SG177282A1 - Method for the production of polyether polyols comprising terminal primary hydroxyl groups - Google Patents
Method for the production of polyether polyols comprising terminal primary hydroxyl groups Download PDFInfo
- Publication number
- SG177282A1 SG177282A1 SG2011093952A SG2011093952A SG177282A1 SG 177282 A1 SG177282 A1 SG 177282A1 SG 2011093952 A SG2011093952 A SG 2011093952A SG 2011093952 A SG2011093952 A SG 2011093952A SG 177282 A1 SG177282 A1 SG 177282A1
- Authority
- SG
- Singapore
- Prior art keywords
- hydrogen
- aryl
- alkyl
- koh
- polyether polyol
- Prior art date
Links
- 229920000570 polyether Polymers 0.000 title claims abstract description 87
- 239000004721 Polyphenylene oxide Substances 0.000 title claims abstract description 78
- 229920005862 polyol Polymers 0.000 title claims abstract description 71
- 125000002887 hydroxy group Chemical group [H]O* 0.000 title claims abstract description 69
- 150000003077 polyols Chemical class 0.000 title claims abstract description 69
- 238000000034 method Methods 0.000 title claims abstract description 50
- 238000004519 manufacturing process Methods 0.000 title description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 56
- 239000003054 catalyst Substances 0.000 claims abstract description 47
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 36
- 239000000203 mixture Substances 0.000 claims abstract description 33
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 26
- 150000002924 oxiranes Chemical class 0.000 claims abstract description 26
- 125000004433 nitrogen atom Chemical group N* 0.000 claims abstract description 16
- 239000004814 polyurethane Substances 0.000 claims abstract description 15
- 229920002635 polyurethane Polymers 0.000 claims abstract description 15
- 229910052751 metal Inorganic materials 0.000 claims abstract description 14
- 239000002184 metal Substances 0.000 claims abstract description 14
- 150000003972 cyclic carboxylic anhydrides Chemical class 0.000 claims abstract description 13
- 239000007858 starting material Substances 0.000 claims abstract description 12
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920000642 polymer Polymers 0.000 claims abstract description 6
- 150000003512 tertiary amines Chemical class 0.000 claims abstract description 6
- 125000004122 cyclic group Chemical group 0.000 claims abstract description 4
- 238000006243 chemical reaction Methods 0.000 claims description 45
- 239000000047 product Substances 0.000 claims description 32
- 229910052739 hydrogen Inorganic materials 0.000 claims description 29
- 239000001257 hydrogen Substances 0.000 claims description 29
- -1 alkyl radical Chemical class 0.000 claims description 23
- 125000000217 alkyl group Chemical group 0.000 claims description 22
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 claims description 21
- 125000003118 aryl group Chemical group 0.000 claims description 21
- 150000001412 amines Chemical class 0.000 claims description 19
- 239000002253 acid Substances 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 14
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 8
- 125000001931 aliphatic group Chemical group 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 6
- 238000004821 distillation Methods 0.000 claims description 6
- 238000000746 purification Methods 0.000 claims description 6
- 229920001228 polyisocyanate Polymers 0.000 claims description 5
- 239000005056 polyisocyanate Substances 0.000 claims description 5
- RXYPXQSKLGGKOL-UHFFFAOYSA-N 1,4-dimethylpiperazine Chemical compound CN1CCN(C)CC1 RXYPXQSKLGGKOL-UHFFFAOYSA-N 0.000 claims description 4
- ZMSQJSMSLXVTKN-UHFFFAOYSA-N 4-[2-(2-morpholin-4-ylethoxy)ethyl]morpholine Chemical compound C1COCCN1CCOCCN1CCOCC1 ZMSQJSMSLXVTKN-UHFFFAOYSA-N 0.000 claims description 4
- 239000012043 crude product Substances 0.000 claims description 4
- 239000012971 dimethylpiperazine Substances 0.000 claims description 4
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- QVCUKHQDEZNNOC-UHFFFAOYSA-N 1,2-diazabicyclo[2.2.2]octane Chemical compound C1CC2CCN1NC2 QVCUKHQDEZNNOC-UHFFFAOYSA-N 0.000 claims description 3
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 claims description 3
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 150000005840 aryl radicals Chemical class 0.000 claims description 3
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 3
- 150000005690 diesters Chemical group 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 229940014800 succinic anhydride Drugs 0.000 claims description 3
- SCZNXLWKYFICFV-UHFFFAOYSA-N 1,2,3,4,5,7,8,9-octahydropyrido[1,2-b]diazepine Chemical compound C1CCCNN2CCCC=C21 SCZNXLWKYFICFV-UHFFFAOYSA-N 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- 125000005702 oxyalkylene group Chemical group 0.000 claims 1
- 238000006555 catalytic reaction Methods 0.000 abstract description 13
- 239000002243 precursor Substances 0.000 description 47
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 36
- 150000008064 anhydrides Chemical class 0.000 description 15
- 239000011541 reaction mixture Substances 0.000 description 15
- 229910001220 stainless steel Inorganic materials 0.000 description 15
- 239000010935 stainless steel Substances 0.000 description 15
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 14
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical group CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 12
- GTEXIOINCJRBIO-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]-n,n-dimethylethanamine Chemical compound CN(C)CCOCCN(C)C GTEXIOINCJRBIO-UHFFFAOYSA-N 0.000 description 10
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 7
- 239000007795 chemical reaction product Substances 0.000 description 6
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 239000012973 diazabicyclooctane Substances 0.000 description 4
- 238000005160 1H NMR spectroscopy Methods 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 239000003446 ligand Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- 239000012855 volatile organic compound Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 125000005488 carboaryl group Chemical group 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 2
- 239000012972 dimethylethanolamine Substances 0.000 description 2
- 150000002148 esters Chemical group 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 238000007142 ring opening reaction Methods 0.000 description 2
- 238000004611 spectroscopical analysis Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 125000003006 2-dimethylaminoethyl group Chemical group [H]C([H])([H])N(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical group C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000005815 base catalysis Methods 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 238000011097 chromatography purification Methods 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 229960004793 sucrose Drugs 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4887—Polyethers containing carboxylic ester groups derived from carboxylic acids other than acids of higher fatty oils or other than resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
- C07C69/708—Ethers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/73—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
- C07C69/734—Ethers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
- C07C69/757—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
- C07C69/80—Phthalic acid esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
- C07C69/80—Phthalic acid esters
- C07C69/82—Terephthalic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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Abstract
AbstractProcess for producing polyether polyols having primary hydroxyl end groupsThe present invention relates to a process for producing polyether polyols having primary hydroxyl end groups, comprising the steps of reacting a starter compoundcontaining active hydrogen atoms with an epoxide under double metal cyanide catalysis, reacting the resulting product with a cyclic carboxylic anhydride and reacting this resulting product with ethylene oxide in the presence of a catalyst containing at least one nitrogen atom per molecule, excluding non-cyclic, identically substituted tertiary amines. The invention further relates to polyether polyolsobtainable by this process, compositions containing said polyols and polyurethane polymers based on said polyols.
Description
‘ : WO 2011/000560 PCT/EP2010/003958 -1-
Process for producing polyether polyols having primary hydroxyl end groups
The present invention relates to a process for producing polyether polyols having primary hydroxyl end groups, comprising the steps of reacting a starter compound containing active hydrogen atoms with an epoxide under double metal cyanide catalysis, reacting the resulting product with a cyclic carboxylic anhydride and reacting this resulting product with ethylene oxide in the presence of a catalyst containing at least one nitrogen atom per molecule, excluding non-cyclic, identically substituted tertiary amines. The invention further relates to polyether polyols obtainable by this process, compositions containing said polyols and polyurethane polymers based on said polyols.
