使其通過6毫米篩網。該聚合 體具有0.736公合/克之固有黏度及i〇4°C之Tg。NMR分析顯 示該聚合體係由85.4莫耳％ 1，4-環己烷二甲醇殘基及14.6 莫耳°/〇 2,2,4,4-四甲基-1，3-環丁二醇殘基組成。該聚合體 具有顏色值為：L* = 78.20、a*=-1.62 及 b* = 6.23。Example 3A 21.24 lb (49.71 g-mol) dimethyl terephthalate, 14.34 lbs (45-21 g-mole) 1 in the presence of 200 ppm bismuth bis(2-ethylhexanoate) butyltin. 4-cyclohexanedimethanol was reacted with 4 to 58 lbs (14.44 g-mol) of 2,2,4,4-tetramethyl-1,3-cyclobutanediol. The reaction was carried out in an 18-gallon stainless steel pressure bottle equipped with a condensing tower, a vacuum system and a HELICONE-type stirrer under nitrogen scrubbing. The stirrer was operated at 25 RPM, the reaction mixture temperature was increased to 250 ° C and the pressure was increased to 20 psig. The reaction mixture was maintained at 25 ° C and 20 psig for 2 hours. The pressure is then reduced to 〇 psig at a rate of 3 psig / -322 - 119732.doc 200804457 minutes. The temperature of the reaction mixture was then increased to 270 ° C and the pressure was reduced to 90 mm Hg. After maintaining at 270 ° C and 90 mm Hg for 1 hour, the stirrer speed was reduced to 丨 5 rPM, the reaction mixture temperature was increased to 290 ° C and the pressure was lowered to < 1 mm Hg. The reaction mixture was maintained at 290 ° C and a pressure of < 1 mm Hg until the power applied to the agitator was no longer increased (70 minutes). The pressure of the pressure bottle was then increased to 1 atmosphere using nitrogen. The molded polymer is then extruded from the pressure bottle. The cooled, extruded polymer was ground through a 6 mm screen. The polymer had an intrinsic viscosity of 0.736 com/g and a Tg of i 〇 4 °C. NMR analysis showed that the polymerization system consisted of 85.4 mol% 1,4-cyclohexanedimethanol residue and 14.6 mol/〇2,2,4,4-tetramethyl-1,3-cyclobutanediol residue Base composition. The polymer has color values of L* = 78.20, a*=-1.62 and b* = 6.23.

實例3B至實例3D 實例3B至實例3D所述之聚酯係根據類似實例3A之步驟 製備。此等聚酯之組成及性質係顯示於表3。Example 3B to Example 3D The polyesters described in Examples 3B to 3D were prepared according to the procedure similar to Example 3A. The composition and properties of these polyesters are shown in Table 3.

實例3E 在200 ppm觸媒參（2·乙基己酸）丁基錫存在下，將21.24 磅（49.71克-莫耳）對苯二甲酸二甲基酯、12.61磅（39.77 克-莫耳）1，4-環己烷二曱醇及6.30磅（19.88克-莫耳）2,2,4,4-四甲基-1，3-環丁二醇一起反應。在氮滌氣下，在裝配有冷 凝塔、真空系統及HELICONE-型攪拌器之18-加侖不鏽鋼 壓力瓶中進行反應。使攪拌器在25 RPM運作，將反應混 合物溫度增加至250°C及將壓力增加至20 psig。反應混合 物在25 0°C及20 psig壓力下維持2小時。壓力隨後以3 psig/ 119732.doc -323 - 200804457 刀鐘速率降低至〇 pSig。隨後將反應溫度增加至27〇亡及將 壓力降低至90毫米Hg。在270°C及90毫米Hg維持1小時時 間之後，將攪拌器速度降低至15RPM，將反應混合物溫度 增加至290°C且將壓力降低至〈丨毫米Hg。將反應混合物維 持在290°C及&lt;1毫米Hg之壓力下歷時60分鐘。隨後使用氮 氣將壓力瓶之壓力增加至1大氣壓。隨後自該壓力瓶擠壓 該模製聚合體。研磨該冷卻、經擠製聚合體，使其通過6 毫米篩網。該聚合體具有〇·715公合/克之固有黏度及11()t 之Tg。X-射線分析顯示該聚合體具有223 ppm錫。NMR* 析顯示該聚合體係由78·6莫耳❹/◦ l，4-環己烷二甲醇殘基及 21.4莫耳％ 2,2,4,4_四甲基-l，3-環丁二醇殘基組成。該聚合 體具有顏色值為：1^* = 76.45、&amp;*=-1.65及13*=:6.47。Example 3E 21.24 lb (49.71 g-mole) dimethyl terephthalate, 12.61 lbs (39.77 g-mole) 1 in the presence of 200 ppm bismuth bis(ethylhexanoate) butyltin. 4-cyclohexanedimethanol was reacted together with 6.30 lbs (19.88 g-mol) of 2,2,4,4-tetramethyl-1,3-cyclobutanediol. The reaction was carried out in an 18-gallon stainless steel pressure bottle equipped with a condensing tower, a vacuum system and a HELICONE-type stirrer under nitrogen scrubbing. The stirrer was operated at 25 RPM, the reaction mixture temperature was increased to 250 ° C and the pressure was increased to 20 psig. The reaction mixture was maintained at 25 ° C and 20 psig for 2 hours. The pressure is then reduced to 〇 pSig at a knife rate of 3 psig / 119732.doc -323 - 200804457. The reaction temperature was then increased to 27 dying and the pressure was reduced to 90 mm Hg. After maintaining at 270 ° C and 90 mm Hg for 1 hour, the stirrer speed was lowered to 15 RPM, the temperature of the reaction mixture was increased to 290 ° C and the pressure was lowered to < 丨 mm Hg. The reaction mixture was maintained at 290 ° C and a pressure of &lt; 1 mm Hg for 60 minutes. The pressure of the pressure bottle was then increased to 1 atmosphere using nitrogen. The molded polymer is then extruded from the pressure bottle. The cooled, extruded polymer was ground through a 6 mm screen. The polymer has an intrinsic viscosity of 715 Å/g and a Tg of 11 ()t. X-ray analysis showed the polymer to have 223 ppm tin. NMR* analysis showed that the polymerization system consisted of 78·6 moles/◦ 1,4-cyclohexanedimethanol residue and 21.4 mol% 2,2,4,4-tetramethyl-l,3-cyclobutane The diol residue is composed. The polymer has color values of 1^* = 76.45, &amp;*=-1.65 and 13*=:6.47.

實例3F 實例3F所述之聚酯係根據類似實例3a之步驟製備。此 等聚S旨之組成及性質係顯示於表3。Example 3F The polyester described in Example 3F was prepared according to the procedure analogous to Example 3a. The composition and properties of these compositions are shown in Table 3.

實例3G 實例3G所述之聚酯係根據類似實例3A之步驟製備。此 等聚酯之組成及性質係顯示於表3。Example 3G The polyester described in Example 3G was prepared according to the procedure similar to Example 3A. The composition and properties of these polyesters are shown in Table 3.

實例3H 在200 ppm觸媒參（2-乙基己酸）丁基錫存在下，將2124 磅（49.71克-莫耳）對苯二甲酸二甲基酯、1261磅（39.77 克莫耳）1，4-環己烷二甲醇及6.30磅（19.88克-莫耳）2,2,4，心 四甲基-1，3-環丁二醇一起反應。在氮務氣下，在裝配有冷 凝塔、真空系統及HELICONE-型擾拌器之18-加侖不錄網 119732.doc -324- 200804457 壓力瓶中進行反應。使攪拌器在25 RPM運作，將反應混 合物溫度增加至250°C及將壓力增加至20 psig。反應混合 物在250°C及20 psig壓力下維持2小時。壓力隨後以3 psig/ 分鐘速率降低至0 psig。隨後將反應混合物溫度增加至27〇 °C及將壓力降低至90毫米Hg。在270°C及90毫米Hg維持1 小時時間之後，將攪拌器速度降低至15 RPM，將反應混 合物溫度增加至290°C且將壓力降低至&lt;1毫米Hg。將反應 混合物維持在290°C及&lt;1毫米Hg之壓力下，歷時12分鐘。 隨後使用氮氣將壓力瓶之壓力增加至1大氣壓。隨後自該 壓力瓶擠壓該模製聚合體。研磨該冷卻、經擠製聚合體， 使其通過6毫米篩網。該聚合體具有0.590公合/克之固有黏 度及106°C之Tg。NMR分析顯示該聚合體係由77.1莫耳％ 1，4-環己烧二甲醇殘基及22.9莫耳％2,2,4,4-四甲基-1，3-環 丁二醇殘基組成。該聚合體具有顏色值為：L* = 83.27、 a* = -1.34及 b* = 5.08 〇 實例31 在200 ppm觸媒參（2-乙基己酸）丁基錫存在下，將21·24 磅（49.71克-莫耳）對苯二甲酸二甲基酯、12.61磅（39.77 克-莫耳）1，4·環己烧二甲醇及6.30時（19·88克-莫耳）2,2,4,4-四甲基·l，3-環丁二醇一起反應。在氮務氣下，在裝配有冷 凝塔、真空系統及HELICONE-型攪拌器之18_加侖不鏽鋼 壓力瓶中進行反應。使攪拌器在25 RPM運作，將反應混 合物溫度增加至250°C及將壓力增加至20 psig。反應混合 物在25 0°C及20 psig壓力下維持2小時。壓力隨後以3 pSig/ 119732.doc -325 - 200804457 分鐘速率降低至〇 psig。隨後將反應混合物溫度增加至270 °C及將壓力降低至9〇毫米Hg。在270°C及90毫米Hg維持1 小時時間之後，將攪拌器速度降低至丨5 RPM，將反應混 合物溫度增加至290°C且將壓力降低至4毫米Hg。將反應混 合物維持在290°C及4毫米Hg之壓力下，歷時30分鐘。隨後 使用氮氣將壓力瓶之壓力增加至1大氣壓。隨後自該壓力 瓶擠壓該模製聚合體。研磨該冷卻、經擠製聚合體，使其 通過6毫米篩網。該聚合體具有〇·53丨公合/克之固有黏度及 l〇5°C之Tg。NMR分析顯示該聚合體係由76·9莫耳％丨，心環 己烧一甲酵殘基及23_1莫耳％ 2,2,4,4-四甲基- l，3-環丁二醇 殘基組成。該聚合體具有顏色值為：L* = 80.42、a*=-1.28 及 b* = 5.13 〇Example 3H 2124 lbs (49.71 g-mol) dimethyl terephthalate, 1261 lbs (39.77 g moles) 1,4 in the presence of 200 ppm bismuth bis(2-ethylhexanoate) butyltin - cyclohexanedimethanol and 6.30 lbs (19.88 g-mol) 2,2,4, cardiotetramethyl-1,3-cyclobutanediol were reacted together. The reaction was carried out in a pressure vessel of 18-gallon 119732.doc-324-200804457 equipped with a condensing tower, a vacuum system and a HELICONE-type scrambler under nitrogen gas. The stirrer was operated at 25 RPM, the reaction mixture temperature was increased to 250 ° C and the pressure was increased to 20 psig. The reaction mixture was maintained at 250 ° C and 20 psig for 2 hours. The pressure is then reduced to 0 psig at a rate of 3 psig/min. The temperature of the reaction mixture was then increased to 27 ° C and the pressure was reduced to 90 mm Hg. After maintaining at 270 ° C and 90 mm Hg for 1 hour, the stirrer speed was reduced to 15 RPM, the reaction mixture temperature was increased to 290 ° C and the pressure was lowered to &lt; 1 mm Hg. The reaction mixture was maintained at 290 ° C and a pressure of &lt; 1 mm Hg for 12 minutes. The pressure of the pressure bottle was then increased to 1 atmosphere using nitrogen. The molded polymer is then extruded from the pressure bottle. The cooled, extruded polymer was milled through a 6 mm screen. The polymer had an intrinsic viscosity of 0.590 com/g and a Tg of 106 °C. NMR analysis showed that the polymerization system consisted of 77.1 mol% 1,4-cyclohexanthene dimethanol residue and 22.9 mol% 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues. . The polymer has a color value of: L* = 83.27, a* = -1.34, and b* = 5.08 〇 Example 31 in the presence of 200 ppm bismuth (2-ethylhexanoate) butyl tin, 21·24 lbs ( 49.71 g-mole) dimethyl terephthalate, 12.61 lbs (39.77 g-mole) 1,4·cyclohexane dimethanol and 6.30 hrs (19·88 g-mole) 2,2,4 , 4-tetramethyl-l,3-cyclobutanediol is reacted together. The reaction was carried out in an 18-gallon stainless steel pressure bottle equipped with a condensing tower, a vacuum system and a HELICONE-type stirrer under nitrogen gas. The stirrer was operated at 25 RPM, the reaction mixture temperature was increased to 250 ° C and the pressure was increased to 20 psig. The reaction mixture was maintained at 25 ° C and 20 psig for 2 hours. The pressure was then reduced to 〇 psig at a rate of 3 pSig / 119732.doc -325 - 200804457 minutes. The temperature of the reaction mixture was then increased to 270 ° C and the pressure was reduced to 9 mm Hg. After maintaining at 270 ° C and 90 mm Hg for 1 hour, the stirrer speed was reduced to 丨 5 RPM, the reaction mixture temperature was increased to 290 ° C and the pressure was reduced to 4 mm Hg. The reaction mixture was maintained at 290 ° C and a pressure of 4 mm Hg for 30 minutes. The pressure in the pressure bottle was then increased to 1 atmosphere using nitrogen. The molded polymer is then extruded from the pressure bottle. The cooled, extruded polymer was ground and passed through a 6 mm screen. The polymer has an intrinsic viscosity of 〇 53 丨 com / gram and a Tg of 〇 5 ° C. NMR analysis showed that the polymerization system consisted of 76·9 mol% 心, heart-ring carbitol residue and 23_1 mol% 2,2,4,4-tetramethyl-l,3-cyclobutanediol residue Base composition. The polymer has color values of L* = 80.42, a*=-1.28 and b* = 5.13 〇

實例3J 在200 ppm觸媒參（2-乙基己酸）丁基錫存在下，將21.24 碎（49.71克-莫耳）對苯二甲酸二甲基酯、12.61磅（39.77 克-莫耳）1，4-環己烷二曱醇及6.30磅（19.88克-莫耳）2,2,4,4-四曱基-1，3-環丁二醇一起反應。在氮滌氣下，在裝配有冷 凝塔、真空系統及HELICONE-型攪拌器之18-加侖不鏽鋼 壓力瓶中進行反應。使攪拌器在25 RPM運作，將反應混 合物溫度增加至250°C及將壓力增加至20 psig。反應混合 物在25 0°C及20 psig壓力下維持2小時。壓力隨後以3 psig/ 分鐘速率降低至0 psig。隨後將反應混合物溫度增加至270 °C及將壓力降低至90毫米Hg。在270°C及90毫米Hg維持1 小時時間之後，將攪拌器速度降低至15 RPM，將反應混 119732.doc -326- 200804457 合物溫度增加至290°C且將壓力降低至4毫米Hg。當反應混 合物溫度為290°C且壓力為4毫米Hg時，立即使用氮氣將壓 力瓶之壓力增加至1大氣壓。隨後自該壓力瓶擠壓該模製 聚合體。研磨該冷卻、經擠製聚合體，使其通過6毫米篩 網。該聚合體具有0.364公合/克之固有黏度及98°c之Tg。 nmr分析顯示該聚合體係由77 5莫耳％丨，4_環己烷二甲醇 殘基及22.5莫耳❶/◦ 2,2,4,4_四甲基-i，3-環丁二醇殘基組成。 该聚合體具有顏色值為：L*=7 7.20、a*=-1.47及b* =4.62。 實例4 此實例說明2,2,4,4-四甲基-i，3-環丁二醇可改善以pCT為 主之共聚酯（含對苯二甲酸及丨，4_環己烷二曱醇之聚酯）的 韌度。此實例中所製備之聚酯包含大於25至小於4〇莫耳〇/〇 之2,2,4,4_四甲基_1，3_環丁二醇殘基。 以對苯二甲酸二甲基酯' 2,2,4,‘四甲基-丨义環丁二醇 及1，4-環己烷二甲醇（31/69順/反）係如下述方法製備且具有 表4所示之組成及性質。表4中將聚酯中二醇類組份平衡至 100莫耳％者為環己烷二曱醇（31/69順/反）。 材料係射出成型形成3.2毫米及6·4毫米厚之棒塊，且隨 後切凹口用於Iz〇d衝擊試驗。獲得於23之切口 Iz〇d衝擊 強度，並報告於表4中。於棒塊上測量密度、以及結晶化 作用半衰期。在錠塊上於29(rc測量熔融黏度。 119732.doc -327- 200804457 表4 特定聚酯各種性質之彙整 實例 TMCD 莫耳％ %順式 TMCD 錠塊 IV (公合/ 克） 模製棒 塊 IV (公合/ 克） 3.2 mm 厚棒塊 於 23〇C 之切口 Izod (焦耳/公尺） 6.4 mm 厚棒塊 於 23〇C 之切口 Izod (焦耳/公尺） 比重 (克/毫 升） Tg (°C) 於 170°C 自熔融物 結晶化作 用半衰 (分鐘） 於290°C及 1弧度/秒 熔融黏度 (Poise) A 27 47.8 0.714 0.678 877 878 1.178 113 280 8312 B 31 NA 0.667 0.641 807 789 1.174 116 600 6592 NA=不可取得。Example 3J 21.24 (49.71 g-mol) dimethyl terephthalate, 12.61 lbs (39.77 g-mole) 1 in the presence of 200 ppm bisphenol (2-ethylhexanoate) butyl tin. 4-cyclohexanedimethanol was reacted together with 6.30 lbs (19.88 g-mol) of 2,2,4,4-tetradecyl-1,3-cyclobutanediol. The reaction was carried out in an 18-gallon stainless steel pressure bottle equipped with a condensing tower, a vacuum system and a HELICONE-type stirrer under nitrogen scrubbing. The stirrer was operated at 25 RPM, the reaction mixture temperature was increased to 250 ° C and the pressure was increased to 20 psig. The reaction mixture was maintained at 25 ° C and 20 psig for 2 hours. The pressure is then reduced to 0 psig at a rate of 3 psig/min. The temperature of the reaction mixture was then increased to 270 ° C and the pressure was reduced to 90 mm Hg. After maintaining at 270 ° C and 90 mm Hg for 1 hour, the stirrer speed was reduced to 15 RPM, the temperature of the reaction mixture 119732.doc - 326 - 200804457 was increased to 290 ° C and the pressure was reduced to 4 mm Hg. When the reaction mixture temperature was 290 ° C and the pressure was 4 mm Hg, the pressure of the pressure bottle was immediately increased to 1 atm using nitrogen gas. The molded polymer is then extruded from the pressure bottle. The cooled, extruded polymer was ground and passed through a 6 mm screen. The polymer had an intrinsic viscosity of 0.364 com/g and a Tg of 98 °c. The nmr analysis showed that the polymerization system consisted of 77 5 mole % 4, 4 - cyclohexane dimethanol residue and 22.5 moles / ◦ 2,2,4,4 -tetramethyl-i,3-cyclobutanediol. Residue composition. The polymer has a color value of L*=7 7.20, a*=-1.47, and b*=4.62. Example 4 This example demonstrates that 2,2,4,4-tetramethyl-i,3-cyclobutanediol improves pCT-based copolyesters (containing terephthalic acid and hydrazine, 4_cyclohexane Toughness of sterol polyester). The polyester prepared in this example contains 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues of from more than 25 to less than 4 moles of oxime/oxime. The dimethyl terephthalate ' 2,2,4,' tetramethyl-decylcyclobutanediol and 1,4-cyclohexanedimethanol (31/69 cis / trans) were prepared as follows And has the composition and properties shown in Table 4. The balance of the diol component in the polyester to 100 mol% in Table 4 is cyclohexanedimethanol (31/69 cis/reverse). The material was injection molded to form rods of 3.2 mm and 6.4 mm thick, and then the notches were used for the Iz〇d impact test. The Iz〇d impact strength at 23 incisions was obtained and reported in Table 4. The density, as well as the crystallization half-life, were measured on the bars. The melt viscosity was measured on the ingot at 29 (rc. 119732.doc -327- 200804457 Table 4 Example of the various properties of the specific polyester TMCD Mo % % cis TMCD ingot IV (common / gram) molded rod IV (common/gram) 3.2 mm thick bar at 23〇C slit Izod (joules/meter) 6.4 mm thick bar at 23〇C slit Izod (joules/meter) specific gravity (g/ml) Tg (°C) at 170 ° C from the crystallization of the melt half-life (minutes) at 290 ° C and 1 radians / second melt viscosity (Poise) A 27 47.8 0.714 0.678 877 878 1.178 113 280 8312 B 31 NA 0.667 0.641 807 789 1.174 116 600 6592 NA=Not available.

實例4A 在200 ppm觸媒參（2-乙基己酸）丁基錫存在下，將21·24 磅（49.71克-莫耳）對苯二甲酸二甲基酯、11.82磅（37·28 克-莫耳）1，4-環己烷二甲醇及6·90磅（21·77克-莫耳）2,2,4,4-四甲基-l,3-環丁二醇一起反應。在氮滌氣下，在裝配有冷 凝塔、真空系統及HELICONE-型攪拌器之18-加侖不鏽鋼 壓力瓶中進行反應。使攪拌器在25 RPM運作，將反應混 合物溫度增加至250°C及將壓力增加至20 psig。反應混合 物在250°C及20 psig壓力下維持2小時。壓力隨後以3 psig/ 分鐘速率降低至〇 psig。隨後將反應混合物溫度增加至270 °C及將壓力降低至90毫米Hg。在270°C及90毫米Hg維持1 小時時間之後，將攪拌器速度降低至15 RPM，將反應混 合物溫度增加至290°C且將壓力降低至&lt;1毫米Hg。將反應 混合物維持在290°C及&lt;1毫米Hg之壓力下直到加至攪拌器 之動力不再增加（50分鐘）。隨後使用氮氣將壓力甑之壓力 增加至1大氣壓。隨後自該壓力瓶擠壓該模製聚合體。研 119732.doc -328 - 200804457 磨忒冷卻經擠製聚合體，使其通過6毫米篩網。該聚合 體具有G.714A σ /克之固有_度及⑴。c之^。疆r分析領 示該聚合體係由73.3莫耳％ M_環己烧二甲醇殘基及Μ 莫耳％2,2,4,4，甲基#環丁二醇殘基組成。Example 4A 21.24 lb (49.71 g-mole) dimethyl terephthalate, 11.82 lbs (37.28 g-mo in the presence of 200 ppm bismuth bis(2-ethylhexanoate) butyltin The ear) 1,4-cyclohexanedimethanol and 6.90 lbs (21.7 g-mol) 2,2,4,4-tetramethyl-l,3-cyclobutanediol were reacted together. The reaction was carried out in an 18-gallon stainless steel pressure bottle equipped with a condensing tower, a vacuum system and a HELICONE-type stirrer under nitrogen scrubbing. The stirrer was operated at 25 RPM, the reaction mixture temperature was increased to 250 ° C and the pressure was increased to 20 psig. The reaction mixture was maintained at 250 ° C and 20 psig for 2 hours. The pressure is then reduced to 〇 psig at a rate of 3 psig/min. The temperature of the reaction mixture was then increased to 270 ° C and the pressure was reduced to 90 mm Hg. After maintaining at 270 ° C and 90 mm Hg for 1 hour, the stirrer speed was reduced to 15 RPM, the reaction mixture temperature was increased to 290 ° C and the pressure was lowered to &lt; 1 mm Hg. The reaction mixture was maintained at 290 ° C and a pressure of &lt; 1 mm Hg until the power applied to the agitator was no longer increased (50 minutes). Nitrogen gas was then used to increase the pressure of the pressure helium to 1 atmosphere. The molded polymer is then extruded from the pressure bottle. Grinding 119732.doc -328 - 200804457 The crucible polymer was cooled and passed through a 6 mm screen. The polymer has an inherent degree of G.714A σ / gram and (1). c^^. The analysis by r showed that the polymerization system consisted of 73.3 mol% of M_cyclohexane dimethanol residue and Μmol %2,2,4,4,methyl #cyclobutanediol residues.

實例4B 實例4B所述之聚酯係根據類似實例* a之步驟製備。此 等聚酯之組成及性質係顯示於表4。 實例5 此實例說明2,2,4,4·四甲基·1，3-環丁二醇可？文善以PCT為 ^之共聚_ (含對苯二甲酸及Μ環己烧二甲醇之聚酉旨）的 早刃度。此實例中所製備之聚酯包含4〇莫耳％或更多之量之 2,2,4,4-四甲基-1，3_環丁二醇殘基。 以對苯一甲酸二甲基酯、2,2,4,4•四甲基义弘環丁二醇 及M-裱己烷二甲醇（31/69順/反）係如下述方法製備且具有 表5所示之組成及性質。表5中將聚酯中二醇類組份平衡至 100莫耳％者為丨，4·環己烷二曱醇（3 1/69順/反）。 材料係射出成型形成3·2毫米及6·4毫米厚之棒塊，且隨 後切凹口用於120(1衝擊試驗。獲得23。〇之切口 iz〇d衝擊強 度，並報告於表5中。於棒塊上測量密度、Tg及結晶化作 用半衰期。在錠塊上於29〇°C測量熔融黏度。 119732.doc 200804457 表5 特定聚酯各種性質之彙整 實 例 TMCD 莫耳％ %順式 TMCD 錠塊 IV (公合/ 克） 模製棒 塊 IV (公合/克) 3.2 mm 厚棒塊 於 23°C 之切口 Izod (焦耳/公尺） 6.4 mm 厚棒塊 於 23〇C 之切口 Izod (焦耳/公尺） 比重 (克/毫 升） Tg (°C) 於 170°C 自熔融物 結晶化作 用半衰期 (分鐘） 於290°C及 1弧度/秒 熔融黏度 (Poise) A 44 46.2 0.657 0.626 727 734 1.172 119 NA 9751 B 45 NA 0.626 0.580 748 237 1.167 123 NA 8051 C 45 NA 0.582 0.550 671 262 1.167 125 19782 5835 D 45 NA 0.541 0.493 424 175 1.167 123 NA 3275 E 59 46.6 0.604 0.576 456 311 1.156 139 NA 16537 F 45 47.2 0.475 0.450 128 30 1.169 121 NA 1614 NA=不可取得。Example 4B The polyester described in Example 4B was prepared according to the procedure of similar example * a. The composition and properties of these polyesters are shown in Table 4. Example 5 This example illustrates 2,2,4,4·tetramethyl·1,3-cyclobutanediol? Wenshan uses PCT as the copolymerization of _ (containing terephthalic acid and anthraquinone hexahydromethane). The polyester prepared in this example contained 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues in an amount of 4% by mole or more. Benzyl benzoic acid dimethyl ester, 2,2,4,4•tetramethylyihongcyclobutanediol and M-hexane hexane dimethanol (31/69 cis/trans) are prepared as follows and have The composition and properties shown in Table 5. In Table 5, the balance of the glycol component in the polyester to 100 mol% is 丨, 4·cyclohexanedioxanol (3 1/69 cis/reverse). The material was injection molded to form rods of 3·2 mm and 6.4 mm thick, and then the notches were used for 120 (1 impact test. Obtained 23 incision iz〇d impact strength, and reported in Table 5 Density, Tg and crystallization half-life were measured on bars. Melt viscosity was measured on ingots at 29 ° C. 119732.doc 200804457 Table 5 Summary of various properties of specific polyesters TMCD Mo % % cis TMCD Ingot IV (common / gram) Molded bar IV (common / gram) 3.2 mm thick bar at 23 ° C slit Izod (Joule / meter) 6.4 mm thick bar at 23 ° C slit Izod (Joules/meter) Specific Gravity (g/ml) Tg (°C) at 170°C Self-melting crystallization half-life (minutes) at 290°C and 1 radians/second Melt viscosity (Poise) A 44 46.2 0.657 0.626 727 734 1.172 119 NA 9751 B 45 NA 0.626 0.580 748 237 1.167 123 NA 8051 C 45 NA 0.582 0.550 671 262 1.167 125 19782 5835 D 45 NA 0.541 0.493 424 175 1.167 123 NA 3275 E 59 46.6 0.604 0.576 456 311 1.156 139 NA 16537 F 45 47.2 0.475 0.450 128 30 1.169 121 NA 1614 NA=Not desirable .

實例5A 在200 ppm觸媒參（2-乙基己酸）丁基錫存在下，將21.24 磅（49.71克-莫耳）對苯二甲酸二曱基酯、8.84磅（27.88克-莫 耳）1，4-環己烷二甲醇及10.08磅（31.77克-莫耳）2,2,4,4_四甲 基-1，3 -環丁二醇一起反應。在氮滌氣下，在裝配有冷凝 塔、真空系統及HELICONE-型攪拌器之18-加侖不鏽鋼壓 力瓶中進行反應。使攪拌器在25 RPM運作，將反應混合 物溫度增加至250°C及將壓力增加至20 psig。反應混合物 在25 0°C及20 psig壓力下維持2小時。壓力隨後以3 psig/分 鐘速率降低至0 psig。隨後將攪拌器之速度降低至15 RPM，且隨後將反應混合物溫度增加至290°C及將壓力降 低至2毫米Hg。將反應混合物維持在290°C及2毫米Hg之壓 力下直到加至攪拌器之動力不再增加（80分鐘）。隨後使用 -330 - 119732.doc 200804457 氮氣將壓力瓶之壓力增加至丨大氣壓。隨後自該壓力瓶擠 壓該模製聚合體。研磨該冷卻、經擠製聚合體，使其通過 6毫米篩網。該聚合體具有〇 657公合/克之固有黏度及 119°C之Tg。NMR分析顯示該聚合體係由563莫耳％丨，4•環 己烷二甲醇殘基及43.7莫耳％2,2,4,4-四甲基-1，3-環丁二醇 殘基組成。該聚合體具有顏色值為：l* = 75.04、a*=-1.82 及 b* = 6.72。Example 5A 21.24 lb (49.71 g-mol) didecyl terephthalate, 8.84 lbs (27.88 g-mole) 1 in the presence of 200 ppm bismuth bis(2-ethylhexanoate) butyltin. 4-cyclohexanedimethanol was reacted with 10.08 lbs (31.77 g-mol) of 2,2,4,4-tetramethyl-1,3-cyclobutanediol. The reaction was carried out in an 18-gallon stainless steel pressure bottle equipped with a condensation column, a vacuum system and a HELICONE-type stirrer under nitrogen scrubbing. The stirrer was operated at 25 RPM, the reaction mixture temperature was increased to 250 ° C and the pressure was increased to 20 psig. The reaction mixture was maintained at 25 ° C and 20 psig for 2 hours. The pressure is then reduced to 0 psig at a rate of 3 psig/min. The speed of the stirrer was then reduced to 15 RPM, and then the temperature of the reaction mixture was increased to 290 ° C and the pressure was reduced to 2 mm Hg. The reaction mixture was maintained at 290 ° C and a pressure of 2 mm Hg until the power applied to the agitator was no longer increased (80 minutes). The pressure in the pressure bottle is then increased to atmospheric pressure using -330 - 119732.doc 200804457 nitrogen. The molded polymer is then extruded from the pressure bottle. The cooled, extruded polymer was milled through a 6 mm screen. The polymer had an intrinsic viscosity of 657 gal/gram and a Tg of 119 °C. NMR analysis showed that the polymerization system consisted of 563 mol% 丨, 4 • cyclohexane dimethanol residue and 43.7 mol% 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues. . The polymer has color values of: l* = 75.04, a*=-1.82, and b* = 6.72.

實例5B至實例5D 實例5B至實例5D所述之聚g旨係根據類似實例5A之步驟 製備。此等聚酯之組成及性質係顯示於表5。Example 5B to Example 5D The polyg described in Example 5B to Example 5D was prepared according to the procedure similar to Example 5A. The composition and properties of these polyesters are shown in Table 5.

實例5E 在200 ppm觸媒參（2-乙基己酸）丁基錫存在下，將2124 碎（49.71克-莫耳）對苯二甲酸二甲基酯、6.43碎（2 0.28克-莫 耳）1，4-環己烧二甲醇及12.49碎（39.37克-莫耳）2,2,4,4_四甲 基-1，3-¾ 丁二醇一起反應。在氮務氣下，在裝配有冷凝 塔、真空系統及HELICONE-型攪拌器之18-加侖不鏽鋼壓 力瓶中進行反應。使攪拌器在25 RPM運作，將反應混合 物溫度增加至250°C及將壓力增加至20 psig。反應混合物 在250°C及20 psig壓力下維持2小時。壓力隨後以3 pSig/分 鐘速率降低至0 psig。隨後將攪拌器之速度降低至i 5 RPM，且隨後將反應混合物溫度增加至290°C及將壓力降 低至2毫米Hg。將反應混合物維持在290。〇及&lt;1毫米Hg之 壓力下直到加至擾拌器之動力不再增加（50分鐘）。隨後使 用氮氣將壓力瓶之壓力增加至1大氣壓。隨後自該壓力瓶 119732.doc -331- 200804457 擠壓該模製聚合體。研磨該冷卻、經擠製聚合體，使其通 過ό毫米篩網。該聚合體具有〇·6〇4公合/克之固有黏度及 139°C之Tg。NMR分析顯示該聚合體係由4〇·8莫耳。丨，‘環 己烧二甲醇殘基及59·2莫耳0/〇 2,2,4,4_四曱基·-環丁二酵 殘基組成。该聚合體具有顏色值為·· L* = 8〇.48、 及 b* = 6.82。Example 5E 2124 was chopped (49.71 g-mol) dimethyl terephthalate, 6.43 (2 0.28 g-mole) in the presence of 200 ppm bismuth (2-ethylhexanoate) butyltin 1 4-cyclohexanyl dimethanol and 12.49 comminuted (39.37 g-mol) 2,2,4,4-tetramethyl-1,3-3⁄4 butanediol were reacted together. The reaction was carried out in an 18-gallon stainless steel pressure bottle equipped with a condensation column, a vacuum system and a HELICONE-type stirrer under nitrogen gas. The stirrer was operated at 25 RPM, the reaction mixture temperature was increased to 250 ° C and the pressure was increased to 20 psig. The reaction mixture was maintained at 250 ° C and 20 psig for 2 hours. The pressure is then reduced to 0 psig at a rate of 3 pSig/min. The speed of the stirrer was then lowered to i 5 RPM, and then the temperature of the reaction mixture was increased to 290 ° C and the pressure was lowered to 2 mm Hg. The reaction mixture was maintained at 290. Under the pressure of &lt; 1 mm Hg until the power added to the scrambler is no longer increased (50 minutes). The pressure of the pressure bottle was then increased to 1 atmosphere using nitrogen. The molded polymer was then extruded from the pressure bottle 119732.doc -331-200804457. The cooled, extruded polymer is ground through a millimeter screen. The polymer had an intrinsic viscosity of 〇6〇4 com/g and a Tg of 139 °C. NMR analysis showed the polymerization system to be 4 〇·8 mol.丨, ‘Cyclohexene dimethanol residue and 59·2 molar 0/〇 2,2,4,4_tetradecyl·-cyclobutanin residue. The polymer has a color value of L* = 8 〇.48, and b* = 6.82.

