TH40959B - Ant and termite control chemicals, and methods for applying these chemicals? - Google Patents

Abstract

DC60 (23/08/43) This invention relates to the preparation of a highly effective termite control agent to protect wood materials such as trees, fences, timber sleepers, etc., and structures such as places of worship, churches, houses, outbuildings, factories, etc., from termites, and to control termites that are harmful to crops or humans. It consists of an active ingredient of these hydrazine derivatives, represented by the general structural formula (I): (chemical formula) (l) (where A represents one of the structural formulas) as follows: -N(R4)-N=C- -N(R4)-N(R5)-CH- -C(R4)=N-N- -CH(R4)-NH-N- (chemical formula) (chemical formula) (chemical formula) (chemical formula) X, X, X, X (where R4 and R5 are H,C1-C6 alkyl, etc.; X is a substituent group 1-5 selected from H, halogen, and (halo)C1-C6 alkyl); R1 is H or C1-C6 alkyls; R2 and R3 are H, OH, C1-C6 alkyls, phenylcarbonyls, etc.; Y is a substituent group 1 to 5 selected from H, halogen, nitro, and cyanobacteria; Z is halogen, cyanobacteria, C1-C6 alkyls, etc.; and W is O or S. And a method for the application of termite control agents. This invention involves the preparation of a very good termite control agent to protect wood materials such as trees, fences, timber sleepers, etc., and structures such as places of worship, churches, houses, outbuildings, factories, etc., from termites, and to control termites that harm crops or humans. It consists of an active ingredient of these hydrazine derivatives, represented by the general structural formula (I): (chemical formula) (l) (where A represents one of the structural formulas) as follows: -N(R4)-N=C- -N(R4)-N(R5)-CH- -C(R4)=N-N- -CH(R4)-NH-N- (chemical formula) (chemical formula) (chemical formula) (chemical formula) X, X, X, X (where R4 and R5 are H, C1-C6 alkyl, etc.; X is a substituent group 1-5 selected from H, halogen, and (halo) C1-C6 alkyl); R1 is H or [C1-C6 alkyls; R2 and R3 are H,OH, C1-C6 alkyls, phenylcarbonyls, etc.; Y is a substituent group 1 to 5 selected from H, halogen, nitro, and cyanobacteria; Z is halogen, cyanobacteria, C1-C5 alkyls, etc.; and W is O or S]; and methods for applying the substance to control ants and termites.

Claims (7)

