TW200412359A - Stabilized polyamide compositions - Google Patents

Abstract

Polyamide compositions, in particular polyamide fibers, films and molded articles, are effectively stabilized by the incorporation therein of a combination of at least one s-triazine UV absorber and a copper salt in the absence of carbon black.

Description

200412359 Description of the invention: Technical field to which the invention belongs The present invention relates to stable polyamidoamine compositions, in particular polyvinylamine fibers, films, molded articles and the like. In particular, the present invention relates to a stable polyamine composition comprising a carbon black-free homo-triazine (S-tnazine) ultraviolet light absorber and a copper salt. Prior art Polyamide (or nylon) is a type of widely used thermoplastic engineering resin, which is characterized by excellent lubricity, abrasion resistance, and chemical resistance. However, the industry is still looking for suitable stabilization systems to protect nylon from the harmful effects of heat, light and oxygen. Polyamines have been stabilized against the deleterious effects of heat and light by the addition of small amounts of copper salts (for example, in combination with alkali metal halides), for example, as described in U.S. Patent Nos. 2,630,421 and 2,705,227. When used as an additive in nylon, copper salts have some problems, for example, as described in U.S. Patent Nos. 2,960,498, 3,359,235, 4,74; 06 and UK Patent No. 1,148,244. Workers have attempted to use copper salts in other forms (e.g., complexes), for example, as described in U.S. Patent Nos. 3,499,867, 4,851, Couch No., and European Patent No. 61,015. WO 96/28503 discloses a stable polyamide composition comprising a thermally stable additive and incorporating at least one inorganic carbon black. Surprisingly, it was found that the carbon black-free homo-triazine ultraviolet light absorber ⑽A) and the polyamine compound of copper salt provide excellent stabilization against the harmful effects of heat 200412359, light, and oxygen . SUMMARY OF THE INVENTION The detailed disclosure discloses a polyamine composition stabilized against the harmful effects of heat, light, and oxygen, which includes an effective stable amount of at least one species selected from the group consisting of homo-triazine ultraviolet light absorbers Compounds in the group, and copper salts, where substantially no carbon black is present. The carbon black excluded from the composition of the present invention is, for example, carbon black. The term "substantially free of carbon black" means that the content of carbon black can exist without substantially affecting the basic characteristics of the polyamide composition. For example, the composition of the present invention does not include carbon black. Uv absorption 丨 The homo-triazine of the present invention is usually based on 4, 6-bis- (2, 4-diaryl) -2- (2,4-dihydroxyphenyl) -homo-triazine Commercially available homo-triazine νν absorbents, for example, Tinuvin (R) 400 or Tinuvin® 1577 (Cibaite Chemicals) or CyasorbMlGd (Cytec), or they are red-transferred homo-triazines 'for example' such as US Patent The disclosures of Nos. 5,556, 973, and 5,354,794, or homo-triazines with high Molar extinction coefficients, are disclosed in US Patent No. 6,255,483, which is incorporated herein by reference.

Homo-triazine UV absorber of component (b), having formula (I v), (V 200412359), (VI), (VII), (VIII) or (IX):

7 200412359

(VIII)

(IX) 8 200412359 wherein X and Y are independently phenyl, naphthyl, or alkyl via one to three 1 to 6 carbon atoms, halogen, via hydroxyl, or oxyalkyl via 1 to 6 carbon atoms Or the phenyl group or the Zeidyl group substituted by a mixture thereof; or X and Υ are independently Z! Or ζ2; R1 疋 hydrogen, a straight or branched bond of 4 to 4 carbon atoms, 5 to 12 A cycloalkyl group of 7 carbon atoms, a phenylalkyl group of 7 to 15 carbon atoms, halogen, -SR3, -S0R3, or -S02R3; or via one to three halogens, -r4, -5, -N (R5) 2 , -C0R5, -C00R5, -0C0R5, -CN, -N02, -SR5, -S0R5 or -S02R5 or -P (〇) (〇R5) 2, molybdenyl, pyridinyl, 2,2,6, 6-tetramethylpiperidinyl, piperazinyl, or N-methyltonidinyl or a combination thereof substituted by the alkyl group, the% alkyl group or the benzoyl group; or via one to four phenyl groups,- 〇-,-nr5-, -conr5-, -coo-, -0C0-, or -C0 group or the combination of the alkyl group or the cycloalkyl group; or the substitution and interruption through the combination of the above groups The alkyl group or the cycloalkyl group; R3 is an alkyl group of 1 to 20 carbon atoms, 3 to 18 carbon atoms Alkenyl, cycloalkyl of 5 to 12 carbon atoms, phenylalkyl of 7 to 15 carbon atoms, aryl of 6 to 10 carbon atoms, or calcination via one or two i to 4 carbon atoms R4 is an aryl group of 6 to 10 carbon atoms, or an alkyl group of 1 to 3 carbon atoms, an alkyl group of 1 to 8 carbon atoms, an alkoxy group of 8 to 8 carbon atoms, or The aryl group substituted by a combination thereof; a cycloalkyl group of 5 to 12 carbon atoms; a phenylalkyl group of 7 to 15 carbon atoms, or a benzene ring via one to three Alkynyl, i M 8 carbon atom alkoxy group or a combination thereof to replace the _ group of 200412359; or a straight or branched chain dilute group of 2 to 18 carbon atoms; the meaning of 5 4, or the heart is also hydrogen, Or a straight or branched alkyl group of 1 to 24 carbon atoms, a dilute group of 2 to 24 carbon atoms; or R is a group of the formula:

— ^ (NT V, T is a hydrogen′oxy group, a hydroxyl group, −0 Tι, an alkyl group of 24 to 24 carbon atoms, the alkyl group substituted through − to 3 hydroxyl groups; benzyl of 2 to 18 carbon atoms Or alkyl; 1 Tl is an alkyl group of 1 to 24 carbon atoms, a cycloalkyl group of 5 to 12 carbon atoms, an alkenyl group of 2 to 24 carbon atoms, a cycloalkenyl group of 5 to 12 carbon atoms , Phenylalkyl groups of 7 to 15 carbon atoms, groups of saturated or unsaturated bicyclic or tricyclic hydrocarbons of 7 to 12 carbon atoms, or aryl groups of 6 to 10 carbon atoms, or via one to This aryl group is substituted by two alkyl groups of 1 to 4 carbon atoms; R2 疋 氲, a straight or branched alkyl group of 1 to 24 slave atoms, or a cycloalkyl group of $ to 12 slave atoms; or via One to four oxins, epoxy, glycidyloxy, furanoxy, -R4, -0R5, -N (r5) 2, -cON (R5) 2, -coR5, -coor5,- ocor5, -ococ (r5) = c (r5) 2, -c (R5) = CCOOR5, -CN, -NC0 or

10 2 200412359 or a combination thereof substituted by the alkyl group or the cycloalkyl group; or via one to four epoxy groups, -0-, _sex 5-, -00, 5-,-. 00-, -0. 0-,-() 0-, -c (r5) = c (r5) coo-, -OCOC (R5) = C (R5)-, -C (R5) = C (R5) -, Phenylene or phenylene-G-phenylene (where G is -0-, -S -'- S02-, -CH2- or -c (ch3) 2-) or a combination thereof Alkyl or the cycloalkyl; or the alkyl or the cycloalkyl substituted and interrupted by a combination of the above groups; or -so2r3 or -cor6; h is a straight or branched chain of 1 to 18 carbon atoms Alkyl group, straight or branched alkenyl group of 2 to 12 carbon atoms, phenoxy group, alkylamino group of 1 to 12 carbon atoms, arylamine group of 6 to 12 carbon atoms, -R7cOH or —NH—Rs—NC〇; 7 is an alkylene group or phenylene group of 2 to 14 carbon atoms; I is an alkylene group, phenylene group, methylphenylene group of 2 to 24 carbon atoms , Diphenylmethane or group:

Mind and mind are the same or different, and are defined as | ^; R2 and I are the same or different, and are defined as dagger; X λ fork,, y, and Υ are the same or different and are as The meaning of γ is 0. L is an extended alkylene group of 1 carbon atom to 9; a straight or branched chain alkylene group of 12 carbon atoms, 5 to ^ cycloalkyl group, or via extended ring Hexyl or phenyl and substituted or middle, or L is phenylene f; or L is —s—, —s—s—, n 200412359

E is a carbonized group of 2 to 12 carbon atoms, a carbonized group of 5 to 12 carbon atoms, or a carbonized group that is interrupted or terminated by a carbonized group of 5 to 12 carbon atoms; η is 2 , 3, or 4; when η is 2, Q is a straight or branched alkylene group of 2 to 16 carbon atoms; or the alkylene group substituted via one to three hydroxyl groups; or via one to two -CH = CH- or -〇- interrupted by the alkylene group; or substituted and interrupted by a combination of the above groups; or Q is xylylene or the group-CONH-R8-NHC0-, -CH2CH (0H) CH20-R9-0CH2CH (0H) CH2-, -C0- R1〇-CO- or-(CH2) m-COO-Ru-〇〇C- (CH2) m-, where m is 1 to 3; or Q is

Rg is an alkylene group of 2 to 50 carbon atoms, or via one to ten carbon atoms, or an alkylene group-an alkylene group-G-phenylene group (where G is -0-, -S-, -12 200412359 S〇2-, -CHr or -C (CH3) 2-) interrupted by the alkylene group; R10 is an alkylene group of 2 to 10 carbon atoms, or via one to four 010,- S- or -CH = CH- and the alkylene group interrupted; or ri0 is an alkylene group of 6 to 12 carbon atoms; R " is an alkylene group of 2 to 20 carbon atoms, or via one to eight The alkylene group was interrupted by 101; when η is 3, Q is the group one [(CH2) mc〇〇] 3-R12, where m is 1 to 3, and R! 2 is 3 to 12 Carbon atom alkanetriy1; when 11 is 4, 卩 is a group _ [((: 112) 1 „(: 00] 4-13, where 111 is 1 to 3, and R14 is 4 to 12-carbon alkane tetrayl (alkanetetray1);

Zi is a group of the following formula ...

Z2 is a group of the following formula ...

13 200412359 Among them, and R20, R21, R22, and R23 are each ri and I: 2 are each independently o or] R ", R15, R16, R17, R18,% are independently hydrogen, hydroxyl, cyano, and Alkyl group of 20 carbon atoms, oxyalkyl group of 1 to 20 carbon atoms, phenylalkyl group of 7 to J 15 slave atoms, cycloalkyl group of 5 to 12 stone counter atoms, 5 to 12 stone mountains Stores JU slaves cycloalkoxy groups, halogens, haloalkyl groups with 1 to 5 carbon atoms, furnace stone cumyl, carboxyl groups, donkey amino groups with 2 to 2 carbon atoms, 2 to 12 carbons ; A good human atom, a tick group, a 2 to 12 carbon atom alkoxycarbonyl group, or an amine carbonyl group; or 〆17 and R18 or R22 and R23 and the phenyl group linked to them, via a main one- 0- or -NR5-and a middle-aged cyclic group. For example, the present invention relates to compounds of formula (IV) in which X and γ are the same or different and are phenyl, or via one to three ^ 6-carbon alkyl group, functional element, hydroxyl group or alkoxy group substituted by 12 to 12 carbon atoms; or X and γ are 4 or Z2; I is hydrogen, 1 to 24 carbon atoms Straight or branched Radicals, cyclohexyl radicals of 5 to 12 carbon atoms, benzyl radicals or halides of 7 to 15 carbon atoms; R2 is hydrogen, 1 to J straight or branched chain radicals of 24 carbon atoms or 5 to A cyclohexyl group of 12 carbon atoms; or the alkyl group or the cycloalkyl group substituted through one to three meanings, I, __5, —OCOR5 or a combination thereof, or via one to two epoxy groups, -0-, -coo-, -〇nco_ and the broken alkyl group; only 4 to 6 to 10 stone anti-aryl aryl groups, or via one to three peptin, 1 to 8 carbon atoms, An alkoxy group of 1 to 8 carbon atoms or a combination thereof 200412359; a cycloalkyl group of 5 to 12 carbon atoms; a phenylalkyl group of 7 to 15 broken atoms, or The phenylalkyl group substituted with three halogens, an alkyl group of 1 to 8 carbon atoms, an alkoxy group of 1 to 8 carbon atoms, or a combination thereof; R5 is as defined for R4; or R5 is also hydrogen, or 1 to Straight or branched bond of 24 carbon atoms,

Zi is a group of the formula:

Z2 is a group of the formula:

