TW200519120A - Method for producing cyclic organic silicon compound and organic silicon resin having alcoholic hydroxyl group - Google Patents
Method for producing cyclic organic silicon compound and organic silicon resin having alcoholic hydroxyl groupInfo
- Publication number
- TW200519120A TW200519120A TW093134008A TW93134008A TW200519120A TW 200519120 A TW200519120 A TW 200519120A TW 093134008 A TW093134008 A TW 093134008A TW 93134008 A TW93134008 A TW 93134008A TW 200519120 A TW200519120 A TW 200519120A
- Authority
- TW
- Taiwan
- Prior art keywords
- organic silicon
- carbon atoms
- group
- silicon compound
- formula
- Prior art date
Links
- 150000003377 silicon compounds Chemical class 0.000 title abstract 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title abstract 4
- 239000011347 resin Substances 0.000 title abstract 4
- 229920005989 resin Polymers 0.000 title abstract 4
- 229910052710 silicon Inorganic materials 0.000 title abstract 4
- 239000010703 silicon Substances 0.000 title abstract 4
- 125000004122 cyclic group Chemical group 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 230000001476 alcoholic effect Effects 0.000 title abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 title abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 7
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 3
- 125000003545 alkoxy group Chemical group 0.000 abstract 2
- 229910052739 hydrogen Chemical group 0.000 abstract 2
- 239000001257 hydrogen Chemical group 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 230000007774 longterm Effects 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- GHFHFNDKTYBBNZ-UHFFFAOYSA-N oxasilolane Chemical class C1CO[SiH2]C1 GHFHFNDKTYBBNZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
- C07F7/1872—Preparation; Treatments not provided for in C07F7/20
- C07F7/1892—Preparation; Treatments not provided for in C07F7/20 by reactions not provided for in C07F7/1876 - C07F7/1888
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
- C07F7/1872—Preparation; Treatments not provided for in C07F7/20
- C07F7/1876—Preparation; Treatments not provided for in C07F7/20 by reactions involving the formation of Si-C linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Silicon Polymers (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The object of this invention is to provide a production method wherein synthesis of a cyclic organic silicon compound similar to oxa-silacyclopentanes is completed in a single-step reaction. Also disclosed are an organic silicon resin having an alcoholic hydroxyl group which has long-term stability and whose composition is easily controlled, and a method for producing such an organic silicon resin. A cyclic organic silicon compound of this invention represented by the formula (3) below is produced by reacting an olefin represented by the formula (1) below and an alkoxysilane represented by the formula (2) below in the presence of a transition metal catalyst. (In the above formula, Z represents an alkenyl group having 2-5 carbon atoms wherein the terminal carbon atom forms a C=C bond, R represents a methyl group or a hydrogen, and Me represents a methyl group.) (In the above formula, R1 represents an alkyl group or an alkoxyl group having 1-3 carbon atoms, R2 represents an alkyl group having 1-3 carbon atoms, and a plurality of R2 can be identical or heterologous.) (In the above formula, Z' represents an alkylene group having 2-5 carbon atoms, R represents a methyl group or a hydrogen, R1 represents an alkyl group or an alkoxyl group having 1-3 carbon atoms, and R2 represents an alkyl group having 1-3 carbon atoms.) An organic silicon resin of this invention is obtained by hydrolyzing and condensing the organic silicon compound represented by the above formula (3) or a mixture of the organic silicon compound and a multifunctional alkoxysilane.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003377752 | 2003-11-07 | ||
| JP2004039063 | 2004-02-16 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200519120A true TW200519120A (en) | 2005-06-16 |
| TWI341842B TWI341842B (en) | 2011-05-11 |
Family
ID=34575920
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW093134008A TW200519120A (en) | 2003-11-07 | 2004-11-08 | Method for producing cyclic organic silicon compound and organic silicon resin having alcoholic hydroxyl group |
Country Status (4)
