TH114184B - Direct and selectable production of ethyl Acetate from acetic acid utilizing a binary metal-backed catalyst. - Google Patents
Direct and selectable production of ethyl Acetate from acetic acid utilizing a binary metal-backed catalyst.Info
- Publication number
- TH114184B TH114184B TH901003496A TH0901003496A TH114184B TH 114184 B TH114184 B TH 114184B TH 901003496 A TH901003496 A TH 901003496A TH 0901003496 A TH0901003496 A TH 0901003496A TH 114184 B TH114184 B TH 114184B
- Authority
- TH
- Thailand
- Prior art keywords
- acetic acid
- ethyl acetate
- direct
- backed
- catalyst
- Prior art date
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title claims abstract 15
- XEKOWRVHYACXOJ-UHFFFAOYSA-N acetic acid ethyl ester Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 title claims abstract 12
- 239000003054 catalyst Substances 0.000 title claims abstract 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052802 copper Inorganic materials 0.000 claims abstract 2
- 239000010949 copper Substances 0.000 claims abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 2
- 239000001257 hydrogen Substances 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims abstract 2
- 229910052697 platinum Inorganic materials 0.000 claims abstract 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N Rhenium Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 229910052803 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 1
- 229910052750 molybdenum Inorganic materials 0.000 claims 1
- 239000011733 molybdenum Substances 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 229910052763 palladium Inorganic materials 0.000 claims 1
- 229910052702 rhenium Inorganic materials 0.000 claims 1
- 238000007493 shaping process Methods 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
Abstract
กระบวนการสำหรับการผลิตที่เลือกเฟ้นได้ของเอทิล อะซิเตทโดยปฏิกิริยาของเฟสไอ สำหรับกรดอะซิติคบนสารผสมของตัวเร่งปฏิกิริยาการไฮโดรจีเนทเพื่อสร้างรูปร่างเป็นเอทิล อะซิเตท จะถูกเปิดเผยและถูกอ้างสิทธิ ในรูปลักษณะของการประดิษฐ์นี้ ปฏิกิริยาของกรดอะซิติคและ ไฮโดรเจนบนแพลตินัมและคอปเปอร์ที่ถูกสนับสนุนบนซิลิกา จะผลิตเอทิล อะซิเตทในเฟสไอ อย่างเลือกเฟ้นได้ที่อุณหภูมิประมาณ 250ซ Process for selective production of ethyl. Acetate by vapor phase reaction For the acetic acid on the hydrogenate catalyst mixtures to form ethyl acetate is revealed and claimed. In the form of this invention Acetic acid reaction, and Hydrogen on platinum and copper supported on silica produces ethyl acetate in the vapor phase. Selectively at temperatures around 250C
Claims (1)
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TH114184B true TH114184B (en) | 2012-05-31 |
| TH114184A TH114184A (en) | 2012-05-31 |
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