Long-chain polyether polyols produced by double metal cyanide catalysis (DMC catalysis) are also known as IMPACT polyethers. The nature of the system is such that they contain predominantly secondary hydroxyl end groups. The use of ethylene/propylene oxide mixes (EO/PO) is possible only up to a certain proportion of EO; for that reason it is not possible to obtain long-chain polyether polyols containing predominantly primary hydroxyl end groups by the impact method.
Instead such polyethers are obtained either by catalysing exclusively with conventional base catalysis (for example KOH) or in a two-stage procedure by polymerising an EO end block onto an IMPACT PO polyether obtained by DMC catalysis, optionally a PO/EO mixed polyether or a polyether having PO/EO mixed end blocks, under KOH catalysis.
The KOH method generally has the disadvantage that this catalyst has to be separated off by laborious means, for example by neutralisation and filtration.
Furthermore, in the case of long-chain polyethers in particular, undesired olefinic end groups are formed as secondary products. Such olefinic end groups or allyl ether end groups reduce the functionality of these polyethers and make them more difficult to use in certain applications. They also lead to polyurethane (PUR) products, which are of a poorer quality.
US 4,487,853 discloses a process for producing a polyether ester polyol with a high content of primary hydroxy! groups. In this process a) the reaction product of a condensate of a polyol with an alkylene oxide is reacted with a cyclic carboxylic acid and b) ethylene oxide at a temperature of 50°C to 125°C. The condensate is obtained from a polyol having 2 to 8 hydroxyl groups and an equivalent weight of 30 to 45 and an alkylene oxide having 2 to 4 carbon atoms and mixtures thereof. The condensate has an equivalent weight of 500 to 10,000. Following reaction with the cyclic carboxylic anhydride a semiester is obtained. The reaction of a) with ethylene oxide takes place in the presence of an effective amount of an amine, oxide or divalent metal catalyst. The ratio of equivalents of the anhydride to equivalents of the condensate is in the range from approximately 1:1 to approximately 1:2 and the molar ratio of ethylene oxide to anhydride is in the range from approximately 2:1 to approximately 1.5:1. A polyurethane from the reaction of an organic polyisocyanate with such polyols is also disclosed.
However, US 4,487,853 does not describe how polyether polyols produced under
DMC catalysis can be converted into polyols having primary hydroxyl end groups with as little processing effort as possible. There is consequently still a need for alternative production processes for polyether polyols having primary hydroxyl end groups and in particular for such processes which convert polyethers produced with
DMC catalysis.
The invention provides a process for producing polyether polyols having primary hydroxyl end groups, comprising the following steps: 1. Reacting a starter compound containing active hydrogen atoms with an epoxide of the general formula (1):
O
Le,
R1 (1) in which R1 denotes hydrogen, an alkyl radical or an aryl radical and with the proviso that > 0 wt.% to < 30 wt.%, relative to the total amount of the epoxide (1) used, are ethylene oxide, the reaction being performed in the presence of a double metal cyanide catalyst and the crude product of this reaction undergoing no further purification other than a possible distillation step;
' ‘ WO 2011/000560 PCT/EP2010/003958 “3. 2. Reacting the product obtained in step 1 with a cyclic carboxylic anhydride; and 3. Reacting the product obtained in step 2 with ethylene oxide in the presence of a catalyst containing at least one nitrogen atom per molecule, excluding non-cyclic, identically substituted tertiary amines.
Where the present invention refers to the production of polyether polyols as the end product, the term naturally encompasses such polyether polyols which as a consequence of the process according to the invention also contain ester units.
One advantage of the process according to the invention is that polyethers produced under DMC catalysis which even with high average molecular masses exhibit no difference or only a technically insignificant difference between the actual and the ideal OH functionality, react to form polyols having a relatively high proportion of primary OH groups. The overall process is simplified by the fact that removal of the catalyst after the first step is dispensed with.
Compounds having (number-average) molecular weights of > 18 g/mol to < 2000 g/mol and > 1 to < 8 hydroxyl groups are preferably used as starter compounds containing active hydrogen atoms in step 1. Examples thereof are ethylene glycol, diethylene glycol, triethylene glycol, 1,2-propylene glycol, dipropylene glycol, 1,4-butanediol, hexamethylene glycol, bisphenol A, bisphenol F, trimethylolpropane, glycerol, castor oil, pentaerythritol, sorbitol, cane sugar, degraded starch and/or water,
Such starter compounds containing active hydrogen atoms can moreover also be used which were produced by for example conventional alkali catalysis from the aforementioned low-molecular-weight starter compounds and which are oligomeric alkoxylation products having (number-average) molecular weights of > 200 g/mol to <2000 g/mol.
The epoxide of the general formula (1) is a terminal epoxide with a substituent R1, which can be hydrogen, an alkyl radical or an aryl radical. In the context of the
’ WO 2011/000560 PCT/EP2010/003958 “4 overall invention the term "alkyl" generally encompasses substituents from the group comprising n-alkyl such as methyl, ethyl or propyl, branched alkyl and/or cycloalkyl.
In the context of the overall invention the term "aryl" generally encompasses substituents from the group comprising mononuclear carboaryl or heteroaryl substituents such as phenyl and/or polynuclear carboaryl or heteroaryl substituents. It is also possible for mixtures of various epoxides to be used in the process according to the invention, provided that the constituents of the epoxide mixture all fall under the general formula (1). If mixtures of various epoxides are used, it is also possible for the mixing ratio of the epoxides to be altered incrementally or continuously during metering,
The double metal cyanide catalysts that are suitable for step 1 of the process according to the invention preferably have the general formula
M'[M*(CN)p(A)eld - £M'eX, + h (H,0) - e L.
M! here is a metal ion selected from the group containing Zn, Fe? Co, Ni¥*,
Mn, Co¥, Sn*, Pb*, Mo™, Mo®, AP, V*, Vs, Ww, Wo, cr, opt and/or Cd**. M? denotes a metal ion selected from the group containing Fe?*, Fe",
Co™, Cosy, Migs, Mags, V¥, V¥*, Cr, Cr**, Rh*, Ru?" and/or Ir**. M! and M? are identical or different.
A is an anion selected from the group containing halide, hydroxide, sulfate, carbonate, cyanide, thiocyanate, isocyanate, cyanate, carboxylate, oxalate and/or nitrate. X is an anion selected from the group containing halide, hydroxide, sulfate, carbonate, cyanide, thiocyanate, isocyanate, cyanate, carboxylate, oxalate and/or nitrate. L is a water-miscible ligand selected from the group containing alcohols, aldehydes, ketones, ethers, polyethers, esters, ureas, amides, nitriles and/or sulfides.
The counting variables a, b, ¢, d, g and z are selected so as to ensure the electroneutrality of the compound. Furthermore, e denotes the coordination number of the ligand, f a fraction or integer greater than or equal to 0 and h a fraction or integer greater than or equal to 0.
' WO 2011/000560 PCT/EP2010/003958 -5.
The DMC catalysts that are suitable for step 1 of the process according to the invention are known in principle from the prior art (US 3,404109, US 3,829,505, US 3,941,849 and US 5,158,922). Improved, highly active DMC catalysts, which are described for example in US 5,470,813, EP 0 700 949 A2, EP 0 743 093 Al,
EP 0761708 A2, WO 97/40086 Al, WO 98/16310 Al and WO 00/47649 Al, are preferably used. They have an exceptionally high activity and allow polyether polyols to be produced with very low catalyst concentrations. The highly active
DMC catalysts described in EP 0 700 949 A2, which in addition to a double metal cyanide compound such as zinc hexacyanocobaltate(IIl) and an organic complex ligand such as tert-butanol also contain a polyether having a number-average molecular weight of greater than 500 g/mol, are a typical example.
