SU475002A3 - Soil Composition - Google Patents

Soil Composition

Info

Publication number
SU475002A3
SU475002A3 SU1811691A SU1811691A SU475002A3 SU 475002 A3 SU475002 A3 SU 475002A3 SU 1811691 A SU1811691 A SU 1811691A SU 1811691 A SU1811691 A SU 1811691A SU 475002 A3 SU475002 A3 SU 475002A3
Authority
SU
USSR - Soviet Union
Prior art keywords
composition
silicate
soil composition
gelatinizing
soil
Prior art date
Application number
SU1811691A
Other languages
Russian (ru)
Inventor
Филле Пьер
Боннель Бернар
Original Assignee
Рон-Прожиль (Фирма)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Рон-Прожиль (Фирма) filed Critical Рон-Прожиль (Фирма)
Application granted granted Critical
Publication of SU475002A3 publication Critical patent/SU475002A3/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/04Carboxylic acids; Salts, anhydrides or esters thereof
    • C04B24/045Esters, e.g. lactones
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C1/00Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
    • B22C1/16Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
    • B22C1/18Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of inorganic agents
    • B22C1/186Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of inorganic agents contaming ammonium or metal silicates, silica sols
    • B22C1/188Alkali metal silicates
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00Silicon; Compounds thereof
    • C01B33/20Silicates
    • C01B33/32Alkali metal silicates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/40Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
    • C09K17/42Inorganic compounds mixed with organic active ingredients, e.g. accelerators
    • C09K17/46Inorganic compounds mixed with organic active ingredients, e.g. accelerators the inorganic compound being a water-soluble silicate
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00732Uses not provided for elsewhere in C04B2111/00 for soil stabilisation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Soil Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)
  • Colloid Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Description

(54) СОСТАВ ДЛЯ УПЛОТНЕНИЯ ПОЧВЫ(54) COMPOSITION FOR SOIL SEALING

33

Если алккловые дпэфпры примен ют БМСсте с другим желатжифующим агентом известного типа, то соответствующие пропорции двух желатинирующих реактивов в смеси могут составл ть 100-60 вес. ч. диэфи.ров на О-40 вес. ч. другого реактива.If alkaline agents are used with BMSST with another gelatinizing agent of a known type, then the respective proportions of the two gelatinous reagents in the mixture can be 100-60 wt. h diefi.rov on O-40 weight. h. another reagent.

Дл  расчета относительных количеств комнонеитов, вход ишх в состав, можно иримен ть следующие формулы:The following formulas can be used to calculate the relative numbers of komnoneits, the input of ishh into the composition:

вес реактива (S} объем водыreagent weight (S} water volume

объем силиката обьем силикатаsilicate volume silicate volume

Составы приготавливают по известным методикам желатинирова ии  П1елочных силикатов . Так, иредночтительным вариапто.м изготовлени   вл етс  введение при перемешиваНИИ в течение 1---2 мин in водный раство р щелочного силиката, выдерживаемого при нормальной температуре, раствора или водной дисперсии желатинирующего реактива.The compositions are prepared according to known methods of gelatinizing and Pelcolelic silicates. Thus, the average production vari able is to introduce, with stirring, for 1 --- 2 min in an aqueous solution of an alkaline silicate, maintained at normal temperature, a solution or aqueous dispersion of a gelatinizing reagent.

Полученные таким образо.м составы в этом случае, готовы дл  иижектировани  в почву, 25 предназначенную дл  уилотиени  илн герметизации .The formulations thus obtained in this case are ready for injection into the soil, 25 intended for sealing or sealing.

В приведениых примерах используют следующие составы, вес.In the examples, the following compositions are used, wt.

Метил су кцннатMethyl methyl acid

МетилглутаратMethylglutarate

А1етиладинатA1ethyladinate

ВодаWater

ЭтилсукнинатEthylsuccinate

ЭтилглутаратEthylglutarate

ЭтиладипатEtiladipate

Этиловый спирEthyl alcohol

ВодаWater

Указанные смеси могут бьпъ нолуче1н( на основе любого известного .метода.These mixtures can be obtained (based on any known method.

Пример. Приготавливают серию гелей, смен1нва  перед самым уиотреблеиием водные растворы силикатов натри  с растворамп нли водными дисперсн. мн, содержаиимн различ1 ые ко,.1ичества желатииирующего реактива. Окончательные составы устанавливают согласно определенным соотнощени м а и Ь. Затем определ ют основные характернстнкн иолученных смесей.Example. Prepare a series of gels, just before the use of aqueous sodium silicate solutions with solution dispersed in water. Mn, containing different amounts, the amounts of the gelatinizing reagent. The final compositions are set according to certain ratios of a and b. The main characteristics of the mixtures are then determined.