20, feet 21, feet 22, and feet 23 are each independently hydrogen, hydroxyl, cyano, alkyl of 1 to 20 carbon atoms, lactyl of i to 20 slave atoms, 7 to 15 carbon atoms Benzyl, cycloalkyl of 5 to 12 carbon atoms, cycloalkoxy of 5 to 12 carbon atoms, halogen, alkyl of 1 to 5 carbon atoms, thio, fluorenyl, 2 to 2 Carbon atom 15 200412359 fluorenylamino group, fluorenyloxy group of 2 to 12 carbon atoms, or 2 to 12 allyl, alkoxycarbonyl or aminocarbonyl groups. For example, a homo-triazine UV absorber also has the formula (V), where: X is phenyl, naphthyl, or an alkyl group via one to three 1 to 6 carbon atoms, via a prime, via a hydroxyl group, or via 1 Phenyl or the naphthyl substituted by alkoxy to 6 carbon atoms or via a mixture thereof; or X is A. For example, the 'homo-trisaminophen-V absorbent also has formula (VI) or (v π) or (VIII). For example, a homo-triazine UV absorber also has the formula (π), wherein: X and Y are each independently a phenyl group, or an alkyl group, halogen, hydroxyl, or 1 to 6 via one to three 1 to 6 carbon atoms. A phenyl group substituted by a carbon alkoxy group or a mixture thereof; or X and Y are each independently d or Z2; and L is a linear or branched alkylene group of 1 to 12 carbon atoms, 5 to 12 A cycloalkylene of a carbon atom, or a cycloalkylene substituted or interrupted via a cyclohexyl or a phenylene. For example, the homo-triazine UV absorber of the present invention has formula (IV), where x and Y are the same or different, and are phenyl, or substituted via one to three alkyl groups of 1 to 6 carbon atoms. The phenyl group; Zι or Z2;

Ri is hydrogen or a phenylalkyl group of 7 to 15 carbon atoms; h is hydrogen, a straight or branched chain alkyl group of 1 to 18 carbon atoms; or substituted by one to two -h, -OR5 or a mixture thereof The alkyl group; or the alkyl group interrupted via one to eight -0- or -C00; h is an aryl group of 6 to 10 carbon atoms; h is hydrogen; 16 17.200412359

Zi is a group of the formula:

R 16

R 14

R

R 18

R 15 Γι ζ2 is a group of the formula:

23 ^ 20-1 'Γ2 where Π and r2 are each 1; and

Rl4, Rl5, Rl6, Rl7, Rl8, Rl9, ruler 20, horse 1, horse 2 and horse 3 are each hydrogen. For example, the homo-triazine UV absorber of the present invention is a compound which is

17 200412359

18 200412359

Methylene bridge dimer mixture at 3: 5 ’, 5: 5’ and 3: 3 ’bridges at a ratio of 5 ·· 4: 1

19 200412359

(10)

20 200412359

(12)

The names of the compounds of the present invention shown in the structures provided above are listed as follows: (1) 2, 4-bis (4-biphenyl) -6- (2-Ethyl-4 -octyloxyalkylene) Ethyloxyphenyl) -me-triazine; (2) 2-phenyl-4- [2-hydroxy-4- (3-second-butoxy-2-hydroxypropoxy) phenyl] -6- [2-hydroxy-4- (3-second-pentyloxy-2-hydroxypropoxy) phenyl] -h-triazine; (3) 2,4-bis (2,4-a Fluorenylphenyl) -6- [2-meridyl-4- (3-fluorenyl-2-ylpropenyl) phenyl] -h-difluorene; 21 200412359 (4) 2, 4-bis (2-hydroxy-4-n-butoxyphenyl) -6- (2,4-di-n-butoxyphenyl) -me-triazine; (5) 2, 4-bis (2, 4-Difluorenylphenyl) -6- [2-hydroxy-4- (3-nonyloxy * -2-merylpropoxy) — 5-α-cumyl] -h-triazine; ( * Represents a mixture of octyloxy, nonyloxy and decoxy); (6) methylene-bis- (2, 4-bis (2, 4-diamidinophenyl) -6- [2-hydroxy -4- (3-butoxy-2-hydroxypropoxy) phenyl] -h-triazine}, at a ratio of 5: 4: 1 at 3: 5, 5, 5: 5, and 3: 3, Amidine bridge dimer mixture of position bridges; (7) 2, 4, 6-tri (2- Hydroxy-4-isooctyloxycarbonyl and isopropyloxyphenyl) -me-triamidine; (8) 2,4-bis (2,4-difluorenylphenyl) -6- (2-hydroxy -4-hexyloxy-5-α_cumyl) -h-triazine; (9) 2, 4-bis (2, 4-dimethylphenyl) -6- (2-hydroxy-4- Octyloxyphenyl) -me-triazine, CYASORB ⑧ 1164, Cytec; (10) 2- (2, 4, 6-trimethylphenyl) -4, 6-bis [2-hydroxy-4- ( 3-butoxy-2-hydroxypropoxy) phenyl] -me-triazine; (11) 2, 4, 6-tri [2-hydroxy-4- (3-second-butoxy-2 -Hydroxypropoxy) phenyl] -h-triazine; (12) 4, 6-diphenyl-2- (4-hexyloxy-2-hydroxyphenyl) -h-triazine; or (13 ) 2- (2-hydroxy-4- (2-ethylhexyl) oxy) phenyl-4,6-bis (4-phenyl) phenyl ~ 1,3,5-triazine. For example, the component ( b) The homo-triazine UV absorber is: 22 200412359 (1) 2,4-bis (4-bibenzyl) -6_ (2-hydroxy-4_octyloxycarbonyl and ethyloxyphenyl) -Me-triazine; (5) 2,4-bis (2,4-dimethylphenyl) -6- [2-hydroxy-4- (3-nonyloxy * -2-hydroxypropoxy) -5- α-phenylene] -me-tri-n-qin; (* stands for octyloxy, nonyloxy and Mixture of decyloxy); (7) 2, 4, 6-tris (2-hydroxy-4 -isooctyloxycarbonyl isopropyloxyphenyl) -h-triazine; or (12) 4, 6-Diphenyl-2- (4-hexyloxy-2-hydroxyphenyl) -h-triazine. H-triazine UV absorber is, for example, 4, 6-diphenyl-2- (4-hexane Oxy-2-hydroxyphenyl) -me-triazine, sold under the name Tinuvin® 1 577, was purchased from Cibathe Chemicals, CAS # 147315-50-2. Linear or branched alkyl groups are, for example, methyl, ethyl, propyl, isopropyl, n-butyl, first-butyl, isobutyl, third-butyl, 2-ethylbutyl, N-pentyl, isopentyl, 1-fluorenylpentyl, 1,3-dimethylbutyl, n-hexyl, 1-methylhexyl, n-heptyl, isoheptyl, 1,1,3 , 3-tetramethylbutyl, p-methylheptyl, 3-methylheptyl, n-octyl, 2-ethylhexyl, 1,1,3-trimethylhexyl, 1,1,3, 3- Tetramethylpentyl, nonyl, decyl, undecyl, 1-methylundecyl, dodecyl, 1,1,3, 3, 5, 5-hexamethylhexyl, thirteen Alkyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, eicosyl, or fluorenyldialkyl. A cycloalkyl group or a cycloalkyl group substituted by one to three alkyl groups is, for example, cyclopentyl, fluorenylcyclopentyl, difluorenylcyclopentyl, cyclohexyl, methylcyclohexyl, difluorenylcyclohexyl, Trimethylcyclohexyl, tert-butylcyclohexyl, 23 200412359 cycloheptyl or cyclooctyl. Phenyl substituted via one to three alkyl groups is, for example, o-, m- or p-methylphenyl, 2,3-diamidylphenyl, 2,4-dimethylphenyl, 2,5-di Methylphenyl, 2,6-dimethylphenyl, 3,4-dimethylphenyl, 3,5-dimethylphenyl, 2-methyl-6-ethylphenyl, 4-thyl Tri-butylphenyl, 2-ethylphenyl or 2, 6-diethylphenyl. The present alkyl group is, for example, carboyl, α-methylfluorenyl, α, α-dimethylbenzyl, or 2-phenylethyl. Benzyl groups substituted by one to three alkyl groups on the benzene ring are, for example, 2-methylbenzyl, 3-methylbenzyl, 4-methylbenzyl, 2,4-diamidino, 2 , 6-monomethylfluorenyl or 4-tert-butyl benzyl. Linear or branched alkoxy groups are, for example, methoxy, ethoxy, propoxy, isopropoxy, n-butoxy, isobutoxy, pentyloxy, isopentyloxy, hexyloxy , Heptyloxy, octyloxy, decyloxy, tetradecyloxy, hexadecyloxy or octadecyloxy. Cycloalkyloxy is, for example, cyclopentyloxy, methylcyclopentyloxy, dimethylcyclopentyloxy, cyclohexyloxy, methylcyclohexyloxy, difluorenylcyclohexyloxy, trimethylcyclo Hexyloxy, tert-butylcyclohexyloxy, cycloheptyloxy or cyclooctyloxy. Homo-triazines of the present invention are known and can be used as WO 96/28431 and U.S. Patent Nos. 3,843,371,4,61,956,4,740,542, 5,096,489, 5,106,891, 5, 298, 067, 5,300,414, 5,354,794, 5,461,151, 5, 476, 937, 5,489, 503 > 5, 543, 518, 5, 556, 973, 5, 597, 854, 5, 681, 955, 24 200412359 5, 726, 309, 5, 736, 597, 5, 942, 626, 5, 959, 008, 5,998, 116, 6,013,704-6, 060, 543, 6,187,919, 6, 242, 598, and 6, 255 , Prepared by the disclosure of No. 483. Relevant U.S. patent disclosures are incorporated herein by reference. Copper salts: Copper salts effective in the present invention include cuprous and steel salts of inorganic and organic acids, and mixtures of one or more thereof. Effective salts can be in anhydrous form. Copper salts in a hydrated form are also advantageous. The copper salt may be a copper salt of an alkanoic acid (eg, acetic acid, butyric acid, lauric acid, palmitic acid, stearic acid, and the like). Other copper anions include citrate, lactate, oleate, oxalate, tartrate, benzoate, salicylate and the like. Suitable inorganic anions include, for example, gas, bromide, iodide, nitrate, and the like. Specific copper salts of the present invention include copper (I) chloride, copper (I) bromide, copper (I) iodide, copper acetate (π), copper chloride (11), copper bromide (JJ), and copper nitrate. (11), copper sulfate (11) and mixtures thereof. Polyamidoamine: Polyamidoamine is, for example, a monoamine group having at least two carbon atoms between an amine group and a carboxylic acid, or a monocarboxylic acid or its amine, and a diamine (in an amine group in substantially equal mole ratio). And dicarboxylic acid containing at least two carbon atoms), or a monoamine carboxylic acid or its lactam or lactam as defined above, together with the diamine and the dicarboxylic acid in substantially equal mole ratios Polyamine prepared by polymerization. The term "25 200412359 essentially iso-mole" ratio includes a strict iso-mole ratio and a slightly deviated iso-mole ratio, which involves techniques traditionally used to stabilize the viscosity of the resulting polyamide. Dicarboxylic acids can be used in the form of their functional derivatives, for example, esters or fluorenyl chloride. Examples of the above monoamine-monocarboxylic acid-monocarboxylic acid or its lactam that are effective for the preparation of polyamidamine include compounds containing 2 to 16 carbon atoms between the amine and the carboxylic acid, and examples of linapamide These carbon atoms form a ring containing -co-NH. As for specific examples of aminocarboxylic acids and lactams, mention may be made of ε-aminocaproic acid, butyrolactam, pivalidamine, ε-caprolactam, caprylamine, Heptamine, undecyllactam, dodecyllactam, and 3-mono- and 4-aminobenzoic acid. Diamines suitable for the preparation of polyamines include straight and branched chain alkyl, aryl and alkylaryl diamines. Exemplary diamines are trimethylenediamine, tetramethylenediamine, pentamethylenediamine, octamethylenediamine, hexamethylenediamine, trimethylmethylenehexamethylenediamine, M-phenylene diamine and m-xylylene diamine. The dicarboxylic acid may be represented by, for example, the following formula:

