SU672159A1 - Glass with anionic conductivity - Google Patents

Glass with anionic conductivity

Info

Publication number
SU672159A1
SU672159A1 SU782574966A SU2574966A SU672159A1 SU 672159 A1 SU672159 A1 SU 672159A1 SU 782574966 A SU782574966 A SU 782574966A SU 2574966 A SU2574966 A SU 2574966A SU 672159 A1 SU672159 A1 SU 672159A1
Authority
SU
USSR - Soviet Union
Prior art keywords
glass
conductivity
anionic conductivity
anionic
bromine
Prior art date
Application number
SU782574966A
Other languages
Russian (ru)
Inventor
Константин Константинович Евстропьев
Алексей Алексеевич Пронкин
Наталия Георгиевна Артюшкина
Галина Израиловна Векслер
Анатолий Александрович Ильин
Original Assignee
Ленинградский Ордена Трудового Красного Знамени Технологический Институт Им.Ленсовета
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ленинградский Ордена Трудового Красного Знамени Технологический Институт Им.Ленсовета filed Critical Ленинградский Ордена Трудового Красного Знамени Технологический Институт Им.Ленсовета
Priority to SU782574966A priority Critical patent/SU672159A1/en
Application granted granted Critical
Publication of SU672159A1 publication Critical patent/SU672159A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/12—Silica-free oxide glass compositions
    • C03C3/23—Silica-free oxide glass compositions containing halogen and at least one oxide, e.g. oxide of boron
    • C03C3/247—Silica-free oxide glass compositions containing halogen and at least one oxide, e.g. oxide of boron containing fluorine and phosphorus
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/12—Silica-free oxide glass compositions
    • C03C3/23—Silica-free oxide glass compositions containing halogen and at least one oxide, e.g. oxide of boron
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00—Compositions for glass with special properties
    • C03C4/18—Compositions for glass with special properties for ion-sensitive glass

Description

(54) СФЁКЛО С .ЙНЙОЙНОЙ ПРОВОДИМОСТЬЮ(54) SPUTTER WITH CORRECT CONDUCTIVITY

Изобретение относитс  к стеклооб разным неорганическим материалам и 46жeт быть использовано дл  ионоселективньак мембран, обратимте по отнриению к растворам с различйьам соде1йсаиием анионов брома, при элект .рохймическом получении сверхчистых ИЗ стёкла,а также в р де друJгйх областей; техники, где необходимы неорганические материалы с ани рнной проводимостью.; Известны технические решени , в ;котойах Дешевизна и простора производства материалов с анионной прово димостью достигаетс  путем npro «iенй сте1сйооб1разньк композиций на основе метафосфата бари . К таким : ршени м относитс  стекло. Содержащее, вес.%1 Ва(РОз)а - 35,7-49, MgF -0,1-12,2, BaF - 20,4-48,4, CaClg - 0,1-19,9 Hi, a также стек no состава, вес.%: Ва(РОд)л - 50|80 , ВаЕз - 10-20, BaClj - 5-35 21. I Указанные стекла имеет значительную йроводимость по хлору. Однако возможность введени  бромистых соединений в стекла на основе метафосфата бари  до сих пор неизвестна. В то же врем  наличие преимущественно анионной проводимости по брому в этих стеклах позволиЛб бы рекс лендовать их в качестве Конструкцй6ннб1 0 материала стекл нного электрода, обратимого относительно Вг7 Цель изобретени  - получение анионной проводимости по брому . Эта цель достигаетс  тем, что в метафосфат бари Дополнительно ввод т брсжид бари  и указанные компоненты берутс  в следующем соотношеиии , вес.%: Ва(РОз)аВаВгг 69,9-97,52,5-30,1 : Исследование природы проводимости стекол этих систем показало наличие значительной анионной проводимости по брому в них. Некоторые физикохимические свойства разработанных броьюодержащих фосфатных стекол приведены в таблице.The invention relates to glassy inorganic materials and should not be used for ion-selective membranes, reversible in relation to solutions with different concentrations of bromine anions, for electrochemical production of ultrapure glass, as well as in some other areas; technology that requires inorganic materials with anin ry conductivity .; Technical solutions are known, in which the cheapness and scope of production of materials with anionic conductivity is achieved by npro ' steamyyo1bn barium metaphosphate based compositions. These include: glass glass. Containing, wt.% 1 Ba (Rhoz) a - 35.7-49, MgF -0.1-12.2, BaF - 20.4-48.4, CaClg - 0.1-19.9 Hi, a also a stack of the composition, wt.%: Ba (XD) l - 50 | 80, VaEz - 10-20, BaClj - 5-35 21. I These glasses have significant chlorine conductivity. However, the possibility of introducing bromide compounds into barium metaphosphate glass is still unknown. At the same time, the presence of predominantly anionic conductivity over bromine in these glasses would allow Rex to bend them as a Constructive 6nb1 0 material of a glass electrode reversible with Br7. The purpose of the invention is to obtain anionic conductivity for bromine. This goal is achieved by the fact that briskid bari are additionally introduced into the metaphosphate of barium and the indicated components are taken in the following ratio, wt.%: Ba (PO3) aBaBy 69.9-97.52.5-30.1: Study of the nature of the conductivity of these glasses systems showed the presence of significant anionic conductivity for bromine in them. Some physicochemical properties of the developed phosphate-containing glasses are given in the table.

