TW200804200A - The treatment method for electroless copper plating rinsing wastewater - Google Patents

The treatment method for electroless copper plating rinsing wastewater Download PDF

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Publication number
TW200804200A
TW200804200A TW95125261A TW95125261A TW200804200A TW 200804200 A TW200804200 A TW 200804200A TW 95125261 A TW95125261 A TW 95125261A TW 95125261 A TW95125261 A TW 95125261A TW 200804200 A TW200804200 A TW 200804200A
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TW
Taiwan
Prior art keywords
wastewater
rinsing
reverse osmosis
copper plating
electroless copper
Prior art date
Application number
TW95125261A
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Chinese (zh)
Inventor
qi-liang Chen
Original Assignee
Mitac Prec Technology Corp
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Filing date
Publication date
Application filed by Mitac Prec Technology Corp filed Critical Mitac Prec Technology Corp
Priority to TW95125261A priority Critical patent/TW200804200A/en
Publication of TW200804200A publication Critical patent/TW200804200A/en

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  • Separation Using Semi-Permeable Membranes (AREA)
  • Treatment Of Water By Ion Exchange (AREA)

Abstract

The invention provides a treatment method of electroless copper plating rinsing wastewater, which includes the following basic steps: rinsing wastewater of electroless copper plating → adjusting PH value → ion exchanging → ultrafiltration → reverse osmosis → reusing the cleaning water/loop treatment of concentrated water. The process is that heavy metals are recycled from wastewater by exchanging the heavy metals in the wastewater with the same type ions in the ion exchande resin. Then, the macromolecular impurities are removed by processing ultrafiltration. The reverse osmosis process is carried out to separate the unpurified wastewater. Then, the unpurified wastewater is transferred back to the beginning untreated rinsing wastewater to proceed loop treatment together. Finally the purified cleaning water is recycled and reused.

Description

200804200 九、發明說明: 【發明所屬之技術領域】 本發明係關於一種化學鍍銅處理 鍍銅廢水處理方法。 友,知別係關於一種化學 【先前技術】 膠表應用於塑 銅中,漂洗工件触巾舰生縣目含該化學鑛 理後才能回收或排放。儘管傳統之化學沉酽 、須進仃處 =金屬_子,但仍會產生需要專業處ς的重去= 【發明内容】 廣水之問本發明之目的在於提供一種化學鑛鋼卢洗 廢水處理方法,以基本實現漂洗廢水之零排放。錢幻你洗 本發明採_子交換法和反渗透相結合 收大^之金屬銅資源,且無廢渣污泥產生之^環^僅可以回 本發明的化學鍍銅漂洗廢水處理方法其流程為: =·凋正值,將化學鑛銅漂洗廢水之ρΗ值調整為3〜 •離子父換,將該化學鑛銅漂洗廢水流經一離子交 她廢水中之重金屬離子與離子交換樹脂中相同類型離子^杆六’ 換,以回收廢水中之重金屬; 又 c·超濾,藉以一半透膜以除去廢水中所含之大分子雜質; 來· d·反滲透,藉以一反滲透膜將已淨化及未淨化廢水分離出 e·淨水回用/濃水迴圈處理,將上述經反滲透膜分離200804200 IX. Description of the Invention: [Technical Field of the Invention] The present invention relates to a method for treating copper plating wastewater by electroless copper plating. Friends, knowing about a kind of chemistry [Previous technology] The rubber meter is used in plastic copper, and the rinsing of the workpiece can be recovered or discharged after the chemical mine is contained in the shipowner. Despite the traditional chemical deposition, the need to enter the = = metal _ sub, but still need to be professionally required to go to the weight = [Summary of the content] The purpose of the present invention is to provide a chemical mine steel Lu Wash wastewater treatment The method is to substantially achieve zero discharge of the rinsing wastewater. The money illusion you wash this invention combined with the _ sub-exchange method and reverse osmosis combined with the large metal copper resources, and no waste slag sludge produced ^ ring ^ can only return to the invention of the electroless copper rinsing wastewater treatment process : = · Withered positive value, the pH value of the chemical copper rinsing wastewater is adjusted to 3~ • Ion parent exchange, the chemical copper rinsing wastewater flows through the same type of heavy metal ions in the ionized wastewater Ion ^ rod six ' change to recover heavy metals in wastewater; c · ultrafiltration, half of the membrane to remove the macromolecular impurities contained in the wastewater; to · d · reverse osmosis, whereby a reverse osmosis membrane will be purified And the unpurified wastewater is separated from the e·clean water reuse/concentrated water loop treatment, and the above reverse osmosis membrane is separated.

收利用,而對於未淨化之廢水,則將其輸送回開始之化學ιΓ 銅漂洗廢水重新處理。 X 、、使用本發明之化學鏡銅漂洗廢水處理方法,其方法本身可以 成為閉路迴圈,在回收重金屬之同時能基本上實現漂洗廢水之零 5 200804200 排放,避免其造成環境污染。 為使對本發明之目的、構、生 茲配合圖示詳細說明如下··绝寸徵及其功能有進一步之瞭解, 【實施方式】 如圖1所示,其為本發明法 出,本發明開始是對化學錢銅^,圖’由該圖可以很明顯的看 以將其PH信舖Μ〜』η ^味洗廢水進行調整PH值101步驟,For reuse, for unpurified wastewater, it is transported back to the original chemical Γ 铜 copper rinsing wastewater for reprocessing. X, using the chemical mirror copper rinsing wastewater treatment method of the invention, the method itself can be a closed loop, and the heavy metal can be recovered substantially at the same time as the effluent wastewater can be realized to avoid environmental pollution. In order to make the purpose, structure, and living diagram of the present invention detailed, the following is a brief understanding of the features and functions of the present invention. [Embodiment] As shown in FIG. 1, it is a method of the present invention, and the present invention begins. It is the chemical money copper ^, the picture 'from the figure can be very obvious to put its PH letter paved ~ η ^ taste washing wastewater to adjust the pH value of 101 steps,

