TW200800396A - Dehumidification rotor, method of manufacturing the same, and dehumidifier - Google Patents
Dehumidification rotor, method of manufacturing the same, and dehumidifier Download PDFInfo
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- TW200800396A TW200800396A TW96108430A TW96108430A TW200800396A TW 200800396 A TW200800396 A TW 200800396A TW 96108430 A TW96108430 A TW 96108430A TW 96108430 A TW96108430 A TW 96108430A TW 200800396 A TW200800396 A TW 200800396A
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200800396 九、發明說明: 【發明所屬之技術領域】 本發明係關於同時執行利用除濕劑對被處理空氣之除 •濕、以及將已吸濕著水分的該除濕劑之再生,並連續施行 .該被處理空氣除濕之旋轉再生式除濕機所使用的除 筒及其製造方法、暨具有該除濕滚筒的除濕機。 【先前技術】 家庭用除濕機係具備有:載持著除濕劑的旋轉式除濕滾 筒、以及將該除濕劑再生的加熱器之旋轉再生式除@機二 所以,該家庭用除濕機不僅在絕對濕度較高的夏天,就 低的冬天’仍可使用於在室内將洗滌物乾燥、 :乂、"路方面。因而’该家庭用除濕機的除濕滾筒必需 即使在絕對濕度偏低的條件下,仍 π而 , r 1乃擁有優越的除濕性能。 炎曰w *用除濕機領域中,講求更低濕度空氣的需 求曰漸增加,特別係在半導體萝 因的水分盡力去除之所將氧化肇 產業用除濕機亦必需即便在二漲。因而’ 有優越除濕性能。在絕對濕度較低的條件下,仍具 可將較低絕對濕度空氣中的水分吸附之物質,已知有、、弗 石。該沸石係可舉例如v 物貝已知有沸 該等之中,因為…二 型彿石、及A型彿石, 為Y i沸石相較於χ型彿 下,可依低溫施行水分的㈣π弗石之 執行除渴f ^ 的…、,因而認為最適合於連續式 轨仃除濕的豕庭除濕機用除濕齊卜 叙利用合成所獲得的滞石係該涛石將成為鋁部位離 312XP/發明說鴨(補件)/96•咖61 6 200800396 子的_子為納料之㈣石。該㈣ 濕度較低的空氣中,仍具有㈣速㈣ 越的吸濕性能。 “迓&將發揮優 该鈉沸石的物質 所以,習知的除濕滾筒便使用载持著 【發明内容】 (發明所欲解決之問題) 但是’該鈉彿石雖屬於高吸濕性,但是脫濕性卻偏低。 鲁所以’為將該㈣石利用加熱施行脫濕,而使該鈉彿石的 吸濕性能再生時’便需要大量的熱能。換言之,家庭 ,機,當使用載持著該納彿石的除濕滾筒之情況時,便: 需提南加熱器機溫。 但是’近年在省能源化的基礎下,該家庭歸濕機的加 …為機溫將有降低的傾向。然而,若加熱器機溫較低 無法充分地執行該鈉彿石的再生。所以,載持著該納沸石 的除濕滾筒,若降低加熱器機溫而低於習知,便將出現^ _濕性能不足的問題。 ^ 相較於該鈉沸石之下,可依低溫進行脫濕的沸石,例如 在專利文獻1的日本專利特開200卜33412〇號公報中,便 有揭不將親水性沸石中的部分鈉取代為鑭的沸石。 [專利文獻1]日本專利特開2001 —33412〇號公報(申往 專利範圍第1項) % 若使加熱器機 沸石的除濕滾 但是,即便是專利文獻1所揭示的沸石, 溫低於習知,便將出現再生不足,載持著該 筒之除濕性能將呈不足狀態。 312ΧΡ/發明說明書(補件)/96-06/96108430 7 200800396 斤另方面,能依低溫進行脫濕的吸濕劑,已知有如:二 ^化石夕4膠、二氧化石卜氧化銘非晶質多孔體、中孔洞二 b石夕等無機吸濕劑;離子交換樹脂、聚丙烯酸鹽樹脂、 環氧烧樹脂等吸水性樹脂。但是,該等二氧化石夕凝膠等該 無機吸濕劑,在相較於沸石之下,於高溫下重複進行吸/ 脫濕時的吸濕量將大幅降低,且在絕對濕度較低的條件 下丄水分的吸附量較少。所以,該無機吸濕劑並無法使用 ^家庭用除濕機的除濕滾筒、以及製造通稱為乾燥空氣的 :…吼之產業用除濕機方面。此外,因為離子交換樹 水性樹脂的耐熱性較低,因而並無法將該吸水性 =用於習知的家庭用除濕機之除濕滚筒、產業用除濕 於供一種即便將加熱器溫度低 較少之除濕滾筒。"、里、且長期的除濕量降低程度 φ (解決問題之手段) 研本::二見等之能解決上述習知技術的問題,經深入鑽 滾筒係由依厚度方向上正交的面 刀J之弟一载持部與第 所載持的彿石、及第二载 擇該弟一载持部 定公式計算出將該第—除的除濕劑,更利用特 置,藉此便可獲得除渴量’1、 一弟一除濕部分割的位 除濕滾筒,遂完成本發明且除濕量降低程度較少的 換言之,本發明⑴所提供的除濕滾筒,係载體上载持 312XP/發明說明書(補件跡咖觸〇 8 200800396 著除濕劑的除濕滾筒,而該除濕滾筒係利 正交的面,分割為载持著第一除濕劑的第=方向呈 载持著第二除濕劑的第二载持 寺邛、以及 ώ 0 弟一除濕劑係脫濕尖痊、、西 度為4(M〇〇C,且脫濕尖峰溫度較低於 二二 脫濕尖峰溫度5。(:以上的非晶皙盔嬙少,弟除濕劑的 丄W非日日貝無機多孔質體 脂;該除濕滾筒將使用於再生*衰Α &飞及水丨生树 —C的除濕機中。…側的開口面溫度為 再者,本發明(2)的除濕滾筒製 . 度方向主正父的面,分割為载持著第一除濕劑的第—載持 部、以及載持著第二除濕劑的第二载持部,且再生空氣入 口側的開口面溫度為250〜500ν夕咚、瓦挑& ’、 筒之製造方法,包括有:c之除濕機所使用的除濕滚 ;製作出載持著1G(M6()g/m3的該第—除濕劑,且厚度與200800396 IX. Description of the Invention: [Technical Field] The present invention relates to the simultaneous execution of the dehumidification of the air to be treated by the dehumidifying agent, and the regeneration of the dehumidifying agent which has absorbed moisture, and is continuously carried out. A cleaning cylinder used in a rotary regenerative dehumidifier that is dehumidified by a process air, a method for manufacturing the same, and a dehumidifier having the dehumidification roller. [Prior Art] The household dehumidifier is provided with a rotary dehumidifying drum that carries a dehumidifying agent, and a rotary regenerative type of a heater that regenerates the dehumidifying agent, so that the household dehumidifier is not only absolute In the summer when the humidity is high, the low winter can still be used to dry the laundry indoors: 乂, "路 aspect. Therefore, the dehumidification drum of the household dehumidifier must have π, and r 1 has superior dehumidification performance even under conditions of low absolute humidity. In the field of dehumidifiers, the demand for lower-humidity air is increasing, especially in the case where the moisture of the semiconductor radix is removed as much as possible. Thus, there is superior dehumidification performance. Under conditions of low absolute humidity, there are still substances that can adsorb moisture in the air of lower absolute humidity. The zeolite system may, for example, be known to have a boiling of v, and the like, because ... the type II buddha and the type A phoenix, the y zeolite can be hydrated at a lower temperature than the χ type buddha. The implementation of the stone removal thirst f ^ ..., and therefore considered the most suitable for continuous derailment dehumidification of the dehumidifier with dehumidification Qi Buxu using the synthesis of the stagnation of the stone will become the aluminum part away from 312XP / Invented that the duck (supplement) / 96 • coffee 61 6 200800396 _ son is the material (four) stone. The air in the lower humidity (4) still has the (four) speed (four) moisture absorption performance. "迓& will exert the substance of the sodium zeolite. Therefore, the conventional dehumidification roller is used. [Summary of the invention] (The problem to be solved by the invention) However, the sodium sulphate is highly hygroscopic, but The dehumidification is low. Lu said that 'the dehumidification of the (four) stone by heating, and the regeneration of the hygroscopic performance of the sodium fossil 'will require a lot of heat. In other words, the family, the machine, when using the carrier When the dehumidification roller of the Nafo stone is used, it is necessary to raise the temperature of the south heater. However, in recent years, on the basis of energy saving, the addition of the household humidifier will have a tendency to decrease in temperature. If the heater temperature is low, the regeneration of the sodium smectite cannot be sufficiently performed. Therefore, if the dehumidification roller holding the zeolite is lower than the conventional heater temperature, the _wet performance is insufficient. The problem is that a zeolite which can be dehumidified at a low temperature in comparison with the sodium zeolite, for example, in the Japanese Patent Laid-Open Publication No. 200-33412, the disclosure of which is incorporated herein by reference. The sodium is replaced by a cerium zeolite. Japanese Patent Laid-Open Publication No. 2001-33412 (Japanese Patent Application Laid-Open No. Hei No. Hei No. Hei No. Hei. No. Hei. Insufficient regeneration will occur, and the dehumidification performance of the cartridge will be insufficient. 312ΧΡ/Invention Manual (supplement)/96-06/96108430 7 200800396 Another aspect, a moisture absorbent that can be dehumidified at low temperatures, It is known, for example, that it is an inorganic moisture-absorbing agent such as a smectite resin, a polyacrylic acid resin, or an epoxy resin. Resin. However, the inorganic moisture absorbent such as the cerium dioxide gel is substantially lower in moisture absorption when it is repeatedly subjected to suction/desorption at a high temperature compared to zeolite. In the lower condition, the adsorption amount of the hydrazine moisture is small. Therefore, the inorganic moisture absorbent cannot be used in the dehumidification drum of the household dehumidifier, and the industrial dehumidifier which is known as dry air. Because of ion exchange The tree-changing water-based resin has low heat resistance, and thus the water absorption property cannot be used for a dehumidification drum of a conventional household dehumidifier, and industrial dehumidification is provided for a dehumidification drum which has a low heater temperature. ;,, and long-term dehumidification reduction degree φ (means to solve the problem) Research:: see two can solve the above-mentioned problems of the prior art, after deep drilling the drum is made by the surface knife orthogonal to the thickness direction The first part of the carrier and the Buddha's stone held by the first and the second set of the formula of the younger brother to calculate the dehumidification agent for the first-division, and then use the special purpose, thereby obtaining thirst The quantity '1, a younger-dehumidifying part divided by the dehumidifying section, and the present invention is completed and the degree of dehumidification is reduced to a lesser extent. In other words, the dehumidifying drum provided by the invention (1) is carried by the carrier 312XP/invention manual (repair) The tracer is touched 8 200800396 The dehumidification roller of the dehumidifier, and the dehumidification roller is orthogonal to the surface, and is divided into the second carrier holding the second dehumidifier in the = direction carrying the first dehumidifying agent.邛, and ώ 0 brother-dehumidifier Dewetting the tip, the West is 4 (M〇〇C, and the dehumidification peak temperature is lower than the 2nd dehumidification peak temperature of 5. (: The above amorphous 皙 helmet is less, the younger dehumidifier 丄W is not a daily inorganic porous body fat; the dehumidification roller will be used in the regeneration * Α & fly and water 丨 tree - C dehumidifier In the middle of the opening surface temperature of the side of the dehumidifying roller of the present invention (2), the surface of the main positive father of the dehumidifying roller is divided into a first carrier carrying the first dehumidifying agent, and carrying a second carrier portion of the second desiccant, and an opening surface temperature of the inlet side of the regeneration air is 250 to 500 ν, watts & ', a manufacturing method of the cylinder, including a dehumidifying roller used in a dehumidifier of c: Producing the first dehumidifying agent carrying 1G (M6()g/m3, and the thickness is
該除濕滾筒相同的溫度測量用滾筒之溫度測量势 作步驟; 衣 將該溫度測量用滾筒設置於除濕機中,並測量再生空氣 入口侧的開口面溫度、及再生空氣出口侧的開口面溫度、, 接著依下式(la),· KT1-15G)/(15()-T2)g(Dl/D2A{(T 卜 25G)/(25G-T2)} (la) (式中,D1係指該第一載持部的厚度(mm) ; D2係指該第二 載持部的厚度(mm);Tl係指再生空氣人口侧的開口面溫 度(C ) , T2係指再生空氣出口侧的開口面溫度(。c ) ; 係 250 C 以上,T2 係未滿 i5〇t:,且 T1+T2 > 30(TC。) 312XP/發明說明書(補件)/96-〇6/961〇8430 9 200800396 驟计异出該第_载持部厚度與該第二載持部厚度的計算步 二f得具有依該計算步驟所計算之該第一载持部厚度的 。亥=载持部之第一载持部製成步驟; 製得具有依該計算步驟所計算之該第二载持部 忒第一载持部之第二载持部製成步驟;以及 、 將^亥第载持部與該第二載持部固定的固定步驟; φ 泫第一除濕劑係脫濕尖峰溫度為90〜160°C的沸石; 2第二除濕劑係脫濕尖峰溫度為4〇〜1〇(rc,且脫濕尖 峰/JBL度較低於該第一除濕劑的脫濕尖峰溫度5°C以上的非 晶質無機多孔質體或吸水性樹脂。 再者本發明(3)所提供的除濕機,係具有上述本發明 (1)所圯載的除濕滾筒,且再生空氣入口侧的開口面溫 為250〜500°c。 又 (發明效果) _根據本务明,便可提供即便使力口熱器溫度低於習知,仍 可具較多的除濕量、且長期間的除濕量降低程度較少之 濕滾筒。 ' 【實施方式】 μ本發明的除濕滾筒係在載體上載持著除濕劑的除濕滾 ,,該除濕滾筒係利用正交於厚度方向的面,分割為載持 著第一除濕劑的第一載持部、以及載持著第二除濕劑的第 二載持部; 該第一除濕劑係脫濕尖峰溫度為9〇〜丨⑽它的沸石; 312ΧΡ/發明說明書(補件)/96-06/96108430 10 200800396 除濕劑係脫濕尖峰溫度為4〇〜i〇(rc,且脱濕尖 /皿又#又低於该第一除濕劑的脫濕尖峰溫 的、 濕劑; 工扪除 該除濕滾筒係將使用於再生空氣入 為250〜50(TC的除濕機中。 面酿度 相關本么明第-形態的除濕滾筒,參照圖1與圖2進行 Γ;所圖Γ示係本發明實施形態例的除濕滚筒示意圖, = 載持部5,第二载心 空氣與再生成,平订於旋轉抽方向’且供被處理 工;…、二氣進行通氣用的通氣空洞4。該第二载样邱 =部形成有平行於旋轉軸方向,且供被處理再 生空氣騎通氣用的通氣空洞4。該第—_部5=, 係D1,該弟二载持部6的厚度係D2。該第一载持邱= ,載持部6.使該第一载持部5 == 開口面,與該第二载持部6的再生空氣入口側:= 之 接觸亚較,即,該除濕滾筒〗係利料厚产 目 的面7分割為該第一載持部5與該 ^ α正父 滾筒1在二端係具有開口面3a: 3b。:開口: 6。該除濕 被處理空氣與再生空氣的a、此係 的中心附近處係設有供滾筒轴安裝用的中心=濕IT 所示,該通氣空洞4係由平坦狀部8 。如圖2 互積層而形成。在該第一载持部5的载體Μ::用交 該第一除濕劑,又,在該第 將载持著 3Ι2ΧΡ/發明說明書(補件)/96-06/96108430 戰符σΡ 6的载體11上將载 11 200800396 持著該第二除濕劑。 =-載持部5的該載體10、與該第二載持部6的謗 椹 ,係如圖2所示,均具有蜂巢式構造。該蜂巢式 構造的該載體10與該載體u,係例如將 " =該平坦狀基材施行瓦愣加工而獲得的瓦愣狀; ::機黏著劑或有機黏著劑’利用該瓦楞狀基材的脊部声 進行黏著並積層而進行製造。此時, 处 與該瓦楞狀基材之間所形成的略半圓 空乳的流路’因而二者便依該空洞朝該除濕滚筒i旋轉= 方向形成的方式進行積層。施行該積層的方法,係例如 對該平坦狀基材與該瓦愣狀基材重疊,並捲取成捲筒狀 且進行積層的方法。圖i與圖2所示係蜂巢式構造 體10與該載體1卜但是該載體10與該載體u的構造並 不,侷限於此,只要在朝滚筒軸的平行方向形成通氣空洞 的前提下便可,其他尚可如擴充蜂巢式構造等。 所以,該除濕滚筒1將使用於再生空氣入口侧的開口面 3b溫度為250〜50(rc的除濕機中。本發明中,所謂「該開 口面3b溫度」係指使除濕滾筒的再生空氣入口侧,即該 開口面3b接觸到熱電偶,且當除濕機運轉時,由該敎電 偶所測得的溫度。相關該開口面溫度參照圖3進行說明。 圖3所示係測量除濕機運轉時之開口面溫度的示意圖,圖 (3-1)所示係除濕機内的除濕滾筒、加熱器及熱電偶之侧 視圖,圖(3-2)所示係除濕機内的除濕滚筒、加熱器及熱 電偶之立體圖。另外,配合說明上的方便,圖3中將省略 312XP/發明說明書(補件)/96_〇6/961〇843〇 12 200800396 其他的構成要件。圖3中,在除濕機内,將於除濕滾筒1 的再生空氣入口侧之開口面3b附近處設置加熱器15,並 對該開口面3b導入經通過該加熱器15的再生空氣17。 然後,當測量該開口面3b溫度之際,便使熱電偶16a接 觸於該開口面3b。該熱電偶16a係由從該加熱器15所產 生的輻射熱18、從經該加熱器15加熱過的該再生空氣17 所產生的熱19、及從該除濕滚筒1所產生的傳導熱2〇等 _ 3種熱而被加熱。所以,所謂「該開口面3b溫度」便指 該輕射熱18、從該再生空氣ι7所產生的熱19、及該傳導 熱20等3種熱而加熱的該熱電偶16a溫度。此外,所謂 「该開口面3a溫度」係指使除濕滾筒的再生空氣出口 側,即該開口面3a接觸到熱電偶i 6b,當除濕機運轉時 利用該熱電偶16b所測得的溫度。 该第一載持部5的載體、及該第二載持部6的載體係纖 、准貝載體或金屬載體。該纖維質載體係能形成平坦狀纖維 質基材的载體。此外,該金屬載體係能形成平坦狀金屬基 材的載體,例如日本專利特開平2〇〇2_2827〇6號公報、或 特開平2G02-28謂號公報所記載的金屬蜂巢式載體。 該纖維質載體的該纖維質基材係由纖維形成的織布或 =气布》亥義維亚無特別的限制,可舉例如:e玻璃纖維一、 Γ維玻^纖t、應纖維、咖纖維、s玻璃纖維、A坡壤 、義、、隹專玻5肖纖維或其切月合广 μ 、 驭(ch〇PPed strand);陶瓷纖維、 室、ί冋鋁紅柱石纖維、二氧化矽纖維、礦棉纖維、 钱料無機藝財_維。錢纖維係可使用諸如: 312ΧΡ/發明說明書(補件)/96·〇6/96108430 13 200800396 聚芳醯胺纖維、尼龍纖維、聚對苯二甲酸乙二 該纖維質載體的纖維係就從提高除濕滾筒強觀、曰 好使用無機纖維。 现j,取 再者’形成該纖維質龍之該_f基材的該纖維 有如.生物讀性無機纖維。該生物溶解性 4〇 C的生理食鹽水溶解率達U以上的無機纖維更;ί 之’該生物溶解性無機纖維係有如:日本專 ; 2_一220037號公報、特開2002-68777號公報、特; 2003-73926號公報、或特開2〇〇3_212596號公報中所; ,的無機纖維’即,諸如:抓與⑽合計含有量達85 L 量%以上,並含有0.5〜3.0質請MgO與2.0〜"質量貝% 的且依德國危險物質規範的致癌性指數⑴值。 4〇以上的無機纖維;以仙2、%〇及削2為必要成益 ::維;以Si〇2、Mg0及氧化鐘為必要成分的無機纖維了 :.Si〇2.52~72 質量%、Al2〇3:3 質量%未滿、_·〇〜?質 ^、(^0:7.5〜9.5質量%、匕〇3:〇〜12質量%、_:〇〜4質 ^'SrO:〇~3.5 f *%^Na2〇:l〇~2〇.5 f * % ^ K2〇 : 〇. 5~4. 〇 質,、及Ρ2〇5:〇〜5質量%的無機纖維;含有:si〇2„ 質 ι%、αι2〇3··ι.0~3·0 質量%、_:16〜2〇 質量 %、 =3. 0〜5· 〇質量%、K2〇及/或Μ:"· 〇質侧無機The same temperature measuring step of the temperature measuring roller of the dehumidifying roller is performed as a step; the temperature measuring roller is placed in the dehumidifier, and the opening surface temperature on the inlet side of the regeneration air and the opening surface temperature on the outlet side of the regeneration air are measured, , then according to the following formula (la), · KT1-15G) / (15 () - T2) g (Dl / D2A { (T Bu 25G) / (25G-T2)} (la) (where D1 refers to The thickness (mm) of the first carrier portion; D2 refers to the thickness (mm) of the second carrier portion; T1 refers to the opening surface temperature (C) on the regenerative air population side, and T2 refers to the regeneration air outlet side. Opening surface temperature (.c); above 250 C, T2 is less than i5〇t:, and T1+T2 > 30(TC.) 312XP/invention manual (supplement)/96-〇6/961〇8430 9 200800396 The difference between the thickness of the first carrier portion and the thickness of the second carrier portion is calculated to have the thickness of the first carrier portion calculated according to the calculation step. a first carrying portion forming step; a second carrying portion forming step of the second carrying portion 忒 first carrying portion calculated according to the calculating step; and a second holding portion With the a fixing step of fixing the second carrier portion; φ 泫 the first dehumidifying agent is a zeolite having a dehumidification peak temperature of 90 to 160 ° C; 2 the second dehumidifying agent has a dehumidification peak temperature of 4 〇 1 〇 (rc, and The dehumidification peak/JBL degree is lower than the amorphous inorganic porous body or the water-absorbent resin having a dehumidification peak temperature of 5 ° C or more of the first dehumidifying agent. Further, the dehumidifier provided by the invention (3) is The dehumidification roller provided in the above (1) of the present invention has an opening surface temperature of 250 to 500 ° C on the inlet side of the regeneration air. (Effect of the invention) _ According to the present invention, it is possible to provide even a heat exchanger The temperature is lower than the conventional one, and the wet roller which has a large amount of dehumidification and has a small degree of dehumidification reduction for a long period of time can be used. 