SU312852A1 - METHOD OF VULCANIZING CHLORESULPHONIZED - Google Patents
METHOD OF VULCANIZING CHLORESULPHONIZEDInfo
- Publication number
- SU312852A1 SU312852A1 SU1418320A SU1418320A SU312852A1 SU 312852 A1 SU312852 A1 SU 312852A1 SU 1418320 A SU1418320 A SU 1418320A SU 1418320 A SU1418320 A SU 1418320A SU 312852 A1 SU312852 A1 SU 312852A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- vulcanizates
- chloresulphonized
- vulcanizing
- cspa
- benzene
- Prior art date
Links
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 2
- 229920002681 Hypalon Polymers 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Inorganic materials [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 230000002588 toxic Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
Description
Известны способы вулканизации хлорсульфированного полиэтилена (ХСПЭ) первичными алифатическими и ароматическими полиаминами .Known methods of vulcanization of chlorosulfonated polyethylene (HSPE) primary aliphatic and aromatic polyamines.
Продукты, используемые в известном способе , высоко токсичны, высоко летучи, кроме того происходит преждевременна вулканизаци смесей.The products used in the known method are highly toxic, highly volatile, and premature vulcanization of the mixtures occurs.
С целью повышени химической стойкости вулканизатов и стойкости к тепловому старению в качестве нового вулканизующего агента дл ХСПЭ предлагаетс примен ть &,« бисамипо- (полидифенилсилоксиарилены).In order to improve the chemical resistance of vulcanizates and the resistance to heat aging, it is proposed to use & Bisimipo (polydiphenylsiloxyarylenes) as a curing agent for CSPA.
Пример 1. 100 мл 18%-ного раствора ХСПЭ в толуоле смешивают с 15 мл 15%-ного раствора 1,4-бис- (дифениламиносилокси) -бензола в метилэтилкетоне. Дл получени вулканизата смесь выливают в форму. Через 8-12 час образовавшуюс в форме пленку нагревают в течение 10-120 мин при температуре 150°С. Кинетика -структурировани ХСПЭ 1,4-бис- (дифениламипосилокси) -бензолом и показатели физико - механических свойств вулканизатов представлены ниже.Example 1. 100 ml of a 18% solution of CSPA in toluene is mixed with 15 ml of a 15% solution of 1,4-bis (diphenylaminosyloxy) benzene in methyl ethyl ketone. To obtain the vulcanizate, the mixture is poured into a mold. After 8-12 hours, the film formed in the form is heated for 10-120 minutes at a temperature of 150 ° C. The kinetics of HSPE-structuring with 1,4-bis- (diphenylamposiloxy) -benzene and the indicators of the physicomechanical properties of vulcanizates are presented below.
Врем нагрева, минHeating time, min
Пример 2. К ХСПЭ добавл ют на вальцах 1,4-бис-(дифениламиносилокси) -бензол. Полученные смеси вулканизуют в течение 60 мин при температуре 155°С, смеси 2 и 9EXAMPLE 2 1,4-bis (diphenylaminosyloxy) benzene was added to CSPA on a roll mill. The resulting mixture is vulcanized for 60 minutes at a temperature of 155 ° C, a mixture of 2 and 9
вулканизуют в течение 60 мин при 120°С.vulcanized for 60 min at 120 ° C.
Состав смесей (вес. ч.) и физико-механические свойства вулканизатов (с различными количествами продук1а) приведены ниже.The composition of the mixtures (parts by weight) and the physicomechanical properties of the vulcanizates (with different amounts of products) are given below.
Пример 3. Вулкаиизаты получают ана- 5 логично примеру 1. Химическую стойкость этих вулканизатов провер ют путем погружени их в 60%-ную H2SO4, 20%-ную НС1, 70%-ную КОН. Образцы выдерживают в агрессивных оредах при 60°С. Одновременно ис- 10 Example 3. Vulkaiisates are prepared similarly to Example 1. The chemical resistance of these vulcanizates is tested by immersion in 60% H2SO4, 20% HC1, 70% KOH. Samples are kept in aggressive environments at 60 ° C. Simultaneously 10
Примечание; I - вулканизаты ХСПЭ с 1,4-бис-(дифениламннос11локси)-бензо лом, И -вулканизаты ХСПЭ с л1-фениле11диам11ном.Note; I - vulcanizates of CSPA with 1,4-bis- (diphenylaminnes 11loxy) -benzene, and C-Vulcanizates of CSPE with h1-phenyl 11 diam.
Пример 4. Вулканизаты получают аналогично примеру 1. Определ ют стойкость полученных вулканизатов к тенловому старению в течение 750 час при 120°С. Одновременно испытывают вулканизаты ХСПЭ, структуТ а б л и ц аExample 4. Vulcanizates were prepared analogously to example 1. Tenil aging of the obtained vulcanizates was determined for 750 hours at 120 ° C. At the same time test the vulcanizates of CSPA, the structure of a b l and c and
рированные лг-фенилендиамином. Через каждые 250 час определ ют изменение веса и физико-механические свойства вулканизатов. Результаты 1федставлены в табл. 2.riated with lg-phenylenediamine. Every 250 hours, the change in weight and the physicomechanical properties of the vulcanizates are determined. The results are presented in table. 2
Таблица 2 пытывают вул.канизаты ХСПЭ, структуриро ванные ж-фенилендиамином. Данные о вли нии агрессивной среды на физико-механические свойства вулканизатов приведены в табл. 1.Table 2 Testing HSPE vulcanised scanners, structured with g-phenylenediamine. Data on the effect of an aggressive environment on the physicomechanical properties of vulcanizates are given in Table. one.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU312852A1 true SU312852A1 (en) |
Family
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2360626A1 (en) * | 1976-08-05 | 1978-03-03 | Ara Werk | CURING MOLDINGS BASED ON CHLOROSULPHONATED POLYOLEFINS |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2360626A1 (en) * | 1976-08-05 | 1978-03-03 | Ara Werk | CURING MOLDINGS BASED ON CHLOROSULPHONATED POLYOLEFINS |
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