TR201603688A2 - A NEW COMPOSITE POLYMER MATERIAL - Google Patents
A NEW COMPOSITE POLYMER MATERIAL Download PDFInfo
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- TR201603688A2 TR201603688A2 TR2016/03688A TR201603688A TR201603688A2 TR 201603688 A2 TR201603688 A2 TR 201603688A2 TR 2016/03688 A TR2016/03688 A TR 2016/03688A TR 201603688 A TR201603688 A TR 201603688A TR 201603688 A2 TR201603688 A2 TR 201603688A2
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- Turkey
- Prior art keywords
- feature
- polymer material
- composite polymer
- material mentioned
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- 239000002131 composite material Substances 0.000 title claims abstract description 152
- 239000002861 polymer material Substances 0.000 title claims abstract description 73
- 229920000642 polymer Polymers 0.000 claims abstract description 75
- 239000000463 material Substances 0.000 claims abstract description 54
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 23
- 239000004971 Cross linker Substances 0.000 claims abstract description 22
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims abstract description 18
- 239000003999 initiator Substances 0.000 claims abstract description 18
- 238000011049 filling Methods 0.000 claims abstract description 13
- 239000011230 binding agent Substances 0.000 claims abstract description 10
- 239000002245 particle Substances 0.000 claims description 75
- 239000000203 mixture Substances 0.000 claims description 65
- 239000000919 ceramic Substances 0.000 claims description 55
- 239000000654 additive Substances 0.000 claims description 48
- 150000001875 compounds Chemical class 0.000 claims description 38
- 230000000996 additive effect Effects 0.000 claims description 28
- -1 acrylate compound Chemical class 0.000 claims description 25
- 230000000844 anti-bacterial effect Effects 0.000 claims description 25
- 239000003063 flame retardant Substances 0.000 claims description 22
- 150000002734 metacrylic acid derivatives Chemical class 0.000 claims description 22
- 239000000126 substance Substances 0.000 claims description 22
- 230000002209 hydrophobic effect Effects 0.000 claims description 20
- 239000000049 pigment Substances 0.000 claims description 19
- 230000006750 UV protection Effects 0.000 claims description 17
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 15
- 239000000945 filler Substances 0.000 claims description 13
- 230000015572 biosynthetic process Effects 0.000 claims description 10
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000011521 glass Substances 0.000 claims description 8
- 239000000178 monomer Substances 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- 239000004005 microsphere Substances 0.000 claims description 6
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 5
- UUEYEUDSRFNIQJ-UHFFFAOYSA-N CCOC(N)=O.CCOC(N)=O.CC(=C)C(O)=O.CC(=C)C(O)=O Chemical class CCOC(N)=O.CCOC(N)=O.CC(=C)C(O)=O.CC(=C)C(O)=O UUEYEUDSRFNIQJ-UHFFFAOYSA-N 0.000 claims description 5
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 5
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 5
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 5
- 239000011737 fluorine Substances 0.000 claims description 5
- 229910052731 fluorine Inorganic materials 0.000 claims description 5
- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 claims description 4
- LTHJXDSHSVNJKG-UHFFFAOYSA-N 2-[2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOCCOC(=O)C(C)=C LTHJXDSHSVNJKG-UHFFFAOYSA-N 0.000 claims description 4
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical class CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 claims description 4
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- 239000003242 anti bacterial agent Substances 0.000 claims description 4
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 4
- IUTYMBRQELGIRS-UHFFFAOYSA-N boric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OB(O)O.NC1=NC(N)=NC(N)=N1 IUTYMBRQELGIRS-UHFFFAOYSA-N 0.000 claims description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 239000000835 fiber Substances 0.000 claims description 4
- LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 claims description 4
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims description 4
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- 238000004040 coloring Methods 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 3
- 239000000347 magnesium hydroxide Substances 0.000 claims description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 3
- GRKDVZMVHOLESV-UHFFFAOYSA-N (2,3,4,5,6-pentabromophenyl)methyl prop-2-enoate Chemical compound BrC1=C(Br)C(Br)=C(COC(=O)C=C)C(Br)=C1Br GRKDVZMVHOLESV-UHFFFAOYSA-N 0.000 claims description 2
- QTKPMCIBUROOGY-UHFFFAOYSA-N 2,2,2-trifluoroethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)F QTKPMCIBUROOGY-UHFFFAOYSA-N 0.000 claims description 2
- CHUGKEQJSLOLHL-UHFFFAOYSA-N 2,2-Bis(bromomethyl)propane-1,3-diol Chemical compound OCC(CO)(CBr)CBr CHUGKEQJSLOLHL-UHFFFAOYSA-N 0.000 claims description 2
- BSWWXRFVMJHFBN-UHFFFAOYSA-N 2,4,6-tribromophenol Chemical compound OC1=C(Br)C=C(Br)C=C1Br BSWWXRFVMJHFBN-UHFFFAOYSA-N 0.000 claims description 2
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 claims description 2
- TYCFGHUTYSLISP-UHFFFAOYSA-M 2-fluoroprop-2-enoate Chemical compound [O-]C(=O)C(F)=C TYCFGHUTYSLISP-UHFFFAOYSA-M 0.000 claims description 2
- QEJPOEGPNIVDMK-UHFFFAOYSA-N 3-bromo-2,2-bis(bromomethyl)propan-1-ol Chemical compound OCC(CBr)(CBr)CBr QEJPOEGPNIVDMK-UHFFFAOYSA-N 0.000 claims description 2
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims description 2
- CFCVHJRJEWDVOG-UHFFFAOYSA-N 4-chloro-2,3-dimethylphenol Chemical compound CC1=C(C)C(Cl)=CC=C1O CFCVHJRJEWDVOG-UHFFFAOYSA-N 0.000 claims description 2
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 2
- GHXZTYHSJHQHIJ-UHFFFAOYSA-N Chlorhexidine Chemical compound C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 GHXZTYHSJHQHIJ-UHFFFAOYSA-N 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 2
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 claims description 2
- 239000002262 Schiff base Substances 0.000 claims description 2
- 150000004753 Schiff bases Chemical class 0.000 claims description 2
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical class [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 claims description 2
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 claims description 2
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 2
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 claims description 2
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- RREGISFBPQOLTM-UHFFFAOYSA-N alumane;trihydrate Chemical compound O.O.O.[AlH3] RREGISFBPQOLTM-UHFFFAOYSA-N 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 2
- FHPAAYZTTWZXEB-UHFFFAOYSA-N aluminum strontium oxygen(2-) Chemical compound [O-2].[Al+3].[Sr+2] FHPAAYZTTWZXEB-UHFFFAOYSA-N 0.000 claims description 2
- MHCAFGMQMCSRGH-UHFFFAOYSA-N aluminum;hydrate Chemical compound O.[Al] MHCAFGMQMCSRGH-UHFFFAOYSA-N 0.000 claims description 2
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052586 apatite Inorganic materials 0.000 claims description 2
- 239000000987 azo dye Substances 0.000 claims description 2
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 claims description 2
- 229910001863 barium hydroxide Inorganic materials 0.000 claims description 2
- 229910052916 barium silicate Inorganic materials 0.000 claims description 2
- HMOQPOVBDRFNIU-UHFFFAOYSA-N barium(2+);dioxido(oxo)silane Chemical compound [Ba+2].[O-][Si]([O-])=O HMOQPOVBDRFNIU-UHFFFAOYSA-N 0.000 claims description 2
- WAKZZMMCDILMEF-UHFFFAOYSA-H barium(2+);diphosphate Chemical compound [Ba+2].[Ba+2].[Ba+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O WAKZZMMCDILMEF-UHFFFAOYSA-H 0.000 claims description 2
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 2
- 239000000920 calcium hydroxide Substances 0.000 claims description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000292 calcium oxide Substances 0.000 claims description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 2
- 239000001506 calcium phosphate Substances 0.000 claims description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 2
- 235000011010 calcium phosphates Nutrition 0.000 claims description 2
- 239000000378 calcium silicate Substances 0.000 claims description 2
- 229910052918 calcium silicate Inorganic materials 0.000 claims description 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims description 2
- 239000004917 carbon fiber Substances 0.000 claims description 2
- 239000002041 carbon nanotube Substances 0.000 claims description 2
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 2
- 229960003260 chlorhexidine Drugs 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 229910052570 clay Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 claims description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims description 2
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 claims description 2
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 2
- 239000003365 glass fiber Substances 0.000 claims description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 2
- 235000013980 iron oxide Nutrition 0.000 claims description 2
- UETZVSHORCDDTH-UHFFFAOYSA-N iron(2+);hexacyanide Chemical compound [Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] UETZVSHORCDDTH-UHFFFAOYSA-N 0.000 claims description 2
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 claims description 2
- LRDFRRGEGBBSRN-UHFFFAOYSA-N isobutyronitrile Chemical compound CC(C)C#N LRDFRRGEGBBSRN-UHFFFAOYSA-N 0.000 claims description 2
- 239000012948 isocyanate Substances 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 235000012254 magnesium hydroxide Nutrition 0.000 claims description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
- 235000012245 magnesium oxide Nutrition 0.000 claims description 2
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 claims description 2
- 239000004137 magnesium phosphate Substances 0.000 claims description 2
- 229910000157 magnesium phosphate Inorganic materials 0.000 claims description 2
- 229960002261 magnesium phosphate Drugs 0.000 claims description 2
- 235000010994 magnesium phosphates Nutrition 0.000 claims description 2
- 239000000391 magnesium silicate Substances 0.000 claims description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 claims description 2
- 235000019792 magnesium silicate Nutrition 0.000 claims description 2
- KLOKZFORZOBLOH-UHFFFAOYSA-N magnesium strontium silicate Chemical compound [Si]([O-])([O-])([O-])[O-].[Mg+2].[Sr+2] KLOKZFORZOBLOH-UHFFFAOYSA-N 0.000 claims description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 2
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 2
- QYZFTMMPKCOTAN-UHFFFAOYSA-N n-[2-(2-hydroxyethylamino)ethyl]-2-[[1-[2-(2-hydroxyethylamino)ethylamino]-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCNCCO QYZFTMMPKCOTAN-UHFFFAOYSA-N 0.000 claims description 2
- 239000002105 nanoparticle Substances 0.000 claims description 2
- 150000002894 organic compounds Chemical class 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 claims description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 2
- 229920005594 polymer fiber Polymers 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical class CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000010453 quartz Substances 0.000 claims description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 2
- 229940096522 trimethylolpropane triacrylate Drugs 0.000 claims description 2
- 150000003673 urethanes Chemical class 0.000 claims description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical class [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 2
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Landscapes
- Polymerisation Methods In General (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
Buluş konusu mekanik ve termal dayanımı yüksek, ısı ile şekillendirilebilen yeni bir kompozit polimer malzeme ve bahsedilen kompozit polimer malzemenin sentezlenmesi için geliştirilen yöntem ile ilgilidir. Buluş kapsamında geliştirilen kompozit malzeme için temel bileşenler; bağlayıcı polimer oluşturulması için en az bir mono fonksiyonel akrilat veya metakrilat, ve en az bir çapraz bağlayıcı, polimer yapının oluşması için kullanılan en az bir başlatıcıdır. Viskozite arttırıcı ve mekanik dayanım için dolgu malzemesi eklenmektedir.The present invention relates to a novel thermoformable composite polymer material having high mechanical and thermal strength and to a method for synthesizing said composite polymer material. The basic components for the composite material developed in accordance with the invention are; at least one monofunctional acrylate or methacrylate for forming the binder polymer, and the at least one crosslinker is at least one initiator used to form the polymer structure. Viscosity increasing and filling material is added for mechanical strength.
