TR201821279A2 - Water-soluble multi-layer film at different times and temperatures - Google Patents
Water-soluble multi-layer film at different times and temperatures Download PDFInfo
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- TR201821279A2 TR201821279A2 TR2018/21279A TR201821279A TR201821279A2 TR 201821279 A2 TR201821279 A2 TR 201821279A2 TR 2018/21279 A TR2018/21279 A TR 2018/21279A TR 201821279 A TR201821279 A TR 201821279A TR 201821279 A2 TR201821279 A2 TR 201821279A2
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 83
- 239000000203 mixture Substances 0.000 claims abstract description 30
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 16
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 16
- -1 polytrimethylene Polymers 0.000 claims description 13
- 229920002334 Spandex Polymers 0.000 claims description 12
- 239000003599 detergent Substances 0.000 claims description 12
- 239000013543 active substance Substances 0.000 claims description 7
- 239000003752 hydrotrope Substances 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 238000004806 packaging method and process Methods 0.000 claims description 7
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 6
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 6
- 239000004327 boric acid Substances 0.000 claims description 6
- 239000001913 cellulose Substances 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 6
- 150000002500 ions Chemical class 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 5
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 5
- 239000002516 radical scavenger Substances 0.000 claims description 5
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 229920006316 polyvinylpyrrolidine Polymers 0.000 claims description 4
- 239000010410 layer Substances 0.000 description 33
- 238000004090 dissolution Methods 0.000 description 7
- 239000002775 capsule Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000002979 fabric softener Substances 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- JDRSMPFHFNXQRB-CMTNHCDUSA-N Decyl beta-D-threo-hexopyranoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)C(O)[C@H](O)C1O JDRSMPFHFNXQRB-CMTNHCDUSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- WGLDZLZWKPBBLK-UHFFFAOYSA-N aminomethyl dimethyl phosphate Chemical compound COP(=O)(OC)OCN WGLDZLZWKPBBLK-UHFFFAOYSA-N 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 229940073499 decyl glucoside Drugs 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 230000003165 hydrotropic effect Effects 0.000 description 1
- 238000005040 ion trap Methods 0.000 description 1
- 229920000831 ionic polymer Polymers 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229960000999 sodium citrate dihydrate Drugs 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Abstract
Buluş özellikle, bahsedilen katmanlardaki kompozisyonların farklı zaman ve sıcaklıklarda suya dağılmasını sağlamak üzere, en az 40 °C sıcaklıktaki sularda çözünen sıcak suda çözünebilir film katmanı (11) ve en fazla 30 °C sıcaklıktaki sularda çözünen soğuk suda çözünebilir film katmanı (12) içeren suda çözünebilir çok katmanlı film (10) ile ilgilidir.In particular, the invention is used in water containing hot water-soluble film layer (11) soluble in water at a temperature of at least 40 ° C and a cold water-soluble film layer (12) soluble in water at a temperature of up to 30 ° C, in order to disperse the compositions in said layers to water at different times and temperatures. It relates to the soluble multilayer film (10).
Description
TARIFNAME Farkli zaman ve sicakliklarda suda çözünebilir çok katmanli film Teknik Alan Bulus, toz/granüI/sivi formda deterjan, yumusatici vb. ev tipi bakim kompozisyonlarini konumlandirmak üzere, en az iki katmana sahip ambalajlarin üretiminde kullanilan, farkli zaman ve sicakliklarda suda çözünebilir çok katmanli film ile ilgilidir. DESCRIPTION Water-soluble multilayer film at different times and temperatures Technical Area The invention includes detergent, softener, etc. in powder/granular/liquid form. home care compositions used in the production of packages with at least two layers, to position It is about multi-layered film that can dissolve in water at time and temperature.
Bulus özellikle, bahsedilen katmanlardaki kompozisyonlarin farkli zaman ve sicakliklarda suya dagilmasini saglamak üzere, en az 40 °C sicakliktaki sularda çözünen sicak suda çözünebilir film katmani ve en fazla 30 °C sicakliktaki sularda çözünen soguk suda çözünebilir film katmani içeren suda çözünebilir çok katmanli film ile ilgilidir. In particular, the invention shows that the compositions in the said layers can be produced at different times and temperatures. dissolved in water with a temperature of at least 40 °C, to allow it to disperse into the water. soluble film layer and in cold water soluble in waters up to 30 °C relates to a water-soluble multilayer film containing a soluble film layer.
