SG191013A1 - Carbon fiber composite - Google Patents
Carbon fiber composite Download PDFInfo
- Publication number
- SG191013A1 SG191013A1 SG2013043435A SG2013043435A SG191013A1 SG 191013 A1 SG191013 A1 SG 191013A1 SG 2013043435 A SG2013043435 A SG 2013043435A SG 2013043435 A SG2013043435 A SG 2013043435A SG 191013 A1 SG191013 A1 SG 191013A1
- Authority
- SG
- Singapore
- Prior art keywords
- carbon fiber
- fiber layer
- layer
- substrate
- secondary carbon
- Prior art date
Links
- 229920000049 Carbon (fiber) Polymers 0.000 title claims abstract description 149
- 239000004917 carbon fiber Substances 0.000 title claims abstract description 149
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 149
- 239000002131 composite material Substances 0.000 title claims abstract description 41
- 239000000758 substrate Substances 0.000 claims abstract description 69
- 238000007789 sealing Methods 0.000 claims abstract description 37
- 239000000203 mixture Substances 0.000 claims abstract description 28
- 238000000034 method Methods 0.000 claims abstract description 23
- 229920000642 polymer Polymers 0.000 claims abstract description 13
- 239000011159 matrix material Substances 0.000 claims abstract description 12
- 229920003986 novolac Polymers 0.000 claims description 65
- 239000003365 glass fiber Substances 0.000 claims description 28
- 229920005989 resin Polymers 0.000 claims description 27
- 239000011347 resin Substances 0.000 claims description 27
- 229920001971 elastomer Polymers 0.000 claims description 14
- 239000000806 elastomer Substances 0.000 claims description 14
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 10
- 229940106691 bisphenol a Drugs 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 230000002708 enhancing effect Effects 0.000 claims description 4
- 239000003822 epoxy resin Substances 0.000 claims description 3
- 229920000647 polyepoxide Polymers 0.000 claims description 3
- 239000010410 layer Substances 0.000 description 245
- 229920006241 epoxy vinyl ester resin Polymers 0.000 description 76
- 239000011521 glass Substances 0.000 description 33
- 239000000463 material Substances 0.000 description 15
- 239000001993 wax Substances 0.000 description 15
- 210000001503 joint Anatomy 0.000 description 14
- 210000002310 elbow joint Anatomy 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 229910000831 Steel Inorganic materials 0.000 description 7
- 230000037452 priming Effects 0.000 description 7
- 239000010959 steel Substances 0.000 description 7
- 238000004140 cleaning Methods 0.000 description 6
- 239000011152 fibreglass Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 230000007797 corrosion Effects 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- -1 polybutylene Polymers 0.000 description 5
- 229910002012 Aerosil® Inorganic materials 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 239000013535 sea water Substances 0.000 description 4
- 239000000565 sealant Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 3
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 229910021485 fumed silica Inorganic materials 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 229920001748 polybutylene Polymers 0.000 description 2
- 238000007665 sagging Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 238000005488 sandblasting Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000206607 Porphyra umbilicalis Species 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- MUMGGOZAMZWBJJ-DYKIIFRCSA-N Testostosterone Chemical compound O=C1CC[C@]2(C)[C@H]3CC[C@](C)([C@H](CC4)O)[C@@H]4[C@@H]3CCC2=C1 MUMGGOZAMZWBJJ-DYKIIFRCSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000012164 animal wax Substances 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000012184 mineral wax Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000012169 petroleum derived wax Substances 0.000 description 1
- 235000019381 petroleum wax Nutrition 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000012056 semi-solid material Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000012178 vegetable wax Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/14—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by a layer differing constitutionally or physically in different parts, e.g. denser near its faces
Landscapes
- Reinforced Plastic Materials (AREA)
- Inorganic Fibers (AREA)
- Laminated Bodies (AREA)
Abstract
The present disclosure relates to a composite for sealing a substrate including a primary carbon fiber layer having a first weave density and a secondary carbon fiber layer having a second weave density that is different from the first weave density of the primary carbon fiber layer. Both the primary and secondary carbon fiber layers are encapsulated in a polymer matrix. The disclosure also provides a polymerizable composition and method of sealing a substrate.