The DMC catalyst in step 1 is preferably obtained in accordance with the teaching from EP 0 700 949 A2, to which reference is made in full extent. The catalyst can contain as components a double metal cyanide compound, in other words a reaction product of a water-soluble metal salt and a water-soluble metal cyanide salt, also an organic complexing agent L and > 5 wt.% to < 80 wt.%, relative to the amount of catalyst, of a polyether having a number-average molecular mass of > 500 g/mol.
The catalyst can be used in a proportion of, for example, > 1 ppm to < 100 ppm and preferably > 10 ppm to < 50 ppm , relative to the total mass of starter compound and epoxide (1) used.
The DMC-catalysed reaction between the starter compound and the epoxide (1) in step 1 generally takes place at temperatures of > 20°C to < 200°C, preferably in the range from > 40°C to < 180°C, particularly preferably at temperatures from > 50°C to < 150°C. The reaction can be performed at total pressures of 0.0001 to 20 bar.
The (number-average) molecular weights of the polyether polyols produced in step 1 of the process according to the invention can be > 500 g/mol to < 100,000 g/mol, preferably > 1000 g/mol to < 50,000 g/mol, particularly preferably > 2000 g/mol to <20,000 g/mol.
The reaction in step 1 can be performed continuously or discontinuously, for example in a batch or semi-batch process.
In the process according to the invention it is provided that in step 1 the epoxide (1) contains at most 30 wt.% of ethylene oxide. It has been found that with higher cthylene oxide contents no satisfactory reaction products are obtained for further processing in the subsequent steps of the process.
Within the context of the present invention it is provided that the crude product of the reaction from step 1 undergoes no further purification other than a possible distillation step. This distillation step is thus optional. The distillation step can remove unreacted epoxide (1), for example, from the resulting polyol. Purification steps which are not used on the product would include filtration, solvent extraction or chromatographic purification. This is an advantage of the process according to the invention, as costly purification steps for polyether polyols produced by the KOH method are avoided. A special purification step is not necessary because the double metal cyanide catalysts can remain in the crude product without disrupting the subsequent reactions and because they are needed in only small quantities.
In step 2 of the process according to the invention the product from step 1, which has been purified only by distillation if at all, is reacted further. In this step terminal hydroxy! groups of the polyether polyol obtained are reacted with a cyclic carboxylic anhydride. Opening the anhydride group results in an ester bond to the polyether polyol and a further free carboxyl group. The reaction is optionally performed in the presence of a catalyst containing at least one nitrogen atom per molecule. This is preferably an organic molecule, so the catalyst is an organic amine. Non-cyclic, identically substituted tertiary amines are excluded, however. An example of one such unsuitable amine is triethylamine. If a catalyst is used it is advantageously the same catalyst as in the subsequent step 3.
The amount of nitrogen-containing catalyst, relative to the total mass of the reaction batch in step 2, can be for example > 10 ppm to < 10,000 ppm, preferably > 50 ppm to < 5000 ppm and more preferably > 100 ppm to < 2000 ppm. The reaction temperature in step 2 can be > 70°C to < 150°C and preferably > 80°C to < 135°C.
. WO 2011/000560 PCT/EP2010/003958 -7-
Step 3 of the process according to the invention relates to the reaction of the product obtained in step 2 with ethylene oxide. Reacting the carboxyl groups of the polyether by means of a ring-opening reaction produces hydroxyalkyl groups. Preferably > 80%, = 90% or > 95% of the carboxyl groups react with the epoxide, and a proportion of primary hydroxyl groups of > 50 mol% to < 100 mol% or > 60 mol% to < 85 mol% is obtained.
It is provided according to the invention that this reaction is performed in the presence of a catalyst containing at least one nitrogen atom per molecule. This is preferably an organic molecule, so the catalyst is an organic amine. Non-cyclic, identically substituted tertiary amines are however excluded according to the invention. An example of one such unsuitable amine is triethylamine.
The amount of nitrogen-containing catalyst, relative to the total mass of the reaction batch in step 3, can be for example > 10 ppm to < 10,000 ppm, preferably > 50 ppm to < 5000 ppm and more preferably > 100 ppm to < 2000 ppm. The reaction temperature in step 3 can be > 70°C to < 150°C and preferably > 80°C to < 135°C.
This step advantageously follows immediately after step 2, such that the ethylene oxide is added to the reaction batch from step 2 on completion of the reaction with the cyclic carboxylic anhydride.
In one embodiment of the process according to the invention the starter compound used in step 1 is a poly(oxyalkylene) polyol with an average functionality of > 2.0 to < 5.0, a number-average molecular mass of > 62 g/mol to < 1000 g/mol and an OH value of > 100 mg KOH/g to < 1860 mg KOH/g. The average functionality can also be > 2.3 to < 4.0, the number-average molecular mass > 100 g/mol to < 500 g/mol and the OH value 200 mg KOH/g to < 300 mg KOH/g. The OH value can be determined in accordance with the standard DIN 53240.
In a further embodiment of the process according to the invention R1 in the epoxide of the general formula (1) is hydrogen, methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, isobutyl, tert-butyl, cyclohexyl and/or phenyl. R1 is preferably methyl.
Then the epoxide used is propylene oxide. Mixtures of propylene oxide and ethylene oxide arc likewise preferred, resulting in mixed polyether blocks. A plurality of mixtures of propylene oxide and ethylene oxide with various mixing ratios can also be used in succession.
In a further embodiment of the process according to the invention the double metal cyanide catalyst in step 1 comprises zinc, cobalt and tert-butanol. This catalyst preferably also comprises > 5 wt.% to < 80 wt.%, relative to the amount of catalyst, of a polyether with a number-average molecular mass of > 500 g/mol. The proportion of polyether can also be > 10 wt.% to < 70 wt% and particularly preferably > 15 wt.% to < 60 wt.%. Particularly suitable polyethers are for example polyether polyols with an average OH functionality of 2 to 8 and a number-average molecular mass of > 1000 g/mol to < 10,000 g/mol and preferably > 1000 g/mol to < 5000 g/mol. Poly(oxypropylene) polyols, in particular diols and/or triols, with a number-average molecular mass of > 1000 g/mol to < 4000 g/mol are cited by way of example.
In a further embodiment of the process according to the invention the cyclic carboxylic anhydride used in step 2 is selected from the group comprising phthalic anhydride, tetrahydrophthalic anhydride, succinic anhydride and/or maleic anhydride.
In a further embodiment of the process according to the invention the catalyst used instep 3 is selected from the group comprising: (A) Amines of the general formula (2):
R2 0 N
Re”, TR3 (2) in which:
R2 and R3 are independently of each other hydrogen, alkyl or aryl; or
R2 and R3 together with the N-atom bearing them form an aliphatic, unsaturated or aromatic heterocycle;
n is a whole number from 1 to 10;
R4 is hydrogen, alkyl or aryl; or - R4 denotes ~(CH,),—N(R41)(R42), in which:
R41 and R42 are independently of each other hydrogen, alkyl or aryl; or
R41 and R42 together with the N-atom bearing them form an aliphatic, unsaturated or aromatic heterocycle; x 1s a whole number from 1 to 10; (B) Amines of the general formula (3):
RS
0 N Oo ~~ ~ o RE” I, 5 R7 (3) in which:
RS5 is hydrogen, alkyl or aryl;
R6 and R7 are independently of each other hydrogen, alkyl or aryl; m and o are independently of each other a whole number from 1 to 10; and/or: (C) Diazabicyclo[2.2.2]octane, diazabicyclo[5.4.0]Jundec-7-ene, dialkylbenzylamine, dimethylpiperazine, 2,2'-dimorpholinyldiethyl ether and/or pyridine,
The catalyst which can optionally be used in step 2 of the process can likewise be selected from groups (A), (B) and/or (C) described above.
Amines of the general formula (2) can be described in the broadest sense as amino alcohols or ethers thereof. If R4 is hydrogen then the catalysts can be incorporated into a polyurethane matrix if the polyether polyol is reacted with a polyisocyanate.