Teknigin Bilinen Durumu Suda çözünür polimerik filmler, yaygin olarak çamasir, bulasik deterjanlari gibi ev tipi bakim kompozisyonlarinin birakildigi sulu alana dagilmasini, çözülmesini ve dozlanmasini kolaylastirmak üzere ambalaj malzemeleri olarak kullanilmaktadir. Bahsedilen ambalajlar birden fazla keseye sahip kapsül formundadir ve tüketicinin kompozisyonu ölçme ihtiyacini ortadan kaldirirken dogru dozajlama yapmasini saglamaktadir. State of the Art Water-soluble polymeric films are widely used in household care products such as laundry, dishwashing detergents. dispersion, dissolution and dosing of the compositions in the aqueous area where they are deposited. It is used as packaging materials to facilitate Mentioned packaging It is in the form of capsules with multiple pouches and meets the consumer's need to measure the composition. while eliminating, it ensures correct dosing.
Mevcut teknikte kullanilan çözünebilir filmler yalnizca belirli bir sicakliga sahip suyla temas halinde direkt çözülerek içerisindeki maddeyi disari vermektedir. Kullanicilar suda çözünebilir film kapli deterjanlari kullanirken film tek bir sicaklikta ve tek seferde çözünmektedir. Soluble films used in the current art can only come into contact with water of a certain temperature. It dissolves directly and releases the substance inside. Users can dissolve in water When using film-coated detergents, the film dissolves at one temperature and in one go.
Piyasada bulunan çoklu sayida keseye sahip kapsüllerde, her bir kese içerisine konumlandirilan maddeler ambalajin tek seferde çözünmesiyle ayni anda suya dagilmaktadir. Dolayisiyla farkli zaman ve sicaklikta suda kullanilan yumusatici gibi ek malzemelerin deterjan kompozisyonu ile birlikte ayni kapsüle konumlandirilmasi söz konusu olmayip, kullanicinin el ile makinenin yumusatici kismina koymasi gerekmektedir. Tüm bunlarin yani sira, çözünme hizi ve malzeme yapisina bagli olarak su temasiyla eriyen film hizla yok olmamakta ve agregasyona sebep olmaktadir Teknigin bilinen durumunda konu ile ilgili olarak U85658977A numarali Amerikan patent basvurusuna rastlanilmistir. Bulus, sicak suda çözünür ve/veya dagilabilir, tek kullanimlik filmler, kumaslar ve ürünler ve bunlarin üretimi için reçine karisimlari ile ilgili olup, bahsedilen reçine %50-52 kismen hidrolize polivinil alkol, %35 polikaprolakton, %6-7 plastiklestirici, %3- sivi alifatik ester içermektedir. Bulusa konu filmin çözünme sicakligi 60 derecedir. In capsules with multiple pouches available in the market, each pouch positioned substances into the water at the same time as the packaging dissolves in one go. disperses. Therefore, additional additives such as softener used in water at different times and temperatures. the materials are placed in the same capsule with the detergent composition. not, the user has to manually put it on the softener part of the machine. All In addition to these, depending on the dissolution rate and material structure, the film melts with water contact. does not disappear rapidly and causes aggregation In the state of the art, the US patent number U85658977A is related to the subject. reference has been found. The invention is hot water soluble and/or dispersible, disposable relates to films, fabrics and products and resin mixtures for their manufacture, resin 50-52% partially hydrolyzed polyvinyl alcohol, 35% polycaprolactone, 6-7% plasticizer, 3%- Contains liquid aliphatic ester. The dissolution temperature of the inventive film is 60 degrees.
