SG11202103828RA - Alkane-soluble non-metallocene precatalysts - Google Patents

Alkane-soluble non-metallocene precatalysts

Info

Publication number
SG11202103828RA
SG11202103828RA SG11202103828RA SG11202103828RA SG11202103828RA SG 11202103828R A SG11202103828R A SG 11202103828RA SG 11202103828R A SG11202103828R A SG 11202103828RA SG 11202103828R A SG11202103828R A SG 11202103828RA SG 11202103828R A SG11202103828R A SG 11202103828RA
Authority
SG
Singapore
Prior art keywords
alkane
soluble non
precatalysts
metallocene
metallocene precatalysts
Prior art date
Application number
SG11202103828RA
Inventor
Bethany M Neilson
Roger L Kuhlman
Ian M Munro
John F Szul
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of SG11202103828RA publication Critical patent/SG11202103828RA/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic System without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/0805—Compounds with Si-C or Si-Si linkages comprising only Si, C or H atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64082—Tridentate ligand
    • C08F4/64141—Dianionic ligand
    • C08F4/64148—NN(R)N
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/05—Bimodal or multimodal molecular weight distribution
SG11202103828RA 2018-11-06 2019-10-11 Alkane-soluble non-metallocene precatalysts SG11202103828RA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201862756237P 2018-11-06 2018-11-06
PCT/US2019/055878 WO2020096732A1 (en) 2018-11-06 2019-10-11 Alkane-soluble non-metallocene precatalysts

Publications (1)

Publication Number Publication Date
SG11202103828RA true SG11202103828RA (en) 2021-05-28

Family

ID=68387431

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11202103828RA SG11202103828RA (en) 2018-11-06 2019-10-11 Alkane-soluble non-metallocene precatalysts

Country Status (9)

Country Link
US (1) US11891464B2 (en)
EP (1) EP3877391B1 (en)
JP (1) JP2022504861A (en)
KR (1) KR20210090648A (en)
CN (1) CN112805289A (en)
BR (1) BR112021006521B1 (en)
CA (1) CA3117995A1 (en)
SG (1) SG11202103828RA (en)
WO (1) WO2020096732A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20230144520A1 (en) * 2020-05-29 2023-05-11 Dow Global Technologies Llc Attenuated post-metallocene catalysts
EP4157892A1 (en) * 2020-05-29 2023-04-05 Dow Global Technologies LLC Attenuated post-metallocene catalysts
EP4157896A1 (en) * 2020-05-29 2023-04-05 Dow Global Technologies LLC Attenuated post-metallocene catalysts
US20230203218A1 (en) * 2020-05-29 2023-06-29 Dow Global Technologies Llc Chemically converted catalysts
CA3180283A1 (en) * 2020-05-29 2021-12-02 Rhett A. BAILLIE Chemically converted catalysts
BR112022023953A2 (en) * 2020-05-29 2022-12-20 Dow Global Technologies Llc METHODS FOR MAKING AN ATTENUATED HYBRID CATALYST, FEEDING A HYBRID CATALYST INTO A PASTE-PHASE OR GAS-PHASE POLYMERIZATION REACTOR, AND MANUFACTURING A POLYOLFIN POLYMER, ATTENUED HYBRID CATALYST, AND, MULTIMODAL CATALYST SYSTEM
US20230406967A1 (en) 2020-10-28 2023-12-21 Exxonmobil Chemical Patents Inc. Non-Aromatic Hydrocarbon Soluble Olefin Polymerization Catalysts and Use Thereof

