TR201607901T1 - Fertilizer products. - Google Patents
Fertilizer products. Download PDFInfo
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- TR201607901T1 TR201607901T1 TR2016/07901T TR201607901T TR201607901T1 TR 201607901 T1 TR201607901 T1 TR 201607901T1 TR 2016/07901 T TR2016/07901 T TR 2016/07901T TR 201607901 T TR201607901 T TR 201607901T TR 201607901 T1 TR201607901 T1 TR 201607901T1
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- Prior art keywords
- mixture
- fertilizer product
- total weight
- feature
- cellulose
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 58
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 56
- 239000000203 mixture Substances 0.000 claims abstract description 51
- 239000011593 sulfur Substances 0.000 claims abstract description 47
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 47
- 238000000034 method Methods 0.000 claims abstract description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229910001868 water Inorganic materials 0.000 claims abstract description 36
- 239000000126 substance Substances 0.000 claims abstract description 32
- 239000011230 binding agent Substances 0.000 claims abstract description 25
- 230000008569 process Effects 0.000 claims abstract description 19
- 239000004604 Blowing Agent Substances 0.000 claims abstract description 17
- 238000001035 drying Methods 0.000 claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 13
- 239000005648 plant growth regulator Substances 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 10
- 238000004898 kneading Methods 0.000 claims abstract description 3
- 239000002245 particle Substances 0.000 claims description 68
- 229910003480 inorganic solid Inorganic materials 0.000 claims description 22
- 241000196324 Embryophyta Species 0.000 claims description 17
- 229920002401 polyacrylamide Polymers 0.000 claims description 16
- 238000002360 preparation method Methods 0.000 claims description 16
- 230000008961 swelling Effects 0.000 claims description 16
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 14
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 14
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- IXORZMNAPKEEDV-OBDJNFEBSA-N gibberellin A3 Chemical class C([C@@]1(O)C(=C)C[C@@]2(C1)[C@H]1C(O)=O)C[C@H]2[C@]2(C=C[C@@H]3O)[C@H]1[C@]3(C)C(=O)O2 IXORZMNAPKEEDV-OBDJNFEBSA-N 0.000 claims description 13
- 239000008187 granular material Substances 0.000 claims description 13
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- IXORZMNAPKEEDV-UHFFFAOYSA-N gibberellic acid GA3 Natural products OC(=O)C1C2(C3)CC(=C)C3(O)CCC2C2(C=CC3O)C1C3(C)C(=O)O2 IXORZMNAPKEEDV-UHFFFAOYSA-N 0.000 claims description 11
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- -1 extrudates Substances 0.000 claims description 10
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- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 9
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- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 claims description 2
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- 230000001131 transforming effect Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000010803 wood ash Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
- C05F11/10—Fertilisers containing plant vitamins or hormones
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/12—Granules or flakes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Botany (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
Abstract
Bu bildiri, ilk karışım hazırlanması, harmanlama, karışımın hamur oluşturacak şekilde yoğrulması, hamurun şekilli maddeler oluşturacak şekilde işlemden geçirilmesi ve bu şekillerin anlatılan gübre ürününü oluşturacak şekilde kurutulmasını içeren bir süreç ile ilgilidir. Bu bildirimde açıklanan gübre ürünü, element biçiminde sülfür, en az bir şişirme maddesi, en az bir bağlama maddesi, en az bir bitki büyüme regülatörü ve isteğe bağlı olarak en az bir inorganik madde ve su içermektedir.This notice is about a process that involves preparing the first mixture, blending, kneading the mixture to form dough, processing the dough to form shaped materials and drying these figures to form the described fertilizer product. The fertilizer product disclosed in this disclosure comprises sulfur in elemental form, at least one blowing agent, at least one binding agent, at least one plant growth regulator, and optionally at least one inorganic substance and water.
Description
TARIFNAME GÜBRE ÜRÜNLERI Teknik Alan Bu bildirim, gübre ürünleri ve bu ürünlerin hazirlik süreci ile ilgilidir. Bu bildirim, temel olarak sülfür bazli gübre ürünleri ile ilgilidir. DESCRIPTION FERTILIZER PRODUCTS Technical Area This notification is about fertilizer products and the preparation process of these products. This notice is basic as regards sulfur-based fertilizer products.
Teknigin Bilinen Durumu Gübreler, bitkilere büyümeleri için gerekli besin maddelerini haricen saglamak üzere uygulanan yardimci kimyasallardir. Gübreler inorganik veya organik nitelikte olabilir ve genellikle kati, granül veya toz, sivi, yari sivi ve aerosol biçimlerde sunulur.State of the Art Fertilizers are used to externally supply plants with the nutrients necessary for their growth. used auxiliary chemicals. Fertilizers can be inorganic or organic. and is generally available in solid, granular or powdered, liquid, semi-liquid and aerosol forms.
Gübreler, hayvan diskisi, yarasa diskisi, bitkisel gübre, turba yapan yosun, odun külü, azot, fosfor ve potasyum, kalsiyum, sülfür, demir, çinko ve magnezyum gibi birçok farkli madde içerir. Fertilizers, animal disc, bat disc, vegetable manure, peat moss, wood ash, nitrogen, phosphorus and potassium, calcium, sulfur, iron, zinc and magnesium contains many different substances.
Sülfür, bitkilerin büyümesi açisindan önemi büyük bir maddedir ve bitkilere gübre araciligiyla, element biçiminde ya da sülfat (8042') gibi inorganik biçimlerde saglanabilir. Bitkiler, ayni zamanda atmosferdeki sülfür dioksiti (802) de kullanabilir.Sulfur is an important substance for the growth of plants and it is a fertilizer for plants. in elemental form or in inorganic forms such as sulfate (8042') can be provided. Plants can also use sulfur dioxide (802) in the atmosphere.
Element halinde sülfür, yalnizca nem/su bulunan ortamlarda, topraktaki Thiobacillus adi verilen bakteriler araciligiyla sülfat olusturacak sekilde oksitlendikten sonra bitkiler tarafindan emilebilir. Ayrica, element halinde sülfür suda çözünmez ve toz formunda kullanildiginda gözleri tahris eden ve sagliga zararli bir toza dönüsür.Elemental sulfur is found only in moisture/water environments, Thiobacillus in soil After being oxidized to form sulphate by bacteria called can be absorbed by plants. In addition, elemental sulfur is insoluble in water and powder When used in its form, it turns into a powder that irritates the eyes and is harmful to health.
Ayrica, kullanilmayan sülfürün yagmur veya sulama sirasinda, suyla birlikte akarak suyu kontamine etmesi de olasidir. Bu nedenle, gübre ürünleri genellikle element halinde sülfürün toprak katki maddesi olarak kullanilan kil minerali gibi tasiyici maddelerle karistirilmasiyla hazirlanir. Ancak kil minerali, demir, nikel ve benzeri agir metallerin topraga karismasina neden olabilir. Kil minerali, ayni zamanda topragin salinitesinin artmasina yol açacak sekilde yüksek düzeyde sodyum içerir. Dahasi, kil mineralinin nem emme ve parçalanma kapasitesi düsüktür; bu nedenle topraktaki sülfürün kullanilabilirligi ve gerekli sülfat formune dönüstürülebilirligi de daha düsük Bu baglamda, geleneksel sülfür içerikli gübrelerle iliskili sorunlari ortadan kaldiran, element halinde sülfür içeren etkili bir gübre ürünü gelistirilmesi yönünde bir ihtiyaç mevcuttur. In addition, unused sulfur may run off with water during rain or irrigation. It is also possible to contaminate the water. For this reason, fertilizer products are often elemental. as a clay mineral used as a soil additive for sulphur. It is prepared by mixing with ingredients. However, clay mineral, iron, nickel and similar heavy may cause metals to leach into the soil. Clay mineral, also soil It contains high levels of sodium, which leads to increased salinity. Moreover, clay the moisture absorption and disintegration capacity of the mineral is low; therefore in the ground The availability of sulfur and its convertibility to the required sulfate form are also lower. In this context, eliminating the problems associated with traditional sulfur-containing fertilizers, There is a need to develop an effective fertilizer product containing elemental sulfur. available.
Bulusun Kisa Açiklamasi En az bir somut öge içerecek sekilde uyarlanmis olan bu bildirimin bazi hedefleri asagida siralanmistir: Bu bildirimin bir hedefi, bir gübre ürünü için bir hazirlik süreci tanimlamaktir. Brief Description of the Invention Some of the objectives of this statement, adapted to include at least one concrete element, are as follows: are listed: One objective of this notice is to define a preparation process for a fertilizer product.
Bu bildirimin bir diger hedefi de yukarida bahsi geçen süreç kullanilarak hazirlanmis bir gübre ürünü sunmaktir. Another objective of this notice is to provide a report prepared using the above-mentioned process. to provide a fertilizer product.
Bu bildirimin baska bir hedefi de kullanici için tehlike yaratmayan bir gübre ürünü sunmaktadir. Another objective of this notice is to produce a fertilizer product that does not pose a hazard to the user. offers.
Bu bildirimin hedeflerinden biri, ekonomik, biyolojik olarak bozunan, kullanimi kolay ve çevre dostu bir gübre ürünü sunmaktir. One of the objectives of this statement is to be economical, biodegradable, easy to use and to offer an environmentally friendly fertilizer product.
