TW200538279A - One piece shim - Google Patents

One piece shim Download PDF

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Publication number
TW200538279A
TW200538279A TW93115415A TW93115415A TW200538279A TW 200538279 A TW200538279 A TW 200538279A TW 93115415 A TW93115415 A TW 93115415A TW 93115415 A TW93115415 A TW 93115415A TW 200538279 A TW200538279 A TW 200538279A
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Taiwan
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carbon
ring
scope
item
annular
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TW93115415A
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Chinese (zh)
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TWI332901B (en
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Kenny Chang
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Messier Bugatti
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Abstract

A one-piece or otherwise unitary annular shim member made from a carbon material is used to maintain a space between stacked annular preforms during a manufacturing process, such as densification. The one-piece structure advantageously simplifies the arrangement of the preforms in a process chamber and causes less deformation in the preforms. The carbon composition also provides beneficial thermal effects that improve the densification process. A debonding coating is provided on the annular shim member in order to facilitate separation of the annular preforms from the shim members.

Description

200538279 九、發明說明: 【發明所屬之技術領域】 本發明係關於用於在製程期間分開堆疊的多孔性芙材之 分隔片元件。本發明之特定實例係關於用於尤其在緻密化 製程(如,化學蒸氣滲透(CVI))期間分開堆疊的環形複合材 料預型件之碳環形分隔片元件。 複合材料預型件可特別為用於製造制動盤或其他摩擦元 件之環形預型件。 【先前技術】 使環开^/預型件緻岔化以製造制動盤及類似之裝置揭示於 2〇〇3年8月14曰申請的美國專利申請案第1〇/468,〇31號;其 代表顯示於圖1中。 圖1為具有封閉空間10之處理室之高度圖解說明,其中包 含由碳纖維製成的環形預型件或基材20填充物。填充物為 基材f片組形式,且基材具有-般垂直對準的各中心通 f。豐片組可由複數個由一或多個中間載盤12分隔的疊加 疊片組區域組成。 。堆叠的基材由隔片30相互分隔。如圖2中所示,隔片3〇 :k向佈i ’且其數目可以改變。它們在相鄰的基材之間 提(、在}個疊片組實質不變高度之間隙22,同時使疊片組 之内部容積24(由-般對準的基材中心通道組成)與位於疊 外4和封閉空間丨〇内部的外部容積相通。 在圖1之實例中,封閉空間1〇包含單個基材疊片組。在一 變體中,可在相同封閉空間内並列佈置複數個基材疊片組。 93555.doc 200538279 封閉空間10由基座14(例如,由石墨製成)加熱,基座w 用於界定封閉空間10,並與在基座周圍的鑄件17外=^應4 線圈16電感耦合。可使用其他加熱方法,例如,電阻加熱Z 耳效應)。 ^ 一 使含一或多種碳之前驅體之氣體進入封閉空間, 為烴氣體,如f烧及/或乙统。在所示實例中,進入通過封 ,空間之底部1Ga進行。氣體通過由單或多片盤形成的預熱 器區域1 8,盤在封閉空間底部一片高 J 乃师置,在盤 11下支撐.基材疊片組。由預熱器盤加熱的氣體(升到封閉空 間内現有的溫度)自由流入封閉空間,同時通入内部容積 24’進入外部容積26,並進入間隙22。殘餘氣體由抽吸自 封閉空間通過在蓋丨〇b中形成的開口提取。 隔片30為單獨放置的塊元件,最通常由氧化铭製成。但, -旦形成’氧化紹塊元件很脆’且自斷裂的損失很高。實 除上在正*使用中,習知氧化鋁塊通常持續不大於2或3 個緻密化週期。這自然增加製造成本,因為必須替換氧化 鋁塊。 另外’在各預型件層之間適當手工放置單獨氧化铭塊元 和耗寺在圖2中舉例顯示6個此等塊元件,在實際實行 /用12個塊。時間負擔由處理易碎塊而不斷裂所需的非 ^:加重°通常’包含7個預型件盤(各具有12至14個預 豎片組)的完全'敏密化過程可能耗費一或二個工作日 才能根據習知方法建立。 與使用单個隔片元件3〇相關的另一問題為它們傾向於由 93555.doc 200538279 如上堆豐的預型件(和隔片)之重量導致預型件變形(實際上 為凹下)。可自圖2瞭解,在隔片元件30之間圓周有預型件 的大非支撐區域。由於預型件材料一般易彎,且由於氧化 鋁組成的隔片元件3〇不變形,凹入發生在對應於隔片元件 :位置的預型件表面。儘管輕微,但此等變形必須在額外 完成步驟機械加工掉,以獲得用於摩擦應用的所需平坦表 因此各預型件之厚度比最終產品需要的厚,預期變 形發生在已知製程及去除此等變形的最終機械加工步驟。 機械加工·掉的材料表現出經濟浪費。 【發明内容】 蓉於前述,本發明係關於用於分開堆疊 單片或其他單元環形分隔片元件。 H件之 根據本發明之分隔片元件具有具相反第一和第二表面之 一般平坦化環形形狀。至少—個表面經成形,以至少部分 界定用於連通分隔片元件内部空間與外部的徑向延伸氣流 根據本發明之分隔Μ件較佳在徑向尺寸上類似於盘立 相鄰的環形預型件。即’分隔片元件較佳具有與環形預型 件相似的内徑及外徑。如果公 如果刀隔片兀件在尺寸上與環形預 件-般不相同,則較佳使分隔片元件略小(即,呈有大於 環形預型件之内徑及/或小於環形預型件之外徑),而不是分 隔片疋件大於環形預型件(即,徑向較寬)。 ,:本發明一實例中’分隔片元件由其中具有所形成剝離 1層之碳材料(如,石墨或碳/碳複合材料)組成。 93555.doc 200538279 .實施方式】 般而言, 特性 根據本發明之分隔片元件具有明確基本有 用 在晶_ μ 件=較組中每個環形預型件之間使用多個單獨隔片元 形預型件:片或其他單元結構極大便於負荷具有堆疊的環 兩亜:之處理室。如上注意到,關於圖2的上述習知佈置 通常由言/隔片元件。另外’由於習知隔片元件 的手工:碎材料製成’如氧化紹,必須在已超長且乏味 斷裂。隔Γ期間用極大細心處理各隔片元件,以試圖避免 兀件亦相對較小,且很薄(例如,1Πχ4,,χ〇 1 這亦使它們處理困難。 · :用根據本發明之單片式分隔片元件,佈置分隔片元件 晉I:動作代替根據習知方法佈置單獨隔片元件的數個放 ^ 與用以上討論的習知方式裝載處理室之一或二天 比幸乂,使用根據本發明之單片式 時間減到2至4小時。 Ά片在相專基礎使裝載 此外,與如圖2所示的習知使用單獨隔片元件比較,根據 本發明之單片式分隔片元件之結構在更大範圍較佳支撐豆 上堆登的一或多個環形預型件之重量。特別為,環形單片式 分隔片元件之徑向寬度約等於或略窄於環形預型件之寬 度。因此’在自處理室移出後,各環形預型件有較小變形。 這意味,在緻密化製程後需要較少補救性機械加工獲得有 用不變形表面。 剛已提到,單片式分隔片元件較佳具有與環形預型件約 93555.doc 200538279 相同之向寬度,或略窄(例如,相對於其外 5毫米)。如果單片式分隔片元件寬於環形預型件二約 部分趨向於自緻密化氣體分解在其上具有殘餘積累二 溫分解的碳)。這將減少分隔片元件的使用壽命 阿 除此等積累需要額外再磨光步驟。此外 ”、’移 不^刀隔片元株 |向向外伸出環形預型件之外邊緣,則可能導致的 為’在用於同時處理的處理室放置數個環形預型件 (這通常進行)。這將負面影響製造效率達到這樣一種^度且 由於處理室内的間隔問題,可-起處理較小數個疊片,: 通常,根據本發明之單片式分隔片元件在其一或二個表 面包括徑向延伸㈣道或其他特徵,科道以、淨效庫至小 部分界定連通單片式分隔片元件之徑向内側與其徑向外二 :乳流通道。在此應注意”部分"界定的氣流通道,因為在 :些例中,氣流通道亦部分由與單片式分隔片元件結構妹 5的環形預型件之—之相對表面界定。