'Embodiment】 μ The dehumidification roller of the present invention is provided with dehumidifying agent on the carrier. Rolling, the dehumidification roller is divided into a first carrier portion carrying the first dehumidifying agent and a second carrier portion carrying the second dehumidifying agent by a surface orthogonal to the thickness direction; The desiccant dehumidification peak temperature is 9〇~丨(10) of its zeolite; 312ΧΡ/invention specification ( ())/96-06/96108430 10 200800396 Dehumidifier dehumidification peak temperature is 4〇~i〇(rc, and dehumidification tip/dish again # is lower than the dehumidification peak temperature of the first dehumidifier, wet In addition to the dehumidification roller, the dehumidification roller will be used in a dehumidifier of 250 to 50 (TC dehumidifier). The dehumidification roller of the present invention is described with reference to Figs. 1 and 2; BRIEF DESCRIPTION OF THE DRAWINGS FIG. 4 is a schematic view of a dehumidification drum according to an embodiment of the present invention, = carrier portion 5, second carrier air and regeneration, flattened in the rotary pumping direction 'and supplied to the processor; Ventilation cavity 4. The second load sample is formed with a venting cavity 4 parallel to the direction of the rotation axis and for breathing the air to be ventilated. The _th portion 5=, the system D1, and the thickness of the second carrier portion 6 is D2. The first carrier Qiu = the carrier portion 6. The first carrier portion 5 == the opening surface, and the contact portion of the regeneration air inlet side of the second carrier portion 6: =, that is, the dehumidification The roller 7 is divided into the first material holding portion 5 and the first positive bearing roller 1 having the opening faces 3a: 3b at both ends. : Opening: 6. The dehumidified air to be treated and the regenerative air a, the center of the system are provided with a center for the drum shaft mounting = wet IT, and the ventilation hole 4 is formed by the flat portion 8. As shown in Figure 2, the layers are formed. The carrier Μ of the first carrier 5: the first dehumidifying agent is used, and the third 载 2ΧΡ/invention specification (supplement)/96-06/96108430 σ Ρ 6 is carried in the first carrier. The carrier 11 will carry the second dehumidifying agent on the 11 200800396. The carrier 10 of the carrier portion 5 and the enthalpy of the second carrier portion 6 have a honeycomb structure as shown in FIG. 2 . The carrier 10 of the honeycomb structure and the carrier u are, for example, a corrugated shape obtained by corrugating the flat substrate; a mechanical adhesive or an organic adhesive is used for the corrugated base The ridge sound of the material is adhered and laminated to manufacture. At this time, the flow path of the slightly semicircular empty milk formed between the corrugated substrate and the corrugated substrate is laminated in such a manner that the cavity is formed in the direction of rotation of the dehumidifying drum i. The method of performing the lamination is, for example, a method in which the flat substrate is superposed on the corrugated substrate, and wound up in a roll shape and laminated. The configuration of the honeycomb structure 10 and the carrier 1 shown in Fig. 2 and Fig. 2 is not limited to the configuration of the carrier 10 and the carrier u, as long as a ventilation hole is formed in a direction parallel to the axis of the drum. Yes, others can be expanded, such as a honeycomb structure. Therefore, the dehumidification drum 1 is used in a dehumidifier in which the temperature of the opening surface 3b on the inlet side of the regeneration air is 250 to 50 (rc). In the present invention, the "opening surface 3b temperature" means the regeneration air inlet side of the dehumidification drum. That is, the opening surface 3b is in contact with the thermocouple, and when the dehumidifier is in operation, the temperature measured by the xenon couple. The opening surface temperature is described with reference to Fig. 3. Fig. 3 shows the measurement of the dehumidifier operation. Schematic diagram of the opening surface temperature, Figure (3-1) shows the side view of the dehumidifying drum, heater and thermocouple in the dehumidifier. Figure (3-2) shows the dehumidifying drum, heater and thermoelectricity in the dehumidifier. In addition, for the convenience of the description, the other components of the 312XP/invention manual (supplement)/96_〇6/961〇843〇12 200800396 will be omitted in Fig. 3. In Fig. 3, in the dehumidifier, The heater 15 is disposed in the vicinity of the opening face 3b on the regeneration air inlet side of the dehumidifying drum 1, and the regeneration air 17 that has passed through the heater 15 is introduced into the opening face 3b. Then, when the temperature of the opening face 3b is measured , the thermocouple 16a is contacted The opening face 3b is formed by the radiant heat 18 generated from the heater 15, the heat 19 generated from the regeneration air 17 heated by the heater 15, and the heat generated from the dehumidification drum 1. The heat of conduction is equal to the heat of the three types of heat. Therefore, the term "the temperature of the opening surface 3b" means the light-emitting heat 18, the heat 19 generated from the regeneration air ι7, and the conduction heat 20, etc. 3 The temperature of the thermocouple 16a is heated and heated. The term "the temperature of the opening surface 3a" means that the regeneration air outlet side of the dehumidification drum, that is, the opening surface 3a is in contact with the thermocouple i 6b, and is used when the dehumidifier is operated. The temperature measured by the thermocouple 16b. The carrier of the first carrier 5 and the carrier fiber, the quasi-shell carrier or the metal carrier of the second carrier 6. The cellulosic carrier can form a flat cell. The carrier of the substrate. The metal carrier is a carrier capable of forming a flat metal substrate. For example, the metal honeycomb described in Japanese Laid-Open Patent Publication No. Hei. No. 2-2, No. 2, No. 2, No. 2, No. 2, No. 2, No. Carrier of the cellulosic carrier There is no particular limitation on the woven fabric or the air cloth formed by the fiber. For example, e-glass fiber, Γ维玻璃^fiber t, fiber, coffee fiber, s glass fiber, A slope , Yi, 隹 special glass 5 Xiao fiber or its cut Yuehe μ, 驭 (ch〇PPed strand); ceramic fiber, room, 冋 冋 mullite fiber, cerium oxide fiber, mineral wool fiber, money inorganic Artisan_dimensional. Money fiber can be used, for example: 312ΧΡ/invention specification (supplement)/96·〇6/96108430 13 200800396 polyarylene fiber, nylon fiber, polyethylene terephthalate The fiber system is used to enhance the strength of the dehumidification drum and to use inorganic fibers. Now, the fiber which forms the _f substrate of the fibrous dragon is, for example, a bio-readable inorganic fiber. The biosoluble 4 〇C physiological saline solution has a dissolution rate of more than U inorganic fibers; ί 'the biosoluble inorganic fiber system is as follows: Japanese Patent; 2_220037, JP-A-2002-68777 The inorganic fiber of the invention, such as: the total content of the grasping and the (10) is more than 85 L%, and contains 0.5 to 3.0. The carcinogenicity index (1) of MgO and 2.0~"% by mass and according to the German hazardous substance specification. Inorganic fiber of 4 〇 or more; it is necessary to use sen, 2, 〇 and 2 to cut into: 维; inorganic fiber with Si〇2, Mg0 and oxidized clock as essential components: .Si〇2.52~72% by mass, Al2〇3:3 mass% not full, _·〇~? Quality ^, (^0: 7.5~9.5% by mass, 匕〇3: 〇~12% by mass, _: 〇~4 quality^'SrO: 〇~3.5 f *%^Na2〇: l〇~2〇.5 f * % ^ K2〇: 〇. 5~4. Tannins, and Ρ2〇5: 〇~5 mass% of inorganic fibers; containing: si〇2„ 质%, αι2〇3··ι.0~ 3·0% by mass, _: 16~2〇% by mass, =3. 0~5· 〇% by mass, K2〇 and/or Μ:"· 〇-side inorganic
Ju隹。此外,該生物溶解性無機纖維射單獨使们種、 或混合使用2種以上。 針對該生理食鹽水溶解率的測量方法進行說明。首先, 將無機纖維經粉碎至200篩目以下的試料ig、及生理食Ju隹. In addition, the biosoluble inorganic fiber is used alone or in combination of two or more kinds. A method of measuring the dissolution rate of the physiological saline solution will be described. First, the inorganic fiber is pulverized to a sample ig of 200 mesh or less, and a physiological food.
312XP/發明說明書(補件)/96-06/96腦30 M 200800396 鹽水150ml裝入於三角燒瓶(300ml)中,並設置於4〇〇c恆 溫箱中。接著,對該三角燒瓶施行每分鐘120次旋轉的水 平振盪,連續施行50小時。經振盪後,施行過濾,針對 所獲得液中含有的矽、鎂、鈣及鋁,利用ICP發光分析測 定各元素的濃度(mg/L)。然後,從該濾液中的各元素濃 度、及溶解前的無機纖維中之各元素含有量(質量,利 用下式(2)計算出生理食鹽水溶解率b(%)。另外,將利用 鲁ICP發光分析所獲得的各元素濃度設定為:石夕元素濃 度:cl(rag/L)、鎂元素濃度:c2(mg/L)、鈣元素濃 度:c3(mg/L)、及鋁元素濃度c4(mg/L),並將溶解前的無 機纖維中之各元素含有量設定為:矽元素含有量:el(質量 W、鎂元素含有量:e2(質量«、鈣元素含有量:e3(質量 %)、及紹元素含有量:e4(質量%)。 B(%) = {濾液量(L)x(cl+c2+C3+C4)xi〇0}/{溶解前的無 機纖維量(mg)x(el+e2 + e3+e4)/l〇〇} (2) _再者,該纖維質載體係在該纖維質載體的纖維間,具有 多數空隙的多孔質體。該纖維質載體的纖維間空隙率通常 係80〜95%,該纖維質載體的厚度通常係〇1〜lmp該纖維 間空隙率係指從纖維質載體表觀體積減去該纖維質載體 中的纖維體積的部分在該纖維質載體表觀體積中所佔的 比例。 該金屬載體的該金屬基材係涵蓋所有的實質平坦狀全 屬材料。該金屬基材的金屬材質並無特別的限制,可舉例 如:銘、白金、不錄鋼、銅等,其中,紹係屬於輕量、加 312XP/發明說明書(補件)/96-06/96108430 15 200800396 工性良好,而硬度、厚度的種類豐富,且廉價,因而屬較 佳材質。 該金屬載體的該金屬基材厚度最好為10〜100//m,尤以 20〜50 // m為佳。若該金屬載體的該金屬基材厚度未滿 1 〇 // m,則經加工後的載體壓縮強度將容易變小,而不符 實用。反之,若該金屬載體的該金屬基材厚度超過 100//m,則該金屬基材的加工性將容易變差,且載體的開 ⑩口率將容易變小,因而除濕滾筒的除濕性能將容易降低。 在该金屬載體的表面上,亦可如日本專利特開 2〇〇2:mm號公報所記載般的設置表面處理層,此情況 下,該第-除濕劑與該第二除濕劑便載持於該表面處理層 〜々你成隊源澴筒1的說明中,雖就該第一載持邱5 =載持部6係記載著將平坦狀基材成形為:;式 !1严在所獲得成形物上載持著除濕劑而獲得,但: 任獲:態的除濕滾筒尚可為依如下述⑴或⑴二 增著該第-除濕劑,並在該第:二: 體上載持著該第二除_的方法。 麟相载 先’製成該第一除濕劑所载持的平坦狀美* 该弟二除濕劑所载持的平坦狀基材,接著;材、及 劑所載持的平坦狀基材、 將該弟一除濕 及該弟-除濕劑所载持的平坦狀 312册發明麵書(補件)/96彻61〇_ π 200800396 载持部的形狀之方 基材,成形為該第一载持部與該 法。 … =構造、舆該第二載持部一構 ^:除濕劑係脫濕尖峰溫度4 9(M6(rc的彿石 :將該弟-除*劑的脫濕尖峰溫度設定在心 可增加除濕滾筒的除渴量。若嗲m ^ ^ murrr , —除濕劑的脫濕尖峰溫 二二广、"貝^再生空氣入口側的開口面溫度較低之 i“牛下,除濕滾筒的除濕量將變少。反之, 劑的脫濕尖缘溫度未滿90t,則因為該彿石將容易劣二、 因而長期間除濕滾筒除濕量降低程度將增加。 另外,本發明中,該脫濕尖峰溫度係指^依下述所求得的 數值。首先,試驗試料在25Ϊ、50%RH中靜置到達飽和為 止而吸附著水分。接著’採取已吸附水分的試驗試料 2〇mg ,並利用微分掃描熱量計從室溫依1〇。〇/分升溫至 6〇〇°C,並測量脫濕能量。然後,將所獲得脫濕能量曲線 的峰頂溫度設定為「該脫濕尖峰溫度」。該脫濕尖峰溫度 係降低溫度時的脫濕容易度指標,例如當沸石a的脫濕尖 峰溫度為150°C,沸石b的脫濕尖峰溫度為1〇〇。〇時,便 表示該沸石b可脫濕的溫度下限,較低於該沸石a可脫濕 的溫度下限。另外,該脫濕尖峰溫度並非直接代表沸石完 全脫濕的溫度。 312χΡ/發明說明書(補件)/96-06/96108430 17 200800396 $弟-除關在耐水熱性試驗的比表面 用上除濕滾筒的除濕量幾乎不致降低,且 期除濕量的觀點’最好為㈠⑽。 ㈣維持初 另外,本發明的該耐水熱性試驗係依以下順序實施. (1) 在上部呈開放的内徑30mm、高度3〇咖玻璃312XP/Invention Manual (supplement)/96-06/96 Brain 30 M 200800396 Saline 150 ml was placed in a conical flask (300 ml) and placed in a 4 °C constant temperature chamber. Next, the Erlenmeyer flask was subjected to a horizontal oscillation of 120 rotations per minute for 50 hours. After shaking, filtration was carried out to determine the concentration (mg/L) of each element by ICP emission analysis for bismuth, magnesium, calcium and aluminum contained in the obtained liquid. Then, the concentration of each element in the filtrate and the content of each element in the inorganic fibers before dissolution (mass, the physiological saline dissolution rate b (%) is calculated by the following formula (2). The concentration of each element obtained by luminescence analysis was set as follows: concentration of lithium element: cl (rag/L), concentration of magnesium element: c2 (mg/L), concentration of calcium element: c3 (mg/L), and concentration of aluminum element c4 (mg/L), and the content of each element in the inorganic fiber before dissolution is set to: 矽 element content: el (mass W, magnesium content: e2 (mass «, calcium content: e3 (mass %), and elemental content: e4 (% by mass) B (%) = {filtrate amount (L) x (cl + c2 + C3 + C4) xi 〇 0} / { amount of inorganic fiber before dissolution (mg x (el+e2 + e3+e4)/l〇〇} (2) Further, the fibrous carrier is a porous body having a plurality of voids between the fibers of the fibrous carrier. The interfiber void ratio is usually 80 to 95%, and the thickness of the fibrous carrier is usually 〜1 to lmp. The interfiber void ratio means the fiber volume in the fibrous carrier is subtracted from the apparent volume of the fibrous carrier. The ratio of the portion of the fibrous carrier to the apparent volume of the fibrous carrier. The metal substrate of the metal carrier covers all of the substantially planar materials. The metal material of the metal substrate is not particularly limited, and for example, : Ming, Platinum, non-recorded steel, copper, etc., among which, Shao is a lightweight, plus 312XP / invention manual (supplement) / 96-06/96108430 15 200800396 good workability, and a wide variety of hardness and thickness, and The thickness of the metal substrate of the metal carrier is preferably 10 to 100 / / m, particularly preferably 20 to 50 / m. If the thickness of the metal substrate of the metal carrier is not full 1 〇 / / m, the compressive strength of the processed carrier will be easily reduced, which is not practical. On the contrary, if the thickness of the metal substrate of the metal carrier exceeds 100 / / m, the processability of the metal substrate will be It is easy to be deteriorated, and the opening ratio of the carrier will be easily reduced, so that the dehumidifying performance of the dehumidifying roller will be easily lowered. On the surface of the metal carrier, it can also be as disclosed in Japanese Patent Laid-Open Publication No. 2:2:mm Documented surface treatment layer, this case The first dehumidifying agent and the second dehumidifying agent are carried in the surface treatment layer 々 々 成 成 成 成 成 成 成 成 成 成 成 = = = = = = = = = = = = = = = = = = = = = = The flat substrate is formed into the following formula: (1) is obtained by strictly holding the desiccant on the obtained molded product, but the dehumidifying roller in any of the following states may be added as follows (1) or (1). a desiccant, and in the second: the body holds the second method of removing _. Lin phase first 'made the first desiccant to hold the flat shape of the beauty * the second two dehumidifier contained a flat substrate, followed by a flat substrate supported by the material and the agent, a dehumidification of the younger brother, and a flat shape of the 312-book invention (supplement)/96 61〇_ π 200800396 The base material of the shape of the carrier is formed into the first carrier and the method. ... = structure, 第二 the second carrier part structure ^: desiccant dehumidification peak temperature 4 9 (M6 (rc of the Buddha: the dehumidification peak temperature of the younger - except * agent can be added to the heart to increase the dehumidification roller The amount of thirst quenching. If 嗲m ^ ^ murrr, - the desiccant peak temperature of the desiccant is two and two wide, and the temperature of the open surface of the inlet side of the regeneration air is lower, the dehumidification amount of the dehumidification roller will be Conversely, if the desiccant sharp edge temperature of the agent is less than 90t, the defoaming roller will be easily inferior, so the degree of dehumidification of the dehumidification roller will increase during the long period. In addition, in the present invention, the dehumidification peak temperature system Refer to the value obtained by the following method. First, the test sample is allowed to stand at 25 Ϊ and 50% RH until it reaches saturation and adsorbs moisture. Then, 'take the test sample with adsorbed moisture 2 〇mg, and use differential scanning heat. The temperature was measured from room temperature to 〇〇/min to 6 ° C, and the dehumidification energy was measured. Then, the peak top temperature of the obtained dehumidification energy curve was set to "the dehumidification peak temperature". The wet spike temperature is an indicator of the ease of dewetting when the temperature is lowered, for example, when zeolite a The dehumidification peak temperature is 150 ° C, and the dehumidification peak temperature of zeolite b is 1 〇〇. When 〇, it means that the lower limit of the temperature at which the zeolite b can be dehumidified is lower than the lower limit of the temperature at which the zeolite a can be dehumidified. The dehumidification peak temperature is not directly indicative of the temperature at which the zeolite is completely dehumidified. 312χΡ/Invention Manual (Supplement)/96-06/96108430 17 200800396 $Different Dehumidification of the Dehumidification Cylinder with the Desuperheating Roller The amount is almost not reduced, and the viewpoint of the amount of dehumidification is '(1)(10). (4) Maintaining the initial, the hydrothermal resistance test of the present invention is carried out in the following order. (1) The inner diameter is 30 mm at the upper portion and the height is 3 〇. Coffee glass