Bu bildirimin hedeflerinden bir digeri de demir ve nikel gibi agir metallerden arindirilmis bir gübre ürünü sunmaktir. Another of the objectives of this notification is the removal of heavy metals such as iron and nickel. to offer a fertilizer product.
Bu bildirimin bir diger hedefi toprak salinitesinin artmasini önlemek üzere düsük sodyum içerikli bir gübre ürünü sunmaktir. Another goal of this statement is low sodium to prevent increased soil salinity. To offer a fertilizer product with ingredients.
Bu bildirimin baska bir hedefi, daha önceki yöntemlerin neden oldugu sorunlardan biri veya daha fazlasinda iyilesme saglamak ya da en azindan faydali bir alternatif sunmaktir. Another target of this notice is one of the problems caused by previous methods or more, or at least a useful alternative is to present.
Bu bildirimin diger hedef ve avantajlari, bildirim kapsamini sinirlama amaci tasimayan asagidaki açiklama ile çok daha açik bir sekilde ortaya çikacaktir.The other objectives and advantages of this notice are not intended to limit the scope of the notice. It will be revealed much more clearly with the following explanation.
Bu bildirim, element halinde sülfür, en az bir sisirme maddesi, en az bir baglama maddesi, en az bir bitki büyümesi regülatörü, istege bagli olarak 15 ila 40 °C arasi sicaklikta en az bir sulu inorganik kati maddenin karistirilmasi yoluyla bir ilk karisim hazirlanmasi, bu ilk karisimin hamur olusturacak sekilde harmanlanmasi ve yogurulmasi, bahsi geçen hamurun isleme alinarak sekilli maddelere dönüstürülmesi, bahsi geçen sekillerin gübre ürünü olusturacak sekilde kurutulmasini içeren bir gübre ürünü hazirlik süreci sunmaktadir. Tipik olarak, bahsi geçen isleme alma adimi peletleme, pastilleme, ekstrüze etme ve granül haline getirme süreçlerinden en az birini ve bahsi geçen sekilli madde de pelet, pastil, ekstrüdat, tanecik, pul ve granül seçeneklerinden en az birini içerecektir. Bu bildirime göre, gübre ürünü, %0,1 ile 1,0 arasinda degisen nem içerigi ile karakterize edilmektedir. This declaration includes elemental sulfur, at least one blowing agent, at least one bonding agent. substance, at least one plant growth regulator, optionally between 15 and 40 °C A first mix by mixing at least one aqueous inorganic solid at a temperature preparation, blending this first mixture to form dough and kneading, processing the mentioned dough and transforming it into shaped materials, a fertilizer that involves drying the aforementioned shapes to form a fertilizer product. presents the product preparation process. Typically, said processing step at least one of the processes of pelleting, lozenge, extruding and granulating and said shaped material is also pellets, lozenges, extrudates, granules, flakes and granules. will contain at least one of the options. According to this notification, the fertilizer product is between 0.1% and 1.0%. It is characterized by varying moisture content between
Bulusun Detayli Açiklamasi Bu bildirimin bir amaci baglaminda, bir gübre ürününün hazirlanmasi için bir süreç sunulmustur. Süreç temel olarak malzemelerin önceden belirlenmis miktarda, 15 ila 40 0(3 sicaklik arasinda su içinde karistirilmasi yoluyla bir ilk karisim hazirlanmasini içerir.Detailed Description of the Invention For one purpose of this notice, a process for the preparation of a fertilizer product has been presented. The process basically consists of a predetermined amount of materials, 15 to 40 It includes the preparation of a first mix by mixing in water between 0(3 temperatures).
Tipik olarak, karisimin hazirlanmasi için kullanilan malzemeler, karisimin toplam agirliginin %70'i ile 98'i arasinda degisen miktarda element halinde mikronize sülfür, karisimin toplam agirliginin %O,1'i ila %10'u arasinda degisen miktarda en az bir sisirme maddesi, karisimin toplam agirliginin %0,5`i ila %30'u arasinda degisen miktarda en az bir baglama maddesi, karisimin toplam agirliginin %0,005'i ila %5'i arasinda degisen miktarda en az bir bitki büyütme regülatörü ve istege bagli olarak karisimin toplam agirliginin %O'i ila %30'u arasinda degisen miktarda en az bir inorganik kati madde içerir. Su gereksinimlere uygun sekilde kullanilir ve tipi olarak karisimin toplam agirliginin %5'i ila %40'i arasinda degisen miktarda haricen eklenir. Bu bildirimin karakteristik bir özelligi, hem sisirme hem baglama maddelerinin eklenmesi ile ortam sicakliginda karisim yapma olanagi sunmasidir; bu özellik, isleme alma ve kullanimi büyük oranda kolaylastirir ve sürecin maliyetini azaltir. Typically, the materials used for the preparation of the mixture, the total Micronized sulfide in the form of elements ranging from 70% to 98% by weight, at least one in an amount ranging from 0.1% to 10% of the total weight of the mixture blowing agent, ranging from 0.5% to 30% of the total weight of the mixture amount of at least one binding agent, 0.005% to 5% of the total weight of the mixture at least one plant growth regulator and optionally at least one in an amount ranging from 0% to 30% of the total weight of the mixture Contains inorganic solids. The water is used in accordance with the requirements and according to its type. It is added externally in an amount varying between 5% and 40% of the total weight of the mixture. This A characteristic feature of the notification is the addition of both inflation and binding agents. it offers the opportunity to mix at ambient temperature; this feature, processing and greatly simplifies the use and reduces the cost of the process.
Bir somut gösterimde, ilk karisimin hazirlik adimi, karisimin toplam agirliginin %1 ila 'u arasi oranda en az bir inorganik kati madde, karisimin toplam agirliginin %0,5 ila 'u arasi oranda en az bir baglama maddesi, karisimin toplam agirliginin %70 ila 98'i arasi oranda sivi erimis sülfürün bir araya getirilmesinden olusmaktadir. Bu adim, 119 ile 140 0C arasi degisen bir sicaklikta uygulanmis ve inorganik kati maddenin erimis sülfüre tamamen dagilmasi için ilk karisimin karistirilmasi da sürece dahil edilmistir. In a concrete demonstration, the preparation step of the first mix is 1% to 1% of the total weight of the mix. at least one inorganic solid in a proportion of 0.5 to 0.5% of the total weight of the mixture at least one binder, 70 to 98% of the total weight of the mixture It consists of bringing together liquid molten sulfur in a ratio of . This step is 119 It was applied at a temperature ranging from 0 to 140 0C and the inorganic solid material was melted. The mixing of the first mixture is also included in the process so that it is completely dispersed into the sulfur.
Sonuç olarak ortaya çikan karisim harmanlanmis ve hamur haline gelene kadar yogrulmus ve bu hamur da sekilli madde Üretimi için islemden geçirilmistir. kazandirilmasi ve karisimin diger islemler için uygun bir hale getirilmesini içerir. Sekilli maddeler 25 ila 50°C arasi sicaklikta kurutulduktan sonra bu bildirimde açiklanan gübre ürünü açiga çikar. Tipik olarak, isleme alma adimi peletleme, pastilleme, ekstrüze etme ve granül haline getirme süreçlerinden en az birini ve sekilli madde de pelet, pastil, ekstrüdat, tanecik, pul ve granül seçeneklerinden en az birini içerecektir. The resulting mixture is blended and mixed until it becomes dough. kneaded and this dough is also processed for the Production of Shaped Matter. and making the mixture suitable for other processes. shaped After the materials have been dried at a temperature between 25 and 50°C, the fertilizer described in this notification reveal the product. Typically, the processing step is pelletizing, lozenges, extruding. and at least one of the granulation processes, and the shaped substance is pellets, lozenges, extrudate shall contain at least one of the choices of granules, flakes and granules.
Bu bildirimin yukaridaki açiklanan süreci bazi belirli amaçlara ulasmayi hedeflemek için tasarlanmistir. Peletleme, pastilleme, ekstrüze etme ve granül haline getirme islem adimlari, makromoleküler boyutlarda birimlerden (sekilli maddeler) olusan bir gübre ürünü olusturmak için kasti olarak sürece dahil edilmistir. Bu, bu bildirimde açiklanan ürünün özel bir islevidir ve bu islev, sülfür tozu ile iliskili sorunlarin ortadan kaldirilmasi, su tutma kapasitesinin artirilmasi ve potasyum, azot, su ve bitki büyüme regülatörlerinin topraga saliminin yavaslatilmasi gibi birçok avantaj ile iliskilidir ve bu sekilde ürünü tarim ve bahçivanlik uygulamalarinda kullanim için oldukça uygun bir hale getirmektedir. Ayrica, üründe kullanilan ana malzemelerden bazilari isiya karsi hassastir ve hazirlik sürecinde ( yüksek sicakliklara maruz kalmasi durumunda bozunabilir. Bu nedenle, açiklanan süreç gibi ortam sicakliklarina yürütülebilecek süreçler daha fazla tercih edilmektedir. The above-described process of this notice is intended to achieve certain specific purposes. is designed. Pelletizing, lozenge, extruding and granulating process a fertilizer consisting of macromolecular sized units (shaped substances) deliberately included in the process to create the product. This is described in this notice is a special function of the product, and this function is to eliminate the problems associated with sulfur dust, increasing the water holding capacity and improving the potassium, nitrogen, water and plant growth regulators. It is associated with many advantages such as slowing the release to the soil and in this way the product making it very suitable for use in agricultural and horticultural applications. brings. In addition, some of the main materials used in the product are heat resistant. sensitive and exposed to high temperatures during preparation ( may degrade. Therefore, depending on ambient temperatures, such as the process described processes that can be carried out are more preferred.
