SG11202002605TA - Bis-phenyl-phenoxy polyolefin catalysts having an alkoxy- or amido-ligand on the metal for improved solubility - Google Patents

Bis-phenyl-phenoxy polyolefin catalysts having an alkoxy- or amido-ligand on the metal for improved solubility

Info

Publication number
SG11202002605TA
SG11202002605TA SG11202002605TA SG11202002605TA SG11202002605TA SG 11202002605T A SG11202002605T A SG 11202002605TA SG 11202002605T A SG11202002605T A SG 11202002605TA SG 11202002605T A SG11202002605T A SG 11202002605TA SG 11202002605T A SG11202002605T A SG 11202002605TA
Authority
SG
Singapore
Prior art keywords
amido
ligand
alkoxy
bis
phenyl
Prior art date
Application number
SG11202002605TA
Inventor
Arkady L Krasovskiy
David R Wilson
Tulaza Vaidya
Edmund M Carnahan
Philip P Fontaine
Carl N Iverson
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of SG11202002605TA publication Critical patent/SG11202002605TA/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64006—Bidentate ligand
    • C08F4/64041—Monoanionic ligand
    • C08F4/64058—OO
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64168—Tetra- or multi-dentate ligand
    • C08F4/64186—Dianionic ligand
    • C08F4/64193—OOOO
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
SG11202002605TA 2017-09-29 2018-09-19 Bis-phenyl-phenoxy polyolefin catalysts having an alkoxy- or amido-ligand on the metal for improved solubility SG11202002605TA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201762565780P 2017-09-29 2017-09-29
PCT/US2018/051680 WO2019067280A1 (en) 2017-09-29 2018-09-19 Bis-phenyl-phenoxy polyolefin catalysts having an alkoxy- or amido-ligand on the metal for improved solubility

Publications (1)

Publication Number Publication Date
SG11202002605TA true SG11202002605TA (en) 2020-04-29

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
SG11202002605TA SG11202002605TA (en) 2017-09-29 2018-09-19 Bis-phenyl-phenoxy polyolefin catalysts having an alkoxy- or amido-ligand on the metal for improved solubility

Country Status (9)

Country Link
US (1) US11242415B2 (en)
EP (1) EP3688043B1 (en)
JP (1) JP7208981B2 (en)
KR (1) KR102590973B1 (en)
CN (1) CN111164110A (en)
ES (1) ES2951157T3 (en)
SA (1) SA520411657B1 (en)
SG (1) SG11202002605TA (en)
WO (1) WO2019067280A1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116997581A (en) 2021-03-31 2023-11-03 陶氏环球技术有限责任公司 Process and catalyst system for producing isotactic polypropylene