HOOOB-C00H where B is a divalent aliphatic or aromatic group containing at least 2 carbon atoms. Examples of fatty acids are sebacic acid, octadecanedioic acid, suberic acid, glutaric acid, pimelic acid, and adipic acid. Both crystalline and amorphous polyamines can be used, with crystalline species generally having superior solvent resistance. Typical examples of polyamidoamine or commonly known as 26 200412359 nylon include, for example, polyamido-6 (polycaprolactam), 6,6 (polyhexamethylenehexamethylenediamine), 11, 12 , 4,6,6,10 and 6,12 'and polyamidoamines obtained from p- and / or isophosphonic acid and trimethylhexamethylenediamine; adipic acid and m-benzenediamine Polyfluorene of fluorenyldiamine; polyacrylic acid obtained from monoacid, azelaic acid, and 2,2-bis (p-aminophenyl) propane or 2,2-bis (p-aminohexyl) propane Amines; and polyamines obtained from para-deficient acids and 4, 4, diaminodicyclohexylmethane. Mixtures and / or copolymers of two or more of the foregoing polyamides or their prepolymers are also within the scope of the present invention, respectively. The polyamides of the present invention are, for example, polyamide-6, 4, 6, 6, 6, 6 '9, 6' 10, 6, 12, 11, and 12, for example, polyamide-β and polyamide- The copper compound of 6,6 is present, for example, from about 1 PP "parts per million-), based on polyamidamine to 500 ppm. For example, the copper compound exists in the following range from about 10- To about 300, from about Gang Qing to, 300 ppm from about 150 ppm to about 300, from about 卯 ⑴ to about 500, from about 200 to about 500, From about 300 ppm to about 500 ppm, from about 10 ppm to about 500 ppm, from about 10 ppm to about 150 ppm, or from about 10 ppm to about 100 ppm. Homo-triazine ultraviolet light absorbers are From about 0.1% to about 2% by weight is present based on the weight of polyamide. Homo-triazine absorbent is, for example, about 0.5% by weight, based on the weight of polyamide. For example Homo-triazine UV absorbent is present from about M% by weight to about 15% by weight, from about ^ weight to about 1% by weight, or from about U% by weight to about 0.5% by weight. Weight as a basis. For example, a homo-triazine UV absorber is 27 200412359 wt% to about 2 wt% Existing from about Wangli to about 2 wt% or from about u wt% to about 2 wt%, based on the weight of the polyamine. The stable polyamine composition may further include at least A metal test compound. An alkali metal halide is, for example, a Group 13 alkali metal (for example, lithium, sodium, sodium, etc.) and a group VIIa dentin (for example, fluorine, chlorine, iron, and moth). For example, the present The metal oxides of the invention are bump discharge, fill discharge, chlorination discharge, sodium agglomerate, sodium desertification, sodium vaporization, or mixtures thereof. For example, the alkali metal south compounds of the present invention are potassium desertification, potassium iodide, Or a mixture of desertification potassium and potassium iodide. Alkali metal halides may be present in the stable composition of the present invention from about 100,000 to about 10,000 ppm, based on polyamines, For example, from about 500 ppm to about 2000 ppm, based on polyamide. For example, the alkali metal halide can be from about 100 ppm to about 5000 ppm, from about 100 ppm to about 2000 ppm, from about 100 ppm to about 1,000 ppm, or from about ppm to It is present at about 500 ppm, based on polyamide. For example, the alkali metal halide may be from about 500,000 ppm to about 10,000 ppm, from about 10,000 ppm to about 1,000 ppm, from about 2000 ppm to about 10,000 ppm, or from about 10,000 ppm to about 10,000 ppm. 5000 PPm to about 10,000 ppm, based on polyamines. The composition of the present invention may further include an alkali metal salt and a soil test metal salt of a higher fatty acid, for example, rhenium stearate, zinc stearate, selenic acid town, magnesium stearate, sodium cis-ricinate, and Potassium palmitate, antimony pyrocatechuate, or zinc zinc pyrocatechol. For example, the composition of the present invention may further include zinc stearate. The fat liL is present in the polyamine composition of the present invention at a content of, for example, the same as that of a copper compound. The obtained composition of the present invention Π ΠΊ ^ I 疋 may optionally include from about

υ · 01 to about 10% by weight V ?, 0 ', for example, from about 0.025 to about 5% by weight, for example, from about 0.1 to 1 ,, and' J 0% by weight of various conventional stabilizer co-additives For example, the following substances or mixtures thereof are listed below: 1 · Anti-gasification:-For example, 2,6-di-third-butyl-4-methylphenolbutyl-4, 6-dimethylpan, 2,6-di-tertiary-butyl-4-ethylphenol, 2, 6-di-tertiary-butyl-qi, earth-butyl-n-butylphenol, 2,6 -Di-Third-Butyl-4 Isobutyl Age, 2, 6-Di-ντν, Glycine, # Isoamyl-4-methylphenol, 2- (α-methylcyclohexyl) -4,6 -Difluorenyl scale, 9 β, di-octadecyl-4-fluorenyl, 2 tricyclohexylphenol, 2,6-, thallium "'6- octadecane second-butyl M- Methoxymethyl, and the side chain is linear or branched nonylphenol, such as 疋 9, ，, υ sign 4 monomethylphenol, di-f--6-6 (p-methyl ten 1-pyl) age, 24_ two A: 1-methyl heptadenium + yl), 2 dimethyl_6_ (bujia * x: burning-1 ~ yl) s and its mixture. 1,2 [Sulfur & y grade 'for example , 2,4-di-octylthiomethyl-6_ --- Butylphenol, 2,4-di-octylthiomethyl-6-fluorenylphenol, 2-ylmethyl-6-ethylphenol, 2, 6-di-dodecylthiomethyl + nonyl Phenol, L 3 quinone and calcined gas ft, for example, 2, 6-di-tertiary-butamin-4 methoxyphenol, 2, 5-di-tertiary-butylhydroquinone, 2, 5-12-Third-pentylxanthene, 2, 6-di-phenyl-4-octadecyloxyphenol, 2,6-di-Third-butyme = hydrazone, 2, 5-di- Tertiary-butyl-4-hydroxyanisole, 3,5 one-two-third-two = ~ 4-Anylidene anisole, stearic acid 3, 5 ~ di-third-butyl-private Phenyl :: 29 200412359 Adipic acid bis- (3, 5-di-tertiary-butyl-4-hydroxybenzyl) ester. 1.4 L tocopherols ··, eg, α-tocopherol, cold-tocopherol , ^-Tocopherol, 3-tocopherol, and mixtures thereof (vitamins. 1β 5 fish monohalogenated sulfur diphenyl, for example, 2,2, -thiobis (6-third-butyl 4-methylphenol), 2, 2'-thiobis (4-octylphenol), 4, 4, -thiobis (6-third-butyl-3-methylphenol), 4, 4, monothiobis (6 _Third-butyl-2 methylphenol), 4,4, -thiobis (3,6 one-second-pentylphenol), 4,4, one bis (2 , 6-monomethyl-4- via sulfonium) disulfide. 1-6 Benzene > radical bis___, for example, 2, 2'-methylenebis (6-third-butyl- 4-fluorenyl phenol), 2, 2, -methylene bis (6-third -butyl-4-ethyl phenol), 2, 2 '-methylene bis [4-methyl-6-( α-fluorenylcyclohexyl) phenol], 2, 2, -methylenebis (4-methyl-6-cyclohexylphenol), 2,2,1-methylenebis (6-nononyl-4, 4-methyl) Based phenol), 2,2'-methylenebis (4,6-di-tertiary-butylphenol), 2,2, monoethylidene (4,6-di-tertiary-butylphenol) , 2, 2, -ethylidenebis (6-third-butyl-4-isobutylphenol), 2, 2'-fluorenylenebis [6- (α-methylbenzyl) —4— Nonylphenol], 2, 2'-fluorenylenebis [6 — (α, α -dimethylbenzyl) -4 4-nonylphenol], 4,4 methylenebis (2, 6-bis- Tertiary-butyl phenol), 4, 4, monofluorenylbis (6-second-butyl-2-methylphenol), li-bis (5-third-butyl-4-hydroxy-2 Monomethylphenol) butane, 2, 6-bis (3-third-butyl-5-fluorenyl-2-hydroxybenzyl) -4 methylol, 1,1,3-bis (5- Tertiary-butyl-4-hydroxy 2-methylphenyl) butane, 1,1-bis (5-third-butyl-1,4-hydroxy-2-methylphenyl) -3-n-dodecylfluorenylbutane , Ethylene glycol bis [3, 3-bis (3-third-butyl-4-hydroxyphenyl acid ester], bis (3-third-butyl-4_hydroxy-5-methylphenyl) Dicyclopentadiene, bis [2- (3-Second-butyl-2-hydroxy- 5-methylbenzyl) -6-third-butyl-200412359 4-fluorenylphenyl] p-peptidic acid Ester, ij bis (3,5-dimethyl-2-hydroxyphenyl) butane, 2,2-bis (3,5-di-third-butyl-4-phenyl) propane, 2,2-bis (5-Third-butyl-4-hydroxy-2-methylphenyl) -4-n-dodecylfluorenylbutane, 1,1,5,5-tetrakis (5 -Third-butyl-4-Ethyl-2-fluorenylphenyl) propane. 1-7 benzyl compounds, for example, 3, 5, 3 ', 5'-tetra-third-butyl-4,4'-dihydroxydibenzyl ether, octadecyl-4-hydroxy-3, 5-dimethylbenzylmercaptoacetate, tridecyl-4-hydroxy-3,5-di-tert-butylbenzylmercaptoacetate, tris (3, 5-di-tert-butyl) 4-Hydroxybenzyl) amine, 1,3,5-bis (3,5 -mono-di-butyl-4-acrylfluorenyl) -2,4,6-trifluorenylbenzene, bis ( 3,5-Di-tertiary-butyl-4-benzylidene) sulfur, 3,5-Di-tertiary-butyl-4-hydroxybenzylfluorenyl isooctyl acetate, p-peptidic acid Bis (4-third-butyl-3-hydroxy-2,6-dimethylbenzyl) dithiocarbamate, isocyanuric acid 13,5-tris (3, 5-di-third-butyl 4-hydroxybenzyl) ester, isocyanuric acid 1,3,5-tris (4-third-butyl-3-hydroxy-2, 6-dimethylbenzyl) ester, 3, 5-di -Di-octadecyl phosphate of the third-butyl-4-hydroxybenzyl phosphate and 3,5-di-tertiary-butyl-4-light benzyl acid mono-ethyl moieties, salt . 1-8 light alkyl amidinyl malonate B, for example, di-octadecyl-2 2 -bis (3,5-di-third-butyl-2-meryl) malonate Ester, dioctadecyl-2- (3-tert-butyl-4-hydroxy-5-methylbenzyl) malonate, dodecylcarbylethyl-2, 2-bis (3, 5-Di-Third-Butyl-4-Bynoyl) Malonate, bis [4- (1,1,3,3-tetramethylbutyl) phenyl] -2, 2-bis (3,5-bis-tertiary-butyl-4-mercapto) malonate. 1 · 9 square aromatic hydroxyfluorenyl compounds, for example, 1,3,5-tris (3 5 -di-di-di-butyl-4 -sylfluorenyl) -2,4,6-trimethylbenzene 1,2,4-bis (3, 5- 31 200412359 bis-third-butyl-4-ylbenzyl) -2, 3, 5, 6-tetrafluorenylbenzene, 2, 4, 6-tris ( 3, 5-Di-Third-Butyl-4 ~ (based on dry basis). 1.10 Triazines. For example, 2, 4-bis (octylmercapto) -6- (3, 5-bis-tertiary-butyl-4-meranilidene) -1,3,5-triazine , 2-octylfluorenyl-4,6-bis (3,5-di-tertiary-butyl-4-hydroxyaniline) -1,3,5-tri-U-Qin, 2-octyl-weiyl- 4,6 -bis (3, 5-di-tertiary-butyl-4-triphenylphenoxy) -1,3,5-difluorene, 2,4,6-di (3,5 -—- Tert-butyl-4-mercaptophenoxy) -1,2,3-dioxo, 1,3,5-bis (3,5-«— -tris-butyl-4-mercapto Radical) isorhamnetic acid, 1,3,5-tris (4-second-butyl-3-meryl-2,6-dimethylbenzyl) isocyanurate, 2, 4 , 6-tris (3,5-di-tertiary-butyl-4-hydroxyphenethyl) -1,2,3-triazine, 1,3,5-tris (3, 5-di-tertiary -Butyl-4-hydroxyphenylpropionamidine) -hexahydro-1,3,5-triazine, 1,3,5-tris (3,5-dicyclohexyl-4-hydroxybenzyl) isocyano Uric acid ester. 1.11 Amidinophosphonic acid S, for example, 2,5-bis-tertiary-butyl-4-acylbenzylphosphonic acid dimethyl ester, 3,5-bis-tertiary-butyl-4-hydroxyl Benzylphosphonic acid diethyl ester, 3, 5-di-tertiary-butyl-4-hydroxybenzylphosphonic acid di-octadecyl ester, 5-tertiary-butyl-4-hydroxy-3- Dibenzylphosphonic acid di-octadecyl ester, phosphonium salt of 3, 5-di-tertiary-butyl-4-4-methylidenephosphonic acid monoethyl vinegar. 1.12 H-based amines, for example, 4-benzyl-laurate tanilide, 4-benzyl-stearate styridine, 2,4-bis (octylM) -6- (3, 5-Di-tertiary-butyl-4-hydroxyaniline) -h-tri- and ν- (3,5-di-tertiary-butyl-4-hydroxyphenyl) carbamic acid octyl ester. 1.13 bis-tertiary-butyl-4-fluorenyl) propanoic acid with single or ^ 'For example, with methanol, ethanol, n-octanol, iso-octanol, 32 200412359 stearyl alcohol, 1,6 -Hexanediol, -nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, S ethylene glycol, pentaerythritol, tris (hydroxyethyl) iso Cyanouric acid, N, N, -bis (hydroxyethyl) oxadiamine, 3-thioundecanol, 3-thiopentadecanol, trimethylhexanediol, trimethylolpropane, 4 — Esters of hydroxymethyl + phosphorus-2,6,7-trioxane [2,2,2] octane. 1,14 K5—Ester esters of third-butyldimethyldimethylzA polyol, for example, with methanol, ethanol, n-octanol, iso-octanol, stearyl alcohol, hexamethylene Alcohol, 1,9-nonanediol, ethylene glycol, monopropylene glycol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris (hydroxyethyl) isocyanuric acid , N, N, -bis (hydroxyethyl) humoxamine, 3-thioundecyl alcohol, 3-thiopentadecanyl alcohol, trimethylhexanediol, trimethylolpropane, 4-hydroxymethyl -i-phospho-2,6,7-trioxabicyclo [2,2,2] octane: ester 1.15