Description
TARIFNAME YENI BIR KOMPOZIT POLIMER MALZEME Bulusun Konusu Bulus konusu mekanik ve termal dayanimi yüksek, isi ile sekillendirilebilen yeni bir kompozit polimer malzeme ve bahsedilen kompozit polimer malzemenin sentezlenmesi için gelistirilen yöntem ile ilgilidir. DESCRIPTION A NEW COMPOSITE POLYMER MATERIAL Subject of the Invention The subject of the invention is a new thermoformable composite with high mechanical and thermal strength. developed for synthesizing polymer material and said composite polymer material. relates to the method.
Teknigin Bilinen Durumu Gelisen malzeme teknolojileri ile birlikte polimer malzemeler oldukça yaygin kullanim alani bulmaktadir. Mutfak ve banyo tezgâhlari, iç duvar kaplamalari ve cephe giydirmeleri en yaygin kullanim alanlarindandir. Polimer malzemelerin kullanildiklari uygulama alanina göre mekanik dayanim, kolay temizlenebilir, yenilenebilir ve tamir edilebilir özellikleri barindirmasinin yaninda makul her türlü tasarima göre sekillendirilebilmeleri en önemli tercih sebepleridir. State of the Art With the developing material technologies, polymer materials are widely used. finds. Kitchen and bathroom countertops, interior wall coverings and facade cladding It is one of the common usage areas. According to the application area where polymer materials are used mechanical strength, easy to clean, renewable and repairable The most important thing is that they can be shaped according to any reasonable design, as well as are reasons for preference.
Mevcut durumda US3847865 numarali yayinda PMMA bilesimindeki malzemeler için agirlikça %55-80 araliginda aluminyum hidroksitin 0,1-70 mikron araligindaki partiküllerinden eklenerek termal dayanimi yüksek bir kompozisyon anlatilmistir. araliginda aluminyum hidroksit kullanildigi kompozisyon anlatilmistir. agirlikça %10-80 oraninda aluminyum hidroksit, magnezyum hidroksit ve baryum sülfat içeren gruptan seçilen bir dolgu malzemesinden olusan bir komposizyon tanimlanmistir. For materials in PMMA composition currently published in US3847865 from 0.1-70 micron particles of aluminum hydroxide in the range of 55-80% by weight A composition with high thermal resistance is explained by adding The composition in which aluminum hydroxide is used in the range is described. 10-80% by weight of aluminum hydroxide, magnesium hydroxide and barium sulfate A composition comprising a filling material selected from the group consisting of
US7345123 numarali yayinda floroakrilat çok fonksiyonlu akrilat kopolimerinin hazirlanmasi tarif edilmektedir. Burada flor içeren bir alkol, simetrik diizosiyanat ve hidroksi grubu içeren alkil metakrilattan hazirlanan karisim anlatilmaktadir. Bu yöntemin dezavantaji çevre ve insan sagligi için olumsuz sonuçlar dogurabilecek flor içerikli bilesiklerin kullanilmasidir. katkilanarak hazirlanan ve USS466756 numarali yayinda ise düz zincirli alifatik alkol ve yüksek kaynama noktasina sahip hidroksil grubu içeren bilesikler kullanilarak hazirlanan UV bozunmalarina karsi dirençli PMMA bilesimine ait bir kompozisyon anlatilmaktadir. Preparation of fluoroacrylate multifunctional acrylate copolymer in publication US7345123 is described. Here, a fluorine-containing alcohol, symmetrical diisocyanate and hydroxy group-containing The mixture prepared from alkyl methacrylate is described. The disadvantage of this method is environmental and is the use of fluorine-containing compounds that may cause negative consequences for human health. In the publication numbered USS466756, which was prepared with contribution, straight chain aliphatic alcohol and UV prepared using compounds containing hydroxyl group with high boiling point A composition of PMMA composition resistant to degradation is disclosed.
Bahsedilen teknigin bilinen durumunda UV dayanimi yüksek, kolay temizlenebilir veya termal dayanimi yüksek polimer kompozisyonlar gelistirilmis olup bulus kapsaminda tüm bu özelliklerin yani sira seramik partikülü içeren, isi ile sekillendirilebilen kompozit polimerler sentezlenmistir. Ilave olarak anti-bakteriyel, UV bozunmalarina karsi direnç, alev geciktirici, kolay temizlenebilir özelliklerinin yaninda renkli, fosforesans özellik gösteren ve isi ile renk degistirebilen özelliklerin saglanabildigi kompozit polimerler hazirlanmistir. In the known state of the mentioned technique, it has high UV resistance, easy to clean or thermal High-strength polymer compositions have been developed and all these thermoformable composite polymers containing ceramic particles as well as synthesized. In addition, anti-bacterial, resistance to UV degradation, flame retardant, In addition to its easy-to-clean properties, it is colored, phosphorescent and can be colored with heat. Composite polymers that can provide changeable properties have been prepared.
Bulusun Amaci Bulusun amaci mekanik ve termal dayanimi yüksek, isi ile sekillendirilebilen yeni bir kompozit malzeme gelistirmektedir. Purpose of the Invention The aim of the invention is to produce a new thermoformable composite with high mechanical and thermal strength. developing material.
Bulusun bir diger amaci ayni zamanda anti-bakteriyel, UV bozunmalarina karsi dirençli, alev geciktirici, kolay temizlenebilir olma özelliklerinin yaninda isi ile renk degistirebilme özelliklerinin kazandirildigi renkli olarak üretilebilen, fosforesans özellik gösteren yeni bir kompozit malzeme gelistirmektir. Another object of the invention is also anti-bacterial, resistant to UV degradation, flame retardant In addition to being retardant and easy to clean, it can change color with heat. It is a new product with phosphorescent properties that can be produced in colored to develop composite materials.
Tablolarin Açiklamasi Tablo 1. UV dayanimi için katki malzemesi içeren bulus konusu kompozit polimer malzeme örnekleri, UV dayanimi için katki malzemesi içermeyen bulus konusu kompozit polimer malzeme örnegi ve referans üründe renk degisim bilgileri Tablo 2. Alev testi sonuçlari Tablo 3. Hidrofobik katki malzemesi içeren kompozit ve kontrol grubu örneklerin su ile Tablo 4. Kimyasallardan etkilenme ve leke test sonuçlari Tablo 5. Anti-Bakteriyel test sonrasi besin ortaminda gözlenen CFU sayilari Tablo 6. Anti-Bakteriyel test sonrasi bakteri popülasyonundaki % azalma Tablo 7. Agirlikça %75 SF800 içeren kompozit polimere ait kesit alaninin çesitli bölgelerinden yapilan EDX analiz sonuçlari Sekillerin Açiklamasi: Sekil 1: Agirlikça % 25 oraninda SF800 içeren kompozit polimere ait SEM fotografi Sekil la: Agirlikça %25 oraninda SF800 içeren kompozit polimere ait büyütülmüs SEM fotografi Sekil 2: Agirlikça % 50 oraninda SF800 içeren kompozit polimere ait SEM fotografi Sekil 3: Agirlikça % 75 oraninda SF800 içeren kompozit polimere ait SEM fotografi Sekil 3a: Agirlikça % 75 oraninda SF800 içeren kompozit polimere ait büyütülmüs SEM fotografi Sekil 4a: Agirlikça % 75 oraninda SF800 içeren kompozit polimere ait kesit alaninin üst bölgesinden yapilan EDX analiz alanini gösteren SEM fotografi Sekil 4b: Agirlikça % 75 oraninda SF800 içeren kompozit polimere ait kesit alaninin alt bölgesinden yapilan EDX analiz alanini gösteren SEM fotografi Sekil Sa: Agirlikça % 75 oraninda SF800 içeren kompozit polimere ait kesit alaninin üst bölgesinden yapilan EDX analiz spektrumlari Sekil 5b: Agirlikça % 75 oraninda SF800 içeren kompozit polimere ait kesit alaninin alt bölgesinden yapilan EDX analiz spektrumlari Sekil 6: Agirlikça % 50 SF300 içeren kompozit polimere ait SEM fotografi Sekil 7: Agirlikça % 50 SF600 içeren kompozit polimere ait SEM fotografi Referanslarin Açiklamasi: 1: Agirlikça % 25 oraninda SF800 içeren kompozit polimer SEM görüntüsü la: Agirlikça %25 oraninda SF800 içeren kompozit polimere ait büyütülmüs SEM görüntüsü 2: Agirlikça % 50 oraninda SF800 içeren kompozit polimere ait SEM görüntüsü 3: Agirlikça % 75 oraninda SF800 içeren kompozit polimere ait SEM görüntüsü 3a: Agirlikça % 75 oraninda SF800 içeren kompozit polimere ait büyütülmüs SEM görüntüsü 4a: Agirlikça % 75 oraninda SF800 içeren kompozit polimere ait kesit alaninin üst bölgesinden yapilan EDX analiz alanini gösteren SEM görüntüsü 4b: Agirlikça % 75 oraninda SF800 içeren kompozit polimere ait kesit alaninin alt bölgesinden yapilan EDX analiz alanini gösteren SEM görüntüsü 5a: Agirlikça % 75 oraninda SF800 içeren kompozit polimere ait kesit alaninin üst bölgesinden yapilan EDX analiz spektrumu 5b: Agirlikça % 75 oraninda SF800 içeren kompozit polimere ait kesit alaninin alt bölgesinden yapilan EDX analiz spektrumu 6: Agirlikça % 50 SF300 içeren kompozit polimere ait SEM görüntüsü 7: Agirlikça % 50 SF600 içeren kompozit polimere ait SEM görüntüsü Bulusun Detayli Açiklamasi Bulus konusu mekanik ve termal dayanimi yüksek, isi ile sekillendirilebilen yeni bir kompozit malzeme ve bahsedilen kompozit malzemenin sentezlenmesi için gelistirilen yöntem ile Bulus kapsaminda radikalik katilma polimerizasyonu ile düsük sicakliklarda isisal olarak istenilen boyutlardaki kaliplarda hem yüksek seramik partikülü içeren hemde isi ile sekillendirilebilen kompozit polimerler sentezlenmistir. Bulus kapsaminda gelistirilen kompozit malzeme ayni zamanda anti-bakteriyel olma, UV bozunmalarina karsi dirençli olma, alev geciktirici olma, kolay temizlenebilir olma, renkli olma, fosforesans özellik ve isi ile renk degistirebilme gibi özelliklerin saglanabildigi bir malzemedir. Description of Tables Table 1. Composite polymer material of the invention containing additive material for UV resistance The samples of the invention are composite polymers that do not contain additives for UV resistance. color change information on material sample and reference product Table 2. Flame test results Table 3. Composite and control group samples containing hydrophobic additives were mixed with water. Table 4. Chemical exposure and stain test results Table 5. CFU counts observed in the nutrient medium after the Anti-Bacterial test Table 6. % decrease in bacterial population after Anti-Bacterial test Table 7. From various regions of the cross-sectional area of the composite polymer containing 75% SF800 by weight EDX analysis results Description of Figures: Figure 1: SEM photograph of composite polymer containing 25% by weight of SF800 Figure la: Enlarged SEM of composite polymer containing 25% by weight of SF800 photography Figure 2: SEM photograph of composite polymer containing 50% by weight of SF800 Figure 3: SEM photograph of composite polymer containing 75% by weight of SF800 Figure 3a: Enlarged SEM of composite polymer containing 75% by weight of SF800 photography Figure 4a: Upper cross-sectional area of composite polymer containing 75% by weight SF800 SEM photograph showing the EDX analysis area made from the Figure 4b: Lower cross-sectional area of composite polymer containing 75% by weight SF800 SEM photograph showing the EDX analysis area made from the Figure Sa: Upper cross-sectional area of composite polymer containing 75% by weight SF800 EDX analysis spectra from the region Figure 5b: Lower cross-sectional area of composite polymer containing 75% by weight SF800 EDX analysis spectra from the region Figure 6: SEM photograph of composite polymer containing 50% SF300 by weight Figure 7: SEM photograph of composite polymer containing 50% SF600 by weight Description of References: 1: SEM image of composite polymer containing 25% by weight of SF800 la: Magnified SEM image of composite polymer containing 25% by weight of SF800 2: SEM image of composite polymer containing 50% by weight of SF800 3: SEM image of composite polymer containing 75% SF800 by weight 3a: Magnified SEM image of composite polymer containing 75% by weight SF800 4a: Upper cross-sectional area of composite polymer containing 75% by weight SF800 SEM image showing the EDX analysis area made from the 4b: From the lower region of the cross-sectional area of the composite polymer containing 75% by weight SF800 SEM image showing the EDX analysis area performed 5a: Upper cross-sectional area of composite polymer containing 75% by weight SF800 EDX analysis spectrum made from the region 5b: From the lower region of the cross-sectional area of the composite polymer containing 75% by weight SF800 EDX analysis spectrum 6: SEM image of composite polymer containing 50% SF300 by weight 7: SEM image of composite polymer containing 50% SF600 by weight Detailed Description of the Invention The subject of the invention is a new thermoformable composite with high mechanical and thermal strength. material and the method developed for the synthesis of the said composite material. In the scope of the invention, it can be thermally produced at low temperatures by radical addition polymerization. in molds of desired sizes, containing both high ceramic particles and heat Composite polymers that can be formed have been synthesized. Developed within the scope of the invention composite material is also anti-bacterial, resistant to UV degradation being flame retardant, easy to clean, colored, phosphorescent and heat resistant. It is a material that can provide features such as color change.