Description
CARBON FIBER COMPOSITE
The invention relates broadly to composite for sealing a substrate. The invention further relates to a polymerizable composition for sealing a substrate and method of sealing a substrate.
Conduits, such as pipes, are utilized in a myriad of industries for the purpose of transporting liquid, gas, and semi-solid material. They are typically made of metal, fiberglass or plastic, have various diameters and extend various lengths. Rarely does a single piece of pipe traverse the entire distance over which the pipe extends. Rather, single pieces of pipe are joined at what are referred to as “joints”. The pipes are sealed at these joints by, for example, threading on the pipe itself, welding, soldering, flange with or without a gasket, Teflon tape, or sealing compounds.
Sealing compounds are also used when a conduit, such as a pipe, 1s damaged or corrodes and leaks. Leaks may occur for many reasons, for example, corrosion or physical damage. Corrosion may be caused by the environment surrounding the pipe, the chemical nature of the material the pipe is transporting, and the like.
Certain conditions are more conducive to corrosion.
These include warm, moist, wet environments and conditions where the pipe 1s exposed to the natural elements. Unfortunately, the use of sealing compounds in these environments is also challenging. Sealing compounds often need a specific temperature and humidity to cure properly. Accordingly, a sealing compound that is durable, structurally secure, and works in environments conducive to corrosion is needed.
In accordance with a first aspect of the disclosure, there is provided a composite for sealing a substrate. The composite includes a primary carbon fiber layer having a first weave density and a secondary carbon fiber layer having a second weave density that is different from the first weave density of the primary carbon fiber layer. Both primary and secondary carbon fiber layers may be encapsulated in a polymer matrix.
In another aspect, there is provided a polymerisable composition for sealing a substrate comprising a primary carbon fiber layer having a first weave density and a secondary carbon fiber layer having a second weave density that is different from the first weave density of the primary carbon fiber layer and wherein both primary and secondary carbon fiber layers are encapsulated in a curable resin. :
Advantageously, the composite and polymerizable composition form a durable seal that is permanent, structurally sound and suitable for industrial use. The composite and polymerizable composition are capable of sealing even pinhole size gaps and defects in a substrate.
Furthermore, the composite and polymerizable composition resist corrosion even in environments with high humidity and temperature.
The composite and polymerizable composition may be used to replace (or substitute for) a substrate, such as a conduit, by coating the entire surface. Thus, even if the substrate erodes beneath the surface, the coating formed on the conduit will remain in place of the conduit. Rather than replace a conduit, such as a pipe, in its entirety (which requires removal of the pipe and installing a replacement), the composite and polymerizable composition provide a cost effective method of replacing the substrate.
The composite and polymerizable composition are also a cost effective substitute for the sealants of the prior art.
In one embodiment, the composite and polymerizable composition comprises at least two different carbon fiber layers to construct an anticorrosive, durable, permanent sealant.
In another aspect of the disclosure, there is provided a method of sealing a substrate comprising applying a composite over the substrate to seal the substrate, the composite comprising a primary carbon fiber layer having a first weave density and a secondary carbon fiber layer having a second weave density that 1s different from the first weave density of the primary carbon fiber layer, and wherein both primary and secondary carbon fiber layers are encapsulated in a polymer matrix.
In one embodiment, the disclosed method of sealing a substrate uses a composite comprising at least a primary and secondary carbon fiber layer encapsulated in a polymer matrix.
The following words and terms used herein shall have the meaning indicated:
. WO 2012/078115 . PCT/SG2011/000430
The word “substantially” does not exclude “completely” e.g. a composition which is “substantially free” from Y may be completely free from Y. Where necessary, the word “substantially” may be omitted from the definition of the invention.
Unless specified otherwise, the terms "comprising" and "comprise", and grammatical variants thereof, are intended to represent "open" or "inclusive" language such that they include recited elements but also permit inclusion of additional, unrecited elements.
As used herein, the frerm "about", in the context of concentrations of components of the formulations, typically means +/- 5% of the stated value, more typically +/- 4% of the stated value, more typically +/- 3% of the stated value, more typically, +/- 2% of the stated value, even more typically +/- 1% of the stated value, and even more typically +/- 0.5% of the stated value.
As used herein, the phrase “weave density” refers to the weight (in grams per meter squared) of a fiber layer.