| Country | Link |
|---|---|
| JP (2) | JP4470886B2 (en) |
| KR (2) | KR101064063B1 (en) |
| TW (1) | TW200519120A (en) |
| WO (1) | WO2005044828A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104470935A (en) * | 2012-07-11 | 2015-03-25 | 瓦克化学股份公司 | Oxasilacyclenes and method for the production thereof |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008239634A (en) * | 2005-07-12 | 2008-10-09 | Toagosei Co Ltd | Organic silicon resin having alcoholic hydroxy group, and method for producing the same |
| DE102012013710A1 (en) | 2012-07-11 | 2014-01-16 | Technische Universität München | Crosslinkable siloxanes by acid-catalyzed polymerization of oxasilacycles |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3173935B2 (en) * | 1993-12-01 | 2001-06-04 | 信越化学工業株式会社 | Organosilicon compound and its production method |
| JP4739613B2 (en) | 2001-09-20 | 2011-08-03 | 富士通株式会社 | Resist composition and pattern forming method using the same |
-
2004
- 2004-11-05 KR KR1020117013078A patent/KR101064063B1/en active IP Right Grant
- 2004-11-05 KR KR1020067008701A patent/KR101097570B1/en active IP Right Grant
- 2004-11-05 WO PCT/JP2004/016445 patent/WO2005044828A1/en active Application Filing
- 2004-11-05 JP JP2005515324A patent/JP4470886B2/en active Active
- 2004-11-08 TW TW093134008A patent/TW200519120A/en unknown
-
2009
- 2009-08-27 JP JP2009197359A patent/JP5062231B2/en active Active
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104470935A (en) * | 2012-07-11 | 2015-03-25 | 瓦克化学股份公司 | Oxasilacyclenes and method for the production thereof |
| CN104470935B (en) * | 2012-07-11 | 2016-09-21 | 瓦克化学股份公司 | Oxa-cyclosilane and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5062231B2 (en) | 2012-10-31 |
| KR101064063B1 (en) | 2011-09-08 |
| KR101097570B1 (en) | 2011-12-22 |
| WO2005044828A1 (en) | 2005-05-19 |
| JP2010013653A (en) | 2010-01-21 |
| KR20060111489A (en) | 2006-10-27 |
| KR20110070928A (en) | 2011-06-24 |
| TWI341842B (en) | 2011-05-11 |
| JP4470886B2 (en) | 2010-06-02 |
| JPWO2005044828A1 (en) | 2007-05-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO2001040184B1 (en) | Methods for the syntheses of alfentanil, sufentanil and remifentanil | |
| ATE480517T1 (en) | METHOD FOR THE PRODUCTION AND PURIFICATION OF 2-HYDROCARBYL-3,3-BIS(4-HYDROXYARYL-PHTHALIMIDINE MONOMERS | |
| TW200702325A (en) | Synthesis of amino-alkoxy-heptanoic acid alkyl ester | |
| IL175940A0 (en) | Prostaglandin synthesis | |
| EP1698625A4 (en) | Epoxy compounds and cured epoxy resins obtained by curing the compounds | |
| TW200604161A (en) | Chemical process | |
| ATE377593T1 (en) | 9,10-ALPHA,ALPHA-OH-TAXANE ANALOGUE AND METHOD FOR THE PRODUCTION THEREOF | |
| TW200500430A (en) | Crosslinking composition | |
| TW200519120A (en) | Method for producing cyclic organic silicon compound and organic silicon resin having alcoholic hydroxyl group | |
| UA85428C2 (en) | Process for the preparation of c-2, c-3 substituted n-alkylated indoles, intemdiates and process for the preparation thereof | |
| WO2008081726A1 (en) | Process for production of amide or lactam | |
| MXPA04003568A (en) | Aralkyl-tetrahydro-pyridines, their preparation and pharmaceutical compositions containing same. | |
| HUP0202006A2 (en) | Process for preparing 2-amino-4-(4-fluorphenyl)-6-alkylpyrimidine-5-carboxylate | |
| EP1493765A4 (en) | Organic polymers having at the ends epoxy- and/or oxetanyl-containing silicon groups and process for production thereof | |
| ATE372332T1 (en) | METHOD FOR PRODUCING INTERMEDIATE COMPOUNDS IN THE PRODUCTION OF DISCODERMOLID AND DISCODERMOLID ANALOGS | |
| WO2004031313A3 (en) | Process for the manufacture of alkoxysilanes and alkoxy orthosilicates | |
| WO2002076515A3 (en) | Method of producing 1-hydroxy-1,1-diphosphonic acid compounds | |
| TWI635119B (en) | Nitrogen-containing organoxysilane compound composition and making method | |
| EP1790628A4 (en) | Method for producing unsaturated vicinal diol compound | |
| TW200736218A (en) | Method for producing tertiary amines | |
| JP2020527584A5 (en) | ||
| MY136296A (en) | Use of an extractant in the preparation of anhydrous formic acid | |
| Achini et al. | Synthesis of pyrrolidines by intramolecular carbanionic epoxide opening | |
| ATE202080T1 (en) | METHOD FOR PRODUCING 2-CYANOBIPHENYL COMPOUNDS | |
| TW200517442A (en) | Silane compound, polysiloxane and radiation-sensitive resin composition |