瓶中i叙人〇.5〜2g試驗試料1〜4個,並設置於容積扎的 壓力谷器中。此時,該樣品瓶的設置位置係設置成較後續 :裝入於該壓力容器中之蒸德水水面更靠上方處的灸: 悲’且為使結露水不致滴落於該樣品瓶内,便在該樣品瓶 的開口上方設置防結露水滴落工具。 (2) 在該壓力容器中裝入蒸餾水500ml,並將該壓力容 器密閉。 。(3)將該壓力容器加熱至1〇5Ί〇,並將試驗試料在ι〇5 C、0· 12MPa的水蒸氣中暴露48小時。 (4)經48小時後,將該壓力容器冷卻,並開啟該壓力容 ⑩态且取出試驗試料,便獲得試驗後的試驗試料。 然後,測量該耐水熱性試驗前的試驗試料比表面積 F(mm2/g)、及該耐水熱性試驗後的試驗試料比表面積 G(mm2/g),並依下式(3)求取比表面積降低率H(%)。 H={(F-G)/F}xl00 (3) 另外,該耐水熱性試驗的比表面積降低率,係除濕劑(該 弟一除濕劑或該第二除濕劑)在高溫下重複施行脫濕時的 劣化容易度,即長期間除濕量降低速度的指標。所以,該 耐水熱性試驗的比表面積降低率降低之除濕劑,即便在高 312XP/發明說明書(補件)/96-06/96108430 18 200800396 溫下土重複脫濕純難劣化,反之,該財水熱性試驗的比表 面和降低率較间之除濕劑,在高溫下重複脫濕時將較容易 劣化。 该:-除濕劑係在屬於脫濕尖峰溫度為9〇。⑶彿 =雨提下’其餘並無特別的限制。該沸石的骨架構造並 別的限制,可諸如:A型、X型、八面沸石型等。苴中, 就從脫濕尖峰溫度較低的觀點,最好為八面彿石型「而八 =:石型中則已γ型為特佳。該沸石係依下述一般式⑷ jMxOy · AI2O3 · kSi〇2 /丄… ⑷ (式中,M係指納、舞、稀土族、辞、m鉀、 猛、鐵;X與y值係指!以上的整數,將 j值係0.5〜5,k值係卜20。) 頂歡向…, 該第:除濕劑係有如利用周知合成方法所合成的沸 石,且未施行離子交換處理 成方法所合成的沸石,且未施行二,利用周知合 記為「原沸石」。 “仃離子父換處理的彿石,亦 。該原沸石的脫濕尖峰溫度係125〜16代,最好i3〇〜i45 f ° f外’該料石在耐水熱性試驗巾的比表面積降 率,最好0〜8%,尤以〇〜5%為佳。 貝牛低 即無,位(A1,離子對之氫離子的酸點, T便有亦疋屬…所以,因為沸石中的酸點越 熱Γ驗中的比表面積降低率將越小,因而就長期間除渴 滚甸吸濕量降低程度較小的觀點(即提高除濕滾筒耐= 312XP/發明說明書(補件)/96-06/96108430 19 200800396 的d,弟一除濕劑最好為原沸石。 遠原彿石係可舉例如:原沸石且 :子之:彿石;原沸石且該銘;::::為鈉 因為工業性製造的該原滞石=卸離子的鉀滞石。 廉價的觀點,該第_卜夕’、於鈉沸石,因而就 兮㈣最好為該納彿石。 =::可:用周知彿石之製造方法進行製造。 之離子對::r有如實施將該原彿石的該紹部位 離子對半數以上it施行離子交換,而獲得該銘部位的 二ί虱離子之彿石的氫離子交換步驟,而# 二=用子=彿石。以下’將該原沸石的該銘部位之‘ 對半數以二=施行離子交換,而獲得該銘部位的離子 "女2風離子的沸石,亦記為「氨離子交換彿石」。 二虱雔子父換沸石中,將有較多的鋁部位(Α卜〇一)之離 子,為氫離子的酸點。所以,因為沸石中的酸點越多,脫 濕j峰溫度將越低,因而就增加除濕滾筒的除濕量觀點, $亥第一除濕劑最好為該氫離子交換沸石。 該氫離子交換沸石的脫濕尖峰溫度係90〜14(TC,最好 9〇〜120°C。此外,該氫離子交換沸石在耐水熱性試驗中的 比表面積降低率最好15〜45%,尤以15〜40%為佳。 再者’該第一除濕劑係有如依照:將該原沸石的該銘部 位之離子對,利用氫離子施行離子交換,而獲得氫離子交 換沸石的氫離子交換步驟;以及將該氫離子交換沸石的氫 離子’利用第二金屬離子施行離子交換,而獲得經該第二 312XP/發鴨鴨(綱0/96.06/96108430 20 200800396 金屬離子施行離子交換的彿石 =·而所獲得的第二金屬離子交㈣石== 離子交換沸石的氣離子,利用第 η 將該風 而所獲得,經該第二全屬離 、子施仃離子交換 為「第二金屬離子交子=離:交換的濟石,亦記 二金屬雜子在社t 、 」另外,本發明中,所謂厂第 一金屬離子」係如與利用氫離子施 之該鋁部位離子對為八 又、刖的原沸石 換步驟中,因為°該第二金屬離子交 被該弟二金屬離子施行離子交換,因而該第二金 換沸石巾,仍將殘留著該銘 雜 子乂 酸點。然而,因為,石中的酸點:::對: 越降低,因而該第一除濕劑係就從增 觀點^:最好為該第二金屬離子交換彿石。问的除濕篁 該第二金屬離子交換沸石的 f軟。此外,該第二 财水熱性試驗中的比表面積降低率,最屬好離子:冻石在 15〜30%為佳。 子15〜4(U,尤以 在該氫離子交換沸石或該第二 氣離子交換靖,關於將該輪的銘部 ::子:行離子交換的方法,並無特別的限制可為" 氯化兹水溶液中,_用銨離子,潰於 燥、燒成而實施。 "仃料讀後,經乾 該第二金屬離子交換步驟的第二金屬離子,係只要與在 312XP/發明說明書(補件)勝〇6/961〇8430 21 200800396 該風離子父換步驟中, 離子斑”、施仃離子父換的原沸石鋁部位之 如· M # Μ工 了其餘亚無特別的限制,例 •稀土無離子、鋅離子、錫離子等。 將施行該氫離子令播丰 石之氫離子,利用# 所獲侍的該氫離子交換沸 亚热特別的限制,將可沪立 、的方法 孟屬離子父換步驟係將該氫弟 第二金屬離子的水溶液中之方法:二石:=有該 水溶液係將例如稀土族、 \ 一至屬離子的 鹽、硝酸鴎等、、θ人、、5、々諸如氯化物鹽、硫酸 月四夂麗寺此合於水中而獲得。此 交換步驟亦可在離子交換後,視需要施行;1 一:屬離子 交換沸石的洗淨或乾燥。 ^弟一金屬離子 ★=述,因為工業性製造的該原滞石,大 U而該弟-除濕劑就廉價的觀點 將該原沸石且!巧位的離 取實施: 子,利用氫離子施抒離早六始 離子的納彿石之鈉離 的氫離子交換牛驟]二、❿獲得該氳離子交換沸石 利用該子:=氫離子_石的氫離子, 至屬雔子施打離子交換,而 子交換沸石的第-+屬献工 > 又、以弟一金屬離 金屬離子交換子父換步驟;而所獲得的該第二 位的離子對為=離,二該第一除濕劑最好屬於銘部 :于對為除鈉離子以外的金屬離子之非 再者’以二金屬離子交換彿石的第二全屬離 =族離子,因為該第二金屬離子交料石的脫為稀 低’因而將有助於降低再生空氣入口側的開二度 312XP/發明說明書(補件)/96-06/96108430 22 200800396 故為佳。換言之,該第一除濕劑最好鋁部位的離 土族離子之稀土族沸石。 T马稀 所以,該第一除濕劑(即,該滞石)即便在Μ 對屬未滿〇.15的偏低情況下,仍屬於具有優 的除濕劑。 、注月b 該第二除濕劑係脫濕尖峰溫度為40〜loot,且脫濕,,、 峰溫度較低於該第一除濕劑脫濕尖峰溫度5Ϊ以上的= 質無機多孔質體或吸水性樹脂。藉由將該第二除濕劑^ 濕尖峰:度:定在40〜10{rc範圍内,便可增加除濕滾筒 的除濕篁。若該第二除濕劑的脫濕尖蜂溫度未滿靴, 滾筒的除濕量降低程度將變大,即除濕滾筒 濕:將減ΤΗ二反若超過1〇rC ’則除濕滾筒的除 、里:'夕丨’藉由使該第二除濕劑的脫濕尖峰溫度 較低於該第-除濕劑的㈣㈣Μ代以 除濕滚筒的除濕量。 文』0加 φ該第二除濕劑的脫濕尖峰溫度最好為5〇~95〇c 60〜9(TC為佳。此外,該第二^ 弟一除濕劑的脫濕尖峰溫度,最 好較低於該第-除濕劑的脫濕尖峰溫度2 低40〜80°C為佳。 凡 該第二除濕劑係屬於非晶f無機多孔質體或吸水 脂,而该弟二除濕劑的非晶質 、mn〜lnrrr 機多孔質體係在脫濕尖峰 /m二Γ 。且脫濕尖峰溫度較低於該第一除濕劑 的脫濕尖峰溫度5 °C以上之前挺π 制,可舉例如:二氧化錢餘並無特別的限 一虱化矽-氧化鋁非晶質多 312ΧΡ/發明說明書(補件)/96-06/96108430 23 200800396 孔質體、中孔洞二氧化矽等非晶質無機多孔質體。此外, 該第二除濕劑的吸水性樹脂係在脫濕尖峰溫度為〜丨⑽ C,且脫濕尖峰溫度較低於該第一除濕劑的脫濕尖峰^卢 5^C以上之前提下,其餘並無特別的限制’可舉例如 交換樹脂、聚丙烯酸鹽樹脂、環氧烷樹脂。另外,該a二 除濕劑係可單獨使用“重、或混合使用2種以上, 〇亥非日日貝無機多孔質體與該吸水性樹脂的組合。,1 to 4 test samples of 5 to 2 g in the bottle, and placed in a volumetric pressure barn. At this time, the setting position of the sample vial is set to be more subsequent: the moxibustion is placed on the upper side of the steamed water surface in the pressure vessel: sadly, and so that the dew condensation water does not drip in the sample bottle, An anti-condensation drop tool is placed over the opening of the vial. (2) 500 ml of distilled water was placed in the pressure vessel, and the pressure vessel was sealed. . (3) The pressure vessel was heated to 1 〇 5 Torr, and the test sample was exposed to water vapor of ι 5 C, 0·12 MPa for 48 hours. (4) After 48 hours, the pressure vessel was cooled, and the pressure capacity was turned on and the test sample was taken out to obtain a test sample after the test. Then, the specific surface area F (mm2/g) of the test sample before the hydrothermal resistance test and the specific surface area G (mm2/g) of the test sample after the hydrothermal resistance test were measured, and the specific surface area was reduced according to the following formula (3). Rate H (%). H={(FG)/F}xl00 (3) In addition, the specific surface area reduction rate of the hydrothermal resistance test is when the dehumidifying agent (the dehumidifying agent or the second dehumidifying agent) is repeatedly subjected to dehumidification at a high temperature. Ease of deterioration, that is, an index of the rate of decrease in the amount of dehumidification during a long period of time. Therefore, the desiccant having a reduced specific surface area reduction rate in the hydrothermal resistance test is difficult to degrade even if it is repeatedly dehumidified at a high temperature of 312XP/invention specification (supplement)/96-06/96108430 18 200800396, and vice versa. In the heat test, the specific surface area and the lowering rate of the dehumidifying agent are more likely to deteriorate when the dehumidification is repeated at a high temperature. The:-dehumidifying agent is at a dehumidification peak temperature of 9 〇. (3) Buddha = rain is raised. There are no special restrictions on the rest. The skeleton structure of the zeolite is not particularly limited and may be, for example, a type A, an X type, an faujasite type or the like. In the sputum, from the viewpoint of the lower temperature of the dehumidification peak, it is preferable to be the octahedron type "and the eight =: the γ type is particularly good in the stone type. The zeolite is based on the following general formula (4) jMxOy · AI2O3 · kSi〇2 /丄... (4) (In the formula, M refers to nano, dance, rare earth, rhetoric, m potassium, fierce, iron; X and y values refer to! The above integer, the value of j is 0.5~5, The value of k is 2020.) The top: the desiccant is a zeolite synthesized by a known synthesis method, and the zeolite synthesized by the ion exchange treatment method is not subjected to the method, and the second method is used. It is "original zeolite". "The cesium ion parent is treated with the Buddha stone. Also, the dewetting peak temperature of the original zeolite is 125~16 generations, preferably i3〇~i45 f ° f outside the specific surface area reduction rate of the stone in the heat resistant test towel. Preferably, 0 to 8%, especially 〇~5% is preferred. Bei Niu is low, no (A1, the acid point of the hydrogen ion of the ion pair, T is also a genus...so, because of the acid in the zeolite The hotter the point is, the smaller the specific surface area reduction rate will be, so that the degree of decrease in the moisture absorption of the thirst is reduced during the long period of time (ie, improving the dehumidification roller resistance = 312XP / invention manual (supplement) / 96- 06/96108430 19 200800396, d, the dehumidifier is preferably the original zeolite. The Yuanyuan Buddha stone can be, for example, the original zeolite and: sub-foun: Buddha stone; the original zeolite and the Ming;:::: for sodium Industrially produced this raw stagnation stone = potassium stagnation of unloading ions. From a cheap point of view, the _ _ _ _ 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 The method of manufacturing the Buddha stone is carried out. The ion pair::r is obtained by performing ion exchange on the portion of the original part of the original Buddha stone by more than half of it. The hydrogen ion exchange step of the phoenix ion of the two 虱 虱 ion, and #二 =用子=佛石. The following 'the original part of the original zeolite' of the 'half number of two = ion exchange, and obtain the name The ion of the part of the female " female 2 wind ion is also recorded as "ammonia ion exchange Buddha stone". In the diterpene parent exchange zeolite, there will be more ions of the aluminum part (Α卜〇一), which is hydrogen The acid point of the ion. Therefore, since the acid point in the zeolite is more, the dehumidification j peak temperature will be lower, and thus the dehumidification amount of the dehumidification drum is increased, and the first dehumidifying agent is preferably the hydrogen ion exchange zeolite. The deionization peak temperature of the hydrogen ion exchanged zeolite is 90 to 14 (TC, preferably 9 Torr to 120 ° C. Further, the hydrogen ion exchange zeolite preferably has a specific surface area reduction rate of 15 to 45% in the hydrothermal resistance test, In particular, it is preferably 15 to 40%. Further, the first dehumidifying agent is obtained by ion ion exchange of hydrogen ions at the ion pair of the original zeolite. a step; and utilizing the hydrogen ion of the hydrogen ion exchanged zeolite The second metal ion is subjected to ion exchange, and the second metal ion exchanged (four) stone obtained by the second 312XP/duck duck (the 0/96.06/96108430 20 200800396 metal ion ion exchanged Buddha stone is obtained == The gas ions of the ion-exchanged zeolite are obtained by using the η to obtain the wind, and the second all-ion and the sub-salt ion exchange are "the second metal ion interon = the exchange: the exchanged stone, and the second metal In the present invention, the so-called first metal ion is used in the step of replacing the original zeolite with an ion pair of argon and argon by the application of hydrogen ions, because the second The metal ion exchange is ion exchanged by the second metal ion, so that the second gold-forward zeolite towel will still retain the sulphuric acid point. However, because the acid point in the stone:::pair: the lower, the first desiccant system is increased from the viewpoint of: preferably, the second metal ion exchanges fossil. Asked for dehumidification 篁 The second metal ion exchange zeolite f soft. In addition, the specific surface area reduction rate in the second financial heat test is the most good ion: the frozen stone is preferably 15 to 30%. Sub- 15~4 (U, especially in the hydrogen ion exchange zeolite or the second gas ion exchange Jing, there is no particular limitation on the method of the wheel of the inscription:: sub: row ion exchange) In the aqueous solution of chlorinated solution, _ is carried out with ammonium ions, and is dried and calcined. " After reading, the second metal ion of the second metal ion exchange step is dried as long as it is in the 312XP/invention specification. (Supplement) Sheng Sheng 6/961 〇 8430 21 200800396 In the wind ion father replacement step, the ion plaque", the original zeolitic aluminum portion of the Shiyan ion parent, such as · M # completed the remaining Asian no special restrictions, Example: Rare earth has no ions, zinc ions, tin ions, etc. The hydrogen ion will be applied to the hydrogen ion of the soda stone, and the hydrogen ion exchanged by the # is the special limitation of the boiling heat. The method of changing the parent of the genus genus is the method of the second metal ion in the aqueous solution of the hydrogen hydride: two stones: = the aqueous solution is, for example, a rare earth group, a salt of a genus ion, a cerium nitrate, etc., θ human, 5, such as chloride salt, sulfuric acid, the four-year-old temple in the water and This exchange step can also be carried out after ion exchange, as needed; 1: Washing or drying of the ion-exchanged zeolite. ^Di-metal ion ★== because of the industrially manufactured raw stagnation stone, large U And the younger-dehumidifying agent is cheaper to implement the separation of the original zeolite and the smart position: sub-hydrogen ion exchange with the hydrogen ion of the Nafite of the early six ions And obtaining the ytterbium ion-exchanged zeolite using the hydrogen ion of the sub-type: = hydrogen ion_stone, to the ion exchange of the genus scorpion, and the -+ genus of the sub-exchanged zeolite> The metal ion exchange sub-family replaces the step; and the ion pair of the second position obtained is =, and the first dehumidifier is preferably belonged to the inscription: the non-renewer of the metal ion other than the sodium ion The second metal ion exchange of the second all-ion = group ion, because the second metal ion exchange stone is thin, which will help reduce the opening degree of the regeneration air inlet side 312XP / invention specification (supplement) /96-06/96108430 22 200800396 It is better. In other words, the first The desiccant is preferably a rare earth zeolite derived from a terrestrial ion at the aluminum portion. Therefore, the first dehumidifying agent (i.e., the staghorn) is still in a low degree of Μ to 15 未. It has excellent dehumidifying agent. The second dehumidifying agent has a dehumidification peak temperature of 40~loot, and dehumidification, and the peak temperature is lower than the dehumidification peak temperature of the first dehumidifier by more than 5Ϊ. The inorganic porous body or the water-absorbent resin can increase the dehumidification enthalpy of the dehumidification drum by setting the second desiccant: the wetness peak: in the range of 40 to 10 {rc. If the second desiccant is off If the temperature of the wet tip is not full, the degree of dehumidification of the drum will be reduced, that is, the dehumidification roller will be wet: if the dehumidification is more than 1〇rC', then the dehumidification roller will be removed. The dehumidification peak temperature of the second desiccant is lower than the dehumidification amount of the dehumidification drum of (4) (4) of the first dehumidifying agent. The dehumidification peak temperature of the second dehumidifier is preferably 5〇~95〇c 60~9 (TC is better. In addition, the second dehumidifier dehumidification peak temperature is best. It is preferable that the dehumidification peak temperature lower than the first desiccant is lower than 40 to 80 ° C. Where the second dehumidifying agent belongs to the amorphous f inorganic porous body or the water absorption grease, and the second dehumidifying agent is not The crystal, mn~lnrrr machine porous system is at the dehumidification peak/m Γ, and the dehumidification peak temperature is lower than the dehumidification peak temperature of the first dehumidifier by 5 °C or more, for example: There is no special limit for the amount of carbon dioxide. Amorphous bismuth-alumina amorphous 312ΧΡ/invention specification (supplement)/96-06/96108430 23 200800396 Amorphous inorganic body such as pores and mesopores In addition, the water-absorbent resin of the second desiccant is at a dehumidification peak temperature of ~丨(10) C, and the dehumidification peak temperature is lower than the dehumidification peak of the first desiccant. Before the mention, there are no special restrictions on the rest 'for example, an exchange resin, a polyacrylate resin, an alkylene oxide resin. In addition, the a two division Based agents may be used alone, "weight, or a mixture of two or more kinds, combinations of non-square Hai day Pui inorganic porous body and the water-absorbent resin.,
