TW200504111A - Method for making a heat resistant epoxy resin having an excellent transparency - Google Patents

Method for making a heat resistant epoxy resin having an excellent transparency

Info

Publication number
TW200504111A
TW200504111A TW093117455A TW93117455A TW200504111A TW 200504111 A TW200504111 A TW 200504111A TW 093117455 A TW093117455 A TW 093117455A TW 93117455 A TW93117455 A TW 93117455A TW 200504111 A TW200504111 A TW 200504111A
Authority
TW
Taiwan
Prior art keywords
epoxy resin
fluorene
making
heat resistant
excellent transparency
Prior art date
Application number
TW093117455A
Other languages
Chinese (zh)
Other versions
TWI341846B (en
Inventor
Koichi Fujishiro
Motozumi Mitani
Yukuo Akimaru
Kazunori Matsugaki
Hirotoshi Manago
Original Assignee
Nippon Steel Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Chemical Co filed Critical Nippon Steel Chemical Co
Publication of TW200504111A publication Critical patent/TW200504111A/en
Application granted granted Critical
Publication of TWI341846B publication Critical patent/TWI341846B/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22Di-epoxy compounds
    • C08G59/24Di-epoxy compounds carbocyclic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02Polycondensates containing more than one epoxy group per molecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/20Filters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Epoxy Resins (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)
  • Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)

Abstract

This invention provides a method for making a heat resistant epoxy resin having an excellent transparency and is adapted for use in the field of display material or optical elements and optical modulation elements which require a transparency and heat resistance. The epoxy resin is made by reacting bis(hydroxy phenyl) fluorene(BHPF) represented by the following formula (1), and epichlorohydrine, wherein, as a bis(hydroxy phenyl) fluorene, a solution of (A) having 4g of bis(hydroxyphenyl) fluorene resolved in 100ml of methyl ethyl setone and having an yellow index (YI value) of less than 6, and (B) containing less than 100ppm of fluorene is used in order to obtain an epoxy resin having a Hue of less than APHA 120.
TW093117455A 2003-06-27 2004-06-17 Method for making a heat resistant epoxy resin having an excellent transpancy TWI341846B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2003184821A JP5009486B2 (en) 2003-06-27 2003-06-27 Manufacturing method of heat-resistant epoxy resin with excellent transparency

Publications (2)

Publication Number Publication Date
TW200504111A true TW200504111A (en) 2005-02-01
TWI341846B TWI341846B (en) 2011-05-11

Family

ID=34184470

Family Applications (1)

Application Number Title Priority Date Filing Date
TW093117455A TWI341846B (en) 2003-06-27 2004-06-17 Method for making a heat resistant epoxy resin having an excellent transpancy

Country Status (3)

Country Link
JP (1) JP5009486B2 (en)
KR (1) KR100996601B1 (en)
TW (1) TWI341846B (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4915895B2 (en) * 2005-07-07 2012-04-11 日本化薬株式会社 Production method of epoxy resin
JP4915896B2 (en) * 2005-07-07 2012-04-11 日本化薬株式会社 Production method of epoxy resin
JP5062856B2 (en) * 2009-04-17 2012-10-31 田岡化学工業株式会社 Method for producing 9,9-biscresol fluorene
KR101178725B1 (en) 2010-04-05 2012-08-31 제일모직주식회사 Transparent and highly heat resistant epoxy curing resin and preparation method thereof
JP6508921B2 (en) * 2014-02-27 2019-05-08 日鉄ケミカル&マテリアル株式会社 Method for producing fluorene skeleton-containing epoxy resin, epoxy resin composition, and cured product
JP6739136B2 (en) * 2015-07-08 2020-08-12 田岡化学工業株式会社 Crystal of alcohol having fluorene skeleton and method for producing the same
KR101861917B1 (en) * 2016-04-14 2018-05-28 삼성에스디아이 주식회사 Epoxy compound, epoxy resin composition for encapsulating semiconductor device comprising the same, and semiconductor device encapsulated by using thereof
WO2020213992A1 (en) * 2019-04-19 2020-10-22 국도화학 주식회사 Epoxy resin, preparation method thereof, and epoxy resin composition comprising same
KR102245604B1 (en) * 2019-10-10 2021-04-28 주식회사 케이씨씨 Epoxy resin composition

Also Published As

Publication number Publication date
KR20050001477A (en) 2005-01-06
TWI341846B (en) 2011-05-11
JP2005015696A (en) 2005-01-20
KR100996601B1 (en) 2010-11-25
JP5009486B2 (en) 2012-08-22

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