US4654395A numarali Amerikan patent basvurusunda, çamasir bakim katki maddelerinin için suda çözünür bir tasiyici açiklanmaktadir. Bulusa konu tasiyici, agirlikça %40-95 oraninda suda çözünmeyen yumusak monomer, %3-15 oraninda suda çözünür anyonik monemer, %0-25 oraninda suda çözünür non-iyonik monomer ve %0-40 oraninda suda çözünmeyen sert monomer içermektedir. Bahsedilen tasiyici, tek seferde 15-60 oC Söz konusu basvurularda bahsedilen suda çözünür tasiyicilar belli bir sicaklikta tek bir seferde çözünmektedir. In the American patent application numbered US4654395A, the use of laundry care additives A water-soluble carrier is disclosed for Inventive carrier, 40-95% by weight water-insoluble soft monomer, 3-15% water-soluble anionic monemer, 0-25% water soluble non-ionic monomer and 0-40% water Contains insoluble hard monomer. Said carrier, 15-60 oC in one go The water-soluble carriers mentioned in the aforementioned applications are a single substance at a certain temperature. dissolves at once.
Sonuç olarak yukarida bahsedilen olumsuzluklardan ve eksikliklerden dolayi, ilgili teknik alanda bir yenilik yapma ihtiyaci ortaya çikmistir. As a result, due to the above-mentioned disadvantages and shortcomings, the relevant technical There is a need for innovation in the field.
Bulusun Amaci Mevcut bulus, yukarida bahsedilen gereksinimleri karsilayan, tüm dezavantajlari ortadan kaldiran ve ilave bazi avantajlar getiren, farkli zaman ve sicakliklarda suda çözünebilir çok katmanli film ile ilgilidir. Purpose of the Invention The present invention satisfies the above-mentioned requirements, eliminates all disadvantages. soluble in water at different times and temperatures, which lifts and brings some additional advantages. It's about layered film.
Bulusun ana amaci, hem sicak hem de soguk suda çözünme özelligi gösteren çok katmanli polimer yapiya haiz suda çözünebilir film ortaya koymaktir. The main object of the invention is to create a multi-layered multilayer that is soluble in both hot and cold water. to produce a water-soluble film with a polymer structure.
Bulusun amaci, içerisinde çözündügü suya antibakteriyel özellik kazandiran bir suda çözünebilir film ortaya koymaktir. The aim of the invention is to produce a water solution that gives antibacterial properties to the water in which it is dissolved. to reveal soluble film.
Bulusun amaci, suda çözünebilir film yapisina hidrotroplar eklenmesi ile suda çözünürlügü arttirmaktir. The aim of the invention is to increase water solubility by adding hydrotropes to the water-soluble film structure. is to increase.
Bulusun amaci, suda çözünebilir film yapisina elastan eklenmesi ile söz konusu filme esneklik kazandirmaktir. The aim of the invention is to add elastane to the water-soluble film structure to the film in question. to give flexibility.
Bulusun amaci, sicak suda çözünen bir yarisi ile Ca+2 ve Mg+2 iyonlarini baglayici nitelikte bir film ortaya koymaktir. Böylelikle, suda çözünebilir film ayni zamanda su yumusatma özelligi de göstermektedir. The aim of the invention is to bind Ca+2 and Mg+2 ions with a half dissolved in hot water. movie reveal. Thus, the water-soluble film also has water softening properties. also shows.
Bulusun amaci, sahip oldugu soguk suda çözünen yarisina çamasir yumusatici konumlandirmaktir. Böylelikle, ayni ambalajda hem deterjan hem de çamasir yumusatici konumlandirilabilmektedir. The purpose of the invention is to produce a half-in-a-cold water-soluble fabric softener. is to position. Thus, both detergent and fabric softener in the same package. can be positioned.
Yukarida anlatilan amaçlarin yerine getirilmesi için bulus, toz/granül/sivi formda deterjan, yumusatici vb. gibi ev tipi bakim kompozisyonlarini konumlandirmak üzere, en az iki katmana sahip ambalajlarin üretiminde kullanilan suda çözünebilir çok katmanli film olup, özelligi; bahsedilen katmanlardaki kompozisyonlarin farkli zaman ve sicakliklarda suya dagilmasini saglamak üzere, en az 40 °C sicakliktaki sularda çözünen sicak suda çözünebilir film katmani ve en fazla 30 °C sicakliktaki sularda çözünen soguk suda çözünebilir film katmani içermektedir. To fulfill the above-described purposes, the invention includes detergent in powder/granule/liquid form, softener etc. to position home care compositions such as It is a water-soluble multi-layered film used in the production of multi-layered packages. feature; the compositions in the mentioned layers into the water at different times and temperatures. soluble in hot water, soluble in water with a temperature of at least 40 °C, to ensure dispersion film layer and cold water soluble film soluble in waters up to 30 °C contains the layer.