Bulus konusu çalisma kapsaminda yukarida bahsedilen özellikleri içeren poliakrilik ve/veya polimetakrilik bazli malzemeler gelistirilmistir. Bu amaçla, yeterli mekanik özelligin saglanabilmesi için uygun seramik partikülleri içeren kompozit yapida polimerler sentezlenmistir. Ayrica kir-leke tutmayan yüzeylerin olusturulmasi ve/veya kolay temizlenebilir özelliginin iyilestirilmesinin yani sira zamana bagli kullanim esnasinda üründe olusan renk degisimi ve malzeme özelliginde meydana gelen bozulmalarin örnegin mekanik özellikler gibi malzemenin temel Özelliklerini kaybetmesinin önlenmesi saglanmistir.Within the scope of the study subject of the invention, polyacrylic and/or Polymethacrylic based materials have been developed. For this purpose, sufficient mechanical properties Composite polymers containing suitable ceramic particles to provide synthesized. In addition, the creation of dirt-stain-proof surfaces and / or easy In addition to improving its cleanable feature, the product can be damaged during time-dependent use. For example, mechanical discoloration and deterioration in material properties It is ensured that the material is prevented from losing its basic properties such as properties.
Dekoratif uygulamalar için termokromik (isi ile renk degistiren) ve fosforesans özelliklere sahip malzemeler gelistirilmistir. Thermochromic (change color with heat) and phosphorescent properties for decorative applications materials have been developed.
Bulus kapsaminda organik polimerlerin sentezi için çesitli monometakrilatlar ve çapraz baglayicilar ile organik polimerler hazirlanmistir. Sentezlenen örneklerdeki monometakrilat ve çapraz baglayicilarin tür ve polimer yapisindaki oranlari ile elde edilen malzeme özellikleri arasindaki iliski belirlenmis, böylece, termal ve mekanik dayanimi yüksek polimer sistemine yüzeyleri modifiye edilmis seramik partikülleri katkilanarak kompozit malzemeler hazirlanmistir. Yapilan yüzey modifikasyonu ile polimer yapisina yüksek oranda seramik partikülü katkilanmis, ayrica kompozit yapida homojen partikül dagilimi saglanmistir. Various monomethacrylates and cross-links for the synthesis of organic polymers within the scope of the invention organic polymers were prepared with binders. Monomethacrylate in synthesized samples and the material properties obtained by the type and proportions of cross-linkers in the polymer structure. The relationship between Composite materials by adding surface modified ceramic particles. has been prepared. With the surface modification made, a high percentage of ceramics to the polymer structure particle is added, and homogeneous particle distribution is provided in the composite structure.
Kullanilan seramik partiküllerinin tane boyutunun ve polimer yapisina katkilanma oraninin elde edilen kompozit malzemeler üzerine olan etkileri incelenmistir. Elde edilen kompozit malzemelerin bilinen ürünlere göre daha yüksek mikrosertlik degerlerine sahip ayni zamanda sekillendirilebilir özellikte oldugu sonucu elde edilmistir. Bunun yaninda sentezlenen kompozit malzemeye anti-bakteriyel, UV bozunmalarina karsi direnç, alev geciktirici, kolay temizlenebilir olma gibi temel özelliklerin kazandirilmasiyla malzemenin kullanim alani genisletilmistir. Ayrica elde edilen kompozit malzemenin renklendirilebilecegi, fosforesans özellik gösterebilecegi ve isi ile renk degistirebilme gibi özelliklerin saglanabilecegi gösterilmistir. Böylece sentezlenen kompozit malzemelerin bilinen ürünlere göre üstünlügü ortaya konulmustur. The particle size of the ceramic particles used and the rate of contribution to the polymer structure. The effects on the obtained composite materials were investigated. The resulting composite materials have higher microhardness values than known products, but also It has been obtained as a result that it is formable. Besides, the synthesized composite material anti-bacterial, resistance to UV degradation, flame retardant, easy the usage area of the material by gaining basic features such as being cleanable has been expanded. In addition, the obtained composite material can be colored, phosphorescence It can show properties and it can be provided with features such as changing color with heat. shown. Thus, the superiority of the synthesized composite materials over the known products has been revealed.
Bulus konusu çalismada gelistirilen kompozit malzemeler uygun partikül boyutuna sahip yüksek seramik partikül içerigi ile hem sert, hem de termoplastik özellik göstermektedir. Bu özelliklerin yaninda; anti-bakteriyel Özelligi ile hijyenik ortamlarin saglanmasinda; UV bozunmasina karsi dirençli olma özelligi sayesinde dis ortam kosullarinda kullanimi; yanmaz özelligi sayesinde kullanim kolayligi, görsel açidan çesitli renk ve özellikleri ile dekoratif amaçli kullanimi mümkün olmaktadir.Composite materials developed in the present study have suitable particle size. With its high ceramic particle content, it shows both hard and thermoplastic properties. This besides the features; In providing hygienic environments with its anti-bacterial feature; UV Its use in outdoor conditions, thanks to its resistance to degradation; fireproof Ease of use thanks to its feature, decorative visually with various colors and features. purpose is possible.
Bulus kapsaminda gelistirilen kompozit malzeme için temel bilesenler; baglayici polimer olusturulmasi için en az bir mono fonksiyonel akrilat ve/veya metakrilat, en az bir çapraz baglayici ve polimer yapinin olusmasi için kullanilan en az bir baslaticidir. The basic components for the composite material developed within the scope of the invention; binding polymer at least one mono-functional acrylate and/or methacrylate to form at least one cross binder and at least one initiator used to form the polymer structure.
Kompozit malzeme yapisina viskozite arttirici olarak ve mekanik dayanimin güçlendirilmesi için dolgu malzemesi eklenebilmektedir. Bahsedilen dolgu malzemesi tercihen yüzeyleri modifiye edilmis seramik partikülleridir. As a viscosity increaser in composite material structure and strengthening of mechanical strength Filling material can be added for Said filling material preferably surfaces modified ceramic particles.
Organik baglayici polimerin hazirlanmasinda mono fonksiyonel akrilat bilesikleri ve/veya mono fonksiyonel metakrilat bilesikleri kullanilmistir. Mono fonksiyonel akrilat bilesigi olarak metil akrilat, etil akrilat, propil akrilat; mono fonksiyonel metakrilat bilesigi olarak ise metil metakrilat, 2-hidroksi etil metakrilat, hidroksi propil metakrilat; özellikle metakrilat içeren monomerler tercih edilmistir. Polimerlerin hazirlanmasinda bu bilesikler ve/veya bunlarin karisimi kullanilabilmektedir. Tercihen 2-Hidroksietilmetakrilat ve/veya hidroksi propil metakrilat kullanilmistir. Mono-functional acrylate compounds and/or in the preparation of organic binder polymer monofunctional methacrylate compounds were used. As a mono-functional acrylate compound methyl acrylate, ethyl acrylate, propyl acrylate; methyl as a mono-functional methacrylate compound. methacrylate, 2-hydroxy ethyl methacrylate, hydroxy propyl methacrylate; especially methacrylate monomers are preferred. These compounds and/or their mix can be used. Preferably 2-Hydroxyethylmethacrylate and/or hydroxypropyl methacrylate is used.
Organik baglayici polimerin hazirlanmasinda çapraz baglayici için akrilat bilesikleri ve/veya metakrilat bilesikleri kullanildi. Trimetilol propan triakrilat, trimetilol propil triakrilat, pentaeritritol triakrilat tri -fonksiyonel akrilat bilesikleri olarak; pentaeritritol tetraakrilat bilesikleri tetra - fonksiyonel akrilat bilesigi olarak kullanilabilmektedir. Etilen glikol dimetakrilat, dietilen glikol dimetakrilat, trietilen glikol dimetakrilat, tetraetilen glikol dimetakrilat, diüretan dimetakrilat bilesikleri di - fonksiyonel metakrilat bilesikleri olarak kullanilabilmektedir. Polimerlerin hazirlanmasinda bu bilesikler ve/veya bunlarin karisimi kullanilabilmektedir. Tercihen tetraetilen glikol dimetakrilat ve/veya diüretandimetakrilat (DUDMA) kullanilmistir. Çapraz baglayici olarak kullanilan bilesikler yukarida bahsedilen mono fonksiyonel olarak kullanilan akrilat veya metakrilat bilesiklerinin molce % 1 - 75 özellikle % 5 - 50, daha çok % 20 - 45' i kadar olacak sekilde kompozisyona eklenmektedir. Acrylate compounds and/or for crosslinker in the preparation of organic binding polymer methacrylate compounds were used. Trimethylol propane triacrylate, trimethylol propyl triacrylate, pentaerythritol triacrylate as tri-functional acrylate compounds; pentaerythritol tetraacrylate compounds can be used as tetra-functional acrylate compound. ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, triethylene glycol dimethacrylate, tetraethylene glycol dimethacrylate, diurethane dimethacrylate compounds as di - functional methacrylate compounds can be used. These compounds and/or their mixtures in the preparation of polymers can be used. Preferably tetraethylene glycol dimethacrylate and/or diurethanedimethacrylate (DUDMA) is used. The above-mentioned compounds used as cross-linkers 1 - 75% by mole of acrylate or methacrylate compounds used as mono-functional It is added to the composition especially as 5 - 50%, more often 20 - 45%.
Organik baglayici polimerin hazirlanmasinda monomer karisimina baslatici olarak; tert-amil peroksi-2 etilhekzanoat (Trigonox 121); 1,1 Azobis (sikloheksankarbonitril); Benzoil peroksit; 4,4 azobis(4 siyanopentanoik) asit; 2,2'-azobis(2-metilpropionitrill; 2,2 azobis(2 metilpropiyonamid) dihidroklorür bilesiklerinden seçilmis bir veya birkaç madde ilave edilebilmektedir. Tercihen benzoil peroksit kullanilmistir. Baslatici orani toplam monomer karisimindaki yani eklenen mono fonksiyonel akrilat bilesikleri ve/veya mono fonksiyonel metakrilat bilesikleri ile çapraz baglayici olarak eklenen akrilat bilesikleri ve/veya metakrilat bilesiklerinin sahip oldugu çift bag mol sayisinin % 0,1 - 5, özellikle % 0,5 - 2 mol karsiligi olarak ilave edilmektedir. Polimerlerin hazirlanmasinda baslatici olarak bu bilesikler ve/veya bunlarin karisimi kullanilmaktadir. In the preparation of organic binder polymer, as initiator of monomer mixture; tert-agent peroxy-2 ethylhexanoate (Trigonox 121); 1,1 Azobis (cyclohexanecarbonitrile); Benzoyl peroxide; 4.4 azobis(4 cyanopentanoic) acid; 2,2'-azobis(2-methylpropionitrile; 2,2 azobis(2) Addition of one or more substances selected from methylpropionamide) dihydrochloride compounds can be achieved. Preferably benzoyl peroxide is used. Initiator ratio total monomer mono-functional acrylate compounds and/or mono-functional acrylate compounds and/or methacrylate added as crosslinkers with methacrylate compounds 0.1 - 5%, especially 0.5 - 2 mol%, of the number of double bond moles of their compounds is added as These compounds and/or as initiators in the preparation of polymers a mixture of these is used.