Eighty esters, for example, with methanol, ethanol, n-octanol, iso-octanol, alkanol, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol, propylene glycol, neopentyl Glycols, thiodiethylene glycol, diethylene glycol, 2 ethylene glycol, pentaerythritol, di (transethyl) isocyanuric acid, N, N, -bis (hydroxyethyl) oxadiamine, 3-monosulfide Deca-alkanol, 3-thiopentadecanyl alcohol, trimethylhexanediol, tris-methylpropane, 4-hydroxymethyl-1-phosphono-2,6,7-trioxane [2,2 , 2] Octane ester. L 16 Di-tertiary-butyl-4-fluorenylacetic acid fluorene mono- or multi-opening, for example, with methanol, ethanol, n-octanol, iso-octanol, stearyl alcohol, 1,6- Hexanediol, 1,9-nonanediol, ethylene glycol, [1,2-propylene glycol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, 33 200412359 diethylene glycol Group) isocyanuric acid, N, N, -bis (hydroxyethyl) humoxamine, 3-thiodecane gardenia 3thiopentadecanol, trimethylhexylene glycol, trimethylolpropane, 4 -Hydroxymethyl small phosphorus—2,6,7-trioxabicyclo [2,2,2] octane ester. 7 Dan 111-5-di-diyl-4-benzyl) propanine, for example, N, N,-instead of hr-a- 筮-卞 aunt, 芰 (^, 5 1-second -Butyl-4-hydroxyphenylpropanidine) hexamethylenediamine, ^, _ bis (3,5_di_third_butyl_4_ via phenylpropyl) trimethylenedifluorene Amine, Ν, Ν, bis (3,5_di_third-butyl_4_hydroxyphenylpropanyl entropy hydrazine, N 'Ν, -bis [2 一 (3_ [3, 5_di_section Tri-butyl + Naphard (g) via phenyl] propoxyl) ethyl] oxadiamine (Uniroyal. 1 · 18 A ut (vitamin c). L '19 oxidant, for example, N, N'-diisopropyl-p-phenylene-N, N-mono-second-butyl-p-phenylenediamine, ^, _ bis (1'4-dimethyl (Pentyl) -p-phenylene diamine, N, N, bis (buthyl-3_fluorenylpentyl) -p-phenylene diamine, N, N, _bis (1-fluorenylheptyl) _P-phenylene monoamine, N, N'-dicyclohexyl-p-phenylene diamine, N, N, _diphenyl-p-phenylene diamine, N, N, _bis ( 2-naphthyl) _p-phenylene diamine, n-isopropyl-N'-phenyl-p-phenylene diamine, n_ (1,3-dimethyl Group) _n, -phenyl-p-phenylene diamine, N- (1-fluorenylheptyl) _ ^, _ phenyl_p-phenylene diamine, N-% hexyl_N'-benzene P-p-phenylenediamine, 4_ (p-toluenesulfonyl) diphenylamine, N, N, -dimethyl-N, N, _: _ second_butyl_p-phenylene Diamine, diphenylamine, N-allyldiphenylamine, 4-isopropoxydiphenylamine, N-phenyl-1-naphthylamine, N_ (4_third_octyl Phenyl) —bnaphthylamine, Nphenyl-2-naphthylamine, octylated diphenylamine (eg, p-, p-bis-third-octyldiphenylamine), 4-n- Butylaminophenol, 4-butylaminoamine 34 200412359, 4-nonylaminophenol, 4-dodecylaminophenol, 4-octadecylaminophenol, bis (4-methoxy Phenyl) amine, 2, 6-di-tert-butyl-4-dimethylaminomethylphenol, 2, 4, -diaminodiphenylmethane, 4, 4, monodiaminodiamine Phenyl methylbenzene, N, N, N ', N'-tetramethyl-4, 4'-diaminodiphenylmethane, ι, 2-bis [(2-methylphenyl) amino] ethyl Alkane, 1,2-bis (aniline) propane, (o-tolyl) biguanide, bis [4- (Γ, 3, -di Butyl) phenyl] amino, tertiary octyl N-phenyl-1-naphthylamine, mono- and di-alkylated tertiary-butyl / second-octyl diphenyl Mixtures of monoamines, mixtures of mono- and di-alkylated nonyldiphenylamines, mixtures of mono- and di-alkylated dodecyldiphenylamines, mono- and di-alkyl Mixture of isopropyl / isohexyl diphenylamine, mixture of mono- and di-alkylated tert-butyldiphenylamine, 2, 3-dihydro-3, 3-dimethyl -4Η-1,4-Benzylpyridine, phenidazine, mono- and di-alkylated tertiary-butyl / third-octylphenothiazine mixtures, mono- and di-alkylated A mixture of tertiary-octylphenidone, N-allylphenothiazine, 1 ^, 1 ^, 1 ^ ', 1 ^'-tetraphenyl-1,4-diaminobut-2- Ene,] \}, 1 ^ -bis (2,2,6,6-tetramethyl-butane-4-yl) -hexamethylenediamine, sebacic acid bis (2,2,6,6 -Tetramethyl-naphthidine-4-yl) S, 2, 2, 6, 6-tetramethyl-n-stilbone, 2,2,6,6-tetramethyl-pyridine-4 -alcohol. 2. UV absorber and light stabilizer 2. 1 2- (2-hydroxyphenyl) -2pyrene-benzoH, for example, known commercially available hydroxyphenyl-2pyrene-benzotriazole and benzotriazole , Such as U.S. Patent Nos. 3,004,896, 3,055,896, 3,072,585, 3,074 910, 3, 189, 615 > 3, 218, 332 ^ 3, 230, 194 > 4,127,586, 4,226,763, 4,275,004, 4,278,589, 4,315,848, 35 200412359 4, 347, 180, 4, 383, 863, 4, 675, 352, 4, 681,905, 4, 853, 471 5, 268, 450, 5, 278 , 314, 5, 280, 124, 5,319,091 5,410,071 ^ 5, 436, 349, 5,516,914, 5, 554, 760, 5, 563, 242, 5, 574, 166, 5, 607, 987, 5, 977, 219 and Disclosure No. 6, 166, 218, for example, 2- (2-Ethyl-5-methylphenyl) -2H-benzotriazole, 2- (3,5-di-tertiary-butyl-2 —Hydroxyphenyl) -2H-benzotriazole, 2- (2-hydroxy-5-third-butylphenyl) _2H-benzotriazole, 2- (2-hydroxy-5-third-octyl Phenyl) -2H-benzotriazole, 5-chloro-2- (3, 5-di-third-butyl-2-hydroxyphenyl) -2H-benzotriazole, 5-chloro-2 -(3 -Third-butyl-2-hydroxy-5-methylphenyl) -2H-benzotriazole, 2- (3-Second-butyl-5-5-Third-butyl-2-hydroxyphenyl) -2H-benzotriazole, 2- (2-Cyclo-4-octyloxyphenyl)- 2H-benzotriα, 2- (3,5-bis-tertiary-pentyl-2-hydroxyphenyl) -2H-benzotriazole, 2- (3, 5-bis-α-cumyl 2-Ethylphenyl) -2H-benzotriazole, 2- (3-Third-butyl-2-Ethyl-5- (2- (ω-hydroxy-octyl- (ethoxy)) Carbonylethyl) phenyl) — 2η-benzotriazole, 2- (3-dodecyl-2-hydroxy-5-methylphenyl) -2Η-benzotriazole, 2- (3-th Tri-butyl-2-hydroxy-5- (2-octyloxycarbonyl) ethylphenyl) — 2H-benzotriazole, dodecyl 2- (2-hydroxy-5-methylphenyl) ) -2H-benzotriazole, 2- (3-tert-butyl-2-hydroxy-5- (2-octyloxycarbonylethyl) phenyl) -5 monochloro-2H-benzotriazole , 2- (3-Third-butyl-5- (2- (2-ethylhexyloxy) carbonylethyl) -2-hydroxyphenyl) -5-gas-2H-benzotriazole, 2 -(3 -Third-butyl-2-hydroxy-5- (2-fluorenyloxyethyl) phenyl) -5_gas-2H-benzotriazole, 2- (3-Third-butane 2-hydroxy-5- (2-methoxycarbonylethyl) phenyl) -2H-benzotriazole, 2- (3-third-butyl-5- (2- (2-ethylhexyloxy) 36 200412359 carbonylethyl) -2-hydroxyphenyl) -2H-benzotriazole, 2- (3-third-butyl-2-hydroxy-5- (2- Isooctyloxycarbonylethyl) phenyl) -2H-benzotriazole, 2, 2'-fluorenylene-bis (4-third-octyl- (6-2H-benzotriazole-2- Phenol), 2- (2-hydroxy-3-o: -cumyl-5-third-octylphenyl) -211-benzotriazole, 2- (2-hydroxy-3-third- Octyl-5-«-cumylphenyl) -211-benzotriazole, 5-fluoro-2- (2-hydroxy-3,5-di-α-cumylphenyl) -2H-benzotriazole Azole, 5-Ga-2- (2-hydroxy-3,5-di-α-cumylphenyl) -2H-benzotriazole, 5-Ga-2- (2-hydroxy-3-α-cumyl -Yl-5-tert-octylphenyl) -2H-benzotriazole, 2- (3-tert-butyl-2-meryl-5- (2-isooctyloxyethyl) Phenyl) -5-chloro-21! -Benzotriazole, 5-trifluorofluorenyl-2- (2-hydroxy-3-"-cumyl-5-third-octylphenyl) -2H- Benzotriazole, 5-trifluorofluorenyl-2- (2-hydroxy-5-third-octylphenyl) -2H-benzotriazole, 5-trifluorofluorenyl-2- (2-hydroxy -3, 5-bis-third-octylphenyl) -2H-benzotriazole, 3- (5-trifluorofluorenyl-2H-benzotrifluorene-2 -yl) -5 -third- Butyl-4-via hydrogen Methylsulfonyl laurate, 5-butylsulfonium-2- (2-hydroxy-3-α-cumyl-5-third-octylphenyl) -2fluorene-benzotriazole, 5-trifluoro Methyl-2- (2-hydroxy-3-α-cumyl-5-third-butylphenyl) -2fluorene-benzotriazole, 5-trifluorofluorenyl-2- (2-hydroxy-3 , 5-di-tertiary-butylphenyl) -2H-benzotriazole, 5-trifluoromethyl-2- (2-hydroxy-3,5-di--0: _cumylphenyl)- 211-benzotrimethylene, 5-butyl quinone-2- (2-Cyclo-3,5-di-tertiary-butylphenyl) -2H-benzotriton and 5-phenyl quinone_2 -(2-Cyclo-3,5-di-third-butylphenyl) -211-benzotris17. 2.2 2-Hydroxybenzirone, for example, 2, 2, 2-dihydroxy, 4-hydroxy, 4-methoxy, 4-octyloxy, 4-decoxy, 4-dodecyloxy, 4 -Benzyloxy, 4,2,4'-trihydroxy and 2'-hydroxy-4,4'-dimethoxy derivatives. 37 200412359 .3 The first generation of formic acid is not taken, for example, salicylic acid 4-di-monobutyl radical S, salicylic acid phenyl ester, salicylic acid octylphenyl ester, dibenzoyl resorcinol, Bis (4-tertiary-butylbenzophenazine) resorcinol, benzophenanthrene resorcinol, 3,5-tris-butyl-3,4-hydroxybenzoic acid-2,4,1,21 Tert-butylphenyl ester, 3,5-di-tert-butyl-4-hydroxybenzoic acid hexadecyl ester, 3,5-di-tert-butyl-4-hydroxybenzoic acid ten Octyl ester, 3, 5-di-tertiary-butyl-4 monohydroxybenzoic acid 2-methyl-4, 6-12 tertiary butylphenyl @ Purpose. 