Bir diger açidan, bu bildirim, bahsi geçen süreç kullanilarak hazirlanmis bir gübre ürünü sunmaktir. Ürün, 1,5 ila 6 mm arasi büyüklüklerde degisen pelet, pastil, ekstrüdat, tanecik, pul ve granül seçeneklerini içeren gruptan seçili sekilli maddeleri içerir. Tipik olarak, gübre ürününün nem içerigi %0,1 ile 1,0 arasinda degismektedir. Ürün, burada asagida verilen maddeleri içerir. On the other hand, this notice is a fertilizer product prepared using the aforementioned process. is to present. The product consists of pellets, lozenges, extrudates, varying in size from 1.5 to 6 mm. contains selected shaped substances from the group consisting of granules, flakes and granules. Typical As a result, the moisture content of the fertilizer product varies between 0.1% and 1.0%. The product is here Contains the following items.
Mikronize element halinde sülfür, ilk karisimin %70'i ila 98'i oraninda, tercihen %87'si ila 98'i oraninda karisima dahil edilir. Bitkiler için oldukça önemli bir besin maddesi olan sülfür, birçok farkli faaliyet sergiler. Sülfür, gerekli bitki besin maddelerinin toprakta bulunabilirligini artirir, bu da tarimsal mahsullerin kalitesi ve verimini iyilestirir. Ayrica, sülfür, sülfür içere aminoasitler ve proteinler, koenzim A, biyotin, tiyamin, glutation, kIorofiI, Iipitler ve uçucu yaglar gibi sülfür içeren birimlerin sentezi için gerekli bir elementtir. Dahasi, element biçiminde sülfür, topraktaki hasere ve mikro-organizmalara karsi bir hasere ve mantar ilaci olarak görev görür. Bu ürüne dahil edilen sülfürün parçacik boyutu 10 um ila 250 um arasindadir. Bir somut örnekte, yag rafinerisinde hidrojenle kükürt giderme sonrasinda Claus prosesi ile elde edilen sonuca göre element biçiminde sülfürün saflik degeri %99'un üzerindedir. Ürün, ilk karisimin toplam agirliginin %0,1'i ila %10'u, tercihen %1 ila 10'u arasinda, poliakrilik asit, poliakrilamit polimer, selüloz asilanmis poliakrilamit polimer, selüloz asilanmis poliakrilamit ve nisasta asilanmis poliakrilamitin potasyum tuzunu içeren gruptan en az birini içeren en az bir sisirme maddesi içerir. Sisirme maddesinin islevi, gübre ürünü topraga katildiktan sonra sulama suyu ve çökelmis atmosfer nemi gibi toprak alani çevresindeki suyu emmektir. Suyun emilmesi sonrasinda, ürün peletlerin, ekstrüdatlarin ve benzerlerin bitki büyüme regülatörleri gibi diger maddeler ile birlikte oldukça genis bir alana yayilacak sekilde parçalara ayrilmasina yol açacak sekilde genisler. Bir somut örnekte, sisme sonrasinda gübre ürününde mevcut bulunan element halindeki sülfür, 30 um'den küçük Çapta parçaciklara ayrilmistir. Sülfür parçaciklarinin boyutlarinda küçülme saglanmasi, sülfat biçiminde kolaylikla okside olmalarini saglar. Micronized elemental sulfur, 70% to 98%, preferably 87% to 98% of the initial mixture 98 percent of it is included in the mixture. An essential nutrient for plants sulfur exhibits many different activities. Sulfur provides essential plant nutrients in the soil. increases its availability, which improves the quality and yield of agricultural crops. Moreover, sulfur, amino acids and proteins containing sulfur, coenzyme A, biotin, thiamine, glutathione, Chlorophyll is an essential component for the synthesis of sulfur-containing units such as lipids and essential oils. element. Moreover, sulfur in elemental form is harmful to soil damage and micro-organisms. acts as an anti-insect and fungicide. Sulfur contained in this product particle size is from 10 µm to 250 µm. In one concrete example, at the oil refinery element according to the result obtained by the Claus process after desulfurization with hydrogen In the form of sulfur, the purity value is over 99%. The product is 0.1% to 10%, preferably 1 to 10%, of the total weight of the first mix, polyacrylic acid, polyacrylamide polymer, cellulose acylated polyacrylamide polymer, cellulose containing the potassium salt of grafted polyacrylamide and starch grafted polyacrylamide comprising at least one inflation agent comprising at least one of the group. The function of the inflation agent, such as irrigation water and precipitated atmospheric moisture after the fertilizer product is incorporated into the soil. soil area is to absorb water around it. After absorbing the water, the product pellets, together with other substances such as plant growth regulators of extrudates and the like in such a way as to cause it to disintegrate into pieces that will spread over a fairly large area. they expand. In one embodiment, the element present in the fertilizer product after swelling The sulfur in the form of sulphide is divided into particles smaller than 30 µm in diameter. sulfur particles Reducing their size allows them to be easily oxidized in the form of sulfates.
Sülfür içerigi yüksek, sisirme maddesi içerigi düsük gübre ürünlerinin salinitesi ve su içerigi yüksek topraklarda uygulanabilirliginin yüksek oldugunu belirtmek gerekir. Bunun nedeni, sisirme maddesi içeriginin az olmasinin su tutma kapasitesini de azaltmasidir; bu da su içerigi yüksek topraklar için kabul edilebilir bir durumdur. Benzer sekilde, sülfür içerigi düsük ve sisirme maddesi içerigi yüksek gübre ürünlerinin su tutma kapasitesi yüksektir ve bunlar su açisindan kurak bölgelerde kullanima uygundur. The salinity and water content of fertilizer products with high sulfur content and low blowing agent content It should be noted that its applicability is high in soils with high content. This this is because the low blowing agent content also reduces the water holding capacity; This is acceptable for soils with high water content. Similarly, sulfur Water holding capacity of fertilizer products with low content and high blowing agent content high and they are suitable for use in arid regions in terms of water.
Mikronize element halinde sülfür ve diger maddelerin birbirine baglanarak estetik ve tek tip bir gübre ürünü olusturmasini kolaylastirmak için ürüne baglama maddeleri ilave edilmistir. Bu bildirimde bahsi geçen ürün, ilk karisimin toplam agirliginin %0,5'i ila 30'u arasi, tercihen %1 ila 13'ü arasinda miktarda, karboksimetil selüloz, metil selüloz, etil selüloz, hidroksimetil selüloz, hidroksietil selüloz, hidroksipropilmetil selüloz, hidroksietilpropil selüloz, misir nisastasi, patates nisastasi, nisasta asetatlari, iyonik nisastalar, polivinil alkol, polivinil asetat, polietilen glikol ve polilaktik asit grubundan en az birini içeren bir baglama maddesi içermektedir. Micronized elemental sulfur and other substances are bonded to each other for aesthetic and uniqueness. Binding agents are added to the product to facilitate the formation of a type of fertilizer product. has been made. The product referred to in this statement is 0.5% to 30% of the total weight of the first mix between, preferably 1 to 13%, carboxymethyl cellulose, methyl cellulose, ethyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropylmethyl cellulose, hydroxyethylpropyl cellulose, corn starch, potato starch, starch acetates, ionic starches, polyvinyl alcohol, polyvinyl acetate, polyethylene glycol and polylactic acid group a binding agent containing at least one.
Bu bildirimde bahsi geçen ürün, ilk karisimin toplam agirliginin %0,005'i ila %5'i, tercihen %0,005 ila 1'i arasi oranda, oksinler, gibberelinler, sitokininler ve absisik asitteri (ABA) en az birini içeren en az bir bitki büyüme regülatörü içerir. Daha da ayrintili olarak, bitki büyüme regülatörü, indol-3-asetik asit (lAA), gibberelik asit(GA) ve 6-benzil adenin (BA) grubundan en az birini içerir. The product referred to in this notification is 0.005% to 5% of the total weight of the first mix, preferably 0.005% to 1% of auxins, gibberellins, cytokinins and abscisic acids (ABA) includes at least one plant growth regulator. even more detailed As a plant growth regulator, indole-3-acetic acid (lAA), gibberellic acid (GA) and 6-benzyl contains at least one of the adenine (BA) group.