利用單片式分隔片 ° 的氣流通道之橫截面面積較佳以淨效應可Μ前佈置中^ 不的橫載面面積比較此考慮可根據單獨情況變化。 應睁解,所顯示的氣流通道之集合性橫載面面積可受(例 ^ )調節各通道或類似| ^ 寸或^供多個通道或類似者 衫響。關於此點的決定因素為保持用於覆蓋環形預型件的 理想載體水平。 ^根據本發明之單片式分隔片元件應由能夠經受至 2 1100 C (較佳咼達約1200〇c至14〇(rc (出於完全目的)) 度之材料製成。所選擇材料較佳在所提到操作溫度與 93555.doc 200538279 預型件為最低反應性。 於)適:::片式分隔片元件的材料之實例包括(但不限 人人如石墨、碳/碳及織造碳纖維紗線;模製的陶 鎢。“材料’如不銹鋼、InCC)nel合金、鈦、鉬、鈕及 圖 3a-3c、4 a - 4 r Γ β 5a_5c顯示根據本發明之以碳為主之單 熱導性石墨。在後例中,適用石墨在如_、 UCAR和MKU-S之名義下購得。 可根據本發明用Ρ左十j Α 碳/碳材料製成環形分3:預f件(可針剌)將 八,※ 、 或自夕層織造碳纖維織物層 σ ΛΛ Y CVI或樹脂浸潰製程緻密化。 :將…炭為主的原料用已知方式模製或/或編 所if 了將用作原料的石墨用已知方式自機械加工 所需幾何形。 在圖3a-3c中’圖3a為根據本發明之環形分隔片元件则 之俯視圖。圖3b為環形分隔片元件3⑼之透視圖。圖& 垂直於其令環形分隔片元件3⑼平放平面之平 件300之橫截面正視圖。 阳片70 =分:片元件3。。具有複數個分開的一般規則形狀高 起#刀(一些在304a表示)與其—侧上其間的相 (一些在顯表示)交替。同樣,環形分隔請的另 有對應分開的一般規則形狀高起部分(一些由虛線在如: 表不)與其間的相對低下部分(-些在302b表示)交替。 93555.doc 10 200538279 /本實例中,高起部分3()2a,3()4a之邊緣部分在環形分 '片兀件300的另一側重疊對應高起部分之邊緣。例 圖V。它們共同比以上提到的習知隔片元件^提供更大重 量負荷面積。因此,疊片組之重量在更大面積展開,且負 何不以在對應習知隔片元件3〇定位的習知方法中導致相對 嚴重影響之習知方式集中。 ’ 低下部分302b,304b界定緻密化氣體能夠自堆疊環形預 型件内部流到外部的徑向延伸通道或氣流通道。如上提 到’此等通道對緻密化氣流顯示的集合性橫截面面積一船 可根據較操作情況變化。g,橫截面面積通常應可盘使又 用以上所提到習知隔片元件30時顯示者比較。 在圖仏_,圖4a為根據本發明之環形分隔片元件彻 之俯視圖。圖4b為環形分隔片元件4⑼之透視圖。圖 垂直於其:環形分隔片元件4〇〇平放平面之平面分隔片元 件4 0 0之橫截面正視圖。 環形分隔片元件400結構與環形分隔片元件_的類似之 處在於’其兩侧均具有相對高起部分似,4〇4a與相對低 下部分4—心侧交替。在此,相對低下部分觸,侧 同樣界疋緻密化氣體能夠自堆疊環形預型件内部流 部的徑向延伸通道或氣流通道。 八 成=二中广',環形分隔片元件3〇°之結構係相對於組 成材料之中心平面厚度界^。因此,可在環形分隔片元 件3 00之外部邊緣周圍追蹤直圓周路徑。 相反’由於環形分隔片元件400相對薄於環形分隔片元件 93555.doc 200538279 所以沒有其中組成材料的相當平面厚度。因此,只可 沿壞形件㈣部邊緣追钱㈣ 替高起部分和低下部分)。(例如,見圖4c)。 … 在圖We中,圖化為根據本發明之環形分隔片元件· 之俯視圖。圖5b為環形分隔片元件5〇〇之透視圖。圖5c為在 垂直於其中環形分隔片元件5⑻平放平面之平面分隔片元 件5 0 0之橫截面正視圖。 &環形分隔片元件與環形分隔片元件3⑽和彻的最一 般區別在於’環形分隔片元件5⑻相反側的相對高起部分 5〇2a,504晴準’如同低下部分,尤其見㈣。 如前’低下部分502b,504b至少部分界定緻密化氣體能夠 在堆疊環形預型件内部及其外部t間能夠通過的通道。 在一實例中,可自於碳(例如,石墨)坯料的相反面上形 成對應通道502b,504b之觀點考慮製造環形分隔片元件 5〇〇,坯料在高起部分502a,504a對應的位置具有至少在環 形分隔片元件500厚度級的初始厚度。 如上提到,前述幾何形可由任何已知適當方法獲得,尤 其但不僅由機械加工或模製或二者獲得。 在用碳材料製造根據本發明之分隔片元件用於複合碳環 形預型件時,有時在緻密化製程後有分隔片元件接著到預 i件之問通。為解決此問題,本發明涵蓋在分隔片元件表 ®上提供剝離塗層,以幫助避免此接著。 有用剝離塗層的一個實例包括在分隔片元件上形成的由 Mosh組成之第一層和在第一層上形成的由八丨2〇3組成之第 93555.doc -12- 200538279 二層。例如,此等層可用已知 區& & m六口 水贺射方法形成。MoSi, 層作為橋接層,以改良八喊層對結構 - 應注意到,提供以碳為主的分者。 , k ^ . 刀隔片儿件在製造期間具有 頭外ϋ處,尤其為石墨分隔Κ 品η & _ ^片疋件。通常,對環形預型件 :!:片、,且^供石墨分隔片元件給 仵^曰加®片組的熱質,以促進加 熱且依次促進緻密化。由於 、早獨熒升預型件溫度相對較 難’這很有益。(在習知方、、表由 丄 ⑼白夫方法中’由於與疊片組中的中間預 型件比較較高暴露於加熱,預型件疊片組頂部和底部具有 最南水隼緻密化水平)。同樣’由於碳分隔片元件的優良教 導性,可跨相鄰環形預型件之徑向寬度提供更均勾溫度分 佈0 雖然已關於最實際具體實施例㉝述本發明,但應特別注 f到,這僅作為實例,且適當修改和變化在附㈣請專利 範圍的主旨和範圍内亦為可能。 【圖式簡單說明】 參考附圖將更佳理解本發明,其中·· 圖1顯示用於使堆疊的環形預型件緻密化之處理室; 圖2顯示用於分開圖1中所示堆疊的環形預型件之單獨隔 片元件之佈置; ^ 圖3a-3c顯示根據本發明之單片式分隔片元件之第一實 例; 圖4a-4c顯示根據本發明之單片式分隔片元件之第二 例; 圖5a-5c顯示根據本發明之單片式分隔片元件之第三實 93555.doc 13 200538279 例。 明確強調的是’本文令各圖只說明本發明之實例,而不 作為以任何方式限制其定義解釋。亦應注意到,以通常或 相關觀點,本文中各圖不一定按比例繪製。 【主要元件符號說明】 10 封閉空間 10a 封閉空間之底部 10b 蓋 11 盤 12 中間載盤 14 基座 16 感應線圈 17 铸件 18 預熱器區域 20 環形預型件或基材 22 間隙 24 内部容積 26 外部容積 30 隔片(環形分隔片元件) 300 續形分隔片元件 302a , 304a 一般規則形狀高起部分 302b , 304b 相對低下部分 306 組成材料 400 %形分隔片元件200538279 IX. Description of the invention: [Technical field to which the invention belongs] The present invention relates to a separator sheet element for porous fragrant materials that are separately stacked during the manufacturing process. A particular example of the present invention relates to a carbon annular separator element for annular composite preforms that are stacked separately, especially during a densification process, such as chemical vapor infiltration (CVI). Composite preforms can be particularly annular preforms used in the manufacture of brake discs or other friction elements. [Prior art] Bifurcation of ring-opening / preforms to manufacture brake discs and similar devices is disclosed in U.S. Patent Application No. 10/468, 〇31, filed on August 14, 2003; Its representative is shown in FIG. 1. Fig. 1 is a high-level illustration of a processing chamber having an enclosed space 10, which contains a ring-shaped preform or substrate 20 filler made of carbon fiber. The filler is in the form of a substrate f sheet group, and the substrate has center centers f which are generally vertically aligned. The film group may consist of a plurality of stacked film group regions separated by one or more intermediate carriers 12. . The stacked substrates are separated from each other by a spacer 30. As shown in FIG. 2, the spacers 30: k-direction cloth i 'and their number can be changed. They provide (,) a gap 22 of substantially constant height between the lamination stacks between adjacent substrates, and at the same time make the inner volume 24 of the lamination stacks (composed of the center channel of the substrate generally aligned) and Outer stack 4 communicates with the external volume inside the enclosed space. In the example of FIG. 1, the enclosed space 10 contains a single substrate stack. In a variant, multiple bases can be arranged side by side in the same enclosed space. 