This is advantageous as a means of preventing the escape of catalyst, which in the case of amines can be associated with disadvantageous odour problems, to the polyurethane surface, a phenomenon known as the fogging or VOC (volatile organic compounds) problem.
Amines of the general formula (3) can be described in the broadest sense as amino (bis)alcohols or ethers thereof. If R6 or R7 is hydrogen then these catalysts can likewise be incorporated into a polyurethane matrix.
It is preferred that in the amine of the general formula (2) R2 and R3 are methyl, R4 is hydrogen and n = 2 or that R2 and R3 are methyl, R4 is —(CH,),~N(CH3); and n = 2. This therefore results overall in either N,N-dimethylethanolamine or bis(2- (dimethylamino)ethyl) ether.
It is further preferred that in the amine of the general formula (3) RS is methyl, R6 and R7 are hydrogen, m = 2 and o = 2. This therefore results overall in N- methyldiethanolamine.
In a further embodiment of the process according to the invention the molar ratio in step 2 of cyclic anhydride to hydroxyl groups in the product obtained in step 1 is 20.75:1t0<13: 1. The ratio is preferably > 0.95 : 1 to < 1.25 : 1, more preferably >102:1to<1.15: 1.
In a further embodiment of the process according to the invention the catalyst containing at least one nitrogen atom per molecule is present in step 3 in a proportion of > 500 ppm to < 1500 ppm relative to the total mass of the reaction batch in step 3. The proportion of catalyst can also be > 750 ppm to < 1250 ppm.
The same applies correspondingly if such a catalyst is used in step 2 too.
In a further embodiment of the process according to the invention the molar ratio in step 3 of ethylene oxide to hydroxyl groups in the product obtained in step 1 is 20.90: 1to<5.0: 1. The ratio can also be > 1.0 : 1 to <2.0 : 1 or preferably 21.05:1t0<1.2:1.
The present invention also provides a polyether polyol having primary hydroxyl end groups, obtainable by a process according to the invention and comprising a polyether block, a terminal hydroxyethyl group and a diester unit linking the polyether block and the terminal hydroxyethyl group and wherein the molar proportion of terminal double bonds, relative to all end groups of the polyether polyol, is > 0 milliequivalents per kg to < 10 milliequivalents per kg. The polyether polyol is obtainable by a process according to the invention and in particular is obtained in this way. For that reason reference is made to the embodiments of the process in regard to details of its synthesis.
Without being limited thereto, the polyether block can for example be an ethylene oxide block, propylene oxide block, ethylene oxide/propylene oxide mixed block and/or any sequence of these blocks, started on a di-, tri-, tetra- or pentafunctional alcohol. The number of monomer units in the polyether block, in other words for example the number of ethylene oxide or propylene oxide units, can be in a range from > 10 monomer units to < 5000 monomer units, preferably > 50 monomer units to < 1000 monomer units.
A diester unit which can be attributed to the product of the reaction of an OH end group of the polyether block with a cyclic carboxylic anhydride is connected to the polyether block. In a ring-opening reaction a semiester is initially formed which then reacts with ethylene oxide to form the hydroxyethyl end group. Examples of the cyclic carboxylic anhydride are phthalic anhydride, tetrahydrophthalic anhydride, succinic anhydride and/or maleic anhydride.
The polyether polyol according to the invention is characterised in that the proportion of terminal double bonds, relative to all end groups of the polyether polyol (meaning the total number of polyether polyol molecules), is in the range from > 0 to < 10 milliequivalents per kg, regardless of the molar mass. For all practical purposes it is therefore free from unsaturated end groups. These end groups would reduce the functionality of the polyether and bring about corresponding disadvantages in the production of polyurethane polymers. Terminal double bonds are avoided for example by polymerising the polyether block onto the starter alcohol by means of DMC catalysis. The polyether polyol according to the invention can be checked for the absence of unsaturated end groups by 'H-NMR spectroscopy.
Another common method is the determination of terminal double bonds using
' ‘ WO 2011/000560 PCT/EP2(10/003958 -12- mercury acetate in accordance with ISO 17710. The content can also be > 0 milliequivalents per kg to <5 milliequivalents per kg. Polyether polyols according to the invention can furthermore have functionalities in the range from > 2 to < 6 and molar masses in the range from > 1800 Da to < 20,000 Da.
In one embodiment of the polyether polyol according to the invention the molar proportion of primary hydroxyl groups is = 50 mol% to < 100 mol%. This is understood to be the molar proportion of primary hydroxyl groups as compared with secondary hydroxyl groups in the polyether polyol overall, in other words not relative to a single molecule. This can be determined by "H-NMR spectroscopy, for example. The proportion can also be in a range from > 55 mol% to < 90 mol% or from > 60 mol% to < 85 mol%.
In a further embodiment of the polyether polyol according to the invention it has an
OH value of > 10 mg KOH/g to < 100 mg KOH/g. The hydroxyl value can be determined by reference to the standard DIN 53240 and can also be > 15 mg KOH/g to <80 mg KOH/g or> 20 mg KOH/g to < 50 mg KOH/g.
In a further embodiment of the polyether polyol according to the invention it has an acid value of > 0.01 mg KOH/g to < 5 mg KOH/g. The acid value can be determined by reference to the standard DIN 53402 and can also be > 0.02 mg KOH/g to <4.9 mg KOH/g or > 0.02 mg KOH/g to < 4.8 mg KOH/g.
The present invention also provides a polyether polyol composition comprising a polyether polyol according to the invention and additionally: (A) Amines of the general formula (4):
R3
O N
R107 tJ, “RO (4) in which:
R38 and R9 are independently of each other hydrogen, alkyl or aryl; or
R8 and RO together with the N-atom bearing them form an aliphatic, unsaturated or aromatic heterocycle; p is a whole number from 1 to 10,i.e.1,2,3,4,5,6,7, 8,9 or 10;
R10 is hydrogen, alkyl or aryl; or
R10 denotes —(CH,),—N(R11)(R12), in which:
R11 and R12 are independently of each other hydrogen, alkyl or aryl; or
R11! and R12 together with the N-atom bearing them form an aliphatic, unsaturated or aromatic heterocycle; y is a whole number from 1 t0 10,1e.1,2,3,4,5,6,7, 8,9 or 10; (B) Amines of the general formula (5):
R1 3 0 N O
R147 5 R15 (5) in which:
R13 is hydrogen, alkyl or aryl;
R14 and R15 are independently of each other hydrogen, alkyl or aryl; r and s are independently of each other a whole number from 1 to 10, i.e. 1, 2,3,4,5,6,7,8,%0r 10; and/or: (C) Diazabicyclo[2.2.2]octane, diazabicyclo[5.4.0]undec-7-ene, dialkylbenzylamine, dimethylpiperazine, 2,2'-dimorpholinyldiethyl ether and/or pyridine.
In certain variants such compounds can also be used as blowing catalysts, which means that they preferentially catalyse the reaction of the isocyanate groups with water to form carbon dioxide and to a lesser extent also their reaction with hydroxyl groups to form urethane groups. For that reason this composition can be used directly in the production of polyurethanes. If Zerewitinoff-active hydrogen atoms
S14 - are present, these catalysts can be incorporated into a polyurethane matrix. This reduces the content of volatile organic compounds in the polyurethane. N,N-
Dimethylethanolamine, bis(2-(dimethylamino)ethyl) ether or N- methyldiethanolamine are preferred.
The proportion of these compounds (A), (B) and/or (C) relative to the polyol according to the invention can be for example > 10 ppm to < 10,000 ppm, preferably > 50 ppm to < 5000 ppm and more preferably > 100 ppm to < 2000 ppm.
The present invention also provides a polyurethane polymer, obtainable from the reaction of a polyisocyanate with a polyether polyol according to the invention or a polyether polyol composition according to the invention. Also included according to the invention under the term "polyurethane polymer" are prepolymers obtainable from the reaction of a polyisocyanate with a polyether according to the invention or a polyether polyol composition according to the invention.