Bu bildirimde açiklanan ürün, ilk karisimin %0 ila 30'u, tercihen %0 ila 10'u arasi oranda en az bir inorganik kati madde içerir. Inorganik kati madde, zeolitler, killer, alüminosilkatlar ve moleküler elek grubundan, daha ayrintili olarak da zeolit A, zeolit X, ZSM-5, klinoptilolit, filipsit, alüminyum fosfat (AIPO4) zeolitler, silikon alüminyum fosfat (SAPO4) zeolitler, montmorilonit, kaolinit, hectorit, atapulgit, mordenit, moleküler elek MS-SA, moleküler elek 4A ve harcanan sivi katalist çatlatma (FCC) katalisti grubundan en az birini içerir. Bir somut örnekte, bu bildirimde açiklanan ürün için inorganik kati madde nanogözenekli olarak seçilmistir. Bir somut örnekte, inorganik madde olarak hava kurutma ve petrokimyasal veya rafineri komplekslerinde solvent kurutma için kullanilan ve toz ya da granüler olarak kullanilabilen moleküler elekler kullanilmistir.The product described in this notice contains 0 to 30%, preferably 0 to 10%, of the first mix. contains at least one inorganic solid. Inorganic solids, zeolites, clays, from the group of aluminosilicates and molecular sieves, more specifically zeolite A, zeolite X, ZSM-5, clinoptilolite, philipsite, aluminum phosphate (AIPO4) zeolites, silicon aluminum phosphate (SAPO4) zeolites, montmorillonite, kaolinite, hectorite, attapulgite, mordenite, molecular sieve MS-SA, molecular sieve 4A and spent liquid catalyst cracking (FCC) catalyst group contains at least one. In one embodiment, the inorganic solid for the product described in this notice The material was chosen as nanoporous. In one embodiment, as inorganic matter for air drying and solvent drying in petrochemical or refinery complexes Molecular sieves are used which can be used as powder or granular.
Nanogözenekli inorganik katilar topraktaki agir metal iyonlarini tuttugundan bu katilarin kullanilmasi avantaj saglar; bu sekilde bitkilerde agir metal birikimi olmaz. Dahasi, çogu dogal zeolitin susuz durumda yüksek su emme kapasitesine sahip olmasi ve iyon degistirme kapasitesi sayesinde, bu maddeler etkili bitki ilaci, mantar ilaci ve böcek ilaci tasiyicilaridir. Ayrica, zeolitler, ayni zamanda toprak dokusunun degistirilmesinde de etkilidir; iyon degistirme kapasiteleri sayesinde topraktaki alkalinligi giderebilirler.Since nanoporous inorganic solids hold heavy metal ions in the soil, these solids its use is advantageous; In this way, heavy metal accumulation does not occur in plants. Moreover, most Natural zeolite has high water absorption capacity in the anhydrous state and ion Thanks to their modifying capacity, these substances are effective herbicides, fungicides and insecticides. are carriers. In addition, zeolites are also useful in changing soil texture. it is effective; Thanks to their ion exchange capacity, they can eliminate alkalinity in the soil.
Zeolitlerin toprak ile karistirilmasi, topragin neminin tutulmasina ve yeterli havalandirmanin saglanmasina yardimci olarak ekin verimini iyilestirir. Bu bildirimde bahsi geçen inorganik kati madde, emilen bitki besin maddelerini de içerir. Inorganik kati maddeler topraga salinmalarinin ardindan ekinlerin oldukça fayda saglayacagi sekilde besin maddelerini de topraga verir. Inorganik kati maddelerde bulunan bitki besin maddeleri, K, Mg, Ca, Fe, Mn, Mo, PO4, NHg, Zn, Cu, B, ve C0 grubundan en az biri olacaktir.Mixing zeolites with soil helps to retain soil moisture and provide adequate It improves crop yield by helping to provide aeration. In this notice said inorganic solid also includes absorbed plant nutrients. Inorganic crops will benefit greatly after the solids are released into the soil. In this way, it also gives nutrients to the soil. plant contained in inorganic solids nutrients, K, Mg, Ca, Fe, Mn, Mo, PO4, NHg, Zn, Cu, B, and C0 groups at least will be one.
Hamur olusumunun kolaylastirilmasi için ürüne su dahil edilmistir. Tipik olarak, su, ilk karisimin agirliginin %5'i ila 40'i, tercihen %10 ila 33'ü arasinda degisen miktarda olacaktir. Water is included in the product to facilitate dough formation. Typically, the first in an amount ranging from 5% to 40%, preferably 10 to 33% by weight of the mixture will be.
Bir somut örnekte, bu bildirimde açiklanan gübre ürünü, element halinde sülfür, en az bir sisirme maddesi, en az bir baglama maddesi, en az bir bitki büyüme regülatörü ve su içermektedir. Baska bir somut örnekte, bu bildirimde açiklanan gübre ürünü, element halinde sülfür, en az bir sisirme maddesi, en az bir baglama maddesi, en az bir bitki büyüme regülatörü, en az bir inorganik kati madde ve su içermektedir. In one embodiment, the fertilizer product described in this notice is elemental sulfur, containing at least a blowing agent, at least one binding agent, at least one plant growth regulator, and water. contains. In another embodiment, the fertilizer product described in this notice, element sulfur, at least one blowing agent, at least one binding agent, at least one plant The growth regulator contains at least one inorganic solid and water.
Bu bildirimde açiklanan gübre ürününün etkisi, pelet, pastil ve benzeri sekillerin hazirlanmasi ve su emme ilkesinin kullanilmasinda yatmaktadir. Sisirme maddeleri, suyun emilmesinin ardindan sekilli maddeleri büyük orada sisirerek oldukça küçük sülfür parçaciklarinin yayilmasini saglar. Küçük parçaciklarin oksidasyon orani büyük parçaciklardan daha yüksek oldugundan, bitkilere istenen biçimde daha fazla sülfür saglanir ve bu da bitkilerin kalite ve verimini iyilestirir. Ayrica, ürünün topraga yayilmasinin ardindan pH degeri 7,4 ila 8,5 arasinda degisir, bu da bitkiler, toprak ve topraktaki mikroplar için uygun bir degerdir. Bu bildirimde açiklanan gübre ürününde geleneksel ürünlerdeki gibi dolgu maddesi, surfaktanlar, islatma maddeleri ve benzerleri kullanilmaz. Malzemelerin karakteristik kombinasyonu, özellikle sisirme ve baglama maddelerinin bir arada kullanilmasi, gübre ürünlerinin ezilme dayanikliligi, sisirme ve dagilma indekslerinin en iyi düzeye çikarilmasini saglar. Tipik olarak, bu bildirimde açiklanan gübre ürününün mekanik kuvveti 1,5 ile 6 Kgf arasidir, bu da gerekli dispersiteye sahip toz içermeyen bir ürün imalati için gerekli orandir. The effect of the fertilizer product described in this notification is the effect of pellets, lozenges and similar forms. It lies in the preparation and use of the principle of water absorption. inflating agents, After absorbing the water, it swells the shaped materials into large, very small sulfur It allows the particles to spread. Small particles have a large oxidation rate Since it is higher than the particles, more sulfur is given to the plants as desired. is provided, which improves the quality and yield of plants. In addition, the product After spreading, the pH changes between 7.4 and 8.5, which means plants, soil and It is a suitable value for microbes in the soil. In the fertilizer product described in this notification fillers, surfactants, wetting agents and the like as in conventional products not used. Characteristic combination of materials, especially inflation and bonding combination of substances, crushing resistance of fertilizer products, swelling and It allows the dispersion indices to be maximized. Typically, this statement The mechanical strength of the described fertilizer product is between 1.5 and 6 Kgf, which is necessary It is the ratio required for the manufacture of a powder-free product with dispersion.
Bu bildirim, bu noktadan sonra sinirlama amaci tasimayan asagidaki somut örneklerin isiginda tartisilacaktir: Örnek 1: Gübre ürününün hazirlanmasi - Süreç Optimizasyonu Örnek 1A: Sülfür + Baglama maddesi selülöz ile karistirilmistir. Ilk karisimin olusturulmasi için kuru agirliga yeterli miktarda su eklenmistir. Ilk karisim harmanlanmis ve yogrulmus; sonuç olarak ortaya çikan hamur bir ekstrüder kullanilarak mekanik olarak 1,5 x 5 - 7 mm boyut araliginda (çap x uzunluk) ekstrüdatlara dönüstürülmüstür. Hamurun kalan yarisi, tava veya tamburlu granül olusturucu ile 3 ila 4 mm boyutlarda küresel parçaciklara ayrilmistir. Sonuç olarak olusan ekstrüdatlar ve küresel parçaciklar, kuru agirlik bazinda %0,5'ten az nem içerecek sekilde havada kurumaya birakilmistir. Olusturulan parçaciklari kurutma yöntemleri arasinda vakumlu veya mikrodalga isinli kurutma da yer almaktadir; ilgili konuda bilgi sahibi kisiler bu yöntemler konusunda bilgi sahibidir. This notice is hereinafter explained by the following concrete examples, which are not intended to be limiting. will be discussed in the light of: Example 1: Preparation of fertilizer product - Process Optimization Example 1A: Sulfur + Binding agent mixed with cellulose. Sufficient water per dry weight to form the first mix has been added. The first mixture is blended and kneaded; the resulting dough mechanically using an extruder in a size range of 1.5 x 5 - 7 mm (diameter x length) were converted into extrudates. Remaining half of dough, pan or drum It was divided into spherical particles of 3 to 4 mm in size with a granule generator. Conclusion extrudates and spherical particles, less than 0.5% moisture on a dry weight basis It was left to dry in air. Drying the formed particles Methods include vacuum or microwave drying; relating to Those who are knowledgeable on the subject are knowledgeable about these methods.
Olusturulan ekstrüdatlar ve parçaciklarin sisme ve dagilma özellikleri, olusturulan ekstrüdatlardan 10 ml'lik bir kismin su ile dolu 100 ml'lik bir tüpe alinmasi ile ölçülmüstür. 60 dakika sonra olusturulan ekstrüdatlarin hacminin %70 oranda arttigi ve saat sonra da 30 mikrondan küçük parçaciklara tamamen ayrildigi gözlemlenmistir. The swelling and dispersion properties of the formed extrudates and particles by taking 10 ml of the extrudate into a 100 ml tube filled with water. has been measured. The volume of extrudates formed after 60 minutes increased by 70% and After an hour, it was observed that it completely disintegrated into particles smaller than 30 microns.