Yukarida anlatilan amaçlarin yerine getirilmesi için bulus, toz/granüI/sivi formda deterjan, yumusatici vb. gibi ev tipi bakim kompozisyonlarini konumlandirmak üzere, en az iki katmana sahip ambalajlarin üretiminde kullanilan suda çözünebilir çok katmanli filmin üretim yöntemi olup, özelligi; bahsedilen katmanlardaki kompozisyonlarin farkli zaman ve sicakliklarda suya dagilmasini saglamak üzere, 0 sicak suda çözünebilir film katmani elde etmek üzere, su, polivinil alkol, elastan, iyon tutucu, non-iyonik aktif madde ve hidrotropun reaktör içerisine alinarak karistirilmasi ve elde edilen karisimin kaliplanarak kurutulmasi, - soguk suda çözünebilir film katmani elde etmek üzere, su, polivinil alkol, polivinil pirolidin, oligomerik politrimetilen oksit, elastan, selüloz, borik asit ve kuarterner amonyum bilesiklerinin reaktör içerisine alinarak karistirilmasi ve elde edilen karisimin sicak suda çözünebilir film katmanindan daha kalin olacak sekilde kaliplanarak kurutulmasi, o elde edilen sicak suda çözünebilir film katmani ve soguk suda çözünebilir film katmaninin suda çözünür PVA film paketleme makinesinde birlestirilmesi, Bulusun yapisal ve karakteristik özellikleri ve tüm avantajlari asagida verilen detayli açiklama sayesinde daha net olarak anlasilacaktir ve bu nedenle degerlendirmenin de bu detayli açiklama göz önüne alinarak yapilmasi gerekmektedir. To fulfill the above-described purposes, the invention includes detergent in powder/granule/liquid form, softener etc. to position home care compositions such as Production of water-soluble multilayer film used in the production of multilayer packaging method, its feature is; the compositions in the mentioned layers at different times and in order to allow it to disperse into the water at high temperatures, To obtain 0 hot water soluble film layer, water, polyvinyl alcohol, elastane, ion mixing the scavenger, non-ionic active substance and hydrotrope into the reactor and drying the obtained mixture by molding, - water, polyvinyl alcohol, polyvinyl to obtain cold water soluble film layer pyrrolidine, oligomeric polytrimethylene oxide, elastane, cellulose, boric acid and quaternary mixing the ammonium compounds into the reactor and the mixture to be thicker than the hot water soluble film layer. molding and drying, o the resulting hot water soluble film layer and cold water soluble film assembling the layer in the water-soluble PVA film packaging machine, The structural and characteristic features of the invention and all its advantages are described in detail below. will be more clearly understood by means of must be made taking into account the description.
Bulusun Anlasilmasina Yardimci Olacak Sekiller Sekil-1: Bulus konusu farkli zaman ve sicakliklarda suda çözünebilir çok katmanli filmin tercih edilen yapilanmasina ait sematik görünümüdür. Çizimlerin mutlaka ölçeklendirilmesi gerekmemektedir ve mevcut bulusu anlamak için gerekli olmayan detaylar ihmal edilmis olabilmektedir. Bundan baska, en azindan büyük ölçüde özdes olan veya en azindan büyük ölçüde özdes islevleri olan elemanlar, ayni numara ile gösterilmektedir. Figures to Help Understand the Invention Figure-1: The subject of the invention is the water-soluble multilayer film at different times and temperatures. is the schematic view of the preferred configuration. Drawings do not necessarily need to be scaled and are necessary to understand the present invention. details may be neglected. Moreover, at least largely Elements that are identical, or at least substantially identical, are assigned the same number. is shown.
