SU262019A1 - COMPOSITION FOR FINISHING VARIOUS SURFACES - Google Patents

Description

The invention relates to compositions for the finishing of surfaces of all kinds, for example for the treatment of surfaces from inorganic materials (stone, stone-ceramic materials, metal, etc.) and from organic materials (wood, leather, plastics, as well as textiles and paper).

Found that monobasic amines of the general formula

IJRe

 -R,

G V I I

h / nr.

in which Ri, Ra, Rs and R4 independently of one another denote by one substituted by one or two aliphatic amino group residues or an unsubstituted or substituted saturated nitrogen heterocycle which may be further heteroatoms connected via a nitrogen ring atom; R5 denotes a group

two aliphatic residues, an amino group or an unsubstituted or substituted, saturated three-seven-membered nitrogen heterocycle attached via a nitrogen ring atom, which may have further heteroatoms and Re — hydrogen or an alkyl residue with 1-4 carbon atoms — have waxy properties and are therefore suitable as components of surface finishing agents.

The aliphatic substituents of the amino group Ri, Ra, Rs, Ri or Rs are open-chain aliphatic residues, aliphatic residues with an open chain substituted by heterocyclic residues, or cycloaliphatic residues. As for the open-chain aliphatic residues, as substituents of the amino group, this concerns, in particular, those having direct

0 or branched chains of alkyl or alkenyl residues having 1-22 carbon atoms.

The open-chain aliphatic residue as a substituent for the nervous amino group is predominantly as such with 6-

5 12 and in particular 10-22 carbon atoms, while in both open-chain residues as substituents of the secondary amino group, one is a predominantly alkyl or alkenyl residue with 1 -

6 carbon atoms and another - those with 6-22 carbon atoms. These alkyl and alkenyl residues can be unsubstituted or one or multiple substituted by hydroxyl groups or halogen atoms.

Nitrogen heterocycles connected via the nitrogen atom of the nitrogen ring are considered mainly as five-seven-membered ring systems, which may also contain other heteroatoms (oxygen and sulfur) as a ring unit, for example, pyrrolidine, piperidine, piperazine, 1-alkylpiperazine , morpholine, thiomorpholine, as well as hexahydroazepines and hexahydrodiazepines. These heterocycles can be unsubstituted or one or multiple substituted, for example, alkyl or haloalkyl.

New amines have characteristic melting points and have waxy properties. They can therefore be used instead of the usual commercial natural and synthetic waxes or in conjunction with them for processing and refining surfaces of all kinds. They have properties characteristic of natural waxes, such as solubility in fatty solvents, miscibility with natural and synthetic waxes, and can be prepared in the form of finely dispersed emulsions in water upon addition of suitable emulsifiers.

New compounds provide coatings that are resistant to chemicals, especially alkalis. New triazinylamines are suitable for softening textiles of all kinds.

Compositions for refining surfaces are obtained by displacing an amine of a general formula or several such substances of this formula with suitable materials for surface finishing.

Such materials are, for example, the following: natural and synthetic wax, resins, silicones, etc., which improve physical properties, as well as solvents, inorganic or organic nanofillers, for example silicates, ground synthetic substances, anionic, cationic or non-ionic dispersants detergents, such as natural or synthetic soaps, tensio-active substances, pigments, means for improving light resistance, stabilizers of all kinds, corrosion inhibitors, fragrances, dyes, biologically active substances.

The proposed surface treatment composition can be made and applied in the form of aerosols, solutions, emulsions, semi-solid and solid pastes.

The composition can therefore be used for protection and for refining (for example, in the form of shiny waxing) surfaces of all kinds, including paper processing.

The following are examples of the manufacture of surface finish compositions according to the invention:

Liquid floor wax

5.25 weight. including N, N-bis-2- (G, 3-di-n-octadecylguanidino) - 4 - n - octadecylamino-5-triazinyl- (6) -ethylamine;

0.75 weight. h. polyvinyl octadecyl ether | a) (mp. 49 ° C);

1.50 weight. including microvosk (t. pl. 74-76 ° C, penetration A S TM 30);

7.50 weight. including paraffin wax (mp. 50-52 °);

5.00 weight. including 1,4-dioxane;

80.00 weight. including fractions of oil (boiling range: 150-180 ° C).

The components are introduced into the solution at 120 ° C, the bright solution is rapidly cooled with stirring, and a homogeneous, iron-like liquid arises, which can be used as a wax for rubbing floors with good gloss.

Emulsion wax

a) 4,250 weight. including (1,3-di-n-octadecylguanidino) -4-n-octadecylamino-S-triazinyl- (6) -Y- (2,4-bis-n-octadecylamino-S-triazinyl- (6) -ethylamine;

4,250 weight. including wax of the type of montanacid ester (m.p. 80-83 ° C, acid number 20 -30, saponification number: 135-150);

4,250 weight. including petroleum wax (mp. 86- 88 ° C, acid number 13-16, saponification number 45-55, penetration 4-6 at 100 g / 25 ° (5 sec);

0,850 weight. including olein;

0.765 weight. including emulsifier type polyglycolic ester of fatty alcohol;

0,680 weight. including aminomethyl propanol;

69,955 hours of water.

b) 2,250 weight. including synthetic resin type rosin-modified phenolic

resins;

0.675 weight. including concentrated ammonia; 12,075 weight. h of water. The components of the mixture are, with the exception of water,

melted at 150 ° C, the homogeneous melt is cooled to 100-110 ° C and the latter is then added with stirring to boiled water. The resulting emulsion is cooled to room temperature and the mixture is introduced into it while stirring.

The resulting emulsion wax gives excellent results when finishing modern floors, and during the subsequent polishing

Shine is obtained without additional processing.

If this flooring, obtained on tiles made of polyvinyl chloride, is rubbed with a wet rub, the gloss number is obtained

41.0, while an emulsion made according to the present example, in which the waxy amine according to the present invention is replaced by carnauba wax, gives, when waxing, a gloss number

Subject invention

Claims (2)

1. A composition for finishing various surfaces based on resins and waxes, also containing wax-like triazine derivatives and other auxiliary additives, characterized in that, in order to improve the appearance of the coating, a wax-like amine of the general formula is used as a wax-like triazine: N F re / I r Ky R " RS In which RI, Ra, RS and R4 are independently from each other, one amino group substituted by one or two aliphatic residues or one connected via atom of the nitrogen ring, unsubstituted or replaced, saturated three-seven-membered nitrogen heterocycle, which may have further heteroatoms, Rs denoted-Ri em group In which RI and Ra g have the indicated meanings or denotes an amino group substituted by one or two aliphatic residues or an unsubstituted or substituted, saturated three-seven-membered nitrogen heterocycle attached via a nitrogen ring atom, which may have further heteroatoms and Re is hydrogen or an alkyl residue with 1-4 carbon atoms. 2. The composition according to claim 1, characterized in that it contains at least one amine according to the general formula indicated in paragraph 1, where at least one of the symbols Ri, Ra, Rs, R4 and RS is an amino group substituted aliphatic residue with 10-22 carbon atoms.