As used herein, the “polymer matrix” means a polymer that forms a continuous phase and/or surrounds one or more materials or components.
Throughout this disclosure, certain embodiments may be disclosed in a range format. It should be understood that the description in range format is merely for convenience and brevity and should not be construed as an inflexible limitation on the scope of the disclosed ranges.
Accordingly, the description of a range should be considered to have specifically disclosed all the possible sub-ranges as well as individual numerical values within that range. For example, description of a range such as from 1 to 6 should be considered to have specifically disclosed sub-ranges such as from 1 to 3, from 1 to 4, from 1 to 5, from 2 to 4, from 2 to 6, from 3 to 6 etc., as well as individual numbers within that range, for example, 1, 2, 3, 4, 5, and 6. This applies regardless of the breadth of the range.
Disclosure of Optional Embodiments
Exemplary, non-limiting embodiments of a composite for sealing a substrate and a polymerizable composition will now be disclosed.
The substrate may be composed of materials selected from the group consisting of: plastic, fiberglass, concrete, ceramic, clay, metal, glass, and the like, and combinations thereof. Plastics may include, for example, polyvinyl chloride (PVC), polybutylene (PB), acrylonitrile butadiene styrene (ABS), polyethylene (PE), polypropylene : (PP), fluoroplastics, polyacrylates, polycarbonates, polyesters, and the like, and combinations thereof. Metals may include, for example, lead, copper, steel, iron, brass, aluminium, titanium, and alloys and the like, and combinations thereof. In one embodiment, the substrate is steel.
In embodiments, the primary carbon fiber layer is innermost to the substrate relative to the secondary carbon fiber layer.
The primary carbon fiber laver may be a plain weave carbon fiber material. In embodiments, the primary carbon fiber layer may possess a first weave density in the range of 200g/m? to 400 g/m?. In some embodiments, the first weave density may be 200 g/m’.
In embodiments, the primary carbon fiber layer may have a thread count per centimetre of from five to 10 in both the warp and weft directions. In some embodiments, the .
thread count per centimetre may be five in both the warp and weft directions. The primary carbon fiber layer may be, for example, KDL 8003 (SIGRATEX®) . The higher thread count of the primary carbon fiber layer may allow for better conformation to the shape of the substrate and for forming a more impermeable seal.
The secondary carbon fiber layer may be a plain weave carbon fiber material. The secondary carbon fiber layer may have a second weave density. In embodiments, the second weave density may be in the range of 480 g/m’ to 960 g/m°.
In some embodiments, the second carbon fiber layer may have a weave density of 480 g/m®’. The secondary carbon fiber layer may impart strength and durability due to the higher weight of the fiber. 16 In embodiments, the secondary carbon fiber layer may have thread count per centimetre in. the range of three to four in both the warp and weft directions. In some embodiments, the secondary fiber layer may have a thread count per centimetre of three in both the warp and weft directions. The secondary carbon fiber layer may be, for example, KDL 8001 (SIGRATEX®).
The secondary carbon fiber layer may be alternated with the primary carbon fiber layer and/or layered on itself, i.e., one secondary carbon fiber layer on top oI another secondary carbon fiber layer.
The polymer matrix and/or curable resin may be selected from the group consisting of: an elastomer modified epoxy vinyl ester resin, a novolac-based epoxy vinyl ester resin, a bisphenol-A epoxy vinyl ester resin and combinations thereof. In embodiments, the polymer matrix is a cured epoxy resin. In embodiments, the polymerisable composition has a curable resin selected from the group consisting of: a novolac-based resin, a bisphenol-A resin, and an elastomer modified resin.
Examples of elastomer modified epoxy vinyl resins include EPON® (Momentive Specialty Chemicals), 20-3236 (EPOXIES), and DERAKANE® 8084 (ASHLAND®). Examples of novolac-based epoxy vinyl ester resins include, for example
VIPEL® K095-AAA-00 (AOC) and DERAKANE® 470-300 (ASHLAND®).
Examples of bisphenol-A epoxy vinyl ester resins include, for example VIPEL® FO10 and DERAKANE® 411-350 (ASHLAND®).
