SU73173A1 - Method of two-stage electrolytic separation of cobalt from nickel - Google Patents
Method of two-stage electrolytic separation of cobalt from nickelInfo
- Publication number
- SU73173A1 SU73173A1 SU304532A SU304532A SU73173A1 SU 73173 A1 SU73173 A1 SU 73173A1 SU 304532 A SU304532 A SU 304532A SU 304532 A SU304532 A SU 304532A SU 73173 A1 SU73173 A1 SU 73173A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- nickel
- cobalt
- electrolytic separation
- dimethylglyoxime
- stage electrolytic
- Prior art date
Links
Landscapes
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Description
Предлагаемый способ двухступенчатого отделени кобалг та от никел заключаетс в следующем. Первоначально из растворов кобальта, содер;ка;дих сравнительно большое KOVTHMCCTBG , выдел етс загр зне- ны11 кобальт при погиощи электролиза с нерастворимыми анодами, ириготозлениыми из кобальтокрелгниевого сплава. При электролизе раствороз , содержа:цих кобальт и никель в 4:1, получаетс .катодный осадок, в котором отношеи е кобальта к и 1кел;о равно 30:1. Электролиз ведетс при температуре 50 - 60, при плоткюсти тока на катоде 4-8 au/rf/j- при рН раствора 1,5-2 и iij}ii суммарном содержанш коба;1ьта и никел 30-70 г/.-.The proposed method for the two-stage separation of cobalt from nickel is as follows. Initially, a relatively large KOVTHMCCTBG is released from cobalt solutions, cobalt is contaminated, and electrolyzed with insoluble anodes, irigotozlenymi from cobalt-ramnium alloy. In electrolysis, dissolving, containing: cich cobalt and nickel in 4: 1, a cathode precipitate is obtained, in which the ratio of cobalt to and 1 kel is about 30: 1. Electrolysis is conducted at a temperature of 50–60, with a current density of 4–8 au / rf / j– on the cathode, with a pH of 1.5–2 and iij} ii the total content of coba, 1g and nickel 30–70 g /.-.
О5разую:ца с ири этом свободиа i-inc.iOTa нейтрализуетс jeлo.Oruha: iri inca ii ia inca ii is neutralized jelo.
Полученные при первом электролизе осад:;и используютс в качестве ааодов второго электролиза, в результате которого получаетс кобачьт , Г1)акт ;чески свободный от . Второй электролиз проводитс при рМ 5-6 раствора и введении в электрол ;т буферных добавок и г,ро1юд 1цих солей.The sieges obtained during the first electrolysis are:; and used as aodes of the second electrolysis, which results in cobacht, G1), which is free from. The second electrolysis is carried out with a pM 5-6 solution and the addition of buffer additives and r, 1 × salts to the electrolyte.
Во избежание накоплени никел в электролите, ои удал етс осаждеиием диметилглиоксимом, который в электролит в виде суепеизии .In order to avoid accumulation of nickel in the electrolyte, it is removed by precipitation with dimethylglyoxime, which is in the electrolyte in the form of creeping.
р-1ейтрализацн образующейс при это.м свободной серной кислоты производитс добавлением щелочи, осиовиых ил: углекислых соединений НЛП гидрата окиси кобальта.The p-1 neutralization resulting from this. of free sulfuric acid is produced by the addition of alkali, axis sludge: carbonic compounds of NLP cobalt oxide hydrate.
Дл предотвращени растрескивани катод -:ого осадка избыток д :метилглиоксима удал етс обработкой электролита активированным углел5.In order to prevent cracking of the cathode -: th precipitate, excess g: methylglyoxime is removed by treating the electrolyte with activated carbon 5.
Осадок диметилглиоксима никел регенерируетс обработкой его дес ти-п тнадиати процентной серной кислотой при нагревании и при перелшщивани: . При этом получаетс свободный диметилглиоксим, возвра1цающн1 с в производство, и чистый сернокислый никель, из которого Электролизом получаетс химически чистый никель.The dimethylglyoxime nickel precipitate is regenerated by treating its ten-pnadiaty with percentage sulfuric acid when heated and under refluxing:. This produces free dimethylglyoxime, returning to production, and pure nickel sulphate, from which electrolysis produces chemically pure nickel.
ДСо 73173- 2 Предмет изобретени DSo 73173-2 Subject of the invention
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU304532A SU73173A1 (en) | 1941-02-04 | 1941-02-04 | Method of two-stage electrolytic separation of cobalt from nickel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU304532A SU73173A1 (en) | 1941-02-04 | 1941-02-04 | Method of two-stage electrolytic separation of cobalt from nickel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU73173A1 true SU73173A1 (en) | 1947-11-30 |
Family
ID=48249303
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU304532A SU73173A1 (en) | 1941-02-04 | 1941-02-04 | Method of two-stage electrolytic separation of cobalt from nickel |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU73173A1 (en) |
-
1941
- 1941-02-04 SU SU304532A patent/SU73173A1/en active
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| SU73173A1 (en) | Method of two-stage electrolytic separation of cobalt from nickel | |
| CN108928851A (en) | A method of ammonium vanadate sodium is prepared by sodium vanadate solution | |
| DE1115322B (en) | Process for the regeneration of double skeleton catalyst electrodes | |
| US2317153A (en) | Process for the electrodeposition of manganese | |
| US2162385A (en) | Process of manufacturing large surface electrodes | |
| US1754125A (en) | Electrolytic recovery of metals | |
| US3218254A (en) | Treatment of toxic copper-containing solutions | |
| CS199597B2 (en) | Method of electrolytical obtaining gallium from alkaline metals solutions | |
| US3390063A (en) | Electrolytes and method for anodizing aluminum | |
| US1299414A (en) | Electrolytic refining of metallic zinc-bearing materials. | |
| US2770589A (en) | Electrolytic production of alkali salts | |
| GB221851A (en) | Improvements in or relating to vacuum electric tubes | |
| US1314632A (en) | Pbocess fob the electrolytic tbeatment of cabboit | |
| US1687056A (en) | Process of electrolytically separating the alloys of silver with other precious or base metals | |
| RU2553318C1 (en) | Gallium production method from alkali-aluminate solutions of alumina industry | |
| RU2221902C2 (en) | Process of winning gallium from alkaline-aluminate solutions of alumina production | |
| JPS6158556B2 (en) | ||
| US2436940A (en) | Method of regenerating anodizing baths | |
| SU62742A1 (en) | Method for producing active manganese dioxide and copper sponge | |
| DE476344C (en) | Process for the production of accumulator plates | |
| GB397538A (en) | Improvements in and relating to the preparation of aluminium or aluminium alloy anodes for electrolytic condensers and rectifiers | |
| Chirnside et al. | The separation of metals by means of the mercury cathode: chromium | |
| Swann et al. | The electrolytic reduction of benzophenone in acidic and in alkaline Media | |
| RU2002107096A (en) | A method of producing gallium from alkaline aluminate solutions of alumina production | |
| SU2319A1 (en) | The method of electrolytic processing of brass on powdered copper and zinc chloride |