Family Cites Families (68)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1069848A (en) 1965-05-17 1967-05-24 Imp Chemical Imdustries Ltd Process for the polymerisation of vinyl chloride
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US7163907B1 (en) 1987-01-30 2007-01-16 Exxonmobil Chemical Patents Inc. Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
JP2545006B2 (en) 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー Addition polymerization catalyst
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5350723A (en) 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
US5372682A (en) 1993-06-24 1994-12-13 The Dow Chemical Company Electrochemical preparation of addition polymerization catalysts
US5625087A (en) 1994-09-12 1997-04-29 The Dow Chemical Company Silylium cationic polymerization activators for metallocene complexes
WO1997035892A1 (en) 1996-03-27 1997-10-02 The Dow Chemical Company Solution polymerization process with dispersed catalyst activator
CN1120849C (en) 1996-03-27 2003-09-10 陶氏环球技术公司 Highly soluble olefin polymerization catalyst activator
CN1142192C (en) 1996-05-02 2004-03-17 伊奎斯塔化学有限公司 Catalyst system containing reaction product of liquid cilicone and polyamine
US5783512A (en) 1996-12-18 1998-07-21 The Dow Chemical Company Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same
US6103657A (en) 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
US6696379B1 (en) 1997-09-19 2004-02-24 The Dow Chemical Company Supported modified alumoxane catalyst activator
JP2000159829A (en) 1998-11-27 2000-06-13 Tosoh Corp Catalyst for olefin polymerization and production of polyolefin using same
AU1773901A (en) 1999-12-10 2001-06-18 Dow Chemical Company, The Substituted group 4 metal complexes, catalysts and olefin polymerization process
US6841502B2 (en) 2002-04-24 2005-01-11 Symyx Technologies, Inc. Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom
US7060848B2 (en) 2002-04-24 2006-06-13 Symyx Technologies, Inc. Bridged bi-aromatic catalysts, complexes, and methods of using the same
CN101724110B (en) 2002-10-15 2013-03-27 埃克森美孚化学专利公司 Multiple catalyst system for olefin polymerization and polymers produced therefrom
BRPI0508173B1 (en) 2004-03-17 2016-03-15 Dow Global Technologies Inc multiblock copolymers, polymer, copolymer, a functional derivative, homogeneous polymer blend, process for preparing a propylene-containing multiblock copolymer and process for preparing a 4-methyl-1-pentene multiblock copolymer
US20050276835A1 (en) 2004-04-30 2005-12-15 Joerg Lahann Photo-reactive polymer platform for use in biomedical devices
DE102004030714A1 (en) 2004-06-25 2006-01-12 Clariant Gmbh Melt adhesives
US8354484B2 (en) 2006-05-17 2013-01-15 Dow Global Technologies, Llc High temperature solution polymerization process
WO2009105938A1 (en) 2008-02-29 2009-09-03 Dow Global Technologies Inc. Oriented films comprising ethylene/α-olefin block interpolymer
US8372930B2 (en) 2008-06-20 2013-02-12 Exxonmobil Chemical Patents Inc. High vinyl terminated propylene based oligomers
US8802797B2 (en) 2008-06-20 2014-08-12 Exxonmobil Chemical Patents Inc. Vinyl-terminated macromonomer oligomerization
CN102131837B (en) * 2008-08-21 2014-10-15 陶氏环球技术有限责任公司 Metal-ligand complexes and catalysts
WO2010061630A1 (en) 2008-11-28 2010-06-03 三菱レイヨン株式会社 Processing assistant for expansion molding, vinyl chloride resin composition for expansion molding, and expansion molded body
US20110054122A1 (en) * 2009-08-31 2011-03-03 Jerzy Klosin Catalyst and process for polymerizing an olefin and polyolefin prepared thereby
US8716400B2 (en) 2009-10-02 2014-05-06 Dow Global Technologies Llc Block composites and impact modified compositions
JP5806218B2 (en) 2009-10-02 2015-11-10 ダウ グローバル テクノロジーズ エルエルシー Block composite and impact-resistant modified composition
EP3549960B1 (en) 2010-02-19 2021-03-24 Dow Global Technologies LLC Process for polymerizing an olefin monomer and catalyst therefor
RU2012141894A (en) 2010-03-02 2014-04-10 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи POLYMER COMPOSITIONS BASED ON ETHYLENE
MX350592B (en) 2010-05-17 2017-09-11 Dow Global Tech Llc * Process for selectively polymerizing ethylene and catalyst therefor.
WO2011146044A1 (en) 2010-05-17 2011-11-24 Dow Global Technologies Llc Process for selectively polymerizing ethylene and catalyst therefor