Dolgu malzemesi (filler) olarak; alumina, aluminyum trihidrat (ATH), aluminyum monohidrat, aluminyum hidroksit, aluminyum oksit, aluminyum sülfat, aluminyum fosfat, aluminyum silikat, borosilikat, kalsiyum sülfat, kalsiyum silikat, kalsiyum fosfat, kalsiyum karbonat, kalsiyum hidroksit, kalsiyum oksit, apatit, quartz, silika (SIOZ), cam bubbles ( küre), cam microspheres (mikroküre), cam fiber, cam flake, cam tozu, karbon fiber, seramik fiber, metal fiber, polimer fiber, karbon nanotüpleri, kil, baryum karbonat, baryum hidroksit, baryum oksit, baryum sulfat, baryum fosfat, baryum silikat, magnesyum sulfat, magnesyum silikat, magnesyum fosfat, magnesyum hidroksit, magnesyum oksit, kaolin, montmorillonit, bentonit, mika, seramik mikroküre (microspheres) ve seramik partikülü, toz talk, titanyum dioksit, silisyumkarbür yalniz basina ve/veya karisim seklinde kullanilabilmektedir. Kullanilan dolgu malzemelerinin partikül boyutlari 0,01 ila 100 pm (mikro metre) araliginda olabilmektedir. Dolgu malzemeleri tercihen mineral partikül ve/veya partikül karisimlari olarak tercih edilmektedir. Bulus kapsaminda Nano-SiOz (Aerosil kullanimi tercih edilmistir. Eklenen dolgu mazlemesi miktari temel bilesen olarak eklenen mono fonksiyonel akrilat bilesikleri ve/veya mono fonksiyonel metakrilat bilesikleri, çapraz baglayici için akrilat bilesikleri ve/veya metakrilat bilesikleri ve baslatici olarak eklenen maddenin toplaminin agirlikça %25-75'i ve daha çok %50-75'i arasinda olacaktir. As filling material (filler); alumina, aluminum trihydrate (ATH), aluminum monohydrate, aluminum hydroxide, aluminum oxide, aluminum sulfate, aluminum phosphate, aluminum silicate, borosilicate, calcium sulfate, calcium silicate, calcium phosphate, calcium carbonate, calcium hydroxide, calcium oxide, apatite, quartz, silica (SIOZ), glass bubbles (sphere), glass microspheres, glass fiber, glass flake, glass powder, carbon fiber, ceramic fiber, metal fiber, polymer fiber, carbon nanotubes, clay, barium carbonate, barium hydroxide, barium oxide, barium sulfate, barium phosphate, barium silicate, magnesium sulfate, magnesium silicate, magnesium phosphate, magnesium hydroxide, magnesium oxide, kaolin, montmorillonite, bentonite, mica, ceramic microspheres (microspheres) and ceramic particles, powdered talc, titanium dioxide, silicon carbide can be used alone and/or in the form of a mixture. Used The particle sizes of the filling materials range from 0.01 to 100 pm (micrometers). can happen. Filling materials are preferably mineral particles and/or particle mixtures. is preferred. Within the scope of the invention, Nano-SiOz (Aerosil use is preferred. The amount of filler added as a basic component monofunctional acrylate compounds and/or monofunctional methacrylate compounds, cross acrylate compounds and/or methacrylate compounds for binder and added as initiator it will be between 25-75% and more often 50-75% by weight of the total of the substance.
Partiküllerin organik matrikste homojen dagiliminin saglanmasina katkida bulunmak ve seramik partiküllerinin polimer yapisina kimyasal olarak baglanmasi için, seramik partiküllerinin yüzey modifikasyonu gerçeklestirilmektedir. Bu amaçla kullanilan modifikatörler; viniltrimetoksisilan, viniltrietoksisilan, 3-metakriloksipropiltrimetoksisilan, 3- MetakriloksipropiItrietoksisilan olabilmekte ve agirlikça partikül miktarinin % 0,5 - 10, daha çok % 1 - 7,5 ve özellikle % 2,5 - 5 oraninda kullanimi tercih edilmektedir. Çözücü olarak; metanol, etanol, propanol, izopropanol, bütanol, izobütanol, tersiyerbütanol, pentanol, 1- metoksi-Z-propanol, 2-bütoksi etanol, 1-propoksi propanol, 2-etil hekzanol, diaseton alkol, hekzan ve/veya bunlarin karisimlari, özellikle etil alkol ve/veya hekzan kullanilmaktadir. Çözücü olarak tercihen hekzan kullanilmistir. Yüzey modifikasyonu yapilacak seramik partikülün agirlikça iki kati kadar çözgen eklenmektedir. Contributing to the homogeneous distribution of particles in the organic matrix, and for the chemical bonding of the ceramic particles to the polymer structure. surface modification of the particles is carried out. used for this purpose modifiers; vinyltrimethoxysilane, vinyltriethoxysilane, 3-methacryloxypropyltrimethoxysilane, 3- It can be methacryloxypropylitriethoxysilane and the amount of particles by weight is 0.5 - 10%, more It is mostly preferred to use 1 - 7,5% and especially 2.5 - 5%. As a solvent; methanol, ethanol, propanol, isopropanol, butanol, isobutanol, tertiarybutanol, pentanol, 1- methoxy-Z-propanol, 2-butoxy ethanol, 1-propoxy propanol, 2-ethyl hexanol, diacetone alcohol, hexane and/or their mixtures, especially ethyl alcohol and/or hexane are used. Hexane is preferably used as the solvent. Ceramic to be surface modified twice as much solvent is added by weight of the particle.
Yüzey modifikasyonunun yapilacagi partiküller çözgen ortaminda tamamen dagitilmaktadir ve bu islem için bahsedilen seramik partikülü çözgen içerisine ilave edilerek bilyeli degirmende 3000rpm hizinda zirkon bilye kullanilarak yaklasik 30 dakika süre ile karistirilmaktadir. Ayri bir kapta hazirlanan modifikatör ve çözgen homojen olarak karistirilmakta ve bu karisim kuvvetlice karismakta olan seramik partikülü çözgen karisimina ilave edilmektedir. Çözgenin dörtte üçü seramik partikülü ve kalan dörtte biri modifikatör ile kullanilmaktadir. Tercihen modifikatör ve çözgen karisimi seramik partikül ve hekzan karisimina 2 g/dk süre ile ilave edilmektedir. Karisim 1 ila 6 saat arasinda oda kosullarinda karistirilmaktadir. Tercihen 3 saat 750 rpm hizinda karistirilmaktadir. Sonrasinda partikülleri kurutmak amaciyla etüvde 50 ila 150°C arasinda tercihen 1 ila 5 saat arasinda bekletilmektedir. Tercih edilen sicaklik 80°C'dir. Elde edilen modifiye seramik partikülleri yikanarak santrifüj ile çöktürülüp tekrar kurumaya birakilmaktadir. Seramik partikülleri yaklasik üç defa yikanmaktadir. Böylece kullanilan modifikatör silan uç kisimlari ile partikül yüzeyine metakril uç kisimlari ise polimer yapisina baglanmayi saglamaktadir. The particles on which the surface modification will be made are completely dispersed in the solvent environment. and for this process, the ceramic particle mentioned for this process is added into the solvent and the ball using 3000rpm zirconia ball in the mill for about 30 minutes. are mixed. The modifier and solvent prepared in a separate container are homogeneously mixed. is mixed and this mixture is mixed vigorously with the ceramic particle solvent mixture. is added. Three-quarters of the solvent is with ceramic particles and the remaining one-quarter is with the modifier. is used. Preferably a mixture of modifier and solvent, ceramic particles and hexane. It is added to the mixture for 2 g/min. Mixture 1 to 6 hours at room conditions are mixed. Preferably it is mixed at 750 rpm for 3 hours. Then the particles to dry in an oven between 50 and 150°C, preferably between 1 and 5 hours. is on hold. The preferred temperature is 80°C. The resulting modified ceramic particles It is washed and precipitated by centrifugation and left to dry again. ceramic particles It is washed about three times. Thus, the modifier used with silane ends and particle The methacryl ends on the surface provide bonding to the polymer structure.
Ayni islem kullanilan her seramik partikülü için gerçeklestirilmektedir. Ve yüzey modifikasyonu tamamlanmis partiküller kompozisyona eklenmektedir. Çözgen olarak tercihen hekzan kullanilabilir. The same process is performed for each ceramic particle used. and surface The modified particles are added to the composition. As a solvent preferably hexane can be used.
Kompozit polimer malzemelerin hazirlanmasinda yukaridaki temel bilesenler kullanilmaktadir. Bulus kapaminda kompozisyona eklenen ilave katki maddeleri ile Anti- bakteriyel, UV bozunmalarina karsi dirençli, alev geciktirici, kolay temizlenebilir olma özelliklerinin yaninda renkli olabilen, fosforesans özellik gösteren ve isi ile renk degistirebilen kompozit polimerler hazirlanabilmektedir. The above basic components in the preparation of composite polymer materials is used. With the additional additives added to the composition in the scope of the invention, Anti- bacterial, resistant to UV degradation, flame retardant, easy to clean In addition to its properties, it can be colored, show phosphorescent properties and change color with heat. composite polymers can be prepared.
Mikroorganizmalardan kaynaklanan mikrobiyal kirlilik insan yasaminda çesitli problemlere neden olmaktadir. Enfeksiyonlari önlemek için tamamen steril bir ortam olusturmak olanaksizdir fakat mikroorganizmalarin sayisinin artmasini engelleyecek önlemlerin alinmasi mümkündür. Günümüzde mikroorganizmalarin yogun olarak bulundugu alanlarda (mutfak, okul ve hastane donanimlari, ev esyalari, implant vs.) kullanilan malzemelerin anti-bakteriyel özellige sahip olarak üretilmesi büyük önem kazanmistir. Böylece daha saglikli ortamlarin olusturulmasi mümkün olabilmektedir. Microbial pollution caused by microorganisms causes various problems in human life. causes. Creating a completely sterile environment to prevent infections impossible, but taking measures to prevent the increase in the number of microorganisms possible. Today, in areas where microorganisms are concentrated (kitchen, school and hospital equipment, household goods, implants, etc.) anti-bacterial It has gained great importance to be produced with a special feature. Thus, healthier environments possible to be created.
Antibakteriyel özellik için organik ve/veya inorganik yapiya sahip anti-bakteriyel ajanlar ve bunlarin oranlari kompozisyona eklenmektedir. Anti-bacterial agents with organic and/or inorganic structure for antibacterial property and their proportions are added to the composition.