2 · 4 No. Sulfuric acid S and malonic acid vinegar, for example, α-cyano-cold / 3-diphenylethyl acrylate or isooctyl, α-methyl-cinnamate methyl ester , Cyano- / 3-methyl-p-methoxy-cinnamate methyl ester or butyl ester, α-methyl-p-methoxy-cinnamate methyl ester, N- Ester-Cold-Cyanovinyl) -2-Methyl, Benzyl, Sanduvoi ^ PRZS, dimethyl p-methoxybenzylidenemalonate (CAS No. 7443-25-6) And SanduVOI " PR3l, p-methoxybenzylidenemalonate di (1,2,2,6,6-pentamethylpiperidine-4-yl) ester ((: 仏 number 147783- 69—5 2 · 5 produces ^^, for example, 2,2, -thio_bis- [4-(mg-tetramethylbutyl) phenol] nickel complex, for example, 丨: i or 丨: A complex of 2, with or without additional ligands, for example, n-butylamine, triethanolamine or N-cyclohexyldiethanolamine; dibutyldithiocarbamate; A salt of a monoalkyl ester of 5-di-tertiary-butylbenzylphosphonic acid (for example, methyl or ethyl radicals); a lipid (for example, 2-mercapto-4-methyl) Phenyl undecyl ketone oxime) Nickel complex 4-benzyl-4—lauryl hydrazine-5, bisapthyl nickel complex 38 200412359 complex, with or without additional ligands. 2 · 6 double interlayer. .1 array of A stabilizers, for example, 4-hydroxy-2, 2, 6, 6-tetramethylpyridine; [monoallyl-4-mercapto-2, 2, 6,6-tetra Methyl pie bite, Budyl-4 ~ hydroxy-2,2,6,6-tetramethylmorphine, sebacic acid bis (2 2,6 6-tetrafluorenyl 4 ~ piperidinyl) ester, butyl Bis (2, 2, 6, β-tetramethylimidinyl) diacid, bis (1,2, 2, 6, 6-pentamethyl-4-piperidinyl) sebacate, decyl Bis (businoxy-2, 2, 6, 6-tetramethyl-4-piperidinyl) diacid, n-butyl-3, 5 one-one third-butyl-4-hydroxybenzyl Bis (1,2,2,6,6-pentamethyl-1,4-pentinyl) malonate, 1- (2-hydroxyethyl) -2, 2, 6, 6-tetramethyl- Condensate of 4-Hydroxyline and succinic acid, Ν, Ν'-bis (2, 2, 6, 6-tetramethyl-4-benzyl) hexamethylenediamine and 4-tertiary- Linear or cyclic condensate of octylamino-2, 6-dichloro-n 5 -triazine, nitrogen triacetate tri (2, 2, 6, 6-tetramethyl-1, 4-one) Amidyl) ester, tetracarboxylic acid tetra (2, 2, 6, 6-tetramethyl-4-nonidinyl) -1,2, 3, 4-butane ester, 1,1 '-(1,2- Ethanediyl) -bis (3, 3, 5, 5-tetramethylpiperazinone), 4-phenylhydrazone-2, 2, 6, 6-tetramethylmorphine, 4-stearyloxine -2, 2, 6, 6-tetramethylammonium, malonate bis (1,2, 2, 6, 6-pentamethylneidyl) -2-n-butyl-2- (2 -Hydroxy-3,5-di-tert-butylbenzyl) ester, 3-n-octyl-7, 7, 9, 9-tetramethyl-1,3, 8-triazaspiro [4 , 5] dec-2,4-di-, sebacic acid bis (1-octyloxy-2, 2, 6, 6-tetramethylpiperidinyl) ester, succinic acid bis (buoctyloxy- 2,2,6,6-tetramethylpiperidinyl) ester, N, N, -bis (2,2,6,6-tetramethyl-4-ane. Linear or cyclic condensate of hexamethylenediamine and 4-morphoyl-2,6-dichloro-i, 3,5-triazine, 2-gas ~ 4,6-bis (4- N-Butylamino-2, 2, 6, 6-tetramethylpiperidinyl) -condensate of 1,3,5-triazine and l 2-bis (3-aminopropylamino) ethane, 2 -Chloro-4,6-di- (4 ~ n-butane 39 200412359 Amino-1,2,2,6,6-pentamethylmethylbenzyl)-ι, 3,5-triazine and i, 2 Condensate of a bis (3-aminoaminopropylamine) group B, 8-ethenyl-3-dodecyl-7, 7, 9, 9-tetramethyl-1, 3, 8-triaza Spiro [4, 5] dec-2,4-dione, 3-dodecyl-1- (2,2,6,6-tetramethyl-4-〇pyridinyl) pyrrolidine-2,5 Monodione, 3-dodecyl-Bu (1,2,2,6,6-pentamethyl-4 piperidinyl) pyrrolidine-2, 5-dione, 4-hexadecyloxy A mixture of stilbyl- and 4-stearylfluorenyloxy_2,2,6,6-tetramethylmethylpyridine, N, N'-bis (2, 2, 6, tetramethyl-4-4-pyridinyl) Condensation products of hexamethylene diamine and 4-cyclohexylamino_2, 6-digas-ng-triazine, 1,2-bis (3-aminopropylamino) ethane, and 2, 4, 6 -Condensation products of trichloro-1,3,5-triazine and 4 -Butylamino-2, 2, 6, 6-tetramethylpyridine (CAS registration number [136504-96-6]); N- (2, 2, 6, tetramethyl-4-piperidinyl) One n-dodecyl succinimide ,! ^-(1,2,2,6,6-pentamethyl-4-.pyridinyl) -n-dodecylsuccinimide, 2-undecyl-7,7,9,9 —Tetramethyl— 丨 —A 3, 8-diaza-4_oxospiro [4, 5] decane, 7, 7, 9, 9-tetramethyl-2 2-cycloundecyl-1 -腭 -3, 8-diaza-4-oxospiro [4, 5] decane and epichlorohydrin reaction product, 1, bis (1,2,2,6,6 ~ pentamethyl- 4-erpyridyloxycarbonyl) -2- (4-methoxyphenyl) ethylene, N, N, a bis-formamyl- & n, a bis (2, 2, 6, 6-tetramethyl) -Piperidinyl) hexamethylenediamine, 4-methoxymethoxymethylene-malonic acid and 1,2,2,6,6-pentamethyl-4 4-hydroxypyridine Esters, poly [methylpropyl-3-oxy-4 — (2,2,6,6 ~ tetramethyl-4, pyridyl)] siloxane, maleic anhydride-α-olefin ~ Copolymer with 2,2,6,6-tetramethyl-4-amino group. Stable or sterically hindered amines can also be one of the compounds described in U.S. Patent No. 5,98〇, 783, the relevant part of which is incorporated herein by reference, 40 200412359 is also the component bua), bub ), 1-c), id) 1-g), 1-h) -e), 1-f) l-i 1-j), 1-k) or 丨-丨): not listed The light stabilizers in the U.S. Patent Nos. 5,980,783 and 64-72, BU a-1, BU a-2, BU b-1, BU c-1, BU c d-2, ld-3 1 -dl, 1 -e- 1, Bu f-1, 1 a g-; [, Bu g-2 or Bu ki. The sterically hindered amine can also be one of the compounds described in European Patent No. 782994, for example, the compounds in the scope of patents No. M or 或 or Examples 1-12 or D-1 to D-5 . Substituted alkoxy groups are substituted by alkoxy groups substituted with N groups in N ortho. For example, US Patent No. 6,271,377 and US Patent Application No. 09 / 794,710 (application date February 27, 2001 ) Chemical compounds disclosed, for example, 1 (2-hydroxy-2-methylpropoxy) -4-octadecanoyloxy-2, 2, 6, 6-tetramethylpiperidine, ^ (2 Monohydroxy_2-methylpropoxy) -4-hexadecanoyloxy-2,2,6,6-tetramethylpyridine; i monooxy-4 monohydroxy-22,6,6 The reaction product of tetramethylammonium and the carbon group of tert-pentanol, (2-hydroxy-2 2-methylpropoxy) -4-hydroxy-2,2,6,6-tetrafluorenyl Pyridine, 1- (2-hydroxy- 2-methylpropoxy) -4-oxo-2, 2, 6, 6-tetramethylpiperidine, sebacic acid bis (2- (2-yl-2- Fluorenylpropoxy) -2, 2, 6, 6-tetramethylbenzyl-4-yl), bis (1— (2-meryl-2-methylpropoxy) -1 2, 2, 6, 6-tetramethylpentamidine-4-yl) ester, succinate bis (2- (hydroxyl-2-methylpropoxy))-2, m tetramethylpiperidine-4 -Yl) ester, glutaric acid bis (1- (2-hydroxy-2-methylpropoxy) -2, 2, 6, 6-tetra Thiomorphin-4-yl) ester and 2, 4-bis {N-[[(2-Crylyl-2-methylpropoxy) -2, 2, 6, 6-tetramethylmeridin-4- [] -N-butylamino} -6- (2-hydroxyethylamino) -h-triazine. 200412359 2 · 8 straw brewing month text 'for example, 4,4 dioctyl lactol tamidine, 2, 2, ~ diethoxy oxaloptidine, 2, 2, -dioctyloxy-5, 5 , -Di-tertiary-butylcurfenacet, 2, 2, -di-dodecyloxy-5, 5, -di-tertiary-butylcurfenidine, 2-ethoxy- 2, -Ethylpyridamine, N, N, -Bis (3-dimethylaminopropyl) oxadiamine, 2-ethoxy-5-Third-butyl-2, -ethylgrass Panethanilide and its mixture with 2-ethoxy-2, -ethyl-5,4, -tert-butyloxafenidanilide, o- and p-methoxy-disubstituted oxalopidine Mixtures of aniline and mixtures of ortho- and p-ethoxy-disubstituted scopolamine. 3. Jinzhan_Deactivating agent, for example, N, N'-diphenylhumoxamine, N-salicyl-N, -salicylhydrazine, N, N, -bis (salicyl) hydrazine, N, Ν, -bis (3,5-bis-tertiary ~ butyl-4-hydroxyphenylpropylhydrazine) hydrazine, 3-salicylamine-1,2,4-triazole, bis (benzylidene) ) Grasshopper dihydrazine, grasshopper aniline, isophthalamidine dihydrazine, sebacamide bisphenylhydrazine, Ν, Ν, -diethylhydrazine dihydrazide, Ν, Ν, -bis ( Shuiyang 醯) grass hydrazone dihydrazine, ν, ν,-bis (salina salamander) thiopropyl hydrazone dihydrazine. 4. Phosphonic acid phospholipids, such as triphenyl phosphite, dibenzyl phosphite, phenyl dialkyl phosphite, tri (nonylbenzyl) phosphite, Trilauryl phosphate, tris (octadecyl) phosphite, distearyl phosphite pentaerythritol phosphite, tris (2,4-di-tert-butylbenzyl) phosphite, diisophosphite Decyl pentaerythritol ester, bis (2-di-4-tri-butylphenyl) diphosphite, bis (2, 6-di-dibutylbutyl 4-methylbenzyl) pentaerythritol diphosphite, Phosphonic acid diisodecyl pentaerythritol ester, acid bis (2,4-di-tertiary-butyl-6-methylphenyl earth) pentaerythritol, diphosphite bis (2, 4, 6 one three (the Phenyl)) 42 200412359 pentaerythritol ester, tristearyl triphosphite sorbitol ester, 4, 4, 4-phenylene diphosphonic acid tetra (2, 4-bis-tertiary-butylphenyl) ester 6-isooctyloxy-2, 4, 8, 10-tetra-tertiary-butyl-dibenzo [d, f] [i, 3, 2] dioxaphosphepin, 6-fluoro -2, 4, 8, 10-tetra-tertiary-butyl-12-methyl-dibenzo [(1 ; ^ [1,3,2] Diphosphine ((11 (^ 3011〇3011〇 (^ 11), bis (2,4-bis-third-butyl-6-methylphenyl) phosphite) Methyl ester, bis (2,4-di-tertiary-butyl-6-methylphenyl) ethyl phosphite, 2,2,2 ,,-nitrogen [triethyltri (3, 3,5,5, -tetra-tertiary-butyl-1, Γ-biphenyl-2,2, -diyl) phosphite], 2-ethylhexyl phosphite (3, 3, 5, 5 , 5, -tetra-tertiary-butyl-1,1, -biphenyl-2, 2, -diyl) ester. For example, the following phosphites: Tris (2,4-di-tertiary phosphite —Butylphenyl) ester (1 to 8 £ 03 < §) 168, Cibabat Chemical Company), tris (nonylphenyl) phosphite,

