SU458603A1 - Method of extracting plutonium from nitrate solutions - Google Patents

Method of extracting plutonium from nitrate solutions

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Publication number
SU458603A1
SU458603A1 SU7301891053A SU1891053A SU458603A1 SU 458603 A1 SU458603 A1 SU 458603A1 SU 7301891053 A SU7301891053 A SU 7301891053A SU 1891053 A SU1891053 A SU 1891053A SU 458603 A1 SU458603 A1 SU 458603A1
Authority
SU
USSR - Soviet Union
Prior art keywords
plutonium
nitrate solutions
extracting
extracting plutonium
iron salt
Prior art date
Application number
SU7301891053A
Other languages
Russian (ru)
Inventor
Н.Е. Цветаева
Д.А. Федосеев
Л.А. Иванова
Н.А. Землянухина
Original Assignee
Предприятие П/Я Р-6575
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Предприятие П/Я Р-6575 filed Critical Предприятие П/Я Р-6575
Priority to SU7301891053A priority Critical patent/SU458603A1/en
Application granted granted Critical
Publication of SU458603A1 publication Critical patent/SU458603A1/en

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Description

1one

Изобретение относитс  к способам извлечени  плутони  из азотнокислых растворов и может быть использовано дл  определени  содержани  плутони  в объектах внешней среды.The invention relates to methods for extracting plutonium from nitric acid solutions and can be used to determine the content of plutonium in environmental objects.

РЬвестен способ извлечени  плутони  из азотнокислых растворов, заключающийс  в том, что в азотнокислый раствор, содержащий плутоний, ввод т моноизооктиловый эфир метилфосфоновой кислоты, толуол и раствор хлорного железа с последующим отделением образовавшегос  осадка железной соли моноизооктилметилфосфоновой кислоты, содержащего плутоний, от раствора.The brewer is a method of extracting plutonium from nitric acid solutions, which consists in introducing methylphosphonic acid monoisoctyl ester, toluene and ferric chloride solution into a nitrate solution containing plutonium, followed by separating the precipitated iron salt, monoisoctylmethyl pattern and

Цель изобретени  - очистка плутони  от урана и америци .The purpose of the invention is the purification of plutonium from uranium and americium.

Дл  этого используют предварительно синтезированную порошкообразную железную соль моноизооктнлметилфосфоновой кислоты.For this, pre-synthesized powdered iron salt of monoisooctyl methylphosphonic acid is used.

Пример. В азотнокислый раствор объемом 2 л, содержащий смесь плутони  (1,05-10-1 Ки/л), америци  (1,2-10-8 Ки/л) и урана (2 мг/л), ввод т 0,3 г миомфатаExample. In a 2 l nitrate solution containing a mixture of plutonium (1.05-10-1 CI / l), americium (1.2-10-8 CI / l) and uranium (2 mg / l), enter 0.3 g miomfata

железа. Раствор перемешивают в течение 30 мин и затем добавл ют 1,4 мл толуола, после чего смесь перемешивают еще в течение 10 мин. Образовавшийс  осадок отдел ют от раствора путем его фильтрации через два сло  марли и определ ют его а-активность измерени  на сцинтилл ционном а-счетчике с использованием эталонов с соответствующим слоем осадка.gland. The solution was stirred for 30 minutes and then 1.4 ml of toluene was added, after which the mixture was stirred for another 10 minutes. The precipitate formed is separated from the solution by filtering it through two layers of gauze, and its a-activity is measured on a scintillation a-counter using standards with an appropriate layer of sediment.

Полученна  а-активность (5,85-10 Ки) обусловлена только нлутонием-239. Выход плутони  87%.The resulting a-activity (5.85-10 Ci) is due only to nlutonium-239. The yield of plutonium is 87%.

Claims (1)

Формула изобретени Invention Formula Способ извлечени  плутони  из азотнокислых растворов, включающий обработку последних железной солью моноизооктилметилфосфоновой кислоты с последующим отделением плутонийсодержащего осадкаThe method of extracting plutonium from nitric acid solutions, including the treatment of the latter with iron salt of monoisooctylmethylphosphonic acid followed by separation of the plutonium-containing sludge от раствора, иапример, фильтрацией, отличающийс  тем, что, с целью очистки плутони  от урана и америци , используют предварительно синтезированную порошкообразную железную соль моноизооктилметилфосфоновой кислоты.from solution, i.e., by filtration, characterized in that, in order to purify plutonium from uranium and americium, the previously synthesized powdered iron salt of monoisooctylmethylphosphonic acid is used.
SU7301891053A 1973-03-14 1973-03-14 Method of extracting plutonium from nitrate solutions SU458603A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU7301891053A SU458603A1 (en) 1973-03-14 1973-03-14 Method of extracting plutonium from nitrate solutions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU7301891053A SU458603A1 (en) 1973-03-14 1973-03-14 Method of extracting plutonium from nitrate solutions

Publications (1)

Publication Number Publication Date
SU458603A1 true SU458603A1 (en) 1978-07-30

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Family Applications (1)

Application Number Title Priority Date Filing Date
SU7301891053A SU458603A1 (en) 1973-03-14 1973-03-14 Method of extracting plutonium from nitrate solutions

Country Status (1)

Country Link
SU (1) SU458603A1 (en)

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