93555.doc 200538279 The enclosed space 10 is heated by a pedestal 14 (for example, made of graphite), and the pedestal w is used to define the enclosed space 10 and outside the casting 17 around the pedestal = ^ 应 4 Coil 16 is inductively coupled. Other heating methods can be used, such as resistance heating Z-ear effect). ^ A The gas containing one or more carbon precursors is brought into a closed space, and is a hydrocarbon gas, such as sintered and / or ethane. In the example shown, the entry through the seal, the bottom 1Ga of the space. The gas passes through the preheater area 18 formed by a single or multiple disks. The disks are placed at the bottom of the enclosed space at a height J, and are supported under the disks. The gas heated by the pre-heater plate (rising to the existing temperature in the enclosed space) flows freely into the enclosed space, while passing into the internal volume 24 ', into the external volume 26, and into the gap 22. Residual gas is extracted from the enclosed space by suction through an opening formed in the cover. The spacer 30 is a separately placed block element and is most often made of an oxidized inscription. However,-once the 'oxidized sintered element is brittle', the loss from self-fracture is high. In fact, in normal use, the conventional alumina block usually lasts no more than 2 or 3 densification cycles. This naturally increases manufacturing costs because the aluminum oxide block must be replaced. In addition, a separate oxidized ingot element and a waste temple are appropriately manually placed between each preform layer. Fig. 2 shows an example of 6 such block elements, and 12 blocks are actually implemented / used. The time burden is not required for processing fragile pieces without breaking: Aggravation ° Usually 'complete' densification processes containing 7 preform trays (each with 12 to 14 pre-riser groups) may take one or more It takes two working days to establish according to the conventional method. Another problem associated with the use of a single spacer element 30 is that they tend to deform (actually recessed) the preforms (and spacers) due to the weight of the preforms (and spacers) piled up as described above. As can be understood from Fig. 2, there is a large unsupported area of the preform between the spacer elements 30 on the circumference. Since the preform material is generally easy to bend, and since the spacer element 30 composed of alumina is not deformed, the depression occurs on the surface of the preform corresponding to the position of the spacer element:. Although slight, these deformations must be machined in additional steps to obtain the required flat surface for friction applications. Therefore, the thickness of each preform is thicker than required for the final product. The deformation is expected to occur in known processes and removals. These deformed final machining steps. Materials that are machined and dropped represent economic waste. [Summary of the Invention] As mentioned above, the present invention relates to a ring-shaped separator element for separately stacking single sheets or other units. The H-piece separator element according to the present invention has a generally flattened annular shape having opposite first and second surfaces. At least one surface is shaped to at least partially define a radially extending airflow for communicating the internal space of the separator element with the outside. The partitioning member according to the present invention is preferably similar in radial dimension to an adjacent ring preform Pieces. That is, the 'separator member preferably