TW200536878A - Method for recycling polycarbonate plastic from discarded mixed compact disc - Google Patents

Method for recycling polycarbonate plastic from discarded mixed compact disc Download PDF

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Publication number
TW200536878A
TW200536878A TW93112833A TW93112833A TW200536878A TW 200536878 A TW200536878 A TW 200536878A TW 93112833 A TW93112833 A TW 93112833A TW 93112833 A TW93112833 A TW 93112833A TW 200536878 A TW200536878 A TW 200536878A
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TW
Taiwan
Prior art keywords
disc
acetic acid
acid solution
pour
broken
Prior art date
Application number
TW93112833A
Other languages
Chinese (zh)
Inventor
Cheng-Wen Chuang
Original Assignee
Cheng-Wen Chuang
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cheng-Wen Chuang filed Critical Cheng-Wen Chuang
Priority to TW93112833A priority Critical patent/TW200536878A/en
Publication of TW200536878A publication Critical patent/TW200536878A/en

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

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  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

Abstract

Provided is one kind of means of recycling discarded hybrid compact discs. Slowly add calcium hypochlorite solution to the broken discard mixed compact discs and adjust the pH value to 3 to 5 by adding acetic acid, which will produce a great deal of activated oxygen and hypochlorous acid to oxidize the dyes and metals like silver, aluminum on the surface layer of the compact discs. Filter and remove the liquid after reaction, add acetic acid solution with heating at a high temperature to make the plastic film of the surface layer be peeled off or dissolved. When the compact discs become transparent, the purpose of recycling polycarbonate plastics can be achieved.

Description

200536878 五、發明說明(1) ^_ 【發明所屬之技術領域] 本發明係利用次氯酸舞的強氧化能力氧化光碟片表 及反射層的金屬,@時藉廢棄的混合光碟 二枓 溶解於醋酸的原理,從廢華纟#Η φ 骖艇可 處理方式。 4棄先碟片中回收聚碳酸醋塑膠的 【先前技術】 已知的廢棄光碟片回收處理方式僅可回收單層之 其主要處理方式可分為刨除法及溶劑法兩帛 :: 用鋼絲或砂輪對廢光碟的濺鑛金屬層高速研2二二 父,業過程將造成金屬鑛層粉末的污染問㉟ 片浸泡於i 5%以上氮化卸溶液並V以破 5。〜7代及剝離時間為15秒至15分則可剝離二 碟片上的金屬層,再以70%以上之乙_ $ 此口先 料層,而氮化鉀溶液所含之貴重之金乙/再^ =以j容解染 式回收。 萄丹以化學法/電解方 【發明内容】 過去因DVD由雙層聚碳酸酯塑膠貼人200536878 V. Description of the invention (1) ^ _ [Technical field to which the invention belongs] The present invention uses the strong oxidizing power of hypochlorous acid to oxidize the metal on the surface of the optical disc and the reflective layer. The principle of acetic acid, from waste Hua 纟 # Η φ 骖 boat can be processed. 4 [Previous technology] Recycling of discarded polycarbonate discs from previous discs [Previous technology] Known disposal methods of discarded discs can only recover single layers. The main processing methods can be divided into two methods: planing and solvent methods: using steel wire or The high-speed grinding of the splattered metal layer of the waste disc by the grinding wheel will cause contamination of the powder of the metal ore layer. The sheet is immersed in i 5% or more of the nitriding unloading solution and V is broken. ~ 7th generation and the peeling time is 15 seconds to 15 minutes, the metal layer on the second disc can be peeled off, and then more than 70% of B_ $ This material is the first layer, and the valuable gold B contained in the potassium nitride solution / Then ^ = recover by j volume de-staining. Grapevine uses chemical method / electrolysis method [Inventive content] In the past, DVD was made of double-layer polycarbonate plastic

膜及染料夾雜,一直無法有效處理",明間^有塑 棄的混合光碟〇,、緩緩加入次氣妒^明將破碎後a 層上的染料及銀、㉟等金屬,再利 ==先碟> 在高溫下可溶解於醋酸水溶液的特性蚀' β之塑用 明狀,達到回收聚碳酸酯塑膠的 σ各類光碟片i 光碟片免除分類之成本。的目的,同時處理各類肩Membrane and dye inclusions have not been able to effectively handle "Mingjian ^ there are plastic discs discarded, and slowly add secondary gas jealousy ^ Ming will break the dye on the layer a and metals such as silver, osmium, and so on. = First disc > The characteristic corrosion that can be dissolved in an acetic acid aqueous solution at high temperature, β, the shape of plastic is used to achieve recovery of polycarbonate plastic σ various optical discs i Optical discs are exempt from the cost of classification. Purpose while handling all kinds of shoulders