US8822599B2 (en) 2010-06-21 2014-09-02 Dow Global Technologies Llc Crystalline block composites as compatibilizers
EP2591019A2 (en) 2010-07-06 2013-05-15 Ticona GmbH Process for producing high molecular weight polyethylene
WO2012004683A2 (en) 2010-07-06 2012-01-12 Ticona Gmbh Ultra-high molecular weight polyethylene, its production and use
BR112013001966A2 (en) 2010-07-27 2019-09-24 Henkel Ag & Co Kgaa process for manufacturing an adhesive by extrusion
KR20180066258A (en) 2010-08-25 2018-06-18 다우 글로벌 테크놀로지스 엘엘씨 Process for polymerizing a polymerizable olefin and catalyst therefor
US20120116034A1 (en) * 2010-11-08 2012-05-10 Dow Global Technologies, Inc. Solution polymerization process and procatalyst carrier systems useful therein
ES2835230T3 (en) 2010-11-19 2021-06-22 Henkel Ag & Co Kgaa Adhesive compositions and their use
WO2012069428A1 (en) 2010-11-22 2012-05-31 Noscira, S.A. Bipyridine sulfonamide derivatives for the treatment of neurodegenerative diseases or conditions
BR112013013634B1 (en) 2010-12-03 2020-11-10 Dow Global Technologies Llc process for forming an ethylene-based polymer composition, polymer composition, composition, article
US9643900B2 (en) 2011-03-25 2017-05-09 Dow Global Technologies Llc Hyperbranched ethylene-based oils and greases
WO2014209927A1 (en) 2013-06-28 2014-12-31 Dow Global Technologies Llc Hyperbranched ethylene-based oligomers
WO2012149391A1 (en) 2011-04-28 2012-11-01 Adherent Laboratories, Inc. Polyolefin based hot melt adhesive composition
US9522855B2 (en) 2011-12-29 2016-12-20 Dow Global Technologies Llc Process for producing low molecular weight ethylene- and alpha-olefin-based materials
WO2013101376A1 (en) 2011-12-29 2013-07-04 Dow Global Technologies Llc Hyperbranched olefin oil-based dielectric fluid
WO2014043522A1 (en) 2012-09-14 2014-03-20 Dow Global Technologies Llc Multilayered polyolefin-based films
JP6211088B2 (en) 2012-10-09 2017-10-11 ダウ グローバル テクノロジーズ エルエルシー Sealant composition
JP6175507B2 (en) 2012-10-18 2017-08-02 ダウ グローバル テクノロジーズ エルエルシー Low viscosity high flash point dielectric fluid based on oleic acid and medium chain length triglycerides
EP2938649B1 (en) 2012-12-27 2019-04-10 Dow Global Technologies LLC A polymerization process for producing ethylene based polymers
US20150337062A1 (en) 2012-12-27 2015-11-26 Dow Global Technologies Llc Ethylene Based Polymer
WO2014105413A1 (en) 2012-12-27 2014-07-03 Dow Global Technologies Llc An ethylene based polymer
JP6393693B2 (en) * 2012-12-27 2018-09-19 ダウ グローバル テクノロジーズ エルエルシー Catalytic system for olefin polymerization.
SG11201505073SA (en) 2012-12-27 2015-07-30 Dow Global Technologies Llc A polymerization process for producing ethylene based polymers
SG11201510689SA (en) 2013-06-28 2016-01-28 Dow Global Technologies Llc Molecular weight control of polyolefins using halogenated bis-phenylphenoxy catalysts
US10072172B2 (en) 2013-09-25 2018-09-11 Mitsubishi Chemical Corporation Flexible vinyl chloride resin composition, molded product, electric wire coating material, and coated electric wire
CN105723471B (en) 2013-09-25 2019-01-11 三菱化学株式会社 Coating electric wire material and the electric wire being coated
JP7149051B2 (en) 2014-06-30 2022-10-06 ダウ グローバル テクノロジーズ エルエルシー ethylene polymer
BR112016029439B1 (en) 2014-06-30 2022-01-04 Dow Global Technologies Llc PROCESS TO FORM AN OLEFIN-BASED POLYMER
WO2016003878A1 (en) * 2014-06-30 2016-01-07 Dow Global Technologies Llc Catalyst systems for olefin polymerization
KR102521433B1 (en) 2014-07-24 2023-04-14 다우 글로벌 테크놀로지스 엘엘씨 Bis-biphenylphenoxy catalysts for polymerization of low molecular weight ethylene-based polymers
US10870713B2 (en) 2015-09-30 2020-12-22 Dow Global Technologies Llc Procatalyst and polymerization process using the same
WO2018022238A1 (en) 2016-07-28 2018-02-01 Exxonmobile Chemical Patents Inc. Catalyst compositions and use thereof

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Publication number Publication date
CN111164110A (en) 2020-05-15
WO2019067280A1 (en) 2019-04-04
EP3688043A1 (en) 2020-08-05
US20200277412A1 (en) 2020-09-03
KR102590973B1 (en) 2023-10-19
US11242415B2 (en) 2022-02-08
ES2951157T3 (en) 2023-10-18
JP2020535243A (en) 2020-12-03
SA520411657B1 (en) 2023-02-05
WO2019067280A4 (en) 2019-05-23
BR112020006332A2 (en) 2020-09-24
EP3688043B1 (en) 2023-06-14
JP7208981B2 (en) 2023-01-19
KR20200055032A (en) 2020-05-20

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