Bulus kapsaminda gelistirilen kompozit malzemeye anti-bakteriyel ajan olarak organik veya anorganik bilesiklerin eklenmesi mümkündür. Organik bilesikler olarak Klorhekzidin, Benzalkoyum klorür, Irgasan, Klorodimetilfenol arasindan seçilen bir veya birkaç madde kullanilabilmektedir. Anorganik olarak ise gümüs nano partikülleri ve/veya gümüs bilesikleri- kompleksleri, bakir nano partikülleri ve/veya bakir bilesikleri-kompleksleri kullanilabilmektedir. Antibakteriyel özellik için bu bilesiklerden herhangi birisi yalniz basina veya bu bilesiklerin karisimi kompozisyona eklenebilmektedir. Anti-bakteriyel ajan (madde) toplam karisim agirliginin (baglayici polimer olusturulmasi için mono fonksiyonel akrilat veya metakrilat, çapraz baglayici, polimer yapinin olusmasi için kullanilan baslatici ve dolgu kullanilmaktadir. As an anti-bacterial agent, organic or Addition of inorganic compounds is possible. Chlorhexidine as organic compounds, One or more substances selected from Benzalkoium chloride, Irgasan, Chlorodimethylphenol can be used. Inorganic silver nanoparticles and/or silver compounds complexes, copper nanoparticles and/or copper compounds-complexes can be used. Any of these compounds alone for antibacterial property or a mixture of these compounds can be added to the composition. Anti-bacterial agent (substance) the total weight of the mixture (mono-functional acrylate or methacrylate, crosslinker, initiator and filler used to form the polymer structure is used.
Günesten kaynaklanan yüksek enerjili radyasyon atmosfer tarafindan absorbe olur ve 280 - 400 nm (UV) araligindaki radyasyon dünyamiz yüzeyine ulasir. Bu radyasyonun enerjisi kovalent baglari kirmaya yeterli oldugundan organik polimer yapilarinin zamanla bozulmasina neden olmaktadir. Kompozit malzemelerde UV dayanim/direnç özelliginin saglanmasi amaciyla Hindered Amine Light Stabilizers (HALS), 2-hidr0ksi-4-n- oktoksibenzofenon, bis(2,2,6,6-tetrametiI-4-piperidinil)sebakat, 2-(2H benzotriazoI-Z-iI)-4,6- ditertpentilfenol bilesiklerinden herhangi birisi veya bu bilesiklerin birkaçi veya tamami karisim seklinde; agirlikça toplam karisim agirliginin (baglayici polimer olusturulmasi için mono fonksiyonel akrilat veya metakrilat, çapraz baglayici, polimer yapinin olusmasi için kullanilan baslatici ve dolgu malzemesi) % 01-15 arasinda, özellikle %0,1-10 arasinda, daha çok %O,5-5'i arasinda kompozisyona eklenebilmektedir. High-energy radiation from the sun is absorbed by the atmosphere and 280 - Radiation in the 400 nm (UV) range reaches the earth's surface. The energy of this radiation Since it is sufficient to break the covalent bonds, the organic polymer structures causes degradation. UV resistance/resistance properties of composite materials Hindered Amine Light Stabilizers (HALS), 2-hydroxy-4-n- octoxybenzophenone, bis(2,2,6,6-tetramethyl-4-piperidinyl)sebacate, 2-(2H benzotriazoI-Z-II)-4,6- any or some or all of the ditertpentylphenol compounds in the form of a mixture; by weight, the total weight of the mixture (for the formation of the binder polymer mono-functional acrylate or methacrylate, crosslinker, to form polymer structure initiator and filler material used) between 01-15%, especially between 0.1-10%, more It can be added to the composition between 0.5 and 5%.
Kompozit malzemelerde alev geciktirici özelligin saglanmasi amaciyla amonyum bromür, tribromoneopentil alkol, dibromoneopentil glikol, tribromofenol, polipentabromobenzil akrilat, pentabromobenzil akrilat, pentabromodifenol hekzabromociclododekan, oktabromodifenil oksit, dekabromodifenil oksit, tetrabromobisfenoI-A, gibsit (AI(OH3)), huntit (3MgC03 .CaCOa ), melamin fosfat, melamin borat, melamin siyanürat, daha çok melamin türevleri tercihen kullanilmis olup, toplam karisim agirliginin (baglayici polimer olusturulmasi için mono fonksiyonel akrilat veya metakrilat, çapraz baglayici, polimer yapinin olusmasi için kullanilan baslatici ve dolgu malzemesi) %1-50 arasinda, özellikle %5-40 arasinda, daha çok %10-30 arasinda kullanilabilmektedir. Bu bilesiklerden herhangi birisi tek basina veya bu bilesiklerin tamami veya birkaçinin karisimi kompozisyona eklenebilmektedir. Ammonium bromide for providing flame retardant properties in composite materials, tribromoneopentyl alcohol, dibromoneopentyl glycol, tribromophenol, polypentabromobenzyl acrylate, pentabromobenzyl acrylate, pentabromodiphenol hexabromociclododecane, octabromodiphenyl oxide, decabromodiphenyl oxide, tetrabromobisphenol-A, gibbsite (AI(OH3)), huntite (3MgCO3 .CaCOa), melamine phosphate, melamine borate, melamine cyanurate, more Melamine derivatives are preferably used, and it is determined that the total weight of the mixture (binding polymer mono-functional acrylate or methacrylate, crosslinker, polymer structure to form initiator and filling material used for the formation of It can be used between 10-30%. Any one of these compounds alone or all or a mixture of these compounds can be added to the composition.
Kompozit polimer malzemelerin pürüzsüz yüzeye sahip olmalari yüzeylerine temas eden çesitli kirleticilerin kolay temizlenmesine katki saglamaktadir fakat yeterli degildir. Bu nedenle yüzeylere hidrofobik özellik kazandirilmasi ile kolay temizlenebilir hale getirilmektedirler. Hidrofobik karakterin saglanabilmesi amaciyla bütil metakrilat, hekzilmetakrilat, viniliden poliflorit, fl0r0(met)akrilat (co)polimer, flor içerikli üretan bilesikleri, ror içerikli izosiyanat bilesikleri, 2-floroakrilat monomeri, 2,2,2-tri floro etil metakrilat, 1H,1H-heptaflorobütilmetakrilat, 1H,1H,5H - oktofloropentil metakrilat bilesiklerinden bir veya birkaçi karisim sekline kullanilabilmektedir. Daha çok 1H,1H,5H- oktofloropentil metakrilat ve/veya bütil metakrilat ve/veya hekzilmetakrilat tercihen kullanilmis olup, eklenen bilesik veya bilesiklerin karisimi toplam mono fonksiyonel akrilat ve/veya metakrilat karisiminin molce % 1 - 50'si arasinda kullanilmistir. Composite polymer materials have a smooth surface, It contributes to the easy cleaning of various pollutants, but it is not sufficient. This Therefore, it becomes easy to clean by imparting hydrophobic properties to the surfaces. they are brought. Butyl methacrylate in order to provide hydrophobic character, hexylmethacrylate, vinylidene polyfluoride, fluor0(meth)acrylate (co)polymer, fluorine-containing urethane compounds, isocyanate compounds containing ror, 2-fluoroacrylate monomer, 2,2,2-tri fluoro ethyl methacrylate, 1H,1H-heptafluorobutylmethacrylate, 1H,1H,5H - octofluoropentyl methacrylate One or more of its compounds can be used as a mixture. More 1H,1H,5H- Octofluoropentyl methacrylate and/or butyl methacrylate and/or hexylmethacrylate preferably was used and the added compound or mixture of compounds was used as a total mono-functional acrylate. and/or between 1 - 50 mole % of the methacrylate mixture.
Sentezlenen kompozit malzemenin renklendirilebilmesi amaciyla kullanilan pigmentler organik ve anorganik olmak üzere iki sinifa ayrilabilir. Basta titanyum dioksit (beyaz) olmak üzere, demir oksitler sari, kirmizi, siyah ve kahve renkleri kullanilabilmektedir. Organik pigmentlere azo boyalari, kinakridonun boyalari örnek olarak verilebilir. Kullanilan araliginda olmasi tercih edilmektedir. Pigmentler toplam karisim agirliginin (baglayici polimer olusturulmasi için mono fonksiyonel akrilat veya metakrilat, çapraz baglayici, polimer yapinin olusmasi için kullanilan baslatici ve dolgu malzemesi) % 1-50'si araliginda, özellikle %2-40 araliginda, daha çok %5-30'u araliginda eklenmektedir.Pigments used for coloring the synthesized composite material It can be divided into two classes, organic and inorganic. Being mainly titanium dioxide (white) Iron oxides yellow, red, black and brown colors can be used. Organic Examples of pigments include azo dyes and quinacridone dyes. Used range is preferred. Pigments are determined by the total mixing weight (binding polymer mono-functional acrylate or methacrylate, crosslinker, polymer structure to form initiator and filler material used for the formation of It is added in the range of 5-30%, mostly in the range of 5-30%.
Sentezlenen kompozit örneklere fosforesans özelligin saglanabilmesi için uygun partikül boyutlarindaki tercihen stronsiyum aluminyum oksit, magnezyum stronsiyum silikat ve çinko sülfit türevleri eklenebilmektedir. Eklenen bilesik veya karisimlari toplam karisim agirliginin (baglayici polimer olusturulmasi için mono fonksiyonel akrilat veya metakrilat, çapraz baglayici, polimer yapinin olusmasi için kullanilan baslatici ve dolgu malzemesi) %1-20'si araliginda, özellikle %2-15'i araliginda, daha çok %5-10'u araliginda kullanilabilmektedir. Particle suitable for providing phosphorescence properties to synthesized composite samples. sizes preferably strontium aluminum oxide, magnesium strontium silicate and zinc sulfide derivatives can be added. of the added compound or mixtures of the total mixture weight. (mono functional acrylate or methacrylate, cross-linked to form binder polymer) binder, initiator and filler used to form the polymer structure) 1-20% It can be used in the range, especially in the range of 2-15%, mostly in the range of 5-10%.
Sentezlenen kompozit örneklerde termokromik özellik için uygun partikül boyutlarinda termokromik pigmentler tercih edilmistir. Örnegin Spiroheterohalkalilar (spiropiranlar, spirooxazinler), schiff bazlar, biantronlar, poli(3-alkiltiyofen), 1,4-difenil-1,3- butadien'in zirkonosen kompleksi ve kobalt hekzasiyanoferrat kullanilabilecek termokromik pigmentlere örnek olarak verilebilir. Eklenecek pigmentler toplam karisim agirliginin (baglayici polimer olusturulmasi için mono fonksiyonel akrilat veya metakrilat, çapraz baglayici, polimer yapinin olusmasi için kullanilan baslatici ve dolgu malzemesi) % 1 - 50'si araliginda, özellikle %2-40 araliginda, daha çok %5-30'u araliginda eklenmektedir. Suitable particle sizes for thermochromic properties in synthesized composite samples. thermochromic pigments are preferred. For example, Spiroheterocyclics (spiropyranes, spirooxazines), schiff bases, biantrons, poly(3-alkylthiophene), 1,4-diphenyl-1,3-butadiene zirconocene complex and cobalt hexacyanoferrate are thermochromic pigments that can be used. can be given as an example. The pigments to be added must be determined by the total mixing weight (binding polymer mono-functional acrylate or methacrylate, crosslinker, polymer structure to form initiator and filling material used for the formation of It is added in the range of 5-30%, mostly in the range of 5-30%.
Bahsedilen ilave katki maddeleri kompozit malzemeye kazandirilmasi istenen özellige uygun olarak eklenebilmektedir. Tüm özelliklerin kazandirilmasi için bahsedilen bilesenler bahedilen oranlarda eklenebilmektedir. Ancak bahsedilen özelliklerin bazilarinin kazandirilmasi isteniyorsa aralarindan seçilen maddeler kompozisyona eklenerek istenen özellik kazandirilabilmektedir. The aforementioned additional additives are suitable for the properties desired to be imparted to the composite material. can be added as The components mentioned for gaining all the features are rates can be added. However, gaining some of the mentioned features If desired, the substances selected from among them can be added to the composition and the desired feature can be added. can be gained.