另外,該二氧化石夕-氧化銘非晶質多孔質體係由 石夕與氧化銘形成的凝膠,例如日本專利特開昭 號公報中所記載者。此外,該中孔洞二氧切係指 :質具有中孔的多孔體’例如日本專利特表平5 號公報中所記載者。 " 弱酸性 陰離子 日該離子交換樹脂係可為強酸性陽離子交換樹脂、 陽離子交換樹脂、強驗性陰離子交換樹 交換樹脂中任一者。 籲該聚丙烯酸鹽樹脂係可舉例如:聚丙烯酸鹽交聯 父聯聚丙烯酸鹽、澱粉_丙烯酸鹽接枝 乙烯醇-丙烯酸_ i£哿物、不p * 版又如物、 解物等。物㈣㈣共聚合體交聯物的水 泫衣减a係⑽氧㈣聚合物, 乙烷聚合物、聚環氧丙烷聚合」·來锹虱 烷聚合物等。 “勿A乳乙烷-聚環氧丙 該第二除濕劑係有如:二氧化石夕凝膠、二氧化石夕—氧化紹 非晶質多孔質體或中孔洞二氧切,因為當再生空氣入口 312XP/發明說明書(補件)/96_06/961()843() 24 200800396 側的開口面溫度為400〜5〇(rc時,將增加除 所 礼/·生目而就对熱性較高的觀點,將屬較 貝。此外,該第二除濕劑係有如:離子交換樹脂 酸,樹脂或環氧坑樹脂,就即便再生空氣入開= :度為跡35吖的遠低於習知情況下,仍可獲得:二 除濕滾同除濕量之觀點,將屬較佳材質。 ’ 驗二二該:晶質無機多孔質體在耐水熱性試 筒的除濕量,=二?上幾乎不致降低除濕滾 15*尤二:ΓΓ量的觀點,最好為 b(U為佳,更以15〜50%為佳。 再者,該二氧化矽凝膠、該二 孔質體、及該中孔洞二氧切在二化:~乳化銘非晶質多 仔极* : 熱輯驗中的比表面 =低率,取好為15傷尤以15~而為佳,更以15〜_ 該非晶質無機多孔質體及該吸水性樹 水相對壓達°.15以上的較高情況時,仍屬於且有= 濕性能的除濕劑。 、/、有k越及 j該第-載持部5的載體1〇、該纖 基材上,載持著該第一除濕劑的方法並 2 = 舉例如=該載冑1〇、該纖維質基材或該金屬基材V在含 ^該弟-除濕劑與減_漿料中施行輯 =理的方法。該浸潰處理係例如利用在含有 = 與:結劑的聚:中’靜置著該載㈣、該纖維質:文 該最屬基材而貝施。此外,該塗佈處理係例如對該載體 312XP/發明說明書(補件)/96-06/96108430 25 200800396 …該纖維質基材或該金屬基材上,將 與黏結劑的漿料’利用諸如輥塗機涂第-除濕劑 實施。同樣的,在該第二载㈣ 、H施行塗伸而 =或該金屬基材上’载持著該第二除:二:纖維質 扣別的限制,可舉例如將該第二载.·' 〇方法,並無 纖維質基材或該金屬基材,在含有該 、、载體11、該 的聚料中施行浸潰處理或塗佈處理的方去除濕劑與黏結劑 =黏結劑並無特別的限制,可舉例如:二氧 石夕酉夂鹼、氧化銘溶朦、二氧化鈦溶膠等。 夕轉、 5的厚度D1相對該第二载持部6的厚度 D 2之比’大約0 · 1〜9,最好〇 1 β β丄 又 再者,该弟一载持部5的厚度D1相對古亥 立 的厚度D2之比,最好収下式(la): Up 6 {(T1-150)/(150-T2)}^(D1/D2)^{(T1-250)/(250-T2)} α λ (t:,:係指第一載持部5的厚度;D2係指第二载:部 籲6的厗度,T1係指再生空氣入口側的開口面%溫度(。〇); Π係指再生空氣出口側的開口面扑溫度(。〇 ; τι係Μ。 °C 以上,T2 係未滿 151TC,且 Tl+T2> 300°c ) 。尤以該第一載持部5的厚度D1相對該第二載持部β的 厚度D2之比,滿足下式(ib): {(Tl-170)/(170-T2)}^(Dl/D2)^{(Tl-230)/(230-T2)}⑽) 為更佳’並以該第一載持部5的厚度D1相對該第二載持 部6的厚度D2之比,滿足下式(ic): KTM9〇)/(190-T2)}2(D1/D2)2{(T1-210)/(210-T2)} 〇c) 312XP/發明說明書(補件)/96-06/96108430 26 200800396 為特佳。藉由使該第一载持部的厚 厚度之比能滿足上式,當除::弟-载持部的 溫度為25〇〜_的除_^用於開口面扑 :Γ5—條件下,仍可獲得較多:= 本發明的除濕滾筒係可使 口側之開口面、㈣第一載持部的再生空氣出 ,、4弟—载持部的再 面相接觸,且亦可使該第-载持部的再:空氣出::開口 離。 生二軋入口側之開口面相遠 使該第-载持部的再生空氣出口侧外 载持部的再生空氣人σ側之開口面^ ”該弟二 ;先:別製作該第一除濕劑所载持;筒及:、 載持的該第二载持部爰 口 Ρ的再生空氣出口侧 夂丹伋这弟一載持 氣入口側之開口面相接觸之二與载持部的再生空 二载持部進行固定而所製^ 亥弟一载持部與該第 =著該第一除濕劑與該第二除;劑二:可f-:载體上載 由該第一载持部所形成的部分,利用入古將該載體中 黏結劑的裝料施行浸潰户王"用s有該第一除濕劑與 該第-载持部所形成的;分=!,而使該载體中由 將該载體u該第二载持部广除濕劑,然後, 二除濕劑與黏結劑的漿料施行分,利用含有該第 該载體中由該第二载持部㈣m理或塗佈處理,而使 〆成的σ卩分载持著該第二除 312ΧΡ/發明說明書(補件跡__卿 27 200800396 濕劑而進行製造。 使該第一载持部的再生空氣 载持部的再生空氣人σ側門'開σ面、與該第二 可在該第—載 :開口面相运離的除濕滚筒,係 载持部的再生空氣入口侧開口面、與該第二 如金屬網),並隔著該中空^物面耸間插人中空間隔物(例 該第二載持部進行固定而所載持部與 載持部的再生空氣出D側之開 =氣入D侧之開口面相遠離,並將 進行製造。而此情況下,該第一載持部的再生:氣 之開口面、與該第二載持部的再生空氣 口面間之距離,最好設定在5随以内。 。二:::„空氣入口側的開口面溫度為25。,〇 的除濕機中之除濕滾筒的製造方法( :除:滾筒之製造方法」),係利用對厚度方向 刀剎為載持者第一除濕劑的第一载持部、盥 二除濕劑的第二載持部,且將制於再生空“ 口侧的開 口面溫度為250〜50(TC的除濕機中之除濕滾筒 方 法,包括有: 製作出载持著l〇〇~16〇g/m3該第一除濕劑,且厚度與該 除濕滾筒相同的溫度測量用滾筒之溫度測量用=== 步驟; 问衣邗 將該溫度測量用滚筒設置於除濕機中,並測量再生空氣 入口側的開口面溫度、與再生空氣出口側的開口面溫1轧 312XP/發明說明書(補件)/96-06細08430 28 200800396 然後,依照下式(la): {(T1-150)/(15{KT2)}2(D1/D2)2{(T1-250)/(250-T2)} (la) (式中,D1係指該第一載持部的厚度(mm) ; D2係指該第二 - 載持部的厚度(mm) ; T1係指再生空氣入口側的開口面溫 . 度(°C ) ; T2係指再生空氣出口側的開口面溫度(°C ) ; T1 係 250T:以上,T2 係未滿 150^,且 T1+T2〉300t ) ,最好依照下式(lb): {(T1-170)/(170-T2)}2(D1/D2)2{(T1-230)/(23042)} (lb) ®,尤以依照下式(lc)為佳: {(T1-190)/(190-T2)}2(D1/D2)2{(T1-210)/(210-T2)} (lc) ,計算出該第一載持部厚度、與該第二載持部厚度的計算 步驟; 製得具有依該計算步驟所計算之該第一載持部厚度之 第一載持部的第一載持部製成步驟;、 製得具有依該計算步驟所計算之該第二載持部厚度之 馨第二載持部的第二載持部製成步驟;以及 將該第一載持部與該第二载持部施行固定的固定步驟; 其中, 該第一除濕劑係脫濕尖峰溫度為90〜160°C的彿石; 該第二除濕劑係脫濕尖峰溫度為40〜100°C,且脫濕尖 . 峰溫度較低於該第一除濕劑的脫濕尖峰溫度5°C以上的除 濕劑; 該除濕滾筒係使用於再生空氣入口側的開口面溫度為 250〜500°C的除濕機中。 312XP/發明說明書(補件)/96-06/90108430 29 200800396 換言之,本發明除濕滾筒之 第一載持部5的厚度D1相對1 ,,糸預先計算出該 該第二載持部6之厚度ϋ2:Γ著?4 ::之有厚度D〗、與 度的第一载持部與第二载 妒%衣于一有所叶异之厚 持部盥嗲第A 後,將所獲得該第—载 該溫度:二=定的除濕滾筒之製造^ ^ 度而里用滾同製作步驟,係 厚度的載體,然後在與該除 二除濕滾同相同 :、該弟-载持部上所载持第一除濕劑 將 二:依刚,(W载持量施行載二;= 滾筒。該溫度測量用滾筒中,與該 二==用 再者,本發明除濕滾筒之㈣部的載體。 一載捭邱夕截Μ ^门之衣以方法中,第一载持部、第 载持邛之载體、苐—除濕劑、第二载持 的载體與第二除濕劑,係如同本發明:m 部、第-载持部之載體、第一除濕劑、第=二-j持 载持部之載體及第二除濕劑。 夺。p、第二 5亥计异步驟係在已設置降μ 、 度測量用滾筒,並測量再生:二口 =機中’設置該溫 屮〇加从 里冉生工軋入口侧的開口面溫度、盥 截側㈣Π面溫度’再根據所獲得數值,計算出^ 、部厚度與該第二载持部厚度的步驟。 Μ 該第-載㈣製成㈣亦可首先製 :::計算得第-載持部厚度的載體,然後再二 濕劑而製得該第-载持部,或者亦可首先在適當^^ 312ΧΡ/發明說明書(補件)/96-06/96應430 3〇 200800396 體上載持著該第— 皙杧坌一、μ —除濕劑,然後切片成依該計算步驟所計 ί于鄱姓载持部的厚度’而製得該第-載持部。此外,該 弟一载持部贺忐at 該金屬基材上二f亦可首先在平坦狀該纖維質基材或 第一除濕劑的第一除濕劑,然後將已载持著該 得該第-载持部/貝基材或該金屬基材施行成形,而製 上,載持著該;二=、該纖維質基材或該金屬基材 如將該载體、該纖亚無特別的限制’可舉例 一除濕南1盥斑Γ、貝土材或該金屬基材,利用含有該第 法。…劑的漿料施行浸潰處理或塗佈處理的方 料中,藉由靜置著3有該弟一除濕劑與黏結劑的漿 實施。此外,、亥塗;t 纖維質基材或該金屬基材而 或該金丄在該載體、該纖維質基材 使用諸如嶋、濕劑與黏結劑的聚料’ 部製成步驟中製得Ί施口二而實施。該第二載持 部厚度的該第二戴持部之情況,亦 -载持 同之外’其餘均如同上 :斤载持的除濕劑不 具有依該计异步驟所計算之第一 衣仵 持部之情況。 寺邛;度的該第一载 ^結劑並無㈣的限制,可舉例如: 矽酸鹼、氧化鋁溶膠、二氧化鈦溶膠等。 夕鱗、 該固定步驟中,將該第一载持部與該 定的方法,係可例如下述的方去戰符部施行固 (1)依使該第-载持部的再生空氣出則 风 < 開D面、與 3I2XP/發明說明書(補件)/96-06/96108430 200800396 =,_载,部的再生空氣人口側之開口面相接觸 工’將该第-載持部與該第二載持部施行固^;、 —(⑴在該第—载持部的再生空氣出口側 第二載持部的再生介, 面、兵該Further, the dioxide-oxidized amorphous porous system is a gel formed by Shi Xi and Oxidation, and is described, for example, in Japanese Laid-Open Patent Publication. Further, the mesoporous dioxate means a porous body having a mesoporous body, for example, as described in Japanese Patent Laid-Open No. Hei-5. " Weakly acidic anion The ion exchange resin may be any of a strongly acidic cation exchange resin, a cation exchange resin, and a strong anion exchange tree exchange resin. The polyacrylate resin may, for example, be a polyacrylate cross-linking parent polyacrylate, a starch-acrylic acid graft, a vinyl alcohol-acrylic acid, or a p* version. (4) (4) Water of the crosslinked product of the copolymer, a system (10) oxygen (tetra) polymer, ethane polymer, polypropylene oxide polymerization, and decane polymer. "Do not A-lactethane-polyepoxypropylate. The second dehumidifying agent is such as: dioxide dioxide gel, silica dioxide, oxidized amorphous porous body or mesoporous dioxo, because when the regeneration air Entrance 312XP / invention manual (supplement) / 96_06 / 961 () 843 () 24 200800396 side of the open surface temperature is 400 ~ 5 〇 (rc, will increase the heat of the ritual / · life and high In addition, the second desiccant is such as: ion exchange resin acid, resin or epoxy pit resin, even if the regeneration air is opened = : the degree is trace 35 远 is far lower than the conventional case , still available: the second dehumidification roll with the dehumidification point of view, will be a better material. 'Test two two: the crystalline inorganic porous body in the water-resistant heat test tube dehumidification, = two? almost no reduction in dehumidification roll 15* especially two: the viewpoint of the amount of strontium, preferably b (U is better, more preferably 15 to 50%. Further, the cerium oxide gel, the two pores, and the medium pores Cut in the second: ~ emulsified Ming amorphous multi-pole *: The specific surface of the heat test = low rate, take 15 damage, especially 15 ~ and better, more 15~ _ When the relative pressure of the amorphous inorganic porous body and the water-absorbing tree water is higher than or equal to or higher than 15.15, it is still a dehumidifying agent having a wet performance. /, and k is the same as the first load. The carrier 1 of the holding portion 5, the method for carrying the first dehumidifying agent on the fiber substrate, and 2 = for example, the carrier substrate, the fibrous substrate or the metal substrate V is contained The method of applying the code to the dehumidifier and the de-slurry is used. The dipping treatment is used, for example, in the presence of a mixture of = and : a mixture of the agent (4), the fiber: The coating process is, for example, the carrier 312XP/invention specification (supplement)/96-06/96108430 25 200800396 ... on the fibrous substrate or the metal substrate, The slurry of the binder is carried out by applying a first-dehumidifying agent such as a roll coater. Similarly, in the second load (4), H is applied for coating = or the metal substrate is carried with the second divided: The limitation of the fibrous fastener may be, for example, the second carrier-containing method, and the fibrous substrate or the metal substrate is not contained therein, and the carrier 11 and the carrier are contained therein. The desiccant and the binder are not particularly limited as long as the impregnation treatment or the coating treatment is carried out in the material, and examples thereof include dioxetine, oxidized insoluble cerium, titanium oxide sol, and the like. The ratio of the thickness D1 of the fifth portion to the thickness D 2 of the second carrier portion 6 is about 0 · 1 to 9 , preferably 〇 1 β β 丄. Further, the thickness D1 of the carrier-bearing portion 5 is relatively old. The ratio of thickness D2 of Haili is best to accept the formula (la): Up 6 {(T1-150)/(150-T2)}^(D1/D2)^{(T1-250)/(250-T2 }) α λ (t:,: refers to the thickness of the first carrier 5; D2 refers to the second load: the degree of the portion 6, and T1 refers to the opening surface % temperature of the regeneration air inlet side. 〇); Π refers to the opening surface temperature of the regenerative air outlet side (.〇; τι系Μ. °C or more, T2 is less than 151TC, and Tl+T2> 300°c). In particular, the ratio of the thickness D1 of the first carrier portion 5 to the thickness D2 of the second carrier portion β satisfies the following formula (ib): {(Tl-170)/(170-T2)}^(Dl/ D2)^{(Tl-230)/(230-T2)}(10)) is better and satisfies the ratio of the thickness D1 of the first carrier portion 5 to the thickness D2 of the second carrier portion 6 Formula (ic): KTM9〇)/(190-T2)}2(D1/D2)2{(T1-210)/(210-T2)} 〇c) 312XP/Invention Manual (supplement)/96-06 /96108430 26 200800396 is especially good. By making the ratio of the thickness of the first carrier portion satisfy the above formula, when the temperature of the second-carrier portion is 25 〇 _ _ is used for the opening face flap: Γ 5 - Still more can be obtained: = The dehumidification roller of the present invention can make the opening surface of the mouth side, (4) the regeneration air of the first carrier portion, and the rear face of the four-carrier portion, and can also make the first - Re-loading of the carrier: air out:: opening. The opening surface of the inlet side of the second rolling is farther away from the opening surface of the regeneration air outlet side of the first carrier-receiving portion on the regeneration air outlet side of the first carrier portion. Carrying; cylinder and:, the second carrier holding portion of the reclaimed air outlet side of the port 夂 汲 汲 汲 汲 汲 汲 汲 汲 汲 汲 汲 汲 汲 汲 汲 汲 汲 汲 汲 汲 汲 汲 汲 汲 汲 汲The holding portion is fixed and the prepared portion is the first dehumidifying agent and the second dividing agent; the second agent: the f-: carrier is loaded by the first carrier portion In part, using the charge of the binder in the carrier to be impregnated with the first desiccant and the first-carrier portion; The second carrier portion of the carrier u is widely used as a desiccant, and then the slurry of the second desiccant and the binder is applied, and the second carrier portion (four) is coated or coated by the carrier. Processing, and the 卩 卩 卩 持 持 持 持 ΧΡ ΧΡ ΧΡ ΧΡ 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 a regenerative air sliding door of the regenerative air carrier, a σ plane, and a second dehumidification drum that can be transported away from the first surface: the regenerative air inlet side opening surface of the carrier Second, such as a metal mesh, and a hollow spacer is interposed between the hollow surfaces (for example, the second carrier is fixed, and the regenerative air from the carrier and the carrier is opened D side = The opening surface of the gas entering D side is far away and will be manufactured. In this case, the regeneration of the first carrier portion: the distance between the opening surface of the gas and the surface of the regeneration air of the second carrier portion is the most It is set to be within 5 degrees. 