The present invention is illustrated in more detail by the examples below. The meanings and sources of the materials and abbreviations used are as follows: 2,2,2-Diazabicyclooctane (DABCO): Aldrich
N,N-Dimethylethanolamine (DMEA): Aldrich
Bis(2-(dimethylamino)ethyl) ether (DMAEE): Alfa Aesar
Triethylamine: Aldrich
Tetrahydrophthalic anhydride (THPA): Aldrich
The analyses were performed as follows:
Viscosity: MCR 51 rheometer from Anton Paar
Determination of the molar proportion of primary OH groups: by "H-NMR (Bruker
DPX 400, deuterochloroform)
Hydroxyl value: by reference to DIN 53240
Acid value: by reference to DIN 53402
1. Production of the DMC-catalysed precursors:
Precursor A: 117.6 g of a poly(oxypropylene) triol with an OH value of 238 mg KOH/g and 0.024 g of DMC catalyst (produced in accordance with EP 0 700 949 A2) were placed in a 1-litre stainless steel pressure reactor under nitrogen, heated to 130°C and then stripped for 30 minutes at 0.1 bar while passing nitrogen through the reactor. Then 682 g of propylene oxide were added at 130°C within 3 hours.
Following a post-reaction time at 130°C to establish constant pressure in the reactor, highly volatile components were distilled off under vacuum at 90°C for 30 minutes and the reaction mixture was then cooled to room temperature. The OH value of the product was 34.1 mg KOH/g at a viscosity (25°C) of 967 mPas.
Precursor B: 117.6 g of a poly(oxypropylene) triol with an OH value of 238 mg KOH/g and 0.024 g of DMC catalyst (produced in accordance with EP 0 700 949 A2) were placed in a 1-litre stainless steel pressure reactor under nitrogen, heated to 130°C and then stripped for 30 minutes at 0.1 bar while passing nitrogen through the reactor. Then a mixture of 504 g of propylene oxide and 38 g of ethylene oxide, followed by a mixture of 53 g of propylene oxide and 17 g of ethylene oxide and finally a mixture of 35 g of propylene oxide and 35 g of ethylene oxide were added at 130°C within 3 hours. Following a post-reaction time at 130°C to establish constant pressure in the reactor, highly volatile components were distilled off under vacuum at 90°C for 30 minutes and the reaction mixture was then cooled to room temperature. The OH value of the product was 34.6 mg KOH/g at a viscosity (25°C) of 954 mPas.
Precursor C: 117.6 g of a poly(oxypropylene) triol with an OH value of 238 mg KOH/g and 0.024 g of DMC catalyst (produced in accordance with EP 0 700 949 A2) were placed in a 1-litre stainless steel pressure reactor under nitrogen, heated to 130°C and then stripped for 30 minutes at 0.1 bar while passing nitrogen through the reactor. Then a mixture of 439 g of propylene oxide and 33 g of ethylene oxide,
followed by a mixture of 53 g of propylene oxide and 17 g of ethylene oxide, then a mixture of 35 g of propylene oxide and 35 g of ethylene oxide and finally a mixture of 21 g of propylene oxide and 49 g of ethylene oxide were added at 130°C within 3 hours. Following a post-reaction time at 130°C to establish constant pressure in the reactor, highly volatile components were distilled off under vacuum at 90°C for 30 minutes and the reaction mixture was then cooled to room temperature. The OH value of the product was 35.3 mg KOH/g at a viscosity (25°C) of 916 mPas.
Table 1 below summarises the data for precursors A, B and C.
Terr
A B C romeenoste | wa | wiv | min reasaon os | wa | se posers | wa || [am mm [ epoxide used
I EE
25°C] 2. Reaction of DMC-catalysed precursors with cyclic anhydrides and ethylene oxide under amine catalysis:
Example 1 (comparative example): 400 g of the DMC-catalysed precursor A, 40.66 g of tetrahydrophthalic anhydride and 0.462 g (1000 ppm, relative to the complete batch) of triethylamine were placed in a l-litre stainless steel pressure reactor under nitrogen. The molar ratio of
' WO 2611/000560 PCT/EP2010/003958 -17- anhydride to the hydroxyl groups in precursor A was 1.1 : 1. Then the mixture was heated to 125°C and stirred at this temperature for 3 hours. Then 21.42 g of ethylene oxide were metered into the reactor at 125°C over a period of 30 minutes. The molar ratio of ethylene oxide to the hydroxyl groups in precursor A was 2 : 1. Following a post-reaction time at 125°C to establish constant pressure in the reactor, highly volatile components were distilled off under vacuum at 90°C for 30 minutes and the reaction mixture was then cooled to room temperature. The acid value of the product was 23.6 mg KOH/g at a viscosity (25°C) of 4140 mPas. The very high acid value shows that only a small conversion with ethylene oxide occurred.
Example 2: 400 g of the DMC-catalysed precursor A, 40.66 g of tetrahydrophthalic anhydride and 0.462 g (1000 ppm, relative to the complete batch) of DABCO (triethylenediamine) were placed in a 1-litre stainless steel pressure reactor under nitrogen. The molar ratio of anhydride to the hydroxyl groups in precursor A was
LI: 1. Then the mixture was heated to 125°C and stirred at this temperature for 3 hours. Then 21.42 g of ethylene oxide were metered into the reactor at 125°C over a period of 30 minutes. The molar ratio of ethylene oxide to the hydroxyl groups in precursor A was 2 : 1. Following a post-reaction time at 125°C to establish constant pressure in the reactor, highly volatile components were distilled off under vacuum at 90°C for 30 minutes and the reaction mixture was then cooled to room temperature.
Product characteristics:
OH value: 28.2 mg KOH/g
Acid value: 2.58 mg KOH/g
Viscosity (25°C): 3035 mPas
Primary OH groups: 65%
Example 3: 400 g of the DMC-catalysed precursor A, 40.66 g of tetrahydrophthalic anhydride and 0.462 g (1000 ppm, relative to the complete batch) of bis(2-dimethylaminoethyl) ether were placed in a 1-litre stainless steel pressure reactor under nitrogen. The
' WO 2011/000560 PCT/EP2010/003958 -18- : molar ratio of anhydride to the hydroxyl groups in precursor A was 1.1 : 1. Then the mixture was heated to 125°C and stirred at this temperature for 3 hours. Then 21.42 g of ethylene oxide were metered into the reactor at 125°C over a period of 30 minutes. The molar ratio of ethylene oxide to the hydroxyl groups in precursor A was 2: 1. Following a post-reaction time at 125°C to establish constant pressure in the reactor, highly volatile components were distilled off under vacuum at 90°C for 30 minutes and the reaction mixture was then cooled to room temperature.
Product characteristics:
OH value: 32.8 mg KOH/g
Acid value: 0.04 mg KOH/g
Viscosity (25°C): 2685 mPas
Primary OH groups: 69%
Example 4: 400 g of the DMC-catalysed precursor B, 37.54 g of tetrahydrophthalic anhydride and 0.459 g (1000 ppm, relative to the complete batch) of bis(2-dimethylaminoethyl) ether were placed in a 1-litre stainless steel pressure reactor under nitrogen. The molar ratio of anhydride to the hydroxy! groups in precursor B was 1 : 1. Then the mixture was heated to 125°C and stirred at this temperature for 3 hours. Then 21.74 g of ethylene oxide were metered into the reactor at 105°C over a period of 30 minutes. The molar ratio of ethylene oxide to the hydroxyl groups in precursor B was 2 : 1. Following a post-reaction time at 105°C to establish constant pressure in the reactor, highly volatile components were distilled off under vacuum at 90°C for 30 minutes and the reaction mixture was then cooled to room temperature.