In embodiments, the polymer matrix and curable resin } include one or more of the elastomer modified epoxy vinyl : ester resin, the novolac-based epoxy vinyl ester resin, and the Dbisphenol-A epoxy vinyl ester resin. In some embodiments, the polymer matrix and/or curable resin include an elastomer modified epoxy vinyl ester resin nearer (or innermost) to the substrate followed by a novolac-based epoxy vinyl ester resin.
In certain embodiments, the composite also includes a glass fiber. In embodiments, the polymerizable composition further includes a glass fiber. The glass fiber may be a fiberglass material selected from the group consisting of: a C-glass veil, a chopped strand mat E-glass, and the like.
The glass fiber, in some embodiments, is innermost to the substrate relative to the primary carbon fiber layer. In some embodiments, the glass fiber is outermost to the substrate relative to the secondary carbon fiber layer.
In embodiments, the fiberglass is a C-glass veil. In embodiments, the C-glass veil may have a weight per meter squared that is preferably from about 25 to about 55 g/m?, more preferably the C-glass is about 30 g/m*.
In embodiments, the fiberglass material is an E-glass.
Preferably, the E-glass 1s a chopped strand mat. In embodiments, the E-glass material may have a weight per meter squared that 1s preferably from about 400 to about 500 g/m?, more preferably the E-glass is about 450 g/m’. In some embodiments one or more types of glass fiber may be used.
The composite and polymerizable composition may comprise at least one type of a glass fiber with the two different carbon fiber layers. In the case of a metal substrate, such as a steel pipe, layers of glass fiber material may be applied directly to the substrate before applying the carbon fiber layers thereon. Thus, the carbon fiber layer does not come into direct contact with the substrate, which would result in oxidation of the substrate, but is applied to the substrate over a glass fiber material to create strength and durability. :
In some embodiments, the composite and/or polymerizable composition may further include putty selected from the group consisting of sealing putty, such as clay based putty, epoxy putty or a combination of these.
In some embodiments, the putty includes a glass fiber, a viscosity enhancing agent, and a curable resin. In other embodiments, the putty may include, for example, a curable resin, a glass fiber, and viscosity enhancing agent.
In embodiments, the curable resin of the putty is a
Dbisphenol-A epoxy resin. In embodiments, glass fiber : material of the putty is a fiberglass chopped strand mat E- glass. In embodiments, the viscosity enhancing agent of the putty 1s silica. Preferably the silica is fumed silica, such as, for example AEROSIL® (AEROSIL).
In some embodiments, a wax may also be included in the composite and/or polymerizable composition of the disclosure. The wax may be any type of wax for example, a natural wax such as animal, mineral, or vegetable wax, a synthetic wax such as a polyethylene wax, or a petroleum wax such as paraffin or microcrystalline wax and combinations of waxes. In embodiments, the wax selected from the group consisting of: paraffin wax, polyethylene wax, and combinations of these. An example wax that may be used is BOSNY WAX® (RICHARD LONDON CHEMICAL INDUSTRIES CO.,
LTD.) .
Exemplary, non-limiting embodiments of a method of sealing a substrate will now be disclosed,
In embodiments, the applying step includes sealing and structuring. In embodiments, the sealing step includes sealing a glass fiber to the substrate. For example, a resin may be applied to the substrate, followed by one or more layers of glass fiber and additional resin. In embodiments the resin is an elastomer modified epoxy vinyl ester resin. In some embodiments, the sealing layer includes both a C-glass veil glass fiber and a chopped strand mat E-glass fiber. In embodiments, a layer of C- glass veil is applied followed by one or more layers of chopped strand mat E-glass fiber. In some embodiments, one layer of C-glass veil 1s applied followed by two layers of chopped strand mat E-glass fiber.
The structuring step may include alternating a primary carbon fiber layer and a secondary carbon fiber layer on the substrate. In some embodiments, the structuring step includes alternating layers of the primary carbon fiber layer and the secondary carbon fiber layer on the substrate. The structuring step may include, for example one or more primary carbon fiber layer(s) and one or more secondary carbon fiber layer(s) alternately applied. In embodiments, the structuring step includes a first primary carbon fiber layer, a first secondary carbon fiber layer, a second primary carbon layer and a second secondary carbon fiber layer. The primary or secondary carbon fiber layers may be innermost relative to the substrate. In embodiments, the structuring step further includes applying the primary carbon fiber layer innermost relative to the substrate.