以將其ΡΗ值調為3〜1〇,,缺後推 六4名也时a — , · 设進仃離子交換102步驟,利用離子 相同類 3步驟, 通過^-將其淨 水、水迴圈處理1Q5 交換樹脂特性,使廢水中之曹八^丁^于父賴 別絡ϋ ^ μ 一 T之重至屬離子與離子交換樹脂中相同類 濾103步驟 :後即通過一 巧糊:該淨水巾幾乎檢測不將其淨 型離子進行交換, 通過-半透膜以去除其廢水中:含屬、子103步驟’ =透104步驟,以將已淨化與未淨化==行=後即通過一 g廢水中,重新處理,如此迴圈即可淨化廢水,可基In order to adjust its devaluation to 3~1〇, after the lack of six or four, a-, · set into the 仃 ion exchange 102 step, using the same 3 steps of the ion, through the ^- to its clean water, water back The ring treatment 1Q5 exchange resin characteristics, so that the waste water in the Cao Ba ^ Ding ^ in the father Lai Bie ϋ ^ μ a T weight to the same ion and ion exchange resin in the same type of filtration 103 steps: then through a clever paste: The water-washing towel almost detects that it does not exchange its net-type ions, and passes through the semi-permeable membrane to remove its waste water: containing the genus, sub-step 103' = 104 steps, to clean and unpurify == line = after Through a g of wastewater, re-treating, so that the loop can be purified, the base

以上所述者,僅為本發明其中之較佳實施例而已, 限定本發明之實施即凡依本發明申料利 作解 變化與修飾,皆為本發明專利範圍所涵蓋。 厅作之均4 【圖式簡單說明】 圖1係為本發明之流程示意圖。 【主要元件符號說明】 101〜105 步驟 6The above is only the preferred embodiment of the present invention, and the implementation of the present invention, which is defined by the present invention, is covered by the scope of the present invention. The average of the halls is as follows: Figure 1 is a schematic diagram of the flow of the present invention. [Main component symbol description] 101~105 Step 6

Claims (1)

200804200 十、申請專利範圍· 1. -種化賴銅漂洗廢水處理方法,財法之步驟包括有: a. 調整PH值’將化學鑛銅漂洗廢水之pH值調整為3〜1〇; b. 離子交換’其中該步驟係為利用離子交換樹脂之特性 廢水中之重金屬離子與離子交換樹脂中相同類型離子進行交換 以回收廢水中之重金屬, C·超濾,通過一半透膜以除去廢水中所含之大分子雜質; d反滲透,該步驟係為通過一反滲透膜將已淨化與未淨化廢 水分離出來; x • e.淨水回用/濃水迴圈處理’將上述經反渗透膜分離出來之淨 水回收利用,而對^未淨化之廢水,則將其輪送回開始之化學鐘 銅漂洗廢水重新處理。200804200 X. Patent application scope 1. 1. The method for processing the lyophilized copper rinsing wastewater, the steps of the financial method include: a. Adjusting the pH value to adjust the pH value of the chemical copper rinsing wastewater to 3~1〇; b. Ion exchange 'where the step is to utilize the characteristics of the ion exchange resin, the heavy metal ions in the wastewater are exchanged with the same type of ions in the ion exchange resin to recover the heavy metals in the wastewater, C·Ultrafiltration, through half of the membrane to remove the waste water Containing macromolecular impurities; d reverse osmosis, this step is to separate the purified and unpurified wastewater through a reverse osmosis membrane; x • e. purified water reuse / concentrated water loop treatment 'the above reverse osmosis membrane The separated purified water is recycled, and the unpurified wastewater is sent back to the beginning of the chemical clock copper rinsing wastewater for reprocessing.
TW95125261A 2006-07-11 2006-07-11 The treatment method for electroless copper plating rinsing wastewater TW200804200A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104016510A (en) * 2014-05-22 2014-09-03 国家电网公司 Utilization method for interactive treatment of heat-engine plant reverse osmosis concentrated water and municipal sewage
TWI471180B (en) * 2012-06-04 2015-02-01 Triumphant Gate Ltd Surface treatment of wet process cleaning fluid in the gold and cyanide recycling system
CN105712517A (en) * 2016-04-11 2016-06-29 浙江碧源环保科技有限公司 Copper-containing electroplating rinse wastewater treatment system and treatment process
CN106007040A (en) * 2016-07-23 2016-10-12 杭州真水流体技术有限公司 Heavy metal wastewater treatment system and method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI471180B (en) * 2012-06-04 2015-02-01 Triumphant Gate Ltd Surface treatment of wet process cleaning fluid in the gold and cyanide recycling system
CN104016510A (en) * 2014-05-22 2014-09-03 国家电网公司 Utilization method for interactive treatment of heat-engine plant reverse osmosis concentrated water and municipal sewage
CN104016510B (en) * 2014-05-22 2016-04-06 国家电网公司 The Application way of a kind of thermal power plant reverse osmosis concentrated water and municipal effluent interaction process
CN105712517A (en) * 2016-04-11 2016-06-29 浙江碧源环保科技有限公司 Copper-containing electroplating rinse wastewater treatment system and treatment process
CN106007040A (en) * 2016-07-23 2016-10-12 杭州真水流体技术有限公司 Heavy metal wastewater treatment system and method
CN106007040B (en) * 2016-07-23 2022-09-06 杭州真水流体技术有限公司 Heavy metal wastewater treatment system and method

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