實例5F 在200 ppm觸媒參（2-乙基己酸）丁基錫存在下，將2ι·24 石旁（4 9.71克-莫耳）對苯二曱酸二曱基醋、884碎（2 7.88克-莫 耳）1，4-環己烷二甲醇及1〇〇8磅（3177克_莫耳）2,2,4,4-四甲 基-1，3-環丁二醇一起反應。在氮滌氣下，在裝配有冷凝 塔、真空系統及HELICONE-型攪拌器之18-加侖不鏽鋼壓 力瓶中進行反應。使攪拌器在25 RPM運作，將反應混合 物溫度增加至250°C及將壓力增加至20 psig。反應混合物 在250°C及20 psig壓力下維持2小時。壓力隨後以3 psig/* 鐘速率降低至0 psig。隨後將反應混合物溫度增加至]^^ 及將壓力降低至90毫米Hg。維持270°C及90毫米Hg，歷時 1小時後，將攪拌器之速度降低至丨5 rpm，及將壓力降低 至4毫米Hg。當反應混合物溫度為27〇。〇及壓力為4毫米 Hg ’立即使用氮氣將壓力瓶之壓力增加至1大氣壓。隨後 自該壓力瓶擠壓該模製聚合體。研磨該冷卻、經擠製聚合 體，使其通過6毫米篩網。該聚合體具有〇·475公合/克之固 有黏度及121°C之Tg。NMR分析顯示該聚合體係由55 5莫 耳％ 1，4-環己烧二甲醇殘基及44.5莫耳％ 2,2,4,4-四甲基 119732.doc -332- 200804457 1，3-環丁二醇殘基組成。該聚合體具有顏色值為： L* = 85.63、a*=-〇 88及 b*=4.34。 實例6-比較實例 此實例顯示關於表6中比較材料之數據。PC為得自Bayer 之Makr〇l〇I1 26〇8，名義上組成為1〇〇莫耳％雙酚A殘基及 1〇〇莫耳。/〇碳酸二苯基酯。Makrolon 2608具有20克/10分鐘 之名義上熔融流率，其係使用1.2 kg重量於300°C量測。 PET為得自伊士曼化學公司之Eastar 9921，名義上組成為 1〇〇莫耳％對苯二甲酸、3.5莫耳％環己烷二甲醇（CHDM)及 96·5莫耳％乙二醇。PetG為得自伊士曼化學公司之Eastar 6763，名義上組成為1〇〇莫耳％對苯二甲酸、31莫耳％環己 烷二甲醇（CHDM)及69莫耳％乙二醇。PCTG為得自伊士曼 化學公司之Eastar DN001，名義上組成為1〇〇莫耳％對苯二 甲酸、62莫耳％環己烷二甲醇（CHDM)及38莫耳％乙二醇。 PCTA為得自伊士曼化學公司之Eastar AN001，名義上組成 為65莫耳％對苯二甲酸、35莫耳％間苯二甲酸及1〇〇莫耳％ 環己院二甲醇（CHDM)。聚颯為得自Solvay之Udel 17〇〇， 名義上組成為100莫耳％雙酚A殘基及100莫耳％ 4，扣二氣磺 醯基石風（4,4-dichlorosulfonyl sulfone)殘基。Udel 17〇〇具有 6· 5克/10分鐘之名義上溶融流率，其係使用2·16 kg重量於 343°C量測。SAN為得自Lanxess之Lustran 31，名義上組成 為76重量％苯乙稀及24重量％丙稀猜。Lustr an 3 1具有7 5 克/10分鐘之名義上炼融流率’其係使用kg重量於230 °c量測。此等包含2,2,4,4-四甲基-1，3-環丁二醇之實例相較 119732.doc -333 - 200804457 於所有其他樹脂，顯示了在6.4毫米厚度棒塊之改良的韌 度。 表6 特定市售聚酯各種性質之彙整Example 5F In the presence of 200 ppm bismuth bis(2-ethylhexanoate) butyltin, 2 ι·24 stoneside (4 9.71 gram-mole) terephthalic acid dimercapto vinegar, 884 (2 7.88 g) - Molar) 1,4-cyclohexanedimethanol and 1 Torr (8177 g-mol) 2,2,4,4-tetramethyl-1,3-cyclobutanediol were reacted together. The reaction was carried out in an 18-gallon stainless steel pressure bottle equipped with a condensation column, a vacuum system and a HELICONE-type stirrer under nitrogen scrubbing. The stirrer was operated at 25 RPM, the reaction mixture temperature was increased to 250 ° C and the pressure was increased to 20 psig. The reaction mixture was maintained at 250 ° C and 20 psig for 2 hours. The pressure is then reduced to 0 psig at a rate of 3 psig/*. The temperature of the reaction mixture was then increased to [...] and the pressure was reduced to 90 mm Hg. Maintaining 270 ° C and 90 mm Hg, after 1 hour, the speed of the stirrer was reduced to 丨 5 rpm and the pressure was reduced to 4 mm Hg. When the temperature of the reaction mixture was 27 Torr. The helium pressure was 4 mm Hg. The pressure of the pressure bottle was immediately increased to 1 atmosphere using nitrogen. The molded polymer is then extruded from the pressure bottle. The cooled, extruded polymer was milled through a 6 mm screen. The polymer had a solid viscosity of 475 Å/g and a Tg of 121 °C. NMR analysis showed that the polymerization system consisted of 55 5 mol% 1,4-cyclohexane-small dimethanol residue and 44.5 mol% 2,2,4,4-tetramethyl 119732.doc -332- 200804457 1,3- The composition of the cyclobutanediol residue. The polymer has color values of L* = 85.63, a*=-〇 88 and b*=4.34. Example 6 - Comparative Example This example shows data on the comparative materials in Table 6. PC is Makr〇l〇I1 26〇8 from Bayer, nominally composed of 1 mole% bisphenol A residue and 1 mole. / Diphenyl carbonate. Makrolon 2608 has a nominal melt flow rate of 20 g/10 min, which is measured using a 1.2 kg weight at 300 °C. PET is Eastar 9921 from Eastman Chemical Company, nominally 1 〇〇 mol % terephthalic acid, 3.5 mol % cyclohexane dimethanol (CHDM) and 96 · 5 mol % ethylene glycol . PetG is Eastar 6763 from Eastman Chemical Company, nominally composed of 1 mole % terephthalic acid, 31 mole % cyclohexane dimethanol (CHDM) and 69 mole % ethylene glycol. PCTG is Eastar DN001 from Eastman Chemical Company and nominally consists of 1 mole % terephthalic acid, 62 mole % cyclohexane dimethanol (CHDM) and 38 mole % ethylene glycol. PCTA is Eastar AN001 from Eastman Chemical Company, nominally composed of 65 mole % terephthalic acid, 35 mole % isophthalic acid and 1 mole % cycloheximide dimethanol (CHDM). Polyfluorene is Udel 17 from Solvay, nominally composed of 100 mole % bisphenol A residue and 100 mole % 4, 4,4-dichlorosulfonyl sulfone residue. Udel 17 has a nominal melt flow rate of 6.5 g/10 minutes, which is measured using a weight of 2·16 kg at 343 °C. The SAN is Lustran 31 from Lanxess, nominally composed of 76% by weight of styrene and 24% by weight of propylene. Lustr an 3 1 has a nominal smelting flow rate of 7 5 g/10 min' which is measured using a kg weight of 230 °c. Examples of these 2,2,4,4-tetramethyl-1,3-cyclobutanediols compared to 119732.doc-333 - 200804457 for all other resins, show improved in 6.4 mm thick bars tenacity. Table 6 Summary of various properties of specific commercially available polyesters

實例 聚合體 名稱 錠塊 IV (公合/克） 模製棒塊 IV (公合/克） 3.2 mm 厚棒塊 於 23〇C 之切口 Izod (焦耳/公尺） 6.4 mm 厚棒塊 於 23°C 之切口 Izod (焦耳/公尺） 比重 (克/毫升） Tg (°C) 於自熔融物 結晶化作用 半衰期 (分鐘） A PC 12MFR NA 929 108 1.20 146 NA B PCTG 0.73 0.696 NB 70 1.23 87 170°C，30分鐘 C PCTA 0.72 0.702 98 59 1.20 87 150°C，15 分鐘 D PETG 0.75 0.692 83 59 1.27 80 130°C，2500分鐘 E PET 0.76 0.726 45 48 1.33 78 170°C，1.5 分鐘 F SAN 7.5 MFR NA 21 NA 1.07 〜110 NA G PSU 6.5 MFR NA 69 NA 1.24 〜190 NA NA=不可取得。 實例7 此實例係說明用於製備多種聚酯之2,2,4,4-四甲基-1，3-環丁二醇之量，對於聚酯玻璃轉移溫度之作用。在此實例 中製成之聚酯包含15至25莫耳％ 2,2,4,4-四甲基·1，3·環丁 二醇殘基。Example Polymer Name Ingot IV (common/gram) Molded Bar IV (common/gram) 3.2 mm thick bar at 23〇C slit Izod (joules/meter) 6.4 mm thick bar at 23° C slit Izod (Joules/meter) Specific gravity (g/ml) Tg (°C) Crystallization half-life from the melt (minutes) A PC 12MFR NA 929 108 1.20 146 NA B PCTG 0.73 0.696 NB 70 1.23 87 170 °C, 30 minutes C PCTA 0.72 0.702 98 59 1.20 87 150°C, 15 minutes D PETG 0.75 0.692 83 59 1.27 80 130°C, 2500 minutes E PET 0.76 0.726 45 48 1.33 78 170°C, 1.5 minutes F SAN 7.5 MFR NA 21 NA 1.07 ~ 110 NA G PSU 6.5 MFR NA 69 NA 1.24 ~ 190 NA NA= Not available. Example 7 This example illustrates the effect of the amount of 2,2,4,4-tetramethyl-1,3-cyclobutanediol used to prepare a plurality of polyesters on the transfer temperature of the polyester glass. The polyester produced in this example contained 15 to 25 mol% of 2,2,4,4-tetramethyl·1,3·cyclobutanediol residues.

實例7Α至實例7G 將對苯二甲酸二甲酯、1,4-環己烷二甲醇及2,2,4,4-四甲 基-1，3-環丁二醇稱重置於500-毫升單頸圓底燒瓶中。關於 2,2,4,4-四甲基-1，3-環丁二醇起始物質之NMR分析，顯示 順/反比例為53/47。此實例之聚酯係以1.2/1二醇/酸比例製 -334- 119732.doc 200804457 成’其中整體過望係來自2,2,4,4 -四曱基-1，3 -環丁二醇。 添加足夠氧化二丁基錫觸媒，以在最後聚合體中獲得3〇〇 ppm錫。燒瓶係在〇·2 SCFC氮滌氣下，具有真空降低能 力。將燒觀浸沒在200°C下之Belmont金屬浴中，並在反廣 物已熔解後，於200 RPM下攪拌。約2.5小時後，使溫度升 南至210 C，並將此等條件保持另外2小時。使溫度升高至 285°C (在大約25分鐘内），並使壓力降至〇·3毫米Hg，歷經5 分鐘期間。當黏度增加時，降低攪拌，其中丨5 RPM為所 使用之表小攪拌。總聚合時間係經改變，以獲得標的固有 黏度。於聚合反應完成後，使Belmont金屬浴下降，並使 聚合體冷卻至低於其玻璃轉移溫度。約3〇分鐘後，使燒瓶 再浸沒於Belmont金屬浴中（在此30分鐘等候期間，溫度已 增加至295°C )，並將聚合體團塊加熱，直到其拉離玻璃燒 瓶為止。聚合體團塊係在燒瓶中，於中等程度下擾拌，直 到聚合體已冷卻為止。將聚合體移離燒瓶，並研磨以通過 3宅米師網。施行對此程序之變型，以製造下文所述之共 聚酯’具有標的組成為20、3 2及45莫耳％。 固有黏度係按上文”度量方法”段落中所述度量。聚酯之 組成係如前文在度量方法段落中所解釋，藉由1H NMR測 疋。玻璃轉移溫度係藉由DSC，在驟冷後，於2〇 分鐘之 速率下，使用第二次加熱測定。Example 7 to Example 7G Reset dimethyl terephthalate, 1,4-cyclohexanedimethanol, and 2,2,4,4-tetramethyl-1,3-cyclobutanediol to 500- ML in a single neck round bottom flask. NMR analysis of the starting material of 2,2,4,4-tetramethyl-1,3-cyclobutanediol showed a cis/inverse ratio of 53/47. The polyester of this example is made up of a ratio of 1.2/1 diol/acid -334-119732.doc 200804457 into 'the whole of the system is from 2,2,4,4-tetradecyl-1,3-cyclobutane alcohol. Sufficient dibutyltin oxide catalyst was added to obtain 3 〇〇 ppm tin in the final polymer. The flask was vacuum-reduced under 〇·2 SCFC nitrogen scrubbing. The burnt immersion was immersed in a Belmont metal bath at 200 ° C and stirred at 200 RPM after the counter-product had melted. After about 2.5 hours, the temperature was allowed to rise to 210 C and these conditions were maintained for an additional 2 hours. The temperature was raised to 285 ° C (within about 25 minutes) and the pressure was lowered to 〇 3 mm Hg over a period of 5 minutes. When the viscosity is increased, the agitation is lowered, wherein 丨5 RPM is a small agitation of the used table. The total polymerization time is varied to obtain the intrinsic viscosity of the target. After completion of the polymerization, the Belmont metal bath was lowered and the polymer was allowed to cool below its glass transition temperature. After about 3 minutes, the flask was re-immersed in a Belmont metal bath (the temperature had increased to 295 °C during this 30 minute waiting period) and the polymer mass was heated until it was pulled away from the glass vial. The polymer mass was tied to the flask and moderately scrambled until the polymer had cooled. The polymer was removed from the flask and ground to pass through the 3 house net. A variation of this procedure was carried out to produce a copolyester&apos; as described below having a nominal composition of 20, 3 2 and 45 mole %. The intrinsic viscosity is measured as described in the "Measuring Methods" section above. The composition of the polyester was as described above in the section on measurement methods and was measured by 1H NMR. The glass transition temperature was determined by DSC using a second heating at a rate of 2 Torr after quenching.

實例7H至實例7Q 此等實例係藉由在個別階段中進行酯交換與聚縮合反應 而製成。酯交換實驗係在連續溫度上升（Ctr)反應器中進 119732.doc -335- 200804457 行。CTR為3000毫升玻璃反應器，褒有單軸葉輪片挽拌 器，以電加熱罩覆蓋，及裝有熱包裝回流冷凝管柱。於反 應器中裝填7 7 7公克（4莫耳）對苯二甲酸二甲醋、2 3 〇公克 ㈤莫耳即从四甲基^-環丁二醇^㈣公克即莫 耳）環己炫二甲醇及丨.12公克參_2_乙基己酸了基錫（以致將 有200 ppm錫金屬在最後聚合體中）。將加熱罩以手動方式 設定至厮。輸出。肢點與數據收集係藉助於㈤以程序 控制系統。-旦反應物被熔解’即起始攪拌，且慢慢地增 加至250 rpm。反應器之溫度係隨著操作時間逐漸增加。 所收集之甲醇重里係經由天平記錄。當停止甲醇釋出或在 預先選擇之較低溫度26(TC下時，使反應停止。將寡聚物 以鼠滌氣排放，並冷卻至室溫。以液態氮使寡聚物冷凍並 破碎成足夠小之片塊，以被稱重置於5〇〇毫升圓底燒瓶 中。 在聚縮合反應中，係於500毫升圓底燒瓶中裝填大約15〇 克上文製成之寡聚物。燒瓶係裝有不銹鋼攪拌器與聚合體 頭部。將玻璃器具安裝在半莫耳聚合體機床上，並起始 Camile順序。一旦寡聚物熔解，即將攪拌器定位，自燒瓶 底4 一整圈。對各實例藉由Camile軟體控制之溫度/壓力/ 攪拌速率順序係報告於下列表中 實例7H與實例71之Camile順序 階段 時間(分鐘） 溫度(°C) 真空(托） 挽拌(rpm) 1 5 245 760 0 2 5 245 760 50 119732.doc •336- 200804457 3 30 265 760 50 4 3 265 90 50 5 110 290 90 50 6 5 290 6 25 7 110 290 6 25 實例7N至實例7Q之Camile順序 階段 時間(分鐘） 溫度(°c) 真空(托） 攪拌(rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 3 265 90 50 5 110 290 90 50 6 5 290 3 25 7 110 290 3 25 實例7K與實例7L之Camile順序 階段 時間(分鐘） 溫度(°c) 真空(托） 攪拌(rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 3 265 90 50 5 110 290 90 50 6 5 290 2 25 7 110 290 2 25 119732.doc -337 - 200804457 實例7J與實例7M之Camile順序 階段 時間(分鐘） 溫度(°c) 真空(托） 挽拌(rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 3 265 90 50 5 110 290 90 50 6 5 290 1 25 7 110 290 1 25 將所形成之聚合體自燒瓶回收，使用液壓切斷器切斷， 並研磨至6毫米篩網大小。使各經研磨之聚合體試樣接受 測試，關於固有黏度係在60/40 (重量/重量）酚/四氯乙烷 中，於0.5克/100毫升之濃度下，在25。〇下，觸媒含量（Sn) 藉由X-射線螢光，及顏色（L*，a*，b*)藉由透光率光譜學。 聚合體組成係藉由1H NMR獲得。使試樣接受熱安定性與 溶融黏度測試，使用流變學機械光譜儀（RMS_8〇㈠。 下表顯示此實例聚酯之實驗數據。數據顯示增加 2,2,4,4-四曱基- i，3-環丁二醇之含量，會以幾乎線性方式 提升玻璃轉移溫度，對恒定固有黏度。圖3亦顯示Tg對於 組成與固有黏度之依存性。 119732.doc -338 - 200804457 表7 玻璃轉移溫度作為固有黏度與組成之函數 實例 莫耳％ TMCD %順式 TMCD IV (公合/克） Tg (°C) η0於 260°C 下 (泊) η〇於 275〇C 下 (泊） η〇於 290°c 下 (泊） A 20 51.4 0.72 109 11356 19503 5527 B 19.1 51.4 0.60 106 6891 3937 2051 C 19 53.2 0.64 107 8072 4745 2686 D 18.8 54.4 0.70 108 14937 8774 4610 E 17.8 52.4 0.50 103 3563 1225 883 F 17.5 51.9 0.75 107 21160 10877 5256 G 17.5 52 0.42 98 ΝΑ ΝΑ ΝΑ Η 22.8 53.5 0.69 109 ΝΑ ΝΑ ΝΑ I 22.7 52.2 0.68 108 ΝΑ ΝΑ ΝΑ J 23.4 52.4 0.73 111 ΝΑ ΝΑ ΝΑ K 23.3 52.9 0.71 111 ΝΑ ΝΑ ΝΑ L 23.3 52.4 0.74 112 ΝΑ ΝΑ ΝΑ Μ 23.2 52.5 0.74 112 ΝΑ ΝΑ ΝΑ N 23.1 52.5 0.71 111 ΝΑ ΝΑ ΝΑ 0 22.8 52.4 0.73 112 ΝΑ ΝΑ ΝΑ P 22.7 53 0.69 112 ΝΑ ΝΑ ΝΑ Q 22.7 52 0.70 111 ΝΑ ΝΑ ΝΑ N A =不可取得。 實例8 此實例係說明用於製備多種聚酯之2,2,4,4-四甲基-1，3-環丁二醇之量，對於聚酯玻璃轉移溫度之作用。在此實例 中製成之聚酯係包含大於25至低於40莫耳％之2,2,4,4-四甲 基-1，3-環丁二醇殘基。 -339 - 119732.doc 200804457 將對苯二甲酸二甲酯、丨，仁環己烷二甲醇及2,2,4,4_四曱 基-1，3-環丁二醇稱重置於5〇〇_毫升單頸圓底燒瓶中。關於 2,2,4,4-四甲基·1，3-環丁二醇起始物質之nmr分析，顯示 順/反比例為53/47。此實例之聚酯係以丨w二醇/酸比例製 成’其中整體過量係來自2,2,4,4_四甲基_1，3_環丁二醇。 添加足夠氧化二丁基錫觸媒，以獲得3〇〇 ρρηι錫在最後聚 合體中。燒瓶係在0·2 SCFC氮滌氣下，具有真空降低能 力。將燒瓶浸沒在200°C下之Belmont金屬浴中，並在反應 物已熔解後，於200 RPM下攪拌。約2.5小時後，使溫度升 高至21 0°C，並將此等條件保持另外2小時。使溫度升高至 285°C (在大約25分鐘内），並使壓力降至〇·3毫米Hg，歷經5 分鐘期間。當黏度增加時，降低擾拌，其中1 5 RPM為所 使用之最小攪拌。總聚合時間係經改變，以獲得標的固有 黏度。於聚合反應完成後，使Belmont金屬浴下降，並使 聚合體冷卻至低於其玻璃轉移溫度。約3〇分鐘後，使燒瓶 再浸沒於Belmont金屬浴中（在此30分鐘等候期間，溫度已 增加至295°C)，並將聚合體團塊加熱，直到其拉離玻璃燒 瓶為止。聚合體團塊係在燒瓶中，於中等程度下擾摔，直 到聚合體已冷卻為止。將聚合體移離燒瓶，並研磨以通過 3宅米師網。施&gt;f亍對此程序之變型，以製造下文所述之丘 聚酯，具有標的組成為20、32及45莫耳％。 固有黏度係按上文”度量方法”段落中所述度量。聚醋之 組成係如前文在度量方法段落中所解釋，藉由1H NMR測 定。玻璃轉移溫度係藉由DSC，在驟冷後，於2〇。〇/分鐘之 119732.doc -340- 200804457 速率下，使用第二次加熱測定。 下表顯示此實例聚酯之實驗數據。數據顯示增加 2,2,4,4·四甲基-1，3-環丁二醇之含量，會以幾乎線性方式 提升玻璃轉移溫度，對恒定固有黏度。圖3亦顯示Tg對於 組成與固有黏度之依存性。 表8 玻璃轉移溫度作為固有黏度與組成之函數 實例 莫耳％ TMCD %順式 TMCD IV (公合/克） Tg (°C) η0於 260°C 下 m η0於 275°C 下 m η〇於 290°c 下 (泊） A 32.2 51.9 0.71 118 29685 16074 8522 B 31.6 51.5 0.55 112 5195 2899 2088 C 31.5 50.8 0.62 112 8192 4133 2258 D 30.7 50.7 0.54 111 4345 2434 1154 E 30.3 51.2 0.61 111 7929 4383 2261 F 30.0 51.4 0.74 117 31476 17864 8630 G 29.0 51.5 0.67 112 16322 8787 4355 Η 31.1 51.4 0.35 102 ΝΑ ΝΑ ΝΑ N A =不可取得。 實例9Examples 7H to 7Q These examples were made by performing a transesterification and a polycondensation reaction in individual stages. The transesterification experiment was carried out in a continuous temperature rise (Ctr) reactor at 119732.doc - 335 - 200804457. The CTR is a 3000 ml glass reactor equipped with a single-axis impeller blade stirrer, covered with an electric heating hood, and equipped with a heat-packed reflux condenser column. Fill the reactor with 7 7 7 grams (4 moles) of dimethyl phthalate, 2 3 gram grams (5) Moer from tetramethyl-cyclobutanediol ^ (four) grams of Moule) Dimethanol and hydrazine. 12 g of ginseng-2-ethylhexanoate (so that there will be 200 ppm of tin metal in the final polymer). Set the heating cover to 厮 manually. Output. The limbs and data collection system is controlled by (5) with a program control system. Once the reactants were melted, the stirring was initiated and slowly increased to 250 rpm. The temperature of the reactor gradually increases with the operating time. The collected methanol is recorded via the balance. When the methanol evolution is stopped or at a preselected lower temperature of 26 (TC), the reaction is stopped. The oligomer is discharged as a rat scrub and cooled to room temperature. The oligomer is frozen and broken into liquid nitrogen. A small enough piece to be reset in a 5 liter round bottom flask. In a polycondensation reaction, a 500 ml round bottom flask was filled with approximately 15 gram of the oligomer prepared above. It is equipped with a stainless steel stirrer and a polymer head. The glassware is mounted on a semi-molar polymer machine and the Camile sequence is initiated. Once the oligomer is melted, the stirrer is positioned one full turn from the bottom of the flask. The temperature/pressure/stirring rate sequence controlled by Camile software for each example is reported in the following list. Example 7H and Example 71 Camile Sequence Stage Time (minutes) Temperature (°C) Vacuum (Torr) Mixing (rpm) 1 5 245 760 0 2 5 245 760 50 119732.doc •336- 200804457 3 30 265 760 50 4 3 265 90 50 5 110 290 90 50 6 5 290 6 25 7 110 290 6 25 Case 7N to Example 7Q Camile Sequence Stage Time (minutes) Temperature (°c) Vacuum (Torr) Stirring (rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 3 265 90 50 5 110 290 90 50 6 5 290 3 25 7 110 290 3 25 Example 7K and Example 7L Camile Sequence Stage Time (minutes) Temperature (° c) Vacuum (Torr) Stirring (rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 3 265 90 50 5 110 290 90 50 6 5 290 2 25 7 110 290 2 25 119732.doc -337 - 200804457 Example 7J and Example 7M Camile Sequence Stage Time (minutes) Temperature (°c) Vacuum (Torr) Mixing (rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 3 265 90 50 5 110 290 90 50 6 5 290 1 25 7 110 290 1 25 The formed polymer was recovered from the flask, cut with a hydraulic cutter, and ground to a size of 6 mm. The ground polymer samples were ground. Tested for intrinsic viscosity in 60/40 (w/w) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25. Under the armpit, the catalyst content (Sn) is measured by X-ray fluorescence, and the color (L*, a*, b*) by transmittance spectroscopy. The polymer composition was obtained by 1H NMR. The sample was subjected to thermal stability and melt viscosity test using a rheological mechanical spectrometer (RMS_8〇(1). The following table shows experimental data for this example polyester. The data shows an increase of 2,2,4,4-tetradecyl-i The content of 3-cyclobutanediol increases the glass transition temperature in a nearly linear manner for a constant intrinsic viscosity. Figure 3 also shows the dependence of Tg on composition and intrinsic viscosity. 119732.doc -338 - 200804457 Table 7 Glass Transfer Temperature as a function of intrinsic viscosity and composition. MoM % TMCD % cis TMCD IV (common / gram) Tg (°C) η0 at 260 ° C (poise) η 〇 at 275 ° C (poise) η〇 At 290 ° C (Pool) A 20 51.4 0.72 109 11356 19503 5527 B 19.1 51.4 0.60 106 6891 3937 2051 C 19 53.2 0.64 107 8072 4745 2686 D 18.8 54.4 0.70 108 14937 8774 4610 E 17.8 52.4 0.50 103 3563 1225 883 F 17.5 51.9 0.75 107 21160 10877 5256 G 17.5 52 0.42 98 ΝΑ ΝΑ ΝΑ Η 22.8 53.5 0.69 109 ΝΑ ΝΑ ΝΑ I 22.7 52.2 0.68 108 ΝΑ ΝΑ ΝΑ J 23.4 52.4 0.73 111 ΝΑ ΝΑ ΝΑ K 23.3 52.9 0.71 111 ΝΑ ΝΑ ΝΑ L 23.3 52.4 0.7 4 112 ΝΑ ΝΑ ΝΑ Μ 23.2 52.5 0.74 112 ΝΑ ΝΑ ΝΑ N 23.1 52.5 0.71 111 ΝΑ ΝΑ ΝΑ 0 22.8 52.4 0.73 112 ΝΑ ΝΑ ΝΑ P 22.7 53 0.69 112 ΝΑ ΝΑ ΝΑ Q 22.7 52 0.70 111 ΝΑ ΝΑ ΝΑ NA = Not available. EXAMPLE 8 This example illustrates the effect of the amount of 2,2,4,4-tetramethyl-1,3-cyclobutanediol used to prepare a plurality of polyesters on the transfer temperature of a polyester glass. The polyester is composed of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues of more than 25 to less than 40 mol%. -339 - 119732.doc 200804457 Dimethyl formate, hydrazine, cyclohexane dimethanol and 2,2,4,4-tetradecyl-1,3-cyclobutanediol were reconstituted in a 5 〇〇-ml single-necked round bottom flask. The nmr analysis of the starting material of 2,2,4,4-tetramethyl·1,3-cyclobutanediol showed a cis/inverse ratio of 53/47. The polyester of this example was prepared in a 丨w diol/acid ratio. The overall excess was derived from 2,2,4,4-tetramethyl-1,3-cyclobutanediol. Add enough dibutyltin oxide catalyst to obtain 3〇〇 ρρηι tin in the final polymer. The flask was vacuum-reduced under 0·2 SCFC nitrogen scrubbing. The flask was immersed in a Belmont metal bath at 200 ° C and stirred at 200 RPM after the reaction had melted. After about 2.5 hours, the temperature was raised to 210 ° C and these conditions were maintained for an additional 2 hours. The temperature was raised to 285 ° C (within about 25 minutes) and the pressure was lowered to 〇 3 mm Hg over a period of 5 minutes. When the viscosity increases, the scrambling is reduced, with 15 RPM being the minimum agitation used. The total polymerization time is varied to obtain the intrinsic viscosity of the target. After completion of the polymerization, the Belmont metal bath was lowered and the polymer was allowed to cool below its glass transition temperature. After about 3 minutes, the flask was again submerged in a Belmont metal bath (the temperature had increased to 295 °C during this 30 minute wait) and the polymer mass was heated until it was pulled away from the glass vial. The polymer mass was tied to the flask and was moderately disturbed until the polymer had cooled. The polymer was removed from the flask and ground to pass through the 3 house net. A modification of this procedure was carried out to produce a mound polyester as described below having a composition of 20, 32 and 45 mol%. The intrinsic viscosity is measured as described in the "Measuring Methods" section above. The composition of the vinegar was determined by 1H NMR as explained above in the section on measurement methods. The glass transition temperature is by DSC, after quenching, at 2 Torr. 〇/min 119732.doc -340- 200804457 At the rate, use the second heating test. The table below shows experimental data for this example polyester. The data show that increasing the 2,2,4,4·tetramethyl-1,3-cyclobutanediol content will increase the glass transition temperature in a nearly linear manner for a constant intrinsic viscosity. Figure 3 also shows the dependence of Tg on the composition and intrinsic viscosity. Table 8 Glass transition temperature as a function of intrinsic viscosity and composition. Mohr % TMCD % cis TMCD IV (common / gram) Tg (°C) η0 at 260 ° C m η0 at 275 ° C m η 〇 290°c (parking) A 32.2 51.9 0.71 118 29685 16074 8522 B 31.6 51.5 0.55 112 5195 2899 2088 C 31.5 50.8 0.62 112 8192 4133 2258 D 30.7 50.7 0.54 111 4345 2434 1154 E 30.3 51.2 0.61 111 7929 4383 2261 F 30.0 51.4 0.74 117 31476 17864 8630 G 29.0 51.5 0.67 112 16322 8787 4355 Η 31.1 51.4 0.35 102 ΝΑ ΝΑ ΝΑ NA = Not available. Example 9

