SU462002A1 - Method of metallization of textile materials from cellulosic and synthetic fibers - Google Patents

Method of metallization of textile materials from cellulosic and synthetic fibers

Info

Publication number
SU462002A1
SU462002A1 SU1378746A SU1378746A SU462002A1 SU 462002 A1 SU462002 A1 SU 462002A1 SU 1378746 A SU1378746 A SU 1378746A SU 1378746 A SU1378746 A SU 1378746A SU 462002 A1 SU462002 A1 SU 462002A1
Authority
SU
USSR - Soviet Union
Prior art keywords
metallization
aqueous solution
synthetic fibers
textile materials
cellulosic
Prior art date
Application number
SU1378746A
Other languages
Russian (ru)
Inventor
Грунд Хайнрих
Хаубольд Клаус
Мюллер Хайнц
Хойер Вальхайм
Клем Людвиг
Original Assignee
Втц Технише Текстилиен (Инопредприятие)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Втц Технише Текстилиен (Инопредприятие) filed Critical Втц Технише Текстилиен (Инопредприятие)
Application granted granted Critical
Publication of SU462002A1 publication Critical patent/SU462002A1/en

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06Q—DECORATING TEXTILES
    • D06Q1/00—Decorating textiles
    • D06Q1/04—Decorating textiles by metallising
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18—Pretreatment of the material to be coated
    • C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
    • C23C18/22—Roughening, e.g. by etching

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Description

ской пленки обычно необходима толщина металлического сло  от 0,01 до 0,3 ммк. Однако толщину пленки можно увеличить химическим или электрохимическим способом с нанесением металлов, способных к осаждению из водного раствора.The thickness of the metal layer is usually required from 0.01 to 0.3 mmk. However, the film thickness can be increased by chemical or electrochemical method with the application of metals capable of deposition from an aqueous solution.

Пример. Текстильный материал из полиакрилонитрильного волокна промывают 10 мин при температуре 50°С (свободный от жира и воска материал просушивают без промывки ), обрабатывают в 2%-ном водном растворе танина при 75°С в течение 25 мин, прополаскивают , обрабатывают 2 мин в 1%-ном водном растворе хлорида олова при 20°С, прополаскивают , обрабатывают 2 мин в 0,1%-ном водном растворе хлорида паллади  при 20°С, прополаскивают и обрабатывают при 60°С в течение 1-3 мин в ванне дл  восстановительной металлизации, содержащей (г/л):Example. Polyacrylonitrile fiber textile material is washed for 10 minutes at a temperature of 50 ° C (free from fat and wax material is dried without washing), treated in a 2% aqueous solution of tannin at 75 ° C for 25 minutes, rinsed, treated for 2 minutes in 1 % aqueous solution of tin chloride at 20 ° C, rinsed, treated for 2 min in a 0.1% aqueous solution of palladium chloride at 20 ° C, rinsed and treated at 60 ° C for 1-3 min in a reducing bath metallization containing (g / l):

Сульфат никел 20Nickel sulfate 20

Гипофосфит натри 15Sodium hypophosphite 15

Пропионова  кислота3Propionic acid3

Молочна  кислота30Lactic acid30

Гидроокись свинца1 (мг/л)Lead hydroxide1 (mg / l)

КомплексообразовательComplexing agent

(«тепон тип 59)5 (мг/л)("Tepone Type 59) 5 (mg / l)

Едкий натрДо рН 5Caustic soda pH 5

По окончании обработки материал прополаскивают и высущивают.At the end of treatment, the material is rinsed and dried.

Предмет изобретени Subject invention

Claims (3)

1.Способ металлизации текстильных материалов из целлюлозных и синтетических волокон , включающий сенсибилизацию в водном1. The method of metallization of textile materials from cellulose and synthetic fibers, including sensitization in water растворе хлорида олова, активацию в водном растворе соли благородного металла и обработку в ванне дл  восстановительной металлизации , отличающийс  тем, что, с целью повыщени  прочности металлического покрыти  при сохранении прочности волокна, перед сенсибилизацией материал обрабатывают в 0,3-10%-ном водном растворе танина при температуре 50-90°С.tin chloride solution, activation of a noble metal salt in an aqueous solution and treatment in a bath for reducing metallization, characterized in that the material is treated in 0.3-10% aqueous solution in order to increase the strength of the metal coating while maintaining the strength of the fiber tannin at a temperature of 50-90 ° C. 2.Способ по п. 1, отличающийс  тем, что материал из целлюлозных волокон перед обработкой в водном растворе танина обрабатывают в I-37о-ном водном растворе едкого натра при температуре 20-50°С.2. A method according to claim 1, characterized in that the material from cellulosic fibers is treated with an I-37O aqueous caustic soda solution at a temperature of 20-50 ° C before treatment in an aqueous solution of tannin. 3.Способ по пп. 1 и 2, отличающийс  тем, что исходный материал промывают дл  удалени  жира и воска.3. Method according to paragraphs. 1 and 2, characterized in that the starting material is washed to remove grease and wax.
SU1378746A 1968-12-12 1969-11-21 Method of metallization of textile materials from cellulosic and synthetic fibers SU462002A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DD13662868 1968-12-12

Publications (1)

Publication Number Publication Date
SU462002A1 true SU462002A1 (en) 1975-02-28

Family

ID=5480671

Family Applications (1)

Application Number Title Priority Date Filing Date
SU1378746A SU462002A1 (en) 1968-12-12 1969-11-21 Method of metallization of textile materials from cellulosic and synthetic fibers

Country Status (3)

Country Link
AT (1) AT291923B (en)
DE (1) DE1939878C3 (en)
SU (1) SU462002A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2821035C1 (en) * 2023-04-27 2024-06-17 Федеральное государственное казённое военное образовательное учреждение высшего образования "Военная академия радиационной, химической и биологической защиты имени Маршала Советского Союза С.К. Тимошенко" Министерства обороны Российской Федерации Method for chemical metallization of linen fibers with nickel subjected to sulphite-alkaline cooking

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004011514B4 (en) * 2004-03-08 2010-09-30 W.E.T. Automotive Systems Ag Electric heating element

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2821035C1 (en) * 2023-04-27 2024-06-17 Федеральное государственное казённое военное образовательное учреждение высшего образования "Военная академия радиационной, химической и биологической защиты имени Маршала Советского Союза С.К. Тимошенко" Министерства обороны Российской Федерации Method for chemical metallization of linen fibers with nickel subjected to sulphite-alkaline cooking

Also Published As

Publication number Publication date
AT291923B (en) 1971-07-15
DE1939878C3 (en) 1978-03-23
DE1939878B2 (en) 1977-07-21
DE1939878A1 (en) 1970-07-09

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