Parça Referanslarinin Açiklamasi . Suda çözünebilir çok katmanli film 11. Sicak suda çözünebilir film katmani 12. Soguk suda çözünebilir film katmani Bulusun Detayli Açiklamasi Bu detayli açiklamada, bulus konusu farkli zaman ve sicakliklarda suda çözünebilir çok katmanli film (10), sadece konunun daha iyi anlasilmasina yönelik olarak ve hiçbir sinirlayici etki olusturmayacak sekilde açiklanmaktadir. Description of Part References . water soluble multilayer film 11. Hot water soluble film layer 12. Cold water soluble film layer Detailed Description of the Invention In this detailed description, the subject of the invention is water soluble at different times and temperatures. layered film (10), only for better understanding of the subject and no limiting are explained in a way that has no effect.
Bulus, deterjan vb. gibi ev tipi bakim kompozisyonlarini konumlandirmak üzere, en az iki katmana sahip ambalajlarin üretiminde kullanilan ve bahsedilen katmanlardaki kompozisyonlarin farkli zaman ve sicakliklarda suya dagilmasini saglayan suda çözünebilir çok katmanli film (10) ile ilgilidir. Invention, detergent etc. to position home care compositions such as used in the production of packaging with layers and water-soluble, allowing the compositions to disperse into water at different times and temperatures relates to the multi-layer film 10.
Sicak suda Çözünebflfr film katmani (11) formülasvonu; Içerik Agirlikça Kullanilabilir Miktar (%) Polivinil alkol 5 - 20 Iyon tutucu 0,3-1 Non-iyonik aktif madde 0,1-1 Elastan 0,02-0,08 Hidrotrop 0,1-1 Su 65-80 Soguk suda Çözünebiiir film katmani (12) formülasvonu; Içerik Agirlikça Kullanilabilir Miktar (%) Polivinil alkol 20 - 45 Oligomerik politrimetilen oksit 2-5 Polivinil pirolidin 0,5 - 5 Elastan 0,02-0,08 Kuarterner amonyum bilesikleri 0,2-1 Selüloz 5-10 Borik Asit 1-5 Su 45-65 Polivinil alkol, söz konusu bulusun ana hammaddesidir. PVA sentetik bir polimer olup, suda çözünebilen esnek filmlerinin üretilmesinde kullanilmaktadir. Hot water Soluble film layer (11) formulation; Usable Amount by Weight of Content (%) Polyvinyl alcohol 5 - 20 Ion trap 0.3-1 Nonionic active ingredient 0.1-1 Elastane 0.02-0.08 Hydrotrope 0.1-1 water 65-80 Cold water Soluble film layer (12) formulation; Usable Amount by Weight of Content (%) Polyvinyl alcohol 20 - 45 Oligomeric polytrimethylene oxide 2-5 Polyvinyl pyrrolidine 0.5 - 5 Elastane 0.02-0.08 Quaternary ammonium compounds 0.2-1 Cellulose 5-10 Boric Acid 1-5 water 45-65 Polyvinyl alcohol is the main raw material of the present invention. PVA is a synthetic polymer. It is used in the production of soluble flexible films.
Su, homojen bir karisim elde etmek ve PVA”nin çözünüp film olusturabilmesi için kullanilmaktadir. Water is necessary to obtain a homogeneous mixture and to dissolve the PVA to form a film. is used.
Iyon tutucu, sudaki Ca+ ve Mg+ iyonlarini baglayarak su yumusatma etkisi göstermektedir. The ion scavenger has a water softening effect by binding the Ca+ and Mg+ ions in the water.