Bu bildirimde açiklanan ekstrüdatlarin ezilme dayanikliligi 4,4 Kgf'dir. The crush strength of the extrudates described in this statement is 4.4 Kgf.
Prosedürün geri kalani Örnek 1A'daki ile ayni sekilde tutulacak sekilde bazi ilave çalismalar yürütülmüstür. Elde edilen sonuçlar, burada, Tablo 1'de verilmektedir. Ör.! Üründe kullanilan Ü Dene maddeler r Sülfür Baglama Boyut Nem içerigi Ezilme % D (9) maddesi (mm) (%) dayaniklili olarak gi (Kgf) Sisme g Baglay Miktar 1) 5-7 Dene Parçacik: 3 ila 4 Parçacik: 3 ila 4 Parçacik: 3 ila 4 -7 Parçacik: 3 Parçacik: 3 ila 4 1,5 x 4-5 Parçacik: 3 ila 4 Nisast 1,5 x 5-6 asi Parçacik: 3 ila 4 CMC: karboksi metil selüloz; HPC: hidroksi propil selüloz Çikarim: Sonuçlar, ürünün sülfür ve baglama maddesi içermesi durumunda, ezilme dayanikliliginin 1,5 ila 4,5 Kgf, sisme yüzdesinin %5 ila 70 arasinda degistigini, dagilim süresinin de 20 saat oldugunu göstermektedir. Örnek 1B: Sülfür + Baglama maddesi + Sisirme maddesi 97 g element halinde mikronize sülfür, baglama maddesi olarak 2 g karboksimetil selüloz ve sisirme maddesi olarak da 19 selüloz asilanmis poliakrilamit potasyum tuzu ile karistirilmistir. Ilk karisimin elde edilmesi için kuru agirliga yeterli miktarda su eklenmistir. Karisim harmanlanmis ve yogrulmus; sonuç olarak ortaya çikan hamur bir ekstrüder kullanilarak mekanik olarak 1,5 x 4 - 7 mm boyut araliginda (çap x uzunluk) ekstrüdatlara dönüstürülmüstür. Hamurun kalan yarisi, tava veya tamburlu granül Olusturucu ile 3 ila 4 mm boyutlarda küresel parçaciklara ayrilmistir. Sonuç olarak olusan ekstrüdatlar ve küresel parçaciklar, kuru agirlik bazinda %0,5'ten az nem içerecek sekilde havada kurumaya birakilmistir. Olusturulan parçaciklari kurutma yöntemleri arasinda vakumlu veya mikrodalga isinli kurutma da yer almaktadir; ilgili konuda bilgi sahibi kisiler bu yöntemler konusunda bilgi sahibidir. Keeping the remainder of the procedure the same as in Example 1A, some additional studies have been carried out. The results obtained are presented here in Table 1. eg! U used in the product try substances r Sulfur Bonding Size Moisture content Crushing % D (9) substance (mm) (%) as durable gi (Kgf) Inflatables g Baglay Quantity 1) 5-7 Try Particle: 3 to 4 Particle: 3 to 4 Particle: 3 to 4 -7 Particles: 3 Particle: 3 to 4 1.5 x 4-5 Particle: 3 to 4 Starch 1.5 x 5-6 rebel Particle: 3 to 4 CMC: carboxy methyl cellulose; HPC: hydroxy propyl cellulose Conclusion: The results are crushing if the product contains sulfur and binding agent. Its durability is between 1.5 and 4.5 Kgf, its swelling percentage varies between 5 and 70%, distribution shows that the duration is 20 hours. Example 1B: Sulfur + Binding agent + Blowing agent 97 g elemental micronized sulfur, 2 g carboxymethyl as binding agent cellulose and as blowing agent 19 cellulose acrylized polyacrylamide potassium salt mixed with. Sufficient water per dry weight to obtain the first mix has been added. The mixture is blended and kneaded; The resulting dough is a in the size range of 1.5 x 4 - 7 mm (diameter x length) mechanically using an extruder converted into extrudates. Remaining half of dough, pan or drum granules It was divided into spherical particles of 3 to 4 mm in size with the generator. As a result extrudates and spherical particles formed, moisture less than 0.5% dry weight It was left to dry in air. Drying the formed particles Methods include vacuum or microwave drying; relating to Those who are knowledgeable on the subject are knowledgeable about these methods.
Olusturulan ekstrüdatlar ve parçaciklarin sisme ve dagilma özellikleri, olusturulan ekstrüdatlardan 10 ml'lik bir kismin su ile dolu 100 ml'lik bir tüpe alinmasi ile ölçülmüstür. 80 dakika sonra olusturulan ekstrüdatlarin hacminin %89 oranda arttigi ve 12 saat sonra da 30 mikrondan küçük parçaciklara tamamen ayrildigi gözlemlenmistir. The swelling and dispersion properties of the formed extrudates and particles by taking 10 ml of the extrudate into a 100 ml tube filled with water. has been measured. The volume of extrudates formed after 80 minutes increased by 89% and After 12 hours, it was observed that it completely disintegrated into particles smaller than 30 microns.
Bu bildirimde açiklanan ekstrüdatlarin ezilme dayanikliligi 1,9 Kgf'dir. The crush strength of the extrudates described in this statement is 1.9 Kgf.
Prosedürün geri kalani Örnek 1B'deki ile ayni sekilde tutulacak sekilde bazi ilave çalismalar yürütülmüstür. Elde edilen sonuçlar, burada, Tablo 2'de verilmektedir. ÖrJ Üründe kullanilan maddeler Ü Sülfür Baglam Sisirme Boyut Nem Ezilme % Dagilim (9) a maddesi (mm) içerigi dayaniklili olarak süresi maddes (g) (%) gi (Kgf) Sisme (saat I (9) olarak) 2) (2) x 5-7 Parçacik: 3 ila Ekstrüdat: 1,5 (2) x 5-7 Parçacik: 3 ila Ekstrüdat: 1,5 <0,5 2,2 70 6 Parçacik: 3 ila (2) (0,5) + x 5-7 Poli B Parçacik: 3 ila Ekstrüdat: 1,5 Parçacik: 3 ila Nisasta Ekstrüdat: 3,0 Parçacik: 3 ila Ekstrüdat: 1,5 Parçacik: 3 ila (05) + (1,5) PouAin Ekstrüdat: 1,5 Parçacik: 3 ila (1,5) Ekstrüdat: 1,5 Parçacik: 3 ila Ekstrüdat: 1,5 Parçacik: 3 ila Ekstrüdat: 6,0 Parçacik: 3 ila Ekstrüdat: 1,5 Parçacik: 3 ila Poli A: Selüloz asili poliakrilamit potasyum tuzu; Poli B:P0liakrilik Asit; CMC:Karboksi metil selüloz; EC: Etil selüloz; HPMC:Hidr0ksi propil metilselüloz; PVA: Polivinil alkol Çikarim: Sonuçlar, ürünün sülfür, baglama maddesi ve sisirme maddesi içermesi durumunda, ezilme dayanikliliginin 1,5 ila 4,5 Kgf, sisme yüzdesinin %33 ila 250 arasinda, dagilim süresinin de 4 ila 20 saat arasinda degistigini göstermektedir. Örnek 1C: Sülfür + Baglama maddesi + Sisirme maddesi + Bitki Büyüme Regülatörleri 96 g element halinde mikronize sülfür, baglama maddesi olarak 1,995 9 karboksimetil selüloz, sisirme maddesi olarak 2 g selüloz asilanmis poliakrilamit potasyum tuzu ve bitki büyüme hormonu olarak da 0,005 9 GA ile karistirilmistir. Ilk karisimin elde edilmesi için kuru agirliga yeterli miktarda su eklenmistir. Karisim harmanlanmis ve yogrulmus; sonuç olarak ortaya çikan hamur bir ekstrüder kullanilarak mekanik olarak 1,5 x 5 - 7 mm boyut araliginda (çap x uzunluk) ekstrüdatlara dönüstürülmüstür.Keeping the remainder of the procedure the same as in Example 1B, some additional studies have been carried out. The results obtained are presented here in Table 2. ExJ Substances used in the product Ü Sulfur Context Swelling Size Moisture Crushing % Distribution (9) substance a (mm) content durably duration substance (g) (%) gi (Kgf) Inflatables (hours) as I (9) 2) (2) x 5-7 Particle: 3 to Extrudate: 1.5 (2) x 5-7 Particle: 3 to Extrudate: 1.5 <0.5 2.2 70 6 Particle: 3 to (2) (0.5) + x 5-7 Poly B Particle: 3 to Extrudate: 1.5 Particle: 3 to Starch Extrudate: 3.0 Particle: 3 to Extrudate: 1.5 Particle: 3 to (05) + (1.5) PouAin Extrudate: 1.5 Particle: 3 to (1.5) Extrudate: 1.5 Particle: 3 to Extrudate: 1.5 Particle: 3 to Extrudate: 6.0 Particle: 3 to Extrudate: 1.5 Particle: 3 to Poly A: Cellulose acryl polyacrylamide potassium salt; Poly B: Polyacrylic Acid; CMC:Carboxy methyl cellulose; EC: Ethyl cellulose; HPMC:Hydroxypropyl methylcellulose; PVA: Polyvinyl alcohol Conclusion: The results show that the product contains sulfur, binding agent and blowing agent. in case of crushing strength of 1.5 to 4.5 Kgf, swelling percentage of 33 to 250%. It also shows that the distribution time varies between 4 and 20 hours. Example 1C: Sulfur + Binding agent + Spraying agent + Plant Growth regulators 96 g elemental micronized sulfur, 1.995 9 carboxymethyl as binder cellulose, 2 g of cellulose-grafted polyacrylamide potassium salt as blowing agent and It was mixed with 0.005 9 GA as plant growth hormone. get my first mix Sufficient amount of water was added to the dry weight to The mixture is blended and kneaded; The resulting dough is mechanically extruded using an extruder. Converted to extrudates in the 1.5 x 5 - 7 mm size range (diameter x length).