Product characteristics:
OH value: 32.8 mg KOH/g
Acid value: 0.05 mg KOH/g
Viscosity (25°C): 2437 mPas
Primary OH groups: 73%
’ WO 2011/000560 PCT/EP2(:10/003958 -19-
Example 5: 400 g of the DMC-catalysed precursor B, 37.54 g of tetrahydrophthalic anhydride and 0.459 g (1000 ppm, relative to the complete batch) of bis(2-dimethylaminoethyl) ether were placed in a l-litre stainless steel pressure reactor under nitrogen. The molar ratio of anhydride to the hydroxyl groups in precursor B was 1 : 1. Then the mixture was heated to 125°C and stirred at this temperature for 3 hours. Then 21.74 g of ethylene oxide were metered into the reactor at 145°C over a period of 30 minutes. The molar ratio of ethylene oxide to the hydroxyl groups in precursor B was 2 : 1. Following a post-reaction time at 145°C to establish constant pressure in the reactor, highly volatile components were distilled off under vacuum at 90°C for 30 minutes and the reaction mixture was then cooled to room temperature.
Product characteristics:
OH value: 32.1 mg KOH/g
Acid value: 0.66 mg KOH/g
Viscosity (25°C): 2229 mPas
Primary OH groups: 69%
Example 6: 400 g of the DMC-catalysed precursor B, 41.29 g of tetrahydrophthalic anhydride and 0.463 g (1000 ppm, relative to the complete batch) of bis(2-dimethylaminoethyl) ether were placed in a I-litre stainless steel pressure reactor under nitrogen. The molar ratio of anhydride to the hydroxyl groups in precursor B was 1.1 : 1. Then the mixture was heated to 125°C and stirred at this temperature for 3 hours. Then 21.74 g of ethylene oxide were metered into the reactor at 105°C over a period of 30 minutes. The molar ratio of ethylene oxide to the hydroxyl groups in precursor B was 2: 1. Following a post-reaction time at 105°C to establish constant pressure in the reactor, highly volatile components were distilled off under vacuum at 90°C for minutes and the reaction mixture was then cooled to room temperature.
Product characteristics:
OH value: 32.2 mg KOH/g
Acid value: 0.53 mg KOH/g
Viscosity (25°C): 2750 mPas
Primary OH groups: 74%
Example 7: 400 g of the DMC-catalysed precursor B, 41.29 g of tetrahydrophthalic anhydride and 0.463 g (1000 ppm, relative to the complete batch) of bis(2-dimethylaminoethyl) ether were placed in a 1-litre stainless steel pressure reactor under nitrogen. The molar ratio of anhydride to the hydroxyl groups in precursor B was 1.1 : 1. Then the mixture was heated to 125°C and stirred at this temperature for 3 hours. Then 21.74 g of ethylene oxide were metered into the reactor at 145°C over a period of 30 minutes. The molar ratio of ethylene oxide to the hydroxyl groups in precursor B was 2 : 1. Following a post-reaction time at 145°C to establish constant pressure in the reactor, highly volatile components were distilled off under vacuum at 90°C for 30 minutes and the reaction mixture was then cooled to room temperature.
Product characteristics:
OH value: 28.3 mg KOH/g
Acid value: 2.84 mg KOH/g
Viscosity (25°C): 2525 mPas
Primary OH groups: 66%
Example 8: 400 g of the DMC-catalysed precursor B, 41.29 g of tetrahydrophthalic anhydride and 0.463 g (1000 ppm, relative to the complete batch) of bis(2-dimethylaminoethyl) ether were placed in a I-litre stainless steel pressure reactor under nitrogen. The molar ratio of anhydride to the hydroxyl groups in precursor B was 1.1 : 1. Then the mixture was heated to 125°C and stirred at this temperature for 3 hours. Then 21.74 g of ethylene oxide were metered into the reactor at 90°C over a period of minutes. The molar ratio of ethylene oxide to the hydroxyl groups in precursor B 30 was 2: 1. Following a post-reaction time at 90°C to establish constant pressure in
‘ WO 2011/000560 PCT/EP2010/003958 -21 - the reactor, highly volatile components were distilled off under vacuum at 90°C for 30 minutes and the reaction mixture was then cooled to room temperature.
Product characteristics:
OH value: 28.2 mg KOH/g
Acid value: 2.41 mg KOH/g
Viscosity (25°C): 3074 mPas
Primary OH groups: 75%
Example 9: 200 g of the DMC-catalysed precursor B, 20.64 g of tetrahydrophthalic anhydride and 0.232 g (1000 ppm, relative to the complete batch) of bis(2-dimethylaminoethyl) ether were placed in a 1-litre stainless steel pressure reactor under nitrogen. The molar ratio of anhydride to the hydroxyl groups in precursor B was 1.1 : 1. Then the mixture was heated to 125°C and stirred at this temperature for 3 hours. Then 6.0 g of ethylene oxide were metered into the reactor at 125°C over a period of 30 minutes. The molar ratio of ethylene oxide to the hydroxyl groups in precursor B was 1.1 : 1, Following a post-reaction time at 125°C to establish constant pressure in the reactor, highly volatile components were distilled off under vacuum at 90°C for 30 minutes and the reaction mixture was then cooled to room temperature.
Product characteristics:
OH value: 24.1 mg KOH/g
Acid value: 4.75 mg KOH/g
Viscosity (25°C): 2578 mPas
Primary OH groups: 63%
Example 10: 300 g of the DMC-catalysed precursor C, 31.59 g of tetrahydrophthalic anhydride and 0.348 g (1000 ppm, relative to the complete batch) of DABCO (triethylenediamine) were placed in a 1-litre stainless steel pressure reactor under nitrogen. The molar ratio of anhydride to the hydroxyl groups in precursor C was 1.1 : 1. Then the mixture was heated to 125°C and stirred at this temperature for 3 hours. Then 16.63 g of ethylene oxide were metered into the reactor at 125°C over
' WO 2411/000560 PCT/EP2010/003958 -22.- a period of 30 minutes. The molar ratio of ethylene oxide to the hydroxyl groups in precursor C was 2 : 1. Following a post-reaction time at 125°C to establish constant pressure in the reactor, highly volatile components were distilled off under vacuum at 90°C for 30 minutes and the reaction mixture was then cooled to room temperature.
Product characteristics:
OH value: 33.7 mg KOH/g
Acid value: 0.23 mg KOH/g
Viscosity (25°C): 2760 mPas
Primary OH groups: 76%
Example 11: 300 g of the DMC-catalysed precursor C, 31.59 g of tetrahydrophthalic anhydride and 0.348 g (1000 ppm, relative to the complete batch) of N,N- dimethylethanolamine were placed in a 1-litre stainless steel pressure reactor under nitrogen. The molar ratio of anhydride to the hydroxyl groups in precursor C was 1.1 : 1. Then the mixture was heated to 125°C and stirred at this temperature for 3 hours. Then 16.63 g of ethylene oxide were metered into the reactor at 125°C over a period of 30 minutes. The molar ratio of ethylene oxide to the hydroxyl groups in precursor C was 2 : 1. Following a post-reaction time at 125°C to establish constant pressure in the reactor, highly volatile components were distilled off under vacuum at 90°C for 30 minutes and the reaction mixture was then cooled to room temperature.