1.Врем  нриготовленн  смеси - врем , необходимое дл  того, чтобы поверхность резервуара , заиолнеиного желатинируемой смесью и наклоненного к гориз()нта,ли, не деформировалась.1. The mixture prepared time is the time required for the surface of the tank, the wave of the gelatinized gel and inclined to the horizons () nta, does not deform.

2.В зкость V, оиределениа  при 20 С с помощью вискозиметра Эгщрехта тина «Реомат 15.2. Viscosity V, determined at 20 ° C using Egschrecht's viscometer “Reomat 15.

Результаты иредстав.тенгл в тлбл. 1 и 2.Results and the presentation of the Tengl in tlbl. 1 and 2.

Т а б л и ц а 1Table 1

Водный растнор си,; иката натри  при 31° БомеWater solution ,; ikata sodium at 31 ° baume

Si02/Na20-3,84Si02 / Na20-3,84

Р д Л - желатинирующий состав 1 Рпд (желатинирующий состав 1(50 вес.%)R d L - gelling composition 1 Pd (gel composition 1 (50 wt.%)

I желатинирующий состав 2 (50 вес. %)I gelatinous composition 2 (50 wt.%)

0,060.06

0,080.08

0,10.1

Si02/Na2O 3,34 желатинирующий состав 1 /желатинирующий состав 1(50 вес,;;,) желатинпрующий состав 2 (50 вес, %Si02 / Na2O 3.34 gelatinous composition 1 / gelatinous composition 1 (50 wt ;,;;) gelatinous composition 2 (50 wt,%

0,060.06

0.080.08

П р и м ер 2. Цилиндрическую форму (внутренний диа.метр 40 мм и длина 1500 м.и) заполн ют сухим песком фо1гг9небло.Example 2. The cylindrical shape (internal diameter 40 mm and length 1500 m.) Is filled with dry sand from a foil neblo.

После усадки песка через основание формы внрыскивают состав, приготовленный из водного раствора с:-;;п ката натри  и с.месн метиловых диэф-фс;; и/нлн этиловых диэф)ров с различнылг-; тсппцентпани ми.After the sand has shrunk, a composition prepared from an aqueous solution is sprayed through the base of the form with: - ;; sodium catalate and c-mixture of methyl diethfs ;; and / nl of ethyl diaphragms with different y; tsppsentpani mi.

После заполнени  составом форму разрезают на цилиндрические бруски высотою 80 мм, которые хран т с закрытой при 20° С в течение 7 дней. Затем бруски агломерированного песка вытаскивают из формы и подвергают распл10И1ива 1Ию сжатием посредством пресса, скорость подачи которого регулируетс  до 20 мм/мин.After filling with the formulation, the mold is cut into cylindrical bars, 80 mm high, which are stored closed at 20 ° C for 7 days. Then the bars of agglomerated sand are pulled out of the mold and subjected to flattening by pressing with a press, the feed rate of which is adjusted to 20 mm / min.

Результаты представлены в табл. 3.The results are presented in table. 3

т а б л и ц а 3t a b l and c a 3

i Прочность брусков на сжатие i Compressive strength of bars

Значение I (кг/см-}, изготовленных oTHoijjeiiHM с 11р1 ме ениемI value (kg / cm-}, manufactured by oTHoijjeiiHM with 11p1 me

водного раство- чодного раствора силиката , ра силиката при 31° Боме прн Боме {SiO2/Na2O (SiOo/Na2O 3,84) , 3,34)an aqueous solution of silicate, potassium silicate at 31 ° Bome prn Bome {SiO2 / Na2O (SiOo / Na2O 3.84), 3.34)

0606

14,0414.04

0,80.8

14,6614.66

11,1911.19

,00, 00

1one

9,159.15

8,478.47

1,21.2

6,386.38

1,351.35

7,837.83

6,5G6.5G

1,501.50

4,194.19

Продолжение Tdit.i. 3Continued Tdit.i. 3

0,80.8

0,С0, C

l-i.-l:l-i.-l:

2(),();;2 (), () ;;

1one

14.9814.98

i.:)1 ,2 i)J7 i.:)1, 2 i) J7

1,31,3

1,351.35

9,67 7,8 9.67 7.8

1,50 6.761.50 6.76

7,937.93

0,80.8

l-,:i;l - ,: i;