Etilendiamin tetraasetik asitin sodyum tuzu, sodyum glukonat, sodyum sitrat dihidrat, dietilen triamin penta asit, 1-hidroksi etilen-1, 1-difosf0nik asit, amino trimetil fosforik asit, sodyum poliakrilat, glukonik asit, sodyum karbonat, sodyum silikat, maleik asit/akrilik asit kopolimeri sodyum tuzu, alanine, N,N-bis(carboksimetiI)-trisodium salt maddeleri iyon tutucu olarak kullanilabilmektedir. Sodium salt of ethylenediamine tetraacetic acid, sodium gluconate, sodium citrate dihydrate, diethylene triamine penta acid, 1-hydroxy ethylene-1, 1-diphosphonic acid, amino trimethyl phosphoric acid, sodium polyacrylate, gluconic acid, sodium carbonate, sodium silicate, maleic acid/acrylic acid copolymer sodium salt, alanine, N,N-bis(carboxymethyl)-trisodium salts as ion-scavengers can be used.
Non-iyonik aktif madde, hem aktiflige katkida bulunmakta hem de içeriginde bulundugu katmanin çözünürken temizleme özelligi göstermesini saglamaktadir. Bulus tercih edilen yapilanmasinda 6 etoksile yag alkolleri non-iyonik aktif madde olarak kullanilmaktadir. Bunun yani sira, polietilen glikolün non-iyonik polimerii 7-etoksile poliglikol eter yag alkolü, alkol etoksilat ve alkil glukosit karisimi, Kaprilil i' desil glukozit, 8 ve 9 etoksile yag alkolleri, etilen oksit ve propilen oksit de non-iyonik aktif madde olarak kullanilabilmektedir. The non-ionic active substance both contributes to the activity and It allows the layer to show cleaning feature while it dissolves. Invention preferred 6 ethoxylated fatty alcohols are used as non-ionic active substance in its structuring. This as well as non-ionic polymer of polyethylene glycol 7-ethoxylated polyglycol ether fatty alcohol, alcohol mixture of ethoxylate and alkyl glucosides, Capryllyl i' decyl glucoside, 8 and 9 ethoxylated fatty alcohols, ethylene oxide and propylene oxide can also be used as non-ionic active substances.
Elastan, suda çözünebilir çok katmanli filme esneklik kazandirmaktir. Elastane is to give flexibility to the water-soluble multi-layer film.
Hidrotrop, Sicak suda çözünecek olan katmana çözünürlügü arttirmak, daha hizli çözünme saglamak için kullanilmaktadir. Bulusun tercih edilen yapilanmasinda kullanilan hidrotroplar, sodyum tolüen sülfonat, 6 etoksile alkollerdir. Hydrotrope, to increase the solubility to the layer that will dissolve in hot water, faster dissolution is used to provide. Hydrotropes used in the preferred embodiment of the invention, sodium toluene sulfonate is 6 ethoxylated alcohols.
Selüloz ve borik asit, soguk suda çözünen katmana daha geç çözünmesini saglamak ve filmin dayanikliligi arttirmak için kullanilmaktadir. Cellulose and boric acid dissolve into the cold water soluble layer later, and It is used to increase the durability of the film.
Kuarterner amonyum bilesikleri, dezenfektan özelligin saglanmasi amaciyla kullanilmaktadir. Quaternary ammonium compounds are used to provide disinfectant properties.
Oligomerik politrimetilen oksit, politrimetilen oksitin yalnizca Oligomerik yapilari suda çözünür durumda olup, uzun zincirli politrimetilen oksitler suda çözünmemektedir. Oligomerik politrimetilen oksit, hem geç çözünmeyi saglamak adina hem de direnci arttirmak üzere kullanilmaktadir. Oligomeric polytrimethylene oxide, only Oligomeric structures of polytrimethylene oxide are water soluble long-chain polytrimethylene oxides are insoluble in water. oligomeric polytrimethylene oxide is used both to provide late dissolution and to increase resistance. is used.
Polivinil pirolidin, polivinil alkol ile karistirilarak geç çözünme saglamaktadir. Ayni zamanda çözünme direncini arttirmaktadir. Polyvinyl pyrrolidine provides late dissolution by mixing with polyvinyl alcohol. At the same time increases the dissolution resistance.