The secondary carbon fiber layers provide both strength and durability to the seal.
In some embodiments, the structuring step further includes applying at least one additional secondary carbon fiber layer as compared to the number of primary carbon fiber layers to the substrate. For example, after applying the alternating primary and secondary carbon fiber layers, one or more additional secondary carbon fiber layers may be applied. The number of additional secondary carbon fiber layers applied may range from three to eleven. In embodiments, the number of additional secondary carbon fiber layers applied is four, in some embodiments six, in other embodiments eight secondary carbon fiber layers are applied.
The substrate to which the sealant is applied may be cleaned prior to application of the sealant. The substrate may be cleaned using chemical, physical, or mechanical cleaning methods. In one embodiment, the cleaning method 1s sandblasting.
The substrate may be primed prior to sealing. Priming may include applying resin, a glass fiber material, and putty. In embodiments, priming includes applying an elastomer modified epoxy vinyl ester resin layer, a C-glass veil, and putty. In some embodiments, the sealing step may occur after priming and be followed by structuring. In
. WO 2012/078115 PCT/SG2011/000430 some embodiments, a top coat is applied. The top coat may include a resin containing a wax.
In some embodiments, a glass fiber is layered on top of the final secondary carbon fiber layer. In embodiments, the glass fiber is a C-glass veil. The top coat may include a novolac-based epoxy vinyl ester resin combined with a wax.
In embodiments, the structuring step includes offsetting the layers of primary carbon fiber and secondary carbon fiber on the substrate. Advantageously, this offset method of applying the layers is capable of providing a uniform thickness to the ‘seal and prevent bulking or sagging of the seal. By offsetting and lapping the layers, maximum adhesion of the ‘layers to the substrate and the layers to one another is achieved. Additionally, offsetting and lapping the layers prevents lumping or sagging of the composite at a given location. In embodiments where the substrate is a pipe, the layers are offset by 30°.
In embodiments, the substrate includes a first part and a second part with a conduit extending there between.
In some embodiments, the substrate is a conduit.
In embodiments, the substrate may be a conduit. In some embodiments, the conduit may be a pipe, tube, duct, channel, penstock, trough, and the like. When the conduit is cylindrical, the diameter of the cylinder may be used to determine the needed thickness of the composite.
The accompanying drawings illustrate a disclosed "embodiment and serves to explain the principles of the disclosed embodiment. It is to be understood, however, that the drawings are designed for purposes of illustration only, and not as a definition of the limits : of the invention.
Fig. 1 is a plan view of a cleaned elbow joint including a primer layer;
Fig. 2 is a plan view of the elbow joint of Fig. 1, further including a putty layer;
Fig. 3 is a plan view of the elbow joint of Fig. 1, further including a layer of glass fiber material;
Fig. 4 is a plan view of the elbow joint of Fig. 1, further including all of the layers of the composite;
Fig. 5 is an alternate view of a pipe showing offset/lapped application of the layers.
Fig. 1 depicts an elbow joint 10 of a steel pipe as a substrate. The elbow joint 10, which includes two butt joints 12/14, is sandblasted and a layer of elastomer modified epoxy vinyl ester resin 16 is applied followed by a single layer of C-glass veil 18. The elastomer modified epoxy vinyl ester resin 16 and C-glass veil 18 are applied to the entire elbow joint 10 including both butt joints 12/14.
As shown in Fig. 2, putty 20 is then applied to the area of the substrate in need of sealing - in this case the butt joints 12/14 of the elbow joint 10. An additional layer of C-glass 22 is then applied only to the areas that have received putty (Fig. 3). Fig. 4 depicts the C-glass veil 18, putty layer 20, second C-glass veil 22, two E- glass chopped strand mat 24/26, one primary carbon fiber layer 28, one secondary carbon fiber layer 30, a second primary carbon fiber layer 32, followed by seven layers of secondary carbon fiber layer material 34, and a layer of C- glass veil 36. The C-glass veil 36 1s covered by a top coat of resin and wax (not shown).
As depicted in Fig. 5, each layer 102 of the composite surrounds the entire diameter of the pipe 100.
Furthermore, each layer is. applied offset 104 from the previous layer in order to provide a consistent diameter to the substrate each layer laps the previous layer by at least 100 millimetres.
