TW200510468A - Polybutylene terephthalate - Google Patents

Polybutylene terephthalate

Info

Publication number
TW200510468A
TW200510468A TW093122692A TW93122692A TW200510468A TW 200510468 A TW200510468 A TW 200510468A TW 093122692 A TW093122692 A TW 093122692A TW 93122692 A TW93122692 A TW 93122692A TW 200510468 A TW200510468 A TW 200510468A
Authority
TW
Taiwan
Prior art keywords
titanium
polybutylene terephthalate
ppm
less
content
Prior art date
Application number
TW093122692A
Other languages
Chinese (zh)
Other versions
TWI338013B (en
Inventor
Masanori Yamamoto
Takahiro Uesaka
Original Assignee
Mitsubishi Chem Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chem Corp filed Critical Mitsubishi Chem Corp
Publication of TW200510468A publication Critical patent/TW200510468A/en
Application granted granted Critical
Publication of TWI338013B publication Critical patent/TWI338013B/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/82Preparation processes characterised by the catalyst used
    • C08G63/85Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Artificial Filaments (AREA)

Abstract

Polybutylene terephthalate containing a titanium catalyst in an amount of not more than 150 ppm, calculated as a titanium atom and having an end methoxycarbonyl group concentration of not more than 0.5 μeq/g, an active titanium content (α) in the titanium catalyst, defined by the following formula (I), being not less than 0.8, α =X/[M] (I) wherein [M] is a titanium atom concentration (ppm) in polybutylene terephthalate; and X is an activation parameter defined by the specific formula. The above PBT has excellent color tone, hydrolytic resistance, heat stability, transparency and moldability as well as a less content of extraneous materials, and is suitably applicable to films, monofilaments, fibers, electric and electronic parts, automobile parts, etc.
TW93122692A 2003-07-31 2004-07-28 Polybutylene terephthalate TWI338013B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2003204355 2003-07-31

Publications (2)

Publication Number Publication Date
TW200510468A true TW200510468A (en) 2005-03-16
TWI338013B TWI338013B (en) 2011-03-01

Family

ID=34113641

Family Applications (1)

Application Number Title Priority Date Filing Date
TW93122692A TWI338013B (en) 2003-07-31 2004-07-28 Polybutylene terephthalate

Country Status (4)

Country Link
CN (1) CN100424113C (en)
MY (1) MY157379A (en)
TW (1) TWI338013B (en)
WO (1) WO2005012391A1 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1938361B (en) * 2004-04-01 2010-11-10 三菱化学株式会社 Polybutylene terephthalate
JP4725029B2 (en) * 2004-04-22 2011-07-13 三菱化学株式会社 Polybutylene terephthalate
JP5079226B2 (en) * 2005-08-29 2012-11-21 三菱化学株式会社 Polybutylene terephthalate
CN102993420A (en) * 2012-12-10 2013-03-27 金发科技股份有限公司 Ternary polymerization polybutylene terephthalate (PBTG) polyether and preparation method thereof
CN103665351A (en) * 2013-11-29 2014-03-26 金发科技股份有限公司 Poly-terephthalic acid cyclohexanedimethanol /butanediol copolyester, and preparation and application thereof
CN112646133B (en) * 2019-10-12 2023-02-03 中国石油化工股份有限公司 Low-dielectric-constant PBT copolyester and preparation method and application thereof
CN112646147B (en) * 2019-10-12 2023-05-05 中国石油化工股份有限公司 Weather-resistant low-dielectric-constant PBT copolyester and preparation method thereof
CN112646326B (en) * 2019-10-12 2022-08-09 中国石油化工股份有限公司 Preparation method of lightweight low-dielectric-constant PBT copolyester master batch and polyester film
CN112724376A (en) * 2019-10-14 2021-04-30 中国石油化工股份有限公司 Preparation method of light-weight low-dielectric-constant PBT polyester
CN114685768B (en) * 2020-12-31 2024-03-08 中国石油化工股份有限公司 High-viscoelasticity polyester and preparation method thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002284868A (en) * 2001-03-27 2002-10-03 Toray Ind Inc Process for preparation of poly(butylene terephthalate)
JP2004091756A (en) * 2002-09-04 2004-03-25 Mitsubishi Chemicals Corp Polybutylene terephthalate resin

Also Published As

Publication number Publication date
MY157379A (en) 2016-06-15
CN1826367A (en) 2006-08-30
CN100424113C (en) 2008-10-08
TWI338013B (en) 2011-03-01
WO2005012391A1 (en) 2005-02-10

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Legal Events

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