has an inner diameter and an outer diameter similar to those of the ring preform. If the knife spacer element is not the same in size as the ring preform, it is preferable to make the separator element slightly smaller (that is, have an inner diameter larger than the ring preform and / or smaller than the ring preform. Outside diameter), rather than the spacers being larger than the ring preform (ie, wider in the radial direction). : In one example of the present invention, the 'separator' element is composed of a carbon material (e.g., graphite or a carbon / carbon composite material) having a peeling layer formed therein. 93555.doc 200538279. In general, the characteristics of the separator element according to the present invention have a clear and fundamental usefulness. Crystal_ μ pieces = using multiple separate spacer element shaped pre-forms between each ring preform in the group. Profiles: Sheets or other unit structures greatly facilitate the loading of stacking rings. Two processing chambers. As noted above, the conventional arrangement described above with respect to Fig. 2 is generally composed of speech / spacer elements. In addition, because of the conventional manual: made of shredded material of the spacer element, such as oxide shaw, it must be broken in a long and tedious manner. Each spacer element is treated with great care during the interval Γ in an attempt to avoid that the elements are also relatively small and thin (e.g., 1Πχ4, χ〇1 which also makes them difficult to handle. ·: Using a single chip according to the present invention Type separator element, arranging the separator element. I: Action instead of placing several separate elements of the separator element according to the conventional method. ^ As compared with loading one of the processing chambers in the conventional manner discussed above or two days later, use this method. The invention's monolithic time is reduced to 2 to 4 hours. The cymbal is loaded on a special basis. In addition, compared with the conventional use of separate spacer elements as shown in FIG. 2, the monolithic separator element according to the present invention The structure preferably supports the weight of one or more ring preforms stacked on the bean in a larger range. In particular, the radial width of the ring-shaped single-piece separator element is approximately equal to or slightly narrower than the width of the ring preform. . Therefore 'the ring preforms have less distortion after being removed from the processing chamber. This means that less remedial machining is required after the densification process to obtain a useful non-deformable surface. As mentioned earlier, the monolithic partition Chip component Has the same directional width as the ring preform about 93555.doc 200538279, or is slightly narrower (for example, 5 mm outside of it). If the single-piece separator element is wider than the ring preform, the second part tends to be self-dense The decomposition gas has residual carbon on which there is residual dithermal decomposition. This will reduce the useful life of the separator elements. In addition to this accumulation, additional repolishing steps are required. In addition, "," Move the knife septum element | outward | extending the outer edge of the ring preform outward, it may result in 'Place several ring preforms in the processing chamber for simultaneous processing (this is usually This will negatively affect the manufacturing efficiency to such a degree and due to the problem of the space in the processing chamber, it is possible to process a small number of laminations in general: Generally, the single-piece separator element according to the present invention is The two surfaces include radially extending channels or other features. Kedao defines the radial inner side and the radial outer side of the connected monolithic separator element with a small part of the net effect library. The milk flow channel. Attention should be paid here. " Partially defined airflow channels, because in some cases, the airflow channels are also partially defined by the opposing surface of the annular preform of the single-piece separator element