SU222109A1 - CHEMICAL NICKELING METHOD - Google Patents
CHEMICAL NICKELING METHODInfo
- Publication number
- SU222109A1 SU222109A1 SU839555A SU839555A SU222109A1 SU 222109 A1 SU222109 A1 SU 222109A1 SU 839555 A SU839555 A SU 839555A SU 839555 A SU839555 A SU 839555A SU 222109 A1 SU222109 A1 SU 222109A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- nickel
- solution
- hypophosphite
- chemical nickeling
- chemical
- Prior art date
Links
- 239000000126 substance Substances 0.000 title description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 22
- 229910052759 nickel Inorganic materials 0.000 description 11
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 5
- 238000007747 plating Methods 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- LGQLOGILCSXPEA-UHFFFAOYSA-L Nickel(II) sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- ZGKNDXOLMOFEJH-UHFFFAOYSA-M Sodium hypophosphite Chemical compound [Na+].[O-]P=O ZGKNDXOLMOFEJH-UHFFFAOYSA-M 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 229910001382 calcium hypophosphite Inorganic materials 0.000 description 1
- 229940064002 calcium hypophosphite Drugs 0.000 description 1
- SLUKLNLGZBOHPI-UHFFFAOYSA-N calcium;oxido-oxo-phosphophosphanium Chemical compound [Ca+2].[O-][P+](=O)[P+]([O-])=O SLUKLNLGZBOHPI-UHFFFAOYSA-N 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 229940053662 nickel sulfate Drugs 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- -1 phosphite ions Chemical class 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000003638 reducing agent Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 229910001379 sodium hypophosphite Inorganic materials 0.000 description 1
- XWKBMOUUGHARTI-UHFFFAOYSA-N tricalcium;diphosphite Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])[O-].[O-]P([O-])[O-] XWKBMOUUGHARTI-UHFFFAOYSA-N 0.000 description 1
Description
Известны способы химического никелировани в растворах, содержащих по меньшей мере два компонента, - растворимую никелевую соль и гипофосфит натри или кальци .Known methods for chemical nickel plating in solutions containing at least two components are soluble nickel salt and sodium or calcium hypophosphite.
Предлагаемый способ позвол ет производить химическое никелирование в растворе, содержащем только один компонент - гипофосфит Никел в количестве 10-15 г/л. При этом повыщаетс стабильность раствора к упрощаетс его корректировка.The proposed method allows chemical nickel plating in a solution containing only one component, nickel hypophosphite, in an amount of 10-15 g / l. This increases the stability of the solution and makes its adjustment easier.
Способ состоит в том, что осаждение никел производ т при рН 5,0-5,5 и температуре 94-96°С.The method consists in that the deposition of nickel is carried out at a pH of 5.0-5.5 and a temperature of 94-96 ° C.
Скорость Осаждени 12-14 мк/час при толщине покрыти 5-10 мк. и пористости 1 - 2 поры на 1 слгз. Количество фосфора в никелевом покрытии около 0,2%.The sedimentation rate is 12-14 microns / hour with a coating thickness of 5-10 microns. and porosity 1 - 2 pores to 1 sgls. The amount of phosphorus in the nickel coating is about 0.2%.
Гипофосфит никел готов т взаимодействием растворов сульфата никел € гипофосфатом кальци , причем гипофосфит никел долгое врем может хранитьс в виде концентрированного раствора. рН раствора корректируют разбавленным раствором (10-15 г/л) едкого натра, едкого кали или гидроокиси аммони в течение всего процесса осаждени при перемещивании. Одновременно (в случае непрерывного процесса) добавл ют гипофосфит никел дл поддержани концентрации этой соли в оптимальных интервалах.Nickel hypophosphite is prepared by reacting nickel sulfate solutions with calcium hypophosphate, and nickel hypophosphite can be stored as a concentrated solution for a long time. The pH of the solution is adjusted with a dilute solution (10–15 g / l) of caustic soda, caustic potash, or ammonium hydroxide during the whole precipitation process during transfer. At the same time (in the case of a continuous process), nickel hypophosphite is added to maintain the concentration of this salt at optimal intervals.
Детали из меди никелируют только в контакте с железными.Parts made of copper are nickel-plated only in contact with iron.
10ten
Предмет изобретени Subject invention
Способ химического никелировани в растворе , содержащем в качестве восстановител ионы гипоф.осфита, отличающийс тем, что, с целью повышени стабильности раствора и упрощени его корректировки, осаждение никел производ т из раствора, содержащего гипофосфит никел в количестве 1-0-15 и ироцесс ведут при рН 5,0-5,5 и температуре 94-96°С.A method of chemical nickel plating in a solution containing hypophonic phosphite ions as a reducing agent, characterized in that, in order to increase the stability of the solution and simplify its adjustment, nickel is deposited from an amount of 1-0-15 containing nickel hypophosphite and at pH 5.0-5.5 and a temperature of 94-96 ° C.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU222109A1 true SU222109A1 (en) |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2572914C2 (en) * | 2014-04-09 | 2016-01-20 | Акционерное общество "Научно-исследовательский институт микроприборов-К"(АО "НИИМП-К") | Method for depositing nickel-phosphorus coating on metal surfaces |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2572914C2 (en) * | 2014-04-09 | 2016-01-20 | Акционерное общество "Научно-исследовательский институт микроприборов-К"(АО "НИИМП-К") | Method for depositing nickel-phosphorus coating on metal surfaces |
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