Product characteristics:
OH value: 34.3 mg KOH/g
Acid value: 0.12 mg KOH/g
Viscosity (25°C): 2274 mPas
Primary OH groups: 65%
Example 12: 300 g of the DMC-catalysed precursor C, 31.59 g of tetrahydrophthalic anhydride and 0.348 g (1000 ppm, relative to the complete batch) of bis(2-dimethylaminoethyl)
' WO 2011/000560 PCT/EP2010/003958 -23. ether were placed in a I-litre stainless steel pressure reactor under nitrogen. The molar ratio of anhydride to the hydroxyl groups in precursor C was 1.1 : 1. Then the mixture was heated to 125°C and stirred at this temperature for 3 hours. Then 16.63 g of ethylene oxide were metered into the reactor at 125°C over a period of 30 minutes. The molar ratio of ethylene oxide to the hydroxyl groups in precursor C was 2 : 1. Following a post-reaction time at 125°C to establish constant pressure in the reactor, highly volatile components were distilled off under vacuum at 90°C for 30 minutes and the reaction mixture was then cooled to room temperature,
Product characteristics:
OH value: 34.6 mg KOH/g
Acid value: 0.06 mg KOH/g
Viscosity (25°C): 2535 mPas
Primary OH groups: 70%
Tables 2 below summarises the data for Examples 1 to 12: ee [ea [oo
Polyether polyol from precursor te [aa ae
Cyclic carboxylic anhydride hydroxyl groups in polyether polyol hydroxyl groups in polyether polyol voiemnma | wo | we | 6 0 (*): Comparative example oe [5 [eo [1
Type
Polyether polyol from precursor
Type THPA | THPA | THPA | THPA
Cyclic carboxylic anhydride 37.54 41.29 41.29 41.29
Molar ratio of anhydride to hydroxyl [mol / mol] 1:1 1.1:1 11:1 | 1.1:1 groups in polyether polyol
Type DMAEE | DMAEE | DMAEE | DMAEE
Catalyst 0.459 0.463 0.459 | 0.463
Ethylene oxide Cw 21.74 21.74 21.74 21.74
Molar ratio of ethylene oxide to [mol / mol] 2:1 2:1 2:1 2:1 hydroxyl groups in polyether polyol eve | ra | us | os | ws ow ewe | [sw aw
Polyether polyol from precursor we |B ccf oc
Cyclic carboxylic anhydride we [oe [ran groups in polyether polyol esse | w | s [wwe] en groups in polyether polyol piamie wena] as | wn [on | une
It is clear from the very low acid values in the end products of the examples according to the invention that scarcely any free carboxyl groups which form after the opening of the cyclic anhydride did not react with ethylene oxide. Furthermore, a comparison of the hydroxyl values of the end products and of the precursor polyethers A, B and C used at the start shows that only a slight increase in the molecular weights of precursors A, B and C occurred as a result of the process according to the invention. Finally the results show that primary end groups were obtained in each case in a proportion of over 50%.
Claims (15)
1. Process for producing polyether polyols having primary hydroxyl end groups, comprising the following steps:
1. Reacting a starter compound containing active hydrogen atoms with an epoxide of the general formula (1): 0 Lo R1 (1) in which R1 denotes hydrogen, an alkyl radical or an aryl radical and with the proviso that > 0 wt.% to < 30 wt.%, relative to the total amount of the epoxide (1) used, are ethylene oxide, the reaction being performed in the presence of a double metal cyanide catalyst and the crude product of this reaction undergoing no further purification other than a possible distillation step;
2. Reacting the product obtained in step 1 with a cyclic carboxylic anhydride; and
3. Reacting the product obtained in step 2 with ethylene oxide in the presence of a catalyst containing at least one nitrogen atom per molecule, excluding non-cyclic, identically substituted tertiary amines.
2. Process according to claim 1, wherein the starter compound used in step 1 is apoly(oxyalkylene) polyol with an average functionality of > 2.0 to < 5.0, a number- average molecular mass of > 62 g/mol to < 1000 g/mol and an OH value of > 100 mg KOH/g to < 1860 mg KOH/g.
3. Process according to claim 1, wherein R1 in the epoxide of the general formula (1) is hydrogen, methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, isobutyl, tert-butyl, cyclohexyl and/or phenyl.
4. Process according to claim 1, wherein the double metal cyanide catalyst in step 1 comprises zinc, cobalt and tert-butanol.
‘ WO 2011/000560 PCT/EP2010/0039538
-28.
5. Process according to claim 1, wherein the cyclic carboxylic anhydride used in step 2 is selected from the group comprising phthalic anhydride, tetrahydrophthalic anhydride, succinic anhydride and/or maleic anhydride.
6. Process according to claim 1, wherein the catalyst used in step 3 is selected from the group comprising: (A) Amines of the general formula (2): R2 Oo N Re”, TR3 (2) in which: R2 and R3 are independently of each other hydrogen, alkyl or aryl; or R2 and R3 together with the N-atom bearing them form an aliphatic, unsaturated or aromatic heterocycle; n is a whole number from 1 to 10; R4 is hydrogen, alkyl or aryl; or R4 denotes —(CHz),—N(R41)(R42), in which: R41 and R42 are independently of each other hydrogen, alkyl or aryl; or R41 and R42 together with the N-atom bearing them form an aliphatic, unsaturated or aromatic heterocycle; X is a whole number from 1 to 10; (B) Amines of the general formula (3): RO 0 N 0 R6” J, 5 R7 (3) in which: RS 1s hydrogen, alkyl or aryl;
R6 and R7 are independently of each other hydrogen, alkyl or aryl, m and o are independently of each other a whole number from I to 10; and/or: (Cy) Diazabicyclo[2.2.2]octane, diazabicyclo[5.4.0Jundec-7-ene, dialkylbenzyl- amine, dimethylpiperazine, 2,2'-dimorpholinyldiethyl ether and/or pyridine.
7. Process according to claim 1, wherein the molar ratio in step 2 of cyclic anhydride to hydroxyl groups in the product obtained in step 1 is > 0.75 : 1 to <13:1.
8. Process according to claim 1, wherein the catalyst containing at least one nitrogen atom per molecule is present in step 3 in a proportion of = 500 ppm to < 1500 ppm relative to the total mass of the reaction batch in steps 2 and 3.
9. Process according to claim 1, wherein the molar ratio in step 3 of ethylene oxide to hydroxyl groups in the product obtained in step 1 is> 0.90: 1t0 £5.0: 1.
10. Polyether polyol having primary hydroxyl end groups, obtainable by a process according to claim 1, comprising a polyether block, a terminal hydroxyethyl group and a diester unit linking the polyether block and the terminal hydroxyethyl group and wherein the molar proportion of terminal double bonds, relative to all end groups of the polyether polyol, is > 0 milliequivalents per kg to < 10 milliequivalents per kg.
11. Polyether polyol according to claim 10, wherein the molar proportion of primary hydroxyl groups is > 50 mol% to < 100 mol%.
12. Polyether polyol according to claim 10 with an OH value of > 10 mg KOH/g to < 100 mg KOH/g.
13. Polyether polyol according to claim 10 with an acid value of > 0.01 mg KOH/gto<5mgKOH/g.
) WO 2011/000560 PCT/EP2010/003958 -30-
14. Polyether polyol composition comprising a polyether polyol according to claim 10 and additionally: (A) Amines of the general formula (4): RE 0 N R107 05 “RO (4) in which: R8 and RY are independently of each other hydrogen, alkyl or aryl; or R8 and R9 together with the N-atom bearing them form an aliphatic, unsaturated or aromatic heterocycle; p is a whole number from 1 to 10,16. 1,2,3,4, 5,6, 7,8, 9 or 10; R10 is hydrogen, alkyl or aryl; or R10 denotes —(CH,),—N(R11)(R12), in which: R11 and R12 are independently of each other hydrogen, alkyl or aryl; or R11 and R12 together with the N-atom bearing them form an aliphatic, unsaturated or aromatic heterocycle; y is a whole number from 1 to 10, i.e. 1,2, 3,4,5,6,7,8,9 or 10; (B) Amines of the general formula (5): R1 3 O N 0 R14770, © R15 (5) in which: R13 is hydrogen, alkyl or aryl, R14 and R15 are independently of each other hydrogen, alkyl or aryl; r and s are independently of each other a whole number from 1 to 10, i.e. 1, 2,3,4,5,6,7,8,9o0r 10;
Co WO 2011/000560 PCT/EP2010/003958 -31- and/or: (C} Diazabicyclo[2.2.2]octane, diazabicyclo{5.4.0]undec-7-ene, dialkylbenzylamine, dimethylpiperazine, 2,2'-dimorpholinyldiethyl ether and/or pyridine.