Bulus kapsaminda gelistirilen kompozisyonun hazirlanmasi için mono fonksiyonel akrilat veya metakrilat ile çapraz baglayici bilesik magnetik karistiricida homojen olana dek karistirilmaktadir. Karistirma hizi tercihen 500 rpm'dir. Bahsedilen karisima baslatici bilesik BPO ilave edilerek çözününceye kadar karistirilmaktadir. For the preparation of the composition developed within the scope of the invention, mono-functional acrylate or until the cross-linking compound with methacrylate is homogeneous in the magnetic stirrer. are mixed. The mixing speed is preferably 500 rpm. Said mixing initiating compound BPO is added and mixed until dissolved.
Ardindan kompozisyona kazandirilmasi istenen ilave özellikler için ki bunlar anti-bakteriyel olma, UV bozunmalarina karsi dirençli olma, alev geciktirici olma, kolay temizlenebilir olma, renkli olma, fosforesans özellik gösterme ve isi ile renk degistirebilme özelligi olarak belirtilebilir ilgili ve yukarida anlatilan kimyasallardan tercih edilenler belirtilen oranlarda ilave edilmektedir. Sonrasinda yüzeyi yukarida anlatildigi gibi modifiye edilen dolgu malzemeleri (seramik partiküller) ilave edilerek homojen bir karisim elde edinceye dek karistirilmaktadir. Elde edilen karisim teflon kaliba tamamen doldurularak malzemenin hava ile temasinin ortadan kaldirilmasi için üzerleri polietilen folyo ile kapatilarak 70°C' de polimerlestirilmektedir. Bu islem için karisim 70°C' de yaklasik 2 saat etüvde bekletilmektedir. Then for the additional properties desired to be imparted to the composition, which are antibacterial being resistant to UV degradation, being flame retardant, being easy to clean, being colored, showing phosphorescence and changing color with heat. may be specified related and preferred chemicals from the above-mentioned chemicals in the specified ratios is added. Afterwards, the surface is modified as described above. materials (ceramic particles) are added until a homogeneous mixture is obtained. are mixed. The mixture obtained was completely filled into the Teflon mold and the material was air-conditioned. In order to eliminate their contact with is polymerized. For this process, the mixture is incubated at 70°C for approximately 2 hours. is on hold.
Yukaridada belirtildigi gibi temel bilesenler mono fonksiyonel akrilat veya metakrilat, çapraz baglayici bilesik olarak kullanilan akrilat bilesikleri ve/veya metakrilat bilesikleri ve baslatici olarak kullanilan bilesiktir. As mentioned above, the main components are mono functional acrylate or methacrylate, cross acrylate compounds and/or methacrylate compounds used as binders and initiator compound used as
Bulus kapsaminda mekanik ve termal dayanimi yüksek, isi ile sekillendirilebilen yeni bir kompozit malzeme elde edilmis ve ayni zamanda yapisina eklenen katki maddeleri ile de farkli özellikler kazandirilmistir. Within the scope of the invention, a new form of heat-formable, high mechanical and thermal resistance composite material is obtained and at the same time with the additives added to its structure. different features have been added.
Bulus kapsaminda gelistirilen kompozit malzemelerin içerisine eklenen UV dayanimi için katki maddesi, alev geciktirici özellik kazandiran katki maddesi, hidrofobik özellik kazandiran katki malzemesi, anti-bakteriyel özellik kazandirilmasi için eklenen katki malzemesinin etkilerinin görülebilmesi için testler yapilmis ve elde edilen sonuçlar asagida belirtilmistir. Additive for UV resistance added to composite materials developed within the scope of the invention. additive that gives flame retardant properties, additive that gives hydrophobic properties material, the effects of the additive material added to give it anti-bacterial properties. Tests were carried out in order to be seen and the results obtained are given below.
Tablo 1. UV dayanimi için katki malzemesi içeren bulus konusu kompozit polimer malzeme örnekleri, UV dayanimi için katki malzemesi içermeyen bulus konusu kompozit polimer malzeme örnegi ve referans üründe renk degisim bilgileri Test Öncesi Test Sonrasi Örnekler Tabloda; (A): Seramik partikül içeren referans ürün (B): Dolgu malzemesi (seramik partikül) ve temel bilesenleri içeren ancak UV dayanimi için katki malzemesi içermeyen bulus konusu kompozit polimer malzeme UV dayaniminin test edilmesi için bulus kapsaminda hazirlanan ve UV dayanimi için katki malzemesini içeren UV-0,1, UV-0,25, UV-0,5 ve UV-1 örnekler, bulus kapsaminda gelistirilen dolgu malzemesi (seramik partikül) ve temel bilesenleri içeren fakat UV dayanimi için herhangi bir katki malzemesi içermeyen örnek (B) ve kontrol grubu olarak UV katki malzemesi içermeyen ancak seramik partikülü içeren kontrol grubu olarak kullanilan referans ürün (A) birlikte solar box test cihazinda 168 saat isinlandirilmistir. Isinlandirma öncesi ve sonrasinda renk degerlerini ifade eden L, a, b degerleri renk ölçüm cihazi ile belirlenmistir.Table 1. Composite polymer of the invention containing additives for UV resistance material samples, subject of the invention without additives for UV resistance Composite polymer material sample and color change information in reference product Before Test After Test Examples In the table; (A): Reference product containing ceramic particles (B): Contains filler material (ceramic particle) and basic components but for UV resistance Composite polymer material of the invention that does not contain additives Additives for UV resistance prepared within the scope of the invention for testing UV resistance. UV-0.1, UV-0.25, UV-0.5 and UV-1 samples containing the containing filler material (ceramic particle) and basic components but for UV resistance sample (B) without any additives and UV additive as control group reference material used as the control group containing ceramic particles The product (A) was heated together in the solar box tester for 168 hours. Before heating and Afterwards, L, a, b values, which express color values, were determined with a color measuring device.
Elde edilen degerlerden AE, renk degisim miktarlari hesaplanmis olup sonuçlar tablo 1'de gösterilmistir. UV dayanimi testi için SABOSTAB UV 70 (SUV70) bis(2,2,6,6-tetrametiI-4- piperidinil)sebakat) katki maddesi kullanilmistir. UV-O,1 ifadesi ile kastedilen ilgili örnegin UV dayanimi için eklenen katki malzemesini agirlikça % 0,1 içerdigi, UV-O,25 ile kastedilen ilgili örnegin UV dayanimi için eklenen katki malzemesini agirlikça % 0,25 içerdigi, UV-O,5 ile kastedilen ilgili örnegin UV dayanimi için eklenen katki malzemesini agirlikça % 0,5 içerdigi ve UV-1 ile kastedilen ilgili örnegin UV dayanimi için eklenen katki malzemesini agirlikça % 1 içerdigidir. AE, color change amounts were calculated from the obtained values, and the results are in Table 1. shown. SABOSTAB UV 70 (SUV70) bis(2,2,6,6-tetramethyl-4- for UV resistance testing) piperidinyl)sebacate) additive was used. UV-O,1 refers to, for example, UV It contains 0.1% by weight of the additive material added for its durability, UV-0.25 means the relevant For example, it contains 0.25% by weight of the additive material added for UV resistance, with UV-O,5 means that the relevant sample contains 0.5% by weight of the additive added for UV resistance, and What is meant by UV-1, for example, the additive material added for UV resistance is 1% by weight. it contains.
Elde edilen sonuçlar degerlendirildiginde; insan gözünün renk degisimini fark edebilme alt siniri için AE = 3 oldugu göz önüne alindiginda, test süresi içerisinde B örnegi; UV-O,1; UV- UV-0,5 ve UV-l örneklerindeki renk degisim degerleri sirasiyla 2,05 ve 1,92' dir. Bu elde edilen sonuçlar dogrultusunda katkinanan ajanin etkin konsantrasyonu %1 olarak belirlenmistir. Böylece sentezlenen kompozit polimerlerde özellikle günes isinlari sebebiyle meydana gelen foto-oksidasyon proseslerinden, serbest radikaller ve peroksit ara ürünlerden kaynakli polimer yapisindaki bozulmalara bagli problemlerin engellenebilecegi görülmüstür.When the results obtained are evaluated; the ability to detect the color change of the human eye Considering that AE = 3 for the limit, B sample within the test period; UV-O,1; UV- Color change values in UV-0.5 and UV-1 samples are 2.05 and 1.92, respectively. get this In line with the results obtained, the effective concentration of the contributing agent was determined as 1%. has not been determined. Thus, in the composite polymers synthesized, especially due to sun rays. from photo-oxidation processes, free radicals and peroxide intermediates. It has been observed that the problems related to the deterioration in the welded polymer structure can be prevented.
Ayrica bu süre içerisinde (A) numunesi olumsuz yönde etkilenirken bulus kapsaminda sentezlenen UV-O,5 ve UV-1 örneklerinde bu etkiler ortadan kaldirilmistir.In addition, while the sample (A) is adversely affected during this period, it is within the scope of the invention. These effects were eliminated in the synthesized UV-O,5 and UV-1 samples.
Tablo 2. Alev testi sonuçlari Örnekler Gözlem l Gözlem ll Alevde 5 saniye Alev etkisinden uzaklastirildiktan C sonra yanmaya sonra artarak yanma devam basliyor. ediyor.Table 2. Flame test results Examples observation l observation ll 5 seconds in flame After being removed from the flame effect C then continue burning then increasing starting. is doing.
Alevde 15. Alev etkisinden uzaklastirildiktan B saniyeden sonra sonra artarak yanma devam yanma basliyor. ediyor.In Flame 15. After being removed from the flame effect After B seconds, increasing and burning continues. it's starting to burn. is doing.
Alevde 15' Alev etkisinden uzaklastirildiginda A saniyeden sonra . N. .. .. kendiliginden sonuyor. yanma basliyor.15' in Flame When removed from Flame effect After a second. N. .. .. ends on its own. it's starting to burn.
Alevde 20' Alev etkisinden uzaklastirildiginda kendiliginden sonuyor. yanma basliyor.20' in Flame When removed from Flame effect ends on its own. it's starting to burn.
Alevde 20' Alev etkisinden uzaklastirildiginda 2YG saniyeden sonra . .-. .. .. kendiliginden sonuyor. yanma basliyor.20' in Flame When removed from Flame effect After 2HG seconds. .-. ..... ends on its own. it's starting to burn.
Alevde 20' Alev etkisinden uzaklastirildiginda kendiliginden sonuyor. yanma basliyor.20' in Flame When removed from Flame effect ends on its own. it's starting to burn.
Alevde 15' Alev etkisinden uzaklastirildiginda 4YG saniyeden sonra . _u_ .. .. kendiliginden sonuyor. yanma basliyor.15' in Flame When removed from Flame effect After 4HG seconds . _u_ .. .. ends on its own. it's starting to burn.
Alevde 15' Alev etkisinden uzaklastirildiginda kendiliginden sonuyor. yanma basliyor.15' in Flame When removed from Flame effect ends on its own. it's starting to burn.
Alevde 15' Alev etkisinden uzaklastirildiginda 6YG saniyeden sonra . ..,. .. .. kendiliginden sonuyor. yanma basliyor.15' in Flame When removed from Flame effect After 6HG seconds . ..,. ..... ends on its own. it's starting to burn.
Alevde 15. Alev etkisinden uzaklastirildiktan 3 7YG saniyeden sonra saniye sonra kendiliginden yanma basliyor. sönüyor.In Flame 15. After being removed from the flame effect 3 7YG automatically after second after second it's starting to burn. goes out.
Alevde 15. Alev etkisinden uzaklastirildiktan 2 8YG saniyeden sonra saniye sonra kendiliginden yanma basliyor. sönüyor.In Flame 15. After being removed from the flame effect 2 8HG automatically after second after second it's starting to burn. goes out.
Alevde 15. Alev etkisinden uzaklastirildiktan 2 9YG saniyeden sonra saniye sonra kendiliginden yanma basliyor. sönüyor. In Flame 15. After being removed from the flame effect 2 9HG automatically after second after second it's starting to burn. goes out.