structure 5. The cross-sectional area of the airflow channel using the single-piece separator ° is better. The net effect can be compared in the previous layout. The area of the cross-section is compared. This consideration can be changed according to individual circumstances. It should be explained that the area of the collective cross-section of the displayed airflow channel can be adjusted (for example, ^) for each channel or similar | ^ inch or ^ for multiple channels or similar. The deciding factor in this regard is to maintain the ideal carrier level for covering the annular preform. ^ The monolithic separator element according to the present invention should be made of a material that can withstand temperatures up to 2 1100 C (preferably up to about 12 00c to 14 0 (rc (for complete purpose)). The selected material is Fortunately, the mentioned operating temperature is the lowest reactivity with the 93555.doc 200538279 preforms. Applicable to :: Examples of materials for sheet separator elements include (but are not limited to, for example, graphite, carbon / carbon and weaving. Carbon fiber yarns; molded ceramic tungsten. "Materials' such as stainless steel, InCC) nel alloys, titanium, molybdenum, buttons, and Figs. 3a-3c, 4a-4r Γ β 5a_5c show that carbon Single thermally conductive graphite. In the latter example, suitable graphite is purchased under the names such as _, UCAR, and MKU-S. According to the present invention, it can be made into a ring shape with P 分 十 j Α carbon / carbon material 3: pref It is possible to densify the carbon fiber fabric layer σ Λ Λ Y CVI or resin impregnation process of woven carbon fiber fabrics ※, 、, or satin layers.: The carbon-based raw materials are molded or known in a known manner. If the graphite is used as the raw material, the required geometry is self-machined in a known manner. Figures 3a-3c 'Figure 3a is a ring shape according to the invention The top view of the separator element. Figure 3b is a perspective view of the ring separator element 3⑼. Figure & A cross-sectional front view perpendicular to the flat piece 300 which makes the ring separator element 3⑼ flat. The male piece 70 = points: Slice element 3. Has a plurality of separate general regular shapes with high #knife (some indicated in 304a) and alternate phases (some indicated in explicit) on the side of it. Similarly, the ring-separated please have another correspondingly divided general Regularly shaped raised portions (some indicated by dotted lines such as: not shown) alternate with their relatively lower portions (some indicated by 302b). 93555.doc 10 200538279 / In this example, the raised portions 3 () 2a, 3 ( ) The edge portion of 4a overlaps the edge of the raised portion on the other side of the annular segment piece 300. Example V. They collectively provide a larger weight load area than the conventional spacer element ^ mentioned above. Therefore The weight of the lamination group is spread over a larger area, and it is not necessary to focus in a conventional manner that leads to a relatively serious impact in the conventional method of positioning the conventional spacer element 30. 'Lower part 302b, 304b defines densification Gas can Radially extending channels or airflow channels that flow from the inside of the stacking ring preform to the outside. As mentioned above, 'these channels show a collective cross-sectional area for densified airflow. A boat can vary depending on the operating conditions. G, cross-section The area should generally be comparable to that shown when using the conventional spacer element 30 mentioned above. In Figure __, Figure 4a is a top view of the annular spacer element according to the present invention. Figure 4b is an annular spacer element A perspective view of 4mm. The figure is perpendicular to it: a cross-sectional front view of a ring-shaped separator element 400 flat planar plane separator element 400. The structure of the ring-shaped separator element 400 is similar to that of the ring-shaped separator element _ in that it has a relatively high raised portion on both sides, and 404a alternates with a relatively low portion 4-heart side. Here, the relatively