2:::„The opening surface temperature of the air inlet side is 25. The manufacturing method of the dehumidifying drum in the dehumidifier of the dehumidifier (: except: the manufacturing method of the drum)) The directional knife brake is the first carrier portion of the carrier first dehumidifying agent and the second carrier portion of the second dehumidifying agent, and the opening surface temperature of the retentive side is 250~50 (TC dehumidification) The dehumidification roller method in the machine includes: preparing the carrier to hold l〇〇~16〇g/m3, the first division Wet agent, and the temperature measurement of the same temperature measuring roller as the dehumidification roller === step; the clothing is set in the dehumidifier, and the temperature of the opening surface on the inlet side of the regeneration air is measured, With the surface temperature of the opening side of the regeneration air outlet 1 rolling 312XP / invention manual (supplement) / 96-06 fine 08430 28 200800396 Then, according to the following formula (la): {(T1-150) / (15{KT2)} 2 (D1/D2)2{(T1-250)/(250-T2)} (la) (wherein D1 is the thickness (mm) of the first carrier; D2 is the second-bearing The thickness of the part (mm); T1 means the opening surface temperature of the regenerative air inlet side (°C); T2 means the opening surface temperature of the regenerative air outlet side (°C); T1 is 250T: above, T2 is not Full 150^, and T1+T2>300t), preferably according to the following formula (lb): {(T1-170)/(170-T2)}2(D1/D2)2{(T1-230)/(23042 )} (lb) ®, especially in accordance with the following formula (lc): {(T1-190)/(190-T2)}2(D1/D2)2{(T1-210)/(210-T2) } (lc), calculating a thickness of the first carrier portion and a thickness of the second carrier portion; and obtaining a thickness of the first carrier portion calculated according to the calculating step a first carrier portion of the first carrier portion is formed; and a second carrier portion having a second carrier portion having a thickness of the second carrier portion calculated according to the calculating step is formed And a fixing step of fixing the first carrier portion and the second carrier portion; wherein the first dehumidifying agent is a dehumidification peak having a peak temperature of 90 to 160 ° C; the second desiccant system Dehumidification peak temperature is 40~100 ° C, and the dehumidification tip is lower than the desiccant peak temperature of the first desiccant 5 ° C or more; the dehumidification roller is used on the inlet side of the regeneration air The dehumidifier has an open surface temperature of 250 to 500 ° C. 312XP/Invention Manual (Supplement)/96-06/90108430 29 200800396 In other words, the thickness D1 of the first carrier portion 5 of the dehumidifying drum of the present invention is relatively 1, and the thickness of the second carrier portion 6 is calculated in advance. ϋ 2: Γ ? ? :: The thickness of the D 〗, and the first carrier and the second 妒% clothing in a different layer of the thick 持 盥嗲 A, will get the first - carrying the temperature: two = fixed dehumidification drum manufacturing ^ ^ degrees and using the same manufacturing steps, the thickness of the carrier, and then the same as the de-wetting roller: Holding the first dehumidifying agent will be two: according to the following, (W carrying capacity is carried out; = roller. The temperature measuring roller, and the second == used again, the carrier of the (four) portion of the dehumidifying roller of the present invention. According to the method of the present invention, the first carrier, the carrier carrying the crucible, the deuterium-dehumidifying agent, the second carrier and the second dehumidifying agent are as in the present invention. :m part, the carrier of the first-carrier portion, the first dehumidifying agent, the carrier of the second-j holding unit, and the second dehumidifying agent. The second step is set in the second and second steps. Drop the μ, measure the roller, and measure the regeneration: two = the machine 'set the temperature 屮〇 plus the opening surface temperature from the inlet side of the 冉 冉 轧 盥, 盥 侧 ( (4) Π surface temperature ' and then calculate the value based on the obtained value ^, the thickness of the portion and the thickness of the second carrier portion. Μ The first-load (four) can be made into (4) first::: the carrier of the thickness of the first-carrier portion is calculated, and then the wettizer is prepared. The first-carrier, or may first be carried on the appropriate ^^ 312ΧΡ/invention specification (supplement)/96-06/96 should be 430 3〇200800396 And then slicing to the thickness of the carrying portion of the surname according to the calculation step to obtain the first-carrier portion. In addition, the carrier-holding portion of the metal substrate can also be First, the first dehumidifying agent of the fibrous substrate or the first dehumidifying agent is flattened, and then the first-supporting portion/shell substrate or the metal substrate is loaded and formed, and then formed. Carrying the same; two =, the fibrous substrate or the metal substrate, such as the carrier, the fiber is not particularly limited 'can be exemplified In the case of the immersion treatment or the coating treatment of the slurry containing the first method, the scutellaria, the shellfish or the metal substrate is dehumidified by standing still 3 And a slurry of a binder. Further, a coating; or a metal substrate; or the metal is used in the carrier, and the fibrous substrate uses a material such as a hydrazine, a wet agent, and a binder. The portion is formed in the step of making the second portion of the second holding portion, and the second holding portion is also loaded with the same as the other: The agent does not have the first clothing holding portion calculated according to the different step. The first loading agent of the degree is not limited by (4), and examples thereof include: citrate, alumina sol, Titanium dioxide sol and the like. In the case of the scale, in the fixing step, the first carrier portion and the predetermined method may be, for example, the following warfighter portion (1), and the regeneration air of the first carrier portion may be discharged. Wind < open D face, and 3I2XP / invention manual (supplement) / 96-06/96108430 200800396 =, _, the part of the regenerative air population side of the open face contact worker 'the first - carrying part and the first The second carrier performs a solidification; (1) the regeneration of the second carrier on the regeneration air outlet side of the first carrier portion,
m 再生工 側之開口面間,插入中处PH 物(例如金屬網),並隔著該中空間 中: 部與該第二载持部施行固定,、戈 +將该弟-載持 」出)使該第一载持部的再生空氣出口 该弟二載持部的再生办 汗 、與 離,並料第㈣立ΓΓ 開口面相接觸、或相遠 上 该弟一载持部與該第二載持部固定於同一滾筒; 然後,將該第一載持部盥該第- 除濕滾筒。 卩”該第一载持部施行固定便可獲得 該固定步驟亦可在將除濕滾筒安 或者亦可在將除濕滾筒安裝於::中二:便 二先施行該第-载持部與該第二载持“固Γ而 獲付该弟一載持部與該第二 疋而 後再將所獲得 15呈體的除濕滾筒,然 兮當= 裝於除濕機上’或者亦可首先將 上’然後’再將該第一載持部或該第4=;:, 安裝於除濕機上,藉此便在除濕滚筒安裝之二t: 一 該第-载持部與該第二载持部的固定。 守,便%打 另外,本發明除濕滾筒之製 溫度測量用滾筒製作步驟與該計算步驟,^函蓋首先執行該 計算步驟所獲得的該第_载持 ^ =後再根據依該 戰符料度與該第二載持部厚 312XP/發明說明書(補件)/96·〇繼〇843〇 32 200800396 度,重複施行複數次的該第一载持部形成步驟、該第二 持部形成步驟及該固定步驟,而製造複數個除濕滾筒的情 況。 本發明的除濕機係具有本發明的除濕滾筒。而,本笋明 的除濕機運轉時’再生空氣入口侧的開口面溫^ 250〜500°C。 、 相關本發明的除濕機,參照圖4〜7進行說明。圖4所示 馨係家庭用除濕機的滾筒箱内之構件構造圖,圖5所示係= 家庭用除濕機的滾筒箱内之構件配置位置剖視圖,圖6所 示係該家庭用除濕機的立體圖,圖7所示係該家庭用除濕 機從蜂巢式滾筒開口面3b側所觀看到的圖。 如圖4所示,家庭用除濕機的滾筒箱内係由:滾筒軸 22、該除濕滾筒21、第一供應機27、第二供應機24、加 熱器25、及吸濕空氣排氣風管26構成,各構成構件在滾 筒箱内的配置位置係如圖5所示。而該除濕滾筒21便係 _本發明的除濕滾筒。 “ 圖6與圖7所示的家庭用除濕機30,係由滾筒箱犯、 以及在該滾筒箱32内所設置的該除濕滾筒21、該第一供 應機27、該第二供應機24、該加熱器25、該吸濕空氣排 氣風管26、乾燥空氣吸氣風管3][、附設有排放配管扣且 内部设置冷卻風扇的冷凝機35 '及未圖示之使該除濕滾 筒21旋轉的馬達構成。該滾筒箱32係在該除濕滾筒^ 的開口面3a、3b侧由輻射狀肋條34構成。另外,該第二 供應機24與該加熱器25係設置於該乾燥空氣吸氣風管 312XP/發明說明書(補件)/96〇6/9_43〇 33 200800396 31内。 广孩吸濕空氣排氣風管26係如圖5所示,屬於將吸濕空 氣上排放出於該滾筒箱32外的排氣風管,且具有使= 5亥第一供應機27而供應給該滚筒箱32内的被處理空気 1,不致再度流入於該除濕滾筒21中之再生區的阻隔 因為在該家庭用除濕機30中並未設置將該開口面%、 φ 3b,分割為除濕區與再生區的分割構件,因而利用 -供應機27與該第二供應機24所供應的空氣流動,便將 在該除濕滚筒21内形成除濕區與再生區。換言之,該除 濕滾筒21㈣通著被纽μ M的料便將成為除渴 區’而乾燥用^氣K所流通的部分便將屬於再生區。^ 外,開口面3a +,接受利用該第二供應機24所供應乾焊 用空軋K之一面便將成為再生區,而該開口面扑中,除 阻斷由遺吸濕空氣排氣風管26對除濕滚筒21供應被處理 φ空氣Μ之一面外,其餘均屬於除濕區。 該家庭用除濕機30的運轉係依如下述實施。該家庭用 除濕機30係設置於被處理空氣Μ所存在的室内。然後, 利用該第—供應機27,將周邊所存在的被處理空氣Μ供 應給該除濕滾筒21內,兮处占 ^ 門5亥被處理空氣Μ便藉由在通過該 除濕滾R 21内之時’而與除濕劑進行接觸,藉此便將該 被處理空氣Μ中的水分移往該除濕劑中,因而該被處理空 氣Μ便被除濕。經去除太八从μ 陈水刀的除濕空氣Ν,便將從該除濕 滾筒21的開口面3a排放出於周邊。 312XP/發明說明書(補件)/96-06/96108430 34 200800396 其次,在該除濕區中已吸濕水分的該除濕劑,便利 除濕滾筒21的旋轉,而移往再生區。然後,使用該第: 供應機24,將通過該加熱器25而被加熱的乾燥用空氣f 供應給該除濕滾筒2卜因為該乾燥用空氣κ係藉由與$ 除濕劑進行接觸,而將該除關巾的水分移往該乾燥用、空/ 氣Κ中,因而該除濕劑便將被脫濕。已吸濕水分的吸濕: 氣L,將從吸濕空氣排氣風管26被排放出於該除濕滾= 21外,該吸濕空氣L將藉由在該冷凝冑35内接觸到冷^ 風扇,利用冷凝現象從該吸濕空氣L中將水分去除,經 除水分的空氣Ρ便被排放出於周邊。 其次,在該再生區中被脫濕的該除濕劑,將利用該除渴 滾筒21的旋轉’而朝該除濕區移動,並再度使用被 處理空氣Μ的除濕〇 汉 士該除濕滾筒21的旋轉係可連續式,亦可間歇式。當 續式旋轉該除減筒21的情況,_速度並無特別^ 制,大概HM20轉/小時,最好2〇〜8〇轉/小時。此外a 當間歇式旋轉該除濕滾筒21的情況,則該除濕滾筒心 每1次旋轉量便設定為1/12〜1/3轉,旋轉間隔可 或不定期等任意形式。最好使該除濕滾筒21連續式進_ 旋轉,因為可經常將一定量的再生除濕劑供應給除;區仃 就除濕效率較高且除濕性能較安定的觀點,將屬較、、佳 式。 太 另外,該被處理空氣Μ與該乾燥用空氣1(係從同一 * 進行供應,而該除濕空氣Ν與該經去除水分的空氣 312ΧΡ/發明說明書(補件)/96.06/96108430 35 200800396 被排放出於同一空間中。 除濕滾筒中的除濕劑溫度隨遠離再生空氣入口側的開 口面而降低’在再生空氣出口侧的開口面將屬最低。二 以,為使除濕滾筒能發揮充分的性能,便必需使除渴滾筒 所有範圍的除濕劑溫度均達除濕劑的脫濕溫度以上。作 是,因為習知除濕滾筒的除濕劑係使用原沸石,因而若將 ==口側的開口面溫度設定為25〇〜5〇〇t,則便將 錢濕滾向中,出現除濕劑溫度未滿原涕石脫濕溫度的部 =因t在較低於原彿石脫濕溫度的部分處所载持的原沸 =將不έ被再生’因而即便移往除濕區,仍將無法進行吸 此現象得知’習知的除濕滾筒若將再生空氣入口側 面溫度設定為250,rc,便將降低除濕滾筒的除 面’本發明的除濕滾筒係在除濕滚筒溫度較高的 低的入口侧形成该第一载持部,且在除濕滾筒溫度較 形成該第二載持部。所以,因為該第 、° 、/皿又#又问,因而即便脫濕尖峰溫度較 再生,且因為在除濕滾筒溫度變低的 處一’載持著脫濕尖峰溫度較低的該第二除濕 •濕滾筒的除濕量便將增1充刀地再生。所以,本發明除 •尖:ΐ度中,該非晶質無機多孔質體雖脫濕 德疋乎全部在耐水熱性試驗中的比表面 率均偏大。因而,若該非晶質無機多孔質體在高溫 312XP/發明說明書(補件_6/_43() 36 200800396 下重複施行水分的吸/脫濕,便將大幅降低吸附量,所以 就連暴露於高溫中的部分,除濕劑所載持的習知除濕滾筒 仍無法使用該非晶質無機多孔質體。另,該第二除濕劑 •中,該吸水性樹脂的脫濕尖峰溫度較低,且耐熱性亦= .低。所以,若該吸水性樹脂暴露於高溫中便將分解,因而 就連恭露於高溫的部分,除濕劑所載持的習知除濕滾筒仍 無法使用該吸水性樹月旨。反<,本發明的除濕滾筒,因為 鲁酿度較低的該第二載持部將載持著該非晶質無機多孔質 體’因而該非晶f無機多孔質體即便重複騎水分的吸附 /★脫吸,比表面積降低現象仍較少,或因為在溫度較低的 =一載持部載持著該吸水性樹脂,因而該吸水性樹脂將不 會分解。所以,本發明的除濕滾筒將可使用習知除濕滾筒 所無法使用的脫濕尖峰溫度較低之除濕劑(即該第二除濕 劑)。故,本發明的除濕滚筒係即便在再生空氣入口侧的' 開:面溫度為250〜50(TC的偏低條件下,仍具有較多的除 鲁濕量。 再者,若該第一載持部的厚度過厚,則因為在該第一載 持部中將發生該第一除濕劑溫度在脫濕溫度以下的部 分,❿將存在有未被再生的該第一除濕劑。反之,若該 第=载持部的厚度過厚,則因為在該第二載持部中將出= '該第二除濕劑溫度過高的部分,因而在重複施行水分的吸 • /脫濕時,在除濕量降低變大的溫度區域中、或進行分解 的溫度區域,便將存在有該第二除濕劑。 但是,因為除濕滾筒中的除濕劑溫度並無法直接測量, 312XP/發明說明書(補件)/96〇6/__ 200800396 因而決定該第一载持部與 不易。 /、 —载持部的分割位置便屬 所以,習知便將靠近再生办 工軋入口側的開口面前方之再 絕熱性軟管抽出,並求取再生空氣入口側 氣!?!靠近再ΐ空氣出口側的開口面後方之 侧的浪产而_熱性軟官抽出,並求取再生空氣出口 側::度太而進行除濕滾筒中的除濕劑溫度推測。 <一疋’本發明者等,堂續 測除濕滾筒中的除濕‘度二::生空氣溫度推 =弟-載持科割位置的計算式,可是卻無法獲得計算 戶二=發明者等經深入探討,結果發現使除濕滾筒的 二!=熱電偶而所測得的溫度(即從開口面溫度推 广广滾肉中的除濕劑溫度),若將該溫度為!5〇〜25吖 取子170〜230 C ’尤以19〇〜21〇t為佳)的位 為该弟-載持部與該第二載持部的分割位置,:2 持:的整個區域中,該第一除濕劑的溫度均將達該第一除 ,劑的脫濕溫度以上,且該第二載持部的整個區域中,該 弟-除濕劑的溫度均將達該第二除濕劑的脫濕溫度以上°: 再者,若該第一載持部的厚度、與該第二载持部的厚 又’均為依照上式(la)〜(lc)所計算的厚度,則該 濕劑即便重複施行水分的吸/脫濕,均仍將载持於成= ,量較不㈣低之溫度的部分處、或韻於成為未分解= 溫度的部分處,因而該第二除濕劑在重複施行水分的吸/ 312XP/發明說明書(補件)/96-06/96108430 38 200800396 脫糾,除濕量降低程度仍 發明除濕峨輪μ降低繼Γ 本 —的后藉由在滿足上式(ia)〜(lc)的位置處,設置 ㈣與該第二載持部的分割面,便可在適切位置 :::广、载持部與該第二載持部。所以,根據依照上 士、 、c)決定。亥第一載持部與該第二載持部之厚度的 裔明除濕滾筒,即便再生空氣人口側的開口面溫度設定 ::50 500 C /皿度範圍内的各種溫度,仍可經常在適切位 置处形成該第一載持部與該第二載持部。 再者,諸如:二氧化石夕凝膠、二氧化石夕-氧化銘非晶質多 孔質體、中孔洞二氧切等非晶f無機多孔質體、或離子 父換樹脂、聚丙稀酸鹽樹脂、環氧烧樹脂等吸水性樹脂, 在如夏季的高絕對濕度條件下’除濕量雖較多,但是在如 冬季的低絕對濕度條件下,則除濕量便偏少,因而並無法 適用於家庭用除濕機的除濕滾筒。m Between the opening faces of the regenerating work side, insert the middle PH (for example, metal mesh), and between the middle space: the part and the second carrying part are fixed, and the ge + the younger-bearing And causing the regenerative air outlet of the first carrier to regenerate the sweating of the second carrier, and to contact the opening surface of the (four) vertical opening, or to further the first carrier and the second The carrier is fixed to the same roller; then, the first carrier is clamped to the first dehumidification roller.卩" The first carrier portion is fixed to obtain the fixing step. The dehumidifying roller may be installed or the dehumidifying roller may be installed in the second: the first carrier portion and the first portion Secondly, the "dehumidification roller that has been paid by the younger one and the second sputum and then the 15th body is obtained, and then it is installed on the dehumidifier" or it can be first 'The first carrier or the fourth=;: is mounted on the dehumidifier, whereby the dehumidification roller is mounted on the second side: a fixing of the first carrier portion and the second carrier portion . In addition, the drum manufacturing step of the temperature measuring cylinder of the dehumidifying drum of the present invention and the calculating step are performed, and the first _ carrier is obtained by first performing the calculating step, and then according to the warfare material. And the second carrier portion thickness 312XP/invention specification (supplement)/96·〇继〇843〇32 200800396 degrees, the first carrier portion forming step and the second holding portion forming step are repeated And the fixing step, in the case of manufacturing a plurality of dehumidification rollers. The dehumidifier of the present invention has the dehumidification drum of the present invention. On the other hand, when the dehumidifier of this bamboo shooter is operated, the opening surface temperature of the regeneration air inlet side is 250 to 500 °C. A dehumidifier according to the present invention will be described with reference to Figs. 4 to 7 . 4 is a structural view of a member in a drum box of a sleek household dehumidifier, and FIG. 5 is a cross-sectional view showing a position of a member in a drum box of a household dehumidifier, and FIG. 6 is a view of the household dehumidifier. The perspective view, which is shown in Fig. 7, is a view of the household dehumidifier viewed from the side of the honeycomb drum opening face 3b. As shown in FIG. 4, the drum box of the household dehumidifier is composed of a drum shaft 22, the dehumidifying drum 21, the first supply machine 27, the second supply unit 24, the heater 25, and the moisture absorbing exhaust duct. The configuration of each of the constituent members in the drum box is as shown in Fig. 5 . The dehumidifying drum 21 is a dehumidifying drum of the present invention. The household dehumidifier 30 shown in FIG. 6 and FIG. 7 is made up of a drum box, and the dehumidifying drum 21 disposed in the drum box 32, the first supply machine 27, the second supply unit 24, The heater 25, the moisture-absorbing air exhaust duct 26, the dry air intake duct 3] [, a condenser 35 with a discharge pipe buckle and a cooling fan provided therein, and a dehumidification drum 21 (not shown) The rotating drum is formed by the radial ribs 34 on the opening faces 3a, 3b side of the dehumidifying drum ^. In addition, the second supplying machine 24 and the heater 25 are provided in the dry air to take in air. Duct 312XP / invention manual (supplement) / 96 〇 6 / 9_43 〇 33 200800396 31. Guang children's moisture-absorbing air exhaust duct 26 is shown in Figure 5, belonging to the discharge of moisture on the drum The exhaust duct outside the tank 32 has a treated space 1 that is supplied to the drum tank 32 by the first supply machine 27, and does not flow into the regeneration zone of the dehumidifying drum 21 again because of the The household dehumidifier 30 is not provided with the opening surface %, φ 3b, and is divided into a dehumidification zone and regeneration. The dividing member, and thus the air supplied by the supply machine 27 and the second supply unit 24, will form a dehumidification zone and a regeneration zone in the dehumidification drum 21. In other words, the dehumidification roller 21 (four) is passed through the button The material will become the thirst-removing area' and the part that is circulated by the drying gas will belong to the regeneration zone. ^ Outside, the opening surface 3a + accepts the dry-rolling dry-rolling K supplied by the second supply machine 24. One side will become a regeneration zone, and the opening surface will be in the dehumidification zone except for blocking the supply of the treated φ air enthalpy to the dehumidification drum 21 by the exhausted humid air exhaust duct 26. The operation of the dehumidifier 30 is carried out as follows. The household dehumidifier 30 is installed in a room in which the treated air enthalpy is present. Then, the first supply machine 27 supplies the treated air enthalpy existing in the periphery to In the dehumidifying drum 21, the sputum is in contact with the desiccant when passing through the dehumidifying roller R 21, thereby absorbing moisture in the treated air Moved to the desiccant, thus being placed The air sputum is dehumidified. After the dehumidified air enthalpy of the damper is removed from the damper, the opening surface 3a of the dehumidifying drum 21 is discharged from the periphery. 