(ch3) 3c (A)

43 200412359

(D) (ch3) 3c—〇 一 < > --〇 一 ^^ >-c (ch3):

C (CH3) 3 (CH3) 3C C (CH3) 3 (ch3) 3c,

c (ch3) 3 (CH3) 3C

5. Hydroxylamines, for example, N, N-dibenzylhydroxylamine, N, N-diethylhydroxylamine, N, N-dioctylhydroxylamine, N, N-dilaurylhydroxylamine, N, N -Di-tetradecylhydroxyamine, N-heptadecyl-N-octadecylhydroxylamine, N-methyl-N-octadecylhydroxylamine, and N, N- Dialkyl via amines. 44 200412359 6 · Copper nitrate 'for example' N-fluorenyl-q: monophenylnitrone, N-ethyl- -fluorenyl fluorene, N-octyl-heptyl fluorene, Ν-lauryl fluorene —Brokenyl stilbone, N-tetradecanyl-α-tridecylenyl nitrate J, N-hexadecyl pentadecyl chrysostanol, N-octadecyl yl-α-seventhyl benzene Ketone, N-hexadecyl-α-heptadecyl nitrone, N-octadecyl-α-pentadecyl nitrone, N-heptadecyl-α-heptadecyl nitrone, [N-octadecyl-O; -hexadecyl-based trimon], N-fluorenyl-α-heptadecyl nitrone and derived from N, N-dialkylhydroxylamine (which is derived from hydrogenated fatty oleylamine ) Of nitrone. 7. Amine oxides, for example, amine oxide derivatives, didecylfluorenylamine oxide, tridecylamine oxide, tri-dodecyl group disclosed in U.S. Patent Nos. 5,844,029 and 5,880,191 Amine oxide and tri-hexadecylamine oxide. 8. Benzofuranone and β-Domanone, for example, US Patent Nos. 4,325,863, 4,338,244, 5,175,312, 5,21 6,052, 5,252,643 , German patents DE-A-431661 1, DE-A-4316622, DE-A-4316876, European patent EP-A-0589839 or EP-A-0591 102 disclosed benzofuran pyrene and Zhao B Duoman_ , Or 3- [4- (2-Ethylpyroxyethoxy) phenyl] -5, 7-di-third-butylbenzofuran-2-one, 5,7-di-third- Butyl-3- [4- (2-stearylethoxyethoxy] phenyl) benzofuran-2-one, 3, 3-bis [5,7-bis-third-butyl-3 -(4- [2-hydroxyethoxy] phenyl) benzofuran-2-one], 5, 7-bis-third-butyl-3- (4-ethoxybenzyl) benzofuran -2-ketone, 3- (4-acetamidooxy_3,5_dimethylphenyl) _5,7_di__tertiary-butylbenzofuran-2-one, 3- (3, 5-dimethyl_4_tetrapentyloxyphenyl) -5,7-di-tert-butylbenzofuran_2_one, 3_ (3, 4-dimethylbenzene 45 200412359 group) _ Perylene di-butyl benzfurfurol_2-one (irg_x @ Hp_136, :: Special Chemicals Corporation) and 3_ (23_dimethylphenyl) _57_di — didi-butylben Skin pyran -2 - g the same. • Long-acting 1 'such as' dilauryl thiodipropionate or distearyl thiodipropionate. & For example, vinegar of thiodipropionic acid, such as lauryl, stearyl, myristyl or tridecyl vinegar, weylbenzene Dysprosium, -Zinc isobutyl dithiocarbamate, eicosyl monosulfide, tetrakis (m-dodecylmercapto) propionate pentaerythritol purpose 0 11 · 'For example, with iodide Copper salt and / or phosphorus compound combined with divalent manganese salt, for example, Cul. 5 12 ·, for example, melamine, polyvinylpyrrolidone, cyanodimethamine, triallyl cyanurate, urea derivative, hydrazone derivative, Yue'an, polyamide, polyurethane, Alkali and alkaline earth metal salts of higher fatty acids, such as calcium stearate, stearate, magnesium sorbate, magnesium stearate, sodium cis-ricinoleate and potassium palmitate, antimony pyrocatechuate, or Zinc Catechinate. 13, where, for example, inorganic substances, such as talc, metal oxides (eg, Shikou, titanium monoxide, or oxidized iron, for example, inscriptions, carbonates, or sulfates of soil test metals; organic compounds, such as, Mono- or polycarboxylic acids and their salts, for example, 4-tert-butylbenzoic acid, adipic acid, phenylhydrazone, sodium succinate or sodium benzoate; polymeric compounds, for example, ionic copolymers (Ionomer). 8 46 200412359 14. Fillers and reinforcements 1. Examples of fibers, glass bubbles, asbestos, talc metal oxides and hydroxides, wood flour, synthetic fibers. For example, calcium carbonate, silicates, Powders or fibers of glass, kaolin clay, mica, barium sulfate, and other natural products 15. For example, polyethylene oxides, waxes, or mineral oils. , Lubricants, emulsifiers, pigments, dyes, optical bleaching and rheological additives, catalysts, flow control agents, slip agents, cross-linking agents, cross-linking propellants, anthrax scavengers, smoke inhibitors, fire retardants, Antistatic agents, purifying agents (e.g., substituted or Substituted bisbenzylidene sorbitol), Benzo-UV absorbent (for example, 2, 2-p-phenylene-bis (3, benzobenzoxazine_4-one)), CyaS. rb®3638 (CAS No. i8600 —59 — 4) and blowing agent. The polyamide composition of the present invention is prepared by melt blending techniques well known to those skilled in the art, for example, by Blending methods to form intimate mixing of ingredients. Suitable methods include solution blending and melt blending. For example, polyamide and various ingredients are made using traditional mixing equipment (eg, mill, Banbury mixer, Brabender force flow Variable, single or twin screw extruder, continuous mixer, kneader, etc.) and intimately mix. For example, the ingredients can be intimately a in a high shear mixer in the form of granules and / or powder. For example, ' The ingredients may be mixed by drying and then extruded to obtain the polymer composition of the present invention. Therefore, the present invention also relates to a method for stabilizing a polyamide composition against the harmful effects of heat, light, and oxygen. The method includes An effective stable amount 47 20041 The following ingredients of 2359 are incorporated into the polyamine composition ... At least one compound selected from the group consisting of homo-triazine UV absorbers, and copper salts, wherein substantially no carbon black is present. The polyfluorene of the present invention Amine films, fibers, and molded articles are effective as 'for example' insulators, transparent and thin ", fabrics, coatings, coatings, filaments, textile materials, yarns, and tire cords. The examples are provided for illustration; they should not be construed as limiting the invention in any way. Example 1 Polyamide-6 (ULTRAMID BS-7GG-F powder) was mixed with the additives in a Turbula mixer Blend for 15_2 minutes. The total amount dispensed is grams. The mixture was then extruded with a 27 mm Leistritz twin screw extruder. Squeezing is performed at a zone temperature of 475, ⑽, ⑽. F was performed under conditions of a 500 ° C. nuclear degree. The obtained resin is made into pellets by a cutting machine: the pelletized resin composition is dried in a vacuum oven (82., air peach): ,,, ##, and then spun. The dry blend was spun into fibers in the following dust / spinning configuration (pdf)). Single screw extruder (m; L / D ratio = 24: i) and F extruded Mm wire nozzle 5 cross section (41 holes, 15 denier / fibril 48 200412359) Then these samples were placed in Blue Μ circulating air at 120 ° C In the oven, accelerated weathering is performed using the Atlas C1-65 Xenon Arc Lamp Weathering System (XAW), operated in accordance with ASTM G26-90 Method C. This method uses 0.35 watts per square meter of light and 63 ° Xenon arc system weatherproof box operated by the dark panel temperature of C. The color is measured on the samples aged in the oven and exposed to the xenon gas (the yarns and knitting socks wound on the card), using the DCI SF600 colorimeter The tensile properties are measured on oven-aged and xenon-exposed samples (flat wires) and measured with the INSTRON 4501 device. Details of the formulations and results are listed in the table below. Tables of formulations Numbered weight percent on amidine 01 Blank — 02 Irganox® 1098 + Irgafos® 168 0. 375 + 0. 375 03 Irganox® 3790 + Irgafos® 168 0. 375 + 0. 375 04 Chimassorb® 944 + Irganox® 3790 + Irgafos ®168 0.5 + 0.125 + 0. 125 05 Irganox® 3790 + Irganox⑨HP-136 0.6 + 0.15 06 Irganox® 3790 + Irgafos® 168 + Irganox® HP-136 0.3 + 0.3 + 0.15 07 Irganox® 3790 + Irgafos® 126 0. 375 + 0. 375 08 Irganox® 3790 + Irgafos® 38 0. 375 + 0. 375 09 Irganox® 3790 + Irgastab® FS042 0. 375 + 0. 375 10 Chimassorb® 944 0.75 11 Chimassorb® 944 + Irganox® 1098 + Irgafos® 168 0.5 + 0.125 + 0.125 12 Chimassorb ®119 + Tinuvin®234 (Tinuvin®C353) 0. 5 + 0. 25 13 Chimassorb®119 + Tinuvin®234 + Irganox®1098 0.33 + 0.17 + 0.25 14 Chiraassorb®119 + Tinuvin®234 + Irganox®1098 + 0.33 + 0.17 + 0.125 Irgafos ② 168 + 0.125 15 Chimassorb® 2020 + Irganox® 1098 + Irgafos® 168 0.5 + 0.125 + 0.125 16 CGL 374 + Irganox® 1098 + Irgafos® 168 0.5 + 0.125 + 0.125 17 CGL 0066 + Irganfos® 168 0.5 + 0.125 + 0.125 18 Cyasorb® UV 3346 + Irganox®! 098 + Irgafos® 168 0.5 + 0.125 + 0.125 49 200412359 19 Uvasorb® HA 88 + Irganox® 1098 + Irgafos® 168 0.5 + 0.125 + 0.125 20 Uvasil® 299 + Irganox ®1098 + Irgafos®168 0.5 + 0.125 + 0.125 21 NYLOSTAB SEED 0. 75 22 NYLOSTAB SEED + Irgafos® P-EPQ 0. 375 + 0.375 23 NYLOSTAB SEED + Irganox® 1098 + Irgafos® 168 0.5 + 0.125 + 0.125 24 Tinuvin® 770 + Chimassorb® 944 + Irganox®1098 + Irgafos⑧168 0.25 + 0.25 + 0.125 + 0.125 25 Tinuvin⑧144 + Irganox®1098 + Irgafos®168 0.5 + 0.125 + 0.125 26 Tinuvin®144 + Chimassorb®944 + Irganox®l098 + Irgafos®168 0.25 + 0.25 + 0.125 + 0.125 27 201 Iodide stabilizer 0.25 28 BRUGGOLEN H3336 0.25 29 201 Iodide stabilizer 0.75 30 201 Ethylene stabilizer + Tinuvin®770 + Chimassorb®944 0 25 + 0 25 + 0 25 31 201 Iodine Compound stabilizer + Uvasil® 299 0 · 25 + 0 · 5 32 201 Iodide stabilizer + NYLOSTAB SEED 0 · 25 + 0 · 5 33 201 Iodide stabilizer + Tinuvin® 1577 0.25 + 0.5 34 Tinuvin® 1577 + Irganox® 1098 + Irgafos®168 0.5 + 0.125 + 0.125 35 Tinuvin®234 + Irganox®1098 + Irgafos⑧168 0.5 + 0.125 + 0.125 36 Irganox⑧565 0.75

Irgafos® 168 is tris (2,4-di-tert-butylphenyl) phosphite.

Irganox® HP-136 is 3- (3,4-dimethylphenyl) -5,7-bis-tertiary-butylbenzofuran-2-one.

Irganox® 1098 is N, N'-hexane-1,6-diylbis (3- (3,5-di-tertiary-butyl-4-hydroxyphenylpropanamide)).

Irganox% 790 is tris (4-tert-butyl-2, 6-dimethyl-3-benzyl) isocyanurate (CAS 40601-76-1).

Tinuvin® 234 is a 2- (2-Cyclo-3, 5-bis-α-brainyl) -2H-benzotriazine. Irgafos® 38 is bis (2,4-di-tertiary-butyl-6-fluorenylphenyl) ethyl phosphite. 1 is 3 (β- £? 卩 is 4,4 ' -biphenylphenylphosphonic acid tetra (2,4-di-tert-butylphenyl) ester. 50 200412359

Irgastab® FS042 is an N, N-bis (carbamoyl) triamine produced by the direct oxidation of N, N-bis (hydrogenated fatty oil) amine.

Tinuvin® 1577 is 4,6-diphenyl-2- (4-hexyloxy-2-hydroxyphenyl) -h-triazine. 201 Iodide stabilizer is 80% KI, 10% CuI, and 10% hard. Zinc fatty acid. 1 ^ 311〇 and (1) 565 are 2,6-di-third-butyl-4- (4,6-bis (octylthio) -1,3,5-triazin-2-ylamino )phenol.

Bruggolen® H3336 is a halogenated halogenated copper linoleate compound available from L. Brueggeman. CGL374 is an oligomeric hindered amine stabilizer. CGL0066 is an erazine-based hindered amine stabilizer. Order [03 丁 八 8 3 ££ 0 is 1,3-Benzodicarboxylic acid amidine, 1 ^ -bis (2,2,6,6-tetramethyl-4-piperidinyl), CAS No. 42774- 15-2 (Clariant).

R'—N Η— (CH2) 3— N — (CH2) 2— N — (CH2) 3- N H-R '