lower part touches, and the side also has the same densified gas that can flow from the radially extending channel or air flow channel of the inner flow portion of the stacked annular preform. Bacheng = Erzhongguang '. The structure of the ring-shaped separator element 30 ° is relative to the thickness boundary of the center plane of the material ^. Therefore, a straight circumferential path can be traced around the outer edge of the annular separator element 300. On the contrary, since the annular spacer element 400 is relatively thinner than the annular spacer element 93555.doc 200538279, there is no considerable planar thickness of the constituent materials therein. Therefore, you can only chase money along the edge of the bad part ㈣ to replace the high and low parts). (See, for example, Figure 4c). … In Figure We, the figure is a top view of the annular separator element according to the present invention. Fig. 5b is a perspective view of the ring-shaped separator element 500. Fig. 5c is a cross-sectional front view of a planar separator element 500, which is perpendicular to the plane in which the annular separator element 5⑻ lies flat. & The most common difference between the ring-shaped separator element and the ring-shaped separator element 3⑽ is that the relatively raised portion 502a, 504 on the opposite side of the ring-shaped separator element 5⑻ is like the lower part, especially see ㈣. As before, the 'lower portions 502b, 504b at least partially define a passage through which the densified gas can pass between the inside and outside t of the stacked ring preform. In one example, it is possible to consider manufacturing a ring-shaped separator element 500 from the viewpoint that corresponding channels 502b, 504b are formed on the opposite side of a carbon (eg, graphite) blank, and the blank has at least a position corresponding to the raised portions 502a, 504a. The initial thickness in the thickness of the annular separator element 500. As mentioned above, the aforementioned geometries can be obtained by any known suitable method, especially but not only by machining or molding or both. When a separator element according to the present invention is manufactured from a carbon material for use in a composite carbon ring preform, sometimes the separator element is followed by the preform after the densification process. To solve this problem, the present invention covers providing a release coating on the separator element table ® to help avoid this. One example of a useful release coating layer includes a first layer composed of Mosh formed on a separator element and a second layer composed of 93555.doc -12-200538279 composed of eighty-two-three formed on the first layer. For example, these layers can be formed using the known area & m Liukou water injection method. The MoSi, layer serves as a bridge layer to improve the structure of the Yahoo layer-it should be noted that a carbon-based splitter is provided. , k ^. The blade spacer has a head outer part during manufacture, especially a graphite-separated K product η & _ ^ piece part. In general, for ring preforms:!: Sheet, and the thermal mass of the graphite separator sheet element to the 仵 ^ Plus® sheet set to promote heating and, in turn, densification. It ’s very beneficial because the temperature of the preform is relatively difficult to rise early. (In the conventional method, the surface and the surface method are used because of the higher exposure to heat than the middle preform in the lamination group. Level). Similarly, 'because of the excellent teaching of the carbon separator element, a more even temperature distribution can be provided across the radial width of adjacent annular preforms. Although the invention has been described in terms of the most practical specific embodiment, special attention should be paid to This is only an example, and appropriate modifications and changes are also possible within the spirit and scope of the scope of the attached patent. [Brief description of the drawings] The present invention will be better understood with reference to the drawings, in which: Fig. 1 shows a processing chamber for densifying stacked ring