312XP/Invention Manual (supplement)/96-06/96108430 34 200800396 Next, the dehumidifying agent which has absorbed moisture in the dehumidifying zone facilitates the rotation of the dehumidifying drum 21 and moves to the regeneration zone. Then, the second supply unit 24 is used to be heated by the heater 25. The drying air f is supplied to the dehumidifying drum 2 because the drying air κ is brought into contact with the dehumidifying agent to move the moisture of the removing towel to the drying, air/air enthalpy, and thus The desiccant will be dehumidified. Moisture absorption of moisture absorption: The gas L will be discharged from the moisture-absorbing air exhaust duct 26 out of the dehumidification roll = 21, and the moisture-absorbing air L will be contacted by the inside of the condensation chamber 35. The fan removes moisture from the moisture-absorbing air L by condensation, and the moisture-removed air is discharged to the periphery. Next, the desiccant dehumidified in the regeneration zone is moved toward the dehumidification zone by the rotation of the quencher drum 21, and the dehumidification of the dehumidification drum 21 by the dehumidification of the treated air is again used. It can be continuous or intermittent. When the eliminator is rotated continuously, the _speed is not particularly controlled, about HM20 rpm, preferably 2 〇 to 8 rpm. Further, a. When the dehumidification drum 21 is intermittently rotated, the dehumidification roller core is set to 1/12 to 1/3 rotation per one rotation, and the rotation interval may be arbitrary or irregular. Preferably, the dehumidifying drum 21 is continuously rotated, because a certain amount of the regenerative dehumidifying agent can be frequently supplied to the separator; the zone has a high dehumidification efficiency and a relatively stable dehumidification performance, and is preferable. In addition, the treated air enthalpy and the drying air 1 are supplied from the same *, and the dehumidified air enthalpy and the moisture-removed air 312 ΧΡ / invention manual (supplement) / 96.06/96108430 35 200800396 are discharged Out of the same space. The temperature of the desiccant in the dehumidification drum decreases with the opening surface away from the inlet side of the regeneration air. 'The opening surface on the outlet side of the regeneration air will be the lowest. Secondly, in order to make the dehumidification roller perform adequately, Therefore, it is necessary to set the desiccant temperature of all ranges of the de-throat roller to be higher than the dehumidification temperature of the dehumidifying agent. Therefore, since the dehumidifying agent of the conventional dehumidifying drum uses the original zeolite, the opening surface temperature of the == mouth side is set. If it is 25〇~5〇〇t, then the money will be wetly rolled to the middle, and the dehumidifier temperature will be less than the temperature of the original vermiculite dehumidification temperature = because t is lower than the part of the original Buddha stone dehumidification temperature. The original boiling = will not be regenerated" so even if it is moved to the dehumidification zone, it will not be able to absorb this phenomenon. Knowing that the dehumidification roller will reduce the dehumidification by setting the side temperature of the regeneration air inlet to 250, rc. Roller In the dehumidification drum of the present invention, the first carrier portion is formed on a low inlet side where the temperature of the dehumidification roller is high, and the second carrier portion is formed at a temperature of the dehumidification roller. Therefore, because the first, °, / The dish is again asked, so even if the dehumidification peak temperature is more regenerative, and because the temperature of the dehumidification drum becomes lower, the dehumidification amount of the second dehumidification/wet roller holding the dehumidification peak temperature is increased. 1 Recycling with a knife. Therefore, in the present invention, in addition to the tip: the amorphous inorganic porous body, although the dehumidification is almost all the surface area ratio in the hydrothermal resistance test is large. Therefore, if the amorphous The porous inorganic body is repeatedly subjected to moisture absorption/desorption in the high temperature 312XP/invention manual (supplement_6/_43() 36 200800396, which will greatly reduce the adsorption amount, so even the part exposed to high temperature, dehumidification The amorphous inorganic porous body is still not used in the conventional dehumidifying drum held by the agent. Further, in the second desiccant, the water-absorbing resin has a low dehumidification peak temperature and low heat resistance. Therefore, if the water absorbent resin is exposed to It will decompose at high temperatures, so even the conventional dehumidification drum held by the desiccant can not use the water-absorbing tree in the part that is exposed to high temperature. Inverse, the dehumidification roller of the present invention, because of the degree of Lu The lower second carrier portion carries the amorphous inorganic porous body. Therefore, even if the amorphous f inorganic porous body repeatedly absorbs moisture/desorption, the specific surface area is reduced, or because The water-absorbent resin is carried at a lower temperature=one carrier, and thus the water-absorbent resin will not be decomposed. Therefore, the dehumidification drum of the present invention can use a dehumidification peak temperature which cannot be used by a conventional dehumidification drum. a lower dehumidifying agent (i.e., the second dehumidifying agent). Therefore, the dehumidifying drum of the present invention has a 'open: surface temperature of 250 to 50 even at the inlet side of the regeneration air (the TC has a low temperature condition, In addition to the amount of Lu wet. Furthermore, if the thickness of the first carrier portion is too thick, the first dehumidifier temperature in the first carrier portion will be lower than the dehumidification temperature, and the crucible will be unregenerated. The first desiccant. On the other hand, if the thickness of the first carrier portion is too thick, the second carrier portion will have a portion where the temperature of the second desiccant is too high, so that the moisture absorption/desorption is repeatedly performed. At this time, the second desiccant is present in a temperature region where the dehumidification amount is increased or in a temperature region where decomposition is performed. However, since the temperature of the desiccant in the dehumidification drum cannot be directly measured, the 312XP/invention specification (supplement)/96〇6/__ 200800396 thus determines that the first carrier is not easy. /, - The position of the carrier is divided. Therefore, it is customary to take out the re-insulating hose in front of the opening face on the side of the reclaimed office rolling inlet and obtain the regenerative air inlet side air! ! Near the side of the rear side of the opening side of the air outlet side, the heat is extracted, and the regenerative air outlet side is obtained: The temperature of the dehumidifying agent in the dehumidifying drum is estimated. <一疋' The inventor, etc., continued to measure the dehumidification in the dehumidification drum 'degree two:: raw air temperature push = brother - carrying the cut position of the calculation formula, but can not get the calculation of the second = inventors, etc. In-depth discussion, the results found that make the dehumidification roller two! = the temperature measured by the thermocouple (ie, the temperature of the desiccant in the wide-rolled meat is pushed from the open surface temperature), if the temperature is! 5〇~25吖子170~230 C' especially 19〇~21〇t is better) The position of the younger-carrier and the second carrier is: 2: The entire area of the holding: The temperature of the first desiccant will be above the first dehumidification temperature of the agent, and the temperature of the dehumidifier will reach the second dehumidification in the entire region of the second carrier. Further, if the thickness of the first carrier portion and the thickness of the second carrier portion are both calculated according to the above formulas (la) to (lc), Even if the moisture is repeatedly subjected to moisture absorption/desorption, it is carried at a portion where the temperature is lower than (4), or at a portion where the temperature is not decomposed = temperature, and thus the second dehumidification In the repeated application of moisture absorption / 312XP / invention manual (supplement) / 96-06/96108430 38 200800396 de-correction, the degree of dehumidification reduction is still invented dehumidification μ wheel μ reduction after the — - after the above formula At the position of (ia)~(lc), the dividing surface of the (4) and the second carrying portion is set to be at a suitable position::: wide, the carrying portion and the second carrying portion . Therefore, according to the decision of the superior, c). The imaginary dehumidification drum of the thickness of the first carrier portion and the second carrier portion can be often used even if the temperature of the opening surface of the regenerating air population side is set to various temperatures within a range of 50 500 C / dish. The first carrier portion and the second carrier portion are formed at the position. Furthermore, such as: a dioxide dioxide gel, a dioxide dioxide oxidized amorphous porous body, a mesoporous dioxo, etc., an amorphous f inorganic porous body, or an ion parent resin, a polyacrylate Water-absorbent resins such as resins and epoxy-fired resins have a large amount of dehumidification under high absolute humidity conditions in summer, but in the case of low absolute humidity in winter, the amount of dehumidification is small, so it is not suitable for use. Dehumidifier roller for household dehumidifiers.
,是,本發明的除錢筒係當對絕對濕度較高的被處理 空氣施行處理時’便首先在高絕對濕度條件下吸濕量較多 的該非晶質無機多孔質體或該吸水性樹脂,將被處理空氣 中大部分水分施行除濕,而降低被處理空氣的絕對濕度。 接著,再將絕對濕度變低的被處理空氣之水分,由即便在 絕對濕度㈣的條件下仍具有較多❺濕量的該第一除濕 劑(該沸石)進行除濕。另外,當對絕對濕度較低的被處理 空氣施行處理時,該非晶質無機多孔質體或該吸水性樹脂 雖亀乎未對被處理空氣中的水分施行除濕,但是若屬於絕 312XP/發明說明書(補件)/96-06/96108430 39 200800396 對濕度較低的被處理空氣中之水分量,僅利 劑便可;分地執行被處理空氣的除濕。換言之::;:: 除濕滚同將可使用f知除濕滚筒所無法使 無機多孔質體或該吸水性樹脂。 ^非日曰貝 =:晶質無機多孔質體或該吸水性樹脂所载持的 弟一載持稱度若不適當,則在高絕對濕度條件下 季)的除濕量、或低絕對濕度條件下(冬季)的除渴量均將 降低’因而將無法使用為家庭用除濕機的除濕滾筒。 本發明除濕滾筒係藉由將該非晶質無機多孔 :^脂所载持的該第二載持部厚度,設定為滿足ί; ()〜()的厚度,則不管高絕對濕度條件下(夏季)、及 =對濕度條件下(冬季),均可增加本發明除濕滾筒的除 其次,舉實施例針對本發明進行更具體的說明,惟立僅 止於例示而已,並非限制本發明。 /、 肇(實施例) (實施例1) (蜂巢式構造纖維質载體之製作) 將生物溶解性纖維、與有機纖維及有機黏結劑一起施行 抄紙,、便獲得片狀纖維質載體。將該片狀纖維質載體施行 加工成間距2. 7随、波頂高度i. 5mm的瓦楞形狀’便獲得 瓦楞狀纖維質載體。然後,將該片狀纖維質載體與該瓦愣 狀纖維貝載體重疊’並捲取呈甜甜圈形狀,便獲得外徑 250mm、㈣20咖、厚度2〇随的蜂巢式構造纖維質載體A。 312XP/發明說明書(補件则_〇6/96麵3〇 40 200800396 (溫度測量用滾筒之製作) 依合成鈉γ型沸石含有量為3〇質量%、膠體二氧化矽的 固形份含有量為6.3質量%之方式,調製成第一除濕劑載 持用漿料B ’接著在該第—除濕劑載持用聚料B中浸潰該 纖維質載體A。然後,將該纖維f載體A從該㈣中取出, 亚在150C下施行乾燥,接著,在5{)()t:下施行工小時燒 成,便獲得溫度測量用滾筒G。所獲得的溫度測量用滾筒 C中》亥σ成鈉γ型沸石(第一除濕劑)的载持量係 •合成鋼Y型彿石:骨架構造係γ型,紹部位的離子對係 納離子,屬於未施行離子交換處理的原沸石。财水孰性試 驗中的比表面積降低率係3%,脫濕尖峰溫度係13代。 (開口面溫度之測量) 在圖6所示該家庭用除濕機3〇中,設置該溫㈣量用 滾筒C,該家庭用除濕機設置於經控制成饥、_㈣ :溫恆濕室内,並依以下的運轉條件施行除濕運轉,且測 ®再生空氣出口側的開口面溫度。結果,當使再生空氣出 口側的蜂巢式滾筒開π面接觸到熱電偶時,由該熱電偶 測量得溫度(Τ2)係47°C。 <試驗條件> •士當使再生空氣人口側的蜂巢式滾筒開口面接觸到熱電偶 時’由該熱電偶所測得溫度(T1):426〇c 除濕滾同21的旋轉速度:q · 5轉/分 將依上述開口面測量所獲得結果,代入下式(la)中. {(Tl-150)/(150-T2)}^(Dl/D2)^{(Tl-250)/C250-T2)} 41 312XP/發明說明書(補件)/96·06/96·430 200800396 便將成為下式: {(426-15G)/(15(M7)}2(D1/D2)^{(426-25G)/(250-47)} ’即 2· 68g (Dl/D2)2 0· 87。 μ以依上述所獲得公式為基礎,將第一载持部的厚度、及 第二载持部的厚度分別決定為D1 = u_、·9_。此時, 、2值係1 · 22 ’因而將滿足上式。然後,將另外製得的 =質载體A切片成厚度llmm的第一載持部用載體d、 | /、厚度9mm的第二載持部用載體E。 (第一載持部之製作) 載筒之製作時所使用的第-除濕'劑 將誃第一恭姓 反'貝者該弟一载持部用載體D。然後, 行二 用載體D從該漿料中取出,並依靴施 後’接著依靴施行1小時燒成,便獲得第一載 (弟一載持部之製作) 乳化石夕一乳化銘非晶質多孔質體含有量為25質量 制Μ ^切的固形份含有量為3.8質量%之方式1 衣成弟一除濕劑载持用漿, 。 用漿料G中浸潰㈣第-錢都耆在該弟—除濕劑载持 恭姓加 、者以弟一載持邵用载體Ε:。然後,將第- 载持部用載體Ε從該漿料中取屮。交將弟— 後,接著依50(ΓΓ浐—1 ,亚依150 C施行乾燥 *仃1小時燒成,#择爲楚— 所獲得第二載持部Η中 更獲付弟-載持邻Η。 質趙u二除濕劑)的载持量二:;氧化銘非晶質多孔 虱化夕乳化銘非晶質多孔質體··脫濕尖峰溫度⑽ 312ΧΡ/發明說明書(補件)/96-06/96108430 42 200800396 〇C、Si〇2:78% 0· 5ml/gIn the degassing cylinder of the present invention, when the treated air having a high absolute humidity is treated, the amorphous inorganic porous body or the water-absorbent resin which absorbs a large amount of moisture under high absolute humidity conditions first is used. The majority of the moisture in the treated air is dehumidified to reduce the absolute humidity of the treated air. Then, the moisture of the air to be treated whose absolute humidity is lowered is dehumidified by the first dehumidifying agent (the zeolite) which has a large amount of moisture even under the condition of absolute humidity (four). In addition, when the treated air having a low absolute humidity is treated, the amorphous inorganic porous body or the water-absorbent resin hardly dehumidifies the moisture in the air to be treated, but if it belongs to the 312XP/invention specification (Supplement)/96-06/96108430 39 200800396 For the moisture content of the treated air with low humidity, only the agent can be used; the dehumidification of the treated air is performed on the ground. In other words: :::: The dehumidification roll can be used to make the inorganic porous body or the water-absorbent resin impossible. ^Non-day mussel==The crystalline inorganic porous body or the water-absorbent resin contained in the water-holding capacity, if not properly, the dehumidification amount or low absolute humidity condition under high absolute humidity conditions) The amount of thirst reduction in the next (winter) will be reduced' so that the dehumidifying drum for the household dehumidifier will not be used. In the dehumidification drum of the present invention, the thickness of the second carrier portion carried by the amorphous inorganic porous resin is set to satisfy the thickness of () to (), regardless of the high absolute humidity condition (summer And the following is a more specific description of the present invention, and the present invention is not limited by the examples, but the present invention is not limited thereto. (Examples) (Example 1) (Production of honeycomb structure fibrous carrier) A paper-like fibrous carrier was obtained by subjecting biosoluble fibers to papermaking together with organic fibers and an organic binder. The sheet-like fibrous carrier was processed to have a corrugated fibrous carrier with a pitch of 2.7 and a corrugated shape of a height of i. 5 mm. Then, the sheet-like fibrous carrier was superposed on the corrugated fiber-shell carrier and wound up in a donut shape to obtain a honeycomb structure fibrous carrier A having an outer diameter of 250 mm, (four) 20 coffees, and a thickness of 2 inches. 