SU251569A1 - METHOD FOR OBTAINING FORMIC ACID ESTERS - Google Patents
METHOD FOR OBTAINING FORMIC ACID ESTERSInfo
- Publication number
- SU251569A1 SU251569A1 SU1239242A SU1239242A SU251569A1 SU 251569 A1 SU251569 A1 SU 251569A1 SU 1239242 A SU1239242 A SU 1239242A SU 1239242 A SU1239242 A SU 1239242A SU 251569 A1 SU251569 A1 SU 251569A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- formic acid
- acid esters
- obtaining formic
- catalyst
- obtaining
- Prior art date
Links
- BDAGIHXWWSANSR-UHFFFAOYSA-N formic acid Chemical class OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 title description 5
- 239000003054 catalyst Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 230000000737 periodic Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 2
- -1 sodium alkoxide Chemical class 0.000 description 2
- 239000001187 sodium carbonate Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
Description
Известен способ получени зфиров муравьиной кислоты при взаимодействии спирта и окиси углерода нри температуре 90-110°С и давлении 200 ат в присутствии в качестве катализатора алкогол та натри . Способ основан на использовании дорогого и взрывоопасного металлического натри , работы с которым в масштабе крупного промышленного предпри ти крайне опасна и вызывает значительные технологические трудности.A known method for the preparation of formic acid zools by the interaction of alcohol and carbon monoxide at a temperature of 90-110 ° C and a pressure of 200 atm in the presence of sodium alkoxide as a catalyst. The method is based on the use of expensive and explosive metallic sodium, work with which in the scale of a large industrial enterprise is extremely dangerous and causes considerable technological difficulties.
Цель изобретени - разработка способа производства эфиров муравьиной кислоты, исключающего применение катализатора, получение которого св зано с использованием натри . Это достигаетс благодар тому, что в качестве катализатора взаимодействи спиртов и окиси углерода используют соли, образованные металлами первой группы Периодической системы элементов и слабыми кислотами, например карбонат натри .The purpose of the invention is to develop a method for the production of formic acid esters, which excludes the use of a catalyst whose preparation is associated with the use of sodium. This is due to the fact that salts formed by metals of the first group of the Periodic Table of Elements and weak acids, for example sodium carbonate, are used as a catalyst for the interaction of alcohols and carbon monoxide.
Процесс осуш,ествл ют следуюш,им образом .The process of drying is as follows.
В реактор загружают спирт и катализатор (безводные соли металлов первой группы Периодической системы элементов и слабы.х. кислот), затем туда же подают окись углерода под давлением 25-200 ат. Включают обогрев и перемешивание. Реакцию ведут при температуре 150-200°С. По окончании реакции продукт выгружают и анализ провод тAlcohol and the catalyst are loaded into the reactor (anhydrous salts of metals of the first group of the Periodic Table of the Elements and weak acids), then carbon monoxide is also fed there under a pressure of 25-200 at. Include heating and mixing. The reaction is carried out at a temperature of 150-200 ° C. At the end of the reaction, the product is discharged and the analysis is carried out
хроматографически. Продолжительность опытов 2 час. Результаты опытов приведены в таблице.chromatographically. The duration of the experiments 2 hours. The results of the experiments are given in the table.
10ten
Продолжительность опыта 15 мин. Получают взаимодействием феиола (слаба кислота ) с едким натром. The duration of the experiment 15 minutes Obtained by reacting feiola (weak acid) with caustic soda.
2525
Предмет изобретени а давлении до 200 ат в присутствии щелочного катализатора, отличающийс тем, что, с целью упрощени процесса и обеспечени его безопасности, в качестве щелочного катали4 затора используют соли металлов первой группы и слабых солей, например карбонат натри , и процесс ведут при температуре 150-200°С.The subject matter of the invention is pressure up to 200 atm in the presence of an alkaline catalyst, characterized in that, in order to simplify the process and ensure its safety, salts of metals of the first group and weak salts, such as sodium carbonate, are used as the alkaline catalyst and the process is carried out at a temperature of 150 -200 ° C.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU251569A1 true SU251569A1 (en) |
Family
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7081547B2 (en) | 2000-02-25 | 2006-07-25 | Nippon Steel Corporation | Process for producing formic ester or methanol and synthesis catalyst therefor |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7081547B2 (en) | 2000-02-25 | 2006-07-25 | Nippon Steel Corporation | Process for producing formic ester or methanol and synthesis catalyst therefor |
| US7208642B2 (en) | 2000-02-25 | 2007-04-24 | Nippon Steel Corporation | Process for preparation of formate esters or methanol and catalyst therefor |
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