Hamurun kalan yarisi, tava veya tamburlu granül Olusturucu ile 3 ila 4 mm boyutlarda küresel parçaciklara ayrilmistir. Sonuç olarak olusan ekstrüdatlar ve küresel parçaciklar, kuru agirlik bazinda %0,5'ten az nem içerecek sekilde havada kurumaya birakilmistir. Olusturulan parçaciklari kurutma yöntemleri arasinda vakumlu veya mikrodalga isinli kurutma da yer almaktadir; ilgili konuda bilgi sahibi kisiler bu yöntemler konusunda bilgi sahibidir. Remaining half of dough, 3 to 4 mm in size with pan or drum granulator divided into spherical particles. The resulting extrudates and spherical particles are allowed to air dry to contain less than 0.5% moisture by dry weight. has been abandoned. Among the drying methods of the formed particles, vacuum or microwave radiation drying is also included; Those who are knowledgeable about the subject should use these methods. is knowledgeable about.
Olusturulan ekstrüdatlar ve parçaciklarin sisme ve dagilma özellikleri, olusturulan ekstrüdatlardan 10 ml'lik bir kismin su ile dolu 100 ml'lik bir tüpe alinmasi ile ölçülmüstür. 60 dakika sonra olusturulan ekstrüdatlarin hacminin %120 oranda arttigi ve 4 saat sonra da 30 mikrondan küçük parçaciklara tamamen ayrildigi gözlemlenmistir. The swelling and dispersion properties of the formed extrudates and particles by taking 10 ml of the extrudate into a 100 ml tube filled with water. has been measured. The volume of extrudates formed after 60 minutes increased by 120% and After 4 hours, it was observed that it was completely separated into particles smaller than 30 microns.
Bu bildirimde açiklanan ekstrüdatlarin ezilme dayanikliligi 1,8 Kgf'dir. The crush strength of the extrudates described in this statement is 1.8 Kgf.
Prosedürün geri kalani Örnek 1C'deki ile ayni sekilde tutulacak sekilde bazi ilave çalismalar yürütülmüstür. Elde edilen sonuçlar, burada, Tablo 3`te verilmektedir. Üründe kullanilan maddeler Ü (50' 9› g E 55 m 3 m 5 !1) : a 5. 9 m 9 m 5 6.Keeping the remainder of the procedure the same as in Example 1C, some additional studies have been carried out. The results obtained are presented here in Table 3. Substances used in the product (50' 9› g E 55 m 3 m 5 !1) : a 5. 9 m 9 m 5 6.
E ) Parçacik: 3 ila ) Parçacik: 3 ila ) Parçacik: 3 ila ) GA Parçacik: 3 ila Parçacik: 3 ila Poli A: Selüloz asili poliakrilamit potasyum tuzu; CMC:Karboksi metil selüloz; GA:GibbereiIIik asit; BA: 6-Benzil adenin; ABA: Absisik asit; IAA: IndoI-S-asetik asit Çikarim: Sonuçlar, ürünün sülfür, baglama maddesi, sisirme maddesi ve bitki büyüme regülatörleri içermesi durumunda, ezilme dayanikliliginin 1,5 ila 2,0 Kgf, sisme yüzdesinin %80 ila 120 arasinda degistigini, dagilim süresinin de 4 saat oldugunu göstermektedir. Örnek 1D: Sülfür + Baglama maddesi + Sisirme maddesi + Inorganik kati maddeler 80 g element halinde mikronize sülfür, 10 g zeolit X tozu, baglama maddesi olarak 2 g karboksimetil selüloz, sisirme maddesi olarak 8 g selüloz asilanmis poliakrilamit potasyum tuzu ile karistirilmistir. Ilk karisimin elde edilmesi için kuru agirliga yeterli miktarda su eklenmistir. Karisim harmanlanmis ve yogrulmus; sonuç olarak ortaya çikan hamur bir ekstrüder kullanilarak mekanik olarak 1,5 x 5 - 7 mm boyut araliginda (çap x uzunluk) ekstrüdatlara dönüstürülmüstür. Hamurun kalan yarisi, tava veya tamburlu granül Olusturucu ile 3 ila 4 mm boyutlarda küresel parçaciklara ayrilmistir.E ) Particle: 3 to ) Particle: 3 to ) Particle: 3 to ) GA Particle: 3 to Particle: 3 to Poly A: Cellulose acryl polyacrylamide potassium salt; CMC:Carboxy methyl cellulose; GA: Gibbereylic acid; BA: 6-Benzyl adenine; ABA: Abscisic acid; IAA: IndoI-S-acetic acid Conclusion: The results show that the product has sulfur, binding agent, blowing agent and plant growth. 1.5 to 2.0 Kgf of crush resistance if it includes regulators. The percentage varies between 80 and 120%, and the dispersion time is 4 hours. shows. Example 1D: Sulfur + Binding agent + Spraying agent + Inorganic solid substances 80 g elemental micronized sulfur, 10 g zeolite X powder, 2 g as binding agent carboxymethyl cellulose, 8 g cellulose-grafted polyacrylamide as blowing agent mixed with potassium salt. Dry weight is sufficient to obtain the first mix. amount of water added. The mixture is blended and kneaded; emerge as a result The resulting dough is mechanically produced in a size range of 1.5 x 5 - 7 mm using an extruder. (diameter x length) converted to extrudates. Remaining half of dough, pan or It is divided into spherical particles of 3 to 4 mm in size with a drum granulator.
Sonuç olarak olusan ekstrüdatlar ve küresel parçaciklar, kuru agirlik bazinda %0,5'ten az nem içerecek sekilde havada kurumaya birakilmistir. Olusturulan parçaciklari kurutma yöntemleri arasinda vakumlu veya mikrodalga isinli kurutma da yer almaktadir; ilgili konuda bilgi sahibi kisiler bu yöntemler konusunda bilgi sahibidir. The resulting extrudates and spherical particles are more than 0.5% dry weight It has been left to dry in the air to contain less moisture. The generated particles drying methods include vacuum or microwave drying; Those who are knowledgeable on the subject are knowledgeable about these methods.
Olusturulan ekstrüdatlar ve parçaciklarin sisme ve dagilma özellikleri, olusturulan ekstrüdatlardan 10 ml'lik bir kismin su ile dolu 100 ml'lik bir tüpe alinmasi ile ölçülmüstür. 60 dakika sonra olusturulan ekstrüdatlarin hacminin %230 oranda arttigi ve saat sonra da 30 mikrondan küçük parçaciklara tamamen ayrildigi gözlemlenmistir. The swelling and dispersion properties of the formed extrudates and particles by taking 10 ml of the extrudate into a 100 ml tube filled with water. has been measured. The volume of extrudates formed after 60 minutes increased by 230% and After an hour, it was observed that it completely disintegrated into particles smaller than 30 microns.
Bu bildirimde açiklanan ekstrüdatlarin ezilme dayanikliligi 3,5 Kgf'dir. The crush strength of the extrudates described in this statement is 3.5 Kgf.