此實例係說明用於製備多種聚酯之2,2,4,4-四甲基·1，3-環丁二醇之量，對於聚酯玻璃轉移溫度之作用。在此實例 中製成之聚酯，係包含2,2,4,4-四甲基-1,3-環丁二醇殘 基，其量為40莫耳％或較大 實例9Α至9AC 此等實例係藉由在個別階段中進行酯交換與聚縮合反應 •341 - 119732.doc 200804457 而製成。酯交換實驗係在連續溫度上升（CTR)反應器中進 行。CTR為3 000毫升玻璃反應器，裝有單軸葉輪片攪拌 器’以電熱罩覆蓋，及裝有經加熱包裝回流冷凝管柱。於 反應器中裝填777克對苯二曱酸二甲酯、375克2,2,4,4-四 曱基-1，3-環丁二醇、317克環己烷二甲醇及112克參乙 基己酸丁基錫（以致將有2〇〇 ppm錫金屬在最後聚合體 中）。將加熱罩以手動方式設定至1〇〇%輸出。設定點與數 據收集係藉助於Camile程序控制系統。一旦反應物被熔 解，即起始攪拌，且慢慢地增加至25〇 rpm。反應器之溫 度係隨著操作時間逐漸增加。所收集之甲醇重量係經由天 平記錄。當停止甲醇釋出或在預先選擇之較低溫度26〇。〇 下時，使反應停止。將寡聚物以氮滌氣排放，並冷卻至室 溫。以液態氮使寡聚物冷;東並破碎成足夠小之片塊，以被 稱重置於500毫升圓底燒瓶中。 在聚縮合反應中，係於500毫升圓底燒瓶中裝填15〇克上 文製成之寡聚物。燒瓶係裝有不銹鋼攪拌器與聚合體頭 部。將玻璃器具安裝在半莫耳聚合體機床上，並起始 CamUe順序。一旦寡聚物熔解，即將攪拌器定位，自燒瓶 底部一整圈。對此等實例藉由Camile軟體控制之溫度/塵力 /攪拌速率順序，係報告於下表中，除非下文另有指明。 聚縮合反應之Camile順序 119732.doc -342- 200804457 階段 時間(分鐘） 溫度(°c) 真空(托） 攪拌(rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 3 265 90 50 5 110 290 90 50 6 5 290 6 25 7 110 290 6 25 實例A、C、R、Υ、AB及AC之Camile順序 階段 時間(分鐘） 溫度(°c) 真空(托） 攪拌(rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 3 265 90 50 5 110 290 90 50 6 5 290 6 25 7 110 290 6 25 對實例B、D及F，係使用前述表中之相同順序，惟在階 段7中時間為80分鐘。對實例G及J，係使用前述表中之相 同順序，惟在階段7中時間為50分鐘。對實例L，係使用前 述表中之相同順序，惟在階段7中時間為140分鐘。 實例E之Camile順序 119732.doc -343 - 200804457 階段 時間(分鐘） 溫度(°c) 真空(托） 攪拌(rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 3 265 90 50 5 110 300 90 50 6 5 300 7 25 7 110 300 7 25 對實例I，係使用前述表中之相同順序，惟在階段6及7 中真空為8托。對實例Ο，係使用前述表中之相同順序，惟 在階段6及7中真空為6托。對實例P，係使用前述表中之相 同順序，惟在階段6及7中真空為4托。對實例Q，係使用前 述表中之相同順序，惟在階段6及7中真空為5托。 實例Η之Camile順序 階段 時間(分鐘） 溫度(°c) 真空(托） 攪拌(rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 3 265 90 50 5 110 280 90 50 6 5 280 5 25 7 110 280 5 25 對實例U及AA，係使用前述表中之相同順序，惟在階段 6及7中真空為6托。對實例V及X，係使用前述表中之相同 119732.doc -344- 200804457 順序，惟在階段6及7中真空為6托且攪拌速率為1 5 rpm。 對實例Z，係使用前述表中之相同順序，惟在階段6及7中 攪拌速率為15 rpm。 實例K之Camile順序 階段 時間(分鐘） 溫度(°c) 真空(托） 攪拌(rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 3 265 90 50 5 110 300 90 50 6 5 300 6 15 7 110 300 6 15 對實例Μ，係使用前述表中之相同順序，惟在階段6及7 中真空為8托。對實例Ν，係使用前述表中之相同順序，惟 在階段6及7中真空為7托。 實例S及Τ之Camile順序 階段 時間(分鐘） 溫度(°c) 真空(托） 攪拌(rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 5 290 6 25 5 110 290 6 25 將所形成之聚合體自燒瓶回收，使用液壓切斷器切斷， 119732.doc -345 - 200804457 並研磨至6毫米筛網大小。使各經研磨之聚合體試樣接受 測試，關於固有黏度係在60/40 (重量/重量）酚/四氯乙烷 中，於0.5克/100毫升之濃度下，在25°C下，觸媒含量（Sn) 藉由X-射線螢光，及顏色（L*，a*，b*)藉由透光率光譜學。 聚合體組成係藉由1H NMR獲得。使試樣接受熱安定性與 熔融黏度測試，使用流變學機械光譜儀（RMS-800)。 實例9AD至實例9ΑΚ及實例9ΑΤ 此等實例之聚酯係按上文關於實例Α至AC所述製成，惟 對實例AD至AK及AT，在最後聚合體中之標的錫量為150 ppm。下列表係描述對此等實例藉由Camile軟體控制之溫 度/壓力/攪拌速率順序。 實例AD、AF及AH之Camile順序 階段 時間(分鐘） 溫度(°c) 真空(托） 攪拌(rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 3 265 400 50 5 110 290 400 50 6 5 290 8 50 7 110 295 8 50 對實例AD，係使攪拌器轉變成25 rpm，其中在階段7留 置95分鐘。 實例AE之Camile順序 119732.doc •346- 200804457 階段 時間(分鐘） 溫度(°C) 真空(托） 攪拌(rpm) 1 10 245 760 0 2 5 245 760 50 3 30 283 760 50 4 3 283 175 50 5 5 283 5 50 6 5 283 1.2 50 7 71 285 1.2 50 對實例ΑΚ，係使用前述表中之相同順序，惟在階段7中 時間為75分鐘。 實例AG之Camile順序 階段 時間(分鐘） 溫度(°C) 真空(托） 攪拌(rpm) 1 10 245 760 0 2 5 245 760 50 3 30 285 760 50 4 3 285 175 50 5 5 285 5 50 6 5 285 4 50 7 220 290 4 50 實例AI之Camile順序 階段 時間(分鐘） 溫度(°C) 真空(托） 攪拌(rpm) 1 5 245 760 0 2 5 245 760 50 119732.doc - 347- 200804457 3 30 265 760 50 4 3 265 90 50 5 110 285 90 50 6 5 285 6 50 7 70 290 6 50 實例AJ之Camile順序 階段 時間(分鐘） 溫度(°c) 真空(托） 攪拌(rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 3 265 90 50 5 110 290 90 50 6 5 290 6 25 7 110 295 6 25This example illustrates the effect of the amount of 2,2,4,4-tetramethyl-1,3-cyclobutanediol used to prepare a plurality of polyesters on the transfer temperature of the polyester glass. The polyester produced in this example contains 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues in an amount of 40 mol% or larger examples 9Α to 9AC. Examples are made by transesterification and polycondensation reactions in the individual stages. 341 - 119732.doc 200804457. The transesterification experiment was carried out in a continuous temperature rise (CTR) reactor. The CTR is a 3 000 ml glass reactor equipped with a single-shaft impeller stirrer' covered with an electric heating hood and equipped with a heated packaging reflux condenser column. The reactor was charged with 777 g of dimethyl terephthalate, 375 g of 2,2,4,4-tetradecyl-1,3-cyclobutanediol, 317 g of cyclohexanedimethanol and 112 g of ginseng. Butyl tin ethyl hexanoate (so that 2 〇〇ppm tin metal will be in the final polymer). The heating mantle is manually set to 1% output. The setpoint and data collection system is controlled by the Camile program. Once the reactants were melted, the agitation was initiated and slowly increased to 25 rpm. The temperature of the reactor gradually increases with the operating time. The weight of methanol collected was recorded via the balance. When the methanol is stopped or at a pre-selected lower temperature of 26 〇. When 〇, the reaction is stopped. The oligomer was purged with nitrogen and cooled to room temperature. The oligomer was cooled with liquid nitrogen; it was broken up into small enough pieces to be reset in a 500 ml round bottom flask. In the polycondensation reaction, a 500 ml round bottom flask was charged with 15 g of the oligomer prepared above. The flask was fitted with a stainless steel stirrer and a polymer head. Install the glassware on the semi-molar machine and start the CamUe sequence. Once the oligomer has melted, the stirrer is positioned one full turn from the bottom of the flask. The temperature/dust/stirring rate sequences controlled by Camile software for these examples are reported in the table below unless otherwise indicated below. Camile sequence for polycondensation reactions 119732.doc -342- 200804457 Stage time (minutes) Temperature (°c) Vacuum (Torr) Stirring (rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 3 265 90 50 5 110 290 90 50 6 5 290 6 25 7 110 290 6 25 Examples of A, C, R, Υ, AB and AC Camile sequence phase time (minutes) Temperature (°c) Vacuum (Torr) Stirring (rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 3 265 90 50 5 110 290 90 50 6 5 290 6 25 7 110 290 6 25 For examples B, D and F, use the same order as in the previous table However, the time in phase 7 is 80 minutes. For Examples G and J, the same order as in the previous table was used, except that the time in Phase 7 was 50 minutes. For instance L, the same order as in the previous table is used, except that the time in phase 7 is 140 minutes. Camile sequence for Example E 119732.doc -343 - 200804457 Stage time (minutes) Temperature (°c) Vacuum (Torr) Stirring (rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 3 265 90 50 5 110 300 90 50 6 5 300 7 25 7 110 300 7 25 For Example I, the same order as in the previous table was used, except that the vacuum was 8 Torr in stages 6 and 7. For the examples, the same order as in the previous table was used, except that the vacuum was 6 Torr in stages 6 and 7. For Example P, the same order as in the previous table was used, except that in Stages 6 and 7, the vacuum was 4 Torr. For example Q, the same order as in the previous table is used, except that the vacuum is 5 Torr in stages 6 and 7. Example CamCamile Sequence Stage Time (minutes) Temperature (°c) Vacuum (Torr) Stirring (rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 3 265 90 50 5 110 280 90 50 6 5 280 5 25 7 110 280 5 25 For the examples U and AA, the same order as in the previous table is used, except that the vacuum is 6 Torr in stages 6 and 7. For Examples V and X, the same order of 119732.doc -344-200804457 was used in the previous table except that the vacuum was 6 Torr in stages 6 and 7 and the agitation rate was 15 rpm. For Example Z, the same order as in the previous table was used, except that the agitation rate was 15 rpm in Stages 6 and 7. Example K Camile Sequence Stage Time (minutes) Temperature (°c) Vacuum (Torr) Stirring (rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 3 265 90 50 5 110 300 90 50 6 5 300 6 15 7 110 300 6 15 For the examples, the same order as in the previous table is used, except that the vacuum is 8 Torr in stages 6 and 7. For the examples, the same order as in the previous table was used, except that the vacuum was 7 Torr in stages 6 and 7. Example S and CamCamile sequence stage time (minutes) Temperature (°c) Vacuum (Torr) Stirring (rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 5 290 6 25 5 110 290 6 25 The formed polymer was recovered from the flask, cut off using a hydraulic cutter, 119732.doc -345 - 200804457 and ground to a 6 mm screen size. Each of the ground polymer samples was tested for intrinsic viscosity in 60/40 (w/w) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25 ° C. The media content (Sn) is obtained by X-ray fluorescence, and color (L*, a*, b*) by transmittance spectroscopy. The polymer composition was obtained by 1H NMR. The samples were subjected to thermal stability and melt viscosity tests using a rheological mechanical spectrometer (RMS-800). Examples 9AD to 9 and Examples 9 The polyesters of these examples were prepared as described above for the examples Α to AC, except for the examples AD to AK and AT, the amount of tin in the final polymer was 150 ppm. The following table describes the temperature/pressure/stirring rate sequence for these examples controlled by Camile software. Examples of AD, AF and AH Camile sequence phase time (minutes) Temperature (°c) Vacuum (Torr) Stirring (rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 3 265 400 50 5 110 290 400 50 6 5 290 8 50 7 110 295 8 50 For the example AD, the stirrer was converted to 25 rpm with a 95 minute hold in stage 7. Example AE Camile Sequence 119732.doc •346- 200804457 Stage Time (minutes) Temperature (°C) Vacuum (Torr) Stirring (rpm) 1 10 245 760 0 2 5 245 760 50 3 30 283 760 50 4 3 283 175 50 5 5 283 5 50 6 5 283 1.2 50 7 71 285 1.2 50 For the example, the same order as in the previous table is used, except that the time in phase 7 is 75 minutes. Example AG Camile Sequence Stage Time (minutes) Temperature (°C) Vacuum (Torr) Stirring (rpm) 1 10 245 760 0 2 5 245 760 50 3 30 285 760 50 4 3 285 175 50 5 5 285 5 50 6 5 285 4 50 7 220 290 4 50 Example AI Camile sequence phase time (minutes) Temperature (°C) Vacuum (Torr) Stirring (rpm) 1 5 245 760 0 2 5 245 760 50 119732.doc - 347- 200804457 3 30 265 760 50 4 3 265 90 50 5 110 285 90 50 6 5 285 6 50 7 70 290 6 50 Example AJ Camile Sequence Stage Time (minutes) Temperature (°c) Vacuum (Torr) Stirring (rpm) 1 5 245 760 0 2 5 245 760 50 3 30 265 760 50 4 3 265 90 50 5 110 290 90 50 6 5 290 6 25 7 110 295 6 25

實例9AL至實例9AS 將對苯二甲酸二甲酯、1，4-環己烷二甲醇及2,2,4,4-四曱 基-1，3-環丁二醇稱重置於500-毫升單頸圓底燒瓶中。此實 例之聚酯係以1.2/1二醇/酸比例製成，其中整體過量係來 自2,2,4,4-四甲基-1，3-環丁二醇。添加足夠氧化二丁基錫 觸媒，以獲得300 ppm錫在最後聚合體中。燒瓶係在0.2 SCFC氮滌氣下，具有真空降低能力。將燒瓶浸沒在200°C 下之Belmont金屬浴中，並在反應物已熔解後，於200 RPM 下攪拌。約2.5小時後，使溫度升高至210°C，並將此等條 件保持另外2小時。使溫度升高至285 °C (在大約25分鐘 119732.doc -348 - 200804457 内），並使壓力降至0.3毫米Hg，歷經5分鐘期間。當黏度 增加時，降低攪拌，其中15 RPM為所使用之最小攪拌。 總聚合時間係經改變，以獲得標的固有黏度。於聚合反應 完成後’使Belmont金屬浴下降，並使聚合體冷卻至低於 其玻璃轉移溫度。約30分鐘後，將燒瓶再浸沒於Belm〇nt 金屬浴中（在此30分鐘等候期間，溫度已增加至295r)，並 將聚合體團塊加熱，直到其拉離玻璃燒瓶為止。聚合體團 塊係在燒觀中，於中等程度下攪拌，直到聚合體已冷卻為 止。將聚合體移離燒瓶，並研磨以通過3毫米筛網。施行 對此程序之變型，以製造下文所述之共聚酯，具有標的組 成為20、32及45莫耳％。 固有黏度係按上文”度量方法”段落中所述度量。聚醋之 組成係如前文在度量方法段落中所解釋，藉由1h 1^熥尺測 定。玻璃轉移溫度係藉由DSC，在驟冷後，於2(rc/分鐘之 速率下’使用第二次加熱測定。 下表顯示此實例聚酯之實驗數據。數據顯示增加 2,2,4,4-四甲基環丁二醇之含量，會以幾乎線性方式 提升玻璃轉移溫度，對恒定固有黏度。圖3亦顯示Tg對於 組成與固有黏度之依存性。 119732.doc -349- 200804457 表9 玻璃轉移溫度作為固有黏度與組成之函數 實例 莫耳％ TMCD %順式 TMCD IV (公合/克） (¾ 於 26〇Υ 下 (泊） 恥於 275 C 下 (泊） TIq於 29〇\:下 (泊） A 43.9 72.1 0.46 131 ΝΑ ΝΑ ΝΑ B 44.2 36.4 0.49 118 ΝΑ ΝΑ ΝΑ C 44 71.7 0.49 128 ΝΑ ΝΑ ΝΑ D 44.3 36.3 0.51 119 ΝΑ ΝΑ ΝΑ E 46.1 46.8 0.51 125 ΝΑ ΝΑ ΝΑ F 43.6 72.1 0.52 128 ΝΑ ΝΑ ΝΑ G 43.6 72.3 0.54 127 ΝΑ ΝΑ ΝΑ Η 46.4 46.4 0.54 127 ΝΑ ΝΑ ΝΑ I 45.7 47.1 0.55 125 ΝΑ ΝΑ ΝΑ J 44.4 35.6 0.55 118 ΝΑ ΝΑ ΝΑ K 45.2 46.8 0.56 124 ΝΑ ΝΑ ΝΑ L 43.8 72.2 0.56 129 ΝΑ ΝΑ ΝΑ Μ 45.8 46.4 0.56 124 ΝΑ ΝΑ ΝΑ N 45.1 47.0 0.57 125 ΝΑ ΝΑ ΝΑ 0 45.2 46.8 0.57 124 ΝΑ ΝΑ ΝΑ P 45 46.7 0.57 125 ΝΑ ΝΑ ΝΑ Q 45.1 47.1 0.58 127 ΝΑ ΝΑ ΝΑ R 44.7 35.4 0.59 123 ΝΑ ΝΑ ΝΑ S 46.1 46.4 0.60 127 ΝΑ ΝΑ ΝΑ T 45.7 46.8 0.60 129 ΝΑ ΝΑ ΝΑ U 46 46.3 0.62 128 ΝΑ ΝΑ ΝΑ V 45.9 46.3 0.62 128 ΝΑ ΝΑ ΝΑ X 45.8 46.1 0.63 128 ΝΑ ΝΑ ΝΑ Y 45.6 50.7 0.63 128 ΝΑ ΝΑ ΝΑ z 46.2 46.8 0.65 129 ΝΑ ΝΑ ΝΑ AA 45.9 46.2 0.66 128 ΝΑ ΝΑ ΝΑ AB 45.2 46.4 0.66 128 ΝΑ ΝΑ ΝΑ AC 45.1 46.5 0.68 129 ΝΑ ΝΑ ΝΑ AD 46.3 52.4 0.52 ΝΑ ΝΑ ΝΑ ΝΑ AE 45.7 50.9 0.54 ΝΑ ΝΑ ΝΑ ΝΑ AF 46.3 52.6 0.56 ΝΑ ΝΑ ΝΑ ΝΑ AG 46 50.6 0.56 ΝΑ ΝΑ ΝΑ ΝΑ AH 46.5 51.8 0.57 ΝΑ ΝΑ ΝΑ ΝΑ AI 45.6 51.2 0.58 ΝΑ ΝΑ ΝΑ ΝΑ AJ 46 51.9 0.58 ΝΑ ΝΑ ΝΑ ΝΑ AK 45.5 51.2 0.59 ΝΑ ΝΑ ΝΑ ΝΑ AL 45.8 50.1 0.624 125 ΝΑ ΝΑ 7696 AM 45.7 49.4 0.619 128 ΝΑ ΝΑ 7209 AN 46.2 49.3 0.548 124 ΝΑ ΝΑ 2348 AP 45.9 49.5 0.72 128 76600 40260 19110 AQ 46.0 50 0.71 131 68310 32480 17817 AR 46.1 49.6 0.383 117 ΝΑ ΝΑ 387 AS 45.6 50.5 0.325 108 ΝΑ ΝΑ ΝΑ AT 47.2 NA 0.48 ΝΑ ΝΑ ΝΑ ΝΑ NA =不可取得。 -350- 119732.doc 200804457 實例1 ο 此實例係說明優勢類型之2,2,4,4_四甲基^义環丁二醇 /、構物（順式或反式）對於聚酯玻璃轉移溫度之作用。 字對苯—甲酸二甲酯、丨，^環己烷二甲醇及2,2,4,仁四曱 土 1’3%丁二醇稱重置於500_毫升單頸圓底燒瓶中。此實 例之聚酯係以12/1二醇/酸比例製成，其中整體過量係來 ，’4四甲基·1，3-環丁二醇。添加足夠氧化二丁基錫 觸媒，以獲得300 ppm錫在最後聚合體中。燒瓶係在〇.2 CFC氮滌氣下，具有真空降低能力。將燒瓶浸沒在2⑽π 下之Belmont金屬浴中，並在反應物已溶解後，於2〇〇RpM 下攪拌。約2.5小時後，使溫度升高至：⑺艺，並將此等條 件保持另外2小時。使溫度升高至285 °C(在大約25分鐘 内），並使壓力降至〇·3毫米Hg，歷經5分鐘期間。當黏度 增加時，降低攪拌，其中15 RPM為所使用之最小攪拌。 總聚合時間係經改變，以獲得標的固有黏度。於聚合反應 完成後，使Belmont金屬浴下降，並使聚合體冷卻至低於 其玻璃轉移溫度。約30分鐘後，將燒瓶再浸沒於Belm〇nt 金屬浴中（在此30分鐘等候期間，溫度已增加至295〇c )，並 將聚合體團塊加熱，直到其拉離玻璃燒瓶為止。聚合體團 塊係在燒瓶中，於中等程度下攪拌，直到聚合體已冷卻為 止。將聚合體移離燒瓶，並研磨以通過3毫米篩網。施行 對此程序之變型，以製造下文所述之共聚酯，具有標的組 成為20、32及45莫耳〇/0。 固有黏度係按上文”度量方法”段落中所述度量。聚酯之 119732.doc -351 · 200804457 組成係如前文在度量方法段落中所解释，藉由1H NMR測 疋。玻璃轉移溫度係藉由DSC，在驟冷後，於2〇。〇 /分鐘之 速率下，使用第二次加熱測定。 下表顯示此實例聚酯之實驗數據。數據顯示，對恒定固 有黏度，順式2,2,4,4-四甲基環丁二醇係為反式 2,2,4,4-四甲基-1，3·環丁二醇之大約兩倍有效增加玻璃轉 移溫度。 表10 2,2,4,4-四甲基-l，3-環丁二醇順/反組合物對於Tg之作用 實例 莫耳％ TMCD IV (公合/克） (¾ η〇於 260°C 下 (泊） η〇於 275°C 下 (泊） Μ於 290 C 下 (泊） %順式 TMCD A 45.8 0.71 119 N.A. N.A. Ν.Α. 4.1 B 43.2 0.72 122 N.A. N.A. Ν.Α. 22.0 C 46.8 0.57 119 26306 16941 6601 22.8 D 43.0 0.67 125 55060 36747 14410 _23.8 E 43.8 0.72 127 101000 62750 25330 24.5 F 45.9 0.533 119 11474 6864 2806 _26.4 G 45.0 0.35 107 N.A. N.A. Ν.Α.— _27.2 Η 41.2 0.38 106 1214 757 Ν.Α. 29.0 I 44.7 0.59 123 N.A. N.A. Ν.Α. 35.4 J 44.4 0.55 118 N.A. · N.A. Ν.Α. __35.6 K 44.3 0.51 119 N.A. N.A. Ν.Α. __36.3 L 44.0 0.49 128 N.A. N.A. Ν.Α. 71.7 Μ 43.6 0.52 128 N.A. N.A. Ν.Α. 72.1 N 43.6 0.54 127 N.A. N.A. Ν.Α. 72.3 0 41.5 0.58 133 15419 10253 4252 88.7 P 43.8 0.57 135 16219 10226 4235 __89.6 Q 41.0 0.33 120 521 351 2261 90.4 R 43.0 0.56 134 N.A. N.A. Ν.Α. ___90.6 S 43.0 0.49 132 7055 4620 2120 90.6 T 43.1 0.55 134 12970 8443 3531 91.2 U 45.9 0.52 137 N.A. N.A. Ν.Α. 98.1 NA=不可取得。 -352- 119732.doc 200804457 實例11 此實例係說明製備含有100莫耳％對苯二甲酸二甲酯殘 基、55莫耳％1，4_環己烷二甲醇殘基及45莫耳％2,2,4,4_四 甲基-1，3-環丁二醇之共聚酯。 將97·10克（0·5莫耳）對苯二甲酸二甲酯、52 46克（〇36莫 耳）Μ-%己烷二甲醇、34 〇7克（〇 24莫耳）2,2,4,4_四甲 基_1，3_環丁二醇及〇·〇863克（3〇〇 ppm)氧化二丁基錫之混合 物置於裝有氮入口管、金屬攪拌器及短蒸餾管柱之500-毫 升込瓶中。將此燒瓶置於已被加熱至2〇〇它之伍德氏金屬 浴中。將燒瓶之内容物在200。(：下加熱丨小時，然後使溫度 逐漸增加至21(TC。將反應混合物在：…工下保持2小時， 然後在30分鐘内加熱至29〇°C。在290°C，在下一個3至5分 鐘期間，逐漸施加0.01 psig之真空。維持完全真空（〇 〇1 Psig)歷時總時間約45分鐘，以移除過量未反應之二醇類。 獲得高熔融黏度、視覺上透明及無色聚合體，具有玻璃轉 移溫度為125°C，且固有黏度為〇·64公合/克。 實例12-比較實例 此實例係說明以100% 2,2,4,4_四甲基_ΐ53·環丁二醇為基 料之聚酯具有緩慢結晶化作用半衰期。 僅僅以對苯二曱酸與2,2,4，心四曱基4,3-環丁二醇為基 料之聚酯，以類似實例11中所述之方法製成，具有表 所示之性質。此聚酿係以300 ppm氧化二丁基錫製成。 2,2,4,4-四曱基-1，3-環丁二醇之反式/順式比例為65/35。 薄膜係自經研磨之聚合體於320。(3下壓製。自炼融體之 119732.doc -353 - 200804457 、=化仙半衰期度量係在，至25代之溫度下，於抓 、:：下轭仃’且報告於表11中。試樣之最快速結晶化作用 半衰』係被h取為結晶化作用半衰期作為溫度函數之最低 值。此聚酯之最快速結晶化作用半衰期為約1300分鐘。此 數值係與以下事實成對比，僅僅以對苯：甲酸與1,4-環己 燒一甲醇（無共單體改質）為基料之聚酯（PCT)具有極端地短 之結晶化作用半衰期（&lt;1分鐘），如圖1中所示。 表11 結晶化作用半衰期（分鐘） 共單體 (莫耳％) IV (公合/克） Tg (°C) Tmax (°C) 於 220°C 下 (分鐘） 於 230°C 下 (分鐘） 於 240°C 下 (分鐘） 於250°C下 (分鐘） 100莫耳％ F 0.63 170.0 330 3291 3066 1303 1888 其中· F為2,2,4,4-四甲基_1，3-環丁二醇（65/35反式/順式） 實例13 包含聚酯之薄片係使用3.5英吋單螺桿壓出機製成，該 聚酯已被製成具有標的組成為1〇〇莫耳％對苯二甲酸殘 基、80莫耳。/〇 1，4-環己烷二甲醇殘基及2〇莫耳％ 2,2,4,4_四 甲基-1，3-環丁二醇殘基。薄片係連續地被壓出，經計量至 厚度為177密爾’然後將各種缚片剪切至適當大小。固有 黏度與玻璃轉移溫度係在一個薄片上度量。薄片固有黏度 係經度量為0.69公合/克。薄片之玻璃轉移溫度係經度量為 106 C。然後，將薄片在50%相對濕度與60°c下調理2週。 接著，使薄片於陰模中熱成形，具有拉伸比為2.5 : 1，使 用Brown熱成形機。熱成形烘箱加熱器係設定至7〇/6〇/6〇0/〇 119732.doc •354· 200804457 輸出，僅使用頂部加熱。將薄片留在烘箱中，歷經不同量 之時間，以測定薄片溫度對於零件品質之作用，如下表中 所示。零件品質係藉由度量熱成形零件之體積，計算拉 伸，及目視檢查熱成形零件而測得。拉伸係以零件體積除 以在此實驗（實例G)設定中所達成之最高零件體積計算= 得。熱成形零件係以目視檢查任何氣泡，及被分級為無 (N)、低（L)或咼（H)之形成氣泡程度。下文結果證實，此等 具有玻璃轉移溫度為1〇6它之熱塑性薄片可在下文所示之 條件下熱成形，如藉由此等具有至少95%拉伸且未形成氣 泡之薄片u者’而無需在熱成形之前使薄片預乾燥。Example 9AL to Example 9AS Resetting dimethyl terephthalate, 1,4-cyclohexanedimethanol, and 2,2,4,4-tetradecyl-1,3-cyclobutanediol to 500- ML in a single neck round bottom flask. The polyester of this example was prepared at a ratio of 1.2/1 diol/acid in which the overall excess was derived from 2,2,4,4-tetramethyl-1,3-cyclobutanediol. Add enough dibutyltin oxide catalyst to obtain 300 ppm tin in the final polymer. The flask was vacuum-reduced under 0.2 SCFC nitrogen scrubbing. The flask was immersed in a Belmont metal bath at 200 ° C and stirred at 200 RPM after the reactants had melted. After about 2.5 hours, the temperature was raised to 210 ° C and these conditions were maintained for an additional 2 hours. The temperature was raised to 285 ° C (in about 25 minutes 119732.doc -348 - 200804457) and the pressure was reduced to 0.3 mm Hg over a period of 5 minutes. When the viscosity increases, the agitation is reduced, with 15 RPM being the minimum agitation used. The total polymerization time is varied to obtain the intrinsic viscosity of the target. After the completion of the polymerization, the Belmont metal bath was lowered and the polymer was cooled to below its glass transition temperature. After about 30 minutes, the flask was re-immersed in a Belm〇nt metal bath (the temperature had increased to 295 r during this 30 minute wait) and the polymer mass was heated until it was pulled away from the glass flask. The polymer mass is in the burnt zone and is stirred at moderate levels until the polymer has cooled. The polymer was removed from the flask and ground to pass through a 3 mm screen. A variation of this procedure was carried out to produce the copolyesters described below, with the target group being 20, 32 and 45 mole %. The intrinsic viscosity is measured as described in the "Measuring Methods" section above. The composition of the vinegar is as explained in the section on measurement methods, as measured by 1h 1^熥. The glass transition temperature was determined by DSC using a second heating at 2 (rc/min rate) after quenching. The following table shows experimental data for this example polyester. The data shows an increase of 2, 2, 4, The content of 4-tetramethylcyclobutanediol increases the glass transition temperature in a nearly linear manner for a constant intrinsic viscosity. Figure 3 also shows the dependence of Tg on the composition and intrinsic viscosity. 119732.doc -349- 200804457 Table 9 Glass transition temperature as a function of intrinsic viscosity and composition Mox % TMCD % cis TMCD IV (common / gram) (3⁄4 at 26 〇Υ under (poor) shame at 275 C (poor) TIq at 29〇\: Lower (Poise) A 43.9 72.1 0.46 131 ΝΑ ΝΑ ΝΑ B 44.2 36.4 0.49 118 ΝΑ ΝΑ ΝΑ C 44 71.7 0.49 128 ΝΑ ΝΑ ΝΑ D 44.3 36.3 0.51 119 ΝΑ ΝΑ ΝΑ E 46.1 46.8 0.51 125 ΝΑ ΝΑ ΝΑ F 43.6 72.1 0.52 128 ΝΑ ΝΑ ΝΑ G 43.6 72.3 0.54 127 ΝΑ ΝΑ ΝΑ Η 46.4 46.4 0.54 127 ΝΑ ΝΑ ΝΑ I 45.7 47.1 0.55 125 ΝΑ ΝΑ ΝΑ J 44.4 35.6 0.55 118 ΝΑ ΝΑ ΝΑ K 45.2 46.8 0.56 124 ΝΑ ΝΑ ΝΑ L 43.8 72.2 0.56 129 ΝΑ ΝΑ ΝΑ Μ 45.8 46.4 0.56 124 ΝΑ ΝΑ ΝΑ N 45.1 47.0 0.57 125 ΝΑ ΝΑ ΝΑ 0 45.2 46.8 0.57 124 ΝΑ ΝΑ ΝΑ P 45 46.7 0.57 125 ΝΑ ΝΑ ΝΑ Q 45.1 47.1 0.58 127 ΝΑ ΝΑ ΝΑ R 44.7 35.4 0.59 123 ΝΑ ΝΑ ΝΑ S 46.1 46.4 0.60 127 ΝΑ ΝΑ ΝΑ T 45.7 46.8 0.60 129 ΝΑ ΝΑ ΝΑ U 46 46.3 0.62 128 ΝΑ ΝΑ 4 V 45.9 46.3 0.62 128 ΝΑ ΝΑ ΝΑ X 45.8 46.1 0.63 128 ΝΑ ΝΑ ΝΑ Y 45.6 50.7 0.63 128 ΝΑ ΝΑ ΝΑ z 46.2 46.8 0.65 129 ΝΑ ΝΑ ΝΑ AA 45.9 46.2 0.66 128 ΝΑ ΝΑ ΝΑ AB 45.2 46.4 0.66 128 ΝΑ ΝΑ ΝΑ AC 45.1 46.5 0.68 129 ΝΑ ΝΑ ΝΑ AD 46.3 52.4 0.52 ΝΑ ΝΑ ΝΑ AE AE 45.7 50.9 0.54 ΝΑ ΝΑ ΝΑ ΝΑ AF 46.3 52.6 0.56 46 ΝΑ ΝΑ ΝΑ AG 46 50.6 0.56 ΝΑ ΝΑ ΝΑ AH AH 46.5 51.8 0.57 ΝΑ ΝΑ ΝΑ AI AI 45.6 51.2 0.58 ΝΑ ΝΑ ΝΑ ΝΑ AJ 46 51.9 0.58 ΝΑ ΝΑ ΝΑ AK AK 45.5 51.2 0.59 ΝΑ ΝΑ ΝΑ ΝΑ AL 45.8 50.1 0.624 125 ΝΑ ΝΑ 7696 AM 45.7 49.4 0.619 128 ΝΑ ΝΑ 7209 AN 46.2 49 .3 0.548 124 ΝΑ ΝΑ 2348 AP 45.9 49.5 0.72 128 76600 40260 19110 AQ 46.0 50 0.71 131 68310 32480 17817 AR 46.1 49.6 0.383 117 ΝΑ 387 387 AS 45.6 50.5 0.325 108 ΝΑ ΝΑ ΝΑ AT 47.2 NA 0.48 ΝΑ ΝΑ ΝΑ ΝΑ NA = No Acquired. -350- 119732.doc 200804457 Example 1 ο This example illustrates the advantageous type of 2,2,4,4_tetramethyl-cyclobutanediol/, structure (cis or trans) for polyester glass transfer The role of temperature. The words p-benzoic acid dimethyl ester, hydrazine, cyclohexane dimethanol and 2,2,4, lenazolium 1'3% butanediol were reset in a 500-ml single-necked round bottom flask. The polyester of this example was prepared in a 12/1 diol/acid ratio in which the overall excess was &4 tetramethyl 1,3-cyclobutanediol. Add enough dibutyltin oxide catalyst to obtain 300 ppm tin in the final polymer. The flask was vacuum-reduced under 〇.2 CFC nitrogen scrubbing. The flask was immersed in a Belmont metal bath at 2 (10) π and stirred at 2 Torr RpM after the reaction had dissolved. After about 2.5 hours, the temperature was raised to: (7) Art and these conditions were maintained for an additional 2 hours. The temperature was raised to 285 ° C (within about 25 minutes) and the pressure was lowered to 〇 3 mm Hg over a period of 5 minutes. When the viscosity increases, the agitation is reduced, with 15 RPM being the minimum agitation used. The total polymerization time is varied to obtain the intrinsic viscosity of the target. After the completion of the polymerization, the Belmont metal bath was lowered and the polymer was cooled to below its glass transition temperature. After about 30 minutes, the flask was re-immersed in a Belm〇nt metal bath (the temperature had increased to 295 °c during this 30 minute wait) and the polymer mass was heated until it was pulled away from the glass flask. The polymer mass was placed in a flask and stirred at moderate levels until the polymer had cooled. The polymer was removed from the flask and ground to pass through a 3 mm screen. A variation of this procedure was performed to produce the copolyesters described below with the target groups of 20, 32 and 45 moles/0. The intrinsic viscosity is measured as described in the "Measuring Methods" section above. Polyester 119732.doc -351 · 200804457 The composition is as described in the section on measurement methods, and is measured by 1H NMR. The glass transition temperature is by DSC, after quenching, at 2 Torr. At a rate of 〇 / min, a second heating test is used. The table below shows experimental data for this example polyester. The data shows that for a constant intrinsic viscosity, cis 2,2,4,4-tetramethylcyclobutanediol is trans 2,2,4,4-tetramethyl-1,3·cyclobutanediol. About twice as effective to increase the glass transition temperature. Table 10 Effect of 2,2,4,4-tetramethyl-l,3-cyclobutanediol cis/reverse composition on Tg Example Mox % TMCD IV (common/g) (3⁄4 η〇 at 260° C (parking) η〇 at 275°C (poor) 290 at 290 C (poise) %cis TMCD A 45.8 0.71 119 NANA Ν.Α. 4.1 B 43.2 0.72 122 NANA Ν.Α. 22.0 C 46.8 0.57 119 26306 16941 6601 22.8 D 43.0 0.67 125 55060 36747 14410 _23.8 E 43.8 0.72 127 101000 62750 25330 24.5 F 45.9 0.533 119 11474 6864 2806 _26.4 G 45.0 0.35 107 NANA Ν.Α.— _27.2 Η 41.2 0.38 106 1214 757 Ν.Α. 29.0 I 44.7 0.59 123 NANA Ν.Α. 35.4 J 44.4 0.55 118 NA · NA Ν.Α. __35.6 K 44.3 0.51 119 NANA Ν.Α. __36.3 L 44.0 0.49 128 NANA Ν. 1.7. 71.7 Μ 43.6 0.52 128 NANA Ν.Α. 72.1 N 43.6 0.54 127 NANA Ν.Α. 72.3 0 41.5 0.58 133 15419 10253 4252 88.7 P 43.8 0.57 135 16219 10226 4235 __89.6 Q 41.0 0.33 120 521 351 2261 90.4 R 43.0 0.56 134 NANA Ν.Α. ___90.6 S 43.0 0.49 132 7055 4620 2120 90.6 T 43.1 0.55 134 12970 8443 353 1 91.2 U 45.9 0.52 137 NANA Ν.Α. 98.1 NA=Not available. -352- 119732.doc 200804457 Example 11 This example illustrates the preparation of a dimethyl ether terephthalate residue containing 100 mol%, 55 mol% a copolyester of 1,4_cyclohexanedimethanol residue and 45 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol. 97.10 g (0.5 mol) dimethyl terephthalate, 52 46 g (〇36 mol) Μ-% hexane dimethanol, 34 〇 7 g (〇 24 mol) 2, 2 , 4,4_tetramethyl-1,3_cyclobutanediol and 〇·〇863g (3〇〇ppm) dibutyltin oxide mixture is placed in a nitrogen inlet tube, a metal stirrer and a short distillation column In a 500-ml bottle. The flask was placed in a Wood's metal bath that had been heated to 2 Torr. The contents of the flask were at 200. (: Heat down for a few hours, then gradually increase the temperature to 21 (TC. Hold the reaction mixture for 2 hours, then heat to 29 °C for 30 minutes. At 290 °C, the next 3 to During the 5 minute period, a vacuum of 0.01 psig was gradually applied. Maintain a full vacuum (〇〇1 Psig) for a total time of about 45 minutes to remove excess unreacted glycol. Obtain high melt viscosity, visually clear and colorless polymer It has a glass transition temperature of 125 ° C and an intrinsic viscosity of 〇·64 com / gram. Example 12 - Comparative Example This example illustrates 100% 2,2,4,4_tetramethyl-ΐ53·cyclobutene The diol-based polyester has a slow crystallization half-life. It is similar to a polyester based on terephthalic acid and 2,2,4, tetratetramethyl 4,3-cyclobutanediol. The method described in Example 11 was prepared to have the properties shown in the table. This polymer was made with 300 ppm of dibutyltin oxide. 2,2,4,4-Tetradecyl-1,3-cyclobutanediol The trans/cis ratio is 65/35. The film is from the ground polymer at 320. (3 presses. Self-smelting 119732.doc -353 - 200804457, = The half-life metric is at the temperature of 25 generations, and is: 下 下 : and is reported in Table 11. The fastest crystallization half-life of the sample is taken by crystallization as the crystallization half-life as temperature The lowest value of the function. The fastest crystallization half-life of this polyester is about 1300 minutes. This value is in contrast to the fact that only benzene: formic acid and 1,4-cyclohexane-methanol (no comonomer) The modified (base) polyester (PCT) has an extremely short crystallization half-life (&lt;1 minute) as shown in Figure 1. Table 11 Crystallization half-life (minutes) Co-monomer (mole) %) IV (common/gram) Tg (°C) Tmax (°C) at 220°C (minutes) at 230°C (minutes) at 240°C (minutes) at 250°C (minutes) 100 mol % F 0.63 170.0 330 3291 3066 1303 1888 where · F is 2,2,4,4-tetramethyl-1,3-cyclobutanediol (65/35 trans/cis) Example 13 contains The polyester sheet is made using a 3.5 inch single screw extruder which has been formulated to have a nominal composition of 1 mole % terephthalic acid residue, 80 moles. / 〇 1,4-cyclohexane dimethanol residue and 2 〇 mol % 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues. The flakes are continuously extruded, The thickness was measured to 177 mils' and the various tabs were then sheared to the appropriate size. The intrinsic viscosity and glass transition temperature were measured on a sheet. The intrinsic viscosity of the sheet was measured to be 0.69 com/g. The glass transition temperature of the flakes was measured to be 106 C. The sheets were then conditioned for 2 weeks at 50% relative humidity and 60 °C. Next, the sheet was thermoformed in a negative mold to have a draw ratio of 2.5:1, and a Brown thermoforming machine was used. The hot forming oven heater is set to 7〇/6〇/6〇0/〇 119732.doc •354· 200804457 output, using only top heating. The sheets were left in the oven for varying amounts of time to determine the effect of sheet temperature on part quality, as shown in the table below. Part quality is measured by measuring the volume of the thermoformed part, calculating the stretch, and visually inspecting the hot formed part. The tensile system is calculated by dividing the part volume by the highest part volume achieved in this experiment (example G) setting. Thermoformed parts are visually inspected for any bubbles and are classified as having no (N), low (L) or 咼 (H) bubble formation. The results hereinafter confirmed that these thermoplastic sheets having a glass transition temperature of 1 〇6 can be thermoformed under the conditions shown below, such as by using such a sheet having at least 95% stretch and no bubble formation. It is not necessary to pre-dry the sheet before thermoforming.