Tabloda; A: Seramik partikül içeren referans ürün B: Dolgu malzemesi (seramik partikül) ve temel bilesenleri içeren ancak yanma geciktirici özellik için katki malzemesi içermeyen bulus konusu kompozit malzeme C: Yalnizca temel bilesenleri içeren, seramik partikül ve yanma geciktirici özellik için katki malzemesi içermeyen bulus konusu kompozit malzeme 1YG-9YG: Bulus kapsaminda gelistirilen ve seramik partikülü ve yanma geciktirici katki malzemesi içeren örnek anlaminda kullanilmistir. In the table; A: Reference product containing ceramic particles B: Fire retardant containing filler material (ceramic particle) and basic components but Composite material of the invention that does not contain additives for the property C: Additive for ceramic particle and fire retardant property, containing only essential components composite material which is the subject of the invention 1YG-9YG: Ceramic particle and fire retardant additive developed within the scope of the invention sample with material meaning is used.
Alev testi için bulus kapsaminda hazirlanan örnekler yani yanma geciktirici katki malzemesini içeren örnekler, yine bulus kapsaminda gelistirilen temel bilesenler ve seramik partikülü içeren ancak yanma geciktirici ajan içermeyen örnek (B) ve bulus kapsaminda gelistirilen ancak yalnizca temel bilesenleri içeren yani yanma geciktirici veya dolgu malzemesi içermeyen kompozit örnek (C) ve seramik partikülü içeren ancak yanma geciktirici içermeyen referans ürün (A) kullanilmis ve karsilastirma sonuçlari yukarida tablo 2'de belirtilmistir. For the flame test, the samples prepared within the scope of the invention, that is, the fire retardant additive material. samples, basic components and ceramic particles developed within the scope of the invention. Example (B) containing but not flame retardant agent and but containing only essential components i.e. fire retardant or filler material composite sample (C) without and containing ceramic particles but no flame retardant reference product (A) was used and the comparison results are given in table 2 above.
Bulus kapsaminda gelistirilen seramik partikülü veya yanma geciktirici katki malzemesi içermeyen yalnizca temel bilesenleri içeren örnek (C) aleve maruz birakildiginda 5 saniyede yanmaya baslayip, alev etkisinden uzaklastirildiktan sonra yanmaya artarak devam etmektedir. Ancak bulus kapsaminda gelistirilen ve temel bilesenlere ilave olarak seramik partikül içeren ve yanma geciktirici katki malzemesi içermeyen örnek (B) ise 15. saniyede yanmaya baslamis ve bu durum tutusma süresini kompozit malzemeye eklenen seramik partikülünün uzattigini göstermistir. Yalniz bu süre sonunda alev etkisinden uzaklastirilan örnekte yanma devam etmistir. 1YG, 2YG ve 3YG' de artan oranlarda ilave edilen melamin fosfat, (B) örnegine göre alev alma süresini 20 saniyeye çikartmis, ayrica alev etkisinden uzaklastirilan örneklerdeki alevin kendiliginden hemen sönmesini saglamistir. 4Y, 5Y, EY' de artan oranlarda ilave edilen melamin borat, (B) örnegine göre alev alma süresinde degisiklik meydana getirmez iken, alev etkisinden uzaklastirilan örneklerdeki alevin kendiliginden söndügü görülmektedir. 7Y, 8Y, 9Y' de artan oranlarda ilave edilen melamin siyanurat, (B) örnegine göre alev alma süresinde degisiklik meydana getirmez iken, alev etkisinden uzaklastirildiktan 3 saniye içerisinde örneklerdeki alevin kendiliginden söndügü görülmektedir.Ceramic particle or fire retardant additive developed within the scope of the invention sample (C) containing only essential components, not containing After it starts to burn and is removed from the flame effect, it continues to burn increasingly. is doing. However, in addition to the basic components developed within the scope of the invention, ceramic The sample (B), which contains particles and does not contain fire retardant additives, is on the 15th second. started to burn and this caused the ignition time of the ceramic added to the composite material. showed that the particle elongated. Only those that are removed from the flame effect at the end of this period In the example, the burning continued. Melamine phosphate added at increasing rates in 1HG, 2YG and 3YG, flammability according to the (B) example increased its duration to 20 seconds, in addition, the flame in the samples removed from the flame effect it made it go out on its own right away. Melamine borate added at increasing rates in 4Y, 5Y, EY, flammability according to the (B) sample While it does not cause a change in the duration of the flame, the flame in the samples removed from the flame effect appears to be self-extinguishing. Melamine cyanurate added at increasing rates in 7Y, 8Y, 9Y, flammability according to (B) example While it does not cause any change in its duration, 3 seconds after being removed from the flame effect. It is seen that the flame in the samples extinguished by itself.
Elde edilen sonuçlar degerlendirildiginde melamin fosfat eklenerek hazirlanan örneklerin melamin borat ve melamin siyanurat eklenerek hazirlanan örneklere göre daha uzun sürede yanmaya basladigi ve alev etkisi kaldirildiginda kendiliginden hemen alevin söndügü görülmüstür. Ayrica elde edilen sonuçlar bulus kapsaminda sentezlenen örneklerin (B ve C) A numunesine göre daha uzun sürede yanmaya basladigini göstermektedir. Bu durumda bulus kapsaminda gelistirilen kompozit malzemenin referans ürüne oranla daha geç sürede yandigi görülmektedir. When the results obtained are evaluated, it is seen that the samples prepared by adding melamine phosphate It takes longer time than the samples prepared by adding melamine borate and melamine cyanurate. when it starts to burn and when the flame effect is removed, the flame immediately goes out. has been seen. In addition, the results obtained show that the samples (B and C) synthesized within the scope of the invention are It shows that it starts to burn in a longer time than the sample. In this case, find It is observed that the composite material developed within the scope of the project burns later than the reference product. is seen.
Tablo 3. Hidrofobik katki malzemesi içeren kompozit polimer malzeme ve kontrol grubu örneklerinin su ile yapmis olduklari temas açilari Örnek Temas Açisi ( °) A 78,8 B 56,8 1HF 75,8 2HF 76,2 3HF 79,3 4HF 75,6 5HF 76,5 6HF 79,1 7HF 76,6 8HF 81,4 9HF 85,3 Tabloda; A: Seramik partikül içeren referans ürün B: Dolgu malzemesi (seramik partikül) ve temel bilesenleri içeren ancak hidrofobik özellik için katki malzemesi içermeyen bulus konusu kompozit malzeme Bulus kapsaminda gelistirilen kompozit malzemelere hidrofobik katki maddesi eklenerek su ile yaptiklari temas açilari ölçülmüstür. Referans ürün (A), bulus kapsaminda gelistirilen ve seramik partikül içeren ancak hidrofobik ajan içermeyen ürün (B) ve bulus kapsaminda gelistirilen hem seramik partikül hem de hidrofobik ajan içeren diger örnekler test kapsaminda karsilastirilmistir. 1HF-9HF hidrofobik katki malzemesi içeren ve seramik partikülü içeren bulus konusu kompozit malzemeyi temsil etmektedir. 1HF-3HF ile gösterilen örneklere ayni hidrofobik katki malzemesi artan oranlarda eklenmektedir. 4HF-6HF ile belirtilen örneklere ayni hidrofobik katki malzemesi yine artan oranlarda eklenmektedir ancak bahsedilen katki malzemesi ilk üç örnege eklenenden farklidir. Ve 6HF-9HF arasinda bir diger hidrofobik katki malzemesi yine artan oranlarda eklenmistir. Table 3. Composite polymer material containing hydrophobic additive material and control group contact angles of samples with water Sample Contact Angle (°) A 78.8 B 56.8 1HF 75.8 2HF 76.2 3HF 79.3 4HF 75.6 5HF 76.5 6HF 79.1 7HF 76.6 8HF 81.4 9HF 85.3 In the table; A: Reference product containing ceramic particles B: For hydrophobic property containing filler material (ceramic particle) and basic components Composite material of the invention that does not contain additives By adding hydrophobic additive to the composite materials developed within the scope of the invention, water The contact angles they made with them were measured. Reference product (A) is a product developed within the scope of the invention and product (B) containing ceramic particles but not hydrophobic agent and within the scope of the invention Other samples developed containing both ceramic particles and hydrophobic agents were tested. are compared in scope. Invention subject containing 1HF-9HF hydrophobic additive material and ceramic particle represents the composite material. The same hydrophobic properties as the 1HF-3HF additives are added at increasing rates. Same as examples specified with 4HF-6HF hydrophobic additive material is also added at increasing rates, but said additive material is different from that added to the first three examples. And another hydrophobic additive between 6HF-9HF material was added in increasing proportions.
Tablo 3 incelendiginde eklenen hidrofobik katki maddesi orani ile yüzey temas açilari artmaktadir. 1H,1H,5H - oktofloropentil metakrilat (OFPMA) ile hazirlanan 1HF - 2HF - 3HF sistemlerinin yüzey temas açilari ayni oranlarda Bütilmetakrilat (BlVlA) kullanilarak hazirlanan 4HF - 5HF - 6HF örnekleri ile neredeyse ayni degerleri göstermektedir. 7HF, 8HF ve 9HF örneklerinde kullanilan Hekzilmetakrilat (HMAY nin artan alkil zincir uzunlugu ile temas açilarinda artmalar görülmektedir. When Table 3 is examined, the surface contact angles with the hydrophobic additive ratio added increasing. 1H,1H,5H - 1HF - 2HF - 3HF prepared with octofluoropentyl methacrylate (OFPMA) The surface contact angles of the systems prepared using Butylmethacrylate (BlVlA) in the same proportions. It shows almost the same values as 4HF - 5HF - 6HF samples. 7HF, 8HF and 9HF Hexylmethacrylate used in the samples (contact with the increasing alkyl chain length of HMAY) increases are observed.
Ayrica hidrofobik katki malzemesi eklenmis bulus kousu kompozit malzemeler, hidrofobik katki malzemesini içermeyen referans ürün (A) ve de bulus konusu hidrofobik ajan içermeyen kompozit malzeme (B) için kimyasallardan etkilenme ve leke test sonuçlari asagida tablo 4'te görülmektedir. Sonuçlar incelendiginde örnek yüzeylerin su ile yapmis olduklari temas açilarinin artmasi ile yüzeylerden Iekelerin temizlenmeleri dogru orantili olarak degismektedir. (A) numunesi %5 NaOH ve %5 NaOCl' den etkilenirken 9HF sistemi test edilen kimyasallarin hiçbirisinden etkilenmemistir. In addition, the subject of the invention composite materials with added hydrophobic additives, hydrophobic Reference product (A) without additive and hydrophobic agent of the invention Chemical exposure and stain test results for composite material (B) without shown in table 4 below. When the results were examined, the sample surfaces were made with water. With the increase in the contact angles they are in, the removal of stains from the surfaces is directly proportional. as it changes. While sample (A) is affected by 5% NaOH and 5% NaOCl, the 9HF system is tested. It was not affected by any of the chemicals.