Prosedürün geri kalani Örnek 1D'deki ile ayni sekilde tutulacak sekilde bazi ilave çalismalar yürütülmüstür. Elde edilen sonuçlar, burada, Tablo 4'te verilmektedir. Üründe kullanilan maddeler Ürün özellik 3 m 3 3 2 3 Q 9 : z 3 3 3 ^ 5 3 O `8 5” m 93 ”- g 2. 2 3% e 3 a (1) + (10) Parçacik: 3 ila 4 (8) (10) Parçacik: 3 ila 4 (2) (10) Parçacik: 3 ila 4 (2) t(5) Parçacik: 3 ila 4 (2) Parçacik: 3 ila 4 (2) Parçacik: 3 ila 4 (1) MS (10) Parçacik: 3 ila 4 (1) MS (10) Parçacik: 3 ila 4 nisasta MS (9) Parçacik: 3 ila 4 (1) MS (10) Parçacik: 3 ila 4 nisasta MS (10) Parçacik: 3 ila 4 M8 (10) Parçacik: 3 ila 4 M8 (10) Parçacik: 3 ila 4 MS (10) Parçacik: 3 ila 4 M8 (10) Parçacik: 3 ila 4 (7.5) Parçacik: 3 ila 4 Poli A: Selüloz asili poliakrilamit potasyum tuzu; CMC:Karboksi metil selüloz; PVA: Polivinil alkol; HPMC: Hidroksipropilmetil selüloz; EC: Etil selüloz;Harcanan MS: Havada kurutma için kullanilan harcanan moleküler elek Çikarim: Sonuçlar, ürünün sülfür, baglama maddesi, sisirme maddesi ve inorganik kati maddeleri içermesi durumunda, ezilme dayanikliliginin 1,5 ila 4,5 Kgf, sisme yüzdesinin Örnek 1E: Sülfür + Baglama maddesi + Sisirme maddesi + Inorganik kati maddeler + Bitki büyüme regülatörleri 80 g element halinde mikronize sülfür, 10 g zeolit A tozu, baglama maddesi olarak poliakrilamit potasyum tuzu ve bitki büyüme bileseni olarak 0,005 9 gibberellik asit (GA) ile karistirilmistir. Ilk karisimin elde edilmesi için kuru agirliga yeterli miktarda su eklenmistir. Karisim harmanlanmis ve yogrulmus; sonuç olarak ortaya çikan hamur bir ekstrüder kullanilarak mekanik olarak 1,5 x 5 - 7 mm boyut araliginda (çap x uzunluk) ekstrüdatlara dönüstürülmüstür. Hamurun kalan yarisi, tava veya tamburlu granül Olusturucu ile 3 ila 4 mm boyutlarda küresel parçaciklara ayrilmistir. Sonuç olarak olusan ekstrüdatlar ve küresel parçaciklar, kuru agirlik bazinda %0,5'ten az nem içerecek sekilde havada kurumaya birakilmistir. Olusturulan parçaciklari kurutma yöntemleri arasinda vakumlu veya mikrodalga isinli kurutma da yer almaktadir; ilgili konuda bilgi sahibi kisiler bu yöntemler konusunda bilgi sahibidir. Keeping the remainder of the procedure the same as in Example 1D, some additional studies have been carried out. The results obtained are presented here in Table 4. Ingredients used in the product feature 3 m 3 3 2 3 Q 9 : z 3 3 3 ^ 5 3 O `8 5” m 93 ”- g 2. 2 3% e 3 a (1) + (10) Particle: 3 to 4 (8) (10) Particle: 3 to 4 (2) (10) Particle: 3 to 4 (2) t(5) Particle: 3 to 4 (2) Particle: 3 to 4 (2) Particle: 3 to 4 (1) MS (10) Particle: 3 to 4 (1) MS (10) Particle: 3 to 4 Starch MS (9) Particle: 3 to 4 (1) MS (10) Particle: 3 to 4 Starch MS (10) Particle: 3 to 4 M8 (10) Particle: 3 to 4 M8 (10) Particle: 3 to 4 MS (10) Particle: 3 to 4 M8 (10) Particle: 3 to 4 (7.5) Particle: 3 to 4 Poly A: Cellulose acryl polyacrylamide potassium salt; CMC:Carboxy methyl cellulose; PVA: polyvinyl alcohol; HPMC: Hydroxypropylmethyl cellulose; EC: Ethyl cellulose; Spent MS: Spent molecular sieve used for air drying Inference: The results show that the product has sulfur, binder, blowing agent and inorganic solid. If it contains substances, the crush strength is 1.5 to 4.5 Kgf, the percentage of swelling Example 1E: Sulfur + Binding agent + Spraying agent + Inorganic solid Ingredients + Plant growth regulators 80 g elemental micronized sulfur, 10 g zeolite A powder, as binder 0.005 9 gibberellic acid (GA) as polyacrylamide potassium salt and plant growth ingredient mixed with. Sufficient water per dry weight to obtain the first mix has been added. The mixture is blended and kneaded; The resulting dough is a in the size range of 1.5 x 5 - 7 mm (diameter x length) mechanically using an extruder converted into extrudates. Remaining half of dough, pan or drum granules It was divided into spherical particles of 3 to 4 mm in size with the generator. As a result extrudates and spherical particles formed, moisture less than 0.5% dry weight It was left to dry in air. Drying the formed particles Methods include vacuum or microwave drying; relating to Those who are knowledgeable on the subject are knowledgeable about these methods.
Olusturulan ekstrüdatlar ve parçaciklarin sisme ve dagilma özellikleri, olusturulan ekstrüdatlardan 10 ml'lik bir kismin su ile dolu 100 ml'lik bir tüpe alinmasi ile ölçülmüstür. 60 dakika sonra olusturulan ekstrüdatlarin hacminin %200 oranda arttigi ve saat sonra da 30 mikrondan küçük parçaciklara tamamen ayrildigi gözlemlenmistir.The swelling and dispersion properties of the formed extrudates and particles by taking 10 ml of the extrudate into a 100 ml tube filled with water. has been measured. The volume of extrudates formed after 60 minutes increased by 200% and After an hour, it was observed that it completely disintegrated into particles smaller than 30 microns.
Bu bildirimde açiklanan ekstrüdatlarin ezilme dayanikliligi 2,1 Kgf'dir. The crush strength of the extrudates described in this statement is 2.1 Kgf.
Prosedürün geri kalani Örnek 1E'deki ile ayni sekilde tutulacak sekilde bazi ilave çalismalar yürütülmüstür. Elde edilen sonuçlar, burada, Tablo 5'te verilmektedir. Üründe kullanilan maddeler Ürün özellikleri Bêsg Aci› 3% 2; aa 9%& &“45 2 A 5 0) “D 7 5 E. V S_ mi :2 0› (I) m cn. 9- ci› v : «2 to ~2 : 3 v ;0 S Parçacik:3 Harcana ABA Ekstrüdat: <0,5 3,2 240 20 (10) Parçacik: 3 Haroana BA Ekstrüdat: <0,5 4,4 220 20 X (10) Parçacik: 3 ZSM-S BA Ekstrüdat: <0,5 2,9 220 20 + GA Parçacik: 3 Poli A: Selüloz asili poliakrilamit potasyum tuzu; CMC:Karboksi metil selüloz; GA:GibbereiIIik asit; BA: 6-benzil adenin; ABA: absisik asit; Harcanan MS: Havada kurutma için kullanilan harcanan moleküler elek Çikarim: Sonuçlar, ürünün sülfür, baglama maddesi, sisirme maddesi, inorganik kati maddeler ve bitki büyüme regülatörleri içermesi durumunda, ezilme dayanikliliginin 2,1 ila 4,5 Kgf, sisme yüzdesinin %2 ila 280 arasinda degistigini, dagilim süresinin de 20 saat oldugunu göstermektedir.Keeping the remainder of the procedure the same as in Example 1E, some additional studies have been carried out. The results obtained are presented here in Table 5. Ingredients used in the product properties Bêsg Pain 3% 2%; mm 9%& &“45 2 A 5 0) “D 7 5 E. V S_ mi :2 0› (I) m cn. 9- ci› v : «2 to ~2 : 3 v ;0 S Particle:3 Spend ABA Extrudate: <0.5 3.2 240 20 (10) Particle: 3 Haroana BA Extrudate: <0.5 4.4 220 20 X (10) Particle: 3 ZSM-S BA Extrudate: <0.5 2.9 220 20 + GA Particle: 3 Poly A: Cellulose acryl polyacrylamide potassium salt; CMC:Carboxy methyl cellulose; GA: Gibbereylic acid; BA: 6-benzyl adenine; ABA: abscisic acid; Spent MS: In the Air spent molecular sieve used for drying Inference: The results show that the product is sulfur, binder, blowing agent, inorganic solid. 2.1. to 4.5 Kgf, the percentage of swelling varies between 2 and 280%, and the dispersion time is 20 shows the time.
Sonuç: Tüm örneklerin çikarimlari incelendikten sonra ezilme dayanikliligi, sisirme % orani ve dagitim süresi açisindan istenilen özellikleri en iyi sekilde yansitan örneklerin Örnek 1C ve 1E oldugu görülmektedir. Örnek 2: Gübre ürününün hazirlanmasi - baska bir somut örnek 90 g element halinde sülfür, 119-140 ûC arasinda degisen sicakliklarda eritilmis ve erimis sülfür bulamacina 10 g harcanan FCC eklenmistir. Eriyen kütle, soguk yüzeye birakma ya da suya atma yoluyla 3 ila 5 mm arasi büyüklükte pastil ve granül olusturacak sekilde islemden geçirilmistir. Conclusion: After examining the inferences of all samples, the crush strength, swelling % samples that best reflect the desired properties in terms of rate and distribution time. It can be seen that there are examples 1C and 1E. Example 2: Preparation of fertilizer product - another concrete example 90 g elemental sulfur is melted at temperatures varying between 119-140 ºC and 10 g spent FCC was added to the molten sulfur slurry. Melting mass, cold surface Lozenges and granules from 3 to 5 mm in size by dropping or throwing into water It has been processed to form
Sekilli maddelerin sisme ve dagilma özellikleri, olusturulan sekilli maddelerden 10 ml'lik bir kismin su ile dolu 100 ml'lik bir tüpe alinmasi ile ölçülmüstür. 60 dakika sonra olusturulan ekstrüdatlarin hacminin %5 oranda arttigi ve 72 saat sonra da 30 mikrondan küçük parçaciklara tamamen ayrildigi gözlemlenmistir. Bu bildirimde açiklanan sekilli maddelerin ezilme dayanikliligi 3,0 Kgf'dir. Swelling and dispersion properties of shaped substances, 10 ml of formed shaped substances. It was measured by placing a portion of the sample in a 100 ml tube filled with water. 60 minutes later The volume of extrudates formed increased by 5% and decreased to 30 microns after 72 hours. It has been observed that it is completely separated into small particles. as described in this notice The crushing resistance of the materials is 3.0 Kgf.