Non-limiting examples of the invention will be further described in greater detail by reference to specific
Examples, which should not be construed as in any way limiting the scope of the invention.
Example 1: 30" Diameter 90° Elbow with Two 30" Butt Joints
Two butt joints of an elbow of a 30” diameter steel pipe used for transporting sea water were repaired using the composite of the invention. :
Cleaning
The elbow of the steel pipe was sand blasted with sharp edged form to remove oil, grease, rust and scale.
All sand and dust were then removed from the surface of the pipe. The surface profile following sand blasting was 50 pm (determined using Press-O-Film (TESTEX)) and surface roughness was achieved.
Each of the materials layered as discussed below was offset by 100 mm from the previous layer and the subsequent layer overlaps the previously applied layer by 30°.
Priming
A layer of DERAKANE® §084 (ASHLAND®) elastomer modified epoxy vinyl ester resin was immediately applied to the surface of the elbow of "the steel pipe followed by one layer of C-glass veil (30 g/m?) and the resin was allowed to cure for one and one-half hours.
Next, putty was prepared as follows: 1000 grams DERAKANE® 411-350 (ASHLAND®) bisphenol-A epoxy vinyl ester resin; one gram 6% cobalt naphthenate; 15 grams of chopped strand mat cut into pieces; 150 grams AEROSIL® (AEROSIL) fumed silica; and,
Two to three drops of dimethylaniline (DMA) were mixed until the 6% cobalt naphthenate was completely incorporated. Finally 12 millilitres of methylethylketone peroxide (MEKP) was added to the mixture to form the putty.
The putty was applied to the step from the pipe surface up to the butt joint and at irregularities in the surface of the elbow joint. The putty was allowed to dry, sanded, and the surface of the elbow joint was cleaned to remove dust and debris. :
Sealing
A layer of C-glass veil (30 g/m’) was layered onto the puttied areas of the elbow joint.
The following layers were applied .sequentially to the elbow joint: a layer of DERAKANE® 8084 (ASHLAND®) elastomer modified epoxy vinyl ester resin;
] WO 2012/078115 . PCT/SG2011/000430 a layer of chopped strand mat E-glass (450 g/m?) ; a layer of DERAKANE® 8084 (ASHLAND®) elastomer modified epoxy vinyl ester resin; a layer of chopped strand mat E-glass (450 g/m?) ; and, a layer of DERAKANE® 8084 (ASHLAND®) elastomer modified epoxy vinyl ester resin.
The seal was allowed to cure for 24 hours.
Structuring
The following layers were sequentially applied following curing of the seal: a primary carbon fiber layer (200 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?); a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a primary carbon fiber layer (200 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?); and a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin.
These layers were allowed one and one-half hours to cure.
Next the following additionally secondary carbon fiber : layers were applied: a secondary carbon fiber layer (480 g/m?); a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin;
a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?) ; and a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin.
The layers were then allowed to cure for one and one- half hours. a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a layer of C-glass veil (30 g/m?) ; and a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin.
Cure for one and one-half hours.
Top Coat
The following components were combined to form a top coat: 1000 grams DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; one gram 6% cobalt naphthenate; two to three drops DMA; and 40 grams wax.
These components were mixed until the 6% cobalt naphthenate was thoroughly incorporated and then 12 millilitres of MEKP was added to the mixture.
One layer of top coat was then applied.
Example 2: Tee Joint including a 24” pipe and a 36” pipe
A tee joint including three junctures - two between the tee joint and a 36” pipe and one between the tee joint and a 24” pipe, used for transporting sea water were repaired using the composite and method of the invention.
The «cleaning, priming, and sealing of the three junctures of the tee joint were prepared as in Example 1.
Structuring
The structural layer of the juncture of the tee joint and 24” pipe was prepared as follows:
The following layers were sequentially applied following curing of the seal: a primary carbon fiber layer (200 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; } a secondary carbon fiber layer (480 g/m) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a primary carbon fiber layer (200 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?) ; and a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin.
These layers were allowed one and one-half hours to cure.
The following additionally secondary carbon fiber layers were sequentially applied: a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?) ;
a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a layer of C-glass veil (30 g/m?); and a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin.
Cure for one and one-half hours.
Top Coat
One layer of top coat, prepared as in Example 1 was then applied to the structural layer.