Tablo 4. Kimyasallardan etkilenme ve leke test sonuçlari .. %1 Metilen Ornekler %10 HAc %5 NaOH %70 EtOH %5 NaOCI . _ A Etki yok Matlasma Etki yok Matlasma Etki yok B Etki yok Matlasma Matlasma Matlasma Lekelenme 1HF Etki yok Matlasma Etki yok Etki yok Az Lekelenme 2HF Etki yok Matlasma Etki yok Etki yok Etki yok 4HF Etki yok Matlasma Etki yok Etki yok Lekelenme 5HF Etki yok Az Matlasma Etki yok Etki yok Lekelenme 6HF Etki yok Etki yok Etki yok Az Matlasma Etki yok 7HF Etki yok Az Matlasma Etki yok Etki yok Etki yok 8HF Etki yok Az Matlasma Etki yok Etki yok Az Lekelenme Tablo 5. Anti-Bakteriyel test sonrasi besin ortaminda gözlenen CFU sayilari E. coh' S. aureus Örnek Etki Süresi Etki Süresi Tablo 6. Anti-Bakteriyel test sonrasi bakteri popülasyonundaki % azalma E. coli / % Azalma S. aureus I % Azalma Örnek Etki Süresi Etki Süresi Tablo 5 ve 6 için; A: Seramik partikül içeren referans ürün olarak kullanilmistir. Table 4. Chemical exposure and stain test results .. 1% Methylene Examples 10% HAc 5% NaOH 70% EtOH 5% NaOCI . _ A No effect Matting No effect Matting No effect B No effect Matting Matting Matting Staining 1HF No effect Matting No effect No effect Little Staining 2HF No effect Matting No effect No effect No effect 4HF No effect Matting No effect No effect Staining 5HF No effect Little matting No effect No effect Staining 6HF No effect No effect No effect Little Matting No effect 7HF No effect Little matting No effect No effect No effect 8HF No effect Little matting No effect No effect Less staining Table 5. CFU counts observed in the nutrient medium after the Anti-Bacterial test E. coh' S. aureus Example Duration of Effect Duration of Effect Table 6. % decrease in bacterial population after Anti-Bacterial test E. coli / % Decrease S. aureus I % Decrease Example Duration of Effect Duration of Effect For Tables 5 and 6; A: It was used as a reference product containing ceramic particles.
Tablo 5 ve 6'da gösterildigi üzere hazirlanan örneklere anti-bakteriyel özellikte katki malzemesi eklenmis ve testler gerçeklestirilmistir. Seramik partikül içeren ve herhangi bir katki malzemesi içermeyen referans ürün (A) ile bulus kapsaminda gelistirilen ve hem seramik partikül hem de anti-bakteriyel özellik kazandiran katki malzemesini içeren örnekler (1AB-6AB) karsilastirilmistir. Örnekler 1'den 6'ya dogru artan miktarlarda katki malzemesi içermektedir. Testler için organik anti-bakteriyel madde kullanilmistir. Örneklerin antibakteriyel aktivite testleri yapilmadan önce her iki bakterinin, Laktoz Broth (LB) ortaminda bakteriyel populasyon artisi egrileri olusturulmustur. Çalisilan kosullar altinda bakterilerin populasyon artisinin maksimum oldugu süre E. coli için 5.30 saat, S. aureus için 6 Sivi besi ortami içinde inkübe edilen bakteri inokulumlari seyreltilerek sterile hale getirilmis ve bulus kapsaminda gelistirilen kompozit malzeme ve referans ürünün yüzeylerine uygulanmistir. Yüzeyler 37°C'deki inkübatöre koyularak 30, 60 ve 90 dakika etki sürelerinde bekletildikten sonra, steril kati besi yerleri üzerine ters çevrilerek yerlestirilmis ve inkübatöre koyulmustur. 12 saat sonra yüzeylerdeki bakteri kolonileri sayilarak, koloni olusturan ünite Sentezlenen anti-bakteriyel özellik kazandirilmis polimer kompozit örneklerin E. Coli ve S.Anti-bacterial additives to the samples prepared as shown in Tables 5 and 6 material was added and tests were carried out. containing ceramic particles and Developed within the scope of the invention with the reference product (A) without additives and Examples containing both ceramic particles and additives that provide anti-bacterial properties (1AB-6AB) are compared. Additives in increasing quantities from examples 1 to 6 contains. Organic anti-bacterial material was used for the tests. Before the antibacterial activity tests of the samples, both bacteria were tested in Lactose Broth. Bacterial population growth curves were generated in (LB) medium. under working conditions The maximum population growth time of bacteria is 5.30 hours for E. coli, 6 hours for S. aureus. Bacterial inoculums incubated in liquid media were diluted and sterilized. and the surfaces of the composite material and reference product developed within the scope of the invention. has been applied. The surfaces were placed in an incubator at 37°C for exposure times of 30, 60 and 90 minutes. After waiting, they were placed upside down on sterile solid media and placed in the incubator. has been set. After 12 hours, the bacterial colonies on the surfaces are counted and the colony forming unit is counted. E. Coli and S. of the synthesized polymer composite samples with antibacterial properties.
Aureus bakteri türlerine karsi etkinlik testleri incelenmistir. Örneklerin bakteriler ile 30, 60 ve 90 dakika temas süreleri sonrasinda gözlenen CFU sayilari Tablo 5'te, bakteriyel popülasyondaki bagil azalmalar tablo 6'da gösterilmistir. Efficacy tests against Aureus bacterial species were investigated. Samples with bacteria 30, 60 and CFU numbers observed after 90 min contact times are shown in Table 5, bacterial The relative reductions in the population are shown in Table 6.
Tablo 7. Agirlikça %75 SF800 içeren kompozit polimere ait kesit alaninin çesitli bölgelerinden yapilan EDX analiz sonuçlari Element Agirlik, % Bilesik, % Formül Sekil 1'de agirlikça % 25 oraninda SF, sekil 2'de agirlikça % 50 oraninda SF, sekil 3'te agirlikça % 75 oraninda SF görülmektedir. Sekillerde görülen açik renkli bölgeler seramik partiküllerini, daha koyu olarak görülen bölgeler ise polimer yapisini göstermektedir. Elde edilen sonuçlar dogrultusunda polimer matriks içerisinde seramik partiküllerinin homojen dagildigi görülmektedir. Table 7. From various regions of the cross-sectional area of the composite polymer containing 75% SF800 by weight EDX analysis results Element Weight, % Compound, % Formula In figure 1, 25% by weight of SF, figure 50% by weight of SF in 2, fig. 75% SF by weight at 3 is seen. The light colored areas in the figures show the ceramic particles as darker. The regions seen show the polymer structure. In line with the results obtained It is seen that the ceramic particles are homogeneously dispersed in the polymer matrix.
SF sirasiyla 10, 3 ve 2 pm' dir. Sekil 1, sekil 2, sekil 3'te farkli oranlarda SF800 partikülünün kullanimina ait görüntü, sekil 6'da agirlikça % 50 SF ve sekil 7'de agirlikça % 50 SF görülmektedir. Sekiller incelendiginde SF 800 seramik partiküllerinin artan oranlarda miktari ile partiküller arasindaki bosluklarin kullanilan seramik partiküllerinin polidispers özelliginden dolayi azaldigi ve homojen dagilimin oldugu sonucuna ulasilmistir. Elde edilen bu sonuçlar kompozit malzemelerin sertliklerinin daha küçük seramik partikülleri ile hazirlanan sistemlerde daha yüksek olmasi konusundaki düsünceleri desteklemektedir. SF is 10, 3 and 2 pm respectively. Shape 1, figure 2, image of the use of SF800 particles in different proportions in figure 3, figure 6 50 wt% SF and figure 7 wt% 50 SF is seen. figures When examined, the particles with increasing amounts of SF 800 ceramic particles Due to the polydisperse property of the ceramic particles used, the spaces between It was concluded that there was a decrease and homogeneous distribution. These results are composite. The hardness of the materials is higher in systems prepared with smaller ceramic particles. supports the ideas about being high.
Sekil la'da agirlikça %25 oraninda SF800 içeren kompozit polimere ait büyütülmüs SEM görüntüsü (la) ve sekil 3a'da agirlikça % 75 oraninda SF800 içeren kompozit polimere ait büyütülmüs SEM görüntüsü (33) görülmektedir. Sekil la ve sekil 3a incelendiginde kullanilan seramik partiküllerinin yüzey modifikasyonu sayesinde partiküllerin polimer yapisi ile çevrelendigi ve aglomerasyonun neredeyse olmadigi görülmektedir. Enlarged SEM of composite polymer containing 25% by weight of SF800 in Figure la image (la) and Figure 3a of the composite polymer containing 75% by weight of SF800. The magnified SEM image (33) is shown. When Figure la and Figure 3a are examined, the Thanks to the surface modification of the ceramic particles, the polymer structure of the particles It is seen that it is surrounded and agglomeration is almost non-existent.
Elde edilen kompozit polimer örneklerinde seramik partiküllerinin dagilimlarinin homojen olup olmadiginin arastirilmasi amaciyla agirlikça %75 oraninda SF800 seramik partikülü içeren kompozit polimerin kesit alaninin farkli bölgelerinden elementel analizler yapilmistir.Homogeneous distribution of ceramic particles in the obtained composite polymer samples. 75% by weight of SF800 ceramic particles to investigate whether Elemental analyzes were made from different parts of the cross-sectional area of the composite polymer containing
Sekil 4a'da agirlikça % 75 oraninda SF800 içeren kompozit polimere ait kesit alaninin üst bölgesinden yapilan EDX analiz alanini gösteren SEM görüntüsü (4a) ve Sekil 4b'de agirlikça analiz alanini gösteren SEM görüntüsü (4b) görülmektedir. Sekil Sa'da Agirlikça % 75 oraninda SF800 içeren kompozit polimere ait kesit alaninin üst bölgesinden yapilan EDX analiz spektrumu (5a) ve sekil 5b'de Agirlikça % 75 oraninda SF800 içeren kompozit polimere ait kesit alaninin alt bölgesinden yapilan EDX analiz spektrumu (5b) görülmektedir. Ayrica yukarida verilen tablo 7'de agirlikça %75 SF800 içeren kompozit polimere ait kesit alaninin çesitli bölgelerinden yapilan EDX analiz sonuçlarini göstermektedir. Sekiller ve tablodan anlasildigi üzere söz konusu seramik partiküllerinin etiketlenen bölgelerdeki dagilimlari homojene yakindir. In Figure 4a, the upper cross-sectional area of the composite polymer containing 75% by weight SF800 SEM image (4a) showing the EDX analysis area made from the region of weight and in Figure 4b. The SEM image (4b) showing the analysis area is shown. 75% by Weight in Figure Sa EDX made from the upper region of the cross-sectional area of the composite polymer containing SF800 composite polymer containing 75% by weight of SF800 in the analysis spectrum (5a) and figure 5b. The EDX analysis spectrum (5b) made from the lower region of the cross-sectional area (5b) is shown. Moreover In Table 7 above, the cross-sectional area of the composite polymer containing 75% SF800 by weight It shows the EDX analysis results from various regions. From figures and table As it is understood, the distribution of the said ceramic particles in the labeled regions is close to homogeneous.
Bulus kapsaminda gelistirilen kompozit malzeme ile mekanik ve termal dayanimi yüksek, isi ile sekillendirilebilen yeni bir kompozit malzeme elde edilmis ve ayrica anti-bakteriyel, UV bozunmalarina karsi dirençli, alev geciktirici, kolay temizlenebilir, isi ile renk degistirebilen, renkli olarak üretilebilen, fosforesans özellik gösteren yeni bir kompozit malzeme elde edilmistir. With the composite material developed within the scope of the invention, it has high mechanical and thermal resistance, A new composite material that can be shaped with resistant to decomposition, flame retardant, easy to clean, change color with heat, A new composite material with phosphorescent properties that can be produced in color is obtained. has been made.
Sekil 1a Sekil 4a Sekil 4b Sekil 5b Sekil 5a ' :17** iâ-:Igipîifgv 7 Figure 1a Figure 4a Figure 4b Figure 5b Figure 5a ' :17** iâ-:Igipîifgv 7
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| CN113999545A (en) * | 2021-12-02 | 2022-02-01 | 攀钢集团重庆钛业有限公司 | Titanium dioxide for high-light-resistance decorative paper and preparation method thereof |
-
2016
- 2016-03-22 TR TR2016/03688A patent/TR201603688A2/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113999545A (en) * | 2021-12-02 | 2022-02-01 | 攀钢集团重庆钛业有限公司 | Titanium dioxide for high-light-resistance decorative paper and preparation method thereof |
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