實例14 包含聚酯之薄片係使用3·5英吋單螺桿製成，該聚酯已 被製成具有標的組成為100莫耳％對苯二曱酸殘基、8〇莫 耳％ M-環己烷二甲醇殘基及2〇莫耳％ 2,2,4,4_四甲基a，3_ 119732.doc - 355 - 200804457 環丁二醇殘基。薄片係連續地被壓出，經計量至厚度為 177密爾，然後將各種薄片剪切至適當大小。固有黏度與 玻璃轉移溫度係在一個薄片上度量。薄片固有黏度係經度 量為0.69公合/克。薄片之玻璃轉移溫度係經度量為1〇6 °C。然後，使薄片在1〇〇。/0相對濕度與25t：下調理2週。接 著，使薄片於陰模中熱成形，具有拉伸比為25 ··丨，使用 Brown熱成形機。熱成形烘箱加熱器係設定至6〇/4〇/4〇%輸 出，僅使用頂部加熱。將薄片留在烘箱中，歷經不同量之 時間，以測定薄片溫度對於零件品質之作用，如下表中所 示。零件品質係藉由度量熱成形零件之體積，計算拉伸， 及目視檢查熱成形零件而測得。拉伸係以零件體積除以在 此實驗（實例G)設定中所達成之最高零件體積計算而得。 熱成形零件係以目視檢查任何氣泡，及被分級為無（n)、 低（L)或咼（Η)之形成氣泡程度。下文結果證實，具有玻璃 轉移溫度為106 C之此等熱塑性薄片可在下文所示之條件 下熱成形，如藉由具有至少95%拉伸且未形成氣泡之薄片 生產所證實者，而無需在熱成形之前使薄片預乾燥 熱成η ------^ m件 實例 加熱時間 薄片溫度 零件體積 (秒） CC) (毫升） A 154 394 B 163 157 606 C 185 160 702 D 195 161 698 零件品質 拉伸(％) 95 95 119732.doc -356- 200804457 Ε 215 163 699 95 L F 230 168 705 96 L G 274 174 737 100 Η Η 275 181 726 99 Η 實例is-比較實例 由Kelvx 201所組成之薄片係使用3·5英吋單螺桿壓出機 製成。Kelvx為包含 69.85% PCTG (Eastar，得自 Eastman 化 學公司’具有100莫耳％對苯二甲酸殘基、62莫耳％ 1，4-環 己烧二甲醇殘基及38莫耳％乙二醇殘基）；30% PC (雙酚A 聚碳酸酉旨）；及0.15% Weston 619(安定劑，由Crompton公 司銷售）之摻合物。薄片係連續地被壓出，經計量至厚度 為17 7松爾’然後將各種薄片剪切至適當大小。玻璃轉移 溫度係在一個薄片上度量，且為100°C。然後，將薄片在 50%相對濕度與6(rc下調理2週。接著，使薄片於陰模中 熱成形，具有拉伸比為2.5:1，使用Brown熱成形機。熱成 形供箱加熱器係設定至70/60/60%輸出，僅使用頂部加 熱。將薄片留在烘箱中，歷經不同量之時間，以測定薄片 溫度對於零件品質之作用，如下表中所示。零件品質係藉 由度ϊ熱成形零件之體積，計算拉伸，及目視檢查熱成形 零件而測得。拉伸係以零件體積除以在此實驗（實例£)設 定中所達成之最高零件體積計算而得。熱成形零件係以目 視檢查任何氣泡，及被分級為無（N)、低（L)或高（H)之形成 ；T ^ 下文結果證實’此等具有玻璃轉移溫度為1〇〇 C之熱塑⑯薄片可在下文所示之條件下熱成开[如藉由具 119732.doc -357 - 200804457 有至少95%拉伸且未形成氣泡之薄片生產所證實者，而無 需在熱成形之前使薄片預乾燥。Example 14 A sheet comprising polyester was made using a 3·5 inch single screw which had been formulated to have a composition of 100 mole % terephthalic acid residue, 8 mole % M-ring Hexane dimethanol residue and 2 〇 mol% 2,2,4,4-tetramethyl a, 3 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The flakes were continuously extruded, metered to a thickness of 177 mils, and the various flakes were then sheared to the appropriate size. The intrinsic viscosity and glass transition temperature are measured on a sheet. The intrinsic viscosity of the sheet is 0.69 metric/g. The glass transition temperature of the flakes was measured to be 1〇6 °C. Then, the sheet is placed at 1 inch. /0 relative humidity and 25t: lower conditioning for 2 weeks. Next, the sheet was thermoformed in a negative mold to have a draw ratio of 25 ··丨, and a Brown thermoforming machine was used. The thermoformed oven heater is set to 6 〇 / 4 〇 / 4 〇 % output, using only top heating. The flakes were left in the oven for varying amounts of time to determine the effect of the flake temperature on the quality of the part, as shown in the table below. Part quality is measured by measuring the volume of the thermoformed part, calculating the stretch, and visually inspecting the hot formed part. The tensile system is calculated by dividing the part volume by the highest part volume achieved in this experiment (Example G) setting. Thermoformed parts are visually inspected for any bubbles and are classified as having no (n), low (L) or 咼 (Η) bubble formation. The results below demonstrate that such thermoplastic sheets having a glass transition temperature of 106 C can be thermoformed under the conditions shown below, as evidenced by the production of sheets having at least 95% stretch and no bubble formation, without Pre-drying the sheet to η before thermoforming ------^^ Example heating time sheet temperature part volume (seconds) CC) (ml) A 154 394 B 163 157 606 C 185 160 702 D 195 161 698 parts Quality Stretching (%) 95 95 119732.doc -356- 200804457 Ε 215 163 699 95 LF 230 168 705 96 LG 274 174 737 100 Η 275 275 181 726 99 实例 Example is-Comparative example A sheet consisting of Kelvx 201 It is made using a 3.5-inch single-screw extruder. Kelvx contains 69.85% PCTG (Eastar, available from Eastman Chemical Company) with 100 mole % terephthalic acid residues, 62 mole % 1,4-cyclohexane dimethanol residue and 38 mole % ethylene glycol Residue); 30% PC (bisphenol A polycarbonate); and 0.15% Weston 619 (stabilizer, sold by Crompton Corporation) blend. The flakes are continuously extruded and weighed to a thickness of 17 7 ' and then the various flakes are cut to the appropriate size. The glass transition temperature is measured on a sheet and is 100 °C. Then, the sheet was conditioned at 50% relative humidity for 2 weeks at 6 (rc). Next, the sheet was thermoformed in a negative mold having a draw ratio of 2.5:1 using a Brown thermoforming machine. Thermoformed box heater Set to 70/60/60% output, use only top heating. Leave the sheet in the oven for a different amount of time to determine the effect of sheet temperature on part quality, as shown in the table below. The volume of the thermoformed part is calculated, the tensile is calculated, and the thermoformed part is visually inspected. The tensile line is calculated by dividing the part volume by the highest part volume achieved in this experiment (example £) setting. The formed parts were visually inspected for any bubbles and classified as none (N), low (L) or high (H); T ^ The following results confirmed that 'there are thermoplastics with a glass transition temperature of 1 〇〇C The 16 sheets can be thermally opened under the conditions shown below [as evidenced by the production of sheets having at least 95% stretch and no bubble formation with 119732.doc -357 - 200804457, without the need to make the sheets prior to thermoforming Pre-drying.

實例 熱成η 多條件 零件品質 加熱時間 (秒） 薄片溫度 (°C) 零件體積 (毫升） 拉伸(％) 氣泡 (N，L，H) A 90 146 582 75 N B 101 150 644 83 N C 111 154 763 98 N D 126 159 733 95 N E 126 159 775 100 N F 141 165 757 98 N G 148 168 760 98 L 實例16-比較實例 由Kelvx 201所組成薄片係使用3·5英吋單螺桿壓出機製 成。薄片係連續地被壓出，經計量至厚度為177密爾，然 後將各種薄片剪切至適當大小。玻璃轉移溫度係在一個薄 片上度里，且為l〇〇°c。然後，使薄片在1〇〇%相對濕度與 饥下調理2週。接著，使薄片於陰模中熱成形，具有拉 伸比為2.5 : 1，使用31^〜11熱成形機。熱成形烘箱加熱器 係汉疋至60/40/40%輸出，僅使用頂部加熱。將薄片留在 烘箱中，歷經不同量之時間，以測定薄片溫度對於零件品 質之作用’如下表中所示。零件品質係藉由度量熱成形零 牛〃體積5十算拉伸，及目視檢查熱成形零件而測得。拉 伸係以零件體積除以在此實驗（實例H)設定中所達成之最 119732.doc •358 - 200804457 局零件體積計算而得。熱成形零件係以目視檢查任何氣 泡，及被分級為無（N)、低（L)或高（H)之形成氣泡程度。下 文結果證實，此等具有玻璃轉移溫度為1〇〇〇c之熱塑性薄 片可在下文所示之條件下熱成形，如藉由具有大於95%拉 伸且未形成氣泡之薄片生產所證實者，而無需在熱成形之 前使薄片預乾燥。Example Thermal η Multi-condition part quality heating time (seconds) Sheet temperature (°C) Part volume (ml) Stretch (%) Bubble (N, L, H) A 90 146 582 75 NB 101 150 644 83 NC 111 154 763 98 ND 126 159 733 95 NE 126 159 775 100 NF 141 165 757 98 NG 148 168 760 98 L Example 16 - Comparative Example A sheet consisting of Kelvx 201 was made using a 3.5 inch single screw extruder. The flakes were continuously extruded, measured to a thickness of 177 mils, and then the various flakes were cut to the appropriate size. The glass transition temperature is on a thin sheet and is l〇〇°c. Then, the sheets were conditioned for 2 weeks at 1% relative humidity and hunger. Next, the sheet was thermoformed in a negative mold having a draw ratio of 2.5:1 using a 31^11 hot forming machine. The thermoformed oven heater is a 60/40/40% output from Hanhan, using only top heating. The flakes were left in the oven for varying amounts of time to determine the effect of the flake temperature on the quality of the part as shown in the table below. The quality of the part was measured by measuring the volume of the hot formed zero burdock and measuring the thermoformed part by visual inspection. The extension is calculated by dividing the part volume by the maximum 119732.doc •358 - 200804457 part volume achieved in this experiment (Example H) setting. Thermoformed parts are visually inspected for any bubble and are classified as having no (N), low (L) or high (H) bubble formation. The results hereinafter confirmed that these thermoplastic sheets having a glass transition temperature of 1 〇〇〇c can be thermoformed under the conditions shown below, as evidenced by the production of sheets having greater than 95% stretch and no bubble formation, It is not necessary to pre-dry the sheet before thermoforming.

NR=未記錄 實例17-比較實例 由PCTG 25976⑽莫耳％對苯二甲酸殘基、62莫耳％ μ-環己炫二甲醇殘基及38莫耳％乙二醇殘基)所組成之薄 片，係使用3.5英單螺桿壓出機製成。薄片係連續地被 壓出’經計量至厚度為118密爾，然後將各種薄片剪切至 適當大小。玻璃轉移溫度係在_個薄片上度量，且為87 119732.doc -359 - 200804457 °C。然後’將薄片在50%相對濕度與6(rc下調理4週。水 含量經度量為〇·17重量％。接著，使薄片於陰模中熱成 开&gt; ’具有拉伸比為2.5 : 1，使用Brown熱成形機。熱成形 烘箱加熱器係設定至70/60/60%輸出，僅使用頂部加熱。 將薄片留在烘箱中，歷經不同量之時間，以測定薄片溫度 對於零件品質之作用，如下表中所示。零件品質係藉由度 1熱成形零件之體積，計算拉伸，及目視檢查熱成形零件 而測得。拉伸係以零件體積除以在此實驗（實例A)設定中 所達成之最同零件體積計算而得。熱成形零件係以目視檢 查任何氣泡，及被分級為無⑺）、低（L)或高（H)之形成氣泡 私度。下文結果證實，此等具有玻璃轉移溫度為87。〇之熱 塑性薄片可在下文所示之條件下熱成形，如藉由具有大於 95%拉伸且未形成氣泡之薄片生產所證實者，而無需在熱 成形之前使薄片預乾燥。NR = unrecorded Example 17 - Comparative Example A sheet consisting of PCTG 25976 (10) mole % terephthalic acid residue, 62 mole % μ-cyclohexanedimethanol residue and 38 mole % ethylene glycol residue) It is made using a 3.5 inch single screw extruder. The flakes were continuously pressed out to a thickness of 118 mils and the various flakes were then sheared to the appropriate size. The glass transition temperature is measured on _ sheets and is 87 119732.doc -359 - 200804457 °C. Then the sheet was then conditioned at 50% relative humidity for 6 weeks at 6 rc. The water content was measured as 〇17 wt%. Then, the sheet was allowed to open in the negative mold &gt; 'with a draw ratio of 2.5: 1. Use a Brown thermoforming machine. The hot forming oven heater is set to 70/60/60% output, using only top heating. Leave the sheet in the oven for a different amount of time to determine the sheet temperature for part quality. The effect is shown in the following table. The quality of the part is measured by the volume of the thermoformed part, the calculated stretch, and the visual inspection of the hot formed part. The tensile part is divided by the part volume in this experiment (Example A) The most common part volume is calculated in the setting. The thermoformed part is visually inspected for any bubbles, and is classified into no (7)), low (L) or high (H) to form the bubble. The results below confirm that these have a glass transition temperature of 87. The hot plastic sheet of the crucible can be thermoformed under the conditions shown below, as evidenced by the production of flakes having greater than 95% stretch and no bubble formation, without pre-drying the flake prior to thermoforming.

熱成开 多條件 零件品質 實例 加熱時間 (秒） 薄片溫度 CC) 零件體積 (毫升） 拉伸(％) 氣泡 (N，L，H) A 102 183 816 100 N B 92 171 811 99 N C 77 160 805 99 N D 68 149 804 99 N E 55 143 790 97 N F 57 138 ------— 697 ----—__ 85 N 實例18-比較實例 119732.doc -360 - 200804457 包含20重量°/。Teijin L-1250聚碳酸酯（雙盼_A聚碳酸 酯）、79.85重量 ％ PCTG 25976及 0.15重量％ Weston 619之 可溶混摻合物，係使用1.25英吋單螺桿壓出機製成。包含 此摻合物之薄片係接著使用3 · 5英吋單螺桿壓出機製成。 薄片係連續地被壓出，經計量至厚度為U8密爾，然後將 各種薄片剪切至適當大小。玻璃轉移溫度係在一個薄片上 度里，且為94 C。然後，將薄片在5〇%相對濕度與下 調理4週。水含量經度量為〇·25重量％。接著，使薄片於陰 模中熱成形，具有拉伸比為2.5 : 1，使用Brown熱成形 機。熱成形烘相加熱器係設定至70/60/60%輸出，僅使用 頂部加熱。將薄片留在烘箱中，歷經不同量之時間，以測 定薄片溫度對於零件品質之作用，如下表中所示。零件品 質係藉由度量熱成形零件之體積，計算拉伸，及目視檢查 熱成形零件而測得。拉伸係以零件體積除以在此實驗（實 例A)設定中所達成之最高零件體積計算而得。熱成形零件 係以目視檢查任何氣泡，及被分級為無（N)、低（L)或高（h) 之形成氣泡程度。下文結果證實，此等具有玻璃轉移溫度 為94 C之熱塑性薄片可在下文所示之條件下熱成形，如藉 由具有大於95%拉伸且未形成氣泡之薄片生產所證實者， 而無需在熱成形之前使薄片預乾燥。 119732.doc -361 - 200804457 熱成形條件 零件品質 實例 加熱時間 (秒） 薄片溫度 (°C) 零件體積 (毫升） 拉伸(％) 氣泡 (H L，H) A 92 184 844 100 Η B 86 171 838 99 Ν C 73 160 834 99 Ν D 58 143 787 93 Ν E 55 143 665 79 Ν 實例19-比較實例 包含30重量。/◦ Teijin L-1250聚碳酸酯、69.85重量％ PCTG 25976及0.15重量％ Weston 619之可溶混摻合物，係 使用1.25英吋單螺桿壓出機製成。包含此摻合物之薄片係 接著使用3 · 5英吋單螺桿壓出機製成。薄片係連續地被壓 出，經計量至厚度為118密爾，然後將各種薄片剪切至適 §大小。玻璃轉移溫度係在一個薄片上度量，且為99。〇。 然後，將薄片在50%相對濕度與6(rc下調理4週。水含量 經度量為0.25重量％。接著，使薄片於陰模中熱成形，具 有拉伸比為2·5 : 1，彳吏用Brown熱成形機。熱成形供箱加 …、器係。又疋至70/60/60%輸出，僅使用頂部加熱。將薄片 留在烘箱巾，歷經不同量之時間，以測定薄片溫度對於零 件口口質之作用’如下表中所示。零件品質係藉由度量熱成 …V件之體積，计算拉伸，及目視檢查熱成形零件而測 付。拉伸係以零件體積除以在此實驗（實例Α)設定中所達 成之最面零件體積計算而得。熱成形零件係以目視檢查任 119732.doc •362- 200804457 何氣泡，及被分級為無…）、低（L)或高（H)之形成氣泡程 度。下文結果證實’此等具有玻璃轉移溫度為99〇c之熱塑 性薄片可在下文所不之條件下熱成形，如藉由具有大於 95%拉伸且未形成氣泡之薄片生產所證實者，而無需在熱 成形之前使薄片預乾燥。 實例 熱成刃 多條件 零件品質 加熱時間 (秒） 薄片溫度 (°C) 零件體積 (毫升） 拉伸(％) 氣泡 (N，L，H) A 128 194 854 100 Η B 98 182 831 97 L C 79 160 821 96 Ν D 71 149 819 96 Ν E 55 145 785 92 Ν F 46 143 0 0 ΝΑ G 36 132 0 0 ΝΑ NA=不可應用。零之數值表示薄片未被形成，因其未拉入 模具中（可能是因其太冷）。 實例20-比較實例 包含4〇重量％ Teijin L-l25〇聚碳酸酯、59·85重量％ PCTG 25976及0.15重篁％ Weston 619之可溶滿換合物，係 使用1.25英吋單螺桿壓出機製成。包含此摻合物之薄片係 接著使用3.5英吋單螺桿壓出機製成。薄片係連續地被壓 出，經計量至厚度為118密爾，然後將各種薄片剪切至適 當大小。玻璃轉移溫度係在一個薄片上度量，且為1 〇5 119732.doc -363 - 200804457 C。然後，將薄片在50%相對濕度與6〇〇c下綱理4週。水 含量經度量為0.265重量％。接著，使薄片於陰模中熱成 形〆、有拉伸比為2.3:1，使用Br〇wn$成形機。熱成形焕 箱加熱器係設定至70/60/6〇%輸出，僅使用頂部加熱。將 薄片留在烘箱巾’歷經不同量之時間，以測定薄片溫度對 於零件品質之作用’如下表中所示。零件品質係藉由度量 熱成形零件之體積’計算拉伸，&amp;目視檢查熱成形零件而 測得。拉伸係以零件體積除以在此實驗（實例8八至吒)設定 中所達成之最高零件體積計算而得。熱成形零件係以目視 檢查任何氣泡，及被分級為無⑼、低（L)或高（H)之形成氣 泡程度。下文結果證實，此等具有玻璃轉移溫度為1〇5。〇 之熱塑性薄片可在下文所示之條件下熱成形，如藉由且有 大於95%拉伸且未形成氣泡之薄片生產所證實者，而無需 在熱成形之前使薄片預乾燥。Hot-to-open multi-condition part quality example heating time (seconds) sheet temperature CC) part volume (ml) stretch (%) bubble (N, L, H) A 102 183 816 100 NB 92 171 811 99 NC 77 160 805 99 ND 68 149 804 99 NE 55 143 790 97 NF 57 138 ------— 697 -----__ 85 N Example 18 - Comparative Example 119732.doc -360 - 200804457 Contains 20 weight ° /. Teijin L-1250 polycarbonate (double _A polycarbonate), 79.85 wt% PCTG 25976 and 0.15 wt% Weston 619 miscible blends were made using a 1.25 inch single screw extruder. The sheet containing this blend was then made using a 3.5 inch single screw extruder. The flakes are continuously extruded, metered to a thickness of U8 mils, and the various flakes are then sheared to the appropriate size. The glass transition temperature is on a sheet and is 94 C. Then, the sheets were conditioned at 5% relative humidity for 4 weeks. The water content is measured as 〇·25% by weight. Next, the sheet was thermoformed in a negative mold to have a draw ratio of 2.5:1, and a Brown thermoforming machine was used. The thermoformed bake phase heater is set to 70/60/60% output with only top heating. The sheets were left in the oven for varying amounts of time to determine the effect of the sheet temperature on the quality of the part, as shown in the table below. The part quality is measured by measuring the volume of the thermoformed part, calculating the stretch, and visually inspecting the hot formed part. The tensile system is calculated by dividing the part volume by the highest part volume achieved in this experiment (Example A) setting. Thermoformed parts are visually inspected for any bubbles and are classified as having no (N), low (L) or high (h) bubble formation. The results hereinafter confirmed that these thermoplastic sheets having a glass transition temperature of 94 C can be thermoformed under the conditions shown below, as evidenced by the production of sheets having greater than 95% stretch and no bubble formation, without The sheet is pre-dried prior to thermoforming. 119732.doc -361 - 200804457 Hot forming condition Part quality example Heating time (seconds) Sheet temperature (°C) Part volume (ml) Stretching (%) Bubble (HL, H) A 92 184 844 100 Η B 86 171 838 99 Ν C 73 160 834 99 Ν D 58 143 787 93 Ν E 55 143 665 79 实例 Example 19 - Comparative example contains 30 weights. /◦ Teijin L-1250 polycarbonate, 69.85% by weight PCTG 25976 and 0.15 wt% Weston 619 miscible blend, made using a 1.25 inch single screw extruder. The sheet containing this blend was then made using a 3.5 inch single screw extruder. The flakes were continuously extruded, metered to a thickness of 118 mils, and the various flakes were then sheared to the appropriate size. The glass transition temperature is measured on a sheet and is 99. Hey. Then, the flakes were conditioned at 50% relative humidity for 6 weeks at 6 rc. The water content was measured to be 0.25 wt%. Next, the flakes were thermoformed in a negative mold having a draw ratio of 2·5:1. BrUse Brown Thermoforming Machine.The hot forming is supplied to the box and the system is added to the 70/60/60% output, only the top heating is used. The sheet is left in the oven towel for a different amount of time to determine the sheet temperature. The effect on the quality of the mouth of the part is shown in the following table. The quality of the part is measured by measuring the volume of the heat into the V part, calculating the stretch, and visually inspecting the hot formed part. The tensile part is divided by the part volume. Calculated in the most complete part volume achieved in this experiment (example Α) setting. Thermoformed parts are visually inspected for 119732.doc •362- 200804457, and are classified as none...), low (L) Or high (H) to form a bubble. The results below confirm that 'the thermoplastic sheets having a glass transition temperature of 99 〇c can be thermoformed under conditions not hereinafter, as evidenced by the production of sheets having greater than 95% stretch and no bubble formation, without The sheet is pre-dried prior to thermoforming. Example Thermal Insertion Multi-condition Part Quality Heating Time (seconds) Sheet Temperature (°C) Part Volume (ml) Stretch (%) Bubble (N, L, H) A 128 194 854 100 Η B 98 182 831 97 LC 79 160 821 96 Ν D 71 149 819 96 Ν E 55 145 785 92 Ν F 46 143 0 0 ΝΑ G 36 132 0 0 ΝΑ NA= Not applicable. A value of zero indicates that the sheet was not formed because it was not pulled into the mold (probably because it was too cold). Example 20 - Comparative Example comprising 4 〇 wt% Teijin L-l25 〇 polycarbonate, 5.98% by weight PCTG 25976 and 0.15 篁 % Weston 619 soluble full compound, using a 1.25 inch single screw extrusion Mechanism into. The sheet containing this blend was then made using a 3.5 inch single screw extruder. The flakes were continuously extruded, measured to a thickness of 118 mils, and then the various flakes were cut to the appropriate size. The glass transition temperature is measured on a sheet and is 1 〇 5 119732.doc -363 - 200804457 C. The sheets were then placed at 50% relative humidity and 6 〇〇c for 4 weeks. The water content was measured to be 0.265% by weight. Next, the sheet was heat-formed in a negative mold, and the draw ratio was 2.3:1, and a Br〇wn$ molding machine was used. The thermoformed glow box heater is set to 70/60/6〇% output, using only top heating. The sheet was left in the oven towel for a different amount of time to determine the effect of the sheet temperature on the quality of the part as shown in the table below. Part quality is measured by measuring the volume of the thermoformed part 'calculated stretch, &amp; visually inspecting the hot formed part. The tensile system is calculated by dividing the part volume by the highest part volume achieved in this experiment (Example 8-8) setting. Thermoformed parts are visually inspected for any air bubbles and are classified as having no (9), low (L) or high (H) bubble formation. The results below confirm that these have a glass transition temperature of 1〇5. The thermoplastic sheet of 〇 can be thermoformed under the conditions shown below, as evidenced by the production of sheets having greater than 95% stretch and no bubble formation, without pre-drying the sheets prior to thermoforming.