1. Control ants and termites with special characteristics. It consists of the active ingredients of these substances that are hydrazine derivatives represented by structural formula 1: (Chemical formula) (l), where A represents -N (R4) -N = C- (Chemical formula) X (where Where R4 represents the hydrogen atom or C1-C6 alkyl group and X represents the same or different displacement group 1 to 5 groups selected from the hydrogen atom, halogen atom, C1-C6 Al group. Kills and halo groups C1-C6 alkyl), -N (R4) -N (R5) -CH- (chemical formula) X (where R4 and X are described above, and R5 represents R5. Hydrogen atom, C1-C6 alkyl carbonyl group or phenylcarbonyl group Which may have the same or different substitution groups, 1 to 2 selected from Group consisting of C1-C6 alkyl groups), -C (R4) = NN- (chemical formula) X (where R4 and X are described above), or -C (R4) = NN- ( Chemical formula) X (where R4 and X are described above); R1 represents the hydrogen atom or the C1-C6 alkyl group, R2 and R3. Or different Denoted by hydrogen atom, hydroxyl group, C1-C6 alkyl group, C1-C6 alkoxy group, C1-C6 alkyl carbonyl group. Or phenol carbonyl Y group to represent the same or different substitution groups 1 to 5 selected from the group containing Hydrogen atoms, halogen atoms, nitro groups and cyanos; Z represents halogen atoms, Cyano group, C1-C6 alkyl group, C1-C6 alkyl halo group, C1-C6 alkyl group, C1-C6 alkyl group. C, C1-C6 alkylthio, C1-C6 alkylsulfinyl group or C1-C6 alkylsulfonyl group; And W represents the oxygen atom. Or sulfur atom 2. Control substances for ants and termites According to claim I, represented by the structural formula (I-1); (Chemical formula) (l-1) where R1 represents the hydrogen atom or the C1-C6 alkyl groups, R2 and R3, which may be the same Or differently instead of hydrogen atom, hydroxyl group, C1-C6 alkyl group, C1-C6 alkoxy group, C1-C6 alkyl carbonyl group or phenylcarb group. Bonil R4 represents the hydrogen atom or C1-C6 alkyl group, X represents the identical displacement group. Or different 1 to 5 groups to choose from among that include Hydrogen atom, halogen atom, C1-C6 alkyl group and C1-C6 halo group Y alkyl represents the same displacement group. Or different 1 to 5 groups to choose from among Containing hydrogen atoms, halogen atoms, nitro and Cyano-Z groups instead of halogen atoms, cyanocene, C1-C6 alkyl group, C1-C6 alkyl halo group, Group C1-C6 alkoxy, C1-C6 halo alkoxi, C1-C6 halo alkylthio, C1-C6 alkylsulfinyl group or Ha Lo C1-C6 alkylsulfonyl; And W represents the oxygen atom. Or sulfur atom 3. Control substances for ants and termites According to claim I, represented by the structural formula (I-2) (chemical formula) (l-2), where R1 represents the hydrogen atoms or C1-C6 alkyl groups, R2 and R3, which may be the same. Or different Denoted by hydrogen atom, hydroxyl group, C1-C6 alkyl group, C1-C6 alkoxy group, C1-C6 alkyl carbonyl group. Or among phenyl carbonyls; R4 represents hydrogen atom or C1-C6 alkyl group, R5 alkyl group, C1-C6 alkyl carbonyl group or phenylcarbonyl group. This may have 1 to 2 identical or different displacement groups selected from the C1-C6 alkyl X representing 1 to 5 identical or different displacement groups selected from the hydrogen atomic group. , Atomic halogen, C1-C6 alkyl group and C1-C6 halo group Y alkyl represents 1 to 5 identical or different displacement groups selected from the composite group. With hydrogen atoms, halogen atoms, nitro groups and cyanos; Z represents halogen atoms, Cyano group, C1-C6 alkyl group, C1-C6 alkyl halo group, C1-C6 alkyl group, C1-C6 alkyl group. C, C1-C6 alkylthio, C1-C6 alkylsulfinyl group or C1-C6 alkylsulfonyl group; And W represents the oxygen atom. Or sulfur atom 4. Ants and termites control substances According to the claim I, represented by the structural formula (I-3) as follows: (Chemical formula) (l-3), where R1 represents the hydrogen atom or the C1-C6 alkyl groups, R2 and R3, which may be the same. Or different, instead of hydrogen atom, hydroxyl group, C1-C6 alkyl group, C1-C6 alkoxy group, C1-C6 alkyl carbonyl group or phenylka group. The carbonyl R4 represents the hydrogen atom or the C1-C6 alkyl group, the X represents the 1-5 identical or different displacement groups selected from the containing group. Hydrogen atom, halogen atom, C1-C6 alkyl group and C1-C6 halogen group Y alkyl represents the same or different 1 to 5 group selected from the constituent groups. With hydrogen atoms, halogen atoms, nitro groups and cyano groups 2 instead of halogen atoms, cyanoce group, C1-C6 alkyl group, C1-C6 alkyl group, Group C1-C6 alkoxy, C1-C6 halo alkoxi, C1-C6 halo alkylthio, C1-C6 alkylsulfinyl group or Ha Lo C1-C6 alkylsulfonyl; And W represents the oxygen atom. Or sulfur atom 5. Ants and termites control substances According to claim 1, which can be represented by the formula The structure is as follows (I-4); (Chemical formula) (l-4) where R1 represents the hydrogen atom or the C1-C6 alkyl group, R2 and R3, which may be the same or different. Denoted by hydrogen atom, hydroxyl group, C1-C6 alkyl group, C1-C6 alkoxy group, C1-C6 alkyl carbonyl group. Or phenylcarbonyl group, R4 for hydrogen atom or C1-C6 alkyl group, X for same or different displacement group, 1 to 5 groups selected from the composite group. With hydrogen atoms, halogen atoms, C1-C6 alkyl groups and C1-C6 halo groups, the Y alkyl represents 1 to 5 identical or different displacement groups selected from the constituent groups. With hydrogen atoms, halogen atoms, nitro groups and cyano-Z groups instead of halogen atoms, Cyano group, C1-C6 alkyl group, C1-C6 alkyl halo group, Group C1-C6 alkoxy, C1-C6 alkyl thio, C1-C6 alkylsulfinyl group and C1-C6 alkylsulfo group. jasper; And W represents the oxygen atom. Or sulfur atom 6. Methods for the application of control agents to termite ants consisting of the action of the wooden part. And the soil around which ants and termites live With the amount of control agents, ants, termites that yield the claim 7.Methods for the application of termite ant-control agents according to claim 6, where the hydrazine derivative represented by the general structural formula (I) is the hydrazine derivative referred to in any of the clauses 2 to 5.