Structuring oo
Structuring of the junctures of the tee joint and 36” pipe was as follows:
The following layers were sequentially applied following curing of the seal: a primary carbon fiber layer (200 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy : vinyl ester resin; a primary carbon fiber layer (200 g/m) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; : a secondary carbon fiber layer (480 g/m?) ; and a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin.
] WO 2012/078115 ] PCT/SG2011/000430
These layers were allowed one and one-half hours to cure. a secondary carbon fiber layer (480 g/m®); a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m); a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m°); a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?); and a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin. 156 The layers were then allowed to cure for one and one- half hours: oo a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; : a secondary carbon fiber layer (480 g/m?); a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a layer of C-glass veil (30 g/m); and a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin.
These layers were allowed to cure for one and one-half hours.
Top Coat
One layer of top coat, prepared as in Example 1 was then applied to the structural layer.
Example 3: 18” Pipe with Butt Joint
A butt joint of an 18” pipe used for transporting sea water was repaired using the composite and method of the invention.
The cleaning, priming, and sealing of the butt joint of the pipe was as in Example 1.
Structuring
Structuring of the juncture 18” pipes was as follows:
The following layers were sequentially applied following curing of the seal: a primary carbon fiber layer (200 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m’); a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a primary carbon fiber layer (200 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; : a secondary carbon fiber layer (480 g/m?) ; and a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin.
These layers were allowed one and one-half hours to cure.
The following additional secondary carbon fiber layers were sequentially applied:
a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?); a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a layer of C-glass veil (30 g/m?); and a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin.
These layers were allowed to cure for one and one-half hours.
Top Coat
One layer of top coat, prepared as in Example 1 was then applied.
Example 4: Tee Joint with two 48" pipes and one 18" pipe
A tee joint including three Jjunctures - two between the tee joint and a 48” pipe and one between the tee joint and an 18” pipe, used for transporting sea water were repaired using the composite and method of the invention.
The cleaning, priming, and sealing of the flange joint of the pipe were prepared as in Example 1. Structuring and : top coat for the 18” pipe was as described for the 18” pipe of Example 3.
Structuring
Structuring of the 42” pipe butt. joints of the tee joint was as follows:
The following layers were sequentially applied following curing of the seal:
a primary carbon fiber layer (200 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a primary carbon fiber layer (200 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?) ; and a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin.
These layers were allowed one and one-half hours to cure.
The following additional secondary carbon fiber layers were sequentially applied: a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; : a secondary carbon fiber layer (480 g/m?) ; and a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin.
Cure for one and one-half hours. : a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin;
a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?) ; and a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin.
Cure for one and one-half hours. a secondary carbon fiber layer (480 g/m’); a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a secondary carbon fiber layer (480 g/m?) ; a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin; a layer of C-glass veil (30 g/m?) ; and a layer of DERAKANE® 470-300 (ASHLAND®) novolac-based epoxy vinyl ester resin.
Cure for one and one-half hours.
Top Coat
One layer of top coat, prepared as in Example 1 was : then applied.
The composite of the invention is applicable to myriad substrates for sealing the substrates. The composite may be used to seal leaks in a substrate, conduit joints, damaged or weakened areas of a substrate and the like.
The polymerizable composition of the invention is useful for sealing leaks, joints, damaged areas, and weakened areas of a substrate.
The method of the invention is suitable for industrial and commercial applications. Use of the method provides a sealed substrate.
It will be apparent that various other modifications and adaptations of the invention will be apparent to the person skilled in the art after reading the foregoing disclosure without departing from the spirit and scope of the invention and it is intended that all such modifications and adaptations come within the scope of the appended claims.
Claims (24)
1. A composite for sealing a substrate comprising: a primary carbon fiber layer having a first weave density and a secondary carbon fiber layer having a second weave density that is different from the first weave density of the primary carbon fiber layer, and wherein both primary and secondary carbon fiber layers are encapsulated in a polymer matrix.
2. The composite according to claim 1, wherein the primary carbon fiber layer is innermost to the substrate relative to the secondary carbon fiber layer.
3. The composite according to claims 1 or 2, wherein the first weave density is in the range of 200 g/m? to 400 g/m*.
4. The composite according to any one of claim 1 to 3, wherein the second weave density is in the range of 480 g/m? to 960 g/m°.