119732.doc -364 - 200804457 實例21-比較實例 包含5〇重量％ Teijin L-l25〇聚碳酸酯、49.85重量％ PCTG 23976及0.15重量％ Weston 619之可溶混摻合物，係 使用1.25英吋單螺桿壓出機製成。薄片係連續地被壓出， 經什量至厚度為118密爾，然後將各種薄片剪切至適當大 小。玻璃轉移溫度係在一個薄片上度量，且為111。〇。然 後’將薄片在50%相對濕度與6(rc下調理4週。水含量經 度量為0.225重量％。接著，使薄片於陰模中熱成形，具有 拉伸比為2.5 ·· 1，使用31&lt;〇〜11熱成形機。熱成形烘箱加熱 器係。又疋至70/60/00%輸出，僅使用頂部加熱。將薄片留 在烘箱中，歷經不同量之時間，以測定薄片溫度對於零件 口口質之作用，如下表中所示。零件品質係藉由度量熱成形 零件之體積，計算拉伸，及目視檢查熱成形零件而測得。 拉伸係以零件體積除以在此實驗（實例八至D)設定中所達成 之最高零件體積計算而得。熱成形零件係以目視檢查任何 氣泡，及被分級為無（N)、低（L)或高（H)之形成氣泡程度。 下文結果證實，此等具有玻璃轉移溫度為lire之熱塑性 薄片可在下文所示之條件下熱成形，如藉由具有大於Μ % 拉伸且未形成氣泡之薄片生產所證實者，而無需在熱成形 之前使薄片預乾燥。 119732.doc -365 - 200804457 實例 熱成史 珍條件 零件品質 加熱時間 (秒） 薄片溫度 CC) 零件體積 (毫升） 拉伸(％) 氣泡 (N，L，H) A 118 192 815 100 Η B 99 182 815 100 Η C 97 177 814 100 L D 87 171 813 100 N E 80 160 802 98 N F 64 154 739 91 N G 60 149 0 0 NA NA=不可應用。零之數值表示薄片未被形成，因其未拉入 模具中（可能是因其太冷）。 實例22-比較實例 包含6〇重量％ Teijin L-1250聚碳酸酯、39.85重量％ PCTG 25976及0.15重量❶/〇 Weston 619之可溶混摻合物，係 使用1 · 2 5夬对單螺桿壓出機製成。包含此摻合物之薄片係 接著使用3.5英吋單螺桿壓出機製成。薄片係連續地被壓 出，經计量至厚度為118密爾，然後將各種薄片剪切至適 當大小。玻璃轉移溫度係在一個薄片上度量，且為117 C。然後，將薄片在50%相對濕度與6〇〇c下調理4週。水 含量經度量為0.215重量％。接著，使薄片於陰模中熱成 形，具有拉伸比為2.5 : 1，使用810〜11熱成形機。熱成形 烘箱加熱器係設定至70/6〇/6〇%輸出，僅使用頂部加熱。 將薄片召在烘箱中，歷經不同量之時間，以測定薄片溫度 119732.doc 200804457 夠製造具有大於95%拉伸且未形成氣泡，及無需在熱成形 之丽使薄片預乾燥之薄片所證實者119732.doc -364 - 200804457 Example 21 - Comparative Example comprising 5 〇 wt% Teijin L-l25 〇 polycarbonate, 49.85% by weight PCTG 23976 and 0.15 wt% Weston 619 miscible blend, using 1.25 ft Made by a single screw extruder. The flakes were continuously pressed out, to a thickness of 118 mils, and the various flakes were then sheared to the appropriate size. The glass transition temperature is measured on one sheet and is 111. Hey. Then the sheet was conditioned at 50% relative humidity for 6 weeks at 6° rc. The water content was measured to be 0.225% by weight. Next, the sheet was thermoformed in a negative mold with a draw ratio of 2.5 ··1, using 31&lt; 〇~11 thermoforming machine. Thermoforming oven heater system. It is further heated to 70/60/00% output, only using top heating. The sheet is left in the oven for different amounts of time to determine the sheet temperature for the part. The effect of the mouth quality is shown in the following table. The quality of the part is measured by measuring the volume of the thermoformed part, calculating the stretch, and visually inspecting the hot formed part. The tensile part is divided by the part volume divided in this experiment ( Examples 8 to D) The calculation of the highest part volume achieved in the setting. The thermoformed part is visually inspected for any bubbles and is classified as having no (N), low (L) or high (H) bubble formation. The results hereinafter confirmed that these thermoplastic sheets having a glass transition temperature of lire can be thermoformed under the conditions shown below, as evidenced by the production of sheets having a tensile strength greater than Μ% and no bubbles are formed, without the need for heat. Make thin before forming Pre-drying. 119732.doc -365 - 200804457 Example Thermal History Conditions Part Quality Heating Time (seconds) Sheet Temperature CC) Part Volume (ml) Stretch (%) Bubble (N, L, H) A 118 192 815 100 Η B 99 182 815 100 Η C 97 177 814 100 LD 87 171 813 100 NE 80 160 802 98 NF 64 154 739 91 NG 60 149 0 0 NA NA=Not applicable. A value of zero indicates that the sheet was not formed because it was not pulled into the mold (probably because it was too cold). Example 22 - Comparative Example comprising 6 〇 wt% Teijin L-1250 polycarbonate, 39.85 wt% PCTG 25976 and 0.15 wt ❶/〇 Weston 619 miscible blend using 1 · 25 夬 for single screw pressure Made out of the machine. The sheet containing this blend was then made using a 3.5 inch single screw extruder. The flakes were continuously extruded, measured to a thickness of 118 mils, and then the various flakes were cut to the appropriate size. The glass transition temperature is measured on a sheet and is 117 C. The sheets were then conditioned for 4 weeks at 50% relative humidity and 6 〇〇c. The water content was measured to be 0.215% by weight. Next, the sheet was heat-formed in a negative mold having a draw ratio of 2.5:1, and a 810 to 11 thermoforming machine was used. The hot forming oven heater is set to 70/6 〇 / 6 〇 % output, using only top heating. The wafer was placed in an oven for a different amount of time to determine the sheet temperature. 119732.doc 200804457 It is sufficient to produce a sheet having greater than 95% stretch and no bubbles formed, and which does not require pre-drying of the sheet during hot forming.

實例23-比較實例 :於零件品質之作用，如下表中所示。零件品質係藉由度 量熱^形零件之體積，計算拉伸，及目視檢查熱成形零件 而測侍。拉伸係以零件體積除以在此實驗（實例A)設定中 所達成之最高零件體積計算而得。熱成形零件係以目視檢 查任何氣泡，及被分級為無…）、低（L)或高（H)之形成氣泡 粒度。下文結果證實，此等具有玻璃轉移溫度為UR之 熱塑性溥片不能在下文所示之條件下熱成形，如藉由不能 包含65重量％TeijinL_1250聚錢s旨、34 85重量％ PCTG 25976及〇.15重量％ w 619之可溶混摻合物係 使用m英忖單螺桿壓出機製成。包含此摻合 接著使用3.5英忖單螺桿壓出機製成。薄片係連續地㈣ 出，經计篁至厚度為m密爾，然後將各種薄片剪切至適 119732.doc -367 - 200804457 當大小。玻璃轉移溫度係在_個薄片上度量，且為i2〇 &lt;，、、:後將薄片在50%相對濕度與下調理*週。水 含量經度量為0.23重量％。接著，使薄片於陰模中敎成 形，具有拉伸比為2.5 :】，使用Br〇熱成形機。熱成形 烘箱加熱器係設定至70/6〇/6〇%輸出，僅使用頂部加熱。 將薄片召在烘相中’歷經不同量之時間，以測定薄片溫度 對於零件品質之作用，如下表中所示。零件品質係藉由度 量熱成形零件之體積，計算拉伸，及目視檢查熱成形零件 而測得。拉伸係以零件體積除以在此實驗（實例A)設定中 所達成之最高零件體積計算而得。熱成形零件係以目視檢 查任何氣泡，及被分級為無（N)、低（L)或高（H)之形成氣泡 程度。下文結果證實’此等具有玻璃轉移溫度為12〇它之 熱塑性薄片不能在下文所示之條件下熱成形，如藉由不能 夠製造具有大於95〇/〇拉伸且未形成氣泡’及無需在熱成形 之前使薄片預乾燥之薄片所證實者。Example 23 - Comparative Example: The effect on part quality is shown in the following table. Part quality is measured by measuring the volume of the hot-formed part, calculating the stretch, and visually inspecting the hot-formed part. The tensile system is calculated by dividing the part volume by the highest part volume achieved in this experiment (Example A) setting. Thermoformed parts are visually inspected for any bubbles and are classified into no (...), low (L) or high (H) bubble forming particle sizes. The results below demonstrate that these thermoplastic sheets having a glass transition temperature of UR cannot be thermoformed under the conditions shown below, such as by not including 65% by weight of TeijinL_1250, 3455% by weight of PCTG 25976 and 〇. A 15 wt% w 619 miscible blend was made using a m inch single screw extruder. The blending was followed by a 3.5 inch single screw extruder. The flakes are continuously (iv) out, and the thickness is m mil, and then the various flakes are cut to the appropriate size of 119732.doc -367 - 200804457. The glass transition temperature is measured on _ sheets and is i2 〇 &lt;,,:: The sheets are then conditioned at 50% relative humidity for 4 weeks. The water content was measured to be 0.23% by weight. Next, the sheet was formed into a shape in a female mold having a draw ratio of 2.5:, and a Br〇 thermoforming machine was used. The hot forming oven heater is set to 70/6 〇 / 6 〇 % output, using only top heating. The flakes are called in the baking phase' for varying amounts of time to determine the effect of the flake temperature on the quality of the part, as shown in the table below. Part quality is measured by measuring the volume of the thermoformed part, calculating the stretch, and visually inspecting the hot formed part. The tensile system is calculated by dividing the part volume by the highest part volume achieved in this experiment (Example A) setting. Thermoformed parts are visually inspected for any bubbles and are classified as having no (N), low (L) or high (H) bubble formation. The results below confirm that 'these thermoplastic sheets having a glass transition temperature of 12 Å cannot be thermoformed under the conditions shown below, such as by being unable to produce a stretch having greater than 95 Å/〇 and not forming bubbles, and The sheet which pre-dried the sheet before thermoforming was confirmed.

實例 熱成无 珍條件 零件品質 加熱時間 (秒） 薄片溫度 CC) 零件體積 (毫升） 拉伸(％) 氣泡 (N，L，H) A 120 197 825 100 Η B 101 177 820 99 Η C 95 174 781 95 L D 85 171 727 88 L E 83 166 558 68 L 實例24-比較實例 119732.doc -368 - 200804457 包含70重量。/。Teijin L-1250聚碳酸酯、29.85重量％ PCTG 25976及〇·15重量％ Weston 619之可溶混摻合物，係 使用1 ·25英吋單螺桿壓出機製成。包含此摻合物之薄片係 接著使用3.5英吋單螺桿壓出機製成。薄片係連續地被壓 出’經計量至厚度為118密爾，然後將各種薄片剪切至適 ▲大小。玻璃轉移溫度係在一個薄片上度量，且為123 C °然後’將薄片在5〇%相對濕度與6〇。〇下調理4週。水 含篁經度量為〇·2〇5重量％。接著，使薄片於陰模中熱成 开乂 /、有拉伸比為2·5 : 1，使用Brown熱成形機。熱成形 烘箱加熱器係設定至70/6〇/6〇%輸出，僅使用頂部加熱。 將薄片留在烘箱中，歷經不同量之時間，Μ敎薄片溫度 ，於零件品質之作帛，如下表中所示。零件品質係藉由度 量熱j形零件之體積，計算拉伸，及目視檢查熱成形零件 而測付。拉伸係以零件體積除以在此實驗（實例A與B)設定 中所達成之最高零件體積計算而得。熱成形零件係以目視 泡程度。下文結果證實，此等具有玻璃轉移溫度 薄片不能在下文所示之條件下熱成形，如藉由不 二 =有大於95%拉伸且未形成氣泡，及無需在熱成 形之刚使薄片預乾燥之薄片所證實者。 119732.doc -369 - 200804457 實例 ----—--- 熱成形條件 ------ 零件品質 加熱時間 (秒） 薄片溫度 CC) 零件體積 (毫升） 拉伸(°/〇) 氣泡 (N，L，H) A 126 198 826 100 Η B 111 188 822 100 Η C 97 177 787 95 L D 74 166 161 19 L E 58 154 0 0 ΝΑ F 48 149 0 0 ΝΑ NA=不可應用。零之數值表示薄片未被形成，因其未拉入 模具中（可能是因其太冷）。 實例2S-比較實例 由Teijin L-1250聚碳酸酯所組成之薄片，係使用3·5英吋 單螺桿壓出機製成。薄片係連續地被壓出，經計量至厚度 為Π8密爾’然後將各種薄片剪切至適當大小。玻璃轉移 溫度係在-個薄片上度量，且為149t。然後，將薄片在 50%相對濕度與6(TC下調理4週。水含量經度量為〇16重量 /〇。接著，使薄片於陰模中熱成形，具有拉伸比為2.5·^， 使用Brown熱成形機。熱成形烘箱加熱器係設定至 70/60/60%輸出，僅使用頂部加熱。將薄片留在烘箱中， 歷經不同量之時間，以測定薄片溫度對於零件品質之作 用，如下表中所示。零件品質係藉由度量熱成形零件之體 積，計算拉伸，及目視檢查熱成形零件而測得。拉伸係以 零件體積除以在此實驗（實例A)設定中所達成之最高零件 119732.doc -370- 200804457 體積計算而得。熱成形零件係以目視檢查任何氣泡，及被 分級為無（N)、低（L)或高（H)之形成氣泡程度。下文結果證 實，此等具有玻璃轉移溫度為149°C之熱塑性薄片不能在 下文所示之條件下熱成形，如藉由不能夠製造具有大於 95%拉伸且未形成氣泡，及無需在熱成形之前使薄片預乾 燥之薄片所證實者。 實例 熱成形條件 零件品質 加熱時間 (秒） 薄片溫度 (°C) 零件體積 (毫升） 拉伸(％) 氣泡 (N，L，H) A 152 216 820 100 Η B 123 193 805 98 Η C 113 191 179 22 Η D 106 188 0 0 Η E 95 182 0 0 ΝΑ F 90 171 0 0 ΝΑ NA=不可應用。零之數值表示薄片未被形成，因其未拉入 模具中（可能是因其太冷）。 實例26 此實例係說明製備包含至少一種熱安定劑、其反應產物 及其混合物之聚酯，產生在製程中具有改良的安定性之聚 西旨炼融物。 以下述方式自100莫耳％對苯二甲酸二甲酯（DMT)、1，4-環己烷二曱醇（CHDM)及2,2,4,4-四曱基-1，3-環丁二醇 (TMCD)製備多種聚酯。此實例實驗中TMCD之莫耳％係報 119732.doc -371- 200804457 告於下述表12中，其餘部分之二醇類為CHDM。DMT係購 自 Cape Industries，CHDM (最小值 98%)及 TMCD (最小值 98%)係得自伊士曼化學公司。錫化合物為氧化二甲基錫 (得自Strem化學公司或Gelest Inc·)或參-2-乙基己酸丁基錫 (Aldrich或Arkema)。磷化合物為磷酸三苯基酯（TPP，得自 Aldrich (98%)或FERRO，Corp·)。除非下述另指明，否則 磷來源係與其他聚酯試劑一起預先添加。CHDM之順/反比 例係如上所述，而TMCD之順/反比例係報告於表12。 表12 實例26之聚酯之組成及固有黏度 實例 熔融IV (公合/克） TMCD (莫耳％) TMCD %順式 Sn (ppm) P (ppm) 理論值/測量值 Sn/P 實際重量 比例 最終 Pz 溫度 (°C) A 0.605 44.8 50.0 2051 無 * 290 B 0.583 44.4 51.9 2011 無 * 290 C 0.578 43.9 50.7 1991 無 * 290 D 0.607 44.9 50.5 1992 無 * 290 E 0.437 44.5 52.0 2002 無 氺 290 F 0.292 44.8 51.9 1902 34/34 5.6 290 G 0.240 43.6 52.8 2061 34/37 5.6 290 Η 0.213 43.2 53.7 1922 34/49 3.9 290 I 0.585 45.1 50.2 1912 10/11 17.4 290 J 0.580 45.1 50.5 1921 10/11 17.5 290 K 0.541 44.0 52.3 2022 19/20 10.1 290 L 0.595 45.3 50.6 1982 20/20 9.9 290 Μ 0.632 45.6 49.0 2032 20/22 9.2 265 N 0.577 46.2 50.1 1962 30/26 7.5 265 0 0.608 46.0 49.6 1901 20/19 10.0 265 P 0.517 45.2 49.4 1002 10/10 10.0 265 Q 0.602 46.1 49.2 1022 10/10 10.2 265 R 0.740 19.0 51.7 1902 20/18 10.6 275 1 錫來源為參-2-乙基己酸丁基錫 2 錫來源為氧化二甲基錫 -372- 119732.doc 200804457 表13數據顯示若以相同條件用於試驗工廠或商業規模 時，比較例A至D聚酯熔融物之安定性被認為是無法接受 的。反之，具有適當錫/磷比例之實驗產生穩定熔融物， 適用於規模放大的製程。 表13 實例26之聚酯之性質 實例 L* a* 熔融物 液面 安定性 聚合體 顏色觀察 聚酯中之 泡沫％ 聚酯之 視覺等級 A 82.50 -0.89 4.66 4 黃色 34% 4 B 79.74 -0.75 4.89 4 黃色 21% 4 C 78.64 -0.39 6.83 4 褐-黃色 37% 4 D 85.44 -1.45 4.07 3 淡黃色 27% 4 E 86.19 -1.04 3.94 3 顏色良好：無 黃色 35% 4 F 89.17 -0.78 2.07 1 顏色良好：無 黃色 12% 1 G 88.96 -1.00 3.76 1 淡黃色 9% 1 Η 88.92 -0.64 2.12 1 顏色良好：無 黃色 9% 1 I 80.92 -1.02 3.22 2 顏色良好：無 黃色 20% 3 J 82.10 -1.67 3.69 2 顏色良好：無 黃色 22% 3 K 85.74 -0.81 2.46 1 ΝΜ ΝΜ ΝΜ L 82.51 -1.03 2.56 1 顏色良好：無 黃色 15% 2 Μ 85.54 -1.07 2.06 1 顏色良好：無 黃色 22% 3 N 84.54 -0.71 1.07 1 顏色良好：無 黃色 14% 2 0 85.03 -0.82 1.17 1 淡黃色 14% 3 P 85.02 -0.87 1.59 1 淡黃色 17% 2 Q 82.49 -0.86 1.09 1 顏色良好：無 黃色 17% 2 R 85.27 -1.74 4.40 1 淡黃色 24% 4 S NA NA NA ΝΑ ΝΑ 35% ΝΑ T NA NA NA ΝΑ ΝΑ 9% ΝΑ NM=未測量。 -373 - 119732.doc 200804457 表13所報告的熔融物液面安定性係基於下列規格 7 '——____ f真空標準下不安定之熔融物液面，大 里起泡（foaming及frothing)導致高空隙體 ^ (即增加熔融物總體積之氣泡），不'安 疋之氣體脫離’溶融物液面奔騰只能雜 ”整擾拌速率或藉由使授； ，^面上方將泡沫下壓或破壞而不自燒 瓶溢流而出’過於不穩定以致益法作. i將其規模放大。_…、女1。饪 標準下非 面，過度起泡（foaming及frothing)導致高 空隙體積（氣泡增加熔融物總體積），不 安定之氣體脫離，熔融物液面奔^自燒 瓶溢流而出且頻繁地將溶融物/泡珠推入 真空糸統之氣體空間中。操作常常無法 完成（在此穩定性級別，大於50%以上的 重複操作無法被完成）。 表13所報告的視覺等級係基於下列規格 等級 說明 1 極少的氣泡：可看穿炼融聚合體 2 稀少的氣泡··氣泡足以阻播視線透 過聚合體之視線但不足以劇烈地 增加聚合體體積 3 多量氣泡：聚合體體積受氣泡影響 4 非常密集的泡沫：聚合體體積劇％ 地受多量氣泡影響 ' ~ 實例26S及實例26T為比較實例。實例26S代表以類似下 述實例29 A方式製備之聚酯，其不含磷熱安定劑，具有 119732.doc -374- 200804457 〇·54公合/克之;[V，且含有100莫耳％對苯二甲酸殘基、 43.8莫耳％ TMCD殘基及56.2莫耳。/oCHdm酸殘基。使用 參-2-乙基己酸丁基錫作為錫觸媒（Sn=216 ppm)來源，在 290°C最終加工機溫度下製備此聚酯，其具有顏色值 L* = 60.97、b*=9.02及 a*=-0.89。實例 26T代表含 65 莫耳 ％ 對苯二甲酸殘基、35莫耳％間苯二甲酸殘基及ι〇〇莫耳％ 環己烧二甲醇殘基之市購可得之Keivx聚合體。 此實例之聚酯係於裝有攪拌器及需要時可容許氮滌氣及 真空之聚合體頭部的500毫升圓底燒瓶中製備。將原料稱 重加入燒瓶以進行一 〇·4莫耳的操作（聚合體重複單元=274 克/莫耳）·· 0·400莫耳 DMT (77.6克）、0.224莫耳 CHDM (32.3 克）及0.256莫耳TMCD (36.8克）、及0.112克參-2-乙基己酸 丁基錫或0.03 14克氧化二甲基錫（如表12所報告），使最終 聚合物中有約200 ppm之錫金屬，惟，可隨其他標的濃度 (例如100 ppm之Sn)調整。對應調整TMCD及CHDM之量以 製備實例26之聚酯，其標的TMCD濃度為20莫耳％。 二醇/酸之比例為1.2/1，過量部分為2% CHDM且該20% 過量部分剩餘者為TMCD。將觸媒稱重加入燒瓶，固體或 液體皆可。在各實驗中，以表12所載之量將固體形式之磷 酸三苯基酯稱重加入燒瓶中。使用10〇 ppm(0 0109克液體） 之氫氧化四·甲基銨（TMAH)製備實例26N。 設定點與數據收集係藉助於Camile程序控制系統。一旦 反應物被熔解，即起始攪拌，且慢慢地增加至所對應之 Camile順序中所指定值（如下所述）。反應器之溫度係隨著 119732.doc -375 - 200804457 操作時間逐漸增加。 酯交換與聚縮合反應係在同一個500毫升燒瓶中進行。 在實例26A及實例26B之操作期間，將攪拌器的葉片上移 至熔融物頂端以抑制泡沫層。對各實例藉由Camile軟體控 制之溫度/壓力/攪拌速率順序係報告於下列表中。此實例 各實驗之最終聚合溫度（Pz溫度）係於265°C至290°C之範圍 且報告於表12。 實例26A至實例26L之Camile順序 3 760 1 200 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 5 245 760 50 11 5 245 760 50 12 30 265 760 50 13 3 265 90 50 14 110 290 90 50 15 5 290 6 25 16 110 290 6 25 17 2 290 400 0 18 1 300 760 0 實例26M至實例260之Camile順序 ： ' * 200 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 119732.doc -376- 200804457 5 1 200 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 5 245 760 50 11 3 245 375 50 12 30 245 375 50 13 3 250 20 50 14 30 250 20 50 15 3 255 5 25 16 110 255 5 25 17 3 265 1 25 18 110 265 1 25 19 2 265 400 0 20 1 265 760 0 實例26P之Camile順序 黏度受限制順序、低真空 Η 1 3 200 760 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 5 245 760 50 11 3 245 375 50 12 30 245 375 50 13 3 250 20 50 14 30 250 20 50 15 3 255 5 25 16 110 255 5 25 17 3 265 0.2 25 18 110 265 0.2 25 19 2 265 400 0 •377 · 119732.doc 200804457 20 1 265 760 0 實例26Q之Camile順序 黏度受限制順序、低真空 1 3 200 760 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 5 245 760 50 11 3 245 375 50 12 30 245 375 50 13 3 250 20 50 14 30 250 20 50 15 3 255 3 25 16 110 255 3 25 17 3 265 0.2 25 18 110 265 0.2 25 19 2 265 400 0 20 1 265 760 0 實例26R之Camile順序 1 3 ______劈〔V ；^ η· 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 245 760 100 10 5 260 760 50 11 3 260 375 50 -378 - 119732.doc 200804457 12 30 260 375 50 13 3 260 20 50 14 30 260 20 50 15 3 265 5 25 16 110 265 5 25 17 3 275 1 25 18 110 275 1 25 19 2 275 400 0 20 1 275 760 0 實例27 此實例係說明使用與實例26不同的製程條件製備包含至 少一種熱安定劑、其反應產物及其混合物之聚酯，產生在 製程中具有改良的安定性之聚酯熔融物。 以下述方式自1〇〇莫*%DMT、CHDM及TMCD製備多種 聚酯。用於此實例實驗中之丁1^0〇莫耳％係報告於下述表 14中，其餘部分之二醇類為CHMD。DMT、CHDM及 TMCD係與實例26來源相同。觸媒為氧化二甲基錫（得自 Strem化學公司，Batch B4058112)、參-2-乙基己酸丁基錫 (Aldrich，Batch 06423CD，或 Arkema)或氧化二 丁基錫 (Arkema)。熱安定劑為攝酸三苯基酯亦與實例26具有相同 來源。除非下述另指明，否則磷來源係與其他聚酯試劑一 起預先添加。CHDM之順/反比例係如上所述，而TMCD之 順/反比例係報告於表14。未使用TPP製備實例27A及 27E。 表14 實例27之聚酯之組成及固有黏度 實例 熔融IV (公合/克) TMCD (莫耳％) TMCD %順式Example heat generation condition Quality heating time (seconds) Sheet temperature CC) Part volume (ml) Stretch (%) Bubble (N, L, H) A 120 197 825 100 Η B 101 177 820 99 Η C 95 174 781 95 LD 85 171 727 88 LE 83 166 558 68 L Example 24 - Comparative Example 119732.doc -368 - 200804457 Contains 70 weight. /. A miscible blend of Teijin L-1250 polycarbonate, 29.85 wt% PCTG 25976 and 〇15 wt% Weston 619 was made using a 1.25 inch single screw extruder. The sheet containing this blend was then made using a 3.5 inch single screw extruder. The flakes were continuously pressed out to a thickness of 118 mils and then the various flakes were cut to a suitable size. The glass transition temperature is measured on a sheet and is 123 C ° and then the sheet is at 5 〇 % relative humidity and 6 〇. Underarms for 4 weeks. The water containing strontium is measured as 〇·2〇5 wt%. Next, the sheet was thermally opened in a negative mold, and the stretch ratio was 2·5: 1, and a Brown thermoforming machine was used. The hot forming oven heater is set to 70/6 〇 / 6 〇 % output, using only top heating. The flakes are left in the oven for a different amount of time, the flake temperature, and the quality of the part, as shown in the table below. Part quality is measured by measuring the volume of the hot j-shaped part, calculating the stretch, and visually inspecting the hot formed part. The tensile system is calculated by dividing the part volume by the highest part volume achieved in this experiment (Examples A and B) settings. Thermoformed parts are visually obscured. The results hereinafter confirmed that these glass transition temperature sheets cannot be thermoformed under the conditions shown below, such as by having more than 95% stretching and not forming bubbles, and without pre-drying the sheets immediately after thermoforming The slice is confirmed by the slice. 119732.doc -369 - 200804457 Example-------- Thermoforming conditions ------ Part quality heating time (seconds) Sheet temperature CC) Part volume (ml) Stretch (°/〇) Bubble ( N 、 、 、 、 、 、 、 A value of zero indicates that the sheet was not formed because it was not pulled into the mold (probably because it was too cold). Example 2S - Comparative Example A sheet composed of Teijin L-1250 polycarbonate was made using a 3.5 inch single screw extruder. The flakes are continuously extruded and weighed to a thickness of Π8 mil' and then the various flakes are sheared to the appropriate size. The glass transition temperature was measured on a sheet and was 149 tons. Then, the flakes were conditioned at 50% relative humidity for 6 weeks at 6 (TC). The water content was measured to be 〇16 wt/〇. Next, the flakes were thermoformed in a negative mold with a draw ratio of 2.5·^, using Brown thermoforming machine. The hot forming oven heater is set to 70/60/60% output, using only top heating. The sheet is left in the oven for a different amount of time to determine the effect of sheet temperature on part quality, as follows The quality of the part is measured by measuring the volume of the thermoformed part, calculating the stretch, and visually inspecting the hot formed part. The tensile part is divided by the part volume divided by the setting in this experiment (Example A). The highest part 119732.doc -370- 200804457 is calculated by volume. Thermoformed parts are visually inspected for any bubbles and are classified as having no (N), low (L) or high (H) bubble formation. It was confirmed that these thermoplastic sheets having a glass transition temperature of 149 ° C cannot be thermoformed under the conditions shown below, such as by being unable to produce a stretch having more than 95% and not forming bubbles, and without requiring prior to thermoforming Sheet pre- Example of dried sheet. Example thermoforming conditions Part quality heating time (seconds) Sheet temperature (°C) Part volume (ml) Stretch (%) Bubble (N, L, H) A 152 216 820 100 Η B 123 193 805 98 Η C 113 191 179 22 Η D 106 188 0 0 Η E 95 182 0 0 ΝΑ F 90 171 0 0 ΝΑ NA= not applicable. A value of zero indicates that the sheet is not formed because it is not pulled into the mold ( This may be because it is too cold.) Example 26 This example illustrates the preparation of a polyester comprising at least one thermal stabilizer, its reaction product, and mixtures thereof, resulting in a poly-smelting smelt having improved stability in the process. Said from 100 mol% dimethyl terephthalate (DMT), 1,4-cyclohexanedimethanol (CHDM) and 2,2,4,4-tetradecyl-1,3-cyclobutane The diol (TMCD) was used to prepare a variety of polyesters. The molar % of TMCD in this example experiment is reported in 119732.doc -371-200804457 in Table 12 below, and the rest of the diols are CHDM. DMT is purchased from Cape. Industries, CHDM (minimum 98%) and TMCD (minimum 98%) are from Eastman Chemical Company. Tin compounds are dimethyl oxide Tin (available from Strem Chemical Company or Gelest Inc.) or butyl tin-2-ethylhexanoate (Aldrich or Arkema). The phosphorus compound is triphenyl phosphate (TPP, available from Aldrich (98%) or FERRO, Corp ·). Phosphorus sources are pre-added with other polyester reagents unless otherwise indicated below. The cis/inverse ratio of CHDM is as described above, and the cis/inverse ratio of TMCD is reported in Table 12. Table 12 Composition and Intrinsic Viscosity of the Polyester of Example 26 Example Melt IV (Male/g) TMCD (% by mole) TMCD % cis-Sn (ppm) P (ppm) Theoretical value / measured value Sn / P Actual weight ratio Final Pz temperature (°C) A 0.605 44.8 50.0 2051 None* 290 B 0.583 44.4 51.9 2011 None* 290 C 0.578 43.9 50.7 1991 No* 290 D 0.607 44.9 50.5 1992 No* 290 E 0.437 44.5 52.0 2002 No 290 F 0.292 44.8 51.9 1902 34/34 5.6 290 G 0.240 43.6 52.8 2061 34/37 5.6 290 Η 0.213 43.2 53.7 1922 34/49 3.9 290 I 0.585 45.1 50.2 1912 10/11 17.4 290 J 0.580 45.1 50.5 1921 10/11 17.5 290 K 0.541 44.0 52.3 2022 19/20 10.1 290 L 0.595 45.3 50.6 1982 20/20 9.9 290 Μ 0.632 45.6 49.0 2032 20/22 9.2 265 N 0.577 46.2 50.1 1962 30/26 7.5 265 0 0.608 46.0 49.6 1901 20/19 10.0 265 P 0.517 45.2 49.4 1002 10/10 10.0 265 Q 0.602 46.1 49.2 1022 10/10 10.2 265 R 0.740 19.0 51.7 1902 20/18 10.6 275 1 Tin source is butyl-2-ethylhexanoate butyl tin 2 tin source is dimethyltin oxide - 372- 119732.doc 200804457 Table 13 data shows the same The stability of Comparative Examples A through D polyester melts was considered unacceptable when the conditions were used for pilot plant or commercial scale. Conversely, experiments with appropriate tin/phosphorus ratios produce stable melts that are suitable for scale-up processes. Table 13 Properties of the polyester of Example 26 Example L* a* Liquid level stability of the melt Polymer color observed in the polyester % of the polyester Visual grade A of the polyester A 82.50 -0.89 4.66 4 Yellow 34% 4 B 79.74 -0.75 4.89 4 Yellow 21% 4 C 78.64 -0.39 6.83 4 Brown-yellow 37% 4 D 85.44 -1.45 4.07 3 Light yellow 27% 4 E 86.19 -1.04 3.94 3 Good color: no yellow 35% 4 F 89.17 -0.78 2.07 1 Good color : No yellow 12% 1 G 88.96 -1.00 3.76 1 Light yellow 9% 1 Η 88.92 -0.64 2.12 1 Good color: no yellow 9% 1 I 80.92 -1.02 3.22 2 Good color: no yellow 20% 3 J 82.10 -1.67 3.69 2 Good color: no yellow 22% 3 K 85.74 -0.81 2.46 1 ΝΜ ΝΜ ΝΜ L 82.51 -1.03 2.56 1 Good color: no yellow 15% 2 Μ 85.54 -1.07 2.06 1 Good color: no yellow 22% 3 N 84.54 -0.71 1.07 1 Good color: no yellow 14% 2 0 85.03 -0.82 1.17 1 light yellow 14% 3 P 85.02 -0.87 1.59 1 light yellow 17% 2 Q 82.49 -0.86 1.09 1 Good color: no yellow 17% 2 R 85.27 -1.74 4.40 1 light yellow 24% 4 S NA NA NA ΝΑ ΝΑ 35% ΝΑ TN A NA NA ΝΑ 9% 9% ΝΑ NM=Not measured. -373 - 119732.doc 200804457 The liquid level stability of the melt reported in Table 13 is based on the level of molten solids under the following specifications 7 '-____ f vacuum standard, and high foaming due to foaming and frothing Body ^ (that is, the bubble that increases the total volume of the melt), not the gas of the ampoule is detached from the liquid surface of the molten material, and the flow rate of the molten material can only be mixed, or the foaming force is pressed or destroyed. Without overflowing from the flask, 'too unstable to make it work. i will enlarge its scale. _..., female 1. Non-faceted under the standard, excessive foaming (foaming and frothing) leads to high void volume (bubble increase) The total volume of the melt), the unstable gas is detached, the molten material flows out of the flask and frequently pushes the melt/bubble into the gas space of the vacuum system. The operation is often impossible to complete (here) Stability level, more than 50% of repeated operations cannot be completed.) The visual ratings reported in Table 13 are based on the following specifications. 1 Very few bubbles: Can see through the condensed polymer 2 Rare bubbles · Bubbles are enough to stop Vision The line passes through the line of sight of the polymer but not enough to increase the volume of the polymer violently. 3 A large number of bubbles: the volume of the polymer is affected by the bubbles. 4 Very dense foam: The volume of the polymer is % affected by a large number of bubbles' ~ Example 26S and Example 26T are compared EXAMPLES Example 26S represents a polyester prepared in a manner similar to that of Example 29A below, which does not contain a phosphorous heat stabilizer, having 119732.doc -374-200804457 〇·54 com/g; [V, and containing 100 moles % terephthalic acid residue, 43.8 mole % TMCD residue and 56.2 moles / oCHdm acid residue. Using butyl tin-2-ethylhexanoate as a source of tin catalyst (Sn = 216 ppm), at 290 The polyester was prepared at a final machine temperature of ° C with color values L* = 60.97, b* = 9.02 and a* = -0.89. Example 26T represents 65 mole % terephthalic acid residue, 35 moles Commercially available Keivx polymer of % isophthalic acid residue and oxime mol% cyclohexanol dimethanol residue. The polyester of this example is capable of allowing nitrogen scrubbing when equipped with a stirrer and when needed. Prepared in a 500 ml round bottom flask with a vacuum polymer head. Weigh the raw materials. The bottle was subjected to a 〇·4 mol operation (polymer repeat unit = 274 g/mole) · 0·400 mol DMT (77.6 g), 0.224 mol CHDM (32.3 g) and 0.256 mol TMCD ( 36.8 g), and 0.112 g of butyltin-2-ethylhexanoate or 0.03 14 g of dimethyltin oxide (as reported in Table 12), so that there is about 200 ppm of tin metal in the final polymer, but Other target concentrations (eg, 100 ppm Sn) are adjusted. The amount of TMCD and CHDM was adjusted accordingly to prepare the polyester of Example 26, which had a target TMCD concentration of 20 mol%. The diol/acid ratio was 1.2/1, the excess portion was 2% CHDM and the remainder of the 20% excess was TMCD. The catalyst is weighed into the flask and either solid or liquid. In each experiment, solid form of triphenyl phosphate was weighed into the flask in the amounts set forth in Table 12. Example 26N was prepared using 10 〇 ppm (0 0109 g of liquid) of tetramethylammonium hydroxide (TMAH). The setpoint and data collection system is controlled by the Camile program. Once the reactants have melted, the agitation is initiated and slowly increased to the value specified in the corresponding Camile sequence (described below). The temperature of the reactor gradually increased with the operating time of 119732.doc -375 - 200804457. The transesterification and polycondensation reactions were carried out in the same 500 ml flask. During the operation of Example 26A and Example 26B, the blades of the agitator were moved up to the top of the melt to inhibit the foam layer. The temperature/pressure/stirring rate sequence for each instance controlled by Camile software is reported in the following table. The final polymerization temperature (Pz temperature) for each of the experiments was in the range of 265 ° C to 290 ° C and is reported in Table 12. Camile sequence of Examples 26A to 26L 3 760 1 200 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 5 245 760 50 11 5 245 760 50 12 30 265 760 50 13 3 265 90 50 14 110 290 90 50 15 5 290 6 25 16 110 290 6 25 17 2 290 400 0 18 1 300 760 0 Example 26M Camile sequence to example 260: ' * 200 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 119732.doc -376- 200804457 5 1 200 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 5 245 760 50 11 3 245 375 50 12 30 245 375 50 13 3 250 20 50 14 30 250 20 50 15 3 255 5 25 16 110 255 5 25 17 3 265 1 25 18 110 265 1 25 19 2 265 400 0 20 1 265 760 0 Example 26P Camile sequential viscosity restricted sequence, low vacuum Η 1 3 200 760 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 5 245 760 50 11 3 24 5 375 50 12 30 245 375 50 13 3 250 20 50 14 30 250 20 50 15 3 255 5 25 16 110 255 5 25 17 3 265 0.2 25 18 110 265 0.2 25 19 2 265 400 0 • 377 · 119732.doc 200804457 20 1 265 760 0 Example 26Q Camile sequential viscosity restricted sequence, low vacuum 1 3 200 760 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 5 245 760 50 11 3 245 375 50 12 30 245 375 50 13 3 250 20 50 14 30 250 20 50 15 3 255 3 25 16 110 255 3 25 17 3 265 0.2 25 18 110 265 0.2 25 19 2 265 400 0 20 1 265 760 0 Camile sequence of example 26R 1 3 ______劈[V ;^ η· 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 245 760 100 10 5 260 760 50 11 3 260 375 50 -378 - 119732.doc 200804457 12 30 260 375 50 13 3 260 20 50 14 30 260 20 50 15 3 265 5 25 16 110 265 5 25 17 3 275 1 25 18 110 275 1 25 19 2 275 400 0 20 1 275 760 0 Example 27 This example was prepared based illustrate different process conditions employed in Example 26 comprising at least one thermal stabilizer, and the polyester which is the reaction product mixtures, produced with improved stability of the polyester melt fabrication process. A variety of polyesters were prepared from 1% Mo*% DMT, CHDM and TMCD in the following manner. The dimethyl esters used in this example experiment are reported in Table 14 below, with the remainder of the diols being CHMD. The DMT, CHDM and TMCD lines were identical to the source of Example 26. The catalyst was dimethyltin oxide (available from Strem Chemical Company, Batch B4058112), butyl-2-ethylhexanoate (Aldrich, Batch 06423CD, or Arkema) or butyltin oxide (Arkema). The thermal stabilizer was triphenyl ester and also had the same source as in Example 26. Phosphorus sources are pre-added with other polyester reagents unless otherwise indicated below. The cis/inverse ratio of CHDM is as described above, and the cis/inverse ratio of TMCD is reported in Table 14. Examples 27A and 27E were prepared without using TPP. Table 14 Composition and Intrinsic Viscosity of the Polyester of Example 27 Example Melt IV (Male/g) TMCD (Mole%) TMCD % cis

