SU631513A1 - Method of obtaining alicyclic diamines - Google Patents

Method of obtaining alicyclic diamines

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Publication number
SU631513A1
SU631513A1 SU711724856A SU1724856A SU631513A1 SU 631513 A1 SU631513 A1 SU 631513A1 SU 711724856 A SU711724856 A SU 711724856A SU 1724856 A SU1724856 A SU 1724856A SU 631513 A1 SU631513 A1 SU 631513A1
Authority
SU
USSR - Soviet Union
Prior art keywords
autoclave
minutes
pressure
diamines
obtaining
Prior art date
Application number
SU711724856A
Other languages
Russian (ru)
Inventor
Галина Константиновна Опарина
Лев Хацкелевич Фрейдлин
Виталий Владимирович Якубенок
Лариса Петровна Пивоненкова
Маргарита Константиновна Бычкова
Владимир Израилевич Хейфец
Евгений Федорович Литвин
Original Assignee
Всесоюзный Научно-Исследовательский И Проектный Институт Мономеров
Институт Органической Химии Ан Ссср
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Всесоюзный Научно-Исследовательский И Проектный Институт Мономеров, Институт Органической Химии Ан Ссср filed Critical Всесоюзный Научно-Исследовательский И Проектный Институт Мономеров
Priority to SU711724856A priority Critical patent/SU631513A1/en
Application granted granted Critical
Publication of SU631513A1 publication Critical patent/SU631513A1/en

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Description

i63151.34i63151.34

Horo раствора ГИДРООКИСИ кали .а,аетс  расчетное количество водорода,Horo solution of potassium HYDROXIDE, a calculated amount of hydrogen,

(135 г) и 30 г катализатора 5%-ногоПосле охлаждени  автоклав загружают.(135 g) and 30 g of catalyst 5%. After cooling, the autoclave is charged.

рутенй  на угле. После п15одувкй аз-выход 1,3-диаминоциклогексана 82%. тонлава азотом давление кодорода в системе поддерживают 120 атМо Приruteny on coal. After p15 blow up az-yield of 1,3-diaminocyclohexane 82%. the nitrogen pressure the pressure in the system is maintained at 120 atMo.

Claims (1)

реакци  заканчиваетс  за 40мин.Формула изобретени  the reaction ends in 40 minutes. Formula of the invention Состав продукта по даннш хроматографичвскога; анализа: Ь4-Диа иноцик- способ получени  алициклическихThe composition of the product according to this chromatographic; of analysis: b4-dia inocyc - a method of obtaining alicyclic г «о«п 1« ч ВДклогексанол 2%, цикло-диаминов путем гидрировани  соотгексиламин as.ветствук цих ароматических диаминовg "o" n 1 "h Vdclohexanol 2%, cyclo-diamines by hydrogenating soxyhexylamine as.the word cich aromatic diamines tnnrtВ автоклав емкостьюили п-нитроанилина в присутствии ру1000 шг загружают 50 г 1,3-фенилен- Ютениевых катализаторов при повышендиаг на , 450 мл воды и 7,5 г катали-них температуре и давлении, о т л и затора - 5%-ного рутени  на окиси,чающийс  тем, что, с цельюtnnrtВ an autoclave with a capacity of p-nitroaniline in the presence of py1000 shg is charged with 50 g of 1,3-phenylene-yuthenium catalysts with an increase of 450 ml of water and 7.5 g of catalyst temperature and pressure, about t l and mash of 5% ruthenium on oxide, in order to алюмини . Автоклав продувают азотом,увеличени  выхода целевого продука затем водородом. Давление последне-та и интенсификации процесса, гидри по ® ® ®° ®™ температура 15рование провод т в водном раствореaluminum. The autoclave is flushed with nitrogen, increasing the yield of the target product then with hydrogen. The pressure of the latter and the intensification of the process, the hydri® ® ® ® ° ® ™ temperature, 15 formation, is carried out in an aqueous solution 120 С, Процесс длитс  30 мин, Погло-гидроокиси щелочных металлов.120 ° C, the process lasts 30 minutes, alkali metal hydrochloride.
SU711724856A 1971-12-13 1971-12-13 Method of obtaining alicyclic diamines SU631513A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU711724856A SU631513A1 (en) 1971-12-13 1971-12-13 Method of obtaining alicyclic diamines

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU711724856A SU631513A1 (en) 1971-12-13 1971-12-13 Method of obtaining alicyclic diamines

Publications (1)

Publication Number Publication Date
SU631513A1 true SU631513A1 (en) 1978-11-05

Family

ID=20496201

Family Applications (1)

Application Number Title Priority Date Filing Date
SU711724856A SU631513A1 (en) 1971-12-13 1971-12-13 Method of obtaining alicyclic diamines

Country Status (1)

Country Link
SU (1) SU631513A1 (en)

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