Prosedürün geri kalani Örnek 2'deki ile ayni sekilde tutulacak sekilde bazi ilave çalismalar yürütülmüstür. Elde edilen sonuçlar, burada, Tablo 6'de verilmektedir. Örnek Üründe kullanilan maddeler Ü Sülfür Baglama Harcanan Inorganik kati Ezilme % olarak Dagilim (9) maddesi FCC (g) maddeler (g) dayaniklili Sisme süresi (9) Çil (Kef) (saat 4,2 7 70 CMC:Karboksi metil selüloz; HPMC: Hidroksipropilmetil selüloz; Harcanan MS: Havada kurutma için kullanilan harcanan moleküler elek; Harcanan FCC: Harcanan sivi katalitik Çikarim: Sonuçlar, ürünün sülfür, baglama maddesi, harcanan katalist ve inorganik kati madde içermesi durumunda, ezilme dayanikliliginin 3,0 ila 5,0 Kgf, sisme yüzdesinin göstermektedir. Keeping the rest of the procedure the same as in Example 2, some additional studies have been carried out. The results obtained are presented here in Table 6. Substances used in the sample product Ü Sulfur Binding Spent Inorganic Solid Crush % Distribution Item (9) FCC (g) items (g) durable Inflate time (9) Chil (Kef) (clock) 4.2 7 70 CMC:Carboxy methyl cellulose; HPMC: Hydroxypropylmethyl cellulose; Spent MS: In the Air spent molecular sieve used for drying; Spent FCC: Spent liquid catalytic Conclusion: The results show that the product has sulfur, binder, spent catalyst and inorganic solid. If it contains a substance, the crush strength is between 3.0 and 5.0 Kgf, the percentage of swelling shows.
Gereksiz laf kalabaligindan kaçinmak üzere buradaki somut örneklerde bilinen bilesen ve isleme alma tekniklerine yer verilmemistir. Burada kullanilan örnekler, temel olarak buradaki somur örneklerin uygulama seklinin anlasilmasi ve gerekli becerilere sahip kisilerin bu somut örnekleri uygulayabilmesinin saglanmasidir. Benzer sekilde, örneklerin buradaki somut açiklamalarin kapsamini kisitladigi düsünülmemektedir. Known component in concrete examples here to avoid unnecessary clutter and processing techniques are not included. The examples used here are basically understanding the application form of the concrete examples here and having the necessary skills It is to ensure that people can apply these concrete examples. Similarly, The examples are not considered to limit the scope of the concrete explanations here.
Yukarida belirli somut örnekler ile ilgili olarak yapilmis olan açiklama, burada diger kisilerin mevcut bilgileri uygulayarak genel konseptten sapmadan belirli somut örnekler sunulmasi gibi farkli uygulamalara basvurmasi ile buradaki somut örneklerin genel niteliginin açiga çikarilmasini amaçlamaktadir ve bu nedenle, bu tür adaptasyonlar ve degisikliklerin açiklanan somur örnek esdegeri baglaminda ve araliginda incelenmesi gerekir. Burada kullanilan ifade biçimlerinin veya terminolojinin tamamen açiklama amaçli oldugu ve herhangi bir kisitlama içermedigi anlasilmalidir. Bu nedenle, buradaki somur örnekler tercih edilen somut uygulamalar olarak açiklanmistir; bu konuda bilgi sahibi kisiler, bu uygulamanin ruhuna sadik sekilde burada açiklanan somut uygulamalarin üzerinde degisiklik yapabilir. The explanation made above regarding certain concrete examples is here specific concrete examples without deviating from the general concept by applying existing knowledge of the persons the general examples of concrete examples here, by applying to different applications such as nature, and therefore, such adaptations and examining the changes in the context and range of the concrete sample equivalent described must. Full disclosure of expressions or terminology used herein It should be understood that it is for purposes only and does not contain any restrictions. Therefore, here concrete examples are described as preferred concrete embodiments; information about it True to the spirit of this application, the owners of can make changes to the applications.
Teknik Avantajlar Ve Ekonomik Önem - Gübre ürünü, yüksek sülfür içerigi, yüksek su tutma kapasitesi ve bitki besin maddelerinin topraga yavasça salinmasi ile çok islevli bir nitelige sahiptir. 0 Bu bildirim, bahçivanlik amaçli besleme için toz içermeyen, ekonomik, toksik metal içermeyen element halinde sülfür sunmaktadir. 0 Bu bildirim, yalnizca bitki destegi olarak yüksek sülfür içerikli bir gübre ürünü saglamakla kalmamakta ayni zamanda belirli toprak hasereleri ve mikroorgaizmalara karsi mantar önleyici faaliyetler sergileyerek bitkileri korumaktadir. Technical Advantages and Economic Importance - Fertilizer product, high sulfur content, high water holding capacity and plant nutrients It has a multifunctional quality with the slow release of substances into the soil. 0 This statement is a dust-free, economical, non-toxic product for horticultural feed. It offers elemental sulphur, which does not contain metals. 0 This notice describes a fertilizer product with a high sulfur content as a plant supplement only. not only provides protection against certain soil pests and microorganisms. It protects plants by exhibiting anti-fungal activities.
- Bu bildirim, daha düsük Na içerikli, pH degeri 7,5 ila 8,5 arasinda olan, toprak salinitesini düsürecek bir gübre ürünü sunmaktadir. - This notification applies to soils with lower Na content, pH values between 7.5 and 8.5. offers a fertilizer product that will reduce salinity.
- Bu bildirim, ayni zamanda istenilen mekanik kuvvete sahip bir gübre ürününün hazirlanmasi için basit, etkili ve ekonomik bir süreç sunmaktadir. o Gübre ürününün hazirlanma sürecinde, gübre bilesenlerinin çamur biçiminde karistirilma adimlarina gerek bulunmamaktadir. 0 Bu bildirim, moleküler elekler, Sivi katalitik çatlama (FCC) katalistleri ve benzerleri gibi harcanan katalistlerin yeniden kullanilmasi için etkili bir yöntem sunmaktadir. - This notification also states that a fertilizer product with the desired mechanical strength It offers a simple, effective and economical process for preparation. o In the preparation process of the fertilizer product, the fertilizer components are in the form of sludge. no mixing steps are required. 0 This notice applies to molecular sieves, Liquid catalytic cracking (FCC) catalysts and an effective method for reusing spent catalysts like their counterparts offers.
Bu özellikler dahilinde kullanilan "olusma" kelimesi, bahsi geçen element, tamamlayici madde ya da adim, elementler grubu, tamamlayici madde grubu veya adim grubunun dahil oldugunu ifade etse de diger element, tamamlayici madde ya da adim, elementler grubu, tamamlayici madde grubu veya adim grubunu hariç tutmamaktadir. veya adet kullanildigini ifade eder; bu kullanim bir veya daha fazla istenilen nesne veya sonuç elde etmek için müdahalenin somutlastirilmasi yönünde olabilir. The word "formation" used within these properties, the element in question, the complementary substance or step, group of elements, complementary substance group or step group other element, supplementary substance or step, elements does not exclude a supplementary substance group or a step group. or means that menstruation is used; this use for one or more desired objects or may be in the direction of embodying the intervention to achieve results.
Belirli fiziksel parametreler, ebatlar ve adetler için verilen sayisal degerler, yalnizca yaklasik degerlerdir ve aksi yönde bir ifade bulunmadigi takdirde, fiziksel parametreler, ebatlar ve adetlere atanan sayisal degerden yüksek degerlerin kesfin ve iddialarin kapsami dahilinde olacaktir. The numerical values given for certain physical parameters, sizes and quantities are only are approximate and unless otherwise stated, physical parameters are discovery of values higher than the numerical value assigned to sizes and will be within its scope.
Kesiflerin belirli somut uygulamalari açiklanmis olsa da bu somut uygulamalar yalnizca örnek amaçli olarak açiklanmistir ve kesfin kapsamini sinirlama amaci tasimamaktadir. While certain concrete applications of the discoveries have been described, these concrete applications are only it is described for illustrative purposes and is not intended to limit the scope of exploration.
Bu konuda bilgi sahibi kisiler, bu kesfin süreci, bileseni, formülasyonu veya kombinasyonu üzerinde kesif kapsami dahilinde yapilacak degisiklik veya modifikasyonlar belirleyebilir. Bu degisiklik veya modifikasyonlar da bu kesfin ruhuna uygun olarak kabul edilecektir. Iddialar ve esdegerlerinin kesif ruhu ve kapsamina uygun biçim ya da degisiklikleri kapsamasi hedeflenmektedir.Persons skilled in the art will know the process, component, formulation, or formulation of this discovery. modification or modification to be made within the scope of the discovery on the combination of can identify modifications. These changes or modifications are also in the spirit of this discovery. will be considered appropriate. The spirit of discovery and scope of claims and their equivalents It is intended to cover appropriate format or changes.
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| PCT/IN2015/000022 WO2015114651A2 (en) | 2014-01-31 | 2015-01-15 | Fertilizer products |
| IN350MU2014 IN2014MU00350A (en) | 2014-01-31 | 2015-01-15 |
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| JOP20190274A1 (en) * | 2017-05-23 | 2019-11-24 | Mosaic Co | Swellable fertilizer granules containing elemental sulfur with increased oxidation rates |
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