SU833479A1 - Method of producing reducing gas containing hydrogen sulfide and carbon monoxide - Google Patents

Method of producing reducing gas containing hydrogen sulfide and carbon monoxide Download PDF

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Publication number
SU833479A1
SU833479A1 SU792833294A SU2833294A SU833479A1 SU 833479 A1 SU833479 A1 SU 833479A1 SU 792833294 A SU792833294 A SU 792833294A SU 2833294 A SU2833294 A SU 2833294A SU 833479 A1 SU833479 A1 SU 833479A1
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SU
USSR - Soviet Union
Prior art keywords
reducing gas
carbon monoxide
gas containing
containing hydrogen
hydrogen sulfide
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SU792833294A
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Russian (ru)
Inventor
Валерий Яковлевич Скрипко
Николай Геннадиевич Вилесов
Владимир Михайлович Распутько
Николай Николаевич Левчук
Владимир Иванович Калько
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Институт Газа Академии Наук Усср
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Priority to SU792833294A priority Critical patent/SU833479A1/en
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Publication of SU833479A1 publication Critical patent/SU833479A1/en

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(54) СПОСОБ ПОЛУЧЕНИЯ ВОССТАНОВИТЕЛБНОГО ГАЗА, СОДЕРЖАЩЕГО СЕРОВОДОРОД И ОКИСБ УГЛЕРОДА(54) METHOD FOR OBTAINING RECOVERY GAS CONTAINING HYDROGEN AND CARBON OXIDE

Через слой твердого углеродсодержащего материала, например, кокса, каменного или древесного угл , продувают газовую .смесь, содержащую сернистый ангидрид, кислород и пары воды с объемным соотношением 1:2-3:1, При этом протекают реакцииA gas mixture containing sulfurous anhydride, oxygen and water vapor with a volume ratio of 1: 2-3: 1 is blown through a layer of solid carbon-containing material, for example, coke, coal or charcoal.

SO1.+7С + НгО + 2Ог Hj + 7СО S02+9C + НлО + ЗОг НгЗ + 9СО SO1. + 7С + НгО + 2Ог Hj + 7СО S02 + 9C + НлО + ЗОг НгЗ + 9СО

Процесс экзотермический и в зоне взаимодействи  кислорода и углеродсодержащего сырь  развиваетс  температура до 1500°С, необходима  дл  протекани  реакции между сернистым ангидридом, углеродсодержащим материалом и парами воды.The process is exothermic and a temperature of up to 1500 ° C develops in the zone of interaction between oxygen and carbon-containing raw materials, which is necessary for the reaction to take place between the sulfur dioxide, carbon-containing material and water vapor.

Пример. В алундовый трубчатый реактор диаметром 28мм загружают 100 г каменного угл  фракции 5 мм, помещают его в печь и нагревают до 800°С. Затем в реактор подают смесь, содержащую сернистый ангидрид , пары воды и кислород в количествах соответственно л/ч: 13,5 13,5 и 27.Example. In an alundum tubular reactor with a diameter of 28 mm, 100 g of coal of a fraction of 5 mm are loaded, placed in a furnace and heated to 800 ° C. Then a mixture containing sulfuric anhydride, water vapor and oxygen in amounts, respectively, l / h, is fed into the reactor: 13.5 13.5 and 27.

После подачи реагентов обогрев печи отключают, температура в реакторе повыщаетс  до 1000°С. Полученный восстановительный газ имеет следующий состав, %об: HzS 12; СО 78; СО 3; Н« 3; 4.After the supply of reagents, the heating of the furnace is turned off, the temperature in the reactor rises to 1000 ° C. The resulting reducing gas has the following composition,% vol: HzS 12; CO 78; CO 3; H "3; four.

Предлагаемый способ позвол ет исключить расход дефицитного продукта-серы и затраты тепла на испарение серы.The proposed method makes it possible to eliminate the consumption of a scarce sulfur product and the cost of heat for the evaporation of sulfur.

Технико-экономическа  оценка предлагаемого способа показывают, что при мощности предпри ти  10 тыс т в год экономи  составит 151 тыс руб.The technical and economic assessment of the proposed method shows that with a plant capacity of 10 thousand tons per year, the savings will be 151 thousand rubles.

Claims (2)

1.«Industrial and Engineering Chemistry 37, 1945, № 5, p. 469-474.1. “Industrial and Engineering Chemistry 37, 1945, No. 5, p. 469-474. 2.Авторское свидетельство СССР № 618341, кл. С 01 В 17/16, 05.08.78.2. USSR author's certificate number 618341, cl. From 01 to 17/16, 08/05/78.
SU792833294A 1979-10-29 1979-10-29 Method of producing reducing gas containing hydrogen sulfide and carbon monoxide SU833479A1 (en)

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SU792833294A SU833479A1 (en) 1979-10-29 1979-10-29 Method of producing reducing gas containing hydrogen sulfide and carbon monoxide

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SU792833294A SU833479A1 (en) 1979-10-29 1979-10-29 Method of producing reducing gas containing hydrogen sulfide and carbon monoxide

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SU833479A1 true SU833479A1 (en) 1981-05-30

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2517510C2 (en) * 2008-07-18 2014-05-27 Эвоник Дегусса Гмбх Reactor and method of use
RU2621755C2 (en) * 2012-06-22 2017-06-07 Эвоник Дегусса Гмбх Reactor and method for hydrogen sulfide obtaining
RU2623766C2 (en) * 2012-06-22 2017-06-29 Эвоник Дегусса Гмбх Reactor and method for hydrogen sulfide obtaining

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2517510C2 (en) * 2008-07-18 2014-05-27 Эвоник Дегусса Гмбх Reactor and method of use
RU2621755C2 (en) * 2012-06-22 2017-06-07 Эвоник Дегусса Гмбх Reactor and method for hydrogen sulfide obtaining
RU2623766C2 (en) * 2012-06-22 2017-06-29 Эвоник Дегусса Гмбх Reactor and method for hydrogen sulfide obtaining

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