preforms; Fig. 2 shows a separation chamber for separating the stacks shown in Fig. 1 Arrangement of individual spacer elements of a ring preform; ^ Figures 3a-3c show a first example of a single-piece separator element according to the present invention; Figures 4a-4c show a first example of a single-piece separator element according to the present invention Two examples; Figures 5a-5c show a third example of a single-piece separator element according to the present invention. It is explicitly emphasized that 'the drawings are only illustrative of the invention and are not to be construed as limiting its definition in any way. It should also be noted that, from a general or related point of view, the figures in this article are not necessarily drawn to scale. [Description of main component symbols] 10 Closed space 10a Bottom of closed space 10b Cover 11 Plate 12 Intermediate carrier plate 14 Base 16 Induction coil 17 Casting 18 Preheater area 20 Ring preform or substrate 22 Gap 24 Internal volume 26 External Volume 30 Separator (ring-shaped separator element) 300 Continued separator element 302a, 304a Generally regular shaped raised part 302b, 304b Relatively low part 306 Composition material 400% shaped separator element

93555.doc 14 200538279 402a , 404a 相對高起部分 402b , 404b 相對低下部分 500 環形分隔片元件 502a , 504a 相對高起部分 502b , 504b 低下部分 93555.doc -15 -93555.doc 14 200538279 402a, 404a relatively high portion 402b, 404b relatively low portion 500 Ring separator element 502a, 504a relatively high portion 502b, 504b low portion 93555.doc -15-

Claims (1)

200538279 十、申請專利範圍: 種.、有第和第一相反表面之環形單元分隔片元件, /、 —件由在其上具有所形成剝離塗層之碳材料製 成’该兀件包括在第一和第二表面之至少一個表面上形 成的複數個徑向延伸通道。 2·根據申請專利範圍第1項之元件,其中該複數個徑向延伸 通道係形成於第一和第二表面二者上。 3.根據申請專利範圍第2項之元件,其中該在第一表面上形 成的複數個通道實質上與在第二表面上形成的複數個通 道對準。 4.根據申請專利範圍第2項之元件,其中該在第一表面上形 成的複數個通道實質上以圓周方向偏離在第二表面上形 成的複數個通道。 5. 6. 根據申請專利範圍第1項 料和固體石墨材料之一 根據申請專利範圍第5項 織造碳纖維紗織物。 之元件,其中該碳材料為碳/碳材 之元件,其中該碳/碳纖維材料為 艮據申請專利範圍第1項之元件,其中該剝離塗層包括在 :材料上形成的第一祕2層和在第_Mosi2層上形成的 第—Al_2〇3 層。 δ. 檀I備複數個用 系、虱滲透製程之環形碳 型件之方法,其包括: 堆疊複數個環形碳纖維預料,其巾在各對環形碳 預型件之間提供由碳材料製成的環形單元分隔片 丁 93555.doc 200538279 件’堆疊的複數個環形碳纖維預型件和環形單元分 凡件集合性界定該疊片組内的内部空間, w 其中各環形單元分隔片元件具有反向相對的第一和第 組内部空間與疊片組外部的在 弟一、面之至少-個表面上形成的複數個徑向 二:,Γ單元分隔片元件具有在其上形成的用 於防止核形奴纖維預型件接著的剝離塗声。 9. ==利範圍第8項之方法,其中各環形單元分隔片 道。 和第-表面具有在其上形成的各複數個通 10. =申請專利範圍第9項之方法,其中該在第-表面上形 =數個通道實質上與在第二表面上形成的複數個通 η::請專利範圍第9項之方法其中該在第一表面上形 成的複數個通道0周方向偏離在第二表面上形 1 2.根據申請專利範圍第8項之方 1 山 維材料和固體石墨㈣之_。 讀料為碳/碳纖 ^==^]範_12項之方法’其中該碳/碳纖維材料 為織Xe兔纖維紗織物。 14.根據申請專利範圍第8項之 碳材料上形成的剝離塗層包括在 第二㈣層。 2層和在第—M咖層上形成的 包括 15· -種自碳纖維製造單元環形分隔片之方法,該方法 93555.doc 200538279 自厌材料开7成兔形元件,該環形元件具有第一和第二 相反表面及在和第二相反面之至少—面上形成的徑 向延伸通道;及 在環形元件上形成剝離塗層。 根據申。月專利範圍第1 $項之方法,#中該形成剝離塗層 匕括在石反材料上形&第一心叫層和在第一心叫層上形 成第二ai2o3層。 根據申1專利範圍第i 6項之方法,#中該形成剝離塗層 包括用-電疲噴射在碳材料上形成第一 M〇Si]層和在第一 MoSi2層上形成第二ai2〇3層。 18·根據中請專利範圍^項之方法,其中該形成環形元件 包括機械加工石墨±5料。 19. 根據中請專利_第15項之方法,其中該碳材料為碳/碳 纖維材料和織造碳纖維紗織物之一。 20. 根據申請專利範圍第8項之方法,其中該提供由介於各對 環形碳纖維預型件間之碳材料製成的環形單元分隔片元 件增加該疊片組之熱質,以改良化學蒸氣滲透製程之效 率 〇 21. 根據申請專利範圍第8項之方法,其中各環形分隔片具有 小於環形碳纖維預型件外徑之外徑及大於環形碳纖維預 型件内徑之内徑。 22. 根據申請專利範圍第21項之方法,其中各環形分隔片之 外徑及内徑分別小於及大於環形碳纖維預型件外徑及内 徑約5毫米。 93555.doc200538279 10. Scope of patent application: Kinds of ring-shaped unit separators with first and first opposite surfaces, /,-made of carbon material with a release coating formed thereon, the element is included in the first A plurality of radially extending channels are formed on at least one of the first and second surfaces. 2. The element according to item 1 of the scope of patent application, wherein the plurality of radially extending channels are formed on both the first and second surfaces. 3. The element according to claim 2 of the scope of patent application, wherein the plurality of channels formed on the first surface are substantially aligned with the plurality of channels formed on the second surface. 4. The element according to item 2 of the scope of patent application, wherein the plurality of channels formed on the first surface are substantially offset in a circumferential direction from the plurality of channels formed on the second surface. 5. 