Family Cites Families (77)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4003712A (en) 1970-07-29 1977-01-18 Union Carbide Corporation Fluidized bed reactor
US3709853A (en) 1971-04-29 1973-01-09 Union Carbide Corp Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts
US4011382A (en) 1975-03-10 1977-03-08 Union Carbide Corporation Preparation of low and medium density ethylene polymer in fluid bed reactor
US4302566A (en) 1978-03-31 1981-11-24 Union Carbide Corporation Preparation of ethylene copolymers in fluid bed reactor
CA1168521A (en) 1982-02-01 1984-06-05 Clifford F. Thompson Leak detector
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4988783A (en) 1983-03-29 1991-01-29 Union Carbide Chemicals And Plastics Company Inc. Ethylene polymerization using supported vanadium catalyst
US4665208A (en) 1985-07-11 1987-05-12 Exxon Chemical Patents Inc. Process for the preparation of alumoxanes
WO1988002378A1 (en) 1986-09-24 1988-04-07 Mitsui Petrochemical Industries, Ltd. Process for polymerizing olefin
JPH0780933B2 (en) 1986-11-20 1995-08-30 三井石油化学工業株式会社 Olefin Polymerization Method
JPH0742301B2 (en) 1987-02-14 1995-05-10 三井石油化学工業株式会社 Particulate aluminoxane, its manufacturing method and its use
JP2538588B2 (en) 1987-04-03 1996-09-25 三井石油化学工業株式会社 Method for producing solid catalyst for olefin polymerization
US5206199A (en) 1987-04-20 1993-04-27 Mitsui Petrochemical Industries, Ltd. Catalyst for polymerizing an olefin and process for polymerizing an olefin
FR2618786B1 (en) 1987-07-31 1989-12-01 Bp Chimie Sa PROCESS FOR THE POLYMERIZATION OF GASEOUS OLEFINS IN A FLUIDIZED BED REACTOR
US5091352A (en) 1988-09-14 1992-02-25 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins
US5041584A (en) 1988-12-02 1991-08-20 Texas Alkyls, Inc. Modified methylaluminoxane
US4908463A (en) 1988-12-05 1990-03-13 Ethyl Corporation Aluminoxane process
US5103031A (en) 1989-02-21 1992-04-07 Ethyl Corporation Falling film aluminoxane process
US4968827A (en) 1989-06-06 1990-11-06 Ethyl Corporation Alkylaluminoxane process
US4924018A (en) 1989-06-26 1990-05-08 Ethyl Corporation Alkylaluminoxane process
US4994534A (en) 1989-09-28 1991-02-19 Union Carbide Chemicals And Plastics Company Inc. Process for producing sticky polymers
AU9136391A (en) 1990-12-27 1992-08-17 Exxon Chemical Patents Inc. An amido transition metal compound and a catalyst system for the production of isotactic polypropylene
TW218884B (en) 1991-05-01 1994-01-11 Mitsubishi Kakoki Kk
US5341124A (en) 1991-05-29 1994-08-23 Se-Kure Controls, Inc. Mountable product sensor and display stand
US5157137A (en) 1991-07-26 1992-10-20 Ethyl Corporation Method of making gel free alkylaluminoxane solutions
US5235081A (en) 1992-03-18 1993-08-10 Ethyl Corporation Method of removing gel forming materials from methylaluminoxanes
US5329032A (en) 1992-03-18 1994-07-12 Akzo Chemicals Inc. Polymethylaluminoxane of enhanced solution stability
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
US5473202A (en) 1992-06-05 1995-12-05 Brian Platner Control unit for occupancy sensor switching of high efficiency lighting
US5248801A (en) 1992-08-27 1993-09-28 Ethyl Corporation Preparation of methylaluminoxanes
US5939346A (en) 1992-11-02 1999-08-17 Akzo Nobel N.V. Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group
US5462999A (en) 1993-04-26 1995-10-31 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
ZA943399B (en) 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
CA2127822A1 (en) 1993-07-13 1995-01-14 Yoshinori Morita Process for gas phase polymerization of olefin
EP0649992B1 (en) 1993-10-23 1997-07-30 WABCO GmbH Disc brake actuator
US5648310A (en) 1993-12-23 1997-07-15 Union Carbide Chemicals & Plastics Technology Corporation Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
US5506184A (en) 1994-06-22 1996-04-09 Mobil Oil Corporation Olefin polymerization catalyst system
US5770755A (en) 1994-11-15 1998-06-23 Phillips Petroleum Company Process to prepare polymeric metallocenes
US5677375A (en) 1995-07-21 1997-10-14 Union Carbide Chemicals & Plastics Technology Corporation Process for producing an in situ polyethylene blend
JP3582181B2 (en) 1995-10-04 2004-10-27 住友化学工業株式会社 Carrier for olefin polymerization catalyst, olefin polymerization catalyst and method for producing olefin polymer
US5688880A (en) 1995-12-11 1997-11-18 The Dow Chemical Company Readily supportable metal complexes
US5665818A (en) 1996-03-05 1997-09-09 Union Carbide Chemicals & Plastics Technology Corporation High activity staged reactor process
