SU167871A1 - METHOD FOR PREPARING TRIAL KILSYLILALOXYACETYLENES - Google Patents
METHOD FOR PREPARING TRIAL KILSYLILALOXYACETYLENESInfo
- Publication number
- SU167871A1 SU167871A1 SU866937A SU866937A SU167871A1 SU 167871 A1 SU167871 A1 SU 167871A1 SU 866937 A SU866937 A SU 866937A SU 866937 A SU866937 A SU 866937A SU 167871 A1 SU167871 A1 SU 167871A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- kilsylilaloxyacetylenes
- trial
- preparing
- ether
- preparing trial
- Prior art date
Links
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000002901 organomagnesium compounds Chemical class 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- FKMCADCEOYUAFV-UHFFFAOYSA-N 2-ethoxyethynyl(trimethyl)silane Chemical group CCOC#C[Si](C)(C)C FKMCADCEOYUAFV-UHFFFAOYSA-N 0.000 description 1
- RDHPKYGYEGBMSE-UHFFFAOYSA-N Bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 description 1
- -1 Trimethylsilylbutoxyacetylene Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- IYYIVELXUANFED-UHFFFAOYSA-N bromo(trimethyl)silane Chemical compound C[Si](C)(C)Br IYYIVELXUANFED-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- WMYNMYVRWWCRPS-UHFFFAOYSA-N ethynoxyethane Chemical group CCOC#C WMYNMYVRWWCRPS-UHFFFAOYSA-N 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- HZZOEADXZLYIHG-UHFFFAOYSA-N magnesiomagnesium Chemical class [Mg][Mg] HZZOEADXZLYIHG-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
Description
Предложен способ получени триалкилсилилалкокоиацетиленов путем взаимодействи триалкилгалоидсиланов с магнийорганическими соединени ми алкокоиацетиленов при нагревании в среде эфира с последующим выделением целевого продукта известным способом , например фильтрацией.A method for producing trialkylsilylalkoociacetylenes is proposed by reacting trialkylhalidesilanes with organomagnesium compounds of alkocioacetylenes by heating in ether and then isolating the target product in a known manner, for example by filtration.
Синтезированные соединени могут быть истюльзованы дл получени различных кремнийсодержащих мономеров.The synthesized compounds can be used to obtain various silicon-containing monomers.
Пример. Из 9,3 г (0,39 моль) магни , 44 г (0,40 моль) бромистого этила и 30 г (0,43 моль) этокси ацетилен а в абсолютном эфире приготовлено магнийорганическое соединение , к которому добавлено 50 г (0,33 люль) триметилбромсилана. После кип чени в эфире остаток отфильтровывалс , из фильтрата отгон лс эфир, а остаток фракционировалс . Выделено 25 г (53% теоретического ко ичества ) триметилсилилэтоксиацетилена. Т. кип. 57,2°С/34 мм; 1,4262, d f 0,8204, ,45,Example. Out of 9.3 g (0.39 mol) of magnesium, 44 g (0.40 mol) of ethyl bromide and 30 g (0.43 mol) of ethoxy acetylene, the organomagnesium compound was prepared in absolute ether, to which 50 g (0, 33 people) trimethylbromosilane. After boiling in ether, the residue was filtered, ether was distilled off from the filtrate, and the residue was fractionated. 25 g (53% of the theoretical value) of trimethylsilyl ethoxyacetylene were isolated. T. Kip. 57.2 ° C / 34 mm; 1.4262, d f 0,8204, 45,
MRoKbm. 44,16.MRoKbm. 44.16.
Найдено, %: С 59,91; Н 10,33.Found,%: C 59.91; H 10.33.
Вычислено, %: С 59,10; Н 9,32.Calculated,%: C 59.10; H 9.32.
CyHuSiO.CyHuSiO.
Аналогично был получен триметилсилилбутоксиацетилен . Выход (35% теоретического количества). Т. кип. 83-84°С/32 мм, 1,4305, 20 0,8268, М. 53,35, MR выч. 53,45.Trimethylsilylbutoxyacetylene was obtained similarly. Yield (35% of theoretical amount). T. Kip. 83-84 ° C / 32 mm, 1.4305, 20 0.8268, M. 53.35, MR deduction. 53.45.
Найдено, %: Si 16,99.Found%: Si 16.99.
Вычислено, %: Si 16,49.Calculated,%: Si 16.49.
CgHigSiO.CgHigSiO.
Предмет изобретен-и Subject invented and
Способ получени триалкилсилилалкоксиацетиленов , отличающийс тем, что триалкилгалоидсиланы подвергают взаимодействию с магнийоргашическими соединени ми алкоксиацетиленов при нагревании в среде эфира с последующим выделением целевого продукта известным способом.A method for producing trialkylsilylalkoxyacetylenes, characterized in that trialkylhaloxylanes are reacted with magnesium magnesium compounds of alkoxyacetylenes by heating in ether and then isolating the target product in a known manner.
Publications (1)
Publication Number | Publication Date |
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SU167871A1 true SU167871A1 (en) |
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