6. Weaving carbon fiber yarn fabric according to item 1 of the scope of patent application and one of solid graphite materials. A component, wherein the carbon material is a carbon / carbon material component, wherein the carbon / carbon fiber material is a component according to item 1 of the patent application scope, wherein the release coating includes a first layer 2 formed on the material And the -Al_203 layer formed on the _Mosi2 layer. δ. A method for preparing a plurality of annular carbon profiles using a system and a lice infiltration process, including: stacking a plurality of annular carbon fiber predictions, and providing a towel made of carbon material between each pair of annular carbon preforms Ring-shaped unit separators 93555.doc 200538279 'stacked multiple ring-shaped carbon fiber preforms and ring-unit specials collectively define the internal space within the stack group, where each ring-unit separator element has oppositely opposed The first and second sets of internal spaces and the plurality of radial two formed on at least one surface of the first surface and the outer surface of the lamination group: the Γ unit separator element has a shape formed thereon for preventing nucleation Slave fiber preform is then peeled and painted. 9. == The method of the eighth range, in which each ring-shaped unit separates a slice track. And the first surface has a plurality of channels formed thereon. 10. = The method of claim 9 in the scope of patent application, wherein the shape on the first surface = several channels are substantially the same as the plurality of channels formed on the second surface. Tong n :: The method of item 9 of the patent scope, wherein the plurality of channels formed on the first surface are deviated from the shape of the second surface on the second surface 1 2. According to the method of item 8 of the scope of patent application 1 And solid graphite ㈣ 之 _. The reading material is carbon / carbon fiber ^ == ^] The method of item _12, wherein the carbon / carbon fiber material is a woven Xe rabbit fiber yarn fabric. 14. The release coating formed on the carbon material according to item 8 of the scope of patent application is included in the second hafnium layer. 2 layers and a method of forming 15 · -ring-shaped separators made of carbon fiber on the M-th coffee layer, the method 93555.doc 200538279 self-loathing material is 70% rabbit-shaped element, the ring element has a first and A second opposite surface and a radially extending channel formed on at least one of the second opposite surface; and forming a release coating on the annular element. According to Shin. In the method of item 1 of the monthly patent, the method of forming a peeling coating in # is to form a & first heart layer and a second ai2o3 layer on the first heart layer. According to the method of item i 6 of the scope of the patent of claim 1, the formation of the release coating in # includes forming a first MoSi layer on the carbon material by electro-spraying and forming a second AI203 on the first MoSi2 layer Floor. 18. The method according to the patent claim ^, wherein the forming of the ring-shaped element includes machining graphite material. 19. The method according to the patent claim No. 15, wherein the carbon material is one of a carbon / carbon fiber material and a woven carbon fiber yarn fabric. 20. The method according to item 8 of the scope of patent application, wherein the provision of a ring-shaped cell separator sheet element made of a carbon material interposed between each pair of ring-shaped carbon fiber preforms increases the thermal mass of the stack to improve chemical vapor penetration The efficiency of the manufacturing process 21. According to the method of claim 8 in the scope of patent application, each annular separator has an outer diameter smaller than the outer diameter of the annular carbon fiber preform and an inner diameter larger than the inner diameter of the annular carbon fiber preform. 22. The method according to item 21 of the scope of patent application, wherein the outer diameter and inner diameter of each annular separator are smaller and larger than the outer diameter and inner diameter of the annular carbon fiber preform by about 5 mm, respectively. 93555.doc
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