Sn (ppm) P (ppm) 理論值/測量值Sn (ppm) P (ppm) theoretical value / measured value

Sn/P 實際重量 比例 最終 Pz 溫度 119732.doc -379- 200804457 (°C) A 0.548 46.3 50.1 1903 無 * 290 B 0.696 45.3 49.3 1932 10/9 21.4 275 C 0.597 45.1 50.4 1992 20/18 11.1 275 D 0.547 45.6 50.4 1952 30/27 7.2 275 E 0.714 45.4 49.9 1982 無 氺 265 F 0.731 44.5 48.0 1882 30/25 7.5 265 G 0.727 44.7 48.5 2032 30/26 7.8 265 Η 0.645 44.0 51.0 552 7.5/8 6.9 265 I 0.605 43.3 48.6 552 7.5/8 6.9 265 J 0.711 46.1 48.6 1962 20/17 11.5 275 K 0.721 45.8 48.8 1932 20/17 11.4 275 1 錫來源為參-2-乙基己酸丁基錫 2 錫來源為氧化二曱基錫 3 錫來源為氧化二丁基錫 表15數據顯示可藉由調整製程條件（例如，在其他條件 中之最終聚合溫度、在反應器建立真空之速率、於真空下 時間（如下文所述））以增強聚合體熔融物之安定性。表15所 報告之熔融物液面安定性及視覺等級係依據實例26所揭示 之規格。 380- 119732.doc 200804457 表15 實例27之聚酯之性質 實例 L* a* b* 熔融物 液面 安定性 聚合體 顏色觀察 聚酯中之 泡沫％ 聚酯之 視覺等級 A 83.55 -0.93 2.44 2 淡黃色 30% 4 B 84.39 -1.48 3.89 1 顏色良好：無 黃色 29% 4 C 84.46 -0.98 1.82 1 淡黃色 21% 2 D 86.30 -0.75 1.27 1 顏色良好：無 黃色 17% 2 E 85.60 -1.20 2.68 3 黃色 38% 4 F 83.88 -0.97 1.64 1 淡黃色 12% 1 G 85.76 -0.92 2.03 1 淡黃色 12% 2 Η 84.40 -0.98 1.61 1 顏色良好：無 黃色 NM 1 I 84.88 -0.63 0.99 1 淡黃色 11% 1 J 85.01 -1.02 1.77 1 淡黃色 18% 3 K 84.13 -0.93 1.56 1 淡黃色 25% 4 NM=未測量Sn/P actual weight ratio final Pz temperature 119732.doc -379- 200804457 (°C) A 0.548 46.3 50.1 1903 no* 290 B 0.696 45.3 49.3 1932 10/9 21.4 275 C 0.597 45.1 50.4 1992 20/18 11.1 275 D 0.547 45.6 50.4 1952 30/27 7.2 275 E 0.714 45.4 49.9 1982 No 265 F 0.731 44.5 48.0 1882 30/25 7.5 265 G 0.727 44.7 48.5 2032 30/26 7.8 265 Η 0.645 44.0 51.0 552 7.5/8 6.9 265 I 0.605 43.3 48.6 552 7.5/8 6.9 265 J 0.711 46.1 48.6 1962 20/17 11.5 275 K 0.721 45.8 48.8 1932 20/17 11.4 275 1 Tin source is butyl-2-ethylhexanoate butyl tin 2 tin source is dinonyl tin oxide 3 tin The source is dibutyltin oxide. Table 15 data shows that the polymer can be enhanced by adjusting process conditions (eg, final polymerization temperature in other conditions, rate of vacuum build up in the reactor, time under vacuum (as described below)) The stability of the melt. The liquid level stability and visual rating of the melts reported in Table 15 are in accordance with the specifications disclosed in Example 26. 380- 119732.doc 200804457 Table 15 Properties of the polyester of Example 27 Example L* a* b* Liquid level stability of the melt The color of the foam observed in the polyester % The visual grade of the polyester A 83.55 -0.93 2.44 2 Light Yellow 30% 4 B 84.39 -1.48 3.89 1 Good color: no yellow 29% 4 C 84.46 -0.98 1.82 1 Light yellow 21% 2 D 86.30 -0.75 1.27 1 Good color: no yellow 17% 2 E 85.60 -1.20 2.68 3 yellow 38% 4 F 83.88 -0.97 1.64 1 Light yellow 12% 1 G 85.76 -0.92 2.03 1 Light yellow 12% 2 Η 84.40 -0.98 1.61 1 Good color: no yellow NM 1 I 84.88 -0.63 0.99 1 Light yellow 11% 1 J 85.01 -1.02 1.77 1 Light yellow 18% 3 K 84.13 -0.93 1.56 1 Light yellow 25% 4 NM=Not measured

實例27A 於500毫升圓底燒瓶中裝填0.4莫耳DMT (77.6克）、0.224 莫耳 CHDM (32.3克）、0_256 莫耳 TMCD (36.8 克）及 0.0460 克氧化二丁基錫。燒瓶配置有攪拌器及需要時可容許氮滌 氣及真空能力之聚合體頭部。將燒瓶浸沒在200 °C下之 Belmont金屬浴中，且於25 RPM下攪拌至使内含物熔解。 將攪拌增加至200 RPM，並將此等條件保持3小時1 5分 鐘。使溫度升高至220 °C，並將此等條件保持另一 30分 鐘。在20分鐘内，使溫度升高至290°C。在達到290°C之 -381 - 119732.doc 200804457 後’使壓力自大氣壓力降至〇·3之設定點（SP)，歷經15分鐘 期間。當黏度增加時，降低攪拌至最小值丨5 RPM。所測 得隶低真空為0.70 (即使SP為0.3)，且在真空下的總時間為 3 0分鐘。 此實例中其他聚酯係於裝有攪拌器及需要時可容許氮滌 氣及真空之聚合體頭部的5〇〇毫升圓底燒槪中製備。將原 料稱重加入燒瓿以進行一 〇·4莫耳的操作（聚合體重複單元 —274 克 / 莫耳）：〇·4〇〇 莫耳 dmT (77.6克）、〇·224 莫耳 CHDM (32.3克）及0.256莫耳TMCD (36.8克）、及0.112克參-2-乙基 己酸丁基錫、0.0314克氧化二甲基錫或0·0460克氧化二丁 基錫（如表14所報告）。這些數值係預設最終聚合物中有標 的濃度為200 ppm之錫金屬，且可隨其他標的濃度調整。 此實例中各聚酯的實際錫濃度係報告於表14。 在此實例中，除了兩個操作之外，其餘操作的二醇/酸 之比例為1.2/1，過量部分為2% CHDM且該20%過量部分 剩餘者為TMCD。實例27H之二醇/酸比例為l.i/i，過量部 分為TMCD。實例271之二醇/酸比例為ι·05/1，過量部分為 TMCD。將觸媒稱重加入燒瓶，固體或液體皆可。以表 所載之量將固體形式之磷酸三苯基酯稱重加入燒瓶中。實 例27K中TPP較慢才自甲醇溶液中添加。 設定點與數據收集係藉助於Camile程序控制系統。一旦 反應物被熔解，即起始攪拌，且慢慢地增加至所對應之 Carmle順序中所指定值（如下所述）。反應器之温度係隨著 操作時間逐漸增加。 119732.doc 200804457 酯交換與聚縮合反應係在同一個500毫升燒瓶中進行。 對各實例藉由Camile軟體控制之溫度/壓力/攪拌速率順序 係報告於下列表中。此實例各實驗之最終聚合溫度（Pz溫 度）係於265°C至290°C之範圍且報告於表14。 實例27B至實例27D之Camile順序 1 3 200 760 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 5 245 760 50 11 32 250 375 50 12 30 255 375 50 13 3 255 50 50 14 30 260 50 50 15 3 265 15 25 16 110 265 15 25 17 3 270 2 25 18 110 275 2 25 19 2 275 400 0 20 1 275 760 0 實例27E之Camile順序 ; 雜 ㈣嚼、命 。 ΜΙϋ^ΜΙΜϋΙΗΙΜΜΒ 1 3 200 760 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 760 100 6 0.1 200 760 200 -383 - 119732.doc 200804457 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 5 245 760 50 11 3 245 375 50 12 30 245 375 50 13 3 250 20 50 14 30 250 20 50 15 3 255 5 25 16 110 255 5 25 17 3 265 1 25 18 110 265 1 25 19 2 265 400 0 20 1 265 760 0 實例27F及實例27G之Camile順序 黏度受限制順序、低真空 1 3 200 760 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 5 245 760 50 11 3 245 375 50 12 30 245 375 50 13 3 250 20 50 14 30 250 20 50 15 3 255 5 25 16 110 255 5 25 17 3 265 0.2 25 18 110 265 0.2 25 19 2 265 400 0 20 1 265 760 0 -384- 119732.doc 200804457 實例27H及實例271之Camile順序 黏度受限制順序、低真空 —^.ί«从.」t·.二to “一从-〇 -&gt; ____________________ H 200 760 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 5 245 760 50 11 3 245 375 50 12 30 245 375 50 13 3 250 20 50 14 30 250 20 50 15 3 255 3 25 16 110 255 3 25 17 3 265 1 25 18 110 265 1 25 19 2 265 400 0 20 1 1 265 760 0 實例27J及實例27K之Camile順序 丨Y獅输 ΙΒΒΡΙΙί^ΜΒΙΙΙΜΙΒ——1 200 760 feamsi— 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 5 245 760 50 11 3 245 375 50 12 30 245 375 50 119732.doc • 385 - 200804457 13 3 250 20 50 _ 14 30 250 20 50 15 3 260 5 25 16 110 260 5 25 17 3 275 1 25 18 110 275 1 25 19 2 275 400 0 20 1 275 760 0 實例28 此實例係說明使用不同熱安定劑製備聚酯，並顯示其對 製程中聚酯熔融物之安定性的效應。 以下述方式自100莫耳％DMT及不同濃度的CHDM與 TMCD製備多種聚酯。用於此實例實驗中之TMCD莫耳％係 報告於下述表16中，其餘部分之二醇類為CHDM。DMT、 CHDM及TMCD係與實例26來源相同。觸媒為氧化二甲基 錫（得自Strem化學公司，Batch B4058112)或參-2_乙基己酸 丁基錫（Aldrich，Batch 06423CD)。熱安定劑係記載於表 16中且選自：Merpol A (得自DuPont之一種辛基酵構酸酉旨 混合物）、麟酸三乙基酿（Aldrich) 、Irgafos 168 (參（2,4-二-第三丁基苯基）填酸 g旨，Ciba Specialty Chemicals)、 Doverphos 9228 (CAS# 154862-43-8、雙（2,4-異丙苯基苯 基）季戊四醇二亞填酸自旨、Dover)、Weston 619g (CAS# 85190- 63·2，2-丙醇，1，Γ，1&quot;·氮基參-，混和3,9-雙（十八烷 基氧基）-2,4,8，10-四噁基-3,9-二磷螺[5.5]十一烷，GE SC)、三苯基氧化膦（AldHch)、磷酸三苯基酯（Aldrich或 FERRO)、NaH2P04 (Aldrich)、Zn3(P04)2 (Aldrich)及 H3P〇4 (Aldrich)。除非下述另指明，否則磷來源係與其他聚酯試 119732.doc •386· 200804457 糾述，而 劑一起預先添加。CHDM之順/反比例係如上所 TMCD之順/反比例係報告於表16 〇 表16Example 27A A 500 mL round bottom flask was charged with 0.4 Mole DMT (77.6 g), 0.224 Mohr CHDM (32.3 g), 0-256 Molex TMCD (36.8 g) and 0.0460 g of dibutyltin oxide. The flask was equipped with a stirrer and a polymer head that allowed nitrogen scrubbing and vacuum capacity when needed. The flask was immersed in a Belmont metal bath at 200 ° C and stirred at 25 RPM until the contents were melted. Stirring was increased to 200 RPM and these conditions were maintained for 3 hours and 15 minutes. Increase the temperature to 220 °C and keep these conditions for another 30 minutes. The temperature was raised to 290 ° C in 20 minutes. After reaching -290 - 119732.doc 200804457 at 290 °C, the pressure was reduced from atmospheric pressure to the set point (SP) of 〇3 for a period of 15 minutes. When the viscosity increases, reduce the agitation to a minimum of R5 RPM. The measured low vacuum was 0.70 (even if SP was 0.3) and the total time under vacuum was 30 minutes. The other polyesters in this example were prepared in a 5 liter round bottom crucible equipped with a stirrer and, if desired, a nitrogen blanket and a vacuum polymer head. The raw materials were weighed and added to the crucible for a one-fourth molar operation (polymer repeat unit - 274 g / mol): 〇·4 〇〇 m ear dmT (77.6 g), 〇·224 Mote CHDM ( 32.3 g) and 0.256 mol TMCD (36.8 g), and 0.112 g of butyltin-2-ethylhexanoate, 0.0314 g of dimethyltin oxide or 0. 0460 g of dibutyltin oxide (as reported in Table 14). These values are preset to a standard concentration of 200 ppm tin metal in the final polymer and can be adjusted with other standard concentrations. The actual tin concentration of each polyester in this example is reported in Table 14. In this example, the ratio of diol/acid was 1.2/1, the excess was 2% CHDM, and the remainder of the 20% excess was TMCD, except for the two operations. The diol/acid ratio of Example 27H was 1.i/i and the excess portion was TMCD. The diol/acid ratio of Example 271 was ι·05/1 and the excess was TMCD. The catalyst is weighed into the flask and either solid or liquid. The solid form of triphenyl phosphate was weighed into the flask in the amounts indicated in the table. In Example 27K, TPP was added slowly from the methanol solution. The setpoint and data collection system is controlled by the Camile program. Once the reactants are melted, the agitation is initiated and slowly increased to the value specified in the corresponding Carmle sequence (described below). The temperature of the reactor gradually increases with the operating time. 119732.doc 200804457 The transesterification and polycondensation reactions were carried out in the same 500 ml flask. The temperature/pressure/stirring rate sequence controlled by the Camile software for each example is reported in the following table. The final polymerization temperature (Pz temperature) for each of the experiments in this example ranged from 265 ° C to 290 ° C and is reported in Table 14. Camile sequence of Example 27B to Example 27D 1 3 200 760 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 5 245 760 50 11 32 250 375 50 12 30 255 375 50 13 3 255 50 50 14 30 260 50 50 15 3 265 15 25 16 110 265 15 25 17 3 270 2 25 18 110 275 2 25 19 2 275 400 0 20 1 275 760 0 The Camile sequence of Example 27E; Miscellaneous (four) Chew, life. ΜΙϋ^ΜΙΜϋΙΗΙΜΜΒ 1 3 200 760 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 760 100 6 0.1 200 760 200 -383 - 119732.doc 200804457 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 5 245 760 50 11 3 245 375 50 12 30 245 375 50 13 3 250 20 50 14 30 250 20 50 15 3 255 5 25 16 110 255 5 25 17 3 265 1 25 18 110 265 1 25 19 2 265 400 0 20 1 265 760 0 Example 19F and Example 27G Camile sequential viscosity restricted sequence, low vacuum 1 3 200 760 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 5 245 760 50 11 3 245 375 50 12 30 245 375 50 13 3 250 20 50 14 30 250 20 50 15 3 255 5 25 16 110 255 5 25 17 3 265 0.2 25 18 110 265 0.2 25 19 2 265 400 0 20 1 265 760 0 -384- 119732.doc 200804457 Example 27H and Example 271 Camile sequential viscosity restricted order, low vacuum—^. ί«从."t·.二to "一从-〇-&gt; ____________________ H 200 760 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 5 245 760 50 11 3 245 375 50 12 30 245 375 50 13 3 250 20 50 14 30 250 20 50 15 3 255 3 25 16 110 255 3 25 17 3 265 1 25 18 110 265 1 25 19 2 265 400 0 20 1 1 265 760 0 Example 27J and Example 27K Camile Sequence 丨Y 狮ΙΒΒΡΙΙΙΒΒΡΙΙί^ΜΒΙΙΙΜΙΒ——1 200 760 feamsi— 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 5 245 760 50 11 3 245 375 50 12 30 245 375 50 119732.doc • 385 - 200804457 13 3 250 20 50 _ 14 30 250 20 50 15 3 260 5 25 16 110 260 5 25 17 3 275 1 25 18 110 275 1 25 19 2 275 400 0 20 1 275 760 0 Example 28 This example illustrates the use of different thermal stabilizers to prepare polyesters and shows their effect on the stability of the polyester melt in the process. A variety of polyesters were prepared from 100 mole % DMT and varying concentrations of CHDM and TMCD in the following manner. The TMCD Moll % used in this example experiment is reported in Table 16 below, with the remainder of the diol being CHDM. The DMT, CHDM, and TMCD are the same sources as Example 26. The catalyst was dimethyltin oxide (available from Strem Chemical Company, Batch B4058112) or butyl-2-ethylhexanoate (Aldrich, Batch 06423CD). The thermal stabilizer is described in Table 16 and is selected from the group consisting of: Merpol A (a mixture of octyl-fermented acid from DuPont), triethyl sulphate (Aldrich), Irgafos 168 (parameter (2, 4-) Di-t-butylphenyl) acid-filled, Ciba Specialty Chemicals), Doverphos 9228 (CAS# 154862-43-8, bis(2,4-cumylphenyl)pentaerythritol dihydric acid , Dover), Weston 619g (CAS# 85190- 63·2, 2-propanol, 1, Γ, 1&quot;·N-based ginseng, mixed 3,9-bis(octadecyloxy)-2,4 , 8,10-tetraoxa-3,9-diphosphole[5.5]undecane, GE SC), triphenylphosphine oxide (AldHch), triphenyl phosphate (Aldrich or FERRO), NaH2P04 (Aldrich ), Zn3(P04)2 (Aldrich) and H3P〇4 (Aldrich). Unless otherwise indicated below, the source of phosphorus is clarified with other polyesters 119732.doc • 386. 200804457, and the agents are pre-added together. The cis/inverse ratio of CHDM is as follows. The cis/inverse ratio of TMCD is reported in Table 16 〇 Table 16

2 錫來源為氧化二甲基錫 3 錫來源為氧化二丁基錫 4 聚合體因不溶物而模糊 ^ 表17數據顯示使用不同磷來源作為熱安定劑之聚合來t 融物之安定性。此等數據顯示填酸醋類及可水解成麟酸酉曰 類之磷化合物提供安定熔融物及可接受之聚酯產物。熔融 物液面安定性及視覺等級報告於表17中，且係依據實例26 -387- 119732.doc 200804457 所揭示之規格。 表17 實例28之聚酯之性質 實例 L* a* b* 磷來源 熔融物 液面 安定性 stability 聚合體 顏色觀察 聚酯中之 泡沫％ 聚酯之 視覺等級 A 83.87 -1.09 1.61 Merpol A 1 NM NM NM B NM NM NM H3PO4 1 顏色良好：無 黃色 7% 1 C 84.84 -0.94 1.40 Merpol A 1 顏色良好：無 黃色 22% 3 D 85.86 -0.69 1.07 在EE之後添加Merpol A 1 淡黃色 21% 3 E 83.77 -1.12 1.91 磷酸三乙基酯 2 淡黃色 25% 4 F 84.05 -2.06 8.66 磷酸三乙基酯 2 褐-黃色 22% 4 G 77.63 -0.82 3.33 Irgafos 168 3 NM NM NM Η 78.68 -0.83 3.34 在EE之後添加Irgafos 168 3 褐-黃色 24% 4 I NM NM NM 無 NN 淡黃色 26% 4 J NM NM NM Doverphos 9228 NN 顏色良好：無 黃色 21% 3 K NM NM NM Doverphos 9228 NN NM NM NM L NM NM NM Weston 619g NN 顏色良好：無 黃色 21% 4 Μ NM NM NM 磷酸三苯基酯 NN 淡黃色 14% 2 N NM NM NM NN 淡黃色 23% 3 0 NM NM NM 無 NN 淡黃色 19% 2 P NM NM NM 磷酸三苯基酯 NN NM NM NM Q NM NM NM 磷酸三苯基酯 NN 顏色良好：無 黃色 10% 1 R NM NM NM NaH2P04 NN 顏色良好：無 黃色 17% 1 S NM NM NM Zn3(P〇4)2 NN 顏色良好：無 黃色 16% 2 EE=酯交換反應；NM=未測量；NN=未注意 實例R之樣品為模糊的，因此視覺等級可能已受損 -388- 119732.doc 2008044572 Tin source is dimethyltin oxide 3 Tin source is dibutyltin oxide 4 Polymer is blurred by insoluble matter ^ The data in Table 17 shows the stability of the t-melt using different phosphorus sources as the thermal stabilizer. These data show that the acid vinegar and the phosphorus compound which can be hydrolyzed to the lanthanide are provided as a stable melt and an acceptable polyester product. The liquid level stability and visual grade of the melt are reported in Table 17, and are based on the specifications disclosed in Example 26-387-119732.doc 200804457. Table 17 Properties of the polyester of Example 28 Example L* a* b* Phosphorus source melt level stability stability Polymer color observed foam % in polyester Polyester visual grade A 83.87 -1.09 1.61 Merpol A 1 NM NM NM B NM NM NM H3PO4 1 Good color: no yellow 7% 1 C 84.84 -0.94 1.40 Merpol A 1 Good color: no yellow 22% 3 D 85.86 -0.69 1.07 Add Merpol A 1 after EE Yellow 21% 3 E 83.77 -1.12 1.91 Triethyl phosphate 2 Light yellow 25% 4 F 84.05 -2.06 8.66 Triethyl phosphate 2 Brown-yellow 22% 4 G 77.63 -0.82 3.33 Irgafos 168 3 NM NM NM Η 78.68 -0.83 3.34 After EE Add Irgafos 168 3 Brown-Yellow 24% 4 I NM NM NM None NN Light yellow 26% 4 J NM NM NM Doverphos 9228 NN Good color: no yellow 21% 3 K NM NM NM Doverphos 9228 NN NM NM NM L NM NM NM Weston 619g NN Good color: no yellow 21% 4 Μ NM NM NM triphenyl phosphate NN light yellow 14% 2 N NM NM NM NN light yellow 23% 3 0 NM NM NM no NN light yellow 19% 2 P NM NM NM Triphenyl phosphate NN NM NM NM Q NM NM NM Triphenyl phosphate NN Good color: no yellow 10% 1 R NM NM NM NaH2P04 NN Good color: no yellow 17% 1 S NM NM NM Zn3(P〇4)2 NN Good color: no yellow 16% 2 EE=transesterification; NM= Not measured; NN = not paying attention to the sample of example R is ambiguous, so the visual level may have been compromised -388- 119732.doc 200804457

實例28A至實例28H 此等聚S旨係以下述方式製備。將77·6克（0.4莫耳）對苯二 甲酸二曱基酯、32.3克（0.224莫耳）1，4-環己烷二曱醇、 36.8克（0.256莫耳）2,2，4,4-四曱基-1，3-環丁二醇之混合物置 於裝有氮入口管、金屬擾拌器及短蒸館管柱之5〇〇_毫升燒 瓶中。亦將觸媒加入反應燒瓶中。觸媒種類及用量係詳述 於表16。亦將填化合物加入反應燒瓶中。此實例各實驗中 科化合物之理論及測得之用量係詳述於表16。將此燒甑置 於已被加熱至2 0 0 C之伍德氏金屬浴中。各實例之溫度/壓 力/授拌速率順序係藉由Camile軟體控制並報告於下列表 中。在一些案例中（實例28D及實例28H，其已提及，磷添 加劑係於6旨交換反應後才添加。此情形可對應至其對應 Camile順序第9階段末。Examples 28A to 28H These are intended to be prepared in the following manner. 77. 6 g (0.4 mol) of didecyl terephthalate, 32.3 g (0.224 mol) of 1,4-cyclohexanedimethanol, 36.8 g (0.256 mol) 2, 2, 4, A mixture of 4-tetradecyl-1,3-cyclobutanediol was placed in a 5 〇〇-ml flask equipped with a nitrogen inlet tube, a metal scrambler, and a short steaming column. The catalyst was also added to the reaction flask. The types and amounts of catalysts are detailed in Table 16. The compound was also added to the reaction flask. The theory and measured amounts of the compounds in each of the experiments in this example are detailed in Table 16. The crucible was placed in a Wood's metal bath that had been heated to 200 ° C. The temperature/pressure/intake rate sequences for each example are controlled by Camile software and reported in the following table. In some cases (Example 28D and Example 28H, it has been mentioned that the phosphorus additive is added after the 6 exchange reaction. This situation may correspond to the end of stage 9 of its corresponding Camile sequence.