Chimassorb®l19 is 51 200412359

Chimassorb⑧2020 is h9c4 c4h9 h9c4

C4H9 Cyasorb® UV 3346 Yes

Uvasil® 299 is ch3

I -〇-Si-

52 200412359

Uvasil⑧ HA88 is R '3 N-C—

(CI NHR " NHR " 3 N——C,

N—〇4H9

Where R ’= R” or H

And where fT

Tinuvin⑧770 is

〇 II 〇 II 〇C- (CH2) g-C-〇

inuvin®144 is

CH

Formulation 33 is the formulation 53 200412359 of the present invention. Table 1: Measure the color of the yarn entangled on the card after xenon exposure. Formulation number yellow index Δ0 0 hours 2000 hours 250 hours 2000 hours 01 29.2 15.0 9.2 8.5 02 27.6 16.4 7.9 6.7 03 30.6 20.2 8.7 6.7 04 33.4 11.5 11.0 13.1 05 36.7 20.6 10.6 9.9 06 34.5 19.1 10.5 9.8 07 31.9 19.2 9.4 7.6 08 31.8 18.9 9.5 7.9 09 27.5 21.3 6.8 3.7 10 27.1 11.7 8.8 10.0 11 23.9 10.5 7.1 8.1 12 32.2 13.7 9.6 11.4 13 26.4 12.9 7.0 8.5 14 25.5 11.9 7.1 8.6 15 21.5 11.9 5.6 5.8 16 20.1 9.8 5.0 7.0 17 22.1 9.7 6.2 8.1 18 31.6 10.4 10.9 13.0 19 35.1 11.4 12.3 14.8 20 49.3 12.6 17.8 22.7 21 50.4 13.8 17.6 23.3 22 56.2 14.0 20.7 26.1 23 35.9 11.4 12.2 14.5 24 29.0 10.5 9.5 12.1 25 33.2 10.9 11.1 13.8 26 31.1 10.5 10.5 12.4 27 49.7 18.5 14.5 19.2 28 38.7 13.2 12.3 15.5 29 38.7 18.4 7.9 12.8 30 48.1 16.6 14.6 18.9 31 30.7 12.9 8.6 11.2 32 32.6 13.9 8.8 11.5 33 31.7 17.1 7.1 8.7 34 34.5 15.7 9.3 11.3 35 31.9 15.7 8.8 10.4 36 37.0 25.3 8.0 8.3 54 200412359 Table 2: Color measurement of knitting machine after xenon exposure. Formula number: Yellow index Δ0 0 hours 1000 hours 250 hours 1000 hours 01 35.6 12.5 13.6 14.9 02 36.5 11.2 13.4 15.9 03 39.8 13.3 13.3 16.5 04 43.1 11.3 16.8 19.7 05 45.0 16.1 14.3 18.2 06 45.2 14.9 15.8 19.4 07 40.9 13.2 14.6 17.2 08 41.5 13.2 14.4 17.3 09 34.2 13.0 10.2 13.4 10 32.7 10.6 13.2 14.6 11 29.5 10.0 10.9 12.5 12 38.5 13.8 14.0 15.8 13 34.5 13.8 11.4 13.4 14 33.1 12.7 11.2 13.1 15 26.2 10.5 8.7 10.2 16 30.3 10.0 11.7 13.1 17 27.2 9.8 9.8 11.4 18 38.8 10.2 16.1 18.2 19 43.7 10.7 18.9 21.1 20 58.6 11.5 25.2 28.7 21 64.7 13.0 26.6 31.2 22 70.9 14.4 28.8 34.2 23 44.0 11.4 17.7 20.5 24 35.0 10.3 14.0 15.9 25 43.9 10.9 17.5 20.0 26 39.9 10.7 15.7 18.0 27 60.7 21.1 20.4 24.2 28 44.6 12.9 16.5 19.6 29 48.0 32.1 11.8 10.1 30 60.2 18.9 20.9 25.0 31 41.4 17.7 13.3 14.3 32 43.2 16.5 13.3 16.2 33 40.1 21.6 10.2 10.9 34 42.3 15.8 13.8 16.2 35 39.2 15.2 13.1 15. 0 36 48.8 17.8 9.3 18.8 55 200412359 Table 3: Measure the color of the yarn entangled on the card after the aging of the oven. The yellow number ΔΕ 0 hours 2000 hours 250 hours 2000 hours 01 28.5 115.8 27.5 52.4 02 27.2 65.3 7.8 23.6 03 31.0 87.8 10.1 35.2 04 32.9 109.6 11.8 46.5 05 36.4 89.0 8.7 32.7 06 34.9 84.4 6.1 31.4 07 31.5 88.7 8.0 35.7 08 31.6 87.1 8.5 34.4 09 26.8 84.8 14.6 36.0 10 27.7 115.5 22.9 53.6 11 23.6 107.9 15.6 51.4 12 32.4 118.7 20.6 52.6 13 26.7 104.2 12.2 47.8 14 25.8 107.5 11.2 50.1 15 21.3 100.0 12.4 47.9 16 21.1 101.2 15.3 49.2 17 22.6 80.8 9.8 36.3 18 31.6 103.2 15.9 44.6 19 35.5 113.0 13.6 47.9 20 49.8 116.8 10.9 40.7 21 52.2 114.2 19.0 37.0 22 56.2 117.3 14.5 35.2 23 35.3 111.7 23.6 46.7 24 30.1 116.2 22.2 52.4 25 33.9 105.7 12.0 44.0 26 30.9 107.5 13.3 46.8 27 49.8 82.8 8.9 19.9 28 38.9 70.6 5.3 19.2 29 39.2 79.3 11.3 23.9 30 47.9 79.8 8.5 19.7 31 31.1 66.8 7.7 21.4 32 33.0 66.6 7.7 20.6 33 32.0 66.4 8.7 21.2 34 34.4 108.8 11.1 45.9 35 32.7 97.6 7.4 40.5 36 37.7 74.7 10.1 22.6 56 200412359 Table 4: Measurement of the color of knitted socks after the aging of the oven Number of the yellow index ΔE 0 hours 1000 hours 250 hours 1000 hours 01 35.3 110.5 36.3 47.8 02 36.3 71.5 15.0 23.2 03 39.5 83.3 16.5 29.4 04 42.6 99.0 20.4 36.9 05 45.5 83.7 16.0 26.7 06 45.1 82.4 13.6 26.1 07 40.5 87.6 17.2 31.4 08 42.0 84.9 15.1 28.5 09 33.4 82.8 21.6 32.0 10 33.3 106.6 32.2 47.5 11 29.1 96.0 24.4 42.3 12 38.7 107.7 28.7 45.2 13 34.2 89.2 20.1 35.7 14 32.4 96.6 19.5 41.4 15 25.8 92.2 21.7 41.2 16 29.2 92.9 23.8 40.3 17 27.5 75.9 17.7 30.6 18 38.5 94.8 23.2 36.8 19 42.7 101.9 20.3 39.0 20 58.0 107.8 15.7 32.6 21 65.3 111.3 24.6 32.7 22 70.2 111.2 18.3 27.1 23 42.2 103.2 30.9 41.1 24 34.3 101.9 28.2 42.8 25 43.7 96.0 19.4 33.7 26 39.7 98.0 21.7 37.5 27 60.7 21.1 20.4 24.2 28 45.9 77.6 11.2 20.3 29 47.9 85.8 19.0 26.5 30 60.6 85.7 13.2 19.2 31 42.0 71.5 11.7 19.0 32 43.3 74.1 12.8 20.7 33 41.1 72.9 14.5 21.5 34 4 2.5 97.0 17.7 36.0 35 38.9 86.1 14.5 30.6 36 49.0 74.8 14.3 17.3 57 200412359 Table 5: Tensile properties of flat wire after xenon exposure Formulation strength% Extension of leaf cracks 0 hours (g / dan) 1000 hours 0 hours ( %) 1000 hours (g / dan)% Reserve%% Reserve 01 2.7 1.5 57 668 103 15 02 2.7 1.8 68 344 96 28 03 2.8 1.0 37 352 35 10 04 2.8 1.7 61 583 160 28 05 2.6 0.7 26 495 21 4 06 2.9 0.8 27 518 28 5 07 2.5 0.7 27 445 21 5 08 2.9 1.1 38 470 45 10 09 2.7 0.2 7 503 13 3 10 2.6 1.6 62 594 108 18 11 2.9 1.8 63 550 171 31 12 2.8 1.7 61 647 147 23 13 13 2.9 1.7 58 614 135 22 14 2.9 1.9 66 599 184 31 15 2.8 1.9 66 539 175 32 16 2.7 2.2 81 570 332 58 17 3.1 2.0 65 661 201 30 18 2.8 1.7 62 643 191 30 19 2.6 1.6 64 555 163 29 20 2.4 1.4 59 602 150 25 21 2.1 1.3 62 512 122 24 22 2.2 1.5 69 541 164 30 23 2.5 1.6 64 571 181 32 24 2.6 1.9 74 559 239 43 25 2.9 1.8 64 675 217 32 26 2.7 1.9 72 709 250 35 27 2.3 1.5 67 614 185 30 28 2.2 1.6 7.2 516 166 32 29 2.4 1.6 66 684 213 31 30 2.3 1.6 69 628 198 32 31 2.6 2.0 77 520 210 40 32 2.9 2.0 68 537 162 30 33 2.8 2.6 92 523 367 70 34 2.7 2.0 74 584 241 41 35 2.6 1.6 62 542 100 18 36 2.7 0.2 8 503 11 2 58 200412359 Table 6: Tensile properties of flat wire after oven aging. Numbering strength 1 Extension of jins cracked place 0 hours (g / dan) 1000 hours 0 hours (%) 1000 hours (g / dan)% retention%% retention 01 2.7 1.1 39 668 39 6 02 2.7 2.4 88 344 148 43 03 03 2.8 2.2 78 352 101 29 04 2.8 1.1 40 583 45 8 05 2.6 2.1 83 495 102 21 06 2.9 2.0 69 518 98 19 07 2.5 1.8 74 445 94 21 08 2.9 2.0 70 470 101 21 09 2.7 1.9 71 503 91 18 10 2.6 0.8 30 594 26 4 11 2.9 1.3 45 550 46 8 12 2.8 0.7 27 647 30 5 13 2.9 1.9 66 614 100 16 14 2.9 1.5 51 599 56 9 15 2.8 1.6 56 539 64 12 16 2.7 1.8 66 570 68 12 17 3.1 2.2 73 661 128 19 18 2.8 1.4 48 643 51 8 19 2.6 0.8 31 555 37 7 20 2.4 0.9 36 602 35 6 21 2.1 0.9 45 512 37 7 22 2.2 1.2 55 541 42 8 23 2.5 1.1 44 571 52 9 24 2.6 1.1 44 559 42 7 25 2.9 1.8 63 675 92 14 26 2.7 1.4 53 709 69 10 27 2.3 2.1 91 614 221 36 28 2.2 2.0 88 516 223 43 29 2.4 2.1 87 684 250 36 30 2.3 2.1 93 628 244 39 31 2.6 2.6 101 520 250 48 32 2.9 2.7 95 537 230 43 33 2.8 2.6 95 523 280 54 34 2.7 2.0 73 584 88 15 35 2.6 1.8 67 542 82 15 36 2.7 2.3 84 503 156 31 The formulations of the invention provide a stabilizing effect that is significantly resistant to the effects of heat, light and oxygen. 59 200412359 Excellent results were also obtained when Example 1 was repeated with Polyamine-6, 6 instead of Polyamine-6. 60

Claims (1)