US5627242A (en) 1996-03-28 1997-05-06 Union Carbide Chemicals & Plastics Technology Corporation Process for controlling gas phase fluidized bed polymerization reactor
ES2129323B1 (en) 1996-04-18 2000-09-16 Repsol Quimica Sa PROCEDURE FOR OBTAINING A CATALYTIC SYSTEM FOR THE POLYMERIZATION OF ALPHA-OLEFINS IN SUSPENSION IN GAS PHASE AT LOW AND HIGH TEMPERATURES OR IN MASS AT HIGH PRESSURES AND HIGH OR LOW TEMPERATURES
US6255419B1 (en) 1997-02-07 2001-07-03 Mitsui Chemicals, Inc. Olefin polymerization catalyst and process for producing olefin polymers
EP0878486B1 (en) 1997-02-21 2006-01-25 Council of Scientific and Industrial Research A process for the preparation of supported metallocene catalyst
US5889128A (en) 1997-04-11 1999-03-30 Massachusetts Institute Of Technology Living olefin polymerization processes
JP3458656B2 (en) 1997-05-27 2003-10-20 東ソー株式会社 Olefin polymerization catalyst and method for producing olefin polymer
US5972510A (en) 1997-06-05 1999-10-26 Isis Innovation Limited Spherulite particles of isotactic polypropylene
US6465543B1 (en) 1998-03-16 2002-10-15 The Dow Chemical Company Polyolefin nanocomposites
BR9909200A (en) 1998-03-26 2000-11-14 Chemical Company Aerogels of aluminum-magnesium silicate or fluorinated magnesium subjected to ion exchange and catalyst supports produced from them
JP2002509949A (en) 1998-03-27 2002-04-02 エクソンモービル・ケミカル・パテンツ・インク Polymer supported catalyst for olefin polymerization
CA2331413C (en) 1998-05-18 2007-04-17 Phillips Petroleum Company Catalyst composition for polymerizing monomers
KR100568839B1 (en) * 1998-10-23 2006-04-10 엑손 케미칼 패턴츠, 아이엔씨. Bridged metallocenes for olefin copolymerization
US6274684B1 (en) 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US6489408B2 (en) 2000-11-30 2002-12-03 Univation Technologies, Llc Polymerization process
US7795366B2 (en) 2002-08-12 2010-09-14 Exxonmobil Chemical Patents Inc. Modified polyethylene compositions
US6858684B2 (en) 2002-12-30 2005-02-22 Univation Technologies, Llc Processes for transitioning between various polymerization catalysts
US6949612B2 (en) 2002-12-31 2005-09-27 Univation Technologies, Llc Processes for transitioning between metallocene and Ziegler-Natta polymerization catalysts
US20050182210A1 (en) 2004-02-17 2005-08-18 Natarajan Muruganandam De-foaming spray dried catalyst slurries
US6967184B2 (en) 2004-02-17 2005-11-22 Univation Technologies, Llc Fluoroalcohol leaving group for non-metallocene olefin polymerization catalysts
US7973112B2 (en) 2004-02-17 2011-07-05 Univation Technologies, Llc De-foaming spray dried catalyst slurries
WO2006083303A1 (en) 2004-06-21 2006-08-10 Exxonmobil Chemical Patents Inc. Polymerization process
DE102004047371A1 (en) 2004-09-29 2006-03-30 Siemens Ag Method for distributing software and configuration data and corresponding data network
JP4692761B2 (en) 2006-03-29 2011-06-01 カシオ計算機株式会社 OFDM receiving apparatus, OFDM receiving method, and terrestrial digital receiving apparatus
TWI359822B (en) 2006-06-16 2012-03-11 Lg Chemical Ltd Method for polymerizing cyclic olefin having polar
US8835577B2 (en) 2007-11-15 2014-09-16 Univation Technologies, Llc Catalyst systems having a tailored hydrogen response
TWI445751B (en) 2008-07-16 2014-07-21 Univation Tech Llc Polyethylene compositions
WO2010053696A2 (en) 2008-11-10 2010-05-14 Univation Technologies, Llc Processes for the preparation of arylamine compounds
EP2750797B1 (en) 2011-11-08 2020-04-01 Univation Technologies, LLC Methods of preparing a catalyst system
ES2644669T3 (en) 2013-03-15 2017-11-29 Univation Technologies, Llc Ligands for catalysts
RU2674254C1 (en) 2014-02-11 2018-12-06 ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи Obtaining polyolefin products
CN107108804B (en) 2014-12-31 2020-07-24 陶氏环球技术有限责任公司 Polyolefin composition and process for producing the same
SG11201708069UA (en) 2015-04-08 2017-10-30 Univation Tech Llc Closed reactor transitions between metallocene catalysts
WO2016172567A1 (en) 2015-04-24 2016-10-27 Univation Technologies, Llc Methods for operating a polymerization reactor
EP3580245B1 (en) 2017-02-13 2020-11-25 Univation Technologies, LLC Bimodal polyethylene resins

Also Published As

Publication number Publication date
CN112805289A (en) 2021-05-14
EP3877391B1 (en) 2023-11-15
CA3117995A1 (en) 2020-05-14
US20220049032A1 (en) 2022-02-17
WO2020096732A1 (en) 2020-05-14
BR112021006521A2 (en) 2021-07-06
US11891464B2 (en) 2024-02-06
EP3877391A1 (en) 2021-09-15
BR112021006521B1 (en) 2024-03-05
JP2022504861A (en) 2022-01-13
KR20210090648A (en) 2021-07-20

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