5. The composite according to any one of claims 1 to 4, wherein the polymer matrix is a cured epoxy resin.
6. The composite according to any one of claims 1 to 5, further comprising a glass fiber.
7. The composite according to claim 6, wherein the glass fiber is innermost to the substrate relative to the primary carbon fiber layer.
. WO 2012/078115 PCT/SG2011/000430
8. The composite according to any one of claims 6 or 7, wherein the glass fiber is outermost to the substrate relative to the secondary carbon fiber layer.
9. A polymerisable composition for sealing a substrate comprising a primary carbon fiber layer having a first weave density and a secondary carbon fiber layer having a second weave density that is different from the first weave density of the primary carbon fiber layer and wherein both primary and secondary carbon fiber layers are encapsulated in a curable resin.
10. The polymerisable composition according to claim 9, wherein the curable resin is selected from the group consisting of: a novolac-based resin, a bisphenol-A resin, and an elastomer modified resin.
11. The polymerizable composition according to any one of claims 9 or 10, further comprising a glass fiber.
12. The polymerizable composition according to any one of © claims 9 to 11, further comprising a putty.
13. The polymerizable composition according to claim 12, : wherein the putty comprises: a glass fiber, a viscosity enhancing agent, and a curable resin.
14. The polymerizable composition according to any one of claims 9 to 13, wherein the first weave density is in the range of 200 g/m? to 400 g/m.
15. The polymerizable composition according to any one of claims 9 to 14, wherein the second weave density is in the range of 480 g/m? to 960 g/m’.
16. A method of sealing a substrate comprising applying a composite over the substrate to seal the substrate, the composite comprising a primary carbon fiber layer having a first weave density and a secondary carbon fiber layer having a second weave density that is different from the first weave density of the primary carbon fiber layer, and wherein both primary and secondary carbon fiber layers are encapsulated in a polymer matrix. :
17. The method according to claim 16, wherein the "applying step comprises sealing and structuring.
18. The method according to claim 17, wherein the sealing step comprises sealing a glass fiber to the substrate.
19. The method according to any one of claims 16 or 17, wherein the structuring step comprises alternating layers of the primary carbon fiber layer and the secondary carbon fiber layer on the substrate.
20. The method according to any one of claims 16 to 19, wherein the structuring step further comprises applying at least 1 additional secondary carbon fiber layer as compared to the number of primary carbon fiber layers to the substrate.
21. The method according to any one of claims 16 to 20, wherein the structuring step comprises offsetting the layers of primary carbon fiber and secondary carbon fiber on the substrate.
22. The method according to any one of claims 16 to 21, wherein the structuring step further comprises applying the primary carbon fiber layer innermost relative to the substrate.
23. The method according to any one of claims 16 to 22, wherein the substrate comprises a first part and a second part with a conduit extending there between.
24. The method according to any one of claims 16 to 23, wherein the substrate is a conduit.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SG2013043435A SG191013A1 (en) | 2010-12-08 | 2011-12-08 | Carbon fiber composite |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SG201009156 | 2010-12-08 | ||
SG2013043435A SG191013A1 (en) | 2010-12-08 | 2011-12-08 | Carbon fiber composite |
PCT/SG2011/000430 WO2012078115A1 (en) | 2010-12-08 | 2011-12-08 | Carbon fiber composite |
Publications (1)
Publication Number | Publication Date |
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SG191013A1 true SG191013A1 (en) | 2013-07-31 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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SG2013043435A SG191013A1 (en) | 2010-12-08 | 2011-12-08 | Carbon fiber composite |
Country Status (2)
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SG (1) | SG191013A1 (en) |
WO (1) | WO2012078115A1 (en) |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
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US6759352B2 (en) * | 2001-07-05 | 2004-07-06 | Sony Corporation | Composite carbon fiber material and method of making same |
CN101532253B (en) * | 2008-03-12 | 2012-09-05 | 比亚迪股份有限公司 | Carbon fiber composite material product and manufacturing method thereof |
-
2011
- 2011-12-08 SG SG2013043435A patent/SG191013A1/en unknown
- 2011-12-08 WO PCT/SG2011/000430 patent/WO2012078115A1/en active Application Filing
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