312XP/Invention Manual (Repair _〇6/96面3〇40 200800396 (Preparation of temperature measuring roller) The content of solid sodium γ-type zeolite is 3% by mass, and the solid content of colloidal cerium oxide is 6.3 mass%, the first desiccant-carrying slurry B' is prepared and then the fibrous carrier A is impregnated in the first desiccant-carrying polymer B. Then, the fiber f-carrier A is In the above (4), the film was dried at 150 C, and then baked at 5 {) () t: for the hour, and the temperature measuring roll G was obtained. In the obtained temperature measuring drum C, the holding amount of the sigma gamma-type γ-type zeolite (first dehumidifying agent) is: Synthetic steel Y-type Fossil: skeletal structure γ type, ion-pairing nucleus It belongs to the original zeolite which is not subjected to ion exchange treatment. The specific surface area reduction rate in the fiscal test was 3%, and the dehumidification peak temperature was 13 generations. (Measurement of the opening surface temperature) In the household dehumidifier 3A shown in Fig. 6, the temperature (four) amount roller C is provided, and the household dehumidifier is installed in the controlled hunger, _(4): temperature and humidity chamber, and The dehumidification operation was performed under the following operating conditions, and the opening surface temperature on the outlet side of the regeneration air was measured. As a result, when the honeycomb roller on the outlet side of the regeneration air was brought into contact with the thermocouple, the temperature (Τ2) measured by the thermocouple was 47 °C. <Test conditions> • When the honeycomb opening face of the regenerative air population side is brought into contact with the thermocouple, 'the temperature measured by the thermocouple (T1): 426 〇 c Dehumidification roll 21 rotation speed: q · 5 rpm will be measured according to the above open face measurement and substituted into the following formula (la). {(Tl-150)/(150-T2)}^(Dl/D2)^{(Tl-250)/ C250-T2)} 41 312XP/Inventive Manual (supplement)/96·06/96·430 200800396 will become the following formula: {(426-15G)/(15(M7)}2(D1/D2)^{ (426-25G)/(250-47)} 'that is 2·68g (Dl/D2)2 0·87. μ is based on the formula obtained above, the thickness of the first carrier, and the second load The thickness of the holding portion is determined as D1 = u_, ··9_. At this time, the value of 2 is 1 · 22 ' and thus the above formula is satisfied. Then, the separately prepared = mass carrier A is sliced into the first thickness of llmm. The carrier d, | /, and the carrier E for the second carrier for a thickness of 9 mm. (Preparation of the first carrier) The first dehumidification agent used in the production of the carrier will be the first Anti-Bei's brother, the carrier used carrier D. Then, the second carrier D was taken out from the slurry and was applied after the boots. Then, it is fired for one hour according to the boots, and the first load is obtained (the production of the first carrier). The content of the amorphous porous body is 25 mass Μ. The solid content of the cut is 3.8 mass% of the way 1 Yi Chengdi a desiccant carrier slurry, used in the slurry G impregnation (four) the first - money are in the brother - dehumidification agent carrying Gong surg, the younger brother to carry Shao load Body: Then, the first carrier is taken from the slurry with a carrier 屮. After the transfer, the latter is followed by 50 (ΓΓ浐-1, Yayi 150 C drying * 仃 1 hour firing , #择为楚—The second carrier department received the more paid brothers - carrying the neighbors. The quality of the Zhao u two dehumidifiers: 2: Oxidation Ming amorphous porous 虱 乳化 emulsified Ming Amorphous porous body··Dehumidification peak temperature (10) 312ΧΡ/Invention manual (supplement)/96-06/96108430 42 200800396 〇C, Si〇2: 78% 0·5ml/g
Al2〇3:20%、比表面積 44〇n]2/g、 細孔容積 (除濕滾筒之製作) 依使該第-载持部F其中一面的開口面、與該第二载持 部Η其中一面的開口面相接觸之方式,將二一 滚筒軸上’便製得除濕滾筒、门 (除濕試驗) φ在圖6所示該家庭用除濕機3〇中,設置該除濕滚 並將該家庭用除濕機設置於經控制成饥⑽戰的卜 恒濕室内,且依以下的運轉條件施行除濕運轉。結果如= <試驗條件> 口面接觸到熱電偶Al2〇3: 20%, specific surface area 44〇n] 2/g, pore volume (production of dehumidification drum), according to the opening surface of one side of the first-carrier portion F, and the second carrier portion The dehumidification roller and the door (dehumidification test) φ are prepared on the two-side roller shaft by the contact surface of one side, and the dehumidification roller is provided in the household dehumidifier 3 shown in FIG. The dehumidifier is installed in a bu-wet chamber controlled to be hunger (10), and dehumidification operation is performed according to the following operating conditions. Results such as = <test conditions> oral contact with thermocouple
• ¥使再生空氣入口侧的蜂巢式滾筒開 時,由該熱電偶所測得溫度M26°C 開口面接觸到熱電偶 •當使再生空氣出口側的蜂巢式滾筒 ⑩時,由該熱電偶所測得溫度:47〇c •除濕滾筒21的旋轉速度:〇·5轉/分 (實施例2) (蜂巢式構造載體之製作) 依照如同實施例1相同的方法實施 (溫度測量用滾筒之製作) 依照如同實施例1相同的方法實施 筒C。 1獲得纖維質載體 ’獲得溫度測量用 Α° 滾 (開口面溫度之測量) 312ΧΡ/發明說明書(補件)/96-06/96108430 43 200800396 門件中,除將當使再生空氣入口侧的蜂巢式滾筒 二:_熱電偶時’由該熱電偶所測得溫度瞻定 施纤要之I *餘均依照如同實施例1相同的方法實 到使再生空氣出σ側的蜂巢式滾筒開Π面接觸 先、电偶%,由該熱電偶所測得溫度(Τ2)係42乞。 若將依上述開口面測量所獲得結果 ⑽(Μ5〇να5(Μ2此(D1/D2k{(3.25〇)/(25〇_42)} )· ,便將成為 1· 48g (])1/D2)g 〇 29。 及獲得的公式為基礎,將第-載持部的厚度、 因分別決定為Dl=9mm、D2=u賴。此時, ,二 值係0. 82,因而將滿足上式。然後,將 製得的該纖維質載體A,切y j、 盥;^ 成厚度9醜的第一載持部用 載體/、;度U_的第二載持部用載體l。 (第一載持部之製作) 除取代第一載持部用载體D,改為 體K之:,其餘均依照如同實施例i相同的 = 得第一載持部Μ。 ^ (弟一載持部之製作) 依A型二氧切凝膠含有量為25質量%、膠體二氧 的固形份含有量為3.8 #量%之方式,調製成第二除 f持f漿料N ’接著,在該第二除濕劑载持用漿料N中: 浸潰著該第二载持部用载體L。然後,將該第二载 載體L從該黎料中取出,並依15代施行乾燥後,接^ 50(TC施行1小時燒成,便獲得第二载持部ρ。所獲得第又 312ΧΡ/發明說明書(補件)/96-06/96108430 44 200800396 二除濕劑)的载持 二载持部P中,該A型二氧化矽凝膠(第 量係79g/L。 • A型二氧化矽凝膠:Si〇2:99.6%、比表面積7〇如2 孔容積0. 4 6 in 1 / g (除濕滾筒之製作) 除取代第一载持部F,改用第一载持部M,並取代第二 載持部Η,改用第二載持部p之外,其餘均依照如同實: 例1相同的方法實施,獲得除濕滾筒Q。 ' (除濕試驗) 在圖6所示該家庭用除濕機3()中,設置該除濕滾筒Q, 亚將該家庭用除濕機設置於經控制成肌、5議的怔严 怪濕室内’且依以下的運轉條件施行除濕運轉。結果如表 1所示。 <試驗條件> 口面接觸到熱電偶 口面接觸到熱電偶 •士當使再生空氣入口侧的蜂巢式滾筒開 #時,由該熱電偶所測得溫度:310它 •士當使再生空氣出口侧的蜂巢式滾筒開 時,由該熱電偶所測得溫度:42ΐ •除濕滾筒21的旋轉速度:〇· 5轉/分 (實施例3) 77 (蜂巢式構造載體之製作) 依照如同實施例1相同 (溫度測量用滾筒之製作) 依照如同實施例1相同 的方法實施,獲得纖維質載體Α。 的方法實施,獲得溫度測量用滾 312ΧΡ/發明說明書(補件)/96〇6腦〇843〇 45 200800396 筒c。 (開口面溫度之測量) 在忒驗條件中,除將當使再生空氣入口侧的蜂巢式滾筒 P幵’口面接觸到熱電偶時,由該熱電偶所測得溫度(η )設定 ,270 c之外,其餘均依照如同實施例】相同的方法實 加。結果’當使再生空氣出口侧的蜂巢式滾筒開π面接觸 到熱電偶日寸,由該熱電偶所測得溫度⑺)係㈣。C。 若將依上述開口面測量所獲得的結果,代入下式(la) {(270 15〇)/(150~40)}>(di/D2)^ {(270-250)/(250-40)} ,即將成為 1·〇9^(ΐ)ΐ/ΐ)2)2〇·ι〇。 =依^述所獲得的公式為基礎,將第—載持部的厚度、 =载持部的厚度分別決定為Dl,m、D2=llmm。此時, 因為D1/D2值係〇·82,因而將滿足上式。 (第一載持部之製作) (第依2相同的枝實施,獲得第··載持部M。 C弟一載持部之製作) =離子交換樹絲末含有量為25質量%、丙婦酸黏結 別的固形份含有量為i 3質量% 劑載持用漿料R。接著,在 製成第二除濕 、 有在与度30 # m的鋁箔譬面t,利 用輥塗機施行該第二除 ^載持用漿料R的塗佈,並於 Γ第二:二便獲得片狀第二除濕劑載持㈣。該片 、以 一除濕劑载持鋁箔加工成間 312ΧΡ/發明說明書(補件)/96〇6/9刪— 46 200800396 距2. 7mm、波頂兩度1,5mm的瓦榜形狀,便獲瓦 二除濕劍载持紹箱。然後,將該片狀第二除濕劍載持㈣ 與该瓦楞狀第二除濕劑载持鋁箱重疊,並捲取呈甜甜圈形 狀’且成形為外徑250fflm、内徑2〇咖、厚度2〇咖的蜂巢 式構造體,便獲得陽離子交換樹脂载持蜂巢式構造體s。 所獲得陽離子交換樹脂載持蜂巢式構造體s中,該陽離子 交換樹脂粉末的载持量係、184g/m3。接著,將該陽離子交 換樹脂载持蜂巢式構造體s切片成厚度llmm 得第二載持部T。 役 陽離子又換樹脂粉末:陽離子交換樹脂(DIAi〇N(g)、三菱 化學公司製)的粉碎物、平均粒徑20/zm 夂 (除濕滚筒之製作) —除取代第—載持部F,改為使用第-載持部Μ,並取代 弟二載持部Η,改為使用第二載持部τ之外,其餘均依昭 如同實施例1相同的方法實施,獲得除濕滚筒卜 馨(除濕試驗) 、在圖6所不該豕庭用除濕機3〇中,設置該除濕滾筒U, 並將该豕庭用除濕機設置於經控制成肌、5G·的怪溫 艮濕至内’且依以下料轉條件施行㈣運轉。結 1所示。 衣 <試驗條件> 田使再生工氣入口 j則的蜂巢式滾筒帛口面接觸到埶電偶 時,由該熱電偶所測得溫度:27〇〇c ”、 •當使再生线iB 口侧的蜂巢式滾制口面接觸到熱電偶 312ΧΡ/發明說明書(補件)/9卜〇6/961〇843〇 47 200800396 打,由该熱電偶所測得溫度:4〇。〇 •除濕滾筒21的旋轉速度:〇· 5轉/分 (比較例1) (蜂巢式構造載體之製作) 依知、如同實施例1相同的方沐每 & 』的方法貝苑,獲得纖維質載體A。 C除濕滾筒之製作) f實施例1中所使用的第一除濕劑載持用浆料B :者該纖維質載體A。然後,將該纖維質载體A從該聚料 士取出,亚依15〇C施行乾燥後,接著依50(TC施行1小 A成便獲知除濕滾筒V。所獲得的除濕滚筒v中,該 合成鈉Y型沸石的载持量係143g/L·。 (除濕試驗) 、,在圖6所示該家庭用除濕機30中,設置該除濕滾筒v, 並將該家庭用除濕機設置於經控制成25〇c、5〇%RH的恆溫 恆濕室内,且依以下的運轉條件施行除濕運轉。結果如表 _ 1所示。 <試驗條件> •當使再生空氣入口側的蜂巢式滾筒開口面接觸到熱電偶 時’由該熱電偶所測得溫度:426t: •當使再生空氣出口側的蜂巢式滾筒開口面接觸到熱電偶 ^ 時,由該熱電偶所測得溫度:47°C • •除濕滾筒21的旋轉速度·· 〇 · 5轉/分 (比較例2) (除濕試驗) 312XP/發明說明書(補件)/96-06/96腦30 48 200800396 在圖6所示該家庭用除濕機3〇中,設置依 例^相同的方法所獲得的除濕滚筒v,並將該家二 機没置於經控制成25°C、50%RH的怪溫恆濕室内,且 下的運轉條件施行除濕運轉。結果如表1所示。 ♦ <试驗條件> •當使再生空氣人卩侧的蜂巢式滾㈣σ面接觸到執 時,由該熱電偶所測得溫度:31(rc ‘、、、电 鲁•當使再生空氣出口侧的蜂巢式滚筒開口面接觸到執 牯,由该熱電偶所測得溫度:42°C 私 •除濕滾筒21的旋轉速度:0· 5轉/分 (比較例3) (除濕試驗) 在圖6所示該家庭用除濕機3〇 +,設置依照如同 例1相同的方法所獲得的除濕滚筒v,並將該家庭用^ 機設置於經控制成25。〇、50%RH的恆溫恆濕室内,且:二 _下的運轉條件施行除濕運轉。結果如表丄所示。 、 <試驗條件> •士當使再生空氣人口侧的蜂巢式滾筒開口面接觸到熱 時’由該熱電偶所測得溫度:27〇〇c 包 •士當使再生空氣出口侧的蜂巢式滾筒開口面接觸到熱 . 時,由該熱電偶所測得溫度:4〇。〇 、$偶 .•除濕滾筒21的旋轉速度:〇 · 5轉/分 (比較例4) (蜂巢式構造載體之製作) 312XP/發明說明書(補件)/96-06/96108430 49 200800396 依照如同實施例"目同的方法實施,獲得纖維質載體A。 (除濕滾筒之製作) 、主,實施例1中所使用的第二除濕劑载持賴料g中,浸 'f者該纖㈣_ Α°_’將該纖維質載體A從該聚料 t取出’並们5(TC施行乾燥後,接著依5〇(Γ(:施行】小 了 k成,便獲付除濕滾筒w。所獲得除濕滾筒w中,該二 乳化石夕-氧化銘非晶質多孔質體的载持量係物几。 馨(除濕試驗) ^圖y/f示該家庭用除濕機3G中,設置該除濕滾筒?, =^豕庭用除濕機設置於經控制成25ΐ、5〇爾的恆溫 互濕至内’且依以下的運轉條件施行除濕運轉。結果如表 〈试驗條件> 面接觸到熱電偶 面接觸到熱電偶 二當使再生空氣入口侧的蜂巢式滾筒開 時,由該熱電偶所測得溫度·426<t• When the honeycomb roller on the inlet side of the regeneration air is opened, the temperature measured by the thermocouple is M26°C. The open surface is in contact with the thermocouple. • When the honeycomb roller 10 on the outlet side of the regeneration air is used, the thermocouple is used. Temperature measured: 47 〇 c • Rotation speed of the dehumidification drum 21: 〇·5 rpm (Example 2) (Production of honeycomb structure carrier) The same method as in Example 1 was carried out (production of a roller for temperature measurement) The cylinder C was carried out in the same manner as in the first embodiment. 1 Obtaining a fibrous carrier' for temperature measurement Α° Rolling (measurement of open surface temperature) 312ΧΡ/Invention manual (supplement)/96-06/96108430 43 200800396 In the door, except for the honeycomb that will make the regeneration air inlet side Type 2: _ thermocouple 'the temperature measured by the thermocouple I want to apply the fiber to the same method as in the first embodiment to make the regeneration air out of the σ side of the honeycomb roller opening Contact first, galvanic%, the temperature measured by the thermocouple (Τ2) is 42 乞. If the result (10) (Μ5〇να5(Μ2(D1/D2k{(3.25〇)/(25〇_42)})·) is obtained according to the above open face measurement, it will become 1·48g (])1/D2 )g 〇29. Based on the obtained formula, the thickness of the first-bearing portion and the factor are determined as Dl=9mm and D2=u. In this case, the binary value is 0.82, and thus the above formula is satisfied. Then, the obtained fibrous carrier A is cut into yj, 盥; ^ into a carrier having a thickness of 9 ugly for the first carrier, and a carrier for the second carrier of degree U_. Production of the carrying portion) In place of the carrier D for the first carrier, it is replaced by the body K: the rest is the same as that of the embodiment i = the first carrier Μ. ^ Manufactured according to the method that the content of the A-type dioxy-cut gel is 25% by mass and the solid content of the colloidal dioxygen is 3.8 #% by mass, the second addition is the f-holding slurry N'. In the second desiccant-carrying slurry N: the carrier 25 for the second carrier is impregnated. Then, the second carrier L is taken out from the material and dried after 15 generations. Connected to ^ 50 (TC performed for 1 hour, it will get the second Holder ρ. obtained by the second 312 ΧΡ / invention specification (supplement) / 96-06/96108430 44 200800396 two dehumidifiers in the carrier two holding part P, the type A cerium oxide gel (the first system 79 g / L. • Type A cerium oxide gel: Si 〇 2: 99.6%, specific surface area 7 〇 such as 2 pore volume 0. 4 6 in 1 / g (production of dehumidification roller) In addition to replacing the first carrier F The first carrier portion M is used instead of the second carrier portion Η, and the second carrier portion p is used instead, and the rest is performed in the same manner as in the first example: the dehumidification roller Q is obtained. Dehumidification test) In the household dehumidifier 3 () shown in Fig. 6, the dehumidification drum Q is provided, and the household dehumidifier is placed in a sturdy and wet room controlled by a muscle, and the following The dehumidification operation was carried out under the operating conditions. The results are shown in Table 1. <Test conditions> When the surface of the thermocouple was in contact with the thermocouple, the surface of the thermocouple was contacted with the thermocouple. The temperature measured by the thermocouple: 310. When the honeycomb drum on the outlet side of the regeneration air is opened, the temperature measured by the thermocouple is 42 ΐ. • Rotation speed of the dehumidification drum 21: 〇·5 rpm (Example 3) 77 (Production of honeycomb structure carrier) The same procedure as in Example 1 (production of a drum for temperature measurement) was carried out in the same manner as in Example 1. The method of obtaining the fiber carrier Α is carried out, and the temperature measurement roll 312 ΧΡ / invention specification (supplement) / 96 〇 6 cerebral 〇 〇 843 〇 45 200800396 tube c. (measurement of the opening surface temperature) in the test condition Except when the surface of the honeycomb drum P幵' of the inlet side of the regeneration air is brought into contact with the thermocouple, the temperature (η) measured by the thermocouple is set, except for 270 c, the rest is the same as in the embodiment. The method is actually added. As a result, when the honeycomb roller on the outlet side of the regeneration air was opened to the thermocouple, the temperature (7) measured by the thermocouple was (4). C. If the result obtained by the above open face measurement is substituted into the following formula (la) {(270 15〇)/(150~40)}>(di/D2)^ {(270-250)/(250-40 )}, will soon become 1·〇9^(ΐ)ΐ/ΐ)2)2〇·ι〇. Based on the equation obtained, the thickness of the first carrier portion and the thickness of the carrier portion are determined to be D1, m, and D2 = llmm, respectively. At this time, since the D1/D2 value is 〇·82, the above equation will be satisfied. (Preparation of the first carrier) (Implementation of the same branch according to 2, obtaining the first carrier M. Production of the C-bearing part) = Ion exchange tree filament content of 25% by mass, C The solid content of the guar acid binder is i 3 mass% of the agent-carrying slurry R. Next, in the second dehumidification, the aluminum foil having the degree of 30 #m, the coating of the second de-supporting slurry R is performed by a roll coater, and the second: two A sheet-like second desiccant carrier (four) is obtained. The film, with a desiccant carrying aluminum foil processed into a 312 ΧΡ / invention instructions (supplement) / 96 〇 6 / 9 deleted - 46 200800396 distance 2. 