15. Polyurethane polymer obtainable from the reaction of a polyisocyanate with a polyether polyol according to claim 10 or a polyether polyol composition according to claim 14.
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PCT/EP2010/003958 WO2011000560A1 (en) | 2009-07-03 | 2010-06-30 | Method for the production of polyether polyols comprising terminal primary hydroxyl groups |
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BR (1) | BRPI1011807A2 (en) |
CA (1) | CA2767040A1 (en) |
DE (1) | DE102009031584A1 (en) |
ES (1) | ES2432501T5 (en) |
MX (1) | MX2011013699A (en) |
SG (1) | SG177282A1 (en) |
WO (1) | WO2011000560A1 (en) |
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WO2011075343A1 (en) * | 2009-12-17 | 2011-06-23 | Dow Global Technologies Inc. | Ethylene oxide capping of secondary hydroxyl polyols |
JP5873931B2 (en) * | 2011-12-20 | 2016-03-01 | メディカル・アドヒーシブ・レボリューション・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングMedical Adhesive Revolution GmbH | Hydroxyamino polymers and their use in polyurea / polyurethane tissue adhesives |
EP2617748A1 (en) | 2012-01-23 | 2013-07-24 | Basf Se | Polyether ester polyols and method for their manufacture |
JP6598855B2 (en) | 2014-10-22 | 2019-10-30 | ダウ グローバル テクノロジーズ エルエルシー | Dual catalyst system for high primary hydroxyl polyols |
US11198760B2 (en) * | 2017-09-14 | 2021-12-14 | Dow Global Technologies Llc | Process of manufacturing polyols |
CN109180928B (en) * | 2018-09-14 | 2021-02-02 | 湖北工业大学 | Preparation method of high-purity monocarboxyl-terminated polyethylene glycol |
EP3670568A1 (en) | 2018-12-21 | 2020-06-24 | Covestro Deutschland AG | Method for producing a polyester |
EP3670557A1 (en) * | 2018-12-21 | 2020-06-24 | Covestro Deutschland AG | Method for producing a polyoxyalkylenpolyesterpolyol |
EP3670571A1 (en) | 2018-12-21 | 2020-06-24 | Covestro Deutschland AG | Method for producing a polyester-polyetherpolyol block copolymer |
CN110540640A (en) * | 2019-09-19 | 2019-12-06 | 福建省天骄化学材料有限公司 | Preparation method of special dispersing agent for shoe materials |
EP3875510A1 (en) | 2020-03-03 | 2021-09-08 | Covestro Deutschland AG | Method for producing an ether estol |
EP3889204A1 (en) | 2020-04-02 | 2021-10-06 | Covestro Deutschland AG | Method for producing a polyoxyalkylene carbonate polyol |
CN114369236B (en) * | 2021-11-30 | 2024-04-12 | 山东一诺威新材料有限公司 | High-performance polyester ether polyol, and preparation method and application thereof |
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DE3315381A1 (en) | 1983-04-28 | 1984-10-31 | Basf Ag, 6700 Ludwigshafen | METHOD FOR PRODUCING POLYESTER OR POLYETHER-POLYESTER POLYOLS |
US4487853A (en) | 1983-12-27 | 1984-12-11 | Basf Wyandotte Corporation | Low ethylene oxide/high primary hydroxyl content polyether-ester polyols and polyurethane foams based thereon |
GB8613701D0 (en) * | 1986-06-05 | 1986-07-09 | Ici Plc | Polymeric polyols |
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US5714428A (en) | 1996-10-16 | 1998-02-03 | Arco Chemical Technology, L.P. | Double metal cyanide catalysts containing functionalized polymers |
US5763642A (en) * | 1997-06-19 | 1998-06-09 | Arco Chemical Technology, L.P. | Low monol polyoxy (higher) alkylene polyols with primary hydroxyl content |
US6066683A (en) † | 1998-04-03 | 2000-05-23 | Lyondell Chemical Worldwide, Inc. | Molded and slab polyurethane foam prepared from double metal cyanide complex-catalyzed polyoxyalkylene polyols and polyols suitable for the preparation thereof |
DE19905611A1 (en) | 1999-02-11 | 2000-08-17 | Bayer Ag | Double metal cyanide catalysts for the production of polyether polyols |
US20050085658A1 (en) * | 1999-10-25 | 2005-04-21 | Geiger Eric J. | Phthalic anhydride based polyester-ether polyols and double metal cyanide catalyst system for preparing same |
US7226988B1 (en) † | 2001-12-21 | 2007-06-05 | Basf Corporation | Method of forming polyetherols in the presence of carboxy-modified aluminum-based catalysts |
US6777533B2 (en) † | 2001-12-21 | 2004-08-17 | Basf Corporation | Production of polyetherols using aluminum phosphonate catalysts |
US7186867B2 (en) † | 2004-04-21 | 2007-03-06 | Basf Aktiengesellschaft | Process for preparing reactive polyether polyols having an ethylene oxide end block |
US8933188B2 (en) | 2004-11-12 | 2015-01-13 | Henkel US IP LLC | Low misting laminating adhesives |
DE102007002555A1 (en) * | 2007-01-17 | 2008-07-24 | Bayer Materialscience Ag | Double metal cyanide catalysts for the preparation of polyether polyols |
WO2011075343A1 (en) * | 2009-12-17 | 2011-06-23 | Dow Global Technologies Inc. | Ethylene oxide capping of secondary hydroxyl polyols |
US8680211B2 (en) * | 2010-04-29 | 2014-03-25 | Dow Global Technologies Llc | Hybrid polyester-polyether polyols |
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2009
- 2009-07-03 DE DE200910031584 patent/DE102009031584A1/en not_active Withdrawn
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2010
- 2010-06-30 CN CN201080030088.1A patent/CN102471478B/en not_active Expired - Fee Related
- 2010-06-30 WO PCT/EP2010/003958 patent/WO2011000560A1/en active Application Filing
- 2010-06-30 CA CA2767040A patent/CA2767040A1/en not_active Abandoned
- 2010-06-30 KR KR1020127000005A patent/KR101744362B1/en active IP Right Grant
- 2010-06-30 SG SG2011093952A patent/SG177282A1/en unknown
- 2010-06-30 MX MX2011013699A patent/MX2011013699A/en unknown
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- 2010-06-30 JP JP2012518795A patent/JP2012531506A/en not_active Withdrawn
- 2010-06-30 EP EP10729815.0A patent/EP2448996B2/en not_active Not-in-force
- 2010-06-30 US US13/381,130 patent/US9029495B2/en active Active
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CN102471478B (en) | 2016-03-09 |
BRPI1011807A2 (en) | 2016-05-31 |
ES2432501T5 (en) | 2017-09-11 |
KR20120095338A (en) | 2012-08-28 |
WO2011000560A1 (en) | 2011-01-06 |
ES2432501T3 (en) | 2013-12-03 |
US9029495B2 (en) | 2015-05-12 |
US20120196999A1 (en) | 2012-08-02 |
JP2012531506A (en) | 2012-12-10 |
EP2448996B2 (en) | 2017-04-12 |
EP2448996B1 (en) | 2013-08-28 |
DE102009031584A1 (en) | 2011-01-05 |
CA2767040A1 (en) | 2011-01-06 |
CN102471478A (en) | 2012-05-23 |
MX2011013699A (en) | 2012-02-22 |
EP2448996A1 (en) | 2012-05-09 |
KR101744362B1 (en) | 2017-06-07 |
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