實例281至實例28S 此4聚酯係以下述方式製備。將77 6克（〇·4莫耳）對苯二 甲酸二甲基酯、33.31克（0.231莫耳）1，4_環己烷二甲酵、 35.91克（〇·249莫耳）2,2,4,4-四甲基_l53_環丁二醇之混合物 置於裝有氮入口官、金屬攪拌器及短蒸餾管柱之5〇〇•毫升 燒瓶中。亦將觸媒加入反應燒瓶中。觸媒種類及用量係詳 述於表16。以表16所載之用量（其包含各實驗中磷化合物 之理論及測得之用量），將磷來源稱重加入反應燒瓶中。 將此燒瓶置於已被加熱至20(rc之伍德氏金屬浴中。各實 例之/皿度/壓力/授拌速率順序係冑由軟體控制並報 告於下列表中。 119732.doc -389- 200804457 此實例所有實驗中，二醇/酸之比例為1.2/1，過量部分 為2% CHDM且該20%過量部分剩餘者為TMCD。將觸媒稱 重加入燒瓶，固體或液體皆可。 設定點與數據收集係藉助於Camile程序控制系統。一旦 反應物被熔解，即起始攪拌，且慢慢地增加至所對應之 Camile順序中所指定值（如下所述）。反應器之溫度係隨著 操作時間逐漸增加。 各實例之溫度/壓力/攪拌速率順序係藉由Camile軟體控 制並報告於下列表中。此實例各實驗之最終聚合溫度（Pz 溫度）係265°C。 實例28A及實例28B之Camile順序 黏度受限制順序 厂·1/ ： 1 3 200 760 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 0.1 220 760 200 11 30 220 760 200 12 5 245 760 50 13 3 245 375 50 14 30 245 375 50 15 3 250 20 50 16 30 250 20 50 17 3 255 3 25 18 110 255 3 25 119732.doc •390- 200804457 19 3 265 1 25 20 110 265 1 25 實例28C至實例28S之Camile順序 黏度受限制順序、低真空 麟 - …獅驗_ 1 : 「' ^^二7 麵 : 1 3 200 760 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 1 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 5 245 760 50 11 3 245 375 50 12 30 245 375 50 13 3 250 20 50 14 30 250 20 50 15 3 255 3 25 16 110 255 3 25 17 3 265 1 25 18 110 265 1 25 19 2 265 400 0 20 1 265 760 0 實例29 此實例係說明以試驗工廠規模製備包含至少一種熱安定 劑、其反應產物及其混合物之聚酯，產生在製程中具有改 良的安定性之聚S旨溶融物。 以下述方式自100莫耳％DMT、CHDM及TMCD製備多種 聚酯。用於此實例實驗中之丁]\4€0莫耳％係報告於下述表 18中，其餘部分之二醇類為CHDM。DMT、CHDM及 -391 - 119732.doc 200804457 TMCD係與實例26來源相同。觸媒為氧化二甲基錫（得自 Strem化學公司，Batch B4058112)或參-2-乙基己酸丁基錫 (Aldrich，Batch 06423CD)。熱安定劑為磷酸三苯基酯 (TPP)(Aldr*ich)。除非下述另指明，否則磷來源係與其他 聚酯試劑一起預先添加。CHDM之順/反比例係如上所述， 而TMCD之順/反比例係報告於表1 8。 表18 實例29之聚酯之組成及固有黏度 實例 熔融IV (公合/克） TMCD (莫耳％) TMCD %順式 Sn (ppm) P (ppm) 理論值 L* a* b* A 0.553 46.1 45.8 2282 300 80.50 -1.51 4.27 B 0.620 46.0 46.0 2041 100 83.42 -1.18 4.92 C 0.613 45.1 46.3 1931 100 77.60 -1.80 4.85 D 0.624 45.4 46.2 2092 100 79.69 -1.71 6.45 1 錫來源為參-2-乙基己酸丁基錫 2 錫來源為氧化二甲基錫Example 281 to Example 28S This 4 polyester was prepared in the following manner. 77 6 g (〇·4 mol) of dimethyl terephthalate, 33.31 g (0.231 mol) 1,4_cyclohexane dimethoxyl, 35.91 g (〇·249 mol) 2,2 A mixture of 4,4-tetramethyl-l53-cyclobutanediol was placed in a 5 liter flask containing a nitrogen inlet, a metal stirrer, and a short distillation column. The catalyst was also added to the reaction flask. The types and amounts of catalysts are detailed in Table 16. The phosphorus source was weighed into the reaction flask in the amounts shown in Table 16, which included the theory of the phosphorus compound in each experiment and the amount measured. The flask was placed in a Wood's metal bath that had been heated to 20 (rc). The example/dish/pressure/intake rate sequence of each example was controlled by software and reported in the following table. 119732.doc -389- 200804457 In all the experiments in this example, the ratio of diol/acid was 1.2/1, the excess was 2% CHDM and the remainder of the 20% excess was TMCD. The catalyst was weighed into the flask, either solid or liquid. The point and data collection system controls the system by means of the Camile program. Once the reactants are melted, the agitation is initiated and slowly increased to the value specified in the corresponding Camile sequence (described below). The temperature of the reactor is The operating time is gradually increased. The temperature/pressure/stirring rate sequence for each example is controlled by Camile software and reported in the following table. The final polymerization temperature (Pz temperature) for each example of this example is 265 ° C. Example 28A and Examples 28B Camile Order Viscosity Restricted Order Plant · 1 : 1 3 200 760 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 0.1 220 760 200 11 30 220 760 200 12 5 245 760 50 13 3 245 375 50 14 30 245 375 50 15 3 250 20 50 16 30 250 20 50 17 3 255 3 25 18 110 255 3 25 119732. Doc •390- 200804457 19 3 265 1 25 20 110 265 1 25 Example 28C to Example 28S Camile Order Viscosity Restricted Order, Low Vacuum Lin - ... Lion Test _ 1 : "' ^^二 7面: 1 3 200 760 0 2 0.1 200 760 25 3 2 200 760 25 4 0.1 200 760 100 5 1 200 1 760 100 6 0.1 200 760 200 7 90 200 760 200 8 0.1 210 760 200 9 120 210 760 200 10 5 245 760 50 11 3 245 375 50 12 30 245 375 50 13 3 250 20 50 14 30 250 20 50 15 3 255 3 25 16 110 255 3 25 17 3 265 1 25 18 110 265 1 25 19 2 265 400 0 20 1 265 760 0 Example 29 The examples illustrate the preparation of a polyester comprising at least one thermal stabilizer, its reaction products, and mixtures thereof on a pilot plant scale to produce a poly-smelt that has improved stability in the process. A variety of polyesters were prepared from 100 mole % DMT, CHDM and TMCD in the following manner. The glycerol used in this example experiment is reported in Table 18 below, and the remaining diols are CHDM. DMT, CHDM, and -391 - 119732.doc 200804457 The TMCD is the same source as Example 26. The catalyst was dimethyltin oxide (available from Strem Chemical Company, Batch B4058112) or butyl-2-ethylhexanoate (Aldrich, Batch 06423CD). The heat stabilizer is triphenyl phosphate (TPP) (Aldr*ich). Phosphorus sources are pre-added with other polyester reagents unless otherwise indicated below. The cis/inverse ratio of CHDM is as described above, and the cis/inverse ratio of TMCD is reported in Table 18. Table 18 Composition and Intrinsic Viscosity of the Polyester of Example 29 Example Melt IV (Male/g) TMCD (% by mole) TMCD % cis-Sn (ppm) P (ppm) Theoretical value L* a* b* A 0.553 46.1 45.8 2282 300 80.50 -1.51 4.27 B 0.620 46.0 46.0 2041 100 83.42 -1.18 4.92 C 0.613 45.1 46.3 1931 100 77.60 -1.80 4.85 D 0.624 45.4 46.2 2092 100 79.69 -1.71 6.45 1 Tin source is butyl 2-ethylhexanoate 2 tin source is dimethyltin oxide

實例29A 在200 ppm氧化二甲基錫作為錫觸媒及300 ppm磷酸三苯 基酯（16.35克）存在下，將84.96磅（198.83克-莫耳）對苯二甲 酸二甲基酯、35.3 8磅（111.54克-莫耳）1，4-環己烷二甲醇及 40.3 0磅（127.06克-莫耳）2,2,4,4-四甲基-1,3-環丁二醇一起 反應。在氮滌氣下，在裝配有冷凝塔、真空系統及 HELICONE-型攪拌器之74-加侖不鐵鋼壓力瓶中進行反 應。使攪拌器在25 RPM運作，將反應混合物溫度增加至 250°C及將壓力增加至20 psig。反應混合物在250°C及20 119732.doc -392- 200804457 psig壓力下維持2小時。壓力隨後以3 psig/分鐘速率降低至 0 psig。隨後將攪拌器之速度降低至15 rPm，且隨後將反 應混合物溫度增加至27(TC及將壓力降低至£1毫米Hg。將 反應混合物維持在270它及£1毫米1^之壓力，歷時3.75小 時。隨後使用氮氣將壓力瓶之壓力增加至1大氣壓。隨後 使用擠壓模具自該壓力瓶擠壓該模製聚合體。在該經擠壓 聚合物絲束製成錠塊後，將其推入冷水浴中以將其冷卻。 聚合體具有0.553公合/克之固有黏度。NMR分析顯示該聚 合體係由53.9莫耳％1，4-環己烷二甲醇基團及461莫耳0/〇 2,2,4,4-四曱基-1，3·環丁二醇基團組成。該聚合體具有顏 色值為：L* = 80.50、a*=-1.51 及 b*=4.27。 實例29B至實例29D係根據類似實例29A之方式製備，具 有表18所揭示之組成。 實例29E代表得自伊士曼化學公司之Eastar dn〇〇i ,具 有0.73公合/克之固有黏度且名義上組成為ι〇〇莫耳％對苯 二曱酸殘基、62莫耳％ CHDM殘基及38莫耳％乙二醇殘 基。實例29F代表得自Bayer之Makrolon 2608，名義上組成 為100莫耳％雙酚A殘基及1〇〇莫耳％碳酸二苯基酯。實例 29G代表一伊士曼化學公司聚酯，其名義上組成為1〇〇莫耳 %對苯二甲酸殘基、55莫耳〇/〇 CHDM殘基及45莫耳％1^(：£) 殘基。實例29H代表得自伊士曼化學公司之PEtg Eastar 6763，名義上組成為100莫耳％對苯二甲酸、η莫耳％環己 烷二甲醇（CHDM)及69莫耳％乙二醇。 實例291 119732.doc -393 · 200804457 實例291之聚酯為10種不同聚酯之摻混物，其各自以下 述方式製備。在200 ppm錫觸媒（如參（2-乙基己酸）丁基錫） 存在下，將84.96磅（198.83克-莫耳）對苯二甲酸二曱基酯與 50.45至51.46磅（159.06至162.24克-莫耳，視各批料而 定）1，4-環己烷二甲醇及24_22至31_53磅（76·3 6至99.41克-莫 耳，亦視各批料而定）2,2,4,4-四甲基-1，3-環丁二醇反應。 在氮滌氣下，在裝配有冷凝塔、真空系統及HELICONE-型 攪拌器之74-加侖不鏽鋼壓力瓶中進行反應，以提供1β2/1 至1.3/1之二醇/對苯二甲酸二曱基酯比例。使攪拌器在25 RPM運作，將反應混合物溫度增加至250°C及將壓力增加 至20 psig。反應混合物在250°C及20 psig壓力下維持2小 時。壓力隨後以3 psig/分鐘速率降低至〇 pSig。隨後將攪 拌器之速度降低至1 5 RPM，且隨後將反應混合物溫度增 加至260-270C及將壓力降低至90毫米Hg。將反應混合物 維持在260-270°C及90毫米Hg之壓力，歷時1小時。隨後將 反應混合物溫度增加至275-290°C及將壓力降低至$1毫米 Hg。將反應混合物維持在275-290°C及S1毫米Hg之壓力， 歷時1.5-3小時，以完成聚縮合反應階段。隨後使用氮氣將 壓力瓶之壓力增加至1大氣壓。隨後自該壓力瓶擠壓該模 製聚合體入冷水浴中。研磨該冷卻、經擠製聚合體，使其 通過6宅米筛網。 使用上述步驟製備10個獨立批料。下列表包含由該丨0個 批料所得之NMR組成、IV值及顏色值。最終之聚合物摻混 物具有0.63公合/克之IV、1〇〇莫耳％對苯二曱酸殘基、及 119732.doc -394- 200804457 標的之20莫耳％ TMCD殘基與80莫耳％CHDM殘基。 批料 標的組成 % TMCD 由NMR分析 IV (公合/克） 顏色 L* b* 1 20% TMCD; 80% CHDM 16.8 0.665 73.95 -0.61 10.31 2 20% TMCD; 80% CHDM 17.5 0.691 70.48 -0.49 10.68 3 20% TMCD; 80% CHDM 16.4 0.650 71.14 -0.68 10.16 4 20% TMCD; 80% CHDM 22.2 0.685 79.80 -1.80 7.43 5 20% TMCD; 80% CHDM 24.9 0.668 74.47 -1.11 7.83 6 20% TMCD; 80% CHDM 22.6 0.705 67.94 1.28 26.91 7 20% TMCD; 80% CHDM 22.1 0.627 72.43 0.41 22.68 8 20% TMCD; 80% CHDM 25.3 0.712 76.70 0.41 10.73 9 20% TMCD; 80% CHDM 23.5 0.697 74.21 0.79 15.23 10 20% TMCD; 80% CHDM 25.3 0.724 73.55 -0.61 9.52 在Toyo 110射出成型模壓機中，自表18之聚酯製備板塊 (4英吋χ4英吋xl/8英吋厚）。將各聚酯之錠塊饋入模壓機中 並加熱至表19所報告之溫度。該模製聚合體在射出之前於 119732.doc -395 - 200804457 套筒之停留時間亦報告於表19中。一旦該部件已有改a 卻’可進行視覺分析且紀錄在該射出成型模壓方法中所： 生之展曲（splay)。 表19之數據顯示模壓條件對射出成型模壓板塊（由表18 之聚酯製得）中展曲（splay)之生成的效應。 表19 在由實例29之聚酯製得之模製部件中的展曲（splay)生成 溫度設定點 °F 停留時間， 分鐘 在由表18之聚酯製得之部件中的展曲(splay) A B C D E F G 520 0.47 0 0 0 0 0 0 0 (271°C) 1.02 Π 0 0 0 0 0 0 0 1.59 0 0 0 0 0 0 0 2.7 0 0 0 0 0 0 0 4.94 0 0 0 0 0 0 0 9.4 0 0 0 0 o 1 0 1 550 0.47 0 0 0 0 0 0 0 (288°C) 1.02~1 0 0 0 0 0 0 0 1.59 0 0 0 0 0 0 0 2.7 0 0 0 0 0 0 0 4.94 0 0 0 0 0 0 1 9.4 0 1 1 1 0 0 2-3 580 0.47 0 0 0 0 0 0 0 (30°C) 1.02 0 0 0 0 0 0 0 1.59 0 一 0 0 0 0 0 1 2.7 0 0 1 0 0 0 1-2 4.94 0 1-2 1-2 1-2 0 0 2-3 9.4 1-2 2-3 2-3 2-3 1-2 0 3 610 0.47 0 0 0 0 ΝΑ ΝΑ ΝΑ (321°C) 1.02 0 0 0 0 ΝΑ ΝΑ ΝΑ 1.59 0 0 0 「0 ΝΑ ΝΑ ΝΑ 2.7 0 1-2 1-2 1-2 ΝΑ ΝΑ ΝΑ 4.94 1-3 2·3 2·3 2-3 ΝΑ ΝΑ ΝΑ 9.4 3 3 3 3 ΝΑ ΝΑ ΝΑ -396- 119732.doc 200804457 曲展（Splay)級別：無（0)，輕微（1)，中度（2)，重度（3); NA=不可取得 表20中數據顯示由表18之聚酯製得之薄膜之品質。 在1.5” Killion擠壓機上使用一通用螺桿擠壓聚合體。 聚合體於572°F(300°C)及527°F(275°C)之溫度下擠壓。在各 聚合體於572°F之擠壓中，使用下述擠壓機條件： 樣品 Zone Temp 模具 溫度 連接器 溫度 夾環 溫度 熔融物 溫度 壓力 (PSI) 速度 (RPM) 冷輥速度 (RPM) 1 572 572 572 572 612 1200 70 4.3 2 572 572 572 572 619 1450 35 2.2 3 572 572 572 572 618 2500 105 7.2 在各聚合體於527°F之擠壓中，使用下述擠壓機條件： 樣品 Zone Temp 模具 溫度 連接器 溫度 夾環 溫度 熔融物 溫度 壓力 (PSI) 速度 (RPM) 冷輥速度 (RPM) 1 527 527 527 527 569 1600 70 4.3 2 527 527 527 527 565 900 35 2.3 3 527 527 527 527 571 2200 105 7.2 表20 由實例29聚酯製得之薄膜的品質 擠壓條件 實例 A B C D H I 275〇C：35RPM 1 2 2 2 1 4 275〇C ； 70 RPM 1 2 2 2 1 3 275〇C ； 105 RPM 1 1 2 2 1 3 300〇C：35RPM 2 3 3 3 1 4 300°C ； 70 RPM 1 2 3 2 1 4 300°C ； 105 RPM 1 2 2 1 1 4 -397- 119732.doc 200804457 級別關鍵 級別 良好薄膜品質；未觀察到視覺可見之氣 泡存在於模具或熔融物儲器中；良好薄 膜，難以憑視覺偵測出氣泡。 1 良好薄膜品質；偶爾觀察到氣泡自模具 中離開；薄膜中之氣泡較易以視覺偵 測，但量稀少。 2 中等薄膜品質；易見到氣泡自模具口離 開且在已完成之薄膜中氣泡是非常明顯 的。 3 非常差的薄膜品質；氣泡於熔融物儲器 中是明顯的且存在於模具口；非常差的 顏色 4 於上文有關聯實施例中數據之比較，可清楚地明瞭本發 明之聚酯提供勝過市購可得聚酯之優點為：在聚酯製造及 加工系統中相關之起氣泡、展曲（splaying)、顏色產生、起 泡沫、氣體脫離及無規律熔融物液面中至少一者。 本發明已詳細參考本文中所揭示之具體實施例加以描 述，但應明瞭的是，變型與修正可在本發明之精神與範圍 内達成。 119732.doc 398-Example 29A 84.96 lbs (198.83 g-mole) of dimethyl terephthalate, 35.3 8 in the presence of 200 ppm of dimethyltin oxide as a tin catalyst and 300 ppm of triphenyl phosphate (16.35 g). Pounds (111.54 g-mole) of 1,4-cyclohexanedimethanol and 40.3 0 lbs (127.06 g-mole) of 2,2,4,4-tetramethyl-1,3-cyclobutanediol . The reaction was carried out in a 74-gallon non-ferrous steel pressure bottle equipped with a condenser, a vacuum system and a HELICONE-type stirrer under nitrogen scrubbing. The stirrer was operated at 25 RPM, the reaction mixture temperature was increased to 250 ° C and the pressure was increased to 20 psig. The reaction mixture was maintained at 250 ° C and 20 119732.doc -392 - 200804457 psig pressure for 2 hours. The pressure is then reduced to 0 psig at a rate of 3 psig/min. The speed of the stirrer was then reduced to 15 rPm, and then the temperature of the reaction mixture was increased to 27 (TC and the pressure was reduced to £1 mm Hg. The reaction mixture was maintained at 270 it and a pressure of £1 mm for 3.75. The pressure of the pressure bottle was then increased to 1 atm using nitrogen gas. The molded polymer was then extruded from the pressure bottle using an extrusion die. After the extruded polymer tow was made into an ingot, it was pushed. The mixture was cooled in a cold water bath. The polymer had an intrinsic viscosity of 0.553 metric/g. NMR analysis showed that the polymerization system consisted of 53.9 mol% of 1,4-cyclohexanedimethanol groups and 461 mol/0. , 2,4,4-tetradecyl-1,3·cyclobutanediol group composition. The polymer has color values: L* = 80.50, a*=-1.51 and b*=4.27. Example 29B to Example 29D was prepared in a similar manner to Example 29A, having the composition disclosed in Table 18. Example 29E represents Eastar dn〇〇i from Eastman Chemical Company having an intrinsic viscosity of 0.73 com/g and nominally ι 〇〇mol % terephthalic acid residue, 62 mole % CHDM residue and 38 mole % ethylene glycol Example 29F represents Makrolon 2608 from Bayer, nominally composed of 100 mole % bisphenol A residue and 1 mole % diphenyl carbonate. Example 29G represents an Eastman Chemical Company polyester, Its nominal composition is 1 mole % terephthalic acid residue, 55 mole 〇 / 〇 CHDM residue and 45 mole % 1 ^ (: £) residue. Example 29H represents from Eastman Chemical The company's PEtg Eastar 6763, nominally composed of 100 mole % terephthalic acid, η mol % cyclohexane dimethanol (CHDM) and 69 mol % ethylene glycol. Example 291 119732.doc -393 · 200804457 Examples The polyester of 291 is a blend of 10 different polyesters, each of which is prepared in the following manner: 84.96 lbs (198.83 g) in the presence of 200 ppm tin catalyst (e.g., butyl (2-ethylhexanoate)) - Molar) Didecyl terephthalate with 50.45 to 51.46 lbs (159.06 to 162.24 g-mol, depending on the batch) 1,4-cyclohexanedimethanol and 24_22 to 31-53 lbs (76· 3 6 to 99.41 g-mole, depending on the batch, 2,2,4,4-tetramethyl-1,3-cyclobutanediol. Under nitrogen scrubbing, equipped with a condensation tower The vacuum system and the HELICONE-type stirrer were reacted in a 74-gallon stainless steel pressure bottle to provide a diol/di-terephthalate ratio of 1β2/1 to 1.3/1. The stirrer was operated at 25 RPM. The temperature of the reaction mixture was increased to 250 ° C and the pressure was increased to 20 psig. The reaction mixture was maintained at 250 ° C and 20 psig for 2 hours. The pressure is then reduced to 〇 pSig at a rate of 3 psig/min. The speed of the stirrer was then reduced to 15 RPM and the temperature of the reaction mixture was then increased to 260-270 C and the pressure was reduced to 90 mm Hg. The reaction mixture was maintained at a pressure of 260-270 ° C and a pressure of 90 mm Hg for 1 hour. The temperature of the reaction mixture was then increased to 275-290 ° C and the pressure was reduced to $ 1 mm Hg. The reaction mixture was maintained at a pressure of 275-290 ° C and a pressure of S1 mm Hg for 1.5-3 hours to complete the polycondensation reaction stage. Nitrogen gas was then used to increase the pressure in the pressure bottle to 1 atmosphere. The molding polymer is then extruded from the pressure bottle into a cold water bath. The cooled, extruded polymer is ground and passed through a 6-mesh screen. Ten separate batches were prepared using the procedure described above. The following list contains the NMR composition, IV values, and color values obtained from the 丨 0 batches. The final polymer blend has 0.63 metric/gram IV, 1 〇〇 mole % terephthalic acid residue, and 119732.doc -394-200804457 of 20 mole % TMCD residue with 80 moles %CHDM residue. Composition of batch batch % TMCD by NMR analysis IV (combined / gram) Color L* b* 1 20% TMCD; 80% CHDM 16.8 0.665 73.95 -0.61 10.31 2 20% TMCD; 80% CHDM 17.5 0.691 70.48 -0.49 10.68 3 20% TMCD; 80% CHDM 16.4 0.650 71.14 -0.68 10.16 4 20% TMCD; 80% CHDM 22.2 0.685 79.80 -1.80 7.43 5 20% TMCD; 80% CHDM 24.9 0.668 74.47 -1.11 7.83 6 20% TMCD; 80% CHDM 22.6 0.705 67.94 1.28 26.91 7 20% TMCD; 80% CHDM 22.1 0.627 72.43 0.41 22.68 8 20% TMCD; 80% CHDM 25.3 0.712 76.70 0.41 10.73 9 20% TMCD; 80% CHDM 23.5 0.697 74.21 0.79 15.23 10 20% TMCD; 80% CHDM 25.3 0.724 73.55 -0.61 9.52 In the Toyo 110 injection molding machine, the panel was prepared from the polyester of Table 18 (4 inches 4 inches x 8 inches thick). The ingots of each polyester were fed into a molding press and heated to the temperatures reported in Table 19. The residence time of the molded polymer at 119732.doc -395 - 200804457 sleeve prior to injection is also reported in Table 19. Once the part has been modified, it can be visually analyzed and recorded in the injection molding method: splay. The data in Table 19 shows the effect of molding conditions on the formation of splay in injection molded molded panels (made from the polyester of Table 18). Table 19 Splay generation temperature set point in the molded part made of the polyester of Example 29 °F Residence time, minutes of splay in the parts made from the polyester of Table 18. ABCDEFG 520 0.47 0 0 0 0 0 0 0 (271°C) 1.02 Π 0 0 0 0 0 0 0 1.59 0 0 0 0 0 0 0 2.7 0 0 0 0 0 0 0 4.94 0 0 0 0 0 0 9.4 0 0 0 0 o 1 0 1 550 0.47 0 0 0 0 0 0 0 (288°C) 1.02~1 0 0 0 0 0 0 0 1.59 0 0 0 0 0 0 0 2.7 0 0 0 0 0 0 0 4.94 0 0 0 0 0 0 1 9.4 0 1 1 1 0 0 2-3 580 0.47 0 0 0 0 0 0 0 (30°C) 1.02 0 0 0 0 0 0 0 1.59 0 A 0 0 0 0 0 1 2.7 0 0 1 0 0 0 1-2 4.94 0 1-2 1-2 1-2 0 0 2-3 9.4 1-2 2-3 2-3 2-3 1-2 0 3 610 0.47 0 0 0 0 ΝΑ ΝΑ ΝΑ ( 321°C) 1.02 0 0 0 0 ΝΑ ΝΑ ΝΑ 1.59 0 0 0 ”0 ΝΑ ΝΑ ΝΑ 2.7 0 1-2 1-2 1-2 ΝΑ ΝΑ ΝΑ 4.94 1-3 2·3 2·3 2-3 ΝΑ ΝΑ 9.4 9.4 3 3 3 3 ΝΑ ΝΑ ΝΑ -396- 119732.doc 200804457 Splay level: none (0), slight (1), moderate (2), severe (3); NA=not available Medium data It illustrates using a general purpose screw obtained by the quality of the polyester film of the table 18 on 1.5 "Killion Extruder polymer. The polymer was extruded at temperatures of 572 °F (300 °C) and 527 °F (275 °C). In the extrusion of each polymer at 572 °F, the following extruder conditions were used: Sample Zone Temp Mold Temperature Connector Temperature Clamping Ring Temperature Molten Material Temperature Pressure (PSI) Speed (RPM) Cold Roll Speed (RPM) 1 572 572 572 572 612 1200 70 4.3 2 572 572 572 572 619 1450 35 2.2 3 572 572 572 572 618 2500 105 7.2 In the extrusion of each polymer at 527 °F, the following extruder conditions were used: Sample Zone Temp Mold temperature connector temperature clamp ring temperature melt temperature pressure (PSI) speed (RPM) cold roll speed (RPM) 1 527 527 527 527 569 1600 70 4.3 2 527 527 527 527 565 900 35 2.3 3 527 527 527 527 571 2200 105 7.2 Table 20 Examples of quality extrusion conditions for films made from the polyester of Example 29 ABCDHI 275〇C: 35RPM 1 2 2 2 1 4 275〇C; 70 RPM 1 2 2 2 1 3 275〇C; 105 RPM 1 1 2 2 1 3 300〇C: 35RPM 2 3 3 3 1 4 300°C ; 70 RPM 1 2 3 2 1 4 300°C ; 105 RPM 1 2 2 1 1 4 -397- 119732.doc 200804457 Level of key level Good film quality; no visually visible bubbles are present in the mold or melt reservoir In the device; good film, it is difficult to detect bubbles by vision. 1 Good film quality; occasionally it is observed that bubbles leave the mold; the bubbles in the film are easier to visually detect, but the amount is scarce. 2 Medium film quality; it is easy to see bubbles coming out of the die and the bubbles are very noticeable in the finished film. 3 very poor film quality; bubbles are evident in the melt reservoir and are present at the die opening; very poor color 4 compared to the data in the related examples above, it is clear that the polyester of the present invention provides The advantages over commercially available polyesters are: at least one of bubble, splaying, color generation, foaming, gas detachment, and irregular melt levels associated with polyester manufacturing and processing systems. . The present invention has been described in detail with reference to the specific embodiments disclosed herein, and it should be understood that modifications and modifications may be made within the spirit and scope of the invention. 119732.doc 398-

Claims (1)