200412359 Scope of patent application: Polymerization of harmful effects of light and oxygen 1. A composition stabilized against heat, light and amidine, The amidine composition comprises an effective stable amount of at least one compound selected from the group consisting of homo-triazines, and a copper salt, wherein substantially no carbon black is present. 2. The composition according to item 1 of the scope of the patent application, wherein the polyamide is at least one selected from the group consisting of polyamine 4, polyamine 6, polyamine 4, 6, polyamine 6, 6, polyamine 6 10, Polyamine 11, Polyamine 12, Poly-2, 4, 4-trimethylhexamethylene p-amine, poly-p-phenylene p-amine, poly-m-phenylene Phenylisocyanate S blueamine, nylon-6 / nylon-6,6, nylon-6,12, poly (hexamethylene parapeptide amide) and poly (hexamethylene isopeptide amine) Polyamide in the ethnic group. 3. The composition according to item 1 of the patent application scope, wherein the polyamide is polyamide 6 or polyamide 6,6. 4. The composition according to item 1 of the scope of patent application, wherein the uniform triazine UV absorber has formula (IV), (V), (VI), (VII), (VIII) or (IX): 61 (VI) 200412359 (VH) (VIII) 62 (IX) 200412359 where X and Y are independently phenyl, naphthyl, or alkyl via one to three 1 to 6 carbon atoms, via halogen, via hydroxyl, or alkoxy via 1 to 6 carbon atoms Or the phenyl or the naphthyl group substituted by a mixture thereof; or X and Υ are independently Zi or Z2; h is hydrogen, a linear or branched alkyl group of 1 to 24 carbon atoms, 5 to 12 carbons Atomic cycloalkyl, phenylalkyl with 7 to 15 carbon atoms, halogen, -SR3, -S0R3 or -S02R3; or via one to three halogens, -r4, 10r5, -N (R5) 2,- C0R5 '-C00R5, -〇COR5, -CN, -N02, -SR5, -S0R5, -S02R5, or -P (〇) (〇R5) 2, molybdenyl, pyridinyl, 2, 2, 6, 6 A tetramethyl stilbyl group, a morphazinyl group or an N-methylpiperidinyl group or a combination thereof substituted by the alkyl group, β-fluorenyl group or the present alkyl group; or via one to four phenylene groups,- A sulfanyl group or the cycloalkyl group interrupted by a -nr5-, _conr5-, -C00-, -0C0-, or -C0 group or a combination thereof; or the alkane substituted and interrupted by a combination of the above groups Or the cycloalkyl group; I? 3 is 1 to 20 carbon atoms Alkenyl, 3 to 8 carbon atoms, cycloalkyl of 5 to 12% atoms, phenalkyl of 7 to 5 carbon atoms, aryl of 6 to 10 carbon atoms, or via one or This aryl group is substituted by two alkyl groups of 4 to 4 carbon atoms; R4 is an aryl group of 6 to 10 carbon atoms, or an alkyl group of 1 to 3 carbon atoms, 1 to 8 carbon atoms, This aryl group substituted by an alkoxy group of 8 carbon atoms, or a combination thereof; a cycloalkyl group of 5 to 12 carbon atoms; a benzoyl group of 7 to 15 carbon atoms, or one to three functions on the benzene ring Element, alkyl group of i to 8 carbon atoms, alkoxy group of " " carbon atoms, or a combination thereof to replace 4 alkyl groups of 63 200412359, or straight or branched chain of 2 to 18 carbon atoms 浠I is as defined by R4; or rs is also hydrogen, or a straight or branched chain alkyl group of 1 to 24 carbon atoms, alkenyl group of 2 to 24 carbon atoms; or Rs is a group of the following formula ... T is hydrogen, oxy, hydroxy, -0Tl, an alkyl group of i to 24 carbon atoms, the alkyl group substituted by one to three hydroxyl groups; benzyl or alkanoyl group of 2 to 18 carbon atoms; T! Is an alkyl group of 1 to 24 carbon atoms, a cycloalkyl group of 5 to 12 carbon atoms, an alkenyl group of 2 to 24 carbon atoms, a cycloalkenyl group of 5 to 12 carbon atoms, 7 to 15 carbon atoms Phenyl groups, groups of saturated or unsaturated bicyclic or tricyclic hydrocarbons of 7 to 12 carbon atoms, or aryl groups of 6 to 10 carbon atoms, or via one to three 1 to 4 carbon atoms The aryl group substituted by an alkyl group; I fluorene, a linear or branched alkyl group of 1 to 2 4 slave atoms or a cycloalkyl group of $ to 12 carbon atoms; or via one to four Oxy, glycidyloxy, furanoxy, -R4, -〇r5, -N (1-5) 2, -CDN (R5) 2, -COR5, -C00R5, -0C0R5, -0C0C (R5 ) = C (R5) 2, --c (R5) = CCOOR5, -CN, -NCO or 〇N > -J 2 64 200412359 or the alkyl group or cycloalkyl group substituted by them; or via one to four epoxy groups, -0-, -nr5-, -conr5-, -C00-, -0C0 -, -C0_, -C (R5) = C (R5) C00-, -0C0C (R5) = C (R5)-, -C (R5) = C (R5)-, phenylene or phenylene- G-phenylene (wherein G is -0-, -S-, -S02-, -CH]-or -C (CH3) 2-) or a combination thereof, the alkyl group or the cycloalkyl group; Or the alkyl group or the cycloalkyl group substituted and interrupted by a combination of the above groups; or R2 is -so2r3 or -cor6; R6 is a straight or branched chain alkyl group of 1 to 18 carbon atoms, 2 to 12 Straight or branched chain alkenyl of 1 carbon atom, phenoxy group, alkylamine group of 1 to 12 carbon atoms, arylamine group of 6 to 12 carbon atoms, -R7c00H or -NH-R8-NCO R7 is an alkylene, or phenylene group of 2 to 14 carbon atoms; Rs is an alkylene, phenylene, methylphenylene, diphenylmethane, or group of 2 to 24 carbon atoms: h and Ri are the same or different and are defined as h; R2 and R2 are the same or different and are defined as r2; X, X ', Y and Y' are the same or different and are as Definitions of X and Y; t is 0 to 9; L is a straight or branched chain alkylene group of 1 to 12 carbon atoms, 5 π Sanno J cycloalkylene group of 12 carbon atoms, or via cyclohexyl or Phenylene substituted or broken alkylene; or L is phenylarylene; or l is -S-, -S ~ ς 65 200412359 S-, -SO-, -SO ", -S0-E-SO -, -NH-CH2- or so-2-E-SO, CH9-NH-E- E is a radical group of 2 to 12 carbon atoms, a cycloalkyl group of 5 to i 2 carbon atoms, or a tertiary alkyl group interrupted or terminated by a cycloalkyl group of 5 to 12 carbon atoms, η is 2 , 3 or 4; In the case of η 疋 2, Q 疋 is a straight or branched alkylene group of 2 to 16 carbon atoms; or the alkylene group substituted by one to three hydroxyl groups; or via one to three -CH = CH- or -〇- and the alkylene group interrupted; or the alkylene group substituted and interrupted by a combination of the above groups; or Q is xylylene or a group _ CONH-Rs-NHCO- ^ -CH2CH (0H) CH20-R9-0CH2CH (0H) CH2-^-C0- R10-C〇- or-(CH2) m-COO_Rn_〇〇c_ (CH2V, where m is 1 to 3; or Q is OH 7 Rg is an alkylene group of 2 to 50 carbon atoms, or via one to ten 101, phenylene or group-phenylene-G-phenylene (where G is k,-S〇2 -, -CH2- or -C (CH3) 2-) and the alkylene group interrupted; 66 200412359 R1 alkylene group of 2 to 10 carbon atoms, or via one to four 101, -S- Or ~ CH = CH- and the alkylene group is interrupted; or Ri◦ is an alkylene group of 6 to 12 carbon atoms; Rii is an alkylene group of 2 to 20 carbon atoms, or via one to eight -〇1 And the interrupted alkylene; when η is 3, Q is a group — [(CH2) mCOO] 3-Ri2, where m is 1 to 3, and R12 is an alkanetriyl group of 3 to 12 carbon atoms (Alkanetriy1); when n is 4, 4 is a group [[((: 112) 1〇 (: 00] 4_1? 13, where 111 is 1 to 3 'and R14 is an alkane of 4 to 12 carbon atoms Four groups (alkanetetray1); 4 is a group of the formula: Z2 is a group of the formula: Where 67 200412359 r 1 and r 2 are each independently 0 or 1; and R14, R15, Ri6, Rl7, R18, Ri9, R20, R21, R22, and R23 are each independently hydrogen, hydroxyl, cyano, 1 to Alkyl group of 20 carbon atoms, alkoxyl group of 1 to 20 carbon atoms, phenylalkyl group of 7 to 15 carbon atoms, cycloalkyl group of 5 to 12 carbon atoms, ring of 5 to 12 carbon atoms Alkoxy, oxo, haloalkyl of 1 to 5 carbon atoms, thio, carboxyl, fluorenylamino of 2 to 12 carbon atoms, fluorenyl of 2 to 12 carbon atoms, 2 to 12 Carbon atom alkoxycarbonyl or aminocarbonyl; or phenyl groups to which r17 and Ri8 or r22 and r23 are connected together are cyclic groups interrupted by one to three -0- or -NR ". 5. The composition according to item 4 of the scope of the patent application, wherein the homotriazine UV absorber has formula (IV), where X and Y are the same or different, and are phenyl, or via one to two 1 to 6-carbon alkyl, halogen, hydroxy or phenyl to 2 carbon atoms substituted by phenyl; or X and γ are 4 or Z2; Ri is hydrogen, 1 to 24 carbon atoms straight Or branched alkyl, cycloalkyl of 5 to 2 carbon atoms, phenylalkyl or halogen of 7 to 15 carbon atoms; I is hydrogen, straight or branched alkyl of 1 to 24 carbon atoms, or A cycloalkyl group of 5 to i 2 carbon atoms; or the alkyl group or the cycloalkyl group substituted through one to three—, 10r5, one cORs, ~ OCOR5, or a combination thereof; or via one to three The alkyl or cyclofluorenyl group interrupted by one epoxy group, -0-, -C00-, -0C0- or -C0; h is an aryl group of 6 to 10 carbon atoms, or via one to three Halogen, an alkyl group of 1 to 8 carbon atoms, an alkoxy group of 1 to 8 carbon atoms, or a combination thereof 68 200412359; a cycloalkyl group of 5 to 12 carbon atoms; 7 to 15 carbons Atomic benzyl 'or the phenylalkyl substituted on the benzene ring via one to three carbon atoms, an alkyl group of 1 to 8 carbon atoms, an alkoxy group of 1 to 8 carbon atoms, or a combination thereof; Rs Is as defined by I; or Rs is also hydrogen, or a straight or branched bond of i to 24 carbon atoms; L is a group of the formula: Z2 is a group of the formula: `` 2 where q and r2 are each 1; and RU, R15, R16, R17, R18, R19, r20, r2i, r22, and r23 are each independently hydrogen, hydroxyl, cyano, 1 to 20 carbon atoms Group, i to 1 carbon atom alkoxy group, 7 to 15 carbon atom phenalkyl group, ^ to carbon atom cycloalkyl group, 5 to 2 carbon atom cycloalkoxy group, halo, & lt Haloalkyl, thio, carboxyl groups of 1 to 5 carbon atoms; Carbon atoms 69 200412359 fluorenylamino group, fluorenylamino group of 2 to 12 carbon atoms, or alkoxycarbonyl or aminocarbonyl group of 2 to 2 # atoms; ruler,, or the homo-triazine UV The absorbent has the formula (v), where: X is phenyl, naphthyl, or alkyl via one to three i to 6 carbon atoms, via nansin, via hydroxyl, or via alkoxy to 6 carbon atoms Or the phenyl group or the naphthyl group substituted through a mixture thereof; or X is z · or wherein the homo-triazine uv absorbent has formula (IX), wherein: 1 and X are each independently a phenyl group, or The phenyl substituted via an alkyl group of one to three i to 6 carbon atoms, via a halogen, via a hydroxyl group or via an alkoxy group of from 6 to 6 carbon atoms or via a mixture thereof; or x and γ are independently Zi or ζ2; and linear or branched alkylene of 1 to 12 carbon atoms, cycloalkylene of 5 to 2 carbon atoms, or alkylene substituted or interrupted by cyclohexyl or phenylene base. 6. The composition according to item 4 of the scope of patent application, wherein the homotriazine UV absorber has formula (Iv), where: X and Y are the same or different, and are phenyl, or via one to three 1 This phenyl substituted with an alkyl group of 6 to 6 carbon atoms; Z or B; Ri is hydrogen or a phenylalkyl group of 7 to 15 carbon atoms; h is hydrogen, a straight or branched chain of 1 to 18 carbon atoms Alkyl; or the alkyl substituted via one to two -R4, -0l-5 or a mixture thereof; or the alkyl terminated by one to eight -0 or -C00-; h is 6 to 10 Aryl groups of two carbon atoms; Chi 5 is hydrogen; 70 200412359 is a group of the formula: R 16 R 14 R 17 R 18 R 15 Γι ζ2 is a group of the formula Where q and r2 are each 1; and Rl4, Rl5, Rl6, Rl7, Rl8, Rl9, ft20, hi, R22, and ft23 are each hydrogen. 7. The composition according to item 4 of the scope of the patent application, wherein the homo-triazine UV absorber is selected from: (1) 2,4-bis (4-biphenyl) -6- (2-meryl- 4-octyloxyethanyloxyphenyl) -h-triazine; (2) 2-phenyl-4- [2-hydroxy-4- (3-second-butoxy-2-hydroxy (Propoxy) phenyl] -6- [2-Ethyl-4- (3-Second-pentyloxy-2-Ethylpropoxy) phenyl] -h-triazine; (3) 2, 4-bis (2, 4-dimethylphenyl) -6- [2-hydroxy-4- (3-benzyloxy 71 200412359 yl-2-mercaptopropoxy) phenyl] -me-tri-n-qin (4) 2,4-bis (2-hydroxy-4-n-butoxyphenyl) -6- (2,4-bis-n-butoxyphenyl) -me-triazine; (5 ) 2, 4-bis (2, 4-dimethylphenyl) -6- [2-hydroxy-4- (3-nonyloxy-2--ylpropyloxy) -5_α-cumyl]- Homo-triazine, where nonyloxy represents a mixture of octyloxy, nonyloxy and decoxy; (6) methylene-bis- {2, 4-bis (2, 4-dimethylphenyl) -6- [2-hydroxy-4- (3-butoxy-2-hydroxypropoxy) phenyl] -h-triazine}, in a ratio of 5: 4: 1 at 3 ·· 5 ', 5 : 5 'and 3: 3, Methylene Bridge Dimer Mix (7) 2, 4, 6-tris (2-hydroxy-4-isooctyloxycarbonyl isopropyloxyphenyl) -h-triazine; (8) 2, 4-bis (2, 4-dimethylphenyl) -6- (2-hydroxy-4-hexyloxy-5-α_cumyl) -mesa-triazine; (9) 2, 4-bis (2, 4-bis (Methylphenyl) -6- (2-hydroxy-4-octyloxyphenyl) -me-triamidine; (10) 2- (2, 4, 6-trimethylphenyl) -4, 6- Bis [2-hydroxy-4- (3-butoxy-2-hydroxypropoxy) phenyl] -h-triazine; (11) 2, 4, 6-tri [2-Ceryl-4- ( 3-Second-butoxy-2-hydroxypropoxy) phenyl] -me-tri-D-phenyl; (12) 4, 6-diphenyl-2- (4-hexyloxy-2-hydroxybenzene ) -Me-tri- (13) 2- (2-Cyclo-4- (2-ethylhexyl) oxyphenyl 4,6-bis (4-phenylphenyl) -1,3, 5 -Triazine. 72 200412359 • Composition according to item 1 of the scope of patent application, wherein the copper salt is a cuprous or copper salt of inorganic and organic acid. Ρ 9 · Composition according to item 1 of the scope of patent application, where copper is It is selected from the group consisting of chlorophosphonium, copper bromide, copper sulfide, vinegar: copper I), gasified copper (11), bromide steel (丨), copper nitrate (I 丨), knife L 酉 Wen Steel (11) and its mixture. ^ i〇. The composition according to item 1 of the scope of patent application, which is a fiber, a film, or a molded article. U. The composition according to item 1 of the scope of the patent application, wherein the homo-triazine UV absorber is based on a weight of about 0.1% by weight to about 2% of amidine. Here 12. The composition according to item 丨 of the patent application scope, wherein the copper salt is present at about 1 ppm to about 500 p 卯, based on polyamide. Sol 13. According to the scope of the patent application, the composition includes at least one other component selected from the group consisting of alkali metal compounds of higher fatty acids and alkali metal salts and alkaline earth metal salts. 14. A method of stabilizing a polyamide composition to combat the harmful effects of heat, light, and oxygen 'This method is white-knee-killing-incorporating an effective and stable amount of the following ingredients into the polyamide composition: The homo-triazine UV absorbs at least one of the fourth agent according to the scope of the patent application, and a copper salt, in which no carbon black is present. 15 · —The application of a combination of a triazine liver absorbent and a copper salt, 73 200412359, is used to stabilize polyamines that do not substantially contain carbon black. One, Schematic: None 74 200412359 柒, designated representative map: (a) The designated representative map in this case is: (none) map. (II) Brief description of the representative symbols of the components in this representative drawing: None 捌 If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention None 4