Bulus konusu farkli zaman ve sicakliklarda suda cözünebilir çok katmanli filmin (10) Üretim yontemi; - Su, polivinil alkol, elastan, iyon tutucu, non-iyonik aktif madde ve hidrotrop reaktör içerisine alinir, 80-90 °C'de 3,5 saat süreyle karistirilir ve akabinde elde edilen karisim kaliplanarak 23 saat süreyle 60-65 °C`de kurutularak sicak suda çözünebilir 0 Su, polivinil alkol, polivinil pirolidin, oligomerik politrimetilen oksit, elastan, selüloz, borik asit ve kuarterner amonyum bilesikleri reaktör içerisine alinir, 80-90 °C'de 3,5 saat süreyle karistirilir ve akabinde elde edilen karisim sicak suda çözünebilir film katmanindan (11) daha kalin olacak sekilde kaliplanarak 23 saat süreyle 60-65 °C`de kurutularak soguk suda çözünebilir film katmani (12) elde edilir, 0 Elde edilen sicak suda çözünebilir film katmani (11) ve soguk suda çözünebilir film katmani (12), suda çözünür PVA film paketleme makinesinde birlestirilerek farkli zaman ve sicakliklarda suda çözünebilir çok katmanli film (10) elde edilir. The subject of the invention is the production of water-soluble multilayer film (10) at different times and temperatures. method; - Water, polyvinyl alcohol, elastane, ion scavenger, non-ionic active substance and hydrotropic reactor It is taken in, stirred at 80-90 °C for 3.5 hours and then the obtained The mixture can be molded and dried for 23 hours at 60-65 °C, soluble in hot water. 0 Water, polyvinyl alcohol, polyvinyl pyrrolidine, oligomeric polytrimethylene oxide, elastane, cellulose, boric acid and quaternary ammonium compounds are taken into the reactor, 3.5 at 80-90 °C. hours, and then the resulting mixture is hot water soluble film. It was molded to be thicker than the layer (11) and kept at 60-65 °C for 23 hours. by drying cold water soluble film layer (12) is obtained, 0 The resulting hot water soluble film layer (11) and cold water soluble film layer (12) is combined in the water-soluble PVA film packaging machine and A water-soluble multi-layered film (10) is obtained in time and temperatures.
Tozlgranüllsivi formda deterjan, yumusatici vb. gibi ev tipi bakim kompozisyonlari, film kaplama esnasinda olusturulan katmanlar içerisine doldurulmaktadir. Farkli zaman ve sicakliklarda suda çözünebilir çok katmanli film (10) entegre kesme sistemi sayesinde farkli boyut ve sekillerde olusturulabilmektedir. Detergent, softener etc. in powdered granular liquid form. household care compositions such as film The layers formed during the coating are filled into it. different time and The water-soluble multi-layer film (10) at different temperatures thanks to the integrated cutting system can be created in sizes and shapes.
Bulus konusu farkli zaman ve sicakliklarda suda çözünebilir çok katmanli filmin (10) sahip oldugu sicak suda çözünebilir film katmani (11) en az 40 °C sicakliktaki sularda çözünürken, soguk suda çözünebilir film katmani (12) en fazla 30 °C sicakliktaki sularda çözünmektedir. The subject of the invention is a water-soluble multilayer film (10) at different times and temperatures. While the hot water soluble film layer (11) is soluble in water with a temperature of at least 40 °C, The cold water soluble film layer (12) dissolves in water with a maximum temperature of 30 °C.
Sekil-1'de bulus konusu farkli zaman ve sicakliklarda suda çözünebilir çok katmanli filmin (10) tercih edilen yapilanmasina ait sematik görünümü verilmektedir. In Figure-1, the subject of the invention is the water-soluble multilayer film at different times and temperatures. (10) is given a schematic view of the preferred embodiment.
Bulusun tercih edilen yapilanmasinda, sicak suda çözünebilir film ile olusturulan sicak suda çözünebilir film katmani (11) içerisine ana yikamada kullanilan deterjan, soguk suda çözünebilir film ile olusturulan soguk suda çözünebilir film katmanina (12) durulama esnasinda kullanilan yumusatici konumlandirilmaktadir. In the preferred embodiment of the invention, the hot water formed by the hot water soluble film Detergent used in the main wash into the soluble film layer (11), in cold water rinsing to the soluble film layer (12) in cold water formed by the soluble film The softener used during the process is positioned.
Claims (7)
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