200804457 十、申請專利範圍： l 一種製造至少一種聚酿 # 心万去，其包含下列步驟： ⑴在選自150至250〇C之$ &gt;丨、、垃也Ώ &lt;至夕一溫度及選自〇至75 psig之 至J 力下加勒4 、、曰人*1/ 丄 …、，吧合物，其中該混合物包含： (Μ —叛酸成份，其包含： 1) 70至100莫耳％之對苯二甲酸殘基； 1〇 〇至3〇莫耳％之芳族二羧酸殘基，具有至高20 個碳原子；及200804457 X. Patent application scope: l One type of manufacturing at least one type of brewing, which comprises the following steps: (1) at a temperature selected from the group consisting of 150 to 250 〇C, 垃, 垃 Ώ &lt; From 〇 to 75 psig to J force under Galle 4, 曰人*1/ 丄..., bar compound, wherein the mixture contains: (Μ - tickic acid composition, which contains: 1) 70 to 100 % terephthalic acid residue; 1 〇〇 to 3 〇 mol% of an aromatic dicarboxylic acid residue having up to 20 carbon atoms; ill) 0至10莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b)二醇成份，其包含： 1) 1至99莫耳％之2,2,4,4·四甲基-1，3_環丁二醇 殘基；及 1〇 1至99莫耳％之環己烷二甲醇殘基； 其中步驟（I)中加入之該二醇成份/二羧酸成份之莫耳 比例為 1.0-1.5/1.0 ; 其中步驟（I)中之混合物係在下列物質之存在下加 熱·（1)包含至少一種錫化合物之至少一種催化劑， 及’視需要，至少一種選自鈦、鎵、辞、銻、錄、 錳、鎂、鍺、鋰、鋁化合物及鋁化合物與氫氧化鋰 或氫氧化鈉之催化劑；及（ii)至少一種熱穩定劑，其 係選自至少一種磷化合物、其反應產物及其混合 物； (II)將步驟（I)之產物於230至320°C之溫度及至少一選 119732.doc 200804457 從步驟（I)之最終壓力至0·02托（絕對壓力）範圍内 之壓力下加熱1至6小時，以形成最終聚_ ; 其中該最終聚酯之二羧酸成份之總莫耳。/〇為1〇〇莫耳0/〇， 且該最終聚酯之二醇成份之總莫耳％為1〇〇莫耳％;其中 當在60/40 (重量/重量）酚/四氯乙烷中，於〇.25克/5〇毫升 之濃度下，在25°C下測定時，該最終聚酯之固有黏度為 0.35至1.2公合/克；且其中該最終聚酯具有85至2〇〇。(：之 Tg 〇 2· —種製造至少一種有用於本發明之聚酯之方法，其包含 下列步驟： (I)在選自150至250 °C之至少一溫度及選自〇至75 pSig之 至少一壓力下加熱一混合物，其中該混合物包含： (a) 二羧酸成份，其包含·· i) 70至100莫耳〇/0之對苯二曱酸殘基； ii) 0至30莫耳％之芳族二羧酸殘基，具有至高2〇 個碳原子；及 iii) o至1〇莫耳％之脂族二羧酸殘基，具有至高16 個碳原子；與 (b) 二醇成份，其包含： Ο 1至99莫耳〇/0之2,2,4,4-四曱基環丁二醇 殘基；及 ii) 1至99莫耳％之環己烷二甲醇殘基； 其中步驟⑴中加人之該二醇成份/二叛酸成份之莫耳 比例為 1·(Μ·5/1.〇 ; 119732.doc 200804457 其中步驟（i)中之混合物係在下列物質之存在下加 熱：（i)包含至少一種錫化合物之至少一種催化劑， 及，視需要，至少一種選自鈦、鎵、鋅、銻、始、 短、鎂、鍺、鋰、鋁化合物及鋁化合物與氫氧化鋰 或氫氧化鈉之催化劑； (II)將步驟（I)之產物於230至320°c之溫度、至少一選自 從步驟（I)之最終壓力至〇·〇2托（絕對壓力）範圍内 之壓力及至少一種選自至少一種磷化合物、其反應 產物及其混合物之熱穩定劑之存在下加熱1至6小 時； 其中該最終聚酯之二魏酸成份之總莫耳。/。為1⑼莫耳％， 且该最終聚酯之二醇成份之總莫耳％為1 〇〇莫耳％ ;其中 當在60/40 (重量/重量）酚/四氣乙烷中，於〇·25克/50毫升 之濃度下，在25°C下測定時，該最終聚酯之固有黏度為 〇·35至1.2公合/克；且其中該最終聚酯具有85至2〇〇。〇之 Tg。 3 ·如睛求項1至2中任一項之方法，其中該至少一種熱穩定 劑係選自至少下列一種物質··二亞磷酸酯類、磷酸鹽 類、氧化膦類及混合芳基燒基亞雄酸酯類。 4·如叫求項丨至2中任一項之方法，其中該至少一種熱穩定 劑係選自至少下列一種物質：二亞磷酸酯類。 5.如明求項1至2中任-項之方法，其中該至少一種熱穩定 d係選自至少一種二亞磷酸酯，其包括2,4,8,10-四噁 基_3,9-二磷螺[5.5]十一烷結構。 119732.doc 200804457 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 如》月求項1至2中任一項之方法’其中該至少一種熱穩定 劑係選自至少一種氧化膦。 如明求項1至2中任一項之方法，其中該至少一種熱穩定 劑係選自至少-種混合芳基燒基亞填酸醋。 如前述請求項中任-項之方法，其中該至少—種熱穩定 劑之存在量以聚酯總重量計係約i ppm至約5〇〇〇 ppm。 如前述請求項中任e J苜夕士、+ Τ 1貝之方法，其中該至少一種熱穩定 劑之存在量以聚6旨總重量計係約5() ppm至約3刪ppm。 如前述請求項中任一Jf $ 士、+ ., T 1貝之方法，其中該至少一種熱穩定 劑之存在量以聚S旨總重量計係約i㈣至約⑽ppm。 如前述請求項中任-項之方法，其中該聚醋之固有黏度 為0.35至1公合/克。 如前述請求項中任4之方法，其巾該㈣之固有黏度 為0.35至0.75公合/克。 如前述請求項中任一項之t^ t 、 T 貝之方法，其中該聚酯之固有黏度 為0.50至1.2公合/克。 如前述請求項中任一項之t、、t 貝^方去’其中該聚酯之固有黏度 為〇·50至0.75公合/克。 其中該聚酯之固有黏度 ，其中該聚酯具有85至 ，其中該聚酯具有85至 如前述請求項中任一項之方法， 為〇·55至0.75公合/克。 如前述請求項中任一項之方法 130°C 之 Tg。 如前述請求項中任一項之方法 120°C 之 Tg。 119732.doc 200804457 其中該聚酯具有95至 其中該聚酯具有95至 其中該聚酯具有95至 其中該聚酯具有100至 其中該聚酯具有100至 其中該聚酯具有100至 其中該聚酯具有100至 其中該聚酯具有100至 其中該聚酯之二醇成份 ，3-環丁二醇殘基與95至 18·如前述請求項中任一項之方法 125°C 之 Tg。 19·如前述請求項中任一項之方法 120〇C 之 Tg。 20.如前述請求項中任一項之方、去 115t：之 Tg。 21·如凊求項1至15中任一項之方、去 130°C 之 Tg。 22·如請求項1至15中任一項之方去 125°C 之 Tg。 23 ·如請求項1至1 5中任一項之方法， 123〇C 之 Tg。 24·如請求項1至15中任一項之方法， 120〇C 之 Tg 〇 25. 如請求項1至15中任一項之方法， 115°C 之Tg。 26. 如前述請求項中任一項之方法， 包括1至5莫耳％ 2,2,4,4·四甲基_ι 99莫耳％環己烷二甲醇殘基。 27·如請求…至乃中任一項之方法，其中該聚醋之二酵成 伤包括5至小於50莫耳％ 2,2,4,4-四曱基-1,3-環丁二醇殘 基與大於50至高達95莫耳％環已烷二甲醇殘基。 28.如明求項1至25中任一項之方法，其中該聚酯之二醇成 份包括10至小於50莫耳％ 25254,4_四甲基β1，3_環丁二醇殘 119732.doc 200804457 29. 30. 31. 32. 33. 34. 35. 基與大於50至高達90莫耳％環己烷二甲醇殘基。 如凊求項1至25中任一項之方法，其中該聚酯之二醇成 份包括15至小於50莫耳％ 2,2,4,4-四甲基-1，3-環丁二醇殘 基與大於50至高達85莫耳％環己烷二曱醇殘基。 如明求項1至25中任一項之方法，其中該聚酯之二醇成 份包括15至40莫耳％2,2,4,4•四曱基]，3環丁二醇殘基與 60至85莫耳〇/〇環己烷二甲醇殘基。 如請求項1至25中任—項之方法，其中該聚醋之二醇成 伤包括15至35莫耳％ 2,2,4,4-四甲基_i，3-環丁二醇殘基與 65至85莫耳％環己烷二甲醇殘基。 如請求項125中任一項之方法，其中該聚醋之二醇成 份包括15至30莫耳％ 2,2,4,4_四曱基·^環丁二醇殘基與 70至85莫耳％環己烧二甲醇殘基。 如請求項1至25中任-項之方法，其中該聚醋之二醇成 伤包括20至35莫耳％ 2,2,4,4_四曱基·Μ環丁二醇殘基與 65至80莫耳％環己烷二甲醇殘基。 '、 如請求項1至25中任—項之方法，其中該聚醋之二醇成 伤。括25至35莫耳％ 2,2,4,4_四甲基·込3-環丁二醇殘基與 65至75莫耳〇/〇環己烷二曱醇殘基。 ’、 如請求項1至25中任-項之方法，其中該聚g旨之二醇成 份包括30至40莫耳％2,2,4,4_四甲基_1&gt;3_環丁二醇殘基與 60至70莫耳％環己烧二甲醇殘基。 36. 如請求項1至25中任 份包括15至25莫耳％ 項之方法，其中該聚酯之二醇成 2,2,4，‘四甲基―1，3·環丁二醇殘基與 119732.doc 200804457 75至85莫耳％環己烷二甲醇殘基。 37. 38. 39. 40. 41. 42. 43. 44. 45. 如請求項1至25中任—項之方法，其中該聚酯之二醇成 伤括17至25莫耳％ 2,2,4,4-四甲基义^環丁二醇殘基與 75至83莫耳％環己烷二甲醇殘基。 ” 如請求項1至25中任-項之方法，其中該《之二醇成 伤包括40至65莫耳χ* 斗 ，2,4,4·四甲基_1，3_環丁二醇殘基與 35至60莫耳〇/〇環己烷二甲醇殘基。 如請求項1至25中任—項之方法，其中該《之二醇成 份包括45至55莫耳。/〇 2 ? 4 d 、斗 2,2,4,4_四甲基β1，3_環丁二醇殘基與 45至55莫耳％環己烷二甲醇殘基。 如前述請求項中任—項之方法，其中該聚s旨包含丙 一％或1，4- 丁二醇或及丙二醇及Μ· 丁二醇之混合 物。 〇 如、前述請求項中任—項之方法，其中該㈣之二叛酸成 份=含80至_莫耳％對苯二甲酸或其醋。 如月J述π求項中任―項之方法，其中該聚醋之二緩酸 份包含90至⑽莫耳％對苯二甲酸或其醋。 如前述請求項中任—項之方法，其中該㈣之 包括乙二醇殘基。 咚烕伤 述月求項中任一項之方法’其中該聚醋之2,2,4,4-四 甲基_1’3·環Τ二醇殘基為純順式、純反式或兩者之混合 物。 如前述f求項中任-項之方法，其中該2,2,4,4-四甲 基-1’3-壤丁二醇殘基為包含4()至嶋耳％順式Ία四 119732.doc 200804457 甲基-1，3, 丁二醇殘基與4〇至6〇莫耳〇/〇反式乂 ，心四甲 基-1，3-環丁二醇殘基之混合物。 46·如前述請求項中任一頂古 ，二人 T 1 項之方法，其中該聚酯組合物包含 供該聚S旨用之分枝劑。 47·如前述請求項中任一瑙 1 項之方法，其中該聚酯包含分枝 劑，其量為0 · 0 1至5重晋％^ 更里/❶，以聚酯之總重量為基準。 48·如請求項1至45中任一 j苜夕士 a ^ 1 項之方法，其中該聚酯不含供該 聚S旨用之分枝劑。 49.如前述請求項中任一頊 項之方法，其中該聚酯之熔融黏 度’當在1孤度/秒下，於迴轉式熔融體流變計上，在29〇 它下度量時，係低於30,000泊。 50·如前述請求項中任一 g 1項之方法，其中聚酯為非晶質。 5 1 ·如前述請求項中任一頊 貝之方法，其中該聚酯於17〇 °C下 具有大於5分鐘之結晶化作用半衰期。 52·如前述請求項中任一項 胃 &lt; 方法，其中該聚酯於23 °C下具 有低於1.2克/宅升之密度。 53·如前述請求項中任一 % &lt;方法，其中該聚酯於23°C下， 根據ASTM D256，借用6 丈用费爾切口，在1/8-英吋厚棒塊 中’具有至少3叹-碎/英崎★ 方央寸之切口 Iz〇d衝擊強度。 54·如前述請求項中任一 、&lt;万法，其中該聚酯於23 °C下， 根據ASTM D256，使用1Π &amp; -畨爾切口，在1/4·英吋厚棒塊 中，具有至少3呎-磅/英+ ^ 犬丁之切口 Iz〇d衝擊強度。 55·如前述請求項中任一 v ,、 、万法，其中步驟（I)中之二醇成 为/一叛酸成分之莫耳ϋι 旲斗比為1·〇1·1·5/1·0。 119732.doc 200804457 56.如前述請求項中任一項之方 分…成分之莫耳比為驟， 57·如前述請求項中任一項之方 分/二缓酸成分之莫耳比為⑽.;^ 58·如請求項1至56中任_項之 成分/二缓酸成分之莫耳比為//其中步驟⑴中之二醇 為1.05.1.5/1.〇。 59·如前述請求項中任一項之方 分H&gt;钱 其中步驟（I)中之二醇成 刀/一羧酸成分之莫耳比為l.〇5q 2/1 Λ 如請求項1至57中任一項之 · ·。 # \ 方法’其中步驟⑴中之二醇 成为/二羧酸成分之莫耳比為1〇5_13/1〇。 61·如前述請求項中任一項之方 分t 一靜士、八^ 其中步驟（I)中之二醇成 刀/—羧酸成分之莫耳比為1〇5_115/1〇。 62·如前述請求項中任一項之方 時間為U4小時。 /、、中步驟（Π)中之加熱 63.如前述請求項中任一項之方 鉞 ，、中該最終聚酯中之總 錫原子與總磷原子之重量比為2_10: i。 64·如前述請求項中任一項 ^ I万去，其中該最終聚酯中之總 锡原子與總磷原子之重量比為5_9: 65·如前述請求項中任一項 姐 項万法，其中該最終聚酯中之總 锡原子與總磷原子之重量比為卜I卜 66 :則述請求項中任一項之方法，其中該最終聚醋中之總 錫原子與總磷原子之重量比為7 ·· i。 月J述明求項中任一項之方法，其中該最終聚酯中之錫 原子量，以最終聚醋重量計，為自25至400啊。 119732.d0· 200804457 68·如刖述請求項中任一項 馬；曰 、万去’其中該最終聚酯中之錫 原子ϊ，以最終聚酯重量計，炎α 场 乙〇 l么丄 τ 為自40至200 ppm 〇 69.如前述請求項中任一 m工田 、'^万法’其中該最終聚酯中之錫 原子1，以最終聚醋重量計， 蜴 …L么丄 1 馮自50至125 ppm 〇 70·如刖述請求項中任一 盾工曰 、心万法，其中該最終聚酯中之磷 原子1，以最終聚酯重量 m 2 丁為自 1 至 100 ppm。 71·如前述請求項中任一項 ^ ^ ^ 、 去，其中該最終聚酯中之碟 原子ϊ，以最終聚酯重量 * 為自4至60 ppm。 72·如前述請求項中任一之 心万去，其中該最終聚酯中之磷 原子量’以最終聚醋重量計，為自6至20 ppm。 73. 如請求項1至72中任-項之方法，其中步驟⑴中所使用 之催化劑包含至少一種錫化人 物化合物及至少一種鈦化合物。 74. 如請求項i至72中任一項 項之方法，其中步驟⑴中所使用 之催化劑實質上由至少一種锡化合物所組成。 如請求項e74t任-項之方法，其中至少一種碟化合 物係添加至步驟（I)及步驟（π)中。 其中該錫化合物係選 丁基錫、二丁基氧化 76·如請求項1至74中任一項之方法 自參-2-乙基己酸丁基錫、二贈酸 錫及二甲基氧化錫中之至少_種； 其中至少一種磷化合物係添加至步驟⑴、步驟（11)及/或 步驟（I)及步驟（II)中；及 其中«化合物的添加導致可用於本發明之最終聚醋中 之總錫原子與總鱗原子之重量比為2_丨〇 · J。 77· —種製造物件，其係將如前述請求項中任一項之方法所 119732.doc -10· 200804457 製得之聚酯組合物擠壓模製形成。 7 8 · —種製造物件’其係將如前述請求項中 一 、 項之方、、先 製得之聚ί旨組合物擠壓延伸吹製形成。 所 79· —種製造物件，其係將如前述請求項中任—項 製得之聚醋組合物射出模製形成。 、方去所 80· —種製造物件，其係將如前述請求項中任一項 製得之聚酯組合物射出吹製形成。 、之方法所Ill) 0 to 10 mol% of the aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) a diol component comprising: 1) 1 to 99 mol% of 2, 2, 4, 4·tetramethyl-1,3_cyclobutanediol residue; and 1〇1 to 99 mol% of cyclohexanedimethanol residue; wherein the diol component/dicarboxyl added in step (I) The molar ratio of the acid component is 1.0-1.5/1.0; wherein the mixture in the step (I) is heated in the presence of (1) at least one catalyst comprising at least one tin compound, and 'optionally, at least one a catalyst selected from the group consisting of titanium, gallium, yttrium, lanthanum, manganese, magnesium, lanthanum, lithium, aluminum compounds and aluminum compounds with lithium hydroxide or sodium hydroxide; and (ii) at least one heat stabilizer selected from the group consisting of At least one phosphorus compound, a reaction product thereof, and a mixture thereof; (II) the product of step (I) at a temperature of 230 to 320 ° C and at least one selected 119732.doc 200804457 from the final pressure of step (I) to 0. 02 Heating at a pressure in the range of (absolute pressure) for 1 to 6 hours to form a final poly- _; wherein the final polyester dicarboxylic acid component The total mole. /〇 is 1〇〇莫耳0/〇, and the total molar % of the diol component of the final polyester is 1% mol%; wherein when 60/40 (w/w) phenol/tetrachloroethylene In the alkane, the final polyester has an intrinsic viscosity of 0.35 to 1.2 cf/g when measured at 25 ° C at a concentration of 25 g / 5 〇 ml; and wherein the final polyester has 85 to 2 Hey. (: Tg 〇 2 - a method of producing at least one polyester useful in the present invention, comprising the steps of: (I) at least one temperature selected from 150 to 250 ° C and selected from 〇 to 75 pSig Heating a mixture under at least one pressure, wherein the mixture comprises: (a) a dicarboxylic acid component comprising: i) 70 to 100 moles/0 terephthalic acid residue; ii) 0 to 30 moles % of an aromatic dicarboxylic acid residue having up to 2 carbon atoms; and iii) o to 1 mole % of an aliphatic dicarboxylic acid residue having up to 16 carbon atoms; and (b) two An alcohol component comprising: Ο 1 to 99 moles/0 of 2,2,4,4-tetradecylcyclobutanediol residue; and ii) 1 to 99 mole % of cyclohexanedimethanol residue The molar ratio of the diol component/two resorcinic acid component added in the step (1) is 1·(Μ·5/1.〇; 119732.doc 200804457 wherein the mixture in the step (i) is in the following Heating in the presence of: (i) at least one catalyst comprising at least one tin compound, and, if desired, at least one selected from the group consisting of titanium, gallium, zinc, antimony, primary, short, magnesium, antimony, lithium, a catalyst of an aluminum compound and an aluminum compound with lithium hydroxide or sodium hydroxide; (II) a product of step (I) at a temperature of from 230 to 320 ° C, at least one selected from the final pressure of step (I) to 〇·〇 Heating in the presence of a pressure in the range of 2 Torr (absolute pressure) and at least one heat stabilizer selected from the group consisting of at least one phosphorus compound, its reaction product, and mixtures thereof for 1 to 6 hours; wherein the final polyester is a diwei acid component The total mole is 1 (9) mole %, and the total mole % of the diol component of the final polyester is 1% mol%; wherein when 60/40 (w/w) phenol/four gas B In the alkane, the final polyester has an intrinsic viscosity of 〇35 to 1.2 com/g when measured at 25 ° C at a concentration of 25 g / 50 ml; and wherein the final polyester has 85 to The method of any one of the items 1 to 2, wherein the at least one heat stabilizer is selected from at least one of the following substances: diphosphites, phosphates, a phosphine oxide type and a mixed aryl group alkyl oxoester. 4. The method of any one of the items 2 to 2, The at least one heat stabilizer is selected from the group consisting of at least one of the following: a bisphosphite. The method of any one of the items 1 to 2, wherein the at least one heat stable d is selected from the group consisting of at least one a phosphite comprising a 2,4,8,10-tetraoxa- 3,9-diphosphospiro[5.5]undecane structure. 119732.doc 200804457 6. 7. 8. 9. 10. 11. 12 13. The method of any one of clauses 1 to 2 wherein the at least one heat stabilizer is selected from the group consisting of at least one phosphine oxide. The method of any one of items 1 to 2, wherein the at least one heat stabilizer is selected from the group consisting of at least one mixed aryl ketone. The method of any of the preceding claims, wherein the at least one heat stabilizer is present in an amount from about i ppm to about 5 〇〇〇 ppm based on the total weight of the polyester. A method of any of the preceding claims, wherein the at least one heat stabilizer is present in an amount of from about 5 () ppm to about 3 ppm by weight based on the total weight of the poly 6 weight. A method according to any one of the preceding claims, wherein the at least one heat stabilizer is present in an amount of from about i (four) to about (10) ppm based on the total weight of the poly. The method of any of the preceding claims, wherein the intrinsic viscosity of the polyester is from 0.35 to 1 metric/gram. The method of any of the preceding claims, wherein the (4) inherent viscosity of the towel is from 0.35 to 0.75 com/g. The method of t^t, T, according to any one of the preceding claims, wherein the polyester has an intrinsic viscosity of from 0.50 to 1.2 com/g. Any of the above claims, t, t, and the specific viscosity of the polyester is 〇50 to 0.75 com/g. Wherein the inherent viscosity of the polyester, wherein the polyester has 85 to, wherein the polyester has 85 to a method according to any one of the preceding claims, which is from 55 to 0.75 com/g. The method of any one of the preceding claims, wherein the Tg is 130 °C. A method of any one of the preceding claims, wherein the Tg is 120 °C. 119732.doc 200804457 wherein the polyester has 95 to wherein the polyester has 95 to wherein the polyester has 95 to wherein the polyester has 100 to wherein the polyester has 100 to wherein the polyester has 100 to the polyester And a Tg of 125 ° C of the method of any one of the preceding claims, wherein the polyester has 100 to a diol component of the polyester, a 3-cyclobutanediol residue, and a 95 to 18 method according to any one of the preceding claims. 19. The Tg of the method 120〇C of any of the preceding claims. 20. The Tg of 115t: as in any of the preceding claims. 21. If you wish to use any of items 1 to 15, go to Tg at 130 °C. 22. If any of claims 1 to 15 is to go to a Tg of 125 °C. The method of any one of claims 1 to 15, the Tg of 123 〇C. The method of any one of claims 1 to 15, the Tg of 120 〇 C. 25. The method of any one of claims 1 to 15, a Tg of 115 °C. 26. The method of any of the preceding claims, comprising 1 to 5 mole % 2,2,4,4·tetramethyl-Il 99 mole % cyclohexane dimethanol residue. The method of any one of the preceding claims, wherein the vinegar of the vinegar comprises 5 to less than 50 mol% of 2,2,4,4-tetradecyl-1,3-cyclobutane The alcohol residue is greater than 50 up to 95 mole % cyclohexane dimethanol residue. The method of any one of claims 1 to 25, wherein the diol component of the polyester comprises 10 to less than 50 mol% of 25254,4_tetramethyl β1,3_cyclobutanediol residue 119732. Doc 200804457 29. 30. 31. 32. 33. 34. 35. Base with greater than 50 up to 90 mol% cyclohexanedimethanol residue. The method of any one of items 1 to 25, wherein the diol component of the polyester comprises 15 to less than 50 mol% of 2,2,4,4-tetramethyl-1,3-cyclobutanediol Residues are greater than 50 up to 85 mole % cyclohexanedimethanol residues. The method of any one of items 1 to 25, wherein the diol component of the polyester comprises 15 to 40 mol% of 2,2,4,4·tetradecyl], 3 cyclobutanediol residues and 60 to 85 moles per hydrazine cyclohexane dimethanol residue. The method of any one of claims 1 to 25, wherein the polyglycol diol formation comprises 15 to 35 mol% of 2,2,4,4-tetramethyl-i,3-cyclobutanediol residue Base with 65 to 85 mole % cyclohexane dimethanol residue. The method of any one of claim 125, wherein the polyglycol diol component comprises 15 to 30 mol% of 2,2,4,4-tetradecyl^cyclobutanediol residues and 70 to 85 mo Ears are hexanes to dimethanol residue. The method of any one of clauses 1 to 25, wherein the polyglycol diol formation comprises 20 to 35 mol% of 2,2,4,4-tetradecyl fluorene cyclobutanediol residue and 65 Up to 80 mole % cyclohexane dimethanol residue. The method of any one of claims 1 to 25, wherein the diol of the polyester is damaged. 25 to 35 mol% of 2,2,4,4-tetramethylphosphonium 3-cyclobutanediol residues and 65 to 75 moles per hydrazine cyclohexanediol residue. The method of any one of claims 1 to 25, wherein the diol component of the polyg is 30 to 40 mol% 2,2,4,4_tetramethyl_1&gt;3_cyclobutene The alcohol residue is between 60 and 70 moles of cyclohexane dimethanol residue. 36. A method according to any one of claims 1 to 25, comprising 15 to 25 mol%, wherein the diol of the polyester is 2, 2, 4, 'tetramethyl-1,3·cyclobutanediol Base with 119732.doc 200804457 75 to 85 mole % cyclohexane dimethanol residue. 37. The method of any one of items 1 to 25, wherein the diol of the polyester is contained in the range of 17 to 25 mol% 2,2 , 4,4-tetramethyl-cyclobutanediol residue with 75 to 83 mol% cyclohexane dimethanol residue. The method of any one of claims 1 to 25, wherein the "diol damage comprises 40 to 65 moles*, 2,4,4·tetramethyl-1,3_cyclobutanediol And a method of any one of claims 1 to 25, wherein the diol component comprises 45 to 55 mol. / 〇 2 ? 4 d , 2,2,4,4-tetramethyl β1,3_cyclobutanediol residue and 45 to 55 mol% cyclohexane dimethanol residue. The method according to any one of the preceding claims And the method of any one of the preceding claims, wherein the (4) bis acid is a mixture of the propylene glycol and the propylene glycol. Ingredients = 80 to _ mole % terephthalic acid or its vinegar. The method of any of the items of the sulphuric acid containing 90 to (10) mole % terephthalic acid. The method of any one of the preceding claims, wherein the (4) includes an ethylene glycol residue. The method of any of the items of the month of the present invention, wherein the polyester 2, 2, 4 , 4-tetramethyl-1'3·cyclonondiol residue A pure cis, a pure trans or a mixture of the two. The method of any one of the above, wherein the 2,2,4,4-tetramethyl-1'3-d-butylene glycol residue is Contains 4 () to 嶋 % % cis Ί α 4 119732.doc 200804457 Methyl-1,3, butanediol residue with 4 to 6 moles of 〇/〇 trans, 四tetramethyl-1, A mixture of 3-cyclobutanediol residues. 46. The method of any of the preceding claims, wherein the polyester composition comprises a branching agent for the purpose of the poly(S). The method of any of the preceding claims, wherein the polyester comprises a branching agent in an amount of from 0. 0 1 to 5 % by weight, based on the total weight of the polyester. 48. The method of any one of claims 1 to 45, wherein the polyester does not contain a branching agent for the purpose of the polys. 49. Any of the preceding claims A method wherein the melt viscosity of the polyester is less than 30,000 poise when measured at 29 Torr on a rotary melt rheometer at 1 degree/sec. 50. Any method of g 1 item, The polyester is amorphous. The method of any of the above claims, wherein the polyester has a crystallization half-life of greater than 5 minutes at 17 ° C. 52. A method of stomach, wherein the polyester has a density of less than 1.2 g/home liter at 23 ° C. 53. The method of any of the preceding claims, wherein the polyester is at 23 ° C According to ASTM D256, borrow 6 feet to use the Fair cut, and in the 1/8-inch thick bar, 'have at least 3 smash-break/inakisaki's slit Iz〇d impact strength. 54. The method of any of the preceding claims, wherein the polyester is at 23 ° C, according to ASTM D256, using a 1 Π &amp; - Muir cut, in a 1/4 inch thick bar, Incision Iz〇d impact strength of at least 3 呎-lb/英+^ canine. 55. According to any of the above claims, v, , and 10,000, wherein the diol in the step (I) is a / a tickling component, the molar ratio is 1·〇1·1·5/1· 0. 119732.doc 200804457 56. The molar ratio of the component of any one of the preceding claims is a step, 57. The molar ratio of the square/second acid component of any one of the preceding claims is (10) The molar ratio of the component/di-acidifying component of any of claims 1 to 56 is // wherein the diol in the step (1) is 1.05.1.5/1. 59. The method according to any one of the preceding claims, wherein the molar ratio of the diol forming knife/monocarboxylic acid component in the step (I) is 1. 5q 2/1 Λ as in claim 1 57 of any one. # \方法' wherein the molar ratio of the diol to/dicarboxylic acid component in the step (1) is 1〇5_13/1〇. 61. The method according to any one of the preceding claims, wherein the molar ratio of the diol forming knife/carboxylic acid component in the step (I) is 1〇5_115/1〇. 62. The time of any of the preceding claims is U4 hours. The heating in the step (Π), wherein the weight ratio of the total tin atom to the total phosphorus atom in the final polyester is 2_10: i. 64. The method of claim 1, wherein the weight ratio of total tin atoms to total phosphorus atoms in the final polyester is 5-9: 65. The weight ratio of the total tin atom to the total phosphorus atom in the final polyester is the method of any one of the claims, wherein the weight of the total tin atom and the total phosphorus atom in the final polyester The ratio is 7 ·· i. The method of any one of the preceding claims, wherein the amount of tin atoms in the final polyester is from 25 to 400, based on the weight of the final polyester. 119732.d0· 200804457 68·If you recite any of the requirements of the horse; 曰, 万 went to 'the tin atom in the final polyester, based on the weight of the final polyester, αα field 〇 〇 丄 丄 丄From 40 to 200 ppm 〇69. As in any of the preceding claims, the m-field, '^万法', wherein the tin atom in the final polyester is 1, based on the weight of the final polyester, the larvae... L 丄 1 von From 50 to 125 ppm 〇 70. As described in any of the claims, the phosphorus atom 1 in the final polyester is from 1 to 100 ppm based on the final polyester weight m 2 . 71. The method of any of the preceding claims, wherein the atomic enthalpy of the final polyester is from 4 to 60 ppm by weight of the final polyester. 72. The method of any of the preceding claims, wherein the amount of phosphorus atoms in the final polyester is from 6 to 20 ppm by weight of the final polyester. The method of any one of items 1 to 72, wherein the catalyst used in the step (1) comprises at least one tin compound compound and at least one titanium compound. The method of any one of claims 1 to 72, wherein the catalyst used in the step (1) consists essentially of at least one tin compound. The method of claim e74t, wherein at least one of the dish compounds is added to the step (I) and the step (π). Wherein the tin compound is selected from the group consisting of butyltin and dibutyl oxide. 76. The method according to any one of claims 1 to 74, wherein at least one of butyl tin-2-ethylhexanoate, tin bisphosphonate and tin dimethyltin oxide are present. Wherein at least one phosphorus compound is added to step (1), step (11) and/or step (I) and step (II); and wherein the addition of the compound results in a total of the final polyester which can be used in the present invention. The weight ratio of tin atoms to total scale atoms is 2_丨〇·J. 77. A manufactured article formed by extrusion molding a polyester composition obtained by the method of any one of the aforementioned claims 119732.doc -10. 200804457. 7 8 - A manufactured article' is formed by extrusion stretching of a previously prepared composition according to one of the preceding claims. And a manufactured article obtained by injection molding a polyacetal composition obtained according to any one of the preceding claims. And a manufactured article obtained by injection-blown forming a polyester composition obtained according to any one of the preceding claims. Methodological institute 81. -種製造物件，其係將如前述請求項中任_ 、 製得之聚酯組合物射出延伸吹製形成。 方法所81. An article of manufacture formed by injection-extruding a polyester composition obtained as claimed in any of the preceding claims. Method institute 119732.doc -11 - 200804457 七、指定代表圖： (一) 本案指定代表圖為：（無） (二) 本代表圖之元件符號簡單說明： 八、本案若有化學式時，請揭示最能顯示發明特徵的化學式： (無） 119732.doc119732.doc -11 - 200804457 VII. Designated representative map: (1) The representative representative of the case is: (none) (2) The symbolic symbol of the representative figure is simple: 8. If there is a chemical formula in this case, please reveal the best display. Chemical formula of the invention: (none) 119732.doc
TW96110546A 2006-03-28 2007-03-27 Polyester compositions which comprise cyclobutanediol and at least one phosphorus compound TW200804457A (en)

Applications Claiming Priority (61)

Application Number Priority Date Filing Date Title
US39077306A 2006-03-28 2006-03-28
US78654706P 2006-03-28 2006-03-28
US78659806P 2006-03-28 2006-03-28
US78659606P 2006-03-28 2006-03-28
US78657206P 2006-03-28 2006-03-28
US78657106P 2006-03-28 2006-03-28
US11/390,809 US7959998B2 (en) 2005-03-02 2006-03-28 Transparent, oxygen-scavenging compositions containing polyesters comprising a cyclobutanediol and articles prepared therefrom
US11/390,847 US20060287484A1 (en) 2005-06-17 2006-03-28 Opththalmic devices comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,955 US7915376B2 (en) 2005-06-17 2006-03-28 Containers comprising polyester compositions which comprise cyclobutanediol
US11/390,846 US7955674B2 (en) 2005-03-02 2006-03-28 Transparent polymer blends containing polyesters comprising a cyclobutanediol and articles prepared therefrom
US11/390,655 US8067525B2 (en) 2005-06-17 2006-03-28 Film(s) and/or sheet(s) comprising polyester compositions which comprise cyclobutanediol and have a certain combination of inherent viscosity and high glass transition temperature
US11/390,630 US7807774B2 (en) 2005-06-17 2006-03-28 Vending machines comprising polyester compositions formed from 2,2,4,4,-tetramethyl-1,3,-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,751 US7803440B2 (en) 2005-06-17 2006-03-28 Bottles comprising polyester compositions which comprise cyclobutanediol
US11/391,576 US7803441B2 (en) 2005-06-17 2006-03-28 Intravenous components comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,156 US7812112B2 (en) 2005-06-17 2006-03-28 Outdoor signs comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,125 US20070010650A1 (en) 2005-06-17 2006-03-28 Tough amorphous polyester compositions
US11/390,827 US7893188B2 (en) 2005-06-17 2006-03-28 Baby bottles comprising polyester compositions which comprise cyclobutanediol
US11/390,654 US20060287477A1 (en) 2005-06-17 2006-03-28 Greenhouses comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4- cyclohexanedimethanol
US11/390,631 US7855267B2 (en) 2005-06-17 2006-03-28 Film(s) and/or sheet(s) comprising polyester compositions which comprise cyclobutanediol and have a certain combination of inherent viscosity and moderate glass transition temperature
US11/390,865 US20060287485A1 (en) 2005-06-17 2006-03-28 Sound barriers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,672 US20060287479A1 (en) 2005-06-17 2006-03-28 Polyester compositions containing cyclobutanediol and articles made therefrom
US11/390,812 US7959836B2 (en) 2005-03-02 2006-03-28 Process for the preparation of transparent, shaped articles containing polyesters comprising a cyclobutanediol
US11/390,722 US7893187B2 (en) 2005-06-17 2006-03-28 Glass laminates comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,642 US7510768B2 (en) 2005-06-17 2006-03-28 Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein
US11/390,836 US20060286330A1 (en) 2005-06-17 2006-03-28 Sterilization containers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,908 US7462684B2 (en) 2005-03-02 2006-03-28 Preparation of transparent, multilayered articles containing polyesters comprising a cyclobutanediol and homogeneous polyamide blends
US11/391,659 US20060287496A1 (en) 2005-06-17 2006-03-28 Polyester compositions comprising minimal amounts of cyclobutanediol
US11/390,629 US7803439B2 (en) 2005-06-17 2006-03-28 Blood therapy containers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,124 US20060234073A1 (en) 2005-03-02 2006-03-28 Multilayered, transparent articles containing polyesters comprising a cyclobutanediol and a process for their preparation
US11/391,565 US7781562B2 (en) 2005-06-17 2006-03-28 Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
US11/390,826 US7906610B2 (en) 2005-06-17 2006-03-28 Food service products comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,752 US8063173B2 (en) 2005-06-17 2006-03-28 Polyester compositions containing low amounts of cyclobutanediol and articles made therefrom
US11/391,137 US7985827B2 (en) 2005-06-17 2006-03-28 Polyester compositions which comprise cyclobutanediol having certain cis/trans ratios
US11/390,793 US20060286389A1 (en) 2005-06-17 2006-03-28 Protein-resistant articles comprising cyclobutanediol
US11/391,485 US7842776B2 (en) 2005-06-17 2006-03-28 Appliance parts comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,563 US7902320B2 (en) 2005-06-17 2006-03-28 Graphic art films comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,883 US7834129B2 (en) 2005-06-17 2006-03-28 Restaurant smallware comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,858 US7951900B2 (en) 2005-06-17 2006-03-28 Dialysis filter housings comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,063 US7576171B2 (en) 2005-06-17 2006-03-28 Pacifiers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,864 US7812111B2 (en) 2005-06-17 2006-03-28 LCD films comprising polyester compositions formed from 2,2,4,4-tetramethy1-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,811 US7868128B2 (en) 2005-06-17 2006-03-28 Skylights and windows comprising polyester compositions formed from 2,2,4,4,-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,794 US8119761B2 (en) 2005-06-17 2006-03-28 Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and high glass transition temperature and articles made therefrom
US11/390,882 US20060287486A1 (en) 2005-06-17 2006-03-28 Optical media comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,505 US7838620B2 (en) 2005-06-17 2006-03-28 Thermoformed sheet(s) comprising polyester compositions which comprise cyclobutanediol
US11/390,750 US20060287480A1 (en) 2005-06-17 2006-03-28 Outdoor shelters comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,571 US20060287494A1 (en) 2005-06-17 2006-03-28 Polyester compositions containing high amounts of cyclobutanediol and articles made therefrom
US11/391,495 US7807775B2 (en) 2005-06-17 2006-03-28 Point of purchase displays comprising polyester compositions formed from 2,2,4,4-tetramethyl-1, 3,-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,814 US20060286327A1 (en) 2005-06-17 2006-03-28 Retort containers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,671 US8063172B2 (en) 2005-06-17 2006-03-28 Film(s) and/or sheet(s) made using polyester compositions containing low amounts of cyclobutanediol
US11/390,853 US20070270569A1 (en) 2005-06-17 2006-03-28 Film(s) and/or sheet(s) made from polyester compositions containing cyclobutanediol and articles made therefrom
US11/588,907 US20070106054A1 (en) 2005-10-28 2006-10-27 Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and high glass transition temperature and articles made therefrom
US11/588,527 US20100087574A1 (en) 2005-10-28 2006-10-27 Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
US11/588,524 US20100096589A1 (en) 2005-10-28 2006-10-27 Polyester compositions containing low amounts of cyclobutanediol and articles made therefrom
US11/588,906 US8193302B2 (en) 2005-10-28 2006-10-27 Polyester compositions which comprise cyclobutanediol and certain phosphate thermal stabilizers, and/or reaction products thereof
US11/588,554 US20070100125A1 (en) 2005-10-28 2006-10-27 Polyester compositions comprising minimal amounts of cyclobutanediol
US11/588,458 US20070100122A1 (en) 2005-10-28 2006-10-27 Polyester compositions containing cyclobutanediol and articles made therefrom
US11/588,883 US20070105993A1 (en) 2005-10-28 2006-10-27 Polyester compositions which comprise cyclobutanediol and at least one phosphorus compound
US11/635,434 US7737246B2 (en) 2005-12-15 2006-12-07 Polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and ethylene glycol and manufacturing processes therefor
US11/635,433 US20070142511A1 (en) 2005-12-15 2006-12-07 Polyester compositions which comprise cyclobutanediol ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor
US11/706,791 US20070232779A1 (en) 2006-03-28 2007-02-14 Certain polyester compositions which comprise cyclohexanedimethanol, moderate cyclobutanediol, cyclohexanedimethanol, and high trans cyclohexanedicarboxylic acid
US11/706,476 US20070232778A1 (en) 2006-03-28 2007-02-14 Certain polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and high trans-cyclohexanedicarboxylic acid

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