1. Ва(РОз)л - ВаВг, 1. Va (R) l - VaVg,

1000 - 97,5 2,51000 - 97.5 2.5

2. Ва(РСа), - ВаВГа 2. Va (RSA), - VaVGa

1000 82,7 17,31000 82.7 17.3

3 Ва(РО.)2 - ВаВг, 3 Va (PO.) 2 - VaVg,

1000 69t,9 30,11000 69t, 9 30.1

;- ЧИСЛО переноса брома сопротивление при температуре 200с, ;; - NUMBER of bromine transfer resistance at a temperature of 200s;

Claims (2)

1.Авторское свидетельство СССР 541807, кл. С 03 В 3/18, 1974..1. Authors certificate of the USSR 541807, cl. From 03 To 3/18, 1974 .. 2.Авторское свидетельство СССР 598849, кл. С 03 В 3/12, 1976.2. Authors certificate of the USSR 598849, cl. From 03 To 3/12, 1976.
SU782574966A 1978-02-01 1978-02-01 Glass with anionic conductivity SU672159A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU782574966A SU672159A1 (en) 1978-02-01 1978-02-01 Glass with anionic conductivity

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU782574966A SU672159A1 (en) 1978-02-01 1978-02-01 Glass with anionic conductivity

Publications (1)

Publication Number Publication Date
SU672159A1 true SU672159A1 (en) 1979-07-05

Family

ID=20746791

Family Applications (1)

Application Number Title Priority Date Filing Date
SU782574966A SU672159A1 (en) 1978-02-01 1978-02-01 Glass with anionic conductivity

Country Status (1)

Country Link
SU (1) SU672159A1 (en)

Similar Documents

Publication Publication Date Title
Chantot et al. Physicochemical properties of nucleosides 3. Gel formation by 8‐bromoguanosine
DE3165790D1 (en) STABILIZED TETRAZOLIUM SALT PREPARATION
JPS51151176A (en) Dew condensation sensor
Wieland et al. Affinity of antamanide for sodium ions
SU672159A1 (en) Glass with anionic conductivity
AU499360B2 (en) Manufacture of neutral calcium hypochlorite witha high content of active chlorine
JPS5236589A (en) Membrane of cation exchange resin containing fluorine
Carini et al. The Effect of Potassium Chloride on the Equilibrium between Ethylenediaminetetra-acetate and Calcium Ions1
Flood Aliphatic Germanium Derivatives. III. Ethylgermanium Trihalides
Pearson et al. Rates of Ionization of Pseudo-acids. II. Effect of Alkyl Substituents1, 2
Woisard et al. The low ionic strength form of the sodium salt of poly (dm5C-dG) is a B DNA
Dohno et al. Permeability of mono-carboxylate ions across an anion exchange membrane
JPS57192392A (en) Production of 3-alkoxymethylcephalosporin
ES422967A1 (en) Phosphoric acid purification
Muhuri et al. Solubilities of some alkali-metal salts, tetraphenylarsonium chloride, and tetraphenylphosphonium bromide in propylene carbonate at 25. degree. C using the ion-selective electrode technique
Kumar et al. Viscosity B-coefficients of 1: 1 electrolytes in acetonitrile-water mixtures at 25 and 35. DEG. C.
US4981571A (en) Membrane for barium ion selective electrode
SU672160A1 (en) Glass with anionic conductivity
SU682456A1 (en) Glass exhibiting anion conductance for iodine
ES8103725A1 (en) p-Biphenyl-4-methyl-2-butenoic acids, process for their preparation, pharmaceutical compositions containing them and their use.
Antikainen et al. On the oxyanion chelates of o-diphenols
GB1541561A (en) Cleaning compositions
Osol et al. The “Salting-out” and “Salting-in” of Weak Acids. II. The Activity Coefficients of the Molecules of Ortho, Meta and Para-Hydroxybenzoic Acids in Aqueous Salt Solutions1
Fujinaga et al. EFFECT OF PHENOL DERIVATIVE ON THE SELECTIVITY OF ORGANIC SULFONATE SELECTIVE ELECTRODE
Talley et al. Solubility of lactose and its hydrolytic products