SG11201803782VA - High pressure, free radical polymerizations to produce ethylene-based polymers - Google Patents

High pressure, free radical polymerizations to produce ethylene-based polymers

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Publication number
SG11201803782VA
SG11201803782VA SG11201803782VA SG11201803782VA SG11201803782VA SG 11201803782V A SG11201803782V A SG 11201803782VA SG 11201803782V A SG11201803782V A SG 11201803782VA SG 11201803782V A SG11201803782V A SG 11201803782VA SG 11201803782V A SG11201803782V A SG 11201803782VA
Authority
SG
Singapore
Prior art keywords
ethylene
international
optionally
dow
pct
Prior art date
Application number
SG11201803782VA
Inventor
Otto J Berbee
Cornelis J F Hosman
Joaquin Flores
Sergio E Goncalves
Sarat Munjal
Michael E Bishop
Luiz Rodriguez
Original Assignee
Dow Global Technologies Llc
Dow Brasil Sudeste Ind Ltda
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc, Dow Brasil Sudeste Ind Ltda filed Critical Dow Global Technologies Llc
Publication of SG11201803782VA publication Critical patent/SG11201803782VA/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/0013—Controlling the temperature of the process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1812—Tubular reactors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00159—Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00162—Controlling or regulating processes controlling the pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761—Details of the reactor
    • B01J2219/00763—Baffles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/08—Low density, i.e. < 0.91 g/cm3
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Abstract

INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property - Organization International Bureau (43) International Publication Date ..... ...sr ,„,„1 18 May 2017 (18.05.2017) WIPO I PCT (10) WO International Publication Number 111111111111311111111111111111111111111111111111111111111111111111111311111111111111111 2017/083559 Al (51) International Patent Classification: (74) Agent: TERRY, Jane M.; The Dow Chemical Company, C08F 2/01 (2006.01) CO8F 10/02 (2006.01) P.O. Box 1967, Midland, Michigan 48641-1967 (US). C08F 2/34 (2006.01) (81) Designated States (unless otherwise indicated, for every (21) International Application Number: kind of national protection available): AE, AG, AL, AM, PCT/US2016/061390 AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, (22) International Filing Date: DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, 10 November 2016 (10.11.2016) HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, (25) Filing Language: English KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, (26) Publication Language: English OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, (30) Priority Data: SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, 15382554.2 10 November 2015 (10.11.2015) EP TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (71) Applicants: DOW GLOBAL TECHNOLOGIES LLC [US/US]; 2040 Dow Center, Midland, MI 48674 (US). (84) Designated States (unless otherwise indicated, for every DOW BRASIL SUDESTE INDUSTRIAL LTDA. kind of regional protection available): ARIPO (BW, GH, [BR/BR]; Av. das NacOes Unidas, 14.171, 4 Floor, Part, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, Diamond Tower, Santo Amaro, 04794-000 Sao Paulo/Sp TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, (BR). TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, (72) Inventors: BERBEE, Otto J.; Postbus 48, 4530 AA LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, Terneuzen (NL). HOSMAN, Cornelis J. F.; Postbus 48, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, 4530 AA Terneuzen FLORES, Joaquin; Autovia (NL). GW, KM, ML, MR, NE, SN, TD, TG). Tarragona Salou, 43006 Tarragona GON- - s/n, (ES). Published: CALVES, Sergio E.; Av. Santos Dumont, 4444, Predio ADM, 11460-902 Guaruja (BR). MUNJAL, Sarat; 2301 — with international search report (Art 21(3)) N. Brazosport Blvd., Building B-2830, Freeport, TX 77541 (US). BISHOP, Michael E.; 1254 Enclave Parkway, Hou- TX 77077 RODRIGUEZ, Luiz; Av. Santos ston, (US). Dumont, 4444, Predio ADM, 11460-902 Guaruja (BR). 1-1 .4t Cr \ In in en of:, (54) Title: HIGH PRESSURE, FREE RADICAL POLYMERIZATIONS TO PRODUCE ETHYLENE-BASED POLYMERS 0 ---- (57) : A process to foiin an ethylene-based polymer, said process comprising at least the following: polymerizing a mixture L 3 / 4 -- comprising ethylene, in the presence of at least one free-radical initiator, and in a reactor configuration comprising at least three re - c action zones and at least two ethylene feed streams; and wherein the inlet pressure of the first reaction zone is less than, or equal to, ei 3200 Bar; and wherein the amount of ethylene, and optionally one or more comonomers, and optionally one or more CTAs, fed to 0 the first reaction zone is from 40 mole% to 80 mole%, based on the total moles of ethylene, and optionally one or more co - monomers, and optionally one or more CTAs, fed to the polymerization; and wherein the average polymerization temperature of the first 40 wt% polymer formed (APT 40 , m ) (based on the total amount of polymer foiined) is less than, or equal to, 200°C.
SG11201803782VA 2015-11-10 2016-11-10 High pressure, free radical polymerizations to produce ethylene-based polymers SG11201803782VA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP15382554.2A EP3168237A1 (en) 2015-11-10 2015-11-10 High pressure, free radical polymerizations to produce ethylene-based polymers
PCT/US2016/061390 WO2017083559A1 (en) 2015-11-10 2016-11-10 High pressure, free radical polymerizations to produce ethylene-based polymers

Publications (1)

Publication Number Publication Date
SG11201803782VA true SG11201803782VA (en) 2018-06-28

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Country Status (9)

Country Link
US (1) US10494457B2 (en)
EP (2) EP3168237A1 (en)
JP (1) JP6937298B2 (en)
KR (1) KR20180081084A (en)
CN (1) CN108473604B (en)
BR (1) BR112018009036B1 (en)
ES (1) ES2776631T3 (en)
SG (1) SG11201803782VA (en)
WO (1) WO2017083559A1 (en)

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Also Published As

Publication number Publication date
ES2776631T3 (en) 2020-07-31
CN108473604B (en) 2020-10-16
BR112018009036A8 (en) 2019-02-26
US20180305476A1 (en) 2018-10-25
BR112018009036A2 (en) 2018-10-30
JP6937298B2 (en) 2021-09-22
WO2017083559A1 (en) 2017-05-18
KR20180081084A (en) 2018-07-13
JP2018532861A (en) 2018-11-08
US10494457B2 (en) 2019-12-03
EP3374405B1 (en) 2020-02-12
BR112018009036B1 (en) 2022-01-04
EP3168237A1 (en) 2017-05-17
CN108473604A (en) 2018-08-31
EP3374405A1 (en) 2018-09-19

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