23,1823,18

II

17.2217.22

10,96 10.96

1,2 S,5;l1.2 S, 5; l

13,1713,17

1,351.35

11,0811.08

9,389.38

1,501.50

Предмет изобретени Subject invention

Состав дл  уилотиенл  почвы на основе щелочных силикатов и желатинирующего агента, содержащего алкиловые диэфиры  нтарной кислоты, отличающийс  тем, что, с целью увеличени  прочносгны.х овойств состава , желатинирующий агент содержит дополнительно алкиловые диэфиры глутаровой и адипиновой пр содержании диэфиров в смеси 5-50 вес, ч. сухого экстракта на 100 вес. ч. щелочного силиката.The composition for the uilothienne soil based on alkaline silicates and a gelling agent containing alkyl diesters of succinic acid, characterized in that, in order to increase the strength of the composition, the gelling agent contains additionally alkyl diesters of the glutaric and adipic acid content of the diesters in a mixture of 5-50 weight , including dry extract per 100 weight. including alkaline silicate.

SU1811691A 1971-09-01 1972-07-28 Soil Composition SU475002A3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7132336A FR2151648A6 (en) 1971-09-01 1971-09-01

Publications (1)

Publication Number Publication Date
SU475002A3 true SU475002A3 (en) 1975-06-25

Family

ID=9082623

Family Applications (1)

Application Number Title Priority Date Filing Date
SU1811691A SU475002A3 (en) 1971-09-01 1972-07-28 Soil Composition

Country Status (13)

Country Link
JP (2) JPS4834785A (en)
AT (1) AT327105B (en)
BE (1) BE788271R (en)
DD (1) DD102132A6 (en)
DE (1) DE2242713C3 (en)
ES (1) ES406261A1 (en)
FR (1) FR2151648A6 (en)
GB (1) GB1359433A (en)
HK (1) HK78679A (en)
IT (1) IT1056023B (en)
MY (1) MY8300196A (en)
NL (1) NL172945C (en)
SU (1) SU475002A3 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1986006400A1 (en) * 1985-04-22 1986-11-06 Mta Természettudományi Kutató Laboratóriumai Method for improving the strength and impermeability of soils and engineering structures

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51112A (en) * 1974-06-19 1976-01-05 Mitsui Toatsu Chemicals Jibanno kokaanteikahoho
US4066431A (en) * 1975-09-19 1978-01-03 Daniel Martin Ennis Synthetic n-releasing soil conditioner
JPS5242606A (en) * 1975-09-30 1977-04-02 Sekisui Chemical Co Ltd Method of stabilizing soil
JPS52128613A (en) * 1976-03-20 1977-10-28 Kyokado Eng Co Subsoil solidifying method
JPS609072B2 (en) * 1976-04-08 1985-03-07 日本化学工業株式会社 soil stabilizer
DE2965466D1 (en) * 1978-11-30 1983-07-07 Ici Plc Silicate gelling compositions for use in soil stabilisation, sealing a surface or forming a foundry sand mould, methods of use of said compositions for said purposes and mixtures for use in forming said compositions
US4545820A (en) * 1982-07-30 1985-10-08 Gas Research Institute Soil stabilizer and method for stabilizing soil
EP0760353A1 (en) * 1995-08-30 1997-03-05 Rudolf Schanze A water glass based composition for sealing and method of hardening water glass based mass
CN110606537B (en) * 2019-09-09 2021-10-26 武汉纺织大学 Novel method for treating waste water glass sand wet regeneration sewage and application thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1986006400A1 (en) * 1985-04-22 1986-11-06 Mta Természettudományi Kutató Laboratóriumai Method for improving the strength and impermeability of soils and engineering structures
GB2186879A (en) * 1985-04-22 1987-08-26 Mta Termeszettu Domanyi Kutato Method for improving the strength and impermeability of soils and engineering structures
GB2186879B (en) * 1985-04-22 1989-07-05 Mta Termeszettu Domanyi Kutato Method for improving the strength and impermeability of soils and engineering structures

Also Published As

Publication number Publication date
JPS5723677A (en) 1982-02-06
BE788271R (en) 1973-02-28
HK78679A (en) 1979-11-16
DD102132A6 (en) 1973-12-12
GB1359433A (en) 1974-07-10
NL7211713A (en) 1973-03-05
IT1056023B (en) 1982-01-30
ES406261A1 (en) 1975-07-01
DE2242713C3 (en) 1974-05-30
MY8300196A (en) 1983-12-31
JPS5729507B2 (en) 1982-06-23
AT327105B (en) 1976-01-12
JPS4834785A (en) 1973-05-22
DE2242713A1 (en) 1973-03-15
NL172945C (en) 1983-11-16
DE2242713B2 (en) 1973-10-25
ATA742772A (en) 1975-03-15
FR2151648A6 (en) 1973-04-20

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