TW200728270A - The manufacture method of (meta) acrylic esters - Google Patents

The manufacture method of (meta) acrylic esters

Info

Publication number
TW200728270A
TW200728270A TW095142698A TW95142698A TW200728270A TW 200728270 A TW200728270 A TW 200728270A TW 095142698 A TW095142698 A TW 095142698A TW 95142698 A TW95142698 A TW 95142698A TW 200728270 A TW200728270 A TW 200728270A
Authority
TW
Taiwan
Prior art keywords
meta
manufacture method
general formula
acrylic esters
acrylic
Prior art date
Application number
TW095142698A
Other languages
Chinese (zh)
Inventor
Naoki Hashimoto
Yasuyuki Sanai
Original Assignee
Toagosei Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toagosei Co Ltd filed Critical Toagosei Co Ltd
Publication of TW200728270A publication Critical patent/TW200728270A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/60—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The manufacture method of acrylic ester of this invention is featured in conduct a dehydrating esterification reaction of (meta) acrylic acid and alcohol. Chemical compounds of the general formula (1) and water solution of basic metal hydroxides are added in the reaction liquid and heat treated in the range of 45 ~ 100 DEG C. [In the general formula (1), A is nitrogen atom or phosphorus atom; R1~ R4 is alkyl group, phenyl group or benzyl group having less than 5 carbons and each are the same or different from each other; X- is inorganic anions or organic acid ions.] According to this method, (meta) acrylic esters having improved storage stability and thermal stability are prepared.
TW095142698A 2005-11-21 2006-11-17 The manufacture method of (meta) acrylic esters TW200728270A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2005336369 2005-11-21

Publications (1)

Publication Number Publication Date
TW200728270A true TW200728270A (en) 2007-08-01

Family

ID=38048692

Family Applications (1)

Application Number Title Priority Date Filing Date
TW095142698A TW200728270A (en) 2005-11-21 2006-11-17 The manufacture method of (meta) acrylic esters

Country Status (4)

Country Link
JP (1) JP5119926B2 (en)
CN (1) CN101312938B (en)
TW (1) TW200728270A (en)
WO (1) WO2007058310A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2220023B1 (en) * 2007-12-19 2017-04-05 Evonik Röhm GmbH Process for preparing (meth)acrylates
DE102009030681A1 (en) * 2009-06-26 2010-12-30 Saltigo Gmbh Preparation of substituted 2-fluoroacrylic acid derivatives
CN104230711A (en) * 2013-06-19 2014-12-24 杨巧梅 One-pot n-hexyl acrylate synthetic process
CN104945255B (en) * 2015-02-03 2017-02-22 安庆飞凯高分子材料有限公司 Preparation method of cyclohexyl methacrylate

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3843938A1 (en) * 1988-12-24 1990-06-28 Henkel Kgaa METHOD FOR IMPROVED PRODUCTION OF (METH) ACRYLIC ACIDES OF PRESCRIBED ALCOHOLS (II)
JP2546124B2 (en) * 1993-01-25 1996-10-23 荒川化学工業株式会社 Method for producing polyfunctional (meth) acrylate
JP3887829B2 (en) * 1994-12-13 2007-02-28 東亞合成株式会社 Method for producing (meth) acrylic acid ester
JP2000095731A (en) * 1998-09-22 2000-04-04 Tokuyama Corp Production of (meth)acrylic acid ester compound
JP3788495B2 (en) * 1999-08-06 2006-06-21 東亞合成株式会社 Method for producing (meth) acrylic acid ester

Also Published As

Publication number Publication date
JP5119926B2 (en) 2013-01-16
JPWO2007058310A1 (en) 2009-05-07
CN101312938B (en) 2011-09-28
CN101312938A (en) 2008-11-26
WO2007058310A1 (en) 2007-05-24

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