7mm, wave top two degrees 1,5mm tile shape, it will be The tile two dehumidification sword carries the box. Then, the sheet-shaped second dehumidification sword carrier (4) is overlapped with the corrugated second desiccant carrying aluminum box, and is wound into a doughnut shape and shaped into an outer diameter of 250 fflm, an inner diameter of 2 〇 coffee, and a thickness. In the honeycomb structure of the 〇 coffee, the cation exchange resin is used to carry the honeycomb structure s. In the obtained cation exchange resin-supporting honeycomb structure s, the amount of the cation exchange resin powder supported was 184 g/m3. Next, the cation exchange resin-carrying honeycomb structure s was sliced to a thickness of 11 mm to obtain a second carrier portion T. The cation is replaced by a resin powder: a cation exchange resin (DIAi〇N (g), manufactured by Mitsubishi Chemical Corporation), an average particle size of 20/zm 夂 (produced by a dehumidification roller) - in addition to the replacement of the first carrier F, Instead of using the first carrier portion 并 and replacing the second carrier portion Η, the second carrier portion τ is used instead, and the rest is implemented in the same manner as in the first embodiment, and the dehumidification roller is obtained. Dehumidification test) In the dehumidifier 3〇, which is not shown in Fig. 6, the dehumidification roller U is installed, and the dehumidifier for the atrium is set to the muscle of the controlled muscle, 5G· And (4) operation according to the following conditions. Figure 1 shows. Clothing <Test conditions> When the honeycomb-type drum mouth surface of the regenerative gas inlet j is in contact with the 埶 couple, the temperature measured by the thermocouple is: 27〇〇c ”, • When the regeneration line iB is made The honeycomb side of the mouth side is exposed to the thermocouple 312 ΧΡ / invention manual (supplement) / 9 〇 6 / 961 〇 843 〇 47 200800396, the temperature measured by the thermocouple: 4 〇. 〇 • dehumidification The rotation speed of the drum 21: 〇·5 rpm (Comparative Example 1) (Production of the honeycomb structure carrier) According to the method of the same method of the same method as in the first embodiment, the fiber carrier A was obtained. The production of the C dehumidifying roller) f The first desiccant supporting slurry B used in the first embodiment: the fibrous carrier A. Then, the fibrous carrier A is taken out from the collecting material, After drying at 15 ° C, the dehumidification roller V was obtained by performing a small A to 50 TC. The amount of the synthetic sodium Y zeolite supported was 143 g/L·. Test, in the household dehumidifier 30 shown in FIG. 6, the dehumidification drum v is provided, and the household dehumidifier is set in the The inside of the constant temperature and humidity chamber of 25 〇c and 5〇% RH was prepared, and the dehumidification operation was performed under the following operating conditions. The results are shown in Table 1-1. <Test conditions> • Honeycomb type on the inlet side of the regeneration air When the opening face of the drum contacts the thermocouple, the temperature measured by the thermocouple: 426 t: • When the opening surface of the honeycomb drum on the outlet side of the regeneration air is brought into contact with the thermocouple ^, the temperature measured by the thermocouple: 47 °C • • Rotation speed of the dehumidification roller 21······························································· In the household dehumidifier 3, the dehumidification drum v obtained by the same method is provided, and the second machine is not placed in the strange temperature and humidity chamber controlled to 25 ° C and 50% RH, and The dehumidification operation was carried out under the following operating conditions. The results are shown in Table 1. ♦ <Test conditions> • The temperature measured by the thermocouple was measured when the honeycomb surface of the regenerative air side was brought into contact with the σ surface. :31(rc ', ,, 电鲁• When the open surface of the honeycomb drum on the outlet side of the regeneration air is contacted牯, the temperature measured by the thermocouple: 42 ° C Private rotation speed of the dehumidification drum 21: 0·5 rpm (Comparative Example 3) (Dehumidification test) The household dehumidifier 3 shown in Fig. 6 +, the dehumidification drum v obtained in the same manner as in Example 1 was set, and the household machine was set in a constant temperature and humidity chamber controlled to 25 〇, 50% RH, and: operating conditions of the second _ The dehumidification operation was carried out. The results are shown in Table . <Test conditions> • When the open surface of the honeycomb drum on the side of the reconditioning air is brought into contact with heat, the temperature measured by the thermocouple: 27〇〇c When the surface of the honeycomb drum on the outlet side of the regeneration air is brought into contact with heat, the temperature measured by the thermocouple is 4 〇. 〇, $偶.• Rotation speed of the dehumidification roller 21: 〇·5 rpm (Comparative example 4) (Manufacture of honeycomb structure carrier) 312XP/Invention manual (supplement)/96-06/96108430 49 200800396 Example " The same method was carried out to obtain a fibrous carrier A. (Preparation of dehumidification roller), main, in the second desiccant carrying material g used in Example 1, the fiber (4)_Α°_' is taken out from the polymer t 'And 5 (after the TC is dried, and then according to 5 〇 (: implementation) is small, then the dehumidification roller w is obtained. The obtained dehumidification roller w, the two emulsified stone oxime - oxidized amorphous The holding amount of the porous body is a few. The scent (dehumidification test) ^ Figure y/f shows that the dehumidifier roller is installed in the household dehumidifier 3G, and the dehumidifier is set to 25 ΐ, 5 〇 的 的 恒温 恒温 互 且 且 且 且 且 且 且 且 且 且 且 且 且 且 且 且 且 且 且 且 且 且 且 且 且 且 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 When measured, the temperature measured by the thermocouple is 426 < t
•^當使再生空氣出口侧的蜂巢式滾筒開 時,由該熱電偶所測得溫度·4rc •除濕滾筒21的旋轉速度·· 〇 · 5轉/分 (比較例5) (蜂巢式構造載體之製作) ’獲得纖維質載體A。 依照如同實施例1相同的方法實施 (除濕滾筒之製作) 312XP/發明說明書(補件)/96-06/96108430 200800396 取出,並依15(TC施行乾燥後,接著依5〇(rc施行丨小時 燒,,便獲得除濕滾筒X。所獲得除濕滾筒乂中,該八型 二氧化矽凝膠的載持量係79g/L。 & (除濕試驗) 在圖上所示該家庭用除濕機30中,設置該除濕滾筒χ, 並將忒豕庭用除濕機設置於經控制成25艽、5〇%rh的恆溫 恆濕室内,且依以下的運轉條件施行除濕運轉。結果如表 ⑩1所示。 〈試驗條件> 士田使再生空氣入口側的蜂巢式滾筒開口面接觸到熱電偶 時’由該熱電偶所測得溫度:31〇〇c •士备使再生空氣出口側的蜂巢式滾筒開口面接觸到熱電偶 時,由該熱電偶所測得溫度:42t •除濕滾筒21的旋轉速度:〇 · 5轉/分 (比較例6) 馨(除濕滚筒之製作) 上,照如同實施例3的第二載持部之製作相同方法,製成 -亥陽離子父換樹脂載持蜂巢式構造體s。所獲得陽離子交 $樹脂载持蜂巢式構造體s中’該陽離子交換樹脂粉末的 载持量係184g/m3。 (除濕試驗) 士在圖6所示該家庭用除濕機3G中’設置該陽離子交換 ㈣載持蜂巢式構造體S,並將該家庭用除濕機設置於妳 控制成25X:、50猶的恆溫恒濕室内’且依以下的運轉條 312XP/發明說明書(補件)/96-06/96腦30 51 200800396 件施行除錢轉。目纽㈣始運轉後,經丨分鐘便發生 異臭,因而中止除濕試驗。 <試驗條件> •當使再生空氣人口側的蜂巢式滾筒開口面接觸到熱電偶 時’由该熱電偶所測得溫度:2 7 〇。匸 •當使再生空氣出口侧的蜂巢式滾筒開Π面接觸到熱電偶 時’由遠熱電偶所測得溫度:4 〇它 •除濕滾筒21的旋轉速度:0· 5轉/分 [表1] 實施例1 實施例2 實施例3 比較例1 比較例2 比較例3 比較例4 比較例5 比較例6 第一除濕劑 除濕劑A g濕劑A 除濕劑A — — 一 _ _ 第二除濕劑 除濕劑B 除濕劑C 除濕劑D — — — — 一 一 除濕劑 第一載持部厚度(mm) 11 — 一 除濕劑A 除濕劑A 除濕劑A 除濕劑B 除濕劑C 除濕劑D 9 9 — — 一 一 一 一 第二載持部厚度(mm ) 9 11 11 — — — — 一 一 除濕滚筒厚度〇nm) 20 20 20 20 20 20 20 20 20 T1(°C) 426 310 270 426 310 270 426 310 270 T2(°C) 47 42 40 47 42 40 47 42 40 除濕量(L/day) 7. 66 7. 41 7. 27 7. 35 7. 08 7.14 6. 02 5.81 試驗中止 *除濕劑A:合成鈉γ型沸石 *除濕劑B:二氧化矽-氧化鋁非晶質多孔質體 *除濕劑C: A型二氧化矽凝膠 *除濕劑D:陽離子交換樹脂粉末 (產業上之可利用性) 根據本發明,將可製得即便在再生空氣入口侧的開口面 溫度為250〜500°C的較低狀態,仍可發揮充分除濕性能的 家庭用除濕機。 52 312XP/發明說明書(補件)/96-06/96108430 200800396 【圖式簡單說明】 圖1為本發明實施形態例的除濕滾筒示意圖。 圖2為圖1中的除濕滾筒開口面之人部分放大圖。 圖3為除濕機運轉時,測量開口面溫度的示意圖;其中, (3-1)係除濕機内的除濕滾筒、加熱器及熱電偶之側視 圖; (3 - 2)係除濕機内的除濕滾筒、加熱器及熱電偶之立體 籲圖。 圖4為豕庭用除濕機的滾筒箱内之構件構造圖。 圖5為家庭用除濕機之滾筒箱内的構件配置位置剖視 圖。 圖6為家庭用除濕機的立體圖。 圖7為家庭用除濕機從蜂巢式滾筒開口面扑側所觀看 到的圖。 【主要元件符號說明】 # 1 ^ 21 除濕滾筒 2 中心孔 3a、3b 開口面 4 通氣空洞 5 第一載持部 6 第二載持部 7 對厚度方向呈正交的面 8 平坦狀部 9 瓦楞狀部 312XP/發明說明書(補件)/96-06/96108430 53 200800396 10、11 載體 15、25 加熱器 16a 、 16b 熱電偶 17 再生空氣 18 輻射熱 19 來自再生空氣的熱 20 來自除濕滾筒的傳導熱 22 滾筒軸 24 第二供應機 26 吸濕空氣排氣風管 27 第一供應機 30 家庭用除濕機 31 乾燥空氣吸氣風管 32 滾筒箱 34 輻射狀肋條 35 冷凝機 36 排放配管 K 乾燥用空氣 L 吸濕空氣 Μ 被處理空氣 N 除濕空氣 P 經去除水分的空氣 54 312XP/發明說明書(補件)/96-06/96108430• When the honeycomb drum on the outlet side of the regeneration air is opened, the temperature measured by the thermocouple is 4 rc • The rotation speed of the dehumidification drum 21 · 〇 · 5 rpm (Comparative Example 5) (Hive-type structure carrier Production) 'Get fibrous carrier A. According to the same method as in the first embodiment (the production of the dehumidification roller) 312XP / invention manual (supplement) / 96-06/96108430 200800396 taken out, and according to 15 (TC dry, then according to 5 〇 (rc implementation 丨 hours) When it is burned, the dehumidifying drum X is obtained. In the obtained dehumidifying drum crucible, the loading amount of the octa-type cerium oxide gel is 79 g/L. & (Dehumidification test) The household dehumidifier 30 is shown in the drawing. The dehumidification drum was set, and the dehumidifier for the chamber was placed in a constant temperature and humidity chamber controlled to 25 艽 and 5 〇 % rh, and the dehumidification operation was performed under the following operating conditions. The results are shown in Table 101. <Test conditions> When Shida makes the open surface of the honeycomb drum on the inlet side of the regeneration air contact the thermocouple, the temperature measured by the thermocouple: 31〇〇c • The honeycomb drum on the outlet side of the regeneration air When the open surface is in contact with the thermocouple, the temperature measured by the thermocouple: 42 t • The rotational speed of the dehumidifying drum 21: 〇·5 rpm (Comparative Example 6) Xin (production of the dehumidifying roller), as in the embodiment The second carrier of 3 is produced in the same way. - The cation cationic parent exchange resin holds the honeycomb structure s. The obtained cation exchange $ resin carried the honeycomb structure s 'the cation exchange resin powder carried amount of 184 g / m3. (Dehumidification test) In the household dehumidifier 3G, the cation exchange (4) is carried in the household dehumidifier 3G, and the honeycomb dehumidifier is placed in the constant temperature and humidity chamber of 25X:, 50 s. Operating strip 312XP / invention manual (supplement) / 96-06/96 brain 30 51 200800396 pieces of the implementation of the money transfer. After the start of the operation of the new line (4), the odor is generated after a minute, thus the dehumidification test is aborted. > • When the open surface of the honeycomb drum on the side of the regenerative air is brought into contact with the thermocouple 'The temperature measured by the thermocouple: 2 7 〇. 当 • When the open surface of the honeycomb drum on the outlet side of the regeneration air is contacted To the thermocouple 'temperature measured by the remote thermocouple: 4 〇 it • rotation speed of the dehumidification drum 21: 0·5 rpm [Table 1] Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Comparative Example 6 First division Wet Agent Dehumidifier A g Wet Agent A Dehumidifier A — — _ _ Second Dehumidifier Dehumidifier B Dehumidifier C Dehumidifier D — — — — One Desiccant First Carrier Thickness (mm) 11 — Dehumidifier A Dehumidifier A Dehumidifier A Dehumidifier B Dehumidifier C Dehumidifier D 9 9 — — 1111 Second Carrier Thickness (mm) 9 11 11 — — — — Dehumidification Roller Thickness 〇nm) 20 20 20 20 20 20 20 20 20 T1 (°C) 426 310 270 426 310 270 426 310 270 T2 (°C) 47 42 40 47 42 40 47 42 40 Dehumidification (L/day) 7. 66 7. 41 7. 27 7. 35 7. 08 7.14 6. 02 5.81 Test suspension * Dehumidifier A: Synthetic sodium γ zeolite * Dehumidifier B: cerium oxide - Alumina amorphous porous body * Dehumidifier C: Type A Cerium Oxide Gel* Dehumidifying Agent D: Cation Exchange Resin Powder (Industrial Applicability) According to the present invention, it is possible to obtain a lower state of the opening surface temperature of 250 to 500 ° C even on the inlet side of the regeneration air. A household dehumidifier that can still exert sufficient dehumidification performance. 52 312XP/Invention Manual (Supplement)/96-06/96108430 200800396 [Brief Description of the Drawings] Fig. 1 is a schematic view of a dehumidifying drum according to an embodiment of the present invention. Figure 2 is an enlarged view of a portion of the opening face of the dehumidification drum of Figure 1. 3 is a schematic view of measuring the temperature of the opening surface when the dehumidifier is in operation; (3-1) is a side view of the dehumidifying drum, the heater and the thermocouple in the dehumidifier; (3 - 2) is a dehumidifying roller in the dehumidifier, A three-dimensional view of the heater and thermocouple. Fig. 4 is a structural view showing the structure of a drum box of a dehumidifier for a court. Fig. 5 is a cross-sectional view showing the arrangement of members in a drum box of a household dehumidifier. Fig. 6 is a perspective view of a household dehumidifier. Fig. 7 is a view of the household dehumidifier viewed from the flap side of the honeycomb drum. [Description of main component symbols] # 1 ^ 21 Dehumidification roller 2 Center hole 3a, 3b Opening surface 4 Ventilation cavity 5 First carrier portion 6 Second carrier portion 7 Surface 8 orthogonal to the thickness direction Flat portion 9 Corrugated 312XP/Invention Manual (supplement)/96-06/96108430 53 200800396 10,11 Carrier 15, 25 Heater 16a, 16b Thermocouple 17 Regenerative air 18 Radiant heat 19 Heat from regenerative air 20 Conducted heat from the dehumidification drum 22 Roller shaft 24 Second supply machine 26 Hygroscopic air exhaust duct 27 First supply unit 30 Household dehumidifier 31 Dry air suction duct 32 Roller box 34 Radiant rib 35 Condenser 36 Discharge piping K Drying air L absorbing air Μ treated air N dehumidifying air P dehumidified air 54 312XP / invention manual (supplement) /96-06/96108430
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JP2011121004A (en) * | 2009-12-11 | 2011-06-23 | Panasonic Corp | Dehumidification apparatus |
JP5841413B2 (en) * | 2011-11-28 | 2016-01-13 | 水澤化学工業株式会社 | Humidifier |
JP2015024399A (en) * | 2013-07-29 | 2015-02-05 | 宮崎 泰三 | High-pressure use low dew point dehumidification air generating device |
JP5898361B2 (en) * | 2015-07-09 | 2016-04-06 | 宮崎 泰三 | Low dew point dehumidification air generator for high pressure |
KR20190120195A (en) * | 2017-02-20 | 2019-10-23 | 에이지씨 가부시키가이샤 | Desiccant device for dehumidification |
CN107185487B (en) * | 2017-05-23 | 2021-01-26 | 盛朗(广州)能源科技有限公司 | A-type molecular sieve dehumidification carrier and preparation method thereof |
JP6918183B1 (en) * | 2020-05-20 | 2021-08-11 | ニチアス株式会社 | Dehumidifying member, dehumidifying rotor, and manufacturing method of dehumidifying member |
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JPH0710330B2 (en) * | 1987-03-30 | 1995-02-08 | 株式会社神戸製鋼所 | Dry dehumidifier |
JPH0245125U (en) * | 1988-09-22 | 1990-03-28 | ||
CN2339389Y (en) * | 1998-10-15 | 1999-09-22 | 高略机械股份有限公司 | Rotor-type ceramic honeycomb device of plastic dehumidifying dryer |
JP2001029731A (en) * | 1999-07-26 | 2001-02-06 | Seibu Giken Co Ltd | Air compressor |
JP3880038B2 (en) * | 2001-09-28 | 2007-02-14 | ニチアス株式会社 | Biosoluble honeycomb structure |
JP2005177673A (en) * | 2003-12-22 | 2005-07-07 | Toyobo Co Ltd | Adsorption element |
JP2006063118A (en) * | 2004-08-25 | 2006-03-09 | Nihon Micro Coating Co Ltd | Moisture-absorbing coating and sheet |
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