200536878 五、發明說明(2) 【實施方式】 各式廢棄的混合光碟片(包含CD-R、VCD、DVD等)經破碎 後倒入反應器中,再緩緩加入有效氯1 〇 %以上之次氯酸鈣 溶液,並加醋酸調整p Η為3〜4,反應一段時間後,將濾除 水分後的廢棄光碟片加入醋酸溶液及少量界面活性劑(如 洗碗精),攪拌並控制溫度在8(TC-100 °C,待廢棄的混合 光碟片表層之塑膠膜剝離或溶解後,將光碟片過濾分離後 加清水清洗並烘乾裝袋。200536878 V. Description of the invention (2) [Embodiment] Various types of discarded mixed optical discs (including CD-R, VCD, DVD, etc.) are crushed and poured into the reactor, and then slowly add more than 10% of available chlorine Calcium hypochlorite solution, and add acetic acid to adjust pΗ to 3 ~ 4. After a period of reaction, add the discarded discs after filtering out the water to the acetic acid solution and a small amount of surfactant (such as dishwashing liquid), stir and control the temperature At 8 (TC-100 ° C), after the plastic film on the surface layer of the discarded mixed optical disc is peeled or dissolved, the optical disc is filtered and separated, washed with water, and dried and bagged.

第6頁 200536878 圖式簡單說明Page 6 200536878 Schematic description

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第7頁Page 7

Claims (1)

• 200536878• 200536878 1. 一種從廢棄的混合光碟片中聚碳酸酯塑膠回收再利用方 法,本發明所才曰之光碟片包含CD-R、VCD、DVD等久彳| 碟片,申請專利範圍之製程方法,其步驟為:寺各式先 A·破碎:將光碟片置於破碎機中破碎。 B·加次氣酸鈣氧化:將已破碎之光碟片倒入裝有次氯酸 鈣溶液的反應器中,並控制反應器内PH < 6。 ' C ·濾乾:將水份及沉澱物移除。 D·泡醋酸溶液:將已破碎之光碟片倒入裝有醋酸溶液的 反應器中在高溫下加熱至膠膜剝離或溶解為止。 E.分離··過渡使光碟片與醋酸溶液分離。 F ·清洗:以清水清洗透明光碟片2 一 3次。 G ·乾燥:使用烘乾設備將水份移除。1. A method for recycling polycarbonate plastic from discarded hybrid optical discs. The optical discs disclosed in the present invention include CD-R, VCD, DVD and other long-time | discs, a process for applying for a patent, The steps are as follows: Temple various types of A · Crushing: put the disc in the crusher and crush. B. Calcium hypooxygenate oxidation: Pour the broken disc into the reactor containing the calcium hypochlorite solution, and control the pH in the reactor < 6. 'C · Filter dry: Remove water and sediment. D. Acetic acid solution: Pour the broken disc into the reactor containing the acetic acid solution and heat it at high temperature until the adhesive film peels or dissolves. E. Separation · The transition separates the disc from the acetic acid solution. F · Cleaning: Wash the transparent disc 2 to 3 times with clean water. G · Dry: Use a drying device to remove water. 第8頁 200536878 六、指定代表圖 (一) 、本案代表圖為:第________圖 (二) 、本案代表圖之元件代表符號簡單說明:Page 8 200536878 VI. Designated Representative Map (I) The representative map in this case is: Figure ________ (II) The component representative symbols of the representative map in this case are simply explained: ΙΗΒ 第3頁 200536878 圖式簡單說明 A.破碎:將光碟片置於破碎機中破碎。 B ·加次氣酸鈣氧化:將已破碎之光碟片倒入裝有次氣酸 鈣溶液的反應器中,並控制反應器内pH < 6。 C. 濾乾··將水份及沉澱物移除。 D. 泡醋酸溶液:將已破碎之光碟片倒入裝有醋酸溶液的 反應器中在高溫下加熱至膠膜剝離或溶解為止。 E. 分離:過濾使光碟片與醋酸溶液分離。 F. 清洗:以清水清洗透明光碟片2 - 3次。 G. 乾燥:使用烘乾設備將水份移除。ΙΗΒ Page 3 200536878 Brief description of the drawings A. Crushing: Crush the disc in a crusher. B. Calcium Oxygenate Oxidation: Pour the broken disc into the reactor containing the calcium acid solution, and control the pH < 6 in the reactor. C. Filter dry ... Remove water and sediment. D. Soak acetic acid solution: Pour the broken disc into the reactor containing the acetic acid solution and heat at high temperature until the film peels or dissolves. E. Separation: Filter to separate the disc from the acetic acid solution. F. Cleaning: Rinse the transparent disc 2 to 3 times with water. G. Drying: Use a drying device to remove water. 第7頁Page 7
TW93112833A 2004-05-07 2004-05-07 Method for recycling polycarbonate plastic from discarded mixed compact disc TW200536878A (en)

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Application Number Priority Date Filing Date Title
TW93112833A TW200536878A (en) 2004-05-07 2004-05-07 Method for recycling polycarbonate plastic from discarded mixed compact disc

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
TW93112833A TW200536878A (en) 2004-05-07 2004-05-07 Method for recycling polycarbonate plastic from discarded mixed compact disc

Publications (1)

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TW200536878A true TW200536878A (en) 2005-11-16

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